bluuebunny/crossref_metadata_2025_split huggingface dataset:
Polymerelektrolyte auf Basis ionischer Flüssigkeiten für Batterieanwendungen
Authors: Osada Irene , de Vries Henrik , Scrosati Bruno , Passerini Stefano 
Published: November 2015

AbstractDie Einführung von Festkörper‐Polymerelektrolyten in Lithiumbatterien vor über vierzig Jahren basierte auf der Fähigkeit von Polyethylenoxid (PEO), bestimmte Lithiumsalze zu lösen. Seitdem wurden viele Varianten dieses Systems vorgeschlagen und getestet, unter anderem die Zugabe von herkömmlichen carbonatbasierten Elektrolyten, niedermolekularen Polymeren sowie keramischen Füllstoffen. Dieser Aufsatz gibt einen Überblick über den aktuellen Stand der Forschung zu ternären Polymerelektrolyten, also ionenleitenden Systemen aus einem Polymer und zwei Salzen, eines mit Lithiumkation, das andere mit zusätzlichen Anionen, die das Polymer plastifizieren. Weiterhin werden Grundlagen zu den Wechselwirkungen in Polymerelektrolyten diskutiert, um Überlegungen zu den Herausforderungen und Möglichkeiten von Lithiummetallbatterien anzuregen.
Palladium/Phosphaadamantan‐Katalysator ermöglicht die trans‐selektive Chlorcarbamoylierung von Alkinen
Authors: Le Christine M. , Hou Xiao , Sperger Theresa , Schoenebeck Franziska , Lautens Mark 
Published: November 2015

AbstractEine intramolekulare Palladium(0)‐katalysierte Chlorcarbamoylierung von Alkinen zur Synthese pharmazeutisch relevanter Methylenoxindole wird beschrieben. Dabei wird eine weitgehend unerforschte Klasse von Phosphanliganden verwendet, die sich als besonders geeignet für diese Umwandlung herausstellte und sowohl hohe Reaktivität als auch ausschließliche trans‐Selektivität ermöglicht. Dieser Bericht zeigt die erste übergangsmetallkatalysierte atomeffiziente Addition eines Carbamoylchlorids an ein Alkin.
A Rotational BODIPY Nucleotide: An Environment‐Sensitive Fluorescence‐Lifetime Probe for DNA Interactions and Applications in Live‐Cell Microscopy
Authors: Dziuba Dmytro , Jurkiewicz Piotr , Cebecauer Marek , Hof Martin , Hocek Michal 
Published: November 2015

AbstractFluorescent probes for detecting the physical properties of cellular structures have become valuable tools in life sciences. The fluorescence lifetime of molecular rotors can be used to report on variations in local molecular packing or viscosity. We used a nucleoside linked to a meso‐substituted BODIPY fluorescent molecular rotor (dCbdp) to sense changes in DNA microenvironment both in vitro and in living cells. DNA incorporating dCbdp can respond to interactions with DNA‐binding proteins and lipids by changes in the fluorescence lifetimes in the range 0.5–2.2 ns. We can directly visualize changes in the local environment of exogenous DNA during transfection of living cells. Relatively long fluorescence lifetimes and extensive contrast for detecting changes in the microenvironment together with good photostability and versatility for DNA synthesis make this probe suitable for analysis of DNA‐associated processes, cellular structures, and also DNA‐based nanomaterials.
A Free‐Radical‐Promoted Stereospecific Decarboxylative Silylation of α,β‐Unsaturated Acids with Silanes
Authors: Zhang Lizhi , Hang Zhaojia , Liu Zhong‐Quan 
Published: November 2015

AbstractA stereospecific decarboxylative silylation of acrylic and propiolic acids with silanes was developed. This reaction represents the first example of decarboxylative CSi bond formation and provides an efficient and convenient approach to various synthetically useful alkenyl and alkynyl organosilicon compounds through the reaction of α,β‐unsaturated acids with silanes. Spin‐trapping and EPR experiments support a radical addition/elimination process.
Reaction of Diazo Compounds with Difluorocarbene: An Efficient Approach towards 1,1‐Difluoroolefins
Authors: Zhang Zhikun , Yu Weizhi , Wu Chenggui , Wang Chengpeng , Zhang Yan , Wang Jianbo 
Published: November 2015

AbstractA transition‐metal‐free difluoromethylenation of diazo compounds that proceeds under mild conditions has been developed and is based on the use of TMSCF2Br as the difluoromethylene source and tetrabutylammonium bromide (TBAB) as the promoter. The chemoselective formal carbene dimerization reaction is achieved owing to the electronic properties and the relative stability of the difluorocarbene intermediate.
N‐Linked Glycans of Chloroviruses Sharing a Core Architecture without Precedent
Authors: De Castro Cristina , Speciale Immacolata , Duncan Garry , Dunigan David D. , Agarkova Irina , Lanzetta Rosa , Sturiale Luisa , Palmigiano Angelo , Garozzo Domenico , Molinaro Antonio , Tonetti Michela , Van Etten James L. 
Published: November 2015

AbstractN‐glycosylation is a fundamental modification of proteins and exists in the three domains of life and in some viruses, including the chloroviruses, for which a new type of core N‐glycan is herein described. This N‐glycan core structure, common to all chloroviruses, is a pentasaccharide with a β‐glucose linked to an asparagine residue which is not located in the typical sequon N‐X‐T/S. The glucose is linked to a terminal xylose unit and a hyperbranched fucose, which is in turn substituted with a terminal galactose and a second xylose residue. The third position of the fucose unit is always linked to a rhamnose, which is a semiconserved element because its absolute configuration is virus‐dependent. Additional decorations occur on this core N‐glycan and represent a molecular signature for each chlorovirus.
Preparation and characterization of polysiloxane networks containing metallic platinum particles
Authors: Stochmal Edyta , Strzezik Joanna , Krowiak Agnieszka 
Published: November 2015

ABSTRACTPolysiloxane networks obtained via cross‐linking of D4/V4polysiloxane served as matrices for incorporation of metallic Pt particles. D4/V4polymer used in the crosslinking was synthesized by equilibrium cationic ring‐opening polymerization of the corresponding cyclotetrasiloxane monomers. Linear (HMMH) or cyclic () hydrosiloxanes, at different hydrosiloxane to D4/V4molar ratios, were applied as crosslinking agents. Platinum species were introduced into the crosslinked products from PtCl4solution in THF or in isopropyl alcohol via the reduction of Pt4+to Pt0in the presence of active Si‐H sites. Various analytical techniques: UV‐vis and FTIR spectroscopy, swelling measurements, XRD, SEM, and thermogravimetric analysis were applied to control the progress of the reaction or to characterize the intermediate or final products. IR spectroscopy allowed to determine the efficiency of cross‐linking process and to investigate the consumption of un‐reacted Si‐H groups accompanying the reduction of platinum ions. XRD studies confirmed the incorporation of metallic platinum into all systems. Good thermal stability of obtained products was found using thermogravimetric analysis. According to SEM investigations, the applied network as well as the solvent used in the reduction process influenced the dispersion of metallic particles on the surface of the matrices. The obtained Pt‐systems exhibited mainly redox activity in catalytic isopropyl alcohol conversion used as a test reaction. Significant differences in catalytic properties between systems containing different matrices were observed. The promoting effect on the catalytic activity was found in the case of C‐P type support, i.e. the polysiloxane network obtained using the cyclic hydrosiloxane as the crosslinking agent. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci.2016,133, 43096.
Thermosetting bismaleimide resins generating covalent and multiple hydrogen bonds
Authors: Shibata Mitsuhiro , Satoh Kazuki , Ehara Shouta 
Published: November 2015

ABSTRACTPrepolymerizations of 4,4′‐bismaleimidodiphenylmethane (BMI), diallyl isocyanurate (DAIC), and melamine (ML) at 160–170°C and subsequent compression molding at 200–280°C yielded cured BMI/DAIC/ML resins with feed molar ratios of 4/1/1, 3/1/1, and 2/1/1 (BMI‐DAIC‐ML411, 311, and 211). Similarly, cured BMI/DAIC 1/1 and BMI/ML 3/1 resins (BMI‐DAIC11 and BMI‐ML31) were prepared. The FT‐IR analysis revealed that the maleimide and allyl groups were almost consumed for all the cured resins, and the hydrogen bonding interaction became stronger with decreasing BMI contents for BMI‐DAIC‐MLs. Based on the cured structures elucidated from the FT‐IR result, the numbers of multiple hydrogen bonds and cross‐linking covalent bonds (NMHB and NCB), and total cross‐linking bond energy (ETB) were evaluated to be 0, 7.92, and 618 for BMI‐DAIC‐ML411, 0.71, 7.81, and 627 for BMI‐DAIC‐ML311, and 0.95 mol kg−1, 7.61 mol kg−1, and 617 kcal kg−1 for BMI‐DAIC‐ML211, respectively. A higher order of glass transition and 5% weight loss temperatures for BMI‐DAIC‐MLs was 411 > 311 > 211 in accordance with a higher order of NCB. BMI‐DAIC‐MLs displayed a weak tan δ peak at 70–150°C due to dissociation of the hydrogen bonds. The flexural strength and modulus of BMI‐DAIC‐ML311 were higher than those of BMI‐DAIC‐ML411 in accordance with the difference of ETB. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43121.
Potent oxazoline analog of apratoxin C: Synthesis, biological evaluation, and conformational analysis
Authors: Yoshida Masahito , Onda Yuichi , Masuda Yuichi , Doi Takayuki 
Published: November 2015

ABSTRACTIn this research, the synthesis, biological evaluation, and conformational analysis of an apratoxin C oxazoline analog (3) have been demonstrated. The preparation of synthetic key intermediate 9 was achieved using an improved strategy that involves commercially available 3‐methylglutaric anhydride (12), an enzymatic enantioselective alcoholysis, and a diastereoselective reduction. The Pro‐Dtrina (3,7‐dihydroxy‐2,5,8‐trimethylnonanoic acid) moiety 8 was successfully synthesized in a similar manner as our previously reported synthesis of apratoxin C (1). The cyclization precursor 5 was formed after the coupling of Pro‐Dtrina 8 with a known tetrapeptide 7 to afford a linear peptide 6, the formation of an oxazoline, and the removal of the protecting groups. Finally, the macrolactamization of 5 with O‐(7‐aza‐1H‐benzotriazol‐1‐yl)‐N,N,N′,N′‐tetramethyluronium hexafluorophosphate (HATU)/N,N‐diisopropylethylamine (DIEA) furnished an apratoxin C oxazoline analog (3), which exhibited a potent cytotoxicity against HeLa cells (IC50 value of 22 nM) that was comparable with the cytotoxicity of apratoxin C (1) (IC50 value of 4.2 nM). Conformational analyses of 1 and 3 through NMR experiments showed that oxazoline analog 3 formed a tertiary structure that was similar to the apratoxin C (1) structure in CD3CN, which provided a probable explanation for their comparable cytotoxicities. © 2015 Wiley Periodicals, Inc. Biopolymers (Pept Sci) 106: 404–414, 2016.
Health-related quality of life after pancreatic resection for malignancy
Authors: Heerkens H D , Tseng D S J , Lips I M , van Santvoort H C , Vriens M R , Hagendoorn J , Meijer G J , Borel Rinkes I H M , van Vulpen M , Molenaar I Q 
Published: November 2015

Abstract

Background
Health-related quality of life (QoL) is of major importance in pancreatic cancer, owing to the limited life expectation. The aim of this prospective longitudinal study was to describe QoL in patients undergoing resection for pancreatic or periampullary malignancy.

Methods
QoL was measured on a scale of 0–100 in patients who underwent pancreatic resection for malignancy or premalignancy at the University Medical Centre Utrecht before resection, and 1, 3, 6 and 12 months after surgery. Measures consisted of the RAND-36, the European Organization for Research and Treatment of Cancer (EORTC) core questionnaire (QLQ-C30) and the EORTC pancreatic cancer-specific module (QLQ-PAN26).

Results
Between March 2012 and November 2013, 68 consecutive patients with a malignancy (59 patients) or premalignancy (9) were included. Physical role restriction, social and emotional domains showed a significant and clinically relevant deterioration directly after operation in 53 per cent (RAND-36, P &lt; 0·001), 63 and 78 per cent (QLQ-C30 and RAND-36 respectively, P &lt; 0·001) and 37 per cent (RAND-36, P &lt; 0·001) of patients respectively. Most domains demonstrated recovery to preoperative values or better at 3 months, except for physical functioning. Emotional functioning at 3, 6 and 12 months was better than at baseline (P &lt; 0·001). Symptom scores revealed a deterioration in vitality, pain (P = 0·002), fatigue (P &lt; 0·001), appetite loss (P &lt; 0·001), altered bowel habit (P = 0·001) and side-effects (P &lt; 0·001) after 1 month. After 3 months, only side-effects were worse than preoperative values (P &lt; 0·001).

Conclusion
QoL after pancreatic resection for malignant and premalignant tumours decreased considerably in the early postoperative phase. Full recovery of QoL took up to 6 months after the operation.
Dealing with Relational and Social Challenges After Child Soldiering: Perspectives of Formerly Recruited Youth and Their Communities in Northern Uganda
Authors: Schiltz Julie , Vindevogel Sofie , Broekaert Eric , Derluyn Ilse 
Published: November 2015

AbstractThe reintegration of formerly recruited youth typically engenders a range of relational and social challenges, affecting both formerly recruited youth and the communities to which they return. Yet, research rarely studies the perspectives of community members, hampering the design of much‐needed community‐based interventions. This study aimed to understand how communities in northern Uganda experience and deal with relational and social challenges during the reintegration of youths who were formerly recruited into the Lord's resistance army (LRA). The study was undertaken in 2012 in Lira district. Participatory Ranking Methodology (PRM) was conducted with 267 participants, of whom 49 were formerly recruited youths. The results show five themes that give insight into how communities experience and handle relational and social challenges in the reintegration of formerly recruited youth: (i) letting go of fear, (ii) getting used to life after captivity, (iii) resentment and forgiveness, (iv) reducing insults and nicknaming and (v) coping with ongoing relational and social challenges. We discuss how formerly recruited youths and other community members frame relational and social challenges differently, and value similar resources for different reasons. The results of this study suggest that multiple experiences of and perspectives on relational and social challenges following child soldiering should be taken into account to develop interventions that are supported and valued by the community. Furthermore, interventions should draw upon the strategies that communities have already developed in response to relational and social challenges. Copyright © 2015 John Wiley & Sons, Ltd.
Copper‐Catalyzed 8‐Amido Chelation‐Induced Remote C−H Amination of Quinolines
Authors: Sahoo Harekrishna , Reddy Mallu Kesava , Ramakrishna Isai , Baidya Mahiuddin 
Published: November 2015

AbstractA copper‐catalyzed 8‐amide chelation‐induced remote C−H amination of quinolines has been developed. This direct amination with readily available azodicarboxylates proceeded with perfect C5‐regioselectivity offering amino‐substituted 8‐aminoquinolines, important bioactive molecular scaffolds, in very high yields (up to 96 %). A single‐electron transfer (SET)‐mediated mechanism with kH/kD=1.1 was proposed after trapping of the radical intermediate.
ChemInform Abstract: Synthesis and Structure Determination of Seven Ternary Bismuthides: Crystal Chemistry of the RELi3Bi2 Family (RE: La—Nd, Sm, Gd, and Tb).
Authors: Prakash Jai , Schaefer Marion C. , Bobev Svilen 
Published: November 2015

AbstractLnLi3Bi2 (Ln: La—Nd, Sm, Gd, Tb) are prepared by melting and annealing of stoichiometric amounts of the elements (Nb ampoules in evacuated silica tubes, 1173 K, 1 d; cooling to 1073 K at a rate of 5 K/h, 4 d).
ChemInform Abstract: Effect of X on the Transport Properties of Skutterudites LaFe4X12 (X: P, As and Sb) Compounds.
Authors: Reshak A. H. 
Published: November 2015

AbstractThe effect of substituting P by As and As by Sb on electronic transport properties in LaFe4X12 (X: P, As, Sb) is investigated by calculating the electronic band structures with the all‐electron full‐potential linear augmented plane wave plus local orbitals method within the Becke—Johnson potential.
ChemInform Abstract: Synthesis, Crystal Structure, and Properties of Pentadecafluorotetraantimonate(III) CsRb2Sb4F15.
Authors: Zemnukhova L. A. , Udovenko A. A. , Makarenko N. V. , Fedorishcheva G. A. , Polyantsev M. M. , Kavun V. Ya. 
Published: November 2015

AbstractSingle crystals of isostructural CsRb2Sb4F15 (I) and Cs3Sb4F15 (II) are obtained from aqueous solutions of RbF and/or CsF, and SbF3 in the molar ratios of 0.5:0.5:1 and 0.9:1, respectively.
ChemInform Abstract: Dielectric Relaxations in Multiferroic La2Ti2O7 Ceramics.
Authors: Zhang N. , Li Q. J. , Huang S. G. , Yu Y. , Zheng J. , Cheng C. , Wang C. C. 
Published: November 2015

AbstractThe title ceramics is prepared by solid state reaction of stoichiometric mixtures of La2O3 and TiO2 (1000 °C, 24 h, followed by sintering at 1350 °C for 10 h).
ChemInform Abstract: Electrochemical Preparation of CuBi2O4 Nanoparticles on Nanoporous Stainless Steel as a Binder‐Free Supercapacitor Electrode.
Authors: Ensafi Ali A. , Ahmadi N. , Rezaei B. 
Published: November 2015

AbstractCuBi2O4 nanoparticles are electrochemically deposited on nanoporous stainless steel supports from aqueous HNO3 solutions containing Bi(NO3)3 and Cu(NO3)2 in a molar ratio of 2:1.
ChemInform Abstract: Synthesis of Anhydrous K2TiOF4 via a Mild Hydrothermal Method.
Authors: Felder Justin B. , Yeon Jeongho , zur Loye Hans‐Conrad 
Published: November 2015

AbstractSingle crystals of K2TiOF4 are grown hydrothermally from mixtures of TiF3, KF, HF, and H2O (autoclave, 200 °C, 24 h, 75% yield).
ChemInform Abstract: Single Crystal Growth and Characterization of the Reduced Barium Sodium Siliconiobate, Ba3Na0.32Nb6O12 (Si2O7)2.
Authors: Cortese Anthony J. , Wilkins Branford , Smith Mark D. , Morrison Gregory , zur Loye Hans‐Conrad 
Published: November 2015

AbstractSingle crystals of the title compound are prepared from NaNbO3 in a BaCl2/NaCl eutectic flux in the presence of Zn (evacuated silica tube (wall reaction), 1050 °C, 48 h, ≈75% yield).
ChemInform Abstract: Anionic Ordering and Thermal Properties of FeF3·3H2O.
Authors: Burbano Mario , Duttine Mathieu , Borkiewicz Olaf , Wattiaux Alain , Demourgues Alain , Salanne Mathieu , Groult Henri , Dambournet Damien 
Published: November 2015

AbstractIn view of the potential use of FeF3·0.33H2O with the hexagonal tungsten bronze (HTB) structure as cathode material for batteries from steel industry pickling sludge, β‐FeF3·3H2O is prepared by precipitation from an aqueous solution of Fe(NO3)3 and HF in a 1:4 molar ratio supported by microwave heating (90 °C, 30 min) and followed by cooling and vacuum solvent extraction (85% yield).
ChemInform Abstract: A New Representative of the Cubic Parkerites Family: Synthesis, Crystal and Electronic Structure of Pt3Bi2Se2.
Authors: Zakharova Elena Yu. , Kazakov Sergey M. , Kuznetsov Alexey N. 
Published: November 2015

AbstractPt3Bi2Se2 is prepared by annealing of the elements in stoichiometric quantities (evacuated silica ampoule, 1.
ChemInform Abstract: Catalytic Application of Zwitterionic Palladium Complexes in Mizoroki—Heck Reactions Using Ionic Liquid as Solvent.
Authors: Wang Yi‐Ping , Lee Hon Man 
Published: November 2015

AbstractZwitterionic NHC‐type Pd‐complexes are synthesized, which efficiently catalyze Mizoroki—Heck reactions in ionic liquids.
ChemInform Abstract: Catalytic Asymmetric Hydroamination of Unactivated Internal Olefins to Aliphatic Amines.
Authors: Yang Yang , Shi Shi‐Liang , Niu Dawen , Liu Peng , Buchwald Stephen L. 
Published: November 2015

AbstractEnantiopure alpha‐aliphatic amines are obtained by a copper‐catalyzed hydroamination reaction of unactivated internal olefins.
ChemInform Abstract: Stereoselective Nucleophilic Addition of PhSCF2SiMe3 to Chiral Cyclic Nitrones: Asymmetric Synthesis of gem‐Difluoromethylenated Polyhydroxypyrrolizidines and ‐indolizidines.
Authors: Korvorapun Korkit , Soorukram Darunee , Kuhakarn Chutima , Tuchinda Patoomratana , Reutrakul Vichai , Pohmakotr Manat 
Published: November 2015

AbstractThe title compounds are obtained by a general method involving the sequential stereoselective fluoride‐catalyzed nucleophilic addition of PhSCF2SiMe3 as gem‐difluoromethylene building block to easily available chiral nitrones followed by reductive cleavage of the hydroxy group, N‐alkylation of the obtained pyrrolidines, intramolecular radical cyclization, and hydrogenolysis of the protecting group.
ChemInform Abstract: Organic Synthesis with N‐Heterocyclic Carbenes of Indazole: Synthesis of Benzo(thio)imidates, Benzo[d][1,3]thiazines and Quinazoline‐4‐thiones.
Authors: Guan Zong , Nieger Martin , Schmidt Andreas 
Published: November 2015

AbstractDeprotonation of the starting indazolinium salts (I) provides N‐heterocyclic carbenes.
ChemInform Abstract: Rhenium‐Catalyzed C—H Aminocarbonylation of Azobenzenes with Isocyanates.
Authors: Geng Xiaoyu , Wang Congyang 
Published: November 2015

AbstractAn expedient and atom‐economical access to o‐azobenzamides via an unprecedented chemo‐ and regioselective C—H aminocarbonylation of azobenzenes is described.
ChemInform Abstract: Synthesis of Functionalized Phenols via the Cascade Reactions of Allenic Ketones with β‐Diketones.
Authors: Fan Xuesen , Yan Meng , He Yan , Shen Nana , Zhang Xinying 
Published: November 2015

AbstractA broad spectrum of highly substituted phenols/2‐hydroxyalkyl ketones is readily available in a selective manner in the presence of K2CO3 in different solvents.
ChemInform Abstract: Rhodium(I) Complexes Containing 9,10‐Phenanthrenequinone‐N‐substituted Thiosemicarbazone Ligands: Synthesis, Structure, DFT Study and Catalytic Diastereoselective Nitroaldol Reaction Studies.
Authors: Anitha P. , Manikandan R. , Vijayan P. , Anbuselvi S. , Viswanathamurthi P. 
Published: November 2015

AbstractThe title Rh(I)‐complexes are found to be efficient catalysts in the asymmetric Henry reaction in ionic liquid [emim]BF4.
ChemInform Abstract: Perfluoroalkyl and ‐aryl Zinc Ate Complexes: Generation, Reactivity, and Synthetic Application.
Authors: Wang Xuan , Hirano Keiichi , Kurauchi Daisuke , Kato Hisano , Toriumi Naoyuki , Takita Ryo , Uchiyama Masanobu 
Published: November 2015

AbstractA method for the generation of novel unprecedentedly stable perfluoroalkyl zincates is developed and their coupling reaction with a range of diverse carbonyl compounds is studied.
ChemInform Abstract: Ligand‐Free Palladium‐Catalyzed Hydroxycarbonylation of Aryl Halides under Ambient Conditions: Synthesis of Aromatic Carboxylic Acids and Aromatic Esters.
Authors: Han Wei , Jin Fengli , Zhou Qing 
Published: November 2015

AbstractThe title reaction proceeds in high yields with high selectivity and features simple and scalable operation.
ChemInform Abstract: Direct Access to N‐Alkylsulfoximines from Sulfides by a Sequential Imidation/Oxidation Procedure.
Authors: Dannenberg Carl Albert , Bizet Vincent , Bolm Carsten 
Published: November 2015

AbstractThe imidating agents N‐bromoalkylamines, generated in situ from methyl amines (II) and bromine, react with sulfides [e.g. (I)] to form sulfiliminium, which was subsequently oxidized to sulfoximines [e.g. (III)] in a short time.
ChemInform Abstract: One‐Pot Two‐Step Facile Synthesis of 2,3,5,6‐Tetrafluorobenzonitrile‐Containing Dithiocarbamic Acid Esters.
Authors: Yin Xuguang , Guo Yamei , Liu Cuibo , Wang Zhifang , Zhang Bin 
Published: November 2015

AbstractThe title compounds (IV) and related products (VI) are prepared via nucleophilic substitution of in situ generated thiocarboxylate anions with pentafluorobenzene derivatives.
ChemInform Abstract: Nitromethane as a Cyanating Reagent for the Synthesis of Thiocyanates.
Authors: Wang Zuo‐Hui , Ji Xiao‐Ming , Hu Mao‐Lin , Tang Ri‐Yuan 
Published: November 2015

AbstractNitromethane can serve as a cyanating reagent in the presence of iodine and KOAc.