bluuebunny/crossref_metadata_2025_split huggingface dataset:
Learning and service at the University of Buenos Aires: A theoretical framework guiding the implementation of educational social practices
Authors: García Oscar Gabriel , Hallu Rubén 
Published: June 2017

From 2017 onwards, educational social practices will become obligatory for all students as part of every course at the University of Buenos Aires (UBA), Argentina. For a university with approximately 300 000 students, this is a major change in how higher education is understood. However, its incorporation into the curricula is but the final stage of a clear policy of extensión, developed over decades at UBA, in which the knowledge produced through research and teaching is put into the service of society. In this article, we propose that extensión can be understood as a form of relationship between the university and society, framed by a pedagogical strategy of solidarity learning and service, and implemented through mechanisms that are here called ‘educational social practices’. This article first provides an overview of the different traditions of learning and service, paying particular attention to its development in Latin America, and the emergence in this region of ‘solidarity learning and service’, or situated education. Unlike other forms of learning and service, here, the basic unit of analysis is not the individual or the learning processes, but the reciprocal action; that is, the relational nature of people acting in certain contexts. Next, the article provides a short description of the Comprehensive Community Action Program in Vulnerable Neighborhoods, UBA’s MacJannet Prize–winning program, as a means to illustrate our distinct understanding of extensión in action – relational, situational, pedagogical and the mechanisms that propel it. This successful program has served as a fertile learning ground for the university, informing our understanding of what it means to teach, research and learn. To finish, the article provides a brief overview of these mechanisms by which the university has made whole-of-university participation mandatory: striving towards connectivity, continuity and curricular and social impact.
Particle size dependence of biogenic secondary organic aerosol molecular composition
Authors: Tu Peijun , Johnston Murray V. 
Published: June 2017

Abstract. Formation of secondary organic aerosol (SOA) is initiated by the oxidation of volatile organic compounds (VOCs) in the gas phase whose products subsequently partition to the particle phase. Non-volatile molecules have a negligible evaporation rate and grow particles at their condensation rate. Semi-volatile molecules have a significant evaporation rate and grow particles at a much slower rate than their condensation rate. Particle phase chemistry may enhance particle growth if it transforms partitioned semi-volatile molecules into non-volatile products. In principle, changes in molecular composition as a function of particle size allow non-volatile molecules that have condensed from the gas phase (a surface-limited process) to be distinguished from those produced by particle phase reaction (a volume-limited process). In this work, SOA was produced by β-pinene ozonolysis in a flow tube reactor. Aerosol exiting the reactor was size-selected with a differential mobility analyzer, and individual particle sizes between 35 and 110 nm in diameter were characterized by on- and offline mass spectrometry. Both the average oxygen-to-carbon (O ∕ C) ratio and carbon oxidation state (OSc) were found to decrease with increasing particle size, while the relative signal intensity of oligomers increased with increasing particle size. These results are consistent with oligomer formation primarily in the particle phase (accretion reactions, which become more favored as the volume-to-surface-area ratio of the particle increases). Analysis of a series of polydisperse SOA samples showed similar dependencies: as the mass loading increased (and average volume-to-surface-area ratio increased), the average O ∕ C ratio and OSc decreased, while the relative intensity of oligomer ions increased. The results illustrate the potential impact that particle phase chemistry can have on biogenic SOA formation and the particle size range where this chemistry becomes important.
Four-dimensional variational inversion of black carbon emissions during ARCTAS-CARB with WRFDA-Chem
Authors: Guerrette Jonathan J. , Henze Daven K. 
Published: June 2017

Abstract. Biomass burning emissions of atmospheric aerosols, including black carbon, are growing due to increased global drought, and comprise a large source of uncertainty in regional climate and air quality studies. We develop and apply new incremental four-dimensional variational (4D-Var) capabilities in WRFDA-Chem to find optimal spatially and temporally distributed biomass burning (BB) and anthropogenic black carbon (BC) aerosol emissions. The constraints are provided by aircraft BC concentrations from the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites in collaboration with the California Air Resources Board (ARCTAS-CARB) field campaign and surface BC concentrations from the Interagency Monitoring of PROtected Visual Environment (IMPROVE) network on 22, 23, and 24 June 2008. We consider three BB inventories, including Fire INventory from NCAR (FINN) v1.0 and v1.5 and Quick Fire Emissions Database (QFED) v2.4r8. On 22 June, aircraft observations are able to reduce the spread between a customized QFED inventory and FINNv1.0 from a factor of 3. 5 ( × 3. 5) to only × 2. 1. On 23 and 24 June, the spread is reduced from × 3. 4 to × 1. 4. The posterior corrections to emissions are heterogeneous in time and space, and exhibit similar spatial patterns of sign for both inventories. The posterior diurnal BB patterns indicate that multiple daily emission peaks might be warranted in specific regions of California. The US EPA's 2005 National Emissions Inventory (NEI05) is used as the anthropogenic prior. On 23 and 24 June, the coastal California posterior is reduced by × 2, where highway sources dominate, while inland sources are increased near Barstow by × 5. Relative BB emission variances are reduced from the prior by up to 35 % in grid cells close to aircraft flight paths and by up to 60 % for fires near surface measurements. Anthropogenic variance reduction is as high as 40 % and is similarly limited to sources close to observations. We find that the 22 June aircraft observations are able to constrain approximately 14 degrees of freedom of signal (DOF), while surface and aircraft observations together on 23/24 June constrain 23 DOF. Improving hourly- to daily-scale concentration predictions of BC and other aerosols during BB events will require more comprehensive and/or targeted measurements and a more complete accounting of sources of error besides the emissions.
Benthic foraminiferal Mn / Ca ratios reflect microhabitat preferences
Authors: Koho Karoliina A. , de Nooijer Lennart J. , Fontanier Christophe , Toyofuku Takashi , Oguri Kazumasa , Kitazato Hiroshi , Reichart Gert-Jan 
Published: June 2017

Abstract. The Mn / Ca of calcium carbonate tests of living (rose-Bengal-stained) benthic foraminifera (Elphidium batialis, Uvigerina spp., Bolivina spissa, Nonionellina labradorica and Chilostomellina fimbriata) were determined in relation to pore water manganese (Mn) concentrations for the first time along a bottom water oxygen gradient across the continental slope along the NE Japan margin (western Pacific). The local bottom water oxygen (BWO) gradient differs from previous field study sites focusing on foraminiferal Mn / Ca and redox chemistry, therefore allowing further resolution of previously observed trends. The Mn / Ca ratios were analysed using laser ablation inductively coupled plasma-mass spectrometer (ICP-MS), allowing single-chamber determination of Mn / Ca. The incorporation of Mn into the carbonate tests reflects environmental conditions and is not influenced by ontogeny. The inter-species variability in Mn / Ca reflected foraminiferal in-sediment habitat preferences and associated pore water chemistry but also showed large interspecific differences in Mn partitioning. At each station, Mn / Ca ratios were always lower in the shallow infaunal E. batialis, occupying relatively oxygenated sediments, compared to intermediate infaunal species, Uvigerina spp. and B. spissa, which were typically found at greater depth, under more reducing conditions. The highest Mn / Ca was always recorded by the deep infaunal species N. labradorica and C. fimbriata. Our results suggest that although partitioning differs, Mn / Ca ratios in the intermediate infaunal taxa are promising tools for palaeoceanographic reconstructions as their microhabitat exposes them to higher variability in pore water Mn, thereby making them relatively sensitive recorders of redox conditions and/or bottom water oxygenation.
Factors Predicting the Outcomes of Incomplete Triple Pelvic Osteotomy
Authors: Eceviz Engin , Uygur Esat , Söylemez Mehmet S. , Eren Abdullah 
Published: June 2017

Introduction In the present study, we identified factors affecting the outcomes of patients who underwent incomplete triple pelvic osteotomies due to acetabular dysplasia. Methods Data on a total of 58 hips in 50 patients for whom adequate data were available and who had undergone appropriate follow-up were retrospectively evaluated. We used Ömeroğlu scores for radiological evaluation, Harris Hip Scores for clinical evaluation, Tönnis scores to evaluate osteoarthritis progression and a modified Clavien-Dindo classification to evaluate complications. Results The average patient age was 23.26 (14-47) years, and the average follow-up duration 105.59 (18-191) months. The complication rate was 10.3%, and complications negatively influenced clinical outcomes. Patients with radiologically poorer outcomes had more advanced osteoarthritis. We found minimal improvements in lateral centre edge angle (LCEA), refined centre-edge angle (RCEA), and lateral acetabulum head index (LAHI) were associated with osteoarthritis progression and that good improvements in LCEA, RCEA, acetabular angle (AA), and LAHI were associated with radiological outcomes. Neither patient age at the time of operation nor development of a postoperative relative crossover sign affected osteoarthritis progression or clinical or radiological outcomes. Conclusions The most important factors influencing clinical outcomes were complications. However, neither postoperative acetabular retroversion nor a positive supra-equatorial crossover sign (often viewed as prognostically negative) directly affected clinical outcomes. When treating patients with acetabular dysplasia, either inadequate correction or overcorrection may negatively affect outcomes. In such patients, an incomplete triple pelvic osteotomy (allowing controlled correction) is both safe and effective.
Association between omeprazole use and Clostridium difficile infection among hospitalized patients: A case–control study of the Saudi population
Authors: Al Otaibi Hazza , Ahmed Anwar E. , Alammari Maha 
Published: June 2017

Background: While few international studies have assessed the association between omeprazole use and the risk of Clostridium difficile infection (CDI), research into this is lacking in Saudi Arabia and the Middle East region. The aim of this study was to determine whether exposure to omeprazole is associated with the risk of Clostridium difficile infection in a sample of hospitalized Saudi patients. Methodology: A retrospective matched case–control study was conducted at the King Abdulaziz Medical City in Riyadh, Saudi Arabia, from 1 August 2010 through 31 July 2015. The analysis included a total of 200 patients: 100 CDI cases and 100 matched controls. Results: The majority (60%, 120 out of 200) of patients had received proton pump inhibitors (PPIs), and a minority (18.5%, 37 out of 200) had received omeprazole. The PPI use was insignificantly higher in CDI cases than in controls. However, the use of omeprazole was significantly higher in CDI cases compared with controls. Specifically, patients receiving omeprazole were two times more likely to develop CDI compared with controls (aOR = 2.1, 95% confidence interval (CI) = (1.007–4.437)). After adjusting for potential predictors of CDI, watery diarrhea (aOR = 59.1, 95% CI = 19.831–175.974) and abdominal pain (aOR = 7.5, 95% CI = 2.184–25.445) were found to be independent predictors of CDI. Conclusions: The data suggests that PPIs were commonly used in patients admitted to King Abdulaziz Medical City in Riyadh: six out of ten patients received PPIs. The findings support a possible association between the use of omeprazole and a high risk of CDI. To confirm causality, the link between omeprazole and CDI should be assessed in a large interventional study.
Rapid On-Site Evaluation of Endobronchial Ultrasound–Guided Transbronchial Needle Aspirations for the Diagnosis of Lung Cancer: A Perspective From Members of the Pulmonary Pathology Society
Authors: Jain Deepali , Allen Timothy Craig , Aisner Dara L. , Beasley Mary Beth , Cagle Philip T. , Capelozzi Vera Luiza , Hariri Lida P. , Lantuejoul Sylvie , Miller Ross , Mino-Kenudson Mari , Monaco Sara E. , Moreira Andre , Raparia Kirtee , Rekhtman Natasha , Roden Anja Christiane , Roy-Chowdhuri Sinchita , da Cunha Santos Gilda , Thunnissen Erik , Troncone Giancarlo , Vivero Marina 
Published: June 2017

Context.—Endobronchial ultrasound–guided transbronchial needle aspiration (EBUS-TBNA) has emerged as a very useful tool in the field of diagnostic respiratory cytology. Rapid on-site evaluation (ROSE) of EBUS-TBNA not only has the potential to improve diagnostic yield of the procedure but also to triage samples for predictive molecular testing to guide personalized treatments for lung cancer.Objective.—To provide an overview of the current status of the literature regarding ROSE of EBUS-TBNA in the diagnosis of lung cancer.Data Sources.—An electronic literature search in PubMed and Google databases was performed using the following key words: cytology, lung cancer, on-site evaluation, rapid on-site evaluation, and ROSE EBUS-TBNA. Only articles published in English were included in this review.Conclusions.—Rapid on-site evaluation can ensure that the targeted lesion is being sampled and can enable appropriate specimen triage. If available, it should be used with EBUS-TBNA in the diagnosis of lung cancer because it can minimize repeat procedures for additional desired testing (ie, molecular studies). Some studies have shown that ROSE does not adversely affect the number of aspirations, total procedure time of EBUS-TBNA, or the rate of postprocedure complications; it is also helpful in providing a preliminary diagnosis that can reduce the number of additional invasive procedures, such as mediastinoscopy. As EBUS technology continues to evolve, our knowledge of the role of ROSE in EBUS-TBNA for the diagnosis of lung cancer will also continue to grow and evolve.
Utility of a time frame in assessing psychological pain and suicide ideation
Authors: Meerwijk Esther L. , Weiss Sandra J. 
Published: June 2017

Background
Assessing psychological pain has been recommended as an integral part of a comprehensive suicide risk assessment. The Psychache Scale, an established measure of psychological pain, does not specify a time frame for when pain is experienced, which may inadvertently increase the likelihood of identifying individuals as being at elevated suicide risk when they complete the Psychache Scale based on psychological pain experienced at some undefined time in the past.

Methods
We conducted a national general population survey among United States adults to determine whether addition of a time frame to the instructions of the Psychache Scale would more accurately reflect current psychological pain and more effectively identify people with current suicide ideation. A between-subjects design was used where respondents were randomized to complete the original Psychache scale or a modified scale with time frame. Data were collected online from September 2015 to June 2016. A total of 242 respondents had complete psychological pain data: 133 completed the original Psychache Scale and 109 completed the Psychache Scale with time frame.

Results
Addition of a time frame did not result in differences in psychological pain scores. However, when screening for participants with current suicide ideation, 13% fewer false positives were observed with the modified scale at higher cut-off values than previously reported (38 vs. 24). The substantial increase in positive predictive value suggests that a time frame is a worthwhile addition to the Psychache Scale.

Discussion
We recommend using the Psychache Scale with a time frame and testing the cut-off score for suicide ideation in population samples that reflect the general population more accurately. Psychological pain cut-off scores in clinical samples have yet to be established.
Influences on the location of repeating earthquakes determined from a and b value imaging
Authors: Kawamura Masashi , Chen Kate Huihsuan 
Published: June 2017

AbstractTo explore where earthquakes tend to recur, we statistically investigated repeating earthquake catalogs and background seismicity from different regions (Parkfield, Hayward, Calaveras, and Chihshang Faults). We show that the location of repeating earthquakes can be mapped using the spatial distribution of the seismic a and b values obtained from the background seismicity. Molchan's error diagram statistically confirmed that repeating earthquakes occur within areas with high a values (2.8–3.8) and high b values (0.9–1.1) on both strike‐slip and thrust fault segments. However, no significant association held true for fault segments with more complicated geometry or for wider areas with a complex fault network. The productivity of small earthquakes responsible for high a and b values may thus be the most important factor controlling the location of repeating earthquakes. We inferred that the location of high creep rate in planar/listric fault structures might be indicated by a values of ~3 and b values of ~1.
Zircon, titanite, and apatite (U‐Th)/He ages and age‐eU correlations from the Fennoscandian Shield, southern Sweden
Authors: Guenthner William R. , Reiners Peter W. , Drake Henrik , Tillberg Mikael 
Published: June 2017

AbstractCraton cores far from plate boundaries have traditionally been viewed as stable features that experience minimal vertical motion over 100–1000 Ma time scales. Here we show that the Fennoscandian Shield in southeastern Sweden experienced several episodes of burial and exhumation from ~1800 Ma to the present. Apatite, titanite, and zircon (U‐Th)/He ages from surface samples and drill cores constrain the long‐term, low‐temperature history of the Laxemar region. Single grain titanite and zircon (U‐Th)/He ages are negatively correlated (104–838 Ma for zircon and 160–945 Ma for titanite) with effective uranium (eU = U + 0.235 × Th), a measurement proportional to radiation damage. Apatite ages are 102–258 Ma and are positively correlated with eU. These correlations are interpreted with damage‐diffusivity models, and the modeled zircon He age‐eU correlations constrain multiple episodes of heating and cooling from 1800 Ma to the present, which we interpret in the context of foreland basin systems related to the Neoproterozoic Sveconorwegian and Paleozoic Caledonian orogens. Inverse time‐temperature models constrain an average burial temperature of ~217°C during the Sveconorwegian, achieved between 944 Ma and 851 Ma, and ~154°C during the Caledonian, achieved between 366 Ma and 224 Ma. Subsequent cooling to near‐surface temperatures in both cases could be related to long‐term exhumation caused by either postorogenic collapse or mantle dynamics related to the final assembly of Rodinia and Pangaea. Our titanite He age‐eU correlations cannot currently be interpreted in the same fashion; however, this study represents one of the first examples of a damage‐diffusivity relationship in this system, which deserves further research attention.
Detrital zircon microtextures and U‐PB geochronology of Upper Jurassic to Paleocene strata in the distal North American Cordillera foreland basin
Authors: Finzel E. S. 
Published: June 2017

AbstractDetrital zircon surface microtextures, geochronologic U‐Pb data, and tectonic subsidence analysis from Upper Jurassic to Paleocene strata in the Black Hills of South Dakota reveal provenance variations in the distal portion of the Cordillera foreland basin in response to tectonic events along the outboard margin of western North America. During Late Jurassic to Early Cretaceous time, nonmarine strata record initially low rates of tectonic subsidence that facilitated widespread recycling of older foreland basin strata in eolian and fluvial systems that dispersed sediment to the northeast, with minimal sediment derived from the thrust belt. By middle Cretaceous time, marine inundation reflects increased subsidence rates coincident with a change to eastern sediment sources. Lowstand Albian fluvial systems in the Black Hills may have been linked to fluvial systems upstream in the midcontinent and downstream in the Bighorn Basin in Wyoming. During latest Cretaceous time, tectonic uplift in the study area reflects dynamic processes related to Laramide low‐angle subduction that, relative to other basins to the west, was more influential due to the greater distance from the thrust load. Provenance data from Maastrichtian and lower Paleocene strata indicate a change back to western sources that included the Idaho‐Montana batholith and exhumed Belt Supergroup. This study provides a significant contribution to the growing database that is refining the tectonics and continental‐scale sediment dispersal patterns in North America during Late Jurassic‐early Paleocene time. In addition, it demonstrates the merit of using detrital zircon grain shape and surface microtextures to aid in provenance interpretations.
CO2 Methanation on Nickel Catalysts Supported on Mesoporous High‐Surface‐Area MgSiO3
Authors: Ghods Bahare , Rezaei Mehran , Meshkani Fereshteh 
Published: June 2017

AbstractNickel catalysts prepared on high‐surface‐area mesoporous MgSiO3 were synthesized and applied in methanation of CO2. N2 adsorption analysis confirmed the presence of the mesoporous structure on the synthesized samples and revealed that the increase in nickel content resulted in a shift of the pore size distributions to smaller pore sizes. Temperature‐programmed reduction analysis illustrated an improvement in reducibility of the catalysts by a higher nickel content. Catalytic results indicated enhanced CO2 conversion with the increase in nickel percentage up to 15 wt %. The catalysts with higher percentage of nickel provided lower CO2 conversion and CH4 selectivity. The %15Ni/MgSiO3 catalyst exhibited high catalytic stability under optimized conditions.
Multi‐objective Optimization‐Tool for the Universal Application in Chemical Process Design
Authors: Ernst Philipp , Zimmermann Kristina , Fieg Georg 
Published: June 2017

AbstractA universally applicable procedure for multi‐objective optimization of chemical processes is developed. A set of known methods and procedures is adapted, combined with newly developed concepts, and integrated into the developed optimization tool, namely, the Adv:ProcessOptimizer. It allows for efficient, comfortable, and robust optimization of a process which is modeled in one of the various linked commercial simulation tools. As a result, the application of the process design with an overlaid optimization is easily accessible for academia and process industry. The industrial styrene process was optimized in order to validate the method. The results show a very densely and mostly equally crowded Pareto front and considerable savings in investment as well as operating costs compared to two reference designs.