bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Nitrogen‐Tellurium‐Containing Heterocycles. Part 2. Synthesis of 2‐Substituted Benzotellurazoles.
Authors: SADEKOV I. D. , ABAKAROV G. M. , SHNEIDER A. A. , KUREN' S. G. , STARIKOV A. G. , GARNOVSKII A. D. , MINKIN V. I. 
Published: May 2016

AbstractCyclization of the carboxylic o‐methyltellurophenylamides (I) to give the benzotellurazoles (II) proceeds either directly or via the imidoyl chlorides (III).
ChemInform Abstract: A New Type of Catenand: Interlocked Macrocycles Held Together by Intramolecular Sandwich Benzo‐15‐crown‐5 Potassium Complexes.
Authors: BEER P. D. , ROTHIN A. S. 
Published: May 2016

AbstractThe new crown ether ligand (I), obtained from the condensation of the appropriate bis(bromomethyl)bipyridine derivative and 4‐hydroxymethylbenzo‐15‐crown‐5 in the presence of NaH reacts via bipyridine bound Cu complexes to give the novel catenand (II) (no yield given).
ChemInform Abstract: Uranium Alkoxide Chemistry. Part 3. tert.‐Butyl Isocyanide Adducts of Tris(2,6‐di‐tert.‐butylphenoxy)uranium(III).
Authors: VAN DER SLUYS W. G. , SATTELBERGER A. P. 
Published: May 2016

AbstractThe coordinatively unsaturated U(III) complex (I) is capable of binding one or two tert.‐butyl isocyanide ligands (II) to give the adducts (III).
ChemInform Abstract: Dimeric Complex of a Reduced Nitroxyl Radical with Bis(hexafluoroacetylacetonato)manganese(II).
Authors: CARDUCCI M. D. , DOEDENS R. J. 
Published: May 2016

AbstractIn the course of the formation of the dimeric complex (III) (space group C2/c, Z=4) the nitronyl nitroxyl (II) has undergone deoxygenation and reduction to the amidine oxide.
ChemInform Abstract: Reduction of ReCl5 in the Presence of PMePh2 to Give mer‐ReCl3(PMePh2)3, ReCl(η2‐H2)(PMePh2)4, ReH3(PMePh2)4, or ReCl(CO)3(PMePh2)2, Depending on Conditions.
Authors: COTTON F. A. , LUCK R. L. 
Published: May 2016

AbstractThe direct reduction of ReCl5 in the presence of phosphines is a good synthetic route to low‐valent Re complexes.
ChemInform Abstract: (η5‐1‐Substituted‐Pentadienyl)(tricarbonyl)iron(+1) Cations: Reactivity with Alkynyl Nucleophiles.
Authors: DONALDSON W. A. , RAMASWAMY M. 
Published: May 2016

AbstractThe alkynylcuprates (II) react with the cationic η5‐pentadienyliron complexes (I) to yield the E,Z‐dienyne derivatives (III), whereas (Ib) and the 1‐silylacetylenes (IV) produce the E,E‐configurated analogues (V).
ChemInform Abstract: Concerning the Reaction of (η5‐1‐Methoxycarbonylpentadienyl)(tricarbonyl)iron(+1) with Malonate Anion: A Structural Correction.
Authors: DONALDSON W. A. , RAMASWAMY M. 
Published: May 2016

AbstractIn contrast to previous communications, coupling of the η5‐pentadienyliron complex (I) with the lithiated malonate (II) gives the σ,π‐allyl complex (III) as the predominating primary product and only minor amounts of the diene complex (IV).
ChemInform Abstract: Synthesis and Structure of Fe(C5(CH2Ph)5)2 and Lu(C8H8)(C5(CH2Ph)5).
Authors: SCHUMANN H. , JANIAK C. , KOEHN R. D. + , LOEBEL J. , DIETRICH A. 
Published: May 2016

AbstractDecabenzylferrocene (III) and (cyclooctatetraenyl)(pentabenzylcyclopentadienyl)lutetium (VI) are prepared by treatment of the corresponding metal chlorides (I) or (IV) with the metalated pentabenzylcyclopentadienes (II) or (V).
ChemInform Abstract: Synthesis and Crystal and Molecular Structure of the Dimetalated Olefin Complex (Rh2(H3CN(P(OCH3)2)2)4(μ‐H3CO2CCCCO2CH3))(ClO4)2·CH3OH.
Authors: MAGUE J. T. 
Published: May 2016

AbstractThe binding of the acetylene (II) to the complexes (I) to form the compounds (III) causes one end to each chelating ligand to swing away from the center of the cation by ca. 90° and the metal‐metal distance to decrease in the adducts (for (IIIb): space group P21, Z=2).
ChemInform Abstract: An Unusual Mixed‐Metal Cluster: Synthesis and Molecular Structure of FePt5(CO)9(PEt3)4.
Authors: BENDER R. , BRAUNSTEIN P. , BAYEUL D. , DUSAUSOY Y. 
Published: May 2016

AbstractThe reaction of Na2(Fe(CO)4) with cis‐PtCl2(PEt3)2 in THF yields cluster complexes of nuclearities 3, 5 and 6, and the new hexanuclear heterometallic cluster (I).
ChemInform Abstract: Bi‐ and Trinuclear PtAg Complexes with or Without Pt‐Ag Bonds. Molecular Structure of (PPh3(C6Cl5)ClPt(μ‐Cl)AgPPh3).
Authors: USON R. , FORNIES J. , TOMAS M. , ARA I. , CASAS J. M. 
Published: May 2016

AbstractThe 1:2 molar reaction of the platinate (I) with the Ag(I) compounds (II) results in formation of the chloride‐bridged trinuclear complexes (III).
ChemInform Abstract: Formation of 1:1‐Adducts Between Bis(1,2‐Diaryl‐1,2‐ethylenedithiolato)metal(0) (Metal = Ni, Pd, and Pt) and Quadricyclane and Their Photodissociation.
Authors: KAJITANI M. , KOHARA M. , KITAYAMA T. , AKIYAMA T. , SUGIMORI A. 
Published: May 2016

AbstractThe dithiolatometal complexes (I) are synthesized by the reaction of thiophosphoric acid esters of dithiobenzoins with nickel, palladium, or platinum salts.
ChemInform Abstract: Mesoionic Compounds with a Bridgehead Nitrogen Atom. Part 15. Symmetric Polymethine Dyes from Mesoionic Thiazoloazinium Oxides.
Authors: FEDOTOV K. V. , KACHKOVSKII A. D. , ROMANOV N. N. , TOLMACHEV A. I. 
Published: May 2016

AbstractSymmetric polymethine dyes such as (III), (VI), or (IX) are prepared from the corresponding mercaptoacetic acids (I), (IV), or (VII) by common methods.
ChemInform Abstract: New Sensitizers for Photodynamic Therapy: Controlled Synthesis of Purpurins and Their Effect on Normal Tissue.
Authors: MORGAN A. R. , RAMPERSAUD A. , GARBO G. M. , KECK R. W. , SELMAN S. H. 
Published: May 2016

AbstractThe nickel porphyrinaldehydes (Ia) undergo Wittig olefination with the ester (II) to give the acrylic esters (Ib) which are transformed into the demetalated porphyrins (III).
ChemInform Abstract: 3‐Amino‐2H‐azirines in the Synthesis of Peptides: Tetrapeptides with α,α‐Disubstituted α‐Amino Acids.
Authors: SAHEBI M. , WIPF P. , HEIMGARTNER H. 
Published: May 2016

AbstractAzirines of type (IV) are used for the synthesis of tetrapeptides, e.g. (V).
ChemInform Abstract: Preparation of Heterocyclic Amino Acids via Intramolecular Mukaiyama Aldol Condensation: Synthesis of a Novel Cycloleucine Analogue.
Authors: WALKER D. M. , LOGUSCH E. W. 
Published: May 2016

AbstractHomoserine (I) is converted to the tris‐protected derivative (VII) which reacts with LDA and chlorotrimethylsilane (VIII), forming the aminoketene acetal (IX).
ChemInform Abstract: Nucleophilic Substitution Reactions with 6β‐Chloro‐6‐deoxycodeine.
Authors: KALININ V. N. , KAZANTSEVA S. A. , PETROVSKII P. V. , KOBEL'KOVA N. I. 
Published: May 2016

AbstractThe reaction between the title compound (I) and carbon acid derivatives, viz.
ChemInform Abstract: Absolute Configuration of (2‐Amino‐1‐hydroxyethyl)phosphonic Acid from Acanthamoeba castellanii (Neff) ‐ Preparation of Phosphonic Acid Analogues of (+)‐ and (‐)‐Serine.
Authors: HAMMERSCHMIDT F. , VOELLENKLE H. + 
Published: May 2016

AbstractThe compound (I) and its enantiomer are prepared by resolution of the racemate, and an X‐ray analysis of the (I)‐derived urethane (III) is performed (P212121; Z=4).
ChemInform Abstract: Synthesis of 1β‐Methylcarbapenem Key Intermediates Involving the Labile Acyl Auxiliary 4,4‐Dimethyl‐1,3‐oxazolidine‐2‐thione.
Authors: DEZIEL R. , FAVREAU D. 
Published: May 2016

AbstractThe chiral amide (III), prepared by coupling of the azetidinone (I) with the tin triflate (II), reacts with the nucleophiles (IV) under substitution of the oxazolidinethione moiety, forming the carbapenem precursors (V).
ChemInform Abstract: Stereoselective Synthesis of Methyl (1R)‐trans‐ and (1R)‐cis‐Hemicaronaldehydes from Natural Tartaric Acid: Application to the Synthesis of (S)‐Bioallethrin and Deltamethrin Insecticides.
Authors: KRIEF A. , DUMONT W. , PASAU P. , LECOMTE PH. 
Published: May 2016

AbstractWittig‐Horner or Wittig reaction of the dialuminate derived from the natural tartaric acid derivative (I) leads either to the E,E‐ or Z,Z‐configurated chiral diesters (IV) or (V).
ChemInform Abstract: Electrical and Metallurgical Characterization of Niobium as a Diffusion Barrier Between Aluminum and Silicon for Integrated Circuit Devices.
Authors: FARAHANI M. M. , TURNER T. E. , BARNES J. J. 
Published: May 2016

AbstractIt is found that niobium is an excellent diffusion barrier to Al and Si that is thermally much more stable than titanium.
ChemInform Abstract: Production of NF(a1δ) by Dissociation of Fluorine Azide.
Authors: BENARD D. J. , WINKER B. K. , SEDER T. A. , COHN R. H. 
Published: May 2016

AbstractIn contrast to the reactions of vibrationally excited HF or DF molecules with FN3, which are shown to dissociate the azide without yielding metastable NF fragments, thermal dissociation of FN3 yields metastable NF(a1Δ) (activation energy ∼0.6 eV) with near‐unit efficiency.
ChemInform Abstract: Crystal Structures of the Double Pyrovanadates BaMV2O7 (M: Ca, Cd, Zn).
Authors: MURASHOVA E. V. , VELIKODNYI YU. A. , TRUNOV V. K. 
Published: May 2016

AbstractSingle crystals of the title compounds are prepared from the melts M2V2O7‐Ba2V2O7 by slow cooling.
ChemInform Abstract: Adsorption of Water on ZSM5 Zeolites.
Authors: JENTYS A. , WARECKA G. , DEREWINSKI M. , LERCHER J. A. 
Published: May 2016

AbstractThe surface chemistry of water adsorbed on HZSM5 and a series of alkali‐metal ZSM5 is studied at pressures between 10‐5 and 1 mbar by using mainly time‐resolved transmission absorption IR spectroscopy for analysis.
ChemInform Abstract: Characterization of Supported Palladium Catalysts. Part 2. Pd/SiO2.
Authors: JUSZCZYK W. , KARPINSKI Z. 
Published: May 2016

AbstractThe selectivity of the 0.76 wt.% Pd/SiO2 catalyst for isomerization of neopentane is found to be much higher after high‐temp.
ChemInform Abstract: Laser Flash Photolysis of Chlorine Dioxide: Formation and Ultaviolet Absorption Spectrum of Cl2O3.
Authors: COLUSSI A. J. , REDMOND R. W. , SCAIANO J. C. 
Published: May 2016

AbstractThe kinetic and spectroscopic results obtained for the photodecomposition of ClO2 in CFCl3 solution following nanosecond pulsed 337.1 nm irradiation show that the instantaneous photochemical bleaching is followed by a slower bleaching which obeys pseudo‐first‐order kinetics and leads to the formation of a long‐lived transient species having an absorption spectrum with λmax ∼280 nm.
ChemInform Abstract: Synthesis and Identification by IR Spectroscopy of Gaseous Nitryl Bromide, BrNO2.
Authors: FINLAYSON‐PITTS B. J. , LIVINGSTON F. E. , BERKO H. N. 
Published: May 2016

AbstractThe reactions of N2O5 with solid NaBr and gaseous BrNO at 298 K in 1 atm helium are shown to yield gas‐phase BrNO2 by using FTIR spectroscopy.
ChemInform Abstract: Synthesis and Structure of Dirubidium Oxotetrafluorotellurate(IV) Rb2TeOF4.
Authors: BASTIDE J. P. , GERMAIN P. , PERACHON G. 
Published: May 2016

AbstractThe new title compound (IV) forms orthorhombic crystals and is isostructural with the related M2TeOF4 (M = K, Cs).
ChemInform Abstract: On the Structure of Dicyanoacetates.
Authors: NEIDLEIN R. , KIKELJ D. , KRAMER W. , SUI Z. , BOESE R. , BLAESER D. + , KOCJAN D. 
Published: May 2016

AbstractAccording to 13C NMR and FT‐IR spectra, the title compounds (8 examples) in aprotic solvents favor structure (I), whereas solvents with good hydrogen‐bond‐accepting ability favor formation and dissociation of enols (II).
ChemInform Abstract: Lanthanoid‐Anion Complexation of a New Polyaminopolycarboxylate, DTTAP.
Authors: SAWYER D. J. , POWELL J. E. 
Published: May 2016

AbstractFrom pH measurements in a simulated potentiometric titration the protonation constants for the title ligand (I) and the stability constants of its complexes with the lanthanoids La‐Lu are determined.
ChemInform Abstract: A Stereospecific Convergent Coupling of Nucleophilic and Electrophilic Chiral Carbons.
Authors: MATTESON D. S. , TRIPATHY P. B. , SARKAR A. , SADHU K. M. 
Published: May 2016

AbstractThe optically active boronic ester (I) is transformed into the stannyl ether (IV), whose lithio derivative undergoes stereospecific coupling with a second molecule of (I) to give the boronate (V), a precursor of the dialcohol (VI).
ChemInform Abstract: Studies for Control of the Ni(CO)4‐Promoted Carbonylative Cycloaddition of Allyl Halides and Acetylenes.
Authors: CAMPS F. , COLL J. , MORETO J. M. , TORRAS J. 
Published: May 2016

AbstractThe influence of the solvent and the substitution pattern of the educts on the reaction of acetylenes such as (II), (VIII), and (XI) with allyl chloride (I) and nickel tetracarbonyl (III) are studied.
ChemInform Abstract: Palladium‐Catalyzed Carbonylation of Aromatic Aldehydes and Hydrocarbons. A Novel Synthetic Route to α‐Keto Amides via C‐H Activation.
Authors: OZAWA F. , YAMAGAMI I. , NAKANO M. , FUJISAWA F. , YAMAMOTO A. 
Published: May 2016

AbstractQuinoline‐8‐carbaldehyde (I) reacts with sodium tetrachloropalladate to give an aroylpalladium complex intermediate which undergoes carbonylation reaction with carbon monoxide (III), forming the α‐keto amide (IV), together with a small amount of the oxamide (V).
ChemInform Abstract: Reaction of (E)‐β‐Enamino Amides with Dimethyl Acetylenedicarboxylate (DMAD): Formation of Benzene Derivatives, Enamino Esters, and 2‐Pyridones.
Authors: NUVOLE A. , PAGLIETTI G. 
Published: May 2016

AbstractThe addition reaction of the (E)‐enamino amides (I) with the diester (II) is shown to be influenced by the stereochemistry of the intermediates and the amine component of the enamine system.
ChemInform Abstract: Synthesis of Fluorine‐Containing Nitro Compounds.
Authors: MALIK A. A. , ARCHIBALD T. G. , TZENG D. , GRAVER L. C. , BAUM K. 
Published: May 2016

AbstractSubstitution reaction of the polyfluoroalkyl iodides (I) and (V) with sodium nitrite (II) yields the nitro compounds (III) and (VI).
ChemInform Abstract: Optically Active 2‐Vinylcyclobutanones.
Authors: SALAUN J. , KARKOUR B. , OLLIVIER J. 
Published: May 2016

AbstractEnzymatic resolution of the diester (±)‐(I) leads to the diester (R)‐(+)‐(I) and the ester (S)‐(‐)‐(II) which are used for the preparation of the title cyclobutanones (VIII) and (XI), respectively.
ChemInform Abstract: Preparation and Cyclization Reactions of 3‐Carboxy‐4‐naphthylbut‐3‐enoic Acids.
Authors: GUIRGUIS N. R. , AWAD B. M. , EL‐MARIAH F. A. A. 
Published: May 2016

AbstractThe condensation of α‐naphthaldehyde (I) with the diester (II) under Stobbe conditions gives the hemiester (III), which is further converted to the derivatives (IV), (VI), and (VII).
ChemInform Abstract: Autoassembly of Cage Structures. Part 1. Synthesis, Stereochemistry, and Cyclization of α,α′‐Dihydroxy‐α,α′‐dimethyl‐ and ‐α‐methyl‐α′‐ethylglutaric Acid Derivatives.
Authors: KOSTYANOVSKII R. G. , LESHCHINSKAYA V. P. , EL'NATANOV YU. I. , ALIEV L. E. , CHERVIN I. I. 
Published: May 2016

AbstractTreatment of the β‐diketones (I) with potassium cyanide (II) gives the cyclic imides (III) and (IV) or the lactones (XI) and (XII) depending on the molar ratio and the working up procedure.
ChemInform Abstract: Synthesis of 5‐Substituted 5‐Hydroxy‐2‐pyrrolidones, Metabolites of the Antipsychotic Benzamide Remoxipride.
Authors: GAWELL L. , HAGBERG C.‐E. , HOEGBERG T. + , WIDMAN M. 
Published: May 2016

AbstractThe syntheses are described.
ChemInform Abstract: Conformationally‐Restricted Analogues of the Muscarinic Agent N‐Methyl‐N‐(1‐methyl‐4‐pyrrolidino‐2‐butynyl)acetamide.
Authors: LUNDKVIST J. R. M. , RINGDAHL B. , HACKSELL U. 
Published: May 2016

AbstractStarting with the silyloxohexynoate (I), the aminoalkynyl‐substituted pyrrolidones (IX) are prepared as shown in the reaction scheme.
ChemInform Abstract: Catalytic Reaction of Methyl Diazoacetate with 1‐Methyl‐2‐alkenylpyrroles.
Authors: SHOSTAKOVSKII V. M. , MUSAEV A. U. , VASIL'VITSKII A. E. , GULIEV A. M. , NEFEDOV O. M. 
Published: May 2016

AbstractCopper(I) chloride‐catalyzed reaction of methyl diazoacetate (II) with the vinylpyrroles (I) yields mixtures of the cyclopropanecarboxylates (III) and the pyrroleacetates (IV) and (V).
ChemInform Abstract: Antiviral Activity of 1‐Amino‐1,2,3,4‐tetrahydrocarbazoles.
Authors: AKALAEVA T. V. , BOKANOV A. I. , IVANOV P. YU. , NIKOLAEVA I. S. , PUSHKINA T. V. , FOMINA A. N. , SHVEDOV V. I. 
Published: May 2016

AbstractIn continuation of studies of the antimicrobical activity in the 1‐amino‐1,2,3,4‐tetrahydrocarbazole series, the compounds (IV) are prepared by reductive amination of the carbazolones (I).
ChemInform Abstract: Renal Vasodilators. The Role of the 4‐Substituent in 3‐Isoquinolinol Cardiovascular Agents: 4‐Ureido Derivatives of 3‐Isoquinolinol with Selective Renal Vasodilator Properties.
Authors: KANOJIA R. M. , LEVER O. W. JUN. , PRESS J. B. , WILLIAMS L. , WERBLOOD H. M. , GIARDINO E. C. , FALOTICO R. , TOBIA A. J. 
Published: May 2016

AbstractThe aminoisoquinoline (IV), obtained by nitration and subsequent reduction of the known isoquinoline (I), reacts with acyl chlorides such as (V) and isocyanates such as (VII) to yield the corresponding products (VI) and (VIII).
ChemInform Abstract: N‐Arylsulfonyl‐N′‐(pyrimidin‐4‐yl)ureas. Synthesis and Reaction with Dimethyl Sulfoxide.
Authors: ZEUNER F. , NICLAS H.‐J. 
Published: May 2016

AbstractThe title compounds (III) are synthesized by reaction of the isocyanates (I) with the aminopyrimidines (II).
ChemInform Abstract: 5‐Aroyl‐5,6‐dihydro‐4H‐pyrrolo(1,2‐a)(1,4)benzodiazepine‐4‐carboxylic Acids: Synthesis and Analgesic and Neurobehavioural Activity.
Authors: MASSA S. , CORELLI F. , ARTICO M. , MAI A. , SILVESTRI R. , PANTALEONI G. C. , PALUMBO G. , FANINI D. , GIORGI R. 
Published: May 2016

AbstractThe diazepine (III), obtained by cyclocondensation of the aminomethylphenylpyrrole (I) with the methoxyglycolate (II), reacts with the benzoyl chlorides (IV) to produce the amides (V).
ChemInform Abstract: New Synthetic Strategy to Highly Symmetric Chiral Macrocycles from Carbohydrate Derivatives.
Authors: VICENT C. , MARTIN‐LOMAS M. , PENADES S. 
Published: May 2016

AbstractThe gluco‐crowns (VI) and (VIII) are prepared as shown in the scheme and used as catalysts in the Michael addition of phenylacetate (IX) to methyl acrylate (X).
ChemInform Abstract: 3‐Alkylidenethiagermiranes.
Authors: ANDO W. , TSUMURAYA T. 
Published: May 2016

AbstractDiorganogermylenes, obtained by thermolysis of (I), react with the thioketene (II) to give the 1,2,3‐thiadigermetanes (III), the products of the insertion of germylenes into 3‐alkylidenethiagermiranes.
ChemInform Abstract: Asymmetric Distannoxane Dimers.
Authors: GROSS D. C. 
Published: May 2016

AbstractSolutions of difunctional tetrabutyldistannoxane pairs containing identical and mixed substitutions, (Bu2SnX)2O (X: Cl, OAc, OPh, OMe) plus XBu2SnOSnBu2Y (X: OAc, Y: OMe, OPh; X: Cl, Y: OMe, OAc, OPh; X: OCOCF3, Y: OPh), resp., are examined by 119Sn NMR spectroscopy.
ChemInform Abstract: Monophosphido‐Bridged Early/Late Heterobimetallic Complexes: Cooperative Activation of CO.
Authors: ZHENG P. Y. , NADASDI T. T. , STEPHAN D. W. 
Published: May 2016

AbstractThe reaction of the metal‐metal bonded complex (I) with the zirconocene diphosphide (II) results in reduction of the metal‐metal bond and oxidation of one of the phosphido ligands yielding the monophosphido‐bridged early/late heterobimetallic species (IVa) (space group P21/n, Z=4), belonging to a class of compounds which is heretofore unknown.
ChemInform Abstract: Preparation and Spectral Properties of a Series of Bis(phosphite) Alkyne Complexes and X‐Ray Crystal Structure of (WI2(CO)(P(OMe)3)2(η2‐MeC2Me)).
Authors: BAKER P. K. , ARMSTRONG E. M. , DREW M. G. B. 
Published: May 2016

AbstractThe complexes (IIIb) and analogous compounds (40‐48% yield) containing the same phosphites and diphenylacetylene instead of dimethylacetylene are prepared analogously.
ChemInform Abstract: Hydrogen Atom Transfer Between μ2‐Ethylidyne Radicals Generated by Electron Transfer: A Novel Disproportionation of a μ2‐Ethylidyne Group to μ2‐Vinylidene and μ2‐Ethylidene.
Authors: AASE T. , TILSET M. , PARKER V. D. 
Published: May 2016

AbstractThe bridging ethylidyne complexes (I) are reduced electrochemically or by cobaltocene in one‐electron, chemically irreversible electron‐transfer reactions.
ChemInform Abstract: η6‐Arene Displacement by Halide Ions. Synthesis and Structural Characterization of Chloro‐ and Fluoro‐Bridged Organonickel Complexes (R2MX)2‐ 2 (R: C6F5, SiCl3; X: Halide).
Authors: BREZINSKI M. M. , SCHNEIDER J. , RADONOVICH L. J. , KLABUNDE K. J. 
Published: May 2016

AbstractThe binuclear title complexes are prepared as ammonium and pyridinium salts (III) as shown for the examples (IIIa) and (IIIb).
ChemInform Abstract: Shape‐Selective Targeting of DNA by (Phenanthrenequinone diimine)rhodium(III) Photocleaving Agents.
Authors: PYLE A. M. , LONG E. C. , BARTON J. K. 
Published: May 2016

AbstractThe complexes (I) and (II) belong to a family of new, highly efficient, photocleaving molecules, which appear to recognize ostensible B‐form DNA sites on the basis of considerations of shape.
ChemInform Abstract: Arene‐to‐Alkyne Linkage Isomerizations of Diphenylacetylene on Pentaammineosmium.
Authors: HARMAN W. D. , WISHART J. F. , TAUBE H. 
Published: May 2016

AbstractThe reduction of the Os(III) complex (I) in the presence of excess diphenylacetylene (II) results in formation of the kinetically favored η2‐arene‐Os(II) complex (III).
ChemInform Abstract: Synthesis and Preliminary Evaluation of 2‐(F‐Alkyl)ethyl Glycosides, a Series of New F‐Alkylated Surfactants for in vivo Uses.
Authors: GREINER J. , MANFREDI A. , RIESS J. G. 
Published: May 2016

AbstractThe glycosides (V) ‐ (VII) mentioned in the title are synthesized in three steps from the corresponding pyranosyl bromides using the ortho ester method.
ChemInform Abstract: Synthetic Approach to Stereoisomers of Allylic Alcohols Possessing a Trifluoromethyl Group.
Authors: KITAZUME T. , LIN J. T. , YAMAZAKI T. , TAKEDA M. 
Published: May 2016

AbstractStereoselective reduction of the α‐hydroxyalkynes (III) gives the E‐ or Z‐configurated allylic alcohols (IV) and (V) or (IX) and (X).
ChemInform Abstract: Polyhedral Skeletal Electron Pair Theory (PSEPT) of Bare Clusters. Part 1. Small Silicon Clusters.
Authors: SLEE T. , LIN Z. , MINGOS D. M. P. 
Published: May 2016

AbstractA number of structures previously proposed as candidates for stable structures of a cluster of given nuclearity are ruled out by application of the PSEPT approach.
ChemInform Abstract: Ab initio Studies of Molecular Structures and Energetics. Part 3. Pentacoordinated NFnH5‐n Compounds.
Authors: EWIG C. S. , VAN WAZER J. R. 
Published: May 2016

AbstractAb initio quantum‐chemical calculations of the possible existence of the pentacoordinated title compounds for n = 0‐5 show the species NF3H2, NF4H, and NF5 to be structurally stable and to have trigonal‐bipyramidal structures.
ChemInform Abstract: Structures of Superconducting Palladium Selenides Pd7Se2 (I) and Pd34Se11 (II).
Authors: SATO S. , TAKABATAKE T. , ISHIKAWA M. 
Published: May 2016

AbstractSingle crystals of the title compounds (I) and (II) are obtained by direct reaction of the constitutes in silica‐glass tubes a 1423 K, followed by quenching and annealing the samples at 773 for 6 d and 673 K for 18 d, respectively.
ChemInform Abstract: Oxygen Vacancy Ordering in the Defect Pyrochlore Pb2(TiSb)O6.5: A Rietveld Refinement of Neutron Powder Diffraction Data.
Authors: ALONSO J. A. , CASCALES C. , RASINES I. , PANNETIER J. 
Published: May 2016

AbstractNeutron diffraction data of the title pyrochlore, obtained as yellow polycrystalline powder by heating in air stoichiometric mixtures of PbO, TiO2, and Sb2O3 to a final temp. of 1273 K, are successful fitted in the space group F43m (Z = 8).
ChemInform Abstract: The Structure of Aluminum Iron Molybdate.
Authors: HARRISON W. T. A. , CHEETHAM A. K. 
Published: May 2016

AbstractAlFe(MoO4)3, synthesized following a literature method, crystallizes in the monoclinic system, space group P21/a, Z = 8. A refinement of the structure by Rietveld analysis of constant wavelength neutron powder diffraction data, recorded at 4.2 K show the mixed molybdate to be isomorphous with the end member molybdates Fe2(MoO4)3 and Al2(MoO4)3.