bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Reactions with 2,3‐Dihydro‐5‐methyl‐3‐oxothieno(3,2‐d)isothiazole 1,1‐Dioxide.
Authors: UNTERHALT B. , BODINKA F. 
Published: May 2016

AbstractMethylation of the title compound (I) with diazomethane (II) yields a mixture of the N‐ and O‐methylated compounds (III) and (IV).
ChemInform Abstract: Synthesis of a Cognition Enhancing β‐Lactam Fused γ‐Lactam.
Authors: DRUMMOND J. T. , JOHNSON G. 
Published: May 2016

AbstractThe 3‐butenylazetidinone (III), prepared from 1,5‐hexadiene (I) and chlorosulfonyl isocyanate (II), is cyclized with iodine in the presence of propylene oxide to give the iodomethyl derivative (IV).
ChemInform Abstract: Thermal Rearrangements of 8‐Aza‐ and 8‐Oxa‐3,4‐diazatricyclo‐(5.1.0.02,6)oct‐4‐enes.
Authors: KURITA J. , SAKAI H. , TSUCHIYA T. 
Published: May 2016

AbstractThe oxadiaza‐ and triazatricyclooctenes (I) and (III) are rearranged upon flash vacuum pyrolysis, forming the aminoformylpyrroles (II) or the dihydropyrrolopyrazoles (IV).
ChemInform Abstract: Reaction of 1‐Benzopyrylium Salts with Trialkyl Phosphite: Formation of 2,4‐Disubstituted 1‐Benzopyran Derivatives.
Authors: IWASAKI H. , AKIBA K. 
Published: May 2016

AbstractThe 2H‐benzopyran‐2‐phosphonate (IIIa) is deprotonated and then treated with the aromatic aldehydes (IV) to form the 2‐methylenebenzopyrans (V).
ChemInform Abstract: CNS‐Active Phenylpyranes: 3‐(Dimethylaminomethyl)‐4‐(3‐methoxyphenyl)tetrahydro‐4‐pyranol and ‐4‐thiopyranol. Part 122.
Authors: EIDEN F. , SCHMIDT M. 
Published: May 2016

AbstractThe (hetero)cyclic ketones (I) are transformed into the aminomethyl derivatives (III) or (VIII) which react with the Grignard reagents (IV) and (IX) to give the carbinols (V) or (X).
ChemInform Abstract: Studies on the Synthesis of Some Flavonoid Derivatives Possessing Spasmolytic Activity. Part 5.
Authors: ERTAN M. , ERTAN R. , GOEKER H. + , PINDUR U. 
Published: May 2016

AbstractThe dihydroxyflavone (I) reacts with the α,β‐dibromocarboxylate (II) to give the isomeric benzodioxanes (IIIa) and (IIIb) which are separated and then converted into the amides (IIIc) and (IIId).
ChemInform Abstract: Studies in the Cycloproparene Series: Approaches to Cyclopropaheteroarenes.
Authors: BUCKLAND S. J. , HALTON B. , STANOVNIK B. 
Published: May 2016

AbstractPhotolysis of the compounds (I) gives rise to the intermediate diradicals (II), which do not undergo ring‐closure reaction to afford the corresponding cyclopropane derivatives but react to give the unexpected products (III) via 1,4‐hydrogen transfer.
ChemInform Abstract: Friedlaender Condensation of o‐Aminobenzaldehyde with Hydroxypyridines.
Authors: REISCH J. , SCHEER M. 
Published: May 2016

AbstractCyclocondensation of the benzaldehyde (I) with the hydroxypyridines (II) and (VIII) gives the fused heterocycles (III) or (IX) and (X).
ChemInform Abstract: Base‐Catalyzed Condensation of Acetone with Uracil Derivatives: One‐ Step Synthesis of Pyranopyrimidines.
Authors: AHLUWALIA V. K. , CHANDRA R. , AGGARWAL R. , SINGH S. B. 
Published: May 2016

AbstractThe 6‐substituted uracils (I) undergo cyclocondensation with acetone (II) in the presence of triethylamine to produce moderate yields of the pyranopyrimidinones (III).
ChemInform Abstract: Reaction of 2‐Isocyanatobenzonitrile with Hydrazine Nucleophiles.
Authors: ZINNER G. , KLEIN H. , KAHNERT H. 
Published: May 2016

AbstractThe addition product (III) of tert‐butyl hydrazinecarboxylate (II) and 2‐isocyanatobenzontrile (I) undergoes cleavage of the Boc‐group with HCl in nitromethane.
ChemInform Abstract: 4‐Methyl‐2‐cyclohexyl‐1aα,3,4,4aα,5,10‐hexahydronaphth(2,3‐e)‐1,2‐o# xazino‐3‐carbonitriles. Preparation, Stereochemistry, and Heterocyclization.
Authors: HATTINGH W. C. , HOLZAPFEL C. W. , VAN DYK M. S. 
Published: May 2016

AbstractThe nitrone (III), generated from the aldehyde (I) and the hydroxylamine (II), is dehydrochlorinated to form the nitrosonium salt (IV) which undergoes cycloaddition with 1,4‐dihydronaphthalene (V), yielding the oxazinium derivatives (VIa) and (VIb).
ChemInform Abstract: Rhodium Carbenoid Mediated Cyclizations. Use of Ethyl Lithiodiazoacetate in the Preparation of ω‐Hydroxy‐, ω‐Mercapto‐, and ω‐Boc‐Amino‐α‐diazo‐β‐keto Esters.
Authors: MOODY C. J. , TAYLOR R. J. 
Published: May 2016

Abstractα‐Lithiated diazoacetate (II) reacts with the lactones, thiolactones, or lactames (III), (VI), and (X) under ring cleavage, yielding the 2‐diazo‐3‐keto carboxylates (IV), (VII), or (XI).
ChemInform Abstract: Synthesis of Z‐2‐Benzylidene‐4‐phenyl‐1,3‐diselenole from Metallic Selenium and Phenylacetylene Under Phase‐Transfer Catalysis.
Authors: POTAPOV V. A. , KASHIK A. S. , AMOSOVA S. V. 
Published: May 2016

AbstractThe title compound (III) is formed from metallic selenium (II) and phenylacetylene (I) in aqueous alkali only in the presence of a phase‐ transfer catalyst.
ChemInform Abstract: The Chemistry of Chromium Nitrile Complexes of 1,2‐Bis(dimethylphosphino)‐ethane. X‐Ray Crystal Structures of trans‐(Cr(IV)Cl(NEt)(dmpe)2)CF3SO3,trans‐(Cr(IV)(N=CHMe)2(dmpe)2) (BPh4)2, and trans‐(Cr0(H·NCMe)2(dmpe)2) (BPh4)2.
Authors: BARRON A. R. , SALT J. E. , WILKINSON G. , MOTEVALLI M. , HURSTHOUSE M. B. 
Published: May 2016

AbstractThe reaction of (I) with MeCN (II) under different conditions gives the complexes (III) or (IV) which are oxidized to give (VI) or (VII).
ChemInform Abstract: Preparations and Characterizations of μ3‐Oxo‐hexakis(μ2‐carboxylatopyridine‐O,O)‐triaquatrichromium(III) Perchlorates.
Authors: BRADSHAW J. E. , GROSSIE D. A. , MULLICA D. F. , PENNINGTON D. E. 
Published: May 2016

AbstractThe title complexes (I) are prepared by known method and isolated as their solvates with NaClO4, H2O, and corresponding pyridincarboxylic acid.
ChemInform Abstract: Instant Ligands. Part 2. Preparation of Some Bidentate Ligands Containing PF2O Groups from Aromatic Hydroxy Compounds, and Their Reactions to Form Molybdenum and Tungsten Complexes.
Authors: BELL G. A. , RANKIN D. W. H. , REINISCH P. F. 
Published: May 2016

AbstractThe aromatic bidentate ligands (I)‐(V) are prepared by reactions of corresponding aromatic diols with an excess of S(PF2)2 in ether or chloroform solution.
ChemInform Abstract: Chemistry of Molybdenum. Part 5. Synthesis, Spectroscopic and Electrochemical Properties of Bis(2‐aminocyclopent‐1‐ene‐1‐dithiocarboxylato)(arylimido)dihalomolybdenum(VI) Complexes.
Authors: KUMAR S. B. , CHAUDHURY M. 
Published: May 2016

AbstractStarting with (I) the reaction with (II) gives the complexes (III) by an exchange of the oxo group by the isoelectronic arylimido ligand.
ChemInform Abstract: Seven‐Coordinate Molybdenum(II) Carbonyl Complexes Containing Two Different Bidentate Ligands (2,2′‐Bipyridyl and Ph2PCH2PPh2 or Ph2PCH2CH2PPh2).
Authors: ARNAIZ F. J. , BARTOLOME C. S. , GARCIA G. , PEREZ M. 
Published: May 2016

AbstractHalogenation of the Mo(0) complex (I) leads to the dihalide‐tricarbonyl‐Mo(II) complexes (III).
ChemInform Abstract: Chelate Ring‐Opening of Rhenium‐Diphosphine Complexes by Diazonium Salts.
Authors: CARR S. W. , FONTAINE X. L. R. , SHAW B. L. 
Published: May 2016

AbstractThe reaction of (I) with the diphosphines (II) gives (IIIa), (IIIb) and (IIIc), the latter as a mixture of two geometrical isomers (for one of them exists two possibilities).
ChemInform Abstract: Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 68. Reactions Between Nonacarbonyldiiron and the Salts (NEt4) (W(CR) (CO)2(η5‐C2B9H9Me2)) (R: Me, Ph, or C6H4Me‐4); Crystal Structures of (NEt4) (FeW(μ‐CH(C6H4Me‐4))(.mu±sigma.:η5‐C2B9H8Me2)(μ‐CO)(CO)5) and (NEt4) (Fe2W(μ3‐CPh)(.mu±sigma.:σ′,η5‐C2B9H7Me2)(CO)8).
Authors: BAUMANN F.‐E. , HOWARD J. A. K. , JOHNSON O. , STONE F. G. A. 
Published: May 2016

AbstractTreatment of the compound (Ia) with Fe2(CO)9 (II) in THF affords the trimetal compound (IIIa).
ChemInform Abstract: Activation Parameters for Directly Determined First Order Rate Constants for Outer Spere Electron Transfer Reactions, and Crystal Structure of a Pertinent Pentaammine of Co(III).
Authors: GAUS P. L. , BENEFIELD R. M. , HICSASMAZ H. , PERRY B. , VILLANUEVA J. , FLACK C. E. , PETT V. B. , DEMOULINI S. A. , FAULHABER J. C. , LYNCH D. E. , BACON J. W. 
Published: May 2016

AbstractThe outer sphere reductions of the Co complexes (I) by the Fe complexes (II) are studied.
ChemInform Abstract: Synthesis, Characterization, and Photochemical Properties of a Series of Ruthenium Containing Metallopolymers Based on Poly‐N‐vinylimidazole.
Authors: GERATY S. M. , VOS J. G. 
Published: May 2016

AbstractIn a series of experiments hydrated bis(2,2'‐bipyridyl)ruthenium(II) dichloride is treated with poly‐N‐vinylimidazole (obtained by polymerization of N‐vinylimidazole with 2,2'‐azoisobutyronitrile as the initiator in a 20:1 ratio) using different solvents and reaction times.
ChemInform Abstract: Electrocrystallization and Structural and Physical Properties of Charge‐Transfer Complexes Derived from ((η6‐C6Me6)2M)2+ (M: Fe, Ru) and TCNQ (TCNQ = Tetracyanoquinodimethane).
Authors: WARD M. D. , JOHNSON D. C. 
Published: May 2016

AbstractCharge‐transfer complexes are prepared by reduction of the tetracyanoquinodimethanes (II) in the presence of the cations (I).
ChemInform Abstract: Nitrosobenzene Complexes of (Octaethylporphinato)ruthenium(II).
Authors: CROTTI C. , SISHTA C. , PACHECO A. , JAMES B. R. 
Published: May 2016

AbstractThe diamagnetic bis(nitrosobenzene) Ru complex (III) is readily prepared and characterized by 1H NMR data.
ChemInform Abstract: Azetidinone Imides.
Authors: SPRY D. O. , SNYDER N. J. , BHALA A. R. , PASINI C. E. , INDELICATO J. M. 
Published: May 2016

AbstractAcylation of the β‐lactam carboxamides or carbamates (I), (IV), and (VI) with isopropenyl acetate (II) and the anhydride (VII) gives the imides (III) and (VIII) or the N‐acetyl carbamates (V).
ChemInform Abstract: Synthesis of (S)‐N‐(Benzyloxy)‐4‐acetoxymethyl‐2‐azetidinone, Potential Intermediate for Carbapenem Antibiotics, by Chemomicrobiological Approach.
Authors: YAMADA H. , SUGIYAMA H. , KAJIWARA M. 
Published: May 2016

AbstractEthyl 4‐chloroacetoacetate (Ia) reacts with tert‐butanol (II) to give the ether (Ib) which undergoes microbiological reduction, forming the chiral ethyl tert‐butoxyhydroxybutanoate (R)‐(III).
ChemInform Abstract: Hot Isostatic Pressing of Si3N4 Powder Compacts and Reaction‐Bonded Si3N4.
Authors: HEINRICH J. , BACKER E. , BOEHMER M. + 
Published: May 2016

AbstractSEM, XRD, and density measurements are used to investigate the microstructure of hot isostatically pressed silicon nitride produced by densifying Si3N4 powder compacts and reaction‐bonded Si3N4 (RBSN) parts with Y2O3 as sintering additive.
ChemInform Abstract: Protective Action of Epoxy Resins and Curing Agents ‐ Inhibitive Effects on the Aqueous Acid Corrosion of Iron and Steel.
Authors: SCHWEINSBERG D. P. , GEORGE G. A. , NANAYAKKARA A. K. , STEINERT D. A. 
Published: May 2016

AbstractThe two epoxy resins studied (Ciba‐Geigy MY720 and Shell Epon 828) are found to inhibit the corrosion of iron and steel in acidic solution over a range of concentrations, whereas the curing agents investigated (4,4'‐diaminodiphenyl‐sulfone, 4,4'‐diaminodiphenyl methane, and diethylenetriamine) can stimulate corrosion, particularly at low concentrations.
ChemInform Abstract: The Influence of Grinding and Baking Processes on the Luminescent Properties of Zinc Cadmium Sulfide Phosphors for Vacuum Fluorescent Displays
Authors: ITOH S. , TONEGAWA T. , PYKOSZ T. L. , MORIMOTO K. , KUKIMOTO H. 
Published: May 2016

Abstractis investigated by XRD, SEM, Auger electron spectroscopy and by measurements of the low voltage cathodoluminescence as a function of baking temperature.
ChemInform Abstract: Efficient Vanadium Redox Flow Cell.
Authors: SKYLLAS‐KAZACOS M. , GROSSMITH F. 
Published: May 2016

AbstractPreviously, the excellent performance characteristics of a laboratory‐scale all‐vanadium redox cell employing V(II)/V(III) and V(IV)/V(V) redox couples for the negative and positive half‐cells, resp., have been demonstrated.
ChemInform Abstract: Electrochemical Oxidation of Molten Carbonate‐Coal Slurries.
Authors: VUTETAKIS D. G. , SKIDMORE D. R. , BYKER H. J. 
Published: May 2016

AbstractThe described electrochemical cell for coal oxidation at high temp. utilizes a stirred slurry of coal (or carbon) particles dispersed in a molten carbonate electrolyte (500‐800 °C).
ChemInform Abstract: Zirconium Iodide Clusters that Encapsulate Silicon, Germanium Phosphorus, or Pyrex.
Authors: ROSENTHAL G. , CORBETT J. D. 
Published: May 2016

AbstractThe phases Zr6I14X (X: Si, Ge, P) as well as MxZr6I14P (M: Cs, Rb) are prepared by reaction of stoichiometric amounts of elemental Si, Ge, or P, ZrI4, CsI or RbI when appropriate, and excess Zr (sealed Ta container, 700‐850 °C, 2‐4 weeks, no yields given).
ChemInform Abstract: Effect of Cavity Size on the Charge Distribution in Carbido‐Metal Carbonyl Clusters and Its Possible Catalytic Implications.
Authors: HALET J.‐F. , EVANS D. G. , MINGOS D. M. P. 
Published: May 2016

AbstractMO calculations on carbido‐transition metal carbonyl cluster compounds with 4‐12 metal atoms where the C atom lies in a large cavity indicate a substantial buildup of negative charge on the C atom.
ChemInform Abstract: Stereochemistry of the Thermal Isomerization of Bicyclo(3.2.0)hept‐2‐ene to Bicyclo(2.2.1)hept‐2‐ene.
Authors: BALDWIN J. E. , BELFIELD K. D. 
Published: May 2016

AbstractThe thermal isomerization of (Ia) to yield (II) and (III) occurs with predominant inversion as well as with substantial retention (21%).
ChemInform Abstract: Synthesis of 5‐Alkyl(hetaryl)thiopentanones‐2.
Authors: PATALAKH I. I. , KELAREV V. I. , LISITSYN E. A. , GANKIN G. D. , KARAKHANOV R. A. 
Published: May 2016

AbstractCoupling of the chloro ketone (I) with the mercapto compounds (II) in a basic medium yields the thioethers (III).
ChemInform Abstract: Gibberellins. Part 118. Computer‐Assisted Site‐Specific Functionalization in the Gibberellin Series: Norrish Type II Photocyclization via a 9‐Membered Transition State.
Authors: ADAM G. , PREISS A. , PHAM DINH HUNG PHAM DINH HUNG , KUTSCHABSKY L. 
Published: May 2016

AbstractThe site‐specific Norrish II type reaction of the gibberellin oxo ester (IIIc), prepared in two steps from the GA3 anhydride (I), leads to the photolactone (IV).
ChemInform Abstract: Alkylation of Perfluoro‐2‐methyl‐2‐pentylcarbanion with Alkyl and Allyl Halides.
Authors: DMOWSKI W. , WOZNIAKI R. 
Published: May 2016

AbstractReaction of the alkyl or allyl halides (II) with the perfluoro‐4‐methyl‐2‐pentylcarbanion, generated in situ from the dimer (I) of hexafluoropropene, gives the fluorohydrocarbons (III).
ChemInform Abstract: Novel Synthesis and Spectral Characterization of an N‐Acetoxyarylamine: N‐Acetoxy‐2,4‐dinitrophenylamine.
Authors: HUGGETT A. C. , CONE J. L. , THORGEIRSSON S. S. , ROLLER P. P. 
Published: May 2016

AbstractThe title compound (III) is obtained by the condensation reaction of 2,4‐dinitrofluorobenzene (I) with O‐acetylhydroxylamine (II).
ChemInform Abstract: Non‐Bonded Interactions between Proximate Phenyl and Polyfluorophenyl Rings? The Regiospecific Synthesis of the Facial Tetrafluorojanusene.
Authors: FILLER R. , CANTRELL G. L. 
Published: May 2016

AbstractThe fluorinated janusenes (III) and (VII) are synthesized from the anthracenes (I), (IV), or (VIII) and the dibenzobarrelene derivatives (II) or (V) as outlined in the reaction scheme.
ChemInform Abstract: Vinylogous Carbinolamine Tumor Inhibitors. Part 21. Synthesis, Chemical Reactivity, and Antileukemic Activity of 5‐Substituted 6,7‐Bis(hydroxymethyl)pyrrolo(1,2‐c)thiazole Biscarbamates and the Corresponding Sulfoxides and Sulfones.
Authors: ANDERSON W. K. , MACH R. H. 
Published: May 2016

AbstractStarting with the thiazolidine‐4‐carboxylic acids (I), the target compounds (VI) ‐ (VIII) are prepared as outlined in the reaction scheme.
ChemInform Abstract: Novel Heterocyclic Systems. Part 27. The Synthesis of Various Diazathianthrenes and the Discrimination of Isomeric Structures Using 13C‐NMR and Lanthanide Induced Shift Data.
Authors: LINDSAY C. M. , SMITH K. , MARTIN G. E. 
Published: May 2016

AbstractThe diazathianthrenes (IV) and (V) are prepared by coupling the disodium salt (II) of 2,3‐dimercaptopyridine (I) with 2‐chloro‐3‐nitropyridine (III).
ChemInform Abstract: Condensation of 1‐Methyl‐2‐phenyl‐4‐arylphthalazinium Perchlorates with Aromatic Aldehydes.
Authors: OVCHINNIKOVA I. G. , SAMARTSEVA I. V. , PAVLOVA L. A. 
Published: May 2016

AbstractCondensation of the phthalazinium perchlorates (I) with the aromatic aldehydes (II) or with the salicylic aldehydes (IV) yields the 1‐styrylphthalazinium perchlorates (III) or (V).
ChemInform Abstract: Heterocyclic Systems. Part 8. Synthesis of 1H,4H‐Pyrazolo(4,3‐f)pyrrolo(1,2‐a)azepine Derivatives.
Authors: CORELLI F. , MASSA S. , STEFANCICH G. , SILVESTRI R. 
Published: May 2016

AbstractThe pyrazolylpropionic acid (Ie) is prepared by known methods and then cyclized with PPA to form the fused azepinone (III).
ChemInform Abstract: Angiotensin‐Converting Enzyme Inhibitors: Perhydro‐1,4‐thiazepin‐5‐one Derivatives.
Authors: YANAGISAWA H. , ISHIHARA S. , ANDO A. , KANAZAKI T. , MIYAMOTO S. , KOIKE H. , IIJIMA Y. , OIZUMI K. , MATSUSHITA Y. , HATA T. 
Published: May 2016

AbstractThe perhydro‐1,4‐thiazepin‐5‐ones (X) with hydrophobic substituents at the 2‐position are prepared from Boc‐L‐cysteine (I) as outlined in the reaction scheme.
ChemInform Abstract: Synthesis, Crystal and Molecular Structure of Tetraphenylarsonium Bis(maleonitriledithiolato)tellurate(II), (AsPh4)2(Te(mnt)2), and Single‐Crystal Electron Spin Resonance Spectra of the System (AsPh4)2(Cu/Te(mnt)2).
Authors: GOLIC L. , DIETZSCH W. , KOEHLER K. + , STACH J. , KIRMSE R. 
Published: May 2016

AbstractThe title complex (III) is synthesized according to the scheme and characterized by X‐ray analysis (space group P1, Z=2).
ChemInform Abstract: Direct Synthesis of 3‐Methyl‐ and 2,4‐Dimethylselenophenes and ‐tellurophenes.
Authors: CATEL J.‐M. , MAHATSEKAKE C. , ANDRIEU C. , MOLLIER Y. 
Published: May 2016

AbstractThe acetylenic chlorohydrins (I) are cyclized with the sodium hydrogen chalcogenides (II) to yield the five‐ring compounds (III).
ChemInform Abstract: Insertion Reactions of Chromium‐Carbene Complexes with Organic Nitriles and a Diastereoselective Alkylation of a Resulting Imino‐Carbene Complex.
Authors: YANG D. C. , DRAGISICH V. , WULFF W. D. , HUFFMAN J. C. 
Published: May 2016

AbstractThe heteroatom‐stabilized Fischer carbene complexes (I) react with the aliphatic and aryl nitriles (II) to give the insertion products (III).
ChemInform Abstract: Mn(I)‐Induced 1,6‐Demethanation Across the CC Triple Bond of Linear Alkynes in the Gas Phase. A Case for the Generation of Manganese Cycloalkynes?
Authors: SCHULZE C. , SCHWARZ H. 
Published: May 2016

AbstractComplexes of Mn(alkynes)+, generated in the gas phase, are found to exhibit a reactivity which is even richer than that of analogous Fe species.
ChemInform Abstract: Kinetic Energy Release Distributions as a Probe of Transition‐Metal‐Mediated H‐H, C‐H, and C‐C Bond Formation Processes: Reactions of Cobalt and Nickel Ions with Alkanes.
Authors: HANRATTY M. A. , BEAUCHAMP J. L. , ILLIES A. J. , VAN KOPPEN P. , BOWERS M. T. 
Published: May 2016

AbstractProduct translational energy release distributions are used to investigate the potential energy surfaces for elimination of H2 and small alkanes from ionic Co and Ni complexes with alkanes.
ChemInform Abstract: Synthesis of Benzyl‐ or Pentafluorobenzyl‐diphenylphosphonio(diphenylphosphino)methanide Complexes of Gold(I) and Gold(III) and Their Use as C‐Donor Ligands.
Authors: USON R. , LAGUNA A. , LAGUNA M. , LAZARO I. , TARTON M. T. 
Published: May 2016

AbstractThe salts (II) prepared according to the scheme react with an excess NaH to give the neutral methanide complexes (V) which react with Au(I) or Ag(I) derivatives (I), (VII), and (VIII) to yield binuclear complexes of the type (VI) or (IX).
ChemInform Abstract: Studies on Ruthenium(II) Macrocyclic Amine Complexes. Synthesis and X‐Ray Structure of the (R,S,R,R) Isomer of trans‐(Ru(II)(L)(N3)(NCMe))PF6 (L: 1,4,8,11‐tetramethyl‐1,4,8,11‐tetra‐azacyclotetradecane).
Authors: CHE C.‐M. , LAI T.‐F. , LAU K. , MAK T. C. W. 
Published: May 2016

AbstractThe reaction of the macrocycle (I) with (II) gives an intermediate product (possibly a Ru‐NO complex of (I)) which on treatment with hydrazine in MeCN yields the title compound (V) (no yield given).
ChemInform Abstract: (RhPd2(pyS)4(η3‐C4H7)2) (BF4): Synthesis and X‐Ray Structure of a Mixed‐Metal Trinuclear Complex Containing Two μ3‐Pyridine‐2‐thionato (pyS) Ligands.
Authors: DEEMING A. J. , MEAH M. N. , BATES P. A. , HURSTHOUSE M. B. 
Published: May 2016

AbstractThe Rh(III) complex (I) reacts with triethylamine and two equiv. of the 2‐methylallyl‐Pd(II) complex (III) to yield the trinuclear title complex (II).
ChemInform Abstract: Synthetic Studies on Gangliosides. Part 6. Stereospecific β‐Glycosylation of 2β,3α‐Dibromo‐N‐acetylneuraminic Acid.
Authors: OKAMOTO K. , KONDO T. , GOTO T. 
Published: May 2016

AbstractGlycosylation of the dibromo trideoxynonulopyranosonate (I) with the acceptors (II) yields only the β‐glycosides (III) the bromo group of which is removed with tributylstannane to give the glycosides (IV).
ChemInform Abstract: An Azetidinone Route to 2,3‐Dideoxy‐3‐aminopentoses and 2,3‐Dideoxy‐3‐ C‐methyl‐3‐aminopentoses.
Authors: HAUSER F. M. , ELLENBERGER S. R. , RHEE R. P. 
Published: May 2016

AbstractConsecutive acidic cleavage and N‐benzoylation of the azetidinones (I) yield the β‐benzamidopentenoates (III).
ChemInform Abstract: A New Route to the Indolopyridonaphthyridine Ring System: Synthesis of N‐Benzyl‐13b,14‐dihydronauclefine and N‐Benzyl‐13b,14‐dihydroangustine.
Authors: JAHANGIR JAHANGIR , BROOK M. A. , MACLEAN D. B. , HOLLAND H. L. 
Published: May 2016

AbstractThe title system, which is present in severed alkaloids, is prepared in a single reaction between 3‐cyano‐4‐methylpyridine lithio derivatives such as (IV) and the dihydrocarboline (II).
ChemInform Abstract: Synthetic 1‐Methoxybenzo(d)naphtho(1,2‐b)pyran‐6‐one C‐Glycosides.
Authors: OUTTEN R. A. , DAVES G. D. JUN. 
Published: May 2016

AbstractCoupling the stannylnaphthopyranone (II) with the furanoid glycal (I) in the presence of palladium(II) acetate yields the C‐glycosides (III).
ChemInform Abstract: A Photoconductivity Study of Electron Transfer Between CdS and TiO2 Powders in Vacuum and in an O2 Atmosphere.
Authors: PICHAT P. , BORGARELLO E. , DISDIER J. , HERRMANN J.‐M. , PELIZZETTI E. , SERPONE N. 
Published: May 2016

AbstractPhotoconductance measurements are carried out in the UV/VIS spectral range under vacuum or O2 atmosphere for CdS and TiO2 powders, mixtures of both, and a CdS‐TiO2 double pellet.
ChemInform Abstract: E.m.f. and Calorimetric Investigations of Antimony Oxides.
Authors: KNAUTH P. , SCHWITZGEBEL G. 
Published: May 2016

AbstractThermodynamic data (heat capacities, enthalpies of solution, the enthalpy of reaction (see scheme), Gibbs free energies) of Sb2O3, Sb2O4, and Sb2O5 are determined by solution calorimetry in molten NaOH/KOH, DSC and drop calorimetry, and solid state electrochemistry.
ChemInform Abstract: Effect of Surface Hydroxyl Density on Photocatalytic Oxygen Generation in Aqueous TiO2 Suspensions.
Authors: OOSAWA Y. , GRAETZEL M. + 
Published: May 2016

AbstractTiO2 powders with various surface hydroxyl densities are prepared by thermal treatment (7 h at 600‐1000 °C) and their activity for photocatalytic O2 evolution in aqueous suspensions is studied in the presence of various electron acceptors (AgNO3, K2PtCl4 and KBrO3).
ChemInform Abstract: ortho‐Thioborates and ortho‐Selenoborates: Synthesis, Structure and Properties of Tl3BS3 and Tl3BSe3.
Authors: KREBS B. , HAMANN W. 
Published: May 2016

AbstractThe title compounds are obtained as black crystalline phases from the reaction of stoichiometric amounts of the elements at 800‐950 °C and subsequent annealing at 400‐200 °C. The isotypic compounds crystallize in the monoclinic space group P21/m with Z=2 (single‐crystal XRD).