bluuebunny/crossref_metadata_2025_split huggingface dataset:
Spontaneous formation of discrete arrangement of particles by dipping ultraviolet/ozone‐treated poly(dimethylsiloxane) substrate in solution
Authors: Watanabe Masashi , Nishino Toshihiro 
Published: February 2016

ABSTRACTThe spontaneous formation of well‐ordered microstructures is an interesting research topic because such formation is useful for cost‐effective production of functional materials. In this article, we report a novel method for spontaneous formation of a discrete arrangement of particles using an ultraviolet/ozone‐treated poly(dimethylsiloxane) substrate. The substrate was first dipped in a solution (solvent: mixture of methanol and water, solute: sucrose or lithium perchlorate) in a sealed vessel filled with the vapor of the solvent, and was then dried in air to precipitate the solute as particles. In spite of the simplicity of the procedure, the particles were regularly and discretely arranged in a triangular lattice with a distance between the neighboring particles of about 48 µm. The mechanism of formation of the array was explained by considering the formation of regular dimples due to swelling of the substrate surface with the solution and the dewetting of the liquid film of the solution on the surface. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43506.
Potent antidiuretic agonists, deamino‐vasopressin and desmopressin, and their inverso analogs: NMR structure and interactions with micellar and liposomic models of cell membrane
Authors: Lubecka Emilia A. , Sikorska Emilia , Sobolewski Dariusz , Prahl Adam , Slaninová Jiřina , Ciarkowski Jerzy 
Published: February 2016

ABSTRACTDeamination of vasopressin (AVP) enhances its antidiuretic activity. Moreover, introduction of D‐Arg8 instead of its L enantiomer in deamino‐vasopressin (dAVP) results in an extremely potent and selective antidiuretic agonist ‐ desmopressin (dDAVP). In this study we describe the synthesis, pharmacological properties and structures of these two potent antidiuretic agonists, and their inverso analogs. The structures of the peptides are studied in micellar and liposomic models of cell membrane using CD spectroscopy. Additionally, three‐dimensional structures in mixed anionic‐zwitterionic micelles are obtained using NMR spectroscopy supported by molecular dynamics simulations. Our conformational studies have shown that desmopressin in a membrane mimicking environment adopts one of the characteristic for vasopressin‐like peptides β‐turn ‐ in position 3,4. Furthermore, dDAVP shows the tendency to create a β‐turn in the Cys6‐Gly9 C‐tail, considered to be important for the antidiuretic activity, and also some tendency to adopt a 5,6 β‐turn. In desmopressin, in contrast to the native vasopressin, deamino‐vasopressin and [D‐Arg8]‐vasopressin (DAVP), the Arg8 side chain, crucial for the pressor and antidiuretic activities, is very well exposed for interaction with the receptor, whereas Gly9, crucial for the pressor and uterotonic activities, is situated together with the C‐terminal amide group very close to the tocin ring. The arrangements of the Gln4 and Asn5 side chains, being crucial for OT activity, also differ in desmopressin as compared to those of AVP, dAVP and DAVP. These differences in arrangement of the important for activities side chains are likely to explain extremely potent and selective antidiuretic activities of desmopressin. © 2016 Wiley Periodicals, Inc. Biopolymers (Pept Sci) 106: 245–259, 2016.
DNA‐crosslinker cisplatin eradicates bacterial persister cells
Authors: Chowdhury Nityananda , Wood Thammajun L. , Martínez‐Vázquez Mariano , García‐Contreras Rodolfo , Wood Thomas K. 
Published: February 2016

ABSTRACTFor all bacteria, nearly every antimicrobial fails since a subpopulation of the bacteria enter a dormant state known as persistence, in which the antimicrobials are rendered ineffective due to the lack of metabolism. This tolerance to antibiotics makes microbial infections the leading cause of death worldwide and makes treating chronic infections, including those of wounds problematic. Here, we show that the FDA‐approved anti‐cancer drug cisplatin [cis‐diamminodichloroplatinum(II)], which mainly forms intra‐strand DNA crosslinks, eradicates Escherichia coli K‐12 persister cells through a growth‐independent mechanism. Additionally, cisplatin is more effective at killing Pseudomonas aeruginosa persister cells than mitomycin C, which forms inter‐strand DNA crosslinks, and cisplatin eradicates the persister cells of several pathogens including enterohemorrhagic E. coli, Staphylococcus aureus, and P. aeruginosa. Cisplatin was also highly effective against clinical isolates of S. aureus and P. aeruginosa. Therefore, cisplatin has broad spectrum activity against persister cells. Biotechnol. Bioeng. 2016;113: 1984–1992. © 2016 Wiley Periodicals, Inc.
Chromatographic methods for the bioanalysis of pyrethroid pesticides
Authors: Gullick Darren R. , Mott Kyle B. , Bartlett Michael G. 
Published: February 2016

AbstractReliable analytical methods are needed for the determination of pyrethroid pesticides residues in biological tissues such as whole blood and plasma, meat, eggs, milk, brain, liver, and adipose tissue for monitoring of levels in livestock and for human risk assessment. A review of the current literature is given, with consideration to extraction techniques, sample preparation, and chromatographic approaches including both conventional and new technologies. Copyright © 2016 John Wiley & Sons, Ltd.
Risk of breast cancer after false‐positive results in mammographic screening
Authors: Román Marta , Castells Xavier , Hofvind Solveig , von Euler‐Chelpin My 
Published: February 2016

AbstractWomen with false‐positive results are commonly referred back to routine screening. Questions remain regarding their long‐term outcome of breast cancer. We assessed the risk of screen‐detected breast cancer in women with false‐positive results. We conducted a joint analysis using individual level data from the population‐based screening programs in Copenhagen and Funen in Denmark, Norway, and Spain. Overall, 150,383 screened women from Denmark (1991–2008), 612,138 from Norway (1996–2010), and 1,172,572 from Spain (1990–2006) were included. Poisson regression was used to estimate the relative risk (RR) of screen‐detected cancer for women with false‐positive versus negative results. We analyzed information from 1,935,093 women 50–69 years who underwent 6,094,515 screening exams. During an average 5.8 years of follow‐up, 230,609 (11.9%) women received a false‐positive result and 27,849 (1.4%) were diagnosed with screen‐detected cancer. The adjusted RR of screen‐detected cancer after a false‐positive result was 2.01 (95% CI: 1.93–2.09). Women who tested false‐positive at first screen had a RR of 1.86 (95% CI: 1.77–1.96), whereas those who tested false‐positive at third screening had a RR of 2.42 (95% CI: 2.21–2.64). The RR of breast cancer at the screening test after the false‐positive result was 3.95 (95% CI: 3.71–4.21), whereas it decreased to 1.25 (95% CI: 1.17–1.34) three or more screens after the false‐positive result. Women with false‐positive results had a twofold risk of screen‐detected breast cancer compared to women with negative tests. The risk remained significantly higher three or more screens after the false‐positive result. The increased risk should be considered when discussing stratified screening strategies.
Peptide Synthesis through Cell‐Free Expression of Fusion Proteins Incorporating Modified Amino Acids as Latent Cleavage Sites for Peptide Release
Authors: Liutkus Mantas , Fraser Samuel A. , Caron Karine , Stigers Dannon J. , Easton Christopher J. 
Published: February 2016

AbstractChlorinated analogues of Leu and Ile are incorporated during cell‐free expression of peptides fused to protein, by exploiting the promiscuity of the natural biosynthetic machinery. They then act as sites for clean and efficient release of the peptides simply by brief heat treatment. Dehydro analogues of Leu and Ile are similarly incorporated as latent sites for peptide release through treatment with iodine under cold conditions. These protocols complement enzyme‐catalyzed methods and have been used to prepare calcitonin, gastrin‐releasing peptide, cholecystokinin‐7, and prolactin‐releasing peptide prohormones, as well as analogues substituted with unusual amino acids, thus illustrating their practical utility as alternatives to more traditional chemical peptide synthesis.
Primary apocrine carcinoma of the axilla in a male patient: a case report
Authors: Zahid Rehan , Soofi Madiha E. , Elmalik Hind , Junejo Kulsoom 
Published: February 2016

Key Clinical MessagePrimary apocrine sweat gland carcinoma is a rare neoplasm. It is usually slow growing and is often suspected to be a benign disease at initial assessment. A thorough clinical and histological workup is required for diagnosis. Treatment of choice is wide local excision with clear margins.
Realizing the Promise—The Development of Research on Carbon Nanotubes
Authors: Pellegrino Emilio M. , Cerruti Luigi , Ghibaudi Elena M. 
Published: February 2016

AbstractThe present reflection on the development of research on carbon nanotubes (CNTs) stems from the publication of the report “Realizing the Promise of Carbon Nanotubes” by the US National Nanotechnology Initiative in 2015. The report is a critical assessment of the state‐of‐art of CNT research and highlights some unresolved issues related with this field. Starting from the results of this assessment, we carried out an analysis of the publications’ pool in CNTs and related domains, by exploiting bibliometric tools. We focused on the item of competition/collaboration between disciplines and nations, with the purpose of evaluating the position of chemistry (as a discipline) as well as the position of the main European countries and the European Union (EU) as a whole in the context of CNT research. The results of such analysis outline very clearly the interdisciplinary landscape wherein CNT research is situated and show the highly competitive place occupied by EU in the field.
Morphology‐Tuned Synthesis of NiCo2O4‐Coated 3D Graphene Architectures Used as Binder‐Free Electrodes for Lithium‐Ion Batteries
Authors: Zhang Chunfei , Yu Jong‐Sung 
Published: February 2016

AbstractNanostructured NiCo2O4 is directly grown on the surface of three‐dimensional graphene‐coated nickel foam (3D‐GNF) by a facile electrodeposition technique and subsequent annealing. The resulting NiCo2O4 possesses a distinct flower or sheet morphology, tuned by potential or current variation electrodeposition, which are used as binder‐free lithium‐ion battery anodes for the first time. Both samples exhibit high lithium storage capacity, profiting from the unique binder‐free electrode structures. The flower‐type NiCo2O4 demonstrates high reversible discharge capacity (1459 mAh g−1 at 200 mA g−1) and excellent cyclability with around 71 % retention of the reversible capacity after 60 cycles, which are superior to the sheet‐type NiCo2O4. Such superb performance can be attributed to high volume utilization efficiency with unique morphological character, a well‐preserved connection between the active materials and the current collector, a short lithium‐ion diffusion path, and fast electrolyte transfer in the binder‐free NiCo2O4‐coated 3D graphene structure. The simple preparation process and easily controllable morphology make the binder‐free NiCo2O4/3D‐GNF hybrid a potential material for commercial applications.
Towards Magnetic Carbo‐meric Molecular Materials
Authors: Poidevin Corentin , Malrieu Jean‐Paul , Trinquier Georges , Lepetit Christine , Allouti Faycal , Alikhani M. Esmail , Chauvin Remi 
Published: February 2016

AbstractNumerous studies have underlined the putative diradical character of π‐conjugated molecules that can be described by closed‐shell Lewis structures, for instance, p‐dimethylene p–n phenylenes, or long polyacenes. In the latter compounds, the only way to save the aromaticity of the six‐membered rings is to give up the Lewis electron pairing in the singlet biradical ground state. The present work considers the possibility of doing the same by using the basic C2 units of carbo‐meric architectures. A series of acyclic and cyclic carbo‐meric architectures is studied by using UB3LYP DFT broken‐symmetry calculations, including spin decontaminations and subsequent geometry optimization of the singlet diradical. The C2 units are shown to stabilize the singlet biradical by spin delocalization, two of them playing approximately the same role as one radical‐insulating 1,4 phenylene moiety. The results are generalized to the investigation of open‐shell polyradical singlet states of rigid hydrocarbon structures, the symmetry and rigidity of which can assist cooperativity and self spin polarization effect. Several synthesis targets with challenging magnetic/spin properties are suggested in the carbo‐mer series.
Intercalation of Varied Sulfonates into a Layered MOC: Confinement‐Caused Tunable Luminescence and Novel Properties
Authors: Wen Yuehong , Sheng Tianlu , Zhu Xiaoquan , Zhang Hao , Zhuo Chao , Hu Shengmin , Cao Wenhai , Wu Xintao 
Published: February 2016

AbstractThe pores/channels of porous 3D metal–organic frameworks (MOFs) have been widely applied to incorporate gas, solvent, or organic molecules. On the contrary, the utilization of the interlamellar void of layered metal–organic complexes (MOCs) remains underappreciated, although it is more flexible and available to accommodate molecules with different sizes. In this work, diverse sulfonates have been intercalated purposely into an identical layered MOC, which constructed various novel intercalation compounds possessing fluorescent, white‐light emitting, photochromic, homochiral, or nonlinear optical (NLO) properties. With the help of single‐crystal X‐ray diffraction, their structures and the mutual interactions between the MOC host and the sulfonate guests were characterized. The properties of the guest molecules were tuned and meanwhile some new performances were generated after confining them into the interlayer region. Such a hybrid approach provides an efficient strategy to design and prepare multifunctional materials.
Generation of Complex Azabicycles and Carbobicycles from Two Simple Compounds in a Single Operation through a Metal‐Free Six‐Step Domino Reaction
Authors: Bock Christina M. , Parameshwarappa Gangajji , Bönisch Simon , Neiss Christian , Bauer Walter , Hampel Frank , Görling Andreas , Tsogoeva Svetlana B. 
Published: February 2016

AbstractAza‐ and carbobicyclic compounds possess favorable pharmaceutical properties, but they are difficult to access. Herein, we demonstrate an unprecedented organocatalytic two component six‐step chemodivergent domino reaction, which provides a straightforward, sustainable and atom economical route to difficult‐to‐access complex bicyclic architectures: azabicycles and carbobicycles, whose ratios can be controlled by the applied electrophiles and catalysts. Detailed NMR and X‐ray studies on the structures and relative stereochemistry of selected compounds are presented. Mechanistic investigations of the chemoselective branching step have been carried out with DFT methods in conjunction with semiempirical van der Waals interactions. This new domino reaction opens up a new vista of generating, in a single operation, new bioactive compounds with strong antiviral properties (EC50 up to 0.071 μm for human cytomegalovirus (HCMV)) outperforming clinically used ganciclovir (EC50 2.6 μm).
Iminosugar‐Cyclopeptoid Conjugates Raise Multivalent Effect in Glycosidase Inhibition at Unprecedented High Levels
Authors: Lepage Mathieu L. , Schneider Jérémy P. , Bodlenner Anne , Meli Alessandra , De Riccardis Francesco , Schmitt Marjorie , Tarnus Céline , Nguyen‐Huynh Nha‐Thi , Francois Yannis‐Nicolas , Leize‐Wagner Emmanuelle , Birck Catherine , Cousido‐Siah Alexandra , Podjarny Alberto , Izzo Irene , Compain Philippe 
Published: February 2016

AbstractA series of cyclopeptoid‐based iminosugar clusters has been evaluated to finely probe the ligand content‐dependent increase in α‐mannosidase inhibition. This study led to the largest binding enhancement ever reported for an enzyme inhibitor (up to 4700‐fold on a valency‐corrected basis), which represents a substantial advance over the multivalent glycosidase inhibitors previously reported. Electron microscopy imaging and analytical data support, for the best multivalent effects, the formation of a strong chelate complex in which two mannosidase molecules are cross‐linked by one inhibitor.
Construction of a 2D Graphene‐Like MoS2/C3N4 Heterojunction with Enhanced Visible‐Light Photocatalytic Activity and Photoelectrochemical Activity
Authors: Yan Jia , Chen Zhigang , Ji Haiyan , Liu Zheng , Wang Xin , Xu Yuanguo , She Xiaojie , Huang Liying , Xu Li , Xu Hui , Li Huaming 
Published: February 2016

AbstractInvited for the cover of this issue is the group of Huaming Li and Hui Xu at the Jiangsu University. The image depicts GL‐MoS2/C3N4 as a kind of stable, non‐toxic, and highly efficient photocatalyst for the degradation of pollutants. Read the full text of the article at 10.1002/chem.201503660.
Photoinduced Charge Separation in Molecular Silicon
Authors: Zhou Jiawang , Surampudi Sravan K. , Bragg Arthur E. , Klausen Rebekka S. 
Published: February 2016

AbstractInterest in molecular silicon semiconductors arises from the properties shared with bulk silicon like earth abundance and the unique architectures accessible from a structure distinctly different than rigid π‐conjugated organic semiconductors. We report ultrafast spectroscopic evidence for direct, photoinduced charge separation in molecular silicon semiconductors that supports the viability of molecular silicon as donor materials in optoelectronic devices. The materials in this study are σ–π hybrids, in which electron‐deficient aromatic acceptors flank a σ‐conjugated silicon chain. Transient absorption and femtosecond‐stimulated Raman spectroscopy (FSRS) techniques revealed signatures consistent with direct, optical charge transfer from the silane chain to the acceptor; these signatures were only observed by probing excited‐state structure. Our findings suggest new opportunities for controlling charge separation in molecular electronics.
ChemInform Abstract: SUBSTITUTIONSRK. AN BIS‐(IMINOBORANEN)
Authors: MELLER A. , MARINGGELE W. 
Published: February 2016

AbstractDas Cyclodiborazan (I) reagiert in nichtätherischer Lösung mit Butyl‐MgCl zur Dibutylverbindung (IIa) und mit Butyl‐Li zum Tetrabutylderivat (IIb).
ChemInform Abstract: RK. DES DIPHENYLPHOSPHINSAEUREISOTHIOCYANATS MIT N‐, O‐ UND S‐NUCLEOPHILEN
Authors: TOMASCHEWSKI GEORG , ZANKE DIETER 
Published: February 2016

AbstractDas Phosphinsäureisocyanat (III) reagiert mit den Aminen (II) zu den Thioureiden (I) (65‐99% Ausbeute), mit den Na‐phenolaten (IV) zu den Phosphinsäureestern (V) (42‐76%) und mit dem Mercaptid (VI) zum Thioncarbaminsäurethiolester (VII).
ChemInform Abstract: CHLORMETHYL‐ UND DICHLORMETHYLDICHLORPHOSPHAZOACYLE
Authors: SOKOL V. A. , GAMALEJA V. F. , KUCHAR' V. P. 
Published: February 2016

AbstractDie Halogenacetamide (I) reagieren mit den Tetrachlorphosphorderivaten (II) zu den Verbindungen (III).
ChemInform Abstract: INFRAROT‐SPEKTREN UND STRUKTUR SAURER ALKALIMETALLSALZ‐KOMPLEXE VON ALPHA‐METHOXY‐PHENYLESSIGSAEURE
Authors: COMPERE EDWARD L. JUN. 
Published: February 2016

AbstractDie Titelkomplexe (I) werden durch Reaktion des Ammoniumsalzes des Liganden mit den entsprechenden Alkalimetallchloriden in DMF oder durch Schmelzen von Alkalimetallhydroxiden mit dem Liganden in Ausbeuten von 15‐75% (steigend in der Reihe K, Rb, Na, Cs) erhalten.
ChemInform Abstract: OKTAEDRISCHE METALLCARBONYLE 17. MITT. CARBONYL‐KOMPLEXE DER METALLE DER GRUPPE VI B MIT AETHYLENDIPHOSPHIN
Authors: DOBSON GERARD R. , RETTENMAIER ALBERT J. 
Published: February 2016

AbstractDie Komplexe (III), die monomer und polymer vorliegen können, bilden sich bei der Umsetzung des Diphosphins (I) mit dem entsprechenden Metallcarbonyl (II) in Ausbeuten zwischen 50 und 57%.
ChemInform Abstract: FERROCENDERIVATE 51. MITT. STEREOCHEMIE VON METALLOCENEN 30. MITT. OPTISCHE AKTIVE (3)‐ UND (3)(3)FERROCENOPHANE 3. MITT. ZUR KONFORMATIONSANALYSE VON (3)FERROCENOPHANEN UEBER FERROCENDERIVATE
Authors: FALK H. , HOFER O. 
Published: February 2016

AbstractDie Dipolmomente und die Temperaturabhängigkeit der NMR‐Spektren sowie des Circulardichroismus der "Ferrocenbande" der optisch aktiven [3]Ferrocenophane (I)‐(V) werden gemessen.
ChemInform Abstract: SYNERGETISCHER EFFEKT BEI DER LOESUNGSMITTELEXTRAKTION, EINFLUSS VON SAUERSTOFF UND STICKSTOFF ENTHALTENDEN ORGANISCHEN BASEN AUF DIE STABILITAET VON ADDITIONSVERBINDUNGEN VON BETA‐DIKETONATO‐ZINK(II) UND ‐KOBALT(II)
Authors: SHIGEMATSU TSUNENOBU , HONJYO TAKAHARU , TABUSHI MASAYUKI , MATSUI MASAKAZU 
Published: February 2016

Abstract"Untersuchungen der Extraktion von Zn(II) und Co(II) mit Benzoyltrifluoraceton in Benzol in Gegenwart von 0‐ und N‐Basen ergeben die Bildung der Addukte I in der organischen Phase (Stabilitätskonstanten).
ChemInform Abstract: HYDRIDOCARBONYL‐TRIS‐(TRIPHENYLPHOSPHIN)‐RHODIUM(I) 1. MITT. NATUR DER INAKTIVIERUNG KATALYTISCHER RK. 2. MITT. ISOMERISATION VON N‐PENTENEN UND HEXEN‐(1)
Authors: YAGUPSKY M. , BROWN C. K. , YAGUPSKY G. , WILKINSON G. 
Published: February 2016

AbstractDie homogenen katalytischen Hydrierungs‐ und Isomerisierungsreaktionen von Alkenen in Gegenwart des Komplexes (Ia) werden besonders in verdünnten Lösungen verlangsamt oder gebremst durch eine Zerfallsreaktion des Katalysators, die über den nicht isolierten trans‐Komplex (IIa) zu einem dimeren Komplex (IIIa) führt, der katalytisch inaktiv ist.
ChemInform Abstract: CHEMIE MEHRKERNIGER VERBINDUNGEN 18. MITT. RK. VON DODECACARBONYLTRIOSMIUM UND VERWANDTEN DERIVATEN
Authors: DEEMING A. J. , JOHNSON B. F. G. , LEWIS J. 
Published: February 2016

AbstractDie linearen Dihalogenocarbonyl‐Os‐Verbindungen (I) werden reversibel bei längerem Kochen in Benzol unter Bildung der cyclischen Os‐Carbonyle (II) zersetzt (Ausbeute 82‐93%); neben (II) (X : J ) entsteht die dimere Verbindung (III).
ChemInform Abstract: KERNQUADRUPOLRESONANZSPEKTREN VON CHLOR IN D(8)‐UEBERGANGSMETALLKOMPLEXEN
Authors: FRYER C. W. , SMITH J. A. S. 
Published: February 2016

AbstractDie (35)Cl‐NQR‐Frequenzen in 32 Verbindungen des Typs (I) und (II) werden bezüglich der Elektronenstruktur der Komplexe diskutiert.
ChemInform Abstract: ANALYSE DER SCHWINGUNGSSTRUKTUR IM NAH‐UV‐ZIRKULARDICHROISMUS UND ABSORPTIONSSPEKTREN VON TYROSINDERIVATEN UND RIBONUCLEASE A BEI 77 GRAD K
Authors: HORWITZ JOSEPH , STRICKLAND E. HARDIN , BILLUPS CAROLYN 
Published: February 2016

AbstractDer CD im nahen UV‐Bereich und die Absorptionsspektren von Tyrosin (Ia) und den Derivaten (Ib)‐(Id) als Modellverbindungen werden bei 298 und 77°Kanalysiert, um die Tyrosyl‐CD‐Banden in Ribonuclease A zu identifizieren und ihren Beitrag zum Rotationsvermögen zu bestimmen.
ChemInform Abstract: SUBSTITUENTENEINFLUESSE AUF DIE EIGENSCHAFTEN DER CARBONYLGRUPPE 1. MITT. EINFLUSS DES INDUKTIVEN PI‐EFFEKTES
Authors: GUIHENEUF GEORGES , LAURENCE CHRISTIAN , WOJTKOWIAK BRUNO 
Published: February 2016

AbstractAus IR‐ und Raman‐spektrometrischen Untersuchungen wird für die Carbonylverbindungen (I) und (II) der Einfluß des M‐Effektes der Substituenten R auf die Carbonylgruppe geprüft.
ChemInform Abstract: GENAUE KORRELATION ZWISCHEN DER TRENNUNG VON CH2‐VALENZSCHWINGUNGSFREQUENZEN UND DEM HCH‐WINKEL IN MOLEKUELEN MIT DER H2C=GRUPPE
Authors: DUNCAN J. L. 
Published: February 2016

AbstractEs wird gezeigt, daß eine genaue Korrelation zwischen der Trennung asymm. und symm. CHz‐Valenzschwingungsfrequenzen (Differenzen) und dem HCH‐ Bindungswinkel in Verbindungen vom Typ (Ia) bis (III) existiert.
ChemInform Abstract: EPR‐UNTERSUCHUNG DES MECHANISMUS DER KATALYTISCHEN WIRKUNG EINIGER METALLOXID BEI DER OX. VON METHANOL
Authors: GESMUNDO FRANCESCO , ROSSI PIERFRANCESCO 
Published: February 2016

AbstractEs werden die Umwandlungen von CuO, Fe2O3, NiO und ZnO als Katalysatoren bei der Methanol‐Oxidation untersucht.