bluuebunny/crossref_metadata_2025_split huggingface dataset:
‘Zelfregulering in opdracht ondermijnt de autonomie’
Authors: Westerman Pauline 
Published: May 2016

‘Commissioned self-regulation undermines autonomy’
Self-regulation not always implies autonomy. Spontaneous self-regulation should be distinguished from commissioned self-regulation. The latter form of self-regulation is nowadays widespread and the result of outsourcing governmental activities. Outsourcing can be conceptualized in terms of Principal-Agent relations, in which the P commissions an A to realize P’s aims. In commissioned self-regulation the A is often constituted by the P and required to make rules in order to advance P’s aims. However, rule-making is not an activity which remains unaltered if it changes hands. In a context of spontaneous self-regulation rules fulfill a variety of functions. They guide actions and decision-making, they serve as both justification and as criticism of actions and decisions, and will thereby limit arbitrariness. In commissioned self-regulation, these manifold functions tend to be reduced to one dominant function: justifying performances towards P. In the latter capacity rules tend to be formalized and presented in a format that enables the P to arrive efficiently at a decision. Moreover, for the P the content of the rules matters less than their existence. The degree in which the external function of rules prevails determines not only how rules are presented but also how they are drafted and selected. The more A anticipates the perspective of P, the more autonomy risks to be undermined.
Ultrasonic and mechanical soil washing processes for the remediation of heavy-metal-contaminated soil
Authors: Kim Seulgi , Lee Wontae , Son Younggyu 
Published: May 2016

Abstract
Ultrasonic/mechanical soil washing process was investigated and compared with ultrasonic process and mechanical process using a relatively large lab-scale sonoreactor. It was found that higher removal efficiencies were observed in the combined processes for 0.1 and 0.3 M HCl washing liquids. It was due to the combination effects of macroscale removal for the overall range of slurry by mechanical mixing and microscale removal for the limited zone of slurry by cavitational actions.
Influence of structure of amines on the properties of amines‐modified reduced graphene oxide/polyimide composites
Authors: Ma Lang , Wang Guojian , Dai Jinfeng 
Published: May 2016

ABSTRACTGraphene oxide (GO), as an important precursor of graphene, was functionalized using alkyl‐amines with different structure and then reduced to prepare reduced amines grafted graphene oxide (RAGOs) by N2H4 · H2O. The successful chemical amidation reaction between amine groups of alkyl‐amines and carboxyl groups of GO was confirmed by Fourier transform infrared (FTIR), X‐ray photoelectron spectroscopy (XPS), and thermal gravimetric analysis (TGA). Then RAGOs/polyimide nanocomposites were prepared via in situ polymerization and thermal curing process with different loadings of RAGOs. The modification of amine chains lead to homogenous dispersion of RAGOs in the composites and it formed strong interfacial adhesion between RAGOs and the polymer matrix. The mechanical and electrical properties of polyimide (PI) were significantly improved by incorporation of a small amount of RAGOs, the influence of structure of amines grafted on RAGOs on the enhancement effects of composites was discussed. The research results indicated that the proper structure of amine could effectively enhance the properties of composites. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43820.
The role of the equilibrative nucleoside transporter 1 on tissue and fetal distribution of ribavirin in the mouse
Authors: Endres Christopher J. , Moss Aaron M. , Ishida Kazuya , Govindarajan Rajgopal , Unadkat Jashvant D. 
Published: May 2016

AbstractRibavirin is used for the treatment of hepatitis C virus (HCV) infection. The equilibrative nucleoside transporter 1 (ENT1) expressed in hepatocytes transports ribavirin into the liver, the site of efficacy of the drug. However, it is still unclear whether ENT1 plays a dominant role in the hepatic distribution of the drug in vivo. In addition, due to fetal toxicity, administration of ribavirin to pregnant women with HCV infection is contraindicated. ENT1 might play a role in the fetal distribution and therefore the fetal toxicity of ribavirin. The aim of the present study was to investigate the in vivo contribution of ENT1 to the tissue distribution of ribavirin. When compared with that in Ent1(+/+) mice, the ribavirin tissue to plasma concentration ratio (including phosphorylated metabolites) in Ent1(−/−) mice at 15 min and 6 h after intravenous [3H]‐ribavirin (3 mg/kg) administration was consistently and significantly decreased in the liver and the pancreas. Likewise, when compared with the Ent1(+/+) mice, the fetal distribution of ribavirin at 15 min after administration was significantly reduced in Ent1(−/−) fetuses and placenta. In contrast, there was no significant difference between Ent1(+/+), Ent1(+/−) and Ent1(−/−) mice in the fetal or placental to maternal plasma ribavirin concentration ratio at 2 h after ribavirin administration. The findings in the present study suggest that ENT1 plays a pivotal role in the distribution of ribavirin into tissues including the liver and pancreas, but affects only the rate, but not the extent, of ribavirin distribution into the fetus. Copyright © 2016 John Wiley & Sons, Ltd.
Compared to femoral venous access, upper extremity right heart catheterization reduces time to ambulation: A single center experience
Authors: Speiser Bernadette , Pearson Katrina , Xie Hui , Shroff Adhir R. , Vidovich Mladen I. 
Published: May 2016

ObjectivesTo determine ambulation times after right heart catheterization (RHC) via upper extremity access compared to femoral venous access.BackgroundTransradial coronary angiography has been associated with shorter times to ambulation. We hypothesized that RHC from the upper extremity would be similarly associated with shorter ambulation times when compared to traditional femoral access.MethodsWe performed a single‐center retrospective analysis of 379 consecutive patients who underwent a variety of diagnostic and interventional left‐ and right‐heart procedures through upper extremity and femoral access sites.ResultsThe time to ambulation for RHC through the arm veins versus the femoral vein was lower (42.6 min ± 14.2 vs. 175.0 min ± 65.0, P < 0.001). Fluoroscopy times (8.5 min ± 6.8 vs. 12.8 min ± 8.4, P < 0.001) and radiation doses (64.1 Gy cm−2 ± 60.0 vs. 108.5 Gy cm−2 ± 71.6, P < 0.001) were reduced in the radial compared to femoral group, respectively. In multivariate analyses, upper arm access (P < 0.0001), lower heparin dose (P = 0.032), inpatient status (P = 0.01), and concurrent PCI (P = 0.03) were associated with shorter times to ambulation.ConclusionsRight heart catheterization from the upper extremity is strongly associated with shorter times to ambulation. © 2016 Wiley Periodicals, Inc.
ChemInform Abstract: Heteropoly “Browns” as Class I Mixed Valence (W(IV,VI)) Complexes. Tungsten‐183 NMR of W(IV) Trimers.
Authors: PIEPGRASS K. , POPE M. T. 
Published: May 2016

AbstractSolutions of the 6‐electron reduced "heteropoly browns" of the Keggin anions α‐SiW12O44‐0, α‐BW12O45‐0, and α‐(H2)W12O640 have been investigated by 183W NMR spectroscopy.
ChemInform Abstract: Magnetic Exchange Interactions in Perovskite Solid Solutions. Part 7. A Study of the Non‐stoicheiometric Phase SrCoO3‐y by 57Fe Moessbauer Spectroscopy.
Authors: BATTLE P. D. , GIBB T. C. 
Published: May 2016

AbstractThe 57Fe Mößbauer spectra of 57Fe‐doped samples of Sr2Co2O5 (or SrCoO2.5), SrCoO2.56, and SrCoO2.63 are reported.
ChemInform Abstract: On the Synthesis of Xenon(II) Fluorostannates(IV).
Authors: DRUZINA B. , ZEMVA B. 
Published: May 2016

AbstractThe xenon(II) fluorostannates(IV) (I) and (II) are prepared by treating xenon difluoride (IV) with tin difluoride (III) or hydrazinium tetrafluorostannate(II) (V).
ChemInform Abstract: A New “Active” Chromium(III) Hydroxide: Cr2(μ‐OH)2(OH)4(OH2)4·2 H2O. Characterization and Use in the Preparation of Salts of the (H2O)4Cr(μ‐OH)2Cr(OH2)4+ 4 Ion. Crystal Structure of ((H2O)4Cr(μ‐OH)2Cr(OH2)4) ((H3C)3C6H2SO3)4·4 H2O.
Authors: SPICCIA L. , STOECKLI‐EVANS H. , MARTY W. , GIOVANOLI R. 
Published: May 2016

AbstractRapid addition of a buffer (pH ∼ 6.9, at ∼ 0 °C) to a solution of (I) results in the precipitation of the light blue‐green "active" dimer (II), that instantaneously dissolves on acidification regenerating more than 95% of the original dimer (I).
ChemInform Abstract: Structural Isomers of the Rhenium Azobenzene Complex CpRe(CO)2(N2Ph2).
Authors: EINSTEIN F. W. B. , SUTTON D. , TYERS K. G. 
Published: May 2016

AbstractThe complexes (I), prepared from Re(C5H5)(CO)2(THF) and the respective trans‐azobenzene in hexane, exist in the solid state with the azoligand bound in a cyclic η2‐form.
ChemInform Abstract: Electrogeneration of Low‐Valent‐Oxidation‐State Vanadium Porphyrins. Characterization of the First Vanadium(III) Species.
Authors: REEB P. , MUGNIER Y. , GUILARD R. , LAVIRON E. 
Published: May 2016

AbstractThe first V(III) porphyrin complex (II) is isolated after an exhaustive controlled‐potential electrolysis of (I), evaporation of the solvent and extraction by toluene.
ChemInform Abstract: Condensed Heterocycles: Synthesis of 2‐Aryl‐5‐oxo‐5‐H‐pyrido(3′,2′:5,6)pyrimido(2,1‐b) (1,3,4)oxadiazoles/thiadiazoles, 9‐Aryl‐5‐oxo‐5H‐pyrido(3′,2′:5,6)pyrimido(2,1‐b)thiadiazoles and 2‐Aryl‐6‐hydroxy(1,3,4)thiadiazolo/thiazolo(3,2‐a)benzimidazoles.
Authors: SAHU M. , SAHU J. K. , NAYAK A. 
Published: May 2016

AbstractReaction of the pyridine (I) with the heterocycles (II) or (IV) according to A) and B) yields the title systems (III) and (V).
ChemInform Abstract: Studies on Diazepines. Part 24. Reactions of Monocyclic 1H‐1,3‐Diazepines. Photo‐Sensitized Oxygenation.
Authors: KURITA J. , KOJIMA H. , TSUCHIYA T. 
Published: May 2016

AbstractPhotosensitized oxygenation of the 1H‐1,3‐diazepines (I) yields the fragmentation products (II) ‐ (VII).
ChemInform Abstract: (2σ + 4π) Photocycloaddition of 1,2‐Diarylcyclopropanes to 9,10‐Dicyanoanthracene via Geminate Radical Ion Pair.
Authors: ICHINOSE N. , MIZUNO K. , HIROMOTO Z. , OTSUJI Y. 
Published: May 2016

AbstractAddition of dicyanoanthracene (I) to the diarylcyclopropanes (IIa) ‐ (IId) under irradiation yields the isomeric adducts (IIIa) ‐ (IIId) and (IVa) ‐ (IVd) respectively.
ChemInform Abstract: Photoinduced Formation of Nitriles from Diphenylhydrazones.
Authors: GUELOGLU N. H. + , PARLAR H. 
Published: May 2016

AbstractPhotolytic fission of the diphenylhydrazones (I) yields the nitriles (II) and diphenylamine (III), which is cyclodehydrogenated on further irradiation to form the carbazole (IV).
ChemInform Abstract: Synthesis with Unsaturated Nitriles. Part 7. Trifluoromethanesulfenylation of Ylidenemalononitrile Dimers.
Authors: MOKROSZ M. J. 
Published: May 2016

AbstractThe alkylidenemalononitrile dimers (I), (V), (VII), and (IX) react with trifluoromethanesulfenyl chloride (II) to give the corresponding monosulfenylated products (III), (VI), (VIII), (X), and (XI).
ChemInform Abstract: Nickel Catalyzed Substitution of Allyl Acetates or Allyl Sulfones.
Authors: CUVIGNY T. , JULIA M. 
Published: May 2016

AbstractReaction of the activated methylene compounds (II) with the allylic compounds (I) in the presence of Ni catalysts and a reduction reagent yields mixtures of the olefinic products (IV) ‐ (VII).
ChemInform Abstract: Perfluoroalkyl‐ and Fluorocarbonylhydrazines.
Authors: SUNDERMEYER W. , WITZ M. 
Published: May 2016

AbstractThe title compounds (III), (V), and (VII) are synthesized by reacting xenon difluoride (I) with the isocyanates (II) and (VI) or the perfluoroazapropene (IV).
ChemInform Abstract: Synthesis and Properties of 9,10‐Arylsulphonylimido‐9,10‐dihydrophenanthrene.
Authors: MARKOV V. I. , DANILEIKO D. A. , MALYSH G. G. 
Published: May 2016

AbstractReaction of N,N‐dichloroarylsulfonamides (II) with phenanthrene (I) is reexamined in the presence of different bases (MgO, CaCO3, and (III)) and initiators (Cu, Cu2Cl2).
ChemInform Abstract: Synthesis of Substituted Spiro(azetidin‐2‐one‐4,2′(or 3,2′)‐tricyclo‐(3.3.1.13,7)decane) Derivatives.
Authors: MULLEN G. B. , GEORGIEV V. ST. 
Published: May 2016

Abstract2‐Adamantanone (II) and the spiro‐epoxide (IV) are transformed into the methyleneadamantanes (VI) which undergo cycloaddition with chlorosulfonyl isocyanate (VII), yielding the N‐chlorosulfonyl spiro‐azetidinones (VIII) and (Xa).
ChemInform Abstract: Ethyl 2,4‐Dioxoalkanoates as Starting Materials for a Convenient Route to 3(2H)Furanones and 3(2H)Furanimines.
Authors: BARALDI P. G. , BARCO A. , BENETTI S. , MANFREDINI S. , POLLINI G. P. , SIMONI D. 
Published: May 2016

AbstractThe title compounds (I) are converted to oxazines of type (II)‐(VI).
ChemInform Abstract: A Facile Synthesis and Solvolysis of 4‐(Bis(methylthio))methylene‐2‐phenyl‐2‐oxazolin‐5‐one.
Authors: TRIPATHY P. K. , ROY J. , MUKERJEE A. K. 
Published: May 2016

AbstractThe title compound (IV) can easily be synthesized in a one‐pot procedure starting from hippuric acid (I).
ChemInform Abstract: A Cyclization Reaction of 2‐Cyanomethylbenzothiazole with Acetylenic Compounds via Michael Addition.
Authors: KONWAR D. , BORUAH R. C. , SANDHU J. S. 
Published: May 2016

AbstractReaction of the cyanomethylbenzothiazole (II) with the acetylene derivatives (Ia) ‐ (Ic) yields the cyanopyrido(2,1‐b)benzothiazolones (III).
ChemInform Abstract: Automatic Assembly of Dilactones from the d,l‐Forms of α,α′‐Dihydroxy‐ α,α′‐dimethylglutaric Acid and α,α′‐Dihydroxy‐α,α′‐dimethyladipic Acids.
Authors: KOSTYANOVSKII R. G. , EL'NATANOV YU. I. , LESHCHINSKAYA V. P. , CHERVIN I. I. 
Published: May 2016

AbstractThe dilactones (IV) are formed under mild conditions only from the monolactone (IIa) or the d,l‐form (IIIa) of the dihydroxydimethyladipic acid (III).
ChemInform Abstract: Pyrimidinium N‐Dicyanomethylide. Synthesis and Reactivity Towards Dimethyl Acetylenedicarboxylate.
Authors: DE LA HOZ A. , DE PAZ J. L. G. , DIEZ‐BARRA E. , ELGUERO J. , PARDO C. 
Published: May 2016

AbstractPyrimidine (I) reacts with tetracyanoethylene oxide (II) to yield the pyrimidinium N‐dicyanomethylide (III).
ChemInform Abstract: Attempts to Quaternize Secondary Phosphanes with tert‐Butyl Bromide.
Authors: WOLFSBERGER W. 
Published: May 2016

AbstractThe monoalkyldiphenylphosphanes (I) are cleaved by metallic sodium to form phenylsodium (II) and the phenyl alkyl phosphides (III), which react with tert‐butyl chloride (IV) to give the secondary phosphanes (V).
ChemInform Abstract: Contributions to the Chemistry of Iodine Pentafluoride. Part 4. IF5 as a Selective Oxidizing Fluorinating Agent for Organophosphorus(III) Compounds.
Authors: FROHN H. J. , MAURER H. 
Published: May 2016

AbstractThe aryl and alkylphosphines (II), (IV), (VI), and (VII) are oxidized selectively by IF5 (I) to yield the fluorophosphoranes (III), (V), and (VIII).
ChemInform Abstract: Pentacoordinated Molecules. Part 67. Formation and Structure of Cyclic Five‐Coordinated Antimony Derivatives. The First Square‐Pyramidal Geometry for a Bicyclic Stiborane.
Authors: HOLMES R. R. , DAY R. O. , CHANDRASEKHAR V. , HOLMES J. M. 
Published: May 2016

AbstractThe stiboranes (I) and (II) are formed by the oxidative‐addition reaction of tetrachloro‐o‐benzoquinone with the corresponding stiboles.
ChemInform Abstract: Synthesis and Molecular Structure of a Novel Aluminacarborane, nido‐(μ‐6,9‐AlEt(OEt2)‐6,9‐C2B8H10).
Authors: SCHUBERT D. M. , KNOBLER C. B. , REES W. S. JUN. , HAWTHORNE M. F. 
Published: May 2016

AbstractThe synthesis of the air‐ and water‐sensitive title compound (IIIa) is carried out by reaction of an equimolar amount of (I) (freshly prepared by deprotonation of 5,6‐C2B8H12 with excess NaH) with the Al compound (II) in refluxing toluene.
ChemInform Abstract: The Chemistry of Iodine Pentafluoride. Part 5. IF5 as Oxidizing Fluorinating Agent for Organo Element Compounds of Arsenic, Antimony, and Bismuth: Selectivity and Limits of the Method.
Authors: FROHN H. J. , MAURER H. 
Published: May 2016

AbstractThe reactions of the organo‐metallic compounds (I) ‐ (III) with IF5 in acetonitrile or dichloromethane at temperatures below 0°C are investigated in detail.
ChemInform Abstract: Manganese(III)‐Catecholate Coordination in the Bis(tetrabromocatecholato)(triphenylphosphine oxide)manganese(III) Anionic Dimer.
Authors: LARSEN S. K. , PIERPONT C. G. , DEMUNNO G. , DOLCETTI G. 
Published: May 2016

AbstractTetrabromo‐1,2‐benzoquinone in acetone reacts with MnCl2 in the presence of PPh3 and KOH (15 min reflux) to yield the title complex (I) which crystallizes in the space group P21/n with Z=4.
ChemInform Abstract: Neutral Spin‐Delocalized Mixed‐Valence Mn(I)Mn(II) Dimers Bridged by Alkoxide, Imidazolate, or Malonodinitrile Anions.
Authors: GROSS R. , KAIM W. 
Published: May 2016

AbstractThe complexes (I)‐(III) are produced by oxidation of the Mn(I) precursor complexes with O2 (air) or PbO2 in aprotic media and characterized by EPR as spin‐delocalized Mn(I)/Mn(II) systems.
ChemInform Abstract: Synthesis and Cluster Interconversion Chemistry of a Linear Trinuclear Hexakis(μ‐benzenethiolato)triiron(II) Hexacarbonyl Compound.
Authors: WALTERS M. A. , DEWAN J. C. 
Published: May 2016

AbstractThe neutral title compound (I) assembles in a solution containing NaSPh and FeCl2 in EtOH under CO at 20 °C within 3 days.
ChemInform Abstract: Cobalt(II) Complex of a Novel Pentadentate Half‐Clathro Half‐Cyclidene Ligand Produced by a Base‐Catalyzed Ligand Rearrangement.
Authors: CASTE M. L. , CAIRNS C. J. , CHURCH J. , LIN W.‐K. , GALLUCCI J. C. , BUSCH D. H. 
Published: May 2016

AbstractThe low‐spin Co(II) complex (I) of an unsaturated macrocycle is synthesized by reaction of the protonated ligand with Co acetate in refluxing MeOH under basic conditions.
ChemInform Abstract: Chemical Oxidation of Binuclear Rhodium(I) Complexes with Silver Salts. Synthesis, X‐Ray Crystal Structure, and Electrochemical Properties of the Rh4+ 2 Mixed‐Ligand Complex Rh2(Form)2(O2CCF3)2(H2O)2·0.5 C6H6 (Form: N,N′‐Di‐p‐tolylformamidinate Anion).
Authors: PIRAINO P. , BRUNO G. , TRESOLDI G. , LO SCHIAVO S. , ZANELLO P. 
Published: May 2016

AbstractThe facile chemical oxidation of the binuclear Rh(I) complex (I) with AgO2CCF3 yields the mixed‐ligand complex (IIa) which crystallizes in the space group P1 with Z=2.
ChemInform Abstract: Dissociative Substitution in Four‐Coordinate Planar Platinum(II) Complexes. Part 2. Crystal Structure of cis‐Diphenylbis(dimethyl sulfide)platinum(II) and Kinetics of Thioether Displacement by Bidentate Ligands in Benzene.
Authors: ALIBRANDI G. , BRUNO G. , LANZA S. , MINNITI D. , ROMEO R. , TOBE M. L. 
Published: May 2016

AbstractA single‐crystal X‐ray diffraction study confirms the square planar cis geometry of the title complex (I) (space group P21/n, Z=4).
ChemInform Abstract: Synthesis of (+)‐ar‐Turmerone Employing Organolithium Reagents.
Authors: GHARPURE M. M. , JOSHI P. L. , RAO A. S. 
Published: May 2016

AbstractThe reaction between the lithium salt (Ia) and the racemic acid (II) represents a successful method for the preparation of racemic ar‐turmerone (III).
ChemInform Abstract: Synthetic Studies on d,l‐Aspterric Acid, Carotane Type Sesquiterpene. Part 1. Synthesis of d,l‐(3α,4ξ,6aα,10aα)‐Octahydro‐4‐hydroxy‐7,7‐dimethyl‐8H‐3# ,10a‐methano‐1H‐2‐benzoxocin‐8‐one.
Authors: HARAYAMA T. , SHINKAI Y. , INUBUSHI Y. 
Published: May 2016

AbstractThe diester (I) undergoes twofold Dieckmann cyclization, yielding the bicycle (III).
ChemInform Abstract: Structure of the Products of Reaction Between 3,4,6‐Tri‐O‐acetyl‐2‐deoxy‐2‐nitroso‐α‐D‐glucopyranosyl Chloride and the Methyl Esters of Some N‐(Protected)‐L‐Hydroxyamino Acids.
Authors: SMIATACZ Z. , PASZKIEWICZ E. 
Published: May 2016

AbstractThe reaction of the dimeric title compound (I) with the protected amino acid esters (II) yields the anomeric products (III) and (IV).
ChemInform Abstract: 2‐Amino‐2′‐deoxytubercidin and Related Pyrrolo(2,3‐d)pyrimidinyl‐2′‐deoxyribofuranosides.
Authors: SEELA F. , STEKER H. , DRILLER H. , BINDIG U. 
Published: May 2016

AbstractThe nucleosides (III) are prepared by phase‐transfer glycosylation of (II) with the halogenose (I).
ChemInform Abstract: Nucleosides and Nucleotides. Part 69. Reaction of 5‐Bromouridine Derivatives with Dimethyl Malonate Carbanion. A Novel Entry to the Synthesis of Uridine‐5‐acetic acids.
Authors: INOUE H. , SAITO N. , UEDA T. 
Published: May 2016

AbstractThe 5‐bromo uridine (Ib) reacts with dimethylmalonate (II) to form the substitution product (Ic) which is hydrolyzed under various conditions, producing the compounds (III) ‐ (VI).
ChemInform Abstract: closo‐Halogenohydrohexaborates. Part 1. Preparation of the Pure closo‐Halogenohydrohexaborates XnB6H2‐ 6‐n, n = 1‐6, X: Cl, Br, I, Including the Stereoisomers.
Authors: PREETZ W. , FRITZE J. 
Published: May 2016

AbstractMixtures of the title anions are obtained by carefully controlled treatment of aqueous alkaline solutions of Na2B6H6 with halogens or with NCS or NBS (substitution reaction according to the scheme, preparation conditions for each anion are given in detail).
ChemInform Abstract: Synthesis of γ‐Fe2O3 by Thermal Decomposition of FeC4H4O4·4 H2O.
Authors: VENKATARAMAN A. , MUKHEDKAR V. A. , RAHMAN M. M. , NIKUMBH A. K. , MUKHEDKAR A. J. 
Published: May 2016

AbstractThe thermal decomposition of FeC4H4O4·4 H2O (I) has been studied in static air, dynamic N2, and dynamic air by TGA, DTA, DTG, and d.c.
ChemInform Abstract: Hindered Internal Conversion in Rigid Media. Thermally Nonequilibrated 3IL and 3CT Emissions from (Cu(5‐X‐phen)(PPh3)2)+ and (Cu(4,7‐X2‐phen)(PPh3)2)+ Systems in a Glass at 77 K.
Authors: CASADONTE D. J. JUN. , MCMILLIN D. R. 
Published: May 2016

AbstractThe absorption and emission spectra of the title Cu(I) complexes (I) and (II) are investigated.
ChemInform Abstract: Ligand Perturbation of the Molecular and Electronic Structures of Quadruply Bonded Dimers. The Crystal Structures of Mo2Br4(PMe3)4 and Mo2I4(PMe3)4, and the Vibrational and Electronic Spectra of a Series of M2X4L4 Complexes.
Authors: HOPKINS M. D. , SCHAEFER W. P. , BRONIKOWSKI M. J. , WOODRUFF W. H. , MISKOWSKI V. M. , DALLINGER R. F. , GRAY H. B. 
Published: May 2016

AbstractThe ligand dependence of the molecular and electronic structures of the title dimers (I) are investigated by evaluating four fingerprint experimental parameters: metal‐metal distance and stretching frequency, and 1(δ → δ*) transition energy and intensity.
ChemInform Abstract: Enantioselective Functionalization of Prochiral Diols via Chiral Spiroketals: Preparation of Optically Pure 2‐Substituted 1,3‐Propanediol Derivatives and Asymmetric Synthesis of Chroman Ring and Side Chain of α‐Tocopherol.
Authors: HARADA T. , HAYASHIYA T. , WADA I. , IWA‐AKE N. , OKU A. 
Published: May 2016

AbstractThe reaction of the bis‐ethers (I) with l‐menthone (II) according to the conditions indicated selectively yields the thermodynamically stable equatorial isomers (IVa)‐(IVc).
ChemInform Abstract: An Example of Axial Selectivity in Nucleophilic Additions to Cyclohexanones and Cyclohexenones.
Authors: TROST B. M. , FLOREZ J. , JEBARATNAM D. J. 
Published: May 2016

AbstractHigh axial selectivity is observed in the nucleophilic additions of the anions of the salts (I) to various ketones (II), (IV), (VI), and (VIII) to give the addition products (III), (V), (VII), (IX), or (X).
ChemInform Abstract: Thermal Isomerization of Benzocyclobutene.
Authors: CHAPMAN O. L. , TSOU U.‐P. E. , JOHNSON J. W. 
Published: May 2016

AbstractThermolysis of benzocyclobutene (13CH2, 99%) gives styrene labeled in the β (48%), ortho (30%), α (14%), meta (4%), and para (4%) positions.