bluuebunny/crossref_metadata_2025_split huggingface dataset:
New 3 D Tubular Porous Structure of an Organic–Zincophosphite Framework with Interesting Gas Adsorption and Luminescence Properties
Authors: Wang Chih‐Min , Lee Li‐Wei , Chang Tsung‐Yuan , Fan Bing‐Lun , Wang Chih‐Ling , Lin Hsiu‐Mei , Lu Kuang‐Lieh 
Published: October 2016

AbstractA new 3D tubular zinc phosphite, Zn2(C22H22N8)0.5(HPO3)2⋅H2O (1), incorporating a tetradentate organic ligand was synthesized under hydro(solvo)thermal conditions and structurally characterized by single‐crystal X‐ray diffraction. Compound 1 is the first example of inorganic zincophosphite chains being interlinked through 1,2,4,5‐tetrakis(imidazol‐1‐ylmethyl)benzene to form a tubular porous framework with unusual organic–inorganic hybrid channels. The thermal and chemical stabilities, high capacity for CO2 adsorption compared to that for N2 adsorption, and interesting optical properties of LED devices fabricated using this compound were also studied.
Carboxylic Acids as Directing Groups for C−H Bond Functionalization
Authors: Pichette Drapeau Martin , Gooßen Lukas J. 
Published: October 2016

AbstractThe selective transformation of C−H bonds is one of the most desirable approaches to creating complexity from simple building blocks. Several directing groups are efficient in controlling the regioselectivity of catalytic C−H bond functionalizations. Among them, carboxylic acids are particularly advantageous, since they are widely available in great structural diversity and at low cost. The carboxylate directing groups can be tracelessly cleaved or may serve as the anchor point for further functionalization through decarboxylative couplings. This Minireview summarizes the substantial progress made in the last few years in the development of reactions in which carboxylate groups direct C−H bond functionalizations with formation of C−C, C−O, C−N, or C−halogen bonds at specific positions. It is divided into sections on C−C, C−O, C−N, and C−halogen bond formation, each of which is subdivided by reactions and product classes. Particular emphasis is placed on methods that enable multiple derivatizations by combining carboxylate‐directed C−H functionalization with decarboxylative couplings.
Enantioselective Stereodivergent Nucleophile‐Dependent Isothiourea‐Catalysed Domino Reactions
Authors: Matviitsuk Anastassia , Taylor James E. , Cordes David B. , Slawin Alexandra M. Z. , Smith Andrew D. 
Published: October 2016

Abstractα,β‐Unsaturated acyl ammoniums generated from the reaction of α,β‐unsaturated 2,4,6‐trichlorophenol (TCP) esters bearing a pendent enone with an isothiourea organocatalyst are versatile intermediates in a range of enantioselective nucleophile‐dependent domino processes to form complex products of diverse topology with excellent stereoselectivity. Use of either 1,3‐dicarbonyls, acyl benzothiazoles, or acyl benzimidazoles as nucleophiles allows three distinct, diastereodivergent domino reaction pathways to be accessed to form various fused polycyclic cores containing multiple contiguous stereocentres.
“Shine & Click” Photo‐Induced Interfacial Unmasking of Strained Alkynes on Small Water‐Soluble Gold Nanoparticles
Authors: Luo Wilson , Gobbo Pierangelo , McNitt Christopher D. , Sutton Dewey A. , Popik Vladimir V. , Workentin Mark S. 
Published: October 2016

AbstractIn this study, we report the design, synthesis, and characterization of small 3 nm water soluble gold nanoparticles (AuNPs) that feature cyclopropenone‐masked strained alkyne moieties capable of undergoing interfacial strain‐promoted cycloaddition (i‐SPAAC) with azides after exposure to UV‐A light. A strained alkyne precursor was incorporated onto AuNPs by direct ligand exchange of a thiol‐modified cyclopropenone‐masked dibenzocyclooctyne (photoDIBO) ligand. These photoDIBO‐AuNPs were characterized by 1H NMR, IR, and UV/Vis spectroscopy, as well as transmission electron microscopy (TEM) and thermogravimetric analysis (TGA), and the extent of modification was quantified. Upon irradiation with UV‐A light, photoDIBO‐AuNPs underwent efficient and quantitative regeneration of the parent strained alkyne by photochemical decarbonylation to afford DIBO‐derivatized AuNPs. DIBO‐AuNPs were found to react cleanly and rapidly (k=5.3×10−2 m−1 s−1) by an interfacial strain‐promoted alkyne‐azide cycloadditon (i‐SPAAC) with benzyl azide, which served as a simple model system. Furthermore, DIBO‐AuNPs were reacted with various azides and a nitrone (interfacial strain‐promoted alkyne‐nitrone cycloaddition, i‐SPANC) to showcase the generality of this approach for the facile modification of AuNP surfaces and their properties. The cyclopropenone‐based photo‐triggered click chemistry at the interface of water‐soluble AuNPs offers exciting opportunities for the atom‐by‐atom control and assembly of functional materials for applications in materials and biomaterials science as well as in chemical biology.
Exploring Redox States, Doping and Ordering of Electroactive Star‐Shaped Oligo(aniline)s
Authors: Mills Benjamin M. , Fey Natalie , Marszalek Tomasz , Pisula Wojciech , Rannou Patrice , Faul Charl F. J. 
Published: October 2016

AbstractWe have prepared a simple star‐shaped oligo(aniline) (TDPB) and characterised it in detail by MALDI‐TOF MS, UV/Vis/NIR spectroscopy, time‐dependent DFT, cyclic voltammetry and EPR spectroscopy. TDPB is part of an underdeveloped class of π‐conjugated molecules with great potential for organic electronics, display and sensor applications. It is redox active and reacts with acids to form radical cations. Acid‐doped TDPB shows behaviour similar to discotic liquid crystals, with X‐ray scattering investigations revealing columnar self‐assembled arrays. The combination of unpaired electrons and supramolecular stacking suggests that star‐shaped oligo(aniline)s like TDPB have the potential to form conducting nanowires and organic magnetic materials.
Nanoparticle‐Assisted Affinity NMR Spectroscopy: High Sensitivity Detection and Identification of Organic Molecules
Authors: Diez‐Castellnou Marta , Salvia Marie‐Virginie , Springhetti Sara , Rastrelli Federico , Mancin Fabrizio 
Published: October 2016

AbstractA simple and effective method for high‐sensitivity NMR detection of selected compounds is reported. The method combines 1D NMR diffusion filter experiments and small monolayer‐protected nanoparticles as high‐affinity receptors. Once bound to the nanoparticles, the diffusion coefficient of the analyte decreases in such way that spectral editing based on diffusion filters can separate its signals from those of other mixture components. Using nanoparticles functionalized with Zn2+‐triazacyclonane complexes, detection and identification of phosphorylated organic molecules can be achieved. Diphenyl phosphate can be detected at 25 micromolar concentration with good selectivity. The selectivity toward organic carboxylates is enhanced at pD=3.75. In these conditions, commercial tablets containing betamethasone phosphate and a large excess of benzoate could be successfully analyzed.
Adsorption of Metallocenes on Silica
Authors: Cluff Kyle J. , Blümel Janet 
Published: October 2016

AbstractThe adsorption of the metallocenes ferrocene, doubly deuterated ferrocene, cymantrene and nickelocene, as well as molybdenum hexacarbonyl, proceeds in the absence of a solvent. Large single pieces of silica gel were placed in contact with the solid metallocenes and the adsorption process was visualized on a macroscopic scale and the maximal loadings were determined. 1H, 2H, and 13C solid‐state NMR studies confirmed fast isotropic reorientation of the surface‐adsorbed metallocene molecules within the pores of the silica. All prevalent anisotropic solid‐state interactions were averaged out. The solid diamagnetic and paramagnetic materials were amenable to measurements with a standard solution NMR instrument. All metallocenes adsorbed in a monolayer. In the case of ferrocene and cymantrene, different 13C MAS signals were obtained for the cyclopentadienyl ring carbon nuclei and assigned to one ring interacting with the surface and one ring pointing away from it. The relative adsorption strengths of ferrocene on different silica supports, nanotubes, and activated carbon were determined by a novel straightforward method recording the desorption temperature. The reversibility of adsorption has been demonstrated by competition experiments using ferrocene, doubly deuterated ferrocene, and cymantrene. Adsorbed nickelocene could be reduced to small Ni0 aggregates on the surface and the catalytic activity of the resulting material for the cyclotrimerization of phenylacetylene was proven.
High‐Nuclear Organometallic Copper(I)–Alkynide Clusters: Thermochromic Near‐Infrared Luminescence and Solution Stability
Authors: Zhuo Hong‐Yan , Su Hai‐Feng , Cao Zhao‐Zhen , Liu Wei , Wang Shu‐Ao , Feng Lei , Zhuang Gui‐Lin , Lin Shui‐Chao , Kurmoo Mohamedally , Tung Chen‐Ho , Sun Di , Zheng Lan‐Sun 
Published: October 2016

AbstractCu(CF3COO)2 reacts with tert‐butylacetylene (tBuC≡CH) in methanol in the presence of metallic copper powder to give two air‐stable clusters, [CuI15(tBuC≡C)10(CF3COO)5]⋅tBuC≡CH (1) and [CuI16(tBuC≡C)12(CF3COO)4(CH3OH)2] (2). The assembly process involves in situ comproportionation reaction between Cu2+ and Cu0 and the formation of two different clusters is controlled by reactants concentration. The clusters consist of Cu15 and Cu16 cores co‐stabilized by strong by σ‐ and π‐bonded tert‐butylethynide and CF3COO− (together with methanol molecule in 2). Their stabilities in solution were confirmed using electrospray ionization mass spectrometry in which the cluster core remains intact for 1 in chloroform and acetone, and for 2 in acetonitrile. Strong thermochromic luminescence in the near infrared (NIR) region was observed in the solid‐state. Of particular interest, the emission maximum of 1 is red‐shifted from 710 nm at 298 K to 793 nm at 93 K, along with a 17‐fold fluorescence enhancement. In contrast, 2 exhibits red shift from 298 to 123 K followed by blue shift from 123 to 93 K. The emission wavelength was correlated with the structural parameters using variable‐temperature X‐ray single‐crystal analyses. The rich cuprophilic interaction plays a significant role in the formation of 3LMCT (tBuC≡C→Cux) excited state mixed with cluster‐centered (3CC) characters, which can be considerably influenced by temperature, leading to thermochromic luminescence. The present work provides 1) a new synthetic protocol for the high‐nuclear CuI–alkynyl clusters; 2) a comprehensive insight into the mechanism of thermochromic luminescence; 3) unusual emissive materials with the characters of NIR and thermochromic luminescence simultaneously.
Template‐Free Synthesis of Nanorod‐Assembled Hierarchical Zn1−xMnxS Hollow Nanostructures with Enhanced Pseudocapacitive Properties
Authors: Jin Ying , Xu Jiaying , Wang Lanfang , Lu Qingyi , Gao Feng 
Published: October 2016

AbstractMixed‐metal sulfide Zn1−xMnxS nanorod‐assembled hierarchical hollow spheres were synthesized by a template‐free solvothermal process based on Ostwald ripening. In the reaction system, glycerol plays a key role in the formation of ZnxMn1−xS hierarchical hollow structures by a quasi‐microemulsion‐template mechanism. When applied as capacitor electrode material, the hierarchical Zn1−xMnxS hollow spheres show excellent electrochemical performance. Specifically, Zn0.25Mn0.75S hollow spheres can deliver a high specific capacitance of 664 F g−1 at a current rate of 1 A g−1, which is almost five times of that of MnS under the same conditions and higher than those of previously reported single Mn‐based compounds.
A Highly Efficient Copper‐Mediated Radioiodination Approach Using Aryl Boronic Acids
Authors: Zhang Pu , Zhuang Rongqiang , Guo Zhide , Su Xinhui , Chen Xiaoyuan , Zhang Xianzhong 
Published: October 2016

AbstractA convenient and quantitative radioiodination method by copper‐mediated cross‐coupling of aryl boronic acids was developed. The mild labeling conditions, ready availability of the boronic acid substrate, simple operation, broad functional group tolerance and excellent radiochemical yield (RCY) make this a practical strategy for radioiodine labeling without further purification.
Two‐Dimensional Cobalt‐/Nickel‐Based Oxide Nanosheets for High‐Performance Sodium and Lithium Storage
Authors: Zhang Dan , Sun Wenping , Chen Zhihui , Zhang Yu , Luo Wenbin , Jiang Yinzhu , Dou Shi Xue 
Published: October 2016

AbstractTwo‐dimensional (2D) nanomaterials are one of the most promising types of candidates for energy‐storage applications due to confined thicknesses and high surface areas, which would play an essential role in enhanced reaction kinetics. Herein, a universal process that can be extended for scale up is developed to synthesise ultrathin cobalt‐/nickel‐based hydroxides and oxides. The sodium and lithium storage capabilities of Co3O4 nanosheets are evaluated in detail. For sodium storage, the Co3O4 nanosheets exhibit excellent rate capability (e.g., 179 mA h g−1 at 7.0 A g−1 and 150 mA h g−1 at 10.0 A g−1) and promising cycling performance (404 mA h g−1 after 100 cycles at 0.1 A g−1). Meanwhile, very impressive lithium storage performance is also achieved, which is maintained at 1029 mA h g−1 after 100 cycles at 0.2 A g−1. NiO and NiCo2O4 nanosheets are also successfully prepared through the same synthetic approach, and both deliver very encouraging lithium storage performances. In addition to rechargeable batteries, 2D cobalt‐/nickel‐based hydroxides and oxides are also anticipated to have great potential applications in supercapacitors, electrocatalysis and other energy‐storage‐/‐conversion‐related fields.
Cationic Bismuth Amides: Accessibility, Structure, and Reactivity
Authors: Dengel Hannah , Lichtenberg Crispin 
Published: October 2016

AbstractThe synthetic access to cationic bismuth compounds based on simple, monodentate, synthetically useful amido ligands, [Bi(NR2)2(L)n]+, has been investigated (R=Me, iPr, Ph; L=neutral ligand). With [BPh4]− as a counteranion, the formation of contact ion pairs and subsequent phenyl transfer from B to Bi is observed. An intermediate of this reaction, [Bi(NMe2)2(HNMe2)(BPh4)] (1), could be isolated and fully characterized. The use of a fluorinated tetraarylborate as a counteranion leads to more stable cationic bismuth amides. The solvent‐separated ion pairs [Bi2(μ2‐NMe2)2(NMe2)2(thf)6]2+ (4) and [Bi(NiPr2)2(thf)3]+ (5) were fully characterized, with [B(3,5‐C6H3(CF3)2)4]− anions balancing the positive charge. The coordination chemistry, aggregation in solution, and spectroscopic features of these compounds were investigated. Compounds 4 and 5 show an increased reactivity towards diisopropylcarbodiimide compared to their neutral parent compounds. These reactions result in formation of the first cationic bismuth guanidinates. Characterization techniques include 1H, 11B, 13C, 15N, 19F, and 31P (VT)NMR and IR spectroscopy, single crystal X‐ray diffraction analysis, and DFT calculations.
Ionic Liquids and Poly(ionic liquid)s for Morphosynthesis of Inorganic Materials
Authors: Gao Min‐Rui , Yuan Jiayin , Antonietti Markus 
Published: October 2016

AbstractIonic liquids (ILs) are new, innovative ionic solvents with rich physicochemical properties and intriguing pre‐organized solvent structures; these materials offer great potential to impact across versatile areas of scientific research, for example, synthetic inorganic chemistry. Recent use of ILs as precursors, templates, and solvents has led to inorganic materials with tailored sizes, dimensionalities, morphologies, and functionalities that are difficult to obtain, or even not accessible, by using conventional solvents. Poly(ionic liquid)s (PILs) polymerized from IL monomers also raise the prospect of modifying nucleation, growth, and crystallization of inorganic objects, shedding light on the synthesis of a wide range of new materials. Here we survey recent key progress in using ILs and PILs in the field of synthetic inorganic chemistry. As well as highlighting the unique features of ILs and PILs that enable advanced synthesis, the effects of adding other solvents to the final products, along with the emerging applications of the created inorganic materials will be discussed. We finally provide an outlook on several development opportunities that could lead to new advancements of this exciting research field.
ChemInform Abstract: Redetermination of the Crystal Structure of NbF4.
Authors: Bandemehr Jascha , Conrad Matthias , Kraus Florian 
Published: October 2016

AbstractSingle crystals of NbF4 are prepared by disproportionation of Nb2F5 (Nb Tube in evacuated silica tubes, 1273 K, 2 d) and by solid state reaction of Nb and NbF5 (1073 K, 2 d; heating rate of 16 K/h).
ChemInform Abstract: Fused Perovskite Tunnel Structures in Ba5Fe6+S4+O8 (0.44 ≤ x ≤ 0.55) with x‐Dependent Two‐Stage Magnetizations.
Authors: Wright Taylor , Prots Yurii , Valldor Martin 
Published: October 2016

AbstractPolycrystalline samples of Ba5Fe6+xS4+xO8 (x = 0.44—0.55) are prepared by solid state reaction of stoichiometric amounts of BaO, Fe2O3 and S (Al2O3 crucible in evacuated silica tubes, 800 °C, 70 h).
ChemInform Abstract: Magnetic Properties and Giant Reversible Magnetocaloric Effect in GdCoC2.
Authors: Meng Lingjian , Xu Chi , Yuan Ye , Qi Yang , Zhou Shengqiang , Li Lingwei 
Published: October 2016

AbstractThe title compound is obtained by arc melting of stoichiometric amounts of the elements followed by annealing at 900 °C for six days.
ChemInform Abstract: Asymmetric Synthesis of Nature‐Inspired Bioactive Spiro Compounds Through Organocatalytic Diels—Alder Reactions.
Authors: Ramachary Dhevalapally B. , Krishna Patoju M. 
Published: October 2016

AbstractFor the first time, a highly stereoselective three‐component Diels—Alder reaction of arylideneacetones, aryl aldehydes and 1,3‐indanone using a Barbas dienamine strategy is reported.
ChemInform Abstract: Synthesis of Cyclopentachromans by N‐Heterocyclic Carbene‐Mediated Homoenolate Annulation of Chroman‐3‐ene‐4‐ones.
Authors: Krishnan Jagadeesh , Sinu C. R. , Anusree M. , Seetha Lakshmi K. C. , Mayadevi T. S. , Eringathodi Suresh , Nair Vijay 
Published: October 2016

AbstractAnnulation reaction of arylidene chromanones, thiochromanones, and tetralones with α,β‐unsaturated aldehydes allow the synthesis of a wide variety of tricyclic pentenes.
ChemInform Abstract: Supported Gold Nanoparticles for Efficient α‐Oxygenation of Secondary and Tertiary Amines into Amides.
Authors: Jin Xiongjie , Kataoka Kengo , Yatabe Takafumi , Yamaguchi Kazuya , Mizuno Noritaka 
Published: October 2016

AbstractAn efficient heterogeneously Au/Al2O3‐catalyzed α‐oxygenation of secondary and tertiary amines is developed using elemental oxygen as oxidant.
ChemInform Abstract: Trityl Isocyanide as a Mechanistic Probe in Multicomponent Chemistry: Walking the Line Between Ugi‐ and Strecker‐Type Reactions.
Authors: Cioc Razvan C. , Preschel Hans D. , van der Heijden Gydo , Ruijter Eelco , Orru Romano V. A. 
Published: October 2016

AbstractThe application of title reagent (III) as cyanide source is demonstrated in 3 different types of reaction (Strecker, Ugi, Groebke—Blackburn—Bienaym).
ChemInform Abstract: Synthesis of Surface‐Active N‐Heterocyclic Carbene Ligand and Its Pd‐Catalyzed Aqueous Mizoroki—Heck Reaction.
Authors: Taira Toshiaki , Yanagimoto Takaya , Sakai Kenichi , Sakai Hideki , Endo Akira , Imura Tomohiro 
Published: October 2016

AbstractThe title agent and its Pd complex act as a general surfactant: hydrophobic oily substrates are emulsified in water and thus, an acceleration of the reaction becomes possible under heterogeneous conditions.
ChemInform Abstract: A Phosphotungstic Acid‐Supported Multifunctional Organocatalyst Containing 9‐Amino(9‐deoxy)epi‐cinchonidine and Broensted Acid and Its Application in Asymmetric Aldol Reaction.
Authors: Lan Ling , Xie Guangxin , Wu Tao , Feng Dandan , Ma Xuebing 
Published: October 2016

AbstractThe novel catalyst can be easily recovered by centrifugation and reused up to five times without significant loss of activity.
ChemInform Abstract: Palladium‐Catalyzed Construction of Amidines from Arylboronic Acids under Oxidative Conditions.
Authors: Zhu Fengxiang , Li Yahui , Wang Zechao , Orru Romano V. A. , Maes Bert U. W. , Wu Xiao‐Feng 
Published: October 2016

AbstractThe multicomponent approach to the amidine class tolerates various functional groups and leads to generally moderate to good yields.
ChemInform Abstract: Copper‐Catalyzed Selective Syntheses of Markovnikov‐Type Hydrothiolation Products and Thioacetals by the Reactions of Thiols with Alkenes Bearing Heteroatoms.
Authors: Xi Hui , Ma Enlu , Li Zhiping 
Published: October 2016

AbstractBoth classes of title compounds are readily available by simply switching the copper catalyst.
ChemInform Abstract: A One‐Pot Three‐Component Synthesis of Dithiocarbamates Starting from Vinyl Pyridines and Vinyl Pyrazine under Solvent‐ and Catalyst‐Free Conditions.
Authors: Halimehjani Azim Ziyaei , Martens Juergen , Schlueter Torben 
Published: October 2016

AbstractThe simple procedure is suitable for the preparation of a broad spectrum of title compounds.
ChemInform Abstract: Syn‐Selective Nitro‐Michael Addition of Furanones to β,β‐Disubstituted Nitroalkenes Catalyzed by epi‐Quinine Derivatives.
Authors: Sekikawa Tohru , Kitaura Hayato , Kitaguchi Takayuki , Minami Tatsuya , Hatanaka Yasuo 
Published: October 2016

AbstractA highly diastereo‐ and enantioselective nitro‐Michael addition of furanones to β,β‐disubstituted nitroalkenes catalyzed by epi‐quinine catalyst is reported.
ChemInform Abstract: Pd/Phenanthroline‐Catalyzed Arylative Cyclization of o‐(1‐Alkynyl)thioanisoles: Synthesis of 3‐Arylated Benzo[b]thiophenes.
Authors: Yamauchi Takayuki , Shibahara Fumitoshi , Murai Toshiaki 
Published: October 2016

AbstractAn arylative cyclization between o‐(1‐alkynyl)thioanisoles and aryl iodides, involving a demethylation and subsequent coupling reaction with aryl halides is reported.
ChemInform Abstract: Decarboxylative Coupling of α‐Keto Acids with ortho‐Phenylenediamines Promoted by an Electrochemical Method in Aqueous Media.
Authors: Wang Hai‐Bin , Huang Jing‐Mei 
Published: October 2016

AbstractElectrolysis of ortho‐phenylenediamines and ortho‐aminothiophenols in the presence of α‐keto acids is optimized.
ChemInform Abstract: Copper‐Catalyzed Cascade Reaction via Intramolecular Hydroamination Cyclization of Homopropargylic Amines and Intermolecular Povarov Reaction with Imines.
Authors: Wang Hongkai , Wang Chan , Huang Kaimeng , Liu Lingyan , Chang Weixing , Li Jing 
Published: October 2016

AbstractA series of hexahydro‐1H‐pyrrolo[3,2‐c]quinoline derivatives is synthesized in good to high yields by a one‐pot cascade reaction of homopropargylic amines with simple imines in the presence of Cu(OTf)2.
ChemInform Abstract: A Ruthenium Complex‐Catalyzed Cyclotrimerization of Halodiynes with Nitriles. Synthesis of 2‐ and 3‐Halopyridines.
Authors: Bednarova Eva , Colacino Evelina , Lamaty Frederic , Kotora Martin 
Published: October 2016

AbstractThe Ru‐catalyzed reaction of bromodiynes with nitriles (II) and (VII) gives rise to the corresponding bromopyridines, which are obtained as regioisomeric mixtures in most cases.
ChemInform Abstract: Silane@TiO2 Nanoparticles‐Driven Expeditious Synthesis of Biologically Active Benzo[4,5]imidazo[1,2‐a]chromeno[4,3‐d]pyrimidin‐6‐one Scaffolds: A Green Approach.
Authors: Mahire Vilas N. , Patel Vijay E. , Chaudhari Ashok B. , Gite Vikas V. , Mahulikar Pramod P. 
Published: October 2016

AbstractThe catalyst can be reused at least three times without significant loss of activity.
ChemInform Abstract: Solvent‐Free Pot‐, Atom‐ and Step‐Economic Synthesis of Novel Benzo[d]thiazole‐[1,3]‐thiazine Hybrids in a One‐Pot Reaction.
Authors: Wadhwa Preeti , Kaur Tanpreet , Sharma Anuj 
Published: October 2016

AbstractAn operationally simple one‐pot procedure allows the synthesis of the title species via microwave assisted sequential reaction of benzothiazole‐2‐amines with isothiocyanates and acetylenedicarboxylates.