bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Sulfur‐Based Directed Benzylic Metalations: Lithiations of Alkylarenesulfonates.
Authors: ALO B. I. , FAMILONI O. B. , MARSAIS F. , QUEGUINER G. 
Published: May 2016

AbstractLithiation of toluenesulfonates (I), (XIII) occurs at the methyl group, as in (III).
ChemInform Abstract: n‐Pentenyl Glycosides as Mediators in the Asymmetric Synthesis of Monosubstituted Chiral Nonracemic Tetrahydrofurans and γ‐Lactones.
Authors: LLERA J. M. , LOPEZ J. C. , FRASER‐REID B. 
Published: May 2016

AbstractThe n‐pentenyl glycoside (I) is oxidatively hydrolyzed by NBS to form the furan (R)‐(II) with moderate enantiomeric excess.
ChemInform Abstract: Intramolecular Ring Opening Reactions of 2‐Oxetanones Leading to Tetrahydrofuran Ring Formation: A Lewis Acid Study.
Authors: MEAD K. T. , YANG H.‐L. 
Published: May 2016

AbstractTreatment of (benzyloxy)propyl‐substituted 2‐oxetanones, e.g. (I), with Lewis acids results in ring opening of the oxetanone moiety.
ChemInform Abstract: Synthesis of Protected Indoles from N‐(tert‐Butoxycarbonyl)‐2‐alkylanilines.
Authors: CLARK R. D. , MUCHOWSKI J. M. , SOUCHET M. , REPKE D. B. 
Published: May 2016

AbstractConsecutive treatment of the N‐(tert‐butoxycarbonyl)‐2‐alkylanilines (I) with sec‐butyllithium (II), N,N‐dimethylformamide (IV), and conc.
ChemInform Abstract: 2‐Substituted Benzimidazoles as Antiinflammatory Agents.
Authors: SINGH P. , HINGORANI L. L. , TRIVEDI G. K. , VORA J. 
Published: May 2016

AbstractCondensation of o‐phenylenediamine with the corresponding arylalkanoic acids affords the title compounds (III)‐(VI) in high yields (80‐93%).
ChemInform Abstract: Regiospecific Thermal Rearrangements of 2‐Allyloxypyridine N‐Oxides.
Authors: ALKER D. , MAGESWARAN S. , OLLIS W. D. , SHAHRIARI‐ZAVAREH H. 
Published: May 2016

AbstractThe results from the rearrangement of the methylallyloxypyridine oxides (I) and (IIIa) are a revision of earlier work.
ChemInform Abstract: Selective Hydrogenation of 9‐Aminoacridine over Supported Noble Metal Catalysts.
Authors: SAKANISHI K. , MOCHIDA I. , OKAZAKI H. , SOEDA M. 
Published: May 2016

AbstractThe hydrogenation of 9‐aminoacridine (I) using noble metals such as Pd, Pt, Rh, or Ru on different carrier materials is investigated.
ChemInform Abstract: 1,4‐Dioxane‐2,3‐dithione, the First Cyclic Dithioxooxalate.
Authors: HARTKE K. , LINDENBLATT T. 
Published: May 2016

Abstract2,3‐Dichloro‐1,4‐dioxane (I) is coupled with CS2 (II) and morpholine (III) to give the bisdithiocarbamate (IV).
ChemInform Abstract: Enamines. Part 48. 3,4‐Dihydroquinazolines from Enamines and S,S‐Dimethyl‐N‐(N‐arylbenzimidoyl)sulfimides.
Authors: ROSSI E. , STRADI R. , VISENTIN P. 
Published: May 2016

AbstractTreatment of the sulfimide (I) with enamines such as (II) derived from ketones gives the title compounds (III).
ChemInform Abstract: Synthesis of Pyrido(1′,2′:1,2)imidazo(4,5‐b)quinoxaline Derivatives from 2‐Amino‐3‐chloroquinoxaline and Pyridines.
Authors: TOMODA H. , SAITO S. , SHIRAISHI S. 
Published: May 2016

Abstract2‐Amino‐3‐chloroquinoxaline (I) reacts with pyridines such as (II) in DMF to form the pyridoimidazoquinoxalines (III).
ChemInform Abstract: Synthesis and Reactions of E‐1,4‐Bis(silyl)‐Substituted Enynes.
Authors: OHSHITA J. , FURUMORI K. , MATSUGUCHI A. , ISHIKAWA M. 
Published: May 2016

AbstractThe Rh(I)‐catalyzed dimerization of the silylated acetylene (I) yields the 1,4‐disilylbut‐1‐en‐3‐yne (II).
ChemInform Abstract: Synthesis of Organosilane‐Containing Fused Aromatic Rings by Diels‐Alder Reaction.
Authors: QIU H. , FENG S. , CHEN J. , DU Z. 
Published: May 2016

AbstractThe new compound (III) is prepared in the scope of a study of the syntheses of polyphenylsilanes, which are used as a high temp. stationary phase of gas chromatographs and additives of heat‐vulcanized silicone rubber.
ChemInform Abstract: Preparation of a New Class of C2‐Symmetric Chiral Phosphines: The First Asymmetric Staudinger Reaction.
Authors: WILSON S. R. , PASTERNAK A. 
Published: May 2016

AbstractThe dihydroxyhexane (I), prepared from 2,5‐hexanedione by asymmetric reduction with bakers' yeast, reacts with mesyl chloride (II) to produce the bismesylate (III).
ChemInform Abstract: 2,2,2‐Trifluoroethyl Aryl Tellurides, ArTeCH2CF3 and Their Derivatives Ar(CF3CH2)TeX2 (Ar = C6H5, p‐CH3C6H4; X = Cl, OCH2CF3): Preparation and Characterization.
Authors: SANDHU A. , SINGH S. , BHASIN K. K. , VERMA R. D. 
Published: May 2016

AbstractAlkylation of the in situ formed sodium tellurides (II) with 2,2,2‐trifluoroethyl iodide (III) affords the fluoroalkyl tellurides (IV).
ChemInform Abstract: Polylithiumorganic Compounds. Part 12. Reductive Scission of a Cyclopropane σ‐Bond During the Action of Elemental Lithium on Cyclopropylacetylenes. A cis‐1,2‐Dilithioalkene as Intermediate.
Authors: MAERCKER A. , GIRRESER U. 
Published: May 2016

AbstractThe cis‐dilithioalkene (III) is stable in solution at ‐30 °C (trapping experiments with MeOD, (MeO)2SO2, and CO2 (IV) to give, e.g., (V)); above ‐30 °C cyclopropane‐bond cleavage occurs to give a linear intermediate which undergoes elimination of CH2=CH2 followed by deprotonation yielding finally trilithio compound (VI).
ChemInform Abstract: Synthesis and Structural Characterization of an Air‐Stable 17‐Electron Complex Containing the (Cr(NO))2+ Core.
Authors: SHIU K.‐B. , CHOU J. L. , WANG Y. , LEE G.‐H. 
Published: May 2016

AbstractThe paramagnetic monomer complex (IV) crystallizes in the space group P212121 with Z=4.
ChemInform Abstract: Synthesis and Reactivity of Ruthenium Complexes with Dibenzothiophene and Hexahydrodibenzothiophene Ligands: Models for Catalytic Hydrodesulfurization.
Authors: WANG C.‐M. J. , ANGELICI R. J. 
Published: May 2016

AbstractAs models for the adsorption of dibenzothiophene (II) and hexahydrodibenzothiophene on hydrodesulfurization catalysts, the complex (III), its hexahydrodibenzothiophene analogue (yield 65%), and the binuclear analogue (VI) (54%) are prepared.
ChemInform Abstract: Synthesis of Distamycin and Netropsin Analogs. Part 3. Biologically Active Analogs of Tris(m‐benzamido) Compound.
Authors: RAO K. E. , SASISEKHARAN V. 
Published: May 2016

AbstractStarting from the acid chloride (III), an improved synthesis of the tris(m‐benzamido) compound (VII) and the syntheses of the novel analogs (VIII)‐(X) are achieved.
ChemInform Abstract: Convenient Synthesis of Mono and Cyclic Sulfates of Carbohydrates via Triflate Displacement.
Authors: LATIF F. , SHEKHANI M. S. , VOELTER W. 
Published: May 2016

AbstractMonosulfates such as (III) and (V) and cyclic sulfates such as (VI) are prepared in order to test their biological activity.
ChemInform Abstract: A Novel Route to 1,4‐Anhydro Derivatives of β‐D‐Galactopyranose.
Authors: BULLOCK C. , HOUGH L. , RICHARDSON A. C. 
Published: May 2016

AbstractThe galactopyranose derivatives (I) react with sodium azide (II) to give the anhydro sugars (III) or (IV) mentioned in the title.
ChemInform Abstract: Synthesis of Cytochalasins: The Route to Sulfur‐Bridged (11)Cytochalasans.
Authors: VEDEJS E. , REID J. G. , RODGERS J. D. , WITTENBERGER S. J. 
Published: May 2016

AbstractKey steps of the synthesis of the title compounds (IX) and (XI) include the highly selective Diels‐Alder addition reaction leading to (III), the generation and hetero‐Diels‐Alder trapping of the transient thioaldehyde (VI), and the conversion of the derived compound (VIII) into the sulfur‐bridged 11‐membered carbocycle (IX) (together with its 16‐epimer: 6% yield) via a 2,3‐sigmatropic rearrangement of an intermediate sulfonium ylide.
ChemInform Abstract: A Novel Ring‐Closure Strategy for the Carbapenems: The Total Synthesis of (+)‐Thienamycin.
Authors: HANESSIAN S. , DESILETS D. , BENNANI Y. L. 
Published: May 2016

AbstractStarting with the commercially available optically active azetidinone (I), a total synthesis of (+)‐thienamycin (VI) is described.
ChemInform Abstract: Location, Ligancy, and Reducibility of Metal Ions in Zeolite Cages: Co and Pd in NaY.
Authors: ZHANG Z. , SACHTLER W. M. 
Published: May 2016

AbstractIon migration and reducibility of Co/NaY and (Co + Pd)/NaY after ion exchange of Co(NH3)63+ and Pd(NH3)42+ are investigated by using UV‐VIS diffuse reflectance spectroscopy, and temp.‐programmed reduction and oxidation.
ChemInform Abstract: Low‐Temperature Ion Conductivity of RbAg4I5.
Authors: PINKOWSKI A. , CHIERCHIE T. , LORENZ W. J. 
Published: May 2016

AbstractFour‐probe conductivity data, obtained by impedance spectroscopy on α‐, β‐, and γ‐RbAg4I5 between 28 and 299 K, agree well with previous two‐probe σ data at temp. above the β‐γ phase transition temp. Tβ‐γ = 121.75 K. Between Tβ‐γ and T = 109 K the specific ionic conductivity decreases by 2‐3 orders of magnitude.
ChemInform Abstract: Photocatalytic Activities of Potassium‐Doped Lead Niobates and the Effect of Poling.
Authors: INOUE Y. , HAYASHI O. , SATO K. 
Published: May 2016

AbstractAddition of K to lead niobates with tungsten bronze‐type structure is shown to considerably enhance the photocatalytic activity for water decomposition and the surface photocurrent.
ChemInform Abstract: The Specific Interaction of Mg and Alkaline Earth Metal Ions with Well‐Defined Surfaces of α‐HCrO2 and Cr2O3.
Authors: KITTAKA S. , YAMANAKA S. , YANAGAWA N. , OKABE T. 
Published: May 2016

AbstractElectrophoretic mobility and surface charge density measurements show the selectivity sequence of the alkaline earth metal ions to the surface of α‐HCrO2 to be Mg > Ca > Sr ∼Ba.
ChemInform Abstract: Synthesis and Properties of the Silicoaluminophosphate Molecular Sieve SAPO‐31.
Authors: ZUBOWA H.‐L. , ALSDORF E. , FRICKE R. , NEISSENDORFER F. , RICHTER‐MENDAU J. , SCHREIER E. , ZEIGAN D. , ZIBROWIUS B. 
Published: May 2016

AbstractThe medium‐pore title molecular sieve is synthesized by heating a gel, having the composition 1.0 nPr2NH:1.2 Al2O3:1.0 P2O5:0.6 SiO2:62.0 H2O, at 473 K under autogeneous pressure (24 h, stainless steel vessel lined with inert plastic material) followed by calcination in air at 873 K (7 h).
ChemInform Abstract: Preparation and Vibrational Spectra of Nonahalogenodirhodates(III), (Rh2ClnBr9‐n)3‐, n = 0‐9.
Authors: KUHR W. , PREETZ W. 
Published: May 2016

AbstractThe pure compounds A3(Rh2ClnBr9‐n) with A: K+, Cs+, Bu4N+ and n = 0‐4, 9 are prepared from monomeric (RhClnBr6‐n)3‐ (n = 0‐6) by ligand abstraction in less polar organic solvents (CH2Cl2) to form a mixture of the confacial bioctahedral complexes from which the individual complex ions are separated by ion exchange chromatography on diethylaminoethylcellulose.
ChemInform Abstract: New Compounds of the Ba8Pt4Y3O17.5‐Type: Ba8Pt4Ln3O17.5 (Ln: Er, Yb, Tm).
Authors: GUTAU W. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractThe title compounds (III) crystallize in the cubic space group Pm3m with Z=1.
ChemInform Abstract: Molecular “Light Switch” for DNA: Ru(bpy)2(dppz)2+.
Authors: FRIEDMAN A. E. , CHAMBRON J.‐C. , SAUVAGE J.‐P. , TURRO N. J. , BARTON J. K. 
Published: May 2016

AbstractThe novel transition‐metal complex (I) is a highly sensitive spectroscopic reporter to double‐helical DNA.
ChemInform Abstract: Cyclopentane Ring Formation in the Cycloaddition Reaction of 3‐Alkenyl Radicals to Radicophilic Olefins.
Authors: SAICIC R. N. , CEKOVIC Z. 
Published: May 2016

AbstractRegioselective addition reactions of 3‐alkenyl radicals, generated from the substrates (II), (VII), or (IX), to electron‐deficient olefinic compounds such as (I), (IV), or (VI) lead to final products such as (III), (V), (VIII), (X).
ChemInform Abstract: Unactivated 2‐Aza‐1,3‐dienes: Halogenation and Face Selectivity in Diels‐Alder Reactions.
Authors: BARLUENGA J. , GONZALEZ F. J. , FUSTERO S. 
Published: May 2016

AbstractTreatment of 2‐aza‐1,3‐dienes, e.g. (I), with N‐halosuccinimides, e.g. NCS, results in the formation of two isomeric products due to (1,5)H‐shift.
ChemInform Abstract: Indole as a Dienophile in Inverse Electron Demand Diels‐Alder Reactions: Reactions with 1,2,4‐Triazines and 1,2‐Diazines.
Authors: BENSON S. C. , GROSS J. L. , SNYDER J. K. 
Published: May 2016

AbstractThe reaction of indole (I) with the triazines (II), (V), or (VII) leads to the formation of the γ‐carbolines (III), β‐carbolines (IX) and (X), benzo(f)(1,7)naphthyridines (IV), or noncyclized triazinylindoles (VI).
ChemInform Abstract: Organoaluminum‐Promoted Rearrangement of Allyl Phenyl Ethers.
Authors: MARUOKA K. , SATO J. , BANNO H. , YAMAMOTO H. 
Published: May 2016

AbstractThe sterically hindered methylaluminum compound (I) induces rearrangement of various allyl phenyl ethers to give C‐allylated compounds, in general mixtures of allylated phenols and allylcyclohexadienones.
ChemInform Abstract: Photoreduction of Aryl Ketones by Amides, Lactams and Various Nitrogen‐Containing Heterocycles.
Authors: GRAMAIN J.‐C. , JEANDRAU J.‐P. , LEMAIRE J. , REMUSON R. 
Published: May 2016

AbstractRegioselective hydrogen abstraction α to the nitrogen atom in (II) or in lactams is observed in the photoreduction of benzophenone (I).
ChemInform Abstract: A New Route to Epoxides and Ketones by m‐Chloroperbenzoic Acid Oxidation of β‐Hydroxyalkyl Phenyl Selenides and Tellurides.
Authors: UEMURA S. , OHE K. , SUGITA N. 
Published: May 2016

AbstractMCPBA oxidation of phenyl selenides and phenyl tellurides yields, depending on the nature of the substrate, epoxides (II) or (X)/(XI), β‐diol monomethyl ethers (IV), carboxylic acids or esters (VI), (VII) or ketones (IX), (XVI).
ChemInform Abstract: Geometry Dependence of Intramolecular Photoinduced Electron Transfer in Synthetic Zinc‐Ferric Hybrid Diporphyrins.
Authors: OSUKA A. , MARUYAMA K. , MATAGA N. , ASAHI T. , YAMAZAKI I. , TAMAI N. 
Published: May 2016

AbstractThe rate constants for charge separation of 13 examples of the hybrid diporphyrins of type (I) are determined from the respective fluorescence lifetimes.
ChemInform Abstract: Alkylation of Heteroaryl Alkyl Metals by Bistrialkylsilylperoxides.
Authors: EPIFANI E. , FLORIO S. , TROISI L. 
Published: May 2016

AbstractHeteroalkyl methyl metals obtained from (III)/LDA undergo methylation upon treatment with the silylperoxide (I) to give the compounds (IV); in addition, the trimethylsilyloxylation products (Va) and (Vb) as well as the silylation product (VIa) are formed.
ChemInform Abstract: Fully Regioselective Catalytic Carbonylation of Acrylic Derivatives: Synthesis of Methylmalonic Acid by Iron Pentacarbonyl Catalyzed Hydrocarboxylation of Acrylic Acid.
Authors: BRUNET J.‐J. , PASSELAIGUE E. 
Published: May 2016

AbstractThe first catalytic hydrocarboxylation of acrylic acid (I) into methylmalonic acid (III) is reported.
ChemInform Abstract: Influence of the Solvent on the Regioselectivity of the Oxidative Hydrocarboxylation of α‐Olefins.
Authors: KRON T. E. , STAROSEL'SKAYA L. F. , TEREKHOVA M. I. , PETROV E. S. 
Published: May 2016

AbstractThe ratio of the isomeric heptanecarboxylic acids (III) and (IV), obtained by oxidative hydrocarboxylation of 1‐heptene (I) in the presence of a PdCl2/CuCl2 catalyst, depends on the solvent used.
ChemInform Abstract: Synthesis of Enantiomerically Pure 1‐Methyl‐2‐alkenyl N,N‐Diisopropylcarbamates from (S)‐ or (R)‐Lactates.
Authors: SCHWARK J.‐R. , HOPPE D. 
Published: May 2016

AbstractThe optically active lactates (I) are protected by reaction with the carbamoyl chloride (II) and subsequently reduced with DIBAL to form the aldehydes (III).
ChemInform Abstract: Stereochemistry of the Addition of α‐Metallated N,N‐Dimethylsulfonamides to 4‐tert.‐Butylcyclohexanone.
Authors: MLADENOVA M. , GAUDEMAR‐BARDONE F. 
Published: May 2016

AbstractNa or MgCl analogues of the sulfonamide derivatives (IIa), (IIb) give similar results at ‐50 °C (kinetic control).
ChemInform Abstract: Convenient Preparation of Aryl Dichloromethyl Ketones and Aryl 1,1‐Dichloro‐3‐butenyl Ketones.
Authors: BAL'ON YA. G. , SHUL'MAN M. D. , PARANYUK V. E. 
Published: May 2016

AbstractThe aryl trichloromethyl carbinols (I) are alkylated to give the ethers (III).
ChemInform Abstract: Synthesis of 3‐Alkoxyalkanoic Esters from Acetals. A Novel Application of Reformatskii Reagents in Asymmetric Synthesis.
Authors: BASILE T. , TAGLIAVINI E. , TROMBINI C. , UMANI‐RONCHI A. 
Published: May 2016

AbstractThe acetals (I) are coupled with the Reformatskii reagents (II) in the presence of titanium tetrachloride to produce the β‐methoxycarboxylic acid esters (III).
ChemInform Abstract: Phenanthrylalkanoic Acids. Part 4. Syntheses and Antiinflammatory Activity of 2‐, 3‐, and 9‐Phenanthryl and 9‐Chloro‐3‐phenanthryl Derivatives of Propanoic Acid.
Authors: FERNANDEZ F. , GONZALEZ C. , GOMEZ G. , LOPEZ C. , MEDINA L. , CALLEJA J. M. , CANO E. 
Published: May 2016

AbstractThe title compounds (VI) are prepared as outlined in the reaction scheme.
ChemInform Abstract: Imidazole Derivatives. Part 4. A Novel and Direct Synthesis of 7H‐Pyrrolo(1,2‐a)imidazoles.
Authors: KNOELKER H.‐J. + , BOESE R. 
Published: May 2016

AbstractThe described one‐pot procedure allows a simple and direct access to the title compounds which are of interest because of their broad spectrum of biological activities.
ChemInform Abstract: 5‐Amino‐4‐trifluoromethylthiazoles and 5‐Aminomethyl‐4‐trifluoromethyl‐1,3‐azoles: Useful Starting Materials for the Synthesis of Biologically Active Compounds.
Authors: BURGER K. , HOESS E. + , GEITH K. 
Published: May 2016

AbstractThe aminothiazoles (I) are coupled with the isocyanates and isothiocyanates (II) to produce the ureas (III).
ChemInform Abstract: 1,2,4‐Triazoles. Part 6. Synthesis of New 1,5‐Diphenyl‐1H‐1,2,4‐triazoles Substituted with H, Alkyl, or Carboxyl Groups at C‐3.
Authors: CZOLLNER L. , SZILAGYI G. , LANGO J. , JANAKY J. 
Published: May 2016

AbstractCyclization of the acylamidines (I) with the phenylhydrazines (II) yields the triazole derivatives (III).
ChemInform Abstract: Syntheses of Bicyclic Pyridine Derivatives from 3‐Substituted 2‐(Phenylethynyl)pyridines.
Authors: NISHIWAKI N. , MINAKATA S. , KOMATSU M. , OHSHIRO Y. 
Published: May 2016

AbstractHg(II)‐catalyzed hydration of 2‐phenylethynyl‐3‐acetylpyridine (I) yields 2‐phenacyl‐3‐acetylpyridine (II) which is cyclized in the presence of a base, forming 7‐phenyl‐5‐quinolinol (III).
ChemInform Abstract: 1,2,4‐Triazolo(1,5‐a)pyrimidines. Part 5. Preparation of 7‐Aminesubstituted 6‐Nitro‐1,2,4‐triazolo(1,5‐a)pyrimidines.
Authors: HEMPEL U. , LIPPMANN E. , TENOR E. 
Published: May 2016

AbstractThe nitro compounds (I) and (IV) are prepared starting from the corresponding 7‐hydroxy‐5‐methyl derivatives.
ChemInform Abstract: Synthesis and Positive Inotropic Activity of Novel Pyrimido‐(5,4‐b)(1,4)oxazin‐7(8H)‐ones.
Authors: KASZTREINER E. , RABLOCZKY G. , MAKK N. , MATYUS P. , DIESLER E. , TEGDES A. , KOSARY J. , CZAKO K. , GYUERKI S. + , CSEH G. , KUERTHY M. + , JASZLITS L. 
Published: May 2016

AbstractSeventy‐five title compounds are synthesized and tested for positive inotropic activity.
ChemInform Abstract: Palladium(0)‐Catalyzed Reaction of Z‐2‐Butene‐1,4‐diyl Bis(methyl Carbonate) and Z‐2‐Butene‐1,4‐diyl Diacetate with Bifunctional Nitrogen Nucleophiles.
Authors: TSUDA T. , KIYOI T. , SAEGUSA T. 
Published: May 2016

AbstractThe Pd(0)‐catalyzed reaction of 1,4‐difunctionalized butenes such as (I) with the ethylenediamine derivatives (II) yields the 2‐vinylpiperazines (III).
ChemInform Abstract: Epoxide Ring Opening by Dianions Derived from β‐Keto Sulfones. Synthetic Studies on the 7‐Hydroxy‐4‐oxo‐2,3‐alkenoate System and Medium‐Ring Lactones.
Authors: LYGO B. , O'CONNOR N. 
Published: May 2016

AbstractThe dianion of the keto sulfone (I) is coupled with the oxiranes (II) and (IV) to produce the hydroxy keto sulfones (III) and (V).
ChemInform Abstract: Addition of Tris(trimethylsilyl)silyl Radicals to the Carbonyl Group.
Authors: ALBERTI A. , CHATGILIALOGLU C. 
Published: May 2016

AbstractTitle radicals are generated in situ from silane (II) either photolytically in the presence of (tBuO)2 or by catalytic amounts of AIBN and reacted (free radical chain mechanism) with a range of dialkyl or diaryl ketones and quinones (laser flash photolysis and ESR studies; kinetics).
ChemInform Abstract: Reactions of Salts of Four‐Coordinated Phosphorus Acids with 1‐Chloro‐2,2‐dicyanoethylene.
Authors: RYMAREVA T. G. , LYSAK E. I. , KHASKIN B. A. 
Published: May 2016

AbstractThe potassium O,O‐dialkyl dithiophosphates (I) are coupled with 1‐chloro‐2,2‐dicyanoethylene (II) to give the S‐dicyanovinyl dithiophosphates (III).
ChemInform Abstract: 3‐Dialkoxyphosphoryl‐4‐methyl‐1‐phenyl‐2‐aza‐1,3‐pentadienes.
Authors: ONYS'KO P. P. , KIM T. V. , KISELEVA E. I. , SINITSA A. D. 
Published: May 2016

AbstractReaction of the imidoyl chloride (I) with trialkyl phosphites such as (IIa) and (IIb) produces the title compounds (III).
ChemInform Abstract: α‐Alkenyl Analogs of Phosphorylcholines.
Authors: GOLOLOBOV Y. G. , OGANESYAN A. S. , KOLOMNIKOVA G. D. , KUZNETSOVA S. A. , KASUKHIN L. F. 
Published: May 2016

AbstractThe chloroalkenyl phosphates (I) and (V) react with the trialkylamines and trialkylphosphines (II) to produce the corresponding ammonium and phosphonium derivatives (III) and (VI).
ChemInform Abstract: Organophosphoro(thioperoxoic) Acids: Direct Observation and Reactivity.
Authors: SEGALL Y. , WU S.‐Y. , TOIA R. F. , CASIDA J. E. 
Published: May 2016

AbstractPeracid oxidation of the thiolophosphonate (Ia) or the related phosphate (Ib) generates the phosphorothioperoxoic acids (II) and the isomer (III) which are detected by means of 31P NMR spectroscopy.
ChemInform Abstract: Arylhydrazones of (Dialkoxyphosphoryl)formyl Sulfite.
Authors: SOKOLOV M. P. , BUZYKIN B. I. , MOLODYKH ZH. V. 
Published: May 2016

AbstractThe phosphorylhydrazonoyl chlorides (I) are coupled with sodium sulfite (II) in the presence of hydrochloric acid at room temperature to give the title compounds (III).
ChemInform Abstract: An Unusual Reaction Product from Diethyl Isocyanatophosphite and C,N‐Diphenylnitrilimine.
Authors: DOLGUSHINA T. S. , GALISHEV V. A. , PLOTNIKOV V. F. , SOKOLOV V. V. , BEL'SKII V. K. , PETROV A. A. 
Published: May 2016

AbstractReaction of the isocyanatophosphite (I) with the nitrilimine (II) leads to the formation of the triazolyl phosphonate (III).
ChemInform Abstract: Reactions Involving Selenium Metal as an Electrophile: Scope and Limitations of the Enolate‐Selenolate Transformation.
Authors: SWISS K. , CHOI W.‐B. , MOHAN J. , BARNUM C. , SAINDANE M. , ZIMA G. , KIOTTA D. 
Published: May 2016

AbstractTwelve ketones such as (I) are converted into the enolates by reaction with LDA (II).
ChemInform Abstract: Synthesis of Novel Bidentate (Te, N) Ligands ‐ 2‐Aryltelluroethylamines and Their Complexation with Mercury(II).
Authors: SINGH A. K. , SRIVASTAVA V. 
Published: May 2016

AbstractAs part of the program on ligand chemistry of tellurium the telluroamines (III) are treated with HgCl2 to yield the corresponding complexes (V).
ChemInform Abstract: Dibenzo(b,i)(1,4,8,11)tetra‐azacyclotetradecine Complexes. Part 1. W(CO)4(tmtaa).
Authors: COTTON F. A. , CZUCHAJOWSKA J. 
Published: May 2016

AbstractFrom an X‐ray structure determination of the title complex (III) (space group Pcab, Z = 8) it is confirmed that the previously postulated unconventional mode of coordination of (I) in the complex is real.
ChemInform Abstract: Assessment of Butene‐1,4‐diols as Starting Materials for the Preparation of π‐Allyltricarbonyliron Complexes.
Authors: BATES R. W. , DIEZ‐MARTIN D. , KERR W. J. , KNIGHT J. G. , LEY S. V. , SAKELLARIDIS A. 
Published: May 2016

AbstractThe title reaction is investigated under different conditions.
ChemInform Abstract: Synthesis and Electrochemical Characterization of Binuclear Rhodium and Ruthenium Complexes with 1,8‐Naphthyridine‐2,7‐dicarboxylate. X‐Ray Molecular Structure of Tris(μ‐acetato)(1,8‐naphthyridine‐2,7‐dicarboxylato)diruthenium.
Authors: COLLIN J.‐P. , JOUAITI A. , SAUVAGE J.‐P. , KASKA W. C. , MCLOUGHLIN M. A. , KEDER N. L. , HARRISON W. T. A. , STUCKY G. D. 
Published: May 2016

AbstractTreatment of Rh2(O‐Ac)4(MeOH)2 with (II) in MeOH under reflux gives a Rh(II),Rh(II) complex (78% yield), similar to (III), as its monosodium salt.