bluuebunny/crossref_metadata_2025_split huggingface dataset:
XSLT as a Modern, Powerful Static Website Generator
Authors: Kraetke Martin , Imsieke Gerrit 
Published: July 2016

In scientific, technical, and medical (STM) publishing, XML is a common data format for typeset products. Electronic renditions are regularly created from these XML sources, too. However, these HTML renderings are mainly considered as an alternative rendering with no added value, and most users of STM literature still consume the content in PDF format or on paper. Hogrefe Publishing decided to market its flagship reference product, the Clinical Handbook of Psychotropic Drugs, as a standalone electronic version. The electronic version should offer quicker lookups by several criteria, such as substance name, trade name, indication, and interaction. In addition, it should be mobile-friendly so that healthcare professionals can use their mobile phones to access the content, including large tables.
Although single-source publishing in STM is not considered a “sub rosa” application of XML at all, there are remarkably few known examples of standalone, enriched Web applications that are derived from a printed reference work and published in parallel. This paper argues that this kind of application can be created from XML with relatively moderate effort using modern XSLT versions and that this approach is superior to what has recently become popular for content-driven Web sites – Markdown content and static site generators written in procedural languages.
Theoretical analysis of controllability of interference phenomena between partially coherent fields in the intensity matrix theory
Authors: Yashiki Satoshi 
Published: July 2016

Abstract
We analyze the controllability of interference phenomena between partially coherent fields by introducing the Wigner distribution function (WDF) and entropy, which is defined using the intensity matrix [H. Gamo, J. Opt. Soc. Am. 47, 976 (1957)]. The analytical derivation of the WDF and entropy is presented for a partially coherent imaging system consisting of two pinholes illuminated by a circular source. It is shown that the WDF, defined in the 4D space–spatial frequency region, and entropy can be useful tools to understand how one can freely and quantitatively control the interference when any optical components in the partially coherent imaging system are changed.
Gold and graphific carbon nitride hybrid plasmonic nanocomposites for photocatalytic reduction of 4-nitrophenol and 4-nitrobenzenethiol
Authors: Yan Jiao , Xiao Yuli , Liang Xiu , Yang Nan , Zhao Dongyu , Yin Penggang 
Published: July 2016

Abstract
Gold nanoparticles (GNPs) were deposited on the surface of graphitic carbon nitride (g-C3N4) via an in situ reduction method using either sodium borohydride or trisodium citrate as the reducing agent. The corresponding hybrid Au/C3N4 nanocatalysts, viz., Au@CN-B or Au@CN-C, exhibited high light-driven catalytic activities toward reduction of 4-nitrophenol (4-NP) under either visible-light or ultra violet (UV) irradiation. The photocatalytic efficiency of Au@CN-B was only slightly higher than that of Au@CN-C, most likely owing to the average grain size difference between the both. However, as for plasmon-driven catalytic reactions monitored by surface-enhanced Raman scattering (SERS) technique, an immediate and almost-complete reduction of 4-nitrobenzenethiol (4-NBT) to p,p′-dimercaptoazobenzene (DMAB) occurred when Au@CN-B was utilized as both the nanocatalyst and SERS substrate, whereas distinct characteristic peaks of 4-NBT still existed for the case of Au@CN-C.
High-density channel model and detection method for signal readout from super-resolution near-field structure discs
Authors: Hosogai Shota , Ansai Tsutomu , Yoshinari Takehisa , Tanabe Takaya 
Published: July 2016

Abstract
Although a readout method using the super-resolution near-field structure (super-RENS) effect can overcome diffraction limits, readout characteristics for greatly surpassed high-density conditions do not become clear, because a high-density channel function having a differential response property is superimposed on a normal readout function. We propose a high-density channel model to indicate the properties of the super-RENS effect directly. This model can be expressed as a differential response function using the finite impulse response (FIR) filter model. It expresses the super-RENS readout process, which is divided on the basis of recording densities such as high and normal Blu-ray Disc™ densities. We estimated the properties of super-RENS readout signals by comparison between theoretical expressions and experiments. Results show that good signal quality require readout signals having sharp peaks and smaller offsets. We also evaluated the channel model by adding an adaptive FIR filter and a Viterbi decoder by simulations. Results show that the super-RENS disc can achieve a fourfold higher recording density if the signal-to-noise ratio (S/N) is improved to 6 dB in the case of partial response (PR) (1 + D + D
2).
Magnetooptical and crystalline properties of sputtered garnet ferrite film on spinel ferrite buffer layer
Authors: Furuya Akinori , Sasaki Ai-ichiro , Morimura Hiroki , Kagami Osamu , Tanabe Takaya 
Published: July 2016

Abstract
The purpose of this study is to provide garnet films for volumetric magnetic holography. Volumetric magnetic holography usually employs an easily obtainable short-wavelength laser (visible light, not infrared light) with a large diffraction intensity. Bi-substituted garnet ferrite with a large Faraday rotation is promising for volumetric magnetic holography applications in the visible light region. However, a garnet film without a deteriorated layer must be obtained because a deteriorated layer (minute polycrystalline grains containing an amorphous phase) is formed during the initial deposition on a glass substrate. In particular, the required magnetooptical properties have not been obtained in a thin garnet film (100 nm or less) after annealing (1 h, 700 °C, oxygen atmosphere). Therefore, there is a need for excellent garnet films with the required magnetooptical (MO) properties even if the films are thin. By using a spinel ferrite buffer layer for garnet film deposition, we could obtain a thin garnet film with excellent MO properties. We determined the effect of the initial buffer layer on the crystallinity of the deposited garnet films by observing the film cross section. In addition, we undertook a qualitative estimation of the influence of the crystallinity and optical properties of the garnet film on a glass substrate with a spinel ferrite buffer layer.
The influence of shear‐velocity heterogeneity on ScS2/ScS amplitude ratios and estimates of Q in the mantle
Authors: Chaves Carlos A. M. , Ritsema Jeroen 
Published: July 2016

AbstractRegional waveforms of deep‐focus Tonga‐Fiji earthquakes indicate anomalous traveltime differences (ScS2‐ScS) and amplitude ratios (ScS2/ScS) of the phases ScS and ScS2. The correlation between the ScS2‐ScS delay time and the ScS2/ScS amplitude ratio suggests that shear wave apparent Q in the mantle below the Tonga‐Fiji region is highest when shear wave velocities are lowest. This observation is unexpected if temperature variations were responsible for the seismic anomalies. Using spectral element method waveform simulations for four tomographic models, we demonstrate that focusing and scattering of shear waves by long‐wavelength 3‐D heterogeneity in the mantle may overwhelm the signal from intrinsic attenuation in long‐period ScS2/ScS amplitude ratios. The tomographic models reproduce the trends in recorded ScS2‐ScS difference times and ScS2/ScS amplitude ratios. Although they cannot be ruled out, variations in shear wave attenuation (i.e., the quality factor Q) are not necessary to explain the data.
Response of magnetotail twisting to variations in IMF By: A THEMIS case study 1–2 January 2009
Authors: Pitkänen T. , Hamrin M. , Kullen A. , Maggiolo R. , Karlsson T. , Nilsson H. , Norqvist P. 
Published: July 2016

AbstractTheoretical considerations, observations, and simulations have shown that the By component of the interplanetary magnetic field (IMF) may cause twisting of the magnetotail. However, the fundamental issues, the temporal and spatial responses of the magnetotail in the twisting process, are still unresolved. We report unique multipoint observations of the response of the magnetotail to the variations in IMF By on 1–2 January 2009. For the first time, estimates of the tail twisting response time at different (Time History of Events and Macroscale Interactions during Substorms, THEMIS) distances in the same event are inferred. Using cross‐correlation and timing analyses, we find that the tail twisting propagates from farther out toward the Earth and the response time increases significantly to the inner magnetosphere.
Modellierung, Simulation und Implementierung von Zellen für die solargetriebene Wasserspaltung
Authors: Xiang Chengxiang , Weber Adam Z. , Ardo Shane , Berger Alan , Chen YiKai , Coridan Robert , Fountaine Katherine T. , Haussener Sophia , Hu Shu , Liu Rui , Lewis Nathan S. , Modestino Miguel A. , Shaner Matthew M. , Singh Meenesh R. , Stevens John C. , Sun Ke , Walczak Karl 
Published: July 2016

AbstractEine integrierte Zelle für die solargetriebene Wasserspaltung besteht aus mehreren funktionellen Komponenten und kombiniert verschiedene photoelektrochemische (PEC‐)Prozesse auf unterschiedlichen Längen‐ und Zeitskalen. Der Gesamtwirkungsgrad eines derartigen Systems für die Umwandlung von Solarenergie in Wasserstoff (solar‐to‐hydrogen; STH) wird von der Leistung und den Materialeigenschaften seiner Einzelkomponenten sowie ihrer Integration, von seiner Gesamtarchitektur und den Betriebsbedingungen bestimmt. Dieser Aufsatz beschäftigt sich mit der Implementierung von solargetriebenen Prototypen für die Wasserspaltung auf der Basis von Modellierungen und Simulationen, welche die Wechselwirkungen zwischen den Einzelbauteilen in ihrer Gesamtheit berücksichtigen. Physik und Wechselwirkungen innerhalb der Zelle werden diskutiert, und die Anwendung des Zellmodells für die Bestimmung der benötigten Materialeigenschaften sowie beim Design von herkömmlichen und ungewöhnlichen Architekturen wird erörtert.
Design of Highly Stable Echogenic Microbubbles through Controlled Assembly of Their Hydrophobin Shell
Authors: Gazzera Lara , Milani Roberto , Pirrie Lisa , Schmutz Marc , Blanck Christian , Resnati Giuseppe , Metrangolo Pierangelo , Krafft Marie Pierre 
Published: July 2016

AbstractDispersing hydrophobin HFBII under air saturated with perfluorohexane gas limits HFBII aggregation to nanometer‐sizes. Critical basic findings include an unusual co‐adsorption effect caused by the fluorocarbon gas, a strong acceleration of HFBII adsorption at the air/water interface, the incorporation of perfluorohexane into the interfacial film, the suppression of the fluid‐to‐solid 2D phase transition exhibited by HFBII monolayers under air, and a drastic change in film elasticity of both Gibbs and Langmuir films. As a result, perfluorohexane allows the formation of homogenous populations of spherical, narrowly dispersed, exceptionally stable, and echogenic microbubbles.
Diverse N‐Heterocyclic Ring Systems via Aza‐Heck Cyclizations of N‐(Pentafluorobenzoyloxy)sulfonamides
Authors: Hazelden Ian R. , Ma Xiaofeng , Langer Thomas , Bower John F. 
Published: July 2016

AbstractAza‐Heck cyclizations initiated by oxidative addition of Pd0‐catalysts into the N−O bond of N‐(pentafluoro‐benzoyloxy)sulfonamides are described. These studies, which encompass only the second class of aza‐Heck reaction developed to date, provide direct access to diverse N‐heterocyclic ring systems.
Carbon‐Based Metal‐Free Catalysts for Electrocatalysis beyond the ORR
Authors: Hu Chuangang , Dai Liming 
Published: July 2016

AbstractBesides their use in fuel cells for energy conversion through the oxygen reduction reaction (ORR), carbon‐based metal‐free catalysts have also been demonstrated to be promising alternatives to noble‐metal/metal oxide catalysts for the oxygen evolution reaction (OER) in metal–air batteries for energy storage and for the splitting of water to produce hydrogen fuels through the hydrogen evolution reaction (HER). This Review focuses on recent progress in the development of carbon‐based metal‐free catalysts for the OER and HER, along with challenges and perspectives in the emerging field of metal‐free electrocatalysis.
Modeling, Simulation, and Implementation of Solar‐Driven Water‐Splitting Devices
Authors: Xiang Chengxiang , Weber Adam Z. , Ardo Shane , Berger Alan , Chen YiKai , Coridan Robert , Fountaine Katherine T. , Haussener Sophia , Hu Shu , Liu Rui , Lewis Nathan S. , Modestino Miguel A. , Shaner Matthew M. , Singh Meenesh R. , Stevens John C. , Sun Ke , Walczak Karl 
Published: July 2016

AbstractAn integrated cell for the solar‐driven splitting of water consists of multiple functional components and couples various photoelectrochemical (PEC) processes at different length and time scales. The overall solar‐to‐hydrogen (STH) conversion efficiency of such a system depends on the performance and materials properties of the individual components as well as on the component integration, overall device architecture, and system operating conditions. This Review focuses on the modeling‐ and simulation‐guided development and implementation of solar‐driven water‐splitting prototypes from a holistic viewpoint that explores the various interplays between the components. The underlying physics and interactions at the cell level is are reviewed and discussed, followed by an overview of the use of the cell model to provide target properties of materials and guide the design of a range of traditional and unique device architectures.
A Dual‐Phase Ceramic Membrane with Extremely High H2 Permeation Flux Prepared by Autoseparation of a Ceramic Precursor
Authors: Cheng Shunfan , Wang Yanjie , Zhuang Libin , Xue Jian , Wei Yanying , Feldhoff Armin , Caro Jürgen , Wang Haihui 
Published: July 2016

AbstractA novel concept for the preparation of multiphase composite ceramics based on demixing of a single ceramic precursor has been developed and used for the synthesis of a dual‐phase H2‐permeable ceramic membrane. The precursor BaCe0.5Fe0.5O3−δ decomposes on calcination at 1370 °C for 10 h into two thermodynamically stable oxides with perovskite structures: the cerium‐rich oxide BaCe0.85Fe0.15O3−δ (BCF8515) and the iron‐rich oxide BaCe0.15Fe0.85O3−δ (BCF1585), 50 mol % each. In the resulting dual‐phase material, the orthorhombic perovskite BCF8515 acts as the main proton conductor and the cubic perovskite BCF1585 as the main electron conductor. The dual‐phase membrane shows an extremely high H2 permeation flux of 0.76 mL min−1 cm−2 at 950 °C with 1.0 mm thickness. This auto‐demixing concept should be applicable to the synthesis of other ionic‐electronic conducting ceramics.
The Molecular Mechanism of P2Y1 Receptor Activation
Authors: Yuan Shuguang , Chan H. C. Stephen , Vogel Horst , Filipek Slawomir , Stevens Raymond C. , Palczewski Krzysztof 
Published: July 2016

AbstractHuman purinergic G protein‐coupled receptor P2Y1 (P2Y1R) is activated by adenosine 5′‐diphosphate (ADP) to induce platelet activation and thereby serves as an important antithrombotic drug target. Crystal structures of P2Y1R revealed that one ligand (MRS2500) binds to the extracellular vestibule of this GPCR, whereas another (BPTU) occupies the surface between transmembrane (TM) helices TM2 and TM3. We introduced a total of 20 μs all‐atom long‐timescale molecular dynamic (MD) simulations to inquire why two molecules in completely different locations both serve as antagonists while ADP activates the receptor. Our results indicate that BPTU acts as an antagonist by stabilizing extracellular helix bundles leading to an increase of the lipid order, whereas MRS2500 blocks signaling by occupying the ligand binding site. Both antagonists stabilize an ionic lock within the receptor. However, binding of ADP breaks this ionic lock, forming a continuous water channel that leads to P2Y1R activation.
Biomimetic Total Synthesis of Hyperjapones A–E and Hyperjaponols A and C
Authors: Lam Hiu C. , Spence Justin T. J. , George Jonathan H. 
Published: July 2016

AbstractHyperjapones A–E and hyperjaponols A–C are complex natural products of mixed aromatic polyketide and terpene biosynthetic origin that have recently been isolated from Hypericum japonicum. We have synthesized hyperjapones A–E using a biomimetic, oxidative hetero‐Diels–Alder reaction to couple together dearomatized acylphloroglucinol and cyclic terpene natural products. Hyperjapone A is proposed to be the biosynthetic precursor of hyperjaponol C through a sequence of: 1) epoxidation; 2) acid‐catalyzed epoxide ring‐opening; and 3) a concerted, asynchronous alkene cyclization and 1,2‐alkyl shift of a tertiary carbocation. Chemical mimicry of this proposed biosynthetic sequence allowed a concise total synthesis of hyperjaponol C to be completed in which six carbon–carbon bonds, six stereocenters, and three rings were constructed in just four steps.
Pure red cell aplasia caused by parvovirus B19 in a heart transplant recipient
Authors: Invernizzi Rosangela , Bastia Raffaella , Quaglia Federica 
Published: July 2016

Key Clinical MessageA case of parvovirus B19‐induced pure red cell aplasia occurring in a heart transplant recipient is reported. The diagnosis of this rare but clinically important complication can be suspected on the basis of the pathognomonic morphological features of the bone marrow.
Press‐Printed Conductive Carbon Black Nanoparticle Films for Molecular Detection at the Microscale
Authors: Della Pelle Flavio , Vázquez Luis , Del Carlo Michele , Sergi Manuel , Compagnone Dario , Escarpa Alberto 
Published: July 2016

AbstractCarbon black nanoparticle (CBNP) press‐transferred film‐based transducers for the molecular detection at the microscale level were proposed for the first time. Current‐sensing atomic force microscopy (CS‐AFM) revealed that the CBNP films were effectively press‐transferred, retaining their good conductivity. A significant correlation between the morphology and the resistance was observed. The highest resistance was localized at the top of the press‐transferred film protrusions, whereas low values are usually obtained at the deep crevices or grooves. The amount of press‐transferred CBNPs is the key parameter to obtain films with improved conductivity, which is in good agreement with the electrochemical response. In addition, the conductivity of such optimum films was not only Ohmic; in fact, tunneling/hopping contributions were observed, as assessed by CS‐AFM. The CBNP films acted as exclusive electrochemical transducers as evidenced by using two classes of molecules, that is, neurotransmitters and environmental organic contaminants. These results revealed the potential of these CBNP press‐transferred films for providing new options in microfluidics and other related micro‐ and nanochemistry applications.
Base‐Promoted Tandem Reaction Involving Insertion into Carbon–Carbon σ‐Bonds: Synthesis of Xanthone and Chromone Derivatives
Authors: Cheng Xingcan , Zhou Yuanyuan , Zhang Fangfang , Zhu Kai , Liu Yuanyuan , Li Yanzhong 
Published: July 2016

AbstractTandem reactions using base‐promoted processes have been developed for the synthesis of xanthone and chromone derivatives. The first examples of base‐promoted insertion reactions of isolated carbon–carbon triple bonds into carbon–carbon σ‐bonds have been reported. Using these approaches, polycyclic structures can be prepared. This reaction has the potential to become a general synthetic protocol for the preparation of multi‐substituted xanthones and chromones due to the abundance of easily accessible starting materials possessing diverse substituent groups.
High Performance Fe Porphyrin/Ionic Liquid Co‐catalyst for Electrochemical CO2 Reduction
Authors: Choi Jaecheol , Benedetti Tania M. , Jalili Rouhollah , Walker Ashley , Wallace Gordon G. , Officer David L. 
Published: July 2016

AbstractThe efficient and selective catalytic reduction of CO2 is a highly promising process for both of the storage of renewable energy as well as the production of valuable chemical feedstocks. In this work, we show that the addition of an ionic liquid, 1‐butyl‐3‐methylimidazolium tetrafluoroborate, in an aprotic electrolyte containing a proton source and FeTPP, promotes the in situ formation of the [Fe0TPP]2− homogeneous catalyst at a less negative potential, resulting in lower overpotentials for the CO2 reduction (670 mV) and increased kinetics of electron transfer. This co‐catalysis exhibits high Faradaic efficiency for CO production (93 %) and turnover number (2 740 000 after 4 hour electrolysis), with a four‐fold increase in turnover frequency (TOF) when compared with the standard system without the ionic liquid.
ChemInform Abstract: The Crystal Structure of Cs2S2O3·H2O.
Authors: Winkler Verena , Schlosser Marc , Pfitzner Arno 
Published: July 2016

AbstractCs2S2O3·H2O, being first obtained as a byproduct in the preparation of Cs4In2S5, is prepared from an aqueous solution of Cs2CO3 to which an excess of BaS2O3 is given (90 °C, 1 d).
ChemInform Abstract: A Highly Efficient Metal‐Free Oxygen Reduction Electrocatalyst Assembled from Carbon Nanotubes and Graphene.
Authors: Yang Jia , Sun Haiyan , Liang Haiyi , Ji Hengxing , Song Li , Gao Chao , Xu Hangxun 
Published: July 2016

AbstractCarbon nanotubes and graphene are assembled into hybrid nanospheres by a one‐step aerosol route from aqueous solutions containing oxidized carbon nanotubes and graphene oxides, which are nebulized to generate aerosol droplets flowing through a tube furnace preheated at 350 °C.
ChemInform Abstract: Metal—Organic Frameworks Stabilize Solution‐Inaccessible Cobalt Catalysts for Highly Efficient Broad‐Scope Organic Transformations.
Authors: Zhang Teng , Manna Kuntal , Lin Wenbin 
Published: July 2016

AbstractMixed ligand metal‐organic frameworks (MOF) and UiO‐type MOFs are prepared and their Co‐complexes are used as highly robust and recyclable catalysts in hydrogenation and boration reactions as shown for the UiO‐type CoCl2(bipyv‐MOF) complex.
ChemInform Abstract: Synthesis of Imidates: TFA‐Mediated Regioselective Amide Alkylation Using Meerwein′s Reagent.
Authors: Popov Kirill , Somfai Peter 
Published: July 2016

AbstractA simple protocol for the synthesis of imidates from a variety of lactams is described using triethyloxonium tetrafluoroborate in the presence of catalytic TFA.
ChemInform Abstract: Zinc‐Catalyzed Stereo‐ and Regioselective 1,4‐Hydrative Fluorination of 3‐En‐1‐ynamides with Selectfluor.
Authors: Jadhav Appaso Mahadev , Huple Deepak B. , Singh Rahulkumar Rajmani , Liu Rai Shung 
Published: July 2016

AbstractThe efficient procedure provides diverse 4‐fluoro‐2‐en‐1‐amides with high (E)‐stereoselectivity.
ChemInform Abstract: Efficient Syntheses of Climate Relevant Isoprene Nitrates and (1R,5S)‐(‐)‐Myrtenol Nitrate.
Authors: Bew Sean P. , Hiatt‐Gipson Glyn D. , Mills Graham P. , Reeves Claire E. 
Published: July 2016

AbstractA chemoselective synthesis of isoprene nitrates via substitution of allylic halides using silver nitrate is developed.
ChemInform Abstract: Synthesis of β‐Arylated Alkylamides via Pd‐Catalyzed One‐Pot Installation of a Directing Group and C(sp3)—H Arylation.
Authors: Liu Yunyun , Zhang Yi , Cao Xiaoji , Wan Jie‐Ping 
Published: July 2016

AbstractThe title alkylamides are prepared by one‐pot three‐component condensation of various acyl chlorides, aryl iodides, and aminoquinoline.
ChemInform Abstract: Sustainable Diels—Alder Syntheses in Imidazolium Ionic Liquids.
Authors: Kumar Ganesan Vinoth , Rajendran Annamalai 
Published: July 2016

AbstractDiels—Alder adducts are synthesized in excellent yields within a few minutes under microwave irradiation and using the ionic liquid 3‐methyl‐1‐octyl‐imidazolium tetrachloroaluminate both as catalyst and solvent.