bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Organic Heterocyclothiazenes. Part 3. Synthesis and Structure of 1,3,5,2,4‐Trithiadiazepines.
Authors: MORRIS J. L. , REES C. W. 
Published: May 2016

AbstractThe trithiadiazepine (III) is best prepared by reaction of the trichloro compound (Ic) (obtained from chlorination of (Ia) at 0 °C) with the reagent (II).
ChemInform Abstract: Mechanistic Insights into the Opening of Epoxides with Trimethylsilyl Cyanide‐Zinc Iodide.
Authors: GASSMAN P. G. , OKUMA K. , LINDBECK A. , ALLEN R. 
Published: May 2016

AbstractThe epoxide (I) is cleaved with trimethylsilyl cyanide in the presence of zinc iodide, yielding the isonitriles (II) and (III), together with 7 further isomers.
ChemInform Abstract: Synthesis and X‐Ray Crystal Structure of a Cuboctahedral Platinum Cluster.
Authors: HOWARD J. A. K. , SPENCER J. L. , TURNER D. G. 
Published: May 2016

AbstractReaction of Pt(C2H4)2(P(tBu)3) and Pt(C2H4)3 in hexane solution with H2 (300 at) and a trace of CO affords the cluster (I) in small yield.
ChemInform Abstract: Synthesis and Properties of Heterotrimetallic Complexes Containing M‐Pt‐Hg (M: Mo, W, Fe, Mn, or Co) Arrays.
Authors: CALVET J. , ROSSELL O. , SECO M. , BRAUNSTEIN P. 
Published: May 2016

AbstractThe air‐stable heterotrimetallic cis‐complexes (II) are prepared from the bimetallic trans‐complexes (I) and appropriate carbonylmetalate anions and characterized by 31P NMR spectroscopy.
ChemInform Abstract: Stereospecific Synthesis of (Z,Z,Z,Z,Z,Z,Z,Z,E,E)‐Undecaprenol (Bacterialprenol) Using an all‐cis‐Diterpene Building Block.
Authors: SATO K. , MIYAMOTO O. , INOUE S. , MATSUHASHI Y. , KOYAMA S. , KANEKO T. 
Published: May 2016

AbstractThe chloride (I) is employed as a cisoid diterpene building block for the conversion of E,E‐farnesyl p‐tolylsulfone (II) to bacterialprenol (IV) via betulaprenol‐7 (IIIa).
ChemInform Abstract: Enantioselective Reduction of Vicinally Substituted Monocyclic Aldehydes with Horse Liver Alcohol Dehydrogenase. A New Approach to Chiral Alcohols and Aldehydes.
Authors: BOLAND W. , NIEDERMEYER U. 
Published: May 2016

AbstractReduction of racemic vicinally substituted cyclic aldehydes such as (I) with horse liver dehydrogenase (HLADH) yields chiral alcohols such as (II), together with the unconverted enantiomer of the starting product.
ChemInform Abstract: A New LPCVD Technique of Producing Borophosphosilicate Glass Films by Injection of Miscible Liquid Precursors
Authors: LEVY R. A. , GALLAGHER P. K. , SCHREY F. 
Published: May 2016

Abstracthas been studied using mixtures of tetraethylorthosilicate (TEOS), trimethylborate (TMB), and trimethylphosphite (TMP) as starting materials.
ChemInform Abstract: Properties of CsCl/AlCl3 Melts Near Equimolar Composition and the Problem of Corrosive Action of the Melt Towards Container Materials.
Authors: BERG R. W. , LAURIDSEN T. L. , OSTVOLD T. , HJULER H. A. , VON BARNER J. H. , BJERRUM N. J. 
Published: May 2016

AbstractBased on cryoscopic measurements of the molten title system, the congruent melting point of CsAlCl4 is corrected to 387.7 °C. Potentiometric results obtained at 400 °C for nearly neutral and weakly acidic melts are satisfactorily explained by the equilibrium outlined in the scheme with a stoichiometric equilibrium constant of 10‐7.63 (molar units).
ChemInform Abstract: The Reduction of Different Non‐Metallic Reactants at the Mercury/Electrolyte Interface Inhibited by Trialkylphosphine Oxides.
Authors: DITTRICH J. , PHILIPP R. , DOERFLER H.‐D. + , MUELLER E. + 
Published: May 2016

AbstractThe reduction of HIO3, HBrO3 and K2S2O8 in the presence of C6H13(C2H5)2PO and C8H17(CH3)2PO has been studied by dc polarography.
ChemInform Abstract: Highly Dispersed Rhodium on Alumina Catalysts: Influence of the Atmosphere on the State and Dispersion of Rhodium.
Authors: ZAKI M. I. , KUNZMANN G. , GATES B. C. , KNOEZINGER H. 
Published: May 2016

AbstractThe CO‐assisted conversion of Rh(0) to Rh(I) in highly dispersed Rh/Al2O3 catalysts has been investigated in various reactive atmospheres by low‐temp.
ChemInform Abstract: Complexes of Vitamin B1 with Transition Metal Ions. Crystal and Molecular Structure of Zn(thiamine)Cl3·0.4 H2O.
Authors: BENCINI A. , BORGHI E. 
Published: May 2016

AbstractThe title complex (I), prepared from Zn acetate and thiamine hydrochloride in water at 20 °C, crystallizes in the space group C2/c with Z = 8. This new structure is the third example of binding of thiamine to a transition metal ion and the first example of coordination to a first row transition metal in the 2+ oxidation state.
ChemInform Abstract: Chemistry of Pyrrole Pigments. Part 70. Active Transport by Means of Tripyrrinic Ligands.
Authors: EICHINGER D. , FALK H. 
Published: May 2016

AbstractIn contrast to (Ia) or (Ib)‐(Ic), which are provided with protonatable or deprotonatable functional groups, the tripyrrine derivatives (II) and (III) show an efficient, proton‐driven counter transport of Cu2+ and Zn2+ in a bulk CHCl3 membrane.
ChemInform Abstract: Heat Capacity and Phase Transitions of the Mixed‐Valence Compound (Fe3O(O2CCH3)6(3‐Me‐py)3)·3‐Me‐py.
Authors: SORAI M. , SHIOMI Y. , HENDRICKSON D. N. , OH S. M. , KAMBARA T. 
Published: May 2016

AbstractThe heat capacity under constant pressure of the oxo‐centered title complex (3‐Me‐py: 3‐methylpyridine) are measured with an adiabatic calorimeter between 12 and 350 K. Four phase transitions are found to occur at 181, 263.5, 271.5 and 282.5 K. The cumulative enthalpy and entropy changes due to these four phase transitions are calculated.
ChemInform Abstract: Reaction of Tetracyanoquinodimethane with Aromatic Nucleophiles.
Authors: EROFEEVA O. A. , KRULIKOVSKAYA E. A. , GOSSEN L. P. , VODOLAZHKO I. A. 
Published: May 2016

AbstractThe reactions between the title compounds (I) and (II) afford the N‐, O‐ or S‐tricyano derivatives (IIIa) to (IIIe) along with the N‐, O‐ and S‐dicyano derivatives (IVa)‐(IVc).
ChemInform Abstract: Reaction of Polyhalogenated Unsaturated Compounds with Vanadium Pentafluoride.
Authors: PETROV V. A. , BARDIN V. V. , FURIN G. G. , AVRAMENKO A. A. , GALAKHOV M. V. , KRASIL'NIKOV V. A. , KARELIN A. I. , TUSHIN P. P. , YAKOBSON G. G. 
Published: May 2016

AbstractTerminal alkenes such as (I) or (III) are fluorinated by VF5 at low temperatures according to method A) to give the fluoroalkanes (II) or (IV).
ChemInform Abstract: Azo and Azoxy Compounds. Part 11. Novel Variants of the Synthesis of 1‐Alkoxydiazene‐2‐oxide Derivatives.
Authors: YANDOVSKII V. N. , GIDASPOV B. V. , TSELINSKII I. V. , KUZNETSOV V. S. 
Published: May 2016

AbstractImproved methods for the preparation of the 1‐alkoxydiazene‐2‐oxides (III) and the 1‐oxido‐2‐alkoxydiazenodialkylacetic acids (VII) and the esters (VIII) and (IX) are described.
ChemInform Abstract: Synthesis of Formylcyclopropane, Alkyl Cyclopropyl Ketones and Cyclopropylcarbinols by γ‐Elimination Reactions under the Conditions of Intermediate Phase Catalysis.
Authors: KHUSID A. KH. 
Published: May 2016

AbstractThe novel procedure depicted in the scheme allows the preparation of the title compounds (IV), (VIII) and (IX) in high yields.
ChemInform Abstract: Plant Substances. Part 51. Methoxylation of Substituted 1,4‐Benzoquinones.
Authors: KOPECKY J. , SAMAN D. , NOVOTNY L. 
Published: May 2016

AbstractThe quinones (I) which serve as models for plant benzoquinones are methoxylated to afford compounds (II), (IIIa) and (IIIb) (ca.
ChemInform Abstract: Synthesis and Antilipolytic Activities of Quinolyl Carbanilates and Related Analogues.
Authors: MUSSER J. H. , CHAKRABORTY U. , BAILEY K. , SCIORTINO S. , WHYZMUZIS C. , AMIN D. , SUTHERLAND C. A. 
Published: May 2016

AbstractA series of carbamates (III), (V), (X), and (XIII) is prepared as outlined in the reaction scheme.
ChemInform Abstract: Synthesis and Properties of Bis(vinylenedithio)‐ and Bis(dimethylvinylenedithio)tetrathiafulvalenes.
Authors: KREITSBERGA YA. N. , MEDNE R. S. , EDZHINYA A. S. , PETROVA M. V. 
Published: May 2016

AbstractThe zinc complex (I) reacts with the dihaloethyl ester (IIa) or ether (IIb) to give the ethylenedithiodithiolethiones (III).
ChemInform Abstract: 2,4‐Diamino‐6,7‐dimethoxyquinazolines. Part 1. 2‐(4‐(1,4‐Benzodioxan‐2‐ ylcarbonyl)piperazin‐1‐yl) Derivatives as α1‐Adrenoceptor Antagonists and Antihypertensive Agents.
Authors: CAMPBELL S. F. , DAVEY M. J. , HARDSTONE J. D. , LEWIS B. N. , PALMER M. J. 
Published: May 2016

AbstractDoxazosin (Ia) and its derivatives (Ib) are prepared by condensation of the chloride (II) and piperazine (IV) respectively with the amine (III) or the acid chlorides such as (V).
ChemInform Abstract: Thiono‐ and Dithioesters. Part 39. Condensation of 2‐Morpholinodithiooxalic O‐Esters with Malonodinitrile or Cyanoacetate.
Authors: FALLERT M. , HARTKE K. 
Published: May 2016

AbstractReaction of the dithiooxalic acid derivatives (I) with the activated methylene compounds (II) produces the thioenolates (III) which are alkylated to give the thioenol ethers (V).
ChemInform Abstract: Anticonvulsives. Part 5. Substitution Reactions on 2,4‐Dichloro‐6‐(diallylamino)‐1,3,5‐triazine.
Authors: KREUTZBERGER A. , SCHLAEFER I. + 
Published: May 2016

AbstractThe triazines (I) react with the amines (II), yielding the substitution products (III).
ChemInform Abstract: Reaction of Triethylsilane with Propargyl Chloride in the Presence of the Catalytic System H2PtCl6‐I2.
Authors: PUKHNAREVICH V. B. , USHAKOVA N. I. , TSYKHANSKAYA I. I. , ALBANOV A. I. , VORONKOV M. G. 
Published: May 2016

AbstractThe main product of the title reaction is triethyl(3‐chloropropinyl)silane (III) which decomposes into the propinylsilane (IV) and the propadienylsilane (V) upon distillation.
ChemInform Abstract: Phase‐Transfer and Metal‐Complex Catalysis with Quaternary Ammonium Chlorometallates.
Authors: IOVEL I. G. , GOLDBERG Y. SH. , SHYMANSKA M. V. , LUKEVICS E. 
Published: May 2016

AbstractThe hydrosilylation of phenylacetylene (V) and the subsequent cyclopropanation of the vinylsilanes (VII) and (VIII) in the presence of the catalysts (I) ‐ (IV) are investigated.
ChemInform Abstract: Isolation, Spectroscopic Properties, and Electrochemical Properties of Two Oligomeric Silicon Phthalocyanines.
Authors: DEWULF D. W. , LELAND J. K. , WHEELER B. L. , BARD A. J. , BATZEL D. A. , DININNY D. R. , KENNEY M. E. 
Published: May 2016

AbstractA new way of preparation for the dimeric complex (Ib) (yield given in g) as well as chromatographic methods for isolating (Ic) and (Id) from a product mixture are described.
ChemInform Abstract: Synthesis and Structure of 1‐(Iododimethylsilylmethyl)piperidone‐2.
Authors: KRAMAROVA E. P. , OLENEVA G. I. , SHIPOV A. G. , MACHARASHVILI A. A. , SHKLOVER V. E. , STRUCHKOV YU. T. , BAUKOV YU. I. 
Published: May 2016

AbstractThe chlorine atom in the chlorodimethylsilylmethylpiperidone‐2 (I) is substituted by iodine to give the iodo compound (II).
ChemInform Abstract: Selenylation of cis‐ and trans‐1,2‐Dichloroethenes and Vinylidene Chloride Under Phase‐Transfer Catalysis Conditions.
Authors: MARTYNOV A. V. , MIRSKOVA A. N. , VORONKOV M. G. 
Published: May 2016

AbstractThe reactions between cis‐dichloroethene (I), its trans isomer (VII) or a mixture of these and phenylselenol (II) under the conditions of phase‐transfer catalysis afford the cis‐1‐phenylseleno‐2‐chloroethene (III) as the main product along with its trans isomer (IV), 1‐phenylseleno‐1‐chloroethene (V) and benzyl phenyl selenide (VI).
ChemInform Abstract: Heterogeneous Catalytic Synthesis of 2,3‐Dihydroselenophene and 3,4‐Dihydro‐2H‐selenopyran.
Authors: MAMEDOV E. SH. , BABAKHANOV R. A. , AKHVERDIEVA R. YA. , VEINBERG A. K. , MISHIEV R. D. , NASIBOV SH. S. , LIDAK M. YU. 
Published: May 2016

AbstractReaction of hydrogen selenide with the oxacycloalkenes (I) on a zeolite catalyst gives the selenium analogues (II).
ChemInform Abstract: Tetrakis(n‐alkyltelluro)tetrathiafulvalene (TTeCn‐TTF).
Authors: OKADA N. , YAMOCHI H. , SHINOZAKI F. , OSHIMA K. , SAITO G. 
Published: May 2016

AbstractTetrathiafulvalene (I) is converted to the lithium chalcogenides (III).
ChemInform Abstract: Synthesis and Structure of Group 5 Metal Alkyl and Alkylidene Complexes Containing 2,6‐Dialkylphenoxide Ligands: X‐Ray Crystal Structures of (Ta(OC6H3Me2‐2,6)2(CH2Ph)3), (Ta(OC6H3Me2‐2,6)4Me), and (Ta(OC6H3tBu2‐2,6)2(=CHSiMe3)(CH2SiMe3)).
Authors: CHAMBERLAIN L. R. , ROTHWELL I. P. , FOLTING K. , HUFFMAN J. C. 
Published: May 2016

AbstractThe alkyl and alkylidene Ta and Nb complexes (III) and (VIIa) containing 2,6‐dialkylphenoxide ligation are readily obtained by alkylation of the corresponding mixed chloroaryloxides (I) or (VI).
ChemInform Abstract: Detection of High‐Valent Intermediates in the Chlorine(I) Oxidation of (Porphinato)manganese(III) Complexes.
Authors: RODGERS K. R. , GOFF H. M. 
Published: May 2016

AbstractTreatment of Mn(TPP‐d8)Cl (TPP: 5,10,15,20‐tetraphenylporphin) with Cl2O in CHClF2 at ‐165 °C followed by warming to ‐78 °C affords an oxidized sym. (porphinato)manganese complex which is quantitatively converted to an asym.
ChemInform Abstract: Organometallic Lewis‐Acids. Part 29. Synthesis and Structure of Pentacarbonyl((pentacarbonylrheniooxy)methylcarbene)chromium and ‐tungsten (OC)5M‐C(Me)‐O‐Re(CO)5 (M: Cr, W).
Authors: FRITZ P. M. , STEIMANN M. , BECK W. 
Published: May 2016

AbstractThe reaction between the metal complexes (I) and Re(CO)+ 5 from (II) yields the title compounds (III).
ChemInform Abstract: Chiral Clusters with μ3‐Alkyne and μ3‐Vinylidene Ligands.
Authors: ALBIEZ T. , BERNHARDT W. , VON SCHNERING C. , ROLAND E. , BANTEL H. , VAHRENKAMP H. 
Published: May 2016

AbstractReaction of alkyne‐bridged dicobalt complexes with Fe2(CO)9 or Fe3(CO)12 gives the alkyne‐ and vinylidene‐bridged clusters (III) and (V).
ChemInform Abstract: Carbon Dioxide Chemistry and Electrochemistry of a Binuclear “Cradle” Complex of Ni(0), Ni2(μ‐CNMe)(CNMe)2(PPh2CH2PPh2)2.
Authors: DELAET D. L. , DEL ROSARIO R. , FANWICK P. E. , KUBIAK C. P. 
Published: May 2016

AbstractThe title complex (I) undergoes two one‐electron oxidations to form the complex (II).
ChemInform Abstract: Dinuclear Copper(I) Benzoato Complexes Binding Isocyanides and Azo Compounds.
Authors: TOTH A. , FLORIANI C. , CHIESI‐VILLA A. , GUASTINI C. 
Published: May 2016

AbstractThe Cu(I)‐benzoate complex (I) is a source of the doubly bridged dimetallic unit (Cu2(μ‐PhCO2)2)2 in reaction with many substrates.
ChemInform Abstract: Polarized, Single‐Crystal, Electronic Spectral Studies of Cu2Cl2‐ 6: Excited‐State Effects of the Binuclear Interaction.
Authors: DESJARDINS S. R. , WILCOX D. E. , MUSSELMAN R. L. , SOLOMON E. I. 
Published: May 2016

AbstractA series of chlorocuprates, the mononuclear salts (RNH3)2CuCl4 (R: ‐Me, ‐Et), (N‐(2‐ammonioethyl)piperazinium)CuCl5·2 H2O and the binuclear compounds KCuCl3, (NH2Me2)CuCl3 and LiCuCl3·2 H2O are investigated in order to evaluate the excited‐state effects of the binuclear cupric interaction.
ChemInform Abstract: Phenyl Complexes of Ruthenium(II): Competition Between Carbonyl Substitution and Formation of Benzoyl Complexes, and an X‐Ray Study of a Benzoyl Complex.
Authors: DAUTER Z. , MAWBY R. J. , REYNOLDS C. D. , SAUNDERS D. R. , HANSEN L. K. 
Published: May 2016

AbstractThe dicarbonyl‐Ru complexes (I) react with tBuNC to yield the CO substitution products (IIa), (IIb), (IId) or the benzoyl complexes (IIIa)‐(IIIc), (IIIe) in proportions which vary widely according to the conditions used and the nature of X and Y. The most probable route to the benzoyl complexes appear to be that via intermediates of formula Ru(CO)(CNtBu)(COAr)Y(PMe2Ph)2.
ChemInform Abstract: High‐Yield Syntheses of Sulfido Triruthenium Carbonyl Cluster Complexes Containing Bis(diphenylphosphino)methane.
Authors: FOMPEYRINE P. , LAVIGNE G. , BONNET J.‐J. 
Published: May 2016

AbstractReaction of thiophenol with the complex (I) leads to the thiolato hydrido cluster (II) which crystallizes in the space group P1 with Z=2.
ChemInform Abstract: Synthesis and Antitumor Activity of Organometallic cis‐Dichloro(enamine)(amine) Platinum(II) Complexes.
Authors: KHOKHAR A. R. , DORAN S. L. , BROWN D. B. , HACKER M. P. 
Published: May 2016

AbstractThe title complexes (I) are prepared by a previously published method starting from Zeise's dimer.
ChemInform Abstract: Steroids. Part 327. 2α,3α‐Dihydroxy‐7‐oxa‐6‐oxo‐B‐homo‐5α‐pregnan‐21‐oic Acid and Its Derivatives as Brassinolide Analogues.
Authors: CERNY V. , ZAJICEK J. , STRNAD M. 
Published: May 2016

AbstractThe synthesis of the title compounds (VIIa) starts with the acid (I) as shown in the scheme.
ChemInform Abstract: Utilization of a Nitrenium Ion Cyclization in a Synthesis of a Photoactive Prostaglandin, 17‐(4‐Azido‐2‐hydroxyphenyl)‐18,19,20‐trinorprostaglandin F2α.
Authors: DOLENCE E. K. , MORITA H. , WATT D. S. , FITZ T. 
Published: May 2016

Abstractp‐Nitrocinnamic acid (I) is converted to the saturated azide (II), which is cyclized in TFA/trifluoroacetic anhydride to yield the lactone (IV) via the spiro compound (III).
ChemInform Abstract: A Stereoselective Approach to 1β‐Methylcarbapenem Antibiotic Starting from (R)‐(‐)‐3‐Hydroxybutyric Acid Ester.
Authors: HATANAKA M. 
Published: May 2016

AbstractThe 3‐hydroxybutyrates (I) react with the ketenethioacetals (II) to produce the spiro compounds (III) after acidic treatment.
ChemInform Abstract: Study of InF3‐Based Glasses.
Authors: VIDEAU J.‐J. , DANCE J.‐M. , PORTIER J. , DUBOIS B. 
Published: May 2016

AbstractThe existence ranges of ternary fluoride glasses have been determined in BaF2‐InF3‐MFx systems for MFx: ZnF2, YF3, and ThF4, and their thermal properties have been investigated.
ChemInform Abstract: Anionic Ordering in Ba15V12S34O3, Affording Three Oxidation States of Vanadium and a Quasi‐One‐Dimensional Magnetic Lattice.
Authors: Wong Christina Jessica , Hopkins Emily Jane , Prots Yurii , Hu Zhiwei , Kuo Chang‐Yang , Pi Tun‐Wen , Valldor Martin 
Published: May 2016

AbstractPolycrystalline Ba15V12S34O3 is prepared by solid state reaction of a 12:3:12:22 molar mixture of BaS, BaO, V, and S under 200 mbar Ar (corundum crucible in sealed quartz tube, 1.
ChemInform Abstract: β‐Ag3RuO4, a Ruthenate(V) Featuring Spin Tetramers on a Two‐Dimensional Trigonal Lattice.
Authors: Prasad Beluvalli E. , Kazin Pavel , Komarek Alexander C. , Felser Claudia , Jansen Martin 
Published: May 2016

Abstractβ‐Ag3RuO4 is prepared by hydrothermal reaction of a 3:2 molar mixture of Ag2O and KRuO4 in H2O (autoclave, 190—200 °C, 48—72 h).
ChemInform Abstract: CdP2N4 and MnP2N4 — Ternary Transition‐Metal Nitridophosphates.
Authors: Pucher Florian J. , Karau Friedrich W. , Schmedt auf der Guenne Joern , Schnick Wolfgang 
Published: May 2016

AbstractThe title nitridophosphates are prepared by reaction of metal powders and HPN2 (Walker‐type multianvil apparatus, 5—8 GPa, 1000—1300 °C), which is a safer synthesis method than using metal azides as the starting materials.
ChemInform Abstract: A Simple, Phosphine Free, Reusable Pd(II)—2,2′‐Dihydroxybenzophenone—SBA‐15 Catalyst for Arylation and Hydrogenation Reactions of Alkenes.
Authors: Lazar Anish , Vinod Chathakudath P. , Singh Anand Pal 
Published: May 2016

AbstractA covalently anchored phosphine free Pd(II) based 2,2′‐dihydroxybenzophenone (DHBP) complex over organofunctionalized SBA‐15 is synthesized by the reaction of aminofunctionalized SBA‐15 (NH2SBA‐15) and a DHBP ligand, and further complexation with PdCl2 to get Pd(II)—DHBP@SBA‐15.
ChemInform Abstract: Enantioselective Fluorination of α‐Branched Aldehydes and Subsequent Conversion to α‐Hydroxyacetals via Stereospecific C—F Bond Cleavage.
Authors: Shibatomi Kazutaka , Kitahara Kazumasa , Okimi Takuya , Abe Yoshiyuki , Iwasa Seiji 
Published: May 2016

AbstractDue to difficulties in purification of intermediate fluorinated aldehydes, subsequent reduction to alcohols or stereospecific conversion to α‐hydroxyacetals in a one‐pot fashion is conducted.
ChemInform Abstract: Dual Pathway for the Asymmetric Transfer Hydrogenation of α‐Ketoimides to Chiral α‐Hydroxy Imides or Chiral α‐Hydroxy Esters.
Authors: Zhao Qiankun , Zhao Yuxi , Liao Hang , Cheng Tanyu , Liu Guohua 
Published: May 2016

Abstractα‐Ketoimides undergo transfer hydrogenation with sodium formate as hydrogen source in the presence of chiral ruthenium catalyst.
ChemInform Abstract: Bifunctional Primary Amine 2‐Aminobenzimidazole Organocatalyst Anchored to trans‐Cyclohexane‐1,2‐diamine in Enantioselective Conjugate Additions of Aldehydes.
Authors: Fernandes Talita de A. , Vizcaino‐Milla Pascuala , Ravasco Joao M. J. M. , Ortega‐Martinez Aitor , Sansano Jose M. , Najera Carmen , Costa Paulo R. R. , Fiser Bela , Gomez‐Bengoa Enrique 
Published: May 2016

AbstractThe title catalyst is applied in the Michael reaction of α,α‐branched aldehydes to nitroalkenes (I) and maleimides (IV).
ChemInform Abstract: Synthesis of Some New Thiazole, Oxazole, Pyrimidine and Pyridazine Derivatives from 2‐Cyano‐N‐octadecyl‐acetamide as Antimicrobial and Surface Active Agents.
Authors: El‐Sayed Refat , Ahmed Saleh A 
Published: May 2016

AbstractThe newly synthesized title compounds are converted to nonionic surface active agents by propoxylation using propylene oxide.
ChemInform Abstract: Organocatalysis by an Aprotic Imidazolium Zwitterion: Regioselective Ring‐Opening of Aziridines and Applicable to Gram Scale Synthesis.
Authors: Chakraborty Ghosal Nirnita , Santra Sougata , Das Sudarshan , Hajra Alakananda , Zyryanov Grigory V. , Majee Adinath 
Published: May 2016

AbstractThe aziridine ring is regioselectively opened by various nucleophiles, such like indoles, methanol, acetic acid, and di‐isopropylamine.
ChemInform Abstract: Tin‐Mediated One‐Pot Synthesis of α,α‐Disubstituted Homoallylic Hydrazides from Ketones, Acylhydrazines and Allyl Bromide.
Authors: Lu Ailing , Huang Danfeng , Wang Ke‐Hu , Su Yingpeng , Ma Junyan , Xu Yanli , Hu Yulai 
Published: May 2016

AbstractThe reaction works well with a variety of cyclic and acyclic ketones though 1‐tetralone and benzophenone do not give the desired products.
ChemInform Abstract: Iodine‐Mediated Synthesis of Aromatic Thioethers with Aromatic Amines and Sulfonyl Hydrazides in High Regioselectivity via C(sp2)—H Bond Functionalization.
Authors: Pang Xiaobo , Xiang Likui , Yang Xiaodong , Yan Rulong 
Published: May 2016

AbstractA convenient synthesis of bis(aryl) thioethers having a para‐amino substituent is rendered possible by a highly regioselective oxidative C—H coupling of N,N‐disubstituted anilines with arylsulfonyl hydrazides.
ChemInform Abstract: Intramolecular Addition of Triarylmethanes to Alkynes Promoted by KOtBu/DMF: A Synthetic Approach to Indene Derivatives.
Authors: Chen Yan‐yan , Chen Zhen‐yu , Zhang Niu‐niu , Chen Jia‐hua , Zhang Xue‐jing , Yan Ming 
Published: May 2016

AbstractA wide range of indene derivatives is prepared without the use of any transition‐metal catalyst.
ChemInform Abstract: Halogen‐Adjusted Chemoselective Synthesis of Fluorene Derivatives with Position‐Controlled Substituents.
Authors: Song Juan , Sun Wei , Li Yali , Wei Fuliang , Liu Chao , Qian Yan , Chen Shufen 
Published: May 2016

AbstractThe regioselectivity of the process depends on the ortho‐halogen substituent of the benzyl bromide.
ChemInform Abstract: N‐Heterocyclic Carbene‐Catalyzed [4 + 2] Cyclization of α,β‐Unsaturated Carboxylic Acids Bearing γ‐H with Isatins: An Enantioselective Synthesis of Spirocyclic Oxindole—Dihydropyranones.
Authors: Zhu Ling , Yu Chenxia , Li Tuanjie , Wang Yuhong , Lu Yinan , Wang Wenjing , Yao Changsheng 
Published: May 2016

AbstractThe reaction between various isatin derivatives and 3‐aryl substituted but‐2‐enoic acids succeeds in high yields and with high enantiomeric excesses.
ChemInform Abstract: Reductive Amination/Cyclization of Keto Acids Using a Hydrosilane for Selective Production of Lactams versus Cyclic Amines by Switching of the Indium Catalyst.
Authors: Ogiwara Yohei , Uchiyama Takuya , Sakai Norio 
Published: May 2016

AbstractA direct switch from synthesizing lactams to synthesizing cyclic amines is achieved by changing the catalyst from In(O‐Ac)3 to InI3.