bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Cycloadditions. Part 38. Intramolecular Oxime Olefin Cycloadditions. Stereospecific Formation of Functionalized Pyrrolidines.
Authors: HASSNER A. , MAURYA R. , MESKO E. 
Published: May 2016

AbstractCoupling of the amines (I) with the α‐bromo‐O‐silylaldoximes (II) produces the allylaminooximes (III) which undergo thermally induced ring closure, forming the bicyclic pyrrolidines (IV).
ChemInform Abstract: s‐Triazolo(4,3‐a) (1,3)diazacycloalkanes. Part 5. Synthesis of New Derivatives of 3‐Oxo‐2,3,5,6,7,8‐hexahydro‐s‐triazolo(4,3‐a)pyrimidine.
Authors: KREZEL I. 
Published: May 2016

AbstractThe pyrimidine (I) is transformed to title compounds of type (III) and (VI) which, in turn, are also available by acylation of the basis ring system (VII) at position 2. The latter compound reacts with the isothiocyanates (VIII) with substitution at position 8 to give the derivatives (IX).
ChemInform Abstract: Synthesis and Biological Activity of 5‐Phenyl‐1,3,4‐benzotriazepines. Part 13. Preparation of 2‐Alkylamino‐5‐phenyl‐1,3,4‐benzotriazepines by Reaction of 2‐Thioxo Analogues and Amines in the Presence of Heavy Metal Compounds.
Authors: MORGENSTERN O. , RICHTER P. , BESCH A. 
Published: May 2016

AbstractThe chloro‐1,3,4‐benzotriazepine‐2‐thiones (I) react with the primary and secondary amines (II) to give the aminobenzotriazepines (III).
ChemInform Abstract: Cyclointercalands. Incorporation of the Phenazine Group and of Metal Binding Subunits into Macrocyclic Receptor Molecules.
Authors: LEHN J.‐M. , SCHMIDT F. , VIGNERON J.‐P. 
Published: May 2016

AbstractStarting with the dimethoxy‐ (Ia) or dichlorophenazine (Ic), the macrocyclic ethers (III) and (VIII) are prepared.
ChemInform Abstract: A Short Effective Preparation of Chiral N,3‐Dimethyl‐5,7‐dioxo‐2‐phenylhexahydro‐1,4‐oxazepines.
Authors: BROWN R. T. , FORD M. J. 
Published: May 2016

Abstract(+)‐Ephedrine (+)‐(I) is coupled with dimethyl malonate (II) and subsequently saponified and decarboxylated, yielding the N‐malonylephedrine (III).
ChemInform Abstract: On the Cyclization Behaviour of 2‐Aminoethylphosphines.
Authors: ISSLEIB K. , SCHMIDT H. , LEISSRING E. 
Published: May 2016

Abstract2‐Aminoethylphosphine (I) undergoes cyclization with o‐chlorobenzaldehyde (II), yielding the 1,3‐azaphospholane (III), whereas reaction of (I) with pivaloyl chloride (IV) only produces the N‐acylated derivative (V).
ChemInform Abstract: Preparation and Cycloaddition Reactions of Selenoketones.
Authors: MEINKE P. T. , KRAFFT G. A. 
Published: May 2016

AbstractBase‐induced HCN elimination from the selenocyanates (I), possessing electron withdrawing or conjugating substituents, yields the selenoketones (III), which are trapped by the dienes (II) to afford the cycloadducts (IV) and (V).
ChemInform Abstract: 2‐Methyl‐1‐organo‐1‐halo‐1‐telluracyclopentane: Synthesis, Solution Properties, and Configurational Studies.
Authors: AL‐RUBAIE A. Z. , AL‐SHIRAYDA H. A. , AUOOB A. I. 
Published: May 2016

AbstractStarting with iodotelluracyclopentanes such as (I) or (VI), derivatives such as the allylated product (III), the tetraphenylborate (V), or the chloro compound (VII) are prepared by substitution reactions at the tellurium atom.
ChemInform Abstract: Complexes of Macrocyclic Polyethers with Some Potassium Monoethyl Benzeneazophosphonates.
Authors: TUSEK‐BOZIC LJ. , CURIC M. 
Published: May 2016

AbstractThe new potassium salts (I), prepared by mixing equimolar amounts of the monoethyl ester and KOH in abs.
ChemInform Abstract: Selective Metalation of Bicyclo(3.2.1)octa‐2,6‐diene. Part 1. Monostannylated Derivatives.
Authors: HERTKORN N. , KOEHLER F. H. + 
Published: May 2016

AbstractThe title compound (I) is directly deprotonated with tert‐butyllithium to give the carbanion (II) which is quenched with the trialkyltin chlorides (III), producing mixtures of the stannylated derivatives (IV) and (V).
ChemInform Abstract: Formation and Spectroscopic Identification of Some α‐Phosphaferrocenyl Carbenium Ions.
Authors: ROBERTS R. M. G. , SILVER J. , WELLS A. S. 
Published: May 2016

AbstractThree types of α‐phosphaferrocenyl alcohols (I)‐(III), are synthesized via reduction of their acetyl analogues with LiAlH4 in dry Et2O. The behavior of (I)‐(III) in trifluoroacetic acid solution is studied by investigating changes in 31P NMR and 57Fe Moessbauer spectra.
ChemInform Abstract: Synthesis of Zymosterol, Fecosterol, and Related Biosynthetic Sterol Intermediates.
Authors: DOLLE R. E. , SCHMIDT S. J. , ERHARD K. F. , KRUSE L. I. 
Published: May 2016

AbstractThe dienes (IV) serve as common intermediates in the synthesis of zymosterol (VIIa), fecosterol (VIII) and the related compounds (V) and (VIIb).
ChemInform Abstract: Synthesis of Fluorescent Amino Acids and Peptides with 2‐Aminopyridine at the Carboxyl or Amino Terminus.
Authors: MEGA T. , HAMAZUME Y. , IKENAKA T. 
Published: May 2016

AbstractFluorescent amino acids such as (Ia), (II) and (III) may serve as markers in peptides, e.g. (Ib).
ChemInform Abstract: Glycosylation Reactions with Di‐O‐acetyl‐2,6‐dibromo‐2,6‐dideoxy‐α‐D‐mannopyranosyl Bromide. A Simple Synthesis of Methyl 2,6‐Dideoxy‐D‐arabino‐hexopyranoside.
Authors: BOCK K. , LUNDT I. , PEDERSEN C. , PEDERSEN H. 
Published: May 2016

AbstractThe glycosylation reaction of the title compound (I) with methanol (II) gives a high yield of the two anomeric glycosides (IVa) and (IVb) which provide the dideoxyhexoses (Va) or (Vb) by catalytic hydrogenolysis.
ChemInform Abstract: Molecular Recognition Between Oligopeptides and Nucleic Acids: Sequence‐Specific Binding of the Naturally Occurring Antibiotic (4S)‐(+)‐Anthelvencin A and Its (4R)‐(‐) Enantiomer to Deoxyribonucleic Acids Deduced from 1H NMR, Footprinting, and Thermodynamic Data.
Authors: LEE M. , SHEA R. G. , HARTLEY J. A. , KISSINGER K. , PON R. T. , VESNAVER G. , BRESLAUER K. J. , DABROWIAK J. C. , LOWN J. W. 
Published: May 2016

AbstractThe influence of the chiral center of anthelvencin A (I) on the sequence‐specific molecular recognition of DNA is investigated.
ChemInform Abstract: A New Bromocuprate(I) Cluster: Structure of Tris(methyltriethylammonium) Octa‐μ‐bromo‐μ4‐bromo‐hexacuprate(I), (N(CH3)(C2H5)3)3(Cu6Br9).
Authors: ANDERSSON S. , JAGNER S. 
Published: May 2016

AbstractThe title compound (III) crystallizes in the orthorhombic space group Cmcm with Z=4.
ChemInform Abstract: Raman and IR Spectroscopy of the AlCl3‐SOCl2 System
Authors: MOSIER‐BOSS P. A. , BOSS R. D. , GABRIEL C. J. , SZPAK S. , SMITH J. J. , NOWAK R. J. 
Published: May 2016

Abstractcombined with MO calculations show SOCl2 to be an amphoteric molecule (acting as a donor through the O atom and as an acceptor through the S atom), which forms open chain dimers/oligomers (Cl2SO)n with n ≥ 2. The presence of cyclic dimers is excluded.
ChemInform Abstract: An Oxochromate of Formula BaNi2Cr8O15.
Authors: CUNO E. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractSingle crystals of the title compound are obtained from the reaction of BaCO3, NiO, and Cr2O3 (1:2:4, argon atmosphere, 1500 °C, a few days).
ChemInform Abstract: Semiconducting Properties of Passive Films on Stainless Steels
Authors: DI PAOLA A. 
Published: May 2016

Abstract(one ferritic and two austenitic steels) are studied by measurements of the potential dependence of the capacitance at various frequencies and in different electrolytes (1 N H2SO4, borate buffered 1 N Na2SO4, 1 N NaOH, and 3.5% NaCl).
ChemInform Abstract: Asymmetric Homoaldol Reaction by Enantioselective Lithiation of a Prochiral 2‐Butenyl Carbamate.
Authors: HOPPE D. , ZSCHAGE O. 
Published: May 2016

AbstractThe crystalline complex (R)‐(IV) is obtainable from the respective‐configurationally labile ‐ racemic Li complex formed from the carbamate (I) and (‐)‐sparteine (II)/sBuLi (III) followed by crystallization.
ChemInform Abstract: Photoeffects in Thin‐Film Molecular‐Level Chromophore‐Quencher Assemblies. Part 1. Physical Characterization.
Authors: SURRIDGE N. A. , MCCLANAHAN S. F. , HUPP J. T. , DANIELSON E. , GOULD S. , MEYER T. J. 
Published: May 2016

AbstractThe preparation and physical characterization of a film‐based chromophore‐quencher system is described in order to construct a molecular analogue of the p/n junction in a semiconductor solar cell.
ChemInform Abstract: Ring Cleavage of N‐Alkylisothiazolium Salts by Complex Metal Hydrides. Synthesis of β‐Enaminothio Ketones.
Authors: CUADRADO P. , GONZALEZ A. M. , PULIDO F. J. 
Published: May 2016

AbstractThe isothiazolium salts (III), derived from the isothiazoles (I) by N‐ethylation with triethyloxonium tetrafluoroborate (II), are reductively cleaved upon treatment with sodium borohydride or lithium alanate, forming the β‐enamino thioketones (IV).
ChemInform Abstract: Fulvenes, Fulvalenes. Part 56. Attempted Synthesis of Calicene from Trisubstituted Cyclopropanes and Cyclopentenone.
Authors: WEBER A. , GALLI R. , SABBIONI G. , STAEMPFLI U. + , WALTHER S. , NEUENSCHWANDER M. 
Published: May 2016

AbstractBase treatment of the dihydrocalicene (IV) leads to the desilylated addition products (VI) and (VII), but not to the desired calicene (VIII).
ChemInform Abstract: Thiosulfinic Acids, a New Class of Chiral Organosulfur Compounds.
Authors: MIKOLAJCZYK M. , LYZWA P. , DRABOWICZ J. , WIECZOREK M. , BUJACZ G. 
Published: May 2016

AbstractReaction of the sulfinyl chlorides (I) with Et3N (II) and H2S (III) yields the triethylammonium salts (IV).
ChemInform Abstract: New Hydrocarbons in the Synthesis of Adamantanoids.
Authors: KHUSNUTDINOV R. I. , DOKICHEV V. A. , GALEEV D. K. , ASYLGUZHINA N. F. , SULTANOV S. Z. , DZHEMILEV U. M. 
Published: May 2016

AbstractThe Diels‐Alder product (II) from the spiroheptadiene (I) is irradiated to give the bisspirocyclic bishomocubane (III) which is hydrogenated, producing the tetramethylbishomocubane (IV).
ChemInform Abstract: Reaction of 1‐Phenylethanol with Chiral Alcohols and Carboxylic Acids in the Presence of Montmorillonite.
Authors: OKUDA Y. , YOSHIHARA M. , MAESHIMA T. , FUJII M. , AIDA T. 
Published: May 2016

AbstractWhen the alcohol (I) and the acid (IV) are used for the title reaction the highest d.e.
ChemInform Abstract: Oxygen‐Atom Transfer Chemistry of α‐Azo Hydroperoxides: Effect of Competitive Intramolecular Hydrogen Bonding and α‐Methyl Substitution.
Authors: BAUMSTARK A. L. , VASQUEZ P. C. 
Published: May 2016

AbstractOxidation of the phenylhydrazones (I) with oxygen (II) under pressure leads of the formation of the highly explosive hydroperoxides (III).
ChemInform Abstract: Synthesis of (2R,3S)‐2‐Hydroxymethyl‐3‐hydroxypyrrolidine and the Geissman‐Waiss Lactone from (S)‐Pyroglutamic Acid.
Authors: IKOTA N. , HANAKI A. 
Published: May 2016

AbstractStarting with the protected trihydroxypyrrolidone (I) or the N‐benzyldihydroxypyrrolidine (IV), the (hydroxymethyl)hydroxypyrrolidines (III) and (XVI) and the Geissman‐Waiss lactone (XII) are prepared.
ChemInform Abstract: Preparation and Characterization of Some 4,5‐Methylenedithio‐4′,5′‐bis(alkylthio)tetrathiafulvalenes: Unsymmetrical π‐Donors.
Authors: PAPAVASSILIOU G. C. , MOUSDIS G. A. , YIANNOPOULOS S. Y. , ZAMBOUNIS J. S. 
Published: May 2016

AbstractThe coupling of (I) with the dithioles (II) leads to the cross‐coupling products in addition to the self‐coupling products of (I) and (II).
ChemInform Abstract: 2‐Benzopyrylium Salts. Part 33. 4‐1′‐Dimerization of 2‐Benzopyrylium Salts. Preparation of Benz(a)anthracenes.
Authors: ZHDANOV YU. A. , VERIN S. V. , KOROBKA I. V. , KUZNETSOV E. V. 
Published: May 2016

AbstractReaction of the benzopyrylium salt (I) with alkali gives the dimerization product (II) which is cyclized in the presence of isopropanol (III), forming the dihydrobenzanthracene (IV).
ChemInform Abstract: Remote Dianions. Part 3. Novel Synthesis of Substituted 2‐Piperidones from Imines.
Authors: THOMPSON C. M. , GREEN D. L. C. , KUBAS R. 
Published: May 2016

AbstractBoron trifluoride etherate‐catalyzed cyclocondensation of the imines (I) with the dianion (II) yields the 2‐piperidones (III).
ChemInform Abstract: Synthesis, Structure, and Reactions of Heterobinuclear μ‐Methylene Complexes.
Authors: MACKENZIE P. B. , COOTS R. J. , GRUBBS R. H. 
Published: May 2016

AbstractA series of title complexes (III) are prepared by reaction of titanacyclobutanes (I) as sources of the reactive (C5H5)2Ti=CH2 fragment with late‐transition metal chloride and methoxide complexes such as (II).
ChemInform Abstract: Investigations of Polymerization and Metathesis Reactions. Part 15. Heterogeneous, Metathesis‐Active Schrock‐Type Carbene Complexes by Reaction of Carbyne Tungsten(VI) Complexes with Silica Gel.
Authors: WEISS K. , LOESSEL G. + 
Published: May 2016

AbstractReaction of the surface SiOH groups of silica gel (II) with the carbyne complexes (I) affords the heterogeneous carbene tungsten(VI) complexes (III), which serve as storable metathesis catalysts above 100 °C. Their activity is tested by the reaction of 1‐octene in hexane.
ChemInform Abstract: Isometallocenes. Part 2. (Aminoarene)(tetramethylcyclobutadiene)cobalt(I) Hexafluorophosphates.
Authors: COOK M. R. , PAUSON P. L. 
Published: May 2016

AbstractA range of both ring and N‐substituted aromatic amines such as (IIa‐c) react with tricarbonyl(tetramethylcyclobutadiene)‐Co(I) hexafluorophosphate (I) in the presence of trimethylamine N‐oxide to give the title complexes (IIIa‐c).
ChemInform Abstract: Influence of the Acceptor Part of the Chromophore of Dimethinemerocyanine Dyes Upon the Aggregation Tendency in Aqueous Solution.
Authors: KUSSLER M. , BALLI H. 
Published: May 2016

AbstractA series of novel long‐chain alkyl‐dimethinemerocyanine dyes (Va)‐(Vc) containing sulfonate groups is synthesized in good yields by similar methods as shown for (Va); in contrast only traces of (Vd) are obtained.
ChemInform Abstract: A Rechargeable Cell Based on a Conductive Polymer/Metal Alloy Composite Electrode.
Authors: JOW T. R. , SHACKLETTE L. W. 
Published: May 2016

AbstractA capacity of 234 mAh/g (or 450 mAh/cm3) is achieved with a sodium‐lead alloy based composite electrode consisting of Na3.75Pb, poly(p‐phenylene), and a binder polymer (ethylene‐propylene‐diene‐terpolymer).
ChemInform Abstract: A Kinetic Study of the Reaction of Copper Atoms in the Gas Phase with Molecular Oxygen at 300 K in Microwave‐Induced Plasma Afterglows.
Authors: VINCKIER C. , CORTHOUTS J. , DE JAEGERE S. 
Published: May 2016

AbstractThe title reaction, depicted in the scheme, is investigated at 300 K and in the pressure range 5.5‐12 torr using the novel experimental technique of plasma afterglow atomization of CuCl and Cu(OAc)2 in H2/Ar microwave‐induced plasmas.
ChemInform Abstract: Autoaccelerative Diazo Coupling with Calix(4)arene; Unusual Cooperativity of the Calixarene Hydroxy Groups.
Authors: SHINKAI S. , ARAKI K. , SHIBATA J. , MANABE O. 
Published: May 2016

AbstractThe title reaction of (I) with (II) (molar ratio 1:4) leads to the quantitative formation of (III) which is also the main product in equimolar mixtures.
ChemInform Abstract: Generation and Cycloaddition Reactions of Phenylthio Nitrile Oxide. A Preparation of 3‐(Phenylthio)‐ and 3‐(Phenylsulfonyl)‐δ2‐isoxazolines.
Authors: CURRAN D. P. , CHAO J.‐C. 
Published: May 2016

AbstractPhenylthionitromethane (I) and the alkenes (II) or (V) cyclize in the presence of phenyl isocyanate to give the phenylthioisoxazolines (III) or (VI).
ChemInform Abstract: Substituent Effects on the Photochemistry of o‐Tolualdehydes.
Authors: CHARLTON J. L. , KOH K. 
Published: May 2016

AbstractThe aldehydes (Va) and (VIa), prepared from the alkoxytoluenes (Ia) or (Ib), are acylated to yield the compounds (Vb) ‐ (Vd) and (VIb) ‐(VId).
ChemInform Abstract: Enantioselective Reduction of α,β‐Unsaturated Carboxylates with NaBH4 and Catalytic Amounts of Chiral Cobalt Semicorrin Complexes.
Authors: LEUTENEGGER U. , MADIN A. , PFALTZ A. 
Published: May 2016

AbstractThe enantioselective reduction of the title compounds (I) and (III) is efficiently catalyzed by a semicorrin complex, formed in situ from the semicorrin ligand depicted in the scheme and CoCl2.
ChemInform Abstract: A Procedure for Quantitative Regioselective Nitration of Aromatic Hydrocarbons in the Laboratory.
Authors: CORNELIS A. , DELAUDE L. , GERSTMANS A. , LASZLO P. 
Published: May 2016

AbstractAromatic hydrocarbons such as toluene (I) are oxidized with various metalic nitrates in the presence of acetic anhydride (Menke conditions) to give the corresponding mononitro compounds.
ChemInform Abstract: o‐Lithiothiophenol Equivalents: Generation, Reactions, and Applications in Synthesis of Hindered Thiolate Ligands.
Authors: BLOCK E. , ESWARAKRISHNAN V. , GERNON M. , OFORI‐OKAI G. , SAHA C. , TANG K. , ZUBIETA J. 
Published: May 2016

AbstractThe trimethylsilylbenzenethiol (III) (≡ (VIIa)) can be obtained either from the THP derivative (I) or directly from the thiol (Va) via the dilithio compound (VIa).
ChemInform Abstract: Preparation of (+)‐ and (‐)‐N,S‐Dimethyl‐S‐phenylsulfoximine via an Improved Resolution. Accurate Determination of Very High Enantiomeric Purities by On‐Column GC Analysis of Diastereomeric Derivatives.
Authors: SHINER C. S. , BERKS A. H. 
Published: May 2016

AbstractTreatment of the racemic sulfoximine (I) with (‐)‐10‐camphorsulfonic acid (II) gives the optically pure salt (III).
ChemInform Abstract: High Pressure Mediated Diels‐Alder Reaction of Furan with Dialkyl (Acetoxymethylene)malonate.
Authors: SERA A. , OHARA M. , KUBO T. , ITOH K. , YAMADA H. , MIKATA Y. , KANEKO C. , KATAGIRI N. 
Published: May 2016

AbstractThe Diels‐Alder reaction of furan (I) with the methylenemalonate (II) is performed under high pressure to give the cycloadducts (III) as the main products.
ChemInform Abstract: Synthesis of 2,4‐Dioxoimidazolines from 2‐Arylimino‐1,3‐thiazines and Their Antifungal Activity.
Authors: ICHINARI M. , NAKAYAMA K. , HAYASE Y. 
Published: May 2016

AbstractThe 2‐arylimino‐1,3‐thiazines (I) react with chloroacetyl chloride (II) to give predominantly the 1‐aryl‐3‐mercaptopropyl‐2,4‐imidazolidinediones (III).
ChemInform Abstract: Synthesis and Pharmacological Activity of Stereoisomers of 1,4‐Dihydro‐2,6‐dimethyl‐4‐(3‐nitrophenyl)‐3,5‐pyridinedicarboxylic Acid Methyl 1‐(Phenylmethyl)‐3‐piperidinyl Ester.
Authors: MUTO K. , KURODA T. , KAWATO H. , KARASAWA A. , KUBO K. , NAKAMIZO N. 
Published: May 2016

AbstractEsterification of the dihydropyridinedicarboxylic acid monoester (I) via the intermediate acid chloride with the piperidinol (II) gives the four diastereomers (III) ‐ (VI).
ChemInform Abstract: Synthesis and Ring‐Chain Tautomerism of Stereoisomeric 1,3‐Oxazines Condensed with the Cyclopentane Ring.
Authors: FUELOEP F. + , PIHLAJA K. , MATTINEN J. , BERNATH G. , GABOR B. 
Published: May 2016

AbstractThe isomeric amino alcohols (I) and (V) react with the aromatic aldehydes (II) to give the fused 1,3‐oxazines (III) or (VI), together with the imines (IV) or (VII).
ChemInform Abstract: Lipophilic Cage Ligands Containing Two Tightly Connected 1,7‐Dioxa‐4,10‐diazacyclododecane Rings: Synthesis and X‐Ray Structure of a Sodium Perchlorate Complex.
Authors: ANELLI P. L. , MONTANARI F. , QUICI S. , CIANI G. , SIRONI A. 
Published: May 2016

Abstract4‐Tosyl‐1,7‐dioxa‐4,10‐diazacyclododecane (VII), prepared from the chloroethoxyethanol (I) and p‐toluenesulfonamide (II), is converted into the propanediyl‐bis(dioxadiazacyclododecanes) (X) which undergo sodium‐templated cyclocondensation with the bissulfonates (XI), yielding the sodium perchlorate complexes (XIII).
ChemInform Abstract: Transition Metal‐Promoted Reactions. Part 25. Regioselective Silylolefination of Allylic Dithioacetals. Stereoselective Synthesis of 1‐(Trimethylsilyl)butadienes.
Authors: NI Z.‐J. , LUH T.‐Y. 
Published: May 2016

AbstractThe allylic dithioacetals (I) react with the silylmethyl Grignard compound (II) in the presence of a nickel catalyst, yielding the 1‐(trimethylsilyl)butadienes (III).
ChemInform Abstract: Synthesis, Electrochemistry, and Electron Spin Resonance Spectra of Some Seventeen‐Electron Complexes Containing the (Mo(NO))2+ Core and the Molecular Structure of (Mo(NO)(HB(Me2pz)3)(pyr)2).
Authors: AL OBAIDI N. , EDWARDS A. J. , JONES C. J. , MCCLEVERTY J. A. , NEAVES B. D. , MABBS F. E. , COLLISON D. 
Published: May 2016

AbstractThe reactions between the 16‐electron complex (I) and several neutral, unsaturated N‐heterocyclic ligands (II) are investigated in order to establish the nature of the paramagnetic cationic 17‐electron complexes (III).
ChemInform Abstract: (Diphenylphosphinomethyl)diphenylphosphine Sulfide (Ph2PCH2PPh2S) and Its Methanide Anion Ph2PCHPPh2S‐ as Ligands in Organogold Chemistry. X‐Ray Crystal Structure of Cyclic cis‐(Au(C6F5)2(PPh2CHPPh2S)).
Authors: USON R. , LAGUNA A. , LAGUNA M. , NIEVES FRAILE M. , JONES P. G. , ERDBRUEGGER C. F. + 
Published: May 2016

AbstractStable Au complexes (II) and (III) containing the title ligand uni‐ or bidentately coordinated are prepared according to the scheme.
ChemInform Abstract: Syntheses and Reactivity of Ruthenium Hydride Complexes Containing Chelating Triphosphines. Part 1. Characterization of the Molecular Dihydrogen Complex RuH2(H2)(Cyttp) (Cyttp: PhP(CH2CH2CH2P(c‐C6H11)2)2).
Authors: JIA G. , MEEK D. W. 
Published: May 2016

AbstractMetathesis reactions of the dichloro‐ruthenium complex of the ligand with NaH in THF under a dihydrogen atmosphere at 40‐50 °C yield the title complex (I).
ChemInform Abstract: Structural, Spectroscopic, and Electrochemical Characterization of Tetrakis‐μ‐(2‐pyrrolidinonato)‐dirhodium(II) and Tetrakis‐μ‐(δ‐valerolactamato)‐dirhodium(II).
Authors: BEAR J. L. , LIFSEY R. S. , CHAU L. K. , AHSAN M. Q. , KORP J. D. , CHAVAN M. , KADISH K. M. 
Published: May 2016

AbstractThe title complex (I) (ca.
ChemInform Abstract: Thermal Evolution of an Oxide‐Bound Organometallic Complex in Ultrahigh Vacuum: Stepwise Conversion of Tris(allyl)rhodium to Rhodium Metal on TiO2(001).
Authors: CHANG T. , BERNASEK S. L. , SCHWARTZ J. 
Published: May 2016

AbstractThe stepwise thermal evolution of the TiO2‐bound complex (I) in ultrahigh vacuum is studied by photoelectron spectroscopy and on powdered supports by IR methods.
ChemInform Abstract: Synthesis and Characterization of Complexes of Nickel(II), Palladium(II) and Platinum(II) with the New Bifunctional Aminodiphosphine Ligand HN(CH2CH2CH2PMe2)2.
Authors: EDWARDS P. G. , JAOUHARI R. G. 
Published: May 2016

AbstractThe new title ligand (III) is prepared by a radical addition of dimethylphosphine (II) to the diallylamine (I).
ChemInform Abstract: A Novel Synthesis of the Monobactam Antibiotic Carumonam.
Authors: MANCHAND P. S. , LUK K.‐C. , BELICA P. S. , CHOUDHRY S. C. , WEI C. C. , SOUKUP M. 
Published: May 2016

AbstractStarting with calcium L‐threonate (I), the oxirane (V) is prepared via the dibromo acid ester (III).
ChemInform Abstract: Formation and Magnetic Properties of Crystalline and Amorphous SmCo2 Hydrides.
Authors: KANEMATSU K. , SUGIYAMA T. , SEKINE M. , OKAGAKI T. , KOBAYASHI K. I. 
Published: May 2016

AbstractSamples of SmCox are prepared by arc melting of stoichiometric mixtures of the elements in an argon atmosphere.
ChemInform Abstract: Effect of Substitution of Vanadium in Nd2Fe14B Studied by Moessbauer Spectroscopy.
Authors: KAMAL R. , LOVLEEN LOVLEEN 
Published: May 2016

AbstractIt is found that 10% substitution of V for Fe in Nd2Fe14B increases both the hyperfine field averaged over all 57Fe sites, Bhf, and the Curie temp. TC.
ChemInform Abstract: Preparation and Spectroscopic Characterization of the Decahalogenodirhenates(IV), (Re2X10)2‐, X: Cl, Br.
Authors: KELM W. , PREETZ W. 
Published: May 2016

AbstractThe IR and Raman spectra of the edge‐shared bioctahedral anions (II), obtained as shown in the scheme, are assigned according to point group D2h. The UV‐VIS absorption spectra show eight intraconfigurational transitions between 600 and 1400 nm, which are more intense and shifted slightly bathochromicly compared to the spectra of the monomeric complexes.