bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Cycloaromatization Reactions of Methyl 4‐Carboxymethyl‐5‐methoxypenta‐ 2,4‐dienoate.
Authors: NANTZ M. H. , FUCHS P. L. 
Published: May 2016

AbstractCoumalic acid (I) is cleaved upon prolonged treatment with methanol (II) in the presence of sulfuric acid and trimethyl orthoformate to produce the methoxybutadienedicarboxylate (III), together with minor amounts of the dimethoxy derivative (IV).
ChemInform Abstract: Enantioface Differentiation in cis Dihydroxylation of C‐C Double Bonds by Osmium Tetroxide with Use of a Chiral Diamine with D2
Authors: TOMIOKA K. , NAKAJIMA M. , KOGA K. 
Published: May 2016

AbstractSymmetry. ‐ The enantioselective dihydroxylation of the olefins (I), (IV), and (VI) using OsO4 and the (‐)‐diamine delineated in the scheme (conditions A)) yields the (S)‐ or (S),(S)‐products (III), (V) or (VII) in high enantioselectivities.
ChemInform Abstract: Reactions of Benzenetellurol as a Reducing Agent.
Authors: ASO Y. , NISHIOKA T. , OSUKA M. , NAGAKAWA K. , SASAKI K. , OTSUBO T. , OGURA F. 
Published: May 2016

AbstractPhenyl trimethylsilyl telluride (IV), prepared by two methods as outlined in the reaction scheme, is subjected to methanolysis, yielding phenyltellurol (VII) and methyl trimethylsilyl ether (VIII).
ChemInform Abstract: Hypervalent Iodine Oxidation of Hydrazine Hydrate in Dichloromethane. A New Method for Diimide Generation.
Authors: MORIARTY R. M. , VAID R. K. , DUNCAN M. P. 
Published: May 2016

AbstractThe olefinic compounds (I) are hydrogenated to form the corresponding saturated derivatives (II) by means of a reagent system consisting of hydrazine hydrate and iodosylbenzene diacetate.
ChemInform Abstract: Unusual Regioselectivity in the Carbonylation of Substituted Benzenes via the C‐H Activation Catalyzed by RhCl(CO)(PMe3)2.
Authors: SAKAKURA T. , TANAKA M. 
Published: May 2016

AbstractThe benzenes (I) are carbonylated in the presence of a Rh‐catalyst to give the benzaldehydes (III) and the benzyl alcohols (IV) as the main products.
ChemInform Abstract: Novel Organic Synthesis Using DBU. Part 11. Difference of Chemical Behavior of Carbon Dioxide and Carbon Disulfide on the Reaction with DBU Forming Dialkyl Carbonates and Trithiocarbonates.
Authors: HORI Y. , NAGANO Y. , FUKUHARA T. , TERAMOTO S. , TANIGUCHI H. 
Published: May 2016

AbstractReaction of carbon dioxide (Ia) or carbon disulfide (Ib) with H2O, H2S, the alcohols (VIII), or the mercaptans (III) in the presence of DBU and subsequent treatment with the alkylation agents (II) or (VI) yield the carbonate (IV), the dithiocarbonates (X), or the trithiocarbonates (V) and (VII).
ChemInform Abstract: Lewis Acid‐Induced Reaction of γ,δ‐Epoxy Tin Compounds.
Authors: SATO T. , WATANABE M. , MURAYAMA E. 
Published: May 2016

AbstractThe epoxyethylstannanes (Ia), (Ic), and (Ie) ‐ (Ig), prepared from the corresponding stannylbutenes, undergo rearrangement in the presence of boron trifluoride etherate to form the cyclopropylmethyl carbinols (II).
ChemInform Abstract: The Reaction of Organocopper Reagents with Azobenzene, Azoxybenzene, and N‐Benzylideneamides.
Authors: RAHMAN M. T. , CHOWDHURY R. L. , QUADER M. A. , ROY A. K. 
Published: May 2016

AbstractLithium diphenylcuprate (II) reacts with azobenzene (I) to give a dimetallic species which is hydrolyzed to form hydrazobenzene (III) and biphenyl (IV).
ChemInform Abstract: Reductive Thiolation of Aromatic Ketones and Benzaldehyde with Sulfur, Carbon Monoxide and Water Leading to Thiols.
Authors: NISHIYAMA Y. , OHTORI Y. , HAMANAKA S. , OGAWA A. , MURAI S. , SONODA N. 
Published: May 2016

AbstractReductive sulfurization of the aromatic carbonyl compounds (I) to give the corresponding thiols (II) is achieved by treatment with sulfur, carbon monoxide, and water in the presence of DBU.
ChemInform Abstract: Regio‐ and Stereoselective Synthesis of E‐ and Z‐Vinylic Sulfones and Their Conversion to the Corresponding Allylic Sulfones.
Authors: KOBAYASHI T. , TANAKA Y. , OHTANI T. , KINOSHITA H. , INOMATA K. , KOTAKE H. 
Published: May 2016

AbstractThe terminal olefins (I) are oxidatively sulfonated to produce the vinylic sulfones trans‐(III).
ChemInform Abstract: The Reaction of Thiete 1,1‐Dioxide with Carbanions.
Authors: KOMATSU M. , OGAWA H. , OHSHIRO Y. , AGAWA T. 
Published: May 2016

AbstractThe thiete 1,1‐dioxide (II) is allowed to react with the carbanions of the salts (I): (II) and the anion of (Ia), derived from ethyl phenylacetate, yield mixtures of the normal adduct (IIIa), the cleavage product (IVa), and the thiopyranone derivative (V).
ChemInform Abstract: Synthesis of N‐Unsubstituted α‐Alkylated Pyrrol‐2‐acetonitriles.
Authors: MUCHOWSKI J. M. , SCHELLER M. E. 
Published: May 2016

AbstractPyrrole (I) is subjected to Vilsmeier‐Haack formylation, yielding the iminium salt (III) which is dehydrochlorinated to give the dimethylaminoazafulvene (IV).
ChemInform Abstract: Cycloaddition Reactions of 2‐Pyrones and Related Compounds. Part 5. Regio‐ and Stereoselective Introduction of Functional Groups into 1‐Isoindolinone and 1(2H)‐Isoquinolone Systems.
Authors: NOGUCHI M. , YOSHIOKA M. , KAKIMOTO S. , KAJIGAESHI S. 
Published: May 2016

AbstractMCPBA oxidation of the isoindolinones (I) is carried out regio‐ and stereoselectively to give the 5,6‐epoxides (II), which undergo ring opening reactions with the azide (III), the amine (V) or the alcohols (VII) to give the products shown in the scheme.
ChemInform Abstract: A Novel Formation of 3,4‐Disubstituted Isothiazoles from 5‐Amino‐6‐methylpyrimidinones.
Authors: UEDA T. , SHIBATA Y. , KATO Y. , SAKAKIBARA J. 
Published: May 2016

AbstractThe title compounds (VI), (VII), (VIII) and (XI) are prepared from the pyrimidinone (I) via the formation of the thiazolopyrimidine (III).
ChemInform Abstract: Reaction of Potassium Superoxide with 3‐Nitro‐2‐phenyl‐2H‐1‐benzopyrans and Their Dihydro Derivatives.
Authors: RAO T. S. , TRIVEDI G. K. 
Published: May 2016

AbstractOxidation of the 3‐nitro‐2‐aryl‐2H‐1‐benzopyrans (I) with potassium superoxide gives only low yields of the flavonols (IV), the main products are the benzoic acids (II) and (III) as a result of cleavage.
ChemInform Abstract: Synthesis of Some New 4‐Methylcoumarins.
Authors: PARMAR V. S. , SINGH S. , RATHORE J. S. 
Published: May 2016

AbstractCyclocondensation of the trihydroxybenzenes (I) with the α‐acetyldicarboxylates (II) produces the coumarins (III) which are subsequently methylated or acetylated to yield the coumarins (IV) and (VII).
ChemInform Abstract: Asymmetric Michael Addition/Lactamization via SAMP‐/RAMP‐Hydrazones. Enantioselective Synthesis of Substituted Tetrahydro‐2,5(1H,3H)‐quinolinediones.
Authors: ENDERS D. , DEMIR A. S. , PUFF H. , FRANKEN S. 
Published: May 2016

AbstractThe chiral hydrazine (II) reacts with the cyclohexane‐1,3‐diones (I) to form the tautomers (III) of the corresponding monohydrazones.
ChemInform Abstract: A Two‐Step Synthesis of Mimosamycin.
Authors: MCKILLOP A. , BROWN S. P. 
Published: May 2016

AbstractMimosamycin (VI) is prepared by Diels‐Alder reaction of the benzoquinone (I) and the azadiene (II) and subsequent removal of the siloxy groups, followed by N‐methylation.
ChemInform Abstract: The Effect of Benzannelation Toward Cycl(3.2.2)azine. Synthesis and Physical Properties of Dibenzo(a,h)cycl(3.2.2)azine.
Authors: TOMINAGA Y. , SHIROSHITA Y. , MATSUDA Y. , HOSOMI A. 
Published: May 2016

Abstract1‐Cyanoisoindolo(2,1‐a)isoquinoline (III), prepared from isoquinolinium dicanomethylide (I) and benzyne, reacts with dimethyl acetylenedicarboxylate (IV) to form a mixture of the cycloadducts (V) and (VIa).
ChemInform Abstract: Simple Synthesis of Pyrrolo(3,4‐c)quinolin‐3‐ones and Pyrrolo(3,4‐γ)quinoline‐3,4‐diones.
Authors: SASAKURA K. , SUGASAWA T. 
Published: May 2016

AbstractThe 2‐aminophenacyl chlorides (I) undergo ring closure with ethyl acetoacetate (II) or ethyl malonyl chloride (VI), forming the quinolines (III) or the quinolones (VIII).
ChemInform Abstract: Synthesis of Bridgehead‐Nitrogen Heterocycles from Pyrylium Salts: Preparation of the Novel Tricyclic Thiazolo(2,3‐c)pyrido(2,1‐f)(1,2,4)triazine Ring System.
Authors: MOLINA P. , TARRAGA A. , LORENZO‐PENA M. , ESPINOSA A. 
Published: May 2016

AbstractCyclization of the ethoxycarbonyldiphenylpyrylium tetrafluoroborate (I) with the thiosemicarbazide (II) produces the dihydropyridotriaziniumthiolate (III) which is alkylated with the phenacyl bromides (IV) and trimethyloxonium tetrafluoroborate (VII), forming the phenacylthio or methylthio derivatives (V) and (VIII) respectively.
ChemInform Abstract: Synthesis and Characterization of the Cage 12,17‐Dioxa‐1,5,9‐triazabicyclo(7.5.5)nonadecane. Its Basicity and Complexing Properties.
Authors: BIANCHI A. , CIAMPOLINI M. , MICHELONI M. , CHIMICHI S. , ZANOBINI F. 
Published: May 2016

AbstractThe title macrocycle (III) (= L) acts as a very strong base in the first protonation step, as a moderate base in the second step, and as a very weak base in the last step.
ChemInform Abstract: Reaction of Ethyl Trimethylsilyl Diethoxymethylphosphonite with Carbonyl Compounds.
Authors: PRISHCHENKO A. A. , LIVANTSOV M. V. , MOSHNIKOV S. A. , LUTSENKO I. F. 
Published: May 2016

AbstractThe phosphonite (I) reacts with butyraldehyde (IIa) or benzaldehyde (IIb) to give the phosphinates (III).
ChemInform Abstract: Hydrochlorination of 1,2‐Alkadienephosphinic Acids.
Authors: BELAKHOV V. V. , KOMAROV E. V. , IONIN B. I. , PETROV A. A. 
Published: May 2016

AbstractHydrochlorination of the 1,2‐alkadienephosphinic acids (I) in polar solvents gives the oxaphospholenes (II).
ChemInform Abstract: A New Family of Semibent Rhenium(V) Arylimides Formed by Azo Splitting. Structure, Bonding, and Electrooxidation to Rhenium(VI) Congeners.
Authors: LAHIRI G. K. , GOSWAMI S. , FALVELLO L. R. , CHAKRAVORTY A. 
Published: May 2016

AbstractThe arylazopyridines (I) react with (II) to give the new Re(V) complexes (III) containing an arylimide moiety coordinated in a semibent fashion.
ChemInform Abstract: Synthesis and Characterization of Monometallic and Bimetallic Mixed‐Ligand Complexes of Iron(II) Containing 2,2′‐Bipyrimidine or 2,3‐Bis(2‐pyridyl)pyrazine.
Authors: BREWER K. J. , MURPHY W. R. JUN. , PETERSEN J. D. 
Published: May 2016

AbstractThe monometallic compounds (I) are prepared by published methods and the binuclear complexes (II) by reaction of the ligands with FeCl2 and KCN in boiling water.
ChemInform Abstract: Copper(I) Complexes with Bidentate Tertiary Phosphine Ligands: Solution Chemistry and Antitumor Activity.
Authors: BERNERS‐PRICE S. J. , JOHNSON R. K. , MIRABELLI C. K. , FAUCETTE L. F. , MCCABE F. L. , SADLER P. J. 
Published: May 2016

AbstractThe stability of bischelated diphosphine complexes of copper(I) chloride appears to be highly dependent on the nature of the phosphine ligand.
ChemInform Abstract: Preparation and Characterization of the Disulfur‐Bridged Osmium(IV) Bis(osmocene) Complex ((Cp2OsS)2) (PF6)2.
Authors: DROEGE M. W. , TAUBE H. 
Published: May 2016

AbstractThe reaction of the metal‐metal‐bonded osmocenium dimer (I) with elemental sulfur yields the title complex (II), which crystallizes in the space group P21/n with Z=4.
ChemInform Abstract: Complexes of Platinum(II) and Palladium(II) with the 2,2′‐Biphenyldiyl Dianion as a σ‐Bonded Chelate Ligand.
Authors: CORNIOLEY‐DEUSCHEL C. , VON ZELEWSKY A. 
Published: May 2016

AbstractThe air‐stable, crystalline compounds (V) are prepared from the cis‐Pt complex (I) and the trans‐Pd complex (VIII), resp., whereas the trans‐Pt complex (VI) in the same reaction sequence gives (VII).
ChemInform Abstract: Synthesis of Novel 7,7′‐Bis‐6a,7‐dehydronoraporphines.
Authors: JOSSANG A. , LEBOEUF M. , CAVE A. 
Published: May 2016

AbstractNornuciferine (Ia), nornantenine (Ib), ananaine (Ic), and xylopine (Id) are N‐chlorinated and then treated with sodium ethoxide to give the products (II) ‐ (V).
ChemInform Abstract: Electrodeposition of Aluminum‐Tin Alloys from Organic Electrolytes.
Authors: PLATIS F. S. , CAPUANO G. A. 
Published: May 2016

AbstractIt is demonstrated that bright, adherent, and coherent Al‐Sn coatings on steel can be obtained by electrodeposition from alkyl benzene/AlBr3‐HBr electrolytes with cathode efficiencies approaching 100%.
ChemInform Abstract: Heterojunction Photoelectrodes. Part 4. Electrochemistry and Photoelectrochemistry at Indium Tin Oxide/Nonaqueous Electrolyte Interfaces.
Authors: HO S.‐I. , RAJESHWAR K. 
Published: May 2016

AbstractCyclic voltammetry (CV) has been used to study the kinetics of charge transfer at Sn‐doped indium oxide (ITO) electrode/acetonitrile interfaces for 18 one‐electron outer‐sphere redox systems (e.g.
ChemInform Abstract: The Mono‐, Sesqui‐, and Dibromides of Indium: InBr, In2Br3, and InBr2.
Authors: STAFFEL T. , MEYER G. 
Published: May 2016

AbstractThe three reduced indium bromides are synthesized by heating InBr3/In mixtures in molar ratios of 1:2, 1:1, and 2:1, resp., to 340 °C (1 d).
ChemInform Abstract: Structural Investigations of Two Bismuth‐Ammonium Condensed Phosphates: BiHNH4P3O10 (I) and BiNH4(PO3)4 (II).
Authors: AVERBUCH‐POUCHOT M. T. , BAGIEU‐BEUCHER M. 
Published: May 2016

AbstractFor both the title compounds, crystallized samples are obtained by a flux method at 553 K with Bi2O3 and (NH4)2HPO4 as the starting materials ((I) 1 week and (II) up to 3 weeks of heating).
ChemInform Abstract: Alkylation of Toluene with Methanol on Commercial X Zeolite in Different Alkali Cation Forms.
Authors: ENGELHARDT J. , SZANYI J. , VALYON J. 
Published: May 2016

AbstractThe catalytic alkylation is studied at atmospheric pressure, 698 K, and toluene/MeOH = 5 mol/mol in a fixed bed reactor.
ChemInform Abstract: Methyl 4‐Trimethylsiloxy‐2,4‐pentadienoate. A Novel Diels‐Alder Reactive Diene.
Authors: OREN J. , DEMUTH M. , FUCHS B. 
Published: May 2016

AbstractThe title compound (III), prepared from the oxo ester (I), is used as the diene in cycloaddition reactions with various dienophiles.
ChemInform Abstract: Lead Modified Platinum on Carbon Catalysts for the Selective Oxidation of 2‐Hydroxycarboxylic Acids, and Especially Polyhydroxycarboxylic Acids to Their 2‐Keto Derivatives.
Authors: SMITS P. C. C. , KUSTER B. F. M. , VAN DER WIELE K. , VAN DER BAAN H. 
Published: May 2016

AbstractTreatment of D‐gluconic acid (II) with oxygen at 55°C and pH 8 in the presence of Pt/C leads to predominant oxidation of the primary hydroxyl group, yielding glucaric acid (I) as the main product.
ChemInform Abstract: Reactions of Unsaturated Azides. Part 3. Synthesis, Assignments of Structures, Photolysis, and Thermolysis of 2,3‐Diazido‐1,3‐butadienes.
Authors: BANERT K. 
Published: May 2016

AbstractReaction of the alkynes (I) or (IX) with NaN3 (II) yields the displacement products (III) and the rearranged compounds (IV) or (X) and (XI).
ChemInform Abstract: Stereoselective Synthesis of β‐Amino Alcohols from Optically Active α‐Amino Acids.
Authors: REETZ M. T. , DREWES M. W. , SCHMITZ A. 
Published: May 2016

AbstractThe aldehydes (IV), which are accessible as outlined in the scheme, react with Grignard compounds such as (V) in a highly diastereoselective manner to give amino alcohols such as (VI).
ChemInform Abstract: Synthesis and Carbenic Decomposition of Functionally Substituted Diazoacetic Acid Esters. Part 3. Synthesis of 2‐Aminoethyl Diazoacetates and N‐(2‐Hydroxyethyl)‐N‐alkyldiazoacetamides from 2‐Bromoethyl Diazoacetate and Aliphatic Amines.
Authors: SHAPIRO E. A. , ROMANOVA T. N. , BUNKINA T. A. , DOLGII I. E. , NEFEDOV O. M. 
Published: May 2016

Abstract2‐Bromoethyl diazoacetate (I) reacts with the free secondary amines (II) or the hydrochlorides of the primary amines (V) to give the aminoethyl esters (III) or (VI).
ChemInform Abstract: New Access to Cyclopentane Derivatives. A Radical Chain Reaction.
Authors: WEINGES K. , SIPOS W. 
Published: May 2016

AbstractThe reaction of the ester (V) (obtained starting from the hydroxytetrahydropyrane (I) via the intermediate (III)) with Hg(O‐Ac)2 in the presence of CaO and MeOH (VI) followed by reduction affords a cis‐trans mixture of the cyclopentane derivatives (VII).
ChemInform Abstract: Reactions of Diazoalkanes with Unsaturated Compounds. Part 5. Catalytic Cyclopropanation of Unsaturated Hydrocarbons with Diazoethane.
Authors: TOMILOV YU. V. , BORDAKOV V. G. , LUTSENKO A. I. , KOZHINSKII S. O. , DOLGII I. E. , NEFEDOV O. M. 
Published: May 2016

AbstractReaction of diazoethane (II) with the norbornenes (I), norbornadiene (IV), and styrene (VII) gives the cyclopropanation products (III), (V), (VI), and (VIII).
ChemInform Abstract: Regiocontrolled Cyclization of Acetylenic Ketones. First Example of Selective Desilylation of a Triple Bond in the Presence of a Silyl Enol Ether.
Authors: DROUIN J. , BOAVENTURA M. A. 
Published: May 2016

AbstractCyclization of the 1‐(3‐butyryl)bicyclo(3.3.0)octanone derivatives (I), (Vb), or (VIII) yields the propellanes (II) or (IX) and/or the tricyclic ketones (III) or (VI).
ChemInform Abstract: Synthesis of 3‐(4‐Cyclopentene‐1,3‐dione‐2‐ylidene)‐6‐(diphenylmethylene)cyclohexadienes as Novel p‐Quinodimethanes Stabilized by Antiaromaticity of Cyclopentadienone.
Authors: TODA M. , HATTORI M. , OKADA K. , ODA M. 
Published: May 2016

AbstractThe 2‐diazo‐1,3‐diones (I) are coupled with the ethoxytriphenylmethane (II) in the presence of dirhodium tetraacetate, producing the 2‐substituted dione derivatives (III) ‐ (V).
ChemInform Abstract: Reaction of 3‐Hydroxythiolane and ‐thiolene 1,1‐Dioxides with Carbon Disulfide.
Authors: GAIDAMAKA S. N. , BEZMENOVA T. E. , DUL'NEV P. G. , VARSHAVETS T. N. 
Published: May 2016

AbstractThe hydroxythiolane dioxides (I) react with CS2 (II) in the presence of NaOH to give the thiols (III).
ChemInform Abstract: Heterocycles. Part 10. A Facile Synthesis of 7‐Hydroxy‐6,7‐dihydro‐5H‐ pyrrolo(1,2‐a)imidazole.
Authors: WEINTRAUB P. M. , TIERNAN P. L. , HUFFMAN J. C. 
Published: May 2016

AbstractImidazole (I) react with acrolein (II) to give the addition product (III) which yields the pyrroloimidazole (IVa) on cyclization.
ChemInform Abstract: Polarized Ketene Dithioacetals. Part 54. Reaction of Cinnamoyl and 4‐Phenylbutadienoyl Ketene Dithioacetals with Cyanoacetamide and Synthesis of Novel Substituted 2(1H)‐Pyridones.
Authors: SINGH L. W. , ILA H. , JUNJAPPA H. 
Published: May 2016

AbstractDepending of the nature of the aryl substituents the reaction of the dithioacetals (I) with cyanoacetamide (II) according to A) yields either the pyridones (III) or (IV).
ChemInform Abstract: Reduction of Imines and Enamines with Hydrogen Telluride. An Application to Reductive Alkylation of Amines with Carbonyl Compounds.
Authors: KAMBE N. , INAGAKI T. , MIYOSHI N. , OGAWA A. , SONODA N. 
Published: May 2016

AbstractHydrogen telluride, generated in situ from Al2Te3 and H2O, is used as a reagent in the conversion of the imines (I) and the enamine (III) to the amines (II) or (IV).
ChemInform Abstract: Synthesis and Antibacterial Properties of Amino Acid Derivatives of Oxolinic Acid.
Authors: LEONOVA T. S. , PADEISKAYA E. N. , YASHUNSKII V. G. 
Published: May 2016

AbstractIn order to prepare derivatives of oxolinic acid (Ia), an antibacterial quinolone carboxylic acid with enhanced water solubility, the acid chloride (Ib) is converted to the amides (III) by reaction with the N,O‐bis(trimethylsilyl)amino acids (IIa) or the ethyl ester (IIb).
ChemInform Abstract: Synthesis of Heterocycles Using 5‐Phenylisoxazolium Salts. Part 2. Synthesis and Properties of 2‐Phenacylidenequinazolin‐4‐ones.
Authors: HABER H. , HENNING H.‐G. 
Published: May 2016

AbstractThe preparation of the title compounds (III) and (V) is reported.
ChemInform Abstract: Heterocyclic Systems Containing Bridgehead Nitrogen Atom. Part 56. Synthesis of Thiazolo(3,2‐α)aceperimidin‐3(2H)‐one, a New Heterocyclic System.
Authors: NARAYAN S. , PUJARI H. K. 
Published: May 2016

AbstractThe title system, represented by structure (IVa), is synthesized as shown.
ChemInform Abstract: Novel, Very Strongly Basic, Pentacyclic “Proton Sponges” with Vinamidine Structure.
Authors: SCHWESINGER R. , MISSFELDT M. , PETERS K. , VON SCHNERING H. G. 
Published: May 2016

AbstractReaction of (I) with the diol (II) and subsequent tosylation yields the ditosylate (III), which is converted to the title compound (VII).
ChemInform Abstract: Synthesis and Crystal Structure of Seven‐Membered Sulfur Nitrogen Rings Containing Carbon.
Authors: ROESKY H. W. , BENMOHAMED N. , KELLER K. , KEWELOH N. , NOLTEMEYER M. , SHELDRICK G. M. 
Published: May 2016

AbstractA 1:1 molar mixture of the dichloride (I) and the silyl compounds (IIa) or (IIb) reacts to give the seven‐membered trithiadiaza compounds (IIIa) or (IIIb).
ChemInform Abstract: Gas‐Phase Reaction of Dichlorosilanone and Organochlorosilanes.
Authors: CHERNYSHEV E. A. , MUDROVA N. A. , KRASNOVA T. N. , TARASOVA T. N. , CHERNYSHEV A. E. 
Published: May 2016

AbstractThe chlorosilanes (II) react with dichlorosilanone, generated in situ from the benzyloxysilane (I), to give the siloxanes (III) and (IV).
ChemInform Abstract: Anodic Oxidation of Triphenylphosphine in the Presence of Allylic Silanes. A Facile Electrochemical Preparation of Allyltriphenylphosphonium Tetrafluoroborates.
Authors: TAKANAMI T. , SUDA K. , OHMORI H. , MASUI M. 
Published: May 2016

AbstractAnodic oxidation of the allylsilanes (II) in the presence of triphenylphosphine (I) gives the allylic phosphonium salts (III).
ChemInform Abstract: Organo‐Telluriums. Part 9. Aminotellurinylation of Olefins with Benzenetellurinyl Acetate and Ethyl Carbamate.
Authors: HU N. X. , ASO Y. , OTSUBO T. , OGURA F. 
Published: May 2016

AbstractThe terminal olefins (I) react with the phenyltellurinyl acetates (II) and ethyl carbamate (III) in the presence of boron trifluoride etherate to produce the N‐β‐tellurenylalkyl carbamates (IV) and (V) after reduction with hydrazine.
ChemInform Abstract: f‐Element/Crown Ether Complexes. Part 16. Synthesis, Crystallization and Crystal Structure of (Dy(OH2)8)Cl3·18‐crown‐6·4 H2O.
Authors: ROGERS R. D. 
Published: May 2016

AbstractThe known complex (I) is thermally unstable and when it is allowed to warm up under the original solvent mixture, it redissolves and the title complex (II) is obtained.
ChemInform Abstract: Assessment of the Configurational Stability of Chiral Organo‐Metal Compounds.
Authors: HOFFMANN R. W. , LANZ J. , METTERNICH R. , TARARA G. , HOPPE D. 
Published: May 2016

AbstractThe racemic allenyl‐titanium compound (III), obtained by metalation of the allene (I), reacts with the racemate or the (S)‐(‐)‐form of the aldehyde (IV) to give the products (Va) + (Vb) + (VIa) + (VIb) in the ratios indicated in the scheme.
ChemInform Abstract: Heterocarboxylates of Dichlorobis(cyclopentadienyl)zirconium(IV) and Dichlorobis(cyclopentadienyl)titanium(IV).
Authors: DIXIT S. C. , SHARAN R. , KAPOOR R. N. 
Published: May 2016

AbstractThe reaction of the metallocene dichlorides (I) with the acids (II) and Et3N in the molar ratio 1:1:1 yields the compounds (III).
ChemInform Abstract: Mesitylhalogenohydrogermanes.
Authors: RIVIERE P. , RIVIERE‐BAUDET M. , CASTEL A. , SATGE J. , LAVABRE A. 
Published: May 2016

AbstractThe mesitylgermane (I) is chlorinated with NCS to produce a mixture of the chlorogermanes (II) ‐ (IV).
ChemInform Abstract: The Synthesis and Crystal Structures of Triphenyl(1,2,3‐trimethylallyl)tin and Triphenyl(1,1,2‐trimethylallyl)tin.
Authors: VAN ZYL C. M. , MCKEEBY J. L. , VAN DORT P. C. , LARSON E. J. , SILVER M. E. , HUFFMAN J. C. 
Published: May 2016

AbstractIn an attempt to isolate new allylating reagents the two new title compounds (IV) are prepared as shown and their crystal structures determined (both space group P1, Z=2).
ChemInform Abstract: Preparation and Spectral Properties of Copper(II), Iron(II) and Iron(III) Complexes of 1‐(2′‐Hydroxybenzyl)‐2‐(2′‐hydroxyphenyl)benzimidazole.
Authors: PRABHAKAR L. D. , PRAKASH K. M. M. S. , CHOWDARY M. C. 
Published: May 2016

AbstractAll the complexes are prepared by refluxing methanolic solutions of the appropriate metal salts and the ligand (Cu: 3h, Fe: 6h).