bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: New Aspects in the Synthesis of Mono‐ and Dialkylfurans.
Authors: BOCK I. , BORNOWSKI H. , RANFT A. , THEIS H. 
Published: May 2016

AbstractAlkylations of the bromofuran (I) afford derivatives such as (IIIa)‐(IIIc); (IIIb) is further converted to ursinanolide (V).
ChemInform Abstract: A Convenient One‐Pot Entry into Novel 2‐Substituted‐6,7‐dihydro‐4H‐pyrimido(2,1‐a)isoquinolin‐4‐ones.
Authors: LAL B. , D'SA A. S. , KULKARNI B. K. , DE SOUZA N. J. 
Published: May 2016

AbstractThe reaction of the ureas (I) with malonic acid (II) does not lead to the expected pyrimido(6,1‐a)isoquinoline derivatives.
ChemInform Abstract: 2,2′‐(5,8‐Dihydroquinoxaline‐5,8‐diylidene)bis(1,3‐benzodithiole)s. A New Type of Electron Donors.
Authors: YAMASHITA Y. , SUZUKI T. , MIYASHI T. 
Published: May 2016

AbstractThe quinoxalinediones (I) react with cyclopentadiene (II) to give the Diels‐Alder adducts (III) which are coupled with the phosphonate (IV) to form the fulvalene‐like compounds (V).
ChemInform Abstract: Structure of a Non‐Classically Bridged Methyleneborane in the Crystal.
Authors: WIECZOREK C. , ALLWOHN J. , SCHMIDT‐LUKASCH G. , HUNOLD R. , MASSA W. , BERNDT A. 
Published: May 2016

AbstractThe crystalline methyleneboranes (II) are obtained from (I) and Mg.
ChemInform Abstract: (PhLiNCH2CH2NLiPh)·3 HMPA, a Monomeric Dilithiumethylenediamide Complex with N2Li2 Double Bridging: Synthesis, Crystal Structure, and Model MO Calculations.
Authors: ARMSTRONG D. R. , BARR D. , BROOKER A. T. , CLEGG W. , GREGORY K. , HODGSON S. M. , SNAITH R. , WRIGHT D. S. 
Published: May 2016

AbstractThe monomeric structure of the title complex (IV) (space group P21/n, Z=4) is confirmed by X‐ray analysis.
ChemInform Abstract: The Lewis Acidity of Organylbismuth(III) Compounds. New Organylbismuth(III) Dithiocarbamate Chemistry. The Crystal and Molecular Structure of Bis(diethyldithiocarbamato)phenylbismuth(III) and Bis(diethyldithiocarbamato)(2‐(2′‐pyridyl)phenyl)bismuth(III).
Authors: ALI M. , MCWHINNIE W. R. , WEST A. A. , HAMOR T. A. 
Published: May 2016

AbstractThe Lewis acidity of (III) is investigated by study of the reactions with (IV), Na propionate and (VI).
ChemInform Abstract: Base‐Induced Alkyne Cleavage in W(II) Complexes ‐ A New Way to Low‐Valent Carbyne Complexes from W(CO)6.
Authors: FILIPPOU A. C. , VOELKL C. + , GRUENLEITNER W. + , KIPROF P. 
Published: May 2016

AbstractA new entry to low‐valent, CO‐free W phenylcarbyne complexes such as (X) is developed from fac‐tris(acetonitrile)tricarbonyl‐W (I) via W(II) alkyne complexes according to the scheme.
ChemInform Abstract: A Novel Monooxoruthenium(V) Complex Containing a Polydentate Pyridyl Amine Ligand. Syntheses, Reactivities and X‐Ray Crystal Structure of (RuIII(N4O)(H2O))(ClO4)2.
Authors: CHE C.‐M. , YAM V. W.‐W. , MAK T. C. W. 
Published: May 2016

AbstractFor (V) and its precursor compound (IV) (P2/c, Z=4) the magnetic susceptibilities are determined.
ChemInform Abstract: Isostructural η2‐Dihydrogen Complexes (Os(NH3)5(H2))n+ (n = 2, 3) and the Hydrogenation of Acetone.
Authors: HARMAN W. D. , TAUBE H. 
Published: May 2016

AbstractThe reduction of the Os(III) complex (I) in methanol or aqueous solution affords the dihydrogen complex (II).
ChemInform Abstract: UW4C4, a Distorted Structure Derived from UCr4C4 and the Ternary U‐W‐C System.
Authors: BEHRENS R. K. , JEITSCHKO W. 
Published: May 2016

AbstractUW4C4, prepared by reaction of the elements at 900 °C, crystallizes in the space group P4/m with Z=2.
ChemInform Abstract: Oxygen‐Sensing Properties of Spinel‐Type Oxides for Stoichiometric Air/Fuel Combustion Control.
Authors: SHIMIZU Y. , KUSANO S. , KUWAYAMA H. , TANAKA K. , EGASHIRA M. 
Published: May 2016

AbstractThe temp. dependence of the electrical resistance of the spinel‐type oxides MCr2O4 and MFe2O4 (M: Mg, Zn, Ni) is measured in air/MeOH combustion gases in order to investigate the potential of these oxides as air/fuel stoichiometric oxygen sensors.
ChemInform Abstract: Synthesis of ZSM‐20. Comparison of Properties with Zeolite Y.
Authors: DWYER J. , MILLWARD D. , O'MALLEY P. J. , ARAYA A. , CORMA A. , FORNES V. , MARTINEZ A. 
Published: May 2016

AbstractHighly crystalline samples of ZSM‐20 are obtained by crystallization of a gel prepared by addition of tetraethylorthosilicate to a solution containing sodium aluminate and Et4NOH.
ChemInform Abstract: Acyclic Stereoselection. Part 46. Stereochemistry of the Michael Addition of N,N‐Disubstituted Amide and Thioamide Enolates to α,β‐Unsaturated Ketones.
Authors: OARE D. A. , HENDERSON M. A. , SANNER M. A. , HEATHCOCK C. H. 
Published: May 2016

AbstractVarious substituted amides, e.g. (I) and (V), or thioamides such as (VIII) are converted to lithium enolates and then coupled with enones such as (II) or (IX) to give 1,2‐ and/or 1,4‐adducts depending on the reaction conditions.
ChemInform Abstract: Double H‐Bridged and Single H‐Bridged Diboryl Radicals.
Authors: TRACHTMAN M. , BOCK C. W. , NIKI H. , MAINS G. J. 
Published: May 2016

AbstractUsing ab initio MO calculations with the 6‐31G* basis set the structures of the radicals B2H· 5, B2H5CO· and B2H5N· 2 are investigated.
ChemInform Abstract: New Method for the Selective Reduction of Amides.
Authors: TSAY S.‐C. , ROBL J. A. , HWU J. R. 
Published: May 2016

AbstractA new procedure for the reduction of tert.‐aliphatic, olefinic and aromatic amides such as (I) to aldehydes (III) in the presence of L‐Selectride is described.
ChemInform Abstract: Stereoselective Partial Hydrogenation of the Triple Bond in Methyl 2‐Ethyl‐6,6‐dimethylhept‐2‐en‐4‐ynoate: A Comparison of Lindlar and Montmorillonite Catalysts.
Authors: NIKLES M. , BUR D. , SEQUIN U. 
Published: May 2016

AbstractHydrogenations of the triple bond in (I) are carried out using Lindlar and montmorillonite catalysts in various solvents.
ChemInform Abstract: Photochlorination of Simple Alkanes in Cryogenic Solids.
Authors: WIGHT C. A. , KLIGMANN P. M. , BOTCHER T. R. , SEDLACEK A. J. 
Published: May 2016

AbstractPhotochemical reactions are induced by laser photolysis of amorphous binary solids composed of Cl2 mixed with propane, butane, isobutane, pentane, cyclopentane, hexane, or cyclohexane at 10‐150 K. In each case, the laser dissociates Cl2 into Cl· which reacts with the alkane to form HCl and the corresponding chloroalkane.
ChemInform Abstract: Aromatic Substitution. Part 57. Nitration of Phenylboron Dichloride with Nitronium Tetrafluoroborate. Attempted Nitration of Iodobenzene Dichloride and Phenylphosphorus Dichloride.
Authors: OLAH G. A. , PITEAU M. , LAALI K. , RAO C. B. , FAROOQ O. 
Published: May 2016

AbstractPhenylboronic dichloride (I) is treated with nitryl tetrafluoroborate (II) or N‐nitro‐2,4,6‐collidinium tetrafluoroborate (VI) under various conditions to give the nitrophenylboronic dichlorides (III) ‐ (V).
ChemInform Abstract: “Mixed Staffanes” as Intermediate‐Length Staffs for Molecular‐Size Tinkertoys. Parent Hydrocarbons and Terminal Diiodides Combining Bicyclo‐(1.1.1)pentane with Cubane or Bicyclo(2.2.2)octane Units.
Authors: HASSENRUECK K. + , MURTHY G. S. , LYNCH V. M. , MICHL J. 
Published: May 2016

AbstractIrradiation of the tertiary diiodides (II) in the presence of an excess of the propellane (I) results in the predominant formation of the mono‐(III) or bisadducts (IV) depending on the irradiation time.
ChemInform Abstract: Benzylic Oxidation by the GifIV System.
Authors: BARTON D. H. R. , HALLEY F. , OZBALIK N. , MEHL W. 
Published: May 2016

AbstractWhereas the oxidation of benzene (I) under Gif conditions forms only traces of phenol (II) ‐ trapped as the tribromo derivative (III) ‐ the phenylmethanes (IV) produce the phenyl ketones (V).
ChemInform Abstract: Stereoselective Synthesis of Pipecolic Acid Derivatives Using Aza Diels‐Alder Reactions.
Authors: BAILEY P. D. , WILSON R. D. , BROWN G. R. 
Published: May 2016

AbstractThe iminium salt (III), prepared from ethyl glyoxalate (II) and benzylamine hydrochloride (I), reacts with the cyclic dienes (IV) to form the cycloadducts (V).
ChemInform Abstract: A trans‐Folded Alkene System: Synthesis, Structure and Isomerization of 2,2′‐Diaryl‐1,1′‐bi(1,2‐dihydrophthalazinylidenes).
Authors: BUTLER R. N. , GILLAN A. M. , LYSAGHT F. A. , MCARDLE P. , CUNNINGHAM D. 
Published: May 2016

AbstractThe title compounds (II) formed by dimerization of the phthalazinols (I), are present in the trans‐form in the crystalline state.
ChemInform Abstract: Structure and Reactions of 6‐Oxo‐1,2,4‐triazines.
Authors: EID M. M. , ABDEL‐HADY S. A. , ALI H. A. W. 
Published: May 2016

AbstractCyclization of the α‐(benzoylamino)cinnamic hydrazides (I) under alkaline conditions leads to the formation of the triazinones (II) which are converted to the tetrazolotriazines (VII) and (IX) via the triazinethiones (III) and the hydrazinotriazines (V) as shown in the reaction scheme.
ChemInform Abstract: Synthesis of Organotin Complexes with Ligands of Biological Significance.
Authors: LEE F. L. , GABE E. G. , KHOO L. E. , ENG G. , SMITH F. E. 
Published: May 2016

AbstractRegardless of the proportions of the ligand and triphenyltin chloride used, the new yellow, thermally stable 1:1 complexes (I) are formed (no yields given).
ChemInform Abstract: Derivatives of Tetrathiometallates. Synthesis of (MS4M′(bpy)2) (M: Mo, W; M′: Co, Ni, Mn, Ru) Complexes. Structural Characterization of (Ni(bpy)3)((WS4)2Pd).
Authors: POTVIN C. , MANOLI J.‐M. , SECHERESSE F. 
Published: May 2016

AbstractReaction of dichloro‐bis(2,2'‐bipyridyl)metal complexes e.g. (I), (IV), and (VIII) with tetrathiotungstates or ‐molybdates affords complexes of the type (III) ((IIIa): space group P21/n, Z=4).
ChemInform Abstract: Preparation and Structural Characterization of Rhodium and Palladium Complexes of Mixed Phosphine/Amine Ligands with Methylene Spacers Between Donor Atoms.
Authors: BALCH A. L. , OLMSTEAD M. M. , ROWLEY S. P. 
Published: May 2016

AbstractThe diphenylaminomethyl‐substituted monophosphanes (I) and (VI) and the diphenylphosphinomethylamines (VII) and (VIII) (yield 72/93%) are prepared by condensation of paraformaldehyde (IV) with corresponding phenylamines and phenylphosphanes.
ChemInform Abstract: Simple Synthesis of cis‐4‐Hydroxy‐L‐proline and Derivatives Suitable for Use as Intermediates in Peptide Synthesis.
Authors: PAPAIOANNOU D. , STAVROPOULOS G. , KARAGIANNIS K. , FRANCIS G. W. , BREKKE T. , AKSNES D. W. 
Published: May 2016

AbstractPeptides with improved biological activities are obtained when L‐proline is substituted by cis‐4‐hydroxy‐L‐proline.
ChemInform Abstract: Photocyclization of Enamides. Part 29. Dehydrogenation with Benzeneseleninic Anhydride in the Total Synthesis of Ergot Alkaloids.
Authors: NINOMIYA I. , HASHIMOTO C. , KIGUCHI T. , NAITO T. , BARTON D. H. R. , LUSINCHI X. , MILLIET P. 
Published: May 2016

AbstractThe efficiency of the dehydrogenation of indolines such as (I) by treatment with the title reagent is markedly improved on addition of indole as a scavenger for trapping an intermediate Se(II) species (yield of (IIa) in the absence of indole: 57%).
ChemInform Abstract: A New Way for Preparing Superconducting Materials: The Electrochemical Oxidation of La2CuO4.
Authors: WATTIAUX A. , PARK J.‐C. , GRENIER J.‐C. , POUCHARD M. 
Published: May 2016

AbstractPolarization of La2CuO4 in 1 N KOH at 900 mV (66 h) yields a metallic material which exhibits a superconducting transition around 47 K. The room temp. resistivity of this material is strongly decreased which is explained by the mixed valency of Cu resulting from the electrochemical treatment.
ChemInform Abstract: Preparation of High‐Surface‐Area Transition‐Metal Nitrides: Mo2N and MoN.
Authors: JAGGERS C. H. , MICHAELS J. N. , STACY A. M. 
Published: May 2016

AbstractThe reactions of ammonia with MoO3 (I), (NH4)6Mo7O24·4 H2O (II), (NH4)2MoO4 (III), and HxMoO3 (IV) to produce MoN and Mo2N are studied by TGA, in situ XRD, and surface area measurements as a function of reaction temperature.
ChemInform Abstract: The Reactions of α‐Oxodithioester S‐Methylides.
Authors: MORAN J. R. , TAPIA I. , ALCAZAR V. 
Published: May 2016

Abstractα‐Oxodithioesters of type (I) or (VI) react with CH2N2 (II) to give thiadiazolines which form thiocarbonyl ylides after N2 extrusion.
ChemInform Abstract: Cyclocondensation of 2‐Methylbenzimidazole with Acetylacetone.
Authors: POPOV I. I. 
Published: May 2016

AbstractZnCl2‐catalyzed reaction of 2‐methylbenzimidazole (I) with acetylacetone (II) gives the pyridobenzimidazole (III).
ChemInform Abstract: Studies on Fused Pyrimidine Derivatives. Part 6. Characterization of a Perhydro‐5,6‐di(methylene)‐2,4‐dioxopyrimidine Intermediate and Its Cycloaddition Reactions Leading to Quinazoline Derivatives.
Authors: NOGUCHI M. , DOI K. , KIRIKI Y. , KAJIGAESHI S. 
Published: May 2016

AbstractThe dioxopyrimidinecarbaldehyde hydrazone (I) reacts with N‐methylmaleimide (II) to form the cycloadducts (III).
ChemInform Abstract: Synthetic Methods and Reactions. Part 145. Improved Direct Preparation of O‐Trimethylsilyl Monothioacetals from Thiols and Carbonyl Compounds.
Authors: SASSAMAN M. B. , PRAKASH G. K. S. , OLAH G. A. 
Published: May 2016

AbstractThe reaction of the thiols (I) and 1‐(trimethylsilyl)imidazole (II) with the carbonyl compounds (III) using trimethylsilyl triflate as the catalyst produces the acetals (IV).
ChemInform Abstract: A New Route to Alkoxysilanes and Alkoxysiloxanes of Use for the Preparation of Ceramics by the Sol‐Gel Technique.
Authors: GOODWIN G. B. , KENNEY M. E. 
Published: May 2016

AbstractThe alkoxysilane (III) and the alkoxysiloxanes (V), (VIII), (X), (XII) and (XIII) are prepared as shown.
ChemInform Abstract: Additions of Alkylidene Groups Between Co and S in the Reactions of Dithiolatocobalt Complexes with Diazo Compounds.
Authors: KAJITANI M. , SAKURADA M. , DOHKI K. , SUETSUGU T. , AKIYAMA T. , SUGIMORI A. 
Published: May 2016

AbstractReaction of the dithiolato cobalt(III) complexes (I) with the diazo compounds (II) results in the formation of the bicyclic cobalt complexes (III).
ChemInform Abstract: Exchange Interaction in Multinuclear Transition‐Metal Complexes. Part 14. Exchange Interactions in a Novel Copper(II) Linear‐Chain Compound with Ladderlike Structure: Cu2(1,4‐diazacycloheptane)2Cl4.
Authors: CHIARI B. , PIOVESANA O. , TARANTELLI T. , ZANAZZI P. F. 
Published: May 2016

AbstractX‐Ray structure analysis of the dimeric title compound (III) (space group P21/c, Z=4) confirms that the dimer is connected with neighboring dimers by Cu‐Cl····H‐N‐Cu hydrogen bonding interactions into infinite ladderlike chains.
ChemInform Abstract: The Preparation and Characterization of Pt(Se3PPh)(PR3)2; the X‐Ray Crystal Structure of Pt(Se3PPh)(dppe)·CH2Cl2.
Authors: PARKIN I. P. , PILKINGTON M. J. , SLAWIN A. M. Z. , WILLIAMS D. J. , WOOLLINS J. D. 
Published: May 2016

AbstractThe title compounds (III), the first examples of molecules containing a PtSe2P ring, are prepared by the reaction of the selenium analogue of Lawessons reagent with cis‐dichloroplatinum compounds.
ChemInform Abstract: Sterically Hindered Oxadiazoles as Potential Fluorescent Dopants for Polymeric Scintillators.
Authors: FEYGELMAN V. M. , WALKER J. K. , KATRITZKY A. R. , DEGA‐SZAFRAN Z. 
Published: May 2016

AbstractThe oxadiazoles (I) are obtained by cyclization of the appropriate benzoyl hydrazide in the presence of POCl3.
ChemInform Abstract: Collision‐Induced Elimination of Alkenes from Deprotonated Unsaturated Ethers in the Gas Phase. Reactions Involving Specific β‐Proton Transfer.
Authors: WAUGH R. J. , HAYES R. N. , EICHINGER P. C. H. , DOWNARD K. M. , BOWIE J. H. 
Published: May 2016

AbstractUnsaturated ethers of type (I) deprotonate in the gas phase to form carbanions (II) which, when n = 1 and 2 and R: ‐Et or higher alkyl, undergo predominantly β‐proton transfer to form the E1cB intermediates CH2=CH‐CH2‐(CH2)n‐O‐CH2‐CH2‐, which eliminate ethene to yield the alkoxide CH2=CH‐CH2‐(CH2)n‐O‐.
ChemInform Abstract: Exclusive Ortho Cyanation and Alkylthiocarbonylation of Anilines and Phenols Using Boron Trichloride.
Authors: ADACHI M. , SUGASAWA T. 
Published: May 2016

AbstractThe anilines (I) are coupled with trichloroacetonitrile (II) in the presence of boron trichloride and, eventually, other Lewis acids to give the o‐aminobenzonitriles (III) after alkaline work‐up.
ChemInform Abstract: Preparation of β‐Keto Ester Acetals by Reaction of Ortho Esters with Ketene Silyl Acetals in the Presence of Titanium Tetrachloride.
Authors: COLLINS D. J. , CHOO G. L. P. , OBRIST H. 
Published: May 2016

Abstractβ‐Keto ester acetals such as (III) and (V) are readily available in the presence of TiCl4.
ChemInform Abstract: Lactones. Part 22. Synthesis and Reduction of α‐Aminomethylene‐δ,δ‐diphenyl‐δ‐valerolactones.
Authors: LEHMANN J. , NEUGEBAUER M. , MARQUARDT N. 
Published: May 2016

AbstractConsecutive reaction of the δ‐lactone (I) with ethyl formate (IV)/sodium hydride and piperidine (V) leads to the formation of the 3‐piperidinomethylenetetrahydro‐2(2H)‐pyranone (IIIb).
ChemInform Abstract: Synthesis of Some Substituted Pyrimidinyloximes of Aryl Methyl Ketones and Their Reactions with Nucleophilic Agents.
Authors: DANAGULYAN G. G. , BALASANYAN N. G. , TERENT'EV P. B. , ZALINYAN M. G. 
Published: May 2016

AbstractThe acetophenone oximes (I) are coupled with the 2‐chloropyrimidine (II) to give the 2‐pyrimidinyloximes (III).
ChemInform Abstract: A New Synthesis of 1,2,4‐Triazino(6,1‐b)quinazoline‐4,10‐diones.
Authors: REDDY P. S. N. , REDDY V. G. 
Published: May 2016

AbstractThe aminooxoquinazolinecarboxylate (I) is treated with ammonia (II), the alkylamines (VI), or hydrazine hydrate (IV) to yield the amides (III) or (VII) and the hydrazide (V) respectively.
ChemInform Abstract: Synthesis and Antiesterase Activity of O,O‐Dialkyl S‐Ethoxycarbonylchloromethyl Thiophosphates.
Authors: KHASKIN B. A. , MAKHAEVA G. F. , TORGASHEVA N. A. , ISHMURATOV A. S. , YANKOVSKAYA V. L. , FETISOV V. I. , MALYGIN V. V. , MARTYNOV I. V. 
Published: May 2016

AbstractThe title compounds (III), prepared by reaction of the phosphorylsulfenyl chlorides (I) with ethyl diazoacetate (II), inhibit carboxyl esterase, acetylcholine esterase, and butyrylcholine esterase.
ChemInform Abstract: Preparation, Properties, and Reactions with Sulfur Dioxide of Triphenylphosphine Oxide Complexes of Manganese(II) Thiocyanate. Crystal Structures of ((Mn(OPPh3)2(NCS)(μ‐NCS))2), (Mn(OPPh3)4(NCS)2), and (PPh3O)(PPh3OH)(HSO4), a Derivative of Sulfuric Acid Formed Under Ambient Air Oxidation of Sulfur Dioxide.
Authors: AL‐FARHAN K. , BEAGLEY B. , EL‐SAYRAFI O. , GOTT G. A. , MCAULIFFE C. A. , MAC RORY P. P. , PRITCHARD R. G. 
Published: May 2016

AbstractAnhydrous Mn(II) thiocyanate reacts with triphenylphosphine oxide in toluene in appropriate molar ratio to give the complex series Mn(O=PPh3)n(NCS)2 (n = 1‐4).
ChemInform Abstract: Pyrrolophenanthridines. Part 3. A Novel Synthesis of 1H‐Pyrrolo(2,3‐c)phenanthridine.
Authors: BABERKINA E. P. , AKHVLEDIANI R. N. , BUYANOV V. N. , SAMOILOVA M. E. , LEVINA I. I. , SUVOROV N. N. 
Published: May 2016

AbstractThe title compound (VI) is synthesized.
ChemInform Abstract: Enantiomerically Pure Indoloquinolizines from Tryptophane.
Authors: PENG S. , WINTERFELDT E. 
Published: May 2016

AbstractThe title compounds (VI) are synthesized via Pictet‐Spengler reaction of the tryptophane derivative (I) with the aldehyde (II) followed by addition of the ketone (III).
ChemInform Abstract: Two New Cobalt(II) Compounds Exhibiting Weak Ferromagnetism: Magnetic Susceptibility Study of CoHPO3·H2O (I) and CoCl(H2PO2)·H2O (II) and Crystal Structure of CoHPO3·H2O.
Authors: SAPINA F. , GOMEZ‐ROMERO P. , MARCOS M. D. , AMOROS P. , IBANEZ R. , BELTRAN D. , NAVARRO R. , RILLO C. , LERA F. 
Published: May 2016

AbstractThe title compound (I) crystallizes in the orthorhombic space group Pca21 with Z=4.
ChemInform Abstract: Asymmetric Synthesis of Both Enantiomers of 2‐Trifluoromethyl‐4‐aminobutyric Acid.
Authors: YAMAZAKI T. , OHNOGI T. , KITAZUME T. 
Published: May 2016

AbstractBoth enantiomers of the title compound (V) are prepared by enzymatic hydrolysis of the nitrobutyrate (III).
ChemInform Abstract: A Practical Method for Resolution of the Optical Isomers of 2,2′‐Dihydroxy‐1,1′‐binaphthalene.
Authors: TAMAI Y. , PARK H.‐C. , IIZUKA K. , OKAMURA A. , MIYANO S. 
Published: May 2016

AbstractUsing the (R)‐(‐)‐2‐aminobutanol (II) as the chiral auxiliary , the racemic mixture of the phosphate (I) is converted to a diastereomeric mixture of the salts (III) and (IV).
ChemInform Abstract: Heterocyclisations Induced by Thallium(III) Acetate. Effect of Varying the Internal Nucleophile.
Authors: MICHAEL J. P. , NKWELO M. M. 
Published: May 2016

AbstractTreatment of the hex‐4‐en‐1‐ol (I) with Tl(OAc)3 in acidic aqueous acetone affords the trans‐2,5‐disubstituted tetrahydrofuran (II).
ChemInform Abstract: Pentaalkylguanidines as Etherification and Esterification Catalysts.
Authors: BARCELO G. , GRENOUILLAT D. , SENET J.‐P. , SENNYEY G. 
Published: May 2016

AbstractThe catalytic activity of a series of pentaalkylsubstituted guanidines is investigated in model reactions and compared to the activity of DMAP, the commonly used catalyst in such reactions.
ChemInform Abstract: The Synthesis of Benzofuroquinolines. Part 6. A New Synthesis of Benzofuro(2,3‐c)quinoline Derivatives.
Authors: YAMAGUCHI S. , OH‐HIRA Y. , YAMADA M. , MICHITANI H. , KAWASE Y. 
Published: May 2016

AbstractThe title compounds (III) and (V) can be prepared as shown.
ChemInform Abstract: Synthesis of 11‐Phenyl‐2,3,4,5‐tetrahydro‐1H‐(1,4)diazepino(1,2‐a)indoles and 1‐(3‐Aminopropyl)‐2‐hydroxymethyl‐3‐phenylindoles as 5‐Hydroxytryptamine Antagonists.
Authors: RAJUR S. B. , MERWADE A. Y. , BASANAGOUDAR L. D. 
Published: May 2016

AbstractTreatment of the phenylindoles (I) with acrylonitrile (II) produces the 2‐cyanoethyl derivatives (III) as the key intermediates for the synthesis of the diazepino(1,2‐a)indoles (VI) mentioned in the title.
ChemInform Abstract: Versatile Precursors for the Synthesis of Enynes and Enediynes.
Authors: MYERS A. G. , ALAUDDIN M. M. , FUHRY M. M. , DRAGOVICH P. S. , FINNEY N. S. , HARRINGTON P. M. 
Published: May 2016

AbstractThe dibromoacrylate (II) is coupled with trimethylsilylacetylene (III) to give the enyne (IV) which reacts with the siloxyalkyne (V), forming the enediyne (VI).
ChemInform Abstract: The Preparation and Characterization of Substituted Pentaphenylcyclopentadienyl Ligands, Their Precursors, and Complexes of Iron.
Authors: FIELD L. D. , HO K. M. , LINDALL C. M. , MASTERS A. F. , WEBB A. G. 
Published: May 2016

AbstractA variety of known and novel tetracyclones such as (I), carbinols (II) and bromides (III) are prepared by the standard procedure of Ziegler and Schnell.
ChemInform Abstract: 9,10‐Phenanthrenocyaninatoiron(II) (PhcFe) and Axially Coordinated Isocyanide Complexes.
Authors: HANACK M. , RENZ G. 
Published: May 2016

AbstractThe reaction of the title complex (V) with 1,4‐diisocyanobenzene in CHCl3 yields a bridged complex (60‐80% yield).
ChemInform Abstract: Synthesis, Characterization, and X‐Ray Crystal Structure of (Ru(NO2)(PMe3)2(trpy))(ClO4).
Authors: LEISING R. A. , KUBOW S. A. , CHURCHILL M. R. , BUTTREY L. A. , ZILLER J. W. , TAKEUCHI K. J. 
Published: May 2016

AbstractThe title complex (IX), prepared in a five‐step synthesis with a total overall yield of 27%, crystallizes in P21/c with Z=4.
ChemInform Abstract: Synthetic Design of a Multielectron Series of Homologous Dirhodium Fluorophosphines Possessing an Emissive dσ* Excited State.
Authors: DULEBOHN J. I. , WARD D. L. , NOCERA D. G. 
Published: May 2016

AbstractThe dimer (I) reacts with the amine (II) to yield the Rh(0)/Rh(II) complex (III) (space group P212121, Z=4) and under reducing and oxidizing conditions to yield the Rh(0)/Rh(0) complex (IV) (P1, Z=2) and Rh(II)/Rh(II) complex (V) (C2/c, Z=4), respectively.
ChemInform Abstract: Chloropalladation of 1‐Aryl‐ω‐methylenenebicyclo(n.1.0)alkanes.
Authors: DONALDSON W. A. , NORTH J. T. , GRUETZMACHER J. A. , FINLEY M. , STEPUSZEK D. J. 
Published: May 2016

AbstractThe title reaction shown for (I), (VIII) and (XI), and carried out for 6 other examples of type (Ib), proceeds via cleavage of the C(2)‐C(3) bond of cyclopropane, a mechanism is discussed.