bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Influence of High Concentrations of Fluoride on the Electrosynthesis of Peroxodisulfates at β‐PbO2 Anodes.
Authors: SCHELER I. , WABNER D. W. 
Published: May 2016

AbstractAs already observed by other authors, addition of high amounts of F‐ increases the current efficiency of S2O82‐ during electrolysis in H2SO4/(NH4)2SO4 solutions at β‐PbO2 anodes.
ChemInform Abstract: The Effect of Phosphoric Acid on Rust Studied by Moessbauer Spectroscopy.
Authors: NIGAM A. N. , TRIPATHI R. P. , DHOOT K. 
Published: May 2016

AbstractThe influence of H3PO4 on the corrosion products of mild steel samples corroded in different media (brackish water, and aqueous solutions of NaCl, LiCl, NH4NO3) is studied systematically.
ChemInform Abstract: The Kinetics of Aluminum‐7075 Corrosion by Uranium Hexafluoride
Authors: SANIGER J. M. , ALBA F. , GARRIDO S. J. , AVENDANO E. 
Published: May 2016

Abstractare studied in the temp. range 20‐200 °C. A protective film grows in the temp. range 20‐140 °C. At these temp., the growth of the corrosion film is controlled by the transport of ions through the pores of the film.
ChemInform Abstract: Conformation of (Z)‐3‐Carboxymethyl‐((2E)‐2‐methyl‐3‐phenylpropenylidene)rhodanine (Epalrestat) (I), a Potent Aldose Reductase Inhibitor: X‐Ray Crystallographic, Energy Calculational, and NMR Studies.
Authors: ISHIDA T. , IN Y. , INOUE M. , TANAKA C. , HAMANAKA N. 
Published: May 2016

AbstractIn order to study the key atoms and their spatial disposition necessary for high aldose reductase inhibitory activity, the space group for the title compound (I) (P1, Z=2) is determined.
ChemInform Abstract: Aluminirene (HAlC2H2) and Aluminirane (HAlC2H4): Aluminum‐Substituted Counterparts of Cyclopropene and Cyclopropane.
Authors: XIE Y. , SCHAEFER H. F. III 
Published: May 2016

AbstractTheoretical molecular structures, energetics and vibrational frequencies of all isomers of hydrogenated aluminum‐acetylene and hydrogenated aluminum‐ethylene systems are predicted by ab initio quantum mechanical methods.
ChemInform Abstract: Amino Acid Esters as Chiral Auxiliaries in Lewis Acid Catalyzed Diels‐Alder Reactions.
Authors: WALDMANN H. 
Published: May 2016

AbstractThe asym. Diels‐Alder reaction between various dienes such as (I) and unsaturated N‐acyl‐(S)‐proline esters such as (II) or (V) is investigated.
ChemInform Abstract: Thermal Diels‐Alder Reactions with N‐(2‐Alkenoyl)‐(S)‐proline Esters as Chiral Dienophiles Using Organic and Aqueous Reaction Media.
Authors: WALDMANN H. , DRAEGER M. + 
Published: May 2016

AbstractThe asym. Diels‐Alder reaction of cyclopentadiene with N‐acryloyl‐(S)‐proline benzyl ester or N,N'‐fumaroyl‐bis(proline ester) (see preceding abstract) which is reported to proceed with high stereoselection in the presence of a Lewis catalyst, can also be carried out without a catalyst using an aqueous solvent.
ChemInform Abstract: Extremely High Rate Accelerations in Aldol Reactions of α‐Alkoxy Ketones: Reactivity Governed by Substituent Field Effects.
Authors: DAS G. , THORNTON E. R. 
Published: May 2016

AbstractVery large accelerations are discovered in aldol reactions of α‐substituted ketones, e.g. (I), with the Li enolate (III) of pinacolone (relative reactivities are tabulated).
ChemInform Abstract: Linearly Fused vs Bridged Regioselection in the Intramolecular 1,3‐Diyl Trapping Reaction.
Authors: MASJEDIZADEH M. R. , DANNECKER‐DOERIG I. , LITTLE R. D. 
Published: May 2016

AbstractThe isobutenol (I) is coupled with the 1‐bromo‐3‐siloxypropane (II) to produce the hexanediol derivative (III).
ChemInform Abstract: Kinetics of Reactions Between Methyl and Acetyl Radicals in Gas Phase Produced by Flash Photolysis of Acetic Anhydride.
Authors: HASSINEN E. , KALLIORINNE K. , KOSKIKALLIO J. 
Published: May 2016

AbstractThe flash photolysis of (I) leads to 52% photodissociation and to 48% intramolecular hydrogen transfer to give (IV)‐(VIII).
ChemInform Abstract: Copper(I)‐ and Copper(II)‐Mediated Two‐Electron Oxidations of Benzylic Alcohols and Diarylacetic Acids by Trimethylamine N‐Oxide.
Authors: CAPDEVIELLE P. , SPARFEL D. , BARANNE‐LAFONT J. , CUONG N. K. , MAUMY M. 
Published: May 2016

AbstractThe copper(I) alkoxides, prepared by reaction of the sodium alkoxides (I) or (III) with copper(I) chloride, are oxidized with excess trimethylamine N‐oxide, producing the ketones (II) or the salicylaldehydes (IV).
ChemInform Abstract: Mechanism of Photoreduction of Diethyl Benzylidene Malonates by NAD(P)H Model and Comparison with Thermal Reaction.
Authors: DENG G. , XU H.‐J. , CHEN D.‐W. 
Published: May 2016

AbstractIn a deuterated solvent the photoreduction of title compounds such as (I) leads to β‐deuterated main products (cf.
ChemInform Abstract: The Reduction of Nitrile with 2‐Propanol Over Hydrous Zirconium Oxide.
Authors: TAKAHASHI K. , SHIBAGAKI M. , MATSUSHITA H. 
Published: May 2016

AbstractUsing hydrous zirconium oxide as the catalyst, vapor‐phase reduction of nitriles with 2‐propanol proceeds to give the corresponding alcohols as the main products.
ChemInform Abstract: Regioselectivity of the Amination of Some Nitroisoquinolines by Liquid Ammonia/Potassium Permanganate.
Authors: WOZNIAK M. , BARANSKI A. , NOWAK K. , PORADOWSKA H. 
Published: May 2016

AbstractAmination of the 5‐nitroisoquinolines (I) by liquid NH3 (II) in the presence of KMnO4 proceeds with high regioselectivity to afford the 6‐amino derivatives (III).
ChemInform Abstract: An Improved Method for Reductive Alkylation of Amines Using Titanium(IV) Isopropoxide and Sodium Cyanoborohydride.
Authors: MATTSON R. J. , PHAM K. M. , LEUCK D. J. , COWEN K. A. 
Published: May 2016

AbstractAmines such as (I) are coupled with cyclic ketones such as (II) in the presence of titanium isopropoxide.
ChemInform Abstract: Enzyme‐Catalyzed Interesterification Procedure for the Preparation of Esters of a Chiral Secondary Alcohol in High Enantiomeric Purity.
Authors: MACFARLANE E. L. A. , ROBERTS S. M. , TURNER N. J. 
Published: May 2016

AbstractEnzyme‐catalyzed hydrolysis of the racemic acetoxybicyclo(3.2.0)heptene (±)‐(I) yields the (6R)‐alcohol (+)‐(II) with moderate enantiomeric excess.
ChemInform Abstract: Nucleophilic Attack at Heterocyclic Nitrogen: Unusual Reactivity of the Benzotriazole Heterocyclic Ring.
Authors: KATRITZKY A. R. , RACHWAL S. , OFFERMAN R. J. , NAJZAREK Z. , YAGOUB A. K. , ZHANG Y. 
Published: May 2016

AbstractGrignard reagents attack 1‐imidoylbenzotriazoles (III) at the imidoyl carbon atom and also at the benzotriazolyl N‐2 and N‐3 atoms leading to complex reaction mixtures, the composition of which allows identification of the main reaction paths.
ChemInform Abstract: Claisen Orthoester Rearrangement Reaction with Secondary and Tertiary Allylic Alcohols: Synthesis of 1,2‐Secochrysanthemates and Their Structural Analogues.
Authors: KELKAR S. V. , ARBALE A. A. , JOSHI G. S. , KULKARNI G. H. 
Published: May 2016

AbstractMesityl oxide (I) and citral (IV) are converted to the allylic alcohols (IIa) ‐ (IIc) which are consecutively heated with triethyl orthoacetate (V) and phosphoric acid, performing the rearrangement mentioned in the title to give the γ,δ‐unsaturated carboxylates (VI).
ChemInform Abstract: An Unusual Chemoselectivity in Cobalt(II) Chloride‐Catalyzed Cleavage of Oxiranes with Anilines: A Highly Regioselective Synthesis of β‐Amino Alcohols.
Authors: IQBAL J. , PANDEY A. 
Published: May 2016

AbstractThe oxiranes (I) are cleaved with the amines (II) in the presence of cobalt dichloride to form the vicinal amino alcohols (III).
ChemInform Abstract: Sulfinic Acids and Related Compounds. Part 24. Monothioquinone S,S‐Dioxides and Their Relation to Convergent Syntheses Involving Hydroxyarenesulfonyl Chlorides.
Authors: FIELD L. , LEE C. 
Published: May 2016

AbstractThe hydroxybenzenesulfonyl chlorides (I) react with the p‐methylthiophenol to form the sulfinic acids (II).
ChemInform Abstract: A General Method for the Reductive Carbamation and Sulfonamidation of Aldehydes.
Authors: ALEXANDER M. D. , ANDERSON R. E. , SISKO J. , WEINREB S. M. 
Published: May 2016

AbstractSeven aldehydes such as (I) are treated with the N‐sulfinyl sulfonamide (II) in the presence of triethylsilane and boron trifluoride etherate to produce the sulfonamidation products (III).
ChemInform Abstract: Synthesis, Fungicidal, and Antimicrobic Properties of 1‐Thiocyanato‐1‐alkoxycarbonyl‐2‐arylethanes.
Authors: GRISHCHUK B. D. , PRODANCHUK N. G. , GORBOVOI P. M. , NIVALOV V. N. , SINCHENKO V. G. 
Published: May 2016

AbstractReaction of the arenediazonium salts (I) with the acrylic esters (II) and potassium thiocyanate (III) in the presence of copper(II) acetate gives the phenylthiocyanatopropionic(isobutyric) acid esters (IV).
ChemInform Abstract: Stable Simple Enols. Part 25. Unusual Kinetic Stability of Enols to Ketonization: 1,2‐Dimesityl‐3‐methylbut‐1‐en‐1‐ol and Related β‐Alkyl‐α,β‐dimesitylethenols.
Authors: NADLER E. B. , RAPPOPORT Z. 
Published: May 2016

AbstractAddition of the dimethylcuprate (II) to the enones (I) gives regioselectively the dimesitylbutenols (III) mentioned in the title.
ChemInform Abstract: Thermal Isomerizations of Allenyl Cycloalken‐3‐yl Ethers.
Authors: DULCERE J.‐P. , CRANDALL J. K. 
Published: May 2016

AbstractHeating of the allenyl cyclopentenyl ether (I) results in isomerization to give the cyclopentenylacrolein (II).
ChemInform Abstract: Synthesis of 1,2‐Benzisothiazoles by the Oxidative Ring Contraction of 2‐Aryl‐ and 4‐Aryl‐3,4‐dihydro‐2H‐1,3‐benzothiazines.
Authors: SZABO J. , SZUECS E. + , FODOR L. , BERNATH G. , SOHAR P. 
Published: May 2016

AbstractSodium periodate oxidation of the benzothiazine (I) forms the benzisothiazole (II), whereas oxidation of the N‐substituted benzothiazines (III) yields the benzisothiazolidine oxides (IV).
ChemInform Abstract: Nickel(0)‐Catalyzed Cycloaddition of Silyl Diynes with Carbon Dioxide to Silyl Bicyclic α‐Pyrones.
Authors: TSUDA T. , MORIKAWA S. , HASEGAWA N. , SAEGUSA T. 
Published: May 2016

AbstractNickel‐catalyzed coupling of silyl diynes such as (I) with carbon dioxide (II) produces the bicyclic α‐pyrones (III).
ChemInform Abstract: Synthesis of 1‐(Aminooxy)‐4‐((3‐nitro‐2‐pyridyl)dithio)butane and 1‐(Aminooxy)‐4‐((3‐nitro‐2‐pyridyl)dithio)but‐2‐ene, Novel Heterobifunctional Cross‐Linking Reagents.
Authors: WEBB R. R. II , KANEKO T. 
Published: May 2016

AbstractReaction of the acethydroximate (I) with the dibromides (II) gives the O‐alkylation products (III).
ChemInform Abstract: α‐Lithioamine Synthetic Equivalents: Syntheses of Diastereoisomers from the Boc Piperidines.
Authors: BEAK P. , LEE W. K. 
Published: May 2016

AbstractBoc‐protected piperidines such as (I) are α‐lithiated and subsequently coupled with aldehydes such as (II) to produce the corresponding erythro‐alcohols (III), together with the cyclized form (IV) of the threo‐alcohols.
ChemInform Abstract: Tricyclic Pyridine Derivatives with High Affinity to the Central Benzodiazepine Receptor.
Authors: FISCHER U. , MOEHLER H. + , SCHNEIDER F. , WIDMER U. 
Published: May 2016

AbstractNovel tricyclic heterocycles such as (V)‐(IX) are prepared on different routes as shown for (V) and (VI) and evaluated for their affinity to the central benzodiazepine receptor.
ChemInform Abstract: Reaction of 2‐Chlorocyclohepta(b)pyrrole‐3‐carbaldehyde with o‐Phenylenediamine.
Authors: ABE N. , EMOTO Y. 
Published: May 2016

AbstractReaction of the aldehyde (I) with o‐phenylenediamine (II) gives the products (III) and (IV) instead of the expected benzodiazepine (V).
ChemInform Abstract: Reaction of the Lithium Derivative of Diethyl Phenylmethanephosphonate (I) with Ketones.
Authors: PETROVA J. , VASSILEV N. G. , KIRILOV M. 
Published: May 2016

AbstractThe yields of the adducts (III), (V), (VII) and (VIII) are higher at short reaction times (1‐15 min).
ChemInform Abstract: Acceleration of the Phosphorylation of Phenylacetylene with Red Phosphorus by Ultrasound.
Authors: TROFIMOV B. A. , GUSAROVA N. K. , MALYSHEVA S. F. , RAKHMATULINA T. N. , POLUBENTSEV A. V. , VORONKOV M. G. 
Published: May 2016

AbstractThe title reaction, leading to the formation of the phosphine (III), is accelerated by the application of ultrasound.
ChemInform Abstract: A Novel Preparation of Spirophosphoranes with an Aminomethyl Group at the Phosphorus.
Authors: TERENT'EVA S. A. , PUDOVIK M. A. , PUDOVIK A. N. 
Published: May 2016

AbstractThe benzoxazaphospholane (I) reacts with the glycols (II) under alcoholysis and N→P migration to give the spirophosphoranes (III).
ChemInform Abstract: Reactions of μ3‐Bridging Alkyne Ligands on Heterometallic Clusters.
Authors: BANTEL H. , POWELL A. K. , VAHRENKAMP H. 
Published: May 2016

AbstractThe preparation of the alkyne‐bridged heterometallic clusters (IV) and (V) (yields 59/45/21%) occurs by the one‐pot reaction starting with the RuCo2 cluster (I) as demonstrated for the examples (IV).
ChemInform Abstract: The First Second‐Row Triketone Complex Structure: Synthesis and Properties of a Substituted (1,3,5‐Pentanetrionato)(μ‐oxo)bis(dioxomolybdenum(VI)).
Authors: BORER L. L. , SINN E. 
Published: May 2016

AbstractThe title complex is obtained as its DMSO diadduct (IV) (space group P21/n, Z=4) as shown and characterized by X‐ray structure analysis, magnetic and spectroscopic measurements as well as by cyclic voltammograms.
ChemInform Abstract: Selective Binding and Activation of One Aldehyde Enantioface by a Chiral Transition‐Metal Lewis Acid: Synthesis, Structure, and Reactivity of Rhenium Aldehyde Complexes ((η5‐C5H5)Re(NO)(PPh3)(η2‐O=CHR))+X‐.
Authors: GARNER C. M. , QUIROS MENDEZ N. , KOWALCZYK J. J. , FERNANDEZ J. M. , EMERSON K. , LARSEN R. D. , GLADYSZ J. A. 
Published: May 2016

AbstractThe reaction of the dichloromethane complex (III) with aldehydes such as (IV) gives the π‐aldehyde complexes (V) (6 examples), in which one R‐CHO enantioface is bound with high specificity.
ChemInform Abstract: Chemistry of Boron. Part 204. An Unusual (2 + 2)‐Cycloaddition Reaction of Dicobalt Octacarbonyl.
Authors: CHANNAREDDY S. , LINTI G. , NOETH H. + 
Published: May 2016

AbstractThe (2 + 2)cycloaddition of (II) with (I) is an example of a metal‐mediated activation of CO.
ChemInform Abstract: Synthesis of Novel Polyfunctional Nickel(II)‐Nickel(II) Dimer Ni2Cl2(C(SiMe3)(PMe3))2 by Photolysis of the First ((Trimethylsilyl)diazomethyl)nickel(II) Complex Ni(C(N2)SiMe3)Cl(PMe3)2.
Authors: KOENIG H. + , MENU M. J. , DARTIGUENAVE M. , DARTIGUENAVE Y. , KLEIN H. F. 
Published: May 2016

AbstractAs the first example of a C‐bonded 3d metal diazoalkane complex the Ni(II) compound (III) is synthesized as shown.
ChemInform Abstract: Direct Electrochemical Synthesis of Copper and Silver Derivatives of Alkanedithiols and Crystal Structure of (Cu2S2C3H6‐1,2·(C6H5)2PCH2P(C6H5)2)4·4 CH3CN.
Authors: ANNAN T. A. , KUMAR R. , TUCK D. G. 
Published: May 2016

AbstractThe electrochemical oxidation of Cu or Ag in solutions of various sym. or asym.
ChemInform Abstract: Fixation of Ureas and Thioureas on Trinuclear Ruthenium Clusters: Synthesis and Molecular Structure of (μ2‐H)Ru3(CO)9(μ3‐NPhCSNHPh).
Authors: BODENSIECK U. , STOECKLI‐EVANS H. , SUESS‐FINK G. + 
Published: May 2016

AbstractThe trinuclear clusters (III) are synthesized as demonstrated for the thiourea derivatives (IIIa) (space group P21/m, Z=2) and (IIIb).
ChemInform Abstract: Trapping of Tricyclo(3.3.1.03,7)non‐3(7)‐ene with (Ph3P)2Pt. Structure of the (Ph3P)2Pt Complex of a Highly Pyramidalized Alkene.
Authors: KUMAR A. , LICHTENHAN J. D. , CRITCHLOW S. C. , EICHINGER B. E. , BORDEN W. T. 
Published: May 2016

AbstractNMR coupling constants indicate a highly pyramidalized geometry at the olefinic carbons.
ChemInform Abstract: Technical Procedures for the Syntheses of Carotenoids and Related Compounds from 6‐Oxo‐isophorone: Syntheses of (3R,3′R)‐Zeaxanthin. Part 2.
Authors: SOUKUP M. , WIDMER E. , LUKAC T. 
Published: May 2016

AbstractA 72% overall yield of the synthon (IX), required for the synthesis of the title compound (XI), can be achieved using the new reaction sequence shown in the scheme.
ChemInform Abstract: Synthesis of (3S,4R,3′S,4′R)‐ and (3S,4S,3′S,4′S)‐Crustaxanthins and Further Compounds with 3,4‐Dihydroxy β‐End‐groups.
Authors: BUSCHOR D. J. , EUGSTER C. H. 
Published: May 2016

AbstractThe enantiomerically pure title compounds (IV) and (V) are both synthesized starting from the aldehyde (I).
ChemInform Abstract: The Synthesis of the Labdane Diterpenoid Erigerol and of Analogous Compounds.
Authors: KIENZLE F. , STADLWIESER J. , RANK W. , SCHOENHOLZER P. + 
Published: May 2016

AbstractThe synthesis of the title compound (I) and of some analogues is described in a 23‐step sequence starting from (I).
ChemInform Abstract: Solid‐Phase‐Mediated Peptide Heterodisulfide Formation.
Authors: PONSATI B. , RUIZ‐GAYO M. , GIRALT E. , ALBERICIO F. , ANDREU D. 
Published: May 2016

AbstractA useful new strategy of general applicability is presented for heterodisulfide formation which uses stepwise displacements in a preformed disulfide driven by different acidities according to Pep1‐SH + Y‐S‐S‐X‐Pol → Pep1‐S‐S‐X‐Pol + Y‐SH; Pep1‐S‐S‐X‐Pol + HS‐Pep2 → Pep1‐S‐S‐Pep2 + HS‐X‐Pol.
ChemInform Abstract: A Simple Approach to New 5‐Butenylideneimidazolin‐2‐ones from 2‐Amino‐2‐deoxy‐D‐glucose.
Authors: KOVACS J. , PINTER I. , MESSMER A. , TOTH G. , LENDERING U. , KOELL P. + 
Published: May 2016

AbstractTreatment of the 2‐deoxy‐2‐amino‐D‐glucose hydrochloride (I) with potassium cyanate (II) results in the formation of a complex mixture from which the acyclic (IV) and cyclic derivative (V) are isolated after acetylation.
ChemInform Abstract: Synthesis of Sugar N‐(2‐Thiazolin‐2‐yl)thioureas.
Authors: AVALOS M. , BABIANO R. , CINTAS P. , JIMENEZ J. L. , PALACIOS J. C. 
Published: May 2016

AbstractThe reaction of 2‐deoxy‐2‐isothiocyanato sugars such as (I) with 2‐chloroethylamine hydrochloride (II) in pyridine yields thiazolinylthioureas such as (III).
ChemInform Abstract: Stereoselective Synthesis of 2‐Azapurine 2′‐Deoxy‐β‐D‐ribonucleosides by Nucleobase‐Anion Glycosylation.
Authors: KAZIMIERCZUK Z. , SEELA F. 
Published: May 2016

AbstractNucleobase‐anion glycosylation of the azapurine (II) with the pentafuranosyl chloride (I) yields the regioisomeric products (IIIa), (IV) and (V) stereoselectively.
ChemInform Abstract: Asymmetric Synthesis of (‐)‐Dehydroclausenamide.
Authors: HUANG D.‐F. , HUANG L. 
Published: May 2016

AbstractThe title compound (X), a constituent of Clausena lansium with potent hepatoprotective activity, is prepared starting from cinnamyl alcohol (I) in 2.4% overall yield with > 95% e.e.
ChemInform Abstract: Ab initio Study on Digallane(4), Ga2H4.
Authors: LAMMERTSMA K. , LESZCZYNSKI J. 
Published: May 2016

AbstractAb initio MO calculations of the potential energy surface of the still unknown digallane predict the saltlike tridentate structure (I) to be the most stable isomer of the digallanes (I)‐(VIII).
ChemInform Abstract: Crystal Growth of Tungsten Carbide Plates by Condensation of High‐Temperature Ultrasupersaturated Gas.
Authors: YAMADA K. 
Published: May 2016

AbstractA high temp. ultrasupersaturated gas derived from WC powder by means of the cylindrical shock wave method is used to prepare fine WC plates of various growth forms (trigonal, hexagonal, pentagonal, trapezoidal, rhombic).
ChemInform Abstract: Electrochemical Investigations on Excimer‐Laser Deposited Y‐Ba‐Cu‐O High‐Temperature‐Superconductor Thin Film Electrodes.
Authors: SRIVASTAVA S. K. , ROAS B. , JUETTNER K. + 
Published: May 2016

AbstractEpitaxial YBa2Cu3O7δ thin film electrodes, deposited by the excimer‐laser technique on (100)SrTiO4, exhibit quite a different and unique electrochemical behavior in MeCN solution as compared to that of polycrystalline sintered Y‐Ba‐Cu‐O or Pt electrodes.
ChemInform Abstract: An Investigation of Hydrogen Evolution on Raney‐Nickel Composite‐Coated Electrodes
Authors: CHOQUETTE Y. , BROSSARD L. , LASIA A. , MENARD H. 
Published: May 2016

Abstractin 30 wt.% NaOH aqueous solution at 70 °C by means of the ac impedance technique is undertaken to determine the detailed kinetics of the reaction and the surface coverage of the electrochemically activated electrodes by adsorbed hydrogen.
ChemInform Abstract: Some Unique Aspects of Electrochemical Processes at the Group Ib Metal/Aqueous Solution Interface.
Authors: BURKE L. D. , LEE B. H. , RYAN T. G. 
Published: May 2016

AbstractA unique feature of the Cu, Ag, and Au electrode systems is that they exhibit an adatom (M*)/hydrous oxide transition in which the cation is in the univalent state (M+).
ChemInform Abstract: Application of Ion Implantation/RBS to the Study of Electrocatalysis. Comparison of Chlorine Evolution at Ir‐Implanted and Ru‐Implanted Titanium Electrodes.
Authors: KELLY E. J. , VALLET C. E. , WHITE C. W. 
Published: May 2016

AbstractIr‐implanted titanium near‐surface alloys are prepared by ion implantation, characterized by Rutherford backscattering (RBS), and subsequently anodically oxidized to form electrocatalytically active IrxTi1‐xO2/Ti (I) electrodes.
ChemInform Abstract: Kinetics of Titanium(IV) Chloride Oxidation
Authors: PRATSINIS S. E. , BAI H. , BISWAS P. , FRENKLACH M. , MASTRANGELO S. V. R. 
Published: May 2016

Abstractby Ar/O2 mixtures is studied in a furnace aerosol reactor at temp. in the range 700‐1000 °C. The oxidation rate is first order with respect to (TiCl4) and nearly zero order for (O2) up to a 10‐fold excess.
ChemInform Abstract: Preparation of the Zeolite Nu‐15.
Authors: DUBANSKA V. 
Published: May 2016

AbstractA novel vanadium zeolite of a composition corresponding to formula (I) is synthesized by hydrothermal decomposition of a vanadium glass (15‐17% Na2O, 15‐17% Al2O3, 25‐40% SiO2, 30‐45% V2O5) at 120‐160 °C in strongly basic solution in NaOH.
ChemInform Abstract: The 4‐Chloro‐2‐oxo‐1,3,5,5,8‐pentamethyl‐1,3,8‐triaza‐5‐azonia‐4λ5‐phosphasp# iro(3.4)octyl Cation: X‐Ray Crystal Structure Determination and Variable Temperature 1H NMR Spectra.
Authors: KAUKORAT T. , ERNST L. , SCHMUTZLER R. , SCHOMBURG D. 
Published: May 2016

AbstractThe 1H NMR spectrum of the spirophosphorane (Ia) at room temp. indicates dynamic behavior of the cation involving exchange of N‐methyl groups.
ChemInform Abstract: The Cyclodimerization of Aryl Vinyl Sulfones: A Facile and Specific Reaction when Activated by Cathodic Electron Transfer.
Authors: DELAUNAY J. , MABON G. , ORLIAC A. , SIMONET J. 
Published: May 2016

AbstractThe aryl vinyl sulfones (I) are dimerized by very low cathodic currents to give the trans‐substituted cyclobutanes (II).
ChemInform Abstract: The Nucleophilic Displacement Route to Homochiral Arylphosphine Oxides.
Authors: BROWN J. M. , CAREY J. V. , RUSSELL M. J. H. 
Published: May 2016

AbstractThe results show that it is possible to prepare homochiral di‐ and triarylphosphine oxides (X) by two sequential nucleophilic displacements on a derivative (III) (used without purification) of PPhCl2 (II) utilizing (‐)‐ephedrine as a chiral auxiliary.
ChemInform Abstract: Directed Nitrile Oxide Cycloaddition Reactions. The Use of Hydrogen Bonding to Direct Regio‐ and Stereochemistry in Nitrile Oxide Cycloadditions with Cyclopentenylamides.
Authors: CURRAN D. P. , CHOI S.‐M. , GOTHE S. A. , LIN F.‐T. 
Published: May 2016

AbstractThe 1,3‐dipolar cycloaddition reaction of the 3‐substituted cyclopentenes (I) with benzonitrile oxide (II) generated in situ yields the two regioisomeric cyclization products (III) and (IV).
ChemInform Abstract: On the Oxidation of Saturated Hydrocarbons with H2O2 in the Presence of Iron(II) Picolinate or Iron(II) 1,10‐Phenanthroline‐2‐carboxylate.
Authors: BALAVOINE G. , BARTON D. H. R. , BOIVIN J. , GREF A. 
Published: May 2016

AbstractCyclohexane (I) is oxidized with 30% H2O2 in the presence of pyridine, acetic acid, and an iron‐containing complex catalyst as shown in the reaction scheme to give mainly cyclohexanone and a small amount of cyclohexanol.