bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Homogeneous Deuteration of Alkenes Using (RhCl(4R,5R‐DIOP)) Catalysts.
Authors: GUENGOER M. + , JARDINE F. H. , WHEATLEY J. D. 
Published: May 2016

AbstractMS analyses of the products of homogeneous deuteration of alkenes such as cyclohexene, norbornene, dihydropyran or allylbenzene at sub‐atmospheric pressure using the title catalyst show that considerable quantities of polydeuterated products are obtained.
ChemInform Abstract: Interception of 1,4‐Radical Cations Derived from a Cage Ketone with Molecular Oxygen.
Authors: IKEDA H. , YAMASHITA Y. , KABUTO C. , MIYASHI T. 
Published: May 2016

AbstractReaction of the cage ketone (I) with tetracyanoethylene (II) gives the cycloadduct (III).
ChemInform Abstract: Organic Reactions without Solvent: Michael Additions on an Unsaturated Sulfone and Sulfoxide.
Authors: GALONS H. , LABIDALLE S. , MIOCQUE M. , LIGNIERE B. , BRAM G. 
Published: May 2016

AbstractThe Michael type reaction of the trisubstituted CH‐acidic compounds (I) with the activated olefins (II), mediated by potash and benzyltriethylammonium chloride, is performed in the solid phase to produce the adducts (III).
ChemInform Abstract: Reactivity of 1,1,1‐Trichloroethanal (Chloral) with Pyrroles.
Authors: FALK H. , WOESS H. + 
Published: May 2016

AbstractThe reaction of the pyrroles (I), (IV) and (X) with chloral (II) depends on the strength of the acidic catalyst and on the substituents of the pyrrole leading to 1:1 and 2:1 condensation products.
ChemInform Abstract: Synthesis of New Hydantoin‐3‐acetic Acid Derivatives.
Authors: OH C.‐H. , KANG Y.‐K. , PARK S.‐W. , CHO J.‐H. , KWON S.‐K. 
Published: May 2016

AbstractUsing the Bucherer‐Berg method, new hydantoins such as (IV) are prepared and converted into the acetic acid hydantoins (VI), some of which are transformed into the corresponding sulfones by H2O2 treatment.
ChemInform Abstract: Azaindole Derivatives. Part 2. Synthesis and Analgesic Activity of Pyrazolo(1,5‐a)pyridines.
Authors: GMEINER P. , SCHUENEMANN J. + 
Published: May 2016

AbstractStarting with the azaindolecarboxylate (I), the nitriles (IV), (V), and (VIII) and the amino compunds (XI) or (XII) are prepared by conventional methods.
ChemInform Abstract: Application of the Benzyloxycarbonyloxymethyl Moiety to a Protective Group of 5‐Fluorouracil. Selective Alkylation of Amide Nitrogen of the Uracil Ring.
Authors: NAGASE T. , SEIKE K. , SHIRAISHI K. , YAMADA Y. , OZAKI S. 
Published: May 2016

Abstract5‐Fluorouracil (I) reacts with formaldehyde (II) to give the bis(hydroxymethyl) derivative (III).
ChemInform Abstract: Reactions of Triphenyl Phosphite with Di‐ and Tribromoacetaldehyde.
Authors: SINYASHINA T. N. , MIRONOV V. F. , OFITSEROV E. N. , KONOVALOVA I. V. , PUDOVIK A. N. 
Published: May 2016

AbstractTriphenyl phosphite (I) reacts with the tribromoacetaldehyde (II) to give the phosphate (III) or the phosphonium salt (IV), depending on the molar ratio.
ChemInform Abstract: Iodine‐Induced Cyclization of Organophosphorus Compounds.
Authors: YE M.‐C. , LI L.‐P. , ZHAO Y.‐F. , ZHAI C. 
Published: May 2016

AbstractIodine‐induced cyclization reaction of the ω‐vinyl phosphorus compounds such as (I) or (III) yields the iodomethyl compounds (II) or a mixture of the iodomethyl derivative (IV) and the corresponding homologous iodine‐substituted ring compound (V).
ChemInform Abstract: Tris(pyrazolyl)borate Complexes of Yttrium. X‐Ray Crystal Structures of (HB(pz)3)2YCl(Hpz) and ((HB(pz)3)Y(μ‐O2CCH3)2)2 (pz: Pyrazolyl Ring).
Authors: REGER D. L. , LINDEMAN J. A. , LEBIODA L. 
Published: May 2016

AbstractThe reaction shown in the scheme without pyrazole (III) yields an unsolvated complex (72% yield), which is in solution in a monomer‐dimer equilibrium.
ChemInform Abstract: Lanthanoid Complexes of Potentially Heptadentate Ligands Including the Structure of (Tris(3‐aza‐4‐methylhept‐4‐ene‐6‐on‐1‐yl)amine)tris(nitrato)gadolinium(III).
Authors: SMITH A. , RETTIG S. J. , ORVIG C. 
Published: May 2016

AbstractThree new potentially heptadentate ligands (I) (no yield given) and (II) (86 and 88% yield) are prepared by the Schiff base condensation of tris(2‐aminoethyl)amine with 3 equiv. of an appropriate ketone.
ChemInform Abstract: Fluorescent Lanthanoid Complexes. Part 1. Reaction Between Tb3+ and 4‐Oxo‐4H‐1‐benzopyran‐3‐carboxaldehyde in Alcoholic Medium.
Authors: BISI CASTELLANI C. , CARUGO O. , TOMBA C. , INVERNIZZI GAMBA A. 
Published: May 2016

AbstractIn the title reaction several different products are formed, depending on the experimental conditions.
ChemInform Abstract: Preparation, Chemical and Structural Characterization of Some Molybdenum(III) and Tungsten(III) Coordination Compounds Containing the 1‐(4‐pyridyl)pyridinium Cation.
Authors: BRENCIC J. V. , CEH B. , LEBAN I. 
Published: May 2016

AbstractThe unreactive, air‐stable compound (III) crystallizes in the space group Pbcm with Z=4.
ChemInform Abstract: Convenient Synthesis of Optically Active Iron Acyls.
Authors: HUNGATE R. W. , MILLER F. , GOODMAN M. S. 
Published: May 2016

AbstractThe amino acids (I) and (V) are activated by the conversion to mixed anhydrides and then coupled with the anionic cyclopentadienyldicarbonyliron complex (II) to form the acyliron compounds (III) or (VI).
ChemInform Abstract: Nickel(I) and Nickel(III) Complexes of Substituted Tetraaza Macrocycles Formed by Pulse Radiolysis and Electrochmistry of Nickel(II) Precursors.
Authors: BERNHARDT P. V. , LAWRANCE G. A. , SANGSTER D. F. 
Published: May 2016

AbstractThe Ni(II) complexes (I)‐(III) react rapidly with hydroxyl radicals and aquated electrons eaq to initial transient products which decay via first‐order kinetics within a few milliseconds in neutral aqueous solutions at 22 °C. Electronic spectra and decay rate constants, as well as formation rate constants, are reported for all transients.
ChemInform Abstract: Synthesis and Characterization of Tetraammineruthenium(II) Bound to the Bridging Ligand 2,3‐Bis(2‐pyridyl)pyrazine (dpp).
Authors: RUMINSKI R. R. , COCKROFT T. , SHOUP M. 
Published: May 2016

AbstractThe reaction of the title ligand with (Ru(NH3)5(H2O))3+ in the presence of Zn amalgam gives the complexes (I) and (II), isolated by different work‐up procedures, which are characterized by MLCT transitions in the aqueous visible electronic spectra and electrochemical investigations using cyclic voltammetry.
ChemInform Abstract: Unusually Stable Trimethylplatinum(IV) Complexes with an O3PtC3 Coordination Sphere. Crystal and Molecular Structure of (C5H5Co(P(O)(OEt)2)3PtMe3).
Authors: NETTLE A. , VALDERRAMA M. , CONTRERAS R. , SCOTTI M. , PETERS K. , VON SCHNERING H. G. , WERNER H. 
Published: May 2016

AbstractThe reaction of the tetrameric Pt(IV) compound (I) with the sodium cobaltate (II) gives the heterometallic dinuclear complexes (III).
ChemInform Abstract: Preparation of Chiral 5,6‐Disubstituted‐5,6‐dihydro‐2H‐pyran‐2‐ones via Transformation of D‐Glucal.
Authors: MATSUI T. , KAWANO Y. , NAKAYAMA M. 
Published: May 2016

AbstractThe optimum reaction conditions are tested for the conversion of the D‐glucals (I) into the pseudo‐glucals (II), which after MnO2 oxidation yield the title compounds (III).
ChemInform Abstract: Coupling Constants Variations in a Series of C‐1 gem‐Fluorohalogenosugars with the Anomeric Configuration and Substitution.
Authors: PRALY J.‐P. , DESCOTES G. 
Published: May 2016

Abstract13C and 19F NMR investigations of the pyranosyl fluorides (I) show that the coupling constant 1JC,F at the anomeric center is higher in the case of (Ia).
ChemInform Abstract: Proton Mobility in Liquid and Frozen HClO4·5.5 H2O: NMR and Conductivity Measurements.
Authors: HUANG T.‐H. , DAVIS R. A. , FRESE U. , STIMMING U. 
Published: May 2016

AbstractThe 2H NMR results obtained for liquid and frozen HClO4·5.5 H2O indicate that the protons (deuterons) in this compound are relatively mobile even in the frozen state.
ChemInform Abstract: Thermodynamic Stability of n‐AgInSe2 in Photoelectrochemical Cells (PEC).
Authors: PERALDO BICELLI L. 
Published: May 2016

AbstractThermodynamic calculations are performed to evaluate the standard free energy changes and decomposition potentials of all possible bond cleavage and decomposition photoreactions that may occur in a PEC with a n‐AgInSe2 photoanode and either a polysulfide or a polyiodide electrolyte.
ChemInform Abstract: Oxidation of Primary Aliphatic Amines to C‐Nitroso Dimers.
Authors: ZAJAC W. W. JUN. , WALTERS T. R. , WOODS J. M. 
Published: May 2016

AbstractThe oxidation of primary amines (I) with sodium percarbonate in a biphasic system gives in general the C‐nitroso dimers (II) as the main products.
ChemInform Abstract: Synthesis and Pharmacological Characterization of 1‐Phenyl‐, 4‐Phenyl‐, and 1‐Benzyl‐1,2,3,4‐tetrahydroisoquinolines as Dopamine Receptor Ligands.
Authors: CHARIFSON P. S. , WYRICK S. D. , HOFFMANN A. J. , ADEME SIMMONS R. M. , BOWEN J. P. , MCDOUGALD D. L. , MAILMAN R. B. 
Published: May 2016

AbstractThe key step in the preparation of the substituted tetrahydroisoquinolines (VI) is the ring closure of the amides (IV) upon treatment with P2O5 and POCl3.
ChemInform Abstract: Synthesis of 3‐Substituted Propiorhodanines by the Reaction of 3‐Chloropropanoyl Chloride with N‐Substituted Dithiocarbamates.
Authors: CRUZ C. , MACIAS A. , BELETSKAYA I. P. 
Published: May 2016

AbstractA novel and convenient synthesis of the title compounds, viz the 2‐thioxo‐4‐oxo‐1,3‐thiazines (III), is reported.
ChemInform Abstract: Synthesis of 2‐Thioxo‐4‐oxoperhydro‐1,3‐thiazines by the Reaction of the Chlorides of α,β‐Unsaturated Acids with the Salts of Dithiocarbamic Acid and Its 3‐Substituted Derivatives.
Authors: CRUZ C. , MACIAS A. , BELETSKAYA I. P. 
Published: May 2016

AbstractThe title reaction gives access to a variety of thiazines of type (III), some of which could not be prepared by the hitherto known procedures.
ChemInform Abstract: The Valence Control and Catalytic Properties of La2‐xSrxNiO4.
Authors: NITADORI T. , MURAMATSU M. , MISONO M. 
Published: May 2016

AbstractWithin the series La2‐xSrxNiO4 with x = 0‐1.0, the average oxidation number of Ni increases monotonously upon Sr substitution from 2.32 (x = 0) to 2.90 (x = 1.0).
ChemInform Abstract: Synthesis and Structure of the Soluble Selenido‐ and Telluridochromates ((C6H5)4P)3(Cr3Se24) and ((C6H5)4P)3(Cr3Te24).
Authors: FLOMER W. A. , O'NEAL S. C. , PENNINGTON W. T. , JETER D. , CORDES A. W. , KOLIS J. W. 
Published: May 2016

AbstractThe title compounds (III) both crystallize in space group P1, (IIIa) with Z=2 and (IIIb) with Z=1.
ChemInform Abstract: The Stereochemistry of Organometallic Compounds. Part 32. Hydrocyanation of Derivatives of Amino Alkynes.
Authors: JACKSON W. R. , PERLMUTTER P. , SMALLRIDGE A. J. 
Published: May 2016

AbstractNo regioselectivity is observed in the phosphine‐catalyzed hydrocyanations of the alkynes (I).
ChemInform Abstract: Conventional and Laser Photolysis of a Bisdiazo Compound.
Authors: HANNEMANN K. , WIRZ J. , RIESEN A. 
Published: May 2016

AbstractEntirely different product distributions are observed when the title compound (III) is irradiated by a conventional lamp (254 nm) on one hand and by a pulsed excimer laser (248 nm) on the other.
ChemInform Abstract: Long‐Lived Light‐Induced Charge Separation in a Zeolite L‐Based Molecular Triad.
Authors: KRUEGER J. S. , MAYER J. E. , MALLOUK T. E. 
Published: May 2016

AbstractThe photochemistry of a sensitizer‐acceptor‐secondary acceptor complex which organizes spontaneously at the surface of a zeolite L particle is reported.
ChemInform Abstract: ESR Investigation of C‐C Bond Cleavage in Radical Cations.
Authors: MASLAK P. , ASEL S. L. 
Published: May 2016

AbstractThe kinetics of breakdown of the radical cations (IIa), (IId), and those generated from (VI) are studied together with the corresponding activation parameters ΔH (10.3 to 15.3 kcal/mol) and ΔS (‐12 to ‐27 eu for (II), but +2 ±3 eu for the radical cation from (VI)).
ChemInform Abstract: A Mechanistic Study of the Wittig Reaction Between a Cyclic Anhydride and a Stabilized Phosphorane.
Authors: ABELL A. D. , CLARK B. M. , ROBINSON W. T. 
Published: May 2016

AbstractThe E enol lactone (IV) is available from (I) and (II) by Wittig reaction, the intermediate (III) being identified by its crystal structure (P1, Z=2).
ChemInform Abstract: Improved Synthesis of 2,6‐Dicyano‐1,5‐dimethylsemibullvalene from 1,5‐Dimethylbicyclo(3.3.0)octane‐3,7‐dione.
Authors: QUAST H. , MAYER A. 
Published: May 2016

AbstractThe TiCl4‐mediated reaction of the diketone (I) with the thiophenols (II) affords equal amounts of the isomeric sulfides (III)/(IV) which are oxidized to the sulfones (V)/(VI).
ChemInform Abstract: Endocyclic Nucleophilic Substitution at Tetracoordinate Sulfur(VI).
Authors: ANDERSEN K. K. , CHUMPRADIT S. , MCINTYRE D. J. 
Published: May 2016

AbstractThe tetracoordinate sulfur(VI) compounds (I) and (III) undergo intramolecular nucleophilic substitution at the sulfur atom via four‐ or five‐membered cyclic trasition states, forming the sulfone (II) or the sulfonamide (IV).
ChemInform Abstract: Lithiated Azafulvenes by Halogen/Metal Interchange of Brominated 6‐(Diisopropylamino)‐1‐azafulvene Derivatives. Novel Synthesis of 5‐Mono‐ and 4,5‐Disubstituted 1H‐Pyrrole‐2‐carbaldehydes.
Authors: BRAY B. L. , HESS P. , MUCHOWSKI J. M. , SCHELLER M. E. 
Published: May 2016

AbstractThe lithiated 1‐azafulvene derivatives (VII) and (XIII) are generated for the first time.
ChemInform Abstract: Synthesis of Substituted Pyrroles from Ketones.
Authors: CHELUCCI G. , MARCHETTI M. 
Published: May 2016

AbstractThe hydrazones (I), derived from ketones and 1,1‐dimethylhydrazine, are lithiated and then coupled with 2‐iodomethyldioxolane (II), forming the substitution products (III).
ChemInform Abstract: 1,2,3‐Triazoles: Structural Changes on Two Effective Inhibitors of the Prostaglandin Synthesis in vitro.
Authors: BIAGI G. , LIVI O. , SARTONI V. , VERUGI E. 
Published: May 2016

AbstractVarious triazolyl(methyl)phenylacetic acid derivatives and the corresponding phenoxy analogues, e.g. (III) and (V), are prepared.
ChemInform Abstract: Regioselective Proton‐Catalyzed Diarylmethylation of Indoles with 9H‐Xanthydrol, Dibenzosuberenol, and Bis(4‐dimethylaminophenyl)methanol.
Authors: PINDUR U. , DESCHNER R. 
Published: May 2016

AbstractThe reactivity of the diarylcarbenium ions (II) generated in situ towards the 2‐ or 3‐alkylindoles (III), (VI), or (VIII) is investigated.
ChemInform Abstract: Indolo(2,3‐a)quinolizines and a Convenient Synthesis of Flavoserpentine.
Authors: TEUBER H.‐J. , QUINTANILLA‐LICEA R. , RAABE T. 
Published: May 2016

AbstractReaction of tryptamine·HCl (I) with the acetals (II) gives rise to the salts (IIIa) (+ by‐product (IVa)) or (IIIb).
ChemInform Abstract: Furopyridines. Part 9. Syntheses and Properties of 3‐Ethoxy Derivatives of Furo(2,3‐b)‐, Furo(3,2‐b)‐, Furo(2,3‐c)‐, and Furo(3,2‐c)pyridine.
Authors: SHIOTANI S. , MORITA H. , ISHIDA T. , IN Y. 
Published: May 2016

AbstractThe ethoxycarbonylhydroxyfuropyridines (I) reacts with ethyl bromoacetate (II) to give the ether (III) which is transetherified with sodium ethoxide (IV), producing the ethoxy derivative (V).
ChemInform Abstract: Mechanistic and Synthetic Studies on the Formation of 1,2,4‐Trioxanes Related to Arteannuin. Photooxygenation of a Bicyclic Dihydropyran.
Authors: JEFFORD C. W. , WANG Y. , BERNARDINELLI G. 
Published: May 2016

AbstractThe Rose Bengal sensitized photooxygenation of the compound (II) in MeOH or acetaldehyde (III) gives rise to the various products shown in the scheme.
ChemInform Abstract: Reductive Oligomerization of 1,2‐Di‐tert.‐butyl‐1,1,2,2‐tetrachlorodisilane: The Tetracyclo(3.3.0.02,7.03,6)octasilane and Tricyclo(2.2.0.02,5)hexasilane Systems.
Authors: KABE Y. , KURODA M. , HONDA Y. , YAMASHITA O. , KAWASE T. , MASAMUNE S. 
Published: May 2016

AbstractThe reduction of the disilane (I) by 2.5‐equiv.
ChemInform Abstract: Phosphonomethylation of 2‐Aminoethanethiol and Thiazolidine. An Unexpected Product.
Authors: DHAWAN B. , REDMORE D. 
Published: May 2016

Abstract2‐Aminoethanethiol (I) or thiazolidine (V) react with formaldehyde (II) and phosphorous acid (III) to give the N,N‐bis(phosphonomethyl)thiazolidine (IV).
ChemInform Abstract: Complex‐Induced Proximity Effects and Dipole‐Stabilized Carbanions: Kinetic Evidence for the Role of Complexes in the α′‐Lithiations of Carboxamides.
Authors: HAY D. R. , SONG Z. , SMITH S. G. , BEAK P. 
Published: May 2016

AbstractThe kinetics of the α'‐lithiations of the amides (I) by sec.‐butyllithium (II) are investigated.
ChemInform Abstract: Thermal Encapsulation and Photochemical Deencapsulation of Ag(I) by (Ir2(dimen)4)(PF6)2 (dimen: 1,8‐Diisocyanomenthane). X‐Ray Crystal Structure of (AgIr2(dimen)4)(PF6)3·2 DMSO.
Authors: SYKES A. , MANN K. R. 
Published: May 2016

AbstractThe title complex (IV) is formed by reaction of the diiridium complex (I) with one equiv. AgPF6 (II) and recrystallization of an isolated encapsulation product from DMSO (III).
ChemInform Abstract: Regioselective Methylation of 7,12‐Dihydropyrido(3,2‐b:5,4‐b′)diindole. Experimental and Computational Results.
Authors: TRUDELL M. L. , TAN Y.‐C. , COOK J. M. 
Published: May 2016

AbstractThe pyrido‐fused diindole (I) is consecutively treated with KH in DMSO and methyl iodide (II) to give the 7‐methyl derivative (III).
ChemInform Abstract: Synthesis of Stypandrol, a Toxic Binaphthalenetetrol Isolated from Stypandra imbricata. New Syntheses of Dianellidin and Stypandrone.
Authors: RIZZACASA M. A. , SARGENT M. V. 
Published: May 2016

AbstractNew syntheses of the naphthalenoid natural products dianellidin (IV) and stypandrone (XI), which rely on the Fries rearrangement ((I) → (II), (VIII) → (IX)), are described as outlined in the scheme.
ChemInform Abstract: Characterization of Some New Chromates M2Fe3(OH)5(CrO4)3·3 H2O (M: Li, Na).
Authors: MINEELY P. J. 
Published: May 2016

AbstractThe title chromates, prepared as amorphous red‐brown powders according to the scheme (yields in mg), are characterized by thermal analysis, powder XRD, IR spectroscopy and room temp. Moessbauer studies.
ChemInform Abstract: Theoretical Studies of the Lithiation of Enamines.
Authors: STORK G. , POLT R. L. , LI Y. , HOUK K. N. 
Published: May 2016

AbstractIn order to understand the transition‐state geometries of proton removal, ab initio calculations are carried out on the reactions of lithium hydride and methyllithium with a series of vinylamines at the 3‐21G level.
ChemInform Abstract: Electrochemical Selective Bromoalkoxylation of Arylolefins.
Authors: ELINSON M. N. , MAKHOVA I. V. , NIKISHIN G. I. 
Published: May 2016

AbstractElectrochemical bromoalkoxylation of allylbenzene (I) with methanol (II) in the presence of ammonium bromide leads to the formation of the bromohydrin ethers (III) and (IV), the ethers (V) and (VI), and the dibromide (VII).
ChemInform Abstract: Cobaloxime‐Mediated Radical Alkyl‐Heteroaromatic Substitution.
Authors: BRANCHAUD B. P. , CHOI Y. L. 
Published: May 2016

AbstractThe pyridinium, quinolinium, and benzothiazolium tosylates (I), (V), and (VIII) are alkylated with the Co(III) complexes (II) on anaerobic visible light photolysis, yielding the pyridines (III) and (IV), quinolines (VI) and (VII), or benzothiazoles (IX).
ChemInform Abstract: Diels‐Alder Reactions of Cycloalkenones. Part 13. Reactions of 2‐Cyclohexenones with E‐1‐Methoxy‐1,3‐butadiene.
Authors: FRINGUELLI F. , MINUTI L. , RADICS L. , TATICCHI A. , WENKERT E. 
Published: May 2016

AbstractCycloaddition reaction of the cyclohexenones (I) with the E‐methoxybutadiene (II) yields the 1:1 adducts (III).
ChemInform Abstract: Retropinacoline Rearrangement of α‐Branched Geminal Dichlorohydrocarbons.
Authors: BORODAEV S. V. , ZUBKOVA O. V. , LUK'YANOV S. M. , GASANOV A. G. 
Published: May 2016

AbstractTreatment of the title compounds (I) with SbCl5 causes cleavage of Cl‐ ions and generation of chlorocarbenium ions, which undergo subsequent migration of R1 to afford a more stable cation.
ChemInform Abstract: Heterocyclic Photorearrangements. Photochemical Behaviour of Some 3,5‐Disubstituted 1,2,4‐Oxadiazoles in Methanol at 254 nm.
Authors: BUSCEMI S. , CICERO M. G. , VIVONA N. , CARONNA T. 
Published: May 2016

AbstractThe photolysis of the 1,2,4‐oxadiazoles (I) in methanol is examined.
ChemInform Abstract: Transition‐Metal Promoted Reactions. Part 19. Nickelocene‐Lithium Aluminum Hydride: A Versatile Desulfurization Reagent.
Authors: CHAN M.‐C. , CHENG K.‐M. , HO K. M. , NG C. T. , YAM T. M. , WANG B. S. L. , LUH T.‐Y. 
Published: May 2016

AbstractNickelocene and LiAlH4 react in THF to give a homogeneous metal hydride which is employed in the reduction of several sulfur compounds as shown in the reaction scheme.
ChemInform Abstract: Heterogeneous Acid‐Catalyzed Amination of Isobutene to tert‐Butylamine.
Authors: DEEBA M. , FORD M. E. 
Published: May 2016

AbstractAmmonia (II) is added to the double bond of isobutene (I) in the presence of a zeolite catalyst to give tert‐butylamine (III).
ChemInform Abstract: Polyfluoroalkylsuccinic Acids.
Authors: ALEKSEENKO A. N. , NAZARETYAN V. P. , IL'CHENKO A. YA. , YAGUPOL'SKII L. M. 
Published: May 2016

AbstractIn the presence of an inhibitor of radical reactions the reaction between the perfluoroalkyl iodides (I) and diethyl maleate (II) or diethyl itaconate (V) affords the perfluoroalkylsubstituted diethyl succinates (III) or (VI).
ChemInform Abstract: Reaction of Organic Azides with Unsaturated Compounds. Part 10. Esters of N‐Arylsulfonylcarbamic Acids.
Authors: SEMENOV V. P. , OGLOBLIN K. A. 
Published: May 2016

AbstractThe arylsulfonyl azides (I) react smoothly with acyclic alkenes such as (II) or with cyclohexenes, e.g. (IV), to afford the title compounds of type (III) or (V).
ChemInform Abstract: A New Method for the Synthesis of Linear Allylsulfonium Salts and Their (1,2)‐ or (3,2)‐Reactions Depending on the Nature of the Counterions.
Authors: DRAGAN V. A. , VESELOVSKII V. V. , MOISEENKOV A. M. 
Published: May 2016

AbstractGeranyl acetate (I) reacts with dimethyl sulfoxide (II), activated by trifluoroacetic anhydride, to give the sulfonium salt (IIIa).
ChemInform Abstract: Hydrogenation of 3(2H)‐Isoquinolinones and the Stereochemistry of the Products.
Authors: TOTH G. , HAZAI L. , DEAK G. , DUDDECK H. , KUEHNE H. + , HRICOVINI M. 
Published: May 2016

AbstractA new route of preparing the tetrahydroisoquinolines (II) and the 1,4‐dihydroisoquinolines (III) and (IV) is developed by hydrogenation of (I).
ChemInform Abstract: Synthesis and Reactions of C‐(2‐Thienoyl)‐N‐arylformohydrazonoyl Bromides.
Authors: FARAG A. M. , ALGHARIB M. S. 
Published: May 2016

AbstractCoupling of 1‐thienyl‐2‐dimethylsulfonioethanone bromide (I) with the diazonium salts (II) leads to the formation of the hydrazonoyl bromides (III) which react with the nucleophilic compounds (IV), (VI), (VIII), or (X) to form the derivatives (V), (VII), (IX), and (XI) respectively.
ChemInform Abstract: Trifluorovinylphosphonates.
Authors: KADYROV A. A. , ROKHLIN E. M. , GALAKHOV M. V. 
Published: May 2016

AbstractReaction of the trifluorovinylmagnesium iodide, prepared from the trifluorovinyl iodide (I) and Mg, with the chlorophosphites (II) produces the phosphonites (III) which are oxidized with SeO2 or activated MnO2, yielding the title compounds (IV).
ChemInform Abstract: Synthetic and Structural Studies on the Formation of a Tetradecametallic Yttrium Oxide Alkoxide Chloride Complex: An Example of How Molecular Yttrium Oxygen Frameworks Form Extended Arrays.
Authors: EVANS W. J. , SOLLBERGER M. S. 
Published: May 2016

AbstractYCl3 reacts with 2 equiv. of Na‐O‐tBu in THF to form (I), which crystallizes in P21/c with Z=4.
ChemInform Abstract: Synthesis, Characterization, and Electrochemical Properties of a Family of Dinuclear Rhodium Complexes Containing Two Terminal Hydride Ligands and Two Hydride (or Chloride) Bridges. Stoichiometric and Catalytic Hydrogenation Reactions of Alkynes and Alkenes.
Authors: BIANCHINI C. , MELI A. , LASCHI F. , RAMIREZ J. A. , ZANELLO P. , VACCA A. 
Published: May 2016

AbstractThe trihydride complex (I) can function as precursor for polynuclear polyhydride derivatives by two routes: protonation by strong acids and thermal decomposition in solution.