bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: A Rotating Disc Electrode with Heat Transfer Facilities for Corrosion Studies.
Authors: ALWASH S. H. , ASHWORTH V. , SHIRKHANZADEH M. , THOMPSON G. E. 
Published: May 2016

AbstractThe developed rotating disc electrode (RDE) assembly comprises an RDE, an electrode shaft coupled to the driving shaft, a bearing and slip ring unit, a driving unit and two auxiliary units for supplying and detecting the heat flux (a detailed description of the electrode arrangement is given).
ChemInform Abstract: Dezincification of Brass and Its Inhibition in Acidic Chloride and Sulphate Solutions.
Authors: DINNAPPA R. K. , MAYANNA S. M. 
Published: May 2016

AbstractThe dezincification process is characterized by the potential‐time relationship, which indicates a selective dissolution of Zn at the initial stage followed by simultaneous dissolution of Cu and Zn and subsequent redeposition of Cu.
ChemInform Abstract: Investigation of Chromate Inhibitors on Aluminium Using Fluorescence Detection of X‐Ray Absorption.
Authors: HAWKINS J. K. , ISAACS H. S. , HEALD S. M. , TRANQUADA J. , THOMPSON G. E. , WOOD G. C. 
Published: May 2016

AbstractAl specimens supporting air‐formed and anodic films have been immersed in a NaCl/K2CrO4 electrolyte for 1 h. After immersion, Cr(III) is detected on Al supporting the air‐formed film (2.5 nm), and Cr(VI) is indicated for samples supporting relatively thick (36 nm) anodic films; both oxidation states are present in a 6 nm thick anodic film.
ChemInform Abstract: Reaction Between Nitric Oxide and the Amidogen Radical, NH· 2
Authors: CROWLEY J. N. , SODEAU J. R. 
Published: May 2016

Abstract, produced by photolysis of NH3, has been studied by FTIR spectroscopy in Ar, Ne, N2 matrices at 4.2 K. The results indicate that N2O is a direct product of this reaction.
ChemInform Abstract: New Borates of the Alkali Metals: NaLi2(BO3).
Authors: MIESSEN M. , HOPPE R. 
Published: May 2016

AbstractSingle crystals of the hitherto unknown title compound have been prepared by annealing a mixture of Na2O, Li2O, and B2O3 (Ni tube, 550 °C, 28 d).
ChemInform Abstract: Coupled Substitution (Eu, O) in Strontium Hydroxyapatite.
Authors: LACOUT J.‐L. , TAITAI A. , BONEL G. 
Published: May 2016

AbstractThe coupled substitution of Eu3+ and O2‐ for Sr2+ and OH‐, resp., results in the formation of a continuous series of compounds of the general formula Sr10‐xEux(PO4)6(OH)2‐xOx with 0 ≤ x ≤ 2. The substituted compounds are prepared in a solid state reaction at 1350 °C in air using stoichiometric mixtures of Sr2P2O7, SrCO3, and Eu2O3 as starting materials.
ChemInform Abstract: Spin Equilibrium in Iron(II) Poly(1‐pyrazolyl)borate Complexes: Low‐Temperature and High‐Pressure Moessbauer Spectral Studies.
Authors: LONG G. J. , HUTCHINSON B. B. 
Published: May 2016

AbstractThe complex (Ia), which contains low‐spin Fe(II) from room temp. down to 4.2 K, may be converted in part to high‐spin Fe(II) at pressures above ca. 40 kbar.
ChemInform Abstract: Variable‐Temperature Magnetic, Spectral, and X‐Ray Crystallographic Studies of “Spin‐Crossover” Iron(III) Schiff‐Base‐Lewis‐Base Adducts. Influence of Noncoordinated Anions on Spin‐State Interconversion Dynamics in (Fe(salen)(imd)2)Y Species (Y: ClO‐ 4, BF‐ 4, PF‐ 6, BPh‐ 4; imd: Imidazole).
Authors: KENNEDY B. J. , MCGRATH A. C. , MURRAY K. S. , SKELTON B. W. , WHITE A. H. 
Published: May 2016

AbstractVariation in the components of the complexes (I) and (II) yields spin states such as pure high spin, pure low spin, and spin crossover.
ChemInform Abstract: Structural and Spectroscopic Aspects of a Strained Dicopper Complex with a Tripodal Binucleating Ligand.
Authors: MALONEY J. J. , GLOGOWSKI M. , ROHRBACH D. F. , URBACH F. L. 
Published: May 2016

AbstractThe two complexes (I) with a ligand, which provides two 5‐5‐6 tripodal coordination sites, are characterized by their electronic spectra and an X‐ray structure analysis of (Ib) (space group P1, Z=2).
ChemInform Abstract: Speciation Studies in Relation to Magnesium Bioavailability. Formation of Mg(II) Complexes with Glutamate, Aspartate, Glycinate, Lactate, Pyroglutamate, Pyridoxine and Citrate, and Appraisal of Their Potential Significance Toward Magnesium Gastrointestinal Absorption.
Authors: BLAQUIERE C. , BERTHON G. 
Published: May 2016

AbstractThe formation constants for magnesium complexes with the title ligands are determined under physiological conditions.
ChemInform Abstract: Electrochemistry and Spectroelectrochemistry of Mononuclear and Binuclear Cobalt Phthalocyanines.
Authors: NEVIN W. A. , HEMPSTEAD M. R. , LIU W. , LEZNOFF C. C. , LEVER A. B. P. 
Published: May 2016

AbstractThe electrochemistry of complex (I) and some binuclear analogues (II) and (III) is studied in dichlorobenzene and in dimethylformamide.
ChemInform Abstract: Absence of an Isotope Effect on the Metalation of Chiral Formamidines. The Mechanism of Asymmetric Alkylations Leading to Chiral Amines.
Authors: MEYERS A. I. , DICKMAN D. A. 
Published: May 2016

AbstractLithiation of (S)‐(I) followed by DMSO‐d6 quenching affords the deuterated (S,R)‐formamidine (II) with a diastereomeric ratio SR/SS of 95:5.
ChemInform Abstract: Stereoselective Synthesis of (Z)‐ and (E)‐1,3‐Alkadienes from Aldehydes Using Organotitanium and Lithium Reagents.
Authors: IKEDA Y. , UKAI J. , IKEDA N. , YAMAMOTO H. 
Published: May 2016

AbstractThe titanium reagent generated from the phosphine (I) condenses with the aldehydes (II) to give the (Z)‐dienes (III) with high regio‐ and stereoselectivity.
ChemInform Abstract: Enantioselective Hydrolyses by Baker′s Yeast. Part 2. Esters of N‐Acetyl Amino Acids.
Authors: GLAENZER B. I. + , FABER K. , GRIENGL H. 
Published: May 2016

AbstractA series of racemic esters such as (R,S)‐(I) or (R,S)‐(III) is subjected to the action of fermenting yeast (Saccharomyces cerevisiae).
ChemInform Abstract: Acyclic Stereocontrol in Catalyzed Intramolecular Diels‐Alder Cyclizations Leading to Octahydronaphthalenecarboxaldehydes.
Authors: MARSHALL J. A. , GROTE J. , AUDIA J. E. 
Published: May 2016

AbstractThe Diels‐Alder cyclization of the trienals (Ia), (Ib) with 7‐methoxy, 7‐benzyloxy, or 7‐MOM‐oxy substituents gives the products (IIa), (IIb) + (IIIa), (IIIb) without any diastereoselectivity whereas (Ic), (Id) possessing 7‐silyloxy substituents exhibit high diastereoselectivity yielding predominantly the syn‐isomers (IIIc), (IIId).
ChemInform Abstract: Rearrangement of a Homobrendane to a Perhydro‐1,4‐methanoindene Skeleton. X‐Ray Crystal Structure of a Novel Product.
Authors: KASTURI T. R. , CHANDRA R. , RAMACHANDRA RAMACHANDRA , REDDY S. M. , VENKATESAN K. 
Published: May 2016

AbstractThe tricyclic diols (II), prepared from the hydroxy ketones (I) by Grignard reaction, rearrange in the presence of acids, yielding the ketones (III).
ChemInform Abstract: Halogenation of Phenylacetylene with Alumina Supported Copper(II) Halide.
Authors: KODOMARI M. , SATOH H. , YOSHITOMI S. 
Published: May 2016

AbstractReaction of phenylacetylene (I) with the alumina‐supported copper(II) halides (II) yields mixtures of the monohalides (III), the dihalides (IV) and (V) and the trihalides (VI).
ChemInform Abstract: A New and Convenient Method for the Synthesis of α,β‐Unsaturated Aldehydes.
Authors: LOU J.‐D. , LOU W.‐X. 
Published: May 2016

AbstractUsing the Nef reaction, the 1‐nitro‐2‐alkenes (I) are converted to the α,β‐unsaturated aldehydes (III).
ChemInform Abstract: Syntheses of Diketonic Intermediates for the Total Syntheses of Dihydrojasmone, cis‐Jasmone and d,l‐Muscone Starting from 1,n‐Di(1‐methyl‐ 1H‐imidazol‐2‐yl)‐1,n‐alkanedione.
Authors: OHTA S. , HAYAKAWA S. , TAMAI Y. , YUASA T. , OKAMOTO M. 
Published: May 2016

AbstractN‐Methylimidazole (II) is coupled with the amides (I) to give the imidazolyl ketones (III).
ChemInform Abstract: Synthesis of Methyl Azuleno(1,2‐b)azulene‐2‐carboxylate and Dimethyl Azuleno(1,2‐b)azulene‐2,4‐dicarboxylate.
Authors: KURODA S. , HIROOKA S. , IWAKI H. , IKEDA M. , NAKAO T. , OGISU M. , YASUNAMI M. , TAKASE K. 
Published: May 2016

AbstractThe monoacetal (II), prepared by selective hydrolysis of the bisacetal (I), is converted to the enamine (IV) which reacts with the cycloheptafuranone (V) to give the adduct (VI).
ChemInform Abstract: Photolysis of 7‐Oxanorbornadienes Condensed with Tropone. A Facile Formation of 6‐Hydroxyazulenes.
Authors: NAKAZAWA T. , ASHIZAWA M. , JINGUJI M. , YAMAGUCHI M. , MURATA I. 
Published: May 2016

Abstract4,5‐Dehydrotropone (I) undergoes cycloaddition reaction with the furans (II) to yield the oxanorbornadienes (III) which are photolytically cleaved, forming the hydroxyazulenes (IV) ‐ (VII).
ChemInform Abstract: Stereospecific Oxygenation of 3‐Adamantylidenetricyclo(3.2.1.02,4)octane: Singlet Oxygen vs. Electron‐Transfer Oxygenations.
Authors: AKASAKA T. , ANDO W. 
Published: May 2016

AbstractOxidation of the title compound (I) with the endo‐peroxide (II) in CH2Cl2 leads stereospecifically to endo‐(III) (yield 90%) via 1O2.
ChemInform Abstract: Synthesis of 1,3‐Dimethyladamantane from Tetracyclo(6.2.1.13,6.02,7)dodecane.
Authors: HONNA K. , ICHIKAWA H. , MIZOGAMI S. , SUGIMOTO M. 
Published: May 2016

AbstractThe synthesis of the adamantane derivatives (VII) and (VIII) is achieved by a four‐step procedure using cyclopentadiene (I), ethylene (II), and hydrogen as starting materials.
ChemInform Abstract: Reaction of Isocyanates with Arylsulfonic Hydrazides in the Presence of Fe(III) or Zinc(II) Acetylacetonate in Benzene.
Authors: GREKOV A. P. , SAVEL'EV YU. V. , VESELOV V. YA. 
Published: May 2016

AbstractThe isocyanates (I) react with the sulfonic hydrazides (II), producing the sulfonyl semicarbazides (III).
ChemInform Abstract: A Novel Electrooxidative Methoxylation of Cyanomethyl Sulphides.
Authors: KIMURA M. , KOIE K. , MATSUBARA S. , SAWAKI Y. , IWAMURA H. 
Published: May 2016

AbstractElectrolytic α‐methoxylation of the S‐substituted acetonitriles (I) yields the cyanomonothioacetals (II).
ChemInform Abstract: Synthesis of 1,1′‐Biindenes and 3,3′‐Biindenes.
Authors: NICOLET P. , SANCHEZ J.‐Y. , BENABOURA A. , ABADIE M. J. M. 
Published: May 2016

AbstractThe indenes (I) are converted to the 1,1'‐biindenes (II) by reaction with butyllithium and copper(II) chloride.
ChemInform Abstract: Hydroxy Substituted 10‐Ethyl‐9‐phenylphenanthrenes: Compounds for the Investigation of the Influence of E,Z‐Isomerization on the Biological Properties of Mammary Tumor Inhibiting 1,1,2‐Triphenylbutenes.
Authors: SCHNEIDER M. R. , SCHILLER C.‐D. 
Published: May 2016

AbstractThe triphenylalkenes (I) are photochemically cyclized in the presence of iodine, yielding the phenanthrenes (II).
ChemInform Abstract: A New Approach to Linear Tetracycles via Michael Reactions of Quinizarinquinone with O‐Silylated Ketene Acetals.
Authors: HAYAKAWA K. , ASO M. , KANEMATSU K. 
Published: May 2016

AbstractThe quinone (I) and the acetal (II) form the adduct (III) which rearranges to give the products (IV) or (VI).
ChemInform Abstract: Regioselective Acylation of 1,4:3,6‐Dianhydro‐D‐glucitol.
Authors: STOSS P. , MERRATH P. , SCHLUETER G. + 
Published: May 2016

AbstractAcylation of 1,4:3,6‐dianhydro‐D‐glucitol (I) with the anhydrides (II) in the presence of lead(II) yields the 5‐endo‐acylates (III) as the main products, whereas on heating without a catalyst, predominantly the 2‐exo‐acylates (IV) are formed.
ChemInform Abstract: Synthesis and Physical Properties of First 5,5′‐Bridged Bis(1,3‐dithiolylium‐4‐olates).
Authors: GOTTHARDT H. , PFLAUMBAUM W. 
Published: May 2016

AbstractThe synthesis of the novel title compound (IV) (one of 4 resonating structures is shown in the scheme) is accomplished starting from the bromo acid (Ic) which, in turn, is prepared from (Ia) via (Ib).
ChemInform Abstract: 1,3‐Dipolar Cycloaddition of Pyrazolo(1,2‐a)indazoles with Dimethyl Acetylenedicarboxylate.
Authors: FUJIMURA Y. , NAWATA Y. , HAMANA M. 
Published: May 2016

AbstractThe pyrazoloindazolium bromide (I) and dimethyl acetylenedicarboxylate (II) yield the product (IV) after chromatography.
ChemInform Abstract: Intramolecular Diels‐Alder Cycloaddition of Isoxazole Derivatives Catalyzed by Brnsted Acids.
Authors: BRANDI A. , NUTI P. 
Published: May 2016

AbstractWittig reaction of the isoxazolylmethylenephosphorane (I) and the aldehydes (II) forms the alkenylisoxazoles (III) which give the rearranged products (IV) and (V) or the cycloadducts (VI) and (VII) on thermolysis.
ChemInform Abstract: H2‐Antihistaminics. Part 33. Synthesis and H2‐Antagonistic Activity of Heteroaromatic (Thio)Carboxamides and Triazole(thi)one Derivatives of Piperidinomethylphenoxypropylamine.
Authors: WEGNER K. , KRAEMER I. + , SCHUNACK W. 
Published: May 2016

AbstractThe semicarbazides (I) are converted to the 1,2,4‐triazoles (III) or the pyrazole derivatives (IV) as shown in the reaction scheme.
ChemInform Abstract: Reactions with 3‐Pyrazolin‐5‐ones: Synthesis of 3,4‐Dihydropyridone and Pyrano(2,3‐c)pyrazole Derivatives.
Authors: ELAGAMEY A.‐G. A. , GHALI E. A. , HARB A. F. A. , ELNAGDI M. H. 
Published: May 2016

AbstractThe pyrazolinone (I) derived from antipyrin is coupled with the aromatic aldehydes (II) or the ylidene malononitriles (IV), producing the compounds (III) and (V).
ChemInform Abstract: Electrocyclization of 4‐Azidocoumarins Leading to Benzopyrano(3,4‐d)1,2,3‐triazol‐4‐ones.
Authors: ITO K. , HARIYA J. 
Published: May 2016

AbstractThe 4‐azidocoumarins (II), derived from the chlorides (I), cyclize in the presence of a base, forming the benzopyranotriazolones (III).
ChemInform Abstract: Synthesis of 2,2‐Dimethyl‐2H‐thiochromenes, the Sulfur Analogs of Precocenes.
Authors: TERCIO J. , FERREIRA B. , CATANI V. , COMASSETO J. V. 
Published: May 2016

AbstractThe title compounds (VI) are prepared by Michael addition of the thiophenols (I) to 3‐methyl‐2‐butenoic acid (II), cyclization by PPA, followed by reduction of the carbonyl group and acid catalyzed dehydration.
ChemInform Abstract: Research on Antibacterial and Antifungal Agents. Part 7. Synthesis of (1‐Pyrryl)methylquinolones.
Authors: STEFANCICH G. , CORELLI F. , MASSA S. , SILVESTRI R. , PANICO S. , ARTICO M. , SIMONETTI N. 
Published: May 2016

AbstractThe pyrrylmethylanilines (V), prepared from the nitrophenyl derivatives (I) or (IV), react with the ethoxymethylidenemalonate (VI) to yield the enamines (VII) which are cyclized on heating to form the quinolones (VIII).
ChemInform Abstract: Reaction of Spiro(piperidine‐4,2′‐(1′,2′,3′,4′‐tetrahydroquinazolin))‐ 4′‐ones with Acetic Anhydride.
Authors: YAMATO M. , TAKEUCHI Y. , IKEDA Y. 
Published: May 2016

Abstract2‐Aminobenzamide (Ia) is converted to the spiro compounds (III) which undergo a combined rearrangement and elimination reaction, yielding the heterocycles (IV).
ChemInform Abstract: Simple Preparation of Cyclohex‐2‐ene‐1,4‐dione Monoacetals.
Authors: PAGE P. C. B. , VAN NIEL M. B. 
Published: May 2016

AbstractCycloaddition reaction of the aminoketene dithioacetals (I) with the α,β‐unsaturated carbonyl compounds (II) leads to the formation of the dicarbonyl compounds (IV).
ChemInform Abstract: Demethylations of Methoxypyridazines with Amines.
Authors: NAGASHIMA H. , ODA H. , HAYAKAWA T. , KAJI K. 
Published: May 2016

AbstractChloromethoxypyridazines such as (I) are demethylated by reaction with morpholine (II) and simultanously substituted to form morpholinyl derivatives such as (III) and (IV).
ChemInform Abstract: Stereochemical Studies. Part 106. Saturated Heterocycles. Part 110. Synthesis of Methylene‐Bridged Partially Saturated Quinazolones.
Authors: STAJER G. , SZABO A. E. , FUELOEP F. + , BERNATH G. , SOHAR P. 
Published: May 2016

AbstractThe reaction of the esters (Ia), (Ib) or (Ic), (Id) with imidates (III) yields the di‐endo (II) or di‐exo (IV) methylene‐bridged quinazolinone derivatives (II) or (IV).
ChemInform Abstract: Reaction of Cyclic N,N′‐Disubstituted Thioureas with Carbonyl Activated Dielectrophiles.
Authors: SPINDLER J. , KEMPTER G. 
Published: May 2016

AbstractThe title thioureas (I) or (VIII) react with the diester (III) and the anhydride (V) to afford the heterocyclic compounds (II) and (IV) or (IX) and (X).
ChemInform Abstract: Cycloadditions of Ethyl 2‐Amino‐1‐azaazulene‐3‐carboxylate with Dimethyl Acetylenedicarboxylate.
Authors: ABE N. 
Published: May 2016

AbstractThe aminoazaazulenecarboxylate (I) reacts with dimethyl acetylenedicarboxylate (II), producing a mixture of the cycloadducts (III) ‐ (VI).
ChemInform Abstract: Study of the Pharmacological Properties of Pyridinium Salts, Pyrazolines, and Pyrazoles.
Authors: ZVEZDINA E. A. , ZHDANOVA M. P. , NECHAYUK I. I. , BARCHAN I. A. , SIMKINA YU. N. , BUCHNAYA T. A. 
Published: May 2016

AbstractStarting with the pyrylium perchlorates (I), the pyridinium salts (III), the pyrazolines (V), and the pyrazolopyrimidine (VI) are synthesized as shown in the reaction scheme.
ChemInform Abstract: Synthesis and Antihypertensive Activity of 2‐Imino‐2,3‐dihydro‐5H‐ 1,3,4‐thiadiazolo(2,3‐b)quinazolin‐5‐ones.
Authors: LIU K.‐C. , HU M.‐K. 
Published: May 2016

AbstractHydrazinolysis of isatoic anhydride (I) yields the hydrazides (III).
ChemInform Abstract: Synthesis and Cycloaddition Reaction of 2a,5‐Diazacyclohept(cd)indenes: Formation of Cyclohept(ef)‐6‐azacycl(3.2.2)azine System.
Authors: ABE N. 
Published: May 2016

AbstractThe aminophenylazaazulene (I) and phenacyl bromide (II) are combined to produce the diphenyldiazacycloheptindenes (III).
ChemInform Abstract: Reactions of 2‐Acetyl‐3‐methylquinoxaline 1,4‐Dioxide and Its Derivatives.
Authors: MATOBA K. , TERADA T. , SUGIURA M. , YAMAZAKI T. 
Published: May 2016

AbstractThe cinnamoylmethylquinoxaline dioxide (II) does not undergo intramolecular cyclization on thermolysis, but the deoxygenation product (IIIa) is formed instead.
ChemInform Abstract: Intramolecular 1,3‐Dipolar Cycloadditions of Aryl Azides with Alkynyl Substituents.
Authors: RUDORF W.‐D. , JANIETZ D. 
Published: May 2016

AbstractThe substituted 4‐chlorobutynes (I) react with the potassium salt of o‐acetaminophenol (II) to give the butynes (III).
ChemInform Abstract: Palladium‐Catalyzed Cross Double Carbonylation of Amines and Alcohols: Synthesis of Oxamates.
Authors: MURAHASHI S. , MITSUE Y. , IKE K. 
Published: May 2016

AbstractReaction of the amino alcohols (I) with carbon monoxide (II) and oxygen (III) in the presence of the Pd catalyst (IV) produces the cyclic oxamates (V).
ChemInform Abstract: Activity Against Trypanosoma cruzi of New Analogues of Nifurtimox.
Authors: MESTER B. , ELGUERO J. , CLARAMUNT R. M. , CASTANYS S. , MASCARO M. L. , OSUNA A. , VILAPLANA M. J. , MOLINA P. 
Published: May 2016

AbstractThe analogues (III) of nifurtimox are obtained by coupling 5‐nitrofurfural (I) with the amino derivatives (II).
ChemInform Abstract: Synthesis of Some New Fluorosubstituted Tricyclic Heterocycles. Part 2. 3‐Alkoxy‐7‐fluoro‐10‐(3‐(4‐(2‐hydroxyethyl)‐1‐piperazinyl)propyl)‐2‐ methoxy Phenothiazine Derivatives.
Authors: TAMBI S. B. , ANAND M. , BHARGAVA N. , MITAL R. L. 
Published: May 2016

AbstractThe phenothiazine derivatives (III), (V), and (VI) are synthesized from (I) by substitution reactions and oxidation.
ChemInform Abstract: Oxamic Acid Derivatives in Heterocyclic Synthesis: Preparation of 1,4‐Oxazine and 1,2,4‐Triazino(5,6‐e)(1,3,4)oxadiazine Derivatives.
Authors: MOLINA P. , TARRAGA A. , ESPINOSA A. , LIDON M. J. 
Published: May 2016

AbstractThe oxamoyl chlorides (I) are converted to the 1,4‐oxazine derivatives (IV) and (V) via the oxamides (III).
ChemInform Abstract: A New Synthesis of Pyrimido(4,5‐b)(1,5)benzodiazepin‐2‐one and ‐2‐thione Derivatives.
Authors: TAKAGI K. , MORITA H. , AOTSUKA T. , OKAMOTO Y. 
Published: May 2016

AbstractCoupling of the heterocyclic amine (I) with the iso(thio)cyanates (II) and subsequent cyclization of (III) yield the pyrimidobenzodiazepines (IV).
ChemInform Abstract: Phosphorylation of Benzohomologues of N‐Heterocycles in the Benzene Ring.
Authors: TOLMACHEV A. A. , KOZLOV E. S. , PINCHUK A. M. 
Published: May 2016

AbstractPd(0)‐catalyzed reaction of the bromo compounds (I) with diethyl phosphite (II) gives the phosphonates (III).
ChemInform Abstract: α‐Chlorination and Carbonylolefination: Synthesis of Phenyl 1‐Chloro‐1‐ alken‐1‐yl Selenides (Chlorovinyl Phenyl Selenides).
Authors: COUTROT P. , GRISON C. , YOUSSEFI‐TABRIZI M. 
Published: May 2016

AbstractThe selenenylmethanephosphonate (V), prepared from the iodomethane derivative (I) via the Grignard compound (III), reacts consecutively with butyllithium, tetrachloromethane, and the carbonyl compounds (VII) in a one‐pot procedure, yielding the olefins (VIII).
ChemInform Abstract: Basicity of Nitrogen Donors in an Amino‐Substituted Methylmercury Derivative of Adenine. Crystal Structure of μ‐(Adeninato‐μ‐N6,N9)‐bis(methylmercury(II))·ethanol.
Authors: CHARLAND J.‐P. 
Published: May 2016

AbstractThe title compound is isolated from an ethanolic 2:1 solution of Me‐Hg‐OH and adenine and investigated by X‐ray analysis (space group P21/c; Z = 8).
ChemInform Abstract: Structure and Reactivity of N‐(Arenesulfonyl)diorganyliminostannanes.
Authors: KHMARUK A. M. , POVOLOTSKII M. I. , OLEINIK V. A. , PINCHUK A. M. 
Published: May 2016

AbstractThe dimeric or trimeric title compounds (IV) are obtained from the stannanes (I) and the N,N‐dibromosulfonamides (II) via the monomeric compounds (III).
ChemInform Abstract: Complexes with the Di‐μ‐alkoxy‐tetrakisphenyldiazenido‐dimolybdenum Core, (Mo2(NNPh)4(OR)2)2+. The Synthesis and Structural Characterization of the Phenylhydrazino Derivative, (Mo2(NNPh)4(OMe)4(H2NNHPh)2).
Authors: HSIEH T.‐C. , ZUBIETA J. 
Published: May 2016

AbstractThe title complex (II), the first example of a molybdenum‐diazenido‐hydrazino complex, is prepared by the reaction of (I) with phenylhydrazine in methanol (no yield given).
ChemInform Abstract: Synthesis, Characterization and Antitumor Activity of Iron(II) and Iron(III) Complexes of 3‐ and 5‐Substituted Salicylaldehyde Benzoyl Hydrazones.
Authors: MOHAN M. , GUPTA N. S. , KUMAR A. , KUMAR M. 
Published: May 2016

AbstractThe tridentate Schiff base ligands, prepared by condensation of benzoylhydrazide with the various substituted salicylaldehydes, react in ethanol under reflux with FeSO4·7 H2O or FeCl3 to yield the Fe(II) and Fe(III) complexes (I)‐(III) (no yields given).
ChemInform Abstract: Redox Chemistry of Tetrakis(1‐norbornyl)cobalt. Synthesis and Characterization of a Cobalt(V) Alkyl and Self‐Exchange Rate of a Co(III)/Co(IV) Couple.
Authors: BYRNE E. K. , THEOPOLD K. H. 
Published: May 2016

AbstractWhile the known reaction of the THF adduct of CoCl2 with norbornyllithium in pentane yields the title compound (III), the reaction in Et2O/THF (30:1) gives the paramagnetic, air‐sensitive compound (II).
ChemInform Abstract: Some New Derivatives of Co(III) with Uracil, Uridine and Pyrimidine Nucleotides.
Authors: FIOL J. J. , TERRON A. , MULET D. , MORENO V. 
Published: May 2016

AbstractStarting with the complexes trans‐(Co(en)2Cl2)Cl and (Co(NH3)5Cl)Cl2 the reaction with uracil and uridine in ethylacetate under reflux and with the sodium salts of the nucleotides yields the compounds (I)‐(IV), respectively (no yields given).
ChemInform Abstract: Photosensitive 1:1 Adduct between Bis(1,2‐diphenyl‐1,2‐ethylenedithiolato)nickel(0) and Quadricyclane.
Authors: KAJITANI M. , KOHARA M. , KITAYAMA T. , ASANO Y. , SUGIMORI A. 
Published: May 2016

AbstractThe Ni‐complex (I) reacts with quadricyclane (II) to form the 1:1 adduct (III) which is also obtained from (I) and norbornadiene (IV), together with the by‐product (V).
ChemInform Abstract: An Unusual μ‐Olato‐μ‐Phenolato‐Bridged Dicopper(II) Complex, Cu2(L‐H)(L‐2H)ClO4 (L: 2‐((2‐((o‐Hydroxy‐α‐methylbenzylidene)amino)ethyl)amino)ethanol), with Quasi‐Orthogonal Coordination Planes.
Authors: CROS G. , LAURENT J.‐P. , DAHAN F. 
Published: May 2016

AbstractThe title complex (I) is prepared by reaction of Cu(ClO4)2·6 H2O with the condensation product of N‐(2‐hydroxyethyl)ethylenediamine and 2‐hydroxyacetophenone, the title ligand, in MeOH in the presence of NEt3.