bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Cyclic Organophosphorus Compounds. Part 23. Configurational Assignments in the 4‐Phenyl‐1,3,2λ5‐dioxaphosphorinane Series. X‐Ray Molecular Structure of cis‐2‐Benzylamino‐4‐phenyl‐1,3,2‐dioxaphosphorinane 2‐Oxide.
Authors: EDMUNDSON R. S. , FORTH I. , KING T. J. 
Published: May 2016

AbstractChlorine displacement in (I) by the amine (II) gives the cis product (III) (space group C2/c).
ChemInform Abstract: Complex Hydrogen‐Bonded Cations. X‐Ray Crystal Structure of (((C6H5CH2)NH3)4Cl) (AlCl4)3 and Its Relevance to the Structure of Basic Chloroaluminate Room‐Temperature Melts.
Authors: DUBOIS R. H. , ZAWOROTKO M. J. , WHITE P. S. 
Published: May 2016

AbstractThe title compound (IV) crystallizes in P1.
ChemInform Abstract: Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 85. Synthesis of Chain and Ring Compounds Containing Molybdenum.
Authors: DAVIES S. J. , STONE F. G. A. 
Published: May 2016

AbstractReactions between (I) and (II) afford the trimetal compounds (IIIa) and (IIIb) which are important precursors for the tetra‐ and pentanuclear complexes (IV) and (V).
ChemInform Abstract: Reduction of Ammonium Pertechnetate and Ammonium Perrhenate with CO: Synthesis of M2(CO)10 (M: Tc, Re) and Crystal and Molecular Structure of the Trinuclear Cyano‐Bridged Derivative Re3(CN)3(CO)12.
Authors: CALDERAZZO F. , MAZZI U. , PAMPALONI G. , POLI R. , TISATO F. , ZANAZZI P. F. 
Published: May 2016

AbstractThe decacarbonyl (III) and (VI) are obtained by CO reduction of (I) and (V), respectively, under high pressure and high temperature.
ChemInform Abstract: A 1,10‐Phenanthroline Adduct Complex of Bis(N,N‐diethyldithiocarbamato)nickel(II).
Authors: EMMENEGGER F. P. 
Published: May 2016

AbstractThe first example of the addition of a chelating diamine to a square‐planar bis(dithiocarbamato)nickel(II) complex (acetone, 50 °C) to form the title complex (I) is reported.
ChemInform Abstract: Five‐Coordinate Olefinic Complexes of Platinum(II) Containing σ‐Bonded Carbon Ligands. σ,π‐Methoxyenyl Complexes and the Molecular Structure of Chloro((1,4,5‐η3)‐8‐methoxy‐4‐cycloocten‐1‐yl)(2,9‐dimethyl‐1,10‐phenanthro# line)platinum(II).
Authors: ALBANO V. G. , CASTELLARI C. , MORELLI G. , VITAGLIANO A. 
Published: May 2016

AbstractBy splitting the binuclear complexes (I) with bidentate nitrogen ligands such as (II) the five‐coordinate complexes (III) are prepared.
ChemInform Abstract: Total Synthesis of 6‐Methyl‐5‐androstene‐3,11,17‐trione 3‐Ethylene Acetal, Building Block for 6α‐Methylprednisolone.
Authors: DANIEWSKI A. R. , PIOTROWSKA E. 
Published: May 2016

AbstractThe title compound (XII) represents a suitable precursor for 6α‐methylprednisolone (XIII) which is known to possess a higher antiinflammatory activity than natural cortisone or hydrocortisone.
ChemInform Abstract: Amino Acids and Peptides. Part 70. Optically Active α‐Amino Acids, N‐Boc‐Amino Aldehydes, and α‐Amino‐β‐hydroxy Acids from 2,3‐Epoxy Alcohols.
Authors: SCHMIDT U. , RESPONDEK M. , LIEBERKNECHT A. , WERNER J. , FISCHER P. 
Published: May 2016

AbstractThe 2,3‐epoxy alcohols (I) are converted to the trichloroacetimidic esters (III) which undergo Lewis acid‐induced rearrangement, forming the oxazolines (IV) and/or the dihydrooxazines (V) depending on the structure of the educts and the catalyst.
ChemInform Abstract: A Novel and Stereocontrolled Synthesis of (5R)‐Z‐6‐(1‐Methyl‐1,2,3‐triazol‐4‐ylmethylene)penem‐3‐carboxylic Acid, a Potent Broad Spectrum β‐Lactamase Inhibitor.
Authors: OSBORNE N. F. , BROOM N. J. P. , COULTON S. , HARBRIDGE J. B. , HARRIS M. A. , STIRLING‐FRANCOIS I. , WALKER G. 
Published: May 2016

AbstractChiral 6‐aminopenicillanic acid (I) is transformed into the 6‐bromopenemcarboxylate (IX) which is coupled with the triazolecarboxaldehyde (X) to yield the triazolylacetoxymethyl derivative (XII).
ChemInform Abstract: Synthesis of Cu‐In‐S Compounds and Their Photoelectrochemical Characterization.
Authors: MINOURA H. , UENO Y. , KAIGAWA H. , SUGIURA T. 
Published: May 2016

AbstractCuInS2 (I), CuIn5S8 (II), and CuIn11S17 (III) are synthesized in high yields by homogeneous precipitation of (Cu2S)x(In2S3)1‐x from Na2S2O3 solutions containing appropriate amounts of CuCl2, InCl3 and HOAc and subsequent annealing of the precipitates at 600 °C. Polycrystalline electrodes of n‐type (II) or (III) yield anodic photocurrents of ∼16 mA/cm2 and energy conversion efficiencies as high as 3.3‐3.4% under white light illumination (100 mV/cm2), whereas poor photoresponse is observed for (I).
ChemInform Abstract: Electrical Conduction in γ Irradiated and Unirradiated Fe3O4, CdFe2O4 and CoxZn1‐xFe2O4 (0 ≤ x ≤ 1) Ferrites.
Authors: MOUSA M. A. , SUMMAN A. M. , AHMED M. A. , BADAWY A. M. 
Published: May 2016

AbstractFe3O4 (I), ZnFe2O4 (II), and CdFe2O4 (III) show n‐type conduction, CoFe2O4 (IV) exhibits p‐type conduction, and for CoxZn1‐xFe2O4 (V) it is found that the type of conduction varies with the composition of the ferrites.
ChemInform Abstract: The Phase Diagrams of the Systems Na3AlF6‐Fe0.947O and Na3AlF6‐FeF2 and Related Activities of FeF2 from EMF Measurements.
Authors: JOHANSEN H. G. , STERTEN A. , THONSTAD J. 
Published: May 2016

AbstractPhase diagram investigations (thermal, chemical, and X‐ray analysis), performed in connection with a study of the behavior of iron impurities in the Al production process, show the title systems to be simple eutectic systems.
ChemInform Abstract: Thermal Dehydration of Crystalline NiSO4·6 H2O.
Authors: SINHA S. G. , DESHPANDE N. D. , DESHPANDE D. A. 
Published: May 2016

AbstractThe title compound, synthesized by evaporation of supersaturated aqueous nickel sulfate solutions, shows successive loss of 1 mol, 2 mol, 2 mol and 1 mol of water upon heating, thus confirming the proposed 4‐step dehydration mechanism.
ChemInform Abstract: Optical Resolution of 2′‐Methoxy‐1,1′‐binaphthyl‐2‐carboxylic Acid, and Application as Chiral Derivatizing Agent for HPLC Separation of Enantiomeric Alcohols and Amines.
Authors: MIYANO S. , OKADA S. , HOTTA H. , TAKEDA M. , KABUTO C. , HASHIMOTO H. 
Published: May 2016

AbstractThe (aS) title compound (Ia), obtained by resolution of the racemate by use of (‐)‐menthol, is converted to its acid chloride (Ib).
ChemInform Abstract: para‐Quinone Methide‐Initiated Intramolecular Electrophilic Substitution Reactions.
Authors: ANGLE S. R. , LOUIE M. S. , MATTSON H. L. , YANG W. 
Published: May 2016

AbstractThe 4‐allylphenol (I) is converted to the p‐bromopropylphenyl silyl ether (III) which undergoes substitution with the sodium salt (IV) or the Grignard compounds (VI) to form the (het)aryl derivatives (V).
ChemInform Abstract: Oxidation of Methoxy‐ and/or Methyl‐Substituted Benzenes and Naphthalenes to Quinones and Phenols by H2O2 in HCOOH.
Authors: ORITA H. , SHIMIZU M. , HAYAKAWA T. , TAKEHIRA K. 
Published: May 2016

AbstractThe oxidation of a number of arenes with H2O2 in HCOOH to give quinones and phenols is studied.
ChemInform Abstract: Reduction of Tellurium‐Carbon Bonds of Tellurolactones and Telluroethers.
Authors: COMASSETO J. V. , FERRAZ H. M. C. , BRANDT C. A. , GAETA K. K. 
Published: May 2016

AbstractThe tellurium‐substituted lactones (I) and (III) or cyclic ethers (V) and (VII) are reduced with tributyltin hydride to form the corresponding detellurinated derivatives.
ChemInform Abstract: Reductive Isomerization of Halo Derivatives of 2,2‐Diarylethanes.
Authors: PARNES Z. N. , ROMANOVA V. S. , VOL'PIN M. E. 
Published: May 2016

AbstractReductive treatment of the tri‐, di‐ and monochlorosubstituted geminal diarylethanes (I), (III) or (IV) according to method A) causes hydrogenolysis accompanied by rearrangement to give the 1,2‐diarylethanes (II).
ChemInform Abstract: A Novel Method for Copper(II)‐Catalyzed Coupling Reactions of Triflates with Grignard Reagents.
Authors: KOTSUKI H. , KADOTA I. , OCHI M. 
Published: May 2016

AbstractThe crude triflates (III), generated from the alcohols (I), are treated with the Grignard agents (IV) in the presence of cuprous bromide, yielding the C‐C coupling products (V).
ChemInform Abstract: Synthesis of Long Chain Alkyl Azides and Investigation of Their Aggregation in Formamide Solution.
Authors: MARTI M. J. , RICO I. , ADER J. C. , DE SAVIGNAC A. , LATTES A. 
Published: May 2016

AbstractThe alkyl bromides (I) react with sodium azide (II) in water or formamide in the presence of a phase‐transfer catalyst to form the azides (III).
ChemInform Abstract: Synthesis of N‐Substituted Difluoromalonic and Tetrafluorosuccinic Diamides and X‐Ray Study of Tetrafluorosuccinic Bis(2‐carboxyethylamide).
Authors: FOKIN A. V. , MARTYNOV I. V. , CHEKHLOV A. N. , RAPKIN A. I. , TATARINOV A. S. 
Published: May 2016

AbstractStarting with the perfluorinated alkylenedibromides (I), the title compounds (VI) and (VIII) are prepared via the fluorosulfonates (II) and the methyl esters (IV).
ChemInform Abstract: Cyclopropenone Chemistry. Part 11. Chlorofluorocarbene Addition to Alkynes: A Novel Path to Cyclopropenones with Uncommon Substituents.
Authors: DEHMLOW E. V. , WINTERFELDT A. 
Published: May 2016

AbstractIn contrast to dichlorocarbene, chlorofluorocarbene reacts with sterically demanding alkynes, e.g. (Ib), to give the corresponding cyclopropene derivatives.
ChemInform Abstract: Preparation of Unsaturated α,α‐Dichloro Acid Chlorides and Intramolecular (2 + 2) Cycloadditions of the α‐Chloroketenes Reductively Generated from Them. Effect of Double Bond Geometry on the Cycloaddition.
Authors: SNIDER B. B. , WALNER M. 
Published: May 2016

AbstractThe title reaction leads to cycloadducts of type (V) or type (XIV).
ChemInform Abstract: Tricyclo(3.3.0.02,8)oct‐3‐enes: Their Acid Cleavage Reactions and Cycloadditions with Dienophiles.
Authors: FENTON G. A. , GILBERT A. 
Published: May 2016

AbstractThe title compounds (I), obtained by meta photocycloaddition of ethenes to benzenes, undergo acid‐catalyzed cleavage of the cyclopropane ring to give the bicyclo(3.2.1) and/or (3.3.0)octanes (II) and/or (III).
ChemInform Abstract: Five‐Membered 2,3‐Dioxoheterocycles. Part 12. Thermolysis of 1‐Aryl‐4‐aroyl‐5‐methoxycarbonyl‐2,3‐dihydro‐2,3‐pyrrole‐diones.
Authors: MASLIVETS A. N. , KRASNYKH O. P. , SMIRNOVA L. I. , ANDREICHIKOV YU. S. 
Published: May 2016

AbstractThe title compounds (I) are prepared according to a known procedure.
ChemInform Abstract: Mannich Reactions of Oxazolidines.
Authors: FAIRHURST R. A. , HEANEY H. , PAPAGEORGIOU G. , WILKINS R. F. , EYLEY S. C. 
Published: May 2016

Abstract3‐Methyloxazolidine (I) is cleaved and coupled with the heterocycles (III), the phenols (V), or silyl enol ethers (VII) to produce the amino ethanol derivatives (IV), (VI), or (VIII).
ChemInform Abstract: Cycloaddition Reactions. Part 49. Synthesis of Dihydro‐ and Tetrahydroisoxazolo(3′,4′:3,4)pyrrolo(1,2‐a)indoles via Intramolecular Cycloadditions. A Novel Class of Mitomycin Analogues.
Authors: BHUYAN P. J. , BORUAH R. C. , SANDHU J. S. 
Published: May 2016

Abstract3‐Methylindole (I) is converted to the aldehydes (IV) via coupling with the allylic halides (II) and Vilsmeier formylation.
ChemInform Abstract: Use of Organometallic Complexes of Ruthenium in the Lewis Acid‐Catalyzed Hetero Diels‐Alder Reaction.
Authors: FALLER J. W. , SMART C. J. 
Published: May 2016

AbstractHetero Diels‐Alder reaction of Danishefsky's diene (I) and benzaldehyde (II) in the presence of a Ru(I) catalyst forms the methoxydihydropyran (III).
ChemInform Abstract: Quinoxalines. Part 27. Synthesis of Bis‐azolo(a,c)‐fused Quinoxalines. Part 2. Synthesis from Azolo(a)quinoxaline‐4‐carbaldehydes.
Authors: VOGEL M. , LIPPMANN E. 
Published: May 2016

AbstractThe novel ring system present in the compounds (IV)‐(VII), described in the preceding paper, is synthesized by an alternative route as shown for (IV).
ChemInform Abstract: Synthesis and Characterization of 2‐Alkoxy(aryloxy)‐4,6‐diphenyl‐1,3,5‐triazines.
Authors: HILLER W. , BAUER M. , RUHMANN R. 
Published: May 2016

AbstractCompounds (III) are prepared by reaction of the triazine (I) with the corresponding alcohols in the presence of a base.
ChemInform Abstract: Synthesis and Reaction of 1,2,4‐Trioxanes.
Authors: FUJISAKA T. , MIURA M. , NOJIMA M. , KUSABAYASHI S. 
Published: May 2016

AbstractVarious reactions of peroxides such as (I) or (V) with epoxides such as (II) or (VI) are carried out with WO3 and catalytic amounts of Cl‐SO3H to give corresponding 1,2,4‐trioxanes such as (III) or (VII).
ChemInform Abstract: Strategy for the Synthesis of Unsymmetrical N‐Substituted Polyazamacrocycles.
Authors: GU K. , MERTES K. B. , MERTES M. P. 
Published: May 2016

AbstractThe synthesis of the difunctional polyether polyamine (VIIIc) from the N‐tosylated amino alcohols (I) and (V) is performed as shown in the reaction scheme.
ChemInform Abstract: Reaction of Red Phosphorus with Benzyl Halide in a Superbasic System.
Authors: GUSAROVA N. K. , TROFIMOV B. A. , MALYSHEVA S. F. , RAKHMATULINA T. N. , VYALYKH E. P. , VORONKOV M. G. 
Published: May 2016

AbstractRed phosphorus (I) reacts with benzyl chloride (II) in the system KOH/DMSO or KOH/HMPA to produce the phosphine oxide (III).
ChemInform Abstract: Synthesis and Molecular Structure of CH3(2,6‐((C2H5)2NCH2)2C6H3)InCl, an Intramolecular Stabilized Monomeric Diorganoindium Chloride.
Authors: SCHUMANN H. , WASSERMANN W. , DIETRICH A. 
Published: May 2016

AbstractIndium trichloride (I) reacts with 2,6‐bis‐(dimethylaminomethyl)phenyllithium (II) to form 2,6‐bis‐(dimethylaminomethyl)phenylindium dichloride (III).
ChemInform Abstract: Syntheses and Crystal Structures (No Au‐H Interactions) of Luminescent (Au2(dppm)2) (BH3CN)2 and of (Au2(dppm)2(I)) (Au(CN)2) and (Au2(dppm)2(S2CNEt2)) (BH3CN).
Authors: KHAN MD. N. I. , KING C. , HEINRICH D. D. , FACKLER J. P. JUN. , PORTER L. C. 
Published: May 2016

Abstract(III), recrystallized from CH2Cl2, crystallizes in P21/n with Z=2 and contains 2 mole CH2Cl2, whereas on recrystallization from MeCN the same complex crystallizes in P1.
ChemInform Abstract: A New Two‐Carbon Olefin Homologation Procedure That Leads to α‐Chloroenones. An Efficient Synthesis of dl‐Muscone.
Authors: DEPRES J.‐P. , NAVARRO B. , GREENE A. E. 
Published: May 2016

AbstractThe dichloroketene‐olefin adducts (III) are easily converted to the chloroenones (VI) and (VII).
ChemInform Abstract: Electron Spin‐Echo and Electron Spin‐Resonance Studies of Cupric Ion‐Adsorbate Interactions in Hydrogen, Sodium, Potassium, and Calcium Mordenite.
Authors: SASS C. E. , KEVAN L. 
Published: May 2016

AbstractESR and ESEM studies of the interactions between Cu2+ and polar and nonpolar adsorbates as H2O, MeOH, EtOH, NH3, and C2H6 reveal that Cu2+ coordinates to two H2O or NH3 molecules in the Na, K, and Ca forms of mordenite but to only one molecule of MeOH.
ChemInform Abstract: Photocatalytic Activities of Microcrystalline TiO2 Incorporated in Sheet Silicates of Clay.
Authors: YONEYAMA H. , HAGA S. , YAMANAKA S. 
Published: May 2016

AbstractCompared to those of TiO2 powder particles, showing the quantum size effect, TiO2 microcrystallites incorporated in the interlayer of montmorillonite having ca. 15‐Å pillar height show a ca. 0.58‐eV blue shift in its absorption and fluorescence spectra.
ChemInform Abstract: Synthesis of Zinc Borohydride and Its Derivatives by Mechanical Activation of Mixtures of the Borohydrides of Alkali Metals and Zinc Chloride.
Authors: MAL'TSEVA N. N. , MYAKISHEV K. G. , SAIDOV B. I. , KEDROVA N. S. , GORBACHEVA I. I. , POTAPOVA O. G. , VOLKOV V. V. 
Published: May 2016

AbstractThe reactions between mechanically activated ZnCl2 and MBH4 (M: Li, Na, K) are found to proceed at room temp. to afford Zn(BH4)2 or its 1:1 complexes with MBH4, e.g. LiBH4·Zn(BH4)2.
ChemInform Abstract: Neutral and Ionic Metal‐Hydrogen and Metal‐Carbon Bond Energies: Reactions of Co+, Ni+, and Cu+ with Ethane, Propane, Methylpropane, and Dimethylpropane.
Authors: GEORGIADIS R. , FISHER E. R. , ARMENTROUT P. B. 
Published: May 2016

AbstractThe emphasis of the study is on C‐H and C‐C bond cleavage channels from which bond dissociation energies for M‐H, M‐CH3 and M+‐CH3 are derived from the endothermic reaction thresholds.
ChemInform Abstract: Reductive Transformations of Polyfunctional Nitro Compounds: Synthesis of Methyl 7‐Aminoalkanoates and Five‐Membered Cyclic Nitrones ‐ Inter‐ and Intramolecular 1,3‐Dipolar Cycloadditions.
Authors: ZSCHIESCHE R. , REISSIG H.‐U. 
Published: May 2016

AbstractOn treatment with NH4+HCOO‐ and Pd‐C, the nitro group of the protected nitroketones (Ia), (Ib) is only reduced to the respective amine, whereas the unprotected nitroketones (II) give the five‐membered nitrones (III) under the same conditions.
ChemInform Abstract: Transformation of N‐Tosyl‐2‐(1,3‐butadienyl)aziridine into N‐Tosyl‐2‐ethenyl‐3‐pyrroline.
Authors: FUGAMI K. , MIURA K. , MORIZAWA Y. , OSHIMA K. , UTIMOTO K. , NOZAKI H. 
Published: May 2016

AbstractButadienyl‐aziridines such as (I) or ‐azetidines such as (III) activated by N‐tosyl groups rearrange smoothly to vinyl pyrroline derivatives such as (II) or vinylpiperidines such as (IV) in the presence of a catalytic amount of Pd(PPh3)4.
ChemInform Abstract: Synthesis of Perfluorochemicals for Use as Blood Substitutes. Part 4. Electrochemical Fluorination of N‐Cycloalkylpyrrolidines and ‐piperidines.
Authors: ONO T. , INOUE Y. , ARAKAWA Y. , NAITO Y. , FUKAYA C. , YAMANOUCHI K. , YOKOYAMA K. 
Published: May 2016

AbstractThe title reaction gives a range of perfluorinated amines as outlined in the reaction scheme.
ChemInform Abstract: Reactions of Norbornyl Aldehydes with Diiron Nonacarbonyl: A Stereoselective Pathway to “Geminal‐Faced” Esters and Alcohols.
Authors: BANKSTON D. 
Published: May 2016

AbstractThe norbornanecarbaldehyde (I) reacts with diiron nonacarbonyl to give the ester (II), together with the alcohol (III).
ChemInform Abstract: Palladium‐Catalyzed Acyldemetallation and Carbonylation Reactions of Organomercurials for the Synthesis of Unsymmetrical Ketones.
Authors: BUMAGIN N. A. , MORE P. G. , BELETSKAYA I. P. 
Published: May 2016

AbstractThe organomercurials (I) react with the acyl chlorides (II) in the presence of a Pd‐catalyst and sodium iodide to form the unsymmetrical ketones (III), together with the homo‐coupling products (IV).
ChemInform Abstract: Reaction of Thiazolo(3,2‐a)benzimidazol‐3‐one with Electrophiles.
Authors: AUGUSTIN M. , DOELLING W. + , ELIAS D. 
Published: May 2016

AbstractA known reaction of (I) is extended to other benzaldehydes such as (II) (→ (III), no further details given).
ChemInform Abstract: Thermal Reactions of Arylamidoximes.
Authors: DA COSTA LEITE L. F. C. , SRIVASTAVA R. M. , CAVALCANTI A. P. 
Published: May 2016

AbstractIn contrast to previous work, which demonstrated the need for an acid in the transformation of arylamidoximes to bis‐aryl‐oxadiazoles, it is shown now that the thermal treatment of oximes, e.g. (I), also leads to the desired oxadiazoles such as (II).
ChemInform Abstract: Nucleophilic Substitutions at Ozonides.
Authors: GRIESBAUM K. , VOLPP W. , HUH T.‐S. 
Published: May 2016

AbstractThe ozonides (II) and (VIII), generated from the olefins (I) or (VII), form the cationic degradation product (III) which reacts with the alcohols (IV) to form the oxyozonides (V).
ChemInform Abstract: Iodine Oxidation of α‐Tocopherol and Its Model Compound in Alkaline Methanol: Unexpected Isomerization of the Product Quinone Monoketals.
Authors: OMURA K. 
Published: May 2016

AbstractThe reaction mentioned in the title is performed at 10°C to give the quinone acetals (III) which isomerize at 50°C, forming the methoxy derivatives (IV).
ChemInform Abstract: Reactions of Nitriles with Polyhedral Borane Anions. Reductive‐Cyclocondensation and Carbon‐Insertion Reactions: Syntheses of hypho‐5‐CH3‐5,11,7,14‐CNS2B7H9 and nido‐6‐CH3‐5,6,9‐C3B7H10.
Authors: KANG S. O. , FURST G. T. , SNEDDON L. G. 
Published: May 2016

AbstractThe reactions of acetonitrile (II) with the anions of the two isoelectronic arachno clusters (I) and (IV) are explored and found to result in reduction of the nitrile and either the incorporation of a CN unit into the cage framework giving the air‐stable cluster (III) or a one‐carbon insertion accompanied by deamination yielding the new three‐carbon nido‐carborane (V) as the sole product.
ChemInform Abstract: Tris(trimethylsilyl)methanetellurenyl Halides (Me3Si)3CTeX (X: Cl, Br, I): Synthesis of Stable Alkanetellurenyl Halides.
Authors: GISELBRECHT K. , BILDSTEIN B. , SLADKY F. 
Published: May 2016

AbstractBy halogenolysis of (I) the first stable and isolable alkanetellurenyl halides (IV) are obtained.
ChemInform Abstract: Synthesis of Phospha‐ and Diphosphatitanocene Dichlorides. Crystal and Molecular Structures of Bis(η5‐3,4‐dimethylphospholyl)dichlorotitanium(IV) and of (η5‐3,4‐Dimethylphospholyl)trichlorotitanium(IV).
Authors: NIEF F. , RICARD L. , MATHEY F. 
Published: May 2016

AbstractDepending on the conditions used the reaction of the phospholes (I) with TiCl4 (II) or (C5H5)TiCl3 (V) yields the complexes (III), (IV) (yields not given) or (VI).
ChemInform Abstract: Synthesis of Pentacarbonyl(2,3‐dialkoxycyclopropenylidene)chromium(0), ‐molybdenum(0), and ‐tungsten(0) Complexes by Reaction of Metal Hexacarbonyls with Lithium Ethoxyacetylide.
Authors: JUNEAU K. N. , HEGEDUS L. S. , ROEPKE F. W. 
Published: May 2016

AbstractThe reaction between the anion of (I) and the carbonyls (II) followed by alkylation with Meerwein's reagent (III) yields the unusual title complexes (IV), whose structure is confirmed by an X‐ray analysis of (IVa) (space group Fdd2, Z = 8).
ChemInform Abstract: Half‐Sandwich Complexes of Manganese with the Trifluoromethyl Isocyanide Ligand: Cp*Mn(CO)(CNCF3)(L).
Authors: LENTZ D. , MARSCHALL R. 
Published: May 2016

AbstractPhotolysis of the complex (I) in the presence of cis‐cyclooctene or THF yields the complexes (III).
ChemInform Abstract: Dioxygen Insertion into Iron(III)‐Carbon Bonds. NMR Studies of the Formation and Reactivity of Alkylperoxo Complexes of Iron(III) Porphyrins.
Authors: ARASASINGHAM R. D. , BALCH A. L. , CORNMAN C. R. , LATOS‐GRAZYNSKI L. 
Published: May 2016

AbstractFe(III) alkyl porphyrin complexes such as (I) with simple alkyl groups as axial ligands are thermally stable at 25 °C, but undergo photolytic homolysis with formation of a reactive Fe(II) porphyrin.
ChemInform Abstract: Alkoxy and Aryloxy Derivatives of (Pentamethylcyclopentadienyl)ruthenium. X‐Ray Crystal Structures of ((η5‐C5Me5)Ru(μ‐OMe))2, ((η5‐C5Me5)(CO)Ru(μ‐OEt))2, and (η5‐C5Me5)Ru(η5‐2,6‐tBu2C6H3O) and Molecular Orbital Analysis of ((η5‐C5H5)Ru(μ‐OMe))2.
Authors: LOREN S. D. , CAMPION B. K. , HEYN R. H. , TILLEY T. D. , BURSTEN B. E. , LUTH K. W. 
Published: May 2016

AbstractThe alkoxide‐bridged Ru dimers (IIIa) (space group C2/c, Z = 8) and (IIIb) are prepared according to the scheme.
ChemInform Abstract: Novel Trimetallic Complexes of Rhodium with Bis(difluorophosphino)methylamine: The Crystal and Molecular Structure of (Rh3(μ‐Cl)3(μ‐H3CN(PF2)2)3).
Authors: MAGUE J. T. , JOHNSON M. P. , LLOYD C. L. 
Published: May 2016

AbstractThe air‐stable title complex (III) is obtained as shown and characterized by X‐ray structure analysis (space group C2/c, Z = 8).
ChemInform Abstract: Convenient Synthesis of C‐β‐D‐Glucopyranosyl Arenes ‐ Synthesis of 5,7,4′‐Tri‐O‐methylvitexin.
Authors: FRICK W. , SCHMIDT R. R. 
Published: May 2016

AbstractThe glucopyranosyl derivative (IV) and the title compound (VI) are synthesized via addition of the lithiated phenol derivative (II) and the flavanone derivative (V), resp., to the open‐chain protected D‐glucose (I) followed by hydrogenolytic debenzylation.
ChemInform Abstract: Structure of Samarium(III) Iodate Monohydrate.
Authors: GUPTA P. K. S. , AMMON H. L. , ABRAHAMS S. C. 
Published: May 2016

AbstractA yellow crystal of Sm(IO3)3·H2O, grown from the gel, belongs to the monoclinic space group P21 with Z=2 and is essentially isomorphous with Nd(IO3)3·H2O. In its structure the three I atoms form independent trigonal pyramids with the three closest O atoms, with the average I‐O bond length comparing well with the value in LiIO3.