bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis of Substituted 5,6‐Dihydro‐6,13‐dioxo‐13H‐indolo(2,1‐c) (1,4)diazepines.
Authors: HIREMATH S. P. , BAJJI A. C. , BIRADAR J. S. 
Published: May 2016

AbstractThe title compounds (IV) and their precursors (III) are tested for their antibacterial activity.
ChemInform Abstract: Beryllium‐Nitrogen Compounds. Part 2. Synthesis and Structure of Beryllium Bis(dialkyldithiocarbamates).
Authors: NOETH H. + , SCHLOSSER D. 
Published: May 2016

AbstractMonomeric bis(diisopropylamino)beryllium (I) reacts with CS2 (II) to give the complex (III), which crystallizes in C2/c with Z=4.
ChemInform Abstract: Beryllium‐Nitrogen Compounds. Part 3. Reaction of Beryllium Bis(dialkylamides) with Carbon Dioxide: (Dialkylcarbamoyloxy)beryllium Compounds.
Authors: NOETH H. + , SCHLOSSER D. 
Published: May 2016

AbstractCO2 (II) reacts with monomeric (I) at room temp. to yield (III).
ChemInform Abstract: Platinum(0) Complexes as Catalysts of Metal Carbonyl Substitution Reactions.
Authors: WANG S.‐J. , ANGELICI R. J. 
Published: May 2016

AbstractThe substitution of one CO ligand in a variety of metal carbonyl complexes such as (I), (IV) or (VI) is catalyzed by Pt(PPh3)4.
ChemInform Abstract: Novel Cluster Frameworks from the Reactions of the Unsaturated Clusters Fe4(CO)11(μ4‐PR)2 with Alkynes.
Authors: JAEGER J. T. , POWELL A. K. , VAHRENKAMP H. 
Published: May 2016

AbstractThe unsaturated clusters (I) react with terminal alkynes such as (II) primarily by insertion of the alkyne between one P and two Fe atoms.
ChemInform Abstract: Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 80. Mixed‐Metal Tungsten and Ruthenium Compounds.
Authors: STONE F. G. A. , WILLIAMS M. L. 
Published: May 2016

AbstractIn the reaction of (I) with a threefold excess of (II) the only products are the tetranuclear clusters (III), whereas a similar reaction in a ratio 1:2 provides the isomers (IV) and (V).
ChemInform Abstract: Synthesis and Crystal Structure of Cyclic (Ru(η5‐C5H4CH2CH2PPh2)(PPh3)Cl), a Compound Having a Cyclopentadienyl Proton with a Chemical Shift of δ 1.91 ppm.
Authors: SLAWIN A. M. Z. , WILLIAMS D. J. , CROSBY J. , RAMSDEN J. A. , WHITE C. 
Published: May 2016

AbstractThe title complex (IVa) is obtained according to the scheme and characterized by X‐ray structure analysis (space group Pc21n, Z=4).
ChemInform Abstract: New Glycosidation Reaction. Part 1. Combinational Use of Cp2ZrCl2‐AgClO4 for Activation of Glycosyl Fluorides and Application to Highly β‐Selective Glycosidation of D‐Mycinose.
Authors: MATSUMOTO T. , MAETA H. , SUZUKI K. , TSUCHIHASHI G. 
Published: May 2016

AbstractThe glycosyl fluoride (I) is treated with the alcohols (II) in the presence of zirconocene dichloride and silver perchlorate, forming the glycosides (III).
ChemInform Abstract: A New Lateral Growth Free Formation Technique for Titanium Silicide Using the Si/W/Ti Trilayer Structure.
Authors: LIN M.‐Z. , WU C.‐Y. 
Published: May 2016

AbstractIt is demonstrated that, by using the Si/W/Ti trilayer structure with suitable thicknesses of the W/Ti films, the lateral growth problem in the titanium silicide formation can be overcome.
ChemInform Abstract: Effects of the Ring Size on the Regioselectivity of Amino‐Claisen Rearrangement of Unsymmetrically Fused Anilinium Derivatives.
Authors: KATAYAMA H. , KANEKO K. 
Published: May 2016

AbstractAmino‐Claisen rearrangement of the fused anilinium derivatives (III), prepared by allylation of (I), is carried out under two reaction conditions.
ChemInform Abstract: Generation of α‐Acylcarbenium Ions: A Novel Uncatalyzed C‐C Bond Formation at Room Temperature.
Authors: KULKARNI G. C. , KARMARKAR S. N. , KELKAR S. L. , WADIA M. S. 
Published: May 2016

AbstractA wide range of reactions of desyl chlorides such as (II) with different phenols such as (I), (V), or (VIII) is studied.
ChemInform Abstract: 2‐Hydroxy‐3‐pinanone as Chiral Auxiliary in the Asymmetric Synthesis of α‐Amino Acids.
Authors: EL ACHQAR A. , BOUMZEBRA M. , ROUMESTANT M.‐L. , VIALLEFONT P. 
Published: May 2016

AbstractThe reactivity of Li derivatives of chiral Schiff bases such as (I) toward carbonyl compounds is studied.
ChemInform Abstract: Synthesis of Substituted Cinnamic Acids According to the Heck Reaction in an Aqueous Medium.
Authors: BUMAGIN N. A. , ANDRYUKHOVA N. P. , BELETSKAYA I. P. 
Published: May 2016

AbstractThe aryl halides (I) or (IV) are coupled with the acrylic acid (II) in the presence of potassium carbonate and a palladium catalyst to give the cinnamic acids (III) or (V).
ChemInform Abstract: Synthesis of Various Pyrazole‐1‐carbonylindoles.
Authors: HIREMATH S. P. , ULLAGADDI A. , SEKHAR K. R. , PUROHIT M. G. 
Published: May 2016

AbstractSince pyrazoles which are coupled to an indole moiety may have considerable biological activity, a series of title compounds of type (III), (V) and (VIII) is synthesized from the corresponding hydrazides of type (I).
ChemInform Abstract: Formation and Properties of the Phosphazane Oligomers ((PhNH)PNPh)2 and ((PhNH)PNPh)3.
Authors: TARASSOLI A. , THOMPSON M. L. , HALTIWANGER R. C. , HILL T. G. , NORMAN A. D. 
Published: May 2016

AbstractThe title compounds (IV) and (III) are obtained from transamination reaction between P(NEt2)3 (I) and amine (II) or thermolysis reaction of (V) depending on reaction conditions.
ChemInform Abstract: Dimeric Complexes Containing the (Fe2S2)2+ Cores Coordinated by Non‐Sulfur Terminal Ligands. Synthesis, Structural Characterization, and Spectroscopic Properties of (Et4N)2(Fe2S2(o,o′‐C12H8O2)2), (Et4N)2(Fe2S2(C4H4N)4), and (Et4N)2(Fe2S2(O‐o‐C6H4CH(n‐C4H9)NHC6H4‐o‐S)2) and the Structure of (Ph4P)2(Fe2S2(OC6H4‐p‐CH3)4).
Authors: SALIFOGLOU A. , SIMOPOULOS A. , KOSTIKAS A. , DUNHAM R. W. , KANATZIDIS M. G. , COUCOUVANIS D. 
Published: May 2016

AbstractThe synthesis of the title complexes is achieved by metathetical stoichiometric reactions which occur in MeCN readily under strictly anaerobic and moisture‐free conditions between the anion of (I) and the alkali‐metal salts of the ligands.
ChemInform Abstract: Synthesis of Platinum Bis(phosphonium ylide) Complexes from α‐Halomethyl Precursors.
Authors: HOOVER J. F. , STRYKER J. M. 
Published: May 2016

AbstractIn contrast to (Ia) the reaction of (Ib) with excess triphenylphosphine (II) yields the zwitterionic bis(phosphonium ylide) complex (III), which crystallizes in the space group P21/c with Z=4.
ChemInform Abstract: The Reaction of Enols with Superoxide Anion Radicals: Preparation of Tertiary α‐Ketols.
Authors: BETANCOR C. , FRANCISCO C. G. , FREIRE R. , SUAREZ E. 
Published: May 2016

AbstractOxidation of the pregnan‐20‐one (I) with potassium superoxide and oxygen yields the α‐hydroperoxide (II) which is converted into the α‐ketol (III) on treatment with triphenylphosphine.
ChemInform Abstract: Enzymes in Carbohydrate Synthesis: N‐Acetylneuraminic Acid Aldolase Catalyzed Reactions and Preparation of N‐Acetyl‐2‐deoxy‐D‐neuraminic Acid Derivatives.
Authors: KIM M.‐J. , HENNEN W. J. , SWEERS H. M. , WONG C.‐H. 
Published: May 2016

AbstractThe 50‐mmol‐scale synthesis of N‐acetylneuraminic acid (Neu5Ac) (Ia) from pyruvate and N‐acetyl‐D‐mannosamine (ManNAc) catalyzed by Neu5Ac aldolase and a small‐scale (0.32 mmol) synthesis of Neu5,9Ac2 (Ib) from ManNAc by two separate enzyme reactions, catalyzed by protease N and Neu5Ac aldolase, resp., are described.
ChemInform Abstract: Synthesis of (.+‐.)‐Fredericamycin A.
Authors: KELLY T. R. , BELL S. H. , OHASHI N. , ARMSTRONG‐CHONG R. J. 
Published: May 2016

AbstractBased on the results of a series of model studies, the synthons (VII) and (XII) are prepared from dihydrocoumarin (I) and the diester (VIII), respectively.
ChemInform Abstract: Electrical Properties of Bismuth Doped with Tin and Lead
Authors: BANERJEE D. , TALAPATRA D. , BHATTACHARYA R. 
Published: May 2016

Abstract(0.17% and 0.56% Pb; 0.3 and 0.71% Sn) are studied in the temp. range 100‐300 K. Tin and lead have different effects on the band structure of Bi.
ChemInform Abstract: Potential Oscillations During the Electrocrystallization of Cadmium from Alkaline Cyanide Solutions Under Galvanostatic Conditions.
Authors: KANEKO N. , NEZU H. , SHINOHARA N. 
Published: May 2016

AbstractDuring electrolysis under galvanostatic conditions carried out at current densities which are above the limiting current (caused by the diffusion control of the Cd complex ion with natural convection) potential oscillations are observed and H2 bubbles are evolved periodically from the cathode surface.
ChemInform Abstract: Magnetic Study of Catalytic Particles: Application to Ni/CeO2.
Authors: MAUGER A. , ESCORNE M. , PAUL‐BONCOUR V. , PERCHERON‐GUEGAN A. , ACHARD J. C. , BARRAULT J. 
Published: May 2016

AbstractA new method to determine the particle size distribution of supported Ni catalysts is developed on the basis of the analysis of magnetic properties via the superparamagnetic approximation.
ChemInform Abstract: Synthesis of Polyfunctional Chloroorganic Compounds from 1,1,1,2,3,3,4,4‐Octachlorobutane.
Authors: KABERDIN R. V. , POTKIN V. I. , DUBOVA E. YU. , OL'DEKOP YU. A. 
Published: May 2016

AbstractTreatment of the title compound (I) with oleum affords the pentachlorobutanoic acid (II) in fair yield.
ChemInform Abstract: 1,4‐Dihydro‐ and 2,4‐Dihydropyrrolo(3,4‐b)indoles with Donor Groups in the 3‐Position.
Authors: DYKER G. , KREHER R. P. 
Published: May 2016

AbstractAcid‐promoted dealkylation of the N‐tert‐butyl lactam (I) yields the lactam (II) which is converted into the methoxy‐1,4‐dihydropyrroloindole (V) by methylation with the triflate (III) and subsequent deprotonation.
ChemInform Abstract: Cancerostatics. Part 6. Synthesis and Antineoplastic Properties of Some Benzoiso‐α‐carbolines.
Authors: KACZMAREK L. , BALICKI R. , NANTKA‐NAMIRSKI P. 
Published: May 2016

Abstract2‐Halopyridine derivatives such as the quinolines (I) are coupled with the benzotriazoles (II) to yield the intermediates (III) which release nitrogen upon heating in polyphosphoric acid, forming the fused α‐carbolines (IV).
ChemInform Abstract: Synthesis and Antitumor Activity of Methoxyindolo(2,1‐a)isoquinolines.
Authors: AMBROS R. , VON ANGERER S. , WIEGREBE W. 
Published: May 2016

AbstractThe o‐bromophenylacetates (III) are coupled with the phenethylamines (IV) to form the amides (V) which undergo twofold ring closure, followed by dehydrogenation, yielding the indoloisoquinolines (IX).
ChemInform Abstract: Synthesis and Halogenolysis of Stable Pentacoordinate Bismuth Compounds (10‐Bi‐5): Formation of 1‐Chloro‐1,1‐diaryl‐3,3‐bis(trifluoromethyl)‐3H‐2,1‐benzoxabismoles.
Authors: AKIBA K. , OHDOI K. , YAMAMOTO Y. 
Published: May 2016

AbstractThe triarylbismuth dihalides (II) react with the dilithio compound (I) to give the benzoxabismoles (III).
ChemInform Abstract: Preparation and Structure of a Dinuclear η2‐H2 Complex (P‐N)(η2‐H2)Ru(μ‐Cl)2(μ‐H)Ru(H)(PPh3)2, P‐N=Fe(η‐C5H3(CHMeNMe2)P(i‐Pr)2‐1,2)(η‐C5H5).
Authors: HAMPTON C. , CULLEN W. R. , JAMES B. R. , CHARLAND J.‐P. 
Published: May 2016

AbstractThe title complex (III) is prepared according to the scheme and characterized by X‐ray structure analysis (space group P1, Z=2) and 1H NMR spectrum.
ChemInform Abstract: Organoamidometallics. Part 2. Decarboxylation Syntheses and Structures of (N,N‐Dimethyl‐N′‐(polyfluorophenyl)ethane‐1,2‐diaminato(1‐))platinum(II) Complexes.
Authors: BUXTON D. P. , DEACON G. B. , GATEHOUSE B. M. , GRAYSON I. L. , BLACK D. ST. C. 
Published: May 2016

AbstractSquare‐planar Pt(II) complexes of the type (I) are prepared by decarboxylation reactions between the diamine‐Pt(II) complexes (II), Tl(I) polyfluorobenzoates and polyfluorobenzenes or Tl(I) pentafluorobenzoate in hot pyridine (V) as demonstrated for the examples (Ia) and (Id).
ChemInform Abstract: Synthesis of Amino Acids and Related Compounds. Part 35. Synthesis of β‐Functionalized α,β‐Dehydroamino Acid Derivatives.
Authors: NUNAMI K. , HIRAMATSU K. , HAYASHI K. , MATSUMOTO K. 
Published: May 2016

AbstractBromination of the (Z)‐dehydroamino acid ester (I) yields the bromides (II) and (III).
ChemInform Abstract: Amino Acids. Part 9. Stereospecific Synthesis of Heterocyclic Substituted α‐Dehydroamino Acid Derivatives.
Authors: HERDEIS C. , SYVAERI J. + 
Published: May 2016

AbstractThe pyrrolidinone acetals (I) are coupled with the acetates (II), producing the methylenepyrrolidines (III).
ChemInform Abstract: Fluorine‐Containing Amino Acids and Their Derivatives. Part 7. Synthesis and Antitumor Activity of α‐ and γ‐Substituted Methotrexate Analogues.
Authors: TSUSHIMA T. , KAWADA K. , ISHIHARA S. , UCHIDA N. , SHIRATORI O. , HIGAKI J. , HIRATA M. 
Published: May 2016

AbstractThree types of reactions are proposed for the preparation of fluorine‐containing amino acids.
ChemInform Abstract: Electronic and Vibrational Structure of Transition Metal Trimers: Photoelectron Spectra of Ni‐ 3, Pd‐ 3, and Pt‐ 3.
Authors: ERVIN K. M. , HO J. , LINEBERGER W. C. 
Published: May 2016

AbstractThe title anions are prepared in a flowing afterglow ion source with a cold cathode dc discharge.
ChemInform Abstract: Thermal Stabilization of Transition Alumina by Structural Coherence with LnAlO3 (Ln: La, Pr, Nd).
Authors: OUDET F. , COURTINE P. , VEJUX A. 
Published: May 2016

AbstractThe interaction between lanthanoid oxides and alumina is studied by BET measurements, XRD, TEM, and UV/VIS spectroscopy.
ChemInform Abstract: Enantioselectivity of the Microsomal Epoxide Hydrolase: Hydrolysis of (.+‐.)‐cis‐3‐Bromo‐1,2‐epoxycyclohexane.
Authors: BELLUCCI G. , FERRETTI M. , LIPPI A. , MARIONI F. 
Published: May 2016

AbstractThe acid‐catalyzed and the rabbit microsomal EH catalyzed hydrolysis of (±)‐(I) are both completely regio‐ and stereospecific, giving (II).
ChemInform Abstract: Stereoselectivity in the Formation and Allylic Rearrangement of 8a‐Methyl‐ and 8a‐Ethyl‐1,2,3,4,4a,7,8,8a‐octahydronaphthalenyl Hydroperoxides.
Authors: AVILA D. V. , DAVIES A. G. , DAVISON I. G. E. 
Published: May 2016

AbstractThe octahydronaphthalenes (I) are subjected to singlet oxygen oxygenation and the various hydroperoxides (II)‐(V) which are formed are characterized.
ChemInform Abstract: Selenium Dioxide‐Catalyzed Conversion of Alcohols to Alkyl Chlorides by Chlorotrimethylsilane.
Authors: LEE J. G. , KANG K. K. 
Published: May 2016

AbstractThe alcohols (I) are converted into the corresponding alkyl chlorides (III) by the reaction with trimethylsilyl chloride (II) in the presence of 2‐3 mol% selenium dioxide.
ChemInform Abstract: New Classes of Zerovalent Titanium Carbonyls. First Structural Characterization of a Seven‐Coordinate Titanium Complex Containing Only Unidentate Ligands: Ti(CO)5(SnPh3)22‐.
Authors: CHI K. M. , FRERICHS S. R. , ELLIS J. E. 
Published: May 2016

AbstractConsecutive reduction of the titanium tetrachloride complex (I), reaction with the tin and germanium salts (II) and carbonylation with carbon monoxide (III) yield complexes which are characterized as the tetraethylammonium salts (V).
ChemInform Abstract: Chemistry of Organo‐Transition‐Metal Compounds. Part 53. Synthesis and Properties of Manganese Tetravinyloxide, Mn(OCH=CH2)4·0.5 THF.
Authors: JACOB K. , THIELE K.‐H. 
Published: May 2016

AbstractTetrakis(norbornyl)‐Mn (I) reacts with boiling THF (II) forming ethylene, norbornane, and the Mn title complex (III) as the first Mn tetraalkoxide described.
ChemInform Abstract: Synthesis, Characterization, and Catalytic Activity of a Phosphinidine Stabilized Tethered Triruthenium Cluster.
Authors: ALEXIEV V. D. , BINSTED N. , COOK S. L. , EVANS J. , PRICE R. J. , CLAYDEN N. J. , DOBSON C. M. , SMITH D. J. , GREAVES G. N. 
Published: May 2016

AbstractThe synthesis of the triruthenium cluster (IVa) from the dodecacarbonyl (I) occurs according to the scheme.
ChemInform Abstract: Thermal and Photochemical Reactions of Dibromo(β,β′,β′′‐triaminotriethylamine)rhodium(III) and α‐ and β‐Aquobromo(β,β′,β′′‐triaminotriethylamine)rhodium(III) Cations in Acidic Aqueous Solution: Evidence for an Innocent‐Ligand Effect.
Authors: ARPEY C. J. , JACOBS S. E. , TERZAKIS C. , WILLIAMS A. , SHERIDAN P. S. 
Published: May 2016

AbstractLigand‐field photolysis of (I) in acidic aqueous solution causes Br‐ release and the formation of (III).
ChemInform Abstract: A Concise Route to the Calicheamicin‐Esperamicin Series: The Crystal Structure of a Core Subunit.
Authors: DANISHEFSKY S. J. , MANTLO N. B. , YAMASHITA D. S. , SCHULTE G. 
Published: May 2016

AbstractWith a view to investigations of the total synthesis and the medicinal chemistry of enediyne antibiotics such as calicheamicin or esperamicin, an extensively functionalized core ensemble is required.
ChemInform Abstract: Solubility and Decomposition Kinetics of Nitrous Acid in Aqueous Solution.
Authors: PARK J.‐Y. , LEE Y.‐N. 
Published: May 2016

AbstractThe Henry's law solubility of HNO2 in water and the kinetics of the reactions shown in the scheme are determined by monitoring the gas‐phase concentrations of NO and NO2 (high‐sensitive chemiluminescence NOx detector) as a function of time as purged from a bubbler‐type gas‐liquid reactor of known gas‐liquid mass‐transfer characteristics.
ChemInform Abstract: Surface Active Sites of V2O5‐WO3 Catalysts.
Authors: SATSUMA A. , HATTORI A. , MIZUTANI K. , FURUTA A. , MIYAMOTO A. , HATTORI T. , MURAKAMI Y. 
Published: May 2016

AbstractV2O5‐WO3 catalysts are studied by SIMS, XRD, ESR, XPS, IR spectroscopy of adsorbed NH3, temp.‐programmed desorption of NH3, and the NO‐NH3 rectangular pulse (NARP) technique.
ChemInform Abstract: 59Co NMR of Cobalt(III) Porphyrin Complexes. Part 2. Electric Field Gradients, d‐Orbital Populations, and Hydrogen Bonding.
Authors: HAGEN K. I. , SCHWAB C. M. , EDWARDS J. O. , JONES J. G. , LAWLER R. G. , SWEIGART D. A. 
Published: May 2016

AbstractThe 59Co NMR spectra of (I) are reported in a number of solvents and at several field strengths.
ChemInform Abstract: 3,4‐Didehydropyridine Plus Cyclopentadiene: (2 + 2) or (4 + 2)‐Cycloaddition?
Authors: REINECKE M. G. , BROWN E. S. , CAPEHART B. P. , MINTER D. E. , FREEMAN R. K. 
Published: May 2016

AbstractAccording to complete 1H and 13C NMR assignments the didehydropyridine (I) and cyclopentadiene (II) yield the (4 + 2)‐cycloadduct (III) rather than the (2 + 2)‐adducts (IV) and/or (V) proposed in the literature.
ChemInform Abstract: Oxidative Ring Expansion of 1‐(tert.‐Butylamino)indolines (I) to 1,4‐Dihydrocinnolines. Novel Neophyl Rearrangement of Hydrazyl Radicals.
Authors: WANG S. F. , MATHEW L. , WARKENTIN J. 
Published: May 2016

AbstractDegassed solutions of (I) are stable indefinitely (20 °C, CDCl3).
ChemInform Abstract: The Catalytic Effect of Cationic Amino Micelles on the Hydrolysis of Substituted Phenyl Esters.
Authors: RAV‐ACHA CH. , RINGEL I. , SAREL S. , KATZHENDLER J. 
Published: May 2016

AbstractThe catalytic effects of the two cationic micelles (cat.) on the hydrolysis of esters (I) and (IV) are determined.
ChemInform Abstract: Photocyclization of o‐Phenoxybenzyl Alcohols in Aqueous Solution. A Simple Synthesis of 6H‐Dibenzo(b,d)pyrans.
Authors: WAN P. , HUANG C.‐G. 
Published: May 2016

AbstractIrradiation of the o‐phenoxybenzyl alcohols (I) and (VI) in aqueous solution results in cyclization, producing the 6H‐dibenzo(b,d)pyrans (II) and (VII) as the main products.
ChemInform Abstract: Synthesis, Configuration, and Evaluation of Two Conformationally Restrained Analogues of Phencyclidine.
Authors: DE COSTA B. R. , GEORGE C. , BURKE T. R. JUN. , RAFFERTY M. F. , CONTRERAS P. C. , MICK S. J. , JACOBSON A. E. , RICE K. C. 
Published: May 2016

AbstractOxidation of the bicyclic hexanol (I) yields the ketone (II) which is treated with phenyllithium (III) to give the carbinol (IV).
ChemInform Abstract: Lithium Redox‐Responsive Ferrocene Bis‐Tertiary Amide Derivatives.
Authors: BEER P. D. , SIKANYIKA H. , BLACKBURN C. , MCALEER J. F. 
Published: May 2016

AbstractThe ferrocenedicarboxylic acid dichloride (I) reacts with the amines (II) to form the amides (III).
ChemInform Abstract: Square Wave Voltammetry for the Determination of Kinetic Parameters. The Reduction of Zinc(II) at Mercury Electrodes.
Authors: GO W. S. , O'DEA J. J. , OSTERYOUNG J. 
Published: May 2016

AbstractResults of further evaluation of the performance of the combination of square wave voltammetry and the COOL (Chernoff‐O'Dea‐Osteryoung‐Lane) algorithm are presented.
ChemInform Abstract: A Peculiar Conformation of Normal‐Chain Dicarboxylic Acid Salts in Aqueous Solutions.
Authors: FUKUSHIMA K. , ADACHI K. , WATANABE K. 
Published: May 2016

AbstractThe Raman spectra of adipic acid, pimelic acid and their salts in aqueous NaOH solutions are found to be very different from those in organic solvents.
ChemInform Abstract: Reaction of Phenol with 1‐Hydroxyadamantane in the Presence of Aluminum Diphenyldithiophosphate.
Authors: KOSHCHII V. A. , KOZLIKOVSKII YA. B. , YURCHENKO A. G. 
Published: May 2016

AbstractThe reaction between phenol (I) and adamantan‐1‐ol (II), which is catalyzed by aluminum diphenyldithiophosphate, affords 2‐(1‐adamantyl)phenol (III) as the main product along with the para isomer, di‐ and triadamantyl analogues and the O‐adamantyl derivative.
ChemInform Abstract: Reactions of Phosphorus Ylides with S8 or Se in the Presence of Amines. Formation of Thioaldehydes or Selenoaldehydes.
Authors: OKUMA K. , KOMIYA Y. , OHTA H. 
Published: May 2016

AbstractThe phosphorus ylids (I) are treated with elemental sulfur (II), forming the intermediate thioaldehydes (III) which react with morpholine (IV) to produce the thioamides (V).
ChemInform Abstract: Naphtho(2,1‐b)thiophene‐Linked 1,2‐Dithia‐5,8‐diazacyclodecanes and Imidazolidino(1,2‐d)dithiazepines: Synthesis, Structure Proof by X‐Ray Diffraction Analysis, and DNA Binding Properties.
Authors: SONDHI S. M. , KOLODZIEJCZYK P. , BALL R. G. , LOWN J. W. 
Published: May 2016

AbstractThe esterification of the naphthothiophenecarboxylic acid (II) with the hydroxymethyl compounds (I) or (VII) is achieved in the presence of carbonyldiimidazole.
ChemInform Abstract: Counterattack Reagent Hexamethyldisilane in the Direct Conversion of Aldehydes, Ketones, and Allyl Alcohols to Allyltrimethylsilanes.
Authors: HWU J. R. , LIN L. C. , LIAW B. R. 
Published: May 2016

AbstractThe title compound (IV) is an efficient reagent in the reactions of alcohols such as (I), (V), (VI) or carbonyl compounds such as (IX) or (XIII) shown in the scheme leading to allyltrimethylsilanes, e.g. (II)/(III), (VII), (XI)/(XII), (XV)/(XVI).
ChemInform Abstract: Activated Nitriles in Heterocyclic Synthesis. Part 6. Novel Synthesis of Thiadiazolo(2,3‐a)pyridine Derivatives.
Authors: SOWELLUM S. Z. A. , KHODEIR M. N. M. , EL‐AMIN S. M. , ELAGAMEY A. A. 
Published: May 2016

AbstractReaction of the 2‐cyanomethylthiadiazole (I) with the cinnamonitriles (II) yields the thiadiazolopyridines (III).
ChemInform Abstract: Defined Dimensional Alterations in Enzyme Substrates. Birch Reduction of lin‐Benzopurines. A Contribution to Information Concerning the Binding Sites of Adenosine Deaminase and Xanthine Oxidase.
Authors: LEONARD N. J. , PETRIC A. , RYKOWSKI A. 
Published: May 2016

AbstractThe lin‐benzopurine derivatives (I) and (IX) are subjected to Birch reduction, yielding the deoxygenated product (II) and/or the hydrogenated derivatives (III).
ChemInform Abstract: Transition Metal Dienyls in Organic Synthesis. Dienyl Transfer Reactions from Zirconium to Phosphorus and to Boron.
Authors: FRYZUK M. D. , BATES G. S. , STONE C. 
Published: May 2016

AbstractReaction of the dienylzirconocenes (I) with the chlorophosphines (II) or the bromoborane (IV) yields the corresponding dienylphosphines (III) or the dienylboranes (V) respectively.
ChemInform Abstract: Synthesis of Some Compounds Containing the Selenocarbonyl Group by Using Viehe′s Salt/Sodium Hydrogen Selenide: An Approach to Cyclic Selenocarbonates in the Monosaccharide Series.
Authors: COPELAND C. M. , GHOSH J. , MCADAM D. P. , SKELTON B. W. , STICK R. V. , WHITE A. H. 
Published: May 2016

AbstractSeveral selenothiocarbamates, e.g. (III), selenodithiocarbonates, e.g. (VII), selenothiocarbonates, e.g. (X), cyclic selenocarbonates, e.g. (XII), and selenoureas, e.g. (XVIII) are prepared from appropriate starting compounds such as (I), (VI), (IX), (XI), or (XVII).