bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis and Biological Activity of N′‐Alkoxybenzenesulfonyl‐5‐halogenouracils.
Authors: KALDRIKYAN M. A. , GEBOYAN V. A. , TER‐ZAKHARYAN YU. Z. , PARONIKYAN R. V. , GARIBDZHANYAN B. T. , STEPANYAN G. M. , PARONIKYAN G. M. , AKOPYAN L. G. 
Published: May 2016

AbstractThe alkoxybenzenesulfonyl 5‐fluoro‐ or 5‐bromouracils (III) are prepared from the uracils (I) and the sulfochlorides (II).
ChemInform Abstract: Synthesis of an Indole Analogue of Folic Acid.
Authors: SHENGELIYA M. S. , AVRAMENKO V. G. , KULESHOVA L. N. , ERSHOVA YU. A. , CHERNOV V. A. , SUVOROV N. N. 
Published: May 2016

AbstractStarting with the nitroindolyl carboxylic acid chloride (I) and the glutamates (II), the amides (III) are prepared and subsequently hydrogenated to give the amino indolyl amides (V).
ChemInform Abstract: Syntheses and Spectral Properties of Tropocoronands, a New Class of Versatile Metal‐Complexing Macrocycles Derived from Aminotropone Imines.
Authors: ZASK A. , GONNELLA N. , NAKANISHI K. , TURNER C. J. , IMAJO S. , NOZOE T. 
Published: May 2016

AbstractReaction of the tropones (Ia) with the diamines (II) yields the dimeric aminotropones (III), which are converted to the title compounds (V) (the tropocoronand (Vb) is obtained as a minor product only; the main product of this reaction is 2‐phenyl‐2‐imidazole (51% yield)).
ChemInform Abstract: Flash Vacuum Pyrolysis (FVP) of 2,7‐Dimethyl‐2,3:7,8‐diepoxy‐5‐silaspiro(4.4)nonane (I) with Cyclotrisiloxanes ‐ Synthesis of Spirocyclosiloxanes. Characterization of Silica Formed by FVP of (I).
Authors: HENRY G. K. , DOWD D. R. , BAU R. , MANUEL G. , WEBER W. P. 
Published: May 2016

AbstractFVP of (I) in the presence of the cyclotrisiloxanes (II) yields the siloxanes (II)‐(V) and isoprene (VI).
ChemInform Abstract: Reaction of Chloro‐substituted Methanephosphonic Acid Dialkyl Ester with Dialkylphosphites, Trialkylphosphites, or Alcohol/Sodium Alcoholate.
Authors: ALBRECHT S. , HERRMANN E. 
Published: May 2016

AbstractThe dialkyltrichloromethanephosphonates (I) react analogous CCl4 with dialkylphosphites and alcohol in the presence of NEt3 or with trialkylphosphites and alcohol to yield the diesters (II) of dichloromethanephosphonic acid and trialkylphosphates (III).
ChemInform Abstract: 1,2‐Bis(trimethylsilyl)‐3,4‐di(tert‐butyl)cyclotetraphosphane.
Authors: FRITZ G. , STOLL K. 
Published: May 2016

AbstractThe crystalline title compound (III) is obtained by reaction of the triphosphine (I) with an excess P‐dichloride (II) and characterized by 31P and 1H NMR spectral data.
ChemInform Abstract: Complexes with Phosphinomethane and Phosphinomethanide Ligands. Part 10. La((Ph2P)2CH)3 ‐ a Homoleptic Lanthanum Complex with π‐Allyl‐like Coordinated Diphosphinomethanide Ligands.
Authors: KARSCH H. H. , APPELT A. , MUELLER G. + 
Published: May 2016

AbstractThe 1:3 molar reaction of LaCl3 with potassium bis(diphenylphosphino)methanide in THF at 25 °C leads to the title complex (I).
ChemInform Abstract: Synthesis and Molecular Structure of tert‐Butyliminovanadium(V) Compounds tC4H9N=V(SR)3 (R: tC4H9, SiPh3).
Authors: PREUSS F. , NOICHL H. , KAUB J. 
Published: May 2016

AbstractThe thiolato compounds (III), (V), and (VII) are prepared (see scheme).
ChemInform Abstract: Nitrido Complexes of Vanadium(V): (VNCl3)‐ and VNCl2(dipy).
Authors: SCHERFISE K. D. , DEHNICKE K. 
Published: May 2016

Abstract(I), the anion of which is isoelectronic with VOCl3, is formed in the reaction of (N(PPh3)2)Cl and Cl3VNSiMe3 in CH2Cl2 within a few minutes.
ChemInform Abstract: Oxidative and Electrophilic Pathways in the Reactions of Pentaaquo(organo)chromium(2+) Ions with Nitrous Acid.
Authors: MELTON J. D. , BAKAC A. , ESPENSON J. H. 
Published: May 2016

AbstractThe reactions of HONO with the complexes (I) occur with a 1:1 stoichiometry.
ChemInform Abstract: Reactions of Complex Ligands. Part 26. Diels‐Alder Reactions at Carbene Ligands: A Route to Olefin‐Carbene Complexes.
Authors: DOETZ K. H. + , KUHN W. , MUELLER G. + , HUBER B. , ALT H. G. 
Published: May 2016

AbstractThe Cr carbene complex (I) reacts with (II) to give the exo‐cycloadduct (III) together with its endo‐isomer (IV).
ChemInform Abstract: Synthesis and Thermolysis of Tris(tris(amino)phosphine)molybdenum Tricarbonyls: Synthesis of fac‐((iPrNH)3P)3Mo(CO)3.
Authors: TARASSOLI A. , CHEN H.‐J. , ALLURED V. S. , HILL T. G. , HALTIWANGER R. C. , THOMPSON M. L. , NORMAN A. D. 
Published: May 2016

AbstractThe reaction of isopropylamine with the complex (I) results in the formation of the title complex (II).
ChemInform Abstract: Phosphine‐Substituted Chelate Ligands. Part 20. Synthesis and Diastereoselective Complexation of Chiral Phosphinothioformamides, Ph2P(X)C(S)NHC*HMePh (X: 2e‐, O, S).
Authors: KUNZE U. , JAWAD H. , BURGHARDT R. 
Published: May 2016

AbstractThe amidentate chiral title compounds (‐)‐(S)‐ and (+)‐(R)‐(Ia)‐(Ic) are obtained from optically pure (S)‐ or (R)‐1‐phenylethylamine via isothiocyanate intermediates as shown starting from phenylethylamine (‐)‐(S)‐(II).
ChemInform Abstract: Pentadienyl‐Metal‐Phosphine Chemistry. Part 7. Synthesis, Solid‐State Structure, and Solution Dynamics of (η5‐Pentadienyl)tris(phosphine)rhenium Complexes. Measurement of the Rotational Barrier for the Pentadienyl Ligand.
Authors: BLEEKE J. R. , MOORE D. A. 
Published: May 2016

AbstractThe electron‐rich η‐5‐pentadienyl‐Re complexes (II) are synthesized by reacting the fac‐complex (I) with excess potassium pentadienides.
ChemInform Abstract: Multiple Bonds Between Main‐Group Elements and Transition Metals. Part 29. Reductive Carbonylation of High‐Valent Oxorhenium Complexes ‐ a New Route to Low‐Valent Carbonylrhenium Compounds.
Authors: HERRMANN W. A. , KUESTHARDT U. + , SCHAEFER A. + , HERDTWECK E. 
Published: May 2016

AbstractThe Re(V) complexes (I) and (III) (obtained from (VII) and diphenylketene or phenyl isocyanate via the binuclear complex ((C5Me5)ReO2)2) can be reduced under CO with cleavage of the terminal oxo ligand to give the chiral Re(III) derivatives (II) or (IV).
ChemInform Abstract: Catonic Metal Nitrosyl Complexes. Part 6. Characterization of the 19‐Electron Radical Cation (Fe(NO)2LL′2)+.
Authors: BALLIVET‐TKATCHENKO D. , NICKEL B. , RASSAT A. , VINCENT‐VAUCQUELIN J. 
Published: May 2016

AbstractThe reaction of the dimer (I) with AgPF6 in THF or MeCN leads to the formation of the paramagnetic radical cations (II) that initiates the cationic polymerization of activated olefins.
ChemInform Abstract: Coordination of Pentadentate Macrocycles, Doubly Deprotonated 1,4,7,10,13‐Pentaazacyclohexadecane‐14,16‐dione, to High‐Spin Nickel(II) and Low‐Spin Nickel(III). X‐Ray Study of a Novel Redox System.
Authors: MACHIDA R. , KIMURA E. , KUSHI Y. 
Published: May 2016

AbstractA novel Ni redox system with peptide‐mimic macrocyclic pentaamines (I) is structurally characterized.
ChemInform Abstract: Synthetic Analogue Approach to Metallobleomycins. Part 1. Syntheses, Structures, and Properties of the Copper Complexes of Two Peptides Related to Bleomycins.
Authors: BROWN S. J. , TAO X. , STEPHAN D. W. , MASCHARAK P. K. 
Published: May 2016

AbstractThe peptides (III) and (VII), which are synthesized in high yield via the ester route, can coordinate through three N centers, an aromatic N, a peptide N and an imidazolyl N, and thus resemble part of the metal‐chelating region of bleomycin.
ChemInform Abstract: Transition Metal Substituted Acylphosphines and Phosphaalkenes. Part 10. Phosphaalkenyl‐, Mono‐ and Diacylphosphido Complexes of Ruthenium. X‐Ray Analysis of (η5‐C5Me5)(CO)2RuP(C(O)tBu)2.
Authors: WEBER L. , BUNGARDT D. , REIZIG K. , BOESE R. 
Published: May 2016

AbstractTreatment of the phosphido‐Ru complex (I) with mesitoyl chloride leads to the phosphaalkenyl complex (IIa), whereas with benzoyl chloride a mixture of the phosphaalkenyl complex (IIb) and the dibenzoylphosphido complex (IIIb) is obtained.
ChemInform Abstract: Resolutions Involving Metal Complexation. Synthesis and Resolution of (.+‐.)‐(2‐Mercaptoethyl)methylphenylarsine. Crystal and Molecular Structure of (‐)589‐(Pd((R)‐CH3CH(1‐C10H6)NMe2‐C2,N)((S)‐PhMeAsCH2CH2S‐As,μ‐S)PdCl((R)‐CH# 3CH(1‐C10H6)NMe2‐C2,N))·0.67 CH2Cl2.
Authors: LEUNG P. H. , MCLAUGHLIN G. M. , MARTIN J. W. L. , WILD S. B. 
Published: May 2016

AbstractThe title arsine (II) is obtained in its racemic form as shown.
ChemInform Abstract: Ligand Substitution vs. Ligand Addition. Part 1. Differences in Reactivity Between First‐ and Third‐Row Transition‐Metal Clusters. Reactions of Dimethylamine with the Sulfidometal Carbonyl Clusters M3(CO)9(μ3‐S)2 (M: Fe, Os).
Authors: ADAMS R. D. , BABIN J. E. 
Published: May 2016

AbstractThe reactions of the clusters (III) and (VI) with dimethylamine produce vastly different results.
ChemInform Abstract: Synthesis and Structure of S(NAs(tBu)2(Os3(CO)11))2. The First Sulphur Diimide with trans,trans Configuration in the Solid State.
Authors: GIEREN A. , HUEBNER T. + , HERBERHOLD M. , GULDNER K. , SUESS‐FINK G. + 
Published: May 2016

AbstractThe title compound (I) is prepared by 1:2 molar reaction of bis(di‐tert‐butylarsino) sulphur diimide with Os3(CO)11(NCMe) in CH2Cl2 at room temperature.
ChemInform Abstract: An Asymmetric Synthesis of Enantiomerically Pure (S)‐(+)‐Linalool (3,7‐Dimethyl‐1,6‐octadien‐3‐ol) and a Formal Synthesis of (R)‐(‐)‐Linolool.
Authors: OHWA M. , KOGURE T. , ELIEL E. L. 
Published: May 2016

AbstractSynthesis of S‐(+)‐linalool (VIII), using the optically active oxathiane (Ia) as a chiral template, is described.
ChemInform Abstract: Chromium(III)‐Doped Pillared Clays (PILC′s).
Authors: CARRADO K. A. , SUIB S. L. , SKOULARIKIS N. D. , COUGHLIN R. W. 
Published: May 2016

AbstractBy the use of different synthetic conditions Cr(III) ions are introduced into a low‐iron‐content bentonite clay in both pillared and unpillared forms.
ChemInform Abstract: Phase Relations and Electrical Properties of Samples of the System La2O3‐NiO‐ZrO2.
Authors: MAKHNACH L. V. , KONONYUK I. F. 
Published: May 2016

AbstractThe phase relations and the electrical properties of samples prepared from La2O3·(2‐x)NiO·xZrO2 (0 < x < 2) are studied.
ChemInform Abstract: The Ce(PO3)3‐RbPO3 System.
Authors: MARDIROSOVA I. V. , BUKHALOVA G. A. , ALI M. M. 
Published: May 2016

AbstractCe2(CO3)3 and Rb2CO3 are converted to Ce(PO3)3 and RbPO3 by NH4H2PO4.
ChemInform Abstract: On the Existence and Electrical Properties of New Cubic Ternary Silicides M3Os4Si13 and M3Ir4Si13 (M: Ho, Er, Lu) of Yb3Rh4Sn13‐Type Structure.
Authors: LLORET B. , CHEVALIER B. , LEJAY P. , ETOURNEAU J. 
Published: May 2016

AbstractThe novel title silicides are prepared by arc melting of the elements in a pure argon atmosphere.
ChemInform Abstract: Intramolecular Electron Exchange with Solvent Participation: ESR Study of the Radical‐Anion of Benzene‐1,3‐dicarbaldehyde in Propan‐2‐ol‐Water Mixtures.
Authors: SHOHOJI M. C. B. L. , HEROLD B. J. , NOVAIS H. M. , STEENKEN S. 
Published: May 2016

AbstractAn alternating linewidth effect in the ESR of the Z,E‐rotamer of the title compound is interpreted in terms of a two‐jump model involving the two asymmetrically solvated radical anions (I) and (II) (energy of activation 23.7 kJ/mol).
ChemInform Abstract: 13C NMR Studies of Synthetic (Fe4S4(SR)4)2‐ Iron‐Sulfur Clusters (I).
Authors: OLLERENSHAW T. J. , BRISTOW S. , ANAND B. N. , GARNER C. D. 
Published: May 2016

AbstractExamination of the signs of the paramagnetic isotropic shifts leads to the conclusion that contact interactions dominate the shift mechanism.
ChemInform Abstract: Bis(2‐((3‐aminopropyl)amino)ethanolato)nickel(II) Chloride and Bromide: Crystal Structure and Magnetic Characterization.
Authors: NIEMINEN K. 
Published: May 2016

AbstractThe title compounds (I), prepared by the reaction of NiCl2·6 H2O and NiBr2·3 H2O in absolute ethanol with the amine component (no yields given), are isomorphous and crystallize both in the space group Pnna with Z=4.
ChemInform Abstract: Heterocyclic Nitrogen‐Containing Electron‐Pair Donor Ligands: A Thermochemical Study of Adducts with Zinc, Cadmium, and Mercury Chlorides.
Authors: AIROLDI C. , SILVA M. L. C. P. , CHAGAS A. P. 
Published: May 2016

AbstractThe standard enthalpies of the reactions of metal chlorides with the ligands pyridine, bipyridine and phenanthroline giving the adducts (I)‐(III) are measured calorimetrically.
ChemInform Abstract: NAD(P)H Models. Part 22. Magnesium Ion Mediated Acid Catalysis of the Reduction of Imines by Hantzsch Ester.
Authors: VAN NIEL J. C. G. , KORT C. W. F. , PANDIT U. K. 
Published: May 2016

AbstractThe mechanism of the reduction of the imines (I) derived from butylamine and substituted benzaldehydes by the Hantzsch ester (II) in the presence of Mg(ClO4)2 in MeCN to give the products (III) is investigated in detail.
ChemInform Abstract: A Facile Preparative Method for Thiolesters from Thiols and Thiocarboxylic Acids Catalyzed by a Sodium Salt of Oxo Acid of Sulfur.
Authors: YAMAUCHI T. , NAKAO K. , TAMAKI K. 
Published: May 2016

AbstractThe thiolesters (III), (V) and (VIII) are prepared from the reaction of the thiols (I), (IV) and (VI) with the thiocarboxylic acids (II) or (VII) in the presence of Na2SO3 as catalyst.
ChemInform Abstract: A Convenient Synthesis of 2‐Cyclopentenone.
Authors: TAKANO S. , IWABUCHI Y. , TAKAHASHI M. , OGASAWARA K. 
Published: May 2016

AbstractThe oxidation of cyclopentadiene (I) with the hydroperoxides (II) in the presence of Cu(OAc)2 produces the alkoxycyclopentenyl acetates (III) which are hydrolyzed to give the hydroxyethers (IV).
ChemInform Abstract: The Oxidation of Aldehyde Bisulfite Adducts to Carboxylic Acids and Their Derivatives with Dimethylsulfoxide and Acetic Anhydride.
Authors: WUTS P. G. M. , BERGH C. L. 
Published: May 2016

AbstractThe aldehydes (I) are easily converted to the carboxylic acids (IV) as outlined.
ChemInform Abstract: Studies on Hypolipidemic Agents. Part 2. Synthesis of 1‐Arenesulfonyloxy‐2‐alkanone Derivatives as Potent Esterase Inhibitors and Hypolipidemic Agents.
Authors: OGAWA K. , TERADA T. , MURANAKA Y. , HAMAKAWA T. , HASHIMOTO S. , FUJII S. 
Published: May 2016

AbstractA large series of the arenesulfonyloxy‐2‐alkanones (I) and ‐acetals (II) is synthesized by conventional methods.
ChemInform Abstract: Cycloalkanes. Part 4. Friedel‐Crafts Condensation of cis‐Cyclohexane1,2‐dicarboxylic Acid Anhydride with Aromatic Compounds and Synthesis of Simple and Substituted 2,3‐Tetramethylene‐5,6‐benzocyclohexanes.
Authors: MATHUR K. C. , BHARGAVA L. 
Published: May 2016

AbstractDie partiell hydrierten Anthracen‐Derivate (VI) werden durch FriedelCrafts‐Kondensation von cis‐Cyclohexan‐1,2‐dicarbonsäureanhydrid (I) mit den Aromaten (II) über die im Formelschema angegebenen Zwischenstufen dargestellt.
ChemInform Abstract: The Benzylic Effect in Nucleophilic Attack on Oxiranes.
Authors: LYNAS‐GRAY J. I. , STIRLING C. J. M. 
Published: May 2016

AbstractThe reactivities of the oxiranes (I) and (II) toward the nucleophiles (VI)‐(VIII) are investigated in comparison to those of the oxiranes (III)‐(V).
ChemInform Abstract: Palladium‐Catalyzed Reaction of 2‐Hydroxyaryl and Hydroxyheteroaryl Halides with 1‐Alkynes: An Improved Route to the Benzo(b)furan Ring System.
Authors: ARCADI A. , MARINELLI F. , CACCHI S. 
Published: May 2016

AbstractThe acetylenes (II) react with the hydroxyaryl or pyridyl halides (I), yielding the benzo or pyridofuran derivatives (III).
ChemInform Abstract: Strain‐Barrier Stabilized Products from the Fischer Indole Synthesis. Compounds Containing the 4H‐Imidazo(1,2‐a)pyrrolo(3,4‐b)indole and Dipyrrolo(3,4‐b:3′,4′‐b′)(1,3)diazeto(1,2‐a:3,4‐a′)diindole Ring Systems.
Authors: SOUTHWICK P. L. , SULLIVAN D. S. III 
Published: May 2016

AbstractThe amino compounds (II), obtained from the phenylhydrazones (I) by Fischer indole synthesis, fail to eliminate ammonia when treated with strong acids in methanol.
ChemInform Abstract: Preparation of 1,2‐Benzisoxazole 2‐Oxides.
Authors: BOULTON A. J. , TSOUNGAS P. G. , TSIAMIS C. 
Published: May 2016

AbstractThe title compounds (II), (III), (IV), and (V) are prepared by the oxidative cyclization of the respective o‐acylphenol oximes similarly to the synthesis of (IIa) from (I) using either Pb(‐OAc)4 or sodium hypochlorite.
ChemInform Abstract: An Efficient Synthesis of 4‐Acyl‐5‐hydroxy‐3‐methylisoxazoles through an Acyl‐Transfer Reaction.
Authors: SATO K. , UEDA T. , SUGAI S. 
Published: May 2016

AbstractThe acylation of the methyl isoxazolinone (I) with the acyl chlorides (II) produces mixtures of the isomeric O‐acyl isoxazoles (III) and N‐acyl isoxazolinones (IV), which are converted to the corresponding 4‐acyl isoxazoles (V) in the presence of bases.
ChemInform Abstract: An Improved Synthesis of 1H‐1,2,4‐Triazoles from C‐Triphenylphosphinimino‐hydrazones.
Authors: BRUCHE L. , GARANTI L. , ZECCHI G. 
Published: May 2016

AbstractThe 1‐phenyl‐1,2,4‐triazoles (IV) are obtained from the triphenylphosphine imide (I) by acylation with the acyl chlorides (II) and subsequent treatment with triethylamine.
ChemInform Abstract: Single Electron Transfer Initiated Photocyclization of Substituted Cinnamic Acids to Corresponding Coumarins.
Authors: PANDEY G. , KRISHNA A. , RAO J. M. 
Published: May 2016

AbstractThe alkoxy‐substituted cinnamic acids (I) are converted to the coumarins (III) by photolysis in the presence of 1,4‐dicyano‐naphthalene (II).
ChemInform Abstract: Pyridine Sulphenyl Halides. Part 1.
Authors: KULKARNI Y. D. , SINGH R. V. 
Published: May 2016

AbstractDas Sulfenylbromid (II), welches aus dem Disulfid (I) durch Umsetzung mit Brom erhalten wird, reagiert mit den Aminen (III) unter Bildung der entsprechenden Sulfenamide (IV).
ChemInform Abstract: Dihalotriphenylphosphoranes for Heterocyclic Synthesis. Part 14. A Simple Synthesis of 4‐Cyanomethylpyridine.
Authors: WAMHOFF H. , RUEB H. L. + 
Published: May 2016

AbstractThe title compound (II) is synthesized by two routes: by treating 4‐pyridylcarbinol (I) with KCN in a multisolvent system in the presence of (18)crown‐6 or from 4‐vinylpyridine (III) by the Willgerodt reaction, yielding the amide (IV), followed by dehydration.
ChemInform Abstract: Buspirone Analogues. Part 2. Structure‐Activity Relationships of Aromatic Imide Derivatives.
Authors: NEW J. S. , YEVICH J. P. , EISON M. S. , TAYLOR D. P. , EISON A. S. , RIBLET L. A. , VANDERMAELEN C. P. , TEMPLE D. L. JUN. 
Published: May 2016

AbstractThe anxiolytic activity of the aromatic imide derivatives (I), prepared from the corresponding dicarboxylic acids, is evaluated.
ChemInform Abstract: Preparation of Dimethylsilyl Bis‐enol Ethers.
Authors: FATAFTAH Z. A. , IBRAHIM M. R. , ABU‐AGIL M. S. 
Published: May 2016

AbstractThe ketones (I) are coupled with dimethyl dichlorosilane (II) in the presence of lithium tetramethylpiperidide or triethylamine to produce the bisenol ethers (III).
ChemInform Abstract: The Wagner‐Meerwein Analogous 1,2‐Shift of a Trimethylsilyl Group from Silicon to Carbon During Cleavage of ((Trimethylsilyl)silyl)methyl Ethers.
Authors: MAERKL G. + , HORN M. , SCHLOSSER W. 
Published: May 2016

AbstractTris(trimethylsilyl)silyl lithium (I) and the chloroethers (II) are combined to produce the α‐methoxy silyl derivatives (III).
ChemInform Abstract: Cyano Derivatives of Some Organochlorophosphate(V) Ions.
Authors: DENG R. M. K. , DILLON K. B. 
Published: May 2016

AbstractReaction of excess AgCN with the organochlorophosphates (I) leads to the formation of the tricyanophenylphosphate (IIa) (all three isomers) and of pentacyanomethylphosphate (IIb).
ChemInform Abstract: Desulfurizative Germylation: Synthesis and Reaction of Allyl‐ and Allenylgermanes.
Authors: SANO H. , MIYAZAKI Y. , OKAWARA M. , UENO Y. 
Published: May 2016

AbstractThe allyl‐ and allenylgermanes (III) and (V) are prepared from the allyl‐ or propargyl sulfur compounds (I) and (IV) by radical‐induced reaction with triphenylgermane (II).
ChemInform Abstract: 1,2‐Shift of a Trimethylsilyl Group from Germanium to Carbon During Cleavage of ((Trimethylsilyl)germyl)methyl Ethers.
Authors: MAERKL G. + , WAGNER R. 
Published: May 2016

AbstractTetrakis(trimethylsilyl) germane (I) reacts with methyl lithium to give the tris(trimethylsilyl) derivative (II) which is substituted with the α‐chloroethers (III), yielding the products (IV).
ChemInform Abstract: Steric and Electronic Factors Influencing the Amounts of μ‐Alkylidyne and μ‐Alkenyl Products Obtained from Reaction of Diiron Methylidyne Complexes with Alkenes.
Authors: CASEY C. P. , MESZAROS M. W. , COLBORN R. E. , RODDICK D. M. , MILES W. H. , GOHDES M. A. 
Published: May 2016

AbstractThe reaction of (I) with monosubstituted alkenes gives μ‐alkylidyne products (II), which are characterized by deprotonation to give the μ‐alkenylidene complexes (III).
ChemInform Abstract: HFe(CO)‐ 4, a Versatile Reagent Toward Chlorophosphines. Facile Synthesis of New Phosphorus Transition‐Metal Complexes.
Authors: MATHIEU R. , CAMINADE A.‐M. , MAJORAL J.‐P. , ATTALI S. , SANCHEZ M. 
Published: May 2016

AbstractWhen a solution of the hydride (I) and a solution of the phosphines (II) are added simultaneously, the stable complexes (III) are formed quantitatively.
ChemInform Abstract: Reaction of ((OC)2(cp)FeC(S)SFe(cp)(CO)2) (cp: η5‐C5H5) with Dicobalt Octacarbonyl; X‐Ray Crystal Structure of (Co3Fe(cp)(CO)9(CS)) Containing a Six‐electron Donor Thiocarbonyl Group.
Authors: BUSETTO L. , ZANOTTI V. , ALBANO V. G. , BRAGA D. , MONARI M. 
Published: May 2016

AbstractThe title reaction produces the novel mixed‐metal cluster (II) containing a thiocarbonyl group and the two known derivatives (III) and (IV).
ChemInform Abstract: Metal Ions‐Purine Interactions: Dichloro‐Gold(III) Complexes of Some Theophylline Derivatives.
Authors: COLACIO‐RODRIGUEZ E. , SALAS‐PEREGRIN J. M. , MORENO CARRETERO M. N. 
Published: May 2016

AbstractHAuCl4 reacts with theophylline derivatives in aqueous solution to give the compounds (I) (no yields given) which are characterized by spectral (IR, 1H NMR) and thermal (TG, DSC) methods.
ChemInform Abstract: Syntheses and Reactions of Methyl(methoxymethyl)‐ and Dimethylrhodium(III) Complexes.
Authors: THORN D. L. 
Published: May 2016

AbstractThe complex (I) reacts with Me3SiBr under cleavage of the C‐O bond to produce ethylene, formed by methyl migration to a methylene entity and subsequent β‐elimination.
ChemInform Abstract: Ligand Exchange Reactions in Cyclopalladated Complexes of Benzylideneanilines. Crystal Structure of (Pd(C6H4CH=NC6H5)Br(PPh3)2).
Authors: GRANELL J. , SAINZ D. , SALES J. , SOLANS X. , FONT‐ALTABA M. 
Published: May 2016

AbstractThe acetate‐bridged orthometallated Pd(II) dimers (I) are prepared from Pd(II) acetate and the imine ligands in acetic acid.
ChemInform Abstract: Bimetallic Systems. Part 15. Some Reactions of Platinum‐Manganese Carbonyl Complexes Containing Bridging Ph2PCH2PPh2 (dppm) Ligands.
Authors: CARR S. W. , SHAW B. L. 
Published: May 2016

AbstractStarting from the diphosphine‐bridged Mn‐Pt‐halide complexes (Ia,b) a variety of diphosphine‐bridged Mn‐Pt complexes are prepared.
ChemInform Abstract: Synthesis, Molecular Structures, and NMR Properties of the Macropolyhedral Metallaboranes ((PMe2Ph)4Pt3B14H16) and ((PMe2Ph)PtB16H18(PMe2Ph)), and a Discussion of the Bonding at Platinum in These and Some Related Platinaborane Clusters.
Authors: BECKETT M. A. , CROOK J. E. , GREENWOOD N. N. , KENNEDY J. D. 
Published: May 2016

AbstractThe thermolysis of the arachno‐compound (I) in refluxing toluene solution gives the known 14‐vertex diplatinaborane (II) plus the two novel air‐stable 17‐vertex clusters (III) and (IV).
ChemInform Abstract: Synthesis and Anti‐Herpes‐Virus Activity of Acyclic 2′‐Deoxyguanosine Analogues Related to 9‐((1,3‐Dihydroxy‐2‐propoxy)methyl)guanine.
Authors: MARTIN J. C. , MCGEE D. P. C. , JEFFREY G. A. , HOBBS D. W. , SMEE D. F. , MATTHEWS T. R. , VERHEYDEN J. P. H. 
Published: May 2016

AbstractSeveral acyclic nucleoside analogues were prepared and investigated for their antiviral activities.