bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: New Substitution Reaction of Allylic Nitro Compounds. Regioselective Replacement of Nitro Groups in Cyclic α‐(Nitroalkyl)enones by Nucleophiles.
Authors: TAMURA R. , TAMAI S. , SUZUKI H. 
Published: May 2016

AbstractThe cycloalkanones (I) are coupled with the nitroalkanes (II) and then epoxidized to give the fused nitromethyloxiranes (III).
ChemInform Abstract: Decomposition of Diacyl Peroxides. Part 9. Mechanism of the Carboxy‐Inversion Process in the Thermal Decomposition of Benzoyl Cyclohexanecarbonyl Peroxide and Related Diacyl Peroxides.
Authors: FUJIMORI K. , OAE S. 
Published: May 2016

AbstractThis is studied by a range of 18O‐tracer experiments under a variety of conditions with peroxides such as (I), especially (Ia).
ChemInform Abstract: Acyl Derivatives of Hydroxamic Acids as a Source of Carbon Radicals.
Authors: BARTON D. H. R. , BLUNDELL P. , JASZBERENYI J. C. 
Published: May 2016

Abstractβ‐Phenylpropionic acid (I) reacts with the cyclic hydroxylamines (II) to form the hydroxamic acids (III).
ChemInform Abstract: Diastereoselective Synthesis of α‐Allenic Alcohols from Propargylic Epoxides.
Authors: ALEXAKIS A. , MAREK I. , MANGENEY P. , NORMANT J. F. 
Published: May 2016

AbstractThe 1‐alkynylcyclohexene oxides (I) are cleaved with the organomagnesium bromides (II) in the presence of a copper(I) phosphine catalyst, yielding the ethenylidenecyclohexanols (III).
ChemInform Abstract: Ylidions: A New Reactive Intermediate Prepared by Photosensitized One‐Electron Oxidation of Phenacyl Sulfonium Ylides.
Authors: ZHANG J.‐J. , SCHUSTER G. B. 
Published: May 2016

AbstractPhotosensitized one‐electron oxidation of phenacyl sulfonium ylides such as (I) or (VI) generates phenacyl sulfonium ylidions such as (II).
ChemInform Abstract: Synthesis of Five‐Membered Cyclic Ketones Using Potassium Tetracarbonylferrate(2‐).
Authors: YAMASHITA M. , UCHIDA M. , TASHIKA H. , SUEMITSU R. 
Published: May 2016

AbstractFive‐membered cyclic lactones can be prepared in moderate to high yields from 1,4‐dihaloalkanes according to the reaction conditions A) (discussion of the reaction mechanism).
ChemInform Abstract: Structure and Properties of the Cryptophane‐E/CHCl3 Complex, a Stable van der Waals Molecule.
Authors: CANCEILL J. , CESARIO M. , COLLET A. , GUILHEM J. , LACOMBE L. , LOZACH B. , PASCARD C. 
Published: May 2016

AbstractIn the absence of hydrophobic effects, the driving force for complexation between neutral host and guest molecules (e.g.
ChemInform Abstract: Tris(2,2,2‐trifluoroethyl)amine and Its Reactions with Halogens.
Authors: BUERGER H. + , KRUMM B. , PAWELKE G. 
Published: May 2016

AbstractReaction of excess trifluoroethyl nonaflate (I) with ammonia (II) yields the tris‐ (III) and bis(trifluoroethyl)amines (IV).
ChemInform Abstract: Preparation of Some 9‐Hydroxy‐2‐oxaspiro(4.5)dec‐8‐ene‐1,7‐dione Derivatives by Reductive Alkylation of 3,5‐Dimethoxybenzoic Acid with 1,2‐Dihaloalkane and Oxirane Electrophiles.
Authors: WILKIE J. S. , WINZENBERG K. N. 
Published: May 2016

AbstractTen title compounds of type (III) and (V) are synthesized.
ChemInform Abstract: Synthesis of 1,8,8‐Trimethyl‐5‐methylene‐1,3,6‐cyclooctatriene from 3‐Carene.
Authors: VYGLAZOV O. G. , MANUKOV E. N. , CHUIKO V. A. 
Published: May 2016

AbstractThe dihalotricyclooctanes (I) are prepared from 3‐carene according to well known procedures.
ChemInform Abstract: trans,trans‐p‐Di(1,2‐difluoro‐2‐formylvinyl)benzene.
Authors: CHEREDNICHENKO P. G. , KREMLEV M. M. , YAGUPOL'SKII L. M. 
Published: May 2016

AbstractTreatment of p‐phenylenemagnesium dibromide with chlorotrifluoroethene (II) yields the derivative (III).
ChemInform Abstract: The Chemistry of Perfluoroalkanesulfonyl Iodides.
Authors: HUANG W.‐Y. , HU L.‐Q. 
Published: May 2016

AbstractRadical‐induced addition of ω‐chloropolyfluoroalkanesulfonyl iodides, generated from the silver sulfinates (II), to alkenes and alkynes are investigated.
ChemInform Abstract: Regiospecific Tetrahydropyran‐3‐one Enolates. Synthesis and Reactivity of Silyl Enol Ether Derivatives.
Authors: COX P. , MAHON M. F. , MOLLOY K. C. , LISTER S. , GALLAGHER T. 
Published: May 2016

AbstractThe silyl enol ether (VI), derived from dihydropyran (I), is coupled with various electrophilic moieties in the presence of Lewis acids, e.g. tin or titanium tetrachloride or trimethylsilyl triflate.
ChemInform Abstract: The Effect of the Substituents in (R3Si)2P‐SiR2Cl on the Formation and the Properties of the Hexasilatetraphospha‐adamantanes and Their 31P NMR Spectra.
Authors: FRITZ G. , REUTER J. 
Published: May 2016

AbstractThermolysis of the type (R3Si)2P‐SiR2Cl is investigated.
ChemInform Abstract: Chlorovinylation of Benzeneselenol and Diorganyl Diselenides by Chloro‐ and Dichloroacetylenes.
Authors: MARTYNOV A. V. , MIRSKOVA A. N. , VORONKOV M. G. 
Published: May 2016

AbstractBenzeneselenol (I) and the diselenides (IV) react smoothly with mono(IIa) or dichloroacetylene (IIb) to give the adducts (III) or (V), respectively.
ChemInform Abstract: Preparation of Novel Metal Dithiocarbamate Complexes Containing ω‐OH Group. Stabilization Effect of the OH Group on the HNCS2‐M Linkage.
Authors: NOMURA R. , FUJII S. , TAKABE A. , MATSUDA H. 
Published: May 2016

AbstractThe direct condensation between metal oxide powders, alkanolamines and CS2 yields the metal dithiocarbamate complexes (IV) as demonstrated for (IVa).
ChemInform Abstract: Polyhedral Aluminosilsesquioxanes: Soluble Organic Analogues of Aluminosilicates.
Authors: FEHER F. J. , BUDZICHOWSKI T. A. , WELLER K. J. 
Published: May 2016

AbstractThe 1:1 molar reaction of the trisilanol (I) with AlMe3 (II) affords the new Al‐containing silsesquioxane (III) (space group P22121 or P212121).
ChemInform Abstract: (VO(O2CtBu)3) and (V6O6(μ‐O)4(μ‐O2CPh)9). Structural Characterization of a Mononuclear V(V) and a (2 + 4)‐Nuclear V(IV)V(V)5 Carboxylato Complex. Models for Vanadate‐Dependent Peroxidases.
Authors: REHDER D. , PRIEBSCH W. , VON OEYNHAUSEN M. 
Published: May 2016

AbstractThe two title complexes (III) (space group C2/c, Z = 8) and (VI) ( P21/n, Z=4) prepared according to the scheme are interesting models for the structure of the V center in haloperoxidases from marine brown algae.
ChemInform Abstract: Metal‐Mediated Functionalization of Tetrahydronaphthalene, Octahydroanthracene, and Tetrahydroquinoline: Stereochemical Control of Nucleophilic Addition to Cationic Cyclopentadienyl(η6‐arene)iron(II) Complexes via Benzylic Substitution.
Authors: GRUNDY S. L. , SAM A. R. H. , STOBART S. R. 
Published: May 2016

AbstractTreatment of the cationic tetrahydronaphthalene complex (I) with hydride or carbon nucleophiles such as (II) or (III) affords mixtures of the isomeric neutral η5‐cyclohexadienyl complexes (IV) and (V) with low to moderate regioselectivity.
ChemInform Abstract: Synthesis and Characterization of Copper(II) Complexes with a Tridentate Schiff Base Ligand Derived from 5‐Chloro‐2‐hydroxyacetophenone and Salicylhydrazide. X‐Ray Structure of Copper(II) (5‐Chloro‐2‐hydroxyacetophenone‐salicylhydrazide) Dimethylformamide.
Authors: DANCE J. M. , DO P. GAMBARDELLA M. T. , DE A. SANTOS R. H. , MEDINA E. , MANRIQUE F. G. , PALACIOS M. S. 
Published: May 2016

AbstractThe Schiff base from salicylhydrazide and 5‐chloro‐2‐hydroxyacetophenone reacts with Cu(II) acetate monohydrate in refluxing ethanol to give a 1:1 complex which forms the DMF derivative (I) (space group P1, Z=2) on recrystallization from DMF.
ChemInform Abstract: Synthesis and Spectroscopic Characterization of a Novel Iridium Polyhydride (Ir2(μ‐H)3H2(dippe)2)PF6; dippe: 1,2 Bis(diisopropylphosphino)ethane.
Authors: EL‐AMOURI H. , BOUAYAD A. 
Published: May 2016

AbstractTreatment of the complex (I) with H2 in benzene and in the presence of even 10 equivalents of NEt3 affords the binuclear title complex (II) and not the expected mononuclear pentahydride complex.
ChemInform Abstract: Synthesis of Benzimidazo(1,2‐a)quinolines: Fluorescent Disperse Dyes.
Authors: SHENOY V. U. , SESHADRI S. 
Published: May 2016

AbstractThe Knoevenagel condensation reaction of the aldehyde (I) with the nitrile (II) yields the styryl derivative (III) which is converted to the aldehyde (V) via the nitrile (IV).
ChemInform Abstract: Convenient Syntheses of Substituted Pyranoid Glycals from Thiophenyl Glycosides and Glycosyl Phenyl Sulfones.
Authors: FERNANDEZ‐MAYORALAS A. , MARRA A. , TRUMTEL M. , VEYRIERES A. , SINAY P. 
Published: May 2016

AbstractThe glycosyl phenyl sulfides (I) and (IIIa) ‐ (IIIc) or the related sulfones (VII) are treated with lithium naphthalenide to produce the glycals (II), (IV), or (V).
ChemInform Abstract: Synthesis of Nucleosides and Their Related Compounds. Part 12. Menthyl 2,4‐Dioxo‐1,3‐oxazine‐5‐carboxylates: New Dienophiles for the Asymmetric Diels‐Alder Reaction Directed Towards Synthesis of Carbocyclic C‐Nucleosides.
Authors: KATAGIRI N. , HIROSE M. , SATO M. , KANEKO C. 
Published: May 2016

AbstractFormyl Meldrum's acid (I) is converted to the cyclic acetals (V) via the chiral half esters (III).
ChemInform Abstract: Characterization by Analytical Electron Microscopy and Single Crystal X‐Ray Diffraction of BaNb8O14, a Metal Oxide Containing Octahedral Nb6O12 Clusters.
Authors: HIBBLE S. J. , CHEETHAM A. K. , KOEHLER J. + , SIMON A. 
Published: May 2016

AbstractThe title oxide, obtained by a solid‐state reaction which is outlined in the scheme, crystallizes in two modifications (A) and (B) (Pbam, Z=2, isotypic with SrNb8O14 and Cmca, Z = 8, resp.).
ChemInform Abstract: Crystal Structure of Cd2AsO4F and Its Relation to a Series of Oxide Silicates and Oxide Germanates of the Rare Earth Metals.
Authors: ENGEL G. 
Published: May 2016

AbstractThe title compound belongs to the monoclinic space group C2/c with Z = 8 and is isotypic with Cd2PO4F and Mn2PO4F. Its structure contains distorted CdO4F2 octahedra with the F atoms in neighboring equatorial positions and AsO4 tetrahedra.
ChemInform Abstract: Physico‐Chemical Characterization and Framework Topology of Zeolite ZSM‐20.
Authors: FUELOEP V. + , BORBELY G. , BEYER H. K. , ERNST S. , WEITKAMP J. 
Published: May 2016

AbstractZeolite ZSM‐20 and a dealuminated sample of ZSM‐20 are characterized by XRD, 27Al and 29Si MAS NMR, IR spectroscopy and thermal analysis.
ChemInform Abstract: Preparation and Thermal Properties of Zr‐Intercalated Clays.
Authors: FIGUERAS F. , MATTROD‐BASHI A. , FETTER G. , THRIERR A. , ZANCHETTA J. V. 
Published: May 2016

AbstractIn the preparation of Zr‐pillared montmorillonites, diffusion of the Zr cations controls the rate of ion exchange and the distribution of the Zr pillars.
ChemInform Abstract: Formation of Crystalline Compounds and Catalyst Deactivation During SO2 Oxidation in V2O5‐M2S2O7 (M: Na, K, Cs) Melts
Authors: BOGHOSIAN S. , FEHRMANN R. , BJERRUM N. J. , PAPATHEODOROU G. N. 
Published: May 2016

Abstractis studied over the temp. range 350‐480 °C using a feed gas of 10% SO2, 11% O2, and 79% N2 (a detailed description of the reactor system that allows the isolation of precipitates under operating conditions is given).
ChemInform Abstract: Crystalline Holmium Dichloride.
Authors: GORYUSHKIN V. F. , ASTAKHOVA I. S. , POSHEVNEVA A. I. , ZALYMOVA S. A. 
Published: May 2016

AbstractThe solid phase reaction between HoCl3 and Ho, which is conducted at 780 K under a vacuum, affords the title compound, whose structure is elucidated by XRD.
ChemInform Abstract: Synthesis and Crystal Structure of the Fluorophosphate Na3Cr2(PO4)2F3.
Authors: SLOBODYANIK N. S. , NAGORNYI P. G. , KORNIENKO Z. I. , KAPSHUK A. A. , MITKEVICH V. V. 
Published: May 2016

AbstractThe new title compound is obtained from a melt in the system Na2O‐P2O5‐Cr2O3‐NaF at 950 °C. It crystallizes in the tetragonal space group I4/mmm with Z=2.
ChemInform Abstract: Gas‐Phase Reactions of Nb+ and Ta+ with Alkanes and Alkenes. C‐H Bond Activation and Ligand‐Coupling Mechanisms.
Authors: BUCKNER S. W. , MACMAHON T. J. , BYRD G. D. , FREISER B. S. 
Published: May 2016

AbstractThe reactions of Nb+ with alkanes and alkenes in the gas phase are studied by using Fourier transform mass spectrometry.
ChemInform Abstract: Sodium Bromide‐Catalyzed Regioselective Cleavage of Oxiranes with Chlorotrimethylsilane.
Authors: IQBAL J. , KHAN M. A. , AHMAD S. 
Published: May 2016

AbstractThe ring opening of the epoxides (I) is achieved with the chlorosilane (II) in the presence of catalytic amounts of sodium bromide to produce the α‐chloro silyl ethers (III) and/or (IV).
ChemInform Abstract: Asymmetric Hydrogenation of Prochiral Alkenes Catalyzed by Ruthenium Complexes of (R)‐(+)‐2,2′‐Bis(diphenylphosphino)‐1,1′‐binaphthyl.
Authors: KAWANO H. , IKARIYA T. , ISHII Y. , SABURI M. , YOSHIKAWA S. , UCHIDA Y. , KUMOBAYASHI H. 
Published: May 2016

AbstractAs Ru catalysts have been less well studied than corresponding Rh complexes, substrates of type (I), (III)/(V) and (VI) are subjected to asymmetric hydrogenation using both a binuclear and a mononuclear chiral Ru complex.
ChemInform Abstract: Diastereofacial Selection in the Conjugate Reduction of γ‐Alkyl‐α,β‐Unsaturated Carbonyl Derivatives. Stereocontrol Dictated by Aromatic Ring‐Pd Interaction.
Authors: YAMAMOTO Y. , NISHII S. , IBUKA T. 
Published: May 2016

AbstractThe anti products (III) and (VI) are the major isomers obtained both by Birch reduction of (I) and (IV) and ‐ surprisingly ‐ by treatment with hydride reagents.
ChemInform Abstract: Catalytic Intermolecular Hydrogen Transfer with Photogenerated Hydride Transient CoH(PPh(OEt)2)3.
Authors: ONISHI M. , MATSUDA M. , TAKAKI I. , HIRAKI K. , OISHI S. 
Published: May 2016

AbstractPhotoirradiation of the thermally inert complex (I) generates the coordinatively unsaturated active title hydride species, which catalyzes intermolecular hydrogen transfer from secondary alcohols to ketones (such as cyclohexanone, acetophenone).
ChemInform Abstract: Use of High Pressure in the Reduction of Organic Chlorides with Tri‐n‐butyltin Hydride.
Authors: RAHM A. , AMARDEIL R. , DEGUEIL‐CASTAING M. 
Published: May 2016

AbstractThe organic halides (I), (III), (V), and (IX) are reduced with tri‐n‐butyltin hydride under high pressure in the absence of a catalyst or a free radical initiator, forming the hydrocarbons shown in the reaction scheme.
ChemInform Abstract: Aziridination of Phenylalkenylsilanes and Phenylalkenylstannanes.
Authors: ATKINSON R. S. , KELLY B. J. 
Published: May 2016

AbstractIn contrast to 1‐silyl‐ and 1‐stannylaziridines, very little is known about their 2‐ or 3‐isomers.
ChemInform Abstract: Aromatic Acylation/Reduction: An Efficient Friedel‐Crafts Alkylation Reaction.
Authors: JAXA‐CHAMIEC A. , SHAH V. P. , KRUSE L. I. 
Published: May 2016

AbstractThe title methodology involves the in situ reduction of the carbonyl‐Lewis acid complex formed in the Friedel‐Crafts acylation; it gives access to branched and functionalized alkylated arenes such as (III), (V), (VI) and (IX) without formation of the by‐products usually encountered in Friedel‐Crafts alkylations.
ChemInform Abstract: New Methods and Reagents in Organic Synthesis. Part 85. Enantioselective Synthesis of β‐Hydroxy‐α‐methyl Carbonyl Compounds by Aldol Reaction.
Authors: ANDO A. , SHIOIRI T. 
Published: May 2016

AbstractA variety of nearly 20 chiral amino ethers and diamines derived from amino acids are examined in the enantioselective aldol reaction.
ChemInform Abstract: Reactivity of Dimethyl N‐(Ethoxycarbonylmethyl)iminodithiocarbonate with Carbonyl Compounds in Basic Medium.
Authors: ALVAREZ‐IBARRA C. , LOPEZ‐RANZ M. M. , LOPEZ‐SANCHEZ M. I. , ORELLANA G. , ORTIZ P. , QUIROGA M. L. 
Published: May 2016

AbstractThe anion generated from the title compound (I) reacts with aromatic aldehydes such as (II) to yield acrylates (III), with the reaction proceeding via oxazole intermediates of type (IV).
ChemInform Abstract: α‐Enone by the Reaction of Aldehyde and α‐Bromo Ketone with Tri‐n‐butylstibine.
Authors: HUANG Y.‐Z. , CHEN C. , SHEN Y. 
Published: May 2016

AbstractVarious aldehydes, e.g. (I) or (IX), are coupled with the α‐bromo ketones, e.g. (II) or (X), in the presence of tri‐n‐butylstibine (III) to produce α,β‐unsaturated ketones such as (IV) or (XI) which favour the E‐configuration in general.
ChemInform Abstract: π‐Facial Stereoselectivity in Diels‐Alder Reaction of Hexacyclo‐(7.4.2.01,9.03,7.04,14.06,15)pentadecane‐10,12‐diene‐2,8‐dione.
Authors: PANDEY B. , ZOPE U. R. , AYYANGAR N. R. 
Published: May 2016

AbstractThe polycyclic dienedione (II) mentioned in the title is subjected to (4 + 2)cycloaddition reaction with the olefinic compounds (I), yielding selectively the products (III).
ChemInform Abstract: Synthesis of (R)‐2‐Benzyloxy‐1‐iodo‐3‐butene. A New Chiral Synthon from L‐(+)‐Tartaric Acid: Its Application to (R)‐γ‐Caprolactone.
Authors: YADAV J. S. , RAO E. S. , RAO V. S. 
Published: May 2016

AbstractThe benzyloxyiodobutene (IV) is prepared from the triol (I), derived from L‐tartaric acid, via the trimesylate (III).
ChemInform Abstract: An Efficient Procedure for the Synthesis of p‐Anisidine Phenylglyoxal Imine from Acetophenone.
Authors: DESMOND R. , MILLS S. , VOLANTE R. P. , SHINKAI I. 
Published: May 2016

AbstractOxidation of acetophenone (I) with dimethyl sulfoxide and aqueous hydrogen bromide generates phenylglyoxal (II) which is coupled in situ with p‐anisidine (III), forming the imine (IV).
ChemInform Abstract: Synthesis of Thiiranes from Epoxides in the Presence of Thiourea in a Weakly Hydrated Organic Medium.
Authors: BOUDA H. , BORREDON M. E. , DELMAS M. , GASET A. 
Published: May 2016

AbstractThe oxiranes (I) are treated with thiourea (II) or potassium thiocyanate (IV) in the presence of water at temperatures about 20 , forming the thiiranes (III).
ChemInform Abstract: Indoles. Part 8. Formation of Indolo(3,2‐b)carbazoles from 4,9‐Dihydropyrano(3,4‐b)indol‐1(3H)‐ones.
Authors: LEHMANN J. , HARTMANN U. 
Published: May 2016

AbstractThe δ‐lactone (I) is converted to the hydrazones (V) via reaction of the keto ester (III) with the diazonium salts (IV).
ChemInform Abstract: 1,4‐Dinitroimidazole and Derivatives. Structure and Thermal Rearrangement.
Authors: GRIMMETT M. R. , HUA S.‐T. , CHANG K.‐C. , FOLEY S. A. , SIMPSON J. 
Published: May 2016

AbstractWhen heated in solution, the title compound (IIIa) (space group P212121; Z=4) and its 2‐methyl derivative (IIIb) rearrange to give C‐nitro isomers and denitration products.
ChemInform Abstract: Reactions of 5‐Bromo‐2‐methoxytropone and 8‐Bromo‐ and 6,8‐Dibromocyclohepta(b)(1,4)benzoxazines with o‐Aminophenol.
Authors: NOZOE T. , WAKABAYASHI H. , ISHIKAWA S. 
Published: May 2016

AbstractReaction of the bromomethoxytropone (I) with o‐aminophenol (II) yields the heterocycles (III) and (IV), together with the amine (V).
ChemInform Abstract: Heterodiene Synthesis. Part 1. Reaction of 5‐Arylidenerhodanine Derivatives with 1‐Morpholinocyclohexene Enamine.
Authors: ABDEL‐RAHMAN M. , ABDEL‐GHANY H. , GHATTAS A.‐B. A. G. 
Published: May 2016

AbstractThe title reaction consists in a hetero‐Diels‐Alder cycloaddition process between (I) and (II), leading to the formation of the benzopyran derivatives (III).
ChemInform Abstract: The Interaction of Fluoride Ion with Organosilicons: Facile Isomerizations and New Reactions of Silicon Hydrides.
Authors: BLANKENSHIP C. , CREMER S. E. 
Published: May 2016

AbstractThe exo‐ (I) and endo‐3‐methyl‐3‐silabicyclo(3.2.1)octanes (II) are equilibrated by treatment with cesium fluoride in DMF in sealed 1H NMR tubes to form same exo/endo‐ratios.
ChemInform Abstract: Thiophosphorylated Vinyl Sulfides.
Authors: KOZLOV V. A. , CHURUSOVA S. G. , KONONOVA O. A. , NEGREBETSKII V. V. , GRAPOV A. F. , MEL'NIKOV N. N. 
Published: May 2016

AbstractThe thiophosphorylthio ketones (I) are coupled with the halides (II) under alkaline conditions to give the thiophosphoryloxyvinyl sulfides (III).
ChemInform Abstract: Reaction of Phosphorus(III) Isocyanates with Phosphorylated Unsubstituted and Dichloro‐Substituted Acetaldehyde.
Authors: TARASOVA R. I. , DVOINISHNIKOVA T. A. , SINITSYNA N. I. , GUSEINOV F. I. , ISMAILOV V. M. , MOSKVA V. V. 
Published: May 2016

AbstractReaction of the isocyanates (I) with the phosphorylacetaldehydes (II) followed by aqueous working up gives the diphosphorylethyl carbamates (III).
ChemInform Abstract: Reaction of SeO2 with Dienes. Part 1. Linalyl Acetate.
Authors: SAN FELICIANO A. , MEDARDE M. , LOPEZ J. L. , PEREIRA J. A. P. , CABALLERO E. , PERALES A. 
Published: May 2016

AbstractThe reaction of the linalyl acetate (I) with SeO2 (II) affords the Se containing substances (III) and (IV) among the usual allylic oxidation products.
ChemInform Abstract: Metal and Organometal Complexes of Oxy‐ and Thiophosphorus Acids. Part 4. O,O‐Alkylene and Dialkyl Dithiophosphates of Zirconium(IV).
Authors: YADAV J. S. , MEHROTRA R. K. , SRIVASTAVA G. 
Published: May 2016

AbstractThe Zr(IV) dithiophosphates (III) and (IV) are synthesized as demonstrated for the example (III) in dependence on the stoichiometric ratio.
ChemInform Abstract: Six‐Nitrogen Macrocyclic Complexes of the Dioxouranium(VI) and Praseodymium(III) Ions.
Authors: BENETOLLO F. , BOMBIERI G. , DE COLA L. , POLO A. , SMAILES D. L. , VALLARINO L. M. 
Published: May 2016

AbstractThe Schiff‐base condensation of diacetylpyridine (I) and diaminobenzene (III) in the presence of the uranyl salts (II) produces the complexes (IV).
ChemInform Abstract: Synthesis and Characterization of a Bis(oxo)‐Bridged MnIIIMnIII Complex, Bis(μ‐oxo)bis(N,N′‐bis((6‐methylpyrid‐2‐yl)methyl)ethane‐1,2‐diamine)dimanga# nese(III) Perchlorate.
Authors: GOODSON P. A. , HODGSON D. J. 
Published: May 2016

AbstractThe title complex (I) (space group P1, Z=2) is obtained with 5% yield by oxidation of an aqueous solution of Mn(II) perchlorate and the four‐dentate ligand in an equimolar ratio using oxygen (air).
ChemInform Abstract: Stereoselective Synthesis of a Phenylphosphido‐Bridged Dimetallic Complex: Crystal and Molecular Structure of ((R*,R*),(R*))‐(.+‐.)‐((η5‐C5H5)(1,2‐C6H4(PMePh)2)FePHPh(Cr(CO)5))·2 H2O·0.5 CH2Cl2·0.5 C4H8O.
Authors: HEY E. , WILLIS A. C. , WILD S. B. 
Published: May 2016

AbstractDeprotonation of the phenylphosphine‐Fe complex (I) followed by treatment of the intermediate phenylphosphido‐Fe complex with the Cr‐pentacarbonyl complex (II) produces a separable 3:2 mixture of the diastereomers (IIIa) (space group P1, Z=2) and (IIIb).
ChemInform Abstract: Intramolecular (4 + 2) Diels‐Alder Cycloaddition Reactions of Phospholes with Vinylphosphines Promoted by Nickel.
Authors: SOLUJIC LJ. , MILOSAVLJEVIC E. B. , NELSON J. H. , ALCOCK N. W. , FISCHER J. 
Published: May 2016

AbstractThe reaction of the divinylphosphine (II) with the phosphole (I) in the presence of NiBr2 (III) leads to the formation of a single diastereomer, the complex (IV) as the result of two sequential stereoselective intramolecular (4 + 2) Diels‐Alder cycloadditions.
ChemInform Abstract: Transition Metal Coordination Compounds of Two Pyrazole‐Substituted Ammonia Ligands. X‐Ray Structure of (Bis(bis(1‐pyrazolylmethyl)amine)cobalt(II))bis(nitrate).
Authors: DRIESSEN W. L. , WIESMEIJER W. G. R. , SCHIPPER‐ZABLOTSKAJA M. , DE GRAAFF R. A. G. , REEDIJK J. 
Published: May 2016

AbstractTris(1‐pyrazolyl)amine L1 reacts with corresponding metal salts in ethanol to give the 1:1 adducts (I) and (II), and the 1:3 adducts (III) in dependence on the ligand to metal ratios.
ChemInform Abstract: (μ‐1,1′‐Bis(diphenylphosphino)ferrocene)bis(chlorogold): Synthesis, Iron‐57 and Gold‐197 Moessbauer Spectroscopy, X‐Ray Crystal Structure, and Antitumor Activity.
Authors: HILL D. T. , GIRARD G. R. , MCCABE F. L. , JOHNSON R. K. , STUPIK P. D. , ZHANG J. H. , REIFF W. M. , EGGLESTON D. S. 
Published: May 2016

AbstractThe title complex (IV) crystallizes in the space group P1 with Z=3.
ChemInform Abstract: Insertion of an Ynamine into the C‐N Bond of a (Dimethylamino)carbene Ligand.
Authors: ADAMS R. D. , TANNER J. T. 
Published: May 2016

AbstractThe resulting complex (III), containing a terminally coordinated amidinium‐substituted propenyl ligand, is characterized by an X‐ray analysis (P1, Z=2).