bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2‐Dicarbonyl Compounds.
Authors: Ren Xiaoyu , Du Haifeng 
Published: June 2016

AbstractA variety of optically active α‐hydroxy ketones and esters is prepared utilizing the combination of tricyclohexylphosphine and chiral alkenylborane generated in situ from diyne as frustrated Lewis pair catalyst.
ChemInform Abstract: Cross‐Metathesis of Broensted Acid Masked Alkenylamines with Acrylates for the Synthesis of Polyamide Monomers.
Authors: Spiccia Nicolas Daniel , Solyom Szabolcs , Woodward Clint Peter , Jackson William Roy , Robinson Andrea Jane 
Published: June 2016

AbstractCross‐metathesis of alkenylamine salts with an excess of methyl acrylate or acrylic acid provides commercially valuable polyamide monomers.
ChemInform Abstract: Generation and Synthetic Application of Trifluoromethyl Diazomethane Utilizing Continuous Flow Technologies.
Authors: Pieber Bartholomaeus , Kappe C. Oliver 
Published: June 2016

AbstractThe simple and convenient protocol is based on the transformation of 2,2,2‐trifluoroethaneamine and sodium nitrite to form trifluoromethyl diazomethane.
ChemInform Abstract: N‐Bromosuccinimide‐Mediated Thiocyanation of Cyclohexene‐Fused Isoxazoline N‐Oxides.
Authors: Ichake Sachin S. , Rajawinslin R. R. , Kavala Veerababurao , Villuri Bharath Kumar , Yang Huei‐Ting , Kuo Chun‐Wei , Yao Ching‐Fa 
Published: June 2016

AbstractA NBS‐promoted oxidative ring‐opening of isoxazolines of type (I) and (V) with thiocyanate gives SCN‐containing cyclohexenone oximes.
ChemInform Abstract: Broad Scope Aminocyclization of Enynes with Cationic JohnPhos—Gold(I) Complex as the Catalyst.
Authors: Miller Ricarda , Carreras Javier , Muratore Michael E. , Gaydou Morgane , Camponovo Francesco , Echavarren Antonio M. 
Published: June 2016

AbstractThe novel aminocyclization of 1,6‐enynes works well with a wide variety of primary or secondary amines using a robust cationic gold(I) complex.
ChemInform Abstract: Asymmetric Lewis Acid Organocatalysis of the Diels—Alder Reaction by a Silylated C—H Acid.
Authors: Gatzenmeier Tim , van Gemmeren Manuel , Xie Youwei , Hoefler Denis , Leutzsch Markus , List Benjamin 
Published: June 2016

AbstractEnantioselective Diels—Alder reactions of cinnamates with cyclopentadiene catalyzed by in situ generated silylium‐carbanion pairs as extremely active Lewis acid are investigated.
ChemInform Abstract: Selective Double Carbomagnesiation of Internal Alkynes Catalyzed by Iron‐N‐Heterocyclic Carbene Complexes: A Convenient Method to Highly Substituted 1,3‐Dienyl Magnesium Reagents.
Authors: Liu Yuesheng , Wang Lijun , Deng Liang 
Published: June 2016

AbstractAn iron(II)‐N‐heterocyclic carbene (NHC) complex is found to be effective as precatalyst for double carbometalation of unsymmetrical internal alkynes with Grignard‐reagents.
ChemInform Abstract: Electrochemical Amination of Less‐Activated Alkylated Arenes Using Boron‐Doped Diamond Anodes.
Authors: Herold Sebastian , Moehle Sabine , Zirbes Michael , Richter Frank , Nefzger Hartmut , Waldvogel Siegfried R. 
Published: June 2016

AbstractA previously published protocol for anodic C—amination of electron‐rich arenes is extended towards utilization of less‐activated benzenes.
ChemInform Abstract: Bargellini Condensation of Ninhydrin as a Ketone and Substituted Anilines as Nucleophiles.
Authors: Rashid Zahra , Ghahremanzadeh Ramin , Naeimi Hossein 
Published: June 2016

AbstractNovel α‐amino acids based on ninhydrin are conveniently synthesized by NaOH‐promoted Bargellini reaction of various substituted anilines as nucleophiles with ninhydrin and chloroform under mild reaction conditions in high to excellent yields and with high purity.
ChemInform Abstract: Direct Catalytic Asymmetric Mannich‐Type Reaction of α,β‐Unsaturated γ‐Butyrolactam with Ketimines.
Authors: Lin Shaoquan , Kumagai Naoya , Shibasaki Masakatsu 
Published: June 2016

AbstractThe presence of a thiophosphinoyl group on the nitrogen of the starting ketimines is crucial for both electrophilic activation and α‐addition of γ‐butyrolactams.
ChemInform Abstract: Cu(I) Catalyzed Synthesis of Anhydrides from Aldehydes via CDC‐Pathway at Ambient Temperature.
Authors: Nuree Yasin , Singha Raju , Ghosh Munmun , Roy Pronay , Ray Jayanta K. 
Published: June 2016

AbstractAn easy and efficient methodology for the synthesis of anhydrides starting from commercially available aromatic aldehydes using low‐cost Cu(I) catalyst and TBHP as oxidant at room temperature with satisfactory yields is reported.
ChemInform Abstract: Graphene Oxide: A Promising Carbocatalyst for the Regioselective Thiocyanation of Aromatic Amines, Phenols, Anisols and Enolizable Ketones by Hydrogen Peroxide/KSCN in Water.
Authors: Khalili Darisush 
Published: June 2016

AbstractThe direct thiocyanation of a variety of arenes and carbonyl compounds possessing an α‐hydrogen is accomplished by reaction with KSCN in the presence of hydrogen peroxide using graphene oxide as catalyst.
ChemInform Abstract: SnBr4‐Promoted Friedel—Crafts Type Dehydrative Alkylation Reaction of Diarylmethanols with 2‐Naphthol Derivatives.
Authors: Suzuki Nobuharu , Tsuchihashi Shiori , Nakata Kenya 
Published: June 2016

AbstractAn efficient Friedel—Crafts type dehydrative alkylation reaction of diarylmethanols with 2‐naphthols promoted by SnBr4 under mild conditions is developed.
ChemInform Abstract: Fused Catechol Ethers from Gold(I)‐Catalyzed Intramolecular Reaction of Propargyl Ethers with Acetals.
Authors: Pati Kamalkishore , dos Passos Gomes Gabriel , Harris Trevor , Alabugin Igor V. 
Published: June 2016

AbstractThe title reaction proceeds under mild conditions following an alkyne activation/nucleophilic addition/alkoxyl group migration/cyclization/aromatization mechanism.
ChemInform Abstract: Modular Approach to 9‐Monosubstituted Fluorene Derivatives Using MoV Reagents.
Authors: Franzmann Peter , Trosien Simon , Schubert Moritz , Waldvogel Siegfried R. 
Published: June 2016

AbstractThe MoV‐mediated oxidative intramolecular coupling of functionalized diphenylpropanone derivatives (VII) and (IX) leads to desired 9‐substituted fluorenes (VIII) and (X), resp., in moderate yields.
ChemInform Abstract: Studies of the Mechanism and Origins of Enantioselectivity for the Chiral Phosphoric Acid‐Catalyzed Stereoselective Spiroketalization Reactions.
Authors: Khomutnyk Yaroslav Ya. , Argueelles Alonso J. , Winschel Grace A. , Sun Zhankui , Zimmerman Paul M. , Nagorny Pavel 
Published: June 2016

AbstractHammett analysis of the reaction kinetics reveals positive charge accumulation in the transition state.
ChemInform Abstract: A Convenient and Rapid Microwave‐Assisted Synthesis of Spirooxindoles in Aqueous Medium and Their Antimicrobial Activities.
Authors: Mali Prakash R. , Chandrasekhara Rao L. , Bangade Vikas M. , Shirsat Prashishkumar K. , George Sara A. , Jagadeesh Babu N. , Meshram H. M. 
Published: June 2016

AbstractFunctionalized spirooxindole derivatives are simply and eco‐friendly synthesized by an one‐pot, three‐component aqueous phase protocol under microwave irradiation with good diastereoselectivity.
ChemInform Abstract: Synthesis of Bicyclic γ‐Butyrolactone Derivatives by Rhodium Catalyzed Intramolecular C—H Insertion of α‐Diazo α‐Phosphoryl Cycloalkyl Esters.
Authors: Shie Jr‐Yun , Zhu Jia‐Liang 
Published: June 2016

AbstractFour title esters bearing different cycloalkyl substituents (cyclopentyl‐cyclooctyl) are investigated as suitable substrates in the formation of the desired bicyclic oxygen heterocycles.
ChemInform Abstract: CuBr2 Catalyzed Synthesis of 3‐Furylphthalides.
Authors: Shcherbinin Vitaly A. , Shpuntov Pavel M. , Konshin Valery V. , Butin Alexander V. 
Published: June 2016

AbstractA straightforward and efficient CuBr2/AcOH catalyzed synthesis of the title compounds from readily available phthalaldehydic acids and furans is developed.
ChemInform Abstract: Copper(II)/Silver(I)‐Catalyzed Sequential Alkynylation and Annulation of Aliphatic Amides with Alkynyl Carboxylic Acids: Efficient Synthesis of Pyrrolidones.
Authors: Zhang Jitan , Li Danyang , Chen Hui , Wang Binjie , Liu Zhanxiang , Zhang Yuhong 
Published: June 2016

AbstractThis copper‐catalyzed tandem decarboxylative cross‐coupling/cyclization provides a highly efficient method for preparation of pyrrolidones.
ChemInform Abstract: Stereoselective Synthesis of Functionalized Pyrrolidines by the Diverted N—H Insertion Reaction of Metallocarbenes with β‐Aminoketone Derivatives.
Authors: Nicolle Simon M. , Lewis William , Hayes Christopher J. , Moody Christopher J. 
Published: June 2016

AbstractVarious catalysts are found to promote the diverted N—H insertion of diazocarbonyl compounds with β‐aminoketones to afford highly substituted proline derivatives with good diastereoselectivities.
ChemInform Abstract: Acylation of Indoles via Photoredox Catalysis: A Route to 3‐Acylindoles.
Authors: Gu Lijun , Jin Cheng , Liu Jiyan , Zhang Hongtao , Yuan Minglong , Li Ganpeng 
Published: June 2016

AbstractThe title compounds are efficiently prepared from simple indoles and α‐oxo acids via Ir/Ni‐cocatalyzed, visible light induced C—C and C—H bond activation.
ChemInform Abstract: Bifunctional Tertiary Amine‐Squaramide Catalyzed Asymmetric Catalytic 1,6‐Conjugate Addition/Aromatization of para‐Quinone Methides with Oxindoles.
Authors: Deng Yu‐Hua , Zhang Xiang‐Zhi , Yu Ke‐Yin , Yan Xu , Du Ji‐Yuan , Huang Hanmin , Fan Chun‐An 
Published: June 2016

AbstractThe novel highly diastereoselective and enantioselective approach affords a wide range of diarylmethine‐substituted oxindoles bearing vicinal tertiary and quaternary stereocenters.
ChemInform Abstract: Visible‐Light‐Mediated Photocatalytic Difunctionalization of Olefins by Radical Acylarylation and Tandem Acylation/Semipinacol Rearrangement.
Authors: Bergonzini Giulia , Cassani Carlo , Lorimer‐Olsson Haldor , Hoerberg Johanna , Wallentin Carl‐Johan 
Published: June 2016

AbstractA novel method for the mild photoredox‐mediated tandem radical acylarylation and tandem acylation/semipinacol rearrangement is developed.
ChemInform Abstract: Synthesis of Chiral α‐Trifluoromethylamines with 2,2,2‐Trifluoroethylamine as a “Building Block”.
Authors: Yan Wenjin , et al.  
Published: June 2016

AbstractThe title amines are efficiently prepared by asymmetric SN2′‐SN2′ reaction between trifluoroethylisatin ketimines and MBH type carbonates using β‐isocupreidine, a cinchonine derived alkaloid, as catalyst.
ChemInform Abstract: Functionalization of Silyldienol Ethers at the γ‐Position via 2‐Silyloxypentadienyl Cations.
Authors: Ayala Caitlan E. , Dange Nitin S. , Stepherson Jacob R. , Henry Jeffrey L. , Fronczek Frank R. , Kartika Rendy 
Published: June 2016

AbstractA method for the preparation of silyldienol ethers bearing a tetrasubstituted double bond with controllable stereoconfiguration is elaborated.
ChemInform Abstract: Ruthenium‐Catalyzed, Site‐Selective C—H Allylation of Indoles with Allyl Alcohols as Coupling Partners.
Authors: Kumar Gangam Srikanth , Kapur Manmohan 
Published: June 2016

AbstractThe site‐selectivity of the mono‐selective method is based on the use of an N‐pyridyl directing group which may be cleaved off without or with significant isomerization of the products′ allyl group.
ChemInform Abstract: C—H Activation‐Based Traceless Synthesis via Electrophilic Removal of a Directing Group. Rhodium(III)‐Catalyzed Entry into Indoles from N‐Nitroso and α‐Diazo‐β‐keto Compounds.
Authors: Wang Jie , Wang Mingyang , Chen Kehao , Zha Shanke , Song Chao , Zhu Jin 
Published: June 2016

Abstract41 examples
ChemInform Abstract: Asymmetric Copper‐Catalyzed C—N Cross‐Couplings Induced by Visible Light.
Authors: Kainz Quirin M. , Matier Carson D. , Bartoszewicz Agnieszka , Zultanski Susan L. , Peters Jonas C. , Fu Gregory C. 
Published: June 2016

AbstractFully substituted stereocenters are highly enantioselectively generated by photoinduced copper‐catalyzed coupling of readily available racemic tertiary alkyl chloride electrophiles with various amines.
ChemInform Abstract: Cyclative Cascades of Allenamides Derived from Amino Acids: Synthesis of Annulated Indoxyl Derivatives.
Authors: Petkovic Milos , Nasufovic Veselin , Djukanovic Dimitrije , Vujosevic Zorana Tokic , Jadranin Milka , Matovic Radomir , Savic Vladimir 
Published: June 2016

AbstractThe title compounds are envisioned to be useful building blocks for syntheses of natural products and their analogs.
ChemInform Abstract: Copper(II)‐Catalyzed Synthesis of Indoloquinoxalin‐6‐ones Through Oxidative Mannich Reaction.
Authors: Gogoi Anupal , Sau Prasenjit , Ali Wajid , Guin Srimanta , Patel Bhisma K. 
Published: June 2016

AbstractA Cu‐catalyzed synthesis of indoloquinoxalin‐6‐ones is developed, starting from o‐indolyl‐N,N‐dialkylamines through sp3 C—H bond oxidation in the α‐position to the nitrogen atom with di‐tert‐butyl peroxide as oxidant.
ChemInform Abstract: Asymmetric Broensted Base Catalyzed and Directed [3 + 2] Cycloaddition of 2‐Acyl Cycloheptatrienes with Azomethine Ylides.
Authors: Lauridsen Vibeke H. , Ibsen Lise , Blom Jakob , Joergensen Karl Anker 
Published: June 2016

AbstractThe organocatalytic reaction of 2‐acyl cycloheptatrienes with azomethine ylides proceeds by a [3+2] cycloaddition which is in contrast to the corresponding Lewis acid‐catalyzed reaction, in which a [3+6] cycloaddition takes place.
ChemInform Abstract: Palladium‐Catalyzed Regioselective C‐2 Arylation of 7‐Azaindoles, Indoles, and Pyrroles with Arenes.
Authors: Laha Joydev K. , Bhimpuria Rohan A. , Prajapati Dilip V. , Dayal Neetu , Sharma Shubhra 
Published: June 2016

AbstractA high acid concentration in the reaction medium is essential to obtain complete C‐2 regioselectivity in the arylation of N‐protected 7‐azaindoles and indoles Low acidity of the reaction medium is required to achieve 2‐mono‐arylation in pyrroles.
ChemInform Abstract: A Re‐Engineering Approach: Synthesis of Pyrazolo[1,2‐a]pyrazoles and Pyrano[2,3‐c]pyrazoles via an Isocyanide‐Based Four‐Component Reaction under Solvent‐Free Conditions.
Authors: Shaabani Ahmad , Sepahvand Heshmatollah , Keramati Nejad Mina 
Published: June 2016

AbstractTitle compounds are synthesized in high yields by a novel interesting four‐component reaction of dialkyl acetylenedicarboxylates, isocyanides, and ethyl acetoacetate with hydrazine hydrate or phenylhydrazine under neat conditions.
ChemInform Abstract: Access to Imidazole Derivatives by Silver(I) Carbonate Mediated Coupling of Vinyl Azides with Secondary Amines.
Authors: Adiyala Praveen Reddy , Borra Satheesh , Kamal Ahmed , Maurya Ram Awatar 
Published: June 2016

AbstractAn operationally simple protocol for preparation of a set of imidazole derivatives via formation of three new C—N bonds in a cascade process is developed.
ChemInform Abstract: A Green and Convenient Approach Toward Benzimidazole Derivatives and Their Antimicrobial Activity.
Authors: Wen Jing , Luo Yun‐Lei , Zhang Hui‐Zhen , Zhao Huan‐Huan , Zhou Cheng‐He , Cai Gui‐Xin 
Published: June 2016

AbstractThe title derivatives are synthesized by aza‐Michael addition of benzimidazoles to α,β‐unsaturated compounds in water with palladium acetate as catalyst.
ChemInform Abstract: Copper‐Mediated [3 + 2] Annulation of 3‐N‐Hydroxyallylamines with Nitrosoarenes.
Authors: Ghorpade Satish , Jadhav Prakash D. , Liu Rai‐Shung 
Published: June 2016

AbstractThe title reaction is investigated for a series of substrates to produce 4,5‐disubstituted isoxazolidine structures as single diastereomers (mechanism).
ChemInform Abstract: Facile Synthesis of 1,3‐Tiazolidin‐4‐ones as Antitubercular Agents.
Authors: Subhedar Dnyaneshwar D. , Shaikh Mubarak H. , Arkile Manisha A. , Yeware Amar , Sarkar Dhiman , Shingate Bapurao B. 
Published: June 2016

Abstract21 Title compounds are prepared and tested for their antitubercular activities.
ChemInform Abstract: Copper(I)‐Catalyzed Cascade Reaction of 2‐Haloaryl Isothiocyanates with Isocyanides: A Strategy to Construct Benzo[d]imidazo[5,1‐b]thiazoles.
Authors: Hao Wenyan , Sang Xiaoyan , Jiang Jing , Cai Mingzhong 
Published: June 2016

AbstractThe novel copper‐catalyzed tandem [3 + 2] cycloaddition and C—S coupling of 2‐haloaryl isothiocyanates and isocyanoacetates affords the title benzo[d]imidazo[5,1‐b]thiazoles in high yields.
ChemInform Abstract: Design, Synthesis, and Analysis of Antagonists of GPR55: Piperidine‐Substituted 1,3,4‐Oxadiazol‐2‐ones.
Authors: Abood Mary E. , et al.  
Published: June 2016

AbstractA series of oxadiazole derivatives is prepared and tested for activity as antagonists at GPR55 in cellular beta‐arrestin redistribution assays.
ChemInform Abstract: New Tandem Reductive Rearrangement of 3‐Furylphthalides into 3‐(3‐Oxoalkyl)isocoumarins.
Authors: Shpuntov Pavel M. , Shcherbinin Vitaly A. , Abaev Vladimir T. , Butin Alexander V. 
Published: June 2016

AbstractA high‐yielding tandem procedure for the one‐pot conversion of 3‐(2‐furyl)phthalides into functionalized isocoumarins mediated by readily available reagents is developed.
ChemInform Abstract: 2‐Bromo‐6‐isocyanopyridine as a Universal Convertible Isocyanide for Multicomponent Chemistry.
Authors: van der Heijden Gydo , Jong J. A. W. , Ruijter Eelco , Orru Romano V. A. 
Published: June 2016

AbstractThe title pyridine is utilized in Ugi type and Passerini type reactions leading to various carboxylic amides.
ChemInform Abstract: Copper‐Catalyzed Annulation: A Method for the Systematic Synthesis of Phenanthridinium Bromide.
Authors: Jhang Yuan‐Ye , Fan‐Chiang Tai‐Ting , Huang Jun‐Min , Hsieh Jen‐Chieh 
Published: June 2016

AbstractA series of phenanthridinium bromides (III) and (IX) is readily obtained by a novel copper‐catalyzed annulation of bromo aldehydes with amines.
ChemInform Abstract: Site‐Selective Intermolecular Oxidative C‐3 Alkenylation of 7‐Azaindoles at Room Temperature.
Authors: Kannaboina Prakash , Kumar K. Anil , Das Parthasarathi 
Published: June 2016

AbstractThe title reaction is catalyzed by Pd(OAc)2 and uses Cu(OTf)2 as an oxidative cocatalyst and molecular oxygen as the terminal oxidant.
ChemInform Abstract: Redox‐Annulation of Cyclic Amines and β‐Ketoaldehydes.
Authors: Chen Weijie , Seidel Daniel 
Published: June 2016

AbstractThe intramolecular redox‐Mannich reaction between 1,2,3,4‐tetrahydroisoquinoline or tryptoline and β‐ketoaldehydes provides a facile access to benzo[a]quinolizine‐2‐ones.
ChemInform Abstract: Synthesis of Alkaloid‐Mimicking Tricyclic Skeletons by Diastereo‐ and Regioselective Ugi/Ipso‐Cyclization/Aza‐Michael Cascade Reaction in One‐Pot.
Authors: Yugandhar D. , Kuriakose Sunu , Nanubolu Jagadeesh Babu , Srivastava Ajay Kumar 
Published: June 2016

AbstractThe scalable, operationally simple method generates complex functionalized azaspirofused tricyclic scaffolds with three stereogenic centers one of which is quaternary.
ChemInform Abstract: Rhodium‐Catalyzed/Copper‐Mediated Tandem C(sp2)—H Alkynylation and Annulation: Synthesis of 11‐Acylated Imidazo[1,2‐a:3,4‐a′]dipyridin‐5‐ium‐4‐olates from 2H‐[1,2′‐Bipyridin]‐2‐ones and Propargyl Alcohols.
Authors: Li Ting , Wang Zhiqiang , Xu Kun , Liu Wenmin , Zhang Xu , Mao Wutao , Guo Yongming , Ge Xiaolin , Pan Fei 
Published: June 2016

AbstractThe scalable title reaction tolerates variously functionalized 2H‐[1,2′‐bipyridin]‐2‐ones as well as aryl and hetaryl substituted propargyl alcohols, but no alkyl substituted derivatives of the latter.
ChemInform Abstract: CsOH/γ‐Al2O3: A Heterogeneous Reusable Basic Catalyst for One‐Pot Synthesis of 2‐Amino‐4,6‐diaryl Pyrimidines.
Authors: Nimkar Amey , Ramana M. M. V. , Betkar Rahul , Ranade Prasanna , Mundhe Balaji 
Published: June 2016

AbstractThe title pyrimidines are simply and efficiently synthesized by a green one‐pot three‐component reaction of acetophenone, various aromatic aldehydes, and guanidine hydrochloride using CsOH/γ‐Al2O3 as catalyst.
ChemInform Abstract: Organocatalytic Asymmetric Synthesis of Dihydrobenzoxazinones Bearing Trifluoromethylated Quaternary Stereocenters.
Authors: Lou Hengqiao , Wang Yongtao , Jin Enze , Lin Xufeng 
Published: June 2016

AbstractA chiral phosphoric acid‐catalyzed enantioselective aza‐Friedel—Crafts reaction of trifluoromethyl benzoxazinones with pyrroles is given.
ChemInform Abstract: Formal Ir‐Catalyzed Ligand‐Enabled ortho and meta Borylation of Aromatic Aldehydes via in situ‐Generated Imines.
Authors: Bisht Ranjana , Chattopadhyay Buddhadeb 
Published: June 2016

AbstractTwo complementary methods for ortho‐ and meta‐selective C—H bond activation/borylation of aromatic aldehydes are developed.
ChemInform Abstract: Cobalt‐Catalyzed Benzylic Borylation: Enabling Polyborylation and Functionalization of Remote, Unactivated C(sp3)—H Bonds.
Authors: Palmer W. Neil , Obligacion Jennifer V. , Pappas Iraklis , Chirik Paul J. 
Published: June 2016

AbstractRare examples for diborylation of benzylic and homobenzylic C—H bonds and an unprecedented triborylation of the toluene methyl group are presented.
ChemInform Abstract: Metal‐Free Diimide Reduction of Alkenylphosphonates: Simple and Efficient Protocol for the Synthesis of α‐Substituted Ethylphosphonates.
Authors: Fang Yewen , Yuan Meijuan , Jin Xiaoping , Zhang Li , Li Ruifeng , Yang Shaoshuai , Fang Mei 
Published: June 2016

AbstractAn efficient and simple method for the synthesis of α‐substituted ethylphosphonates via diimide reduction of α‐substituted vinylphosphonates is reported.
ChemInform Abstract: Oxidative C(sp2)—H Phosphonation of Aldehyde Hydrazones.
Authors: Xu Pan , Wu Zhongkai , Zhou Nengneng , Zhu Chengjian 
Published: June 2016

AbstractThe practical procedure is successfully applied to the reaction between various aldehyde hydrazones and diphenylphosphine oxide or ethyl phenylphosphinate, but fails using diethyl or diphenyl phosphonate.
ChemInform Abstract: Highly Regio‐ and Stereoselective Intermolecular Seleno‐ and Thioamination of Alkynes.
Authors: Zheng Guangfan , Zhao Jinbo , Li Zhanyu , Zhang Qiao , Sun Jiaqiong , Sun Haizhu , Zhang Qian 
Published: June 2016

AbstractThe N‐fluorobenzenesulfonimide acts both as the oxidant and the amination reagent in the intermolecular chalcogenative amination of alkynes, which grants facile, highly regio‐ and stereoselective access to chalcogenated enamides.
ChemInform Abstract: De novo Design of Protein Homo‐Oligomers with Modular Hydrogen‐Bond Network‐Mediated Specificity.
Authors: Baker David , et al.  
Published: June 2016

AbstractIn nature, structural specificity in DNA and proteins is encoded differently: In DNA, specificity arises from modular hydrogen bonds in the core of the double helix, whereas in proteins, specificity arises largely from buried hydrophobic packing complemented by irregular peripheral polar interactions.
ChemInform Abstract: Synthesis and Absolute Configuration of Acanthodendrilline, a New Cytotoxic Bromotyrosine Alkaloid from the Thai Marine Sponge Acanthodendrilla sp.
Authors: Sirimangkalakitti Nachanun , Yokoya Masashi , Chamni Supakarn , Chanvorachote Pithi , Plubrukrn Anuchit , Saito Naoki , Suwanborirux Khanit 
Published: June 2016

AbstractAcanthodendrilline (S)‐I is isolated and shown to exhibit a threefold more potent cytotoxicity against human non‐small cell lung cancer H292 cell line than (R)‐(I).
ChemInform Abstract: Defects in Nanodiamonds: Application of High‐Frequency CW and Pulse EPR, ODMR
Authors: Yavkin B. V. , Soltamov V. A. , Babunts R. A. , Anisimov A. N. , Baranov P. G. , Shakhov F. M. , Kidalov S. V. , Vul' A. Ya. , Mamin G. V. , Orlinskii S. B. 
Published: June 2016

AbstractReview: 45 refs.
ChemInform Abstract: Total Syntheses of Echinopines A and B, Sesquiterpenes with a Unique Tetracyclic [3‐5‐5‐7] Skeleton
Authors: Sanogo Youssouf , Allievi Luca , Lecourt Camille , Dhambri Sabrina , Ardisson Janick , Sorin Geoffroy , Lannou Marie‐Isabelle 
Published: June 2016

AbstractReview: 30 refs.
ChemInform Abstract: Advances in Chemistry and Bioactivity of the Genus Chisocheton Blume
Authors: Shilpi Jamil A. , Saha Sanjib , Chong Soon‐Lim , Nahar Lutfun , Sarker Satyajit D. , Awang Khalijah 
Published: June 2016

AbstractReview: 75 refs.