bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Macrolide Fundamental Chemistry: Sequential Conversion of the 14‐Membered Ring Macrolide Antibiotic Oleandomycin to 12‐ and 10‐Membered Ring Macrocyclic Lactone Systems.
Authors: NAGEL A. A. , CELMER W. D. , JEFFERSON M. T. , VINCENT L. A. , WHIPPLE E. B. , SCHULTE G. 
Published: May 2016

AbstractOleandromycin (I) is converted to the macrocyclic lactones (II) and (III) as shown in the reaction scheme.
ChemInform Abstract: Practical Conversion of Artemisinic Acid into Desoxyartemisinin.
Authors: JUNG M. , ELSOHLY H. N. , CROOM E. M. , MCPHAIL A. T. , MCPHAIL D. R. 
Published: May 2016

AbstractArtemisinic acid (I) is converted to the hydroperoxide (II) by esterification, stereoselective reduction, and photooxidation using normal procedures.
ChemInform Abstract: Structure of the Ammonia‐Boryl Radical (BH2NH3), an Inorganic Analogue of the Ethyl Radical. A Non Empirical Study
Authors: RUSSO N. , SUBRA R. , TOSCANO M. , BARONE V. 
Published: May 2016

Abstractat the UHF‐SCF level employing the 6‐31*G basis set including complete geometry optimization on various possible conformations suggests that the distortion of the BH2 group is higher than the corresponding distortion of the CH2 group in the isoelectronic CH2CH3 and CH2NH3 radicals.
ChemInform Abstract: Formation of a Defect‐Spinel Phase in CdSnO3.
Authors: INAGAKI M. , YAMASHITA Y. 
Published: May 2016

AbstractThermal decomposition of CdSn(OH)6 at 550‐800 °C results in the formation of a mixture of ilmenite‐ and spinel‐type CdSnO3.
ChemInform Abstract: A New Electrode‐Active Material for Polymer Batteries: Polyvinylferrocene.
Authors: IWAKURA C. , KAWAI T. , NOJIMA M. , YONEYAMA H. 
Published: May 2016

AbstractCharge‐discharge curves of polyvinylferrocene (PVF) electrodes in LiClO4 containing electrolytes exhibit excellent potential flatness and very high coulombic efficiencies in both nonaqueous and aqueous solutions.
ChemInform Abstract: Solid‐State Decomposition Studies on Fluoroperoxo Species of Transition Metals. Part 13. Kinetics of Isothermal Decomposition of K2(V2O3(O2)2F2) and K3(Ta(O2)2F4)
Authors: GHOSH J. K. , JERE G. V. 
Published: May 2016

Abstracthave been investigated in the temp. range 413‐493 K using a constant volume apparatus.
ChemInform Abstract: Cerium‐Molybdenum‐Tellurium Oxides.
Authors: BART J. C. J. , FORZATTI P. , GARBASSI F. , CARIATI F. 
Published: May 2016

AbstractTernary oxide formation in the Ce‐Mo‐Te‐O system has been investigated in the temp. range 400‐600 °C in air and eight new phases have been identified: Ce6Mo10Te4O47, Ce2Mo2Te2O13, Ce4Mo11Te10O59, Ce2Mo2Te4O17, Ce10Mo12Te14O79, Ce6Mo8Te6O45, Ce2Mo3Te2O16, and (Ce4Mo13Te3O51) (preparative conditions are listed in a table).
ChemInform Abstract: The Chemistry of Vitamin B12. Part 27. The Cage Phosphite Ester 4‐Ethyl‐2,6,7‐trioxa‐1‐phosphabicyclo(2.2.2)octane and the Anionic Dimethyl Phosphite as Ligands for Cobalt(III) Corrinoids.
Authors: CHEMALY S. M. , BETTERTON E. A. , PRATT J. M. 
Published: May 2016

AbstractThe equilibrium constant for the substitution of coordinated H2O in aquocobalamin (vitamin B12a) by the cage phosphite ester is determined in aqueous solution at 25 °C spectrophotometrically; comparison with the estimated pK for the protonation shows the marked preference for Co(III) over the proton.
ChemInform Abstract: Rhodium‐Diphosphine Complexes as Catalysts in Aldol Additions.
Authors: REETZ M. T. , VOUGIOUKAS A. E. 
Published: May 2016

AbstractThe Rh(I) complexes (I) ‐ (III) are employed as catalysts in the aldol reaction of the aldehydes (IV) and the silyl enol ethers (V).
ChemInform Abstract: Synthesis of Isopinocampheyl Halogenoboranes and Their Application as Chiral Catalysts in Asymmetric Diels‐Alder Reactions.
Authors: BIR G. , KAUFMANN D. 
Published: May 2016

AbstractThe haloboranes (III) and (V), prepared as shown in the reaction scheme, are used as catalysts in the Diels‐Alder reaction of cyclopentadiene (VI) with methacrolein (VII), yielding the norbornene carbaldehyde (VIII).
ChemInform Abstract: Photochemistry of Diaryl Substituted 2H‐Tetrazoles. Part 7. Thermal Behavior of 2,5‐Diaryl‐2H‐tetrazoles.
Authors: CSONGAR C. , FEIST M. , TOMASCHEWSKI G. 
Published: May 2016

AbstractThe thermal decomposition of the title compounds (I) gives the tetraaryldihydrotetrazines (II) along with the triaryltriazoles (III).
ChemInform Abstract: Amnesia‐Reversal Activity of a Series of Cyclic Imides.
Authors: BUTLER D. E. , LEONARD J. D. , CAPRATHE B. W. , L'ITALIEN Y. J. , PAVIA M. R. , HERSHENSON F. M. , POSCHEL P. H. , MARRIOTT J. G. 
Published: May 2016

AbstractThe cyclic imides (V) and (VIII) are prepared from the nitroalkanes (I) and the acrylates (II) or from the pyrrolidinones (VI) as outlined in the reaction scheme.
ChemInform Abstract: Manganese(III) Based Oxidative Free‐Radical Cyclizations. Part 2. Polycyclization Reactions Proceeding Through Tertiary Cations.
Authors: SNIDER B. B. , MOHAN R. , KATES S. A. 
Published: May 2016

AbstractThe oxidative cyclization of unsaturated β‐keto esters such as (I) and (IV) or unsaturated malonic diesters such as (IX) in the presence of Mn(III) acetate (II) is investigated.
ChemInform Abstract: Manganese(III) Based Oxidative Free‐Radical Cyclizations. Part 3. Polycyclization Reactions Proceeding Through Secondary Radicals.
Authors: MOHAN R. , KATES S. A. , DOMBROSKI M. A. , SNIDER B. B. 
Published: May 2016

AbstractThe 3‐oxo‐7‐octenoates (I) and (IV) undergo ring closure upon reaction with manganese triacetate, yielding (III) or (V) and (VI).
ChemInform Abstract: Transannular Ring Expansion in Electrophilic Reactions of Spirocyclopropane‐Substituted Norbornene and Its Oxirane and Azirane Derivatives.
Authors: ADAM W. , CARBALLEIRA N. , CRAEMER E. + , PETERS E.‐M. , PETERS K. , VON SCHNERING H. G. 
Published: May 2016

AbstractThe reactions of the spironorbornenes (I) and (VI) with the chloride (II) or of (IXa) and (IXb) with trifluoroacetic acid (XII) leads to the 3,8‐disubstituted brendanes (III), (VIII) or (X) (resulting from skeletal rearrangement of the intermediately formed bridged cations and subsequent transannular ring expansion) and to the 2,6‐disubstituted brendanes (Va) or (XI) (resulting from direct transannular ring expansion) as main products.
ChemInform Abstract: Aromatic Isomerizations and Related Reactions. Part 6. Reactions of the Tetra‐ and Pentamethylbenzenesulfonic Acids and Hexamethylbenzene in Concentrated Sulfuric Acid; the Mechanism of the Jacobsen Reaction.
Authors: KOEBERG‐TELDER A. , CERFONTAIN H. 
Published: May 2016

AbstractThe reactions are studied quantitatively using 1H and 13C NMR and UV spectroscopy.
ChemInform Abstract: cis‐trans Isomerization of Stilbazolium Salts. Part 10. Photoinduced Electron Transfer vs. trans → cis Photoisomerization of Quaternary Salts of 4‐Substituted 4′‐Azastilbenes (R: CN, H, CH3, and OCH3) and Their Quinolinium Analogues
Authors: GOERNER H. + 
Published: May 2016

Abstract((I) and (II); pulse radiolysis and laser flash photolysis; effects of solvents (THF, MeCN, water), anion X‐, electron donors (I‐, SCN‐), and amines (e.g.
ChemInform Abstract: Mechanistic Studies on the Mode of Reaction of Mitomycin C Under Catalytic and Electrochemical Reductive Conditions.
Authors: KOHN H. , ZEIN N. , LIN X. Q. , DING J.‐Q. , KADISH K. M. 
Published: May 2016

AbstractThe catalytic (H2/PtO2) and electrochemical reduction of the antineoplastic antibiotic mitomycin (I) and some of its derivatives is investigated.
ChemInform Abstract: Reactions of Polyfluorinated Cycloalkenes with the Pentafluorides of Vanadium, Antimony and Niobium.
Authors: BARDIN V. V. , AVRAMENKO A. A. , PETROV V. A. , KRASIL'NIKOV V. A. , KARELIN A. I. , TUSHIN P. P. , FURIN G. G. , YAKOBSON G. G. 
Published: May 2016

AbstractThe fluorination of a series of substituted polyfluorocycloalkenes by VF5, SbF5 and by NbF5 is studied.
ChemInform Abstract: 1,2‐Bis(diphenylphosphino)ethane Tetrahalide: A Convenient Reagent for the Conversion of Alcohols to the Corresponding Halides.
Authors: SCHMIDT S. P. , BROOKS D. W. 
Published: May 2016

AbstractThe reagents (III) mentioned in the title are employed for the conversion of the alcohols or tetrahydropyranyl ethers (IV) to the halides (V).
ChemInform Abstract: Applications of Phase‐Transfer Catalysis. Part 35. A Novel Reaction of Trichloroacetate.
Authors: RATHS H.‐C. , DEHMLOW E. V. 
Published: May 2016

AbstractEsterification of sodium trichloroacetate (IV) with allyl bromide (I) under phase‐transfer catalysis conditions leads unexpectedly to the formation of the ester (III).
ChemInform Abstract: Chelation‐Controlled Grignard Reactions of α‐(1H‐1,2,4‐Triazol‐1‐yl) Ketones.
Authors: BUSCHMANN E. , ZEEH B. , GOETZ N. + , SPROESSER L. , WALKER N. 
Published: May 2016

AbstractThe high diastereoselectivity of the Grignard addition to various α‐triazolyl ketones or α‐alkoxy‐α‐triazolyl ketones such as (I), (IV) or (VII) can be rationalized via postulated intermediate chelate complexes.
ChemInform Abstract: Enhancement of Stereoselectivity in Catalytic Cyclopropanation Reactions.
Authors: DOYLE M. P. , LOH K.‐L. , DEVRIES K. M. , CHINN M. S. 
Published: May 2016

AbstractThe stereoselectivity of the Rh(II)‐induced cyclopropanation of olefins such as (III) with the diazoacetic acid derivatives (II) is investigated.
ChemInform Abstract: Stereoselective Synthesis of (2E,4Z)‐Dien‐1‐ols. Key Intermediates for Synthesis of Sex Pheromones of Silk Worm and of Grape Vine Moth.
Authors: KURODA S. , KATSUKI T. , YAMAGUCHI M. 
Published: May 2016

AbstractThe silylalkynols (I) are reduced to form the allylic alcohols (II) which react with bromoacetic acid (III) and isopropyl iodide (IV), yielding the silylalkenyloxyacetates (V).
ChemInform Abstract: Ritter Reaction of 2‐Methyladamantan‐2‐ol.
Authors: KOZLOV N. G. , POPOVA L. A. , KNIZHNIKOV V. A. , OL'DEKOP YU. A. 
Published: May 2016

AbstractThe adamantanol (II), prepared by treatment of the adamantanone (I) with methyllithium, reacts with the nitriles (III) under the conditions of the Ritter reaction to give the amides (IV).
ChemInform Abstract: Synthesis of 1,2‐Benzoquinones from 1,4‐Benzodioxins Using the Reaction with Ozone Followed by Photolysis.
Authors: KASHIMA C. , TOMOTAKE A. , OMOTE Y. 
Published: May 2016

AbstractOzonolysis of the 1,4‐benzodioxins (I) and subsequent photolysis lead to the formation of the o‐quinones (III) and the catechols (IV).
ChemInform Abstract: A Novel Route for the Synthesis of α,β‐Unsaturated Esters, Ketones, and Nitriles Using Dibutyl Telluride.
Authors: HUANG X. , XIE L. , WU H. 
Published: May 2016

AbstractThe dibutyltelluronium salts (II) are coupled with the aldehydes (I) to yield the substituted styrenes (III) which are also prepared from (I), dibutyltelluride (IV), and the carbonyl derivatives (V).
ChemInform Abstract: Synthesis, Biological Evaluation, and Quantitative Structure‐Activity Relationship Analysis of 2‐Hydroxy‐1H‐isoindolediones as New Cytostatic Agents.
Authors: CHAN C. L. , LIEN E. J. , TOKES Z. A. 
Published: May 2016

Abstract4‐Nitrophthalic acid (I) is converted to the N‐hydroxy‐4‐nitrophthalimide (II) which produces the amino sulfonates (IV) after reduction and esterification.
ChemInform Abstract: Synthesis of 2,6‐Dichloro‐ and 2,4,6‐Trichloro‐3,5‐bis(trifluoromethylsulfonyl)nitrobenzenes.
Authors: BOIKO V. N. , GOGOMAN I. V. , SHCHUPAK G. M. , YAGUPOL'SKII L. M. 
Published: May 2016

AbstractThe chlorination of the aniline (I) is best performed by treatment with conc.
ChemInform Abstract: Proton Catalyzed Rearrangement of N‐Alkyl Arene Sulfonanilides to ortho‐Alkylamino Sulfones. Part 3.
Authors: JOSHI B. C. , JOSHI Y. C. , KISHORE D. , SHRIMALI S. S. 
Published: May 2016

AbstractReaction of the sulfonyl chlorides (I) with the anilines (II) yields the sulfonamides (III) which are rearranged to form the sulfones (IV).
ChemInform Abstract: Formation of Disulfones in the Reaction of Sodium Arenesulfinates with 4‐Chloro‐2‐butyn‐1‐ol.
Authors: YAKOVLEV V. V. , MIKHAILOVA V. N. , BULAM A. D. , VEKSLER V. I. 
Published: May 2016

AbstractThe sulfinates (Ia) ‐ (If) react with the chlorobutynol (II) to give the disulfones (III).
ChemInform Abstract: Sterically Stabilized α‐Acyl Free Radicals: α‐Isopropoxycarbonyl, N‐Morpholinocarbonyl and Cyano Bis(pentachlorophenyl)methyl Radicals.
Authors: HEGARTY A. F. , O'NEILL P. 
Published: May 2016

AbstractHexachlorobenzene (Ia) is converted to the Grignard reagent (Ib) which reacts with diisopropyl oxalate (II) to give the α‐hydroxy ester (III).
ChemInform Abstract: Hydroxamic Acid Inhibitors of 5‐Lipoxygenase.
Authors: SUMMERS J. B. , MAZDIYASNI H. , HOLMS J. H. , RATAJCZYK J. D. , DYER R. D. , CARTER G. W. 
Published: May 2016

AbstractHydroxamic acids such as (II) ‐ (IV) are prepared and their in vitro 5‐lipoxygenase inhibitory activities are studied.
ChemInform Abstract: Studies on Epoxy Compounds. Part 51. Investigation of the Dehydration Reaction of Alkoxy‐β‐diols with a Bornane Ring.
Authors: MARCHIK E. F. , SHNYN I. A. , FALALEEVA L. N. , PANSEVICH‐KOLYADA V. I. , DOGADINA A. V. , LUK'YANOVA R. S. 
Published: May 2016

AbstractThe diols (III), obtained from the oxirane (I), are dehydrated at a cationic exchanger to give the spirooxetanes (IV).
ChemInform Abstract: The Reaction of 4‐Hydroxy‐3‐methoxycarbonylthiophene with Sulfurylchloride.
Authors: GEFFKEN D. , WILLMANN W. 
Published: May 2016

AbstractThe title compound (I) reacts with equimolar amounts of SO2Cl2, yielding the 2‐chlorothiophene (II).
ChemInform Abstract: Synthesis of 1,4‐Diketones by the Coupling Reaction of Trimethylsilyl Enol Ethers with Lead Tetraacetate.
Authors: MORIARTY R. M. , PENMASTA R. , PRAKASH I. 
Published: May 2016

AbstractThe ketones (I) are transformed into the silyl enol ethers (II) which are oxidized by lead tetraacetate to give the 1,4‐diketones (III).
ChemInform Abstract: Novel Substituted Adamantane‐spiro‐5‐oxazolidine Derivatives.
Authors: GEORGIEV V. ST. , ACKER C. G. , KINSOLVING C. R. 
Published: May 2016

AbstractThe aminomethylhydroxyadamantane (I) is cyclized with phosgene (II) or the ketones (VIII) to produce the spirooxazolidinone (IIIa) and the bisspiro compounds (IX) respectively.
ChemInform Abstract: Non‐Aromatic 1,3,4‐Thiadiazolinediazonium Cations.
Authors: RYBINOV V. I. , GORELIK M. V. 
Published: May 2016

AbstractDiazotation of the amines (I), followed by reaction of the intermediary diazonium salts with N,N‐dimethylaniline yields the 2‐arylazo derivatives (II).
ChemInform Abstract: Synthesis and Quantitative Structure‐Activity Relationship Analysis of N‐Triiodoallyl‐ and N‐Iodopropargylazoles. New Antifungal Agents.
Authors: KOYAMA M. , OHTANI N. , KAI F. , MORIGUCHI I. , INOUYE S. 
Published: May 2016

AbstractTriiodoallyl and iodopropargyl N‐heterocycles such as (III), (IV), and (VI) are prepared and their antifungal activity is studied.
ChemInform Abstract: Thermolysis of Phenoxyacetylcyanomethylenetriphenylphosphoranes ‐ Tandem Intramolecular Wittig and Claisen Rearrangement Reactions.
Authors: YADLA R. , RAO J. M. 
Published: May 2016

AbstractFlash vacuum pyrolysis of the acylcyanophosphoranes (I) leads to the formation of the cyanoalkynes (II), the chromenes (III), and the benzofuran (IV).
ChemInform Abstract: Heteroaromatic Azoactivated Nucleophilic Substitutions. The Reaction of 4‐(p‐Methoxyphenylazo)pyridinium Methiodide with Piperidine in Dimethyl Sulfoxide.
Authors: ONYIDO I. , UBOCHI C. I. 
Published: May 2016

AbstractReaction of the azopyridinium salt (III) obtained from 4‐aminopyridine (I) with piperidine (IV) yields the substitution products (V) and (VI).
ChemInform Abstract: A New Thienylpyrazoloquinoline: A Potent and Orally Active Inverse Agonist to Benzodiazepine Receptors.
Authors: TAKADA S. , SHINDO H. , SASATANI T. , MATSUSHITA A. , EIGYO M. , KAWASAKI K. , MURATA S. 
Published: May 2016

AbstractThe chloroquinoline (I) reacts with the thienylhydrazine (II) to give the N,N'‐disubstituted hydrazine (III) which is transformed into the thienyldihydropyrazoloquinolone (IV) by cyclization, hydrolysis, and subsequent decarboxylation.
ChemInform Abstract: Synthesis of 7,12‐Dihydropyrido(3,4‐b:5,4‐b′)diindoles. A Novel Class of Rigid, Planar Benzodiazepine Receptor Ligands.
Authors: TRUDELL M. L. , BASILE A. S. , SHANNON H. E. , SKOLNICK P. , COOK J. M. 
Published: May 2016

AbstractThe (benzoyl)oxotetrahydro‐β‐carboline (I) undergoes cyclization with the arylhydrazides (II) and (IV) to produce the indole derivatives (III) and (V).
ChemInform Abstract: The Reaction of 1‐Alkyldihydroisoquinolines with Benzyne. An Unexpected Entry to Dibenzindolizines.
Authors: ATANES N. , GUITIAN E. , SAA C. , CASTEDO L. , SAA J. M. 
Published: May 2016

AbstractThe isoquinolines (IV) and (VIII) react with benzyne (V), generated by decomposition of o‐diazoniumbenzoate, to form the products (VI) or (IX) and (X).
ChemInform Abstract: Synthesis and Properties of Spirocyclohexadien‐2,5‐ones with Pyridazine Cycle.
Authors: TITOVA T. F. , GATILOV YU. V. , KOROBEINICHEVA I. K. , KRYSIN A. P. 
Published: May 2016

AbstractThe condensation of the diones (I) with N2H4 unexpectedly yields the spiro compounds (II).
ChemInform Abstract: A Novel Synthesis of Pyridazines: Inverse Electron Demand Diels‐Alder Reaction of Tetrazines with Acyclic Dienamines.
Authors: BORTHAKUR D. R. , PRAJAPATI D. , SANDHU J. S. 
Published: May 2016

AbstractThe diaryltetrazines (I) react with the tertiary butadienylamines (II), producing the pyridazines (III) and (IV) after fragmentation of the intermediate bicyclic 2:1 adducts.
ChemInform Abstract: Synthesis of 5,6‐Dimethylquinazolin‐2(1H)‐ones.
Authors: PRESS J. B. , BANDURCO V. T. , WONG E. M. , HAJOS Z. G. , KANOJIA R. M. , MALLORY R. A. , DEEGAN E. G. , MCNALLY J. J. , ROBERTS J. R. , COTTER M. L. , GRADEN D. W. , LLOYD J. R. 
Published: May 2016

AbstractThe dimethoxynitrobenzaldehyde (IV), synthesized as shown in the reaction scheme, is used as the starting product in the preparation of the quinazolinones (IX), (X), and (XVIII).
ChemInform Abstract: Ionic‐Radicalic Cleavage of the Carbon‐Carbon Bond in the Oxidation of 1,3,1′,3′‐Tetramethyl‐2,3,2′,3′‐tetrahydro‐2,2′‐diperimidinyl.
Authors: SABANOV V. KH. , KIBIZOVA A. YU. , KLIMOV E. S. , BERBEROVA N. T. , OKHLOBYSTIN O. YU. 
Published: May 2016

AbstractElectrochemical or chemical oxidation of the title compound (I) leads to the formation of dihydroperimidine (II) via ionic and radicalic intermediates.
ChemInform Abstract: Antitumor Agents. Part 86. Synthesis and Cytotoxicity of α‐Methylene‐γ‐ lactone‐Bearing Purines.
Authors: LEE K.‐H. , RICE G. K. , HALL I. H. , AMARNATH V. 
Published: May 2016

AbstractN6‐Acetyladenine (I) is alkylated with chloroacetone (II) and then hydrolyzed to give the oxopropyladenine (III).
ChemInform Abstract: Reaction of Pyrazine‐2,3‐dicarbonitrile and 1,3‐Dimethyllumazine with Alkyl Radicals.
Authors: TADA M. , ITO T. , OHSHIMA K. 
Published: May 2016

AbstractPyrazine‐2,3‐dicarbonitrile (I) and 1,3‐dimethyllumazine (VI) react with the radicals (III), generated from the carboxylic acids (II), yielding the substitution products (IV) and (V) or (VII) ‐ (IX).
ChemInform Abstract: Synthesis of 3H‐3‐Oxophenothiazine Derivatives.
Authors: VARENIKOVA S. F. , NEKHOROSHEV A. A. , SEVBO D. P. , GINZBURG O. F. 
Published: May 2016

AbstractThe syntheses of the 8‐carboxy‐3‐oxophenothiazine (VIII) and of the 8‐carboxy‐3‐dimethylaminophenothiazine hydrochloride (XII) are described.
ChemInform Abstract: Synthesis of 2,4‐Diamino‐6,7‐dihydroimidazo(1,2‐a)(1,3,5)triazine Derivatives.
Authors: UNISHI T. , KITAHAMA T. , SHIMOMURA Y. 
Published: May 2016

AbstractThe β‐hydroxyethylaminotriazines (Ia) and the anilines (II) yield the triaminotriazines (III), but the β‐chloroethylaminotriazines (Ib) and (II) produce the imidazotriazines (IV) by intramolecular alkylation.
ChemInform Abstract: Synthesis, Renal Vasodilator, and Dopamine‐Sensitive Adenylate Cyclase Activities of O‐Methyl Derivatives of 6‐Chloro‐2,3,4,5‐tetrahydro‐1‐(4‐ hydroxyphenyl)‐1H‐3‐benzazepin‐7,8‐diol (SK&F 82526).
Authors: ROSS S. T. , FRANZ R. G. , WILSON J. W. , HAHN R. A. , SARAU H. M. 
Published: May 2016

AbstractThe aldehydes (II), derived from (I), are converted to the arylacetic acids (VI) which are coupled with the amino alcohols (IX) to form the amides (XII).
ChemInform Abstract: 2‐(tert.‐Amino)‐11‐(4‐methylpiperazino)dibenzo(b,f)thiepins and Their 10,11‐Dihydro Derivatives; Synthesis and Neuroleptic Activity.
Authors: KMONICEK V. , HOLUBEK J. , SVATEK E. , METYSOVA J. , PROTIVA M. 
Published: May 2016

AbstractCondensation of (o‐iodophenyl)acetic acid (I) with the p‐tert.‐aminothiophenols (II) in refluxing KOH solution in the presence of Cu gives the (o‐arylthiophenyl)acetic acids (III), which cyclize in PPA to yield the thiepinones (IV).
ChemInform Abstract: Asymmetric Synthesis of New Bicyclic Phenylboronic Esters Containing Configurationally Stable Chiral Nitrogen and Boron.
Authors: MANCILLA T. , CONTRERAS R. 
Published: May 2016

AbstractPhenylboronic acid (II) reacts stereoselectively with the aminoacetic acid derivatives (I) to form the bicyclic esters (III) which contain chiral boron and nitrogen atoms.
ChemInform Abstract: Four‐membered (SiNSiO) Rings by LiF Elimination. Crystal Structure of an Eight‐membered (FLiNSi) Ring.
Authors: DIPPEL K. , KLINGEBIEL U. , SHELDRICK G. M. , STALKE D. 
Published: May 2016

AbstractThe 1,3‐functional siloxanes (I) and (V) are obtained on the reaction of dihalogenosilanes (II) or (IV) with the lithiated silanols (III), respectively.
ChemInform Abstract: Reactions of Phosphorus Hydrides, Containing a P‐S Bond, with Polyhalomethanes.
Authors: SINYASHIN O. G. , GORSHUNOV I. YU. , BATYEVA E. S. , PUDOVIK A. N. 
Published: May 2016

AbstractReaction of the thiophosphinite (I) with the halomethanes (II) leads to the formation of the phosphonous halides (III).
ChemInform Abstract: Reaction of Diphenyl Ditelluride with Acetylene.
Authors: POTAPOV V. A. , KASHIK A. S. , GUSAROVA N. K. , MINKIN V. I. , SADEKOV I. D. , TROFIMOV B. A. , AMOSOVA S. V. 
Published: May 2016

AbstractThe title reaction is studied for the first time.
ChemInform Abstract: Isomerization Pathways of tert‐ButylCp‐Substituted (Diene)zirconocene and ‐hafnocene Complexes.
Authors: ERKER G. , MUEHLENBERND T. + , RUFINSKA A. , BENN R. 
Published: May 2016

Abstractη4‐Diene complexes of tert‐butyl substituted bent metallocene units are prepared by treatment of (I) or (V) with diene‐Mg reagents (II).
ChemInform Abstract: A Binuclear Vanadium(III) Complex Containing the Linear (VOV)4+ Unit: Preparation, Structure, and Properties of (V2O(SCH2CH2NMe2)4).
Authors: MONEY J. K. , FOLTING K. , HUFFMAN J. C. , CHRISTOU G. 
Published: May 2016

AbstractThe title complex (Ia) is prepared by reaction of the Na salt of the thiolate ligand with VCl3 in MeCN (no yield given); it crystallizes in the space group P1 with Z=2.
ChemInform Abstract: Sulfur Ylide Complexes via Addition of Thioethers to Benzylidenepentacarbonyltungsten.
Authors: FISCHER H. , SCHMID J. , ZEUNER S. 
Published: May 2016

AbstractThe benzylidenetungsten complex (I) reacts with thioethers (II) to yield the title complexes (III), which decompose at 20 °C to give mainly (IVa) together with (Va), (VI) and the spectroscopically identified compounds W(CO)6 and cis‐ and trans‐stilbene.
ChemInform Abstract: Synthesis and Characterization of New Heterocyclic Compounds of Tungsten, Selenium, and Tellurium.
Authors: KATTI K. V. , SESEKE U. , ROESKY H. W. 
Published: May 2016

AbstractThe bis‐silylated phosphorane (I) reacts with WF6, WCl6, SeOCl2, and TeCl4 to form the new heterocyclic compounds (II).
ChemInform Abstract: Substituted Metal Carbonyls. Part 2. Facile Syntheses of Mixed‐Ligand Tricarbonyl Complexes of Chromium, Molybdenum and Tungsten.
Authors: HOR T. S. A. 
Published: May 2016

AbstractStarting with M(CO)6 (I) the tetracarbonyl (II) and fac‐tricarbonyl derivatives (III) are prepared by trimethylamine N‐oxide‐induced decarbonylation in the presence of phenanthroline or bis(diphenylphosphino)methane as shown.