bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Methods for Drug Discovery: Development of Potent, Selective, Orally Effective Cholecystokinin Antagonists.
Authors: EVANS B. E. , RITTLE K. E. , BOCK M. G. , DIPARDO R. M. , FREIDINGER R. M. , WHITTER W. L. , LUNDELL G. F. , VEBER D. F. , ANDERSON P. S. , CHANG R. S. L. , LOTTI V. J. , CERINO D. J. , CHEN T. B. , KLING P. J. , KUNKEL K. A. , SPRINGER J. P. , HIRSHFIELD J. 
Published: May 2016

AbstractVarious carboxamides such as (III) and (V) are prepared from aminodihydrobenzodiazepinones such as (I).
ChemInform Abstract: Trityl Salt‐Catalyzed Aldol Reaction Between α,β‐Acetylenic Ketones and Silyl Enol Ethers.
Authors: KOBAYASHI S. , MATSUI S. , MUKAIYAMA T. 
Published: May 2016

AbstractThe α,β‐acetylenic ketones (I) react with the silyl enol ethers (II) in the presence of a catalytic amount of trityl perchlorate to give the isomeric addition products (III) and (IV) with a stereoselectivity in favour of (III).
ChemInform Abstract: Reactions of Secondary Phosphines with a Phosphorus‐Phosphorus Bond and Related Reactions.
Authors: AVENS L. R. , CRIBBS L. V. , MILLS J. L. 
Published: May 2016

AbstractThe reaction of a sec. alkyl‐ or arylphosphine or ‐arsine with the cyclic polyphosphine (I) or (CF3P)5 produces chiral dipnicogens of the type R2E‐P(CF3)H (E: P or As).
ChemInform Abstract: 1,2λ3,3λ3‐Azadiphospholes, an Aromatic Ring System with cis‐P=P Double Bond. 1λ3σ3,3λ3σ2‐Diphospholes.
Authors: MAERKL G. + , DIETL S. , ZIEGLER M. L. , NUBER B. 
Published: May 2016

AbstractThe 1,2,4,5‐tetrazine‐3,6‐dicarboxylates (I) react with tert‐butyl phosphaethyne (II) to give the title compounds (III) which are treated with HCl or methanol (V), forming the addition products (VI).
ChemInform Abstract: Enantioselective α‐Selenenylation of 2‐Phenylpropanal.
Authors: PAULMIER C. , OUTURQUIN F. , PLAQUEVENT J.‐C. 
Published: May 2016

Abstract2‐Phenylpropanal (I) reacts with the arylselenenamides (II) to give the optically active arylselenenylphenylpropanals (IV) via the intermediates (III).
ChemInform Abstract: Novel Reactions of Sterically Protected Fused 1,2,3‐Selenadiazole. A New Aspect of Reactivity of Organoselenium Intermediates.
Authors: ANDO W. , KUMAMOTO Y. , TOKITOH N. 
Published: May 2016

AbstractPhotolysis of the fused selenadiazole (I) is performed in the presence of various trapping agents such as the olefins (II), yielding cycloadducts such as the selenole (III).
ChemInform Abstract: Oxygen‐Selenium Exchange Using Phenylselenophosphonic Dichloride (PhP(Se)Cl2): Conversion of C=O into C=Se.
Authors: MICHAEL J. P. , REID D. H. , ROSE B. G. , SPEIRS R. A. 
Published: May 2016

AbstractTreatment of the carboxamides (I), the aldehydes (IV), and the 1,2‐dithiolone (VI) with phenylselenophosphonic dichloride (II) results in the formation of the corresponding seleno derivatives (III), (V), and (VII).
ChemInform Abstract: Preparation and Structural Characterization of Methylmercury(II) Complexes of 3‐Methyladenine.
Authors: SHELDRICK W. S. , GROSS P. 
Published: May 2016

AbstractThe methylmercury(II) complexes (I)‐(V) are isolated from aqueous solution in the pH range 2‐8 and structurally characterized.
ChemInform Abstract: Chemistry of Yttrium Triisopropoxide Revisited. Characterization and Crystal Structure of Y5(μ5‐O)(μ3‐OiPr)4(μ2‐OiPr)4(OiPr)5.
Authors: PONCELET O. , SARTAIN W. J. , HUBERT‐PFALZGRAF L. G. , FOLTING K. , CAULTON K. G. 
Published: May 2016

AbstractThe title compound is isolated from the reaction of yttrium metal in refluxing 2‐propanol in 75% yield and is characterized by 1H, 13C, and 89Y NMR spectra and an X‐ray structure determination (space group Pbca, Z = 8).
ChemInform Abstract: Thermal and Photochemical Reactions of (η5‐Cyclohexadienyl)2Fe2(CO)4 in the Presence of 2e‐ Donor Ligands: Isolation and Characterization of (η4‐C,C′‐(Cyclohexadiene)2)Fe2(CO)4L2.
Authors: ZOU C. , AHMED K. J. , WRIGHTON M. S. 
Published: May 2016

AbstractProducts from thermal or photochemical reaction of (I) with neutral ligands (II) are the same.
ChemInform Abstract: Mononuclear and Binuclear Cu(I) Complexes with Metal‐Sulfur Ligation.
Authors: KARAGIANNIDIS P. , ASLANIDIS P. , KESSISSOGLOU D. P. , KREBS B. , DARTMANN M. 
Published: May 2016

AbstractThe 1:4 molar reaction of the tetrameric Cu(I) compounds (I) with pyridine‐2‐thione, pyridine‐4‐thione, and pyrimidine‐2‐thione in toluene or CH2Cl2 results in the formation of the dimeric products (III).
ChemInform Abstract: Disperse and Cationic Dyes Derived from 2‐(meta‐ and para‐Aminophenyl)imidazo(4,5‐b)pyridine.
Authors: SAVARINO P. , VISCARDI G. , CARPIGNANO R. , BARNI E. , FERRERO G. 
Published: May 2016

Abstract2,3‐Diaminopyridine (I) reacts with m‐aminobenzoic acid (II) to give the imidazo(4,5‐b)pyridine (III) which is diazotized and then coupled with the anilines (V), forming the azo dyes (VI).
ChemInform Abstract: Inhibitors of Cyclic AMP Phosphodiesterase. Part 4. Synthesis and Evaluation of Potential Prodrugs of Lixazinone (N‐Cyclohexyl‐N‐methyl‐4‐((1,2,3,5‐tetrahydro‐2‐oxoimidazo(2,1‐b)quinazolin‐7‐yl)oxy)butyramide, RS‐82856).
Authors: VENUTI M. C. , ALVAREZ R. , BRUNO J. J. , STROSBERG A. M. , GU L. , CHIANG H.‐S. , MASSEY I. J. , CHU N. , FRIED J. H. 
Published: May 2016

AbstractReductive amination of the nitrobenzaldehyde (I) with the glycine esters (IIa) or the amides (IIb) followed by reduction of the nitro group and cyclization with cyanogen bromide (III) gives the quinazolines (IV).
ChemInform Abstract: Ascorbic Acid. Part 2. Structural Determination and Synthesis of 2‐ and 3‐Acyl Derivatives of 5,6‐O‐Isopropylidene‐L‐ascorbic Acid.
Authors: CABRAL J. , HAAKE P. 
Published: May 2016

AbstractThe 2‐ or 3‐acylated derivatives (III) and (V) respectively are obtained from 5,6‐O‐isopropylidene‐L‐ascorbic acid (II) by convenient acylation reaction with benzoyl chloride (I) or acetyl chloride (IV).
ChemInform Abstract: New Inorganic Ultrafiltration Membranes: Titania and Zirconia Membranes.
Authors: LARBOT A. , FABRE J.‐P. , GUIZARD C. , COT L. , GILLOT J. 
Published: May 2016

AbstractTitania and zirconia membranes are prepared by destabilization of colloidal solutions.
ChemInform Abstract: Anodic Oxidation of Lead in Aqueous Carbonate Solutions. Part 2. Film Formation and Dissolution in the pH Range 9 to 14.
Authors: SHOESMITH D. W. , BAILEY M. G. , TAYLOR P. 
Published: May 2016

AbstractAnodic oxidation of Pb in aqueous carbonate solution results in the formation of a variety of surface phases depending on the pH.
ChemInform Abstract: Activation of Highly Ordered Pyrolytic Graphite for Heterogeneous Electron Transfer: Relationship Between Electrochemical Performance and Carbon Microstructure.
Authors: BOWLING R. J. , PACKARD R. T. , MCCREERY R. L. 
Published: May 2016

AbstractIt is found that modification of highly ordered pyrolytic graphite (HOPG) by both anodization or pulsed laser irradiation accelerates the heterogeneous electron transfer rate constants (k0) for the Fe(CN)3‐/46 and dopamine redox systems by ∼ 6 orders of magnitude.
ChemInform Abstract: Effects of Replacing Oxygen by Sulfur at the Endogenous Bridging Center on the Redox Properties of Binuclear Copper(II) Complexes.
Authors: BOND A. M. , HAGA M. , CREECE I. S. , ROBSON R. , WILSON J. C. 
Published: May 2016

AbstractThe effect of the bridging O or S on the redox properties of (I) is examined by comparative voltammetry at Hg, Pt, Au and glassy‐carbon electrodes in CH2Cl2, THF, DMF and PrCN.
ChemInform Abstract: Stereochemical Studies on the Formation of α,β‐Epoxysulfones Using α‐Chloro‐β‐hydroxysulfones of Known Configuration.
Authors: GROSSERT J. S. , SOTHEESWARAN S. , DHARMARATNE H. R. W. , CAMERON T. S. 
Published: May 2016

AbstractThe synthesis of epoxysulfone (II) once prepared from the same precursor (I) (major diastereomer) by Bohlmann and Haffer (1969) is repeated and the stereochemistry assigned earlier to (II) is confirmed by X‐ray crystallography (space group Pca21 with Z=4).
ChemInform Abstract: Diastereofacial Control in the Reaction of (R)‐α‐(p‐Tolylsulfinyl)acetophenones with Several Organometallics.
Authors: FUJISAWA T. , FUJIMURA A. , UKAJI Y. 
Published: May 2016

AbstractThe p‐tolylsulfinylacetophenones (I) react diastereoselectively with the organometallic reagents (II) or (V), forming mixtures of the compounds (III) and (IV) with predominance of one of these products.
ChemInform Abstract: Anomalous Cycloaddition of Oxazoles with PTAD.
Authors: IBATA T. , ISOGAMI Y. , TAMURA H. 
Published: May 2016

AbstractThe oxazoles (I) react with N‐phenyl‐1,2,4‐triazole‐3,5‐dione (II) to give the anomalous cycloaddition products (III).
ChemInform Abstract: Photochemical Skeletal Redistributions of Permethylated Linear and Cyclic Oligosilyl Groups in (η5‐C5H5)Fe(CO)2‐Substituted Oligosilanes.
Authors: PANNELL K. H. , WANG L.‐J. , ROZELL J. M. 
Published: May 2016

AbstractPhotochemical treatment of the title complexes (I) and (IV) which contain at least four silicon atoms results in very high‐yield formation of the tris(silyl)silyl complexes (II), (III) and (V).
ChemInform Abstract: Photo Diels‐Alder Additions. Part 4. 1,4‐Photoaddition of α‐(tert.‐Butylthio)acrylonitrile to Acylnaphthalenes.
Authors: DOEPP D. + , MEMARIAN H. R. , KRUEGER C. + , RAABE E. 
Published: May 2016

AbstractWhile nitrile (II) does not photoreact with (Ic) or 2‐acetonaphthone, it adds to photoexcited (Ia), (Ib), and (IV) in a (4 + 2) mode with highly regio‐ and stereoselective formation of (IIIa) (not isolable due to its instability), (IIIb) (space group P21/c with Z=4), and (V), respectively.
ChemInform Abstract: Designing Zeolite Catalysts for Size‐ and Shape‐Selective Reactions: Selective Hydrogenation of Acetylene in the Presence of Butadiene and Ethylene
Authors: CORBIN D. R. , ABRAMS L. , BONIFAZ C. 
Published: May 2016

Abstract(on small‐pore zeolites which are ion‐exchanged with Ni2+, subsequently reduced, and poisoned at the metal sites on the external zeolite surface (e.g.
ChemInform Abstract: Homologation of Methanol Catalyzed by Manganese Carbonyl in Tertiary Amine‐Methanol Solutions.
Authors: CHEN M. J. , RATHKE J. W. 
Published: May 2016

AbstractIt is shown that (IV) is formed concurrently via methyl transfer by the methylated tert. amine and by methyl formate formed in the medium.
ChemInform Abstract: Palladium‐Catalyzed Carbonylation of Aryl Iodides in Aqueous Media.
Authors: BUMAGIN N. A. , NIKITIN K. V. , BELETSKAYA I. P. 
Published: May 2016

AbstractPd‐catalyzed carbonylation of (het)aryl iodides such as (I) in the presence of potassium carbonate leads to the formation of carboxylic acids, e.g. (III).
ChemInform Abstract: Orbital Theory Provoked Experiments in Organic Chemistry. Part 4. Selectivities of Aromatic Methyl Metalation. Unexpectedly Strong Interactions of Carbanions with Aromatic Rings.
Authors: INAGAKI S. , IMAI T. , MORI Y. 
Published: May 2016

AbstractThe preferential 3‐metalation of 1,3‐dimethylnaphthalene and 1,3‐dimethylanthracene with K‐diisopropylamide (and subsequent quenching with MeOD) is in conflict with the predictions from the LUMO amplitudes.
ChemInform Abstract: Simple Syntheses of Isomers of Muconaldehyde and 2‐Methylmuconaldehyde.
Authors: GOLDING B. T. , KENNEDY G. , WATSON W. P. 
Published: May 2016

AbstractOxidative cleavage of the cyclohexadienediols (I) yields the Z,Z‐configurated butadienedicarbaldehydes (II).
ChemInform Abstract: Synthesis of Insecticidally Active 3‐Phenoxybenzyl and α‐(RS)‐Cyano‐3‐phenoxybenzyl (.+‐.)‐trans‐2‐(2,2‐Dichlorovinyl)spiro(2.5)octane‐1‐carboxylates.
Authors: KULKARNI G. H. , ARBALE A. A. 
Published: May 2016

AbstractThe spiro‐fused cyclopropanecarboxylates (XIV) and (XVI) mentioned in the title are prepared via dehydrochlorination/cyclization of the tetrachloride (VI).
ChemInform Abstract: 2,6‐Dimethoxybenzenethiol, an Odorless Crystalline Thiol with High Nucleophilicity.
Authors: WADA M. , TENMA K. , KAJIHARA K. , HIRATA K. , ERABI T. 
Published: May 2016

AbstractThe air‐stable title compound is found to possess much stronger nucleophilicity toward alkyl halides than PhSH.
ChemInform Abstract: Reaction of N‐Substituted N′‐Trifluoromethylcarbodiimides with Ammonia.
Authors: MARTYNOV I. V. , AKSINENKO A. YU. , KORENCHENKO O. V. , GONTAR' A. F. , SOKOLOV V. B. 
Published: May 2016

AbstractThe carbodiimides (I) react with ammonia (II) to give the cyanoguanidines (III).
ChemInform Abstract: Novel 1,2‐Phenyl Shift in Silver‐Assisted Reaction of Triphenylchloroallene with Aromatic Amines.
Authors: KITAMURA T. , TANIGUCHI H. 
Published: May 2016

AbstractTriphenylchloroallene (I) is coupled with the anilines (II) in the presence of silver triflate (III) to form the salts (IV) via elimination of chlorine and migration of a phenyl group.
ChemInform Abstract: Synthesis, Structure, and Properties of Triple‐Layered (2.2) (2.2)Naphthalenophane.
Authors: OTSUBO T. , ASO Y. , OGURA F. , MISUMI S. , KAWAMOTO A. , TANAKA J. 
Published: May 2016

AbstractThe outer naphthalene rings of the title compound (III) (space group P1 with Z=4) adopt boat forms while the inner ring exists in a twist form.
ChemInform Abstract: Selective Cleavage of Thiazolidines. Part 1. Mercuric Acetates in Aprotic Media.
Authors: KANG J. , CHOI Y. R. , CHOI S.‐G. , CHO H. G. , LIM D. , IM W. B. , LEE J. H. 
Published: May 2016

AbstractSelective cleavage of thiazolidines such as (I) is carried out in MeCN with CaCO3 as acid scavenger.
ChemInform Abstract: Heterocycle Formation from 1,3‐Dinitroalkanes. A Novel Pyrazole Synthesis.
Authors: CABRERA ESCRIBANO F. , ALCANTARA M. P. D. , GOMEZ‐SANCHEZ A. 
Published: May 2016

AbstractThe 1,3‐dinitroalkanes (III), prepared by coupling the nitroolefins (I) with the nitroalkanes (II) in the presence of bases, react with hydrazine hydrate (IV) to form the pyrazoles (V).
ChemInform Abstract: A Convenient Synthesis of 1,3‐Oxathiole‐2‐thione Derivatives. Reaction Between Sodium 1‐Imidazolecarbodithioate and α‐Halo Ketones.
Authors: ISHIDA M. , SUGIURA K. , TAKAGI K. , HIRAOKA H. , KATO S. 
Published: May 2016

AbstractSodium 1‐imidazolecarbodithioate (III) reacts with the α‐bromo ketones (IV) in the presence of triethylamine or excess (III) to form the 1,3‐oxathiole‐2‐thiones (V).
ChemInform Abstract: Unusual Transformation of N,N′‐Bismesityldichloromalondiimidoyl Dichloride with Sodium Azide.
Authors: DASHKOVSKAYA E. V. , SHIVANYUK A. F. , LOZINSKII M. O. , SOKOLOVA YU. A. , D'YACHENKO O. A. , ATOVMYAN L. O. 
Published: May 2016

AbstractReaction of the diimidoyl dichloride (I) with sodium azide (II) gives the bistetrazolyliminomethane (III).
ChemInform Abstract: The Chemistry of Constrained Hetero Aromatics. Part 6. Synthesis of Two Isomeric (2.2)(2,4)Pyridinophanes.
Authors: KAWASHIMA T. , FUJIMOTO Y. , TOHDA Y. , ARIGA M. , MORI Y. , MISUMI S. 
Published: May 2016

Abstract2,4‐Lutidine (I) is converted to the bisisothiuronium salt (IV) via the bis(chloromethyl)pyridine (II).
ChemInform Abstract: A Novel Method for the Generation of Thial S‐Sulfides from 2,4,6‐Trisubstituted 5,6‐Dihydro‐1,3,5‐dithiazines.
Authors: TAKIKAWA Y. , MAKABE T. , HIROSE N. , HIRATSUKA T. , TAKOH R. , SHIMADA K. 
Published: May 2016

AbstractThe aldehydes (I) react with ammonia (II) and hydrogen sulfide (III) in ethanol to give the 1,3,5‐dithiazine derivatives (IV).
ChemInform Abstract: Heterocyclic Seven‐Membered Ring Compounds. Part 34. A Simple Synthesis of 1‐Benzoxepin and 1‐Benzothiepin.
Authors: HOFMANN H. , DJAFARI H. 
Published: May 2016

AbstractThe Ce(III)‐catalyzed reduction of (IIa) and of the known thio analogue (IIb) yields the alcohols (III).
ChemInform Abstract: Synthesis and Properties of 8H‐3‐Oxaheptalen‐8‐one.
Authors: NAKAZAWA T. , ISHIHARA M. , JINGUJI M. , YAMAGUCHI M. , YAMOCHI H. , MURATA I. 
Published: May 2016

AbstractThe tricyclic ether (I) undergoes photo‐induced rearrangement to form mainly the oxaheptalenone (II), together with the hydroxyazulene (III).
ChemInform Abstract: Replacement of the CHR‐O Fragment in 1,3,5,2‐Dioxaphosphaborinane.
Authors: NIKONOV G. N. , IGNAT'EVA S. N. , BALUEVA A. S. , ERASTOV O. A. , ARBUZOV B. A. 
Published: May 2016

AbstractThe dioxaphosphaborinanes (I) react with the aldehydes (II) or (IV) bearing electron accepting groups under replacement of the CHR‐O fragment to give the corresponding dioxaphosphaborinanes (III) or (V).
ChemInform Abstract: Syntheses and Structures of Ethyl‐, Propyl‐, Butyl‐, and Mesitylantimony.
Authors: ATES M. , BREUNIG H. J. , GUELEC S. + , OFFERMANN W. , HAEBERLE K. + , DRAEGER M. + 
Published: May 2016

AbstractDehalogenation of the alkylantimony dibromides (I) with Mg gives solutions containing mainly the ring compounds (II) and (III).
ChemInform Abstract: Solid‐State Structure of (Li(μ‐OAr‐2,6‐Ph2)3Sn) (OAr‐2,6‐Ph2: 2,6‐Diphenylphenoxide): A Cage Compound Containing a Pyramidal Lithium Atom.
Authors: SMITH G. D. , FANWICK P. E. , ROTHWELL I. P. 
Published: May 2016

AbstractThe title compound (III), obtained as minor product in the reaction of (I) with SnCl4, is obtained in higher yield by using SnCl2 (II) as initial tin compound.
ChemInform Abstract: Formation of Racemic and Meso Isomers of Mono‐ and Dihydroxo‐Bridged Dinuclear Ions by Hydrolysis of the cis‐Aquahydroxobis(1,2‐ethanediamine)rhodium(III) Ion.
Authors: BJERRUM M. J. , KAAS K. , LARSEN E. , NIELSEN B. , SPRINGBORG J. 
Published: May 2016

AbstractThe hydrolysis of the racemic title complex ion at 60, 80 and 100 °C is studied by HPLC, and it is shown that the equilibrium solutions contain the meso (Δ,Λ) and the racemic (Δ,Δ/Λ,Λ) isomers of the species (I) and (II) together with the mononuclear parent compound.
ChemInform Abstract: 1,1′‐Bis(diphenylphosphino)ferrocene Complexes of Platinum(II) and Platinum(I). Crystal and Molecular Structure of ((L‐L)Pt(μ‐H)(μ‐CO)Pt(L‐L)) (BF4)·0.5 H2O, Where L‐L: Fe(η5‐C5H4PPh2)2.
Authors: BANDINI A. L. , BANDITELLI G. , CINELLU M. A. , SANNA G. , MINGHETTI G. , DEMARTIN F. , MANASSERO M. 
Published: May 2016

AbstractStarting with the complex (I) a series of Pt(II) complexes with the title ligand are synthesized as outlined in the scheme and characterized in solution.
ChemInform Abstract: The Chemistry of Thujone. Part 12. The Synthesis of Pyrethroid Analogues via Chiral Cyclopropanation.
Authors: BECALSKI A. , CULLEN W. R. , FRYZUK M. D. , HERB G. , JAMES B. R. , KUTNEY J. P. , PIOTROWSKA K. , TAPIOLAS D. 
Published: May 2016

AbstractThe diene (II) obtained from thujone (I) is treated with ethyl or L‐menthyl diazoacetate (III) in the presence of various chiral and achiral copper catalysts to give cyclopropanes such as (IV) and (V).
ChemInform Abstract: Synthesis and Reactions of 2‐Arylhydrazinotropones. Part 2. Synthesis of 5‐Aryltropolones and B‐Ring‐Open Colchicine Analogues via Benzidine Type Rearrangement of 2‐(2‐Arylhydrazino)tropones.
Authors: NOZOE T. , TAKASE K. , YASUNAMI M. , ANDO M. , SAITO H. , IMAFUKU K. , YIN B.‐Z. , HONDA M. , GOTO Y. , HANAYA T. , HARA Y. , YAMAMOTO H. 
Published: May 2016

AbstractBenzidine type rearrangement of the hydrazinotropones (III) yields the tropones (IV) which are transformed to the title tropolones (V).
ChemInform Abstract: Optically Pure 3,4‐Disubstituted Azetidinones from Sugars.
Authors: CHMIELEWSKI M. , KALUZA Z. , ABRAMSKI W. , GRODNER J. , BELZECKI C. , SEDMERA P. 
Published: May 2016

AbstractGlycolic cleavage of the vic‐diols (I) and (V) yields the corresponding dialdehydes.
ChemInform Abstract: Thermodynamics of Ionization of Hypophosphorous and Phosphorous Acids. Substituent Effects on Second Row Oxy Acids.
Authors: LARSON J. W. , PIPPIN M. 
Published: May 2016

AbstractThe pKa values of H3PO2 and H3PO3 at 5, 25, 45, 65, and 85 °C are determined using an NMR method.
ChemInform Abstract: In situ X‐Ray Diffraction Study of Metal Hydride Formation in Palladium and Palladium‐Based Alloy Electrodes Under Cathodic Hydrogen Charging.
Authors: MACHIDA K. , ENYO M. 
Published: May 2016

AbstractThe in situ XRD technique is improved for accepting samples with low crystallinity and applied to the study of hydride formation in Pd and Pd‐Au alloy foils and amorphous Pd‐Zr electrodes.
ChemInform Abstract: A New Lithosilicate: Rb5LiNiSi2O8 = Rb5(LiNiSi2O8).
Authors: HOFMANN R. , HOPPE R. 
Published: May 2016

AbstractSingle crystals of the title compounds are obtained from the reaction of RbO0.6, LiO0.5, and SiO2 in a sealed Ni‐tube (wall‐reaction, 600 °C, 10 d).
ChemInform Abstract: Single‐Crystal EPR Spectrum of the Phosphido‐Bridged Radical Fe2(CO)7(μ‐PPh2).
Authors: KRUSIC P. J. , BAKER R. T. , CALABRESE J. C. , MORTON J. R. , PRESTON K. F. , LE PAGE Y. 
Published: May 2016

AbstractThe EPR spectrum of the 33e title compound (Ib) is measured in the diamagnetic host (Ia) at 77 K. The crystal structure of the host complex (P1, Z=2) is established by X‐ray diffractometry.
ChemInform Abstract: The Effect of the Nature of the Lowest Unoccupied Molecular Orbital (LUMO) of Some Arylmethylsulfonium Salt Derivatives on Photochemical and Redox Behavior.
Authors: SAEVA F. D. , BRESLIN D. T. , MARTIC P. A. 
Published: May 2016

AbstractFluorescence quantum yield, excited singlet state lifetimes, and electrochemical peak potentials for reduction of (I) and (II) support the conclusion from MO calculations that the nature of the LUMO switches from σ* to π* for (Ib) and (IIb).
ChemInform Abstract: Oxidation of Secondary Cyclic Alcohols with Pb(OAc)4 Catalyzed by Cu(II) Compounds.
Authors: KAPUSTINA N. I. , POPKOV A. YU. , GASANOV R. G. , NIKISHIN G. I. 
Published: May 2016

AbstractCu(II)‐catalyzed oxidation of the secondary cyclic alcohols (I) with Pb(OAc)4 produces the unsaturated aldehydes (II), the ketones (III), and the oxabicycles (IVc) and (IVd).
ChemInform Abstract: Evidence for a Square Scheme Involving Conformational Intermediates in Electron‐Transfer Reactions of Copper(II)/(I) Systems.
Authors: BERNARDO M. M. , ROBANDT P. V. , SCHROEDER R. R. , RORABACHER D. B. 
Published: May 2016

AbstractThe cyclic voltammetric behavior of the complexes (Ia)/(Ib) and related systems is examined in details in both water and 80% MeOH in order to characterize the unusual electron‐transfer behavior previously observed for this system and related complexes.
ChemInform Abstract: Reactions Between Metal Carbonyl Anions and Cations: Rapid Two‐Electron Transfer Followed by One‐Electron Back Transfer.
Authors: ZHEN Y. , ATWOOD J. D. 
Published: May 2016

AbstractIR spectroscopic studies confirm that reaction of Re(CO)5 anions (I) with Mn(CO)6 cations (II) proceeds by a rapid two‐electron, one‐carbonyl transfer producing R(CO)6 cations (III) and Mn(CO)5 anions (IV) followed by a slower one‐electron back transfer to the binuclear products (V) isolated (no yields given).
ChemInform Abstract: Carbonylations Mediated by Dicyclopentadienylsamarium.
Authors: COLLIN J. , KAGAN H. B. 
Published: May 2016

AbstractCarbonylation of tert‐butyl bromide (I) in the presence of dicyclopentadienylsamarium yields the diol (III) and the hydroxy dione (IV) or exclusively (III) depending on the reaction temperature.
ChemInform Abstract: The Role of BF3·Et2O in Reactions of Lower Order (Gilman) Organocuprates.
Authors: LIPSHUTZ B. H. , ELLSWORTH E. L. , SIAHAAN T. J. 
Published: May 2016

AbstractThe effects of BF3·Et2O on low order organocuprate reactions in THF are investigated so as to determine what factors are responsible for the oftentimes dramatic reaction‐rate enhancements observed.
ChemInform Abstract: Synthesis of Bifunctional Molecules by Acid‐Catalyzed Ozone Oxidation of 1‐Methylcycloalkenes.
Authors: GRIESBAUM K. , KIESEL G. 
Published: May 2016

AbstractThe keto esters (III) are produced by ozonolysis of the cycloalkenes (I) in methanol (II) in the presence of HCl.
ChemInform Abstract: Biscarbamoyl Diselenide as a Carbamoylating Reagent. A Convenient Method for the Preparation of ω‐Haloalkyl Carbamates from Cyclic Ethers.
Authors: FUJIWARA S. , OGAWA A. , KAMBE N. , RYU I. , SONODA N. 
Published: May 2016

AbstractThe biscarbamoyl diselenide (I) reacts with the cyclic ethers (II) in the presence of mercuric halides to produce the ω‐haloalkyl carbamates (III).