bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis and X‐Ray Structural Characterization of Novel Binuclear Complexes of Copper(II), Nickel(II), and Cobalt(II) with an Octadentate Ligand, N,N′,N",N"′‐Tetrakis(2‐aminoethyl)‐1,4,8,11‐tetra‐azacyclotetradecane.
Authors: MURASE I. , MIKURIYA M. , SONODA H. , FUKUDA Y. , KIDA S. 
Published: May 2016

AbstractStarting with cyclam (I) the title ligand (IV) was prepared as its octahydrobromide (95% yield) according to the scheme and isolated in its free form by passing it through a column of anion‐exchange resin (yield almost quantitative).
ChemInform Abstract: Transition‐metal Oxo and Nitrido Complexes. Part 8. Reactions of Osmlum Oxoimido Complexes with Alkenes.
Authors: GRIFFITH W. P. , MCMANUS N. T. , WHITE A. D. 
Published: May 2016

AbstractReaction of the complexes (I) and (II) with various alkenes yields the alkanolaminato and diaminato complexes (V) and (VI), re‐ I46 spectively.
ChemInform Abstract: Synthesis of Heterotrimetallic Complexes Containing M‐Hg‐Pt (M: Pt, Fe, Mn, or Co) Arrays.
Authors: ROSSELL O. , SECO M. , TORRA I. 
Published: May 2016

AbstractThe heterotrimetallic Complexes (III) are prepared by reaction of the Pt(O) complex (II) with the derivative (I).
ChemInform Abstract: Reaction of Potassium Salts of Boc‐amino Acids with p‐Bromomethylbenzoyl Polyiethylene Glycol Monomethyl Ether Catalyzed by 18‐Crown‐6.
Authors: YOUNEIS M. E. , RAHMAN S. A. , HATTABA A. 
Published: May 2016

Abstract18‐Crown‐6 is found to be a good catalyst in the quantitative esterification title reaction examined for the examples (I).
ChemInform Abstract: Multielectron Reductions of Alkyl Azides with [Mo2Fe6S8(SPh)9]3‐ and [Mo2Fe6S8(μ‐SEt)3(SCH2CH2OH)6]3‐ in Homogeneous Systems and with a (n‐Bu4N)3[Mo2Fe6S8(SPh)9] Modified Glassy‐Carbon Electrode in H2O.
Authors: KUWABATA S. , TANAKA K. , TANAKA T. 
Published: May 2016

AbstractThe electrochemical behaviors of a (Bu4N)3[Mo2Fe6S8(SPh)9] modified glassy‐carbon electrode ([Mo ‐ Fe]/GC) is studied in water.
ChemInform Abstract: Photoreduction of Indigo Dyes by Electron Donors. One‐ and Two‐Electron‐Transfer Reactions as a Consequence of Excited‐State Quenching.
Authors: SCHANZE K. S. , LEE L. Y. C. , GIANNOTTI C. , WHITTEN D. G. 
Published: May 2016

AbstractPhotoreduction of (I) proceeds via different mechanisms.
ChemInform Abstract: Reactions of Trialkylalkynylborates with 2‐Alkyl‐1,3‐dioxolan‐2‐ylium Fluorosulphonates.
Authors: PELTER A. , COLCLOUGH M. E. 
Published: May 2016

AbstractAus den Ester‐ethern (I) erhält man über die Salze (III) mit den Alkinylboranen (IV) die Addukte (V), die mit Alkali‐ Wasserstoffperoxid zu Ketonen (VI) oxidiert und sauer zu Vinylketonen (VII) hydrolysiert werden.
ChemInform Abstract: Some Derivatives of 2,3,5,6‐Tetrafluorobenzenethiol.
Authors: MAHAR J. A. , PEACH M. E. 
Published: May 2016

AbstractAusgehend von der im Titel genannten Verbindung (I) werden nach verschiedenenen, literaturbekannten Methoden die Thiophenolate von einwertigen (II) und zweiwertigen Metallen (III) hergestellt.
ChemInform Abstract: Oxidative Coupling: The Toluic Acid Dianion System.
Authors: BELLETIRE J. L. , SPLETZER E. G. 
Published: May 2016

AbstractDie aus 0‐ (I) bzw. p‐Tolylsäure (III) generierten Dianionen (VI) werden mit Methyliodid in die homologen Säuren (II) bzw. (IV) übergeführt.
ChemInform Abstract: Unusual Course of the Reaction of Cyclopentanone with 2,5‐Dibenzylidenecyclopentanone in Basic Medium.
Authors: MINAEVA N. N. , TILICHENKO M. N. 
Published: May 2016

AbstractThe reaction between the title compounds (I) and (II) does not afford the expected and known product of the Michael addition, but the condensation products (III) and (IV).
ChemInform Abstract: Polycarbonyl Heterocycles. Part 3. Synthesis of 2,3‐Furanodione Derivatives by Ring Transformations of Thiazolidine‐4,5‐dione Derivatives.
Authors: ZALESKA B. 
Published: May 2016

AbstractTreatment of thiazolidinediones (I) with an equimolar amoünt of the amines (II) leads to the salts (III) (IR, 1H NMR and mass spectra).
ChemInform Abstract: Preparation of 3‐Azabicyclo[3.2.0]heptenones by Intramolecular [2 + 2] Cycloaddition.
Authors: ARYA F. , BOUQUANT J. , CHUCHE J. 
Published: May 2016

AbstractN‐AllyI‐enamino‐ester (I) werden der Pyrolyse unterworfen und hierbei über die Keten‐Zwischenstufen (II) die Bicyclen (III) erhalten.
ChemInform Abstract: Research on Substances with Antibacterial and Antifungal Activity.
Authors: SCALZO M. , BIAVA M. , CERRETO F. , PORRETTA G. C. , PANICO S. , SIMONETTI N. , VILLA A. 
Published: May 2016

AbstractNitrobenzylbromide (I) reagieren mit Imidazol (II) zu den Nitrobenzylimidazolen (IIIa), welche zu den Amino‐benzyl‐imidazolen (IIIb) reduziert werden.
ChemInform Abstract: Synthesis of O‐Heterocycles with an Exocyclic Vinylidene Group by Means of Organo Silicium Compounds.
Authors: PORNET J. , DAMOUR D. , RANDRIANOELINA B. , MIGINIAC L. 
Published: May 2016

AbstractThe silanes (Ia) and (Ib) react with the aldehydes (IIa) to give the title compounds (III).
ChemInform Abstract: Chlorosulfonyl Isocyanate: An Unusual Chlorinating Agent.
Authors: SRINIVASAN T. N. , RAO K. R. , SATTUR P. B. 
Published: May 2016

AbstractDie Pyridazinone (I) werden durch Chlorsulfonylisocyanat (II) in die S‐Chlorpyridazine (III) übergeführt.
ChemInform Abstract: Ruthenium Complexes of N,S‐ and C,N,S‐Coordinating Azo Ligands: Synthesis, Reactions, and Structure.
Authors: MAHAPATRA A. K. , DATTA S. , GOSWAMI S. , MUKHERJEE M. , MUKHERJEE A. K. , CHAKRAVORTY A. 
Published: May 2016

AbstractThe reaction of RuCl3 with the azo ligands (I) afforded the pseudooctahedral complexes (II) (X: ‐ Cl) and (III) containing the ligands bond in a different manner (IR and 1H NMR evidence).
ChemInform Abstract: Synthesis and Structure of Three (Tricyclohexylphosphine)rhodium Complexes and Their Interconversion with Carbon Monoxide and Hydrogen.
Authors: FREEMAN M. A. , YOUNG D. A. 
Published: May 2016

AbstractThe reaction of the acetylacetonato complex (I) with CO and H2 in the presence of tricyclohexylphosphine gives an easily separated mixture of the trans‐square‐planar complex (II) and the binuclear complex (III) with a square‐planar Rh(CO)PCy3 and a distorted‐tetrahedral Rh(PCy3)2 unit.
ChemInform Abstract: Proton Transfer as a Function of Hydration Number and Temperature: Rate Constants and Product Distributions for OH‐ (H2O)0,1,2,3 + HF at 200‐500 K.
Authors: HIERL P. M. , AHRENS A. F. , HENCHMAN M. , VIGGIANO A. A. , PAULSON J. F. , CLARY D. C. 
Published: May 2016

AbstractThe influence of hydration on the rate constants and the product distributions of the title proton transfer reaction has been investigated in a selected ion flow tube.
ChemInform Abstract: Kinetics of the Gas Phase Reaction NO + NO3 → 2 NO2.
Authors: HAMMER P. D. , DLUGOKENCKY E. J. , HOWARD C. J. 
Published: May 2016

AbstractThe rate constant of the title reaction has been measured directly in the temp. range of 209‐414 K by using laser‐induced fluorescence detection of NO3 in a flow tube reactor because of its possible importance in the chemistry of the earth′s atmosphere.
ChemInform Abstract: The Unusual Structural Feature of Binuclear Platinum Chains [Pt2(L‐L)4X].
Authors: WHANGBO M.‐H. , CANADELL E. 
Published: May 2016

AbstractTo gain some insight into the origin of some apparently puzzling properties, the distortions of the model chain Pt2(HCS‐,‐)4X with X: I as a function of the halide ion displacement ö are examined by performing tight‐binding band calculations.
ChemInform Abstract: The Geometry at Nitrogen in N‐Phenylsulphonyl‐pyrroles and ‐indoles.
Authors: BEDDOES R. L. , DALTON L. , JOULE J. A. , MILLS O. S. , STREET J. D. , WATT C. I. F. 
Published: May 2016

AbstractInvestigations of the crystal structures of (I) and (II) (space group P21/c, Z=4), (III) and the triclinic form of (IV) (PI, Z=2), as well as the orthorhombic modification of (IV) (Pbca, Z=8) confirm the substantial tendency of the nitrogen in pyrroles and indoles to be planar and to adopt an orientation, in which nitrogen lone pair and the p orbital at the S‐bearing aromatic carbon are nearly coplanar.
ChemInform Abstract: Studies of Metal ‐ Carbonate Complexes. Part 14. Composition and Equilibria of Trinuclear Neptunium(VI)‐ and Plutonium(VI)‐ Carbonate Complexes.
Authors: GRENTHE I. , RIGLET C. , VITORGE P. 
Published: May 2016

AbstractThe chemical composition of the trinuclear complexes (II) and the equilibrium constants for their formation reactions are determined spectrophotometrically.
ChemInform Abstract: Study of Formation of the Spiro‐Meisenheimer Adduct of NN′‐Dimethyl‐N‐ (2,4,6‐trinitrophenyl)glycinamide and Its Rearrangement to 2‐Methylamino‐N‐methyl‐N‐(2,4,6‐trinitrophenyl)acetamide.
Authors: MACHACEK V. , HASSANIEN M. M. M. , STERBA V. 
Published: May 2016

AbstractThe glycinamide (III) [obtained from (I) and (II)] is cyclized in methanol under base catalysis to give the spiro‐adduct (IV).
ChemInform Abstract: Stereospecific Michael Addition of Dithioester Enethiolates with Acyclic Enones.
Authors: KPEGBA K. , METZNER P. , RAKOTONIRINA R. 
Published: May 2016

AbstractAus dem Dithioester (I) werden die isomeren Li‐thioenolate (II) und (III) erhalten, die mit den Cycloalkenonen (IV) zu Gemischen der Addukte (V) und (VI) unter Bevorzugung der anti‐Form (V) führen.
ChemInform Abstract: Cycloaddition to [b]‐Annulated Indole Derivatives. Part 1. [4 + 2]‐Cycloaddition to 1,1‐Bis(3‐indolyl)ethenes as 3‐Vinylindole Equivalents with Cross Conjugated 6π‐Systems.
Authors: PFEUFFER L. , PINDUR U. 
Published: May 2016

AbstractDie Bis‐indolylethene (I) reagieren mit den Dienophilen (II) zu den Diels‐ Alder‐Addukten (III).
ChemInform Abstract: Application of Phase‐Transfer Catalysis to the Synthesis of Mono‐ and Bis‐stilbenes and Styryls.
Authors: LOKHANDE S. B. , RANGNEKAR D. W. 
Published: May 2016

AbstractReactions between the compounds (I) and (IV) with an active methyl group and the aldehydes (II) and (VI) under optimized conditions allow the synthesis of the desired products (III), (V), (VII) and (VIII) in predominantly good to excellent yields.
ChemInform Abstract: Reactivity Differences between Dimorphs in a Crystalline Phase Norrish Type II Reaction.
Authors: EVANS S. V. , OMKARAM N. , SCHEFFER J. R. , TROTTER J. 
Published: May 2016

AbstractDas Adamantyl‐p‐chloracetophenon (I) wird photochemisch durch intramolekulare Cycloaddition in die Cyclobutanole (II) und (III) übergeführt.
ChemInform Abstract: Functionalization of Saturated Hydrocarbons. Part 4. The Gif System for Selective Oxidation Using Molecular Oxygen.
Authors: BARTON D. H. R. , BOIVIN J. , GASTIGER M. , MORZYCKI J. , HAY‐MOTHERWELL R. S. , MOTHERWELL W. B. , OZBALIK N. , SCHWARTZENTRUBER K. M. 
Published: May 2016

AbstractVarious systems for the selective oxidation of saturated hydrocarbons have been developed.
ChemInform Abstract: Reactivity of the σ‐Actinide Carbon Bond: Tris[bis(trimethylsilylamido)methyl]uranium, a Nucleophilic Methylation Reagent with High Selectivity.
Authors: DORMOND A. , AALITI A. , MOISE C. 
Published: May 2016

AbstractDie Methyluran‐ Verbindung (I) reagiert mit den Oxoverbindungen (II) in hohen Ausbeuten selektiv zu den Addukten (III), die mit Wasser zu den Alkoholen (IV) hydrolysiert werden.
ChemInform Abstract: Design of Ligands Derived from Sulfur Containing Amino Acids for Enantioselective Cross Coupling Catalyzed by Nickel.
Authors: VRIESEMA B. K. , KELLOGG R. M. 
Published: May 2016

AbstractDie Kondensation zwischen der Grignard‐Verbindung (VIII) und Vinylbromid (IX) wird durch verschiedene Liganden (III)‐(VII) hinsichtlich des Enantiomeren‐Verhältnisses unterschiedlich beeinflußt. Die Herstellung des Liganden (III) aus (I) über die Zwischenstufe (II) wird beschrieben.
ChemInform Abstract: A Simple Synthesis of α‐Methylene‐β‐hydroxyalkanones.
Authors: BASAVAIAH D. , GOWRISWARI V. V. L. 
Published: May 2016

AbstractIn Gegenwart von Dabco erhält man aus den Aldehyden (I) und Methyl‐vinyl‐keton (II) die Alkohole (III).
ChemInform Abstract: Chemistry of Organosilicon Compounds. Part 217. Diastereoselective Reaction of Crotylsilanes with Acetals.
Authors: HOSOMI A. , ANDO M. , SAKURAI H. 
Published: May 2016

AbstractDie Crotylsilane (Ia) und (Ib) reagieren mit den Acetalen (IIa)‐(llf) unter Katalyse von Lewis‐Säuren zu einem Gemisch der syn‐/anti‐Ether (lIl)/(IV).
ChemInform Abstract: Cobalt Carbonyl Catalyzed Polycarbonylation of Polyhalogenated Aromatics Under Photostimulation.
Authors: KASHIMURA T. , KUDO K. , MORI S. , SUGITA N. 
Published: May 2016

AbstractAus den Arylhalogeniden (I) erhält man mit Kohlenmonoxid photochemisch unter Cobaltkatalyse über eine Carbonylierung die entsprechenden Benzoesäuren.
ChemInform Abstract: Synthesis of Optically Pure (R)‐ or (S)‐α‐Fluoro‐α‐methyl‐β‐ketoesters.
Authors: KITAZUME T. , KOBAYASHI T. 
Published: May 2016

AbstractAusgehend von dem optischreinen (R)‐ oder (S)‐2‐F1uor‐2‐methyl‐malonsäurehalbester (I) (e.e.
ChemInform Abstract: Platinum Complex Catalyzed Transformation of Amine. Part 2. N‐Alkylation and N‐ Allylation Using Primary Alcohols.
Authors: TSUJI Y. , TAKEUCHI R. , OGAWA H. , WATANABE Y. 
Published: May 2016

AbstractDie Amine (I) werden von den Alkoholen (II) in Gegenwart von Platinkatalysatoren N‐alkyliert.
ChemInform Abstract: Analogues of Poison Ivy Urushiol. Synthesis and Biological Activity of Disubstituted n‐Alkylbenzenes.
Authors: ELSOHLY M. A. , ADAWADKAR P. D. , BENIGNI D. A. , WATSON E. S. , LITTLE T. L. JUN. 
Published: May 2016

AbstractAusgehend von Phenol (I), m‐ (XV) und p‐Dimethoxybenzol (XX), Veratrumaldehyd (X) und Resorcin (XVIII) werden nach dem im Schema angegebenen Reaktionsfolgen einige Isomere wie (XIV), (XIX) und (XXII) und einige Analoge wie (VII), (IX) und (XVII) des 3‐Pentadecylcatechols (XXIII) (PDC) hergestellt.
ChemInform Abstract: A Convenient Synthesis of 1,2‐Benzenedisulphonyl Chloride.
Authors: BARBERO M. , DEGANI I. , FOCHI R. , REGONDI V. 
Published: May 2016

AbstractThe conversion of anthranilic acid (I) to the 2‐alkoxy‐1,3‐benzodithiole (II) and the preparation of the 1,3‐benzodithiolium salt (III) from (II) are syntheses known from the literature.
ChemInform Abstract: Benzocyclo‐octenes. Part 5. Thermal Rearrangements of Benzocyclo‐octenes to Benzo[a]cyclopropa[c,d]pentalenes.
Authors: BARTON J. W. , SHEPHERD M. K. 
Published: May 2016

AbstractCycloadditions of the cyclopentadienones (I) with benzocyclobutene (II) yield the tricyclic compounds (III) which in refluxing diglyme undergo decarbonylation to give the benzocyclooctenes (IV).
ChemInform Abstract: Model Studies Aimed at the Synthesis of Fredericamycin A. A Simple o‐Quinodimethane Route to the Spiro Naphthalene Portion.
Authors: BACH R. D. , KLIX R. C. 
Published: May 2016

Abstracto‐Xylol (I) wird zur Silylverbindung (II) und weiter zu einem Dibromsilyl‐Derivat (III) substituiert.
ChemInform Abstract: Synthesis of Purpuritenin‐A and 4′‐Methylfurano[2",3":7,8]flavone.
Authors: SINHA B. , BHAT V. S. , JOSHI V. S. 
Published: May 2016

AbstractThe compound (III) is synthesized by reaction of the acetophenone (Ia) with the aldehyde (II).
ChemInform Abstract: Intramolecular Cycloadditions Using Vinyl Sulfide Dienophiles.
Authors: WILLIAMS D. R. , GASTON R. D. 
Published: May 2016

AbstractDas Epoxid (I) liefert über zahlreiche Zwischenstufen wie (II)‐(IV) letztlich einen Alkohol (Vb) in Form eines Gemisches aus 4 Diastereomeren‐Paaren.
ChemInform Abstract: Novel Rearrangement of an Isoxazole to a Pyrrole. X‐Ray Molecular Structure of Di‐ ethyl 5‐(Ethoxycarbonylmethyl)pyrrole‐2,4‐dicarboxylate.
Authors: DOLESCHALL G. , SERES P. , PARKANYI L. , TOTH G. , ALMASY A. , BIHATSI‐KARSAI E. 
Published: May 2016

AbstractThe isoxazole compound (IV) of unknown geometry is synthesized Starting from the diacid (I) (study and discussion of the formation mechanism).
ChemInform Abstract: Drug Design via Pharmacophore Identification. Dopaminergic Activity of 3H‐ Benz[e]indol‐8‐amines and Their Mode of Interaction with the Dopamine Receptor.
Authors: ASSELIN A. A. , HUMBER L. G. , VOITH K. , METCALF G. 
Published: May 2016

AbstractAusgehend von den Aminotetralinen (II) werden gemäß Schema in einer vielstu?‐ gen Reaktionsfolge die im Titel genannten Verbindungen (VIII) synthetisiert.
ChemInform Abstract: Synthesis of 3‐Substituted‐4‐Methyl‐5‐acetyl‐4‐thiazoline‐2‐thione.
Authors: D'AMICO J. J. , BOLLINGER F. G. , FREEMAN J. J. 
Published: May 2016

AbstractAus den Dithiocarbaminaten (I) erhält man mit Chlor‐acetylaceton (II) unter energischen Bedingungen die Thiazolthione (III), während bei Raumtemperatur die Dithiocarb‐ i aminate (IV) entstehen.
ChemInform Abstract: Condensation of Quinoline‐5,6‐diamine with Ketones.
Authors: REDDY A. P. R. , VEERANAGAIAH V. 
Published: May 2016

AbstractThe diamine (I) reacts with a series of ketones such as aliphatic ketones, benzophenone, dibenzylketone and cyclohexanone to give condensation products of type (ll)‐(VII).
ChemInform Abstract: Synthesis and Biological Activities of 3‐(2′‐Aryl‐4′‐oxothiazolidin‐3′‐yl)‐2‐phenylquinazolin‐4(3H)‐ones.
Authors: HUSAIN M. I. , SHUKLA S. 
Published: May 2016

AbstractThe title compounds (V) are synthesized as shown in the scheme.
ChemInform Abstract: Synthesis of Crown Ethers Bonded to a Polystyrene Matrix Through an Amido Linkage and Their Use as Phase‐Transfer Catalysts.
Authors: ANELLI P. L. , MONTANARI F. , POLLAK V. , QUICI S. 
Published: May 2016

AbstractThe title compounds (III) are synthesized as described in the scheme and the preparation of the title compounds (V) is carried out analogously (yields 34‐5l%).
ChemInform Abstract: Borane and Monoiodoborane Derivatives of Bis(diphenylphosphino)methane.
Authors: MARTIN D. R. , MERKEL C. M. , RUIZ J. P. 
Published: May 2016

AbstractThe preparation of the borane adduct (IIa), shown in the scheme, together with the previously reported isolation of (IIb) demonstrate that the products of the reaction of borane with the diphosphino methane (I) depend upon the stoichiometry used.
ChemInform Abstract: Tetratelluradicyclopenta[b,g]naphthalene (TTeDCN).
Authors: OKADA N. , SAITO G. , MORI T. 
Published: May 2016

AbstractDurch Tellurierung von (I) erhält man als Zwischenstufe die Verbindung (II), welche mit Tetrachlorethylen (III) zu einem Gemisch von (IV) und (V) reagiert, das durch Kristallisation getrennt werden kann.
ChemInform Abstract: Stereospecific Complexation of Uranyl Ion with Tartaric Acids Studied by NMR Spectroscopy.
Authors: NUNES M. T. , GIL V. M. S. 
Published: May 2016

AbstractA fu11pH range 1H and 13C NMR study is performed on the complexation of U0?′ with (D,L)‐ and meso‐tartaric acids, for variable concentrations and molar ratios, in comparison with (D)‐tartaric acid.
ChemInform Abstract: High‐valent Manganese Complexes of Tetradentate Schiff Base Ligands.
Authors: MCAULIFFE C. A. , PARISH R. V. , ABU‐EL‐WAFA S. M. , ISSA R. M. 
Published: May 2016

AbstractThe 2:1 molar reaction of Mn(II) salts with corresponding tetradentate Schiff base ligands in acetone/ethanol followed by treatment with NaOH in the presence of air leads to the acetone‐bridged dimeric Mn(III) complexes (Ia), (Id).
ChemInform Abstract: Syntheses via Vinyl Sulfones. Part 16. On the Chemistry of Lithium Diallyl Cuprate.
Authors: HUTCHINSON D. K. , FUCHS P. L. 
Published: May 2016

AbstractDas Sulfon (I) reagiert mit Allyllithium (II) zum Addukt(II1), während mit dem Lithiumcuprat (IV) praktisch keine Reaktion erfolgt.
ChemInform Abstract: Preparation and Spectroscopic Characterization of Bond‐Isomeric Halogenorhodanoosmates(IV).
Authors: HORNS U. , PREETZ W. 
Published: May 2016

AbstractThe Compounds (I), (IIb) and (III)‐(V) have been prepared by reaction of the trans Compounds [OsF5Cl]2′, [OsCl4BrI]2′, [OsCI4I2]2′, [OsBr5I]2′, and [OsBr4I2]2′ with (SCN); in CH2Cl2/CCl4.
ChemInform Abstract: A New Type of Angular Phenothiazine Ring System.
Authors: OKAFOR C. O. 
Published: May 2016

AbstractThe aza‐ and diaza‐analogues (III) of benzophenothiazines are prepared by base‐catalysed reaction of the thiones (II) with the dichloro compound (Ia) [use of methanol as solvent results in concurrent formation of the methoxy derivative (Ib)].
ChemInform Abstract: Probes for Narcotic Receptor Mediated Phenomena. Part 9. Synthesis of (±)‐(3α,6aα,11aβ)‐1,3,4,5,6,11a‐Hexahydro‐2‐methyl‐2H‐3,6a‐methanobenzofuro[2,3‐c]azocin‐10‐ol, an Oxide‐Bridged 5‐(m‐Hydroxyphenyl)morphan.
Authors: BURKE T. R. JUN. , JACOBSON A. E. , RICE K. C. , WEISSMAN B. A. , HUANG H.‐C. , SILVERTON J. V. 
Published: May 2016

AbstractDie im Titel genannte Verbindung (XIII) wird gemäß Schema in einer vielstufigen Reaktionsfolge ausgehend von Veratrol (I) und dem Piperidinon (II) synthetisiert.
ChemInform Abstract: Synthetic, Biochemical and Antiviral Aspects of Selected Acyclonucleosides and Their Derivatives.
Authors: MACCOSS M. , TOLMAN R. L. , ASHTON W. T. , WAGNER A. F. , HANNAH J. , FIELD A. K. , KARKAS J. D. , GERMERSHAUSEN J. I. 
Published: May 2016

AbstractThe detailed syntheses of a series of guanine acyclonucleosides and acyclonucleotides related to acyclovir [ACV; (Ia)] are described [for example, a synthesis of (Ib) starting from (IIIa) is shown in the scheme].
ChemInform Abstract: Synthesis of Δ3‐1‐Methylene‐1‐carbacephems.
Authors: HERDEWIJN P. , CLAES P. J. , VANDERHAEGHE H. 
Published: May 2016

AbstractAusgehend vom Hydroxyester (I) bzw. dem Dimethylpentenal (IV) werden in einer mehrstufigen Synthese die α‐Methylenaldehyde (III) hergestellt, die anschließend gemäß Schema in die cis‐β‐Lactame (VIII) übergeführt werden.
ChemInform Abstract: A Lymphotropic Prodrug of L‐Dopa: Synthesis, Pharmacological Properties and Pharmacokinetic Behavior of 1,3‐Dihexadecanoyl‐2‐[(S)‐2‐amino‐3‐ (3,4‐dihydroxyphenyl)propanoyl]propane‐1,2,3‐triol.
Authors: GARZON‐ABURBEH A. , POUPAERT J. H. , CLAESEN M. , DUMONT P. 
Published: May 2016

AbstractDer ausgehend von geschütztem L‐Dopa (I) hergestellte Ester (III) zeigt anti‐Parkinson‐Aktivität (längere Wirkungsdauer als L‐Dopa).
ChemInform Abstract: High‐Pressure Transformation Toughening: A Case Study on Zirconia.
Authors: BLOCK S. , PIERMARINI G. J. , HOCKEY B. J. , LAWN B. R. , MUNRO R. G. 
Published: May 2016

AbstractTransformation‐toughened zirconia compacts have been produced using a pressure‐induced phase of zirconia as the toughening agent.
ChemInform Abstract: Thermoelectrical and Photochemical Properties of 2,5‐Distyrylpyrazine (DSP) and Azodiisobutyronitrile (AIBN) Single Crystals.
Authors: ABOU‐SEKKINA M. M. 
Published: May 2016

Abstractα‐DSP crystals show semiconductivity with a positive activation energy for DC‐electrical conduction, E3 = 0.86 eV.
ChemInform Abstract: Photosensitized NAD(P)H Regeneration Systems; Application in the Reduction of Butan‐2‐one, Pyruvic, and Acetoacetic Acids and in the Reductive Amination of Pyruvic and Oxoglutaric Acid to Amino Acid.
Authors: MANDLER D. , WILLNER I. 
Published: May 2016

AbstractThe two photosensitized enzymatic systems, producing NADPH or NADH, contain Ru(II)‐trisbipyridine (Ru(bpy)%+ ) or Zn(ID‐meso‐tetramethylpyridiniumporphyrin (ZnTMPyPH) as sensitizer, methyl viologen (MVH) as primary electron acceptor, and the electron‐ donors (NH4)3‐ethylenediaminetetra‐acetic acid or 2‐mercaptoethanol.
ChemInform Abstract: The Reduction of Trifluoroacetophenone by Methy1‐Substituted Dihydronicotinamides.
Authors: BOSSAERTS J. , DOMMISSE R. , ALDERWEIRELDT F. 
Published: May 2016

AbstractDie Reduktion des Trifluoracetophenons (I) durch die Dihydronicotinamide (II) unter Bildung des Carbinols (III) und der Pyridiniumalze (IV) wird kinetisch untersucht.
ChemInform Abstract: 2‐Allylisourea as an Effective Agent for Direct α‐Allylation of Ketone and Aldehyde Assisted by Palladium(0) Under Neutral Conditions.
Authors: INOUE Y. , TOYOFUKU M. , TAGUCHI M. , OKADA S. , HASHIMOTO H. 
Published: May 2016

AbstractScope and limitations of the title reaction are studied.
ChemInform Abstract: Stereoselectivity in the Synthesis of Enol Esters from Chloromercurio Aldehydes and Acyl Chlorides.
Authors: FUKUDA W. , SATO H. , KAKIUCHI H. 
Published: May 2016

AbstractThe enol acetates (III) and (X), serving as the starting materials in this study, are prepared by treating the aldehydes (I) and (IX) with either (II) or (XIII) [yield of (IIIb) via the latter procedure: 33%, Z:Eratio = 65:35].