bluuebunny/crossref_metadata_2025_split huggingface dataset:
Continuous body emotion recognition system during theater performances
Authors: Senecal Simon , Cuel Louis , Aristidou Andreas , Magnenat‐Thalmann Nadia 
Published: May 2016

AbstractUnderstanding emotional human behavior in its multimodal and continuous aspect is necessary for studying human machine interaction and creating constituent social agents. As a first step, we propose a system for continuous emotional behavior recognition expressed by people during communication based on their gesture and their whole body dynamical motion. The features used to classify the motion are inspired by the Laban Movement Analysis entities and are mapped onto the well‐known Russell Circumplex Model . We choose a specific case study that corresponds to an ideal case of multimodal behavior that emphasizes the body motion expression: theater performance. Using a trained neural network and annotated data, our system is able to describe the motion behavior as trajectories on the Russell Circumplex Model diagram during theater performances over time. This work contributes to the understanding of human behavior and expression and is a first step through a complete continuous emotion recognition system whose next step will be adding facial expressions. Copyright © 2016 John Wiley & Sons, Ltd.
Asymmetric Total Synthesis of Heronamides A–C: Stereochemical Confirmation and Impact of Long‐Range Stereochemical Communication on the Biological Activity
Authors: Kanoh Naoki , Itoh Shunya , Fujita Kohei , Sakanishi Kohei , Sugiyama Ryosuke , Terajima Yuta , Iwabuchi Yoshiharu , Nishimura Shinichi , Kakeya Hideaki 
Published: May 2016

AbstractHeronamides are biosynthetically related metabolites isolated from marine‐derived actinomycetes. Heronamide C shows potent antifungal activity by targeting membrane phospholipids possessing saturated hydrocarbon chains with as‐yet‐unrevealed modes of action. In spite of their curious hypothesized biosynthesis and fascinating biological activities, there have been conflicts in regard to the reported stereochemistries of heronamides. Here, we describe the asymmetric total synthesis of the originally proposed and revised structures of heronamide C, which unambiguously confirmed the chemical structure of this molecule. We also demonstrated nonenzymatic synthesis of heronamides A and B from heronamide C, which not only proved the postulated biosynthesis, but also confirmed the correct structures of heronamides A and B. Investigation of the structure–activity relationship of synthetic and natural heronamides revealed the importance of both long‐range stereochemical communication and the 20‐membered macrolactam ring for the biological activity of these compounds.
The Total Synthesis of Starfish Ganglioside GP3 Bearing a Unique Sialyl Glycan Architecture
Authors: Goto Kenta , Sawa Maki , Tamai Hideki , Imamura Akihiro , Ando Hiromune , Ishida Hideharu , Kiso Makoto 
Published: May 2016

AbstractThe total synthesis of ganglioside GP3, which is found in the starfish Asterina pectinifera, has been accomplished through stereoselective and effective glycosylation reactions. The sialic acid embedded octasaccharide moiety of the target compound was constructed by [4+4] convergent coupling. A tetrasaccharyl donor and acceptor that contained internal sialic acid residues were synthesized with an orthogonally protected N‐Troc sialic acid donor as the key common synthetic unit, and they underwent highly stereoselective glycosidation. The resulting sialosides were subsequently transformed into reactive glycosyl acceptors. [4+4] coupling furnished the octasaccharide framework in 91 % yield as a single stereoisomer. Final conjugation of the octasaccharyl donor and glucosyl ceramide acceptor produced the protected target compound in high yield, which underwent global deprotection to successfully deliver ganglioside GP3.
ChemInform Abstract: The Development of the Corrosion Resistance of an Fe ‐ Zn Alloy Coating on the Basis of the Behaviour of the Corrosion Product.
Authors: SUZUKI I. , ENJUZI M. 
Published: May 2016

AbstractThe compactness of the corrosion layer is an important factor for the development of the corrosion resistance of a zinc alloy coating used in a salt environment.
ChemInform Abstract: Preparation of Highly Dispersed Cobalt Clusters in Zeolites via Microwave Discharge Methods.
Authors: ZERGER R. P. , MCMAHON K. C. , SELTZER M. D. , MICHEL R. G. , SUIB S. L. 
Published: May 2016

AbstractIt is shown that the microwave discharge approach offers several advantages over other activation procedures for the prepaäation of small metal particles on solid Supports.
ChemInform Abstract: Substitution of 2‐(Sulfonyloxy)carboxylates with Oxygen and Sulfur Nucleophiles Without Racemization.
Authors: BURKARD U. , EFFENBERGER F. 
Published: May 2016

AbstractThe sulfonates(I) react with the phenolates formed from (II) or (IV) and with carboxylates (VI) to give the respective aryloxy‐ (III), (V) or acyloxypropionates (VII) with inversion of configuration.
ChemInform Abstract: Hydrosilylation, Hydrogermylation and Hydrostannylation of 1‐Alkenylsilatranes.
Authors: VORONKOV M. G. , ADAMOVICH S. N. , KUDYAKOV N. M. , KHRAMTSOVA S. YU. , RAKHLIN V. I. 
Published: May 2016

AbstractDie olefinische Doppelbindung der Silatrane (I) läßt sich in Gegenwart des Rhodiumcarbonyl‐Komplexes (III) mit den Trialkylelementhydriden (II) zu den Trialkylsilyl‐, ‐germyl‐ bzw. ‐stannyl‐Derivaten (IV) hydrometallieren.
ChemInform Abstract: Methylenecyclopropane Rearrangement as a Probe for Free Radical Substituent Effects.
Authors: CREARY X. , MEHRSHEIKH‐MOHAMMADI M. E. 
Published: May 2016

AbstractAus den Benzylchloriden bzw. den Aryldiazomethanen (I) werden über die Carbene (II) mit 1,1‐Dimethyl‐allen (III) die Addukte (IV) neben geringeren Anteilen der Isomeren (V) gebildet.
ChemInform Abstract: Chemically Modified Potassium Hydride. Significant Improvement in Yields in Some Oxy‐Cope Rearrangements.
Authors: MACDONALD T. L. , NATALIE K. J. JUN. , PRASAD G. , SAWYER J. S. 
Published: May 2016

AbstractKaliumhydrid in Kombination mit Iod wird zur Oxy‐Cope‐Umlagerung des Divinylcyclohexenols (I) eingesetzt.
ChemInform Abstract: Regioselectivity of Pyridine Ring Migration During Triplet‐Sensitized Di‐n‐methane Photorearrangements of 5,8‐Dihydro‐5,8‐methanoisoquinoline Derivatives.
Authors: PAQUETTE L. A. , COGHLAN M. J. , COTTRELL C. E. , IRIE T. , TANIDA H. 
Published: May 2016

AbstractAus den Chlor‐pyrido‐norbornenen (I) entstehen die Norbornadiene (II).
ChemInform Abstract: Reaction of Hypochloric Acid with 2,6‐Di‐tert‐butylphenol and Its Derivatives.
Authors: BANNIKOV G. F. , VOL'EVA V. B. , NIKIFOROV G. A. 
Published: May 2016

AbstractWährend die Chlorierung von 2,6‐Di‐tert.‐butylphenol (I) mit Hypochlorit zum p‐ Chlorphenol (II) führt, liefern die in p‐Stellung substituierten Derivate (III), (V) und (VII) je nach Art des Substituenten das p‐Chinonderivat (IV) oder die o‐Chinonderivate (VI) biw.
ChemInform Abstract: Some Observation on N‐Chlorosuccinimide Halogenations. A New Bromination Technique.
Authors: WALLING C. , EL‐TALIAWI G. M. , SOPCHIK A. 
Published: May 2016

AbstractDie Photolyse eines Gemisches von Brz, NCS und CH2Cl2 wird ausführlich untersucht.
ChemInform Abstract: Homogeneous, Palladium‐Catalyzed, Selective Hydrogenolysis of Organohalides.
Authors: PRI‐BAR I. , BUCHMAN O. 
Published: May 2016

AbstractAromatische Brom‐ und Iodverbindungen (I) werden mit Polymethylhydrosiloxanen (II) in Gegenwart des Pd‐Katalysators (III) zu (IV) dehalogeniert; analog (I) werden die Halogenverbindungen (V), (VII), (IX) und (XI) beispielhaft aufgeführt.
ChemInform Abstract: Stereoselective Reactions. Part 11. Asymmetrie Alkylation of Cyclohexanone via Chiral Chelated Lithioenamines Derived from D‐Camphor Derivatives.
Authors: IKOTA N. , SAKAI H. , SHIBATA H. , KOGA K. 
Published: May 2016

AbstractDie asymmetrische Alkylierung der chiralen Cyclohexanonimine (IX) verläuft mit hoher Stereoselektivität und führt zu den 2‐Alkylcyclohexanonen (X) (e.e.
ChemInform Abstract: Cross‐Coupling of Magnesium Diacetylides with Functional Allylic and Haloid‐Containing Compounds Catalyzed by Transition Metal Complexes.
Authors: DZHEMILEV U. M. , IBRAGIMOV A. G. , SARAEV R. A. 
Published: May 2016

AbstractEnine vom Typ (IV) lassen sich in hohen Ausbeuten aus dem Magnesiumdiacetylid (Ic) und den Allylverbindungen (II) unter Katalyse verschiedener Übergangsmetallacetylacetonide wie (III) darstellen.
ChemInform Abstract: Synthesis of 1‐Alkylthio‐3‐allylthio‐1‐propenes by Reaction of Diallyl Disulphide with Alkyl Halides in the Superbasic System Alkali Metal Hydroxide‐DMSO.
Authors: AMOSOVA S. V. , NOSYREVA V. V. , MUSORIN G. K. , SIGALOV M. V. , SINEGOVSKAYA L. M. , TROFIMOV B. A. 
Published: May 2016

AbstractThe reaction between the diallyl disulphide (I) and the alkyl halides (II) in KOH/ DMSO affords the 1‐alkylthio‐3‐allylthiopropenes (IIIa)‐(IIIc) as the main products.
ChemInform Abstract: Synthesis of a Dicyclopenta[a,e]pentalene via [6 + 2] Cycloaddition of 1,3‐Di‐tert‐butyl‐5‐vinylidenecyclopentadiene and Consecutive 8π‐Electrocyclic Reaction.
Authors: STOWASSER B. , HAFNER K. 
Published: May 2016

AbstractThe title compound (V) is synthesized via dimerization of the "pentafulveneallene" (II), followed by dehydrogenation, which subsequently affords an acid‐catalyzed tautomerization.
ChemInform Abstract: 3,4‐Dihydro‐2‐arylidene‐1(2H)‐naphthalenones and Their Inhibition of Platelet Aggregation: Synthesis, Pharmacological Evaluation and Structure.
Authors: VARACHE‐BERANGER M. , NUHRICH A. , DEVAUX G. , H'NAIFI A. , CARPY A. 
Published: May 2016

Abstractα‐Tetralon (I) kondensiert mit Benzaldehyden (II) zu den Naphthalenonen (III), deren Kristallstruktur ermittelt wird.
ChemInform Abstract: Synthesis and Isomerization of 2,2′‐Di(N‐aryl‐1,4‐naphthoquinonylimines).
Authors: EKTOVA L. V. , SHISHKINA R. P. , FOKIN E. P. 
Published: May 2016

AbstractThe naphthoquinone monoximes (I) are converted to the dimers (II) by dehydrogenation in alkaline solution.
ChemInform Abstract: Derivatives of 1,2,3,3‐Tetramethyl‐2‐azabicyclo[2.2.2]octan‐5‐trans‐ol with Antiarrhythmic and Other Activities.
Authors: LONGOBARDI M. , BARGAGNA A. , SCHENONE P. , FILIPPELLI A. , TORTORA G. , MARRAZZO R. , MARMO E. 
Published: May 2016

AbstractReduktion des Amids (I) und folgende Acylierung führen zu den Amiden (III).
ChemInform Abstract: Synthesis of 1,2,4‐Benzothiadiazines via Readily Generated Iminium Ions.
Authors: ALO B. I. , ADEGOKE E. A. , LIGALI‐ALI M. , ADESOGAN E. K. 
Published: May 2016

AbstractThe acid chlorides (III) react instantaneously with silver trifluoromethanesulphonate to give the iminium salts (IVa)‐(IVc).
ChemInform Abstract: Dioxides of C‐Amino‐substituted Phosphaalkenes and Phosphaallylic Cations.
Authors: SCHMIDPETER A. , ZIRZOW K.‐H. , WILLHALM A. , HOLMES J. M. , DAY R. O. , HOLMES R. R. 
Published: May 2016

AbstractOn oxidation with ozone the electron‐rich phosphaalkene (I) takes up two equiv. of oxygen smoothly and selectively yielding directly the zwitterionic amidiniophosphinate (II) which is characterized by 13C NMR data.
ChemInform Abstract: Chemistry of Phosphorus. Part 165. P6tBu4O and P7tBu5O ‐ the First Polycyclophosphane Oxides.
Authors: BAUDLER M. , MICHELS M. , PIEROTH M. , HAHN J. 
Published: May 2016

AbstractIn the oxidation of the polycyclophosphanes P6tBu4 and P7tBu5 in benzene with dry air, oxygen is bound exocyclically and is not inserted into the P‐P bonds.
ChemInform Abstract: New Carbide Clusters in the Cobalt Subgroup. Part 16. Preparation and Structural Characterization of μ6‐Carbido‐penta‐μ‐carbonyl‐octacarbonyl‐octahedro‐hexacobaltate(2‐) as its Tetraethylammonium Salt.
Authors: ALBANO V. G. , BRAGA D. , MARTINENGO S. 
Published: May 2016

AbstractThe new anion (II) is prepared by refluxing a solution of (I) in THF under nitrogen.
ChemInform Abstract: Unusual Behavior of the Stable Paramagnetic Dihydridoiridium(IV) Complex Ir(H)2(Cl)2(iPr3P)2 in Solution.
Authors: MURA P. , SEGRE A. 
Published: May 2016

AbstractAtemp.‐dependent equilibrium between the paramagnetic Ir(IV) species (Ia) and the diamagnetic Ir(III) species (Ib) in solution is deduced from the surprisingly sharp ′Hand 31P NMR spectra of the title compound.
ChemInform Abstract: Synthetic Studies Relating to the Structure of Senoxydene. A Sequential Annulation Approach to Angular Triquinane Construction Capable of Varied Tetramethyl Substitution Patterns.
Authors: PAQUETTE L. A. , GALEMMO R. A. JUN. , CAILLE J.‐C. , VALPEY R. S. 
Published: May 2016

AbstractEs werden vollständig sterisch kontrollierte Synthesewege beschrieben, um zum Sesquiterpen Senoxyden zu gelangen.
ChemInform Abstract: Rearrangement of Isoindolo[1,2‐b][3]henzazepinium to Dibenzo[a,g]quinolizinium Ions: Application to the Total Synthesis of (±)‐Tetrahydropalmatine.
Authors: NAPOLITANO E. , FIASCHI R. , SCARTONI V. , MARSILI A. 
Published: May 2016

AbstractThe synthesis of the title compöund (IX) is described.
ChemInform Abstract: Synthetic Studies of Erythromycins. Part 2. Enantiospecific Synthesis of a C‐10‐C‐13 Segment of Erythronolide A from D‐Ribose. Synthetic Studies of Erythromycins. Part 3. Total Synthesis of Erythronolide A Through (9S)‐9‐Dihydroerythronolide A.
Authors: KINOSHITA M. , ARAI M. , TOMOOKA K. , NAKATA M. , OHSAWA N. 
Published: May 2016

AbstractDie Synthese von Erythronolid A (VI) wird, ausgehend von den Komponenten (III)‐(V), beschrieben.
ChemInform Abstract: Total Synthesis of 20‐Hydroxy‐ and 20‐Carboxy‐leukotrienes B4.
Authors: NICOLAOU K. C. , CHUNG Y. S. , HERNANDEZ P. F. , TAFFER I. M. , ZIPKIN R. E. 
Published: May 2016

AbstractDie Synthese von 20‐Hydroxy‐ (Ia) und 20‐Carboxy‐leukotrienen (Ib) als Metaboliten von Leukotrien B4 wird untersucht.
ChemInform Abstract: Mößbauer Spectra at 77 K of Products Formed During Transformation of Fe(OH)2 to Fe3O4 in Aqueous suspension by Air Oxidation.
Authors: KANZAKI T. , KATSURA T. 
Published: May 2016

AbstractIt is shown that after oxidation of an aqueous Fe(II) hydroxide suspension at pH 9 Fe(OH)2 and Fe3O4 are present.
ChemInform Abstract: Kinetics and Mechanism of the Reduction of Dodecatungstocobaltate(III) by Oxalate.
Authors: SAHA S. K. , GHOSH M. C. , BANERJEE P. 
Published: May 2016

AbstractBoth the second‐order rate constants k, and k; (see scheme) depend on the concentration and type of cation present; k, and k; decrease in the order K+ Na+ w Li+ and K+ Na+ Li", respectively.
ChemInform Abstract: Reduction of Nitric Oxide by Hydroxylamine. Part 1. Kinetics and Mechanism.
Authors: BONNER F. T. , WANG N.‐Y. 
Published: May 2016

AbstractThe results of kinetic measurements of the reaction A in the pH range 7.29‐ 13.14 confirm the rate‐determining abstraction o′f an N‐bound H atom by NO (reaction B).
ChemInform Abstract: Photoinduced Oxidation of Bromide to Bromine on Irradiated Platinized TiO2 Powders and Platinized TiO2 Particles Supported in Nafion Films.
Authors: DABESTANI R. , WANG X. , BARD A. J. , CAMPION A. , FOX M. A. , WEBBER S. E. , WHITE J. M. 
Published: May 2016

AbstractIt is demonstrated that the high quantum efficiency for photoelectrochemical oxidation of Br" in O2‐saturated solutions on Pt/TiO2 (in the presence of As(III) added as Br2 scavenger) is, in large part, the result of direct oxidation of As(III) adsorbed on the Pt ‐ TiOZ surface.
ChemInform Abstract: Crystal and Molecular Structure of the Charge Transfer Salt of Decamethylferrocenium and Tricyanomethanide: [Fe(C5Me5)2]+ . [C(CN)3]‐.
Authors: DIXON D. A. , CALABRESE J. C. , MILLER J. S. 
Published: May 2016

AbstractThe reaction of decamethylferrocenium tetraf1uoroborate and potassium tricyanomethanide in MeCN leads to the isolation of the title complex salt (15% yield), which crystallizes in the space group Pma2 with Z=8.
ChemInform Abstract: Reaction of Tropone Hydrazones with Heterocumulenes such as Isocyanate, Ketene, and Sulfene.
Authors: KAJIGAESHI S. , MATSUOKA S. , KANEMASA S. , NOGUCHI M. 
Published: May 2016

AbstractAus den Troponhydrazonen (Ia) und (Ib) erhält man mit den Isocyanaten (II) die Imidazolinone (III), aus (Ib) und Methylisocyanat (IV) entsteht das Acylierungsprodukt (V).
ChemInform Abstract: Quinone‐Amine Reactions. Part 19. Reactions between Di‐ or Trimethyl‐ 1,4‐benzoquinones and Desipramine/Protriptyline.
Authors: KALLMAYER H.‐J. , TAPPE C. 
Published: May 2016

AbstractDie Polymethyl‐p‐benzochinone (I) reagieren mit den sekundären Aminen (II) zu den Aminochinonen (III), die photochemisch zu Methylaminochinonen (IV) und den Aminochinonen (V) abgebaut werden.
ChemInform Abstract: Dye‐Sensitized Photooxygenation of 1,2‐Cyclopentanediones in Methanol.
Authors: UTAKA M. , NAKATANI M. , TAKEDA A. 
Published: May 2016

AbstractDie Oxidation der 1,2‐Cyclopentandione (I) mittels Singulett‐Sauerstoff liefert die Spaltprodukte (II) und (III) über diskutierte Zwischenstufen.
ChemInform Abstract: Chemoselective Oxidation of Secondary Hydroxy Functions Catalyzed by [PMo12O40]3‐[C5H5N+(CH2)15CH3]3.
Authors: YAMAWAKI K. , YOSHIDA T. , NISHIHARA H. , ISHII Y. , OGAWA M. 
Published: May 2016

AbstractDie sekundären Alkohole (I) werden durch tert.‐Butylhydroperoxid in Gegenwart des im Titel genannten Molybdän‐Komplexes MPCP in Benzol zu den Ketonen (II) oxidiert.
ChemInform Abstract: Lanthanides in Organic Synthesis. Part 2. Reduction of α‐Heterosubstituted Ketones.
Authors: MOLANDER G. A. , HAHN G. 
Published: May 2016

AbstractDie α‐heterosubstituierten Ketone (I) werden durch intermediär hergestelltes Samarium(II)‐iodid zu den entsprechenden unsubstituierten Ketonen (II) reduziert.
ChemInform Abstract: Reaction of Hexafluoroisobutene with Hydrogen Peroxide/Ferrous Sulfate/ Methanol.
Authors: MISAKI S. , TAKII K. 
Published: May 2016

AbstractDie im Titel genannte Verbindung (I) reagiert in Methanol mit Cyclohexanonperoxid, das in situ aus Cyclohexanon und H2O2 hergestellt wird, in Gegenwart von Eisen(II)‐sulfat zum Methylester (II).
ChemInform Abstract: On the Relation between Ring Size and Geometry of 2‐Bromo‐2‐cycloalkenyl Acetates Formed from Dibromobicyclo[n.1.0]alkanes by Silver Acetate Catalyzed Reactions.
Authors: ITO S. , ZIFFER H. , BAX A. 
Published: May 2016

AbstractDie Reaktion der gem‐Dibrom‐bicycloalkane (I) zu den trans‐ bzw. cis‐ Cycloole?‐ nen (II) und (III) in Abhängigkeit von der Ringgröße wird diskutiert.
ChemInform Abstract: Stereochemistry of Substituted Glutaric Acids. Part 2. Syntheses of Substituted 3‐(4‐Fluorophenyl)glutaric Acids.
Authors: JAUNICH S. , FRAHM A. W. 
Published: May 2016

AbstractDer aus dem Phosphorylid (I) und Fluorbenzaldehyd (II) zugängliche Fluorzimtsäureester (III) addiert Dimethylmalonat (IV) zum Diastereomerengemisch der Tricarbonsäureester (V) und (VI).
ChemInform Abstract: 1H‐NMR Study of Two Tetradehydrocyclodecabiphenylenes.
Authors: WILCOX C. F. JUN. , WEBER K. A. 
Published: May 2016

AbstractAus dem Bisphosphoniumsalz (I) wird das Bis‐ylid (II) hergestellt, das mit den Dialdehyden (III) zu den Makrocyclen (IV) kondensiert wird.
ChemInform Abstract: Synthesis and Antiinflammatory Activity of 4‐Benzoyloxymethylenepyrazoles.
Authors: MAKHSUMOV A. G. , ZAKIROV U. B. , TALIPOVA M. A. , NIKBAEV A. T. , DZHURAEV A. D. 
Published: May 2016

AbstractDie Benzoesäurepropinylester (I) werden mit Diazomethan zu Pyrazolen (II) cyclisiert.
ChemInform Abstract: Benzoxazolinonic Phenylethanolamine Antagonists of Adrenergic Receptors.
Authors: VACCHER M. P. , LESIEUR D. , LESPAGNOL C. , BONTE J. P. , LAMAR J. C. , BEAUGHARD M. , DURENG G. 
Published: May 2016

AbstractBenzoxazolinone (I) werden mit α‐Bromcarbonsäuren (II) zu den Bromketonen (III) umgesetzt.
ChemInform Abstract: 2‐Cyano‐5‐[(β‐trans‐4‐alkylcyclohexyl)ethyl]pyridines.
Authors: PAVLYUCHENKO A. I. , KOROTKOVA N. I. , SMIRNOVA N. I. , KOVSHEV E. I. , SERGEEVA N. D. , TITOV V. V. 
Published: May 2016

AbstractThe title compounds (VIII) are prepared.
ChemInform Abstract: Synthesis of a Dithia‐18‐crown‐6‐tetracarboxylic Acid.
Authors: ANANTANARAYAN A. , DUTTON P. J. , FYLES T. M. , PITRE M. J. 
Published: May 2016

AbstractAus dem optisch aktiven Weinsäurediamid (Ia) werden in üblicher Weise die Derivate (Ib)‐(Ig) hergestellt.
ChemInform Abstract: Cyclopropane Derivatives Through Charge Directed Conjugate Addition Reactions of Unsaturated Acylphosphoranes.
Authors: COOKE M. P. JUN. , JAW J. Y. 
Published: May 2016

AbstractDer Phosphoranyl‐phosphonsäurediethylester (I) liefert nach Metallierung mit Chloracetaldehyd (II) das Chlormethyl‐ole?n (III), das mit Organo‐Lithiumverbindungen (IV) in guten Ausbeuten zu den Cyclopropanen (V) cyclisiert wird.
ChemInform Abstract: Reactions of Acetylenic Ketones with Phosphites and Aminophosphites in the Presence of Protic Trapping Reagents.
Authors: EL MANOUNI D. , LEROUX Y. , BURGADA R. 
Published: May 2016

AbstractThe reactions of the acetylenic ketones (I), (XX) and (XXIII) with the phosphorus Compounds (II), (XIV), (XIX) and (XXI) in the presence of the trapping reagents (III), (VII) and (X) are investigated.
ChemInform Abstract: Regio‐ and Stereoselective Synthesis of Trisubstituted Vinylstannanes.
Authors: CHU K.‐H. , WANG K. K. 
Published: May 2016

AbstractTriethylbor (I), Li‐acetylide (II) und Trimethylstannylchlorid (IV) reagieren zu den Addukten (V), die nach Metallierung zu den Vinyl‐Zinn‐ Verbindungen (VII) substituiert werden können.
ChemInform Abstract: Mechanisms of Hemin‐Catalyzed Alkene Epoxidation. The Effect of Catalyst on the Regiochemistry of Epoxidation.
Authors: TRAYLOR T. G. , NAKANO T. , DUNLAP B. E. , TRAYLOR P. S. , DOLPHIN D. 
Published: May 2016

AbstractPossible mechanistic pathways for the catalytic epoxidation are discussed.
ChemInform Abstract: Synthesis, Spectroscopy, and X‐Ray Structure of Os2Cl(chp)4: An Unusual Os25+ Complex with a Polar Arrangement of 6‐Chloro‐2‐hydroxypyridinato Ligands and One Axial Chloride.
Authors: COTTON F. A. , DUNBAR K. R. , MATUSZ M. 
Published: May 2016

AbstractThe title compound (I) is prepared by the melt reaction of Os2Cl2(OAc)4 with an excess of the title ligand at 145°C. It is characterized by X‐ ray structural analysis of (I) ‐ 2 MeZCO (space group PT, Z=2), by IR, UV‐VIS, and ESR spectroscopy, magnetic measurements, and cyclic voltamme?try.
ChemInform Abstract: Synthesis, Structures, and Nonrigidity of Heterotrimetallic Alkyne Clusters of the Type CpNiCoM(CO)6(C2RR′) (M: Fe, Ru, 0s).
Authors: EINSTEIN F. W. B. , TYERS K. G. , TRACEY A. S. , SUTTON D. 
Published: May 2016

AbstractThe preparation of the title complexes (III) and (VI) and the derivative (IV) is described.
ChemInform Abstract: Syntheses with the Aid of Sulfones. Part 37. Synthesis of Three Pheromones with a Z Double Bond: (Z)‐8‐DDA (IVa), (Z)‐9‐DDA (IVb) and (Z)‐9‐TDA (IVc).
Authors: JULIA M. , STACINO J.‐P. 
Published: May 2016

AbstractThe title compounds (IVa) (pheromone of Grapholitha species), (IVb) (Paralobaesia viteana) and (IVc) (Spodoptera species) are available in a pure state ( 99%) following the procedure shown in the scheme.
ChemInform Abstract: Structural, Thermal, and Electrical Properties Indicating Covalent Bonding in Mg2NiH4.
Authors: NOREUS D. , JANSSON K. , NYGREN M. 
Published: May 2016

AbstractDSC studies of the phase transition from a low temp. to a high temp. modification of Mg2NiH4 show the presence of microtwinning to increase the kinetics of the phase transition.
ChemInform Abstract: EPR Study of the Formation of Ni+ Ions by Photoreduction in Hydrogen of Ni / Al2O3 Catalysts.
Authors: BONNEVIOT L. , CHE M. , DYREK K. , SCHOELLNER R. + , WENDT G. 
Published: May 2016

AbstractNi+ species can be stabilized on alumina by reduction in H2 at 77 K under UV irradiation and their concentration depends mainly on the pretreatment temperature.
ChemInform Abstract: Kinetics of Hydrogen Production from Illuminated CdS/Pt/Na2s Dispersions.
Authors: FURLONG D. N. , GRIESER F. , HAYES D. , HAYES R. , SASSE W. , WELLS D. 
Published: May 2016

AbstractStudies of the H2 production upon illumination of transparent CdS/Pt/ Na2S dispersions over the complete life of the catalyst as a function of the initial concentration of Na2S indicate that the observed decline in H2 production results from the depletion of the electron donor (Na2S) and the deactivation of the catalysts (poisoning).