bluuebunny/crossref_metadata_2025_split huggingface dataset:
Parent, Unsubstituted Hemiporphycene: Synthesis and Properties
Authors: Ostapko Jakub , Nawara Krzysztof , Kijak Michał , Buczyńska Joanna , Leśniewska Barbara , Pietrzak Mariusz , Orzanowska Grażyna , Waluk Jacek 
Published: October 2016

AbstractAmong seven possible nitrogen‐in constitutional isomers of porphyrin only one, porphycene, has been obtained so far in the free, unsubstituted form. Herein, the synthesis of another isomer, parent hemiporphycene (HPc), and its thorough structural, spectral, photophysical, electrochemical, and theoretical characterization are reported. Most of the properties of HPc are intermediate between those of porphyrin and porphycene, as evidenced by the values of inner‐cavity dimensions, orbital‐energy splittings, absorption coefficients, magnetic circular dichroism parameters, NH‐stretching frequencies, fluorescence quantum yields, tautomerization rates, and redox potentials. The largest differences arise with respect to tautomerism, due to the low symmetry of HPc and inequivalence of the four nitrogen atoms that define the inner cavity. Two trans tautomers are observed, separated in energy by about 1 kcal mol−1. Tautomerization from the higher‐ to the lower‐energy form is detected in the lowest‐excited singlet state and occurs at a rate that is about four orders of magnitude lower than that observed for porphycene. Hemiporphycene is a very good model for the investigation of inequivalent intramolecular H‐bonds present in one molecule; two such bonds in HPc reveal unusual characteristics, and the bond strength results from the interplay between the N⋅⋅⋅N distance and the N−H−N angle.
Oxygenation Chemistry of Magnesium Alkyls Incorporating β‐Diketiminate Ligands Revisited
Authors: Pietrzak Tomasz , Kubisiak Marcin , Justyniak Iwona , Zelga Karolina , Bojarski Emil , Tratkiewicz Ewa , Ochal Zbigniew , Lewiński Janusz 
Published: October 2016

AbstractDespite the fact that extensive research has been carried out, the oxygenation of alkyl magnesium species still remains a highly unexplored research area and significant uncertainties concerning the mechanism of these reactions and the composition of the resulting products persist. This case study compares the viability of the controlled oxygenation of alkylmagnesium complexes supported by β‐diketiminates. The structural tracking of the reactivity of (N,N)MgR‐type complexes towards O2 at low temperature showed that their oxygenation led exclusively to the formation of magnesium alkylperoxides (N,N)MgOOR. The results also highlight significant differences in the stability of the resulting alkylperoxides in solution and demonstrate that [(BDI)Mg(μ‐η2:η1‐OOBn)]2 (in which BDI=[(ArNCMe)2CH]− and Ar=C6H3iPr2‐2,6) can be easily transformed to the corresponding magnesium alkoxide [(BDI)MgOBn]2 at ambient temperature, whilst [(F3BDI)Mg(μ‐OOtBu)]2 (in which F3BDI=[(ArNCMe)2CH]− and Ar=C6H2F3‐2,4,6) is stable under similar conditions. The observed selective oxygenation of (N,N)MgR‐type complexes to the corresponding (N,N)MgOOR alkylperoxides strongly contradicts the widely accepted radical‐chain mechanism for the oxygenation of the main‐group‐metal alkyls. Furthermore, either the observed transformation of the alkylperoxide [(BDI)MgOOBn]2 to the alkoxide [(BDI)MgOBn]2 as well as the formation of an intractable mixture of products in the control reaction between the alkylperoxide [(F3BDI)MgOOtBu]2 and the parent alkylmagnesium [(F3BDI)MgtBu] complex are not in line with the common wisdom that magnesium alkoxide complexes’ formation results from the metathesis reaction between MgOOR and Mg−R species. In addition, a high catalytic activity of well‐defined magnesium alkylperoxides, in combination with tert‐butyl hydroperoxide (TBHP) as an oxygen source, in the epoxidation of trans‐chalcone is presented.
Layered Structural Co‐Based MOF with Conductive Network Frames as a New Supercapacitor Electrode
Authors: Yang Jie , Ma Zhihua , Gao Weixue , Wei Mingdeng 
Published: October 2016

AbstractLayered structural Co‐MOF nanosheets were synthesized and then used as an electrode material for supercapacitors for the first time. This material exhibited a high specific capacitance, a good rate capability, and an excellent cycling stability. A maximum capacitance of 2564 F g−1 can be achieved at a current density of 1 Ag−1. Moreover, the capacitance retention can be kept at 95.8 % respectively of its initial value after 3000 cycles. To the best of our knowledge, both the specific capacitance and the capacitance retention were the highest values reported for MOF materials as supercapacitor electrodes until now. Such a high supercapacitive performance might be attributed to the intrinsic characteristics of this kind of Co‐MOF material, including its layered structure, conductive network frame, and thin nanosheet.
Emulating Natural Product Conformation by Cooperative, Non‐Covalent Fluorine Interactions
Authors: Scheidt Felix , Selter Philipp , Santschi Nico , Holland Mareike C. , Dudenko Dmytro V. , Daniliuc Constantin , Mück‐Lichtenfeld Christian , Hansen Michael Ryan , Gilmour Ryan 
Published: October 2016

AbstractPervasive in Nature, the propane unit is an essential component of numerous bioactive molecules. These range from acyclic systems, such as the neurotransmitter γ‐aminobutyric acid, through to the bicyclic nuclei of various chromanes and dihydrobenzofurans. In the latter case, cyclisation via cyclic ether formation ensures a highly pre‐organised structure, whilst linear scaffolds display more dynamic conformational behaviour resulting from rotation about the two internal C(sp3)–C(sp3) bonds. In this study, the replacement of ‐[CH2]‐ units by ‐[CHF]‐ centres is evaluated as a strategy to achieve acyclic conformational control by hindering these internal rotations. Reinforcing, non‐covalent fluorine interactions are validated as powerful design features that result in programmable conformational behaviours: These are encoded by the relative configuration of each centre. By exploiting cooperative neighbouring stereoelectronic effects in a multi‐vicinal fluoroalkane it is possible to emulate the overall conformation of the dihydrobenzofuran scaffold found in a variety of natural products with an acyclic mimic. This is described as a function of two bond vectors at the chain termini and validated by combined theoretical, crystallographic and spectroscopic analyses. In view of the favourable physicochemical properties associated with fluorine introduction, this approach to bioactive scaffold design may prove to be expansive.
Isomerization of Keggin Al13 Ions Followed by Diffusion Rates
Authors: Oliveri Anna F. , Colla Christopher A. , Perkins Cory K. , Akhavantabib Noushin , Callahan Joseph R. , Pilgrim Corey D. , Smart Scott E. , Cheong Paul H.‐Y. , Pan Long , Casey William H. 
Published: October 2016

AbstractThe solution chemistry of aluminum has long interested scientists due to its relevance to materials chemistry and geochemistry. The dynamic behavior of large aluminum–oxo‐hydroxo clusters, specifically [Al13O4(OH)24(H2O)12]7+ (Al13), is the focus of this paper. 27Al NMR, 1H NMR, and 1H DOSY techniques were used to follow the isomerization of the ϵ‐Al13 in the presence of glycine and Ca2+ at 90 °C. Although the conversion of ϵ‐Al13 to new clusters and/or Baker–Figgis–Keggin isomers has been studied previously, new 1H NMR and 1H DOSY analyses provided information about the role of glycine, the ligated intermediates, and the mechanism of isomerization. New 1H NMR data suggest that glycine plays a critical role in the isomerization. Surprisingly, glycine does not bind to Al30 clusters, which were previously proposed as an intermediate in the isomerization. Additionally, a highly symmetric tetrahedral signal (δ=72 ppm) appeared during the isomerization process, which evidence suggests corresponds to the long‐sought α‐Al13 isomer in solution.
ChemInform Abstract: EuAu3Al2: Crystal and Electronic Structures and Spectroscopic, Magnetic, and Magnetocaloric Properties.
Authors: Schmiegel Jan‐Patrick , Block Theresa , Gerke Birgit , Fickenscher Thomas , Touzani Rachid St. , Fokwa Boniface P. T. , Janka Oliver 
Published: October 2016

AbstractThe title compound is synthesized from the elements (Ta ampule, 1300 K for 10 min and 825 K for 2—8 h) and characterized by single crystal XRD, Moessbauer spectroscopy, magnetic measurements, and DFT calculations.
ChemInform Abstract: Mechanistic Studies and Expansion of the Substrate Scope of Direct Enantioselective Alkynylation of α‐Ketiminoesters Catalyzed by Adaptable (Phebox)Rhodium(III) Complexes.
Authors: Morisaki Kazuhiro , Sawa Masanao , Yonesaki Ryohei , Morimoto Hiroyuki , Mashima Kazushi , Ohshima Takashi 
Published: October 2016

AbstractThe use of (trimethylsilylethynyl)rhodium(III) complexes as catalysts significantly improves the catalysis of the reaction of α‐ketiminoesters (I) and related substrates (IV) and (VI) with terminal alkynes to yield products with quarternary stereocenters with good yields and enantioselectivities.
ChemInform Abstract: The Development of New Amine—Amide Ligands for Application in Cu(II)‐Catalyzed Enantioselective Henry Reactions.
Authors: Ao Chunyan , Men Jian , Wang Yang , Shao Tao , Huang Yuanyuan , Huo Junji , Gao Guowei 
Published: October 2016

AbstractCombined with Cu(II) acetate, novel BINOL‐derived chiral tertiary amine ligands are developed as catalysts for the asymmetric Henry reaction of aromatic, heteroaromatic, and aliphatic aldehyde substrates.
ChemInform Abstract: Synthesis of β‐Phthalimido‐Alcohols via Regioselective Ring Opening of Epoxide by Using Reusable Basic Magnetic Nano Particles and Their Biological Investigation.
Authors: Zolfigol Mohammad Ali , Moosavi‐Zare Ahmad Reza , Zarei Mahmoud , Zare Abdolkarim , Noroozizadeh Ehsan , Karamian Roya , Asadbegy Mostafa 
Published: October 2016

AbstractAll phthalimido‐alcohols are tested for antioxidative properties in a radical scavenging assay showing efficacies similarly to that of ascorbic acid.
ChemInform Abstract: Palladium‐Catalyzed Regioselective C—H Acetoxylation of 2‐Aryloxypyridines with 2‐Pyridyloxy as a Removable Directing Group.
Authors: Wang Liang , Pan Liang , Huang Yibo , Chen Qun , He Mingyang 
Published: October 2016

AbstractYields of mono‐ as well as bis‐acetoxylated arenes depend significantly on the electronic nature of aryl substituents.
ChemInform Abstract: Hantzsch Ester as a Photosensitizer for the Visible‐Light‐Induced Debromination of Vicinal Dibromo Compounds.
Authors: Chen Wenxin , Tao Huachen , Huang Wenhao , Wang Guoqiang , Li Shuhua , Cheng Xu , Li Guigen 
Published: October 2016

AbstractThe scalable, robust, and catalyst‐free method has a broad substrate scope, thus offering access to a broad range of styrene derivatives, α,β‐unsaturated carbonyl compounds as well as 1,2 and 1,2‐disubstituted and even trisubstituted alkenes, including cyclic ones.
ChemInform Abstract: Preparation of Difluoromethylthioethers Through Difluoromethylation of Disulfides Using TMS‐CF2H.
Authors: Howard Joseph L. , Schotten Christiane , Alston Stephen T. , Browne Duncan L. 
Published: October 2016

AbstractThe operationally simple, metal‐free approach tolerates alkyl as well as aryl substituted disulfides which may contain diverse functional groups.
ChemInform Abstract: Practical Synthesis of Amides via Copper/ABNO‐Catalyzed Aerobic Oxidative Coupling of Alcohols and Amines.
Authors: Zultanski Susan L. , Zhao Jingyi , Stahl Shannon S. 
Published: October 2016

AbstractVarious catalyst systems are developed for the synthesis of a wide range of amides from alcohols and amines.
ChemInform Abstract: General Synthesis of Amino Acid Salts from Amino Alcohols and Basic Water Liberating H2.
Authors: Hu Peng , Ben‐David Yehoshoa , Milstein David 
Published: October 2016

AbstractA simple and higlhy efficient method for the dehydrogenative conversion of amino alcohols to structurally diverse amino acids is developed using sodium or potassium hydroxide as base and a ruthenium pincer complex as catalyst.
ChemInform Abstract: NHC—Copper(I) Halide‐Catalyzed Direct Alkynylation of Trifluoromethyl Ketones on Water.
Authors: Czerwinski Pawel , Molga Edyta , Cavallo Luigi , Poater Albert , Michalak Michal 
Published: October 2016

AbstractAromatic and aliphatic trifluoroketone substrates can be used with success in the title process and a wide range of functional groups is tolerated in both reactant types (detailed theoretical calculations).
ChemInform Abstract: Diamination of Domino Aryne Precursor with Sulfonamides.
Authors: Qiu Dachuan , He Jia , Yue Xiao , Shi Jiarong , Li Yang 
Published: October 2016

AbstractVariation of the reaction conditions allows for the preparation of 1,3‐diaminobenzenes or derivatives of the latter containing a triflic group in position 2.
ChemInform Abstract: Sonogashira Coupling Catalyzed by the Cu(Xantphos)I—Pd(OAc)2 System.
Authors: Liu Meilin , Ye Mingyan , Xue Yeye , Yin Guodong , Wang Dunjia , Huang Jinkun 
Published: October 2016

AbstractAryl bromides/iodides and electron‐poor aryl chlorides are suitable substrates for the title reaction.
ChemInform Abstract: Asymmetric Synthesis of Multisubstituted Dihydrobenzofurans by Intramolecular Conjugate Addition of Short‐Lived C—O Axially Chiral Enolates.
Authors: Tomohara Keisuke , Kasamatsu Koji , Yoshimura Tomoyuki , Furuta Takumi , Kawabata Takeo 
Published: October 2016

AbstractThe products are formed with high diastereomeric and enantiomeric excesses.
ChemInform Abstract: Synthesis of 5‐Hydroxy‐Δ1‐pyrrolines from Aryl Isoalkyl Ketoximes and Acetylene in a Tuned Superbase Medium.
Authors: Shabalin Dmitrii A. , Dvorko Marina Yu. , Schmidt Elena Yu. , Protsuk Nadezhda I. , Trofimov Boris A. 
Published: October 2016

AbstractTitle compounds (III) bearing aromatic substituents at the C—N double bond are synthesized in moderate yields by reaction of the corresponding ketoximes (I) and acetylene (II).
ChemInform Abstract: Detrifluoroacetylative in situ Generation of Free 3‐Fluoroindolin‐2‐one‐Derived Tertiary Enolates: Design, Synthesis, and Assessment of Reactivity Toward Asymmetric Mannich Reactions.
Authors: Xie Chen , Zhang Lijun , Sha Wanxing , Soloshonok Vadim A. , Han Jianlin , Pan Yi 
Published: October 2016

AbstractThe robust protocol displays a broad substrate scope and delivers the products in high yields and with very high diastereo‐ and enantioselectivities.
ChemInform Abstract: Isocyano Enones: Addition—Cyclization Cascade to Oxazoles.
Authors: Chao Allen , Lujan‐Montelongo J. Armando , Fleming Fraser F. 
Published: October 2016

AbstractThe modular and rapid synthesis is based on the reaction of various acyclic and 6‐7‐membered isocyano enones with diverse carbon or heteroatom nucleophiles such as dicarbonyl compounds, malonitrile, nitromethane, benzylamine and 4‐methylbenzenethiol.
ChemInform Abstract: One‐Pot Synthesis of Functionalized Benzo[c]coumarins and Their Precursors via the Reaction of 2‐(polyfluoroalkyl)chromones with 4‐Alkyl‐3‐cyanocoumarins.
Authors: Sosnovskikh Vyacheslav Ya. , Korotaev Vladislav Yu. , Kutyashev Igor B. , Barkov Alexey Yu. , Safrygin Alexander V. 
Published: October 2016

AbstractThe novel annulation reaction proceeds in the presence of triethylamine and provides directly benzo[c]coumarin derivatives or their ammonium salts.
ChemInform Abstract: Synthesis of Functionalized Tetrahydropyridazines via Catalyst‐Free Self [4 + 2] Cycloaddition of in situ Generated 1,2‐Diaza‐1,3‐dienes.
Authors: Zhang Zhimin , Zhang Li , Chen Qingqing , Lu Tao , Zhou Qingfa 
Published: October 2016

AbstractThe treatment of chlorides (I) with K2CO3 gives rise to tetrahydropyridazines (II) in high yields.
ChemInform Abstract: Silicon—Carbon Bond Formation via Nickel‐Catalyzed Cross‐Coupling of Silicon Nucleophiles with Unactivated Secondary and Tertiary Alkyl Electrophiles.
Authors: Chu Crystal K. , Liang Yufan , Fu Gregory C. 
Published: October 2016

AbstractFor the first time, the use of metal catalyst NiBr2·diglyme for the title reaction is described to yield a wide range of silylated compounds.
ChemInform Abstract: Pd‐Catalyzed C—P Coupling of Heteroaryl Boronic Acid with H‐Phosphonate Diester.
Authors: Geng Zhiyue , Zhang Yudan , Zheng Lu , Li Jingya , Zou Dapeng , Wu Yangjie , Wu Yusheng 
Published: October 2016

AbstractA novel route to heteroaryl phosphonates (III) using a Pd/Ag‐catalyst system without addition of a base is described.
ChemInform Abstract: Mild and Efficient Oxidation of Phosphorus(III) Compounds with Selectfluor.
Authors: Chen Qian , Zeng Jiekun , Yan Xinxing , Huang Yulin , Du Zhiyun , Zhang Kun , Wen Chunxiao 
Published: October 2016

AbstractSelectfluor is utilized to oxidize a variety of aryl‐, alkyl‐, and alkoxy‐substituted trivalent phosphorous compounds to the corresponding penta‐valent oxides.
ChemInform Abstract: Periplocain A, a New Naphthalene Derivative from Periploca aphylla Growing in Saudi Arabia.
Authors: Al Musayeib Nawal M. , Al‐Massarani Shaza M. , Amina Musarat , El Dib Rabab A. , Mohamed Gamal A. , Ibrahim Sabrin R. M. 
Published: October 2016

Abstractisolation and structure elucidation
ChemInform Abstract: Antiinflammatory Activity of a Novel Acetylene Isolated from the Roots of Angelica tenuissima NAKAI.
Authors: Choi Hyun Gyu , Choi Hyukjae , Lee Jeong‐Hyung , Min Byung Sun , Kim Jeong Ah 
Published: October 2016

AbstractThe novel acetylene (I) shows potent inhibitory activity against LPS‐induced NO production as well as strong inhibitory activities against iNOS and COX‐2.
ChemInform Abstract: Eu2+‐Activated Alkaline‐Earth Halophosphates, M5(PO4)3X:Eu2+ (M: Ca, Sr, Ba; X : F, Cl, Br) for NUV‐LEDs: Site‐Selective Crystal Field Effect.
Authors: Kim Donghyeon , Kim Sung‐Chul , Bae Jong‐Seong , Kim Sungyun , Kim Seung‐Joo , Park Jung‐Chul 
Published: October 2016

AbstractThe title compounds are prepared from stoichiometric mixtures of MCO3 (M: Sr, Ca, Ba), Eu2O3, NH4X (X: F, Cl, Br), and (NH4)H2PO4 (4% H2/Ar, 1100 °C, 3 h) and characterized by powder XRD, XPS, photoluminescence, IR, and UV/VIS spectroscopy.
ChemInform Abstract: Electropolymerized Films of Redox‐Active Ruthenium Complexes for Multistate Near‐Infrared Electrochromism, Ion Sensing, and Information Storage
Authors: Shao Jiang‐Yang , Yao Chang‐Jiang , Cui Bin‐Bin , Gong Zhong‐Liang , Zhong Yu‐Wu 
Published: October 2016

AbstractReview: 76 refs.
ChemInform Abstract: Synthesis of α‐Ethynyl Glycines
Authors: Bolsakova Jekaterina , Jirgensons Aigars 
Published: October 2016

AbstractReview: methods published from 1996 to 2015 for the syntheses of ethynyl glycines and synthetically equivalent ethynyl glycinols in racemic and enantioenriched form; 58 refs.
Fehlinterpretation der Fehling‐Probe auf reduzierende Zucker – Von der Beobachtung im Chemieunterricht zur Evidenz gegen die Oxidation der Aldehydgruppe
Authors: Fleischer Holger 
Published: October 2016

AbstractDie im Chemieunterricht übliche Erklärung der positiven Fehling‐Probe auf reduzierende Zucker – Oxidation der Aldehyd‐ zur Carboxylgruppe – widerspricht der Beobachtung, dass Fructose dabei schneller reagiert als Glucose und Mannose. Primäres Oxidationsprodukt der Reaktion einer Kupfer(II)salz‐Lösung mit Glucose ist nicht die entsprechende Gluconsäure bzw. das Gluconat, sondern Glucoson (2‐Ketoglucose). Sie wird unter den Reaktionsbedingungen durch C−C Bindungsspaltung weiter oxidiert. Diese Tatsache ist seit fast 90 Jahren bekannt, hat sich aber in der Lehr‐ und Schulbuchliteratur nicht durchgesetzt. Für den Chemieunterricht bietet sich hier eine Chance, Erkenntnisgewinnung durch die Falsifizierung einer Hypothese zu vermitteln. Ferner wird erläutert, dass die Bildung von Glucoson aus Glucose nachvollziehbarer zu vermitteln ist als die Bildung von Gluconsäure. Es gibt somit keinen Grund, im Unterricht von der Oxidation der Aldehydgruppe als Ursache der reduzierenden Wirkung von Zuckern auszugehen.
Optimization of Acryloylphenylcarboxamides as Inhibitors of ABCG2 and Comparison with Acryloylphenylcarboxylates
Authors: Kraege Stefanie , Stefan Katja , Köhler Sebastian C. , Wiese Michael 
Published: October 2016

AbstractABCG2 belongs to the superfamily of ATP binding cassette (ABC) proteins and is associated with the limited success of anticancer chemotherapy, given its responsibility for the cross‐resistance of tumor cells, known as multidrug resistance (MDR). Several classes of ABCG2 inhibitors were developed for increasing the efficacy of chemotherapy. A series of chalcones coupled to an additional aromatic residue was synthesized and investigated for their inhibition of ABC transporters. In our previous work we determined the preferred position of the linker on the A‐ring to be ortho, and found several substitution patterns at the additional ring that improved potency. In this study we investigated whether a methoxy group that improved the inhibitory activity of chalcones would also be beneficial for the acryloylphenylcarboxamide scaffold. Indeed, this modification led to highly potent ABCG2 inhibitors. To support the hypothesis of a beneficial effect of the amide linker, six acryloylphenylcarboxylates were synthesized and investigated for their inhibitory activity. Replacement of the amide linker with an ester group resulted in decreased inhibition. Molecular modeling showed that the conformational preference of both series differs, thereby explaining the positive effect of the amide linker. Several compounds were characterized in detail by investigating their intrinsic cytotoxicity and capacity to reverse MDR in MTT assays and their effect on vanadate‐sensitive ATPase activity.
Results of a randomized controlled trial to increase cervical cancer screening among rural Latinas
Authors: Thompson Beti , Carosso Elizabeth A. , Jhingan Esther , Wang Lei , Holte Sarah E. , Byrd Theresa L. , Benavides Maria C. , Lopez Cathy , Martinez‐Gutierrez Javiera , Ibarra Genoveva , Gonzalez Virginia J. , Gonzalez Nora E. , Duggan Catherine R. 
Published: October 2016

BACKGROUNDLatinas have the highest rates of cervical cancer in the United States and the second highest rate of cervical cancer mortality. One factor in the disparity is the relatively low rate of screening for cervical cancer in this population.METHODSEligible women who were out of adherence with cervical cancer screening (>3 years since their last Papanicolaou [Pap] test) were identified via medical record review by a federally qualified local health center. The effects of a low‐intensity intervention (video delivered to participants' homes; n = 150) and a high‐intensity intervention (video plus a home‐based educational session; n = 146) on cervical cancer screening uptake in comparison with a control arm (usual care; n = 147) were investigated. A cost‐effectiveness analysis of the interventions was conducted: all intervention costs were calculated, and the incremental cost‐effectiveness ratio was computed. Finally, women with positive Pap tests were provided navigation by a community health educator to ensure that they received follow‐up care.RESULTSA total of 443 Latinas participated. Seven months after randomization, significantly more women in the high‐intensity arm received a Pap test (53.4%) in comparison with the low‐intensity arm (38.7%; P < .001) and the usual‐care arm (34.0%; P < .01). The incremental cost‐effectiveness ratio for high‐intensity women versus the control group amounted to $4.24. Twelve women had positive Pap tests, which encompassed diagnoses ranging from atypical squamous cells of unknown significance to invasive cancer; these women received navigation for follow‐up care.CONCLUSIONSA culturally appropriate, in‐home, promotora‐led educational intervention was successful in increasing cervical cancer screening among Latinas. Cancer 2017;123:666–674. © 2016 American Cancer Society.