bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Structure‐Activity Relationship of NSTX‐3, Spider Toxin of Nephila maculata.
Authors: TESHIMA T. , MATSUMOTO T. , WAKAMIYA T. , SHIBA T. , NAKAJIMA T. , KAWAI N. 
Published: May 2016

AbstractIn a study on structure‐activity relationship of spider toxin NSTX‐3 (I), nine analogues or fragments of natural toxin are synthesized.
ChemInform Abstract: 1,6‐Anhydro‐β‐D‐glucopyranose Derivatives as Glycosyl Donors for Thioglycosidation Reactions.
Authors: WANG L.‐X. , SAKAIRI N. , KUZUHARA H. 
Published: May 2016

AbstractAnalogously to the glucose derivative (I) and the maltotriose derivative (IV), a 1,6‐anhydromaltose derivative is reacted with the trimethylsilylthio reagents (II).
ChemInform Abstract: Dideoxygenation on the 3′,4′‐Positions of an α‐Linked Disaccharide Derivative: A Key Intermediate for New Aminoglycoside Synthesis.
Authors: HAYASHIDA M. , SAKAIRI N. , KUZUHARA H. 
Published: May 2016

AbstractThe 2',6'‐diazido disaccharide derivative (I) is accessible from maltose according to standard procedures.
ChemInform Abstract: Synthesis of Methyl 2‐O‐ and 3‐O‐Sulfo‐D‐glucopyranosiduronic Acids.
Authors: OKUDA S. , KONDO T. , MURATA S. 
Published: May 2016

AbstractSulfation of the glucopyranosides (I) and (VI) with the sulfur trioxide‐pyridine complex (II) and subsequent deprotection produce the corresponding sulfates (IV) and (VII).
ChemInform Abstract: Synthesis, Antinociceptive Activity, and Opioid Receptor Profiles of 10‐Substituted‐6‐oxamorphinans.
Authors: MCELROY A. B. , BAYS D. E. , SCOPES D. I. C. , HAYES A. G. , SHEEHAN M. J. 
Published: May 2016

AbstractThe 3‐methoxy‐10‐methylene‐6‐oxamorphinans (VI) are the key step for the preparation of the 10‐methylene‐, 10‐oxo‐ and 10α‐methyl‐6‐oxamorphinans (VIIa,b), (VIIIa,b) and (Xa,b).
ChemInform Abstract: New Geometric Isomers of Vitamin A. Part 17. The Doubly Hindered 7,11‐Dicis, 7,9,11‐Tricis, 7,11,13‐Tricis and All‐cis Isomers of Retinonitrile and Retinal.
Authors: TREHAN A. , MIRZADEGAN T. , LIU R. S. H. 
Published: May 2016

AbstractThe reactions of the modified C5‐phosphonate (II) with the C15‐aldehydes (I) or (VIII) give access to the isomers (III)‐(VI) or (IX)‐(XII) of retinonitrile; included are the title isomers (IV), (XI) and the previously unknown title isomers (VI) and (XII).
ChemInform Abstract: The Total Syntheses of dl‐Zygosporin E and dl‐C18‐Desmethylcytochalasin D.
Authors: VEDEJS E. , WITTENBERGER S. J. 
Published: May 2016

AbstractThe sulfur‐bridged (11)cytochalasan (I) serves as a common starting material for the syntheses of dl‐zygosporin E (VIII) and dl‐C18‐desmethylcytochalasin D (IX).
ChemInform Abstract: The Influence of Oxygen Pressure on Oxidation‐Reduction Phenomena Observed with Submicrometer‐Sized Manganese‐Substituted Magnetites
Authors: GILLOT B. , EL GUENDOUZI M. 
Published: May 2016

Abstractis studied over the temp. range 250‐600 °C. The results reveal that the oxidation occurs in several steps, highly depending on oxygen pressure.
ChemInform Abstract: NMR Spectroscopic Characterization and the Crystal and Molecular Structures of Ph3PS·AlCl3 and Ph3PSe·AlCl3: A Classification of the Coordinative Bonding Modes of the Phosphine Chalcogenides.
Authors: BURFORD N. , ROYAN B. W. , VON H. SPENCE R. E. , ROGERS R. D. 
Published: May 2016

AbstractThe adducts R3PE·AlCl3 (R: Ph, NMe2; E: S, Se) are examined by NMR spectroscopy as a contribution toward the characterization of the P‐E bond and of the coordinate bond.
ChemInform Abstract: Hex‐1‐ene Hydroformylation Catalyzed by Rh(acac)(P(OPh)3)2 Modified with Amines, Formation of Reactive HRh(CO)(P(OPh)3)3 and Unreactive Rh4(CO)8(P(OPh)3)4 Species.
Authors: TRZECIAK A. M. 
Published: May 2016

AbstractPyridines and amines are used as modifying ligands in the hex‐1‐ene hydroformylation reaction catalyzed by Rh(acac)(P(O‐Ph)3)2.
ChemInform Abstract: Enantioselective Syntheses of 2‐Arylpropanoic Acids: (S)‐2‐Phenylpropanoic Acid.
Authors: COGHLAN D. R. , HAMON D. P. G. , MASSY‐WESTROPP R. A. , SLOBEDMAN D. 
Published: May 2016

AbstractThe synthesis of the title compound (III), an intermediate for the preparation of optically active Ibuprofen, is described with the Sharpless epoxidation of the enol (I) and subsequent benzylic hydrogenolysis of the epoxide (II) as key steps.
ChemInform Abstract: New Aspects of Platinum‐Catalyzed Hydrosilylation of Disilylethynes.
Authors: SUZUKI T. , LO P. Y. 
Published: May 2016

AbstractThe Pt(0)‐catalyzed hydrosilylations of the silylethynes (I) and (II) at 130‐150 °C are investigated using high molecular weight organosilicon hydrides.
ChemInform Abstract: Electrochemical Coupling of Activated Olefins and Alkyl Dihalides: Formation of Cyclic Compounds.
Authors: LU Y.‐W. , NEDELEC J.‐Y. , FOLEST J.‐C. , PERICHON J. 
Published: May 2016

AbstractThe activated alkenes (I) are electrochemically coupled with the dihaloalkanes (II) to give the corresponding cyclization products (III).
ChemInform Abstract: Oxidation of 1‐ and 2‐Acetylnaphthalenes by Iodate ‐ A Kinetic Study.
Authors: MANIKYAMBA P. 
Published: May 2016

AbstractA mechanism is proposed via attack of IO2+ on the enol form of acetylnaphthalene forming an intermediate carbonium ion, which gives the corresponding ω‐hydroxyacetylnaphthalene as product.
ChemInform Abstract: Enantioselective Hydrogenation of Olefins with Homogeneous Ziegler‐Natta Catalysts.
Authors: WAYMOUTH R. , PINO P. 
Published: May 2016

AbstractZiegler‐Natta systems derived from (Al(CH3)‐O‐)n and (‐)‐(ethylenebis(4,5,6,7‐tetrahydro‐1(R)‐indenyl))zirconium derivatives are used as catalysts in studies of the hydrogenation of the olefins (I)‐(III).
ChemInform Abstract: Reaction of Nitronium Tetrafluoroborate with 4‐Acyloxy‐2‐methyl‐1‐butenes.
Authors: MURSAKULOV I. G. , AZIMZADE A. A. , TALYBOV A. G. , ASLANOVA M. R. 
Published: May 2016

AbstractThe reaction specified in the title affords separable mixtures of the fluoronitro derivatives (III) and the hydroxynitro derivatives (IV), which are formed via unstable 1,3‐dioxane derivatives, which can be detected by low‐temp.
ChemInform Abstract: Alcohols as Sources of Hydrogen in Hydroformylation of Alkenes.
Authors: MACDOUGALL J. K. , COLE‐HAMILTON D. J. 
Published: May 2016

AbstractHeating hex‐1‐ene in the presence of alcohols, CO and (RhH(PEt3)3) gives heptanol and 2‐methoxyhexanol as the major products.
ChemInform Abstract: Effect of Cation, Temperature, and Solvent on the Stereoselectivity of the Horner‐Emmons Reaction of Trimethyl Phosphonoacetate with Aldehydes.
Authors: THOMPSON S. K. , HEATHCOCK C. H. 
Published: May 2016

AbstractThe Horner‐Emmons reaction of the phosphonoacetate (I) with isobutyraldehyde (II) yields an E/Z‐mixture of the α,β‐unsaturated esters (III) and (IV).
ChemInform Abstract: Inhibition of γ‐Butyrobetaine Hydroxylase by Cyclopropyl‐Substituted γ‐Butyrobetaines.
Authors: PETTER R. C. , BANERJEE S. , ENGLARD S. 
Published: May 2016

AbstractStarting with phosphonates such as (I) or (IX), cyclopropyl‐substituted γ‐butyrobetaines, e.g. (VIII) or (X), are prepared.
ChemInform Abstract: Acylation and Acylamidation of Cyclic Dienes.
Authors: GRIDNEV I. D. , BALENKOVA E. S. , BUEVICH A. V. 
Published: May 2016

AbstractThe acylation of norbornadiene (I) and 1,5‐cyclooctadiene (XIII) using acetyl tetrafluoroborate (II) or pivaloyl tetrafluoroborate (V) as the acylating agents and the acylamidation of these dienes using complexes of the derivatives (II) or (V) with MeCN (IX) is determined by the nature of the acylating agents.
ChemInform Abstract: Synthesis of Trishomohypostrophene, Trishomohypostrophenone, Trishomopentaprismane, and Trishomopentaprismanone.
Authors: SKUBALLA N. , MUSSO H. , BOLAND W. 
Published: May 2016

AbstractThe pentacyclic hydroxydicarboxylic acid diester (I), prepared in a known manner from cyclopentadiene, ethyl formate, and dimethyl acetylenedicarboxylate, is converted to the acetal (III) which is rearranged to form the isomeric diester (IV).
ChemInform Abstract: The First Enantioselective Syntheses of Pure (R)‐ and (S)‐Isoproterenol.
Authors: COREY E. J. , LINK J. O. 
Published: May 2016

AbstractStarting with the substituted acetophenone (I), the (R)‐(‐)‐isoproterenol (VIII) is synthesized.
ChemInform Abstract: Efficient Method for the Preparation of Z‐α‐Alkoxy β,γ‐Unsaturated Nitriles Starting from the Corresponding Acetals of E‐Chalcone Derivatives.
Authors: MUKAIYAMA T. , TAKENOSHITA H. , YAMADA M. , SOGA T. 
Published: May 2016

AbstractThe acetals (I) of unsaturated ketones react with trimethylsilyl cyanide (II) to give mixtures of the stereoisomeric 2‐methoxy‐3‐butenenitrile derivatives (III) and (IV).
ChemInform Abstract: Trifluoromethylthio‐ and Pentafluorophenylthio‐substituted Alkenes and Arylalkenes.
Authors: KONDRATENKO N. V. , KHOMENKO L. A. , YAGUPOL'SKII L. M. 
Published: May 2016

AbstractThe reactions between copper trifluoromethyl sulfide (IIa) or copper pentafluorophenyl sulfide (IIb) and the five differently substituted alkenes (I), (IV), (VI), (VIII) and (X) afford the title compounds (III), (V), (VII), (IX) and (XI).
ChemInform Abstract: Metacyclophanes and Related Compounds. Part 26. Tetrahydroxy(2.n.2.n)metacyclophanes. Preparation, Reactions, and Spectra.
Authors: TASHIRO M. , TSUGE A. , SAWADA T. , MAKISHIMA T. , HORIE S. , ARIMURA T. , MATAKA S. , YAMATO T. 
Published: May 2016

AbstractReaction of the dianisylalkanes (I) with formaldehyde (II) and HCl gives the chloromethylation products (III) which are converted into the dithiols (IV) upon treatment with thiourea.
ChemInform Abstract: Reaction of Pyrocatechol and Hydroquinone with Bromo‐ and Hydroxyadamantane.
Authors: MIRYAN N. I. , YURCHENKO A. G. , KIRIENKO E. I. 
Published: May 2016

AbstractPyrocatechol (I) is coupled with 1‐bromoadamantane (II) in the presence of boron trifluoride etherate to give the mono‐ (III) or diadamantylpyrocatechol (IV) depending on the molar ratio.
ChemInform Abstract: Regioselective Cyclopropanation via Unsymmetrical Oxatrimethylenemethanepalladium Intermediates.
Authors: TROST B. M. , URABE H. 
Published: May 2016

AbstractThe carbonates (I) react with the silyl triflates (II) to give the silyl enol ethers (III) and (IV) with predominance of (III).
ChemInform Abstract: The Synthesis of Butenolide α‐Formyl Acetals.
Authors: CHAN K. , SANNER M. A. , CARLSON R. M. 
Published: May 2016

Abstract3‐Phenylthio‐2‐(phenylthiomethyl)propenoic acid (III), prepared by a known procedure, is converted to the symmetrical dianion salt (V) which is coupled and cyclized with the carbonyl compounds (VI), forming the methyl‐γ‐lactones (VII).
ChemInform Abstract: Thermal 1,6‐Electrocyclization Reactions of Acceptor‐Substituted 2,3‐Divinyl‐1H‐indoles Yielding Functionalized Carbazoles.
Authors: PINDUR U. , ADAM R. 
Published: May 2016

AbstractNew synthetic procedures including the title reaction leading to functionalized carbazoles such as (III) or (VIII) are described.
ChemInform Abstract: Synthesis and Physical Studies of Azamitosene and Iminoazamitosene Reductive Alkylating Agents. Iminoquinone Hydrolytic Stability, syn/anti‐Isomerization, and Electrochemistry.
Authors: ISLAM I. , SKIBO E. B. 
Published: May 2016

AbstractCatalyzed by ZnCl2, the pyrrolidinobenzene (I) is cyclized to give the benzimidazole (III).
ChemInform Abstract: Stereospecific Syntheses of erythro‐ and threo‐(1′,2′‐Dihydroxyethyl)‐3‐aryloxazolidin‐2‐ones.
Authors: GENET J. P. , DENIS A. , VILAR A. , SCHOOFS A. R. , ALARD P. 
Published: May 2016

AbstractStarting with cis‐1,4‐dichloro‐2‐butene (II) or trans‐1,4‐dibromo‐2‐butene (VII), the stereoisomeric epoxy carbamates (V) and (IX) are prepared.
ChemInform Abstract: New Synthesis of 1,2,4‐Oxadiazoles.
Authors: YAROVENKO V. N. , TARALASHVILI V. K. , ZAVARZIN I. V. , KRAYUSHKIN M. M. 
Published: May 2016

AbstractThe interaction of amidoximes such as (I) with nitriles such as (II) in the presence of a catalyst and HCl affords the 1,2,4‐oxadiazoles (III).
ChemInform Abstract: New Direct Synthesis of 3‐Nitro‐2H‐chromenes Using Nitroethylene.
Authors: AL NEIRABEYEH M. , KOUSSINI R. , GUILLAUMET G. 
Published: May 2016

AbstractThe 2‐hydroxybenzaldehydes (I) undergo cyclocondensation with nitroethylene (II) in the presence of dibutylamine to form the nitrochromenes (III) mentioned in the title.
ChemInform Abstract: Synthesis of 2‐Cyclopropylchromones Under Phase‐Transfer Catalysis Conditions.
Authors: RAO D. M. S. , RAO E. V. S. B. , RAO A. V. S. 
Published: May 2016

AbstractThe cyclocondensation of the dihydroxyacetophenones (I) with cyclopropanecarboxylic chloride (II) is best performed under phase‐transfer catalysis, forming the 2‐cyclopropylchromones (III).
ChemInform Abstract: Synthesis of 2,4‐Diamino‐thieno(2,3‐d)pyrimidines.
Authors: LINK H. 
Published: May 2016

AbstractIn the course of studies concerning the preparation of dihydrofolate reductase inhibitors, the title compounds (Va) and (Vb) are synthesized; MCPBA oxidation of (Va) leads to the corresponding sulfoxide in 46% yield.
ChemInform Abstract: Unusual Amination by Cleavage of an Exocyclic C‐N Linkage with Formamide.
Authors: RAM V. J. , KUSHWAHA D. S. 
Published: May 2016

AbstractStarting from the 2‐hydrazinoquinazolinones (I) and (VI), a series of seven 2‐(1‐pyrazolyl)‐quinazolinones such as (III) and (VIII) are prepared according to A).
ChemInform Abstract: Stereochemical Studies. Part 145. Saturated Heterocycles. Part 152. Preparation and Conformational Analysis of Stereoisomeric 1,6,7‐11b‐Tetrahydro‐2H(1,3)oxazino(4,3‐a)isoquinolin‐4‐one Derivatives.
Authors: LAZAR L. , FUELOEP F. + , DOMBI G. , BERNATH G. , ARGAY G. , KALMAN A. 
Published: May 2016

AbstractThe known tetrahydroisoquinoline (I) is converted to some trifunctional derivatives such as (III).
ChemInform Abstract: Porphyrins and Their Derivatives. Part 11. Porphyrins Containing an Oxyethylenic Chain.
Authors: MEL'NIK V. I. , ZHILINA Z. I. , ANDRONATI S. A. , MAMONTOV V. P. 
Published: May 2016

AbstractThe reaction between the porphyrin derivative (I) and large excesses of the diols (II) yields the new monoethers (III), which are reacted with a second equivalent of (I) to give the hitherto unknown dimeric porphyrin derivatives (IV), which differ in their steric orientations.
ChemInform Abstract: Synthesis and Biological Activity of Bromides of ω‐(Dimethyltriorganylsilylmethylammonio)alkanoic Acids.
Authors: PISARSKII YU. B. , VVEDENSKII V. YU. , VORONKOV M. G. , KAZIMIROVSKAYA V. B. , KISHKINA I. M. , VASIL'EVA N. N. , MOSKVITINA L. T. 
Published: May 2016

AbstractThe ω‐bromoalkanoic acid trimethylsilyl esters (II) react with the triorganylsilylmethyldimethylamines (I) to give the ammonioalkanoic acids (III) after methanolysis.
ChemInform Abstract: Heptasila(7)paracyclophane.
Authors: ANDO W. , TSUMURAYA T. , KABE Y. 
Published: May 2016

AbstractThe title compound (II), the first example of an (n)paracyclophane with heterometal bridges, is obtained by reductive coupling of (I) with Na in the presence of the crown ether (important to avoid polymeric products).
ChemInform Abstract: Synthesis and Reactivity of 1,1‐Disodio‐2,3,4,5‐tetraphenyl‐1‐silacyclopentadiene.
Authors: JOO W.‐C. , HONG J.‐H. , CHOI S.‐B. , SON H.‐E. , KIM C. H. 
Published: May 2016

AbstractThe synthesized title compound (III) reacts with MeI (IVa) or the methylsilyl chlorides (IVb) and (IVc) to give the 1,1‐disubstituted derivatives (V).
ChemInform Abstract: Fluorosilyl and Fluoroboryl Substituted Cyclotetrasilazanes. Synthesis and Crystal Structures.
Authors: DIPPEL K. , KLINGEBIEL U. , KOTTKE T. , PAUER F. , SHELDRICK G. M. , STALKE D. 
Published: May 2016

AbstractThe monolithium derivative of octamethylcyclotetrasilazane (I) and the dilithiated analogue (V) react with difluorosilanes such as (II) and the difluoroborylamine (VI) with retention of the cyclotetrasilazane structure to yield the mono‐ and disubstituted derivatives of the type (III) ((IIIa) (R2: Me) and (IIIb): space group P21/n, Z=4), (IV) (yields 84‐92%; (IVa) (R2: Me): P21/n, Z=2; (IVa) (R2: tBu): P1, Z=1), and (VII), respectively.
ChemInform Abstract: Studies on Organosilicon Chemistry. Part 100. Pentacoordinate Allylsiliconates in Organic Synthesis: Synthesis of Triethylammonium Bis(catecholato)allylsiliconates and Selective Allylation of Aldehydes.
Authors: HOSOMI A. , KOHRA S. , OGATA K. , YANAGI T. , TOMINAGA Y. 
Published: May 2016

AbstractThe allyl(trimethoxy)silanes (I) react with catechol (II) in the presence of triethylamine (III) to form the siliconates (IV) mentioned in the title.
ChemInform Abstract: Synthesis of the Heptaphosphanortricyclanes R3P7 R, R: Et, iPr, nBu, iBu, SiH2Me, SiH3, Et2P‐SiMe2.
Authors: FRITZ G. , SCHNEIDER H.‐W. 
Published: May 2016

AbstractThe title compounds are synthesized by reaction of Li3P7·3 DME with corresponding alkyl bromides or silyl halides at low temperatures.
ChemInform Abstract: 2,10‐Dichloro‐6‐(aryloxy)dibenzo(d,g)(1,3,6,2)dioxathiaphosphocin 6‐Oxides. Synthesis and Spectral Characteristics.
Authors: REDDY C. D. , ANURADHA K. , BERLIN K. D. , SUNTHANKAR P. S. , MULEKAR S. V. 
Published: May 2016

AbstractThe heterocyclic phosphates (III) mentioned in the title are obtained by base‐induced ring closure of the o,o'‐dihydroxydiphenyl sulfide (I) with the phosphorodichloridates (II).
ChemInform Abstract: Synthesis and Reactions of a Stable 2‐Selenanaphthalene, 1‐Cyano‐2‐methyl‐2‐selenanaphthalene.
Authors: HORI M. , KATAOKA T. , SHIMIZU H. , TSUTSUMI K. , YOSHIMATSU M. 
Published: May 2016

AbstractThe isoselenochromanol (I) is dehydrated to give the isoselenochromene (II) which is chlorinated with sulfuryl chloride and subsequently treated with the silyl cyanide (III) to produce the nitrile (IV).
ChemInform Abstract: iPr2InBr, iPr2InI and iPrInI2.
Authors: HOFFMANN G. G. , FAIST R. 
Published: May 2016

AbstractThe title compounds (IV) and (V) are obtained by reaction of the synthesized triisopropyl‐In (III) with two equiv. InI3 (I) or one equiv. (I) or InBr3, respectively.
ChemInform Abstract: μ‐Hydroxobis(μ‐formato)hexaaquodichromium(III): An Intermediate in the Formation of Basic Chromium Carboxylates.
Authors: TUROWSKI P. N. , BINO A. , LIPPARD S. J. 
Published: May 2016

AbstractThe title cation is obtained by reduction of Cr(VI) oxide (II) in formic acid (I), isolated as its tosylate (IV) (space group C2/c, Z = 8), and characterized by X‐ray structure analysis and magnetic data.
ChemInform Abstract: Phosphinidene and Arsinidene Complexes Containing Pentamethylcyclopentadienyl (Cp*) Ligands at Group 15 Element: Synthesis and Cp* Transfer.
Authors: JUTZI P. , KROOS R. 
Published: May 2016

AbstractThe air‐ and moisture‐sensitive phosphinidene and arsinidene complexes (III) and (IV) (yield 21/23%) are synthesized as shown for the phosphinidene complexes.
ChemInform Abstract: Synthesis, Structure and Reactions of the Novel Cationic Bisbut‐2‐yne Complex (W(CO)(NCMe)(S2CNC4H8)(η2‐MeC2Me)2)(BPh4).
Authors: BAKER P. K. , DREW M. G. B. , FLOWER K. R. 
Published: May 2016

AbstractThe title complex (III) (space group P21/a, Z=4) is obtained by replacement of the iodide ligand in (I) by acetonitrile (II) and characterized by X‐ray structure analysis.
ChemInform Abstract: The Re‐Re Bond in Binuclear Di‐μ‐oxorhenium Complexes Containing the 1,4,7‐Triazacyclononane Ligand.
Authors: BOEHM G. + , WIEGHARDT K. , NUBER B. , WEISS J. 
Published: May 2016

AbstractRe‐Re double bonds characterize complexes (V) (space group P21/c, Z=2) and (VII) ( P21/n, Z=2).
ChemInform Abstract: Synthesis and Characterization of the Linear Trinuclear Complexes (MII 3(O2CCH3)6(biphme)2), M: Mn, Fe.
Authors: RARDIN R. L. , BINO A. , POGANIUCH P. , TOLMAN W. B. , LIU S. , LIPPARD S. J. 
Published: May 2016

AbstractIn the title complexes (III) (for both space group P21/c, Z=2) three two‐valent metal ions form a chain bridged by four bidendate and two monodentate carboxylate ligands.
ChemInform Abstract: The Supercomplex Nature of Buffs ′Ferrocyanethyl′. First Example of a Homoleptic Hydrogen Isocyanide (CNH) Metal Complex.
Authors: RIEGER D. , HAHN F. E. , FEHLHAMMER W. P. 
Published: May 2016

AbstractTreatment of (I) with hydrogen chloride and ethanol (II) results in the formation of the hydrogen isocyanide iron complex (III).
ChemInform Abstract: Synthesis and Structure of Novel Cu Clusters: Cu30‐xSe15(PiPr3)12 (x = 0, 1) and Cu36Se18(P(tBu)3)12.
Authors: FENSKE D. , KRAUTSCHEID H. , BALTER S. 
Published: May 2016

AbstractThe title clusters (IV) (space group P1, Z=2), (V) (P21/c, Z=4), and (VII) (C2/c, Z=4) are obtained according to the scheme and characterized by X‐ray structure analysis.
ChemInform Abstract: Synthesis and Crystal Structure of Hexanuclear Copper(I) Complexes of μ3‐Pyridine‐2‐thionate.
Authors: KITAGAWA S. , MUNAKATA M. , SHIMONO H. , MATSUYAMA S. , MASUDA H. 
Published: May 2016

AbstractThe structure of the synthesized hexanuclear Cu(I) complex (III) (space group P21/n, Z=2) is confirmed by X‐ray structure analysis.
ChemInform Abstract: Novel Basic Ligands for the Homogeneous Catalytic Carbonylation of Methanol. Part 26. Dynamic and Reactive Behavior of (Ether‐Phosphane)Ruthenium(II) Complexes in Dependence on the O‐Basicity.
Authors: LINDNER E. , KARLE B. 
Published: May 2016

AbstractThe reaction of the ether‐phosphane ligand (II) with (I) results in formation of the bis(chelate) complex (III).
ChemInform Abstract: Synthesis of Metal Free Phthalocyaninetetrakis(N‐cyclopropylsulfonamides).
Authors: YAHYA H. K. , DAWOOD A. A. 
Published: May 2016

AbstractThe phthalocyanine derivative, in which the cyclopropylsulfonylamide groups are attached to the 4,4',4'',4'''‐positions, is prepared analogously to (III) with 63% yield.
ChemInform Abstract: Electrochemical and EPR Studies of Carotenoid Cation Radicals and Dications: Effect of Deuteration.
Authors: KHALED M. , HADJIPETROU A. , KISPERT L. 
Published: May 2016

AbstractThe cyclic voltammograms of the carotenoids (I) in CH2Cl2 indicate a reversible transfer of two electrons.
ChemInform Abstract: Total Synthesis of the Methylfuranosides of 2‐Desoxypentoses and 2,6‐Didesoxyhexoses. Application of 1H and 13C NMR Spectroscopies for the Structure Determination of the Glycosides of 2‐Desoxysugars.
Authors: ARSHAVA B. M. , RAIFEL'D YU. E. , MAKIN S. M. 
Published: May 2016

AbstractOptimized yields for 17 title compounds, represented in the scheme by (I) and (III), are attained under the conditions A).
ChemInform Abstract: Novel Types of Cyclonucleosides.
Authors: TRONCHET J. M. J. , BENHAMZA R. , BERNARDINELLI G. , GEOFFROY M. 
Published: May 2016

AbstractThe keto cyclonucleoside (Ia) reacts with hydroxylamine (II) to form the oxime (Ib), together with the cyclic hydroxylamine (III), which is solvolyzed to yield (IV).
ChemInform Abstract: Synthesis and Evaluation of Aborted and Extended CC‐1065 Functional Analogues: (+)‐ and (‐)‐CPI‐PDE‐I1, (+)‐ and (‐)‐CPI‐CDPI1, and (.+‐.)‐, (+)‐, and (‐)‐CPI‐CDPI3. Preparation of Key Partial Structures and Definition of an Additional Functional Role of the CC‐1065 Central and Right‐Hand Subunits.
Authors: BOGER D. L. , COLEMAN R. S. , INVERGO B. J. , SAKYA S. M. , ISHIZAKI T. , MUNK S. A. , ZARRINMAYEH H. , KITOS P. A. , THOMPSON S. C. 
Published: May 2016

AbstractThe CC‐1065 analogue (+)‐CPI‐PDE‐I1 (IV) as well as the other, structurally related, title compounds are prepared as shown for (IV).
ChemInform Abstract: The Preparation and Use of Metallo‐6‐vinylidene Penams.
Authors: BUYNAK J. D. , BORATE H. B. , LAMB G. , ISOM H. , HUSTING C. , KHASNIS D. 
Published: May 2016

AbstractConsecutive treatment of the iodoallene (I) with sec‐butyllithium and acetic acid or the acid chlorides (IV) results in the formation of the acetylene (II) or the keto acetylenes (V).
ChemInform Abstract: Structure of Disodium Triaquatri‐μ‐sulfato‐thorate(IV) Trihydrate.
Authors: HABASH J. , SMITH A. J. 
Published: May 2016

AbstractPrismatic crystals of Na2(Th(SO4)3(H2O)3)·3 H2O are obtained by slow evaporation of a solution of Th(SO4)2·9 H2O and Na2SO4 at room temperature.