bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis and Structure of 7‐Aminobenzo(b)thiophene Derivatives.
Authors: GRINEV A. N. , KHARIZOMENOVA I. A. , KAPUSTINA M. V. , SHEINKER YU. N , ALEKSEEVA L. M. , RUBTSOV N. M. , KULESHOVA E. F. 
Published: May 2016

AbstractThe oximes (II) of the 7‐oxo‐4,5,6,7‐tetrahydrobenzothiophenes (I) react with mixtures of acetyl chloride, acetic anhydride, and pyridine to produce the diacetylaminobenzothiophenes (III).
ChemInform Abstract: Synthesis, Anticonvulsant and Analgesic Activities of Some New Fluorine Containing 1,3,5‐Trisubstituted Hydantoins.
Authors: JOSHI K. C. , PATHAK V. N. , GOYAL M. K. 
Published: May 2016

AbstractThe fluorinated hydantoins (III) are prepared from the phenylglyoxals (I) and the phenylureas (II).
ChemInform Abstract: A Simple Efficient Synthesis of 5,8‐Isoquinolinedione.
Authors: ANDERSON W. K. , CONNARTY B. P. , EL‐HAJI T. 
Published: May 2016

Abstract5‐Hydroxyisoquinoline (I) is converted to the 8‐nitroso derivative (II), which is reduced with sodium dithionite to produce (III).
ChemInform Abstract: Prodrugs of 5‐Fluorouracil. Part 5. 1‐Alkoxycarbonyl Derivatives as Potential Prodrug Forms for Improved Rectal or Oral Delivery of 5‐Fluorouracil.
Authors: BUUR A. , BUNDGAARD H. 
Published: May 2016

AbstractThe hydrolysis and rectal absorption potential of the 1‐alkoxycarbonyl derivatives (III), prepared from 5‐fluorouracil (I) and the chloroformates (II), are studied.
ChemInform Abstract: Synthesis of 1,2‐trans‐2,3‐trans‐1‐Aryloxy‐3‐substituted‐aminocyclohexan‐2‐ols as Potential Biodynamic Agents.
Authors: STARLING S. K. , RASTOGI S. N. , ANAND N. 
Published: May 2016

AbstractReaction of the phenols (I) with 3‐chlorocyclohexene (II) yields the phenoxycyclohexenes (III).
ChemInform Abstract: Synthesis of 6H‐1,2,4‐Triazino‐1,2,4‐triazolopyridazines. Studies in the Field of Pyridazine Compounds. Part 22.
Authors: KOSARY J. , JERKOVICH G. , POLOS K. , KASZTREINER E. 
Published: May 2016

AbstractThe title compounds such as (II), (IV), or (VII) are synthesized either by ring closure of the hydrazones (I) or (III) in polyphosphoric acid or by condensation reaction of the hydrazine (V) with triethyl orthoformate (VI).
ChemInform Abstract: Reaction of (Pentamethylcyclopentadienyl)(tert‐butylimino)phosphane with Tris(acetonitrile)tricarbonylmolybdenum(0): Evidence for a Metalloiminophosphane Intermediate.
Authors: GUDAT D. , NIECKE E. , KREBS B. , DARTMANN M. 
Published: May 2016

AbstractThe 2:1 molar reaction of the title phosphane (III), prepared in a two‐step synthesis from the dichloride (I) as shown, with the Mo(0) complex (IV) affords the spirocyclic compound (VI).
ChemInform Abstract: Molybdenum‐Mediated Methoxycarbonylation of Propargyl Halides: Molecular and Crystal Structure of the Vinylmolybdenum(II) Complex (Mo(bipy)(CO)2(C5H7O2)(py))BF4.
Authors: BRISDON B. J. , BROWN D. W. , WILLIS C. R. , DREW M. G. B. 
Published: May 2016

AbstractThe halo‐Mo(0) complexanions (I) react with propargyl chloride to yield the cis‐dicarbonyl‐Mo(II) complexes (II) which contain an η3‐oxacyclobutenyl ligand formed by methoxycarbonylation of the propargyl moiety.
ChemInform Abstract: Cobalt(I) Complexes: Synthesis and Molecular and X‐Ray Structures of Group 14 (η4‐Metallole)tris(trimethylphosphine)cobalt Tetraphenylborate Complexes.
Authors: DE CARVALHO L. C. A. , DARTIGUENAVE M. , DAHAN F. , DARTIGUENAVE Y. , DUBAC J. , LAPORTERIE A. , MANUEL G. , ILOUGHMANE H. 
Published: May 2016

AbstractReaction of the Co(I) complex (I) with excess tetramethylmetalloles (II) in the presence of NaBPh4 yields the title complexes (III).
ChemInform Abstract: Crystal Structure and Semiconductivity of Tetraethylammonium Bis(isotrithionedithiolato)nickelate(III).
Authors: GROENEVELD L. R. , SCHULLER B. , KRAMER G. J. , HAASNOOT J. G. , REEDIJK J. 
Published: May 2016

AbstractStarting with the corresponding dianionic product the title complex (I) is prepared by oxidation with iodine or by autoxidation by known methods.
ChemInform Abstract: Fluorescent Copper(I) Complexes: Correlation of Structural and Emission Characteristics of ((CuI(quin)2)2) and (Cu4I4(quin)4) (quin: Quinoline).
Authors: RATH N. P. , HOLT E. M. , TANIMURA K. 
Published: May 2016

AbstractThe title complexes (I) and (II) are obtained by 1:2‐ or 1:1‐molar reaction of CuI with quinoline in refluxing acetone in the presence of aqueous KI.
ChemInform Abstract: Synthesis, Spectroscopic Characterization, and Magnetic Properties of a Mixed‐Valence Copper(I,II) Acetato Complex with Triphenylphosphine. Crystal Structure of Hexa‐μ‐acetato‐tetrakis(triphenylphosphine)tetracopper(I,II).
Authors: VALIGURA D. , KOMAN M. , DURCANSKA E. , ONDREJOVIC G. , MROZINSKI J. 
Published: May 2016

AbstractCu(II) acetate reacts with PPh3, in ethanol solution, depending on the concentration of Cu(II) acetate, the molar ratio of PPh3 to Cu(II), and temp., to form the Cu(I) complex (I), the Cu(II) complex (II), and the mixed‐valence Cu(I,II) complex (III).
ChemInform Abstract: Chemistry of Tetrairidium Carbonyl Clusters. Part 1. Synthesis, Chemical Characterization, and NMR Study of Mono‐ and Di‐Substituted Phosphine Derivatives. X‐Ray Crystal Structure Determination of the Diaxial Isomer of (Ir4(CO)7(μ‐CO)3(Me2PCH2CH2PMe2)).
Authors: ROS R. , SCRIVANTI A. , ALBANO V. G. , BRAGA D. , GARLASCHELLI L. 
Published: May 2016

AbstractThe reaction of the anionic cluster (NEt4) (Ir4(CO)11Br) with uni‐ and bidentate phosphines and arsines is investigated.
ChemInform Abstract: Synthesis and Investigation of Some Androstane Derivatives of 5‐Fluorouracil.
Authors: VOLOVE'SKII L. N. , RASTREPINA I. A. , POPOVA N. V. , KORYUKINA V. N. , ZIDERMANE A. A. , DAUVARTE A. ZH. 
Published: May 2016

AbstractMono‐ and disodium salts of fluorouracil (II) react with the 2‐bromodihydrotestosterones (I) to give the mono‐ and disubstituted fluorouracils (III).
ChemInform Abstract: Synthesis and Use of Dibenzylpyrocarbonate: Preparation of Dipeptide Free N‐Benzyloxycarbonyl Glycine.
Authors: SENNYEY G. , BARCELO G. , SENET J.‐P. 
Published: May 2016

AbstractDibenzylpyrocarbonate (III) is synthesized by treatment of benzyl alcohol (I) with sodium hydride and subsequent addition of carbon dioxide and benzyl chloroformate (II).
ChemInform Abstract: Sugar Conjugates of Pyridinium Aldoximes as Antidotes Against Organophosphate Poisoning.
Authors: HELDMAN E. , ASHANI Y. , RAVEH L. , RACHAMAN E. S. 
Published: May 2016

AbstractThe sugar conjugates (III), (VI), and (IX) of pyridinium aldoximes are prepared by direct condensation of the oximes (I) with the appropriate monosaccharides (II), (V), or (VIII).
ChemInform Abstract: Synthesis of Secoisoquinoline Alkaloids: Total Synthesis of Peshawarine.
Authors: CHRZANOWSKA M. , ROZWADOWSKA M. D. 
Published: May 2016

AbstractThe starting materials in the synthesis of the title compound (IV) are the dithian (I) and the aldehyde (II) which are prepared by literature methods from piperonal and hydrastinine respectively.
ChemInform Abstract: Pheromone Synthesis. Part 96. Synthesis of Both the Enantiomers of 7‐Ethyl‐5‐methyl‐6,8‐dioxabicyclo(3.2.1)oct‐3‐ene. The Mus musculus (House Mouse) Pheromone.
Authors: MORI K. , SEU Y.‐B. 
Published: May 2016

AbstractThe title pheromone (VII) is synthesized starting from the alkene (I) which in turn is prepared from (+)‐tartaric acid.
ChemInform Abstract: Stereoselective Synthesis of (2E,4E)‐ and (2Z,4E)‐2,4‐Alkadienoates by the Ester Enolate Claisen Rearrangement of (E)‐1‐Alkyl‐3‐trimethylsilyl‐2‐propenyl Glycolates Followed by the Peterson Reaction.
Authors: SATO T. , TSUNEKAWA H. , KOHAMA H. , FUJISAWA T. 
Published: May 2016

AbstractThe silylated propenyl glycolates (I), prepared from 2‐methyl‐1,3‐dioxolane‐4‐one and E‐1‐trimethylsilyl‐1‐alken‐3‐ols, are transformed into a mixture of threo‐ (II) and erythro‐hydroxytrimethylsilyl‐4‐alkenoates (III) by Claisen rearrangement, silylation of the intermediate dianion and subsequent methylation.
ChemInform Abstract: Crystal Structure of Trisilver(I) Amidosulfate‐3‐Ammonia‐2‐Water, Ag3SO3N·3 NH3·2 H2O.
Authors: BELAJ F. , KRATKY C. , NACHBAUR E. , POPITSCH A. 
Published: May 2016

AbstractThe title compound (prepared for the first time in 1936) crystallizes in the orthorhombic system (P212121, Z=4).
ChemInform Abstract: Stabilization of n‐GaAs in Acidic Concentrated Iodide Electrolytes.
Authors: ALLONGUE P. , CACHET H. , CLECHET P. , FROMENT M. , MARTIN J. R. , VERNEY E. 
Published: May 2016

AbstractResults of rotating ring‐disk experiments, impedance measurements, surface analysis, and chemical analysis of the electrolyte (to study the long‐term stability) demonstrate that a protection of n‐GaAs against photocorrosion and chemical attack can be achieved in acidic concentrated iodide electrolytes under a few mW/cm2 illumination and in the dark.
ChemInform Abstract: Amorphous Molybdenum Sulfide Electrodes for Nonaqueous Electrochemical Cells.
Authors: AUBORN J. J. , BARBERIO Y. L. , HANSON K. J. , SCHLEICH D. M. , MARTIN M. J. 
Published: May 2016

AbstractA series of amorphous Mo sulfides aMoS2, aMo2S5, and aMoS3, synthesized from Mo halides and hexamethylsilathiane, as well as crystalline MoS2 and aMoS3 prepared by previously reported techniques, have been investigated as candidate nonaqueous storage battery electrodes.
ChemInform Abstract: The Effects of pH and Adsorbed Hydrolysed Metal Ions on the Photodissolution of Colloidal Cadmium Sulphide
Authors: HAYES R. , FREEMAN P. A. , MULVANEY P. , GRIESER F. , HEALY T. W. , FURLONG D. N. 
Published: May 2016

Abstracthave been investigated in Ludox stabilized and Ludox‐free solution in the presence and absence of Co(II) and Ni(II) ions.
ChemInform Abstract: Nucleophilic Attack Upon Ethylene Coordinated to Mercury(II): A Molecular‐Orbital Study Concerning the Origin of the Acceleration by Hg(II).
Authors: SAKAKI S. , MARUTA K. , OHKUBO K. 
Published: May 2016

AbstractAn ab initio MO study is carried out on the nucleophilic attack upon free C2H4, (Li(C2H4))+, and (HgH(C2H4))+, using water as a model of the nucleophile ROH.
ChemInform Abstract: Telomerization of Aromatic Nitrogen Heterocycles with Butadiene Catalyzed by Palladium Phosphine Complexes.
Authors: TELIN A. G. , FAKHRETDINOV R. N. , TOLSTIKOV G. A. , DZHEMILEV U. M. 
Published: May 2016

AbstractThe telomerization of various nitrogen and nitrogen,sulfur heterocycles with butadiene (II) is studied in the presence of complex palladium catalysts according to methods A) or B).
ChemInform Abstract: Addition of Organometallics to α,β‐Unsaturated Thiocarbonyl Compounds. Part 4. Five‐Membered Heterocycles by 1,4‐Addition of the Carbenoid ICH2MgCl.
Authors: GUEMAS J.‐P. , VILLIERAS J. 
Published: May 2016

AbstractThe thioxo derivatives (V), (VIII), and (XI) are cyclized by the reaction with iodomethylmagnesium chloride (III), prepared from (I) and (II), to yield the thiophene derivatives (VI), (IX), and (X) or the thiazole (XII).
ChemInform Abstract: Photoinduced Nitrene, Carbene, and Atomic Oxygen Transfer Reactions Starting from the Corresponding Pyridinium N‐, C‐, and O‐Ylides.
Authors: STRUB H. , STREHLER C. , STREITH J. 
Published: May 2016

AbstractUV irradiation of the pyridinium ylides (I) leads to fragmentation of the exocyclic polar bonds, as well as to skeletal rearrangements.
ChemInform Abstract: Photolysis of Cycloalkanones with Dichlorocyclopropanes in α,α′‐Position.
Authors: WEYERSTAHL P. , HASHEM MD. A. 
Published: May 2016

AbstractIrradiation of the doubly fused cyclohexanone (V) leads to the formation of the ring‐opened derivatives (VI) and (VII), the structure of (VI) being established unerringly by NaBH4 reduction to give the cyclohexanol (VIII).
ChemInform Abstract: Organic Photochemistry. Part 79. Photoreaction of 9‐Dicyanomethylene1,2,3,4‐tetrahydro‐1,4‐methanonaphthalene: The 1,3‐Carbon Migrations and the Ethylene Extrusion to Dicyanoisobenzofulvene.
Authors: TANAKA N. , KUMAGAI T. , MUKAI T. 
Published: May 2016

AbstractIrradiation of 9‐dicyanomethylene‐1,2,3,4‐tetrahydro‐1,4‐methanonaphthalene (I) yields the rearranged products (II) ‐ (IV).
ChemInform Abstract: (2.2)(1,4)Benzo(g)chrysenoparacyclophane Dianion: A Novel, Paratropic, Double‐Layered Carbanion.
Authors: FRIM R. , RABINOVITZ M. , HOPF H. , HUCKER J. 
Published: May 2016

Abstract(Ia) is converted into the cyclophane (III) via Arbusov and subsequent Wittig‐Horner reaction with the aldehyde (II).
ChemInform Abstract: Polyfluorocycloalkenes. Part 20. The Preparation of Perfluoro‐alkane and Cycloalkane Diols.
Authors: HUSAIN S. Z. , PLEVEY R. G. , TATLOW J. C. 
Published: May 2016

AbstractOxidation of the fluorinated compounds (I) and (III) yields the title cycloalkane diols (II) and (IV), resp., which remain unchanged in refluxing KMnO4/Me2CO.
ChemInform Abstract: A Simple Method for the Reduction of Higher Oxolactones to Lactones by a Modified Clemmensen‐Reaction Using Non‐Activated Zinc.
Authors: ZAKHARKIN L. I. , PRYANISHNIKOV A. P. 
Published: May 2016

AbstractThe easily accessible oxolactones (I) are reduced by non‐activated zinc powder in the presence of HCl in aprotic solvents ‐ Ac2O, ethers, hydrocarbons ‐ to give the lactones (II) in one step and in much higher yields as compared to earlier methods.
ChemInform Abstract: Applications of 1‐Alkoxycarbonyl‐ and 1‐Acyl‐v‐triazolo(4,5‐b)pyridines as Acylating Reagents.
Authors: TORRINI I. , ZECCHINI P. , AGROSI F. , PARADISI M. P. 
Published: May 2016

AbstractThe two equilibrating isomeric forms (Ia) and (Ib) of triazolopyridine are acylated to yield only the 1‐alkoxycarbonyl derivatives (III).
ChemInform Abstract: Diazo Compounds. Part 65. Isomerization Reactions in the System 4‐Diazo‐1‐butene/2,3‐Diazabicyclo(3.1.0)hex‐2‐ene/1,4‐Dihydropyridazine.
Authors: HEYDT H. , BREINER H.‐W. , HELL V. , REGITZ M. 
Published: May 2016

AbstractReactions between the cyclopropenes (I) and the diazo compounds (II) and (VI) are investigated leading to the results shown in the scheme.
ChemInform Abstract: Electrophilic Fluorination of Tin and Mercury Derivatives as a Route to Fluoroaromatics.
Authors: BRYCE M. R. , CHAMBERS R. D. , MULLINS S. T. , PARKIN A. 
Published: May 2016

AbstractElectrophilic cleavage of the stannanes (I) and (IV) and of the aryl mercurial (III) by CF3OF, CsSO4F or fluorine yields fluorobenzene (II).
ChemInform Abstract: Imination of Sulfur Compounds. Part 28. Arylsulfonylimination of the Sodium Salts of Diacylmethyl Aryl Sulfides.
Authors: KOVAL' I. V. , PANASENKO T. G. , MINYAEV R. M. , PANCHENKO I. S. 
Published: May 2016

AbstractThe diacylmethyl aryl sulfides (I) are converted to the title compounds, i.e. the sodium salts (II).
ChemInform Abstract: Assignment of the 1H‐ and 13C‐NMR Spectra of Congested Helicenes Using Two‐Dimensional NMR Methods: Phenanthro(3′,4′:3,4)phenanthro(2,1‐b)thiophene.
Authors: ZEKTZER A. S. , STUART J. G. , MARTIN G. E. , CASTLE R. N. 
Published: May 2016

AbstractThiophene‐2‐acetonitrile (I) and naphthalene‐1‐carboxaldehyde (II) are combined to produce the olefine (III).
ChemInform Abstract: Preparation of 1,5‐Disubstituted 4‐Sulfonylpyrazoles, β‐Cyano‐β‐sulfonylenamines and 5‐Substituted 4‐Sulfonylisoxazoles from β‐Keto‐β‐sulfonylenamines.
Authors: TAKAHASHI M. , MAMIYA T. , HASEGAWA H. , NAGAI T. , WAKITA H. 
Published: May 2016

AbstractThe sulfonyl ketones (I) react with the dimethylformamide acetal (II) to produce the enamines (III).
ChemInform Abstract: Preparation and Cycloaddition of Functionalized 4,6‐Dialkylpyrone‐5‐ carboxylates. Synthesis of Bicyclic Lactones and Substituted Benzoates.
Authors: JUNG M. E. , HAGENAH J. A. 
Published: May 2016

AbstractCyclization of the ketoesters (Ia) and (Ib) yields the pyrones (IIa), (IV), and (VIIa).
ChemInform Abstract: Rearrangements of 4‐(2‐Aminophenyl)‐1,4‐dihydro‐2,6‐dimethyl‐3,5‐pyridinedicarboxylic Acid Diethyl Ester.
Authors: KIM D. H. 
Published: May 2016

AbstractThe dihydropyridine (I) is refluxed in pyridine, producing a mixture of the compounds (II) ‐ (V).
ChemInform Abstract: Intramolecular Photocycloadditions on Dioxolenones: An Efficient Method for the Synthesis of Medium‐Sized Rings.
Authors: WINKLER J. D. , HEY J. P. , HANNON F. J. , WILLIARD P. G. 
Published: May 2016

AbstractPhotolysis of the dienones (I), (VI), and (XI) yields the intramolecular cycloadducts (II), (III), (VII), and (XII).
ChemInform Abstract: A Facile Synthesis of 1‐Aryl‐3‐heteroaryl‐1H‐pyrazolo(3,4‐b)quinoxalines and Related Compounds with Antifungal Activity.
Authors: KURASAWA Y. , MURAMATSU M. , YAMAZAKI K. , TAJIMA S. , OKAMOTO Y. , TAKADA A. 
Published: May 2016

AbstractThe tetrahydroquinoxalinone (I) is converted to the hydrazone (IV) which is cyclized and then transformed into the hydrazide (VI).
ChemInform Abstract: Degradations of 1‐Methyl‐3‐benzenesulfonyloxyalloxazine by Nucleophilic Reagents.
Authors: HAMBY J. M. , BAUER L. 
Published: May 2016

AbstractReaction of the alloxazine (I) with nucleophiles such as hydroxide, triethylamine, the alcohols (IV), methoxide, or piperidine (VII) yields the cleavage products (II), (III), (V), (VI), and (VIII) ‐ (X).
ChemInform Abstract: The Preparation of Selected Benzopyrano(3,4‐b)pyrazoles by the Condensation of C(α),N‐Dilithiocarboalkoxyhydrazines and Salicylate Esters.
Authors: HUFF A. M. , BEAM C. F. 
Published: May 2016

AbstractThe N‐carboalkoxyhydrazones (I) are converted to the dilithio derivatives (II) which are coupled with the salicylate (III), producing the fused pyrazoles (IV).
ChemInform Abstract: Quinazolines and 1,4‐Benzodiazepines. Part 95. Synthesis of 1,4‐Benzodiazepines by Ring Expansion of 2‐Chloromethylquinazolines with Carbanions.
Authors: WALSER A. , FLYNN T. , MASON C. , FRYER R. I. 
Published: May 2016

AbstractThe chloromethylquinazoline N‐oxides (I) undergo ring expansion with the anions derived from (II), yielding the benzodiazepine N‐oxides (III).
ChemInform Abstract: Synthesis of Some Isomeric 4,11‐Dihydro‐5H‐(1)benzoxocino(3,4‐d) or (3,4‐c)isoxazol‐5‐ones and Isomeric 4,5,10,11‐Tetrahydrobenzo(5,6)cycloocta(2,1‐d) or (1,2‐c)isoxazol‐5‐ones.
Authors: DESHAYES C. , CHABANNET M. , GELIN S. 
Published: May 2016

AbstractThe enamine (I) reacts with the acyl chlorides (II) and subsequently with hydroxylamine to produce the isoxazoles (III), together with the isomeric by‐products (IV).
ChemInform Abstract: Reaction of Pyridine‐1‐Oxide with Methyl Propiolate: A Pyridooxepine and Other Novel Products.
Authors: ABRAMOVITCH R. A. , KISHORE D. , KONIECZNY M. , DAUTER Z. 
Published: May 2016

AbstractReaction of pyridine‐1‐oxide (I) with methyl propiolate (II) yields a mixture of the compounds (III) ‐ (VII).
ChemInform Abstract: Cyclophosphites and Amidophosphites of 3,5‐Di‐tert‐butylpyrocatechol.
Authors: NIFANT'EV E. E. , KUKHAREVA T. S. , SOLDATOVA I. A. , CHUKBAR T. G. 
Published: May 2016

AbstractStarting with the pyrocatechol (I), the cyclic phosphorous acid derivatives (II), (V), and (VIII) ‐ (X) are synthesized as shown in the reaction scheme.
ChemInform Abstract: Organo‐Arsenic Compounds with an As=N Bond. Part 3. Reaction of Diphenyltrichloroarsorane with Primary Aromatic Amines. Diphenyl‐N,N′‐diarylarsamidines and Their Properties.
Authors: KOKOREV G. I. , YAMBUSHEV F. D. , AL'METKINA L. A. 
Published: May 2016

AbstractDiphenyltrichloroarsorane (I) react with the aromatic amines (II) to give the arsamidines (III) which are hydrolyzed, producing diphenylarsinic acid (IV).
ChemInform Abstract: Control of Regiochemistry in Bismetallation of 1‐Decyne.
Authors: SHARMA S. , OEHLSCHLAGER A. C. 
Published: May 2016

Abstract1‐Decyne (I) reacts with tributylstannyldiethylaluminum (II) in the presence of Cu(I) ions to give the adducts (IV) and (V).
ChemInform Abstract: Preparation of Gold Derivatives of Nitrido Clusters. Structural Characterization of Ph3PAuFeRu3N(CO)12.
Authors: BLOHM M. L. , GLADFELTER W. L. 
Published: May 2016

AbstractThe reaction of the nitrides (I) with Ph3PAuCl and TlPF6 leads to the Au‐phosphine adducts (II).
ChemInform Abstract: Reaction of (Os5H2(CO)15) with Pyridine: Crystal and Molecular Structures of (Os5H3(CO)14(C5H4N)) and (Os5H2(CO)14(C5H5N)).
Authors: JOHNSON B. F. , LEWIS J. , NELSON W. J. H. , PEARSALL M. A. , RAITHBY P. R. , ROSALES M. J. , MCPARTLIN M. , SIRONI A. 
Published: May 2016

AbstractThe title reaction (1:2 molar ratio) in refluxing n‐octane affords the three neutral products (I), (II), and (III) (two isomers), together with the monoanion (Os5H(CO)15)‐.
ChemInform Abstract: Sulphur‐Arsenic Ligands. Dimethyl(methylthio)arsine Complexes of Halogenotrimethylplatinum(IV) and Tricarbonylhalogenorhenium(I).
Authors: ABEL E. W. , BECKETT M. A. 
Published: May 2016

AbstractDimethyl(methylmercapto)arsine, prepared with a yield of 69% from AsClMe2 and Pb(SMe)2 in dry light petroleum, is a potentially ambidentate ligand.
ChemInform Abstract: Peptide‐Mediated Chiral Discrimination in Bilipeptides: Biliverdin Di‐ and Tripeptides.
Authors: KROIS D. , LEHNER H. 
Published: May 2016

AbstractThe biliverdin‐IXα peptide derivatives (III) are prepared from biliverdin‐IXa (Ia) and the appropriate amino acid or peptide components (II).
ChemInform Abstract: Asymmetric Synthesis of Lysine Derivatives by Diastereoselective Hydrogenation.
Authors: KLABUNOVSKII E. I. , LEVITINA E. S. , KAIGORODOVA L. N. , GOGOLADZE D. D. , GODUNOVA L. F. , KARPEISKAYA E. I. , CHIVADZE G. O. 
Published: May 2016

AbstractThe hydrogenation of the (S)‐α‐phenylethylamide (III) of 5‐cyano‐2‐oximinovaleric acid in dioxane or in tBuOH in the presence of Ac2O and Raney‐Ni/KOH at atmospheric pressure affords the corresponding diacetylated lysinamide (IV).
ChemInform Abstract: Synthesis of a Novel Carbapenem ‐ Potassium (5R,6R)‐1,1‐Difluoro‐2‐phenyl‐6‐(1R‐hydroxyethyl)‐carbapen‐2‐em‐3‐carboxylate (I). The Use of a New N‐Protecting Group in β‐Lactam Synthesis.
Authors: SHAH N. V. , CAMA L. D. 
Published: May 2016

AbstractPotassium (5R,6R)‐1,1‐Difluoro‐2‐phenyl‐6‐(1R‐ hydroxyethyl)‐carbapen‐2‐em‐3‐carboxylate (I).
ChemInform Abstract: High Sensitivity, High‐Resolution IR Laser Spectroscopy in Split Supersonic Jets: Application to N2HF ν1 and ν5 + ν1 ‐ ν5.
Authors: LOVEJOY C. M. , NESBITT D. J. 
Published: May 2016

AbstractAn IR spectrometer, that combines a narrow linewidth, broadly tunable IR laser with a long path length, low‐temp.
ChemInform Abstract: The Radical Cations of Sulphur (S·+ 8) and Tetrasulphur Tetranitride (S4N·+ 4): A Radiation‐ESR Study.
Authors: CHANDRA H. , RAO D. N. R. , SYMONS M. C. R. 
Published: May 2016

AbstractThe title radical cations are obtained by exposure of dilute solutions of S8 and S4N4 in CFCl3 to 60Co γ‐irradiation at 77 K. From the ESR results it is tentatively concluded that the species formed from sulphur is S+· 8 having a geometric structure close to that of S8 which, on annealing, irreversibly changes into a S+· 8 species having a stable configuration more closely related to that of S82+.
ChemInform Abstract: A Thermodynamic Model of the Hg0.8Cd0.2Te‐Iodine Transport System. Part 1. Te‐Saturated Source Material.
Authors: CHANDRA D. , WIEDEMEIER H. 
Published: May 2016

AbstractBased on the formation of an ideal solid solution between CdTe and HgTe, the thermodynamic analysis of the complex title system could be further simplified by using a source material composition of the Te‐rich boundary of the homogeneity range of Hg0.8Cd0.2Te.
ChemInform Abstract: Dielectric Spectroscopy on Aqueous Solutions of Zinc(II) Chloride, Evidence of Ion Complexes.
Authors: KAATZE U. , LOENNECKE V. + , POTTEL R. 
Published: May 2016

AbstractThe complex dielectric spectra of aqueous solution of ZnCl2 (and, for comparison, of MgCl2) have been measured over a wide range of concentrations.
ChemInform Abstract: The Redox Potential of the Azide/Azidyl Couple
Authors: ALFASSI Z. B. , HARRIMAN A. , HUIE R. E. , MOSSERI S. , NETA P. 
Published: May 2016

Abstracthas been studied by direct pulse radiolysis experiments with halide and pseudohalide (Br, I, SCN) ions and radicals and by cyclic voltammetry.