bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: N‐(Dichlorothiophosphoryl)imide Chlorides and Their Derivatives.
Authors: SEMENII V. YA. , SOLODUSHCHENKO G. F. , KUKHAR' V. P. , BONDAR' V. A. 
Published: May 2016

AbstractThe phosphorylimide chlorides (I) react with phosphorus pentasulfide to give the corresponding thiophosphorylimide chlorides (II).
ChemInform Abstract: Transmetalation from Zirconium to Selenium. Stereoselective Preparation of 1‐Phenylselenenyl‐1,3‐dienes and Isomerization Under Photochemical and Thermal Conditions.
Authors: FRYZUK M. D. , BATES G. S. , STONE C. 
Published: May 2016

AbstractThe dienylzirconium derivatives (I) react with the phenylselenenyl compounds (II) in the dark to produce stereoselectively the selenenyldienes (III).
ChemInform Abstract: Preparation and Characterization of Tris(trimethylsilyl)silyl Derivatives of Zinc, Cadmium, and Mercury. X‐Ray Crystal Structure of Zn(Si(SiMe3)3)2.
Authors: ARNOLD J. , TILLEY T. D. , RHEINGOLD A. L. , GEIB S. J. 
Published: May 2016

AbstractThe thermally stable silyl complexes (III) are prepared by reaction of 2 equiv. of the lithium derivative (I) with the metal halides (II).
ChemInform Abstract: Coordination Chemistry of the Rhenium‐Organodiazenido Core with Facultative Tetradentate Ligands Possessing Thiolate‐Amine and Thiolate‐Thioether Donor Sets. Crystal and Molecular Structures of (Re(SCH2CH2NMeCH2CH2NMeCH2CH2S)(N2COC6H4‐p‐Cl)(PPh3))·CH3OH, (Re(SCH2CH2S(CH2)3SCH2CH2S)(N2COPh)(PPh3)), and (Re(SCH2CH2S(CH2)3SCH2CH2S)(N2CO2Me)(PPh3))·CH2Cl2 and a Comparison with the Structure of the Oxidation Product (N,N′‐Dimethyl‐N,N′‐bis(sulfinatoethyl)ethylenediamine‐S,N,N′,O′) ((2‐chlorophenyl)d
Authors: NICHOLSON T. , ZUBIETA J. 
Published: May 2016

AbstractThe title complexes (III)‐(VI) are synthesized from the Re complexes (I) and the ligands (II) according to the scheme.
ChemInform Abstract: Oxygen Atom Transfer Between Rhenium, Sulfur, and Phosphorus. Characterization and Reactivity of Re(O)Cl3(Me2S)(OPPh3) and Re(O)Cl3(CNCMe3)2.
Authors: BRYAN J. C. , STENKAMP R. E. , TULIP T. H. , MAYER J. M. 
Published: May 2016

AbstractThe diphosphine complex (I) reacts with DMSO (II) to form the phosphine oxide (IV) and the sulfide phosphine oxide complex (III), not "Re(O)Cl3(Me2SO)PPh3" as had been previously reported.
ChemInform Abstract: Nonclassical Polysulfide Complexes: Cage and Ring Compounds ((MeCp)Ru(PPh3))2Sx (x = 6, 4).
Authors: AMARASEKERA J. , RAUCHFUSS T. B. , RHEINGOLD A. L. 
Published: May 2016

AbstractTreatment of the starting compound (III), prepared in high yield as shown, with solid (NBu4)2S6 (IV) gives the two neutral, diamagnetic complexes (V) and (VI), which are isolated by silica gel chromatography.
ChemInform Abstract: Mode of Coordination of Tris(2‐pyridyl)methanol to Ruthenium(II): Synthetic, Spectral, and Structural Studies of the Bis(ligand) Species.
Authors: KEENE F. R. , SZALDA D. J. , WILSON T. A. 
Published: May 2016

AbstractAccording to the scheme the two different bis(ligand)‐Ru(II) complexes (III) and (IV) are prepared which involve one neutral and one deprotonated ligand or two neutral ligands.
ChemInform Abstract: Synthesis, X‐Ray Crystal Structure, and Electrochemical Properties of the Rh4+ 2 Complex Rh2(form)4 (form: N,N′‐Di‐p‐tolylformamidinate Anion).
Authors: PIRAINO P. , BRUNO G. , LO SCHIAVO S. , LASCHI F. , ZANELLO P. 
Published: May 2016

AbstractThe title complex (III) crystallizes in the space group Pn3n with Z = 6. Unlike other dirhodium(II) carbonyl derivatives, its monocarbonyl adduct (V) is remarkably stable.
ChemInform Abstract: Synthesis of the α‐Mannosidase Inhibitors Swainsonine ((1S,2R,8R,8aR)‐1,2,8‐Trihydroxyoctahydroindolizine) and 1,4‐Dideoxy‐1,4‐imino‐D‐mannitol from Mannose.
Authors: BASHYAL B. P. , FLEET G. W. J. , GOUGH M. J. , SMITH P. W. 
Published: May 2016

AbstractThe compound (I), readily available from D‐mannose (yield: 83%), is converted to the synthon (VII) as shown.
ChemInform Abstract: Sucrochemistry. Part 37. Synthesis of 4‐C‐Methyl and 4‐C‐Allyl Derivatives of Sucrose.
Authors: CHIU A. K. B. , HOUGH L. , RICHARDSON A. C. , TOUFEILI I. A. , DZIEDZIC S. Z. 
Published: May 2016

AbstractOxidation and subsequent Grignard reaction of the partially protected sucrose derivatives (Ib) and (III) yield the corresponding 4‐C‐branched‐chain compounds (II), (V), and (VI).
ChemInform Abstract: IR Diode Laser and Microwave Spectra and Molecular Structure of an Unstable Molecule, FBO.
Authors: KAWASHIMA Y. , KAWAGUCHI K. , ENDO Y. , HIROTA E. 
Published: May 2016

AbstractFBO has been generated by dc discharge of a BF3/O2/He mixture and its vibration‐rotation and rotation spectra are recorded.
ChemInform Abstract: Surface Coordination Chemistry of Noble‐Metal Electrodes. Hydrogen/Iodine Ligand (Adsorbate) Substitution at Smooth Polycrystalline Platinum.
Authors: RODRIGUEZ J. F. , BRAVO B. G. , MEBRAHTU T. , SORIAGA M. P. 
Published: May 2016

AbstractMeasurements based on thin‐layer electrochemical methods show that adsorbate displacement/substitution occurs between iodine and hydrogen at smooth polycrystalline Pt electrodes in aqueous acid, neutral, or base electrolyte.
ChemInform Abstract: Cyclic Voltammetric Study of Copper Electrode Pretreatment for Metal Migration and Corrosion Rates.
Authors: HALL L. C. , MAJOR C. P. , STEPPAN J. J. , ROTH J. A. , VAUGHEN B. K. 
Published: May 2016

AbstractCyclic voltammetry is used to evaluate various electrode cleaning procedures by scanning cathodically in an acetate buffered NH4ClO4 solution.
ChemInform Abstract: Stereoelectronic Effects in the Ring Cleavage of Methyl Glycopyranosides Using Dimethylboron Bromide.
Authors: GUINDON Y. , ANDERSON P. C. 
Published: May 2016

AbstractThe glycoside (I) is cleaved with dimethylboron bromide and the nucleophiles (II), yielding the dihydroxytrimethylhexanes (III).
ChemInform Abstract: Synthesis and Neuroleptic Activity of a Series of 1‐(1‐(Benzo‐1,4‐dioxan‐2‐ylmethyl)‐4‐piperidinyl)benzimidazolone Derivatives.
Authors: HENNING R. , LATTRELL R. , GERHARDS H. J. , LEVEN M. 
Published: May 2016

AbstractThe 6‐ and 7‐fluoro analogues (VIII) of the key intermediates (X) are synthesized from the corresponding fluorophenols (I) as outlined in the reaction scheme.
ChemInform Abstract: Ultrasonically Improved Reductive Properties of an Aqueous Zn‐NiCl2 System. Part 1. Selective Reduction of α,β‐Unsaturated Carbonyl Compounds.
Authors: PETRIER C. , LUCHE J.‐L. 
Published: May 2016

AbstractThe reduction of α,β‐unsaturated ketones such as (I) and (III) with zinc and nickel dichloride to give saturated compounds such as (II) or (IV) is optimized by means of sonication.
ChemInform Abstract: Volumes of Activation for the Cycloaddition Reactions of Phenylhalocarbenes to Alkenes.
Authors: TURRO N. J. , OKAMOTO M. , GOULD I. R. , MOSS R. A. , LAWRYNOWICZ W. , HADEL L. M. 
Published: May 2016

AbstractAbsolute rate constants for the cycloaddition of the arylhalocarbenes (II) to the alkenes (III) are measured as a function of pressure (0.1 to 203 MPa).
ChemInform Abstract: Catalytic Hydrogenation of Olefins in Biphasic Water‐Liquid System.
Authors: LARPENT C. , DABARD R. , PATIN H. 
Published: May 2016

AbstractOlefins such as (I), (III), and (V) are hydrogenated in a biphasic aqueous solution in the presence of a catalyst system obtained from RhCl3 and a triphenylphosphine trisulfonate.
ChemInform Abstract: A New Method for the Synthesis of α‐Fluoro and α,α‐Difluoro Benzylic Ketones, Esters and Nitriles.
Authors: LAURENT E. , MARQUET B. , TARDIVEL R. , THIEBAULT H. 
Published: May 2016

AbstractAnodic oxidation of the benzyl methyl ketones (I) in acetonitrile in the presence of fluoride gives mixtures of the α‐fluoro ketones (II) and the acetamido derivatives (III).
ChemInform Abstract: Synthesis and Antiarrhythmic Activity of New 3‐(2‐(ω‐Aminoalkoxy)phenoxy)‐4‐phenyl‐3‐buten‐2‐ones and Related Compounds.
Authors: SALIMBENI A. , MANGHISI E. , FREGNAN G. B. , PRADA M. 
Published: May 2016

AbstractStarting with the mono enol ethers (III) or (VI), the title compounds (XI) are synthesized by the following routes: 1. aminoalkylation of (VI) with the ω‐chloroalkylamines (X).
ChemInform Abstract: 1‐Vinyl‐4‐methyl‐2,6,7‐trioxabicyclo(2.2.2)octanes: Unsaturated Homoenolate Anion Equivalents.
Authors: RICHARDSON S. K. , JEGANATHAN A. , WATT D. S. 
Published: May 2016

AbstractThe acrylic acids (II) are esterified with the hydroxymethyloxetane (IV) to give the esters (V) which rearrange in the presence of boron trifluoride to produce the bicyclic orthoesters (VI).
ChemInform Abstract: Cycloadditions of Vinylindoles to Annellated Indole Derivatives. Part 4. Diels‐Alder Reactions of 2′‐Substituted 3‐Vinyl‐1H‐indoles to New Annellated Indole and Carbazole Derivatives.
Authors: PFEUFFER L. , PINDUR U. 
Published: May 2016

AbstractCycloaddition of the vinylindole (I) with the dienophile (II) gives the products (III) and (IV) resulting from endo‐ and exo‐adduct formation and subsequent (1,3) H shift or H2 elimination.
ChemInform Abstract: Synthesis and Spasmolytic Activity of Aminoalkyl 2‐Substituted 2‐(1,2‐ Benzisoxazol‐3‐yl)acetates.
Authors: NARUTO S. , UEDA S. , YOSHIDA T. , MIZUTA H. , KAWASHIMA K. , KADOKAWA T. 
Published: May 2016

AbstractThe benzisoxazolylacetate (I) is alkylated with cyclohexyl iodide (II) or the α,ω‐dibromoalkanes (IV) to form the esters (III), which are hydrolyzed under acidic or alkaline conditions to give the corresponding acids (V).
ChemInform Abstract: Benzopyrans. Part 22. Reactions of Some Simple Condensates of 3‐Formyl‐4‐oxo‐4H‐(1)benzopyrans with Diazomethane.
Authors: GHOSH C. K. , BHATTACHARYYA A. , GHOSH‐DASTIDAR P. P. 
Published: May 2016

AbstractTreatment of the ethylenes (Ia) and (Ib) with diazomethane (IV) according to A) yields exclusively the dihydrofurans (II).
ChemInform Abstract: Synthesis of 2‐Amino‐3‐(2′‐pyridylamino)benzofuran and Kinetics of Its Rearrangement in the Presence of Alkali and Iron(III).
Authors: PANDA D. , DASH A. C. , DASH B. 
Published: May 2016

AbstractThe title compound (IV) is synthesized as shown in the scheme (no yield given).
ChemInform Abstract: Potential Antitumor Agents. Part 51. Synthesis and Antitumor Activity of Substituted Phenazine‐1‐carboxamides.
Authors: REWCASTLE G. W. , DENNY W. A. , BAGULEY B. C. 
Published: May 2016

AbstractUllmann reaction between the anilines (I) and the 3‐nitrobenzoic acids (II) gives the products (III).
ChemInform Abstract: 1,3‐Oxazines and Related Compounds. Part 14. Facile Synthesis of 2,3,6‐Trisubstituted 2,3‐Dihydro‐1,3‐oxazine‐5‐carboxylic Acids and 1,4‐Disubstituted 3‐Acyl‐β‐lactams from Acyl Meldrum′s Acids and Schiff Bases.
Authors: YAMAMOTO Y. , WATANABE Y. 
Published: May 2016

AbstractReaction of the acylated Meldrum's acids (I) with the benzaldimines (II) in the presence of the silyl chloride (III) produces the silyl oxazinonecarboxylates (IV) which are directly hydrolyzed to form the acids (V).
ChemInform Abstract: Antiviral Compounds. Part 16. Antiviral Activity of 1,2,4‐Triazines.
Authors: SHIBAMOTO S. , NISHIMURA T. 
Published: May 2016

AbstractThe α‐keto oximes (I) react with the thiosemicarbazone (II) to produce the thiosemicarbazides (III) which are cyclized, forming the 3‐mercapto‐1,2,4‐triazines (IV).
ChemInform Abstract: Preparation of Thermodynamically Stable Enol Silyl Ethers of γ,δ‐Unsaturated Ketones by Palladium‐Catalyzed Decarboxylation‐Allylation of Allyl 2,3‐Disubstituted 3‐Trimethylsiloxyacrylates.
Authors: TSUJI J. , OHASHI Y. , MINAMI I. 
Published: May 2016

AbstractThe allyl cycloalkanone‐2‐carboxylates (I) are converted to the silyl enol ethers (II) which are decarboxylated in the presence of Pd catalysts to give the allyl enol ethers (III).
ChemInform Abstract: Interaction Between Copper(II) Ions Separated by 7.6 Å. Crystal Structure and Magnetic Properties of (μ‐Iodanilato)bis((N,N,N′,N′‐tetramethylethylenediamine)copper(II)) Diperchlorate.
Authors: TINTI F. , VERDAGUER M. , KAHN O. , SAVARIAULT J.‐M. 
Published: May 2016

AbstractThe dicationic binuclear Cu(II) complexes (I) and (II) are prepared by treatment of nitranilic acid or of the 1:1 Cu chain compounds of the corresponding 2,5‐dihydroxy‐1,4‐benzoquinones with Cu(II) perchlorate and N,N,N',N'‐tetramethylethylenediamine in methanol.
ChemInform Abstract: Structure‐Activity Relationships in the 2‐Arylcarbapenem Series: Synthesis of 1‐Methyl‐2‐arylcarbapenems.
Authors: GUTHIKONDA R. N. , CAMA L. D. , QUESADA M. , WOODS M. F. , SALZMANN T. N. , CHRISTENSEN B. G. 
Published: May 2016

AbstractTreatment of the S‐pyridyl thioesters (I) with the Grignard reagents (II) gives the aryl ketones (III) which produce the protected carbapenems (IV) on thermolysis.
ChemInform Abstract: Calculated Circular Dichroism of the n‐π* Transition in N‐Acetylglucosamines.
Authors: COHEN A. H. , STEVENS E. S. 
Published: May 2016

AbstractThe rotational strength of the amide n‐π* transition of 2‐acetamido‐2‐deoxy‐α‐ and ‐β‐D‐glucopyranoses is calculated as a function of C1 hydroxyl, C3 hydroxyl, and acetamido group orientations.
ChemInform Abstract: Activation Energies for Molecular Tumbling and Cyclopentadienyl Rotation in (M(η5‐C5H5)(η4‐cod)) (M: Rh or Ir; cod: cycloocta‐1,5‐diene) and the X‐Ray Crystal Structure of and Bonding in (Rh(η5‐C5H5)(η4‐cod)).
Authors: ADAMS H. , BAILEY N. A. , MANN B. E. , TAYLOR B. F. , WHITE C. , YAVARI P. 
Published: May 2016

AbstractThe Rh title complex crystallizes in the space group P21/c with Z=4.
ChemInform Abstract: Equilibrium and Thermodynamic Study of the Aqueous Complexation of 1,4,7‐Triazacyclononane‐N,N′,N′′‐triacetic Acid with Protons, Alkaline‐Earth‐Metal Cations, and Copper(II).
Authors: BEVILACQUA A. , GELB R. I. , HEBARD W. B. , ZOMPA L. J. 
Published: May 2016

AbstractIt is shown that the trianion of the title compound is protonated at the nitrogen sites in the first and second step and that further protonation involves carboxylate groups.
ChemInform Abstract: Oxidation of Olefins by Molecular Oxygen with New Precursors: Palladium Chloro Complexes/BiCl3/LiCl in Ethanol.
Authors: BREGEAULT J.‐M. , FARAJ M. , MARTIN J. , MARTIN C. 
Published: May 2016

AbstractTreatment of the olefins (I) with oxygen in ethanol (II) in the presence of Pd(II) chloro complexes/BiCl3/LiCl yields the ketones (III) as the main products, together with acetaldehyde (IV) and the acetal (V).
ChemInform Abstract: Electrophilic Aromatic Substitution. Part 33. Kinetics and Products of Aromatic Nitrations in Solutions of Dinitrogen Pentaoxide in Nitric Acid.
Authors: MOODIE R. B. , STEPHENS R. J. 
Published: May 2016

AbstractThe nitration of (I) leads predominantly to the m‐nitro isomer (II).
ChemInform Abstract: Hypervalent Iodine Oxidation of 5‐Substituted and 5‐Methyl‐4‐substituted Pyrazol‐3(2H)‐ones. A Facile Synthesis of 2‐Alkynoic and 2,3‐Allenic Esters.
Authors: MORIARTY R. M. , VAID R. K. , FARID P. 
Published: May 2016

AbstractThe pyrazolones (I) and (III) are cleaved by iodosylbenzene diacetate in the presence of methanol, producing the methyl alkynoates (II) or the methoxycarbonylallenes (IV).
ChemInform Abstract: Synthesis of Ethynylanthraquinones.
Authors: PISKUNOV A. V. , MOROZ A. A. , SHVARTSBERG M. S. 
Published: May 2016

AbstractPd‐catalyzed coupling of the iodoanthraquinones (I) with the acetylenic alcohol (II) and subsequent alkaline cleavage of the condensation products (III) gives the ethynylanthraquinones (IV).
ChemInform Abstract: Synthesis and Antimicrobial Activity of Spiro(2‐isoxazoline‐4,2′‐(1′H)‐ naphthalen‐1‐ones).
Authors: RAJANARENDAR E. , RAO C. J. , MURTHY A. K. 
Published: May 2016

AbstractThe benzylidenetetralone (III), prepared from tetralone (I) and benzaldehyde (II), reacts with the nitrile oxides (IV) to yield the spiroisoxazolines (V).
ChemInform Abstract: Carbon‐Carbon Bond Formation by Intramolecular 1,4‐Dipolar Cycloaddition: Heterocyclic Betaines Generated in situ from Amides and N‐Substituted Amides.
Authors: POTTS K. T. , DERY M. O. , KULLNIG R. K. 
Published: May 2016

AbstractCycloaddition reaction and acylation of the allyl‐substituted salicylamides (Ib) and (V) with chlorocarbonyl phenyl ketene (II) give the oxazine derivatives (III) and (VI) which release carbon dioxide on thermolysis, producing the chromenodihydropyridinones (IVb), (VII), and (VIII).
ChemInform Abstract: The Preparation of the First α‐Vinylidene‐β‐lactams.
Authors: BUYNAK J. D. , MATHEW J. , RAO M. N. , HALEY E. , GEORGE C. , SIRIWARDANE U. 
Published: May 2016

AbstractChlorination of the bicyclic trimethylsilylethylidene‐β‐lactam (IIa), prepared from the allene (I), by treatment with hypochlorite gives the allylic chloride (III) which undergoes dechlorosilylation in the presence of fluoride, forming the allene (IV).
ChemInform Abstract: Synthesis and Biological Activity of the Hydrochlorides of α‐Phenyl‐β‐ amino‐(3‐fluoro‐4‐methoxy)propiophenones and Their Reduction Products.
Authors: GEVORGYAN G. A. , GABRIELYAN S. A. , VLASENKO E. V. , DURGARYAN L. K. , MNDZHOYAN O. L. 
Published: May 2016

AbstractMannich reaction of the propiophenone (I) with the cyclic amines (III) gives the amino ketones (IV) which are transformed into their hydrochlorides.
ChemInform Abstract: New Methods for the Regiospecific Substitution of Some N‐Heteroaromatic Ring Systems with Low Reactivity.
Authors: ANDERS E. , MARKUS F. 
Published: May 2016

AbstractThe pyridinium triflates (I) react with triphenylphosphine (IIb) in the presence of triethylamine to give the phosphonium salts (III).
ChemInform Abstract: Structural Effect on the Iodolactonization of Unsaturated Organo‐Phosphorus Compounds.
Authors: YE M.‐C. , CHAI W.‐G. , LI L.‐P. , ZHAO Y.‐F. 
Published: May 2016

AbstractIodolactonization of the alkenyl phosphoric acid derivatives (I) yields the phosphaheterocycles (III) and (IV).
ChemInform Abstract: Synthesis of New Organo‐Silicon and Organo‐Germanium Derivatives of Diallyl Isocyanurate and Cyanuric Acid.
Authors: GORDETSOV A. S. , KOZINA A. P. , BREVNOVA T. N. , CHEREPENNIKOVA N. F. , SEMENOV V. V. , SKOBELEVA S. E. , CHULKOVA T. I. , RUKEVICH O. S. , DERGUNOV YU. I. 
Published: May 2016

AbstractThe diallyl isocyanurate silver salt (I) reacts with the chlorodisilane (II) to give the O‐silylated compound (III), whereas with the germylpropionyl chlorides (IV) the N‐acylated derivatives (V) are prepared.
ChemInform Abstract: Insertion of 2,6‐Dimethylphenyl Isocyanide into the U‐N Bond of (U(η‐C5H5)3(NEt2)). Crystal Structure of (U(η‐C5H5)3(C(NEt2)=NC6H3Me2‐2,6)).
Authors: ZANELLA P. , BRIANESE N. , CASELLATO U. , OSSOLA F. , PORCHIA M. , ROSSETTO G. , GRAZIANI R. 
Published: May 2016

AbstractInsertion of the title isocyanide (II) into the U‐N bonds of the U compounds (I) and (IV) are observed.
ChemInform Abstract: Chiral Recognition in Ion Pairing of an Optically Active Tris(ethylenediamine)cobalt(III) Cation and Application to Chromatographic Resolution of Metal Complex Anions.
Authors: TATEHATA A. , FUJITA M. , ANDO K. , ASABA Y. 
Published: May 2016

AbstractA series of Co(III) complex anions (I)‐(V) have been completely resolved using Λ‐(Co(en)3)Cl3 as the eluting agent.
ChemInform Abstract: Tetranuclear Amido Complexes of Copper(I): A Synthetic and Structural Study.
Authors: GAMBAROTTA S. , BRACCI M. , FLORIANI C. , CHIESI‐VILLA A. , GUASTINI C. 
Published: May 2016

AbstractThe synthesis of the thermally stable tetrameric amido derivatives (III) is performed by a metathesis reaction on copper(I) halides (II) with the lithium amides (I).
ChemInform Abstract: Reactions of Rhodium(V) Hydrido‐Silyl Complexes with Butyl‐lithium and with Lithium Triethylhydridoborate.
Authors: RUIZ J. , MANN B. E. , SPENCER C. M. , TAYLOR B. F. , MAITLIS P. M. 
Published: May 2016

AbstractReaction of the dihydrido‐disilyl complexes (I) with LiBu leads to the anionic monohydrides (II) which regenerate the dihydrides (I) on treatment with MeOH.
ChemInform Abstract: Coordination Chemistry of Higher Oxidation States. Part 23. Synthesis and Properties of Tetrahalogenoiridium(IV) Complexes, (IrL2X4) (X: Cl or Br; L: pyridine, PR3, AsR3, SbR3, SR2, or SeR2). Crystal and Molecular Structure of trans‐(Ir(AsEt3)2Br4).
Authors: CIPRIANO R. A. , LEVASON W. , PLETCHER D. , POWELL N. A. , WEBSTER M. 
Published: May 2016

AbstractThe Ir complexes are prepared as outlined in the scheme.
ChemInform Abstract: A Formal Synthesis of Aspartame via the Oxaziridine ‐ Amide Rearrangement.
Authors: DUHAMEL P. , GOUMENT B. , PLAQUEVENT C. 
Published: May 2016

AbstractReaction of the formyl‐β‐lactam (I) with the phenylalanine ester (II) and subsequent oxidation with a peracid give the oxaziridine (IIIa) which is desilylated, yielding (IIIb).
ChemInform Abstract: Amelioration of the Conjugate Addition Chemistry of α‐Alkoxycopper Reagents: Application to the Stereospecific Synthesis of C‐Glycosides.
Authors: HUTCHINSON D. K. , FUCHS P. L. 
Published: May 2016

AbstractAlkoxymethyllithium reagents such as (IVa) are synthesized via transmetalation of the corresponding alkoxystannanes, e.g. (III) (obtained, in turn, from the compounds (I) and (II)).
ChemInform Abstract: The Synthesis of Heteroaromatic Prostacyclin Analogues via Keto Alkyne Cyclization.
Authors: COOK S. , HENDERSON D. , RICHARDSON K. A. , TAYLOR R. J. K. , SAUNDERS J. , STRANGE P. G. 
Published: May 2016

AbstractCyclization reaction of the keto alkynes (I) or (III) provides the furans (II) or (IV); (IV) is further converted to the benzofuran prostacyclin analogue (XI) via the intermediates shown in the scheme.
ChemInform Abstract: Free‐Radical Anellation in the Synthesis of Bicyclic β‐Lactams. Part 5. Synthesis of Carbapenams.
Authors: BACHI M. D. , DE MESMAEKER A. , STEVENART‐DE MESMAEKER N. 
Published: May 2016

AbstractRadicalic cyclization of the allyl lactams (Ia) and (Ib) yields mixtures of the carbacephams (III) and (IV) or the carbapenams (VI), together with the dehalogenation compounds (V) or (VII).
ChemInform Abstract: The Characterization and X‐Ray Crystal Structure of Pentabromodiselenium Hexafluoroarsenate, Se2Br5AsF6; Some Thermodynamic Considerations and the Nonexistence of Se2I5AsF6.
Authors: MURCHIE M. P. , PASSMORE J. , WHITE P. S. 
Published: May 2016

AbstractSe2Br5AsF6 (I), prepared by reaction of either Se, Br2, and AsF5 in liquid SO2 or Se4(AsF6)2 and Br2 in SO2(l) (previously described), crystallizes in the rhombohedral system, space group R3 with Z = 9. The structure consists of discrete Se2Br5+ and AsF6‐ ions with some cation‐anion interaction.
ChemInform Abstract: A First Investigation of Flow‐Through Porous Electrodes Made of Metallic Felts or Foams.
Authors: MARRACINO J. M. , COEURET F. , LANGLOIS S. 
Published: May 2016

AbstractFlow‐through electrodes have been fabricated using one Ni felt (fibrous and anisotropic texture) and two Ni foams (reticulated and nearly isotropic texture).
ChemInform Abstract: The Susceptibility of Type AISI 304 Stainless Steel to Transgranular and Intergranular SCC in 40% MgCl2 Solution at 100 °C
Authors: MANFREDI C. , MAIER I. A. , GALVELE J. R. 
Published: May 2016

Abstracthas been studied using constant potential intermediate strain rate and slow strain rate techniques.
ChemInform Abstract: Adhesion and Inhibitor Properties of Organic Coatings Investigated with Very Thin Polymer Films on Noble Metal Electrodes.
Authors: DOBLHOFER K. , EISELT I. 
Published: May 2016

AbstractPt electrodes coated with acrylonitrile polymer films, prepared by the method of glow‐discharge polymerization, are investigated by measurement of the time‐dependent impedance in aqueous 1MH2SO4 and the rates of electrocatalytic charge‐transfer reactions as well as the analysis of the interfacial capacitance.
ChemInform Abstract: Selective Molecular Recognition and Separation of Isomeric and Partially Hydrogenated Arenes.
Authors: VOEGTLE F. + , MUELLER W. M. + , WERNER U. , LOSENSKY H.‐W. 
Published: May 2016

AbstractThe hexahydrochloride (IIIb)·6 HCl of the host (IIIb) in aqueous solutions forms specific 1:1 complexes with aromatic molecules such as acenaphthylene, perylene, phenanthrene, pyrene, triphenylene, fluoranthene, benzo(def)chrysene (≡1,2‐benzpyrene), and benzo(ghi)perylene (≡1,12‐benzperylene), when the guest has a topology suitable to fit the cavity of the host (IIIb).