bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: X=Y‐ZH Systems as Potential 1,3‐Dipoles. Part 9. Azaallyl Anion Precursors from the Reaction of (1,3‐Dioxoindan‐2‐ylidene)malononitrile with α‐Amino Acids and Their Methyl Esters.
Authors: GRIGG R. , MONGKOLAUSSAVARATANA T. 
Published: May 2016

AbstractThe reactions between the malononitrile (I) and glycine (IIa), valine (IIb) or the amino acid esters (IIc)‐(IIe) proceed via a Michael addition/elimination sequence and regiospecific substitution of one of the cyano groups to afford the products (III).
ChemInform Abstract: De novo Synthesis of Carbohydrates and Related Natural Products. Part 29. Synthesis of Partially Protected Carbohydrates from meso‐Divinylglycol.
Authors: SCHMIDT R. R. , FRISCHE K. 
Published: May 2016

AbstractThe known enantiomerically pure epoxide (I) (obtained from the title compound) is cleaved by different nucleophiles at C‐1 to give compounds such as (II).
ChemInform Abstract: Conductivity of Ion Implanted and Rapid Thermal Annealed Semi‐Insulating Polycrystalline Silicon
Authors: OZGUEZ V. H. + , WORTMAN J. J. , HAUSER J. R. , LITTLEJOHN M. A. , ROZGONYI G. A. , CURRAN P. 
Published: May 2016

Abstract(SIPOS).
ChemInform Abstract: Matrix Isolation and Mass Spectrometric Studies on the Vaporization of OsO2F3: Characterization of Molecular OsO2F3.
Authors: HOPE E. G. , LEVASON W. , OGDEN J. S. 
Published: May 2016

AbstractThe matrix IR and MS spectra obtained during heating solid OsO2F3 (I) to temp. in the range ∼ 300‐400 K indicate a complex mode of decomposition.
ChemInform Abstract: The Preparation of SeI3SbF6 (I) and TeI3SbF6 (II); the X‐Ray Crystal Structures of SBr3AsF6 (III), SeI3AsF6 (IV), SeI3SbF6, and TeI3SbF6; Some Considerations of the Energetics of the Formation of SBr3AsF6 and SeI3AsF6.
Authors: JOHNSON J. P. , MURCHIE M. , PASSMORE J. , TAJIK M. , WHITE P. S. , WONG C.‐M. 
Published: May 2016

AbstractThe compounds (I) and (II) are prepared by reaction of SbF5, I2, Se and Te, resp., in SO2.
ChemInform Abstract: Structures of the Superconducting Oxides Bi2(Sr1‐xCax)2CuO8‐δ and Bi (Sr1‐yCay)3Cu2O10‐δ with 0 ≤ x ≤ 0.3 and 0.16 ≤ y ≤ 0.33.
Authors: VON SCHNERING H. G. , WALZ L. , SCHWARZ M. , BECKER W. , HARTWEG M. , POPP T. , HETTICH B. , MUELLER P. + , KAEMPF G. + 
Published: May 2016

AbstractThe title oxides are prepared by annealing mixtures of binary oxides or carbonates in air (corundum crucible, 1070‐1255 K).
ChemInform Abstract: Some Phase Relationships Between Basic Bismuth Chlorides in Aqueous Solutions at 25 °C.
Authors: TAYLOR P. , LOPATA V. J. 
Published: May 2016

AbstractThe sequential hydrolysis of BiOCl and the reaction of α‐Bi2O3 (I) with dissolved Cl‐ are examined and solutions of (I) containing the basic chlorides Bi12O17Cl2, BiOCl, and a daubreeite‐like compound with approximate composition Bi2O2(OH)Cl are analyzed to study the interconversion of these solids.
ChemInform Abstract: Chemical and Electrochemical Equilibria and Kinetics in Aqueous Cr(III)/Cr(II) Chloride Solutions.
Authors: KELSALL G. H. , HOUSE C. I. , GUDYANGA F. P. 
Published: May 2016

AbstractThe effects of Cr(III) speciation and electrolyte composition on the electrochemical behavior of the Cr(III)/Cr(II) couple are studied by voltammetry at a hanging mercury drop electrode in chloride and sulfate electrolytes, which are analyzed by spectrophotometry.
ChemInform Abstract: Underpotential Deposition of Copper and Silver on Polycrystalline Ruthenium Electrodes.
Authors: NGUYEN VAN HUONG C. , GONZALEZ‐TEJERA M. J. 
Published: May 2016

AbstractThe electrodeposition of the first monolayer of Cu on Ru occurs in a potential range which is clearly separated from that of bulk Cu deposition.
ChemInform Abstract: Structure and Chemistry of Chemisorbed PF3, PF2, and PF on Ni(111): An ESDIAD Study.
Authors: ALVEY M. D. , YATES J. T. JUN. 
Published: May 2016

AbstractUsing the electron stimulated desorption ion angular distribution technique, TPD, AES, and LEED, PF3 is observed to adsorb molecularly at 85 K on Ni atop sites in the Ni(111) surface.
ChemInform Abstract: Structure of Rh/TiO2 in the Normal and SMSI State as Determined by Extended X‐Ray Absorption Fine Structure and High‐Resolution Transmission Electron Microscopy.
Authors: MARTENS J. H. A. , PRINS R. , ZANDBERGEN H. , KONINGSBERGER D. C. 
Published: May 2016

AbstractAfter reduction of the title catalyst in H2 at 473 K (normal state) the metal particles (containing ∼ 5 Rh atoms) are preferentially located on edges of the TiO2 crystallites.
ChemInform Abstract: Synthesis of Condensed Double Phosphates of Cesium and Manganese in Melts of Polyphosphoric Acid.
Authors: GUZEEVA L. S. , TANANAEV I. V. 
Published: May 2016

AbstractThe reactions proceeding in the system Cs2O‐MnO2‐P2O5‐H2O are investigated between 150 and 400 °C. Three types of condensed double diphosphates of Mn(III) are isolated: the diphosphate Cs2MnH3(P2O7)2, the triphosphate CsMnHP3O10 and the cyclohexaphosphate Cs3Mn3(P6O18)2.
ChemInform Abstract: 119Sn NMR Studies on Adduct Formation and Stereochemistry of Organotin(IV) Trihalides.
Authors: COLTON R. , DAKTERNIEKS D. 
Published: May 2016

Abstract119Sn and 31P NMR spectra for a series of adducts of RSnX3 (R: ‐Me, ‐Ph; X: ‐Cl, ‐Br) with halides, tributylphosphine, and tributylphosphine oxide are discussed.
ChemInform Abstract: Metal Complexes with Tetrapyrrole Ligands. Part 49. Solid‐State and Solution Structures of Iron(III) Porphodimethenes. Effects of Steric Hindrance.
Authors: BOTULINSKI A. , BUCHLER J. W. , LEE Y. J. , SCHEIDT W. R. , WICHOLAS M. 
Published: May 2016

Abstract(Ia), prepared by a published method, crystallizes in C2/c with Z=4.
ChemInform Abstract: Crystal and Molecular Structure of the Tungsten‐Carbene Complex Cyclic W(C(CH2)3CH2)(OCH2‐tBu)2Br2 and of Its Gallium Tribromide Adduct. A Structural Approach to the Mechanism of Olefin Metathesis.
Authors: YOUINOU M. T. , KRESS J. , FISCHER J. , AGUERO A. , OSBORN J. A. 
Published: May 2016

AbstractThe title compound crystallizes as the dimer (I) in the space group P21/c with Z=2.
ChemInform Abstract: cis‐Dichlorobis(methylamine)platinum(II): Crystal and Molecular Structures of Two Crystal Forms.
Authors: WIMMER S. , WIMMER F. , JAUD J. , JOHNSON N. P. , CASTAN P. 
Published: May 2016

AbstractThe title complex exists in the solid state in two different crystallographic forms, form A and form B. The structures of A (space group P21/n, Z=4) and B (P21/c, Z=12) are determined by X‐ray analysis.
ChemInform Abstract: Bifunctional Annulating Reagents: The Use of Novel Allylsilanes for the One‐Pot Preparation of Six‐ and Seven‐Membered Rings.
Authors: LEE T. V. , BOUCHER R. J. , ROCKELL C. J. M. 
Published: May 2016

AbstractReaction of the cycloalkanone enol ethers (VII) with (V) in the presence of TiCl4 and trimethylsilyl triflate gives the exo‐methylenebicycloalkanols (VIII) which are oxidized and dehydrated to form the enones (IX).
ChemInform Abstract: Theoretical Study of α‐Lactone, Acetoxyl Diradical, and the Gas‐Phase Dissociation of the Chloroacetate Anion.
Authors: ANTOLOVIC D. , SHINER V. J. , DAVIDSON E. R. 
Published: May 2016

AbstractThe ab initio Hartree‐Fock and SCF calculations point to an SN2 mechanism for the reaction shown.
ChemInform Abstract: Transesterification of 3‐Oxo Esters with Allylic Alcohols.
Authors: GILBERT J. C. , KELLY T. A. 
Published: May 2016

AbstractThe β‐keto esters (I) react with the allylic alcohols (II) in the presence of DMAP and molecular sieves, producing the allyl acetoacetates (III).
ChemInform Abstract: Selective Reduction of Aromatic/Aliphatic Nitro Groups by Sodium Sulfide.
Authors: HUBER D. , ANDERMANN G. , LECLERC G. 
Published: May 2016

Abstract4‐Nitrobenzyl chloride (I) is coupled with the nitronates (II) to give the p‐(nitrophenyl)nitroalkanes (III).
ChemInform Abstract: Asymmetric Synthesis. Part 13. Synthesis of 2‐Alkylpyrrolidines: Towards Azabicyclic Systems.
Authors: ARSENIYADIS S. , HUANG P. Q. , HUSSON H.‐P. 
Published: May 2016

AbstractThe 2‐cyanooxazolopyrrolidine (I) reacts with LDA and the alkyl halides (II) to give the substituted nitriles (III) which are decyanated to form the oxazolopyrrolidines (IV).
ChemInform Abstract: Transmetalation of N‐(Trialkylstannyl)methylimines. A New Method for the Generation and Cycloaddition of 2‐Azaallyl Anions.
Authors: PEARSON W. H. , SZURA D. P. , HARTER W. G. 
Published: May 2016

AbstractThe trialkylstannylmethylimines (V), prepared by reaction of the iodo‐or mesyloxymethylstannanes (I) with sodium azide (II) and subsequent coupling with the aldehydes (IV), are converted to the 2‐azaallyl anions (VII).
ChemInform Abstract: Synthesis of Molecular Lines, Rigid Linear Molecules with Nanometer Scale Dimensions.
Authors: KENNY P. W. , MILLER L. L. 
Published: May 2016

AbstractDiels‐Alder reaction of the bis(furo)anthraquinone (I) and the N‐aryl maleimide (II) gives a mixture of the mono‐ and bisadducts (III) and (IV) which are transformed into the linear polyacenequinone derivatives (V), (VII), and (VIII).
ChemInform Abstract: Ultrasonically Assisted O‐Alkylation Reactions of 5‐Hydroxychromones.
Authors: MASON T. J. , LORIMER J. P. , TURNER A. T. , HARRIS A. R. 
Published: May 2016

AbstractThe O‐alkylation of 5‐hydroxychromones is electronically hindered due to the hydrogen binding between the carbonyl and OH groups together with some dispersion of the negative charge on O due to resonance stabilization.
ChemInform Abstract: ortho‐Lithiation of 2‐, 3‐, and 4‐Methoxypyridines.
Authors: COMINS D. L. , LAMUNYON D. H. 
Published: May 2016

AbstractLithiation of the isomeric methoxypyridines (I), (IV), and (VI) with LDA followed by quenching with chlorotrimethylsilane (II) produces the silylated pyridines (III), (Va) ‐ (Vc), or (VII) and (VIII).
ChemInform Abstract: Ritter Reactions. Part 3. A Simple Entry into the 3‐Azatricyclo‐(5.3.1.04,9)undecane System.
Authors: BISHOP R. , HAWKINS S. C. , IBANA I. C. 
Published: May 2016

AbstractReaction of 2,6‐dimethylenebicyclo(3.3.1)nonane (I) with acetonitrile (II) and concentrated sulfuric acid in benzene yields the azatricycle (III) as the only product.
ChemInform Abstract: Synthesis of Tetrathiamacrocyclic Ligands and Their Complex Formation with Copper(II) Ions.
Authors: YATSIMIRSKII K. V. , PAVLISHCHUK V. V. , STRIZHAK P. E. 
Published: May 2016

AbstractThe dithiadithiols (V), prepared from mercaptoethanol (I) and 1,2‐dibromoethane (II) via the diol (III), are cyclized with the dibromides (VI) to give the tetrathia crown ethers (VII).
ChemInform Abstract: Lewis Base Properties of 1λ5‐Phospha‐3,5‐dithia‐2,4,6‐triazines: Crystal and Molecular Structures of Ph2PS2N3Me+CF3SO‐ 3 and trans‐(Ph2PS2N3)2SnCl4 and the Electronic Structure of H2PS2N3H+.
Authors: CHIVERS T. , LIBLONG S. W. , RICHARDSON J. F. , ZIEGLER T. 
Published: May 2016

AbstractThe behavior of the title compound L toward Lewis and Bronsted acids is investigated, the following adducts (I)‐(IV) are isolated and characterized by UV/VIS, IR, and 31P NMR spectral data.
ChemInform Abstract: X‐Ray Crystal Structure of the Ethylzinc Enolate of 1‐(2,4‐Cyclopentadienyl)‐2‐(diethylamino)‐1‐ethanone, the Unexpected Reaction Product from Cyclopentadienyl(ethyl)zinc and Ethyl N,N‐Diethylglycinate.
Authors: JASTRZEBSKI J. T. B. H. , BOERSMA J. , VAN KOTEN G. , SMEETS W. J. J. , SPEK A. L. 
Published: May 2016

AbstractThe title compound (III) crystallizes in the space group P21/c with Z=2.
ChemInform Abstract: Synthesis and Structural Characterization of Three Compounds with Zr(III)‐Zr(III) Bonds: Zr2Cl6(dppe)2·2 C2H4Cl2·1.5 C6H5CH3, Zr2Cl6(PMe2Ph)4, and Zr2Cl6(PEt3)4.
Authors: COTTON F. A. , DIEBOLD M. P. , KIBALA P. A. 
Published: May 2016

AbstractThe title compounds (I) are prepared by reduction of ZrCl4 with 1 equiv. sodium amalgam in the presence of the appropriate phosphine and characterized by X‐ray structure analysis.
ChemInform Abstract: Synthesis, Vibrational and Moessbauer Spectra Studies of Complexes of Organotin Chlorides and 2‐Pyridinecarboxaldehyde Thiosemicarbazone.
Authors: BAMGBOYE T. T. , BAMGBOYE O. A. 
Published: May 2016

AbstractThe complex formation between the organotin chlorides (I) and (IV) and the ligand (II) occurs in one case by substitution to yield (III); in all other cases the 1:1 addition complexes (V) are formed.
ChemInform Abstract: High Pressure Organometallic Chemistry: Diastereoselectivity in Diels‐Alder Reactions of 2,3‐Dimethyl‐1,3‐butadiene with Z‐3‐Tributylstannylacrylic Acid (‐)‐Menthyl Ester.
Authors: RAHM A. , FERKOUS F. , DEGUEIL‐CASTAING M. , JURCZAK J. , GOLEBIOWSKI A. 
Published: May 2016

AbstractMenthyl propiolate (I) reacts with the trialkylstannanes (II) to yield the stannylated acrylates (III).
ChemInform Abstract: Organoselenium Chemistry. Preparation of Allyl, Allenyl, and Propargyl Stannanes by Substitution of Phenylseleno with Trimethylstannyl.
Authors: REICH H. J. , RINGER J. W. 
Published: May 2016

AbstractAllylphenyl selenide (I) is coupled with electrophiles such as (II) or (VI), yielding the allylic selenides (III) and (VIII) which react with trimethylstannyllithium (IV) to form the rearranged allylstannanes (V) and (IX).
ChemInform Abstract: Organotin Biocides. Part 10. Synthesis, Structure, and Biocidal Activity of Organotin Derivatives of 2‐Mercaptobenzothiazole, 2‐Mercaptobenzoxazole, and 2‐Mercaptobenzimidazole.
Authors: MOLLOY K. C. , PURCELL T. G. , CUNNINGHAM D. , MCCARDLE P. , HIGGINS T. 
Published: May 2016

AbstractThe thioxo heterocycles (I) react with the tin hydroxides (II) under azeotropic conditions to form the stannyl sulfides (IIIa) ‐ (IIIc).
ChemInform Abstract: Synthesis of (Mo6S8(PEt3)6) by Reductive Dimerization of a Trinuclear Molybdenum Chloro Sulfido Cluster Complex Coordinated with Triethylphosphine and Methanol: A Molecular Model for Superconducting Chevrel Phases.
Authors: SAITO T. , YAMAMOTO N. , YAMAGATA T. , IMOTO H. 
Published: May 2016

AbstractThe title complex (II) is prepared as shown by reductive dimerization of (I), which is a new class of cluster condensation.
ChemInform Abstract: Chemical and Structural Aspects of Cyclopentadienyl Uranium(IV) Tetrahydroborato Complexes.
Authors: ZANELLA P. , BRIANESE N. , CASELLATO U. , OSSOLA F. , PORCHIA M. , ROSSETTO G. , GRAZIANI R. 
Published: May 2016

AbstractThe cyclopentadienyl(tetrahydridoborate) complexes (I) can be easily prepared by stepwise replacement of chlorides from UCl4 with appropriate cyclopentadienyl and BH4 groups.
ChemInform Abstract: Model Fluorogenic Ligand‐Actinoid and Lanthanoid Coordination Chemistry. Formation and Crystal and Molecular Structure of ((i‐C3H7O)2P(O)CH(CH2C6H4NO2‐p)C(O)N(C2H5)2)UO2(NO3)2.
Authors: KARTHIKEYAN S. , PAINE R. T. , RYAN R. R. 
Published: May 2016

AbstractThe preparation of the ligand compounds (III) is shown in the scheme.
ChemInform Abstract: Ab initio Calculation on Oxomanganese Porphine Chloride; Relevance to Its Oxidizing Capacity.
Authors: DEN BOER D. H. W. , VAN LENTHE J. H. , VAN DER MADE A. W. 
Published: May 2016

AbstractThe minimal basis‐set gradient‐SCF calculations on the title complex are reported to give insight into its electronic structure.
ChemInform Abstract: Molecular Design Based on Inclusion Chemistry. Synthesis, Characterization, and Crystal Structures of a New Family of Lacunar Schiff Base Complexes with Promise as Broad‐Range Host Molecules.
Authors: RAMPRASAD D. , LIN W.‐K. , GOLDSBY K. A. , BUSCH D. H. 
Published: May 2016

AbstractThe preparation of the new family of complexes (V) is shown in the scheme.
ChemInform Abstract: Reaction of 9,10‐Phenanthrenesemiquinonato‐bis(triphenylphosphine)copper(I) with Organic Peroxides.
Authors: SPEIER G. 
Published: May 2016

AbstractStudies show that the title complex (I) does not react with di‐tert.butyl, di‐triphenylmethyl, or bis(2‐morpholino‐cyclopentyl) peroxides in CH2Cl2 at room temperature.
ChemInform Abstract: Ruthenium(IV)‐Oxo Complexes: The Novel Utilization of Tertiary Pnictogen Ligands.
Authors: MARMION M. E. , TAKEUCHI K. J. 
Published: May 2016

AbstractThe novel title complexes (II) are generated from the analogous Ru(II)‐aquo species (I) (prepared starting with RuCl2(bipyridine)2 via (Ru(Cl)L(bipyridine)2)+ with a yield of 65‐90%) electrochemically or by addition of Ce(IV).
ChemInform Abstract: Studies of the Chemical Oxidation of Ru(II) Complexes of Porphyrins to Form the Corresponding Ru(IV) Complexes.
Authors: RACHLEWICZ K. , LATOS‐GRAZYNSKI L. 
Published: May 2016

AbstractThe Ru porphyrin complex (I) and its tetrakis (o‐, m‐, and p‐tolyl)porphyrin analogues are readily oxidized with Br2 to form the respective π‐cation radicals whose reactivity is investigated.
ChemInform Abstract: Kinetics and Mechanism of the Oxidative Addition of Iodomethane to β‐Diketonatobis(triphenylphosphite)rhodium(I) Complexes.
Authors: VAN ZYL G. J. , LAMPRECHT G. J. , LEIPOLDT J. G. , SWADDLE T. W. 
Published: May 2016

AbstractThe order of the effect of the β‐diketone on the reactivity of the complexes is Ia > Ib > Ic > Id > Ie > If indicating that electronegative substituents of the β‐diketone decrease the reactivity of the complexes toward oxidative addition reactions.
ChemInform Abstract: Novel Rhodium Porphyrin Derivatives. Part 3. Synthesis and Characterization of Rhodium(III) Porphyrinates in Solution of Alkyl Amides.
Authors: BOSCHI T. , LICOCCIA S. , TAGLIATESTA P. 
Published: May 2016

AbstractHydrated RhCl3 (II) reacts with porphyrines (I) in different alkylamides to form penta‐ or hexacoordinated complexes, depending on the nature of the amide.
ChemInform Abstract: Adducts and Cyclometalated Derivatives of Palladium(II) with Some 1,4‐Benzodiazepin‐2‐ones. Crystal and Molecular Structure of trans‐Dichlorobis(7‐chloro‐1‐(cyclopropylmethyl)‐1,3‐dihydro‐5‐phenyl‐2H‐1,4‐benzodiazepin‐2‐one)palladium(II).
Authors: CINELLU M. A. , GANADU M. L. , MINGHETTI G. , CARIATI F. , DEMARTIN F. , MANASSERO M. 
Published: May 2016

AbstractIn the adducts (IV), prepared as shown, the benzodiazepines act as monodentate ligands through the 4‐nitrogen atom, as determined by an X‐ray structure analysis of (IVb) (it crystallizes as a CHCl3 solvate in the space group P21/n, Z=2 and as a CH2Cl2 solvate in P21/c, Z=4).
ChemInform Abstract: Synthesis, Structure, and Reactivity of a Bridging Difluorocarbene Complex, (CpFeIr(Cl)(CO)2(PMe2Ph)2(μ‐CO)(μ‐CF2)) (BF4)·CH2Cl2.
Authors: CRESPI A. M. , SABAT M. , SHRIVER D. F. 
Published: May 2016

AbstractThe moisture‐sensitive, heterobimetallic complex (IIIa) is prepared by the oxidative addition of (I) to (II).
ChemInform Abstract: Activation of the C‐H Bonds of Benzene by Reaction with (Bis(dicyclohexylphosphino)ethane)platinum(0), Generated by the Thermolysis of cis‐(Bis(dicyclohexylphosphino)ethane)hydridoneopentylplatinum(II).
Authors: HACKETT M. , IBERS J. A. , WHITESIDES G. M. 
Published: May 2016

AbstractThe hydridoneopentyl‐Pt(II) complex (V) prepared according to the scheme undergoes reductive elimination of neopentane on heating in benzene (VII).
ChemInform Abstract: Mixed Platinum‐Gold Clusters. Synthesis, Structure and Properties of PtAu8(PPh3)8(NO3)2.
Authors: BOUR J. J. , KANTERS R. P. F. , SCHLEBOS P. P. J. , STEGGERDA J. J. 
Published: May 2016

AbstractThe title complex (I) is formed by the reaction of H2 with (I) and (II) (or Pt(PPh3)3).
ChemInform Abstract: Photosensitized (4 + 2) Cyclodimerizations of Aromatic Retinoids.
Authors: PFOERTNER K.‐H. , ENGLERT G. , SCHOENHOLZER P. 
Published: May 2016

AbstractThe hematoporphyrin‐sensitized photoreaction of the aromatic retinoid (I) using light with λ ≥ 400 nm yields the cyclodimers (II) (space group P21/a, Z=4) and (III) (P1, Z=2).
ChemInform Abstract: Synthesis of N‐Acetyl Derivatives of (1R,5R)‐6‐Aza‐2‐oxabicyclo(3.3.0)octan‐3‐one and (1S,5R,8R)‐8‐O‐Benzyl‐6‐aza‐2‐oxabicyclo(3.3.0)octan‐3‐one from D‐Glucose.
Authors: GURJAR M. K. , PATIL V. J. , PAWAR S. M. 
Published: May 2016

AbstractThe title compounds (IX) and (XV) can be prepared starting from D‐glucose via the derivatives (I) and (IX), respectively.
ChemInform Abstract: Reductive Nitrosylation of Tetraoxometallates. Part 14. Generation and Proton Induced Disproportionation of the Re(NO)3+ Moiety. Synthesis, Characterization, and Electrochemistry of Novel Hydroxo‐ and Halogenonitrosyl Complexes of Rhenium.
Authors: BHATTACHARYYA R. , ROY P. S. , DASMAHAPATRA A. K. 
Published: May 2016

AbstractThe IR and ESR spectra indicate that the complex (IV) have C4v symmetry and that the neutral complex (VI) also possesses axially symmetric structures containing the nitrogen atoms of the ligand in equatorial‐equatorial position.
ChemInform Abstract: Allylstannation. Part 13. New Synthesis of Unreported Ethers from 4‐n‐Butyldichlorostannoxy‐, 3‐Methyl‐4‐n‐butyldichlorostannoxy‐hepta‐1,5‐diene and 4‐n‐Butyldichlorostannoxy‐nona‐1,5‐diene.
Authors: MARTON D. , FURLANI D. , TAGLIAVINI G. 
Published: May 2016

AbstractThe three constitutional isomeric ethers (III)‐(V), all of which exist as diastereomeric mixtures concerning their two achiral centers, are obtained by allylstannation of crotonaldehyde (II).
ChemInform Abstract: Formation of 2‐Ethylacrolein by Gas Phase Aldol Condensation.
Authors: ALBANESI G. , MOGGI P. 
Published: May 2016

AbstractTungsten oxide supported on silica is employed as a catalyst in the gas‐phase aldol condensation of formaldehyde (II) with n‐butyraldehyde (I), producing 2‐ethylacrolein (III).
ChemInform Abstract: Chelates of Boron with N‐Organyl‐N′‐(1,3‐thiazol‐2‐yl)thioureas and Their Use as Ligands in Transition Metal Complexes.
Authors: DOROKHOV V. A. , BOLDYREVA O. G. , BOCHKAREVA M. N. 
Published: May 2016

AbstractThe thiazolylthiourea (I) is coupled with the thioborinates (II) to give the boron chelates (III) which isomerizes upon heating, producing the thermodynamically more stable chelates (IV).
ChemInform Abstract: Reaction of the Super Acid HGeCl3 with Aromatic Compounds. Part 7. Formation of an Iminium Salt from HGeCl3 and Triphenylamine and Its Transformations.
Authors: KOLESNIKOV S. P. , POVAROV S. L. , SAMOSHIN V. V. , LUTSENKO A. I. 
Published: May 2016

AbstractTriphenylamine (I) is coupled with trichlorogermane (II) to give the iminium salt (III).
ChemInform Abstract: Preparation and Reactivity of Several Alkylidene Complexes of the Type W(CHR′)(N‐2,6‐C6H3‐iPr2)(OR)2 and Related Tungstacyclobutane Complexes. Controlling Metathesis Activity Through the Choice of Alkoxide Ligand.
Authors: SCHROCK R. R. , DEPUE R. T. , FELDMAN J. , SCHAVERIEN C. J. , DEWAN J. C. , LIU A. H. 
Published: May 2016

AbstractRelated with recent findings in olefin and acetylene metathesis, the neutral, four‐coordinate complexes (VI) are prepared in order to study their ability to serve as active olefin metathesis catalysts.
ChemInform Abstract: Halide Substitution Reactions of trans‐(Os(N)(CH2SiMe3)2Cl2)‐. Synthesis of Carbonate, Sulfate, and Perrhenate Complexes of Osmium(VI).
Authors: ZHANG N. , SHAPLEY P. A. 
Published: May 2016

AbstractThe stable Os(VI) complexes (III) and (V) are prepared by reaction of the title complex (I) with appropriate Ag(I) salts (II) and (IV) and characterized by IR, 1H, and 13C(1H) NMR spectral data.
ChemInform Abstract: The Phthalation of 2‐Amino‐2‐deoxy‐D‐glucose and N‐Methyl‐1‐amino‐1‐deoxy‐D‐glucitol: Conversion of the Products to Organotin Derivatives. A Ready Migration of Acetyl from Oxygen to Nitrogen under Neutral Conditions.
Authors: PATEL A. , POLLER R. C. 
Published: May 2016

AbstractThe phthalated 2‐amino‐2‐deoxy‐D‐glucose (Ia) can be metalated by standard methods to yield the biological active derivatives (Ib).
ChemInform Abstract: Preparation and Structural Characterization of an Unprotected Copper Sol.
Authors: CURTIS A. C. , DUFF D. G. , EDWARDS P. P. , JEFFERSON D. A. , JOHNSON B. F. G. , KIRKLAND A. I. , WALLACE A. S. 
Published: May 2016

AbstractColloidal Cu particles are prepared in MeOH by reduction of Cu(II) salts with hydrazine hydrate in the absence of steric stabilizing agents.
ChemInform Abstract: Kinetics of the Reactions of F(2P) and Cl(2P) with HNO3
Authors: WINE P. H. , WELLS J. R. , NICOVICH J. M. 
Published: May 2016

Abstractare studied using a time‐resolved long‐path laser absorption technique to monitor the appearance of NO3 radicals after pulsed laser photolysis (351 nm) of X2/HNO3/He mixtures (X: F, Cl).