bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Relative Intramolecular Reactivity of a π Double Bond and the 10π Annulene Moiety Toward Sulfur Trioxide: Sulfonation of 11‐Methylene‐1,6‐ methano(10)annulene, 12,12‐Dimethyl‐11‐methylene‐1,6‐methano(10)annulene, and 11‐Oxo‐1,6‐methano(10)annulene with SO3.
Authors: CERFONTAIN H. , KOEBERG‐TELDER A. , LAMBRECHTS H. J. A. , LINDNER W. , ZHANG S.‐Z. , VOGEL E. 
Published: May 2016

AbstractThe annulenes (I) are allowed to react with SO3 in an NMR tube.
ChemInform Abstract: Lewis Acid Promoter Reaction of Pentacyclo(5.4.0.02,6.03,10.05,9)undecane‐8,11‐dione with Ethyl Diazoacetate: A Synthetic Entry into the Pentacyclo(6.5.0.04,12.05,10.09,13)tridecane Ring System.
Authors: MARCHAND A. P. , ARNEY B. E. JUN. , GILARDI R. , FLIPPEN‐ANDERSON J. L. 
Published: May 2016

AbstractThe pentacyclic dione (I) reacts with the diazoacetate (II) in the presence of BF3 etherate, yielding the dihydroxydicarboxylate (III).
ChemInform Abstract: Chemistry of Organolanthanoids. Lanthanoid‐Mediated C‐C Bond Formation and Cleavage and C‐C Double Bond Reduction.
Authors: HOU Z. , FUJIWARA Y. , JINTOKU T. , MINE N. , YOKOO K. , TANIGUCHI H. 
Published: May 2016

AbstractThe α,β‐unsaturated carbonyl compounds (I) react regioselectively with equivalent amounts of the organolanthanoids (II) to form the 1,2‐addition products (III).
ChemInform Abstract: Oxidation of Sulfides to Sulfoxides by 1‐Acetyl‐v‐triazolo(4,5‐b)pyridine/Hydrogen Peroxide System.
Authors: TORRINI I. , PARADISI M. P. , ZECCHINI G. P. , AGROSI F. 
Published: May 2016

AbstractThe sulfides (I) are converted to the sulfoxides (II) using the triazolopyridine/hydrogen peroxide reagent system mentioned in the title.
ChemInform Abstract: Reaction of Phenol with Oct‐1‐yne in the Presence of Aluminium Phenolate.
Authors: KOZLIKOVSKII YA. B. , KOSHCHII V. A. , BUTOV S. A. 
Published: May 2016

AbstractThe reaction between phenol (I) and oct‐1‐yne (II) in the presence of aluminum phenolate, molar ratio 3:1:0.5, at 130 °C yields a separable mixture of the desired 2,2‐di(hydroxyphenyl)octanes (III) and (IV) along with the chromane (V) and the chromene (VI).
ChemInform Abstract: Steric Factors in Amide‐Directed Metalations of N,N‐Dialkyl‐6‐methoxynaphthalene‐2‐carboxamides: Synthesis of a Sterically Perturbed Acylnaphthol.
Authors: BINDAL R. D. , KATZENELLENBOGEN J. A. 
Published: May 2016

AbstractThe carboxamides (III) are prepared from the methoxynaphthalenecarboxylic acid (I) by treatment of the acid chloride with the secondary amines (II).
ChemInform Abstract: Convenient Synthesis of 4‐Nitrotetralones by Selective Side‐Chain Nitration of Methyl‐Substituted Acryloylbenzenes, Followed by Intramolecular Michael Reaction.
Authors: KEUMI T. , INAGAKI T. , NAKAYAMA N. , MORITA T. , KITAJIMA H. 
Published: May 2016

AbstractNitration of the polymethyl‐substituted acryloylbenzenes (I) yields the 2‐nitromethyl derivatives (II) which undergo an intramolecular Michael addition reaction on treatment with a base to give the 4‐nitrotetralones (III).
ChemInform Abstract: Synthesis of 1,3‐Disubstituted 4‐Isonitrosopyrazol‐5‐ones from N‐Alkyl(Arylalkyl)‐N‐nitrosohydrazines.
Authors: LANOVAYA G. A. , MASHIKHINA A. S. , FEDOROVA V. A. , MIKHEEVA V. P. , BONDARENKO O. D. 
Published: May 2016

AbstractThe reaction between the N‐nitrosohydrazines (I) and ethyl acetoacetate (II) is studied for the first time.
ChemInform Abstract: Reaction of Diazoalkanes on the Activated C(4)‐C(5) Isoxazole Double Bond: A New Entry of the 2‐Oxa‐3‐azabicyclo(3.1.0)hex‐3‐ene Ring System.
Authors: NESI R. , GIOMI D. , QUARTARA L. , BRACCI S. , PAPALEO S. 
Published: May 2016

AbstractDiazomethane (IIa) and 2‐diazopropane (IIb) undergo cycloaddition reaction with the isoxazole derivative (I) to yield the unstable adducts (III) which release nitrogen to give the bicyclic derivatives (IV).
ChemInform Abstract: Synthesis and Spectrophotometric Characteristics of Substituted 4‐Chromonylmethylenepyrazol‐5‐ones.
Authors: POLYAKOV V. K. , BABICH YU. P. , SHEVTSOVA R. G. , TRUSEVICH N. D. , LAVRUSHIN V. F. 
Published: May 2016

AbstractThe pyrazolone (II) is coupled with the chromonealdehydes (I) to give the chromonylmethylenepyrazolones (III).
ChemInform Abstract: Nickel‐, Palladium‐, and Platinum‐Catalyzed Reactions of Perfluoro‐ and Polyfluoroalkyl Iodides with Tertiary Amines.
Authors: HUANG Y.‐Z. , ZHOU Q.‐L. 
Published: May 2016

AbstractThe enamines (III) are prepared by reaction of the iodide (Ib) with the tertiary amines (II) in the presence of triphenylphosphine metal catalysts.
ChemInform Abstract: Cycloaracylation of Enamines. Part 2. Synthesis of 1‐Amino‐4‐quinolone‐3‐carboxylic Acids.
Authors: GROHE K. , HEITZER H. 
Published: May 2016

AbstractThe aminoquinolonecarboxylic acids (Va)‐(Vd) are prepared from the acrylic esters (I).
ChemInform Abstract: Control by Pyridine Nitrogen of the Dual‐Channeled Triplet‐State Di‐π‐ methane Photorearrangement of 5,8‐Dihydro‐5,8‐methanoquinoline Systems.
Authors: PAQUETTE L. A. , BURKE L. D. , IRIE T. , TANIDA H. 
Published: May 2016

AbstractThe methanoquinolines (I) undergo di‐π‐methane photorearrangement, producing mixtures of the regioisomers (II) and (III).
ChemInform Abstract: Derivatives of 1,2,3,3‐Tetramethyl‐2‐azabicyclo(2.2.2)octan‐5‐trans‐ol with Antiarrhythmic and Other Activities. Part 7.
Authors: LONGOBARDI M. , BARGAGNA A. , SCHENONE P. , DE SANTIS D. , ANGRISANI M. , MARMO E. 
Published: May 2016

AbstractThe bicyclic amine (I) mentioned in the title reacts with the isocyanates (II) to give the ureas (III).
ChemInform Abstract: Rose Bengal Functionalized Phase‐Transfer Catalysts Promoting Photooxidations with Singlet Oxygen. Nucleophilic Displacements on Dioxetanic and Endoperoxide Intermediates.
Authors: GUARINI A. , TUNDO P. 
Published: May 2016

AbstractRose bengal‐promoted photooxidation of 5,6‐dihydro‐2,3‐diphenyl‐p‐dioxin (I) in a two‐phase system in the presence of a phosphonium salt as the phase‐transfer catalyst yields a mixture of the dioxetane (II) and the diester (III).
ChemInform Abstract: Acrolein as a Synthon for 6‐Hydroxytetrahydropyrimidines, 1,4(1,6)‐Dihydropyrimidines, and Pyrimidines.
Authors: WEIS A. L. , ZAMIR D. 
Published: May 2016

AbstractThe amidines (II) are coupled with the aldehydes (I), producing the hydroxytetrahydropyrimidines (III).
ChemInform Abstract: Reactions of Azines. Part 11. Preparation of 4H‐Pyrazolo(1,5‐c)(1,3,5)oxadiazines.
Authors: SCHWEIZER E. E. , LEE K.‐J. 
Published: May 2016

AbstractThe azine phosphoranes (I) undergo ring closure with the acyl isocyanates (II) to give the 4H‐pyrazolo(1,5‐c)(1,3,5)oxadiazines (III).
ChemInform Abstract: Synthesis and Resolution of 3‐Amino‐1,3‐dihydro‐5‐phenyl‐2H‐1,4‐benzodiazepin‐2‐ones.
Authors: BOCK M. G. , DIPARDO R. M. , EVANS B. E. , RITTLE K. E. , VEBER D. F. , FREIDINGER R. M. , HIRSHFIELD J. , SPRINGER J. P. 
Published: May 2016

AbstractThe aminobenzophenone (I) reacts with the N‐protected isopropylthioglycine (II) to produce the amide (III).
ChemInform Abstract: Synthesis of a Metal‐Free Three‐Coordinated Phosphorus(V) Hydride and Its Convertion into a Phosphaalkene via Reductive Hydride Shift.
Authors: BARRON A. R. , COWLEY A. H. 
Published: May 2016

AbstractThe phosphorus(V) hydride (III) is synthesized by reacting the phosphaallene (I) with isopropylmagnesium chloride (II).
ChemInform Abstract: (CH3C5H4)2TiS2SiMe2: A Reactive Complex Containing an Si‐S Ligand.
Authors: GIOLANDO D. M. , RAUCHFUSS T. B. , CLARK G. M. 
Published: May 2016

AbstractThe air‐stable title compound (IV) with a planar TiS2Si ring is prepared as shown and characterized by an X‐ray structure analysis (space group Pnma, Z=4).
ChemInform Abstract: Preparation and Characterization of NaW2Cl7(THF)5. A Synthetically Useful Precursor for X3WWX3 Compounds Where X: CH2‐tBu, NMe2, and O‐t‐Bu.
Authors: CHISHOLM M. H. , EICHHORN B. W. , FOLTING K. , HUFFMAN J. C. , ONTIVEROS C. D. , STREIB W. E. , VAN DER SLUYS W. G. 
Published: May 2016

AbstractThe title compound (III) is obtained by addition of Na/Hg (1 equiv.) to a WCl4 (I) slurry in THF (II) and characterized by X‐ray structure analysis (space group P21/c, Z=4).
ChemInform Abstract: General Pathways to α‐Ferrocenylthiosuccinic Acids: Application to the Resolution of Tertiary Ferrocenyl Carbinols.
Authors: DABARD R. , MISTERKIEWICZ B. , PATIN H. , WASIELEWSKI J. 
Published: May 2016

AbstractDimethyl α‐bromosuccinate (I) is transformed into α‐mercaptosuccinic acid (II) by treatment with Na2CS3/HCl.
ChemInform Abstract: Stereoselective Synthesis of α‐Alkylazetidinones by a Free Radical Chain Reaction.
Authors: SACRIPANTE G. , JUST G. 
Published: May 2016

AbstractBenzhydryl 6,6‐dibromopenicillanate (I) is converted into the trans‐6α‐ (2'‐cyanoethyl)penicillanate (Va) in a one‐pot procedure by reductive debromination and subsequent tributyltin radical‐mediated addition reaction with acrylonitrile (IVa).
ChemInform Abstract: Effect of Sol‐Gel Mixing on Mullite Microstructure and Phase Equilibria in the α‐Al2O3‐SiO2 System.
Authors: PASK J. A. , ZHANG X. W. , TOMSIA A. P. , YOLDAS B. E. 
Published: May 2016

AbstractTwo sol‐gel methods are used to synthesize different starting powders containing 72 wt.% Al2O3 and 28 wt.% SiO2 which are classified as colloidal and polymeric.
ChemInform Abstract: Sintering and Properties of Sialons Without Externally Added Liquid Phase.
Authors: BANDYOPADHYAY S. , MUKERJI J. 
Published: May 2016

AbstractThree different β'‐sialons, Si6‐zAlzOzN8‐z with z = 0.5, 1.0, and 2.0, have been prepared in the Si3N4‐AlN‐Al2O3‐SiO2 system without the addition of a sintering aid, and their densification behavior and thermomechanical properties have been investigated.
ChemInform Abstract: f‐Element/Crown Ether Complexes. Part 13. Direct Coordination of 12‐Crown‐4 to Hydrated Terbium Chloride. Synthesis and Crystal Structure of (Tb(OH2)5(12‐crown‐4))Cl3·2 H2O.
Authors: ROGERS R. D. 
Published: May 2016

AbstractThe reaction of hydrated TbCl3 with 12‐crown‐4 in a 1:3 mixture of MeOH and MeCN yields in very low yield the crystalline title complex.
ChemInform Abstract: Potentiometric and Spectroscopic Study of Copper(II), Nickel(II) and Cobalt(II) Complexation by Methoxy‐D‐glucosamine.
Authors: PUSINO A. , DROMA D. , DECOCK P. , DUBOIS B. , KOZLOWSKI H. 
Published: May 2016

AbstractThe stability constants for the formation of one 1:1 and three different 1:2 species of Cu, Ni and Co with 1‐methoxy‐D‐glucosamine are given.
ChemInform Abstract: Enhanced Cram Selectivity in Carbonyl Alkylation via ′Naked′ Anions and anti‐Cram Selectivity via ′Naked′ Cuprates.
Authors: YAMAMOTO Y. , MATSUOKA K. 
Published: May 2016

AbstractReaction of tetrabutylammonium bromide with the corresponding organolithium or Grignard compounds produces the so‐called 'naked' anions of the compounds (II) which are coupled in situ with the aldehydes (I) to yield the alcohols (III) and (IV).
ChemInform Abstract: Photosensitized Reduction of CO2 to CH4 and H2 Evolution in the Presence of Ruthenium and Osmium Colloids: Strategies to Design Selectivity of Products Distribution.
Authors: WILLNER I. , MAIDAN R. , MANDLER D. , DUERR H. + , DOERR G. + , ZENGERLE K. 
Published: May 2016

AbstractTwo different systems for the photoreduction of CO2 in aqueous solutions by using visible light are studied.
ChemInform Abstract: Chemical Transformation of 1,3‐Difluoro‐1,1,3,3‐tetranitropropane by Reaction with Nucleophiles.
Authors: EREMENKO L. T. , ORESHKO G. V. 
Published: May 2016

AbstractThe difluorotetranitropropane (II) reacts with sodium acetate or ethanol to give the gem.
ChemInform Abstract: Sulfonatodehalogenation of Alkyl Halonitroacetates.
Authors: YURTANOV A. I. , CHEKHLOV A. N. , MARTYNOV I. V. 
Published: May 2016

AbstractReaction of the chloronitroacetic or bromonitroacetic acid esters (I) with dithionite gives the nitrosulfoacetic acid esters (II), together with the nitroacetic acid esters (III).
ChemInform Abstract: Thermal Transformation of trans‐2‐Chlorocyclohexanol.
Authors: ZIL'BERMAN I. E. , KOLESNIKOV V. A. , DANOV S. M. , EFREMOV R. V. 
Published: May 2016

AbstractThermal treatment of the chlorocyclohexanol (I) gives cyclohexanone (II), the ether (III) and the dichloride (IV).
ChemInform Abstract: An Unusual Observation in the Synthesis of Thiazoles.
Authors: AHLUWALIA V. K. , ARORA K. K. , KAUR G. , MEHTA B. 
Published: May 2016

AbstractThe dibromomethyl aryl ketones (I), (IV), and (VI) undergo cyclocondensation with thiourea (IIa) or ammonium dithiocarbamate (IIb) to form the amino‐ and mercaptothiazoles (III), (V), and (VII) respectively.
ChemInform Abstract: Intramolecular Capture of Pummerer Rearrangement Intermediates. Part 3. An Interrupted Pummerer Reaction Induced by Vilsmeier Reagent (POCl3/ DMF).
Authors: BATES D. K. , SELL B. A. , PICARD J. A. 
Published: May 2016

AbstractVilsmeier‐Haack formylation of the fused benzothiazole (I) yields the isomeric aldehydes (III) and (IV).
ChemInform Abstract: Nucleophilic Addition to 1,2,2,6,6‐Pentamethyl‐3,5‐dimethylene‐4‐piperidone.
Authors: BELOSTOTSKII A. M. , SHAPIRO A. B. 
Published: May 2016

AbstractThe amines (II) react with the pentamethyldimethylenepiperidone (I) by addition at the C=C double bonds to give the aminomethyl compounds (III).
ChemInform Abstract: Acetylenic Chemistry. Part 5. PTC Reaction of Hydroxyquinolin‐2‐one and Indolin‐2‐one with 3‐Bromoprop‐1‐yne.
Authors: REISCH J. , BATHE A. 
Published: May 2016

AbstractHydroxyquinoline (I) reacts with 3‐bromopropyne (II) under phase transfer catalysis conditions, yielding the quinolines (III) ‐ (VI) as the main products.
ChemInform Abstract: 1,3‐Dipolar Cycloaddition of Cycloiminium Ylides, Formed from Pyridines and Dichlorocarbene.
Authors: KHLEBNIKOV A. F. , KOSTIKOV R. R. 
Published: May 2016

AbstractThe intermediate cycloiminium ylides, formed from the pyridines (I) and dichlorocarbene, react with the butenedioic acid esters (II) to produce the dihydroindolizines (III).
ChemInform Abstract: Benzylpiperazine Derivatives. Part 1. Syntheses and Biological Activities of 1‐(2,3,4‐Trimethoxybenzyl)piperazine Derivatives.
Authors: OHTAKA H. , MIYAKE M. , KANAZAWA T. , ITO K. , TSUKAMOTO G. 
Published: May 2016

AbstractThe Mannich reaction between the piperazine (I), CH2O (III), and the acetophenones (II) yields the benzoylethylpiperazines (IV) which are reduced by NaBH4 to form the secondary alcohols (V).
ChemInform Abstract: Synthesis of Nitro‐, Nitroso‐, and Azoxy‐1,3,5‐triazines by Oxidation of 2‐Hydroxylamino‐4,6‐bis(dimethylamino)‐1,3,5‐triazine.
Authors: SEDOVA V. F. , KRIVOPALOV V. P. , MAMAEV V. P. 
Published: May 2016

AbstractOxidation of the hydroxylaminotriazine (II) with ozone gives the nitro compound (I), whereas with activated manganese dioxide a mixture of the nitroso compound (III) and the azoxy compound (IV) is obtained.
ChemInform Abstract: Catalytic Activities of Modified Hydrolytic Enzymes in Organic Media: Syntheses of Optically Active Trifluoromethylated Compounds.
Authors: KITAZUME T. , MURATA K. 
Published: May 2016

AbstractThe nucleophiles (I) undergo asymmetric Michael addition reaction with the fluorinated acid ester derivative (II) in the presence of modified hydrolytic enzymes to yield the optically active acid ester (III) or, as a result of simultaneous hydrolysis, the acid (IV).
ChemInform Abstract: Chemistry of Silicon‐Sulfur Compounds. Part 48. Catalytic Activity of Pyridine Derivatives and N‐Containing Heterocycles on the Alcoholysis of the Si‐S Bond of Trialkoxysilanethiols.
Authors: PIKIES J. , PRZYJEMSKA K. , WOJNOWSKI W. 
Published: May 2016

AbstractThe effectiveness of pyridine derivatives and N‐containing heterocycles on the ethanolysis of trialkoxysilanethioles such as (I) producing (III) is investigated by kinetic measurements.
ChemInform Abstract: Reactions of Tris(trimethylsilyl)methylsilicon Compounds with Organolithium Reagents.
Authors: AZARIAN D. B. , EABORN C. , LICKISS P. D. 
Published: May 2016

AbstractReaction of the trisylsilane (III) with the phenyllithium derivatives (II), formed by treatment of the aryl bromides with butyllithium in hexane, gives rather low yields of the trisylarylsilanes (IV).
ChemInform Abstract: Aggregation of Metallo‐β‐oxoporphyrins.
Authors: STOLZENBERG A. M. 
Published: May 2016

AbstractThe free base octaethyl‐2‐porphinone (Ia) is obtained by literature methods and gives the complexes (Ib) and (Ic) upon reaction with Zn acetate in DMF or methylmagnesium bromide.
ChemInform Abstract: Intramolecular Coupling of η2‐Iminoacyl and η2‐Acyl Functions at Group 4 and Group 5 Metal Centers: Structure and Spectroscopic Properties of the Resulting Enamidolate and Enediamide Complexes.
Authors: CHAMBERLAIN L. R. , DURFEE L. D. , FANWICK P. E. , KOBRIGER L. M. , LATESKY S. L. , MCMULLEN A. K. , STEFFEY B. D. , ROTHWELL I. P. , FOLTING K. , HUFFMAN J. C. 
Published: May 2016

AbstractA series of group 4 and group 5 metal aryloxide compounds containing enamidolate or enediamide ligation are prepared by the intramolecular coupling of η2‐acyl and η2‐iminoacyl functional groups.
ChemInform Abstract: Formation of Bis(μ‐methanethiolato)bis(dinitrosyliron) from Parsley Ferredoxins and Nitrite.
Authors: BATY J. D. , WILLIS R. G. , BURDON M. G. , BUTLER A. R. , GLIDEWELL C. , JOHNSON I. L. , MASSEY R. 
Published: May 2016

AbstractIncubation of parsley (petroselinum crispum) with sodium nitrite over a four week period at 20 °C in the dark yields the title complex (I), detected and identified by gas chromatography and mass spectra.
ChemInform Abstract: Adenine N(1)‐Oxide Complexes with Metal Chlorides.
Authors: MIKULSKI C. M. , DE PRINCE R. , MADISON G. W. , GAUL M. , KARAYANNIS N. M. 
Published: May 2016

AbstractThe reaction of the appropriate metal chlorides in ethanol/triethylorthoformiate with adenine N(1)‐oxide (HL) under reflux yields the complexes (I)‐(V).
ChemInform Abstract: Synthesis and Chemistry of (Os3(CO)9(μ3‐CCO))2‐. Metal Ensemble Effects on the Reactions of the CCO Ligand.
Authors: WENT M. J. , SAILOR M. J. , BOGDAN P. L. , BROCK C. P. , SHRIVER D. F. 
Published: May 2016

AbstractThe acylation of the cluster (I) followed by reductive CO cleavage produces the title complex (III) which undergoes a variety of reactions on the metal centers or the CCO ligand.
ChemInform Abstract: Glucosidation. Part 6. Synthesis of Acetal α‐Glucosides. A Stereoselective Entry into a New Class of Compounds.
Authors: TIETZE L. F. , FISCHER R. , GUDER H. J. , GOERLACH A. , NEUMANN M. , KRACH T. 
Published: May 2016

AbstractTreatment of the silylated glucopyranoses (I) with the acetals (II) in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulfonate gives the protected acetal α‐glucosides (III).
ChemInform Abstract: Nitration of 3‐Acylindoles in the Presence of Metal MeCN Solvates and Synthesis of the Antibiotics Alkaloid Chuangxinmycin.
Authors: MURASE M. , KOIKE T. , MORIYA Y. , TOBINAGA S. 
Published: May 2016

AbstractNitration of 3‐acylindoles (I) in the presence of metal acetonitrile complexes yields the nitroindoles (II) ‐ (IV).
ChemInform Abstract: Crystal Growth of Cadmium Oxide from the Vapor Phase.
Authors: SHIMADA S. , NOMURA S. , KODAIRA K. , MATSUSHITA T. 
Published: May 2016

AbstractSingle crystals of CdO are grown at temp. of 930‐1080 °C by air oxidation of Cd vapors which are generated at a constant rate by reaction of CdO with graphite at 790 °C. A crystal conglomerate of 13.5 mm size is obtained by prolonged 70 h‐growth at 1030 °C. The crystals have a low electrical resistivity of 5·10‐4 Ω cm and a high electron density of 1.3·1020 cm‐3 in the .ltbbrac.100.rtbbrac.
ChemInform Abstract: YCoC: A Simple Organometallic Polymer in the Solid State with Strong Co‐C π Bonding.
Authors: HOFFMANN R. , LI J. , WHEELER R. A. 
Published: May 2016

AbstractExtended Hueckel tightbinding calculations on YCoC indicate a substantial π character of the bonding in the CoC3‐ chains, which are the main characteristics of the structure of this polymer.
ChemInform Abstract: Characterization and Crystal Defects of the New YBa2Cu3O7‐x Superconductor.
Authors: BOULESTEIX C. , BEN SALEM M. , MOKRANI R. , MONNEREAU O. , SORBIER J.‐P. , DUBOIS B. , BASSAT J.‐M. , ODIER P. , MORIN D. , NITSCHE S. 
Published: May 2016

AbstractThe title compound has been studied by TEM and XRD.
ChemInform Abstract: Structure of MnPO4·H2O by Synchrotron X‐Ray Powder Diffraction.
Authors: LIGHTFOOT P. , CHEETHAM A. K. , SLEIGHT A. W. 
Published: May 2016

AbstractThe quality of refinement that my be obtained from synchrotron X‐ray data for a pure, well crystalline phase is demonstrated by determination of the crystal structure of the title compound.
ChemInform Abstract: The Distinction of Gallium(I) Tetrachloroaluminate, Ga(AlCl4), from Gallium Dichloride.
Authors: STAFFEL T. , MEYER G. 
Published: May 2016

AbstractGa(AlCl4), which is synthesized following a previously described very convenient route (reduction of GaCl3 with Al and slow cooling of the melt), crystallizes in the monoclinic system, space group P21/n, Z=4 (distorted baryte‐type structure).
ChemInform Abstract: Uranyl Ion as a Probe of the Conduction Plane of β“ Alumina.
Authors: HOLLINGSWORTH G. , ZINK J. I. , BARRIE J. D. , DUNN B. 
Published: May 2016

AbstractIt is shown that sodium β" alumina is able to incorporate the uranyl ion by ion exchange (immersion of a sodium β" alumina crystal in a sodium nitrate melt containing up to 2% uranyl nitrate, 2‐8 h, 350 °C).
ChemInform Abstract: Spectroscopic and Structural Evidence of Temperature Dependent Charge Localization and Structural Differentiation of the Fe Sites within the (Fe6S6X6)2‐ Clusters (X: Cl, Br).
Authors: COUCOUVANIS D. , KANATZIDIS M. G. , SALIFOGLOU A. , DUNHAM W. R. , SIMOPOULOS A. , SAMS J. R. , PAPAEFTHYMIOU V. , KOSTIKAS A. , STROUSE C. E. 
Published: May 2016

AbstractThe Moessbauer spectra of the title clusters, prepared in nearly quantitative yield as shown in the scheme, have been investigated at temp. in the range from 1.6 K to room temperature.
ChemInform Abstract: Effect of Underpotential Deposition of Heavy Metals on the Kinetics of the Cathodic Reduction of Chromium(VI) and Persulfates on Platinum.
Authors: KOKKINIDIS G. , SAZOU D. 
Published: May 2016

AbstractFrom potentiostatic current density‐potential measurements on a Pt rotating‐disc electrode it can be stated that the heterogeneous electrocatalytic reduction of chromium(VI) and persulfates on Pt is strongly promoted by upd adlayers of heavy metals (Bi, Tl).
ChemInform Abstract: Temperature‐programmed Desorption Study of the Interactions of H2, CO and CO2 with LaMnO3.
Authors: TEJUCA L. G. , BELL A. T. , FIERRO J. L. G. , TASCON J. M. D. 
Published: May 2016

AbstractThe results of TPD and IR spectroscopy show that H2 adsorbs molecularly on reduced Mn2+ sites.
ChemInform Abstract: Comparison of Photocatalytic Activities of 3d Transition Metal Ions for Hydrogen Peroxide Photolysis and Photoinitiated Hydroxylation of 2‐Hydroxybenzoic Acid.
Authors: SEDLAK P. , LUNAK S. , LEDERER P. 
Published: May 2016

AbstractAmong the 3d transition metal ions studied, Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), only Cu(II) has a significant catalytic effect on H2O2 photolysis and only Fe(III) catalyzes the photoinitiated hydroxylation of 2‐hydroxybenzoic acid.
ChemInform Abstract: High‐Yield Preparation of the Tetradecahydroundecaborate(1‐) Anion, (B11H14)‐, from Pentaborane(9).
Authors: HOSMANE N. S. , WERMER J. R. , HONG Z. , GETMAN T. D. , SHORE S. G. 
Published: May 2016

AbstractReaction of the borate (I) with 0.4 equiv. of (II) in DME at 85 °C yields pure (B11H14)‐ in essentially quantitative yield.
ChemInform Abstract: Formation and Structure of the Phosphoranyl Radical Derived from 1,2‐Phenylene Phosphorochloridate: A Solid‐State ESR Study.
Authors: CATTANI‐LORENTE M. , BERNARDINELLI G. , GEOFFROY M. 
Published: May 2016

AbstractThe crystal structure of the title compound (I) is determined (space group I2 with Z=4).
ChemInform Abstract: Volumes of Reaction for the Formation of Some Analogues of Tetrahedral Intermediates.
Authors: ISAACS N. S. , RZEPA H. S. , SHEPPARD R. N. , LOBO A. M. , PRABHAKAR S. , MERBACH A. E. 
Published: May 2016

AbstractBoth the equilibria shown in the scheme are studied by NMR.