bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Fused Azetidinones from 2‐Keto‐dihydropyrimidines.
Authors: ATMANI A. , KAJIMA M. 
Published: May 2016

AbstractAus den Ketenen (I) erhält man mit den 2‐Oxo‐ bzw. 2‐Thioxo‐dihydropyrimidinen (II) in Gegenwart von Triethylamin die Azetidinone (III).
ChemInform Abstract: Synthesis of Some New Pyrimido[1,6‐a]pyrimidines.
Authors: PEGIADOU‐KOEMTJOPOULOU S. , TSATSARONIS G. 
Published: May 2016

AbstractAus den 4‐Amino‐pyrimidinen (I) und den im Überschuß eingesetzten Malonestern (II) erhält man beim Erhitzen über die Amide (III) die Pyrimidopyrimidine (IV).
ChemInform Abstract: Synthesis of Pyrido[2,3‐d]pyrimidin‐4‐one Derivatives.
Authors: MONGE A. , MARTINEZ‐MERINO V. , FERNANDEZ‐ALVAREZ E. 
Published: May 2016

AbstractAus 2‐Chlor‐pyridin‐3‐carbonsäure (Ia) erhält man über das Chlorid (Ib) die Amide (Ic)‐(Ie), die thermisch zu den Tricyclen (IIa), (IV) bzw. (V) cyclisiert werden können.
ChemInform Abstract: Preparation of Reissert Compounds Derived from the Thieno[3,2‐c]pyridine, Thieno‐ [2,3‐d]pyridazine and the Thieno[2,3‐d]pyrimidine Ring Systems.
Authors: NEW J. S. , JASS P. A. , BARRETT K. A. 
Published: May 2016

AbstractAus den anellierten Pyridinen (Ia) und (Ib) erhält man mit Trimethylsilylcyanid, AlCl3 und den Säurechloriden (II) die Reissert‐Addukte (III), analog reagiert das Pyridazin (IV).
ChemInform Abstract: Chlorimine Formation and Deamination of the Model Nucleobase 1‐Methylcytosine.
Authors: BEYERLE‐PFNUER R. + , LIPPERT B. , SCHOELLHORN H. + , MATISCHOK P. , THEWALT U. 
Published: May 2016

Abstract1‐Methyl‐cytosin (I) wird zu (II)‐(IV) chloriert, aus (IV) erhält man bei alkalischer Hydrolyse das 5‐Chlor‐1‐methyl‐cytosin (V).
ChemInform Abstract: Regiospecific Alkylation of Guanine via Diacyloxyglyoxal‐N2‐acetylguanine Adduct to Obtain 7‐Alkylguanine Derivatives.
Authors: KJELLBERG J. , JOHANSSON N. G. 
Published: May 2016

AbstractAusbeute und Produktverhältnis der Alkylierung der Guanin‐Derivate (I) mit 4‐Brom‐butyl‐acetat (II) zu den Isomeren (III) und (IV), die sich zu den Guanin‐ Derivaten (V) und (VI) verseifen lassen, werden in Abhängigkeit von der eingesetzten Base untersucht.
ChemInform Abstract: Reactivity of Pyrazolo[4,3‐c][1,2,5]oxadiazin‐3(5H)‐ones toward C‐Nucleophiles: Synthesis of Pyrazolo[3,4‐b]pyrazines.
Authors: GIORI P. , VERONESE A. C. , POLI T. , VICENTINI C. B. , MANFRINI M. , GUARNERI M. 
Published: May 2016

AbstractAus den Pyrazolo‐oxadiazinonen (I) erhält man mit Acetylaceton (II) die Substitutionsprodukte (III).
ChemInform Abstract: Synthesis of Benzophenothiazinone Derivatives from 2,3,5‐Trisubstituted‐1,4‐naphthoquinones with 2‐Aminothiophenol.
Authors: NAN'YA S. , MAEKAWA E. , KANG W.‐B. , UENO Y. 
Published: May 2016

AbstractAus den Naphthochinonen (I) werden mit 2‐Amino‐thiophenol (II) in Gegenwart von HCl oder Pyridin Gemische der Kondensationsprodukte (III) bis (V) hergestellt.
ChemInform Abstract: Synthesis of Novel Azapyridocyanines.
Authors: MUNAVALLI S. , HSU F.‐L. , POZIOMEK E. J. 
Published: May 2016

AbstractDie im Titel genannten Verbindungen (II) werden durch Erhitzen der 2‐Aminopyridine (I) mit Diiodmethan in Acetonitril erhalten.
ChemInform Abstract: Reported New Syntheses of 5,6‐Dihydro‐6,11‐dioxomorphanthridine and 5,6‐Dihydro‐6‐oxomorphanthridine Cannot be Repeated.
Authors: QUINTERO M. G. , DONETTI A. 
Published: May 2016

AbstractThe syntheses of the tricyclic N‐ compounds (I) or (IV) from (II) or (V), published by other authors two years ago, cannot be repeated.
ChemInform Abstract: Polycyclic N‐Hetero Compounds. Part 26. Synthesis of 4‐Substituted 6,7‐Dihydro‐ 5H‐pyrimido[5,4‐d][1]benzazepine.
Authors: HIROTA T. , FUKUMOTO M. , SASAKI K. 
Published: May 2016

AbstractDie im Titel genannten Verbindungen (III) werden aus dem Chlorheterocyclus (I) und den primären Aminen (II) hergestellt.
ChemInform Abstract: Synthesis of Substituted Pyrrolo[1,2‐a][1,3]diazepine. A Correction.
Authors: ZIMMERMANN W. , SINAMBELA J. M. , ROTH H. J. , EGER K. 
Published: May 2016

AbstractAus den 2‐Amino‐3‐cyano‐pyrrolen (I) erhält man mit (n‐Chlor‐buttersäurechlorid (II) über das Amid (III) das Pyrrolodiazepinon (IV).
ChemInform Abstract: Synthesis and Resolution of a New Type of Chiral Bisphosphine Ligand, trans‐Bis‐ 1,2‐(diphenylphosphino)cyclobutane, and Asymmetric Hydrogenation Using Its Rhodium Complex.
Authors: MINAMI T. , OKADA Y. , NOMURA R. , HIROTA S. , NAGAHARA Y. , FUKUYAMA K. 
Published: May 2016

AbstractDie Synthese des neuen chiralen Bis‐phosphin‐Liganden (IV) und seine Anwendung in einem Rhodium‐Komplex‐Katalysator zur asymmetri‐ 159 schen Hydrierung wird beschrieben.
ChemInform Abstract: Stereochemistry of the Reaction of Oxygen Nucleophiles with a Phosphinous Chloride in the 7‐Phosphanorbornene Series.
Authors: QUIN L. D. , KEGLEVICH G. 
Published: May 2016

AbstractThe anti‐chloro derivative (I), obtained by chlorination of the dimer of corresponding l‐aminophosphole oxide with Cl3SiH‐ pyridine, is useful for preparing other Compounds.
ChemInform Abstract: Pentacoordinated Molecules. Part 66. Chain Structures of Trimethyltin Esters of Salicylic Acid and o‐Anisic Acid.
Authors: SMITH P. J. , DAY R. O. , CHANDRASEKHAR V. , HOLMES J. M. , HOLMES R. R. 
Published: May 2016

AbstractThe polymeric trimethylsilyl esters (I) and (II) are prepared by 1:1 molar reaction of trimethyltin hydroxide with o‐anisidic or sa1icylic acid in refluxing benzene.
ChemInform Abstract: Tertiary Phosphine Aluminohydride Complexes of Chromium‐, Molybdenum‐, and Tungsten(II).
Authors: BARRON A. R. , SALT J. E. , WILKINSON G. 
Published: May 2016

AbstractThe aluminohydride complexes (III) are synthesized as shown and characterized by IR and 1H, 31P, and 27A] NMR spectra.
ChemInform Abstract: Mechanism of Alkylation of Alkyldiazenido‐complexes of Molybdenum(II) and Tungsten(II): Influence of Metal and Co‐ligands on the Nucleophilicity of a Diazenido‐group.
Authors: HUSSAIN W. , LEIGH G. J. , MODH‐ALI H. , PICKETT C. J. 
Published: May 2016

AbstractThe alkylation reaction of the diazenido complexes (I) to give the hydrazido(2‐) derivatives (II) proceeds via an SN2 process.
ChemInform Abstract: Electron Self‐Exchange by Hexakis(aryl isocyanide)manganese(I/II): Concentration, Electrolyte, and Temperature Dependences.
Authors: NIELSON R. M. , WHERLAND S. 
Published: May 2016

AbstractRate constants and activation parameters for the complexes with the aryl ligands p‐C6H4CH3 and p‐C6H4OCH3 are determined.
ChemInform Abstract: Site Selectivity Studies on Metal Dimer Complexes: The Substitution Reactions of (η5‐C5H5)Fe(CO)2Mn(CO)5.
Authors: JOHNSTON P. , HUTCHINGS G. J. , COVILLE N. J. 
Published: May 2016

AbstractThe reaction of the dimer (I) with isocyanides yields the salts (II), characterized as their PF6 salts by elemental analysis, IR and NMR spectroscopy.
ChemInform Abstract: Lewis Basicity of Carbonyl Oxygen in the Presence of a Heteroatom: Reaction of (BiFe3(CO)10)‐ with CH3SO3CF3.
Authors: WHITMIRE K. H. , LAGRONE C. B. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe cluster,(I) possesses two possible sites of attack in alkylation reactions: the Bi atom which is left with a lone pair and functions as a 3‐electron donor and the very basic u3‐CO.
ChemInform Abstract: A New Binding Mode of the Anionic Ligand Dihydrobis(1‐pyrazolyl)borate, H2BPz2‐, Towards Iron(II), Cobalt(II) and Nickel(II).
Authors: MANI F. 
Published: May 2016

AbstractBy use of the tetraethylammonium salt (I) in place of the analogous Ksalt the reaction with the appropriate metal(II) chlorides affords the paramagnetic 1:3 complexes (II) (no yields given).
ChemInform Abstract: Intramolecular Electron Transfer in the One‐Electron Oxidation Product of (Tetraphenylporphinato)nickel(II), As Studied by Resonance Raman spectroscopy.
Authors: KIM D. , MILLER L. A. , SPIRO T. G. 
Published: May 2016

AbstractResonance Raman spectroscopy can readily distinguish between oxidation of the porphyrin ring or the metal.
ChemInform Abstract: Effect of a Dansyl Group on the Co‐ordinative Ability of N‐Protected Amino Acids.
Authors: ANTOLINI L. , MENABUE L. , SOLA M. , BATTAGLIA L. P. , BONAMARTINI CORRADI A. 
Published: May 2016

AbstractN‐Dansylglycine (5‐dimethylaminonaphthalene‐1‐sulphonylglycine) HL reacts with Cu(II) acetate in MeOH (pH 7,5) or with Cu(OH)2 in aqueous MeOH (pH 6) producing solvated complexes of empiric formula CuLz ‐ 2 MeOH and CuL2‐4 H2O. On the basis of their spectroscopic and magnetic properties a dimeric Cu(II) acetate‐like Structure for CuL2‐2 MeOH and a monomeric structure with CuOö chromophore for CuL2‐4 H2O are suggested.
ChemInform Abstract: Kinetic Stability of the Cysteine Adduct with [Tris(2‐(2‐pyridyl)ethyl)amine]copper(II).
Authors: BAEK H. K. , KARLIN K. D. , HOLWERDA R. A. 
Published: May 2016

AbstractAkinetic study of Cysteine oxidation by the title complex (I) to the disul‐ ?de cystine has been carried out with the aim of documenting the influence of thermodynamic driving force on the Cu(II) ‐ Sredox decay rate.
ChemInform Abstract: Reactions of Di‐μ‐methylene‐bis(pentamethylcyclopentadienyl)dirhodium(IV) Complexes with Benzylmagnesium Chloride and with Alkynylmagnesium Chloride.
Authors: MEANWELL N. J. , SMITH A. J. , MAITLIS P. M. 
Published: May 2016

AbstractReaction of the methylene‐bridged dirhodium(IV) complex (II) with R‐ C E CMgCl gives‐the bis(alkynyl) Substitution products (I).
ChemInform Abstract: Homogeneous Palladium Catalyzed Oxidations: A Novel, Highly Effective Bimetallic Palladium Lead Acetate Complex Useful in Benzylic Acyloxylation of Alkyl Aromatics.
Authors: GOEL A. B. , THROCKMORTON P. E. , GRIMM R. A. 
Published: May 2016

AbstractThe palladium(II) acetate catalyzed acyloxylation of toluene (scheme) can be significantly affected by various factors, especially by use of a suitable cometal acetate salt.
ChemInform Abstract: Synthesis and Characterization of Mono‐ and Di‐cyclometallated Compounds of Symmetric and Asymmetric Azines with Palladium(II) and Manganese(I). X‐Ray Crystal Structure of [Mn(C6H4CH=N‐N=CHPh)(CO)4] .
Authors: CEDER R. M. , SALES J. , SOLANS X. , FONT‐ALTABA M. 
Published: May 2016

AbstractThe 1:1‐molar reaction, of sym. and asym. benzalazines (Ib)‐(Id) with Pd acetate gives mono‐metallated dimeric compounds (IIb)‐(IId); the electron‐rich ring of the asym. benzalazines is preferably metallated.
ChemInform Abstract: Synthesis, Properties, and Structure of Bis(amidino)‐complexes of Palladium. The Crystal Structure of Bis(N,N‐di‐p‐tolylacetamidino)palladium(II).
Authors: BARKER J. , CAMERON N. , KILNER M. , MAHOUD M. M. , WALLWORK S. C. 
Published: May 2016

AbstractTreatment of the dichloro‐Pd complex (I) with lithioamidines (II) affords the monomeric acetamidino complexes (III) or the dimeric benzamidino complexes (IV) as mass spectral studies show.
ChemInform Abstract: Four‐ and Five‐Coordinate Platinum Complexes of Divinylphenylphosphine.
Authors: HOLT M. S. , NELSON J. H. , ALCOCK N. W. 
Published: May 2016

AbstractThe complexes (III) and (IV) are prepared as shown and characterized by elemental analysis, physical properties, conductance measurements, IR and NMR spectroscopy.
ChemInform Abstract: The N‐Allyloxycarbonyl Derivative of D‐Glucosamine: A Potent Precursor of β‐Glycosidation.
Authors: BOULLANGER P. , DESCOTES G. 
Published: May 2016

AbstractDas in literaturbekannter Weise aus D‐Glucosamin erhältliche Derivat (I) reagiert mit den Alkoholen (II) in Gegenwart von Quecksilber(II)cyanid oder Silber‐trifluormethansulfonat zu Gemischen der Folgeprodukte (III) und (IV).
ChemInform Abstract: A Galactoside Derivative of a Nitrosoisocytosine Inhibitor of Dihydropteroate Synthase: Synthesis and Biological Evaluation.
Authors: LEVER O. W. JUN. , HYMAN C. , RAY P. H. , FERONE R. , KELSEY J. E. 
Published: May 2016

AbstractAus dem Benzylether (Ia) wird das freie Phenol (Ib) hydrogenolytisch freigesetzt und dann mit dem TetraacetyI‐galactosylbromid (II) in das Galaktosid (III) übergeführt.
ChemInform Abstract: C‐Nucleoside Studies. Part 19. The Synthesis of the β‐D‐Xylofuranosyl Analogue of Formycin.
Authors: BUCHANAN J. G. , SMITH D. , WIGHTMAN R. H. 
Published: May 2016

AbstractTreatment of the acyclic pentitol derivative (I) with acidified acetone (II) gives the isomeric rearrangement products (III) and (IVa); after longer reaction times (IVa) and the condensation product (IVb) are obtained.
ChemInform Abstract: Synthesis of Spiroepoxynucleosides.
Authors: HERSCOVICI J. , EGRON M.‐J. , ANTONAKIS K. 
Published: May 2016

AbstractThe L‐keto nucleoside (Ia) can be smoothly converted to the methylene derivative (III), but the attempted epoxidation of the latter using various reagents is uniformly unsuccessful.
ChemInform Abstract: Ring Transformation Reactions of C‐Nucleosides: Facile Synthesis of Pyrazolo[1,5‐a]pyrimidine and Pyrazolo[1,5‐a]triazine C‐Nucleosides.
Authors: CHU C. K. , SUH J. J. , MESBAH M. , CUTLER S. J. 
Published: May 2016

Abstract1,3‐Dimethyluracil (I) wird mit den Amino‐pyrazolen (II) zu den Pyrazolopyrimidinen (III) kondensiert.
ChemInform Abstract: A New Synthesis of 8‐(ω‐Carbomethoxyhexyl)‐11‐hydroxycyclopent‐8(12)‐ene‐9‐one, a Versatile Prostaglandin Intermediate.
Authors: THAKUR S. B. , JADHAV K. S. , BHATTACHARYYA S. C. 
Published: May 2016

AbstractThe acid (I) is transformed to the cyclopentenone (V) which serves as intermediate in the synthesis of the desired title compound (VIII) (most yields given in g).
ChemInform Abstract: Total Syntheses of Prothracarcin (IX) and Tomaymycin (XII) by Use of Palladium Catalyzed Carbonylation.
Authors: MORI M. , UOZUMI Y. , KIMURA M. , BAN Y. 
Published: May 2016

AbstractStarting from the reaction between the carboxylic acid (I) and the aniline (II), the synthesis of the compound (IV) is achieved.
ChemInform Abstract: Diastereoselective and Enantioselective Microbial Reduction of Cyclic α‐Alkyl β‐Ketoesters.
Authors: BUISSON D. , AZERAD R. 
Published: May 2016

AbstractDie mikrobiologische Reduktion der racemischen Cycloalkanon‐2‐carbonsäureester (I) durch zahlreiche verschiedene Schimmelpilz‐ und Hefe‐ Arten wird ausführlich untersucht.
ChemInform Abstract: Sulfur Dioxide Gas Detection with Na2SO4 ‐ Li2SO4 ‐ Y2(SO4)3 ‐ SiO2 Solid Electrolyte by a Solid Reference Electrode Method.
Authors: IMANAKA N. , YAMAGUCHI Y. , ADACHI G. , SHIOKAWA J. 
Published: May 2016

AbstractInstead of a reference SO2 gas circulation, NiSO4‐NiO and CoSO4‐Co3O4 solid reference electrodes have been employed.
ChemInform Abstract: Growth of Selective Tungsten on Self‐Aligned Ti and PtNi Silicides by Low Pressure Chemical Vapor Deposition.
Authors: BROADBENT E. K. , MORGAN A. E. , DEBLASI J. M. , VAN DER PUTTE P. , COULMAN B. , BURROW B. J. , SADANA D. K. , READER A. 
Published: May 2016

AbstractThe Selective deposition of tungsten (WF6 source) onto TiSi2 results in the consumption of Si from the upper 40‐50 nm of the substrate.
ChemInform Abstract: Effect of Fluorine and Magnesium on the Polymorphism of Tricalcium Silicate: A New Fluorine‐Containing Tricalcium Silicate Superlattice.
Authors: PEREZ‐MENDEZ M. , GROVES G. W. , FAYOS J. 
Published: May 2016

AbstractEvidence is given for the presence of a new F′ containing C35 phase by X‐ray powder diffraction and TEM electron diffraction.
ChemInform Abstract: Synthesis and a Physical‐chemical Study of the Compound LiCrTeO4.
Authors: SOROKINA O. V. , CHABAN N. G. , SAFONOV V. V. , POROTNIKOV N. V. 
Published: May 2016

AbstractStoichiometric mixtures of Li2CO3, Cr2O3,and TeOz are heated to more than 600°C to give the title Compound , which on heating to 930°C undergoes a reversible polymorphic conversion.
ChemInform Abstract: Grain‐Boundary Effect in Ceria Doped with Trivalent Cations. Part 1. Electrical Measurements. Part 2. Microstructure and Microanalysis.
Authors: GERHARDT R. , NOWICK A. S. , MOCHEL M. E. , DUMLER I. 
Published: May 2016

AbstractTheinfluences of porosity, of sintering time, and dopant size and ‐concentration (dopants: Y", Gd", La") on the "grain‐boundary" effect in doped ceria, which leads to a reduced dc ionic conductivity, have been investigated.
ChemInform Abstract: Defect Structure and Dielectric Properties of Nd2O3‐Modified BaTiO3.
Authors: SHAIKH A. S. , VEST R. W. 
Published: May 2016

AbstractIn BaTiO3 modified with l‐ 10 mol°/o Nd2O3, Nd occupies the Ba sites and Charge compensation takes plaee by creation of Ti vacancies.
ChemInform Abstract: Alumina‐supported Fluoride Reagents for Organic Synthesis: Optimisation of Reagent Preparation and Elucidation of the Active Species.
Authors: ANDO T. , BROWN S. J. , CLARK J. H. , CORK D. G. , HANAFUSA T. , ICHIHARA J. , MILLER J. M. , ROBERTSON M. S. 
Published: May 2016

AbstractThe influence of reagent loading and drying conditions on the activity of alkali metal fluoride (MF; M: K, Cs)‐Al2O3 supported reagents has been investigated.
ChemInform Abstract: Photoredox Chemistry of Keggin Dodecatungstoborate (BW12O40)5‐ and Role of Heterogeneous Catalysis in Hydrogen Formation.
Authors: YAMASE T. , WATANABE R. 
Published: May 2016

AbstractThe photoexcitation (313 nm) of the oxygen‐to‐tungsten Charge‐transfer band of [BW,2O40]5′ (I) in methanolic solution results in the formation of [BW,2O4O]" (II), H2, and HZCO in the pH range 2.0‐9.4.
ChemInform Abstract: Synthesis and Crystal Structure of the Anion (P4S9N)‐.
Authors: ROESKY H. W. , BENMOHAMED N. , NOLTEMEYER M. , SHELDRICK G. M. 
Published: May 2016

Abstract[Pr4N]+[P4S9N]′ (III) has been obtained from the exothermic reaction between P4810 (I) and (Pr4N)+[S2P(N3)2]′ (II).
ChemInform Abstract: YCoC and Isotypic Carbides with a New, Very Simple Structure Type.
Authors: GERSS M. H. , JEITSCHKO W. 
Published: May 2016

AbstractThe isotypic compounds LnCoC (Ln: Y, Gd‐Tm, Lu) have been prepared by arc melting of cold‐ pressed pellets of stoichiometric mixtures of the elements and subsequent annealing at 900°C for 10d. YCoC crystallizes tetragonally in the space group P42/mmc with Z=2.
ChemInform Abstract: Metal‐Nitroxyl Interactions. Part 47. EPR Spectra of Two Spin‐Labeled Derivatives of EDTA Coordinated to Paramagnetic Metal Ions.
Authors: MORE K. M. , EATON G. R. , EATON S. S. 
Published: May 2016

AbstractThe spin‐labeled derivatives (I) as the triethyl salts (76‐80% yield) are prepared by reaction of an aminosubstituted nitroxyl radical with one carboxylic acid group of EDTA to form an amide linkage; they are converted to the trilithium salts (75‐80% yield) and these react with metal salts in aqueous solution (pH 4, 22°C, l0 min) to yield the complexes (II)‐(V) [(IVb) not isolated].
ChemInform Abstract: An ESR Study of the Formation of a Molecular Oxygen Adduct of the Manganese(II) Chelate of Tetrasodium 3,10,17,24‐Tetrasulphonatophthalocyanine.
Authors: OLIVER S. W. , SMITH T. D. , PILBROW J. R. 
Published: May 2016

AbstractTreatment of the Mn(II) chelate of the title ligand with alkaline aqueous solution in air followed by the addition of EtOH leads to formation and precipitation of an ESR nondetectable form of the chelate.
ChemInform Abstract: Unusual Slow‐Exchange 113Cd NMR Spectra Observed at Ambient Temperature for Ha1ide, Cyanide, ‐and Mercaptide Cadmium Coordination Compounds with Benzimidazole Ligands.
Authors: SUMMERS M. F. , VAN RIJN J. , REEDIJK J. , MARZILLI L. G. 
Published: May 2016

AbstractSlow‐exchange "3Cd NMR spectral data [Cd + L r: "Cd(L)"] are obtained for the ligands (I)‐(III) containing benzimidazole donors in [D5]Me2SO solution and at ambient temperature.
ChemInform Abstract: The Octant Rule. Part 18. Mechanism of Ketone n ‐→ π* Optical Activity. Experimental and Computed Chiroptical Properties of 4‐Axial and 4‐Equatorial Alkyladamantan‐2‐ones.
Authors: LIGHTNER D. A. , BOUMAN T. D. , WIJEKOON W. M. D. , HANSEN A. E. 
Published: May 2016

Abstract(lS,3R)‐4S(a)‐ and 4R(e)‐substituted adamantan‐2‐ones were prepared and their circular dichroism (CD) spectra measured.
ChemInform Abstract: Hydridic Atom Arrangement and Bonding in the Molecular Structure of (C2H5)4N+ (Re2(μ‐H)3H6(CH3C(CH2P(C6H5)2)3)I‐ . CH3CN: A Complex Containing 10‐Coordinated Rhenium.
Authors: ABRAHAMS S. C. , GINSBERG A. P. , KOETZLE T. F. , MARSH P. , SPRINKLE C. R. 
Published: May 2016

AbstractThe title nonahydride dimer (I), obtained from the reaction of ReHä′ with the ligand, crystallizes in the space group PT with Z=2.
ChemInform Abstract: Sm(η6‐C6Me6)(η2‐AlCl4)3 : The First Structure of a Rare Earth Complex with a Neutral π‐Ligand.
Authors: COTTON F. A. , SCHWOTZER W. 
Published: May 2016

AbstractThe crystalline title compound (I) is formed by the reaction of SmCl3, AlCl3 and hexamethylbenzene in refluxing toluene in the presence of pieces of Al foil.
ChemInform Abstract: Synthesis and Crystal and Molecular Structure of In(C5Me5): An Apparent Octahedral Cluster.
Authors: BEACHLEY O. T. JUN. , CHURCHILL M. R. , FETTINGER J. C. , PAZIK J. C. , VICTORIANO L. 
Published: May 2016

AbstractThe reaction of InCl with LiC5Me5 in ether leads to the hexameric octahedral Cluster (I) which is exceedingly air‐ and moisture‐sensitive.
ChemInform Abstract: Characterization of Perchlorate Adduct Formation with Copper(II)‐Cyclic Polythia Ether Complexes and Determination of Corrected Stability Constants.
Authors: YOUNG I. R. , OCHRYMOWYCZ L. A. , RORABACHER D. B. 
Published: May 2016

AbstractThe conditional stability constants for the Complexes formed between Cu(II) and the cyclic polythia ether ligands (I) and (II) are determined spectrophotometrically in the presence of various perchlorate ion concentrations.
ChemInform Abstract: Coordination of Lanthanides by Two Polyamino Polycarboxylic Macrocycles: Formation of Highly Stable Lanthanide Complexes.
Authors: LONCIN M. F. , DESREUX J. F. , MERCINY E. 
Published: May 2016

AbstractThe formation constants of three lanthanide complexes of the macrocyclic tetraacetic acid (Ia) [Ln(III): Eu, Tb, Lu] and of some lanthanide complexes of (Ib) [Ln(III): Nd, Sm, Eu, Gd, Dy, Er, Yb] are measured by potentiometric and competition methods.
ChemInform Abstract: Artificial Receptors for Amino Acids in Water. Local Environmental Effect on Polar Recognition by 6A‐Amino‐6B‐carboxy‐ and 6B‐Amino‐6A‐carboxy‐β‐cyclodextrins.
Authors: TABUSHI I. , KURODA Y. , MIZUTANI T. 
Published: May 2016

AbstractCyclodextrins with both positive and negative charges on C‐6 carbons in adjacent glucose rings are synthesized as shown in the scheme.
ChemInform Abstract: Hydrolysis of Nucleoside Phosphates. Part 10. Comparison of the Metal Ion Facilitated Hydrolysis for the 5′‐Triphosphates of 1,N′‐Ethenoadenosine (e‐ATP), Adenosine (ATP), and Cytidine (CTP).
Authors: SCHELLER‐KRATTIGER V. , SIGEL H. 
Published: May 2016

AbstractThe first‐order rate constants for the dephosphorylation of the uncomplexed title nucleoside 5′‐triphosphates (NTP) in the pH range 2‐10 are virtually identical at the same pH.
ChemInform Abstract: Photochemistry of Pd‐Pd o‐Bonds: Electron‐Transfer Reactions of Photogenerated Pd(CNMe)3.+ Radicals.
Authors: METCALF P. A. , KUBIAK C. P. 
Published: May 2016

AbstractProperties and chemical reactivity of the transients formed by flash photolysis of [Pd2(CNMe)6][PF6]2 in acetonitrile are investigated.
ChemInform Abstract: Synthesis of 3‐Aryl Cyclohexanediones by Photolysis of 2‐Arylsulfonyloxy‐2‐cyclo‐ hexenones.
Authors: POQUET A.‐L. , FEIGENBAUM A. , PETE J.‐P. 
Published: May 2016

Abstract2‐Hydroxy‐2‐cyclohexenon (I) wird mit den Sulfochloriden (II) in die Sulfonsäureester (III) übergeführt, die dann photolytisch zu den 3‐Aryl‐2‐hydroxy‐ 2‐cyclohexenonen (IV) umgelagert werden.
ChemInform Abstract: Preparation and Reactions of Dianions from the Cresols.
Authors: BATES R. B. , SIAHAAN T. J. 
Published: May 2016

AbstractAus den o‐, m‐ und p‐ Kresolen (I) werden mit BuLi/KO‐t‐Bu die Dianionen (II) erhalten, die mit elektrophilen Reagentien überwiegend zu den Substitutionsprodukten (III) und (IV) führen.
ChemInform Abstract: Permanganate Ion Oxidations. Part 17. Kinetics and Mechanism of the Oxidation of (E)‐3‐(2‐Thienyl)‐2‐propenoates and (E)‐3‐(3‐Thienyl)‐2‐propenoates in Phosphate‐ Buffered Solutions.
Authors: FREEMAN F. , CHANG L. Y. 
Published: May 2016

AbstractThe oxidations of the propenoates (I) and (II) are first‐order in both permanganate ion and substrate at pH 6.83.