bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis of 2‐Deoxy‐4‐O‐phosphono‐3‐O‐tetradecanoyl‐2‐((3R)‐ and (3S)‐ 3‐tetradecanoyloxytetradecanamido)‐D‐glucose: A Diastereoisomeric Pair of 4‐O‐Phosphono‐D‐glucosamine Derivatives (GLA‐27) Related to Bacterial Lipid A.
Authors: KISO M. , TANAKA S. , TANAHASHI M. , FUJISHIMA Y. , OGAWA Y. , HASEGAWA A. 
Published: May 2016

AbstractAusgehend von dem Benzylglucosid (Ia) werden nach Desacetylierung zu (Ib) zunächst die diastereomeren N‐Acyl‐Derivate (Ic) dargestellt.
ChemInform Abstract: Prostanoids. Part 16. Dienic Lithium Cuprate Reagents Possessing HighReactivity in Conjugate Addition. Application to the Synthesis of Prostanoids.
Authors: TOLSTIKOV G. A. , MIFTAKHOV M. S. , DANILOVA N. A. , SHITIKOVA O. V. , LAVRINOVICH L. I. , MIKHAILOV B. M. , MAVRODIEV V. K. , FURLEI I. I. 
Published: May 2016

AbstractTreatment of the cis‐iododienes (I) or (VI) with BuLi and, subsequently, pentyn‐1‐yl copper affords the cuprate reagents mentioned in the title.
ChemInform Abstract: Synthesis of (.+‐.)‐11‐Deoxyprostaglandin E1.
Authors: DOMBROVSKII V. A. , FONSKII D. YU. , FILIPPOVA T. M. , MIRONOV V. A. 
Published: May 2016

AbstractThe alkylation reactions between the cyclopentanones (I) and an excess of the corresponding ω,ω'‐dibromoalkanes (II) regioselectively afford the novel 2‐(ω‐bromo)alkylcyclopentanones (IIIa)‐(IIIc) and the known derivatives (IIId).
ChemInform Abstract: N‐Hydroxy Amides. Part 4. Synthesis and Properties of a Trihydroxamic Acid Anilide as a Model for Ferrioxamines.
Authors: SHIMIZU K. , NAKAYAMA K. , AKIYAMA M. 
Published: May 2016

AbstractThe trihydroxamic acid (VIII) is synthesized in a stepwise manner using conventional methods starting from glycinanilide (II).
ChemInform Abstract: Vinyl Carbanions. Part 28. Stereoselective Synthesis of the Major Component of a Mosquito Oviposition Attractant Pheromone from a β‐Lithiopropionate Equivalent.
Authors: BARUA N. C. , SCHMIDT R. R. 
Published: May 2016

AbstractAsymmetric epoxidation of the alcohol (I) and subsequent acetylation yields the (‐)‐epoxide (III) which is used as starting compound in thesynthesis of the natural pheromone (VI).
ChemInform Abstract: Cage Structures of Intermetallic Compounds. On LaRuSn3, CeRuSn3, PrRuSn3, and NdRuSn3.
Authors: EISENMANN B. , SCHAEFER H. + 
Published: May 2016

AbstractThe new title compounds have been prepared by annealing stoichiometric mixtures of the elements (argon atmosphere, 5 h to 1200 °C, 5 h to 900 °C).
ChemInform Abstract: Hydrogen Absorbers, Solvated Mg and Mg‐Cu by Clustering in Organic Matrices.
Authors: IMAMURA H. , MURATA Y. , TSUCHIYA S. 
Published: May 2016

AbstractThe hydrogen absorption of THF solvated Mg particles, prepared by cocondensation of Mg vapor and THF at 77 K, and of the THF solvated Mg‐Cu binary system has been investigated.
ChemInform Abstract: Three Forms of a Copper(III) Tripeptideamide and a Comparison of Their Photochemistry.
Authors: HINTON J. P. , MARGERUM D. W. 
Published: May 2016

AbstractTri‐α‐aminoisobutyryl amide forms the three square‐planar Cu(III) complexes (I)‐(III) dependent on pH value that are stable (25 °C, in the dark) in aqueous solution from pH 0 to 14. On the photochemical decomposition these Cu(III) complexes show varied sensitivity on irradiation into their ligand‐to‐metal charge‐transfer bands.
ChemInform Abstract: Photoinduced Reactions. Part 87. Photochemistry of the Nitrogen‐Thiocarbonyl Systems. Part 8. Photoreaction of N‐Substituted Monothiophthalimides with Styrene Derivatives. An Example of Formation and Fission of the Thietane Ring.
Authors: MACHIDA M. , ODA K. , YOSHIDA E. , KANAOKA Y. 
Published: May 2016

AbstractPhotolysis of the monothiophthalimides (I) in the presence of the styrene derivatives (II) affords mixtures of the spiro‐thietanes (III) and (IV), some of which are inseparable.
ChemInform Abstract: Hydrogenolysis of a C‐Cl Bond of Dichloromethylene Groups in Polychloroalkanes Initiated by Fe(CO)5, Mn2(CO)10 or tert‐Butyl Peroxide/Triethylsilane.
Authors: KISELEVA L. N. , RYBAKOVA N. A. , FREIDLINA R. KH. 
Published: May 2016

AbstractAus den Tetrachloralkanen (I) werden mit Triethylsilan in Gegenwart von Metallcarbonylen oder tert.‐Butylperoxid die 1,3,5‐Trichloralkane (II) erhalten, wobei das System Mn2(CO)10/Et3SiH die besten Ergebnisse liefert.
ChemInform Abstract: Reactions of Bicyclo(2.2.1)heptadienes‐2,5 in the Presence of Zeolites.
Authors: AZBEL' B. I. , GOL'DSHLEGER N. F. , ISAKOV YA. I. , EPEL'BAUM E. T. , YAMPOL'SKII YU. YU. , MINACHEV KH. M. 
Published: May 2016

AbstractBicycloheptadiene (I) reacts with water in the presence of activated zeolites to yield the alcohols (II) and (III) and/or the correspondingethers (IV) and (V).
ChemInform Abstract: Reactions of Electron‐Rich Heterocycles with Orthocarboxylic Acid Derivatives. Part 9. Acylation of Indole and Methylindoles with Dialkoxycarbenium Tetrafluoroborates.
Authors: PINDUR U. , FLO C. , AKGUEN E. + , TUNALI M. 
Published: May 2016

AbstractThe indoles (Ia) and (Ib) are acylated regioselectively with the tetrafluoroborates (IIa) and (IIb) to give the indoles (IVa) and (IVb) via the alkoxyindolylcarbenium salts (III).
ChemInform Abstract: Azoles. Part 17. β‐(4‐Pyrazole)acrylic and ‐propionic Acid and Their Antiinflammatory Activity.
Authors: BERNARD M. , HULLEY E. , MOLENDA H. , STOCHLA K. , WRZECIONO U. 
Published: May 2016

AbstractDie Acetophenonphenylhydrazone (I) liefern mit DMF (II) und POCl3 dieFormylpyrazole (III), die mit Malonsäurediethylester (IV) zu den Diestern (V) kondensieren.
ChemInform Abstract: The Crystal and Molecular Structure of an Unexpected Product from an Attempted Hantzsch Pyridine Synthesis. Imine‐Enamine Tautomerism.
Authors: NATALE N. R. , HOPE H. 
Published: May 2016

AbstractThe reaction of the isoxazole aldehyde (I) with methyl acetoacetate (II) and benzylamine (III) produces the unexpected compound (IV).
ChemInform Abstract: Synthesis of Some Indole Derivatives with Potential Antiinflammatory Activity.
Authors: KADRY A. M. , BADAWY M. A. , HANNA H. R. 
Published: May 2016

AbstractDas aus dem Indolylessigsäureester (I) zugängliche Hydrazid (II) addiert die Arylisothiocyanate (III) zu den Acylarylsemicarbaziden (IV), die thermisch zu den Mercaptotriazolen (V) cyclisieren; Reaktion mit den Alkylhalogeniden (VI) führt zu den Alkylthiotriazolen (VII).
ChemInform Abstract: 1,3,4‐Oxadiazolin‐2‐ones from Carbo‐tert‐butoxyhydrazones.
Authors: BAUMGARTEN H. E. , HWANG D.‐R. , RAO T. N. 
Published: May 2016

AbstractThe hydrazones (I) are oxidized with lead tetraacetate, producing theoxadiazolinones (II) and (III).
ChemInform Abstract: Reaction of Some Hydroxypyrimidine Sodium Salts with α,ω‐Dihalogenalkanes. Part 4. Synthesis of N‐(ω‐Haloalkyl)uracils.
Authors: SALIKHOV I. SH. , REZNIK V. S. , SHVETSOV YU. S. , PETROVA V. V. , SHAGIDULLIN R. R. JUN. 
Published: May 2016

AbstractDurch Alkylierung der entsprechenden Uracilderivate werden die N‐monoalkylierten, die symmetrisch 1,3‐dialkylierten und die asymmetrisch 1,3‐dialkylierten Uracile (Ia) ‐ (Id) hergestellt.
ChemInform Abstract: Hydroalumination of Olefins by the LiAlH4/UCl4 System.
Authors: LE MARECHAL J.‐F. , EPHRITIKHINE M. , FOLCHER G. 
Published: May 2016

AbstractDie Reaktion der Olefine (I) mit Lithiumaluminiumhydrid (II) führt inGegenwart katalytischer Mengen an Uran(III)‐chlorid, das aus UCl4 durch Reduktion entsteht, regiospezifisch unter Anti‐Markownikow‐Addition zu den Alkylaluminaten (III).
ChemInform Abstract: Oxygen Transfer Involving Non‐Heme Iron. The Reaction of (EDTA)Fe(III) with m‐Chloroperbenzoic Acid.
Authors: BALASUBRAMANIAN P. N. , BRUICE T. C. 
Published: May 2016

AbstractThe kinetics for the title reaction using solvent MeOH and 2,4,6‐tri‐tert‐butylphenol as a trapping agent for the reactive iron‐oxo intermediate formed upon oxygen transfer are determined spectrophotometrically at 30 °C by following the appearance of 2,4,6‐tri‐tert‐butylphenoxyl radical.
ChemInform Abstract: An Improved Synthesis of 3β‐Benzoyloxy‐5α,8α‐ergosta‐6,22‐dieno(5,8‐b)‐ 1′,2′,3′,4′‐tetrahydrophthalazino‐1′,4′‐dione.
Authors: SCHOENECKER B. + , HAUSCHILD U. , SCHROETTER E. + , SCHICK H. 
Published: May 2016

AbstractDas Tetrahydrophthalazin (I) wird mit Pb(OAc)4 zu dem nicht isolierten Diazanaphthochinon (II) dehydriert, das mit Ergosterinbenzoat (III) das Diels‐Alder‐Addukt (IV) liefert.
ChemInform Abstract: Palladium‐Catalyzed Regio‐ and Stereoselective Reduction of Allylic Compounds with LiHBEt3. Application to the Synthesis of Co‐Enzyme Q10.
Authors: MOHRI M. , KINOSHITA H. , INOMATA K. , KOTAKE H. , TAKAGAKI H. , YAMAZAKI K. 
Published: May 2016

AbstractDie Tosylcyclohexene (I) werden durch Lithiumtriethylboranat (II) unter Pd‐Katalyse zu den Cyclohexenen (III) bzw. (IV) reduziert.
ChemInform Abstract: Development of Aluminum Titanate‐Mullite Composite Having High Thermal Shock Resistance.
Authors: MORISHIMA H. , KATO Z. , UEMATSU K. , SAITO K. , YANO T. , OOTSUKA N. 
Published: May 2016

AbstractStudies of the thermochemical properties of the title composites over a wide composition range show that the thermal shock resistance tends to increase with increasing aluminum titanate content.
ChemInform Abstract: Novel Approach to Efficient Photoelectrochemical Solar Cells Using Electrolyte/Discontinuous Metal/Semiconductor Junctions.
Authors: NAKATO Y. , UEDA K. , TSUBOMURA H. 
Published: May 2016

AbstractIt is shown that a open‐circuit photovoltage (Voc) of 0.5 V can be reached using an n‐Si electrode coated with a microscopically discontinuous Pt layer in a redox solution.
ChemInform Abstract: Preparation and Electrochemical Characteristics of Amorphous Tungsten Trisulfides.
Authors: TOHGE N. , BABA T. , MINAMI T. 
Published: May 2016

AbstractAmorphous (a‐) WS3, prepared by thermal decomposition of (NH4)2WS4, has been used as cathode material in type A silver cells, and its electrochemical behavior has been compared with that of a‐WOS2 and a‐WO3.
ChemInform Abstract: Kinetics of Metal Oxide Dissolution. Oxidative Dissolution of Chromium(III) Oxide by Potassium Permanganate.
Authors: SEGAL M. G. , WILLIAMS W. J. 
Published: May 2016

AbstractThe kinetics of the title reaction (see scheme) follow an inverse‐cubic law under both acid and alkaline conditions; no inhibition by MnO2 product is observed.
ChemInform Abstract: Characterization of Rh/Al2O3 Catalysts by Gas Adsorption and X‐Ray Photoelectron Spectroscopy.
Authors: DUPREZ D. , DELAHAY G. , ABDERRAHIM H. , GRIMBLOT J. 
Published: May 2016

AbstractThree series of Rh/Al2O3 catalysts have been investigated varying the following preparation parameters: calcination temp. (393‐1173 K), reduction temp. (773‐1173 K), and the introduction of steam in the pretreatment (723 K).
ChemInform Abstract: Semireduced Bridging Ligands Containing ‐N=N‐ Multiple Bond Coordination Sites. ESR Study of Binuclear Group 6 Metal Carbonyl Complexes.
Authors: KAIM W. , KOHLMANN S. 
Published: May 2016

AbstractThe centrosymmetric binuclear radical complexes (I)‐(III), formed by reduction at unusually positive potential, are studied by ESR spectroscopy.
ChemInform Abstract: Spectroscopic Properties of Copper(II) Complexes with Quadridentate Derivatives of L‐Proline Amide and L‐Proline Methyl Amide.
Authors: MURAKAMI T. , HATANO M. 
Published: May 2016

AbstractThe copper complexes (II) and (III) (prepared by addition of base) are characterized by absorption, CD, IR, and ESR spectroscopy.
ChemInform Abstract: Equilibria for Phosphine Ligation to Ferrous Protoporphyrin IX Dimethyl Ester and Related Systems in Toluene.
Authors: STYNES D. V. , FLETCHER D. , CHEN X. 
Published: May 2016

AbstractSpectrophotometrically derived equilibrium constants for PBu3 and P(OBu)3 binding to the complex (Ia) are reported and compared with new and literature‐derived values for the analogous complexes (Ib) and (II).
ChemInform Abstract: Asymmetric Catalyses. Part 31. Enantioselective Catalytic Reduction of Dehydro Amino Acids with Formic Acid.
Authors: BRUNNER H. , KUNZ M. 
Published: May 2016

AbstractThe use of 80% formic acid/HCOONa for enantioselective transfer hydrogenation is described for the first time: The products (II) or (III) are obtained from the unsaturated compounds (I); (III) is formed by concomitant ester group hydrolysis.
ChemInform Abstract: ANRORC Mechanism. Part 35. A 15N Study of the Ammonia‐induced Deamination of 1‐Aminopurinium Salts.
Authors: JONGEJAN H. , KOS N. J. , VAN DER PLAS H. C. 
Published: May 2016

AbstractReaction of the diaminopurinium salts (Ia) or (Ib) with methanolic NH3 leads to deamination at N‐1, yielding the aminopurines (II) or (IV), as well as to dideamination, yielding purine (III).
ChemInform Abstract: α‐Fluoroalkylamines as a New Source of Unhydrated Fluoride Ion.Part 6. Hexamethyl Guanidinium Fluoride.
Authors: IGUMNOV S. M. , DELYAGINA N. I. , KNUNYANTS I. L. 
Published: May 2016

AbstractThe guanidinium salt (IV) mentioned in the title is obtained by threemethods as shown in the reaction scheme.
ChemInform Abstract: Perfluoro‐1,2‐diisopropylidene‐3,3‐dimethylcyclobutane. A New Cross‐ Conjugated Perfluorotriene Isomer.
Authors: TER‐GABRIELYAN E. G. , GAMBARYAN N. P. 
Published: May 2016

AbstractTreatment of the perfluorotriene (I) with cesium fluoride and subsequently with sulfuric acid produces the title compound (II).
ChemInform Abstract: Propellanes. Part 84. Reduction of (20.3.3)Propellane‐24,27‐dione: the Three Isomeric (20.3.3)Propellane‐24,27‐diols.
Authors: ASHKENAZI P. , WEINBERG O. , ZLOTA A. , GINSBURG D. 
Published: May 2016

AbstractThe reduction of the title compound (I) affords only two of the three expected diols (II).
ChemInform Abstract: A Copper(I)‐Catalyzed Photobicyclization Route to exo‐1,2‐Polymethylene‐ and 7‐Hydroxynorbornanes. Nonclassical 2‐Bicyclo(3.2.0)heptyl and 7‐Norbornyl Carbenium Ion Intermediates.
Authors: AVASTHI K. , SALOMON R. G. 
Published: May 2016

AbstractThe vinyl allyl cycloalkanols (III) and (IV), obtained from (I) and (II), are photochemically cyclized to form (VI) and (VII) which give the 7‐exo‐hydroxynorbornanes (VIII) upon solvolysis in 90% trifluoroacetic acid.
ChemInform Abstract: The Behavior of 4‐Alkyl‐4‐bromo‐2,5‐cyclohexadienones Formed During the Aqueous Bromination of p‐Alkylphenols.
Authors: TEE O. S. , IYENGAR N. R. , BENNETT J. M. 
Published: May 2016

AbstractAqueous bromination of the phenols (I) leads to the o‐bromo derivatives (II) and to the "ipso‐dienones" (III), as by‐products observed by UV spectroscopy.
ChemInform Abstract: Chemistry of 1,3,5‐Tris(trimethylsiloxy)‐1‐methoxyhexa‐1,3,5‐triene, a β‐Tricarbonyl Trianion Equivalent.
Authors: CHAN T. H. , STOESSEL D. + 
Published: May 2016

AbstractMethyl triacetate (I) is converted to the bis silyl enol ether (III) and then to the tris(trimethylsilyloxy)hexatriene (IV) which reacts with the orthoesters (V) or the imidazolines (VII) under titanium catalysis to form the aromatic products (VI) and (VIII).
ChemInform Abstract: Chemical Transformation of 1,1‐Dichloro‐2,2‐diarylethanes.
Authors: KUZ'MINA N. A. , VAKHTANGISHVILI L. V. , RUSANOV A. L. , FIDLER S. KH. , CHUKOVSKAYA E. TS. 
Published: May 2016

AbstractReaction of the diaryldichloroethane (Ib) with potassium hydroxide inethanol or dioxane gives the dehydrohalogenation product (II).
ChemInform Abstract: On the Addition of Diazomethane to 7‐Chloronorbornadiene.
Authors: WILT J. W. , PEERAN M. 
Published: May 2016

AbstractThe addition of diazomethane (II) to 7‐chloronorbornadiene (I) produces the endo,anti‐adduct (III) as the main product, together with minimal amounts of the endo,syn‐isomer (IV).
ChemInform Abstract: Synthesis and Pharmacological Evaluation of Some 6‐Substituted 7‐Methyl‐1,4‐dioxa‐7‐azaspiro(4.5)decanes as Potential Dopamine Agonists.
Authors: BRUBAKER A. N. , COLLEY M. JUN. 
Published: May 2016

AbstractThe nitrobenzoate (I) is converted to the indole (II) and then combined with the enamine (VI) to yield (VIIa).
ChemInform Abstract: Synthesis of (((Naphthalenylmethoxy)‐ and (((Quinolinylmethoxy)phenyl)‐ amino)oxoalkanoic Acid Esters. A Novel Series of Leucotriene D4 Antagonists and 5‐Lipoxygenase Inhibitors.
Authors: MUSSER J. H. , KUBRAK D. M. , CHANG J. , LEWIS A. J. 
Published: May 2016

AbstractNitrophenols (I) react with the chloroalkyl derivatives (II) to produce the isomeric ethers (III) which are then reduced to yield either the amines (IV) or the hydroxylamines (V).
ChemInform Abstract: Synthesis of Dihydrodiols and Diol Epoxides of Dibenz(a,h)acridine.
Authors: KUMAR S. , AGARWAL N. L. 
Published: May 2016

AbstractThe isomeric diacetates (IIIa), (IIIb), (VIIIa) and (VIIIb) are obtained from the tetrahydrodibenzacridine (I) as shown in the reaction scheme.
ChemInform Abstract: Fluorine Containing Azoles. Part 4. 2‐Perfluoropolyoxaalkyl Substituted Perimidines.
Authors: POLUDNENKO V. G. , DIDINSKAYA O. B. , POZHARSKII A. F. 
Published: May 2016

Abstract1,8‐Diaminonaphthalin (I) wird mit den polyfluorierten Carbonsäurefluoriden (II) zu den Perimidinen (III) umgesetzt.
ChemInform Abstract: Reaction of Tetrahydropyrimido(2,1‐f)xanthines with Some Electrophilic and Nucleophilic Reagents.
Authors: ROMANENKO N. I. , PRIIMENKO B. A. , KLYUEV N. A. , FEDULOVA I. V. 
Published: May 2016

AbstractReaction of the tetrahydropyrimidoxanthine (I) with phosphorus trichloride/phosphorus pentachloride gives the trichloro derivatives (II) which are dechlorinated to yield the 9‐substituted dihydropyrimidopurines (III).
ChemInform Abstract: Synthesis and Biological Activity of 3‐Amino‐5‐(3,5‐diamino‐6‐chloropyrazin‐2‐yl)‐1,2,4‐oxadiazole: An Amiloride Prodrug.
Authors: BOCK M. G. , SMITH R. L. , BLAINE E. H. , CRAGOE E. J. JUN. 
Published: May 2016

AbstractThe synthesis of the pyrazinyl‐oxadiazoles (Va) und (Vb) from the aminopyrazines (I) or (VI) is described.
ChemInform Abstract: Host‐Guest Chemistry. Part 7. Azamacrocycles with N‐(Aminoalkyl) Side Chains: Syntheses, Metal Complexes, and Catalysis of Acyl Transfer Reactions.
Authors: SCHNEIDER H.‐J. , JUNKER A. 
Published: May 2016

AbstractAzacyclophanes (Vb), (VIb), and (VIIb) as well as open chain analogues (IIIa), (IVb) are prepared from (I), (IVa), (Va), (VIa), or (VIIa) by reaction with bromoacetonitrile (II) as shown for (IIIa).
ChemInform Abstract: Saturated Heterocycles. Part 98. Synthesis and Transformations of 4,5‐Dihydro‐1,4‐benzothiazepin‐3(2H)‐one Derivatives.
Authors: SZABO J. , FODOR L. , KATOCS A. , BERNATH G. , SOHAR P. 
Published: May 2016

AbstractThe benzothiazepinone (IV) is prepared in poor yield by ring closure of the chloroacetamide (II), but in good yield by ring closure of the ammonium salt (VII).
ChemInform Abstract: Ring Extension of 1‐Chloromethylsilatranes.
Authors: KILESSO V. M. , KOPKOV V. I. , SHASHKOV A. S. , STEPANENKO B. N. 
Published: May 2016

AbstractUpon reaction with the sodium alcoholates (II), the chloromethylsilatrane (I) rearranges by ring expansion, giving the alkoxy‐2‐carba‐3‐ oxa‐homosilatranes (III).
ChemInform Abstract: Formation and Reactions of Silylated Triphosphanes.
Authors: FRITZ G. , STOLL K. 
Published: May 2016

AbstractSilylated triphosphanes containing prim. P(SiMe3)2, P(SiMe3)tBu, or P(SiMe3)Me endgroups and sec. PCl, PH, PLi, PSiMe3, or PtBu groups can be prepared by the multistep reaction as shown.
ChemInform Abstract: Low Coordinated Phosphorus Compounds. Part 49. Tetraphospha‐1,5‐hexadienes.
Authors: APPEL R. , PORZ C. , KNOCH F. 
Published: May 2016

AbstractReactions of phosphaketene (I) with the disilyldiphosphines (II) yield the valence‐stable tetraphospha‐1,5‐hexadienes (III) as mixtures of the meso and racemic diastereomer.
ChemInform Abstract: Synthesis and Structures of Bicyclic Phosphoranes ‐ Products Resulting from the Reaction of Hexafluoroacetone with Mercury Salts.
Authors: ROESKY H. W. , POGATZKI V. W. , DHATHATHREYAN K. S. , THIEL A. , SCHMIDT H. G. , DYRBUSCH M. , NOLTEMEYER M. , SHELDRICK G. M. 
Published: May 2016

AbstractHg(SCN)2 reacts with hexafluoroacetone (I) to give the cycloaddition product (II), which is converted to the disulfanes (IV), (V) and (VII).
ChemInform Abstract: Linear Oligophosphaalkanes. Part 14. Synthesis and Structure of Functionalized 1,2,3,5‐Diazadiphospholanes.
Authors: BRAUER D. J. , GOL F. , HIETKAMP S. , STELZER O. 
Published: May 2016

AbstractThe methylenebisphosphanes (II) and (V) react with dimethylhydrazine (Ia), phthalohydrazide (Ib), or hydrazine (Ic) to give the five‐membered mono‐ or bicyclic diazadiphospholanes (IIIa), (IIIb) and (VI), respectively.
ChemInform Abstract: An Improved Procedure for the Generation and Selective Trapping of 2,4′‐Dilithiophenylethyne.
Authors: FURBER M. , TAYLOR R. J. K. , BURFORD S. C. 
Published: May 2016

Abstract2,4'‐Dilithiophenylethyne (III), prepared by treating of 4‐bromophenylethyne (I) with butyllithium (II), reacts selectively with the aldehyde (IV) to yield the carbinol (V), with DMF (VII) the ethynylbenzaldehyde (VI) is formed.
ChemInform Abstract: Alkaline Earth Metal Complexes with the Non‐Cyclic Oxygen‐Containing Ligand: 1,3‐Bis(2‐hydroxyphenyl)‐1,3‐propanedione.
Authors: TEIXIDOR F. , FLOR T. , CASABO J. 
Published: May 2016

AbstractThe reaction of the title ligand with alkaline earth metal acetates in methanol yields 2:1 complexes in yields about 60‐70%.
ChemInform Abstract: A Zirconium(IV) Derivative of Bis(phthalocyaninato)neodymium(III).
Authors: KASUGA K. , MORIMOTO H. , ATARASHI H. , ISA M. 
Published: May 2016

AbstractPotassium bis(phthalocyaninato)neodymium(III) reacts with ZrOCl2 octahydrate in acetone at 40 °C for several min to give the title complex (I) (no yield given).
ChemInform Abstract: Characterization of an Air‐Stable Chromium(II) Dinicotinate Complex: trans‐(Cr(II)(nic‐N)2(H2O)4).
Authors: BRODERICK W. E. , PRESSPRICH M. R. , GEISER U. , WILLETT R. D. , LEGG J. I. 
Published: May 2016

AbstractAddition of aqueous CrCl2 to a solution of nicotinate at pH 6 yields the title complex (Ia) as an air‐stable, high‐spin monomeric solid.
ChemInform Abstract: Chemical and Structural Characterization of W(CO)5OPPh2NPPh3. A Novel Complex Containing a Phosphine Oxide Ligand Derived from the Bis(triphenylphosphine)nitrogen(1+) Cation.
Authors: DARENSBOURG D. J. , PALA M. , SIMMONS D. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe novel ligand, obtained by reaction of (I) with sodium methoxide in methanol, is to be viewed as a zwitterion (II).
ChemInform Abstract: Silicon‐Containing Carbene Complexes. Part 7. Disulfide‐Catalyzed Reaction of (CO)5WC(XR)SiPh3 (X: O, S) with Thiols.
Authors: KRON J. , HOERNIG H. + , SCHUBERT U. 
Published: May 2016

AbstractThe carbene complex (I) reacts with thiols (II) only in the presence of disulfides (III) to yield the complexes (IV).
ChemInform Abstract: The Di‐Schiff‐base of Pyridine‐2‐aldehyde and 1,4‐Diaminobutane, a Flexible Cu(I)/Cu(II) Chelator of Significant Superoxide Dismutase Mimetic Activity.
Authors: LINSS M. , WESER U. 
Published: May 2016

AbstractIt was attempted to prepare flexible mononuclear Cu chelates which would be stable in the +I and +II form and would be catalytically active to accelerate superoxide dismutation.
ChemInform Abstract: Electrosynthesis and X‐Ray Structure of a Dinuclear Rhodium Complex Containing a Bridging Nitrate Ion.
Authors: TORTORELLI L. J. , TUCKER C. A. , WOODS C. , BORDNER J. 
Published: May 2016

AbstractThe electrochemical oxidation of the dinuclear Rh(I) complex (I) in the presence of coordinating nitrate and chloride anions leads to the novel Rh(II) dimer (II).
ChemInform Abstract: Element‐Organic Amine/Imine Compounds. Part 27. Palladium and Platinum Complexes with Diamidochalcogenophosphoric Acid Derivatives as Ligands.
Authors: SCHERER O. J. , FORSTINGER K. , KAUB J. , SHELDRICK W. S. 
Published: May 2016

AbstractThe aminoiminophosphine sulfide and selenide (I) adds water with formation of the silyl bis(amido)phosphates (II) which by treatment with NaOH afford the salts (III).