bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Oxidative Decarboxylation of Aleuritic Acid and Its Derivatives: Synthesis of Tumor Inhibitors, (Z)‐ and (E)‐1,8‐Pentadecadienes.
Authors: SUBRAMANIAN G. B. V. , SHARMA R. 
Published: May 2016

Abstracterythro‐Aleuritic acid (I), threo‐aleuritic acid (VII) (readily obtained from shellac) and related derivatives are found to be useful starting materials for the preparation of synthons which may be elaborated to pheromones or macrocyclic perfume constituents.
ChemInform Abstract: Formal Total Synthesis of 1β‐Methylcarbapenem via a Novel Route to Deoxyamino Sugars.
Authors: UDODONG U. E. , FRASER‐REID B. 
Published: May 2016

AbstractStarting with the pyranoside (I), the gluconolactone (VI) is synthesized via the key intermediates (II), (IV), and (V).
ChemInform Abstract: Sodium Diplatinum.
Authors: RANGE K.‐J. , RAU F. , KLEMENT U. 
Published: May 2016

AbstractSingle crystals of NaPt2 are synthesized from the elements in a modified Belt‐type high pressure apparatus (Na:Pt=4:1; 4.0 GPa; 1650 K, 30 min; 1050 K, 30 min).
ChemInform Abstract: Electronic Structure of a New Ternary Chalcogenide: NbNiTe5.
Authors: HALET J.‐F. , HOFFMANN R. , TREMEL W. , LIIMATTA E. W. , IBERS J. A. 
Published: May 2016

AbstractThe electronic structure and bonding in the recently characterized compound NbNiTe5 is studied by extended Hueckel tight‐binding calculations.
ChemInform Abstract: Chemielectron Spectroscopy: Study of the Ce + O2 Reaction.
Authors: COCKETT M. C. R. , DYKE J. M. , ELLIS A. M. , FEHER M. , MORRIS A. 
Published: May 2016

AbstractThe chemielectron spectrum from the Ce + O2 reaction is recorded and the cationic products are identified under the same experimental conditions using mass‐resolved ion spectra.
ChemInform Abstract: Laser‐Chemical Vapor Precipitation of Submicrometer Silicon and Silicon Nitride Powders from Chlorinated Silanes.
Authors: BAUER R. A. , SMULDERS R. , BECHT J. G. M. , VAN DER PUT P. J. , SCHOONMAN J. 
Published: May 2016

AbstractIt is shown that Si and Si3N4 powders can be made from SiH2Cl2 or SiH2Cl2 + NH3 and SiCl4 + NH3, resp., by using laser‐chemical vapor precipitation.
ChemInform Abstract: Synthesis of a New One‐Dimensional Sodium Molybdenum Phosphate Polymer: Structure of ((H3O)2NaMo6P4O24(OH)7)2‐.
Authors: HAUSHALTER R. C. , LAI F. W. 
Published: May 2016

AbstractLarge orange crystals of the polymeric sodium molybdenum phosphate (V) are synthesized for the first time according to the scheme.
ChemInform Abstract: Novel Cubane‐Type Molybdenum‐Tin Cluster Complexes ((H2O)9Mo3S4SnS4Mo3(H2O)9)8+ and Mo3SnS4(aq)6+
Authors: AKASHI H. , SHIBAHARA T. 
Published: May 2016

Abstractare obtained in solution by reaction of (Mo3S4(H2O)9)4+ (I) with metallic tin or SnCl2, resp., and are characterized by cyclic voltammetry and UV spectra.
ChemInform Abstract: Synthesis, Structure, and Magnetic Properties of Alkali Metal Manganese Chalcogenides A6MnX4 with A: Na or K and X: S, Se, or Te.
Authors: BRONGER W. , BALK‐HARDTDEGEN H. 
Published: May 2016

AbstractStructural investigations on single crystals show all six title compounds, prepared according to the scheme in a stream of H2 charged with the chalcogen (yields not given) to crystallize isotypic (Na6ZnO4 type, P63mc, Z=2).
ChemInform Abstract: Oxocuprates(I) with CO2‐Analogous Anions: Rb3(CuO2). Part 3.
Authors: CARL W. , HOPPE R. 
Published: May 2016

AbstractThe title oxocuprate, prepared for the first time by annealing mixtures of RbO0.63 and Cu2O (Pb:Cu = 3.1:1 (powder) or 4.2:1 (single crystals); 600 °C/10 d or 560 °C/14 d), crystallizes in the monoclinic system ( P21/n, Z=4).
ChemInform Abstract: One‐Dimensional Magnetism of a Linear Chain Compound Containing Yttrium(III) and a Nitronyl Nitroxide Radical.
Authors: BENELLI C. , CANESCHI A. , GATTESCHI D. , PARDI L. , REY P. 
Published: May 2016

AbstractThe complex (I), which behaves as a one‐dimensional antiferromagnet, crystallizes in the space group P21/n with Z=4.
ChemInform Abstract: Maximizing Ligand Intermeshing in Phosphine Complexes: Synthesis and Structural Characterization of cis‐Cl2Pt(PCy3)2.
Authors: CAMERON T. S. , CLARK H. C. , LINDEN A. , NICHOLAS A. M. , HAMPDEN‐SMITH M. J. 
Published: May 2016

AbstractThe title complex (III), crystallizing in P21/n with Z=4, is the first example of the exclusive formation of the cis isomer of such a simple Pt(II) complex containing bulky phosphine ligands.
ChemInform Abstract: Effect of Cation on the Structures, Magnetic Properties and Specific Heats of Salts of Bis(5,6‐dihydro‐1,4‐dithiin‐2,3‐dithiolato)nickelate(III): The Crystal Structure of ((CH3)4N) (Ni(DDDT)2).
Authors: WELCH J. H. , BEREMAN R. D. , SINGH P. , HAASE D. , HATFIELD W. E. , KIRK M. L. 
Published: May 2016

AbstractThe title complex (I) crystallizes in Pbca with Z = 8. The X‐ray powder diffraction spectrum of this salt shows the presence of only one crystallographic species, while that of the tetrabutylammonium salt indicates the possibility of a third polymorph.
ChemInform Abstract: Oxovanadium(V)‐Induced Ring‐Opening Oxygenation of Cyclic Ketones in Alcohol.
Authors: HIRAO T. , MORI M. , OHSHIRO Y. 
Published: May 2016

AbstractWhile previous applications of oxovanadium compounds were usually limited to solutions in aqueous acid, the title reaction leading to (III) and (V) uses equimolar or catalytic amounts of oxovanadium ethoxides and alcohol as the solvent.
ChemInform Abstract: Efficient Charge‐Transfer Photochemistry via Fragmentable Cation Radicals with Variable Lifetimes. Direct Comparison with Chloranil Sensitization.
Authors: SANKARARAMAN S. , PERRIER S. , KOCHI J. K. 
Published: May 2016

AbstractThe photochemistry of 1:1 electron‐donor‐acceptor (EDA) complexes of chloranil (II) and the p‐methoxytoluene donors (I) and (V) is reported.
ChemInform Abstract: Intramolecular Photochemical Addition Reactions of ω‐Styrylaminoalkanes.
Authors: LEWIS F. D. , REDDY G. D. , SCHNEIDER S. , GAHR M. 
Published: May 2016

AbstractThe fluorescent singlet state of phenylpropene (I) is quenched by diethylamine (II) with a rate constant of 1.2 · 1010 M‐1 s‐1 near the rate of diffusion in cyclohexane solution.
ChemInform Abstract: Polyfluorinated Aryl Azides as Photoaffinity‐Labelling Reagents. The Room Temperature CH Insertion Reactions of Singlet Pentafluorophenylnitrene with Alkanes.
Authors: YOUNG M. J. T. , PLATZ M. S. 
Published: May 2016

AbstractThe nitrene, photochemically‐generated from pentafluorophenyl azide (I), reacts with cyclopentane (II) to yield the cyclopentylaniline (III).
ChemInform Abstract: Hydrogen‐Abstraction Reactivity of Excited‐State Para‐Substituted Benzyl Radicals in Solution at Room Temperature.
Authors: TOKUMURA K. , OZAKI T. , ITOH M. 
Published: May 2016

AbstractIn contrast to almost no H‐abstraction reactivtiy of the ground‐state p‐X‐benzyl radicals (X: ‐CN, ‐Cl, ‐F, ‐O‐Me) toward 1,4‐cyclohexadiene (CHD), a significant fluorescence quenching by CHD in hexane at room temp. is confirmed for their fluorescent excited states, which may be assigned to 2B2 for p‐cyanobenzyl and 1A2 for the other three p‐X‐benzyls.
ChemInform Abstract: Free Radical Chlorination of Methyl Derivatives of Pyridine, Pyrazine, and Thiazole with N‐Chlorosuccinimide.
Authors: RUBINA K. I. , IOVEL' I. G. , GOL'DBERG YU. SH. , SHIMANSKAYA M. V. 
Published: May 2016

AbstractChlorination of α‐picoline (I) with NCS in the presence of dibenzoyl peroxide gives the chloromethyl (II) or the dichloromethyl derivatives (III) depending on the molar ratio.
ChemInform Abstract: Asymmetric Dihydroxylation of Alkenes with Osmium Tetroxide: Chiral N,N′‐Dialkyl‐2,2′‐bipyrrolidine Complex.
Authors: HIRAMA M. , OISHI T. , ITO S. 
Published: May 2016

AbstractThe bipyrrolidines (I) are used as chiral catalysts for the enantioselective osmylation of alkenes such as (II) or (IV).
ChemInform Abstract: Carboxylic Acid Participation in Amide Hydrolysis. Competition Between Acid‐Catalyzed Dehydration and Anhydride Formation.
Authors: KLUGER R. , HUNT J. C. 
Published: May 2016

AbstractIn 1 M HCl solution the kinetics of the hydrolysis of (II) become biphasic, indicating the acid‐catalyzed equilibration of (II) with the imide (I).
ChemInform Abstract: Organomanganese(II) Reagents. Part 15. Conjugate Addition of Organomanganese Reagents to Alkylidenemalonic Esters and Related Compounds.
Authors: CAHIEZ G. , ALAMI M. 
Published: May 2016

AbstractIn contrast to conjugated enones (as reported previously), alkylidenemalonic ester derivatives (III), (VII), (IX) and (XIII) generally give high yields of conjugate addition products on treatment with organomanganese compounds generated from MnCl2 and Grignard or organolithium reagents (detailed study of reaction conditions in various transformations of (III) and (IX)).
ChemInform Abstract: Nucleophilic Displacement of Bis(perfluoroalkanoyl) Peroxides with Perfluoroalkanoate.
Authors: YOSHIDA M. , SASAGE S. , KAMIGATA N. , SAWADA H. , NAKAYAMA M. 
Published: May 2016

AbstractThe product mixture obtained on warming a solution of (I) and (II) contains perfluoropropylpyridines and C10F22, indicating the initial formation of the mixed peroxide (III) ‐ this would represent the first example of the title reaction reported so far.
ChemInform Abstract: Reaction of N‐Acetyl‐2‐allyloxy‐ and ‐2‐methallyloxyanilines with Sulfenyl Chlorides.
Authors: MEINHOLD H. , MUSLIH R. M. , MUEHLSTAEDT M. + 
Published: May 2016

AbstractAddition of the sulfenyl chlorides (II) to the allyl ethers (I) at low temp. leads preferentially to the anti‐Markovnikov adducts (III) (for R: ‐Me; X: ‐Br at ‐60 °C is (III)/(IV) = 86:14, according to 1H NMR).
ChemInform Abstract: Organic Photochemistry. Part 77. Photochemistry of Alkylindenes in the Gas Phase.
Authors: SUAREZ M. L. , DUGUID R. J. , MORRISON H. 
Published: May 2016

AbstractReported are a) the qualitative and quantitative results of the gas phase photolyses at ca. 1 torr of the methylindenes (I)‐(III) (in each case the two remaining isomers are formed) as well as of dimethylindene (IV); b) studies with 5 deuterated analogs (extensive scrambling is observed); c) effects of added butane (quenching by collisional deactivation occurs), and d) effects of excitation wavelength and substrate temp. on the photolyses.
ChemInform Abstract: Benzopyrylium Salts. Part 34. Reactions of 3‐Carboxy‐2‐benzopyrylium Salts with Amines. Synthesis of Cyclic Ketoles.
Authors: ZHDANOV YU. A. , BROVCHENKO N. A. , KLYUEV N. A. , KUZNETSOV E. V. 
Published: May 2016

AbstractReaction of the benzopyrylium salts (I) with morpholine (II) gives the morpholinoindenes (III).
ChemInform Abstract: Diastereoselectivity in Intramolecular Diels‐Alder Reactions Starting from Dienols: Short Synthesis of Polyfunctional Lactones.
Authors: MARTELLI J. , GREE D. , KESSABI J. , GREE R. , TOUPET L. 
Published: May 2016

AbstractThe structure of the Diels‐Alder adducts (IV) and (V) is confirmed by NMR spectroscopy and by X‐ray analysis of (IVa) (space group P212121 with Z=4).
ChemInform Abstract: Reaction of Chlorosulfonylthiolene and ‐thiolane 1,1‐Dioxide with Amines and Hydroxy Compounds.
Authors: TUKHAR' A. A. , BEZUGLYI YU. V. , FOREMNAYA V. P. , BRATUNETS A. G. , SHAKHVOROST A. M. 
Published: May 2016

AbstractThe sulfolenesulfonic chlorides (I) and (VII) are coupled with the amines (II) to give the sulfonamides (III) and (VIII).
ChemInform Abstract: Synthesis and Water Elimination of 2‐(α‐Alkyl)‐ or (α‐Aryl)‐Substituted Hydroxymethyl‐5‐methoxy‐1,3‐benzoxathiole 3,3‐Dioxides.
Authors: MEICHLE W. , OTTO H.‐H. 
Published: May 2016

AbstractReaction of the bis(silyl)benzoxathiole dioxides (I) with acetaldehyde (II) in the presence of tetrabutylammonium fluoride gives a mixture of the diastereomeric aldols (III) and (IV) which are separated by crystallization and chromatography.
ChemInform Abstract: Camphorylsulfonylimine Dianion in the Synthesis of New Optically Pure Camphorylsulfonyloxaziridine Derivatives.
Authors: DAVIS F. A. , WEISMILLER M. C. , LAL G. S. , CHEN B. C. , PRZESLAWSKI R. M. 
Published: May 2016

AbstractStarting with the camphorylsulfonylimine (‐)‐(II), the synthesis of (+)‐(Ib) is performed as outlined in the reaction scheme.
ChemInform Abstract: Preparation and Pharmacological Activity of N‐Oxides of 4′‐(Benzotriazol‐2‐yl)phenylalkanoic and ‐phenoxyalkanoic Acids.
Authors: BOIDO A. , VAZZANA I. , SPARATORE F. , CAPELLO B. , DIURNO V. , MATERA C. , MARRAZZO R. , RUSSO S. , CENICOLA M. L. , MARMO E. 
Published: May 2016

AbstractThe title compounds (VII) and (XIII) are synthesized from 4‐aminophenylacetonitrile (I) or the 2‐nitroanilines (VIII) as outlined in the reaction scheme.
ChemInform Abstract: Efficient Chiral Synthesis of Melillo′s Lactone, a Key Intermediate for the Synthesis of Thienamycin.
Authors: KAMETANI T. , HONDA T. , ISHIZONE H. , KANADA K. , NAITO K. , SUZUKI Y. 
Published: May 2016

Abstract(‐)‐Carvone (I) is converted into Melillo's lactone (VI) as outlined in the reaction scheme.
ChemInform Abstract: Design and Synthesis of a Series of Facially‐Coordinating Tridentate Ligands Containing an N2O Donor Atom Set.
Authors: JAMESON D. L. , HILGEN S. E. , HUMMEL C. E. , PICHLA S. L. 
Published: May 2016

AbstractPreparation of the tridentate ligand compounds (Va), (Vb), and (X) is described.
ChemInform Abstract: New Methodology for the Preparation of Quinazoline Derivatives via Tandem Aza‐Wittig/Heterocumulene‐Mediated Annulation. Synthesis of 4(3H)‐Quinazolinones, Benzimidazo(1,2‐c)quinazolines, Quinazolino(3,2‐a)quinazolines and Benzothiazolo(3,2‐c)quinazolines.
Authors: MOLINA P. , ALAJARIN M. , VIDAL A. , FOCES‐FOCES M. C. , HERNANDEZ CANO F. 
Published: May 2016

AbstractThe title reaction of iminophosphoranes, e.g. (III), (X), (XIV) and (XVII), yields the title quinazoline derivatives (V), (VIII), (XI), (XIII), (XVIa) (space group P21/c with Z=4), (XVIb) and (XVIII).
ChemInform Abstract: Condensed Thienopyrimidines. Part 3. Synthesis of Angular‐Anellated Oxazolo(2,3‐b)thienopyrimidin‐5‐one Derivatives.
Authors: SUGIYAMA M. , SAKAMOTO T. , FUKUMI H. 
Published: May 2016

AbstractThe N‐(hydroxyethyl)thienopyrimidinediones (I), prepared from aminothiophenes, are converted into the mesylates (III) which undergo cyclization to form the fused oxazolines (IV).
ChemInform Abstract: Alkylation and Arylation of Pyrazines by Organoboron Compounds.
Authors: OHTA A. , ITOH R. , KANEKO Y. , KOIKE H. , YUASA K. 
Published: May 2016

AbstractOrganoborons, generated from bromobenzene (II) or the alkyl bromides (IV), undergo Pd(0)‐catalyzed coupling with the 2‐chloropyrazines (I) to give the 2‐substituted pyrazines (III) or (V).
ChemInform Abstract: Some Reactions of Sultones.
Authors: YASSIN S. , ISMAIL I. I. , ABD EL‐ALEEM A. H. , ATTIA A. 
Published: May 2016

AbstractThe sultone (I) reacts with p‐phenylenediamine (II) to form the sultam (III) which is derivatized, yielding the phenylureas (V), the Schiff bases (VII), and the amides (IX).
ChemInform Abstract: Potential Antidepressants: 6‐(Aminoalkoxy)dibenzo(b,f)thiepin‐10(11H)‐ones and 6‐(Aminoalkoxy)‐10,11‐dihydrodibenzo(b,f)thiepin‐10‐ols.
Authors: CERVENA I. , HOLUBEK J. , SVATEK E. , RYSKA M. , PROTIVA M. 
Published: May 2016

AbstractThe ketones (III) and (VIIa) are partially demethylated to secondary amines (cf.
ChemInform Abstract: Preparation of Chloromethylated Dibenzo‐18‐crown‐6 Derivatives and Syntheses on Their Basis.
Authors: TASHMUKHAMEDOVA A. K. , STEMPNEVSKAYA I. A. , MOROZOVA I. YU. , SIROTENKO E. G. 
Published: May 2016

AbstractChloromethylation of the dibenzo‐18‐crowns‐6 (I) yields the chloromethyl crowns (III) and (IV).
ChemInform Abstract: Supramolecular Catalysis: Polyammonium Macrocycles as Enzyme Mimics for Phosphoryl Transfer in ATP Hydrolysis.
Authors: HOSSEINI M. W. , LEHN J.‐M. , JONES K. C. , PLUTE K. E. , MERTES K. B. , MERTES M. P. 
Published: May 2016

AbstractSubstituted compounds (Ib)‐(Id) show decreased reaction rates with respect to (Ia).
ChemInform Abstract: 11‐Substituted Polyfluorodibenzo(b,f)(1,4)oxazepines.
Authors: KONSTANTINOVA A. V. , GERASIMOVA T. N. , KOZLOVA M. M. , PETRENKO N. I. 
Published: May 2016

AbstractOxidation of the isomeric tetrafluorodibenzoxazepines (I) gives the dibenzoxazepin‐11‐ones (II) which are transformed into the 11‐chloro derivatives (III).
ChemInform Abstract: Synthesis of Some Heterocycles of Pharmaceutical Interest.
Authors: METWALLY M. A. , EL‐HOSSINY M. S. , EL‐ABLAC F. Z. , KHALIL A. M. 
Published: May 2016

AbstractThe β‐keto acids (I) undergo cyclocondensation with the aminoazoles (II) or (IV), yielding the linear polyheterocycles (III) and (V).
ChemInform Abstract: 2,4,6,8,9,10‐Hexachloro‐2,4,6,8,9,10‐hexaboraadamantane.
Authors: HAUBOLD W. , KELLER W. , SAWITZKI G. 
Published: May 2016

AbstractThermolysis of the alkyldichloroboranes (I) leads to the formation of the hexachlorohexaboraadamantane (II) which is treated with dimethylamine (III), yielding the hexakisamino derivative (IV).
ChemInform Abstract: A New and Easy Synthesis of (S)‐5‐Formyl‐5‐trimethylsilyloxymethylpentanoate, a C6 Synthon for LTB4 from (S)‐(+)‐Glutamic Acid.
Authors: LEGGERI P. , AZZOLINA O. , PIRILLO D. , TRAVERSO G. 
Published: May 2016

AbstractThe C6 synthon (X) for the production of leukotriene B4 (XI) is prepared according to the reaction scheme, starting with the chiral lactone (I).
ChemInform Abstract: Stoichiometric and Catalytic Ring Opening of Hexaalkylcyclodisilazanes by Organoalkali Reagents.
Authors: SEYFERTH D. , SCHWARK J. M. , STEWART R. M. 
Published: May 2016

AbstractThe action of organoalkali reagents R1Li (II), (II)/NaOtBu, or (II)/KOtBu on the cyclodisilazanes (I) and (V) results in ring opening to give alkali‐metal amides which react with the chlorosilanes (III) to give the expected linear trisilazanes such as (IV) and (VI).
ChemInform Abstract: Peterson Olefination Reactions of C‐Silylated Phosphoranimines: Synthesis of P‐Vinyl‐Substituted Phosphazene Precursors.
Authors: SCHEIDE G. M. , NEILSON R. H. 
Published: May 2016

AbstractA series of P‐vinyl‐substituted phosphazene compounds such as (III) and (IV) (yield 72%) are prepared by the application of the Peterson olefination reaction to C‐silylated phosphoranimines (I) and its phenoxy analogue.
ChemInform Abstract: Addition of 2‐Bromo‐1,3,2‐dioxaphospholanes to Ynol Ethers.
Authors: KARLSTEDT N. B. , BOGANOVA N. V. , KAZANKOVA M. A. 
Published: May 2016

AbstractThe bromodioxaphospholane (I) reacts with the ynol ethers (II) to produce stereoselectively the phospholanes (III) as a new type of α,β‐unsaturated derivatives of three‐coordinated phosphorus.
ChemInform Abstract: Synthesis and Structure of Ti(OAr‐2,6‐iPr2)2(py‐4‐Ph)3 (OAr‐2,6‐iPr2 : 2,6‐Diisopropylphenoxide; py‐4‐Ph: 4‐Phenylpyridine): A Compound Containing Both Reduced and Nonreduced 4‐Phenylpyridine Ligands Bound to Titanium.
Authors: DURFEE L. D. , HILL J. E. , KERSCHNER J. L. , FANWICK P. E. , ROTHWELL I. P. 
Published: May 2016

AbstractThe trigonal bipyramidal title complex (IV) is obtained according to the scheme.
ChemInform Abstract: Synthesis of Tetrakis(2,6‐diisopropylphenyl)digermene and Its Reductive Cleavage to the Corresponding Digermyllithium Complex.
Authors: PARK J. , BATCHELLER S. A. , MASAMUNE S. 
Published: May 2016

AbstractThe dichlorodiarylgermane (II) is synthesized by chlorination of the diarylgermane (I) with CCl4 or by coupling of GeCl4 (IV) with the Grignard compound (III).
ChemInform Abstract: Structural, IR and Moessbauer Studies of Octahedral cis‐Dichlorobis(diketonate)tin(IV) Complexes Having Antitumor Activity.
Authors: SEARLE D. , SMITH P. J. , BELL N. A. , MARCH L. A. , NOWELL I. W. , DONALDSON J. D. 
Published: May 2016

AbstractThe complex (I), prepared from SnCl4 and dibenzoylmethane, crystallizes in Pbca with Z = 8. An analogous complex containing benzoylacetonato ligands is prepared similarly.
ChemInform Abstract: Preparation and Structure of tert‐Butyl‐Substituted Tin‐Phosphorus Compounds.
Authors: HAENSSGEN D. + , ALDENHOVEN H. , NIEGER M. 
Published: May 2016

AbstractReaction of tri(tert‐butyl)chlorostannane (I) with the alkali phosphides (II) gives the stannylphosphines (III).
ChemInform Abstract: Reactions of Coordinated Dinitrogen. Part 23. Cis and Trans Isomers of Mo(N2)2(PMe2Ph)4.
Authors: GEORGE T. A. , HAYES R. K. , MOHAMMED M. Y. , PICKETT C. J. 
Published: May 2016

AbstractReduction of the trichloride (I) in the presence of 90% of the stoichiometric amount of the phosphine (II) under a modest pressure of N2 results in formation of both the isomers (IV) and (V) which are effectively separated (purity 96/92%) by their different solubilities in pentane.
ChemInform Abstract: Reactions of the Dirhenium(II) Complexes Re2Cl4(PR3)4 with Lithium Aluminum Hydride. A Convenient Synthetic Route to the Dirhenium Octahydride Complexes Re2H8(PR3)4.
Authors: FANWICK P. E. , ROOT D. R. , WALTON R. A. 
Published: May 2016

AbstractA general synthetic method for preparation of the title complexes (III), (IV) (space group P21/n, Z=2; yield 35%), and (V) (70%), which involves the reaction of triply bonded tetrachloride analogues with LiAlH4, is demonstrated for the examples (III).
ChemInform Abstract: Rhenium. Part 20. Synthesis and Characterization of Oxopentakis(isothiocyanato)rhenate(V).
Authors: CHAKRAVORTI M. C. , GANGOPADHYAY T. 
Published: May 2016

AbstractElectrolytic reduction of KReO4 (I) in the presence of NaSCN (II) and H2SO4, dissolving freshly precipitated ReO2 (IV) in 30% HSCN (V), or boiling of (ReO2(en)2)Cl (VI) in 30% HSCN (V) lead to the title anion which is isolated as its salts (III) by addition of CsCl or NMe4Cl or on electrolysis method ‐ of bipyridyl or phenanthroline.
ChemInform Abstract: Characterization of Open Clusters with Linked GeFe2 or SnFe2 Triangles: Structures of Ge2Fe6(CO)23, Sn2Fe6(CO)23, and Ge2Fe7(CO)26.
Authors: ANEMA S. G. , MACKAY K. M. , NICHOLSON B. K. 
Published: May 2016

AbstractReactions of GeH4 or Ge2H6 with Fe2(CO)9 in hexane at 68 °C have revealed a rich system.
ChemInform Abstract: Synthesis, Characterization, and Reactivity of Iron Carbonyl Clusters Containing Bismuth or Antimony. Crystal Structures of Isomorphous (Et4N) (BiFe3Cr(CO)17) and (Et4N) (SbFe3Cr(CO)17) and the Ring Complex Bi2Fe2(CO)8Me2.
Authors: WHITMIRE K. H. , SHIEH M. , CASSIDY J. 
Published: May 2016

AbstractReaction of (NEt4)2(Fe2(CO)8) (I) with ECl3 (II) forms compounds which are proposed to be the previously characterized clusters (III) based on elemental analysis and spectroscopic data.
ChemInform Abstract: A New Route to the Ni(0) “Cradle” Complex Ni2(μ‐CO)(CO)2(PPh2CH2PPh2)2: μ‐CO Ligand and Metal‐Centered Reactivity.
Authors: GONG J.‐K. , KUBIAK C. P. 
Published: May 2016

AbstractThe new convenient preparation route to the title complex (IV) is shown in the scheme.
ChemInform Abstract: Coordination Chemistry of Divalent Cobalt, Nickel and Copper. Part 8. Selected Complexes Containing N‐Substituted Pyridine‐2,6‐dicarboxamide Ligands; Crystal Structure of Dibromo(N,N′‐dimethyl‐N,N′‐diphenylpyridine‐2,6‐dicarboxamide)nickel(II).
Authors: DU PREEZ J. G. H. , VAN BRECHT B. J. A. M. 
Published: May 2016

AbstractThe reactions of corresponding metal(II) salts with the different N‐substituted pyridine‐2,6‐dicarboxamide ligands L1, L2, and L3 lead to the distorted octahedral complexes (I), the octahedral Ni complex (II), the ionic tetrahedral complexes (III), and the α‐isomer (IV) with a pentacoordinate chromophore and the β‐isomer (V) (space group P21/a, Z=4).
ChemInform Abstract: Reactivity of the Metal‐Metal Multiple Bond in Transition Metal Complexes. Part 16. Reaction of (Cp*)2CoRh(μ‐CO)2 (Cp* = η5‐C5Me5) with Sulfur or Selenium and Molecular Structure of (Cp*)2CoRh(CO)2(μ‐Se)2.
Authors: BRUNNER H. , JANIETZ N. , WACHTER J. , NUBER B. , ZIEGLER M. L. 
Published: May 2016

AbstractReaction of the bridged CoRh complex (I) with elemental sulfur (II) gives the octasulfur complexes (III) and/or (IV).