bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Pentadienyl Ligands in Cluster Complexes. Synthesis and Structural Characterization of Ru5(CO)12(μ4‐S)(μ‐H)(μ‐1,5‐Me2C5H5) and Ru6(CO)15(μ4‐S)(μ‐H)(μ‐1,5‐Me2C5H5).
Authors: ADAMS R. D. , BABIN J. E. , TASI M. , WOLFE T. A. 
Published: May 2016

AbstractThe yields of the title compounds are improved considerably (26 and 18%) by using 2,4‐heptadiene as the precursor to the pentadienyl ligand.
ChemInform Abstract: Sorbic Acid Iron Tricarbonyl Complex as Resolving Agent. Chiral Syntheses of 4‐Hydroxy Nonenal and Coriolic Acid.
Authors: DE MONTARBY L. , MOSSET P. , GREE R. 
Published: May 2016

AbstractThe sorbic acid iron carbonyl complex (II) reacts selectively with the racemic alcohol (I) to give the diastereomeric esters (III).
ChemInform Abstract: Effect of Trace Lead on the Coulombic Efficiency of Zinc Electrowinning in High‐Purity Synthetic Solutions.
Authors: FRAZER E. J. 
Published: May 2016

AbstractMeasurements of the coulombic efficiency (QE) for zinc electrodeposition from acidic zinc sulfate solutions under mass‐transfer controlled conditions show that traces of lead (≤ 5 mg/l) have only a small beneficial effect on QE (≤ 1%).
ChemInform Abstract: Degradation Reaction of the 90 K Superconductor YBa2Cu3O7‐δ in H2O
Authors: CHOY J.‐H. , CHUN S.‐H. , KIM B.‐W. , JUNG D.‐Y. , HONG S.‐T. , BYEON S.‐H. 
Published: May 2016

Abstractand in humid environment is studied by XRD, IR spectroscopy and chemical analysis.
ChemInform Abstract: Macrocyclization in the Lactone, Thiolactone and Lactam Series Containing Ethylenedioxy Moiety. The Effect of Silicon and Tin Matrix.
Authors: LEYGUE N. , PICARD C. , TISNES P. , CAZAUX L. 
Published: May 2016

AbstractThe reaction of the acid chlorides (I) and (V) with the compounds (II) yields the monomeric products (III) and (VI) and the dimers (IV) and (VII), respectively.
ChemInform Abstract: Olefin Epoxidation Catalyzed by Sterically Bulky Metalloporphyrins (Metal=Fe,Mn) by Use of Sodium Hypochlorite as an Oxygen Source ‐ A Kinetic Study.
Authors: AMATSU H. , MIYAMOTO T. K. , SASAKI Y. 
Published: May 2016

AbstractThe styrenes (II), cyclooctene, and 1‐octene are epoxidized by complexes (I) in the presence of NaOCl as an oxidant.
ChemInform Abstract: Conversion of Diallyl Sulfide to 1‐Ethyl‐3‐isopropylbenzene in the System KOH‐DMSO.
Authors: MUSORIN G. K. , KRIVDIN L. B. , AMOSOVA S. V. , KALABIN G. A. 
Published: May 2016

AbstractIn the system KOH‐DMSO the conversion of diallyl sulfide (I) proceeds to afford the known isomerization product (II) along with 1‐ethyl‐3‐isopropylbenzene (III), which is observed for the first time to be a product of this reaction.
ChemInform Abstract: A Convenient Synthesis of α′,β‐Diamino‐α,α‐difluoro Ketones, New Dipeptide Isosteres.
Authors: SCHIRLIN D. , BALTZER S. , ALTENBURGER J. M. 
Published: May 2016

AbstractThe diprotected diamino difluoro alcohols (VII) are synthesized by coupling the aldehydes (I) with the bromo ester (II), followed by amination, reduction of the amide group, and N‐protection.
ChemInform Abstract: Stereoselective Aminohydroxylation of the Double Bond in 7‐Oxabicyclo‐(2.2.1)hept‐5‐en‐2‐yl Derivatives. Remote Substituent Participation in Acid‐Catalyzed Decompositions of Aziridines and Triazolines.
Authors: REYMOND J.‐L. , VOGEL P. 
Published: May 2016

AbstractThe bicyclic acetals (I) react with the azidoformate (II) to give the isomeric cycloadducts (III) and (IV) which are photolyzed to yield the aziridines (V).
ChemInform Abstract: A Convenient Synthesis of 4‐tert‐Butyl‐5‐benzofuranols and Dihydrobenzofuranols.
Authors: ZAMBIAS R. A. , CALDWELL C. G. , KOPKA I. E. , HAMMOND M. L. 
Published: May 2016

AbstractThe benzofuranol (VIII) is prepared from cyclohexa‐1,3‐dione (I) as shown in the reaction scheme.
ChemInform Abstract: Synthetic Reactions and Structural Studies of Heterocycles Containing Nitrogen. Part 2. Reaction of 1‐Hydrazinophthalazine with Phenyl(3‐phenyloxiran‐2‐yl)methanone: A Reinvestigation.
Authors: AMER A. , EL MASSRY A. M. , EL SADANY S. , ZIMMER H. 
Published: May 2016

AbstractWhen the free hydrazine of (II) is reacted with oxirane (III) according to the literature, the starting material (III) is always recovered with none of the reported product (I); only traces of (IV) and (V) are formed.
ChemInform Abstract: Boron Trifluoride‐Assisted Ziegler‐Zeiser Reaction of Perfluoroalkyllithiums. An Efficient Synthesis of Perfluoroalkylated Heterocycles.
Authors: UNO H. , OKADA S. , SHIRAISHI Y. , SHIMOKAWA K. , SUZUKI H. 
Published: May 2016

AbstractThe perfluoroalkyllithium compounds, generated in situ from the iodides (I), react with the quinolines (II) to give the 1,2‐dihydroquinolines (III).
ChemInform Abstract: Formation of Fused Tricyclic Azetidinones and Pyrrolidinones by Intramolecular SH2 Processes.
Authors: BECKWITH A. L. J. , BOATE D. R. 
Published: May 2016

AbstractThe β‐methylthiodimethylpropanoyl chloride (I) is first subjected to selective NCS chlorination and then coupled with the amines (III), yielding the amides (IV) which are transformed into the azetidinones (V) by base‐induced ring closure.
ChemInform Abstract: The Preparation of (1‐(Arylimino)alkyl)zinc by the α‐Addition of Organozinc to Isocyanide.
Authors: MURAKAMI M. , ITO H. , ITO Y. 
Published: May 2016

AbstractThe diorganozinc compounds (I) are coupled with the isocyanate (II), forming the aldimines (III) after hydrolysis.
ChemInform Abstract: Mercury in Organic Chemistry. Part 36. Synthesis of (π‐Allyl)palladium Compounds and 1,4‐Dienes via Vinylpalladation of Monocyclic Alkenes.
Authors: LAROCK R. C. , TAKAGI K. 
Published: May 2016

AbstractReaction of the vinylmercuric chloride (I) with cyclic alkenes such as (II) and Li2PdCl4 (III) yields the (π‐allyl)palladium complex (IV).
ChemInform Abstract: Conversion of 48e Os3(CO)10(R‐DAB(4e)) via 50e Os3(CO)10(R‐DAB(6e)) to 50e Os3(CO)9(R‐DAB(8e)) (R‐DAB: RN=C(H)C(H)=NR). Part 2. X‐Ray Structure of Os3(CO)9(iPr‐DAB(8e)), with Two Elongated Os‐Os Bonds.
Authors: ZOET R. , VAN KOTEN G. , STUFKENS D. J. , VRIEZE K. , STAM C. H. 
Published: May 2016

AbstractThe 48e cluster (I) with a chelating 4e‐donating diazabutadiene ligand is converted in refluxing hexane into the 50e cluster (IIa) with a bridging 6e‐donating ligand.
ChemInform Abstract: Biotransformations of Diterpenes: Conversion of ent‐13‐epi‐Manoyl Oxides by Rhizopus nigricans Cultures.
Authors: ARIAS J. M. , GARCIA‐GRANADOS A. , JIMENEZ M. B. , MARTINEZ A. , RIVAS F. , ONORATO M. E. 
Published: May 2016

AbstractIncubation of the manoyl oxide (Ia) or the normanoyl oxide (Ib) with Rhizopus nigricans cultures leads mainly to the products (II) resulting from hydroxylation at C‐20. Additionally, a variety of other hydroxylation and deacetylation products are isolated, among them (III) and (IV).
ChemInform Abstract: Preparation of “Unnatural” Tellurium Analogues of Naturally Occurring Chromones and Flavones. The Control of Ipso vs Ortho Acylation, Selective Demethylation, and Olefin‐Forming Condensation Reactions in Benzo(b)tellurapyranones.
Authors: DETTY M. R. 
Published: May 2016

AbstractIntramolecular acylation approaches to the title tellurium compounds are complicated by ipso acylation of the tellurium‐bearing ring as shown by the reaction of the acid chloride (I).
ChemInform Abstract: DNA Cleavage by a Synthetic Mimic of the Calicheamicin‐Esperamicin Class of Antibiotics.
Authors: NICOLAOU K. C. , OGAWA Y. , ZUCCARELLO G. , KATAOKA H. 
Published: May 2016

AbstractStarting from the diol (I) the preparation of the cyclodecaenediyne diol (IX) is described.
ChemInform Abstract: Enantioselective Synthesis of the 1β‐Methylcarbapenems via Cycloaddition of 3‐Siloxypentadiene and 4‐Acetoxyazetidinone.
Authors: SOWIN T. J. , MEYERS A. I. 
Published: May 2016

AbstractCycloaddition reaction of the butadiene (II) with the lactam (I) results in the formation of the adducts (III) and (IV).
ChemInform Abstract: Ring Currents in Wholly Inorganic Heteropoly Blue Complexes. Evaluation by a Modification of Evans′s Susceptibility Method.
Authors: KOZIK M. , CASAN‐PASTOR N. , HAMMER C. F. , BAKER L. C. W. 
Published: May 2016

AbstractFor seven diamagnetic heteropoly complexes, α‐isomers of (I), (IIa), and (III), α1‐ and α2‐isomer of (IIb), the difference between the diamagnetic susceptibility of each and that of its 2e‐ reduction product is measured by the Evans NMR susceptibility method.
ChemInform Abstract: Preparation and Properties of Double Dihydrophosphates of Magnesium and Zinc.
Authors: PONOMAREVA I. G. , SHCHEGROV L. N. , ANTRAPTSEVA N. M. 
Published: May 2016

AbstractThe reaction between mixtures of the hydroxocarbonates of Mg and Zn and monophosphoric acid affords the novel title compounds Mg1‐xZnx(H2PO4)2·2 H2O (0 < x < 1).
ChemInform Abstract: Acidity and Dimerization of Three Water‐Soluble Iron(III) Porphyrin Cations: (meso‐α,β,α,β‐Tetrakis(o‐(N‐methylnicotinamido)phenyl)por# phyrinato)iron(III), (meso‐α,α,α,α‐Tetrakis(o‐(N‐methylnicotinamido)phenyl)p# orphyrinato)iron(III), and (meso‐Tetrakis(1‐methylpyridinium‐4‐yl)porphyrinato)iron(III).
Authors: MISKELLY G. M. , WEBLEY W. S. , CLARK C. R. , BUCKINGHAM D. A. 
Published: May 2016

AbstractAcidity data for the monomeric diaquo title porphyrins having both sides of the macrocyclic plane restricted toward further coordination (substituents in α‐ and β‐position) or one face restricted (substituents only in α‐position) or having both faces open toward coordination by a fifth and sixth ligand are determined by spectrophotometric titration.
ChemInform Abstract: Equilibria and Dissociation Kinetics of Lanthanoid Complexes of Diaza Crown Ether Carboxylic Acids
Authors: CHANG C. A. , CHANG P. H.‐L. , MANCHANDA V. K. , KASPRZYK S. P. 
Published: May 2016

Abstract(stability constant of the lanthanoid complexes of (I) and transition‐metal (M) analogues (e.g.
ChemInform Abstract: Reagent‐Controlled Addition of (R)‐ and (S)‐2‐Hydroxy‐1,2,2‐triphenylethyl Acetate to Chiral Aldehydes.
Authors: MAHLER U. , DEVANT R. M. , BRAUN M. 
Published: May 2016

AbstractThe corresponding enantiomeric enolates generated by double deprotonation of the title compounds (I) and (VI) are added to chiral aldehydes such as (III).
ChemInform Abstract: An Efficient, Palladium‐Catalyzed Route to Protected Allylic Amines.
Authors: CONNELL R. D. , REIN T. , AKERMARK B. , HELQUIST P. 
Published: May 2016

AbstractAllylic acetates such as (I) are treated with the sodium or lithium salt of di‐tert‐butyl iminodicarbonate (II) in the presence of a Pd catalyst, yielding di(tert‐butoxycarbonyl) protected allylic amines such as (III).
ChemInform Abstract: Cycloadditions. Part 13. Reactions of Ynamines with 1,1‐Bis(phenylsulfonyl)olefins.
Authors: HIMBERT G. , KOSACK S. 
Published: May 2016

AbstractThe title ynamines (I) react with the alkene (II) via (2 + 2) cycloaddition followed by ring opening to give the dienes (III).
ChemInform Abstract: N‐(1,3‐Thiazol‐5(4H)‐ylidene)amines via 1,3‐Dipolar Cycloaddition of Azides and 1,3‐Thiazole‐5(4H)‐thiones.
Authors: PEKCAN S. , HEIMGARTNER H. 
Published: May 2016

AbstractOrganic azides (II) react with the thiazolethiones (I) in toluene at 90 °C to give the thiazolimines (III).
ChemInform Abstract: Synthesis of Substituted Pyridines Using α,β‐Unsaturated Nitriles and Active Cyano Compounds.
Authors: FUENTES L. , VAQUERO J. J. , ARDID M. I. , LORENTE A. , SOTO J. L. 
Published: May 2016

AbstractCyclocondensation of the benzenesulfonylacetonitrile (I) with the cinnamonitriles (II) in the presence of sodium methoxide (III) yields the 3,4‐dihydropyridines (IV) which are dehydrogenated upon treatment with potassium permanganate, forming the pyridines (V).
ChemInform Abstract: Derivatives of the Benzo(5,6)cyclohepta(1,2,3‐cd)thieno(3,2‐c)pyridine System. X‐Ray Crystal Structure of 8,9‐Dimethoxy‐1,2,3,6,11,11a‐hexahydrobenzo(5,6)cyclohepta(1,2,3‐cd)thieno(3,2‐c)pyridine‐1‐carbonitrile
Authors: BREMNER J. B. , BROWNE E. J. , ENGELHARDT L. M. , HYLAND B. A. , JAMES G. S. , WHITE A. H. 
Published: May 2016

Abstract(IIIb).
ChemInform Abstract: Synthesis and Some Reactions of 2‐(α‐Benzoylaminostyryl)‐3,1(4H)‐benzoxazin‐4‐one and 3‐Amino‐2‐(α‐benzoylaminostyryl)quinazolin‐4(3H)‐one.
Authors: EL‐NAGDY S. , EL‐KHAMRY A. A. , SHAABAN M. A. , HABASHY M. M. 
Published: May 2016

AbstractThe benzoxazinone (I) reacts with sodium azide (II) to yield a mixture of the benzimidazolinone (III) and the tetrazole (IV).
ChemInform Abstract: Metal π Complexes of Heteroarenes, Part 2. η6‐Coordination of Unsubstituted Pyridine: (η6‐Benzene)(η6‐pyridine)chromium and Bis(η6‐pyridine)chromium.
Authors: ELSCHENBROICH C. , KOCH J. , KROKER J. , WUENSCH M. + , MASSA W. , BAUM G. , STORK G. 
Published: May 2016

AbstractThe first bis(arene) complex, (IV), of unsubstituted Py is prepared by a three‐component cocondensation.
ChemInform Abstract: Synthesis and Characterization of (η3‐CPh3)Re(CO)4, a Thermal Precursor for Generation of the Re(CO)5 Radical.
Authors: CROCKER L. S. , MATTSON B. M. , HEINEKEY D. M. , SCHULTE G. K. 
Published: May 2016

AbstractThe reaction of Na(Re(CO)5) in situ with (Ph3C)BF4 (II) affords the title complex (III).
ChemInform Abstract: Nickel(II) and Nickel(III) Bis(dipeptido) Complexes of α‐Aminoisobutyric Acid.
Authors: ANLIKER S. L. , BEACH M. W. , LEE H. D. , MARGERUM D. W. 
Published: May 2016

AbstractNi(II) forms the high‐spin complex (I) which changes at pH 9‐11 to a low‐spin form (II).
ChemInform Abstract: Preparation of a Deuterated Analogue of Tetrahydropapaveroline Suitable for Use as an Internal Standard for GC/MS Analysis of This Alkaloid: Retro Pictet‐Spengler Condensation.
Authors: CLEZY P. S. , DUNCAN M. W. , SMYTHE G. A. 
Published: May 2016

AbstractSome experiments are described with regard to an attempted preparation of deuterated analogues of salsolinol (I) and tetrahydropapaveroline (VII).
ChemInform Abstract: Reactions of Titanium Tetrachloride with Bistrimethylsilyl Sulfide. Crystal Structures of (NEt4)2(TiSCl4), (PPh4)2(TiSCl4)·2 CH2Cl2, (PPh4)2(Ti3O(S2)3Cl6)·CH3CN and Ti4O(S2)4Cl6.
Authors: KRUG V. , KOELLNER G. , MUELLER U. + 
Published: May 2016

AbstractThe title compounds (V) contain the square‐pyramidal (TiSCl4)2‐ ion.
ChemInform Abstract: Formation of Cyclohexadienyl‐Type Radicals in the Photoreduction of Xanthone as Studied by a Laser Photolysis‐ESR Technique.
Authors: SAKAGUCHI Y. , HAYASHI H. , MURAI H. , I'HAYA Y. J. 
Published: May 2016

AbstractIn the photoreaction with isopropanol, the normal ketyl radical (II) is found.
ChemInform Abstract: Stereoselective Synthesis of α‐Methylene‐β‐hydroxy‐γ‐alkoxy Esters and Ketones.
Authors: DREWES S. E. , MANICKUM T. , ROOS G. H. P. 
Published: May 2016

AbstractThe α‐alkoxy aldehydes (I) are coupled with the α,β‐unsaturated esters or ketones (II) in the presence of azabicycles as catalysts, producing the adducts (III) with predominance of the anti‐isomers.
ChemInform Abstract: Intramolecular Diels‐Alder Reaction with Inverse Electron Demand in 2‐(2,3‐Diphenylcyclopropen‐1‐yl)‐β‐tropolone. Construction of a Bridged Semibullvalene‐Type Carbon Skeleton.
Authors: TAKAHASHI K. , NAMEKATA N. , FUKAZAWA Y. , TAKASE K. , MIKAMI E. 
Published: May 2016

AbstractThe tropolone (I) reacts with diphenylcyclopropenium tetrafluoroborate (II) to give an equilibrium between the dione (III) and its tautomer (IV).
ChemInform Abstract: An Annulation Method Leading to Fused Bicyclic Systems Containing an Allylic, Angular Hydroxyl Group.
Authors: PIERS E. , MARAIS P. C. 
Published: May 2016

AbstractThe cyclohexane‐1,4‐dione monoacetal (I) is converted to the iodoalkenyl derivatives (II) which undergo base‐induced ring closure, yielding the cis‐ (III) and trans‐fused hydroxybicycles (IV).
ChemInform Abstract: 4‐Iodo‐1,3,5,7‐tetramethyl‐1,3,5,7‐tetraaza‐4λ5‐phosphaspiro(3.3)heptane# ‐2,6‐dione; Synthesis and Crystal Structure of the First Iodophosphorane.
Authors: BREKER J. , JONES P. G. , STALKE D. , SCHMUTZLER R. 
Published: May 2016

AbstractThe title compound (III) is prepared (see scheme).
ChemInform Abstract: Acetals with a Phosphoryl Substituent in the Alcoholic Fragment.
Authors: GAZIZOV M. B. , KHAIRULLIN R. A. 
Published: May 2016

AbstractThe vinylic ethers (I) or (IV) are coupled with the α‐hydroxyalkylphosphonates(phosphinates) (II) to give the acetals (III) or (V).
ChemInform Abstract: Reactive π‐Complexes of Electron‐Rich Transition‐Metals. Part 7. Tetrakis(bis(trimethylsilyl)ethyne)diiron.
Authors: SCHAEUFELE H. + , PRITZKOW H. , ZENNECK U. 
Published: May 2016

AbstractThe first structurally characterized ( P21/n, Z=2) homoleptical metal alkyne cluster, the title compound (III), is formed from the silylated ethyne (II) and (I) or η6‐toluene‐(η4‐1‐methylnaphthalene)iron (both available by cocondensation) on standing several days.
ChemInform Abstract: Pentamethylcyclopentadienyl Rhodium Complexes of Dihydro‐s‐indacenophanes: Transannular Interactions.
Authors: BICKERT P. , HAFNER K. 
Published: May 2016

AbstractOn treatment of the η6‐complex (I) with alumina BIII deprotonation and subsequent migration of the C5Me5Rh group from the six‐membered to one of the five‐membered rings occurs.
ChemInform Abstract: Heterocycles from Carbohydrate Precursors. Isomerism and Reactions of Some Arylhydrazones of Dehydro‐L‐ascorbic Acid and Its D‐erythro and D‐arabino Analogues.
Authors: EL KILANY Y. , MOUSAAD A. , ABDEL HAMID H. , EL ASHRY E. S. H. 
Published: May 2016

AbstractRegioselective hydrazonization of dehydro‐L‐ascorbic acid (IV), formed by oxidation of L‐ascorbic acid (I), with acetone arylhydrazones such as (II) yields corresponding 2‐arylhydrazones such as (III), whereas the direct reaction of (IV) with two equivalents of arylhydrazines, e.g. (V), gives the respective 2,3‐bis(arylhydrazones) existing as two geometric isomers, e.g. red‐colored (VI) and orange‐colored (VII), which can be isolated in some cases.
ChemInform Abstract: Antiinflammatory 2,3‐Dihydro‐1H‐pyrrolizines. Part 14. Isomeric Diaryldihydropyrrolizinyl Formic and Propionic Acids.
Authors: DANNHARDT G. , LEHR M. 
Published: May 2016

AbstractThe pyrrolizine derivative (I) is lithiated and then carboxylated, yielding the pyrrolizinylcarboxylic acid (III).
ChemInform Abstract: Reactions of 2‐(Tributylstannyl)‐4,4‐dimethyl‐2‐oxazoline with Organic Halides. Unusual Product from Aroyl Halide.
Authors: KOSUGI M. , FUKIAGE A. , TAKAYANAGI M. , SANO H. , MIGITA T. , SATOH M. 
Published: May 2016

Abstract2‐Tributylstannyl‐4,4‐dimethyloxazoline (I) reacts with the halides (II) in the presence of a palladium catalyst to give the substitution products (III).
ChemInform Abstract: A Facile Synthesis of 3‐Amino‐5‐Substituted‐aminoisothiazole‐4‐carboxylic Acid Derivatives.
Authors: SHISHOO C. J. , DEVANI M. B. , ANANTHAN S. , BHADTI V. S. , ULLAS G. V. 
Published: May 2016

AbstractThe diaminoisothiazole‐4‐carboxylic acid derivatives (VI) are synthesized as outlined in the reaction scheme.
ChemInform Abstract: Studies on Polythiaaromatic Compounds. Part 1. Synthesis and Electrochemical Properties of 2,3,6,7‐Tetrahydro‐1,4,5,8‐tetrathiaanthracene (HTA) and Its Derivatives.
Authors: NABESHIMA T. , IWATA S. , FURUKAWA N. , MORIHASHI K. , KIKUCHI O. 
Published: May 2016

AbstractThe 1,2,4,5‐tetrahalobenzenes (I) react with isopropyl mercaptan (II) to form the tetrathioethers (III) which are reduced and then coupled with 1,2‐dibromoethane (IV) to give the octahydrotetrathiaanthracenes (V).
ChemInform Abstract: Synthesis of an Unreactive Ylid Designed as A‐C‐P‐C‐P Diphosphate Isostere Synthon.
Authors: MCCLARD R. W. , JACKSON S. A. 
Published: May 2016

AbstractCoupling of the bis(iodomethyl)phosphinate (I) with diphenyl methyl phosphite (II) yields the iodide (III) which is combined with triphenylphosphine (IV), forming the phosphonium salt (V).
ChemInform Abstract: Synthesis, Electrochemistry, and Spectroscopic Properties of Six‐Coordinate Monooxomolybdenum(VI) Complexes Containing Tridentate Schiff Base and Bidentate Catecholate Ligands. Crystal and Molecular Structure of (N‐Salicylidene‐2‐aminophenolato)(naphthalene‐2,3‐diolato)oxomolybdenum(VI).
Authors: MONDAL J. U. , SCHULTZ F. A. , BRENNAN T. D. , SCHEIDT W. R. 
Published: May 2016

AbstractThe complexes (III) and (IV) are the first examples of a mononuclear MoO4+ center with a coordination number of six.
ChemInform Abstract: Nickel‐Thiolate Chemistry Based on Chelating Ligands: Controlling the Course of Self‐Assembly Reactions via Ligand Bite Distances. Synthesis, Structures, and Properties of the Homoleptic Complexes (Ni3(SCH2C6H4CH2S)4)2‐, (Ni3(SCH2CH2S)4)2‐, and (Ni6(SCH2CH2CH2S)7)2‐.
Authors: TREMEL W. , KRIEGE M. , KREBS B. , HENKEL G. 
Published: May 2016

AbstractThe reaction systems of NiCl2 and appropriate dithiolates in MeOH or acetone afford the title complexes (I) to (III).
ChemInform Abstract: Sulfur Dioxide as Ligand and Synton. Part 7. Phosphane Sulfur Dioxide Nickel(0) and Palladium(0) Complexes.
Authors: HOFFMANN TH. , HOFFMANN H. , KARABIT M. , ZDUNNECK P. , WENSCHUH E. , REINHOLD J. , SCHUELER M. + 
Published: May 2016

AbstractThe reactions of Ni(cod)2 or in some cases of Ni(PPh3)2(CH2=CH2) with tert. phosphanes and SO2 result in formation of phosphane sulfur dioxide complexes of the type (I), (II), and (III) depending on the phosphane substituents and the reaction conditions (molar ratio, temp., solvent, SO2 concentration).
ChemInform Abstract: Orientation and Conformation of NAD and NADH Adsorbed on Colloidal Silver.
Authors: SIIMAN O. , RIVELLINI R. , PATEL R. 
Published: May 2016

AbstractSurface‐enhanced Raman scattering (SERS) from NAD and NADH on colloidal silver is observed after the silver particles are induced to aggregate to varying degrees.
ChemInform Abstract: Drug Tablets Glycyrrhizin and Trapizil as ESR Radiation Dosimeter.
Authors: IKEYA M. , KAI A. 
Published: May 2016

Abstractγ‐Irradiation of commercial drug tablets, Trapidil and Glycyrrhizin for heart and liver treatments gives sharp ESR signals, whose intensity is the strongest at the boundary with the coating material.
ChemInform Abstract: Thermal and Moessbauer Studies of Iron‐Containing Hydrous Silicates. Part 7. Glauconite.
Authors: MACKENZIE K. J. D. , CARDILE C. M. , BROWN I. W. M. 
Published: May 2016

AbstractResults of thermal analysis, XRD, and Moessbauer spectroscopic studies for four purified glauconites indicate the unheated minerals to have monoclinic layer‐lattice structures with the cis‐ and trans‐octahedral sites being occupied.
ChemInform Abstract: Crystal Structure of Holmium Tetramolybdate, Ho2Mo4O15.
Authors: EFREMOV V. A. , DAVYDOVA N. N. , GOKHMAN L. Z. , EVDOKIMOV A. A. , TRUNOV V. K. 
Published: May 2016

AbstractThe title compound is prepared by solid phase reaction of a stoichiometric mixture of Ho2O3 and MoO3, which is heated to 400‐650 °C for two weeks.
ChemInform Abstract: Metal Chloride Equilibria. Part 2. Lead(II) Chloride Complexes.
Authors: FERRI D. , SALVATORE F. 
Published: May 2016

AbstractResults of investigations of the complex formation equilibria between Pb(II) and Cl‐ ions at 25 °C in 5 m NaClO4 medium using potentiometric methods based on a cell without junction can be explained assuming the reactions shown in the scheme.
ChemInform Abstract: Corrosion of Silicon Nitride Ceramics in Aqueous Hydrogen Chloride Solutions.
Authors: SATO T. , TOKUNAGA Y. , ENDO T. , SHIMADA M. , KOMEYA K. , KOMATSU M. , KAMEDA T. 
Published: May 2016

AbstractThe effect of processing additives such as Y2O3, Al2O3, and AlN on the corrosion behavior of Si3N4 ceramics in 0.1‐10 M HCl solutions is studied at 50‐100 °C. Si3N4 ceramics without additives are more resistant to corrosion attack than ceramics containing additives, which show significant degradation of the fracture strength.
ChemInform Abstract: Reaction of Potassium Hydrogendifluoride with Hydrogen Peroxide.
Authors: TITOVA K. V. , GELYUK I. P. , ROSOLOVSKII V. YA. 
Published: May 2016

AbstractThe peroxosolvate KHF2·H2O2 is prepared for the first time by the reaction between KHF2 and 30% H2O2.