bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Imidazo(2,1‐b)benzothiazoles. Part 2. Synthesis and Antiinflammatory Activity of Some Imidazo(2,1‐b)benzothiazoles.
Authors: EL‐SHORBAGI A.‐N. , SAKAI S. , EL‐GENDY M. A. , OMAR N. , FARAG H. H. 
Published: May 2016

AbstractReaction of the imidazobenzothiazoles (I) with acrylic acid (II) yields the propionic acids (III) which are esterified to give the methyl esters (V).
ChemInform Abstract: Synthesis and Antihypertensive Activity of 4‐(1,2‐Dihydro‐2‐oxo‐1‐pyridyl)‐2H‐1‐benzopyrans and Related Compounds, New Potassium Channel Activators.
Authors: BERGMANN R. , GERICKE R. 
Published: May 2016

AbstractThe dihydrobenzopyran epoxides (IV) and the bromobenzopyran (VIII), prepared as outlined in the reaction scheme, are coupled with N‐heterocycles such as (V) to give the corresponding substitution products (VI) and (IX).
ChemInform Abstract: Synthesis of 4‐(Arylthio)‐ and (Alkylthio)thiochromans.
Authors: NAKAZAWA T. , SATO K. , ITABASHI K. 
Published: May 2016

AbstractAddition of the α,β‐unsaturated aldehydes (II) to the thiophenols (I) in the presence of sulfuric acid leads to the formation of the 3‐phenylthiopropionaldehydes (III) which react with the thiols (IV) to give the hemithioacetals (V).
ChemInform Abstract: Alkaline Metal Fluorides in Graphite. New Catalysts in Organic Synthesis. Part 1. Reactions of Polyfluoroaromatic Compounds with O‐ and N‐Nucleophilic Agents.
Authors: AKSENOV V. V. , VLASOV V. M. , DANILKIN V. I. , RODIONOV P. P. , SHNITKO G. N. 
Published: May 2016

AbstractAlkaline metal fluoride graphite intercalates of the general formula C8MF, in which M is Li, K, Rb, or Cs, catalyze nucleophilic aromatic substitution reactions of polyfluoroaromatic compounds, as outlined in the reaction scheme.
ChemInform Abstract: Reversible Inhibitors of the Gastric (H+/K+)‐ATPase. Part 1. 1‐Aryl‐4‐methylpyrrolo(3,2‐c)quinolines as Conformationally Restrained Analogues of 4‐(Arylamino)quinolines.
Authors: BROWN T. H. , IFE R. J. , KEELING D. J. , LAING S. M. , LEACH C. A. , PARSONS M. E. , PRICE C. A. , REAVILL D. R. , WIGGALL K. J. 
Published: May 2016

AbstractThe diaminoquinoline (IV), prepared from the chloronitroquinoline (I) and the aniline (II) and subsequent reduction, is cyclized by reaction with formic acid (V), NaNO2 (VII), or CS2 (IX) to give the five‐membered heterocycles (VI), (VIII), and (X).
ChemInform Abstract: Synthesis of 4‐Oxopyrrolo(1,2‐a)pyrimidine‐3‐carboxylic Acid Derivatives as Potential Antimicrobial Agents.
Authors: BAYOMI S. M. , AL‐OBAID A. R. M. , JADO A. I. , LOUTFY E. A. 
Published: May 2016

AbstractThe synthesis of the title compounds, e.g. (IV), is achieved by reaction of 2‐aminopyrroles, e.g. (I), with the ethoxymethylenemalonate (II) followed by cyclization of the aminomethylene derivative (III).
ChemInform Abstract: Synthesis of 3‐(3,4‐Dihydro‐4‐oxothieno(2,3‐d)pyrimidine‐2‐yl)propionic Acid.
Authors: PECH R. , SCHLEIERMACHER E. , BOEHM R. + 
Published: May 2016

AbstractThe condensation of the 2‐amino‐3‐carboxylic acid ester (Ia) or the amide (Ib) with succinic anhydride (II) gives the adducts (III).
ChemInform Abstract: Pterine Chemistry. Part 87. Regiospecific Synthesis of (Polyhydroxypropyl)‐pterins: Synthesis of D‐Anapterin and L‐Primapterin.
Authors: VISCONTINI M. , BOSSHARD R. 
Published: May 2016

AbstractThe in situ formed semicarbazones (I) and (IV) of D‐ribose or 5‐deoxy‐L‐arabinose, resp., are efficiently used in condensation reactions with the triaminopyrimidinone (II) to provide the title products (III) (D‐anapterin) and (V) (L‐primapterin).
ChemInform Abstract: Design and Synthesis of 4H‐3,1‐Benzoxazin‐4‐ones as Potent Alternate Substrate Inhibitors of Human Leukocyte Elastase.
Authors: KRANTZ A. , SPENCER R. W. , TAM T. F. , LIAK T. J. , COPP L. J. , THOMAS E. M. , RAFFERTY S. P. 
Published: May 2016

AbstractNumerous (175) benzoxazinones are synthesized by different methods partially outlined in the reaction scheme.
ChemInform Abstract: Transition‐Metal‐Catalyzed Cyclization of (a,c) Biladiene Salts as an Efficient Route to the Synthesis of Alkyl Porphyrins.
Authors: BOSCHI T. , PAOLESSE R. , TAGLIATESTA P. 
Published: May 2016

AbstractThe previously studied cyclization of 1,19‐unsubstituted (a,c)‐biladiene salts catalyzed by Cr(III), Ru(III) and Rh(III) is now extended to several 1,19‐disubstituted analogues such as (I).
ChemInform Abstract: New Tetraheterocyclic Macrocycles Containing Triazole, Pyrazole, Pyridine, and/or Furan Subunits. Synthesis and Cation Binding Properties.
Authors: TARRAGO G. , MARZIN C. , NAJIMI O. , PELLEGRIN V. 
Published: May 2016

AbstractThe synthesis of tetraheterocyclic macrocyclic ligands such as (III) is performed as outlined in the reaction scheme.
ChemInform Abstract: Isolation and Unusual Stability of a New Macrocyclic Polyamine Containing a Phthalimidine.
Authors: KIMURA E. , YOSHIYAMA Y. , SHIONOYA M. , SHIRO M. 
Published: May 2016

AbstractThe dibromide (I) is cyclized with the pentamine pentatosylate (II) to yield the macrocycle (III).
ChemInform Abstract: Functionalized Basket‐Shaped Hosts. Synthesis and Complexation Studies with (Alkali) Metal and Ammonium and Diammonium Ions.
Authors: SMEETS J. W. H. , VAN DALEN L. , KAATS‐RICHTER V. E. M. , NOLTE R. J. M. 
Published: May 2016

AbstractThe basket‐shaped hosts such as (IIIa) are prepared by reaction of the concave building block (I) with primary amines such as (II).
ChemInform Abstract: Chemistry of Organosilicon Compounds. Part 263. Synthesis, Properties, and Molecular Structure of Highly Distorted Hexakis(trimethylsilyl)benzene.
Authors: SAKURAI H. , EBATA K. , KABUTO C. , SEKIGUCHI A. 
Published: May 2016

AbstractThe title compound (III), the most distorted benzene to a chair form, crystallizes in the space group P212121 with Z=4.
ChemInform Abstract: Relative Reactivity of Decamethylsilicocene and Decamethylsamarocene: Reduction of (C5Me5)2SiCl2 by Sm(II) Reagents.
Authors: EVANS W. J. , ULIBARRI T. A. , JUTZI P. 
Published: May 2016

AbstractStudies show that decamethylsamarocene (II) is the more strongly reducing of the two title complexes.
ChemInform Abstract: Reaction of Vinylacetylenic Sulfones with Alkanethiols and Amines.
Authors: KURAKIN O. A. , STADNICHUK M. D. 
Published: May 2016

AbstractReaction of the 1‐alken‐3‐ynyl aryl sulfones (I) with ethanethiol (II) gives the 2‐ethylthio‐3‐alkynyl sulfones (III), the 4‐ethylthio‐1,3‐alkadienyl sulfones (IV) and (V), or the ethyl nitrophenyl sulfide (VI) depending on M and the reaction conditions.
ChemInform Abstract: Aspects of the Cleavage of Phosphines with Potassium: Synthesis and Reactivity of Lithium and Potassium Bis(p‐(dimethylamino)phenyl)phosphide.
Authors: TOTH I. , HANSON B. E. , DAVIS M. E. 
Published: May 2016

AbstractFrom the cleavage of arylphosphines with different alkali metals to yield phosphides, it is concluded that it is difficult to predict the success of a particular phosphine cleavage reaction.
ChemInform Abstract: Reaction of Aryltetraiodophosphoranes with N‐Si Compounds.
Authors: KOVALEVA T. V. 
Published: May 2016

AbstractDue to equilibration with the corresponding arylphosphonous diiodides and iodine, the aryltetraiodophosphoranes (I) react in solution with the N‐trimethylsilylphosphine imide (II) to give the phosphonium salts (III).
ChemInform Abstract: Reaction of Aminoarsines with Carbon Disulfide.
Authors: KOKOREV G. I. , BADRUTDINOV SH. KH. , AL'METKINA L. A. , YAMBUSHEV F. D. 
Published: May 2016

AbstractThe arsonous (arsinous) amides (I) and the arsonamidous halides (XII) are coupled with carbon disulfide (II) to give the dithiocarbamates (III) and (XIII) respectively.
ChemInform Abstract: From Germenes to Transient Germanimines.
Authors: LAZRAQ M. , COURET C. , DECLERCQ J. P. , DUBOURG A. , ESCUDIE J. , RIVIERE‐BAUDET M. 
Published: May 2016

AbstractThe reactions of the germene (I), obtained by dehydrofluorination of the corresponding fluorogermane, with the diazo compounds (II) and (VI) lead to the cyclodigermazanes (IV) and (VIII), probably via transient germanimines (III) and (VII) with evolution of fluorenyl carbene from (I).
ChemInform Abstract: Arsenic‐Sulfur Heterocycle Formation via Metal Coordination. Synthesis and Molecular Structure of cyclo‐(CH3AsS)n (n = 3, 4), ((CO)3Mo)(η3‐cyclo‐(CH3As)6S3), and the Triple‐Decker‐Sandwich Complex (η5‐(C5H5)2Mo2(η2,μ‐As3)(η2,μ‐AsS)).
Authors: DIMAIO A.‐J. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe metal‐mediated formation of the cycloarsathianes (IIIa) (space group P1, Z=4) and (IIIb) (Pn21a, Z = 8) occurs via the metal‐bound precursor (IV) (P21/c, Z=4) which can be isolated in 20% yield from the reaction of an excess of (I) with Mo(CO)6 and S8 (molar ratio 2.6:1.9:1.1) in a Carius tube at 100 °C. In the absence of Mo(CO)6, an array of oligomeric products is formed, many containing S‐S or As‐As bonds instead of the perfect S‐As alternation of the arsathianes.
ChemInform Abstract: Electrophilic Addition Reactions of Tungsten η2‐Allenyl Complexes Formed by Deprotonation of Four‐Electron Alkyne Ligands.
Authors: GAMBLE A. S. , BIRDWHISTELL K. R. , TEMPLETON J. L. 
Published: May 2016

AbstractDeprotonation of a series of cationic W alkyne complexes e.g. (III) with strong bases (KH, LDA, or NaN(SiMe3)2) generates corresponding neutral η2‐allenyl complexes which exist as a mixture of the two isomers (IV) and (V) in solution at 25 °C. Since these allenyl complexes readily add electrophiles (H+ and Me+) at the γ‐C atom as demonstrated for the methylation at room temp. giving the two diastereomers (VII) and (VIII), they offer a route to systematically substitute cationic alkyne complexes at the alkyne γ‐C atom position.
ChemInform Abstract: Silicon‐Containing Carbene Complexes. Part 13. Synthesis and Properties of the 16‐Electron Carbene Complexes (CO)4MC(NR2)SiR′3 (M: Cr, Mo, W).
Authors: HEPP W. , SCHUBERT U. 
Published: May 2016

AbstractDialkylaminocarbene complexes of the type (III) are obtained using the amines (II).
ChemInform Abstract: Reaction Between Benzophenone and Ditungsten Hexaalkoxides. Molecular Structure and Reactivity of W(OCH2‐tBu)4(py)(η2‐OCPh2).
Authors: CHISHOLM M. H. , FOLTING K. , KLANG J. A. 
Published: May 2016

AbstractIn contrast to dialkylketones, the reactions between ditungsten hexaalkoxides and diaryl ketones proceed differently, yielding complex mixtures of products in which olefins are minor components.
ChemInform Abstract: Lipophilic Technetium Complexes. Part 9. The Reduction of (3‐Oxapentane‐1,5‐dithiolato)(p‐carbmethoxybenzenethiolato)oxotechnetium(V) by Tertiary Phosphines.
Authors: PIETZSCH H.‐J. , SPIES H. , HOFFMANN S. 
Published: May 2016

AbstractThe reduction of (I) is also possible with PMe2Ph, PBu3 and P(‐CH2‐CH2‐CN)3 as shown by electronic spectral data of the reaction products.
ChemInform Abstract: A New Mononuclear Thiolato Nickel(II) Square Planar Complex with an Uncommon (S2NO) Coordination.
Authors: KANATZIDIS M. G. 
Published: May 2016

AbstractTreatment of the dimeric bis(2‐(2‐mercaptophenyl)salicylaldiminato)dinickel(II) with K‐S‐Ph gives the title complex (I) in 89% yield, which crystallizes in P21/c with Z=4.
ChemInform Abstract: Chelating Properties of Copper(II) Aminoanthracyclines: An ESR Study.
Authors: COSTA L. , MORAZZONI F. , SCOTTI R. , ANGELUCCI F. , SUARATO A. , MALATESTA V. 
Published: May 2016

AbstractThe spectromagnetic characterization of the Cu(II) complexes of the anthracyclines (I) shows that the NH2 group of (Ia) coordinates Cu(II) yielding a mononuclear complex, while (Ib) forms a polymeric complex with both NH2‐ and OH‐group coordination.
ChemInform Abstract: Synthesis and Spectroscopic Characterization of Diruthenium σ,π‐Vinyl Complexes Ru2(μ‐O=C(NMe2),.mu±sigma.,π‐C(Ar)=C(Ar)H)(CO)5PPh3 (Ar: Phenyl or p‐Tolyl) and Ru2(μ‐O=C(NMe2),.mu±sigma.,π‐C(Ph)=CH2)(CO)5PPh3. Crystal and Molecular Structures of Ru2(μ‐O=C(NMe2),.mu±sigma.,π‐C(p‐tolyl)=C(p‐tolyl)H)(CO)5PPh3 and Ru2(μ‐O=C(NMe2),.mu±sigma.,π‐C(Ph)=CH2)(CO)5PPh3.
Authors: XUE Z. , SIEBER W. J. , KNOBLER C. B. , KAESZ H. D. 
Published: May 2016

AbstractIn the reaction of (I) (which are present in solution together with the gem‐isomers in unequal amounts) with PPh3 the vic‐isomers (III) are the only complexes isolated in the solid state while in solution the gem‐compounds predominate.
ChemInform Abstract: Thermal and Photochemical Reactions of (Ru3(CO)12) with Tetraethyldiphosphite. X‐Ray Structure of (Ru3(CO)10(μ‐(EtO)2POP(OEt)2)).
Authors: CABEZA J. A. , RIERA V. , JEANNIN Y. , MIGUEL D. 
Published: May 2016

AbstractThe thermal, 1:1 molar title reaction gives a mixture of at least five compounds which includes the trinuclear products (III), (IVa), and (IVb).
ChemInform Abstract: Rhodium‐Catalyzed Dimerization of Vinyl Ketones. NMR Study of the Dynamic Behavior of Intermediate η2‐ and η4‐Methyl Vinyl Ketone Complexes of Rhodium(I).
Authors: KOVALEV I. P. , KOLMOGOROV YU. N. , STRELENKO YU. A. , IGNATENKO A. V. , VINOGRADOV M. G. , NIKISHIN G. I. 
Published: May 2016

AbstractIn order to study the vinyl ketone catalytic dimerization mechanism the first stage of this reaction, i.e. the vinyl ketone coordination with RhCl(PMe3)3, is investigated.
ChemInform Abstract: Oxygen Atom Transfer from O2 to a Coordinated Olefin: A New Route to Oxametallacyclobutanes.
Authors: DAY V. W. , KLEMPERER W. G. , LOCKLEDGE S. P. , MAIN D. J. 
Published: May 2016

AbstractThe oxygen uptake by (I) to transform into (III) proceeds via several intermediates which can be detected by 31P NMR spectroscopy.
ChemInform Abstract: Synthesis and Characterization of New Platinum(II) Complexes Containing Thiazole and Imidazole Donors. Part 2. Tribromo(styrylheterazole)platinate(II) Anionic Complexes.
Authors: MUIR M. M. , GOMEZ G. M. , CADIZ M. E. , MUIR J. A. 
Published: May 2016

AbstractSeventeen complexes such as (III) are prepared containing a styrylbenzoheterazole, derived from imidazoles, thiazoles, oxazole or selenazole with yields that are in general higher than 80%.
ChemInform Abstract: Porphyrin Synthesis from a,c‐Biladienes. Evidence for a Common Mechanistic Pathway in the Electrochemical and Chemical Routes: Formation of Novel Macrocycles Possessing the Homoporphyrin Carbon Skeleton.
Authors: LIDDELL P. A. , OLMSTEAD M. M. , SMITH K. M. 
Published: May 2016

AbstractCopper(II)‐catalyzed cyclizations of a,c‐biladiene salts are used for the preparation of porphyrins.
ChemInform Abstract: Asymmetric Reactions. Part 65. Preparation of Three Diastereoisomers of 2‐(1‐Methyl‐1‐phenylethyl)‐5‐methylcyclohexan‐1‐ol from (R)‐(+)‐Pulegone.
Authors: CERVINKA O. , SVATOS A. , MASOJIDKOVA M. 
Published: May 2016

AbstractThe mixture of the alcohols (II), prepared from (R)‐pulegone (I) by a known procedure, is transformed to the carbamates (IV)‐(VI) which are separated by crystallization and column chromatography.
ChemInform Abstract: Bioconversion of (3RS,E)‐ and (3RS,Z)‐Nerolidol into Oxygenated Products by Streptomyces cinnamonensis. Possible Implications for the Biosynthesis of the Polyether Antibiotic Monensin A?
Authors: HOLMES D. S. , ASHWORTH D. M. , ROBINSON J. A. 
Published: May 2016

AbstractThe ability of the monensin‐producing organism Streptomyces cinnamonensis to bioconvert the E‐ (I) and Z‐ (IV) isomers of nerolidol into new oxygenated products (II), (III) or (V)‐(VIII) is investigated using 3H labeled samples.
ChemInform Abstract: Structure Determination of a New Spirobicyclic Triterpenoid from Iris foetidissima.
Authors: MARNER F.‐J. , KARIMI‐NEJAD Y. , JAENICKE L. , WRAY V. 
Published: May 2016

AbstractThe structure of the title compound (I) is elucidated spectroscopically and by oxidative degradation.
ChemInform Abstract: Synthesis of Fluorohydrins and of Bromofluoro Derivatives by Anti Addition on the 14,15 Double Bond of Tabersonine in Superacids.
Authors: BERRIER C. , JACQUESY J. C. , JOUANNETAUD M. P. , VIDAL Y. 
Published: May 2016

AbstractTabersonine (I) reacts with H2O2 in HF/SbF5 to yield the fluorohydrins (III), (IV) and (V).
ChemInform Abstract: Direct Bromination or Hydroxylation at C‐11 in Vincadifformine and Tabersonine Derivatives in Superacids.
Authors: BERRIER C. , JACQUESY J. C. , JOUANNETAUD M. P. , VIDAL Y. 
Published: May 2016

AbstractHydroxylation of the substrates (I) or (III) with H2O2 in HF/SbF5 medium gives the derivatives (II) or (IV), respectively.
ChemInform Abstract: Mammalian Alkaloids: O‐Methylation of (.+‐.)‐Norcoclaurine‐1‐carboxylic Acid and Related Isoquinolines Including (S)‐ and (R)‐Norcoclaurine with 14C‐Labeled S‐Adenosyl‐L‐methionine in Presence of Mammalian Catechol O‐Methyltransferase.
Authors: SEKINE Y. , CREVELING C. , BELL M. , BROSSI A. 
Published: May 2016

AbstractMethylation of the title acid (I) proceeds predominantly at the 7‐OH group.
ChemInform Abstract: Synthesis of 8‐Aza‐1,3‐dideaza‐2′‐deoxyadenosine and 5,6‐Disubstituted Benzotriazole 2′‐Deoxy‐β‐D‐ribofuranosides via Nucleobase‐Anion Glycosylation.
Authors: KAZIMIERCZUK Z. , SEELA F. 
Published: May 2016

AbstractThe glycosylation of the benzotriazoles (I), (V), or (IX) is stereoselective in all cases leading to exclusive β‐anomer formation; however, regioisomeric N1‐, N2‐, and N3‐deoxyribofuranosides are formed (→ (III) + (IV) or (VI) + (VII) + (VIII)) after deprotection.
ChemInform Abstract: 1,2,4‐Diazaphosphole Nucleosides. Synthesis, Structure, and Antitumor Activity of Nucleosides with a λ3 Phosphorus Atom.
Authors: RILEY T. A. , LARSON S. B. , AVERY T. L. , FINCH R. A. , ROBINS R. K. 
Published: May 2016

AbstractThe diazaphospholes (II), (VIII), and (XII) are coupled with the ribofuranose (I) in the presence of trimethylsilyl triflate and then deprotected to form the diazaphosphole nucleosides (III), (X), and (XIII).
ChemInform Abstract: Enantioselective Syntheses with Titanium‐Carbohydrate Complexes. Part 6. A Facile Synthesis of Optically Pure (‐)‐(S)‐Ipsenol (IV) Using a Chiral Titanium Complex.
Authors: OERTLE K. , BEYELER H. , DUTHALER R. O. , LOTTENBACH W. , RIEDIKER M. , STEINER E. 
Published: May 2016

AbstractA stereocontrolled synthetic route to optically pure (‐)‐(S)‐ipsenol (IV), the pheromone of Pityokteines curvidens and other bark‐beetle species is described.
ChemInform Abstract: The Michael Type Reaction of the B‐Iodo‐9‐BBN/Ethoxyethyne Adduct with α,β‐Unsaturated Ketones. A Selective Synthesis of δ‐Keto Esters.
Authors: KAWAMURA F. , TAYANO T. , SATOH Y. , HARA S. , SUZUKI A. 
Published: May 2016

AbstractThe adduct (III) of 1‐ethoxyacetylene (II) and 9‐iodo‐9‐borabicyclo‐(3.3.1)nonane (II) reacts with the vinylic ketones (IV) to give the enol boronates (V) which are hydrolyzed to produce the δ‐keto esters (VI).
ChemInform Abstract: Raman and 27Al NMR Investigations on the Existence of the Heptachlorodialuminate Ion (Al2Cl7)‐ in the Solid Reaction Products of the Composition MCl·2 AlCl3 (M: K, Rb, Cs).
Authors: REICH P. , MUELLER D. + , FEIST M. , BLUMENTHAL G. 
Published: May 2016

AbstractFrom the Raman and 27Al NMR results obtained for MCl·2 AlCl3 (M: K, Rb, Cs) it is concluded that the postulated (Al2Cl7)‐ ion containing an Al‐Cl‐Al bridge does not exist in these compounds.
ChemInform Abstract: The System Fluorosulfuric Acid (HSO3F) and Bis(fluorosulfuryl)peroxide (S2O6F2) ‐ a Solution Study.
Authors: CICHA W. V. , HERRING F. G. , AUBKE F. 
Published: May 2016

AbstractThe interactions between the HSO3F solvent and dissolved S2O6F2 (or its dissociation product SO3F·) are studied by Raman, ESR, 1H and 19F NMR spectroscopy.
ChemInform Abstract: A Voltammetric Study of Compound Formation in the Hg‐Cd‐Te System.
Authors: MORI E. , MISHRA K. K. , RAJESHWAR K. 
Published: May 2016

AbstractThe cathodic electrodeposition chemistry in the Hg‐Cd‐Te system is studied in an H2SO4 electrolyte by means of hydrodynamic voltammetry in conjunction with cyclic photovoltammetry, XRD, and optical measurements.
ChemInform Abstract: Surface Protonation and Electrochemical Activity of Oxides in Aqueous Solution
Authors: GOODENOUGH J. B. , MANOHARAN R. , PARANTHAMAN M. 
Published: May 2016

Abstractare studied as a function of pH for the pyrochlores Pb2M2‐xPbxO7‐y (M: Ru, Ir), the rutiles MO2 (M: Ru, Ir), and the perovskite Sr1‐xNbO3‐δ.
ChemInform Abstract: Electrochemical Investigation of Photocatalytic Oxidation of NO‐ 2 at TiO2 (Anatase) in the Presence of O2.
Authors: HORI Y. , BANDOH A. , NAKATSU A. 
Published: May 2016

AbstractThe oxidation of NO2‐ by O2 in illuminated aqueous anatase suspension is found to be zero order in (NO2‐).
ChemInform Abstract: Structural and Electrochromic Properties of Tungsten and Molybdenum Trioxide Electrodes in Acidic Media.
Authors: MACHIDA K. , ENYO M. 
Published: May 2016

AbstractThe unstable phases formed during electrocoloration in 0.5 M H2SO4 of sintered or anodically oxidized WO3 and MO3 film electrodes are studied by in situ XRD.
ChemInform Abstract: Stress Corrosion Cracking (SCC) of Electroless Nickel‐Plated Low‐Carbon Steel in Hot Concentrated NaOH Solutions
Authors: LO P.‐H. , TSAI W.‐T. , LEE J.‐T. 
Published: May 2016

Abstractis studied as a function of NaOH concentration and heat treatment of the Ni‐coating.
ChemInform Abstract: Platinum and Rhodium Substitution by Molybdenum and Tungsten Carbides for Catalysis. Synthesis, Activations and Uses.
Authors: LEDOUX M. J. , PHAM‐HUU CUONG PHAM‐HUU CUONG , MARIN S. , WEIBEL M. , GUILLE J. 
Published: May 2016

AbstractCarbides of Mo and W with high specific surface areas (100‐400 m2/g) are prepared by reaction of MoO3 and WO2 vapors on activated, high surface area carbon at relatively low temp. (∼1200 °C).
ChemInform Abstract: Photo‐Selective Electroless Metal Deposition Following Light Absorption by Titanate Ceramics.
Authors: BAUMGARTNER C. E. , LAMBY E. J. , KOLLMANSBERGER K. A. 
Published: May 2016

AbstractIt is demonstrated that illumination in an O2 containing atmosphere of titanate ceramics which are pretreated in Sn2+ solutions (e.g.
ChemInform Abstract: A Comparative Study of the Liquid‐Crystalline Behavior of Three Homologous Series of 1,2‐Propanediol Derivatives.
Authors: VAN DOREN H. A. , VAN DER GEEST R. , KELLOGG R. M. , WYNBERG H. 
Published: May 2016

AbstractThe propensity for mesophase formation is a function of the heteroatom and the alkyl‐chain length decreasing from S to O and being absent in homologues with more than 10 carbon atoms in the alkyl chain.
ChemInform Abstract: Reductive Cyclization of o‐(3‐Butenyl)fluorobenzene at Mercury and Lead Cathodes.
Authors: LOFFREDO D. M. , SWARTZ J. E. , KARIV‐MILLER E. 
Published: May 2016

AbstractElectrochemical reduction of the fluorobenzene (I) is performed at a mercury or a lead cathode.
ChemInform Abstract: Biocatalytic Preparation of Bicyclo(3.2.0)heptane Derivatives.
Authors: KLEMPIER N. , GEYMAYER P. , STADLER P. , FABER K. , GRIENGL H. 
Published: May 2016

AbstractOptically active bicyclo(3.2.0)heptenols such as (II) or (IV), which are central building blocks for the synthesis of chiral cyclobutane and ‐pentane systems, are prepared with up to >99% e.e.
ChemInform Abstract: Reactions of an o‐Quinone Monoimide with Anthracenes, Phencyclone, and 1,3‐Diphenylisobenzofuran.
Authors: HEINE H. W. , SURIANO J. A. , WINKEL C. , BURIK A. , TAYLOR C. M. , WILLIAMS E. A. 
Published: May 2016

AbstractThe o‐quinone monoimide (I) reacts with the anthracenes (II) in a (4 + 4)cycloaddition reaction to give the products (III) which isomerize in the presence of TFA, forming the 9,10‐disubstituted anthracenes (IV).
ChemInform Abstract: Stereoselective Methylation of α‐Sulfinyl Carbanions Generated from Three Isomeric Pyridylmethyl p‐Tolyl Sulfoxides and Benzyl 2‐Pyridyl Sulfoxide.
Authors: FURUKAWA N. , HOSONO E. , FUJIHARA H. , OGAWA S. 
Published: May 2016

AbstractA high stereoselectivity is observed in the methylation of the 2‐pyridylmethyl sulfoxide (Ia) at low temp. being in contrast to a similar methylation of the isomers (Ib), (Ic) or to that of the sulfoxide (V).