bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Salt and Cosolvent Effects on the Sulphite ‐ Hexacyanoferrate(III) Reaction.
Authors: RODRIGUEZ A. , LOPEZ S. , CARMONA‐GUZMAN M. C. , SANCHEZ F. , PIAZZA C. 
Published: May 2016

AbstractThe rate of the reaction between sulphite and hexacyanoferrate(III) ions has been measured in several concentrated salt solutions (NaClO4, NaCl, NaNO3) and in several isodielectric water‐ solvent mixtures (alcohols, DM F, CH3CN, dextrose, sucrose).
ChemInform Abstract: Coordination Chemistry of Higher Oxidation States. Part 19. Synthesis and Properties of Diphosphine and Diarsine Complexes of Iron(IV) and Iron K‐Edge EXAFS Data on [ Fe(o‐C6H4(PMe2)2)2Cl2]n +(BF4)n (n: 0,2)
Authors: HARBRON S. K. , HIGGINS S. J. , LEVASON W. , FEITERS M. C. , STEEL A. T. 
Published: May 2016

AbstractPure examples of the Fe(IV) complexes (Ia) and (Ib) (X: C1) are obtained by a) nitric acid oxidation or b) chlorine oxidation in TFA of the Fe(III) analogues, followed by precipitation with HBF4.
ChemInform Abstract: Influence of Closed‐Shell Cations on the LMCT Transition of Pentacyanoferrate(III) Complexes.
Authors: WARNER L. W. , HOQ M. F. , MYSER T. K. , HENDERSON W. W. , SHEPHERD R. E. 
Published: May 2016

AbstractThe bathochromic shifts produced on the LMCT spectra of the title complexes [Fe(CN)5L]2‐ (L: 4‐(dimethyamino)pyridine, benzimidazole) are investigated.
ChemInform Abstract: Systematic Design of Chemical Oscillators. Part 36. A New lodate Oscillator: The Landolt Reaction with Ferrocyanide in a CSTR.
Authors: EDBLOM E. C. , ORBAN M. , EPSTEIN I. R. 
Published: May 2016

AbstractAt a temp. of 30°C or higher, the reaction ofsul?te, iodate, and ferrocyanide exhibits sustained oscillation in a continuous flow stirred tank reactor (CSTR).
ChemInform Abstract: Reactions of Coordination Compounds in the Solid State. Part 1. Behavior of Cobalt(III) Bis(ethylenediamine) Diammine Salts.
Authors: FUJIWARA T. , BAILAR J. C. JUN. 
Published: May 2016

AbstractThe behavior of solid, crystalline salts cis‐[Co(Zn)2(NH3)2]X3 (X: Cl, PF6 ), on heating, is studied.
ChemInform Abstract: Synthesis, X‐Ray Structure, and Magnetic Properties of Di‐μ‐chloro‐bis[N‐(2‐hydroxy‐2‐phenylethyl)salicylideneaminatocopper(II)].
Authors: NEPVEU F. , BORMUTH F.‐J. , WALZ L. 
Published: May 2016

AbstractThe title complex (I) was prepared by addition of CuCl2 to a mixture of salicylaldehyde and 2‐amino‐1‐phenylethanol in MeOH and recrystallized from DMF.
ChemInform Abstract: Ruthenium(II)‐Catalyzed Thioether Oxidation. Part 1. Synthesis of Mixed Sulfide and Sulfoxide Complexes.
Authors: RILEY D. P. , OLIVER J. D. 
Published: May 2016

AbstractRuX2(Me2SO)4 complexes (X: Br, C1) are excellent catalysts for the selective oxygen oxidation of thioether.
ChemInform Abstract: Ruthenium(II)‐Catalyzed Thioether Oxidation. Part 3. Syntheses and Structure of Model Complexes with the New Linear Tridentate Ligand Bis(3‐(ethylsulfinyl)propyl) Sulfide.
Authors: RILEY D. P. , OLIVER J. D. 
Published: May 2016

AbstractThe title ligand (II) is obtained beside the bis(sulfoxide) (III), the tris(sulf0xide) (IV), and two monosulfoxide products by the reaction shown in the scheme.
ChemInform Abstract: Synthesis, Crystal Structure, and Spectroscopic Properties of [Mo2(O2CMe)2(MeCN)6][BF4]2, [Rh2(O2CMe)2(MeCN)6 ][ BF4]2, and [Rh2(O2CMe)2(MeCN)4(py)2][BF4]2.
Authors: PIMBLETT G. , GARNER C. D. , CLEGG W. 
Published: May 2016

AbstractTreatment of the dimeric acetato complexes of Mo and Rh with trimethyloxonium tetrafluoroborate in MeCN (20°C, 30 min or 8 h, mol ratio 1:4) produced the title complexes (I) or (IIa), dissolution of the Rh derivative in Py gave (IIb).
ChemInform Abstract: The Reactions of the Tri‐μ‐hydroxo‐bis[η6‐p‐cymeneosmium(II)] Cation with Aldehydes and Acids and the Homogeneously Catalysed Oxidation of Acetaldehyde and Propionaldehyde with Water.
Authors: CABEZA J. A. , SMITH A. J. , ADAMS H. , MAITLIS P. M. 
Published: May 2016

AbstractThe tri‐μ‐hydroxo complex cation (II) reacts with the aldehydes R1‐CHO to give the complexes (III) and with the water‐insoluble aldehydes R2‐CHO to yield the complexes (IVa) and (IVb).
ChemInform Abstract: Arene(phosphane)metal Complexes. Part 12. Unexpected Formation of Monohydrido(phosphane)osmium(II) Complexes C6H6OsH(PMe2(OR))I from C6H6Os(PMe2H)I2. A Compound Containing an Os = PMe2 Bond as Intermediate?
Authors: WEINAND R. , WERNER H. 
Published: May 2016

AbstractThe reaction of the dimeric Compound (I) with the phosphine (II) produces the complex (III) which on addition of KOtBu in MeOH or NHEt2 yields unexpectedly the mononuclear Complexes (IVa) or (IVb).
ChemInform Abstract: Extremely Stereoselective and Stereospecific Reductive Cleavage of β‐Lactams: A Highly Efficient Route to Labelled Homochiral Peptides.
Authors: OJIMA I. , SHIMIZU N. 
Published: May 2016

AbstractCleavage of β‐lactams of type (I) with D2 leads stereospecifically to dipeptide derivatives (II) in quantitative yields.
ChemInform Abstract: Synthesis of 3‐Deoxy‐ and 3‐Deoxy‐3‐fluorosucrose, and α‐D‐Allopyranosyl β‐D‐ Fructofuranoside.
Authors: BINDER T. P. , ROBYT J. F. 
Published: May 2016

AbstractAusgehend von Sucrose (Ia) wird über die Derivate (Ib) und (Ic) zunächst die partiell geschützte Verbindung (Id) dargestellt.
ChemInform Abstract: Corrosion Study and Minority Carrier Diffusion Length Determination of n‐Type SnS2 and SnSSe.
Authors: FOTOUHI B. , KATTY A. 
Published: May 2016

AbstractSnS2 and SnSSe are unstable in the dark in electrolytes containing oxidizing agent such as Fe(CN)63‐ (KOH) and Ce4+ (H2SO4).
ChemInform Abstract: Thermal Decomposition and Dehydration of Magnesium Perchlorate Hexahydrate.
Authors: DEVLIN D. J. , HERLEY P. J. 
Published: May 2016

AbstractDehydration of Mg(C1O4)2‐6 H2O occurs in three distinct steps in the temp. ranges 148‐197, 248‐278, and 344‐395°C, each of them associated with the removal of 2 H2O. The thermal decomposition of Mg(C1O4)2 proceeds via the formation of an intermediate, (MgO‐MgC1O4), which dissociates at low temp. and decomposes rapidly at 417°C to give MgO.
ChemInform Abstract: Catalysis by Amorphous Metal Alloys. Part 4. Structural Modification Towards Metastable States and Catalytic Activity of Amorphous Ni62B38 Ribbon Alloy.
Authors: YAMASHITA H. , YOSHIKAWA M. , FUNABIKI T. , YOSHIDA S. 
Published: May 2016

AbstractStructural modification of amorphous Ni62B38 ribbon alloy by thermal treatment yields alloys in precrystallization, metastable and stable crystallized states the catalytic activities of which (hydrogenolysis of ethane and cyclopropane) are correlated to the surface states (XRD, DTA, ‐SEM, ESCA, electrical resistivity and hydrogen chemisorption measurements).
ChemInform Abstract: Demonstration of Alternative Spin States in Clusters Containing the Biologically Relevant (Fe4S4)+ Core.
Authors: CARNEY M. J. , HOLM R. H. , PAPAEFTHYMIOU G. C. , FRANKEL R. B. 
Published: May 2016

AbstractMagnetic properties and Mößbauer and EPR spectroscopic investigations of the Clusters (I), containing the cubane type odd‐electron [Fe4S4]+ core, demonstrate that different spin ground states of this core can be realized, here S = 1/2 (Ia) and S = 2/3 (Ib), and that a quartet Cluster in the solid state can be transformed to a mixture of quartet and doublet Clusters in solution.
ChemInform Abstract: Electrochemical Oxidation of [Dibenzo‐18‐crown‐6‐K][Cr(CO)5F] and Cr(CO)6 : Characterization of [Cr(CO)6]+ and Its Substitution Reactions with Fluoride and Trifluoroacetate.
Authors: BAGCHI R. N. , BOND A. M. , COLTON R. , LUSCOMBE D. L. , MOIR J. E. 
Published: May 2016

AbstractElectrochemical oxidation of the title carbonyl fluoride complex has been studied in CH2Cl2, CH3CN, and acetone to establish whether electrochemical synthesis of relatively rare higher oxidation state carbonyl fluoride complexes may be achieved.
ChemInform Abstract: The Conductive Sulfur/Carbon Mixture Cathode. An Efficient Synthesis of Thiophenes and Related Compounds from Acetylenes.
Authors: LE GUILLANTON G. , DO QUANG THO DO QUANG THO , SIMONET J. 
Published: May 2016

AbstractDie Elektroreduktion der Acetylene (I) an einer Schwefel‐Kohlenstoff‐ Elektrode liefert aus (Ib)‐(If) die Thiophene (II).
ChemInform Abstract: Metal Ion Catalysis by Blocking Inhibitory Reverse Paths in the Hydrolysis of 3‐Carboxyaspirin.
Authors: SUH J. , CHUN K. H. 
Published: May 2016

AbstractThe hydrolysis of the title compound (I) is kinetically investigated in the presence or absence of tri‐ or divalent metal ions and the mechanism is discussed in detail.
ChemInform Abstract: Doubly Destabilized Carbocations. Strong Aryl Delocalization and the Attenuation of Rate Decelerating Effects of CF3 and CN Groups.
Authors: ALLEN A. D. , KANAGASABAPATHY V. M. , TIDWELL T. T. 
Published: May 2016

AbstractKinetic results of solvolysis in (II) and different other solvents are interpreted in terms of carbocationic transition states and intermediates in which the Charge is largely delocalized onto the aryl group.
ChemInform Abstract: Asymmetrie Michael Additions of Ester Enolates to Enantiomerically Pure Vinylic Sulfoxides.
Authors: POSNER G. H. , WEITZBERG M. , HAMILL T. G. , ASIRVATHAM E. , HE C. , CLARDY J. 
Published: May 2016

AbstractAsymmetrie Michael Additions of Ester Enolates to Enantiomerically Pure Vinylic Sulfoxides.
ChemInform Abstract: Aqueous Intermolecular Diels‐Alder Chemistry. Reaction of (E)‐2,4‐Pentadienyl Ammonium Chloride and Related Ammonium Salts with Dienophiles in Water.
Authors: GRIECO P. A. , GALATSIS P. , SPOHN R. F. 
Published: May 2016

AbstractThe Diels‐Alder reactions of the hydrochlorides of (E)‐2,4‐pentadienyl amine (II), (E)‐3,5‐hexadienyl amine (VI) and of (E)‐4,6‐heptadienyl amine (VIII) in an acidic aqueous medium with a variety of dienophiles ‐ (Ia) to (Ic), (IV) ‐ afford the corresponding adducts (III), (V), (VII) and (IX) in high yields.
ChemInform Abstract: Synthesis of Heterocycles Using Trifluoropyruvic Acid Hydrate.
Authors: MUSTAFA M. E. , TAKAOKA A. , ISHIKAWA N. 
Published: May 2016

AbstractDie im Titel genannte Verbindung (III) kondensiert mit Harnstoffen (II), o‐Phenylendiaminen (IV), o‐Aminophenolen bzw. ‐thiophenolen (VI) zu den fünf‐ (I) bzw. sechsgliedri‐ gen Heterocyclen (V) und (VII).
ChemInform Abstract: New Sigmatropic Sequences Based on the I2,3l‐Wittig Rearrangement of the Bis‐Allylic Ether System: A General Approach to Regiocontrolled C ‐ C Bond Formation of Allylic Moieties Leading to Unsaturated Carbonyl Compounds.
Authors: MIKAMI K. , KISHI N. , NAKAI T. , FUJITA Y. 
Published: May 2016

AbstractFour sigmatropic Sequences triggered by the regiocontrolled [2,3]‐Wittig rearrangement of bis‐allylic ether systems are investigated giving the unsaturated aldehydes shown in the scheme.
ChemInform Abstract: Regiochemical Control in Intramolecular Photochemical Reactions of 1,6‐Heptadienes: Carbony1‐Substituted 1‐(4‐Alkenyl)‐1‐cyclopentenes.
Authors: MATLIN A. R. , GEORGE C. F. , WOLFF S. , AGOSTA W. C. 
Published: May 2016

AbstractThe regiochemistry of intramolecular photochemical reaction is studied in three series of ketones of types (III), (VIII) and (XI).
ChemInform Abstract: Oxygenase Model Reactions. Part 1. Intra‐ and Extradiol Oxygenations of 3,5‐Ditert‐butylcatechol Catalyzed by (Bipyridine)(pyridine)iron(III) Complex.
Authors: FUNABIKI T. , MIZOGUCHI A. , SUGIMOTO T. , TADA S. , TSUJI M. , SAKAMOTO H. , YOSHIDA S. 
Published: May 2016

AbstractThe title compound (I) is oxygenated by (bipyridine)(pyridine)iron(III) complex with insertion of molecular oxygen to give intra‐ and extradiol oxygenation products.
ChemInform Abstract: l,1,3,3‐Tetramethylguanidinium Dichromate. A New Mild Reagent for the Oxidation of Alcohols.
Authors: KIM S. , LHIM D. C. , LEE P. H. 
Published: May 2016

AbstractThe title reagent (II) oxidizes in the presence of pyridinium tosylate (PPTS, equimolar amounts of the reactants) the benzylic alcohols (IIIa) within 4h cleanly to the aldehydes (IVa), the secondary alcohols (IIIb) to the ketones (IVb) (8‐ 12h), and the cycloalkanols (IIIc) to the cycloalkanones (IVc) (16h).
ChemInform Abstract: Catalytic Oxidation of Dithiols by a Semisynthetic Enzyme.
Authors: STEWART K. D. , RADZIEJEWSKI C. , KAISER E. T. 
Published: May 2016

AbstractThe flavopapains (III) are semisynthetic enzymes obtained from the alkylation of Cys‐25 of papain (II) with the isomeric isoalloxazines (I).
ChemInform Abstract: A Novel Method for the Geminal Dialkylation of the Carbonyl Group of Aromatic Aldehydes and Ketones.
Authors: CLAREMBEAU M. , KRIEF A. 
Published: May 2016

AbstractIn den beiden Arbeiten wird die Mono‐ und Dialkylierung von Aryloxyverbindungen wie (I) bzw. entsprechenden Seleniden und Selenoa‐cetalen untersucht und beschrieben.
ChemInform Abstract: Reductive Metallation. A General Preparative Method for Hydrocarbon Allylmetallic Compounds.
Authors: COHEN T. , GUO B.‐S. 
Published: May 2016

AbstractThe reductive lithiation of allyl phenyl sulfides (III), (IX) and (XIV) [prepared from (I), (VI) and (XII), resp.] using radical anions (LN or, preferably, LDMAN) generates the corresponding allylic anions, whose reaction with ke‐ 75 tone (IV) and aldehyde (X) is studied.
ChemInform Abstract: The Stereochemically Controlled Horner‐Wittig Route to Unsaturated Acids: The Baeyer‐Villiger Rearrangement of α‐(1‐Ph2PO‐alkyl)‐cyclohexanones.
Authors: LEVIN D. , WARREN S. 
Published: May 2016

AbstractDiphenylethyl‐phosphinoxid (I) reagiert nach Metallierung in α‐Stellung mit Cyclopenten‐ (IIa) bzw. Cyclohexenoxid (IIb) zu den Addukten (III) und (IV) unter Bevorzugung von (III).
ChemInform Abstract: New Routes to cis‐1,2‐Hydroxyamines and Related Systems.
Authors: SAMMES P. G. , THETFORD D. 
Published: May 2016

Abstract3‐Cyclohexenol (I) wird in das Benzoylamino‐brom‐cyclohexylbenzoat (III) übergeführt, aus dem das Aminocyclohexanol (IV) oder das Aminocyclohexandiolacetat (VII) erhalten werden können.
ChemInform Abstract: Stereospecific Triple Michael Addition.
Authors: THANUPRAN C. , THEBTARANONTH C. , THEBTARANONTH Y. 
Published: May 2016

AbstractDer Acrylester (I) und das Methylencyclopentenon (II) reagieren mit den Nucleophilen (III) zu den Norbornanon‐Derivaten (IV).
ChemInform Abstract: An Efficient Synthesis of Chiral 2‐(p‐Tolylsulfinyl)‐2‐butenolides.
Authors: HOLTON R. A. , KIM H.‐B. 
Published: May 2016

AbstractAus dem Sulfinyl‐phosphonsäureester (I) erhält man nach Metallierung mit den Carbonylverbindungen (II) die Olefine (III), die mit LDA über die Lithium‐Salze (IV) zu den Lactonen (V) carboxyliert und cyclisiert werden.
ChemInform Abstract: An Enantioselective Synthesis of (‐)‐6‐Aza‐6‐carbethoxy‐2‐oxabicyclo‐[3.3.0]octan‐3‐one from S‐(‐)‐Malic Acid.
Authors: SHISHIDO K. , SUKEGAWA Y. , FUKUMOTO K. , KAMETANI T. 
Published: May 2016

AbstractAusgehend von S‐Äpfelsäure (I) läßt sich in einer vielstufigen Synthese der Carbamatester (II) herstellen, dessen intramolekulare Michael‐Addition zum Pyrrolidindiester (III) führt.
ChemInform Abstract: Synthesis of Optically Active 3‐Mercaptopyrrolidine Derivatives.
Authors: SHIBATA T. , IINO K. , SUGIMURA Y. 
Published: May 2016

AbstractDie N‐geschützten chiralen 3‐Mercaptopyrrolidin‐Derivate (V) und (XIII) werden gemäß Schema auf verschiedenen Wegen ausgehend von L‐Hydroxyprolin (I), L‐Äpfelsäure (VI), L‐Asparagin (X) sowie L‐Asparaginsäure (XIV) synthetisiert.
ChemInform Abstract: Synthesis of Novel Hexahydroquinolines and Decahydroacridines.
Authors: ABOU‐GHARBIA M. 
Published: May 2016

AbstractAls potentielle Calcium‐Antagonisten werden die Hexahydrochinoline (IV), (VII) und (IX) sowie die Hexahydroacridine (XI) aus den Aldehyden (I), Cyclohexandion (II) und den β‐Ketosäure‐Derivaten (III), (V), (VI) und (VIII) über eine Hantzsch‐Synthese hergestellt.
ChemInform Abstract: Formation of an Unexpected Product, a Functionalized Dioxane, under Aprotic Acetalization Conditions.
Authors: CHIARELLO J. , CHEN S.‐Y. , JOULLIE M. M. 
Published: May 2016

AbstractDas aus D‐Galactose zugängliche γ‐Lacton (I) liefert nach Debromierung den Methoxymethylether (II), der zu dem γ‐Ketoester (III) oxidiert wird.
ChemInform Abstract: A Selective Synthesis of 5‐(p‐Aminophenyl)barbituric Acid.
Authors: BRIGHT F. V. , BUNCE R. A. , MCGOWN L. B. 
Published: May 2016

AbstractPhenylethylbarbitursäure (I) reagiert mit Nitroniumtetrafluoroborat (II) zu p‐Nitrophenyl‐ethyl‐barbitursäure (III), die zur Aminoverbindung (IV) hydriert werden kann.
ChemInform Abstract: Interlocked Macrocyclic Ligands: A Catenand Whose Rotation of One Ring into the Other is Precluded by Bulky Substituents.
Authors: DIETRICH‐BUCHECKER C. O. , SAUVAGE J. P. , WEISS J. 
Published: May 2016

AbstractDas aus 4,7‐Diphenyl‐l,10‐phenanthrolin (I) und überschüssigem Lithioanisol (II) erhaltene Kondensationsprodukt (IIIa) wird zum freien Bis‐ phenol (IIIb) gespalten, das mit den Diiodid (IV) zum Makrocyclus (V) kondensiert wird.
ChemInform Abstract: On the Origin of the Configurational Instability of (l‐Silyl‐1‐alkenyl)lithiums and Related Alkenylmetals.
Authors: NEGISHI E. , TAKAHASHI T. 
Published: May 2016

AbstractThe origin of the remarkably facile configurational isomerization of 1‐silyl‐1‐metalloalkenes is investigated by using (III) as a representative example.
ChemInform Abstract: Carbonylation of Titanocene Cyclobutenes. Synthesis and Characterization of a Titanocene ‐ Vinylketene Complex.
Authors: MEINHART J. D. , SANTARSIERO B. D. , GRUBBS R. H. 
Published: May 2016

AbstractCarbonylation of the titanocene cyclobutene complexes (I) in the presence of PMe3 yields the corresponding titanocene ‐vinylketene complexes (II) as trimethylphosphine adducts.
ChemInform Abstract: Reactions of Phosphine‐Nitrile Ligands: the Formation of Phosphine‐Amine and Phosphine‐Imidate Complexes of Tungsten Carbonyl from 3‐(Diphenylphosphino)propionitrile and 3‐(Diphenylphosphino)2‐methylpropionitrile.
Authors: AKHAVAN S. , KIM C.‐S. , STORHOFF B. N. 
Published: May 2016

AbstractReactions of W(CO)6 (I) and the phosphine‐nitrile ligands (II) (1 :l molar ratio) with an excess of NaBH4 in refluxing ethanol or propanol in limited reaction times provide mixtures of the phosphine‐imidate (III) and phosphine‐amine Complexes (IV).
ChemInform Abstract: Structure and Properties of HFe3(CO)9BH3R and the Conjugate Bases [HFe3(CO)9BH2R]‐ (R: H and CH3).
Authors: VITES J. , HOUSECROFT C. E. , EIGENBROT C. , BUHL M. L. , LONG G. J. , FEHLNER T. P. 
Published: May 2016

AbstractThe ferraboranes (III), prepared as shown, and their anionic conjugate Brønsted bases (IV), prepared by deprotonation of (III) in methanol, are fully characterized and compared with the hydrocarbyls (V).
ChemInform Abstract: Photochemical Reactions of (n5‐Pentamethylcyclopentadienyl)dicarbonyliron‐Alkyl and ‐Silyl Complexes: Reversible Ethylene Insertion into an Iron‐Silicon Bond and Implications for the Mechanism of Transition‐Metal‐Catalyzed Hydrosilation of Alkenes.
Authors: RANDOLPH C. L. , WRIGHTON M. S. 
Published: May 2016

AbstractThe photochemistry of the complexes (I) is studied.
ChemInform Abstract: Alkylcobalt Carbonyls. Part 7. (η1‐Benzyl)‐, (η3‐Benzyl)‐, and (η1‐Phenylacetyl)cobalt Carbonyls.
Authors: GALAMB V. , PALYI G. , UNGVARY F. , MARKO L. , BOESE R. , SCHMID G. 
Published: May 2016

AbstractBenzyl halides (I) or phenylacetyl halides (VI) react with Na[Co(CO)4] (II) to yield an equilibrium mixture of (η3‐benzyl)‐ (III), (η1‐benzyl)‐ (IV), and (η1‐phenylacetyl)‐Co carbonyls (V).
ChemInform Abstract: Activation of the M‐CO Bond in Transition Metal Complexes. CO Substitution Reactions in Di‐, Tri‐ and Tetra‐nuclear Metal Carbonyl Compounds Catalyzed by [Fe(CO)2(η5‐C5H5]2.
Authors: AIME S. , BOTTA M. , GOBETTO R. , OSELLA D. 
Published: May 2016

AbstractThe catalytic activity of the title complex in the CO substitution reactions has been explored in various systems involving bi‐, tri, and tetranuclear Compounds.
ChemInform Abstract: Synthesis of a Taxane Triene.
Authors: KENDE A. S. , JOHNSON S. , SANFILIPPO P. , HODGES J. C. , JUNGHEIM L. N. 
Published: May 2016

AbstractStarting from the reaction between the acetal (I) and the enolsilane (II), the two separable Z‐esters (III) and (IV) are obtained together with an inseparable mixture of the E‐esters (total yield 261%).
ChemInform Abstract: New Approaches to Enzyme Regulators. Synthesis and Enzymological Activity of Carbocyclic Analogues of D‐Fructofuranose and D‐Fructofuranose 6‐Phosphate.
Authors: WILCOX C. S. , GAUDINO J. J. 
Published: May 2016

AbstractThe analogue (IXc) of D‐fructofuranose 6‐phosphate (X) is an excellent Substrate for phosphofructokinase and 6‐phosphofructo‐2‐kinase.(IXc) inhibits fructose‐2,6‐bisphosphatase with Ki about 500 times higher than that of (X).
ChemInform Abstract: Applications of the Intramolecular Diels‐AldEr Reactions of Heterodienes to the Syntheses of Indole Alkaloids.
Authors: MARTIN S. F. , BENAGE B. , WILLIAMSON S. A. , BROWN S. P. 
Published: May 2016

AbstractThe aldehyde (VII) is synthesized Starting from propargyl alcohol (I) and cyclized to give the lactam (VIII) which in turn serves as key compound for the synthesis of the ester (XI) and the piperidones (XIII) or (XIV).
ChemInform Abstract: A Convergent Approach to Heterocycle Synthesis via Silver Ion Mediated α‐Keto Imidoyl Halide‐Arene Cyclizations.
Authors: WESTLING M. , SMITH R. , LIVINGHOUSE T. 
Published: May 2016

AbstractDie aus den Isonitrilen (I), (VI), (VII) und (IX) und den Acylhalogeniden (II) zugänglichen Ketoimidoylhalogenide, z.B. (III), cyclisieren in Gegenwart von Silberionen zu den Heterocyclen (IV), (VI), (VIII) bzw. (X).
ChemInform Abstract: One‐Proton Catalysis in the Deacetylation of Acetylcholinesterase.
Authors: KOVACH I. M. , LARSON M. , SCHOWEN R. L. 
Published: May 2016

AbstractProton inventories (determination of kinetic parameters in binary mixtures of protium and deuterium oxides) for the action of acetylcholinesterases on phenyl acetate indicate that the overall solvent isotope effects measured for two enzymes (electric‐eel enzyme and erythrocyte enzyme) on k", arises from a single site in the transition state.
ChemInform Abstract: Surface Diffusion of Hydrogen on Ru(00l) Studied Using Laser‐Induced Thermal Desorption.
Authors: MAK C. H. , BRAND J. L. , DECKERT A. A. , GEORGE S. M. 
Published: May 2016

AbstractThe surface diffusion coefficients for hydrogen on Ru(00l) at low coverage display Arrhenius behaviour in the temp. range 260‐330 K. The activation energy of diffusion is found to be 4 kcal mol‐1 and the preexponential factor is 6.3·10‐4 cm2s‐1.
ChemInform Abstract: Reticulated Single‐Crystal Luminescent Screen.
Authors: HUO D. T. C. , HOU T. W. 
Published: May 2016

AbstractAsimpli?ed wet chgmical etching process for the fabrication of YAG (yttrium aluminum garnet) luminescent screens with truncated square mesas has been developed in which a single layer of plasma‐deposited SiO2 is used as the masking material.
ChemInform Abstract: Surface Treatments of n‐CuInSe2 Polycrystalline Electrodes for Photoelectrochemical Applications.
Authors: RAZZINI G. , BICELLI L. P. , ARFELLI M. , SCROSATI B. 
Published: May 2016

AbstractThe effect of surface treatments and electrolyte composition on the efficiency and the stability of polycrystalline n‐CuInSe2 electrodes has been studied.
ChemInform Abstract: SOx (x = 2, 3) Sensor Using Ag+‐β‐Alumina Solid Electrolyte.
Authors: ITOH M. , KOZUKA Z. 
Published: May 2016

AbstractAg+‐β‐alumina prepared by ion‐exchange of Na+‐β‐alumina has been applied as solid electrolyte in the cells I and II .The measured EMF of cell I was in good agreement to the calculated value, while that of cell II differs from the calculated EMF due to the formation of a reaction layer on the Ag+‐β‐alumina surface.
ChemInform Abstract: Electrochemical Oxidation of Pyrite Slurries.
Authors: LALVANI S. B. , SHAMI M. 
Published: May 2016

AbstractThe electro‐oxidation of FeSZ slurries at 0.8 V vs. SCE on Pt electrodes results in dissolution of pyrite in the electrolyte, while H2 gas is generated at the cathode.