bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Total Syntheses of (.+‐.)‐Physovenine and (.+‐.)‐Physostigmine. An Application of Tandem Electrocyclic‐(3,3)Sigmatropic Reaction of Benzocyclobutenes.
Authors: SHISHIDO K. , SHITARA E. , KOMATSU H. , HIROYA K. , FUKUMOTO K. , KAMETANI T. 
Published: May 2016

AbstractThe alkaloids (IV) are synthesized from the benzocyclobutene (I) via (II) and (III).
ChemInform Abstract: Bicyclo(4.1.1)octa‐2,4‐diene, ‐oct‐2‐ene, ‐oct‐3‐ene, and ‐octane from Norpinene.
Authors: CHRISTL M. , HERZOG C. , NUSSER R. 
Published: May 2016

AbstractThe title compounds (V), (VIII), (VI) and (IX) are prepared ((VIII) for the first time) via a new route with the dibromide (III) as common precursor.
ChemInform Abstract: Oxiranylidene Intermediate in the reaction of trans‐2‐Chloro‐3‐tert‐butyloxirane with Sodium Phenoxide.
Authors: GOERING H. L. , PAISLEY S. D. 
Published: May 2016

AbstractThe substitution reaction of the chloro epoxide (I) with phenoxide is supposed to proceed via the carbene (III).
ChemInform Abstract: Synthesis of Benzo(1,2‐b:4,5‐b′)dithiophene and Its 4,8‐Dimethoxy and 4,8‐Dimethyl Derivatives.
Authors: BEIMLING P. , KOSSMEHL G. 
Published: May 2016

AbstractThe synthesis of the dithiophene (V) starts from the reaction of the thiophenes (I) and (II) via (IIIa), LiAlH4 reduction (→ (IIIb)) and (IV).
ChemInform Abstract: Synthesis and Crystal Structure of a Macrocycle from 4‐Cyano‐4′‐ (N‐benzoylamino)diphenylether.
Authors: LINDEMAN S. V. , SHKLOVER V. E. , STRUCHKOV YU. T. , PONOMAREV I. I. , SILING S. A. 
Published: May 2016

AbstractThe title compound (I) is heated with aluminum chloride/sulfuryl chloride in nitrobenzene to produce the 18‐membered heterocycle (II).
ChemInform Abstract: Preparation and Catalytic Performance of Novel Vanadosilicates Having the Pentasil Pore‐Opening Structure.
Authors: MIYAMOTO A. , MEDHANAVYN D. , INUI T. 
Published: May 2016

AbstractVanadosilicates are synthesized by the rapid crystallization method by replacing the Al ingredient in H‐ZSM‐5 with different starting vanadium salts.
ChemInform Abstract: Fluorocarbon Derivatives of Nitrogen. Part 13. Reaction of Perfluoroalkanenitriles with Pyridinium Alkoxycarbonylmethylides: Synthesis of Perfluoroalkylated Imidazo(1,2‐a)pyridines (1‐Azaindolizines). X‐Ray Molecular Structure of Pyridinium 4,5‐Dihydro‐4‐oxo‐2,6‐bis(trifluoromethyl)pyrimidin‐5‐ylide.
Authors: BANKS R. E. , PRITCHARD R. G. , THOMSON J. 
Published: May 2016

AbstractPyridinium t‐butoxycarbonylmethylide ‐ generated in situ by treatment of the pyridinium perchlorate (I) with NaH or NEt3 ‐ reacts with the cyanides (II) to give the imidazopyridines (III), the propenylpyridinium perchlorates (IV) and the ylides (V); the product ratios are varied by changing the reactant ratios.
ChemInform Abstract: Reactions of N‐Silylated Enediamines. Part 1. Transition Metal Complexes of 1,3‐Diaza‐2‐sila‐4‐cyclopentenes.
Authors: ZETTLITZER M. , TOM DIECK H. , STAMP L. 
Published: May 2016

AbstractTreatment of the title compounds (I) with (II) gives the rather unstable complexes (III) in only moderate yields (not quantified).
ChemInform Abstract: Annulations Leading to Diene Systems. Total Synthesis of the Diterpenoid Synthesis of the Diterpenoid (.+‐.)‐(14S)‐Dolasta‐1(15),7,9‐trien‐14‐ ol.
Authors: PIERS E. , FRIESEN R. W. 
Published: May 2016

AbstractThe cyclic ketones (I) are alkylated with the allylic bromide (II) and then converted to the corresponding enol triflates (IV), which are cyclized to give the bicyclic dienes (VI) in the presence of the palladium complex (V).
ChemInform Abstract: Resonance Raman Frequencies and Core Size for Low‐ and High‐Spin Nickel Porphyrins.
Authors: KIM D. , SU Y. O. , SPIRO T. G. 
Published: May 2016

AbstractResonance Raman spectra are reported with B‐ and Q‐band excitation for the nickel(II) complexes of octaethylporphyrin, protoporphyrin IX dimethyl ester and meso‐tetraphenylporphine in CH2Cl2 (4‐coordinate, low spin) and piperidine (6‐coordinate dipiperidine adducts, high spin).
ChemInform Abstract: Synthesis, Crystal Structure, and Absorption Spectroscopy of a Carbazole‐Dinitrofluorene Bichromophore. Identity of Ground‐State Molecular Interactions in the Single Crystal and Aggregates in Solution.
Authors: BRISSE F. , DUROCHER G. , GAUTHIER S. , GRAVEL D. , MARQUES R. , VERGELATI C. , ZELENT B. 
Published: May 2016

AbstractThe bichromophore (V) ( P21/n, Z=4) which is prepared in accordance with the scheme shows no ground‐state intramolecular interaction but solute‐solute or solute‐solvent interactions.
ChemInform Abstract: Redox Properties of Polypyridyl‐Aqua Complexes of Osmium.
Authors: PIPES D. W. , MEYER T. J. 
Published: May 2016

AbstractThe electrochemical properties of the complexes (I) and (II) are studied in aqueous solutions over the pH range 0‐14. Multiple electron, proton coupled redox steps are observed with the formation of lower oxidation state Os(III) and Os(II) hydroxo or aquo complexes upon reduction.
ChemInform Abstract: Synthesis and Characterization of a Lacunar Bis(isothiocyanato)cobalt(III) Cyclidene Complex: A Structural Model for Distal Steric Effects in Hemoproteins.
Authors: JACKSON P. J. , CAIRNS C. , LIN W. , ALCOCK N. W. , BUSCH D. H. 
Published: May 2016

AbstractThe title complexes (I) and (II) (for comparison) are prepared starting with the corresponding Co(II) compounds without axial ligands in MeCN by reaction with NaSCN and oxidation by Ce(IV) ions.
ChemInform Abstract: Meta Photocycloaddition of trans‐1,2‐Dichloroethylene to Benzenoid Compounds: Mechanistic Considerations and Photo and Thermal Labilities of the Adducts.
Authors: CORNELISSE J. , GILBERT A. , RODWELL P. W. 
Published: May 2016

AbstractTrans‐1,2‐dichloroethene (II) and benzene (Ia) or its derivatives (Ib) and (Ic) are irradiated, yielding the adducts (III).
ChemInform Abstract: (S)‐(‐)‐ and (R)‐(+)‐1‐(Pentafluorophenyl)ethanol.
Authors: MEESE C. O. 
Published: May 2016

AbstractThe title compound (S)‐(‐)‐(II) is prepared by enantioselective reduction of the ketone (I) with the chiral Noyori reagent (NRG) or by optical resolution of rac‐(II) using the isocyanate (S)‐(III), and trichlorosilane scission of the (‐)‐form of the diastereomeric urethanes (IV) obtained.
ChemInform Abstract: Degradation of Trialkylamines in the Reaction of 1,1,3‐Trichloro‐1‐Hisoindole with Primary and Secondary Amines.
Authors: BALITSKAYA O. V. 
Published: May 2016

AbstractTrialkylamines such as trimethylamine (IIIa), dimethylbenzylamine (IIIb) or triethylamine (VI) participate in the reaction of the trichloroisoindole (I) with the nitroaniline (II) or the N‐benzylaniline (V) to give the dialkylaminoiminoisoindole (IV) or the salt (VII).
ChemInform Abstract: Structural and Biological Studies on Benzimidazolyl Amino Acid Complexes of Dimethyldichlorosilane.
Authors: AMINABHAVI T. M. , BIRADAR N. S. , PATIL S. B. , HOFFMAN D. E. 
Published: May 2016

AbstractRefluxing a mixture of o‐phenylenediamine, the appropriate amino acid and 6 N HCl for about 70 h leads to the free bases (I) which react with equimolar quantities of Me2SiCl2 to yield the complexes (II) (no yield given).
ChemInform Abstract: UCr4C4 with Filled MoNi4 Type Structure.
Authors: BEHRENS R. K. , JEITSCHKO W. 
Published: May 2016

AbstractThe title compound has been prepared by arc melting of coldpressed pellets of the elements and subsequent annealing at 800 or 1100 °C. UCr4C4 crystallizes in the tetragonal system, space group I4/m, Z=2.
ChemInform Abstract: Diastereoselective Addition of the 2‐Phenylsulfonyl‐Substituted Allylic Bromides to Aldehydes in the Presence of Zinc or Chromium(II) Chloride.
Authors: AUVRAY P. , KNOCHEL P. , NORMANT J. F. 
Published: May 2016

AbstractThe phenylsulfonylallylbromides (I) react with the aldehydes (II) in the presence of zinc or Cr(II) salts, prepared in situ, to give the adducts (III) ‐ (V), depending on the reaction conditions.
ChemInform Abstract: Cobalt Carbonyl Catalyzed Reactions of Esters and Lactones with Hydrosilane and Carbon Monoxide. A Novel Synthetic Method for the Introduction of the Siloxymethylidene Group.
Authors: CHATANI N. , FUJII S. , YAMASAKI Y. , MURAI S. , SONODA N. 
Published: May 2016

AbstractA new methodology for making C‐Co bonds by utilizing the high affinity of Si in R3SiCo(CO)4 for oxygen, has resulted in the development of new catalytic reactions of alkyl acetates and lactones with hydrosilanes R3SiH and CO in the presence of Co2(CO)8.
ChemInform Abstract: Synthesis, Structure and Transformation of 8‐Oxa‐4‐thia‐1‐azabicyclo‐(4,3,0)nonan‐9‐one.
Authors: EREMEEV A. V. , NURDINOV R. , POLYAK F. D. , ZOLOTOYABKO R. M. , MISHNEV A. F. , BELYAKOV S. V. , BLEIDELIS YA. YA. 
Published: May 2016

AbstractReduction of the thiazine dicarboxylate (I) with sodium borohydride produces the bicyclus (II).
ChemInform Abstract: Cyclotrimerization of Rhodanic Acid in Organic Solvents.
Authors: RYBIN A. G. , ZIL'BERMAN E. N. , ETLIS I. V. , CHERVYAKOVA G. N. 
Published: May 2016

AbstractRhodanic acid, obtained from pyridinium rhodanide (II) and sulfuric acid, is trimerized in isopropanol to give 1,3,5‐trimercapto‐s‐triazine (III).
ChemInform Abstract: Reinvestigation of the Pressure Effect on the Outer‐Sphere Electron‐Transfer Reaction Between Aquapentaamminecobalt(III) and Hexacyanoferrate(II) in Aqueous Solution.
Authors: SASAKI Y. , ENDO K. , NAGASAWA A. , SAITO K. 
Published: May 2016

AbstractThe kinetic parameters of the title reaction reported by other authors are corrected on the basis of measurements using other reaction conditions.
ChemInform Abstract: Chemistry of 1,8‐Substituted Naphthalenes. Part 18. peri Hydroxy and peri Acyloxynaphthyl Benzyl Ketones Under the Conditions of the Isoflavone Synthesis.
Authors: ZHUKOVSKAYA O. N. , MEZHERITSKII V. V. , PIVOVARENKO V. G. 
Published: May 2016

AbstractThe reaction of the ketone (I) with a series of carbonyl compounds in the presence of a base affords the peri acyloxysubstituted enol acylates (II).
ChemInform Abstract: Introduction of Acyl Substituents at Position 2 of the Indolinone Ring.
Authors: VELEZHEVA V. S. , SMUSHKEVICH V. YU. , ROMANOVA O. B. , KURKOVSKAYA L. N. , SUVOROV N. N. 
Published: May 2016

AbstractThe reaction between N‐acetylindolinone (I) and the carboxylic anhydrides (II) in the presence of H2SO4 affords products of C‐acylation, i.e. the compounds (III), which are deacetylated to give the 2‐acylindolin‐3‐ones (IV).
ChemInform Abstract: Synthesis of d,l‐(3‐Acetoxy‐1‐octadecylthio)propyl‐2‐phosphorylcholine: A Geometrical Isomer of Thia‐PAF.
Authors: GARRIGUES B. , BERTRAND G. , MAFFRAND J.‐P. 
Published: May 2016

AbstractThe S‐octadecyl thioglycerol (I) is acetylated with acetic anhydride (II) to give the diacetate (III) which is selectively hydrolyzed, producing the monoacetate (IV).
ChemInform Abstract: Preparation and Characterization of an Iron(III) Porphyrin N‐Oxide.
Authors: GROVES J. T. , WATANABE Y. 
Published: May 2016

AbstractThe slow addition of (II) to the complex (I) gives a new species which was identified to be the title compound (III) by spectroscopic evidence and the facility of its demetalation reaction with 4:1‐AcOH/HCl (0 °C, 60 s) to give the free N‐oxide of the porphyrin in 25% yield.
ChemInform Abstract: Mechanistic Informations from trans‐Effect in the Anation Reactions of Some Bis(dimethylglyoximato)Rh(III) Complexes.
Authors: DREOS GARLATTI R. , TAUZHER G. , COSTA G. 
Published: May 2016

AbstractThe parallel lability trend for the title reactions of (I) and analogous Co compounds suggests a dissociative activation process for the reactions of the Rh complexes.
ChemInform Abstract: Nickel(II)‐Promoted Rearrangements of Some N‐Substituted Porphyrins.
Authors: SMITH K. M. , PANDEY R. K. , SNOW K. M. 
Published: May 2016

AbstractThe N‐methoxycarbonylmethylporphyrin (Ia), obtained by standard procedures, rearranges in the presence of nickel(II)‐compounds to give a mixture of the isomeric meso‐substituted nickel(II) porphyrins (IIb) and (IIc); a minor amount of the N‐unsubstituted complex (IIa) is also formed.
ChemInform Abstract: Synthesis of Nα‐(2‐Naphthylsulfonylglycyl)‐4‐guanidino‐ and ‐4‐guanidinomethyl‐phenylalaninepiperidide as a Thrombin Inhibitor.
Authors: HORN H. , WAGNER G. 
Published: May 2016

AbstractThe guanidine derivatives (II) and (IV) mentioned in the title are prepared from the corresponding amino compounds (I) and (III).
ChemInform Abstract: Mechanisms for the Solvolytic Decompositions of Nucleoside Analogues. Part 19. Reactions of 5‐Bromo Substituted Pyrimidine Nucleosides with Aqueous Alkalies: Kinetics and Mechanisms.
Authors: KAEPPI R. + , LOENNBERG H. + 
Published: May 2016

AbstractIn aqueous alkaline solution the bromocytidine (I) is transformed to yield the hydroxy derivative (II) and the uridine (III) in addition to nonchromophoric products.
ChemInform Abstract: Synthesis of 9‐Phenyl‐5H‐2‐benzazepines by Ring Expansion of 1‐Phenyl‐ 2,3‐dihydroisoquinolines.
Authors: LANTOS I. , BHATTACHARJEE D. , EGGLESTON D. S. 
Published: May 2016

AbstractThe phenethylamides (I) are cyclized to form the dihydroisoquinolines (II).
ChemInform Abstract: Spin Density of the Hexacyanochromate(III) Ion Measured by Polarized Neutron Diffraction.
Authors: FIGGIS B. N. , FORSYTH J. B. , REYNOLDS P. A. 
Published: May 2016

AbstractA Cs2KCr(CN)6 single crystal has been investigated by polarized neutron diffraction and the magnetic structure factors obtained are analyzed in terms of valence orbital or alternatively multipole populations on all atoms.
ChemInform Abstract: Configurational Assignment of the Diels‐Alder Adducts of Cyclopentadiene and 9,10‐Dihydro‐9,10‐ethenoanthracene‐11,12‐dicarboxylic Anhydride by PMR Spectroscopy.
Authors: CHATURVEDI J. , VERMA S. M. 
Published: May 2016

AbstractThe reaction between the anhydride (I) and cyclopentadiene (II) yields a mixture of the exo (III)‐ and the endo‐adduct (IV).
ChemInform Abstract: Influence of the Oxygen‐for‐Fluorine Substitution on the Electric Properties of K1‐xBixF1+2x Solid Solutions.
Authors: LABORDE P. , REAU J.‐M. 
Published: May 2016

AbstractIn the KBiF4‐BiF3‐BiOF system a large homogeneity range with fluorite‐type structure is shown to occur.
ChemInform Abstract: Regioselective Monobromination of Aromatic Amines with Tetrabutylammonium Tribromide.
Authors: BERTHELOT J. , GUETTE C. , ESSAYEGH M. , DESBENE P. L. , BASSELIER J. J. 
Published: May 2016

AbstractBromination of the anilines (I) with tetrabutylammonium tribromide (II) yields predominantly the p‐bromoanilines (III), together with small amounts of the 2,4‐disubstituted compounds (IV).
ChemInform Abstract: 1,4‐Naphthoquinones. Part 15. Reaction of 2‐ and 3‐Chloro‐ or Bromojuglone Derivatives with OH‐ in Methanol (Part 1. Monomeric Compounds).
Authors: WURM G. , GURKA H.‐J. , GERES U. 
Published: May 2016

AbstractThe halojuglones (I) react with sodium hydroxide in methanol to yield the substitution products (II) and (III).
ChemInform Abstract: An Efficient One‐Pot Synthesis of 2,5‐Disubstituted Thiophenes from 1‐Propynylamines or Allenic Amines and Thiocarbonyl Compounds.
Authors: DE JONG R. L. P. , BRANDSMA L. 
Published: May 2016

AbstractThe 1‐aminopropynes (I) and the aminoallenes (IV) are treated with Schlosser's reagent (II) to form the salts (III).
ChemInform Abstract: One‐Pot Synthesis of 2,3‐Disubstituted Quinazolin‐4‐ones.
Authors: ASHARE R. , MUKERJEE A. K. 
Published: May 2016

AbstractWhereas reaction of the acid (Ia) with the isothiocyanates (II) gives the title compounds (III), the reaction of (Ib) with (IIa) or (IIb) yields the products (IV) or (V).
ChemInform Abstract: 2‐Aryl‐s‐triazolo(4,3‐a)pyrimidines. Synthesis and Transformations.
Authors: KREZHEL' I. 
Published: May 2016

AbstractThe condensation reaction of the tetrahydropyrimidine (I) with the arylhydrazines (II) gives the triazolo(4,3‐a)pyrimidines (III).
ChemInform Abstract: 2‐Isothiocyanatobenzylpyridinium Bromide. An Intermediate for the Synthesis of 2‐Arylamino‐4H‐benzo(d) (1,3)thiazines.
Authors: GONDA J. , KRISTIAN P. 
Published: May 2016

AbstractThe reaction between the bromide (I) and pyridine affords the title compound (II), which adds the aromatic amines (III) to yield the thiourea bromides (IV).
ChemInform Abstract: 5,6,6a,7,12,14‐Hexahydroisoquino(2,3‐b)benz‐2‐azepine. A New Way of Access.
Authors: HENIN J. , GARDENT J. 
Published: May 2016

AbstractThe tetralone (I) is coupled with the aldehydes (II) to produce the arylidene compounds (III).
ChemInform Abstract: Nickel Complexes with a Propellane Structure.
Authors: SCHWAGER H. , KRUEGER C. + , NEIDLEIN R. , WILKE G. 
Published: May 2016

AbstractThe Ni complexes (II) are prepared by addition of corresponding Ni(0) complexes to the central three‐membered ring double bond of difluorocyclopropabenzene (I) with removal of aromaticity.
ChemInform Abstract: The Structure and Properties of the Products of Reaction between 3,4,6‐Tri‐O‐acetyl‐2‐deoxy‐2‐nitroso‐α‐D‐galactopyranosyl Chloride and Pyrazole.
Authors: SMIATACZ Z. , SZWEDA R. , MYSZKA H. 
Published: May 2016

AbstractCoupling the glycosyl chloride (I) with pyrazole (III) yields the N‐glycosides (III) ‐ (V).
ChemInform Abstract: X‐Ray Molecular Structure of Caissarone, a Novel Purine Derivative from the Sea Anemone Bunodosoma caissarum Correa 1964.
Authors: ZELNIK R. , HARAGUCHI M. , MATIDA A. K. , LAVIE D. , FROLOW F. , WEIS A. L. 
Published: May 2016

AbstractThe title compound is isolated as the hydrochloride (I).
ChemInform Abstract: Effects of CdS Film Thickness on the Photovoltaic Properties of Sintered CdS/CdTe Solar Cells.
Authors: LEE J. S. , JUN Y. K. , IM H. B. 
Published: May 2016

AbstractPolycrystalline CdS/CdTe heterojunction solar cells with various thicknesses of the CdS film (15‐55 μm) have been prepared by the coating (slurry of CdS, CdCl2, propylene glycol) and sintering method.
ChemInform Abstract: An ab initio SCF‐MO Study of the Relative Stability of Carbonyl Imines (R2C=O‐NR).
Authors: ALTMANN J. A. , RZEPA H. S. 
Published: May 2016

AbstractThe thermal ring opening of oxaziridines (I) could, in principle, produce nitrones (II) or carbonyl imines (III).
ChemInform Abstract: Chalcone Aziridines. Part 3. Reaction of trans‐Chalcone Aziridines with Isocyanates, Isothiocyanates and HSCN.
Authors: WEBER F. G. , LIEPERT H. , KOEPPEL H. + 
Published: May 2016

AbstractThe reaction of the aziridines (I) with the isocyanate (II) or with the isothiocyanates (VIII) yields the 1‐phenylcarbamoyl aziridines (III) or the thiazolines (IX).
ChemInform Abstract: Reactions Between Phosphazenes and Organosilicon Compounds. Part 2. Synthesis and Molecular Structure of Methylsilane‐ and Methylsiloxane‐Cyclotriphosphazenes.
Authors: ALLCOCK H. R. , BRENNAN D. J. , GRAASKAMP J. M. , PARVEZ M. 
Published: May 2016

AbstractThe mono‐ and gem‐disubstituted chlorocyclotriphosphazenes (II), (III), and (IV) are prepared as shown in the scheme.
ChemInform Abstract: Cyclic Organylarsino Sulfur Diimides.
Authors: HERBERHOLD M. , GULDNER K. 
Published: May 2016

AbstractThe reactions of the bifunctional bis(chloroarsino) compounds (I) and (III) with the salt K2SN2 lead to mono‐ and bicyclic products (II) and (IV), resp., containing arsino‐substituted sulfur diimide units.
ChemInform Abstract: Synthesis, Characterization, and Electrochemical Studies of Iron, Cobalt, and Nickel Complexes of Polyphosphine Ligands.
Authors: DUBOIS D. L. , MIEDANER A. 
Published: May 2016

AbstractThe reaction of (M(NCMe)6)(BF4)2 (M: Fe, Co, Ni) with the polyphosphine ligands PPh3‐n(CH2CH2PPh2)n (n = 3, 2, 1) results in the formation of the complexes (I)‐(VII).
ChemInform Abstract: Amino Acids and Peptides. Part 12. Synthesis of Thiated Analogues of Boc‐S‐Ala‐Aib‐S‐Ala‐OMe and Ac‐S‐Ala‐Aib‐S‐Ala‐OMe.
Authors: JENSEN O. E. , SENNING A. 
Published: May 2016

AbstractThe synthesis of the title peptides (IIIa), (IIIb) and their thio analogues (IIIc), (IVa), (V), (IVb), and (IX) starts from the reaction of the dipeptide (Ib) (from (Ia)) with the ester (II); the product (IIIa) can be readily transformed to (IIIb) in two steps.
ChemInform Abstract: Synthesis of Disaccharide Analogues of Methyl 4‐O‐α‐D‐Galactopyranosyl‐ β‐D‐galactopyranoside (“Methyl Urobioside”), the Minimum Structure Recognized by p‐Fimbriated E. coli.
Authors: NORBERG T. , OSCARSON S. , SZOENYI M. + 
Published: May 2016

AbstractGlycosidation of the rhamnoside (Ic), prepared from (Ia) by benzoylation, acidic hydrolysis, and partial benzoylation of the resulting diol, with the galactoside (II) gives the disaccharide (III) which is deblocked to yield (IV).
ChemInform Abstract: Palladium‐Catalyzed Substitution of Allylic Nitro Compounds. Regiochemistry.
Authors: TAMURA R. , KAI Y. , KAKIHANA M. , HAYASHI K. , TSUJI M. , NAKAMURA T. , ODA D. 
Published: May 2016

AbstractThe allylic nitro compounds (I) and (VI) undergo allylic substitution with the nucleophiles (II) and (IX) in the presence of the Pd(0) complex (III).
ChemInform Abstract: Oxidative Deiodination of Cubyl Iodides: A Tactic for the Nucleophilic Introduction of Substituents onto the Cubane Framework.
Authors: EATON P. E. , CUNKLE G. T. 
Published: May 2016

AbstractThe cubyl iodide (I) reacts with peracids to yield the acetoxycubane (II) or ‐ via (III) and (IV) ‐ the ester (V).
ChemInform Abstract: Molecular Anion Binding and Substrate Photooxidation in Visible Light by 2,7‐Diazapyrenium Cations.
Authors: BLACKER A. J. , JAZWINSKI J. , LEHN J.‐M. 
Published: May 2016

AbstractDiazapyrenium dications such as (II) combine features of those of pyrene, methylviologen, and nucleic‐acid intercalators.
ChemInform Abstract: Macroscopically Oriented Copper(II) Chelates in Cast Multibilayer Films.
Authors: ISHIKAWA Y. , KUNITAKE T. 
Published: May 2016

AbstractCast films of bilayer membranes consisting of the ammonium compound (I) and Cu(II) chelates (II) or (III) in which the chelate moiety is noncovalently bound are prepared from the ligands and CuSO4 (water, pH 8.1, 20 °C) followed by addition of (I) and by spreading the dispersion on Teflon plates (20‐25 °C, some days).
ChemInform Abstract: Synthesis and Reactivity of (Thioamido S‐oxide)(diene)rhodium(I) Complexes. X‐Ray Structure of Rh(I)((p‐Tol)(p‐TolN)C=S=O) (NBD).
Authors: JANS R. J. F. , VAN KOTEN G. , VRIEZE K. , SPEK A. L. 
Published: May 2016

AbstractAmidosulfines in their anionic form (II) react with the Rh complex (III) to give the title compounds (IV).
ChemInform Abstract: Cationic Arene Complexes of Rhodium and Ruthenium with Functional Substituents in the Side Chain.
Authors: KUDINOV A. R. , KAGANOVICH V. S. , RYBINSKAYA M. I. 
Published: May 2016

AbstractIn the arene complexes of rhodium (I) and ruthenium (IV) the arene is replaced by the substituted arenes (II) to give the title compounds (III) and (V).
ChemInform Abstract: The Use of S‐Acetamidomethyl‐L‐cysteine in the Synthesis of Glutathione, Glutathione Fragments, and Their Amides.
Authors: MINCHEV S. , SOFRONIEV N. V. 
Published: May 2016

AbstractThe tripeptide derivative (III) obtained from the readily accessible dipeptide derivative (I) and the active ester (II) is transformed to the hydrobromide (IV); subsequent oxidation leads to glutathione‐SS (V).
ChemInform Abstract: Preparation of an allo‐Threonine Derivative by Catalytic Hydrogenation of an α‐Acetylamino‐β‐ketobutyric Acid Ester on Modified Catalysts.
Authors: VEDEBYAPIN A. A. , MURINA I. P. , KUZNETSOVA T. I. , KLABUNOVSKII E. I. 
Published: May 2016

AbstractHydrogenation of the N‐acetyl amino ketobutyrate (II), prepared from the derivative (I), in the presence of a modified nickel catalyst leads to the stereoselective formation of N‐acetyl‐allo‐threonine (III).