bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Sulfur Compounds. Part 112. The Molecular Composition of Hydrophilic Sulfur Sols Prepared by Acid Decomposition of Thiosulfate.
Authors: STEUDEL R. , GOEBEL T. + , HOLDT G. 
Published: May 2016

AbstractHydrophilic sulfur sols, obtained by acid decomposition of Na2S2O3 in water (so‐called Raffo sols) are analytically characterized using chemical analysis, IR and Raman spectra, ion‐pair chromatography, and reversed‐phase HPLC.
ChemInform Abstract: Proton and 13C NMR Studies of cis‐eq‐ and trans‐eq‐Ethylenediamine‐N,N,N′‐triacetatocobalt(III) and cis‐eq‐N‐Methylethylenediamine‐N,N′,N′‐triacetatocobaltate(III). Crystal Structure of NH4cis‐eq‐(Co(ed3a)CN).
Authors: MARICONDI C. , UTSUNO S. , RADANOVIC D. J. , TRIFUNOVIC S. R. , ABOLA J. E. , DOUGLAS B. 
Published: May 2016

AbstractThe complexes (I) and (II) as their K salts are investigated by NMR spectroscopy and compared with the corrresponding nitro compounds.
ChemInform Abstract: Highly Reactive Titanium on Graphite. A Universal Reducing Agent for the Coupling of Carbonyl Compounds to Alkenes.
Authors: FUERSTNER A. + , WEIDMANN H. 
Published: May 2016

AbstractTitanium on graphite, derived from titanium trichloride and potassium‐graphite, is a universally applicable McMurry reagent for the conversion of the carbonyl (I) and dicarbonyl compounds (IV) to the alkenes (II) or the cycloalkenes (V).
ChemInform Abstract: Halogenation Using Ammonium Polyhalides. Part 5. Iodination of Phenols by Use of Benzyltrimethylammonium Dichloroiodate(1‐).
Authors: KAJIGAESHI S. , KAKINAMI T. , YAMASAKI H. , FUJISAKI S. , KONDO M. , OKAMOTO T. 
Published: May 2016

AbstractBenzyltrimethylammonium chloride (I) reacts with ICl to give the iodination agent (II) mentioned in the title.
ChemInform Abstract: Reactions of Trimethylsilyl Ketene Acetals with Benzoyl Cyanide and with α‐Keto Esters.
Authors: REDDY C. P. , TANIMOTO S. 
Published: May 2016

AbstractThe ketene acetals (Ia)‐(Ic) react with benzoyl cyanide (II) in the absence of a catalyst to give the iminopropionates (III).
ChemInform Abstract: Synthesis and Properties of Some Silylethynylsilanes. Molecular Structure of Tetrakis(trimethylsilylethynyl)silane.
Authors: SCHMIDBAUR H. , EBENHOECH J. + , MUELLER G. + 
Published: May 2016

AbstractThe silane (VI), a colorless liquid, decomposes above 100 °C with loss of the self‐combustible SiH4.
ChemInform Abstract: 2,4,6‐Tris(bis(trimethylsilyl)methyl)phenyl, a New Sterically Demanding Group for Kinetic Stabilization of Unstable Compounds.
Authors: OKAZAKI R. , UNNO M. , INAMOTO N. 
Published: May 2016

Abstract1,3,5‐Trimethylbenzene (I) is photochlorinated and then treated with the chlorosilane (III) to produce the tris(disilylmethyl)benzene (IV) which is converted to the corresponding aniline (VI).
ChemInform Abstract: Synthesis and Crystal Structure of Tris(bis(trimethylsilyl)amido)oxoniobium(V): A Four‐Coordinated Oxo Niobium Precursor.
Authors: HUBERT‐PFALZGRAF L. G. , TSUNODA M. , LE BORGNE G. 
Published: May 2016

AbstractThe reaction of the tetrachloride (I) with an excess of the Li amide (II) leads to O abstraction of the THF ligand and formation of the first non‐chlorine oxoamido‐Nb compound (III).
ChemInform Abstract: Synthesis, Spectroscopic Studies, and Crystal and Molecular Structure of Bismuth Hexacyanoferrate(III) Tetrahydrate, BiFe(CN)6·4 H2O.
Authors: MULLICA D. F. , PERKINS H. O. , SAPPENFIELD E. L. 
Published: May 2016

AbstractThe title complex is obtained by reaction of K3(Fe(CN)6) with Bi(NO3)3 in aqueous solution at pH 3. This complex is characterized by IR spectroscopy, analytic methods, and an X‐ray structure analysis (space group P21/m, Z=2).
ChemInform Abstract: Thermolysis of Re2(CO)10‐n(P(C6H5)3)n (n = 1, 2).
Authors: HAUPT H.‐J. , BALSAA P. , FLOERKE U. + 
Published: May 2016

AbstractThermolysis of the bis(phosphine) complex (I) containing axial phosphines gives six products of the two types (II) and (III).
ChemInform Abstract: Reaction of 1,2‐Diferrocenylcyclopropanes with Triphenylcarbenium Tetrafluoroborate.
Authors: KLIMOVA E. I. , PUSHIN A. N. , SAZONOVA V. A. 
Published: May 2016

AbstractThe bisferrocenylcyclopropane (I) (E,Z‐mixture) reacts with tritylium tetrafluoroborate (II) to give the allyl cation (III).
ChemInform Abstract: Calorimetric Study on Oxygen Addition to Cobalt(II) Complexes with Tris(2‐aminoethyl)amine and 3,7‐Diazanonane‐1,9‐diamine.
Authors: CABANI S. , CECCANTI N. , TINE M. R. 
Published: May 2016

AbstractThrough spectrophotometric and potentiometric measurements it is shown that in aerated aqueous solution of (I) and (II) the complex ion (III) is totally formed, whereas in solutions containing (IV) only (V) is observed.
ChemInform Abstract: Dicopper(I) Complexes Containing Intramolecular 1,2‐Diaza Bridging Ligands. Behavior of the Dicopper Site in the Dehydrogenation of Hydrazobenzene. Crystal Structure of (Cu2L2(pydz)2) (ClO4)2.
Authors: DREW M. G. B. , YATES P. C. , TROCHA‐GRIMSHAW J. , LAVERY A. , MCKILLOP K. P. , NELSON S. M. , NELSON J. 
Published: May 2016

AbstractThe macrocyclic ligands of the complexes investigated were synthesized by template Schiff base condensation of 2,5‐diformylfuran with the appropriate diamine on Group 2 metal ions.
ChemInform Abstract: Synthesis and Reactivities of trans‐Dioxoosmium(VI) Schiff Base Complexes. X‐Ray Crystal Structure of Dioxo(N,N′‐(1,1,2,2‐tetramethylethylene)bis(3‐tert‐butylsalicylidenaminato))osmium(VI).
Authors: CHE C.‐M. , CHENG W.‐K. , MAK T. C. W. 
Published: May 2016

AbstractThe Os(VI) Schiff base complexes (I) are prepared by reaction of K2(OsO2(OH)4) with the appropriate substituted Schiff base in methanol.
ChemInform Abstract: Enantioselective Synthesis of the Tricyclo(5.2.2.01,5)undecane Skeleton Using Aprotic Michael Additions: Formal Total Synthesis of (+)‐Isoeremolactone.
Authors: SPITZNER D. , SAWITZKI G. 
Published: May 2016

AbstractMichael addition of the ester (I) to the enone (II) affords the adduct (III) (space group P212121; Z=4).
ChemInform Abstract: Porous and Electrically Conducting Clay‐Carbon Composite as Positive Electrodes of Zinc‐Oxygen Primary Cells and Zinc‐Iodine Secondary Cells.
Authors: YAMAMOTO T. , KANBARA T. 
Published: May 2016

AbstractA new porous and electrically conducting clay‐carbon composite, prepared by sintering mixtures of a clay (composed mainly of kaolinite) and porous carbon, can be used as excellent positive electrodes of zinc‐oxygen primary cells and zinc‐iodine secondary cells.
ChemInform Abstract: Liquid Corrosion and High‐Temperature Oxidation Effects on Silicon Carbide/Titanium Diboride Composites.
Authors: SESHADRI S. G. , SRINIVASAN M. 
Published: May 2016

AbstractSiC/TiB2 composites have been exposed to aqua regia solution for 200 h, to 50% aqueous NaOH, and to 10% HF/57% HNO3/H2O solution for up to 500 h at room temperature.
ChemInform Abstract: The Redispersion of Sintered Pt, Rh, and Pt/Rh Catalysts.
Authors: D'ANIELLO M. J. JUN. , MONROE D. R. , CARR C. J. , KRUEGER M. H. 
Published: May 2016

AbstractThe redispersion of thermally aged automotive catalysts containing Pt, Rh, or bimetallic Pt/Rh using high temp. chlorine treatments is investigated by hydrogen chemisorption, HRTEM, and catalytic activity measurements.
ChemInform Abstract: Regulated Dioxygen Affinities by Steric Restrictions on Axial Bases in “Jellyfish” Type Cobalt(II) Porphyrins.
Authors: UEMORI Y. , MIYAKAWA H. , KYUNO E. 
Published: May 2016

AbstractThe title compounds are prepared from the free porphyrin bases (syntheses described) and CoCl2 in THF or Co(O‐Ac)2 in AcOH (no yield given).
ChemInform Abstract: Extraction of 3d‐Metal Ions by Bidentate Sulfonamides. Part 1. Ligands with Sulfur or Heterocyclic Nitrogen as a Second Donor Atom.
Authors: DOERING M. + , HEPPNER A. , UHLIG E. , UNDEUTSCH B. , GLOE K. , MUEHL P. + 
Published: May 2016

AbstractThe hydrazone (I) extracts Cu(II) and Zn(II) from weak acid solutions analogously to LIX 34 via coordination through the amide nitrogen.
ChemInform Abstract: Reactions of 3‐Alkyl‐ and 3,3‐Dialkyl‐1‐bromoallenes with Organocuprates: Effects of the Nature of the Cuprate Reagent on the Regio‐ and Stereoselectivity.
Authors: CAPORUSSO A. M. , POLIZZI C. , LARDICCI L. 
Published: May 2016

AbstractReaction of the monoalkylbromoallene (Ia) with the organocuprates (IIa) and (IIb) yields the alkynes (III), whereas the dialkylated bromoallene (Ib) and the cuprates (II), (IV), or (VI) produce the trisubstituted allenes (V).
ChemInform Abstract: Intramolecular Diels‐Alder Reaction of Bicyclo(6.4.0)dodeca‐4,9,11‐triene.
Authors: GRIMME W. , WIECHERS G. 
Published: May 2016

Abstract1,1‐Dimethoxytetrachlorocyclopentadiene (I) and 1,5‐cyclooctadiene (II) give the Diels‐Alder adduct (III) which is reductively dechlorinated and then selectively chlorinated, yielding (IV).
ChemInform Abstract: Epoxidation of Alkenes and Terpenes with Iodylbenzene Catalyzed by Vanadylacetylacetonate.
Authors: BARRET R. , PAUTET F. , DAUDON M. , SABOT J. F. 
Published: May 2016

AbstractSimple alkenes such as the cyclohexenes (I) are epoxidized with iodylbenzene in the presence of vanadyl acetylacetonate to form the corresponding oxiranes such as (II).
ChemInform Abstract: Synthesis of Alkyl‐ and Phenyl‐Substituted 4‐Aminomethyl‐2‐butenolides‐4.
Authors: KUKHAREV A. S. , TISHCHENKO I. G. , TYVORSKII V. I. 
Published: May 2016

AbstractBase‐catalyzed cyclization of the aminohydroxyalkenoates (I) produces the butenolides (II).
ChemInform Abstract: Structure and Reactivity of Isoanellated Heterocyclic Systems with 4nπ‐ and (4n + 2)π‐Electrons. Part 14. Tri‐ and Tetracyclic Hetarenes with Localized or Delocalized Pyrrole Units.
Authors: KREHER R. P. , HILDEBRAND T. 
Published: May 2016

AbstractThe title compounds (V) and (VII) are prepared by analogous routes and characterized by spectroscopic data.
ChemInform Abstract: A New Access to 2‐Benzoylquinoline and 1‐Benzoylisoquinoline Using a Novel Mode of Base‐Induced Decomposition of N‐Alkoxypyridinium Salts.
Authors: SLIWA H. , OUATTARA L. 
Published: May 2016

AbstractQuinoline‐N‐oxide (I) and isoquinoline‐N‐oxide (VI) are alkylated with α‐bromoisobutyrophenone (II) to give the N‐alkoxy perchlorates (III) and (VII) which undergo intramolecular cyclization in the presence of 2,2,6,6‐tetramethylpiperidine, producing the tricyclic (iso)quinolinium perchlorates (IV) and (VIII).
ChemInform Abstract: Photooxidation of α‐Phellandrene: The Formation of Cyclohexadienyl Hydroperoxides and Their Reduction to Arene 1,4‐Hydrates.
Authors: ATKINS R. , CARLESS H. A. J. 
Published: May 2016

AbstractDye‐sensitized photooxygenation of α‐phellandrene (I) gives the stereoisomeric endo‐peroxides (II) and (III), together with the hydroperoxides (IV).
ChemInform Abstract: Cyclobisintercalands: Synthesis and Structure of an Intercalative Inclusion Complex, and Anion Binding Properties.
Authors: JAZWINSKI J. , BLACKER A. J. , LEHN J.‐M. , CESARIO M. , GUILHEM J. , PASCARD C. 
Published: May 2016

AbstractThe macrocyclic tetramide (III) is obtained by cyclocondensation of the dianhydride (I) with the diamine (II) using the high dilution method.
ChemInform Abstract: The Synthesis of 11‐13‐Membered Diacetylenic and 18‐Membered Tetraacetylenic Ring Systems.
Authors: JUST G. , SINGH R. 
Published: May 2016

AbstractStepwise substitution of 1,2‐dibromobenzene (I) with the alkynes (II) in the presence of Pd catalysts gives the dialkynylbenzenes (III).
ChemInform Abstract: Reaction of Bis(2‐mercaptoethyl)phosphines with Organotin Compounds. Molecular Structure of a Tin Containing Sixteen‐Membered Ring.
Authors: JURKSCHAT K. , UHLIG W. , MUEGGE C. + , TZSCHACH A. , SCHMIDT B. , DRAEGER M. + 
Published: May 2016

AbstractA trans configuration is shown for the dimers (I), derived from tBu2Sn (OMe)2 and the corresponding phosphine followed by the oxidation with S or Se (space group of (Ia): P21/n).
ChemInform Abstract: Diastereospecific Reformatsky Reactions with Chiral Arylaldehyde Tricarbonylchromium Complexes.
Authors: BROCARD J. , PELINSKI L. , LEBIBI J. 
Published: May 2016

AbstractReformatsky reaction of the bromo esters or nitriles (II) with tricarbonylchromium 2‐methoxybenzaldehyde (I) yields diastereoselectively the chiral complexed benzylic alcohols (III).
ChemInform Abstract: Oxo‐Molybdenum(IV) and ‐Tungsten(IV) Complexes with Dithio Acid Ligands. Synthesis and Structural Investigation of MoO(S2C(PMe3)S‐i‐Pr‐S,S′)(S2CS‐i‐Pr‐S,S′,C).
Authors: CARMONA E. , GALINDO A. , GUILLE‐PHOTIN C. , LAI R. , MONGE A. , RUIZ C. , SANCHEZ L. 
Published: May 2016

AbstractThe title compound (IIIa) is synthesized according to the scheme.
ChemInform Abstract: Ligand Substitution in (Ind)W(CO)3Cl and (Ind)W(CO)‐ 3Na+ (Ind = Indenyl): Examples of Mixed Associative and Dissociative Substitution.
Authors: TURAKI N. N. , HUGGINS J. M. , LEBIODA L. 
Published: May 2016

Abstract(I), prepared from W(CO)6 and sodium indenyl in 1,4‐dioxane at 100 °C (yield: 52%), crystallizes in Pc with Z=4 and its substitution product (IV) in P21/c with Z=4.
ChemInform Abstract: Copper(II), Nickel(II), and Cobalt(III) Complexes with New Macrocyclic Ligands. 6,14‐Dimethyl‐1,5,9,13‐tetraazacyclohexadeca‐5,13‐diene (Me2(16)diene) and C‐meso‐ and C‐rac‐6,14‐Dimethyl‐1,5,9,13‐tetraazacyclohexadecane (C‐meso‐ and C‐rac‐Me2(16)ane).
Authors: BEMBI R. , ROY T. G. , JHANJI A. K. 
Published: May 2016

AbstractThe unstable macrocyclic title ligand (III) is synthesized as its dihydroperchlorate by the nontemplate condensation shown in the scheme and is reduced to give the saturated C‐meso and C‐racemic isomers (IVa) and (IVb).
ChemInform Abstract: BINAP‐Ruthenium(II) Dicarboxylate Complexes: New, Highly Efficient Catalysts for Asymmetric Hydrogenations.
Authors: OHTA T. , TAKAYA H. , NOYORI R. 
Published: May 2016

AbstractThe diastereomeric title complexes (I) are prepared by treatment of (RuCl2(cod))n (III) with (S)‐ or (R)‐2,2'‐bis(diarylphosphino)‐1,1'‐binaphthyls and then with sodium carboxylate as shown for the examples (S)‐(Ia) and (R)‐(Ib).
ChemInform Abstract: Crystal Structure Determination of Dipotassium Dihydroxotrioxoruthenate(VI): Configuration of the Ruthenate Ion and Its Electronic Properties.
Authors: ELOUT M. O. , HAIJE W. G. , MAASKANT W. J. A. 
Published: May 2016

AbstractA crystal structure determination of K2RuO3(OH)2, formerly known as K2RuO4·H2O, reveals a five‐coordinate ruthenium with three equatorial oxygens and two apical OH ions in a trigonal‐bipyramidal arrangement (approximately D3h symmetry).
ChemInform Abstract: N,N‐Dialkylated Monophenolic trans‐2‐Phenylcyclopropylamines: Novel Central 5‐Hydroxytryptamine Receptor Agonists.
Authors: ARVIDSSON L.‐E. , JOHANSSON A. M. , HACKSELL U. , NILSSON J. L. G. , SVENSSON K. , HJORTH S. , MAGNUSSON T. , CARLSSON A. , LINDBERG P. , ANDERSSON B. , SANCHEZ D. , WIKSTROEM H. + , SUNDELL S. 
Published: May 2016

AbstractCyclopropanation reaction of the trans‐cinnamate (I) with diazomethane (II) followed by saponification of the ester yields the trans‐phenylcyclopropanecarboxylic acid (III).
ChemInform Abstract: Regiospecific Synthesis and Spectroscopic Identification of New F‐Alkyl Substituted Aminopyrazoles.
Authors: FABRON J. , PASTOR R. , CAMBON A. 
Published: May 2016

AbstractStarting with the phosphonium salt (I), the cyanooctanoyltriphenylphosphorane (IV) is prepared via the ylide (II).
ChemInform Abstract: Reaction of 4‐tert‐Butyldimethylsiloxy‐1‐benzopyrylium Salt with Enol Silyl Ethers and Active Methylenes.
Authors: IWASAKI H. , KUME T. , YAMAMOTO Y. , AKIBA K. 
Published: May 2016

AbstractChromone (I) reacts with the silyl triflate (II) to give the benzopyrylium salt (III) which is coupled with the enol ethers (IV) or the activated methylene compounds (VI) to give the substituted derivatives (V) and (VII).
ChemInform Abstract: α‐Lithiated O,O‐Diethyl Trimethylsilylchloromethylphosphonate. Part 1. Preparations and Properties.
Authors: TEULADE M.‐P. , SAVIGNAC P. 
Published: May 2016

AbstractThe α‐lithiated phosphonate (IV) mentioned in the title is prepared by treatment of the trichloromethylphosphonate (I) with butyllithium (II) and chlorotrimethylsilane (III).
ChemInform Abstract: Polylithiumorganic Compounds. Part 8. A Tetramethylene‐1,4‐distannacyclohexane from 3,4‐Dilithio‐2,5‐dimethyl‐2,4‐hexadiene and Dichlorodimethylstannane, the First Dimetalla(6)radialene.
Authors: MAERCKER A. , BRAUERS F. , BRIEDEN W. , JUNG M. , LUTZ H. D. 
Published: May 2016

AbstractThe compound (III), obtained in the title reaction crystallizes in P21/c with Z = 8 and has a twisted conformation.
ChemInform Abstract: EPR, Ligand Field Spectra and Antimicrobial Activity of Some N‐Pyruvideneglycinatocopper(II) Complexes.
Authors: PLESCH G. , FRIEBEL C. , SVAJLENOVA O. , KRAETSMAR‐SMOGROVIC J. + , MLYNARCIK D. 
Published: May 2016

AbstractThe N‐pyruvideneglycinato‐Cu(II) complexes (III) containing the N‐ligands (II) are prepared according to the scheme.
ChemInform Abstract: The Reaction of Ruthenium(II) Octaethylporphyrin and Ruthenium(II) Tetraphenylporphyrin Complexes with Carbon Monoxide.
Authors: PAULSON D. R. , BHAKTA S. B. , HYUN R. Y. , YUEN M. , BEAIRD C. E. , LEE S. C. , KIM I. , YBARRA J. JUN. 
Published: May 2016

AbstractFor the ligand exchange reactions of the title complexes (I) with CO the kinetics are studied.
ChemInform Abstract: Synthesis and Reactivity of Two cis‐PtH2(Diphosphine) Complexes (Diphosphine = 1,3‐Bis(diphenylphosphino)propane and 1,4‐Bis(diphenylphosphino)butane).
Authors: SCRIVANTI A. , CAMPOSTRINI R. , CARTURAN G. 
Published: May 2016

AbstractIR, 1H and 31P NMR spectral data of (II) and (IV) are reported.
ChemInform Abstract: Simple 4‐Acetoxy‐5,6‐dihydropyridinium Salts: New Synthons for the Preparation of Functionalized Piperidine Systems.
Authors: TUBERY F. , GRIERSON D. S. , HUSSON H.‐P. 
Published: May 2016

AbstractN‐Methyl‐4‐piperidone (I) is converted to the Δ2‐derivative (IV).
ChemInform Abstract: Observations on the Composition of Prussian Blue Films and Their Electrochemistry.
Authors: LUNDGREN C. A. , MURRAY R. W. 
Published: May 2016

AbstractPrussian blue (PB) films grown on Pt and SnO2 electrodes are investigated by cyclic voltammetry, energy dispersive X‐ray analysis (EDX), XPS, ferric equivalent weight determination, and spectroelectrochemistry.
ChemInform Abstract: Synthesis and Characterization of Ca(HSO4)2·2 H2SO4 or H2(Ca(HSO4)4), respectively.
Authors: HASS D. , KEMNITZ E. , WORZALA H. 
Published: May 2016

AbstractA crystalline compound of the empirical formula CaSO4·3 H2SO4, obtained by crystallization from CaSO4 saturated, hot, conc.
ChemInform Abstract: A New Oxoindate K2Na3(InO4).
Authors: HOPPE R. , GLAUM H. 
Published: May 2016

AbstractThe hitherto unknown nesoindate (IV), obtained on two different ways, is found to be isotypic with Na2Li3(GaO4) and K2Na3(TlO4) (Pnnm, Z=4).
ChemInform Abstract: The Hydrogen Bonding of Ligand Fluoride: The X‐Ray Crystal Structure of Difluoro(2,2′:6′,2′′‐terpyridine)copper(II) Trihydrate.
Authors: EMSLEY J. , ARIF M. , BATES P. A. , HURSTHOUSE M. B. 
Published: May 2016

AbstractDissolving CuF2 in wet methanol containing terpyridine yields the title complex (I) which crystallizes in Pbcn with Z = 8. The basal Cu‐F bond (1.862 Å) is the shortest such bond so far reported.
ChemInform Abstract: A Comparison of Counterion Effects in Surfactant and Classical Colloid Systems.
Authors: EVANS D. F. , EVANS J. B. , SEN R. , WARR G. G. 
Published: May 2016

AbstractThe changes of micellar and interfacial properties (critical micelle concentrations, area/molecule, aggregation numbers in solutions of the dodecyl sulfates of Li+, Na+, K+, Me4N+, Ag+, Ca2+, and Ba2+ are studied in the presence of neutral cryptate ligands (18‐crown‐6, (Ia) and (Ib)) with and without added salts.
ChemInform Abstract: Evidence for the Essential Role of Hydrogen Bonding in Promoting Amphiphilic Self‐Assembly: Measurments in 3‐Methylsydnone.
Authors: BEESLEY A. H. , EVANS D. F. , LAUGHLIN R. G. 
Published: May 2016

AbstractIn contrast to H‐bonding solvents with comparable polarity (such as formamide) no association is observed for (I) (surface tension, conductance measurements) or (II) (diffusive interfacial transport experiments) in the aprotic title solvents.
ChemInform Abstract: Addition of 1,4‐Diphenyl‐1‐azabutadiene to Allenic Esters.
Authors: GANDHI R. P. , ISHAR M. P. S. , WALI A. 
Published: May 2016

Abstract1,4‐Diphenyl‐1‐azabutadiene (I) reacts with the allenic carboxylates (II), producing the cyclohexenones (III).
ChemInform Abstract: Sodium Borohydride Desulfurization of Thiolactams to Amines.
Authors: MANDAL S. B. , GIRI V. S. , PAKRASHI S. C. 
Published: May 2016

AbstractReductive desulfurization of the thiolactams (Ia), (II), and (IV) with sodium boranate yields the amines (Ib), (III), and (V).
ChemInform Abstract: A New Aromatization of 1,2‐Cyclohexanediones: Easy Synthesis of 3‐Arylcatechols.
Authors: FEIGENBAUM A. , PETE J.‐P. , POQUET‐DHIMANE A. 
Published: May 2016

AbstractThe 2‐hydroxy‐2‐cyclohexenones (I) react with tosyl chloride (II) and AIBN to give the catechols (III).
ChemInform Abstract: Heterocyclization of Primary Amines with Highly Activated Cyclopropanes: A New Route to Isoretronecanol.
Authors: CELERIER J. P. , HADDAD M. , JACOBY D. , LHOMMET G. 
Published: May 2016

AbstractThe 1,1‐diacylcyclopropanes (I) are coupled with the amines (II) to give the pyrrolines (III).
ChemInform Abstract: Synthesis and Reactions of 4,5‐Diaryl‐2‐mercaptoimidazoles.
Authors: SALAMA M. A. , YOUSIF N. M. , HAMMAM A. G. 
Published: May 2016

AbstractThe imidazoles (III), prepared from the substituted benzils (I) and thiourea (II), are coupled with chloroacetic acid (IV) to give the derivatives (V) which are cyclized, forming the imidazothiazolones (VI).
ChemInform Abstract: Chemistry of the 5:7‐Fused Heteroaromatic Systems: A Novel Rearrangement Involving the Imidazo(4,5‐e)(1,3,4)triazepine and Pyrazolo(3,4‐e)‐(1,3,4)triazepine Systems.
Authors: HOSMANE R. S. , LIM B. B. 
Published: May 2016

AbstractTreatment of the heterocyclic hydrazidines (I) and (IV) with TFA gives the primary amines (II) and (V), together with the methyltriazolyl‐substituted imidazole (III) or pyrazole (VI).
ChemInform Abstract: Towards New Inhibitors of D‐Alanine‐D‐Alanine Ligase: The Synthesis of 3‐Aminobutenylphosphonic and Aminophosphonamidic Acids.
Authors: VO‐QUANG Y. , GRAVEY A. M. , SIMONNEAU R. , VO‐QUANG L. , LACOSTE A. M. , LE GOFFIC F. 
Published: May 2016

AbstractThe aminophosphonic acid (IV) and the aminophosphonamidic acid (X) are prepared as outlined in the reaction scheme.
ChemInform Abstract: Stereoselective Synthesis of trans‐Olefins by the Reaction of Wittig Reagents with Selenium. Formation of Selenocarbonyl Compounds.
Authors: OKUMA K. , SAKATA J. , TACHIBANA Y. , HONDA T. , OHTA H. 
Published: May 2016

AbstractThe methylenephosphoranes (I) undergo coupling reaction in the presence of selenium (II) to form the olefins (IV) and triphenylphosphine selenide (V) via the selenoaldehydes or selenoketones (III).
ChemInform Abstract: Highly Reduced Organometallics. Part 24. (M(CO)4(CH3C(CH2PMe2)3)), M: Ti, Zr, Hf, Complexes with Zero‐Valent Titanium, Zirconium, and Hafnium; First Structural Characterization of a Zr(0) Carbonyl Complex.
Authors: BLACKBURN D. W. , CHI K. M. , FRERICHS S. R. , TINKHAM M. L. , ELLIS J. E. 
Published: May 2016

AbstractThe air‐sensitive, thermally stable title complexes (IV) are prepared according to the scheme and characterized by IR, 13C(1H) and 31P(1H) NMR spectral data.
ChemInform Abstract: Methyl‐ and Phenylgermanium Derivatives of Diethyldithiocarbamic Acid. The Crystal and Molecular Structure of Diphenylbis(N,N‐diethyldithiocarbamato)germanium.
Authors: CHADHA R. K. , DRAKE J. E. , SARKAR A. B. 
Published: May 2016

AbstractMethyl‐ and phenylgermanes (I) react with the Na‐salt (II) in CS2 at low temp. under exclusion of moisture to yield the compounds (III).
ChemInform Abstract: ((η5‐C5Me4Et)Rh(μ,η2‐P2)2Rh(η5‐C5Me4Et)), a Sandwich Complex with a P4 Rectangle.
Authors: SCHERER O. J. , SWAROWSKY M. , WOLMERSHAEUSER G. + 
Published: May 2016

AbstractThe title complex (IIIb) and its analogue (IIIa) are synthesized according to the scheme and characterized by MS, 1H and 31P(1H) NMR data.