bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Preparation of Cyclophosphates, Cyclophosphatophosphonates, Diphosphonates, and Diphosphites in Urea Melts.
Authors: SCHUELKE U. + , KAYSER R. , NEUMANN P. 
Published: May 2016

AbstractAmmonium cyclotriphosphate (NH4)3(P3O9), ammonium cyclotetraphosphate (NH4)4(P4O12), ammonium cyclotriphosphatophosphonates (I), ammonium organyldiphosphonates (II), and ammonium diphosphites such as (NH4)2H2P2O5 are prepared in high yields on heating acidic phosphates, phosphonates, and phosphites in urea or urea/ammonium nitrate melts.
ChemInform Abstract: Organo‐Arsenic Compounds with an As=N Bond. Part 17. Reaction of Arylarsonous Dichlorides with tert‐Butylamine.
Authors: KOKOREV G. I. , MUSIN R. Z. , BADRUTDINOV SH. KH. , KHALITOV F. G. , PLATONOV A. B. , YAMBUSHEV F. D. 
Published: May 2016

AbstractThe arsonous dichlorides (I) react with tert‐butylamine (II) to give the arsonamidous chlorides (III) and the diazadiarsetidines (IV).
ChemInform Abstract: Convenient Method of Synthesis of Organic Selenides.
Authors: RYKOWSKI Z. , SCZESNA E. 
Published: May 2016

AbstractThe reactions of 2,1,3‐benzoselenodiazole (I) with EtMgBr (IIa) in boiling ether, with BuMgBr (IIb) and PhMgBr (IIc) in dioxane at 50‐55 °C lead to the diselenides (III) in good yields.
ChemInform Abstract: Photo‐Induced Selenothio Esterification of Olefins: Radical Addition to Vinylsilanes.
Authors: TORU T. , SEKO T. , MAEKAWA E. , UENO Y. 
Published: May 2016

AbstractPhotolysis of the (selenothioperoxy)benzoate (I) with alkenes such as (II) leads regioselectively and in high yields to the addition products (III).
ChemInform Abstract: SET Mechanism in Substitution Reactions with Diorganyl Dichalcogenides.
Authors: BILDSTEIN B. , GISELBRECHT K. , SLADKY F. 
Published: May 2016

AbstractWhereas methyl‐ or phenyllithium react with the compounds (I) to afford the expected substitution products, (II) reacts instead to the products (IV)‐(VII).
ChemInform Abstract: The Preparation of Metal Sulfides and Organo‐Metal Sulfides from Metal Alkyls and Hydrogen Sulfide.
Authors: BAUCH C. G. , JOHNSON C. E. 
Published: May 2016

AbstractThe room temp. reaction of AlR3 (R: Me, Et, iBu) with H2S in toluene gives air‐sensitive solids which are postulated to be mixtures of Al2S3 and polymeric (RAlS)x. A species of the empirical formula MeGaS is produced from GaMe3 and H2S. The reactions of M(CH2‐SiMe3)n (M: Cd, Hg, n = 2; M: Ti, n = 4) and MgEt2 with H2S are also described.
ChemInform Abstract: Synthesis of Arylthallium Complexes Using Organomercury Compounds. Crystal and Molecular Structures of (NMe4)(Tl(C6H4N=NPh‐2)Cl3) and (Tl(C6H4CH2NMe2‐2)Cl2).
Authors: VICENTE J. , ABAD J. A. , GUTIERREZ‐JUGO J. F. , JONES P. G. 
Published: May 2016

AbstractThe complex (III) crystallizes in P21/n with Z=4 and gives a neutral complex (72% yield) similar to (V) when treated analogously.
ChemInform Abstract: A Reactive Organometallic Oxo Intermediate, Cp*2Zr=O: Generation and Subsequent Trapping Reactions Forming Alkyne and Nitrile Addition Products.
Authors: CARNEY M. J. , WALSH P. J. , HOLLANDER F. J. , BERGMAN R. G. 
Published: May 2016

AbstractThe generation of the title intermediate by thermal decomposition is studied kinetically.
ChemInform Abstract: Metal‐Containing Heterocycles: Preparation, Properties, Reactions. Part 67. Stereochemical Impacts on the Transition of Monomeric Thiophosphinito Manganese Compounds (OC)4Mn(η2‐S‐PR2) to the Dimeric Complexes ((OC)4Mn(μ‐S‐PR2))2.
Authors: LINDNER E. , KAESS V. + 
Published: May 2016

AbstractThe title compounds (III) and (V) are obtained from BrMn(CO)5 (I) and sec. phosphine sulfides (II) and (IV) in dependence on the phosphine substituent.
ChemInform Abstract: Complexes of Technetium, Rhenium, and Rhodium with Sexidentate Schiff‐Base Ligands.
Authors: HUNTER G. , KILCULLEN N. 
Published: May 2016

AbstractAs a part of the investigation of Tc‐complexes with potential application to myocardial imaging, the stable monocationic complexes (I) of this metal and of its heavier congener, i.e. Re, are prepared from the hexachlorometallates and the ligands.
ChemInform Abstract: Syntheses, Characterization and Structural Studies of Copper Complexes of the 1,2‐Dithiolene Ligand, 5,6‐Dihydro‐1,4‐dithiin‐2,3‐dithiolate.
Authors: VANCE C. T. , WELCH J. H. , BEREMAN R. D. 
Published: May 2016

AbstractThe formally Cu(III) complexes (III) (P21/c, Z=4) and (IV) (Pnnm, Z=2) are characterized by X‐ray diffraction studies.
ChemInform Abstract: Synthesis, Structure, and Redox Properties of Dicopper(II,II) Complexes of N‐(2‐Hydroxyphenyl)salicylamide and Homologues. Facile Oxidation to Dicopper‐(II,III) and ‐(III,III) Species; Crystal Structure of Bis(tetrabutylphosphonium) Bis(((2‐oxidobenzoyl)(2′‐oxidophenyl)amido(3‐)‐NO2,μ‐O2′)cuprate(II)).
Authors: KOIKAWA M. , OKAWA H. , MATSUMOTO N. , GOTOH M. , KIDA S. , KOHZUMA T. 
Published: May 2016

AbstractThe binuclear copper(II) complexes (III) are characterized by electronic spectra and magnetic properties.
ChemInform Abstract: Transition Metal Complexes with Sulfur Ligands. Part 47. S2 Bridged Ruthenium Complexes with Sulfur Dominated Coordination Spheres and Highly Unusual Electronic Properties: (μ‐S2(Ru(PPh3)(“S4”))2) and (μ‐S2(Ru(PPh3)(“buS4”))2) (“S4”2‐: 1,2‐Bis(2‐mercaptophenylthio)ethane (2‐); “buS4”2‐: 1,2‐Bis(3,5‐di(tertiarybutyl)‐2‐mercaptophenylthio)ethane (2‐)).
Authors: SELLMANN D. , BARTH I. 
Published: May 2016

AbstractThe title compounds (III) are synthesized by treating the bis(phosphine) monomers (I) or their (PPh3)(N2H4) analogues with elemental sulfur as shown.
ChemInform Abstract: New μ3‐Alkylidyne Heterometal Clusters with Ru(CO)3 and Os(CO)3 Building Blocks.
Authors: SCHACHT H.‐T. , VAHRENKAMP H. 
Published: May 2016

AbstractThe known metal exchange products (I) react with Na2Ru(CO)4 (II) and Na2Os(CO)4 (IV) according to the scheme to give the heterotrinuclear clusters (III) and (V).
ChemInform Abstract: Mechanism and Energetics of Reductive Elimination of Ethane from Some Tetramethylplatinum(IV) Complexes.
Authors: ROY S. , PUDDEPHATT R. J. , SCOTT J. D. 
Published: May 2016

AbstractThe new complexes (III) decompose in the solid state or in solution on thermolysis to give ethane and cis‐PtMe2L2.
ChemInform Abstract: Synthesis of Octyl Ester of p‐Substituted DL‐2‐Phenylglycines.
Authors: SPRUNG W.‐D. , KOBOW M. , SCHULZ E. 
Published: May 2016

AbstractEsterification of ten phenylglycines such as (I) with n‐octanol (II) produces the corresponding n‐octyl phenylglycinate hydrochlorides (III).
ChemInform Abstract: Structural Studies of Substituted 6,7‐Benzomorphan Compounds. Part 15. Structure and Conformational Analysis of the Opioid Antagonist (‐)‐(1R,5R,9R)‐5,9‐Diethyl‐2‐(3‐furylmethyl)‐2′‐hydroxy‐6,7‐benzomorphan (Mr2266).
Authors: VERLINDE C. L. , BLATON N. M. , PEETERS O. M. , DE RANTER C. J. 
Published: May 2016

AbstractThe two molecules present in the asymmetric unit of the title compound (I) (space group P21 with Z=4) adopt different conformations with respect to the N side chain.
ChemInform Abstract: Structure of 7‐Amino‐2‐chloro(1,3)thiazolo(4,5‐d)pyrimidine, an Adenine Analogue.
Authors: LARSON S. B. , ANDERSON J. D. , COTTAM H. B. , ROBINS R. K. 
Published: May 2016

AbstractThe title compound (I) (space group Pccn with Z=16) forms dimers.
ChemInform Abstract: Syntheses Based on Cyclohexadienes. Part 2. Convenient Synthesis of 6‐Alkylsalicylates, 6‐Alkyl‐2,4‐dihydroxybenzoate, and 2,5‐Dialkylresorcinols.
Authors: KANAKAM C. C. , MANI N. S. , RAMANATHAN H. , RAO G. S. R. S. 
Published: May 2016

AbstractAn efficient one‐pot synthesis of 6‐alkylsalicylates and 6‐alkyl‐2,4‐dihydroxybenzoates such as (IV) is described via cycloaddition of the methoxycyclohexadienes (I) with the substituted propiolic ester (II).
ChemInform Abstract: The Aldol Condensation Catalyzed by Metal(II) β‐Cyclodextrin Complexes.
Authors: ZHANG Y. , XU W. 
Published: May 2016

AbstractCoupling of p‐nitrobenzaldehyde (I) with acetone (II) in the presence of metal(II) sulfate/β‐cyclodextrin complexes at a pH about 7 yields predominantly the aldol adduct (III).
ChemInform Abstract: The Effect of the Alkoxy Group and the Structure of the Cycloalkene on (2 + 2) Photocycloaddition to Alkoxy‐Substituted Pentafluorobenzene.
Authors: SKET B. , ZUPAN M. 
Published: May 2016

AbstractThe stereochemical outcome of the photochemical (2 + 2) cycloaddition reactions of the alkoxy‐substituted pentafluorobenzenes (I) with the cycloalkenes (II), (IV), (VI) depends on the structure of the cycloalkene leading a) to the anti adduct (III), b) to the syn adduct (V), or c) to both syn and anti (2 + 2) cycloaddition (→ (VII) + (VIIIa + b)).
ChemInform Abstract: Use of Elemento‐Organic Compounds of the Fifteenth and Sixteenth Groups in Organic Synthesis. Part 75. Reduction of Some Organic Compounds by Tertiary Stibines.
Authors: HUANG Y.‐Z. , CHEN C. , ZHU F. , LIAO Y. 
Published: May 2016

AbstractTrialkylstibines are shown to reduce nitroarenes such as (I), quinones such as (III) or sulfonyl chlorides such as (V) under mild conditions.
ChemInform Abstract: Photoreductive Defluorination of Perfluorinated Esters. Synthesis of Alkyl 2‐Hydro‐perfluoro Esters.
Authors: PORTELLA C. , IZNADEN M. 
Published: May 2016

AbstractPhotoinduced electron transfer from the excited phosphortriamide (HMPA) to the esters (I) leads to the selective reduction of the CF2 group adjacent to the ester group.
ChemInform Abstract: Aromatic Carbonylation Regiocontrolled by Oxazole and Isoxazole Rings. Novel Route to Heterocycle‐Substituted o‐Benzoates.
Authors: SAKAKIBARA T. , KUME T. , OHYABU T. , HASE T. 
Published: May 2016

AbstractThe oxazole (I) and the isoxazole (VIII) react with palladium acetate (II) to form the complexes (III) and (IX) which are coupled with methanol (IVa) and CO (V), producing regioselectively the benzoates (VIa) and (X) as the main products.
ChemInform Abstract: Preparation and Facile Cyclization of 5‐Alkyn‐1‐yllithiums.
Authors: BAILEY W. F. , OVASKA T. V. , LEIPERT T. K. 
Published: May 2016

AbstractThe ω‐iodoalkynes (I) are treated with tert‐butyllithium (II) to give the ω‐lithiated compounds (III).
ChemInform Abstract: Lewis Acid‐Mediated Intramolecular Ene Reactions of Alkylidenemalonates and 2‐Phosphonoacrylates: A Highly Diastereoselective Approach to trans‐1,2‐Disubstituted Five‐Membered Ring Compounds.
Authors: SARKAR T. K. , RAO P. S. V. S. 
Published: May 2016

AbstractThe 1,6‐dienecarboxylates (Ia), (Ib), or the phosphonates (Ic) and (Id) undergo cyclization and valence isomerization upon treatment with zinc dibromide to yield the trans‐1,2‐disubstituted cyclopentanes (II).
ChemInform Abstract: Chiral Organosilicon Compounds in Synthesis. Highly Enantioselective Synthesis of Arylcarbinols.
Authors: CHAN T. H. , PELLON P. 
Published: May 2016

AbstractThe chiral organosilicon compound (III) (yield not given) is used for the enantioselective synthesis of the arylcarbinols (VIII).
ChemInform Abstract: Derivatives of N‐(2‐Chloroethoxymethyl)anilides as Plant‐Growth Regulating Agents.
Authors: VENKOV A. , LUKANOV L. , MINKOV M. 
Published: May 2016

AbstractThe azomethines (I) react with the acyl chlorides (II), forming the adducts (III) which are treated with the epoxides (IV) to give the title compounds (V).
ChemInform Abstract: New General Synthesis of Sulfones from Alkyl or Aryl Halides and p‐Toluenesulfonic Hydrazide.
Authors: BALLINI R. , MARCANTONI E. , PETRINI M. 
Published: May 2016

AbstractThe utilization of commercially available tosylhydrazide (I) as a new nucleophilic reagent in displacement reactions with suitable halides such as (II) provides a general synthesis of sulfones such as (III) (13 examples).
ChemInform Abstract: Regio‐ and Stereoselective Functionalizations of the Wieland‐Miescher Ketone Derivatives at the C‐8 Position.
Authors: SHIMIZU T. , HIRANUMA S. , YOSHIOKA H. 
Published: May 2016

AbstractThe Wieland‐Miescher ketone acetal (I) is transformed into the thioether (IV) upon consecutive reaction with formaldehyde (II) and thiophenol (III).
ChemInform Abstract: Antiinflammatory Agents. Part 10. Synthesis and Antiinflammatory Activity of Some New 4‐(5‐Formyl(acyl)‐2‐furanoxy)phenylalkanoic Acid Esters.
Authors: SARMA C. R. , KRISHNA R. R. , SHRIDHAR D. R. , RAO C. S. , TANEJA V. 
Published: May 2016

AbstractThe compounds (III) with the exception of (IIId) (R2: ‐H) reveal moderate to fair antiinflammatory effects.
ChemInform Abstract: A Convenient Preparation of 2‐Carboxy‐ and 2‐Alkoxycarbonyl‐γ‐butyrolactones from Cyclopropane‐1,1‐dicarboxylic Acid.
Authors: RAO V. S. 
Published: May 2016

AbstractWhen cyclopropane‐1,1‐dicarboxylic acid (I) is treated with triethylamine (II), the diammonium salt (III) is formed.
ChemInform Abstract: Diels‐Alder Reactions of Pyrano(3,4‐b)indol‐3‐ones with Olefinic Compounds: Synthesis of 1,2‐Dihydrocarbazoles.
Authors: VAN DOREN P. , VANDERZANDE D. , TOPPET S. , HOORNAERT G. 
Published: May 2016

AbstractThe Diels‐Alder reaction of the title indole derivatives, e.g. (I) and (XII), yields 1,2‐dihydrocarbazoles.
ChemInform Abstract: Benzologous Reissert Compound Formation from 2‐Methylindazole.
Authors: UFF B. C. , HO Y.‐P. , POPP F. D. 
Published: May 2016

Abstract2‐Methylindazole (I) is treated with trimethylsilyl cyanide (II) and benzoyl chloride (IIIa) or the chloroformates (IIIb) and (IIIc) to produce the acyldihydroindazolecarbonitriles (IV).
ChemInform Abstract: A New Route to N‐Alkyl‐o‐phenylenediamines Utilizing N‐Alkyl‐2,1,3‐benzothiadiazolium Salts and Their Selenium Analogues.
Authors: RALPH J. T. 
Published: May 2016

AbstractThe N‐alkylbenzothiadiazolium salts (I) are cleaved upon treatment with water or aqueous sodium hydroxide, producing the N‐alkylated o‐phenylenediamines (II).
ChemInform Abstract: Synthesis of Isoxazolines and Isoxazoles from Aldoximes by the Use of Sodium Bromite with Organotin Halide.
Authors: MORIYA O. , NAKAMURA H. , KAGEYAMA T. , URATA Y. 
Published: May 2016

AbstractAnthracene‐9‐aldoxime (I) reacts with sodium bromite in the presence of tributyltin chloride to form the nitrile oxide (II) which undergoes 1,3‐dipolar cycloaddition reaction with methyl acrylate (III) to form the isoxazoline (IV) also obtained by an analogous one‐step procedure.
ChemInform Abstract: Synthesis of Some 1,2,4‐Triazolo(3,4‐b)(1,3,4)thiadiazoles as Potential Anthelmintics.
Authors: EL‐KHAWASS S. M. , KHALIL M. A. , HAZZAA A. A. B. , BASSIOUNY H. A. , LOUTFY N. F. 
Published: May 2016

AbstractThe title compounds (VIII), (IX), and (XI) are synthesized as shown in the reaction scheme.
ChemInform Abstract: Stereoselective Syntheses of S‐Phenyl Tetrahydrofuran‐2‐thiocarboxylate and Tetrahydropyran‐2‐thiocarboxylate Derivatives Using (Phenylthio)nitromethane.
Authors: BARRETT A. G. M. , FLYGARE J. A. , SPILLING C. D. 
Published: May 2016

AbstractThe aldehydes (I) are coupled with the nitromethane (II) and subsequently dehydrated to yield the nitromethylene derivatives (III).
ChemInform Abstract: Novel Synthesis of Polyfunctionally‐Substituted Pyridines and Pyrimidines.
Authors: ELGHANDOUR A. H. H. , RAMIZ M. M. M. , ELNAGDI M. H. 
Published: May 2016

AbstractBenzoylacetonitrile (I) is transformed into the imidate (III) which is used as a building block in the formation of the pyridine (V) from the alkylidenemalononitriles (IV), of the pyrimidines (VII) via reaction with the acyl isothiocyanates (VI), and of the thiazoline (IX) from mercaptoacetic acid (VIII).
ChemInform Abstract: Synthesis of Tricyclic Compounds with Thiopyridone Rings.
Authors: HASSAN K. M. , EL‐NAGGAR G. M. , EL‐KHAWAGA A. M. , EL‐DEAN A. M. K. 
Published: May 2016

AbstractThe fused thiopyranthione (III), prepared from the cyanoacetate (I) and carbon disulfide (II), is coupled with hydrazine (IV) to produce the thiopyridone (V).
ChemInform Abstract: Linear and Proximal Benzo‐Separated Alkylated Xanthines as Adenosine‐Receptor Antagonists.
Authors: SCHNELLER S. W. , IBAY A. C. , CHRIST W. J. , BRUNS R. F. 
Published: May 2016

AbstractDialkylation of the 7‐chloro‐6‐nitroquinazolinedione (I) with ethyl iodide (II) gives the derivative (III) which is treated with ammonia (IV) and subjected to catalytic hydrogenation, forming the diamine (VI).
ChemInform Abstract: Practical Syntheses of Optically Pure 1‐ and 3‐Substituted Dihydroorotic Acids.
Authors: SUZUKI M. , MAEDA H. , KONDO K. , SUGANO H. , MATSUMOTO K. 
Published: May 2016

AbstractThe dihydroorotic acid (S)‐(I) is converted to the benzyl ester (S)‐(III) which is alkylated with the halides (IV) to give the 3‐substituted dihydroorotic acids (V) after deprotection.
ChemInform Abstract: Chloroplatinic Acid Catalyzed Cyclization of Silanes Bearing Pendant Acetylenic Groups.
Authors: STEINMETZ M. G. , UDAYAKUMAR B. S. 
Published: May 2016

AbstractThe intramolecular title reaction of the disilanes (I) under high dilution conditions proceeds via syn addition of the Si‐H group to the C‐C triple bond to give, predominantly, cyclic products, having an exocyclic rather than an endocyclic double bond.
ChemInform Abstract: Reaction of Boron Halides with Trialkylstannyltrialkylsilylacetic Acid Esters.
Authors: NIKOLAEVA S. N. , ZOLOTAREVA A. S. , PONOMAREV S. V. , GRISHIN YU. K. 
Published: May 2016

AbstractThe title compounds (III), prepared from the methoxystannane (I) and the ketenes (II), are coupled with the diaminobromoborane (IV) to give the ketene acetals (V).
ChemInform Abstract: Antiviral Activity of N‐Phosphorylated Amides, Thioamides, and Their Salts.
Authors: ZABIROV N. G. , POZDEEV O. K. , SHAMSEVALEEV F. M. , CHERKASOV R. A. , GIL'MANOVA G. KH. 
Published: May 2016

AbstractReaction of thioacetamide (I) with the chlorothiophosphate (II) gives the N‐thiophosphorylthioacetamide (III).
ChemInform Abstract: Facile Stereoselective Synthesis of 2H‐1,2,3‐Diazaphosphole Spirophosphorane Derivatives.
Authors: BACCOLINI G. , DALPOZZO R. , MEZZINA E. 
Published: May 2016

AbstractThe phenylazostilbene (IV) reacts with the dichlorophosphine (V), forming the cyclic adduct (VI).
ChemInform Abstract: Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 92. Synthesis of Alkynylmethylidyne‐Molybdenum and ‐Tungsten Complexes and Their Reactions with (Co2(CO)8) and (Mo2(CO)6(η‐C5H5)2).
Authors: HART I. J. , HILL A. F. , STONE F. G. A. 
Published: May 2016

AbstractThe mononuclear metal‐alkylidyne compounds (V) are prepared as demonstrated for the examples (Va) and (Vb).
ChemInform Abstract: Chemistry of Polyfunctional Molecules. Part 105. Chromium‐, Molybdenum‐ and Tungstentricarbonyl Complexes of Bis(2‐diphenylphosphinoethyl)amine.
Authors: ELLERMANN J. , MOLL M. , WILL N. 
Published: May 2016

AbstractThe fac‐complexes (I) react with (II) to give the title compounds fac‐(III) together with the mer‐isomer (IV) in the case of (IIIa).
ChemInform Abstract: Dithiazolium Salts of Halometalates. Synthesis and Structure of 3‐Diethylamino‐5‐phenyl‐1,2,4‐dithiazolium‐tetrachloroniccolate(II).
Authors: KOEHLER R. + , SIELER J. , RICHTER R. , HOYER E. , BEYER L. , MAARTMANN‐MOE K. 
Published: May 2016

AbstractChlorination of the coordinated thiourea derivative in (I) yields the title compound (II) (C2/c, Z=4), which can be reduced to give (III).
ChemInform Abstract: Synthesis of 8‐Demethyl‐8‐formyl Protoporphyrin IX and of 8‐Demethyl Protoporphyrin IX.
Authors: SAMBROTTA L. , REZZANO I. , BULDAIN G. , FRYDMAN B. 
Published: May 2016

AbstractOxidative cyclization of the a,c‐biladiene dihydrobromide (I), which is constructed by a usual method, leads to the 8‐unsubstituted porphyrin (IVa) and its formyl derivative (IVb).
ChemInform Abstract: Structure and Properties of Long‐Wavelength‐Transmitting Halide Glasses.
Authors: ALMEIDA R. M. , SANTOS L. F. 
Published: May 2016

AbstractA series of ZnX2‐based (X: Cl, Br, I) glasses containing KCl and/or KBr and/or KI as modifiers are prepared and characterized by DSC, FTIR and polarized Raman spectroscopy.
ChemInform Abstract: Doping of Pb Ions into Bi‐Sr‐Ca‐Cu‐O Thin Films from PbO Vapor.
Authors: NAGATA H. , HASHIGUCHI S. , MIN E. 
Published: May 2016

AbstractIt is demonstrated that a thin film with zero resistivity at 103 K can be prepared by annealing a Bi‐Sr‐Ca‐Cu‐O film (multilayered film with total composition of Bi2.4Sr2.0Ca1.8Cu2.8Ox) in PbO vapor.
ChemInform Abstract: Solid Solution in the LiAlO2‐LiCrO2 Ternary Oxide System.
Authors: POEPPELMEIER K. R. , THONG S. H. 
Published: May 2016

AbstractSolid solutions of LiAlxCr1‐xO2 are synthesized over the whole composition range (0 ≤ x ≤ 1.0) by reaction of Li2CO3, boehmite (Al(OOH)), and Cr2O3 at ∼600 °C (2‐5 d) and subsequent heating at 700‐1000 °C. The Al‐rich phases (x > 0.6) are obtained for the first time.
ChemInform Abstract: Behavior of Cyclopropanes Bearing Captodative Substitution Upon Electron‐Impact and Flash Vacuum Pyrolysis Conditions.
Authors: CHEN L.‐Z. , FLAMMANG R. , MAQUESTIAU A. , MASAMBA W. , MERENYI R. , POMMELET J.‐C. , VIEHE H.‐G. 
Published: May 2016

AbstractThe behavior of the cyclopropanes (I) is observed by tandem mass spectrometry.
ChemInform Abstract: A Chiral Ag(I) Coordination Polymer with a Polydentate Chiral Ligand; Crystal Structure of the 1:1 Complex of CF3SO3Ag and N‐(N‐(5‐Methylthenylidene)‐L‐methionyl)histamine.
Authors: MODDER J. F. , VAN KOTEN G. , VRIEZE K. , SPEK A. L. 
Published: May 2016

AbstractA better understanding of the structure of the Cu‐N2S2 chromophores in blue copper proteins may emerge from the title complex obtained in the reaction with a potential N,N',S,S' donor system.
ChemInform Abstract: Asymmetric Synthesis of Tertiary Alcohols from α‐Halo Boronic Esters.
Authors: MATTESON D. S. , HURST G. D. 
Published: May 2016

AbstractReaction of pinanediol boronates such as (I) with the Li species (II), generated in situ at ‐78 °C, followed by rearrangement of the resulting borate complexes, e.g. (III), in the presence of ZnCl2 leads to chirally biased insertion of the dichloroethyl group into the carbon‐boron bond (e.g.
ChemInform Abstract: Chiral Sulfur Compounds. Part 10. Conjugate Addition of Amines to (Rs)‐10‐Isobornyl Vinyl Sulfoxides.
Authors: PYNE S. G. , BLOEM P. , GRIFFITH R. 
Published: May 2016

AbstractThe optically active sulfoxides (I) are prepared by stereoselective MCPBA oxidation of the corresponding sulfides and subjected to conjugate addition with benzylamine (II).
ChemInform Abstract: Thermally Generated Benzanellated Trimethylenemethane Biradicals of the 2‐Methylenecyclohexene‐1,3‐diyl Series Escape Capture by a New Rearrangement to Benzanellated Bicyclo(3.2.0)hept‐1‐enes.
Authors: OSTERMAN V. M. , SCHULTE G. , BERSON J. A. 
Published: May 2016

AbstractThe thermal rearrangement of the benzanellated compounds (I) and (VII) is studied in an attempt to stabilize the intermediate trimethylenemethanes of type (VIII) and to avoid otherwise running rearrangements of these diyls preventing their intermolecular interception.
ChemInform Abstract: Vinyl Radical Rearrangements. ESR Evidence for the Formation of Enol Radical Cations by the Protonation at Carbon of β‐Hydroxyvinyl Radicals and for a 1,4‐Hydrogen Shift in Some β‐Sulfur‐Substituted Analogues.
Authors: GILBERT B. C. , WHITWOOD A. C. 
Published: May 2016

AbstractRadicals are generated by the reaction of ·OH (from Ti(III) + H2O2) and some hydroxyalkyl‐substituted alkynes, e.g. (I).
ChemInform Abstract: Stereo‐ and Enantioselectivity in Catalytic Hydrogenolysis of Chiral Substituted Ferrocenes to Give Cyclopentanes.
Authors: SOKOLOV V. I. , TROITSKAYA L. L. , KHRUSHCHEVA N. S. , REUTOV O. A. 
Published: May 2016

AbstractThe catalytic hydrogenolysis of 1,2‐disubstituted ferrocenes such as (I) or (IV) proceeds under mild conditions in TFA to give stereoselectively the trans‐cyclopentanes (II), (VI) and (VII) as main products.
ChemInform Abstract: Nickel(0)‐Catalyzed Dimerization of 1,2,3‐Cycloheptatriene: Cyclobuta(1,2:3,4)dicycloheptatetraene, a (4)Radialene Derivative.
Authors: HASHMI S. , POLBORN K. , SZEIMIES G. 
Published: May 2016

AbstractAn optimum yield of the air‐sensitive title compound (III) (space group P21/c; Z=2) is obtained under the conditions shown.