bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Isolation and Structure Elucidation of 36 Diterpenoids from Leaf‐Glands of Plectranthus edulis (Vatke) T.T. Aye.
Authors: KUENZLE J. M. + , RUEEDI P. + , EUGSTER C. H. 
Published: May 2016

AbstractA series of minor components, i.e. 6 different royleanones (e.g.
ChemInform Abstract: Regiospecific Ene Reaction of Benzenesulfinyl Chloride with Linear Isoprenoids.
Authors: MOISEENKOV A. M. , DRAGAN V. A. , KOPTENKOVA V. A. , VESELOVSKY V. V. 
Published: May 2016

AbstractThe allylic sulfoxides (III) are obtained by zinc chloride‐catalyzed ene reaction of benzenesulfinyl chloride (II) with myrcene (Ia), geranyl (Ib), and neryl acetates (Ic) or ethyl farnesoate (Id).
ChemInform Abstract: 19‐Norsteroids from Cholesterol and Diosgenin and Aromatization of Ring‐A.
Authors: SENGUPTA P. , SEN M. , SARKAR A. , DAS S. 
Published: May 2016

AbstractThe 19‐hydroxycholestene derivative (I) and the 19‐hydroxydiosgenin derivative (VI) are subjected to reaction conditions A) giving the products shown in the scheme.
ChemInform Abstract: Stereocontrolled Route to 3‐Amino‐2,3,6‐trideoxy‐hexopyranoses. K‐10 Montmorillonite as a Glycosidation Reagent for Acosaminide Synthesis.
Authors: FLORENT J.‐C. , MONNERET C. 
Published: May 2016

AbstractThe 1‐O‐acetyl hexose (VI), prepared from di‐O‐acetyl‐L‐rhamnal (I) by hydrolysis, addition of hydrazoic acid, and subsequent acetylation, reacts with the alcohols (VII) to give stereoselectively the glycosides (VIII).
ChemInform Abstract: Cyclic Monothioacetals of Aldoses: Synthesis and Desulfuration of 2‐Polyacetoxyalkyl‐1,3‐oxathiolan‐5‐ones and ‐3,1‐benzoxathian‐4‐ones.
Authors: SOMOGYI L. 
Published: May 2016

AbstractThe acetylated aldoses (I) react with mercaptoacetic acid or 2‐mercaptobenzoic acid (II) to give the oxathiolanone (IIIa) or the benzoxathianone (IIIb).
ChemInform Abstract: Carbene Ligands as Anthracyclinone Synthons. Part 5. Anthracylinone C‐Ring Synthesis via Chelate‐Carbene Complexes.
Authors: DOETZ K. H. + , POPALL M. 
Published: May 2016

AbstractThe chromium complex (I) is converted to the diketone (VII); the key step being the chromium‐induced anellation of the complex (II) to the alkyne (III).
ChemInform Abstract: Effect of Heating Rate on the Microstructural Evolution During Sintering of BaTiO3 Ceramics.
Authors: YOO Y.‐S. , KIM J.‐J. , KIM D.‐Y. 
Published: May 2016

AbstractThe microstructural evolution during sintering of BaTiO3 powder containing small amounts of unreacted TiO2 depends critically on the heating rate.
ChemInform Abstract: 1,3‐Dipolar Cycloaddition of 2‐Diazopropane to Coumarin. The Synthesis of Derivatives of (1)Benzopyrano(4,3‐c)pyrazol‐4(3H)‐one and (1)Benzopyrano(3,4‐c)pyrazol‐4(1H)‐one.
Authors: CERCEK A. , STANOVNIK B. , STIMAC A. , TISLER M. 
Published: May 2016

AbstractCoumarin (I) and 2‐diazopropane (II) give the cycloaddition products (III) and (IV).
ChemInform Abstract: Oxepines from Pyrylium Salts and Diazo Esters. Cycloaddition Behavior Toward 4‐Phenyl‐1,2,4‐triazoline‐3,5‐dione.
Authors: HOFFMANN K.‐L. , MAAS G. , REGITZ M. 
Published: May 2016

AbstractThe pyrylium salts (I) react with the diazoacetate or diazomethylphosphonate (II), yielding the diazoalkyl‐4H‐pyrans (III).
ChemInform Abstract: Chromium(III) Interactions with Nucleotides. Part 3.
Authors: CALAFAT A. M. , MULET D. , FIOL J. J. , TERRON A. , MORENO V. 
Published: May 2016

AbstractThe new derivatives (V)‐(XI) of Cr(III) are obtained by reaction of cis‐ or trans‐(CrCl2(en)2)Cl with the nucleotides (I)‐(IV) as their disodium salts in water (no yields given).
ChemInform Abstract: Rhodium Alkoxide Complexes: Formation of an Unusually Strong Intermolecular Hydrogen Bond in (PMe3)3Rh‐Otol(HOtol).
Authors: KEGLEY S. E. , SCHAVERIEN C. J. , FREUDENBERGER J. H. , BERGMAN R. G. , NOLAN S. P. , HOFF C. D. 
Published: May 2016

AbstractTreatment of (I) with 2 equiv. of (II) or reaction of (III) with one equiv. leads to the formation of the hydrogen‐bonded species (VI).
ChemInform Abstract: Magnetic Field Effects on Electrolysis. Part 2. Anodic Surface Oxidation of Gold.
Authors: WATANABE T. , TANIMOTO Y. , NAKAGAKI R. , HIRAMATSU M. , SAKATA T. , NAGAKURA S. 
Published: May 2016

AbstractA black deposit, formed at the electrode surface during anodic oxidation of Au in acidic solution, is shown to dissolve immediately after application of an external magnetic field (1 T).
ChemInform Abstract: Structure and Oligomerization of Tetrakis(dithioheptanoato)diplatinum.
Authors: KAWAMURA T. , OGAWA T. , YAMABE T. , MASUDA H. , TAGA T. 
Published: May 2016

AbstractThe dinuclear title complex (III), prepared as shown, crystallizes in the space group C2/c with Z=4.
ChemInform Abstract: Catalytic Asymmetric Syntheses. Part 2. Hydrogenation of α,β‐Unsaturated Ketones Using Chiral Ruthenium Complexes.
Authors: MASSONNEAU V. , LE MAUX P. , SIMONNEAUX G. 
Published: May 2016

AbstractThe cyclic enones (I) are hydrogenated in the presence of a chiral ruthenium catalyst to produce the optically active saturated ketones (II), together with minor amounts of the cycloalkanols (III).
ChemInform Abstract: Flash Vacuum Pyrolysis of 3‐tert‐Butylindeno(1,2‐c)isoxazol‐4‐one. Formation of 2‐Carbonyl‐1,3‐indandione 2‐Azine.
Authors: PEREZ J. D. , WUNDERLIN D. A. , LEMKE T. L. , SAWHNEY K. N. 
Published: May 2016

AbstractFlash vacuum pyrolysis of the indenoisoxazolone (I) yields the spiroazirine (II) as the primary product which undergoes further rearrangement, yielding the azine (III) and the oxazole derivative (IV).
ChemInform Abstract: Synthesis and Structure of Dithioester‐Stabilized Pyridinium Ylides.
Authors: ALVAREZ‐BUILLA J. , GALVEZ E. , CUADRO A. M. , FLORENCIO F. , BLANCO S. G. 
Published: May 2016

AbstractThe pyridines (I) are N‐alkylated to give the pyridinium salts (III) which react with potassium carbonate, carbon disulfide (V), and methyl iodide (VI) to give the dithioester‐stabilized pyridinium ylides (VII).
ChemInform Abstract: 1,4‐Benzodioxins 2,3‐Disubstituted with Pharmacological Active Groups.
Authors: COUDERT G. , BORREDON‐WATRIN C. , GUILLAUMET G. 
Published: May 2016

Abstract1,4‐Benzodioxin‐2‐carboxylic acid (Ia) is converted to the amide (Ib) which is formylated to produce the aldehyde (V).
ChemInform Abstract: Heterocycles. Part 12. Synthesis of New Benzo(6,7)cyclohepta(1,2‐d)pyrimidines.
Authors: EL‐RAYYES N. R. , RAMADAN H. M. 
Published: May 2016

AbstractThe 2‐arylidene‐1‐benzosuberones (I) react with guanidine (II), forming the pyrimidine derivatives (III) and the dihydropyrimidines (IV).
ChemInform Abstract: Synthesis and Properties of Some Hexahydropyrimidin‐6‐one(2,3‐f)theophyllines.
Authors: PAWLOWSKI M. 
Published: May 2016

AbstractCoupling of the 8‐bromotheophylline derivative (I) with ethyl acrylate (II) yields the ester (III) which is transformed into the lactam (V) by substitution with benzylamine (IV) and subsequent ring closure.
ChemInform Abstract: Thermolysis of Arylhaloboranes. Synthesis of 1,3‐Dibora‐ and 1,3‐Borasilaindans.
Authors: SCHACHT W. , KAUFMANN D. 
Published: May 2016

AbstractThermolysis of the 2‐silylphenyldihaloboranes (If) and (Ig) in solution results in desilylation and dimerization, yielding the diboraanthracenes (II), whereas the derivatives (Ia) ‐ (Ie) are stable at temperatures up to 200°C. Flash vacuum pyrolysis of the compounds (Ia), (Ib), (Id), and (If) produces the borasilaindans (III).
ChemInform Abstract: Umpolung in Allylic Phosphonates. Regio‐ and Stereoselective Synthesis of (E)‐γ‐Amino‐α,β‐unsaturated Phosphonates by Palladium‐Catalyzed Reaction of Allylic Acetoxy Phosphonates.
Authors: ZHU J. , LU X. 
Published: May 2016

AbstractThe α‐acetoxyallylphosphonates (I) are coupled with the amines (II) in the presence of a palladium(0) catalyst to give the aminopropenylphosphonates (III).
ChemInform Abstract: Synthesis and Flash Thermolysis of α‐Tributylstannyl Esters.
Authors: DUBOUDIN J. G. , RATIER M. , TROUVE B. 
Published: May 2016

AbstractThe ketones (I) are transformed into the α‐stannyl thiocarbonates (IV), the α‐acetoxystannanes (VI), or the imidazolylcarboxylates (VIII) as shown in the reaction scheme.
ChemInform Abstract: Molecular and Electronic Structure of Six‐Coordinate Low‐Spin Oxo‐Bridged Dimers Formed by the Interaction of (μ‐Oxo)bis((phthalocyaninato)iron(III)) with Nitrogen Bases.
Authors: ERCOLANI C. , GARDINI M. , MURRAY K. S. , PENNESI G. , ROSSI G. , ZWACK P. R. 
Published: May 2016

AbstractCrystalline, stable complexes (I) are prepared by interaction of μ‐oxo‐bis(phthalocyaninato)iron(III) with vapors of liquid or liquid N‐bases (yields partially given in g).
ChemInform Abstract: A Molecular Water‐Oxidation Catalyst Derived from Ruthenium Diaqua Bis(2,2′‐bipyridyl‐5,5′‐dicarboxylic acid).
Authors: ROTZINGER F. P. , MUNAVALLI S. , COMTE P. , HURST J. K. , GRAETZEL M. + , PERN F.‐J. , FRANK A. J. 
Published: May 2016

AbstractControlled‐potential electrolysis of the complex (I) in H2SO4 solutions leads to the formation of a relatively durable and active molecular water‐oxidation catalyst.
ChemInform Abstract: Studies at the Chemometrics ‐ Physical Organic Chemistry Interface. Part 4. Linear Solvation Energy Relationships. Local Empirical Rules ‐ or Fundamental Laws of Chemistry? The Dialogue Continues. A Challenge to the Chemometricians.
Authors: KAMLET M. J. , DOHERTY R. M. , FAMINI G. R. , TAFT R. W. 
Published: May 2016

AbstractPhysical Organic Chemistry Interface.
ChemInform Abstract: A Study of Allylboronates as Substrates in Palladium‐Mediated Arylation.
Authors: NILSSON K. , HALLBERG A. 
Published: May 2016

AbstractThe palladium‐catalyzed arylation of the dioxaborolane (II) yields complex mixtures of the products (III)‐(VI); the product ratios are dependent on the reagents used.
ChemInform Abstract: tert‐Butyldimethylsilyl Ethers of Phenols: Their One‐Step Conversion to Benzyl or Methyl Ethers and Utility in Regioselective ortho Lithiation.
Authors: SINHABABU A. K. , KAWASE M. , BORCHARDT R. T. 
Published: May 2016

AbstractThe silyl phenol ethers (I), (IV), and (VIa) are allowed to react with the alkyl halides (II) in the presence of potassium fluoride to produce the corresponding methyl or benzyl ethers (III), (V), or (VIb).
ChemInform Abstract: Configurational Properties and Chemical Reactivity of Mono and Dianions Derived from Aryl 2‐Alkoxyvinyl Sulfones.
Authors: MCCOMBIE S. W. , SHANKAR B. B. , GANGULY A. K. , PADWA A. , BULLOCK W. H. , DYSZLEWSKI A. D. 
Published: May 2016

AbstractThe E‐alkoxyvinyl sulfone (I) is deprotonated and then coupled with the electrophiles (II) to form the enol ether (IV) after desulfonation.
ChemInform Abstract: Stereocontrolled (m + n) Annulation Reactions. Part 3. A Convenient Approach to Seven‐ and Eight‐Membered Carbocycles by a Novel Annulation Process.
Authors: MOLANDER G. A. , SHUBERT D. C. 
Published: May 2016

AbstractReaction of the allylstannane generated from (I) with the dicarbonyls (II) yields the carbocycles (III).
ChemInform Abstract: Reactions of 4‐Chloro‐1‐nitrobenzene with o‐Substituted Phenylacetonitriles; Synthesis of 8‐Chloro‐1‐methyl(and methylthiomethyl)‐6‐(2‐substituted phenyl)‐4H‐s‐triazolo(4,3‐a)‐1,4‐benzodiazepines.
Authors: VEJDELEK Z. , HOLUBEK J. , RYSKA M. , KORUNA I. , SVATEK E. , BUDESINSKY M. , PROTIVA M. 
Published: May 2016

AbstractThe title reaction of compound (I) with the nitriles (II), (VI) and (IX) yields the benzisoxazoles (III), which are transformed to the title compounds (XVI).
ChemInform Abstract: Dioxygen‐Copper Reactivity: X‐Ray Structure and Characterization of an (Acylperoxo)dicopper Complex.
Authors: GHOSH P. , TYEKLAR Z. , KARLIN K. D. , JACOBSON R. R. , ZUBIETA J. 
Published: May 2016

AbstractA stable and crystalline analogue of a hydroperoxo complex, obtained by protonation of the peroxo complex (IV), is represented by the acylperoxo complex (III), which is best prepared as shown from (I).
ChemInform Abstract: Photo‐Oxidation of Cu(I) at n‐InP in Concentrated Chloride.
Authors: SCHNEEMEYER L. F. , ROSAMILIA J. M. , MILLER B. 
Published: May 2016

AbstractBecause the use of highly concentrated electrolytes can lead to a remarkable stabilization of n‐type semiconductor photoanodes, the oxidation of Cu(I) to Cu(II) at n‐InP has been studied in saturated (> 5 M) CaCl2 solution.
ChemInform Abstract: Preparation and Characterization of High‐Tc Oxides: YBa2Cu3O7 and REBa2Cu3O7.
Authors: CONROY L. E. , CHRISTENSEN A. N. , BOETTIGER J. 
Published: May 2016

AbstractThe title oxides (RE: Nd, Gd, Ho, Yb), prepared by conventional solid state procedures at 950 °C starting from Y2O3(RE2O3), BaCO3, and CuO, crystallize in the orthorhombic YBa2Cu3O7 structure.
ChemInform Abstract: Investigations of Iodoferrates: The Crystal Structures of Fe(THF)6(FeI3THF)2·THF and Fe(CH2O)6(FeI4)2·I2 (THF: C4H8O).
Authors: SAAK W. , POHL S. 
Published: May 2016

Abstract(I) crystallizes in the space group Pa3 with Z=4 and (II) in P21/n with Z=2.
ChemInform Abstract: The Mechanism of Fluxionality of (Ru(η6‐C8H8)(η4‐C7H8)), (Ru(η4‐C8H8)(η4‐C7H8)L) (L: PEt3 or P(OMe)3), and (Os(η6‐C8H8)(η4‐C8H12)) (C8H8: Cyclooctatetraene, C7H8: Norborna‐2,5‐diene, and C8H12: Cyclo‐octa‐1,5‐diene).
Authors: GRASSI M. , MANN B. E. , PICKUP B. T. , SPENCER C. M. 
Published: May 2016

AbstractThe Mechanism of Fluxionality of [Ru(n°‐C3H8)(n"‐C‐,H3)], [Ru(n"‐C8Hs)(n"‐C7H3)LlIL: PEt3 or P(OMe)3l, and [Os(n°‐C3H8)(n"‐C8H,2)l (C8H3: Cyclooctatetraene, C‐,H3:Norborna‐2,5‐diene, and C3H,2: Cyclo‐octa‐1,5‐diene).
ChemInform Abstract: Cooperative (2 + 2 + 2) Cycloaddition Reactions in Polyquadricyclanylidene(n)rotanes. Model Studies in Tris‐spiro(C7H6) Systems.
Authors: TRAH S. , WEIDMANN K. , FRITZ H. , PRINZBACH H. 
Published: May 2016

AbstractThe synthesis of the tris(quadricyclanylidene)cyclopentanedione (I) and related compounds and their conversions are described in the original paper.
ChemInform Abstract: Photochemistry of Methyl Cyclobutyl Ketone. Part 2. Temperature Dependence and the Acetyl Radical Decomposition.
Authors: BALDWIN P. J. , CANOSA‐MAS C. E. , FREY H. M. , WALSH R. 
Published: May 2016

AbstractGaseous mixtures of (I) diluted in argon are photolyzed at temp. up to 205 °C, at pressures up to ca. 2 atm, at wavelengths of 313 nm (steady state conditions) and 308 nm (pulsed photolysis).
ChemInform Abstract: Properties of Hydrogen Bonds in 5,8‐Dihydroxy‐1,4‐naphthoquinone (Ia) and 1,4‐Dihydroxy‐9,10‐anthraquinone (IIa): Reaction with Bases in Aqueous Solution.
Authors: HIBBERT F. , SPIERS K. J. 
Published: May 2016

AbstractRate coefficients and equilibrium constants for the dissociation of (Ia) (pK10 8.51; pK20 11.49) and (IIa) (pK10 9.85; pK20 12.28) are measured in aqueous solution.
ChemInform Abstract: Synthesis of Linear Aliphatic Compounds. Part 2. The Realization of a Strategy for Repeated Molecular Doubling.
Authors: IGNER E. , PAYNTER O. I. , SIMMONDS D. J. , WHITING M. C. 
Published: May 2016

AbstractRoutes from C11 and C12 starting materials, obtainable free from near homologues, to compounds of doubled chain length are explored as approaches to the synthesis of n‐paraffins and of terminally mono‐ or bifunctional derivatives.
ChemInform Abstract: Synthesis of Linear Aliphatic Compounds. Part 4. An Approach to Long‐Chain Paraffins with Lateral Side‐Chains.
Authors: ADEGOKE E. A. , EPHRAIM‐BASSEY H. , KELLY D. J. , WHITING M. C. 
Published: May 2016

AbstractThe ketone (I) reacts with the Grignard reagent (II) to give the alcohol (III) (yield in g), which undergoes either dehydration to yield the unsaturated acetal (IV) or hydrolysis on silica gel followed by Wittig reaction and reduction to yield the C40 and C52 bromo acetals (VI).
ChemInform Abstract: Synthesis of Novel α‐Amino Acids and Derivatives Using Radical Chemistry: Synthesis of L‐ and D‐α‐Amino‐adipic Acids, L‐α‐Aminopimelic Acid and Appropriate Unsaturated Derivatives.
Authors: BARTON D. H. R. , HERVE Y. , POTIER P. , THIERRY J. 
Published: May 2016

AbstractRadicals generated by photolysis of suitably protected amino acid derivatives such as (Ib) add efficiently to activated olefins such as (II) to afford adducts such as (III).
ChemInform Abstract: Synthesis and Antimicrobial Activity of Cationic Surfactants Based on Aminoacetylenic Fatty Acid Esters.
Authors: ERGASHEV M. S. , MAKHSUMOV A. G. , IL'KHAMDZHANOV P. 
Published: May 2016

AbstractAminomethylation of the fatty acid propargyl esters (I) gives the dimethylaminobutynyl esters (IV).
ChemInform Abstract: Organic Reactions at High Pressure. Wittig Reaction of Hindered Ketones with Nonstabilized Ylides.
Authors: DAUBEN W. G. , TAKASUGI J. J. 
Published: May 2016

AbstractWittig olefination of the substituted cyclohexanones (I) with butylidenetriphenylphosphorane (II) is performed at atmospheric and elevated pressure.
ChemInform Abstract: Novel Two‐Step Synthesis of Homobarrelenones, Bicyclo(3.2.2)nona‐3,6,8‐ trien‐2‐ones, from Tropones, and 2,3‐Bis(methoxycarbonyl)‐7‐oxabicyclo‐(2.2.1)heptadiene by High‐Pressure Cycloaddition‐Thermal Cycloreversion Procedure.
Authors: TIAN G. R. , SUGIYAMA S. , MORI A. , TAKESHITA H. 
Published: May 2016

AbstractDiels‐Alder reaction of the tropone derivatives (I) with the oxabicycloheptadienedicarboxylates (II) yields the isomeric adducts (III) ‐ (V).
ChemInform Abstract: Formation of Adamantylideneadamantane‐1,2‐dioxetane via Photoinitiated Electron Transfer Under the Participation of Tetracyanoethylene.
Authors: VOLOSHIN A. I. , SHARIPOV G. L. , KAZAKOV V. P. , TOLSTIKOV G. A. 
Published: May 2016

AbstractIrradiation of adamantylideneadamantane (I) in the presence of oxygen and tetracyanoethylene gives the oxetane (II) and adamantanone (III).
ChemInform Abstract: Stereocontrolled Intramolecular Ketone‐Olefin Reductive Coupling Reactions Promoted by Samarium Diiodide.
Authors: MOLANDER G. A. , KENNY C. 
Published: May 2016

AbstractThe unsaturated β‐keto esters and β‐keto amides (I) undergo stereoselective samarium diiodide‐induced cyclization to form the 2‐hydroxycyclopentanecarboxylic acid derivatives (V).
ChemInform Abstract: Synthesis and Antimicrobial Properties of Derivatives of Bis(5‐indolyl)methane and Bis(5‐indolyl) Oxide.
Authors: SAMSONIYA SH. A. , LOMTATIDZE Z. SH. , OVSYANNIKOVA N. N. , SUVOROV N. N. 
Published: May 2016

AbstractIn order to investigate gramine‐related active compounds, the bis(dimethylaminomethyl) compounds (IV) and (VII) are prepared from the bis(indolylcarboxylic acid) derivatives (I) and (V).
ChemInform Abstract: Synthesis of 4‐Hetero‐Substituted Pyranosides via Dioxenium Cation‐Olefin Cyclization.
Authors: PERRON F. , ALBIZATI K. F. 
Published: May 2016

AbstractTreatment of the orthoesters (I) with a Lewis acid gives dioxenium cation salts as intermediates.
ChemInform Abstract: Synthesis and Biological Properties of Imidazo(1,2‐f)purine Derivatives.
Authors: GARMASH S. N. , PRIIMENKO B. A. , SAMURA B. A. , KLYUEV N. A. , KOVAL' N. V. 
Published: May 2016

AbstractThe imidazopurine (I) is brominated in the 3‐position with bromine and NBS respectively to give the hydrobromide (II) or its free base (III).
ChemInform Abstract: Stereochemical Studies. Part 105. Saturated Heterocycles. Part 109. Synthesis and Steric Structures of Perhydro‐4,1‐benzoxazepin‐2‐ones.
Authors: BERNATH G. , FUELOEP F. + , SOHAR P. 
Published: May 2016

AbstractRing closure of amino alcohols (II) with chloro esters (I) yields the title compounds (III), (IV), and (V), resp. (pure (Vb) cannot be separated).
ChemInform Abstract: Preparation of New Polycyclic Methylated Silanes.
Authors: MITTER F. K. , HENGGE E. 
Published: May 2016

AbstractThe methylated polycyclic silanes (III), (V), and (VII) are prepared by reaction of undecamethylcyclohexasilanyl potassium (I) with the halosilanes (II), (IV), and (VI).
ChemInform Abstract: Reaction of the Two‐Component System Trialkylphosphite/Carbon Tetrachloride with Nucleophiles. Part 3. Reaction in the Presence of Trialkylammonium Salts.
Authors: ALBRECHT S. , HERRMANN E. , JOHN A. 
Published: May 2016

AbstractThe two component system trialkylphosphite (I)/CCl4 (II) affords in the presence of trialkylammonium iodides (III) the dialkyl phosphoryl chlorides (IV).
ChemInform Abstract: New Results on the Reaction of Trialkyl Trithiophosphites with Alkyl Halides.
Authors: KABACHNIK M. I. , PUDOVIK A. N. , BATYEVA E. S. , AL'FONSOV V. A. , ZAMALETDINOVA G. U. 
Published: May 2016

AbstractReaction of triethyl trithiophosphite (I) with the alkyl halides (II) gives the trithiophosphonates (III), together with small amounts of the sulfonium halides (IV).
ChemInform Abstract: Stereoselective Formation of Tetrahydrofuran and ‐pyran by Benzeneselenenyl Triflate.
Authors: MURATA S. , SUZUKI T. 
Published: May 2016

AbstractThe stereoisomeric 2‐allylcyclohexanols (I) undergo cyclization in the presence of phenylselenenyl triflate (II), forming the phenylselenenylmethylperhydrobenzofurans (III).
ChemInform Abstract: Synthesis and Structure of the First Cyclophosphazene Containing a Metal‐Metal Bond Within the Ring Skeleton.
Authors: HERBST R. , KATTI K. V. , ROESKY H. W. , SHELDRICK G. M. 
Published: May 2016

AbstractThe equimolar reaction of (I) with the hexachloride (II) results in the formation of the known cyclotungstaphosphazene (II) and the W‐W compound (IV).
ChemInform Abstract: Metallo‐Ligands Containing Terminal Oxygen Donors Bonded to a Manganese‐Carbonyl Moiety.
Authors: MASON M. , KANG D.‐X. , CIHON I. , KINTZ A. , BLINN E. L. , TEGEN M. , TREICHEL P. M. 
Published: May 2016

AbstractThe reactions of MnBr(CO)5 with the corresponding Schiff‐base complexes ML in refluxing CH2Cl2 result in the binuclear substitution products (I).
ChemInform Abstract: Synthesis of 9‐m‐Carboranylrhenium Pentacarbonyl from 9‐m‐Carboranecarboxylic Acid Chloride.
Authors: ZAKHARKIN L. I. , OL'SHEVSKAYA V. A. 
Published: May 2016

AbstractThe o‐ and m‐carboranecarboxylic acid chlorides (I) react with sodium pentacarbonylrhenate (II) to give the complexes (III).
ChemInform Abstract: Transition Metal Phosphido Complexes. Part 14. P‐Functional Phosphido‐Bridged Heterobimetallic Complexes with and without a Metal‐Metal Bond; PH2‐Bridged Cp(CO)xFe‐Derivatives.
Authors: SCHAEFER H. + , LESKE W. 
Published: May 2016

AbstractThe binuclear phosphido‐bridged Fe complexes (I) are prepared either by cleaving both Si‐P bonds in bis(trimethylsilyl)phosphido analogues such as (II) using MeOH (III), acetic acid, or H2O, or by reaction of the mononuclear complexes (VII) and (VIII).
ChemInform Abstract: Disproportionation, Electrochemistry, and Electronic Coupling Involving Mononuclear and Binuclear Cobalt Phthalocyanine Derivatives.
Authors: LIU W. , HEMPSTEAD M. R. , NEVIN W. A. , MELNIK M. , LEVER A. B. P. , LEZNOFF C. C. 
Published: May 2016

AbstractElectronic spectroscopic data are reported for Co(I), Co(II), and Co(III) mononuclear complexes of (I) and bridged binuclear species (II) and (III) in solution and film phases.
ChemInform Abstract: Copper(I) and Copper(II) Compounds of a Dinucleating, Octadentate Tetrakisbenzimidazole Ligand. Crystal and Molecular Structures of Three Dihalogeno(1,8‐bis(bis(1′‐methylbenzimidazol‐2′‐ylmethyl)amino)‐3,6‐dioxaoctane)dicopper(II) Bis(anion) Compounds (Halogen: F, Cl, or Br; Anion: BF4, CF3SO3, or Cl).
Authors: VAN RIJN J. , REEDIJK J. , DARTMANN M. , KREBS B. 
Published: May 2016

AbstractIn general the title ligand (I) (synthesis described) reacts with copper salts in refluxing EtOH to yield the copper(II) complexes in a yield of about 80%.
ChemInform Abstract: Diplatinum(II) and ‐(III) Complexes with Bridging μ‐Diphosphonito‐P,P′ or μ‐Methylenebis(phosphonito)‐P,P′ Ligands. Synthesis, Structure, and Nuclear Magnetic Resonance Analysis of the ′Lantern′ Complexes. Crystal Structures of K4(Pt2(μ‐CH2(P(O)OH)2)4)·6 H2O and K4(Pt2(μ‐CH2(P(O)OH)2)4Cl2)·8 H2O.
Authors: KING C. , ROUNDHILL D. M. , DICKSON M. K. , FRONCZEK F. R. 
Published: May 2016

AbstractThe title complex (I) is prepared by treating K2PtCl4 with the dipotassium salt of CH2(PH(O)OH)2 in acetic acid at pH 5. This complex (I) and its analogue (III) react with halogenes X2 to give the diplatinum(III) complexes (II) and (IV), respectively.