bluuebunny/crossref_metadata_2025_split huggingface dataset:
Characterization of a hypersonic turbulent boundary layer along a sharp cone with smooth and transverse square−bar roughened wall
Authors: Neeb Dominik , Marquardt Pascal , Gülhan Ali 
Published: September 2024

AbstractIn the present study, the response of a hypersonic turbulent boundary layer at an inflow of Ma∞ = 6 and Re∞ = 16·106 1/m to a smooth and rough surface along a sharp cone is examined. The model consisted of three segments with exchangeable parts to consider smooth and rough surfaces with a roughness topology of square bar elements with a nominal wavelength of four times the height of the elements. In selected regions of interest, the flow field was measured by particle image velocimetry (PIV) which enabled analysis of mean velocity fields and Reynolds stresses. Van Driest transformed smooth wall mean velocity profiles showed the expected incompressible behavior and compared well to previous investigations. A combination of an integral and fitting approach is discussed to enable inner scaling of the rough wall profiles, which showed the expected shift below the smooth wall profile. The smooth wall turbulence profiles from PIV agreed to artificially filtered DNS in case of the streamwise component. Turbulence profiles above the smooth and rough wall agreed to within measurement accuracies. Additionally, two−point correlations were used to investigate turbulent structures above the smooth and rough wall. Both, length scales and orientations of the correlations, showed high level of agreement between smooth and rough walls, with only differences close to the wall. Furthermore, uniform momentum zones could be identified with similar behavior along both smooth and rough walls. Information from turbulence data support outer layer similarity, whereas mean velocity profiles show an increase in Coles wake parameter for the rough wall data. This might be influenced by transitional roughness effects.
Moderate effects of distance to air-filled macropores on denitrification potentials in soils
Authors: van Dijk Hester , Geers-Lucas Maik , Henjes Sina , Rohe Lena , Vogel Hans-Jörg , Horn Marcus A. , Schlüter Steffen 
Published: September 2024

AbstractDenitrification is a major source of the greenhouse gas N2O. As a result of spatial heterogeneity of organic carbon, oxygen and nitrate, denitrification is observed even under relatively dry conditions. However, it is unclear whether denitrification potentials of microbial communities exhibit spatial patterns relative to variations in distance to soil pores facilitating oxygen exchange and nutrient transfer. Thus, we determined genetic and process-level denitrification potentials in two contrasting soils, a cropland and a grassland, with respect to the distance to air-filled pores. An X-ray computed tomography aided sampling strategy was applied for precise sampling of soil material. Process-level and genetic denitrification potentials in both soils were spatially variable, and similar with respect to distance to macropores. In the cropland soil, a minor increase of process-level potentials with distance to pores was observed and related to changes in NO3− rather than oxygen availability. Genetic denitrification potentials after the short-term incubations revealed a certain robustness of the local community. Thus, distance to macropores has a minor impact on denitrification potentials relative to the observed spatial variability. Our findings support the notion that the impact of macropore induced changes of the environmental conditions in soil does not overrule the high spatial variability due to other controlling factors, so that the rather minor proportion of spatial heterogeneity of functional genes and activity potentials related to macropore distances in soil need not be considered explicitly in modelling denitrification.
Multicompartment microparticles of SBM triblock terpolymers: Morphological transitions through homopolymer blending
Authors: Trömer Manuel , Nikoubashman Arash , Gröschel André H. 
Published: September 2024

AbstractBlock copolymers (BCPs) have recently been explored in spherical confinement to form internally structured microparticles. While the behavior of AB diblock copolymers in confinement is comparably well studied, knowledge on confined ABC triblock terpolymers is still rather sparse. The latter are especially interesting as the third block allows the formation of a broader variety of multicompartment microparticles (MMs), but their synthesis is often realized through sequential polymerization, which can be work intensive and challenging. Here, we demonstrate that blending linear ABC triblock terpolymers with homopolymers is a versatile and straightforward method to tune the microphase behavior in MMs. We systematically blend polystyrene-block-polybutadiene-block-poly(methyl methacrylate) (SBM or PS-b-PB-b-PM) with homopolymers of hPS, hPB, or hPM, to study the feasibility of this approach to replicate specific morphologies or access new ones. We utilize Shirasu Porous Glass (SPG) membrane emulsification and evaporation-induced confinement assembly (EICA) to produce narrowly size-dispersed MMs with defined inner structure. We analyze the MMs with dynamic light scattering (DLS), as well as transmission and scanning electron microscopy (TEM, SEM). We show that the resulting blend morphologies can be identical to those of the unblended SBM at same composition and that, depending on the location in the ternary microphase diagram, one SBM morphology can be converted into multiple different morphologies.
Graphical Abstract
Alterations of perfusion and functional connectivity of the cingulate motor area are associated with psychomotor retardation in major depressive disorder
Authors: Bracht Tobias , Mertse Nicolas , Breit Sigrid , Federspiel Andrea , Wiest Roland , Soravia Leila M. , Walther Sebastian , Denier Niklaus 
Published: September 2024

AbstractPsychomotor retardation, characterized by slowing of speech, thoughts, and a decrease of movements, is frequent in patients with major depressive disorder (MDD). However, its neurobiological correlates are still poorly understood. This study aimed to explore if cerebral blood flow (CBF) and resting state functional connectivity (rs-FC) of the motor network are altered in patients with MDD and if these changes are associated with psychomotor retardation. Thirty-six right-handed patients with depression and 19 right-handed healthy controls (HC) that did not differ regarding age and sex underwent arterial spin labelling (ASL) and resting-state functional MRI (rs-fMRI) scans. Psychomotor retardation was assessed with the motoric items of the core assessment of psychomotor change (CORE) questionnaire. Patients with MDD had more pronounced psychomotor retardation scores than HC. Patients with MDD had reduced CBF in bilateral cingulate motor area (CMA) and increased resting-state functional connectivity (rs-FC) between the cluster in the CMA and a cluster localized in bilateral supplementary motor areas (SMA). Furthermore, increased rs-FC between the CMA and the left SMA was associated with more pronounced psychomotor retardation. Our results suggest that reduced perfusion of the CMA and increased rs-FC between the CMA and the SMA are associated with psychomotor retardation in patients with depression.
Exploration of compounds to inhibit the Panton-Valentine leukocidin of Staphylococcus aureus
Authors: Grebe Tobias , Sarkari Mithra Tatjana , Cherkaoui Angelika , Schaumburg Frieder 
Published: September 2024

AbstractThe Panton-Valentine leukocidin (PVL) of Staphylococcus aureus is associated with necrotizing infections. After binding to complement 5a receptor (C5aR/CD88) and CD45 it causes cytolysis in polymorphonuclear neutrophils (PMNs) as well as inflammasome activation in monocytes. The objective of this study was to test if (ant)agonists of C5aR and CD45 can attenuate the effect of PVL on PMNs and monocytes. We tested the effect of various concentrations of six C5aR (ant)agonists (avacopan, BM213, DF2593A, JPE-1375, PMX205 and W-54011) and one CD45 antagonist (NQ301) to attenuate the cytotoxic effect of PVL on human PMNs and monocytes in vitro. Shifts in the half-maximal effective concentration (EC50) of PVL to achieve a cytotoxic effect on PMNs and modulation of inflammatory cytokine response from monocytes were determined by flow cytometry and IL-1β detection. Pre-treatment of PMNs with avacopan, PMX205 and W-54,011 resulted in 3.6- to 4.3-fold shifts in the EC50 for PVL and were able to suppress IL-1β secretion by human monocytes in the presence of PVL. BM213, DF2593A and NQ301 were unable to change the susceptibility of PMNs towards PVL or reduce inflammasome activation in monocytes. Avacopan, PMX205 and W-54,011 showed protection against PVL-induced cytotoxicity and suppressed IL-1β secretion by monocytes. Clinical studies are needed to prove whether these substances can be used therapeutically as repurposed drugs.
Micropeltation in Myrtaceae: a neglected subject
Authors: Dörken Veit M. , Ladd Philip G. , Parsons Robert F. 
Published: September 2024

AbstractThe majority of taxa with peltate leaves are perennial herbs native to swampy or aquatic habitats or to mesic shaded understorey habitats. These large peltate leaves are formed by a meristematic bridge at the lamina–petiole junction. However, there are also several strong-light exposed, small-leaved, xero- and scleromorphic Myrtaceae with leaf peltation which is formed without a meristem fusion/bridge. Here, abaxial laminar tissue at the insertion point of the petiole forms a basal extension, so that a weak peltation occurs. This shifts the petiole onto the adaxial laminar surface. The formation of micropeltation in Myrtaceae leads to erect leaves that are strongly appressed to the shoot axis and the entire foliate, vertical shoots appear as “green columns”, a result that is also the case in taxa with reflexed minute leaves. It seems that micropeltation achieves the same goal as leaf reflexion in small-leaved taxa—reduction of heat-load and transpiration during the hottest phases of the day by a lower light interception at midday compared to the morning and evening. Thus, physiologically micropeltation and reflexion of minute leaves seem to be the result of convergent evolution.
Assessment of the onset of analgesia and length of analgesia following the use of PBM with different wavelengths: a clinical study
Authors: Kulkarni Sachin , Walsh Laurence J. , Bhurani Yash , George Roy 
Published: September 2024

Abstract
This clinical study assessed photobiomodulation (PBM) induced analgesic effects of diode lasers and an LED light source on the dental pulp. Baseline responses to electric pulp testing (EPT) were recorded in 93 healthy unrestored premolar teeth in 26 adults (age range 22–63 years) attending a private dental practice. The teeth were irradiated on buccal and lingual aspects of the crown, by placing the tips on the middle third of the crown of the teeth, on separate days for each of 4 different light sources (660, 808, or 904 nm diode lasers, or a novel multi-wavelength LED light source (700–1100 nm)) using comparable parameters (100 mW, 30 s, 6 J). EPT scores were measured after a further 1-, 2-, 5- and 20-min. Discomfort caused by PBM therapy was recorded using the Wong-Baker scale. EPT changes were tracked over time using repeated measures analysis of variance. Baseline EPT scores were very consistent between different days (linear regression r2 0.9422–0.9648). All PBM devices caused a significant elevation in EPT at 5 min, with an earlier onset at 2 mins for 904 nm and LED. The LED was the only light source that elevated scores at 20 min. Across 2–20 min, when ranked by effectiveness, the greatest EPT elevations were seen for LED, followed by 904 nm, then 660 nm and finally 808 nm. Discomfort during PBM was most common with 904 nm, followed by 808 nm. No discomfort occurred from the LED. Among the light sources utilized, the LED multi-wavelength system demonstrated the largest increase in EPT readings, suggesting its potential as a non-pharmacological alternative for achieving dental analgesia compared to diode lasers.
Compliance with kauri forest protection in New Zealand’s regional parks: the mediating role of trust on local versus visitor populations
Authors: Grant Andrea , Lindsay Nicole , Benson Hugh A. N. 
Published: September 2024

AbstractRealising behavioural change in long invested environmental practices is often difficult to achieve, especially when scientific understanding of the issues is still unfolding. Having confidence in one’s action requires knowledge that actions will be effective in improving environmental outcomes. Currently, we know little about the role of social trust in mediating complex and uncertain knowledge of environmental problems and the required actions needed to address them. In this quantitative study, we surveyed 472 users of endangered kauri forests in New Zealand to better explore the role of trust in relation to pro-environmental behaviours (PEB) designed to mitigate effects of the devastating plant disease, kauri dieback. Findings show uncertainty about the scientific knowledge of the issue, recommended actions and efficacy of proposed solutions significantly influenced PEB for both residents and visitors of forests; however, this relationship was partially mediated by trust, particularly among locals residing within 5 km of infected forest areas. These findings indicate the need for closer engagement with local residents to develop institutional and scientific trust in kauri dieback interventions. We outline activities that may help build trust and recommend new areas of research to support higher compliance with environmental protection initiatives.
How Well Do Popular Bicycle Helmets Protect from Different Types of Head Injury?
Authors: Baker C. E. , Yu X. , Lovell B. , Tan R. , Patel S. , Ghajari M. 
Published: September 2024

AbstractBicycle helmets are designed to protect against skull fractures and associated focal brain injuries, driven by helmet standards. Another type of head injury seen in injured cyclists is diffuse brain injuries, but little is known about the protection provided by bicycle helmets against these injuries. Here, we examine the performance of modern bicycle helmets in preventing diffuse injuries and skull fractures under impact conditions that represent a range of real-world incidents. We also investigate the effects of helmet technology, price, and mass on protection against these pathologies. 30 most popular helmets among UK cyclists were purchased within 9.99–135.00 GBP price range. Helmets were tested under oblique impacts onto a 45° anvil at 6.5 m/s impact speed and four locations, front, rear, side, and front-side. A new headform, which better represents the average human head’s mass, moments of inertia and coefficient of friction than any other available headforms, was used. We determined peak linear acceleration (PLA), peak rotational acceleration (PRA), peak rotational velocity (PRV), and BrIC. We also determined the risk of skull fractures based on PLA (linear risk), risk of diffuse brain injuries based on BrIC (rotational risk), and their mean (overall risk). Our results show large variation in head kinematics: PLA (80–213 g), PRV (8.5–29.9 rad/s), PRA (1.6–9.7 krad/s2), and BrIC (0.17–0.65). The overall risk varied considerably with a 2.25 ratio between the least and most protective helmet. This ratio was 1.76 for the linear and 4.21 for the rotational risk. Nine best performing helmets were equipped with the rotation management technology MIPS, but not all helmets equipped with MIPS were among the best performing helmets. Our comparison of three tested helmets which have MIPS and no-MIPS versions showed that MIPS reduced rotational kinematics, but not linear kinematics. We found no significant effect of helmet price on exposure-adjusted injury risks. We found that larger helmet mass was associated with higher linear risk. This study highlights the need for a holistic approach, including both rotational and linear head injury metrics and risks, in helmet design and testing. It also highlights the need for providing information about helmet safety to consumers to help them make an informed choice.
Lessons learned from establishing and running a Mössbauer laboratory in industry
Authors: de Souza Paulo 
Published: September 2024

AbstractMössbauer spectroscopy offers unique capabilities for primary industry sectors such as mining, mineral processing, and steelmaking, as well as in environmental services and advanced manufacturing. However, there are three key limiting factors: the time required to record a single spectrum, the challenges of managing an additional radioactive source on company premises, and the lack of personnel skilled in analysing Mössbauer spectra and understanding its operation. More commonly used techniques such as XRD, SEM, or XRF have technical staff who can interpret data with support from standard libraries and user-friendly software packages. In contrast, Mössbauer spectroscopists, who often hold degrees in Physics or Chemistry, typically emerge from academic settings and are less commonly employed in industry. This paper addresses the current challenges limiting the widespread adoption of Mössbauer laboratories in the industry and proposes potential solutions to overcome these obstacles. These solutions include promoting internships for undergraduate and postgraduate students familiar with Mössbauer spectroscopy in industrial settings, increasing investment in software development, hosting seminars and workshops to educate industry professionals on the capabilities of Mössbauer spectroscopy, and providing ongoing support from the scientific community to industries interested in operating spectrometers in their facilities.
Impaired Social Attention and Cognitive Empathy in a Paediatric Sample of Children with Symptoms of Anxiety
Authors: Eaton Steve , Dorrans Ellie Mae , van Goozen Stephanie H.M. 
Published: September 2024

AbstractImpairments in social cognition, in particular empathy, have been associated with childhood psychopathology, though previous investigations have yielded inconsistent results. Measures of social attention can reveal processes involved in responses to emotional stimuli and highlight deficits in empathy, or emotional biases in those with anxiety. The current study examined symptoms of anxiety, cognitive and affective empathy scores, and eye-gaze patterns in a pediatric sample of children (n = 178; 51–98 months-old) referred by their teachers for emerging psychopathology symptoms at school. We used eye-tracking metrics to capture gaze patterns during a dynamic video task designed to elicit empathic responses. Anxiety symptomology was reported by parents using the Screen for Child Anxiety Related Disorders scale (SCARED). Associations between eye-tracking variables, cognitive and affective empathy, and anxiety scores were analysed dimensionally in accordance with the Research and Domain Criteria (RDoC) framework. Higher levels of anxiety were associated with lower cognitive empathy and shorter first and total fixation durations to the eyes, across emotions (happiness, sadness, fear). No such associations were found between affective empathy and anxiety. Hierarchical multiple regression analyses revealed that across emotion conditions, first fixation duration negatively predicted anxiety scores. Our results indicate that children high in anxiety display cognitive empathy impairments and shorter attention to the eyes. These findings could inform early intervention programs for individuals at risk of developing anxiety disorders, as educating those high in anxiety on ways to identify emotions in others through changes in social attention could help to reduce anxiety.
Extraction and Characterization of Microcrystalline Cellulose (MCC) from Durian Rind for Biocomposite Application
Authors: Yong Wei Sing , Yeu Yee Lee , Chung Ping Ping , Soon Kok Heng 
Published: September 2024

AbstractThe scientific community has become interested in cellulose extraction from agro-industrial wastes because they contain large quantities of cellulose and are being researched globally due to their application. Cellulose extracted from these wastes offers varying characteristics and structures depending on the specific source. In this study, microcrystalline cellulose (MCC) was extracted from different parts of the durian husk through acid hydrolysis with various concentrations of oxalic acid and cellulose-to-acid ratios. The durian husk underwent a pretreatment method involving bleaching and alkaline treatment. The characteristics of MCC, such as functional group, morphology, and crystallinity, were studied. The findings indicated that lignin was successfully removed through pretreatment. However, traces of hemicellulose were still detected in a few samples. The extracted MCCs demonstrated a diameter range from 6.237 to 25.38 μm and crystallinity within the range of 71.43–78.30%. Polycaprolactone (PCL)-based biocomposites with different MCC weights (0.2, 0.5, and 1.0 wt%) were fabricated, and the performance was evaluated through tensile testing and biodegradability tests. The addition of 1.0 wt% MCC enhanced the tensile strength by 22%. SEM analysis revealed the cross-section fracture surface of the biocomposite, indicating the contribution of the MCC during pull-out. Meanwhile, the biodegradability of the biocomposite increased with the addition of MCC, indicating that the MCC-based biocomposite was fully biodegradable.
Deep learning architectures for data-driven damage detection in nonlinear dynamic systems under random vibrations
Authors: Joseph Harrish , Quaranta Giuseppe , Carboni Biagio , Lacarbonara Walter 
Published: September 2024

AbstractThe primary goal of structural health monitoring is to detect damage at its onset before it reaches a critical level. In the present work an in-depth investigation addresses deep learning applied to data-driven damage detection in nonlinear dynamic systems. In particular, autoencoders and generative adversarial networks are implemented leveraging on 1D convolutional neural networks. The onset of damage is detected in the investigated nonlinear dynamic systems by exciting random vibrations of varying intensity, without prior knowledge of the system or the excitation and in unsupervised manner. The comprehensive numerical study is conducted on dynamic systems exhibiting different types of nonlinear behavior. An experimental application related to a magneto-elastic nonlinear system is also presented to corroborate the conclusions.
On testimony in scenarios with Wigner and Friend
Authors: Placek Tomasz 
Published: September 2024

Abstract
The paper constructs a semi-formal language suited to the analysis of Wigner’s Friend scenarios: it represents an epistemic notion of rational beliefs and perspectives, to accommodate the insights of perspectival interpretations of quantum mechanics. The language is then used to analyze a paradox put forward by Frauchiger and Renner (Nat Commun, 9(1):3711, 2018). Their argument is presented as a semi-formal derivation with specified rules of reasoning. These rules bear an affinity to some of the cherished tenets of epistemology and we argue that they are valid (one universally, and the other in experimental contexts). Since our proof is a reductio, it leaves a choice which premises are responsible for a contradiction. Our first choice is a step that appears incorrect from the point of view of the universal unitary evolution as well as the view that every measurement induces a collapse of a measured system’s state. Our second choice, brought to view by the paper’s attention to perspectives and epistemology, points to a step reporting the transmission of beliefs (testimony) about measurement results. We argue that testimony is not licensed by quantum mechanical formalism; we discuss some recent attempts to save the cogency of testimony in the context of quantum measurements.