bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: The Synthesis and Biological Properties of the Derivatives of 4‐Heterylmercaptoquinazoline.
Authors: SINYAK R. S. , MAZUR I. A. , STETS V. R. , MARTINOVSKII A. A. 
Published: May 2016

AbstractDurch Umsetzung des Chlorchinazolins (I) mit Mercaptochinolin oder Mercaptoacridinen oder von 4‐Mercaptochinazolin (III) mit entsprechenden Chlorchinolinen und Chloracridinen werden die HeterylmercaptochinazoIine (II) und (IV) synthetisiert.
ChemInform Abstract: The Synthesis and Study of the Cardiovascular Activity of the Derivatives of 6‐Nitro‐ 7‐oxo‐4,7‐dihydroazolo[1,5‐a]pyrimidine.
Authors: RUSINOV V. L. , PETROV A. YU. , PILICHEVA T. L. , CHUPAKHIN O. N. , KOVALEV G. V. , KOMINA E. R. 
Published: May 2016

AbstractDie 5‐Aminopyrazole und ‐tria2ole (I) werden durch Kondensation mit Ethoxymethylen‐nitroessigsäureethylester (II) und anschließende alkalische Cyclisierung in 6‐Nltro‐7‐oxo‐4,7‐dihydropyrazolound ‐triazolo‐ pyrimidine (IV) umgewandelt.
ChemInform Abstract: KH/18‐Crown‐6: A Powerful Base for the Protection of Hindered Alcohols with tert‐ Butyldimethylsilylchloride.
Authors: BRAISH T. F. , FUCHS P. L. 
Published: May 2016

AbstractEinige Verfahren zur SiIyIierung von tertiären Alkoholen werden erprobt.
ChemInform Abstract: Tetrakis(diphenylphosphino)allene.
Authors: SCHMIDBAUR H. , POLLOK T. 
Published: May 2016

AbstractThe Iithiatcd form of the propyne (I) reacts with chlorodiphenylphosphine to give the title compound (II), oxidation of which with bisarimethylsilyl)peroxide affords the tetrakis phosphinoxide (IIIa) [for (IIIb) and (IIIc) no inslructions for preparation or yields are given, but their "Cand "P NMR data are presented].
ChemInform Abstract: Chemistry of Phosphorus. Part 164. (tBuP)2P ‐ P(Me)‐ P(tBuP)2: The First Bis(cyclotriphosphano)phosphane, a Novel P7R5 Structure Type.
Authors: BAUDLER M. , DE RIESE‐MEYER L. 
Published: May 2016

AbstractThe first bis(cyclotriphosphano)phosphane (III) has been synthesized by reaction of (I) with (II) in the molar ratio 2:1 [yield 90 P‐% (31P NMR) of two con?guralional isomers in the ratio 1:1].
ChemInform Abstract: Synthesis and Reactivity of Metal α‐Hydroxyalkyl Complexes; Generation of (CO)5MCH(C6H5)OH (M: Mn, Re).
Authors: SELOVER J. C. , VAUGHN G. D. , STROUSE C. E. , GLADYSZ J. A. 
Published: May 2016

AbstractThe reaction of the Mn‐substituted diketone (I) with LIBHEI, gives the metallacycle (II) which is isolated as its [(Ph,P)2N] ;alt (IIb).
ChemInform Abstract: Tetramethylallene and 2,4‐Dimethyl‐1,3‐pentadiene as Hydrogen Atom Acceptors in Reactions with HMn(CO)5 and HCo(CO)4.
Authors: GARST J. F. , BOCKMAN T. M. , BATLAW R. 
Published: May 2016

AbstractReactions of tetramethylallene (I) with the titlc metal hydrides proceed by Initial hydrogen atom transfer, providim the first examples of such reactions of nonconjugated alkenes.
ChemInform Abstract: Partial Purification and Characterization of Raucaffricine β‐D‐Glucosidase from Plant Cell‐Suspension Cultures of Rauwolfia serpentina Benth.
Authors: SCHUEBEL H. + , STOECKIGT J. + , FEICHT R. , SIMON H. 
Published: May 2016

AbstractA highly substrate‐specific enzyme, raucaffricine β‐D‐glucosidase, is isolated from cell‐suspension cultures of R. serpentina.
ChemInform Abstract: Highly Stereoselective Intramolecular Alkylation of Ester Enolate: An Approach to trans‐Hydrindane System.
Authors: AHN S. H. , KIM D. , CHUN M. W. , CHUNG W.‐K. 
Published: May 2016

AbstractBei der Wittig‐Reaktion zwischen dem 2‐Hydroxy‐tetrahydropyran (I) als Aldehydäquivalent und dem Ylid (II) erhält man den Hydroxy‐carbonsäureester (III), der zu (V) butyliert wird.
ChemInform Abstract: Reductive Cleavage of α,β‐Alkynyl Acetals. New Route to Optically Pure Propargylic Alcohols.
Authors: ISHIHARA K. , MORI A. , ARAI I. , YAMAMOTO H. 
Published: May 2016

AbstractAus den Alkinylketonen (I) werden mit dem optisch aktiven Diol (II) die Acetale (III) hergestellt und diese in Gemische der diastereoisomeren Alkoholether (IV) und (V) reduktiv gespalten, wobei deren Anteile je nach Reduktionsmittel und Reaktionsbedingungen variieren.
ChemInform Abstract: The Fries Rearrangement of Phenyl Phenylacetate.
Authors: YAMAMOTO J. , KUROKAWA H. , SUGITA K. 
Published: May 2016

AbstractDie zu den Produkten (II) und (III) führende Fries‐Umlagerung des Phenylacetates (I) mit AlCl3 oder TiCl4 als Katalysator wird systematisch untersucht.
ChemInform Abstract: Syntheses of N‐Trifluoromethyl‐N‐nitroso‐amide, ‐sulfonamide, ‐carbamate and ‐urea Derivatives.
Authors: UMEMOTO T. , MIYANO O. 
Published: May 2016

AbstractGemäß den Formelgleichungen werden ausgehend vom Tri‐ ?uornitrosomethan (I) über die Intermediärstufe (II) die N‐Trifluormethyl‐N‐nitroso‐Derivate (IV), (V), (VIII) und (X) hergestellt.
ChemInform Abstract: Synthesis of Amides with a Fluorine Atom on a Asymmetric Carbon.
Authors: KITAZUME T. , SATO T. , LIN J. T. 
Published: May 2016

AbstractAusgehend von enantiomeren 2‐Methyl‐2‐?uormalonaten (I) werden auf den beiden skizzierten Wegen die chiralen Amide (III) synthetisiert.
ChemInform Abstract: The Reactions of Difluoroiodoacetyl Fluoride with Copper and Silver.
Authors: SAMEJIMA S. , KUMAI S. , MUNEKATA S. , YAMABE M. 
Published: May 2016

AbstractDie Reaktion des aus 1,2‐Diiodtetrafluorethan (I) zugänglichen Di?uoriodacetylfluorids (II) mit Kupfer‐ oder Silberpulver liefert nebeneinander das Bernsteinsäuredi?uorid (III) und das Säure?uorid‐Derivat (IV) als Hauptprodukte sowie das Difluoracetyl?uorid (V) als Nebenprodukt.
ChemInform Abstract: Enantiospecific Synthetic Approach to C,D‐Ring System of Steroids with Functionalized Side‐Chains.
Authors: HUTCHINSON J. H. , MONEY T. 
Published: May 2016

AbstractDas aus (+)‐9,lO‐Dibromcampher in hoher Ausbeute zugängliche Lacton (I) wird mit Halogeniden (II) zu Lactonen (III) alkyliert, die durch Methanolyse und Einführung einer Si‐Schutzgruppe in die Cyclopentylessigsäureester (IV) übergeführt werden.
ChemInform Abstract: Organoaluminum Reagent as a Chemical Tool for Asymmetrization.
Authors: NARUSE Y. , YAMAMOTO H. 
Published: May 2016

AbstractDie Cyclohexanone (I) werden mit dem optisch aktiven Diol (II) in die Acetale (III) übergeführt und diese mit Triisobutylaluminium zu (V) und (VI) unter wesentlicher Bevorzugung von (V) umgesetzt.
ChemInform Abstract: Thermal, Catalytic, and Photochemical Denitrogenation of 1‐Diazo‐3‐(l‐methylcyclopenta‐2,4‐dienyl)‐2‐propanone.
Authors: BURGER U. , ZELLWEGER D. 
Published: May 2016

AbstractThe title compound (VII), prepared via a modified Arndt‐Eistert reaction [(1) ‐ (V)], is surprisingly stable at temp. of up to 100 ° C. Direct irradiation of (VII) affords (VIII) [isolated as (IX)] via Wolff rearrangement, whereas benzophenone‐sensitized photolysis, thermal and catalytic denitrogenation all yield the tricyclic ketone (Xa).
ChemInform Abstract: Synthesis of Octavalene (Tricyclo[5.1.0.02,8]octa‐3,5‐diene) and Several Substituted Octavalenes.
Authors: CHRISTL M. , LANG R. , HERZOG C. 
Published: May 2016

AbstractThe Synthesis of octavalene (IIIa) and its derivatives (IIIb) (sensitive to air) and (IIIc) is performed Starting from the bromo compounds (I).
ChemInform Abstract: Synthesis of (+)‐1,3,5,7‐Tetrakis[2‐(1S,3S,5R,6S,8R,10R)‐D3‐trishomocubanylbuta‐1,3‐diynyl]adamantane. The First Optically Active Organic Molecule with T Symmetry and of Known Absolute Configuration.
Authors: NAEMURA K. , HOKURA Y. , NAKAZAKI M. 
Published: May 2016

AbstractThe trishomocubanethanoic acid (I) is converted to its amide (III).
ChemInform Abstract: Synthesis, Structure and Reactivities of [6]Paracyclophanes.
Authors: TOBE Y. , UEDA K. , KAKIUCHI K. , ODAIRA Y. , KAI Y. , KASAI N. 
Published: May 2016

AbstractPhotocycloaddition of dichloroethylene (II) to the enone (I) and subsequent reductive dehalogenation of the ethylene acetal of the photoadduct gives the propellenone (III).
ChemInform Abstract: Reaction of Ketenes with N,N‐Disubstituted α‐Aminomethyleneketones. Part 16. Synthesis of N,N‐Disubstituted 4‐Amino‐5,6‐tetramethylene‐3‐phenyl‐2‐pyranones.
Authors: BARGAGNA A. , SCHENONE P. , LONGOBARDI M. 
Published: May 2016

AbstractDie 2‐Aminomethylen‐cyclohexanone (I) und Chlor‐phenyl‐keten (II) ergeben die Addukte (III), die mit DBN zu den Pyranonen (IV) dehydrochloriert werden.
ChemInform Abstract: Photochemical Reactions of 3‐Acyl‐2‐thiotetrahydro‐1,3‐thiazines. A New Synthesis of Cepham Analogues.
Authors: SAKAMOTO M. , AOYAMA H. , OMOTE Y. 
Published: May 2016

AbstractBei der Photolyse der cyclischen Dithiourethane (I) erhält man Mischungen aus den Cyclisierungsprodukten (II) und dem Spaltprodukt (III), bei niedrigerer Temperatur erhält man aus (Ic) das Cyclisierungsprodukt (IVc) neben (III).
ChemInform Abstract: 13C N MR Study of the Binding of Nitroprusside and Hexacyanoferrate(II) to Aquocobalamin, Vitamin B12a.
Authors: BUTLER A. R. , GLIDEWELL C. , MCINTOSH A. S. , REED D. , SADLER I. H. 
Published: May 2016

AbstractHigh‐frequency 13C‐NMR spectroscopy using nitroprus‐ side 90% enriched in 13C shows that the nitroprusside anion forms discrete 1:1 and 1 22 complexes, (I) or (II), in solution with aquocobalamin, which is one of the proposed clinical antidotes to cyanide poisoning from nitroprusside metabolism.
ChemInform Abstract: Syntheses of Biologically Important Carbohydrates. Part 34. Syntheses of 3‐C‐Methyl‐branched Hex‐2‐enopyranose Derivatives and Studies on the Rearrangement of Their Trichloroacetimidates.
Authors: DYONG I. , MERTEN H. , THIEM J. 
Published: May 2016

AbstractAusgehend von dem Pyranosid (I) wird die Verbindung (V) synthetisiert, welche das Ole?nzuckerglykosid aus Anhydrolankamycin darstellt.
ChemInform Abstract: Synthesis of New N‐Substituted N‐Demethylaporphine Derivatives.
Authors: BERENYI S. , MAKLEIT S. , RANTAL F. 
Published: May 2016

AbstractThe thebaine derivatives (I) and (III) [obtained by N‐demethylation of (I) and subsequent N‐propylation] rearrange on treatment with methanesulfonic acid to give the 2‐halogenated apocodeines or N‐propyI‐N‐demethylapocodeines, respectively (IV).
ChemInform Abstract: X‐Ray Photoelectron Spectroscopic Study of Copper‐Exchanged X‐ and Y‐Type Sodium Zeolites: Resolution of Two Cupric Ion Components and Dependence on Dehydration and X‐Irradiation.
Authors: CONTARINI S. , KEVAN L. 
Published: May 2016

AbstractThe behavior of the Cu Zpm photoelectron lines in Cu‐ Na‐Xand CuNa‐Yzeolites (10 Cu" per unit cell) is interpreted in terms of coordination state changes of the metal ion.
ChemInform Abstract: S4N4 and Its Derivatives: Isolation and Structure of S4N4H+[SnCl5(H2O)]‐ (I) and (S3N2NH2+)2[SnCl6]2‐(II).
Authors: HOLL K. , THEWALT U. 
Published: May 2016

AbstractReaction of S4N4 with the complex acids occurring in the system SnCl4‐ H2O ‐ AcOI‐Iyields the title salts (I) and (II), both containing protonated S"N," units.
ChemInform Abstract: Ligand Effects on the Electronic Structure, Spectra, and Electrochemistry of Tetracobalt Carbonyl Clusters.
Authors: HOLLAND G. F. , ELLIS D. E. , TROGLER W. C. 
Published: May 2016

AbstractThe effect of different ligand environments on the electronic structure of a common tetrahedral cobalt core is examined with SCF‐XoL‐DV calculations.
ChemInform Abstract: Radical‐Nucleophilic (SRNI) Reactions. Part 4. Radical‐Nucleophilic (SRNI) Reactions: ESR Studies.
Authors: AL‐KHALIL S. I. , BOWMAN W. R. , SYMONS M. C. R. 
Published: May 2016

AbstractOxidative addition of Na‐azide to the radical‐anions derived from (I) leads to the explosive α‐nitro azides (II).
ChemInform Abstract: Mechanism of the Reactions of Alkyl Ions with Alkylamines: Competing Proton Transfer and Condensation Reactions.
Authors: AUSLOOS P. , LIAS S. G. 
Published: May 2016

AbstractCondensation reactions of alkyl cations such as (I) with the amines (II) lead to (IV)‐(VII) via dissociation of (III) through two pathways and compete with direct formation of (VI) and (VII) via deuteron transfer.
ChemInform Abstract: The Uncatalysed and the Copper(II) Promoted Hydrolysis of 4‐Nitrophenyl L‐leucinate.
Authors: HAY R. W. , BASAK A. K. 
Published: May 2016

AbstractIn connection with catalysis of hydrolysis of esters by metalloenzymes, the title ester, which is provided with a good leaving group, is hydrolyzed over the pH range 5.19‐10.46 at 20‐30°C. Cu(II) promoted base hydrolysis of the ester is more than 105 times faster than that of the protonated ester.
ChemInform Abstract: Chromium(II) Reagents. Part 1. Reduction of α‐Acetylenic Ketones to trans‐Enones.
Authors: SMITH A. B. III , LEVENBERG P. A. , SUITS J. Z. 
Published: May 2016

AbstractDie aus den Alkinolen (II) durch Oxidation gut zugänglichen Acetylenketone (IV) werden durch Chrom(II)‐sulfat oder ‐chlorid selektiv zu trans‐Enonen (V) reduziert.
ChemInform Abstract: Synthesis and Biological Activity of Analogues of 1,4‐Benzoquinone‐ guanylhydrazone‐thiosemicarbazone.
Authors: SCHULZE W. , GUTSCHE W. , WOHLRABE K. , TRESSELT D. , HORN G. , FLECK W. 
Published: May 2016

AbstractDie Alkyl‐substituierten Analoga (IVb)‐(IVd) der im Titel genannten Verbindung (IVa) werden auf dem skizzierten Weg erhalten.
ChemInform Abstract: Biscarbamothioates from Isocyanates and Substituted Alkane‐ and Benzenedithiols.
Authors: HANEFELD W. , SCHULZE‐WEISSCHU P. 
Published: May 2016

AbstractDie Dithiole (I) reagieren mit den Isocyanaten (II) zu den Bis‐thiol‐ carbamaten (III).
ChemInform Abstract: The Use of N‐Ethyl‐N′‐dimethylaminopropylcarbodiimide or Silicon Tetrachloride in Pyrrole Syntheses.
Authors: ANDERSON W. K. , HEIDER A. R. 
Published: May 2016

AbstractAus den Acylaminosäuren (I) werden mit dem Carbodiimid (II) bzw. mit SiCl4 (III) die meso.ionischen Oxazolone (IV) hergestellt, die mit den dipolarophilen Acetylenen (V) zu den Pyrrolen (VI) umgesetzt werden.
ChemInform Abstract: Direct Amination. Part 2. Reaction of 2‐Phenylindole with Primary Aromatic Amines.
Authors: BERTI C. , GRECI L. , ANDRUZZI R. , TRAZZA A. 
Published: May 2016

AbstractThe reaction of 2‐phenylindole (I) with the anilines (II) in the presence of strong oxidants yields the 2‐phenyl‐3‐arylimino‐3H‐indoles (III), most of which have been prepared for the first time.
ChemInform Abstract: Nucleophilic Substitution in 4‐Halonitropyrazole Carboxylic Acids.
Authors: MANAEV YU. A. , PEREVALOV V. P. , ANDREEVA M. A. , STEPANOV B. I. 
Published: May 2016

AbstractDie Brom‐nitro‐pyrazolcarbonsäuren (I) und (V) reagieren in wäßrigen Lösungen in Gegenwart von Kupfer(I)‐Salzen mit Arylaminen (II) unter Bildung von Amin‐ und Hydroxyderivaten (III) und (VI) bzw. (IV).
ChemInform Abstract: Action of Hydrogen Peroxide on Some 2‐Aminooxazole and Imidazolin‐2‐ ones.
Authors: GINANNESCHI M. , CHELLI M. , RAPI G. 
Published: May 2016

AbstractDie Oxidation der Amino‐oxazole (I) oder der Imidazolinone (III) führt zu Hydroperoxiden (II).
ChemInform Abstract: Photochemistry of 4‐Acyloxy‐2‐azabuta‐1,3‐dienes. A Novel Photochemical 1,2‐Acyl Migration in an Enol Ester.
Authors: ARMESTO D. , ORTIZ M. J. , PEREZ‐OSSORIO R. , HORSPOOL W. M. 
Published: May 2016

AbstractThe acyloxy‐azabutadienes (I), on irradiation, undergo rearrangement by 1,2‐migration of the acyl group to yield the 2,5‐dihydro‐oxazoles (II), which are found to be the sole products of this photoreaction.
ChemInform Abstract: Studies on 2,3‐Disubstituted Thiazolin‐4‐one.
Authors: ELBANNANY A. A. A. , IBRAHIM A. A. H. 
Published: May 2016

AbstractDie aus den Iminen (I) zugänglichen Thiazolinone (III) liefern in Folgereaktionen die Heterocyclen (V), (VIII) und (XI).
ChemInform Abstract: Ring Contraction of 1,2,6‐Thiadiazines to 1,2,5‐Thiadiazoles: Synthesis of 2‐Substituted 4‐Amino‐2,3‐dihydro‐3‐oxo‐1,2,5‐thiadiazole 1,1‐Dioxides.
Authors: ARAN V. J. , BIELSA A. G. , RUIZ J. R. , STUD M. 
Published: May 2016

AbstractDie Sulfamide (I) addieren Malonylchlorid (II) unter Bildung der Dioxide (III), von denen sich (IIIa), (IIIb) und (IIId) zu den Derivaten (IV) nitrosieren lassen.
ChemInform Abstract: Fused Thiopyrones. Part 2. 2‐Carboxylic Acids of Thiopyrano[3,2‐b]indol‐4(5H)‐one and Thiopyrano[2,3‐b]indol‐4(9H)‐one.
Authors: GOERLITZER K. + , HOELSCHER D. + 
Published: May 2016

AbstractDie Indolylthiofumarsäuren (I) cyclisieren beim Erhitzen mit Polyphosphorsäure in Eisessig zu Gemischen der im Titel genannten Carbonsäuren (II) und (III), die als Methylester getrennt und durch nachfolgende alkalische Hydrolyse in reiner Form erhalten werden.
ChemInform Abstract: Stereochemistry of 3‐Oxo‐5‐phenylcyclopentanecarboxylic Acids.
Authors: BECK M. , FRAHM A. W. 
Published: May 2016

AbstractDie aus den Pyri‐ di‐naldehyden (I) über Wittig‐Reaktion zugänglichen Azazimtsäureester (I‐II‐) reagieren mit dem Triester (IV) unter basischen Bedingungen in einer gekopbe?lten Michael‐ und Dieckmann‐Reaktion zu den Cyclopentanonestern (V), die beim sauren Abbau stereoselektiv die cis‐ Carbonsäuren (VI) liefern.
ChemInform Abstract: Studies on the Synthesis of 3‐Amino‐5‐(4‐pyridinyl)‐1,2‐dihydropyrid‐2‐ one (Cordemcura) from a Technical Mixture of Alkyl Pyridines.
Authors: NIEDRICH H. , HEYNE H. U. , SCHROETTER E. + , JAENSCH H.‐J. + , HEIDRICH H.‐J. , FAUST G. , LOHMANN D. 
Published: May 2016

AbstractDer Vilsmeier‐Komplex aus Phosgen und Dimethylformamid liefert mit 4‐Picolin (I) die Verbindung (II).
ChemInform Abstract: Acetamidacetal Cyclization. Part 2. 2‐Aminoquinolines and Pyrrolo‐[2,3‐b]quinolines.
Authors: EIDEN F. , BERNDL K. 
Published: May 2016

AbstractDie Aminobenzophenone (I) kondensieren mit den Amidacetalen (II), (V) bzw. (VII) über die teilweise isolierten Amidine wie (VIII) zu den im Titel genannten Heterocyclen (III), (VI) bzw. (IX).
ChemInform Abstract: Synthesis of 5‐Oxo and 7‐Oxopyrido[2,3‐d]pyrimidines.
Authors: ANDERSON G. L. , RICHARDSON S. G. 
Published: May 2016

AbstractDer Ester (Ia) wird alkalisch zur Carbonsäure (Ib) verseift und diese thermisch zu (II) decarboxyliert.
ChemInform Abstract: Synthesis of Substituted Thieno[2,3‐d]pyrimidine‐4(3H)‐thiones from Thieno[2,3‐d]‐1,3‐thiazine‐4‐thiones and N‐Nucleophiles by Cyclic Transformation Reactions.
Authors: LEISTNER S. , GUETSCHOW M. + , WAGNER G. 
Published: May 2016

AbstractDie Umsetzung der Thiazin‐thione (I) mit Ammoniak bzw. den primären Aminen (II) liefert die Pyrimidin‐thione (III).
ChemInform Abstract: Synthesis of Some Substituted 1,2,4‐Triazines.
Authors: MIRONOVICH L. M. , PROMONENKOV V. K. , KRYSIN V. P. 
Published: May 2016

AbstractDie Nitrosierung der Triazinonthione und ‐dithione (I) ergibt die entsprechenden 4‐Nitrosoderivate (II).
ChemInform Abstract: Muscle Relaxants. Part 4. Monoacylbutyroguanamines.
Authors: KREUTZBERGER A. , LOCH M. 
Published: May 2016

AbstractVon den aus Butyroguanamin (I) hergestellten Acylderivaten (III) sind (IIIe) muskelrelaxierend bzw. antidiabetisch und (IIIa) trichomonazid und antiviral wirksam.
ChemInform Abstract: Regularities of the Rotational Isomerism of Methyl Substituted Dialkyl‐ and Diarylmethylphosphinoxides.
Authors: PATSANOVSKII I. I. , ISHMAEVA E. A. , SUNDUKOVA E. N. , YARKEVICH A. N. , TSVETKOV E. N. 
Published: May 2016

AbstractDie aus den Phosphinigsäuren (I) durch Hydroxymethylierung mit Formaldehyd (II) und nachfolgende Chlorierung dargestellten Chlormethylphosphinoxide (IV) werden mit Methylat (Va) und den Phenolaten (Vb) zu den Derivaten (VI) umgesetzt.
ChemInform Abstract: P‐Tert‐Butyl‐ and P‐Mesityl‐N‐[2,4,6‐tri(tert‐butyl)‐phenyl]‐λ3‐imino Phosphines.
Authors: ROMANENKO V. D. , DRAPAILO A. B. , RUBAN A. V. , MARKOVSKII L. N. 
Published: May 2016

AbstractAuf der Suche nach neuen, zweifach koordinierten Phosphorverbindungen werden die Iminophosphane (IV) auf dem angegebenen Weg erhalten.
ChemInform Abstract: Hydrolytic Decomposition of Quaternary Phosphonium Salts in the 2‐Phenyl‐9‐oxa‐ 2‐phosphabicyclo[4.4.0]decanone Series.
Authors: BUTIN B. M. , ISAEVA G. M. , ERZHANOV K. B. 
Published: May 2016

AbstractDer früher beschriebene Phosphabicyclus (I) wird mit Methyliodid (II) zu dem Phosphonium‐Salz (III) quaterniert und dieses unter Standardbedingungen zu dem Phosphinoxid (IV) hydrolysiert.
ChemInform Abstract: Addition of Phenylisocyanate to 2‐Phenyl‐1,3,2‐oxazaphosphorinane.
Authors: PUDOVIK M. A. , MIRONOVA T. A. , PUDOVIK A. N. 
Published: May 2016

AbstractDie im Titel genannte Reaktion liefert den Harnstoff (III).
ChemInform Abstract: The Synthesis of Metallaindene and Metallafluorene Compounds.
Authors: RAUSCH M. D. , KLEMANN L. P. , BOON W. H. 
Published: May 2016

AbstractAusgehend von Diphenylacetylen (I) bzw. Dibromdiphenyl (XIII) werden gemäß Schema die Metallaindene (III)‐(V) sowie (XII) bzw. die Metalla?uorene (XIV) und (XV) synthetisiert.
ChemInform Abstract: Some Substituted Urea Complexes of Thorium(IV) and Uranium(IV) N‐Thiocyanates.
Authors: AL‐DAHER A. G. M. , BAGNALL K. W. 
Published: May 2016

AbstractThe Complexes (I) and (II) are prepared by treating the metal tetrachloride or the corresponding complex of the tetrachloride with a stoichiometric amount of potassium thiocyanate and an excess of the ligand in THF.
ChemInform Abstract: Synthesis and Characterization of a Mn(III) Porphyrin Cation Radical and Its Conversion to Mn(IV) by Ligand Metathesis.
Authors: SPREER L. O. , MALIYACKEL A. C. , HOLBROOK S. , OTVOS J. W. , CALVIN M. 
Published: May 2016

AbstractThe complex (Ib) was synthesized by the oxidation of (Ia) with phenoxathiin hexachloroantimonate in CH2Cl2 at room temperature.
ChemInform Abstract: Distinction of the Two Type I Coppers in Bovine Ceruloplasmin.
Authors: SAKURAI T. , NAKAHARA A. 
Published: May 2016

AbstractRedox potentials of the two type Icopper ions, "blue copper ions", ofbovine ceruloplasmin (ferroxidase, iron(II): oxygen oxidoreductase) were determined and the reduction and reoxidation properties of each type of copper studied by using absorption, CD and EPR spectroscopy.
ChemInform Abstract: Copper‐Catechol Chemistry. Synthesis, Spectroscopy, and Structure of Bis(3,5‐ditert‐butyl‐o‐semiquinato)copper(II).
Authors: THOMPSON J. S. , CALABRESE J. C. 
Published: May 2016

AbstractThe dimeric title compound (III) with square pyramidal geometry about the metal ion is prepared by reacting of the Cu(I) complexes (I) with the benzoquinone (II) or of the basic Cu(II) dimer (IW with the catechol (V).
ChemInform Abstract: Formation of Electronically Excited Products in Electron‐Transfer Reactions: Reaction of Polypyridine Complexes of Cobalt(I) and Ruthenium(III) in Acetonitrile.
Authors: LIU D. K. , BRUNSCHWIG B. S. , CREUTZ C. , SUTIN N. 
Published: May 2016

AbstractThe yields of the metal‐to‐ligand charge‐transfer excited state of poly(pyridi‐ ‐ ne)‐Ru(II) complexes RuL%+ produced in the reaction of RuLä+ with CoL3+ complexes in acetonitrile are determined.
ChemInform Abstract: Transition Metal Complexes with Terminal or Bridging Imidato(l ‐) Ligands. X‐Ray Crystal Structures of trans‐[Ir(CO)(NCOC2F4CO)(PPh3)2] and [{Pd(o‐C6H4CH=NPh)(μ‐NCOC2H4CO)}2]·CH2Cl2, Spectroscopic Studies of [Mn(CO)5(NCOC2H4CO)], and the Nature of the Metal ‐ Nitrogen Bond.
Authors: ADAMS H. , BAILEY N. A. , BRIGGS T. N. , MCCLEVERTY J. A. , COLQUHOUN H. M. , WILLIAMS D. J. 
Published: May 2016

AbstractThe reaction of Mn(CO)5Br (I) with the Tl(I) salt (II) ofsuccinimide yields the succinimidato complex (III).
ChemInform Abstract: Fluxionality and Bonding in Formamidine and Formamidinate Complexes of Pt(II) and Pd(II) Containing the 2,6‐Bis[(dimethylamino)methyl]phenyl Ligand: A Proton NMR Study with X‐Ray Crystal Structures of [Pt{C6H3(CH2NMe2)2‐2,6}{p‐MeC6H4N = CHN(H)C6H4Me‐p}][CF3SO3] and [Pt{C6H3(CH2NMe2)2‐2,6}(p‐MeC6H4N = CHNC6H4Me‐p)].
Authors: GROVE D. M. , VAN KOTEN G. , UBBELS H. J. C. , VRIEZE K. , NIEMANN L. C. , STAM C. H. 
Published: May 2016

AbstractThe ligand (II) reacts with the ionic species (I) to form the complexes(1II), whose 1H NMR spectra are consistent with a rigid monodentate bonding mode of neutral (II).
ChemInform Abstract: Synthesis and Structural Characterisation of [Pt2Au2(PPh3)4(CNC6H3Me2‐2,6)4][PF6]2; a Platinum ‐ Gold Cluster with a Distorted Butterfly Geometry.
Authors: BRIANT C. E. , GILMOUR D. I. , MINGOS D. M. P. 
Published: May 2016

AbstractThe title compound (IIIb) and its BF4 analogue (IIIa) are prepared by the 1 :l molar reaction of (I) with (II) as shown.