bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Rapid Olefin Hydrogenation Catalyzed by Anion‐Promoted Ruthenium Clusters.
Authors: ZUFFA J. L. , BLOHM M. L. , GLADFELTER W. L. 
Published: May 2016

AbstractHydrogenation of terminal, unactivated olefins such as (I) can be carried out in the presence of an isocyanate‐promoted Ru Cluster, prepared directly from Ru3(CO)12 and bis(triphenylphosphine)iminium isocyanate.
ChemInform Abstract: Reduction of Allylic Acetates by Using a Novel Pd(0)‐SmI2 System.
Authors: TABUCHI T. , INANAGA J. , YAMAGUCHI M. 
Published: May 2016

AbstractCinnamylacetat (I) wird mit Smlz, Isopropanol und katalytischen Mengen an Pd(O)‐Verbindungen zu den Olefinen (II) und (III) reduziert, die zu gleichen Anteilen auch aus dem isomeren Acetat (IV) erhalten werden.
ChemInform Abstract: Some Properties of Fluorinated α,β‐Unsaturated Sulphones.
Authors: FOKIN A. V. , KOLOMIETS A. F. , SHKURAK S. N. , KONDRASHOV N. V. , MUKHAMETSHIN F. M. 
Published: May 2016

AbstractThe title compounds (I) react smoothly with carbon acids in the presence of bases to form the monoalkylation products (II)‐(IV).
ChemInform Abstract: A One‐Step Synthesis of ω‐Hydroxyacetylenic Carboxylic Acids.
Authors: COSSY J. , PETE J. P. 
Published: May 2016

AbstractDie Alkinole (I) reagieren mit den w‐Halogen‐carbonsäuren (II) in Gegenwart von Butyllithium überwiegend zu den Hydroxy‐alkincarbonsäuren (III) neben den Dehydrohalogenierungsprodukten (IV).
ChemInform Abstract: Stereochemical Control in Type I Intramolecular Ene Reactions of 1,6‐Dienes: Trends in Reactivity and Selectivity Upon Substitution.
Authors: GHOSH S. K. , SARKAR T. K. 
Published: May 2016

AbstractDas Dimethylallylbromid′ (I) reagiert über eine Grignard‐Addition und anschließende Oxidation zum Aldehyd (II), der durch Umsetzung mit dem Phosphonsäureester (IV) bzw. Malonester (V) zu den Dienen (IIIa) bis (IIIc) führt.
ChemInform Abstract: Studies on Quinones. Part 15. A Convenient Entry into the Tetrahydrophenanthrene‐ 1,4‐quinone System Utilizing the Dienone‐phenol Rearrangement of Spiro [Cyclopentanenaphthalene] Triones.
Authors: CASSIS R. , SCHOLZ M. , TAPIA R. , VALDERRAMA J. A. 
Published: May 2016

AbstractBei der Oxidation des Hydrochinons (I) entsteht das Chinon (II), das mit Acetanhydrid/konz.
ChemInform Abstract: Sustained Epoxidation of Olefins by Oxygen Donors Catalyzed by Transition Metal Substituted Polyoxometalates, Oxidatively Resistant lnorganic Analogues of Metalloporphyrins.
Authors: HILL C. L. , BROWN R. B. JUN. 
Published: May 2016

AbstractOxidation of cyclohexene (I) is carried out using transition metal substituted heteropolytungstates or other transition metal‐based catalysts and iodosylbenzene derivatives as oxygen donors.
ChemInform Abstract: A New Reductive Acylation of Azetidinone Disulphide in the Route to Penems.
Authors: BATTISTINI C. , SCARAFILE C. , VIOGLIO S. , PERRONE E. , FRANCESCHI G. 
Published: May 2016

AbstractAus dem Penam‐1‐oxid (I) erhält man mit 2‐Mercapto‐benzthiazol (II) das Disulfid (III), das mit Carbamoyloxyessigsäureanhydrid (IV) in den Thiolester (V) übergeführt wird.
ChemInform Abstract: A New Reaction of Acetylenes, the Addition of Methanol to 5‐Hydroxyhex‐ 3‐yn‐ 2‐one. Synthesis of the "Onion Furanone", 2‐Hexyl‐5‐methyl‐3[2H]furanone.
Authors: THOMAS A. F. , DAMM H. 
Published: May 2016

AbstractDie Acetylen‐bis‐carbinole (I) werden mit Wasserstoffperoxid in Gegenwart von Wolframat zu den Keton‐alkoholen (II) oxidiert, die mit Methylat zu den isomeren Tetrahydrofuranen (III) und (IV) cyclisiert werden können.
ChemInform Abstract: Syntheses and H2‐Antagonistic Activity of 1,3,4‐Thiadiazole‐2,5‐diamines.
Authors: WEGNER K. 
Published: May 2016

AbstractDie primären Amine (I) werden mit dem Bromthiadiazblamin (II) zu den Thiadiazoldiaminen (III) umgesetzt, und die Histamin H2‐antagonistische Wirkung wird untersucht.
ChemInform Abstract: Dimerization of 2‐Arylpropene‐1,1‐dicarbonitriles.
Authors: ABRAMENKO YU. T. , IVASHCHENKO A. V. , NOGAEVA K. A. , ANDRONOVA N. A. , PUTSYKINA E. B. 
Published: May 2016

AbstractThe title compounds (I) dimerize in the presence of basic catalysts to form the aminocyclohexadienes (IIa) and (IIb).
ChemInform Abstract: Directed Ortho Metalation of O‐Pyridyl Carbamates. Regiospecific Entries into Polysubstituted Pyridines.
Authors: MIAH M. A. J. , SNIECKUS V. 
Published: May 2016

AbstractDurch o‐Metallierung der O‐Pyridylcarbamate (II), (VI) und (X) und nachfolgende Einwirkung von Elektrophilen (I) werden regiospezifisch die substituierten Carbamate (III), (VII) und (XI) erhalten.
ChemInform Abstract: Cardiotonic Agents. Part 3. Synthesis and Biological Activity of Novel 6‐(Substituted 1H‐Imidazol‐4(5)‐yl)‐3(2H)‐pyridazinones.
Authors: SIRCAR I. , BOBOWSKI G. , BRISTOL J. A. , WEISHAAR R. E. , EVANS D. B. 
Published: May 2016

AbstractAus den Imidazol‐aldehyden (I) werden über (II), (IVa) und (IVb) die Dihydropyridazinone (V) hergestellt, die zu den Pyridazinonen (VI) dehydriert werden.
ChemInform Abstract: 4,5‐Disubstituted Pyridazin‐3(2H)‐ones as Hypotensive Drugs: Incorporation of a β‐Blocking Moiety.
Authors: GOMEZ‐GIL M. C. , GOMEZ‐PARRA V. , SANCHEZ F. , TORRES T. 
Published: May 2016

AbstractDie 4;5‐Dihalogenpyridazinone (I) werden nach dem im Formelschema angegebenen Verfahren in die 4,5‐disubstituienen Pyridazinone (V) und (VI) übergeführt, die hypotensive und β‐blockierende Wirkung besitzen.
ChemInform Abstract: Conformationally Restricted Inhibitors of Angiotensin Converting Enzyme: Synthesis and Computations.
Authors: THORSETT E. D. , HARRIS E. E. , ASTER S. D. , PETERSON E. R. , SNYDER J. P. , SPRINGER J. P. , HIRSHFIELD J. , TRISTRAM E. W. , PATCHETT A. A. , ULM E. H. , VASSIL T. C. 
Published: May 2016

AbstractAls cyclische Analoga des ACE‐Inhibitors Enalaprilat (I) werden die Lactamdicarbonsäuren (IIa)‐(IIe‐) aus den Estern (III) hergestellt.
ChemInform Abstract: Alkylation of o‐Carborane by Ester Pyrolysis.
Authors: ALBAGLI D. , ZHENG G. , JONES M. JUN. 
Published: May 2016

AbstractPyrolysis of the o‐carboranes (I) in the presence of the esters (II) or (III) in sealed tubes at 200‐275°C produces the 9‐alkyl‐o‐carboranes (IV) in reasonable yield (not given).
ChemInform Abstract: Bora‐Aromatic Systems. Part 8. Physical and Chemical Consequences of Cyclic Conjugation in Boracyclopolyenes.
Authors: EISCH J. J. , GALLE J. E. , KOZIMA S. 
Published: May 2016

AbstractDie gewünschten tiefblauen Borole (VI) lassen sich am besten auf dem beschriebenen Reaktionsweg ausgehend von den Acetylenen (I) synthetisieren.
ChemInform Abstract: First Insertion of NO into a Transition‐Metal Cluster‐‐‐Carbon Bond: Regioselective Formation, Structure, and Reactions of the First Alkanenitrile Oxide Complexes.
Authors: GOLDHABER A. , VOLLHARDT K. P. C. , WALBORSKY E. C. , WOLFGRUBER M. 
Published: May 2016

AbstractThe clusters (I) are converted into the corresponding adducts (II).
ChemInform Abstract: Xanthine Complexes with 3d Metal Perchlorates.
Authors: MIKULSKI C. M. , KURLAN M. K. , BAYNE M. , GAUL M. , KARAYANNIS N. M. 
Published: May 2016

AbstractThe title complexes (I)‐(IV) are prepared by refluxing mixtures of ligand and metal salt in ethyl acetate/triethyl orthoformate.
ChemInform Abstract: Solution Chemistry of Silver Porphyrins. Oxidation of 5,10,15,20‐Tetra(3′‐N‐methylpyridinio)porphyrinatodisilver(I).
Authors: OKOH J. M. , KRISHNAMURTHY M. 
Published: May 2016

AbstractThe peroxodisulphate oxidajion of the title compound to the 1:1 silver(II) complex has been investigated at 25°C by spectro‐ ( 142 photometry.
ChemInform Abstract: Pentacyclo[12.2.2.22,5.26,9.210,13]‐1,5,9,13‐tetracosatetraene and Its Reaction with AgOTf. Synthesis of a Square‐Planar d10 Organometallic Complex.
Authors: MCMURRY J. E. , HALEY G. J. , MATZ J. R. , CLARDY J. C. , MITCHELL J. 
Published: May 2016

AbstractThe title te‐traene (VII) is prepared as shown in the scheme starting from the tetramethylenemonoacetal of 1,4‐cyclohexanedione (I).
ChemInform Abstract: The Structural Assignment of N‐Acylkansosamine, 4,6‐Dideoxy‐4‐[(R)‐2‐methoxypropanamido]‐3‐C‐methyl‐2‐O‐methyl‐L‐mannopyranose, by Chemical Synthesis.
Authors: YOSHIMURA J. , SATO K. , AQEEL A. , SINGH R. B. , HASHIMOTO H. 
Published: May 2016

AbstractDem im Titel genannten verzweigten Aminozucker wird aufgrund spektroskopischer Vergleiche mit den wie angegeben synthetisierten (R)‐ und (S)‐Isomeren sowie den Acetaten (VIb) und (V,Ic) die Struktur (VIa) zugeordnet.
ChemInform Abstract: Selective Acylation of 6‐Deoxyglycals.
Authors: HORTON D. , PRIEBE W. , VARELA O. 
Published: May 2016

AbstractL‐Rhamnal (I) kann unter verschiedenen Bedingungen selektiv acyliert werden, wobei die Ausbeuten der Produkte (II)‐(IV) von den jeweiligen Reaktionsbedingungen abhängen.
ChemInform Abstract: Synthesis of the Methyl and l‐Octyl Glycosides of the P‐Antigen Tetrasaccharide (Globotetraose).
Authors: LEONTEIN K. , NILSSON M. , NORBERG T. 
Published: May 2016

AbstractDurch Blocksynthese des aus (I) erhältlichen Disaccharid‐Derivats (IIe) mit dem aus (III) wie angegeben dargestellten Thioglykosid (V) ist das Globotetraose‐Derivat (VI) zugänglich.
ChemInform Abstract: N‐Glycosides. Part 5. 3‐Glycosyl‐4‐oxy‐hexahydropyrimidine‐2‐thiones and Their Acyclic Precursors.
Authors: IGNATOVA L. A. , SHUTALEV A. D. , UNKOVSKII B. V. , SINILOVA N. G. , DUPLISHCHEVA A. P. 
Published: May 2016

AbstractDas Ribosylchlorid (I) reagiert mit Silberrhodanid zum Thiocyanat (II), aus dem mit Aminen (III) bzw. (VII) die Thioharnstoffe (IV) bzw. (VIII) erhalten werden.
ChemInform Abstract: A Chiral Nitronate Dianion from D‐Glyceraldehyde. Enantiospecific Syntheses of 2,3‐Dideoxy‐3‐nitro Furanosides and Pyranosides.
Authors: WILLIAMS T. M. , MOSHER H. S. 
Published: May 2016

AbstractAus dem (D)‐GIycerinaldehyd‐ Derivat (I) erhält man über das Oxim bei der Oxidation die Nitroverbindung (II), die zu (III) und (IV) substituiert wird.
ChemInform Abstract: Synthesis of Sphingosines. Part 2. Synthesis of D‐erythro‐Sphingosines.
Authors: SCHMIDT R. R. , ZIMMERMANN P. 
Published: May 2016

AbstractDer aus D‐Galaktose über (I) zugängliche Aldehyd (II) reagiert nach Wittig zum Olefin (IV), das über das Azid (V) in das Czo‐Sphingosin (VI) und weiter in die Acylverbindung (VIII) übergeführt wird.
ChemInform Abstract: A General Highly Efficient Access to Prenylated Phenolic Natural Products. Synthesis of Colletochlorins B and D.
Authors: SAIMOTO H. , HIYAMA T. 
Published: May 2016

Abstract3‐Penten‐2‐on (I) und der Malonester (II) werden unter basischen Bedingungen zum Cyclohexenon (III) kondensiert, das auch aus dem Crotonsäureester (IV) und dem Acetessigsäureester (V) erhalten werden kann.
ChemInform Abstract: Chiral Allenylboronic Esters as a Practical Reagent for Enantioselective Carbon‐Carbon Bond Formation. Facile Synthesis of (‐)‐Ipsenol.
Authors: IKEDA N. , ARAI I. , YAMAMOTO H. 
Published: May 2016

AbstractAllenylboronic acid (III) is a rather stable compound, which, in hexane solution, can be stored at ‐20°C for several weeks.
ChemInform Abstract: On Mixed Crystals K2M′X6‐K2M"Y6. Part 6. The System K2OsCl6 ‐ K2OsBr6.
Authors: MUELLER H. + , BEKK P. 
Published: May 2016

AbstractDropwise addition of concentrated solutions o1" KzOsClö and KZOSBTÖ into ethanol yields mixed crystals which are free of mixed hexachlorobromoosmates, OsBr"Clä:" (n: l‐5).
ChemInform Abstract: High‐Pressure DTA Apparatus with Liquid or Gaseous Pressure Medium.
Authors: YAMAMURO O. , OGUNI M. , MATSUO T. , SUGA H. 
Published: May 2016

AbstractFor studies on the phase behavior of crystalline materials u new high‐pressure DTA apparatus has been developed, which operatcs under constant pressure up to 200 MP2: in thylpentane or gaseous helium as the pressure medium.
ChemInform Abstract: Influence of the Valve Metal Oxide on the Properties of Ruthenium Based Mixed Oxide Electrodes.
Authors: DE BATTISTI A. , BRINA R. , GAVELLI G. , BENEDETTI A. , FAGHERAZZI G. 
Published: May 2016

AbstractMicrostructural investigations of RuO2/Ta2O5 mixed oxide electrodes show the existence of a RuO2 rutile phase und a Ta2O5 amorphous phase.
ChemInform Abstract: Electrolytic Deposition of Bismuth on CdS(000l) Single‐Crystal Surfaces.
Authors: ELMORSI M. A. , JUETTNER K. + 
Published: May 2016

AbstractThe initial stage of Bi deposition on CdS surface (from aqueous 0.5 M NaClO4 + xM Bi(ClO4)3 solutions at pH 2) follows a progressive nucleation model with diffusion control of the Bi" transfer at three‐dimensional growth centres.
ChemInform Abstract: Complexation of Divalent and Trivalent Nickel and Copper Ions by Rigid and Flexible Dioxo Tetraaza Macrocycles.
Authors: FABBRIZZI L. , KADEN T. A. , PEROTTI A. , SEGHI B. , SIEGFRIED L. 
Published: May 2016

AbstractPotentiometric, spectrophotometric, kinetic, and electrochemical studies on the Ni(II) and Cu(II) complexes with the macrocycles (I) and (II) are performed to investigate the importance of the flexibility of the macrocyclic ring to the properties of the corresponding complexes.
ChemInform Abstract: Asymmetric Synthesis. Part 7. Enantiospecific Preparation of β‐Aminoalcohols from the N‐Cyanomethyl‐4‐phenyl‐1,3‐oxazolidine Synthon.
Authors: MARCO J. L. , ROYER J. , HUSSON H.‐P. 
Published: May 2016

AbstractDas N‐Cyanomethyl‐oxazolidin (I) wird zu (III) substituiert und dann zum Anomerengemisch (IV) cyclisiert.
ChemInform Abstract: Sequential Michael‐Michael Ring Closure Reactions for 3‐Different‐Component, One‐Pot, [2+2+2] Construction of Acylcyclohexenes and an Acylcyclohexanol.
Authors: POSNER G. H. , LU S.‐B. , ASIRVATHAM E. 
Published: May 2016

AbstractDie Enolate (I) reagieren mit den Vinylketonen (II) in Gegenwart von Triethylbor (III) und Vinyl‐triphenylphosphoniumbromid (IV) zu den Addukten (V).
ChemInform Abstract: Cyclopropanol Formation via β‐Hydrogen Atom Abstraction: The Five Membered Transition State Analogue of the Norrish Type II Reaction.
Authors: ARIEL S. , ASKARI S. H. , SCHEFFER J. R. , TROTTER J. 
Published: May 2016

AbstractDas Diels‐Alder‐Addukt (III) aus o‐Chinodimethan (I) und Naphthochinon (II) bildet bei Photolyse das Cyclopropanol (IV), aus dem durch Sekundärphotolyse der Ketoaldehyd (V) und das Lacton (VI) entstehen.
ChemInform Abstract: Thermodynamics and Kinetics of Carbon‐Carbon Bond Formation and Heterolysis Through Reactions of Carbocations with Carbanions in Solution.
Authors: ARNETT E. M. , MOLTER K. 
Published: May 2016

AbstractRate data are presented for the heterolysis of carbon ‐ carbon bonds and their formation through coordination of resonance‐stabilized carbocations and carbanions in acetonitrile solution at 25°C. These rates were determined by NMR line broadening and by the Tjump technique.
ChemInform Abstract: 2,5‐Quinonemethides of 1,6‐Methano[10]annulene with the Structures of S,N‐ and N,N‐Acylketene Acetals.
Authors: NEIDLEIN R. , HARTZ G. 
Published: May 2016

AbstractReaction ofthe aldehyde (I) with methylamine (II) gi‐ Q ves the imine (III), which undergoes cleavage ofthe ether function with TosOH t0 give the quinonemethide (IV).
ChemInform Abstract: Chromium(II) Salt Mediated Reductive Transposition of an Ester Acyl Group in ortho‐O‐Acyl Benzylic Bromides: A Ready Access to Unmasked ortho‐Hydroxybenzyl Ketones and a New Route to Benzo[b]furans.
Authors: LEDOUSSAL B. , GORGUES A. , LE COQ A. 
Published: May 2016

AbstractAus den Estern (I) erhält man über intermediäre Organo‐Chrom?ID‐Komplexe in Abhängigkeit von den Reaktionsbedingungen die Ketone (II) bzw. die Benzofurane (III).
ChemInform Abstract: Synthesis and Optical Activity of P‐(‐)‐2,7,12‐Tribromo‐3,8,13‐trihydroxycyclotribenzylene and Related Compounds. Evidence for the Nonorthogonality of the B2u und B1u Transitions in Polysubstituted Benzenes and Its Relevance of the Exciton Chirality Method.
Authors: CANCEILL J. , COLLET A. 
Published: May 2016

AbstractDie Cyclotrimerisierung von 4‐Brom‐3‐meth0xybenzylalkohol (I) in Essigsäure mit 65"/oiger Perchlorsäure liefert das Racemat (II), das man mit Bortribromid zu (III) demethyliert und mit (+)‐2‐Phenoxypropionsäure in die optischen Isomeren aufspaltet.
ChemInform Abstract: Absolute Configuration of α‐Substituted β‐Lactams from D‐Glyceraldehyde Acetonide.
Authors: BOSE A. K. , HEGDE V. R. , WAGLE D. R. , BARI S. S. , MANHAS M. S. 
Published: May 2016

AbstractDas aus dem Anilin (I) mit D‐Glycerinaldehydacetonid (II) erhaltene Imin (III) liefert mit (IV) und (VI) oder mit (V) die Cycloaddukte (VII), von denen (VIIa) in das cis‐β‐Lactam (VIII) bzw. (VIIa) und (VIIb) unter Ringspaltung in die Lacto‐ ne (IX) umgewandelt werden.
ChemInform Abstract: Two New Oxindole Syntheses.
Authors: FLEMING I. , LORETO M. A. , WALLACE I. H. M. , MICHAEL J. P. 
Published: May 2016

AbstractTwo approaches to the title compounds (IX) are described, which are complementary with regard to the stereochemistry of the re‐ sulting oxindoles [cIÜ (X) and (XVII)].
ChemInform Abstract: Sulphates of Trivalent Iodine. Novel Reagents for the Functionalization of Olefins to Cyclic Sulphates.
Authors: ZEFIROV N. S. , SOROKIN V. D. , ZHDANKIN V. V. , KOZ'MIN A. S. 
Published: May 2016

AbstractBy reaction of iodosobenzene (I) with S03, using a 1:1 or 2:1 molar ratio, the trivalent iodosulphates (II) or (III) are obtained.
ChemInform Abstract: Heteroarylation of Organometallic Derivatives of Azoles by N‐Acylbenzopyridinium Salts.
Authors: SHEINKMAN A. K. , CHMILENKO T. S. , NEZDIIMINOGA T. N. , TERTOV B. A. , KOSHCHIENKO YU. V. , KLYUEV N. A. 
Published: May 2016

AbstractThe reactions ofthe Grignard reagenls of I‐methylbenzoimidazole (I) und l‐methylimidazole (XII) with isoquinoline (III) orquinoline (X) in the presence o!" benzoyl Chloride (II) are studied.
ChemInform Abstract: Pyrazolo[4,5‐c]quinolines. Part 2. Synthesis and Specific Inhibition of Benzodiazepine Receptor Binding.
Authors: MELANI F. , CECCHI L. , PALAZZINO G. , FILACCHIONI G. , MARTINI C. , PENNACCHI E. , LUCACCHINI A. 
Published: May 2016

AbstractAus den Pyrazolo‐chinolinonen (Ia) werden die N‐Methyl‐ Derivate (Ib) und über die Chlorverbindungen (IIa) die Alkoxy‐ und Amino‐Derivate (IIb) und (IIc) hergestellt, die auf ihre inhibierende Wirkung der Benzodiazepin‐Rezeptoren untersucht werden.
ChemInform Abstract: Synthesis of Quaternary Salts from 2,3′‐Bipyridine and Dibromoalkanes.
Authors: SINGH S. K. , SUMMERS L. A. 
Published: May 2016

AbstractReaction of2,3′‐bipyridine (I) with the dibromoalkanes (II) yields mixtures of the l′‐bromoalkyl‐2,3′‐bipyridinium bromides (III) and the l′,l′"‐alkanediy1‐bis‐2,3′‐bipyri‐ dinium dibromides (IV) in each case.
ChemInform Abstract: The Introduction of a New Sulfamoylation Reagent: N‐Carbo(trimethylsilyloxy)sulfamoylchloride.
Authors: DURHAM P. J. , GALEMMO R. A. JUN. 
Published: May 2016

AbstractAus den N‐Cyano‐N‐alkyl‐pseudoharnstoffen (I) erhält man mit den Chlorsulfonylaminen (II) über eine Substitution zu (III) die Thiatriazin‐dioxide (IV).
ChemInform Abstract: Chemistry of [Bis(trimethylsilyl)amino]‐tert‐butylchloroborane: Synthesis of New Diborylamines and (Borylamino)phosphines.
Authors: LI B.‐L. , NEILSON R. H. 
Published: May 2016

AbstractSubstitution of the Cl of the title compound (I) by the corresponding nucleophiles leads to the aminoboranes (IIa) and the diaminoborane (IIb).
ChemInform Abstract: Synthesis of Bisorganothioselenides from Thiols and Selenium Dioxide.
Authors: PETRIASHVILI K. A. , USOV V. A. , LARIN M. F. , VORONKOV M. G. 
Published: May 2016

AbstractThe reaction of thiophenols, e.g. (I) with wet S603 yields complex product mixtures.
ChemInform Abstract: Reactions of Iron(III) Halobisdithiocarbamates with Halogens: a Novel Series of Fluxional Homobinuclear Iron(III) Complexes with Two Different Coordination Spheres Around the Magnetic Centers.
Authors: VAKOULIS F. D. , KATSOULOS G. A. , TSIPIS C. A. 
Published: May 2016

AbstractIn addition to the variety of products formed during the reaction of Fe(III) halobisdithiocarbamates (I) with halogens, some nove) fluxional homobinuclear Fe(III) complexes (II) with two different coordination spheres around the magnetic Centers are also synthesized (with bridging or chelated thiuramdisulfide and bidentate dithiocarbamates coordinated to only one Fe or to both Fe atoms).
ChemInform Abstract: Reactions of Metal Complexes with Carbohydrates: Nickel(II) Complexes Containing N‐Glycosides Derived from a Sugar and β‐Alanine.
Authors: TSUBOMURA T. , YANO S. , YOSHIKAWA S. 
Published: May 2016

AbstractThe Ni complex (I) und monosaccharides (II) react to yield the new complexes (III), which are the products of the first step of the "Maillard reaction".
ChemInform Abstract: Synthesis and Reactivity of Hydroxo‐Bridged Binuclear Ethylenediamine Complexes of Iridium(III) and the X‐Ray Crystal Structure of [Aquabis(ethylenediamine)iridium(III)](μ‐hydroxo)hydroxobis(ethylenediamine)iridium(III) Dithionate Perchlorate Hydrate.
Authors: GALSBOEL F. , LARSEN S. , RASMUSSEN B. , SPRINGBORG J. 
Published: May 2016

AbstractStarting from the Ir(III) hydroxoaquo complex (I) the salts of the binuclear bis‐(p‐hydroxo) cation (II) and of the binuclear aquo‐μ‐hydroxo cation (III) are prepared as shown.
ChemInform Abstract: Carbonyl Complexes of Rh(I), Ir(I) and Mo(0) Containing Substituted Derivatives of 1,10‐Phenanthroline and 2,2′‐Bipyridine.
Authors: CLAUTI G. , ZASSINOVICH G. , MESTRONI G. 
Published: May 2016

AbstractThe new complexes (I) and (IIa) were prepared by previously published methods.
ChemInform Abstract: Rearrangement of a Steroidal α‐Hydroxyacetal: A Convenient New Method for the Introduction of a 5α‐Methyl Group into the Steroid Nucleus.
Authors: BRIDGE A. W. , MORRISON G. A. , WOOSTER N. F. 
Published: May 2016

AbstractDas Cholestanon (I) ergibt bei der Methylierung über (I I) das Homo‐nor‐ Steroid (III), das in einer weiteren Umlagerung zum Keton (IV) führt.
ChemInform Abstract: Preparation of 6‐Amino‐6‐deoxy‐D‐altronic Acid and Their Derivatives.
Authors: KEFURT K. , CAPEK K. , KEFURTOVA Z. , JARY J. 
Published: May 2016

AbstractThe azidodesoxyglucofuranosides (IIa) and (IIb) obtained from (I) are convened via their mesy1ates(11c),(IId)tothe anhydro derivatives (IIIa) and (IIIb).
ChemInform Abstract: The Synthesis of (R)‐2′,3′‐Dihydroxypropyl 5‐Deoxy‐5‐dimethylarsinoyl‐ β‐D‐riboside, a Naturally‐Occurring, Arsenic‐Containing Carbohydrate.
Authors: MCADAM D. P. , STICK R. V. 
Published: May 2016

AbstractAus dem D‐Ribose‐acetat (Ia) erhält man über das Chlorid (Ib) das Substitutionsprodukt (IIa), das mit (III) zu (IIb) substituiert und dann über (IV) zu (V) gespalten wird.
ChemInform Abstract: Total Synthesis of (‐)‐Dihydrocelacinnine and (±)‐Celabenzine.
Authors: IIDA H. , FUKUHARA K. , MACHIBA M. , KIKUCHI T. 
Published: May 2016

AbstractAus 4‐Aminobutanol (I) werden in der angegebenen Weise die Naturstoffe (VIII) hergestellt.
ChemInform Abstract: A Total Synthesis of Methylenomycin B.
Authors: CAMPS F. , COLL J. , MORETO J. M. , TORRAS J. 
Published: May 2016

Abstract2‐Butin‐1‐ol (I) und Allylchlorid (II) reagieren in Gegenwart von Nikkelcarbonyl in Methanol zu den isomeren Cyclopentenonen (III), deren katalytische Hydrierung zur Dimethylverbindung (IV) führt.
ChemInform Abstract: High Pressure Diamond‐Anvil Studies on Neodymium to 40.0 GPa.
Authors: AKELLA J. , SMITH G. S. 
Published: May 2016

AbstractThe double hexagonal close packed (A3′ type) structure of Nd, which is stable at l atm, transforms to an f.c.c. structure at about 3.8 GPa.
ChemInform Abstract: Stoichiometry of the Allotropic Modification γ‐Bi2O3.
Authors: KHACHANI N. , DEVALETTE M. , HAGENMULLER P. 
Published: May 2016

AbstractAstudy of the solid solutions (I) (obtained from stoichiometric mixtures of (l‐Bi2Ü3, V2O5, or (NH4)2HAsO4 at 800°C / 24 h) leads for x: 0.77 to a phase whose cubic centered symmetry and parameter (10.255 Å) correspond to those previously reported for γ‐Bi2O3.
ChemInform Abstract: Phase Relationships of the Quasibinary System NiCr2S4 ‐ NiGa2S4. Crystal Structure of NiGa2S4.
Authors: LUTZ H. D. , BUCHMEIER W. , SIWERT H. 
Published: May 2016

AbstractThe phase diagram of the title system is established with the aid of X‐ray powder Guinier photographs of quenched samples.