bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Stereoselective Reactions of Alkenylpyranosides: The Effect of Double Bond Geometry on Conformation.
Authors: DENINNO M. P. , DANISHEFSKY S. J. , SCHULTE G. 
Published: May 2016

AbstractIn order to study the effects which determine the facial selectivity of the hydroxylation of alkenylpyranosides such as (I) (space group P21/c, Z=4) and (IIa) ( P21/n; Z=4), their reaction with OsO4 is investigated.
ChemInform Abstract: Saturated Heterocycles. Part 135. Cyclic Aminoalcohols and Related Compounds. Part 29. Synthesis of Condensed‐Sheleton cis‐ and trans‐2‐Phenylimino‐ and 2‐Methyliminotetrahydro‐1,3‐thiazines and ‐1,3‐oxazines.
Authors: FUELOEP F. + , CSIRINYI G. , BERNATH G. 
Published: May 2016

AbstractReaction of the cyclopentane derivatives (I) with the isothiocyanate (II) followed by treatment of the products (III) with HCl or with MeI (V) and alkali gives rise to the heterocycles (IV) or (VI), respectively.
ChemInform Abstract: Investigation into the Redox Behavior of Cp*2Fe2(.mu±eta.1‐S2)(.mu±eta.2‐S2) (Cp*: η5‐C5Me5): An Unexpected Reversible η1 ⇌ η2 Rearrangement of a Disulfur Bridge.
Authors: BRUNNER H. , MERZ A. , PFAUNTSCH J. , SERHADLI O. , WACHTER J. , ZIEGLER M. L. 
Published: May 2016

AbstractThe reaction of (I) with oxidizing agents such as I2 gives the dicationic complex (II).
ChemInform Abstract: Reactions of Tellurium Chloride Pentafluoride, TeF5Cl, with Nitrogen Nucleophiles. Preparation and Characterization of the Adducts (TeF4)2·NR2Cl, Where R = CH3, C2H5.
Authors: THRASHER J. S. , CLARK M. , MORKEN P. A. 
Published: May 2016

AbstractVarious nucleophiles, e.g. (I), (V), or (VII), are treated with tellurium chloride pentafluoride (II) to give the corresponding chlorinated derivatives.
ChemInform Abstract: Unexpected Product from Nitration of 1,3‐Diethoxybenzene.
Authors: SWEENY W. , SINGH G. 
Published: May 2016

AbstractNitration of 1,3‐diethoxybenzene (I) with nitric acid (II) in glacial acetic acid results in the formation of the two isomeric products (III) and (IV).
ChemInform Abstract: Knoevenagel Reaction in the Semiquinoide Series.
Authors: NIKANOROV V. A. , SERGEEV S. V. , ROZENBERG V. I. , REUTOV O. A. 
Published: May 2016

AbstractThe methyltrichloromethylcyclohexadienone (I) reacts with dimedone (II) to give the cross‐conjugated compound (III).
ChemInform Abstract: Preparative UV‐Laser Photochemistry: A Biscarbene Intermediate in the Synthesis of a 5,6‐Dihydrodibenzo(a,e)cyclooctene Containing a trans Double Bond.
Authors: HANNEMANN K. , WIRZ J. 
Published: May 2016

AbstractLaser photolysis of the diazo compound (I) leads to the novel product (II), which is not observed in the conventional photolysis.
ChemInform Abstract: Novel Synthesis of the 2,3‐Benzindolizine Ring System. Mechanism of Formation, Redox, Electronic Absorption, and Fluorescence Behavior.
Authors: SAEVA F. D. , LUSS H. R. 
Published: May 2016

AbstractThe N‐(bromomethylphenyl)pyridinium salt (I) is treated with pyridine in boiling acetonitrile to yield the benzindolizine (II).
ChemInform Abstract: α‐Effect Nucleophiles: A Novel and Convenient Method for the Synthesis of Dibenzo(a,d)cycloheptenimines.
Authors: ROTHAUSER LAMANEC T. , BENDER D. R. , DEMARCO A. M. , KARADY S. , REAMER R. A. , WEINSTOCK L. M. 
Published: May 2016

AbstractGrignard reaction of the dibenzocycloheptenone (I) yield the carbinol (III) which is dehydrated to give the methylene derivative (IV) by treatment with hydrochloric acid in methanol.
ChemInform Abstract: Aziridinyl Ketones and Their Cyclic Anils. Part 8. 1,2‐Diaryl‐1,1a‐dihydroazirino(1,2‐a)quinoxalines from Substituted o‐Phenylenediamines and Chalcone Dibromides.
Authors: ORLOV V. D. , VOROB'EVA N. P. , DEMENKOVA N. N. , CHESNOVSKII V. S. , YAREMENKO F. G. 
Published: May 2016

AbstractReaction of the o‐phenylenediamines (I) with the chalcone dibromides (II) gives the azirinoquinoxalines (III).
ChemInform Abstract: Stereochemistry of a 2,5‐Disubstituted 1,4‐Diazonia‐2,5‐diboratacyclohexane.
Authors: MILLER N. E. 
Published: May 2016

AbstractThe air‐stable cis and trans isomers of the title compound (I) are isolated by sublimation as side products of the synthesis of 1,1‐dimethyl‐1‐azonia‐3‐boratacyclobutane and characterized spectroscopically (IR, 1H NMR, MS).
ChemInform Abstract: Synthesis of Terminal Trimethylsilyl Enynes via a Silylated Arsonium Ylide.
Authors: SHEN Y. , LIAO Q. 
Published: May 2016

AbstractOlefination of the ketones (IV) with the arsonium ylide, generated from the silylated propargylic arsonium bromide (III), yields the ω‐silyl enynes (V).
ChemInform Abstract: Tristrimethylsilylation of Phenol and Related Reactions.
Authors: BARRETT A. G. M. , O'NEIL I. A. 
Published: May 2016

AbstractReaction of the phenols (I) with trimethylsilyl chloride (II) and lithium under ultrasonication and subsequent oxidation of the intermediately formed 1,4‐cyclohexadienes result in the formation of the trissilylated products (III).
ChemInform Abstract: Synthesis of Silyl‐Substituted Cyclopropanes by Reductive Cyclization of Polyhaloalkylsilanes of the Type RCCl2CH2CHClSiMe3.
Authors: KAMYSHOVA A. A. , CHUKOVSKAYA E. TS. 
Published: May 2016

AbstractTreatment of the haloalkylsilanes (I) or (IV) with elemental zinc gives the silylcyclopropane (II) and the chlorobutylsilane (III) or the silanes (V) and (VI).
ChemInform Abstract: Synthesis of (Trimethylsilyl)thiazoles and Reactions with Carbonyl Compounds. Selectivity Aspects and Synthetic Utility.
Authors: DONDONI A. , FANTIN G. , FOGAGNOLO M. , MEDICI A. , PEDRINI P. 
Published: May 2016

AbstractLithiation and subsequent silylation of thiazole (Ia) or 2‐bromothiazole (Ib) leads to the formation of 2‐(trimethylsilyl)thiazole (III) which is further converted to the bis(trimethylsilyl)thiazole (IV).
ChemInform Abstract: Syntheses and Reactions of Allylic and Homoallylic Pyrophosphate Tetraesters.
Authors: BUTSUGAN Y. , NAGAI K. , NAGAYA F. , TABUCHI H. , YAMADA K. , ARAKI S. 
Published: May 2016

AbstractReaction of the alkyl allyl phosphorochloridates (I) with NaHCO3 gives the pyrophosphates (II); the pyrophosphates (III) and (IV) are obtained analogously.
ChemInform Abstract: Derivatives of Germanium and Tin. Part 2. Formation and Structure of Isomeric “Dichlorodisupermesitylstannanes”.
Authors: WEIDENBRUCH M. , SCHAEFERS K. + , POHL S. , SAAK W. , PETERS K. , VON SCHNERING H. G. 
Published: May 2016

Abstract2,4,6‐Tri‐tert‐butyllithium (I) reacts with tin tetrachloride (II) in a molar ratio of 2:1, yielding the aryl(arylmethyl)dichlorostannane (III).
ChemInform Abstract: Reactions of Metal‐Metal Multiple Bonds. Part 16. Tetranuclear Halide‐Alkoxide Clusters of Molybdenum Formed by the Coupling of M‐M Triple‐Bonded Dinuclear Compounds. Synthesis, Characterization, and Molecular Structures of Mo4F2(O‐iPr)10, Mo4X3(O‐iPr)9, and Mo4X4(O‐iPr)8 (X: Cl, Br, I).
Authors: CHISHOLM M. H. , CLARK D. L. , ERRINGTON R. J. , FOLTING K. , HUFFMAN J. C. 
Published: May 2016

AbstractThe complex (II) crystallizes in P1 with Z=1 and is thermally unstable in solution above ‐20 °C, disproportionating into (I) and other products derived from the reactive species Mo2F2(O‐iPr)4, which can be trapped by addition of PMe3 to give (IV).
ChemInform Abstract: Acid‐Catalyzed Anti → Syn Isomerization of the (WV 2O4)2+ Core. Crystal Structures of anti‐(L2W2O4)I2 and syn‐(L2W2O4)2(S2O6)I2·2 H2O (L: 1,4,7‐Triazacyclononane).
Authors: SCHREIBER P. , WIEGHARDT K. , FLOERKE U. + , HAUPT H.‐J. 
Published: May 2016

AbstractPreparations of the yellow syn isomer (II) and its purple anti isomer (IV) are achieved by air oxidation of Zn dust reduced aqueous solutions containing LWO3 (I) or (L2W2O5)(Br3)2 (III).
ChemInform Abstract: Formation of Difluoroethyne as a Ligand by Coupling of Two Fluoromethylidyne Ligands.
Authors: LENTZ D. , MICHAEL H. 
Published: May 2016

AbstractC2F2, which is extremely unstable as a free molecule, is formed by C‐C coupling of the two CF ligands of the Fe cluster (I) on the cluster expansion with the Co complex (II).
ChemInform Abstract: Ketenylidenetriphenylphosphorane Complexes.
Authors: LINDENBERGER H. , BIRK R. , ORAMA O. , HUTTNER G. , BERKE H. 
Published: May 2016

AbstractThe photochemically generated mono(diethyl ether)dicarbonyl derivatives of (I) react with the ketenylidenephosphorane (II) to give the complexes (III).
ChemInform Abstract: Spectroscopic Investigation of the Interaction of Co2(CO)8 with MgO and SiO2.
Authors: RAO K. M. , SPOTO G. , GUGLIELMINOTTI E. , ZECCHINA A. 
Published: May 2016

AbstractCo2(CO)8, when absorbed in the gas phase in vacuo on fully dehydrated MgO, forms a variety of carbonyl clusters both neutral and ionic.
ChemInform Abstract: Mono‐ and Dinuclear Nickel(0) Complexes of Butadiyne.
Authors: BONRATH W. , POERSCHKE K. R. + , WILKE G. , ANGERMUND K. , KRUEGER C. + 
Published: May 2016

AbstractThe diphosphine(cyclooctadiene)‐Ni(0) complexes (I) react with one or a half equiv. butadiyne (II) to give the mononuclear complexes (III) and the dinuclear complexes (IV) with yields above 90%.
ChemInform Abstract: Element‐Organic Amine/Imine Compounds. Part 31. Cyclometalation with N‐tert‐Butyl‐Phosphorus‐Nitrogen Iridium Complexes.
Authors: SCHERER O. J. , FLOERCHINGER M. + , GOEBEL K. + , KAUB J. , SHELDRICK W. S. 
Published: May 2016

AbstractThe interaction of the amino(imino)phosphines (I) and (VIII) with the chloride‐bridged Rh‐ and Ir complexes (II) and (V) are investigated.
ChemInform Abstract: Aluminum Inclusions and Precipitates in Restacked Exfoliated MoS2.
Authors: MIREMADI B. K. , MORRISON S. R. 
Published: May 2016

AbstractExfoliated MoS2 (separated into monomolecular layers in aqueous solution) is restacked with Al3+ ions (mixing of the exfoliated MoS2 suspension with a solution of aluminum nitrate).
ChemInform Abstract: Synthesis and Properties of XeO2F+AsF‐ 6 and (FO2XeFXeO2F)+AsF‐ 6.
Authors: CHRISTE K. O. , WILSON W. W. 
Published: May 2016

AbstractThe new title adducts, prepared as shown in the scheme, ((IV) can also be obtained from (III) by prolonged pumping or exposure to a laser beam), are characterized by Raman spectroscopy.
ChemInform Abstract: Aroylnitrenes with Singlet Ground States: Photochemistry of Acetyl‐Substituted Aroyl and Aryloxycarbonyl Azides.
Authors: SIGMAN M. E. , AUTREY T. , SCHUSTER G. B. 
Published: May 2016

AbstractIn tert.‐butanol the irradiation of the azides (I) into their n‐π* bands leads to the insertion products (IV).
ChemInform Abstract: Optically Pure (4aS)‐(+)‐ or (4aR)‐(‐)‐1,4a‐Dimethyl‐4,4a,7,8‐tetrahydronaphthalene‐2,5(3H,6H)‐dione and Its Use in the Synthesis of an Inhibitor of Steroid Biosynthesis.
Authors: HAGIWARA H. , UDA H. 
Published: May 2016

AbstractThe optically pure (S)‐(+)‐ (IIa) or (R)‐(‐)‐enone (IIb) is obtained by asymmetric cyclization of the triketone (I) in the presence of either L‐ or D‐β‐phenylalanine and D‐camphorsulfonic acid.
ChemInform Abstract: Bruceantin Support Studies. Part 14. Regiospecific Quassinoidal A‐Ring Synthesis via an Olefin Oxidation Strategy.
Authors: GOVINDAN S. V. , FUCHS P. L. 
Published: May 2016

Abstractm‐Chloroperbenzoic acid oxidation of the silyl enol ether (I) yields the α‐siloxy ketone (II) which gives impure fractions of the α‐diketone (III) upon treatment with methoxide.
ChemInform Abstract: Benzoanellated Centropolyquinanes. Part 4. Steric Effects in Multiply Substituted Triptindans (9H,10H‐4b,9a((1,2)Benzenomethano)indeno(1,2‐a)indenes).
Authors: PAISDOR B. , GRUETZMACHER H.‐F. + , KUCK D. 
Published: May 2016

AbstractUnder conditions of cyclodehydration the products with only one endo methyl group are obtained as main products from (I).
ChemInform Abstract: An Unusual Lewis‐Acid‐Catalyzed Addition of Acetonitrile to a Perhydroazulenone.
Authors: SAMMES P. G. , SWANSON A. G. , WHITBY R. J. 
Published: May 2016

AbstractThe known 1,5‐epoxyperhydroazulenone (I) is treated with AlI3 in acetonitrile (II) with the intention to cleave the ether bridge.
ChemInform Abstract: Synthesis of (PCyh3)2Cr(CO)3 and Its Reactions with Hydrogen, Nitrogen, and Other Ligands.
Authors: GONZALEZ A. A. , MUKERJEE S. L. , CHOU S.‐J. , KAI Z. , HOFF C. D. 
Published: May 2016

AbstractThe title complex (III) is obtainable in high yield from the naphthalene analogue (I) and tricyclohexylphosphine (II).
ChemInform Abstract: Doubly Charged Gas‐Phase Heteronuclear Cluster Ions: Synthesis and Reaction of LaFe2+ with Small Hydrocarbons.
Authors: HUANG Y. , FREISER B. S. 
Published: May 2016

AbstractLaser generated La2+ reacts with Fe(CO)5 to give beside charge exchange product ions (∼ 80%) carbonyl displacement reaction products such as LaFe(CO)2+ n (n = 1, 2, 3).
ChemInform Abstract: Synthesis of Octahedral Hydrido(vinyl)iridium(III) Complexes by C‐H Addition: An Example of a Thermodynamically Favored Rearrangement (M(CHR=CHX)) → (M(H)(CR=CHX)).
Authors: WERNER H. , DIRNBERGER T. , SCHULZ M. 
Published: May 2016

AbstractThe five‐coordinate hydrido‐Ir(III) compounds (I) react with the olefins (II) to form the hydrido(vinyl) complexes (III) in almost quantitative yield.
ChemInform Abstract: Enzymes in Organic Synthesis. Part 42. Investigation of the Effects of the Isozymal Composition of Pig Liver Esterase on Its Stereoselectivity in Preparative‐Scale Ester Hydrolyses of Asymmetric Synthetic Value.
Authors: LAM L. K. P. , BROWN C. M. , DE JESO B. , LYM L. , TOONE E. J. , JONES J. B. 
Published: May 2016

AbstractCommercially available pig liver esterase (PLE) is separated in 6 different main isozyme fractions and it is shown that their individual stereospecifities are essentially the same in the hydrolysis of representative monocyclic and acyclic diester substrates (I), (III) (→ (II), (IV)).
ChemInform Abstract: Structural Study of Lithium, Magnesium, and Barium Vanadate Glasses by Means of Moessbauer Spectroscopy.
Authors: NISHIDA T. , SARUWATARI S. , TAKASHIMA Y. 
Published: May 2016

AbstractMoessbauer studies on Li2O‐, MgO‐, and BaO‐V2O5 glasses containing 10% Fe2O3 indicate that iron is present as tetrahedral Fe3+ ions which are located at the substitutional sites of V5+ or V4+ ions.
ChemInform Abstract: Characterization of Active Sites in Sulfided Molybdenum/Alumina Hydrodesulfurization (HDS) Catalysts.
Authors: MAEZAWA A. , KITAMURA M. , OKAMOTO Y. , IMANAKA T. 
Published: May 2016

AbstractBased on the results of XPS, laser Raman, and IR spectroscopic as well as TPD measurements, it is shown that the structure of Mo sulfides formed on MoO3/Al2O3 catalysts varies with the H2S/H2 ratio in the presulfiding atmosphere.
ChemInform Abstract: Zinc(II) Complexes of Dipropylenetriamine and N‐(2‐Aminoethyl)propane‐1,3‐diamine: A 13C NMR Study.
Authors: DAGNALL S. P. , HAGUE D. N. , MORETON A. D. 
Published: May 2016

AbstractThe major zinc complexes present in aqueous solutions containing the linear title triamines or the triamines and a diamine or amino acid are analyzed by computer and chemical shifts measurements.
ChemInform Abstract: Electrochemistry of Vanadyl Porphyrins in Dimethylformamide.
Authors: KADISH K. M. , SAZOU D. , ARAULLO C. , LIU Y. M. , SAOIABI A. , FERHAT M. , GUILARD R. 
Published: May 2016

AbstractElectrode reactions of (I) are monitored in DMF by cyclic voltammetry, rotating‐disk voltammetry, and spectroelectrochemistry.
ChemInform Abstract: Regioselective Alkylation in the Course of Aldol Condensation Under Phase‐Transfer Catalytic Conditions.
Authors: GU X.‐P. , IKEDA I. , OKAHARA M. 
Published: May 2016

AbstractThe application of the title reaction to octanal (I) yields β,γ‐olefinic aldehydes (IV) if the halides (II) are employed, while the ether (VII) is obtained in the reaction with (V).
ChemInform Abstract: A New Synthetic Route to Aliphatic and Alicyclic Nitriles via Homolytic Desulfuration of α‐(Dithiocarbamoylthio) Nitriles.
Authors: YANAGAWA M. , MORIYA O. , WATANABE Y. , UENO Y. , ENDO T. 
Published: May 2016

AbstractAs reported previously, eight derivatives of type (V) are prepared by mono‐ or dialkylation of the intermediate (III) in yields ranging from 40 to 93%.
ChemInform Abstract: The Direct Trifluoromethylation of Aryl Chlorides Using Burton′s Reagent.
Authors: CLARK J. H. , MCCLINTON M. A. , BLADE R. J. 
Published: May 2016

AbstractReaction of the chlorobenzenes (I) with dibromodifluoromethane (II) and copper in N,N‐dimethylacetamide gives the trifluoromethylbenzenes (III).
ChemInform Abstract: A Simple Preparation of (R)‐(+)‐β‐(3,4,5‐Trimethoxybenzyl)butanolide, and Its Use in the Total Syntheses of Naturally Occurring Dibenzylbutanolide Lignans.
Authors: LALAMI K. , DHAL R. , BROWN E. 
Published: May 2016

AbstractResolution of the racemic hemisuccinate (I) and subsequent reduction with calcium borohydride yield the butanolide (R)‐(+)‐(II) which is coupled with the benzylic bromides (III), producing isoyatein (IVa) and cubebinone (IVb).
ChemInform Abstract: Ytterbium Metal‐Promoted Novel Cross‐Coupling Reaction Between Diaryl Ketones and Electrophiles.
Authors: HOU Z. , TAKAMINE K. , AOKI O. , SHIRAISHI H. , FUJIWARA Y. , TANIGUCHI H. 
Published: May 2016

AbstractThe diaryl ketones (I) are coupled with 2‐octanone (II), acetonitrile (V), the oxiranes (VIII), carbon dioxide (X), and tolane (XIII) in the presence of ytterbium and catalytic amounts of methyl iodide to give the 1,2‐diols (III), acyloins (VI), 1,3‐diols (IX), the hydroxy acids (XI), and the allylic alcohol (XIV).
ChemInform Abstract: Phenylsulfonyloxirane: A Versatile Reagent for Organic Synthesis.
Authors: ASHWELL M. , JACKSON R. F. W. 
Published: May 2016

AbstractPhenylsulfonyloxirane (I) reacts with the halides (II) after lithiation or in the presence of butyllithium, yielding the substituted phenylsulfonyloxiranes (III).
ChemInform Abstract: 2‐Aza‐1,3‐dienes as Novel Precursors for the Synthesis of N‐Unsubstituted β‐Lactams. A Three Step Synthesis of 4‐Acetoxy‐3‐phenoxy‐2‐azetidinone.
Authors: GEORG G. I. , KANT J. , HE P. , LY A. M. , LAMPE L. 
Published: May 2016

AbstractThe azadienes (IV), prepared from the aldehydes (I) and allylamine (II) by basic‐induced rearrangement of the intermediate imines (III), are coupled with the ketenes, derived from acid chlorides (V) to give the azetidinones (VI).
ChemInform Abstract: Synthesis of Amino Acids and Related Compounds. Part 34. Synthesis of Ethyl 2‐(4‐Chlorophenyl)‐5‐(2‐furyl)oxazol‐4‐ylacetate, a Hypolipidemic Agent, and Related Compounds.
Authors: MORIYA T. , SEKI M. , TAKABE S. , MATSUMOTO K. , TAKASHIMA K. , MORI T. , ODAWARA A. , TAKEYAMA S. 
Published: May 2016

AbstractThe N‐(acylmethyl)amides (I) are coupled with the bromoacetate (II) and then subjected to ring closure reaction in the presence of phosphoryl chloride, yielding the oxazol‐4‐ylacetates (IV).
ChemInform Abstract: Synthesis and Diels‐Alder Reactions of 5‐Alkenyl‐1,3‐oxathiole 3‐Oxides. A New Class of Diheterosubstituted 1,3‐Dienes.
Authors: FISHER M. J. , OVERMAN L. E. 
Published: May 2016

AbstractCoupling of the sulfonium methylide, derived from the salt (I), with the α,β‐unsaturated acyl chlorides (II), produces the ylides (III) which are cyclized to form the oxathiole oxides (IV).
ChemInform Abstract: Stable 2‐Thianaphthalenes: Synthesis and Reactions with Electrophiles.
Authors: HORI M. , KATAOKA T. , SHIMIZU H. , NARITA K. , OHNO S. , OGURA H. , TAKAYANAGI H. , IITAKA Y. , KOYAMA H. 
Published: May 2016

AbstractThe stable and crystalline 2‐thianaphthalene derivatives (II) are synthesized from the salts (I) by proton abstraction and their ylide nature is established on the basis of spectral and chemical evidence.
ChemInform Abstract: Synthesis, Antiinflammatory, and Analgetic Activity of 1,6‐Disubstituted Pipecolinic and 6‐Substituted Picolinic Acid.
Authors: MASTAFANOVA L. I. , ZHIKHAREVA G. P. , KUTINA N. N. , SIROKO A. S. , FAERMARK I. F. , SYUBAEV R. D. , SHVARTS G. YA. , MASHKOVSKII M. D. , YAKHONTOV L. N. 
Published: May 2016

AbstractThe 6‐methylpicolinic acid ester (I) is coupled with 4‐nitrobenzaldehyde (II) to give the nitrostyrylpicolinic acid ester (III) which is reduced, forming the amino derivative (IV).
ChemInform Abstract: (.+‐.)‐4‐tert‐Butyl‐3‐cyano‐1‐(4‐ethynylphenyl)‐2,6,7‐trioxabicyclo‐(2.2.2)octa# ne: Synthesis of a Remarkably Potent GABAA Receptor Antagonist.
Authors: PALMER C. J. , COLE L. M. , CASIDA J. E. 
Published: May 2016

AbstractThe key steps in the synthesis of the title compound (IX) are the Lewis acid‐induced rearrangement of the (p‐iodobenzoyloxy)cyanomethyloxetane (V), in situ obtained from the cyanohydrin of the aldehyde (II), and the subsequent palladium catalyzed coupling of the iodide (VI) with the acetylene (VII).
ChemInform Abstract: On the Borylation of Benzene and Naphthalene by Dehalogenation Products of Dichloro(diisopropylamino)borane.
Authors: MELLER A. , BROMM D. , MARINGGELE W. , BOEHLER D. + , ELTER G. 
Published: May 2016

AbstractBenzene (I) reacts with the dichloroaminoborane (II) in the presence of Na/K alloy to give the two carboranes (III) and (IV), together with a number of unidentified products (V).
ChemInform Abstract: One‐Pot Synthesis of 3,4‐Bis(methoxycarbonyl)‐2‐trimethylsilylfurans by Diels‐Alder Reaction.
Authors: TANAKA A. , HARIGAYA Y. , NISHINO N. , NAKAYAMA K. 
Published: May 2016

AbstractHeating the trimethylsilylfurans (I) with dimethyl acetylenedicarboxylate (II) without solvents produces directly the silylfurandicarboxylates (III).
ChemInform Abstract: Reaction of Cyclic Silyl Phosphites with Haloacetones.
Authors: MORITA I. , CHOKAI S. , TSUDA M. , KISE M. , SUGIYAMA M. 
Published: May 2016

AbstractThe cyclic silyl phosphites (III), prepared from the phosphites (I) and hexamethyldisilazane (II), react with iodoacetone (IV) in the presence of scavengers of trimethylsilyl halides such as propylene oxide to give the acetonylphosphonates (V), together with the propenyl phosphates (VI).
ChemInform Abstract: On the Synthesis and Structure of New Penta and Hexacoordinated Organotin Compounds.
Authors: JURKSCHAT K. , KALBITZ J. , DARGATZ M. , KLEINPETER E. , TZSCHACH A. 
Published: May 2016

AbstractThe Grignard reagent, derived from the bis(3‐chloropropyl)ethylenediamine (I), reacts with SnCl4 (II) to form the tricyclic organotin compound (III).
ChemInform Abstract: Preparation and Crystal Structures of (AsPh4)4(Tc4N4O2(ox)6) and (AsPh4)2(TcO(ox)2(Hox))·3 H2O: Technetium Complexes Containing Quadridentate or Unidentate Oxalato Ligands.
Authors: BALDAS J. , COLMANET S. F. , MACKAY M. F. 
Published: May 2016

AbstractThe tetrameric complex (III) with both bridging oxo and bridging quadridentate oxalato groups crystallizes in the space group P21/n with Z=4.
ChemInform Abstract: Synthesis of the First Example of a 1,3,4,6‐Tetraphosphahexatriene Complex.
Authors: GALINDO DEL POZO A. , CAMINADE A.‐M. , DAHAN F. , MAJORAL J.‐P. , MATHIEU R. 
Published: May 2016

AbstractThe phosphorus dichlorides (I) undergo coupling reaction in the presence of the iron hydrido complex (II), forming the tetraphosphahexatriene complex (III), together with the iron complexes (IV).
ChemInform Abstract: Lewis‐Base Adducts of Group 11 Metal(I) Compounds. Part 39. A Novel Series of 1:1, 2:1, and 3:1 Heterobimetallic Adducts from the Reaction of Copper(I) Halides with Tris(dithiocarbamato)cobalt(III) Complexes.
Authors: ENGELHARDT L. M. , HEALY P. C. , SHEPHARD R. M. , SKELTON B. W. , WHITE A. H. 
Published: May 2016

AbstractDilute solutions of Co(S2CNEt2)3 in MeCN form on standing over solid CuBr, after a period of days, the complex (I), which crystallizes in C2/c with Z=4.
ChemInform Abstract: Coordinative Abilities of Ligands Which Favor S,S Chelation: Copper(I) Halide Complexes of N,N′‐Diphenyldithiomalonamide. The Crystal and Molecular Structure of Bis(N,N′‐diphenyldithiomalonamide)copper(I) Iodide‐Methanol (2/1).
Authors: BATTAGLIA L. P. , BONAMARTINI CORRADI A. , MARZOTTO A. , MENABUE L. , PELLACANI G. C. 
Published: May 2016

AbstractThe IR, 1H and 13C NMR spectroscopic properties of the complexes (I) are discussed in the light of the results of an X‐ray structure analysis of (Ia) (space group P1, Z=2).