bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Reactions of Coordinated Ligands. Part 43. Alkyne Linking Reactions at Dimetal Centers. Synthesis and Structures of (Mo2(μ‐(σ,η3:η2:η3,σ‐C8H4tBu4))(η‐C5H5)2), (Mo2(μ‐(σ,η3:η3,σ‐CH=CHtBuC6H2tBu3))(η‐C5H5)2), and (FeMo(CO)2(C4Me2Ph2)(η‐C5H5)2).
Authors: GREEN M. , JETHA N. K. , MERCER R. J. , NORMAN N. C. , ORPEN A. G. 
Published: May 2016

AbstractAddition of the cyclopentadienyldicarbonylferrate (II) to a solution of the Mo complexes (Ia) and (Ib) affords the two Mo2 title complexes (III) and (IV), and the MoFe title complex (Va) and its analogue (Vb), respectively.
ChemInform Abstract: Structural Changes at the Titania Surface and Their Relationship to Metal‐Support Interactions in Rh/TiO2 Catalysts.
Authors: BLASCO M. T. , CONESA J. C. , SORIA J. , GONZALEZ‐ELIPE A. R. , MUNUERA G. , ROJO J. M. , SANZ J. 
Published: May 2016

AbstractNMR, XPS, and ESR results are indicative of reconstruction processes at the support surface of Rh/TiO2 catalysts during high‐temp.
ChemInform Abstract: The Synthesis of a Series of (α‐Amino)indol‐3‐yl Ketones.
Authors: SANCHEZ J. P. , PARCELL R. F. 
Published: May 2016

AbstractIndole (I) is coupled with the acyl chlorides (II) to form the 3‐indolyl ketones (IIIa) and (IIIb) which are N‐alkylated, yielding (IIIc) ‐(IIIe).
ChemInform Abstract: Sulfur Nitride in Organic Chemistry. Part 17. Preparation of 1,8‐Diaminocarbazole.
Authors: TAKAHASHI K. , EGUCHI H. , SHIWAKU S. , HATTA T. , KYOYA E. , YONEMITSU T. , MATAKA S. , TASHIRO M. 
Published: May 2016

AbstractUnder the optimized conditions shown in the scheme, treatment of the diols (Ia) and (Ib) with N4S4 (II) yields exclusively the benzothiadiazole (III).
ChemInform Abstract: Stereochemical Control in Microbial Reduction. Part 7. Enantioselective Reduction of 2‐Methyl‐3‐oxopropionate by Bakers′ Yeast.
Authors: NAKAMURA K. , MIYAI T. , USHIO K. , OKA S. , OHNO A. 
Published: May 2016

AbstractThe title reduction of 16 esters of type (I) (undergoing racemization via the enol form) shows high enantioselectivity if the substrate contains a bulky ester group.
ChemInform Abstract: Ion‐Molecule Reactions Involving H3O+, H2O+, and OH+ at Thermal Energy.
Authors: SHUL R. J. , PASSARELLA R. , DIFAZIO L. T. JUN. , KEESEE R. G. , CASTLEMAN A. W. JUN. 
Published: May 2016

AbstractThermal energy rate coefficients are measured and reaction pathways are identified for a variety of reactions between the title cations and CS2, H2S, SO2, NO, NO2, N2O, N2, O2, CH4, CO2, CO, NH3, and H2.
ChemInform Abstract: Face Selectivity in Diels‐Alder Reactions of Chiral Dienes Containing Allylic Substituents.
Authors: FISHER M. J. , HEHRE W. J. , KAHN S. D. , OVERMAN L. E. 
Published: May 2016

AbstractCycloaddition of various conformationally locked 1(E)‐substituted 1,3‐dienes containing a chiral center at the allylic position, such as (I), to N‐phenylmaleimide (II) in various solvents such as toluene, THF, CH2Cl2 or MeOH occurs in most cases from the diene face anti to the allylic substituent to give the adducts (IV); only when the reaction of (Ia) is carried out in toluene as solvent, the syn adduct (IIIa) is formed with a weak preference.
ChemInform Abstract: Regiocontrol by Electron Withdrawing Groups in the Rh‐Catalyzed C‐H Insertion of α‐Diazoketones.
Authors: STORK G. , NAKATANI K. 
Published: May 2016

AbstractThe α‐diazoketones (I) and (III) cyclize in the presence of a rhodium catalyst to give the cyclopentanones (II) and (IV).
ChemInform Abstract: Modification of Photochemical Reactivity by Zeolites: Norrish Type I and Type II Reactions of Benzoin Derivatives.
Authors: CORBIN D. R. , EATON D. F. , RAMAMURTHY V. 
Published: May 2016

AbstractPhotolysis of alkyl benzoin ethers (Ia) and alkyl deoxy benzoins (Ib) in zeolites (included by stirring in trimethylpentane followed by filtration and degassing) is dramatically different from that in benzene.
ChemInform Abstract: Autoxidation of Thiols Catalyzed by a Tetraaza(14)annulene‐Cobalt(II) Complex.
Authors: SAKATA K. , WADA S. , HASHIMOTO M. 
Published: May 2016

AbstractIn contrast to the Ni complex the Co complex (I) catalyzes the autoxidation of (II) under mild conditions.
ChemInform Abstract: Mixded Dimerization of Perfluoroisobutylene with Fluoroolefins Catalyzed by Fluoride Anions.
Authors: POSTOVOI S. A. , KAGRAMANOVA E. M. , ZEIFMAN YU. V. 
Published: May 2016

AbstractPerfluoroisobutylene (I) reacts with cesium fluoride to give the perfluoro‐tert‐butyl anion which is trapped with polyfluoroolefins such as (II) or (IV), producing the substitution products (III) and (V).
ChemInform Abstract: Synthesis and Properties of Aminoarylsulfonanilidesulfonic Acids.
Authors: BLUS K. , KRASKA J. 
Published: May 2016

AbstractThe nitrotoluenes (I) react with chlorosulfonic acid (II), yielding the toluenesulfochlorides (III) which form the sulfonanilides (V) by coupling with the sulfanilic acids (IV).
ChemInform Abstract: The Synthesis of Some Alkylbenzocarbazoles.
Authors: KATRITZKY A. R. , WANG Z. 
Published: May 2016

AbstractCyclocondensation of the phenylhydrazines (I) with the tetralones (II) or (V) or cyclohexanone (VIII) in acidic solutions forms the carbazoles (IV), (VII), or (IX) after dehydrogenation.
ChemInform Abstract: Pictet‐Spengler Reactions in Aprotic Media. Stereospecific Conversion of Optically Active cis‐1,3‐Disubstituted 1,2,3,4‐Tetrahydro‐β‐carbolines into Their Corresponding trans‐Diastereomers.
Authors: ZHANG L.‐H. , COOK J. M. 
Published: May 2016

AbstractCyclocondensation reaction of methylbenzyltryptophan methyl ester (I) with the formylpropionate (II) in refluxing benzene results with predominance of the trans‐tetrahydro‐β‐carboline (III).
ChemInform Abstract: Displacement and Electron‐Transfer Reactions of Substituted 2‐Chloro‐1,3,2‐benzodioxastiboles with Bases.
Authors: MCEWEN W. E. , TIEN J.‐H. , REMBETSY L. M. , KALBACHER B. J. , LUBINKOWSKI J. J. , MARI F. , DEVINCENZO S. , SALGUEIRO R. M. , HOU J. , ALVAREZ J. A. 
Published: May 2016

AbstractThe chlorobenzodioxastiboles (III) are prepared from the corresponding catechols (I) and antimony trichloride (II).
ChemInform Abstract: Reactions of Phenylethyneselenol Potassium Salt with N‐Aryl Carbohydrazonoyl Chlorides.
Authors: ZACHINYAEV YA. V. , BOBROV A. I. 
Published: May 2016

AbstractThe ethyneselenol salt (II), prepared from the selenodiazole (I), reacts with the carbohydrazonoyl chlorides (III) in the presence of triethylamine to give the selenodiazines (IV).
ChemInform Abstract: Synthesis and Psychotropic Properties of Furyl‐ and Thienylgermatranes.
Authors: LUKEVICS E. , IGNATOVICH L. , PORSIUROVA N. , GERMANE S. 
Published: May 2016

Abstract2‐Furyltribromogermane (III) is prepared by insertion reaction of the germanium dibromide dioxanate complex (II) into the bromo‐carbon bond of 2‐bromofuran (I).
ChemInform Abstract: A Novel Molybdenum(0) Dinitrogen Complex Containing Crown Thioether as the Sole Auxiliary Ligand: trans‐Mo(N2)2Me8(16)aneS4 (Me8(16)aneS4: 3,3,7,7,11,11,15,15‐Octamethyl‐1,5,9,13‐tetrathiacyclohexadecane).
Authors: YOSHIDA T. , ADACHI T. , KAMINAKA M. , UEDA T. , HIGUCHI T. 
Published: May 2016

AbstractThe title Mo(0) complex (Ib) is obtained together with another solid (ca.
ChemInform Abstract: Crystal Structures of (MeC5H4)4U2(μ‐NR)2. Unsymmetrical Bridging, R: Ph, and Symmetrical Bridging, R: SiMe3, Organoimide Ligands in Organoactinide Compounds.
Authors: BRENNAN J. G. , ANDERSEN R. A. , ZALKIN A. 
Published: May 2016

AbstractThe U(IV) complexes (III) with the bridging organoimide ligands are prepared by valence disproportionation and ligand redistribution reaction according to the scheme.
ChemInform Abstract: Chiral Metal Complexes. Part 26. Metal Complexes of the New Stereospecific Tetraamine Ligand 3R,4R‐ and 3S,4S‐Diphenyl‐1,6‐di(2‐pyridyl)‐2,5‐diazahexane.
Authors: FENTON R. R. , VAGG R. S. , WILLIAMS P. A. 
Published: May 2016

AbstractStarting with stilbenediamine, which is prepared and resolved by known methods, the new N4 ligand (I) is synthesized in its racemic and enantiomeric forms.
ChemInform Abstract: Synthesis and Physical Properties of a Dinuclear Tantalum‐Cobalt Radical with Spin Localized at One Metal Center.
Authors: GOLDBERG K. I. , BERGMAN R. G. 
Published: May 2016

AbstractThe stable Ta‐Co radical (III) is prepared according to the scheme and characterized by X‐ray structure analysis (space group P212121, Z=4), 1H NMR and EPR spectra.
ChemInform Abstract: Oxidation Reaction of the Copper(I) Phenoxo Complex ((phen)(Ph3P)Cu(OPh)): The Formation of the Copper(II) Derivative ((phen)Cu(OPh)(OC6H4‐2‐(OH))), Having a Catecholate Group Derived from Phenol Hydroxylation Reaction.
Authors: LA MONICA G. , ANGARONI M. A. , CARIATI F. , CENINI S. , ARDIZZOIA G. A. 
Published: May 2016

AbstractDue to the important role of copper‐alkoxo derivatives in metal‐assisted transformations of various organic substrates by Cu(I) the reactions of the bicarbonato complex (I) with phenol (II) under an inert atmosphere and in the presence of O2, and with catechol (V) under oxidative conditions are studied.
ChemInform Abstract: Dicarbonylrhodium(I) Complexes of 8‐Azaadenine Bases with N1 or N3 as Metal Binding Sites.
Authors: SHELDRICK W. S. , GUENTHER B. + 
Published: May 2016

AbstractThe reaction of (Rh(CO)2Cl)2 with the appropriate 8‐azaadenine in MeOH yields the complexes (I) or (II).
ChemInform Abstract: A Facile Preparation of D‐Penicillamine. Reaction of Benzylpenilloic Acid with Arylamines.
Authors: OGAWA T. , TOMISAWA K. , SOTA K. 
Published: May 2016

AbstractReaction of the penilloic acid (I) with aniline (II) yields D‐penicillamine (III), together with the diastereomeric cyclization products (IV) and (V).
ChemInform Abstract: Oxidative Ring Contraction of Benzeneselenenate Adducts of Glycal Ethers. Synthesis of Showdomycin Analogues.
Authors: KAYE A. , NEIDLE S. , REESE C. B. 
Published: May 2016

AbstractThe D‐glucal (I) reacts with benzeneselenenyl chloride (II) to give the adduct (III).
ChemInform Abstract: From Germaphosphene to Germathia‐ (or Germaselena‐)phosphiranes.
Authors: ANDRIANARISON M. , COURET C. , DECLERCQ J.‐P. , DUBOURG A. , ESCUDIE J. , RANAIVONJATOVO H. , SATGE J. 
Published: May 2016

AbstractReaction of sulfur (II) or selenium with the germaphosphene (I) leads to the new stable three‐membered heterocycles (III).
ChemInform Abstract: Synthesis and Characterization of a Complete Series of (MM′(dppm)2(CH3CN)2)(BF4)2 Complexes (M, M′: Ni, Pd, Pt).
Authors: MIEDANER A. , DUBOIS D. L. 
Published: May 2016

AbstractA complete series of the homo‐ and heterobimetallic title complexes of the types (IV) and (V) are prepared by comproportionation of appropriate metal(0) and metal(II) complexes as shown for the NiNi complexes (IVa).
ChemInform Abstract: High Temperature Fuel Cell with Ceria‐Yttria Solid Electrolyte.
Authors: YAHIRO H. , BABA Y. , EGUCHI K. , ARAI H. 
Published: May 2016

AbstractSolid electrolytes of the CeO2‐Y2O3 system exhibit high ionic conductivity and high ionic transference number of oxygen in the temp. range 600‐1000 °C. High current density and electrical power can be obtained from a (CeO2)0.9(YO1.5)0.1 fuel cell operated at 600‐800 °C. The ceria‐based oxide fuel cell is strongly affected by the cathode material used and La0.6Sr0.4CoO3 is found to yield better results than Pt.
ChemInform Abstract: Electrochemical Intercalation of Lithium in V2O5 in Molten Dimethylsulfone at 130 °C.
Authors: FAUCHEUR C. , MESSINA R. , PERICHON J. 
Published: May 2016

AbstractA comparison of theoretical and experimental galvanostatic discharge/charge curves indicates that in molten dimethylsulfone Li behaves as an ideally dispersed solute in the V2O5 host.
ChemInform Abstract: Unusual Hyperporphyrin Spectra for Bis(thiolato)rhodium(III) Octaethylporphyrins and Generation of the Superoxide Anion by the Complexes.
Authors: SAKURAI H. , UCHIKUBO H. , ISHIZU K. , TAJIMA K. , AOYAMA Y. , OGOSHI H. 
Published: May 2016

AbstractThe structure of the title complexes, prepared from the chloro‐rhodium(III) complex, aliphatic or aromatic thiol compounds, and tetrabutylammonium hydroxide in organic solvents, is characterized by comparing their electronic absorption spectra with the spectra of thiolato adducts of cytochrome P‐450 and its cobalt‐substituted enzymes.
ChemInform Abstract: Kinetics of the Formation of E‐ and Z‐Enols in the Thermolysis of 2‐Diazo‐1,3‐dimesityl‐1,3‐propanedione in Nucleophiles.
Authors: MEIER H. , WENGENROTH H. , LAUER W. , VOGT W. 
Published: May 2016

AbstractThe thermolysis of (I) in piperidine (IIa) and morpholine (IIb) (EtOH is studied kinetically as well) leads to enols (IV) and (V).
ChemInform Abstract: Intramolecular Diels‐Alder Reaction with Furan‐Diene. Comparison of Reactivity and Stereoselectivity Within a Set of Structurally Related Substrates of Potential Use in Gibberellin Total Synthesis.
Authors: APPENDINO G. , HOFLACK J. , DE CLERCQ P. J. , CHIARI G. , CALLERI M. 
Published: May 2016

AbstractThe reactivity and stereoselectivity of the intramolecular cycloaddition of structurally related Diels‐Alder precursors such as (I), (IV) and (VI) is studied.
ChemInform Abstract: Knoevenagel Reactions of Aldehydes with Carboxy Compounds. Part 1. Reactions of p‐Nitrobenzaldehyde with Active Methine Compounds.
Authors: TANAKA M. , OOTA O. , HIRAMATSU H. , FUJIWARA K. 
Published: May 2016

AbstractThe reaction of aldehyde (I) with acids (II) in the presence of Py (or another tert. amine) proceeds via a reversible formation of hydroxy intermediate (III) (isolable) which decarboxylates (rate determining step) to give compound (IV) (Hann and Lapworth mechanism).
ChemInform Abstract: Metal‐Catalyzed Cyclization of Enallenes.
Authors: TROST B. M. , TOUR J. M. 
Published: May 2016

AbstractThe Ni‐Cr mediated cyclization of enallenes such as (III) (obtained from the acetylene (I)), (V), (VIIa), (VIIb), (X) gives rise to products such as (IV), (VI), (VIII), (IX) or (XI).
ChemInform Abstract: Some Studies on 6,7‐Unsaturated Carbonyl Radical Cyclizations.
Authors: CRICH D. , FORTT S. M. 
Published: May 2016

AbstractTributylstannane (II) reacts with the phenylselenol esters (I) in the presence of AIBN to give the aldehydes (III) and mixtures of cyclic ketones (IV) and (V).
ChemInform Abstract: A Convenient Synthesis of Sterically Hindered Geminal Dibromides.
Authors: GUZIEC F. S. JUN. , SANFILIPPO L. J. 
Published: May 2016

AbstractThe gem‐dibromides (II) are prepared from the hydrazones (I) upon treatment with two equivalents of bromine and excess triethylamine or from the diazo compounds (III) and one equivalent of bromine.
ChemInform Abstract: Organic Synthesis Using Haloboration Reactions. Part 14. E‐(2‐Bromoethenyl)diisopropoxyborane. A New Building Block for E‐Olefins.
Authors: HYUGA S. , YAMASHINA N. , HARA S. , SUZUKI A. 
Published: May 2016

AbstractThe vinylic zinc chloride (I) is treated with various bromovinylboranes, e.g. (II) or (VII), in the presence of a Pd(II) catalyst and then coupled with phenyl iodide (IV) to give mixtures of the diene (V) and the styrene (VI).
ChemInform Abstract: Synthesis and Crystal Structure of S‐(1‐Benzoyl‐2‐bis‐methylthio)vinyl‐piperidino‐dithiocarbamate.
Authors: DOELLING W. + , KHOUDARY K. , AUGUSTIN M. , BAUMEISTER U. , HARTUNG H. 
Published: May 2016

AbstractThe reaction of the benzoyl compound (and that of some para‐substituted analogues) with CS2 (II) is shown to depend on the conditions used.
ChemInform Abstract: Diastereoselectivity Control Elements. Acyclic Diastereocontrol in Formation and Reactions of γ‐Hydroxysulfones.
Authors: TROST B. M. , MERLIC C. A. 
Published: May 2016

AbstractThe alkylation of sulfones such as (I), (IV), (IX) with epoxides such as (II), (V), (VII), (X), or (XII) leads to unexpected control of stereochemistry under kinetic or thermodynamic conditions.
ChemInform Abstract: A Convenient One‐Pot Synthesis of 4‐Substituted 3,5‐Bis(alkoxycarbonyl)‐4,5‐dihydroisoxazole 2‐Oxides from Aldehydes and Nitroacetic Acid Esters in a Solid‐Liquid Reaction System and Subsequent Deoxygenation.
Authors: MELOT J.‐M. , TEXIER‐BOULLET F. , FOUCAUD A. 
Published: May 2016

AbstractThe aldimines (III), prepared from aldehydes (I) and isopropylamine (II), react with the nitroacetates (IV), forming the trans‐substituted dihydroisoxazole N‐oxides (V).
ChemInform Abstract: Cyclic Allylamine‐Enamine Systems. Part 8. Isomerization Using Rhodium Complexes. 3‐Aminoalkylidene‐3H‐indoles. Part 5. 6,7‐Dihydroindolo(3,2‐a)quinolizine and 1,2,3,4,6,7‐Hexahydroindolo(3,2‐a)quinolizine.
Authors: SALAS M. , AL‐KHAWAJA I. K. , THOMAS M. J. , JOULE J. A. 
Published: May 2016

AbstractThe tetracyclic compound (II), which was previously synthesized from the cyclic allylamine (I) via a multi‐step procedure, can be directly obtained from (I) using the reaction conditions A).
ChemInform Abstract: First Asymmetric Synthesis of β‐Binaphthyl‐Supported Silanes, Stannanes, and Boranes.
Authors: GROSS U.‐M. , BARTELS M. , KAUFMANN D. 
Published: May 2016

AbstractThe binaphthyl (I) reacts after twofold lithiation with the silane (II) to give the silepin (IIIa) and with the stannane (V) to give the stannepin (VIa).
ChemInform Abstract: Preparation and Multinuclear NMR and IR Spectroscopic Characterization of Some Complexes of Acetyldiphenylphosphine, Diphenyl(2‐thienyl)phosphine, Bis(2‐thienyl)phenylphosphine and Cyanodiphenylphosphine.
Authors: VARSHNEY A. , GRAY G. M. 
Published: May 2016

AbstractThe coordination chemistry of the unusual bifunctional title ligands is investigated.
ChemInform Abstract: Transition‐Metal NMR Spectroscopy. Part 11. Synthesis and 1H, 13C, and 57Fe NMR Spectra of Mono‐ and Bis(tricarbonyl(η4‐diene)iron), and (η3‐Allyl)tetracarbonyliron Trifluoroborate Complexes.
Authors: ADAMS C. M. , CERIONI G. , HAFNER A. , KALCHHAUSER H. , VON PHILIPSBORN W. , PREWO R. , SCHWENK A. 
Published: May 2016

Abstract1H, 13C, and 57Fe NMR spectra are reported for 73 olefinic and allylic organoiron complexes of the type shown in the scheme.
ChemInform Abstract: Synthesis of the Hexaamine Ligand 1,4,7‐Tris(3‐aminopropyl)‐1,4,7‐triazacyclononane: Reactivity and X‐Ray Crystal Structures of the Nickel(II) and Cobalt(III) Complexes.
Authors: BUSHNELL G. W. , FORTIER D. G. , MCAULEY A. 
Published: May 2016

AbstractThe title ligand (III) is prepared according to the scheme.
ChemInform Abstract: Alkyl 2‐(Diphenylmethyleneamino)acrylates in the Synthesis of α‐Amino Acids.
Authors: TARZIA G. , BALSAMINI C. , SPADONI G. , DURANTI E. 
Published: May 2016

AbstractThe acrylates (VI) mentioned in the title are prepared from the alkyl N‐diphenylmethyleneglycinates (I) via the Mannich condensation products (III).
ChemInform Abstract: Methyl 4‐Hydroxy‐5‐iodo‐2,3‐dimethoxy‐6‐methylbenzoate: The Aromatic Fragment of Calichemicin γI 1α. Synthesis, X‐Ray Crystallographic Analysis, and Properties.
Authors: NICOLAOU K. C. , EBATA T. , STYLIANIDES N. A. , GRONEBERG R. D. , CARROLL P. J. 
Published: May 2016

AbstractThe title compound (VI) is obtained as a crystalline solid.
ChemInform Abstract: Etching of Tungsten and Tungsten Silicide Films by Chlorine Atoms
Authors: FISCHL D. S. , RODRIGUES G. W. , HESS D. W. 
Published: May 2016

Abstractis performed both within and downstream from a Cl2 plasma discharged at 200 mtorr below 150 °C. Without a discharge, molecular chlorine does not etch the films at the temp. studied.
ChemInform Abstract: Two New Alkaline‐Earth Oxoindates: BaCa2In6O12 (I) and BaSr2In6O12 (II).
Authors: LALLA A. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractSingle crystals of the compounds are obtained from mixtures of BaCO3, CaCO3 (SrCO3), and In2O3 (pressed pellets, 1. 1000 °C, 24 h; 2. CO2‐laser, > 1800 °C).
ChemInform Abstract: Reaction of Ynamino Ketones with Bifunctional Reagents.
Authors: OSTROUMOV I. G. , TSIL'KO A. E. , MARETINA I. A. , PETROV A. A. 
Published: May 2016

AbstractThe reactions between the ynamino ketones (I) and ethylenediamine (II), ethanolamine (IV), o‐aminophenol (VIa) and o‐aminothiophenol (VIb) yield five‐membered heterocycles with two heteroatoms, viz the derivatives (III), (V) and (VII), whereas o‐phenylenediamine (VIII) affords the diazepine derivatives (IX).
ChemInform Abstract: Acid‐Catalyzed Condensation of Isoprene with Hydroxypropiophenones: Synthesis of 2,2‐Dimethylchromans and Some New 2‐Amino‐ and 2‐Mercapto‐4‐aryl‐5‐methylthiazoles.
Authors: AHLUWALIA V. K. , NAYAL L. , BALA S. , RAGHAV S. 
Published: May 2016

AbstractSince 2,2‐dimethylchromans and thiazoles are known to possess many pharmacologically interesting properties, further derivatives of these compounds are required.
ChemInform Abstract: Phase Equilibria in the System Li2O‐K2O‐NiO‐V2O5.
Authors: SURAT L. L. , FOTIEV A. A. 
Published: May 2016

AbstractThe three systems Li2O‐NiO‐V2O5, K2O‐NiO‐V2O5 and Li2O‐K2O‐V2O5 are investigated by X‐ray and optical analyses.
ChemInform Abstract: The Calcium Sulfate‐Induced Corrosion of Iron‐Chromium Alloys
Authors: CHOI S. H. , STRINGER J. 
Published: May 2016

Abstractis studied at 1223 K using a CaSO4/CaO powder bed and an external environment of 1.2% CO/98.8% CO2 (P(O2): 10‐11.2 atm).
ChemInform Abstract: Photochemistry of Colloidal Semiconductors. Part 28. Photo‐Electron Emission from Cadmium Phosphide Particles in Aqueous Solution.
Authors: HAASE M. , WELLER H. , HENGLEIN A. 
Published: May 2016

AbstractLaser illumination at 308 nm of small Cd3P2 particles in aqueous solution leads to the formation of hydrated electrons which are detected by their strong optical absorption.
ChemInform Abstract: Synthesis of Bicyclic and Polycyclic Alkenes via Palladium‐Catalyzed Intramolecular Arylation and Vinylation.
Authors: LAROCK R. C. , SONG H. , BAKER B. E. , GONG W. H. 
Published: May 2016

AbstractThe palladium diacetate‐catalyzed cyclization of vinylic or phenylic iodides containing cycloalkenyl groups is performed under various conditions.
ChemInform Abstract: Half‐Cage Compounds by Radical Reactions with Thiophenol and Bromotrichloromethane from Diels‐Alder Adducts of Benzvalene with Cyclopentadiene Derivatives.
Authors: FREUND S. , HENNEBERGER H. , CHRISTL M. 
Published: May 2016

AbstractThe pentacyclic compounds (IV) obtained by Diels‐Alder reactions (e.g.
ChemInform Abstract: Photochemical Reactions of Triarylmethyl Peroxides. Part 2. α‐ and β‐Naphthyldiphenylmethyl Peroxide.
Authors: NECKERS D. C. , LINDEN S.‐M. , TALIANO R. J. , WILLIAMS B. L. , ZAKRZEWSKI A. 
Published: May 2016

AbstractPhotolysis of bis(triarylmethyl) peroxide (I) gives the phenols (II) and (III), the ketones (IV) and (V), and the olefin (VI), together with some other by‐products.
ChemInform Abstract: Enantioselective Catalysis. Part 43. Enantioselective Catalytic Transfer Hydrogenation of α,β‐Unsaturated Carboxylic Acids Using Triethylammonium Formate.
Authors: BRUNNER H. , LEITNER W. 
Published: May 2016

AbstractThe catalytic properties of Rh complexes in the enantioselective hydrogenation of olefins and in the decomposition of formic acid to give H2 and CO2 are combined in the title reaction, i.e. the hydrogenation of (I) and (III) by procedure A) (bppm being the most efficient out of several chiral ligands tested).
ChemInform Abstract: Aprotic Conjugate Addition of Allyllithium Reagents Bearing Polar Groups to Cyclic Enones. Part 2. 2‐Alkyl‐, 2,3‐Dialkyl‐, and 1,3‐Dialkylallyl Systems.
Authors: HAYNES R. K. , KATSIFIS A. G. , VONWILLER S. C. , HAMBLEY T. W. 
Published: May 2016

AbstractThe validity of the transition state model described previously (cf.
ChemInform Abstract: Cocondensation of Molybdenum Atoms with the Bulky Tertiary Diphosphine 1,2‐Bis(diisopropylphosphino)ethane: The Molecular Structure of (MoH4(iPr2PCH2CH2PiPr2)2).
Authors: CLOKE F. G. N. , GIBSON V. C. , GREEN M. L. H. , MTETWA V. S. B. , PROUT K. 
Published: May 2016

AbstractThe cocondensation of Mo vapor at 77 K with the sterically demanding diphosphine (preparation described) does not afford the homoleptic bis(ligand) complex of Mo but rather the stereochemically non‐rigid tetrahydrido title complex (yield given in g), which crystallizes in Ccca with Z=4.