bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: O,O‐ and O,S‐Dialkyl‐N‐(silatranylalkyl)amido(thio)phosphates.
Authors: VORONKOV M. G. , KUDYAKOV N. M. , ALBANOV A. I. 
Published: May 2016

AbstractDie Trieth‐oxysilane (I) werden mit Triethanolamin (II) zu den substituierten Silatranen (III) umgeethert.
ChemInform Abstract: New Reagents. Part 38. Addition of (α‐Lithioalkyl)diphenylarsane Oxides to Benzaldehyde and Acetophenone with Extreme Diastereoselectivity.
Authors: KAUFFMANN T. , KIEPER G. , KLAS N. 
Published: May 2016

AbstractIn contrast to α‐lithiated alkyldiphenylarsine oxides (II) react extremely diastereoselectively with benzaldehyde or acetophenone to form the alcohols erythro‐(IIIa) and ‐(IV), whereasby reaction with aliphatic aldehydes a mixture of two diastereoisomeric alcohols(IIIb) and (IIIc) is obtained.
ChemInform Abstract: Migrations of the Phenylseleno Group Along the Perimeter of the Cyclopentadiene Ring.
Authors: MIKHAILOV I. E. , MINKIN V. I. , KLENKIN A. A. , OLEKHNOVICH L. P. 
Published: May 2016

AbstractThe lithium salt (I), on reaction with PhSeCl (II), affords the phenylselenoderivative (III) as the compound of interest along with further products.
ChemInform Abstract: Synthesis and Characterization of Eu(III) Complexes with Chiral Schiff Base Ligands Derived from Salicylaldehydes and Amino Alcohols.
Authors: CALIENNI J. J. , BRITTAIN H. G. 
Published: May 2016

AbstractOptically active Schiff base ligands (I) have been formed by condensation of various salicylaldehydes with a series of chiral amino alcohols.
ChemInform Abstract: [U3(μ3‐Cl)2(μ2‐Cl)3(μ1,η2‐AlCl4)3(η6‐C6Me6)3][AlCl4]. A Trinuclear Arene Complex of U(III).
Authors: COTTON F. A. , SCHWOTZER W. , SIMPSON C. Q. II 
Published: May 2016

AbstractThe paramagnetic title Complex could be prepared from UCl4, AlCl3, hexamethylbenzene, and aluminum in refluxing toluene by a modified Friedel‐Crafts reaction (yield 55%).
ChemInform Abstract: Synthesis and Structure of the Cationic Tetrahydrofuran Iron Complex [C5Me5(CO)(Me3P)(THF)Fe]+.
Authors: GROETSCH G. + , BOESE R. , MALISCH W. 
Published: May 2016

AbstractThe reaction of the methyl derivative (I) with (Ph3C)PF6 in THF leads to the Complex salt (II), whose structure is determined by X‐ray analysis (space group P2′/c, Z=4).
ChemInform Abstract: Derivatives of 1,2‐Diborabenzene. Part 1. A 1,2‐Diboratabenzene: Lithium Salt and Transition Metal Complexes.
Authors: HERBERICH G. E. , HESSNER B. , HOSTALEK M. 
Published: May 2016

AbstractThe diborane(4) (I) reacts with the Mg derivative(II) to give the liquid diboracyclohexene derivative (III), which on metalation with lithium 2,2,6,6‐tetramethylpiperidide affords the lithium 1,2‐diboratabenzene (IV).
ChemInform Abstract: Preparation and X‐Ray Crystal Structure of (Ph3P)2PtS2N2 . C7H8 : a Reinvestigation of the Reaction of S4N4H4 with (Ph3P)4Pt.
Authors: CHIVERS T. , EDELMANN F. , BEHRENS U. , DREWS R. 
Published: May 2016

AbstractThe title reaction in toluene produces the title complex (I) whose structure is confirmed by X‐ray analysis (space group P1, Z=2).
ChemInform Abstract: Potential Bile Acid Metabolites. Part 10. Syntheses of Stereoisomeric 3,7‐Dihydroxy‐5α‐cholanic Acids.
Authors: IIDA T. , MOMOSE T. , NAMBARA T. , CHANG F. C. 
Published: May 2016

AbstractDie vier stereoisomeren 3,7‐Dihydroxy‐5α‐cholansäuren (Ia)‐(Id) werden ausgehend von der 3‐Oxo‐7α‐hydroxy‐4‐cholensäure (II) nach den im Schema angegebenen Verfahren synthetisiert.
ChemInform Abstract: Regio‐ and Stereoselective Synthesis of Steroidal Amines.
Authors: KOGA T. , NOGAMI Y. , YAMANAKA S. 
Published: May 2016

AbstractDie sukzessive Umsetzung der α,γ‐Dibrom‐α,β‐enone (I) mit den sekundären cyclischen Aminen (II) führt mit hoher Regio‐ und Stereoselektivität zunächst zu den (α′‐Amino‐α‐brom‐enonen (III) und dann zu den α,γ‐Diamino‐enonen (IV).
ChemInform Abstract: Peptide Synthesis by Prior Thiol Capture. Part 1. A Convenient Synthesis of 4‐Hydroxy‐6‐mercaptodibenzofuran and Novel Solid‐Phase Synthesis of Peptide‐Derived 4‐(Acyloxy)‐6‐mercaptodibenzofurans.
Authors: KEMP D. S. , GALAKATOS N. G. 
Published: May 2016

AbstractAusgehend von Dibenzofuran (Ia) wird das Hydroxy‐mercapto‐Derivat (Ie) hergestellt, das als Sulfenylcarbomethoxy‐Derivat (If) geschützt wird.
ChemInform Abstract: Artificial Receptor Recognizing Hydrophobic Carbonyl Compounds.
Authors: TABUSHI I. , NABESHIMA T. , YAMAMURA K. , TSUDA M. 
Published: May 2016

AbstractDas prim.,prim.‐Bis‐((2‐aminoethyl)‐sulfenyl)‐β‐cyclodextrin (Ia) wird auf einem Acryl‐nitril‐Methacrylat‐Polymer als (Ib) immobilisiert.
ChemInform Abstract: Flavonoids Syntheses. Part 4. Syntheses of 2′,3,4′,5,5′,6,7,8‐Octaoxygenated Flavones.
Authors: IINUMA M. , TANAKA T. , MIZUNO M. , MABRY T. J. 
Published: May 2016

AbstractBeschrieben wird die Synthese der Verbindungen (I) und (II).
ChemInform Abstract: Synthesis of 12(S),20‐, 12(S),19(R)‐, and 12(S),19(S)‐Dihydroxyeicosa‐cis‐5,8,14‐trans‐10‐tetraenoic Acids, Metabolites of 12(S)‐HETE.
Authors: MANNA S. , VIALA J. , YADAGIRI P. , FALCK J. R. 
Published: May 2016

AbstractAusgehend von dem D‐Glucofuranose‐Derivat (I) erhält man über die Verbindungen (II)‐(IV) den Aldehyd (V).
ChemInform Abstract: Electrocatalysis of CO2 Reduction at Surface Modified Metallic and Semiconducting Electrodes.
Authors: CABRERA C. R. , ABRUNA H. D. 
Published: May 2016

AbstractElectrodes have been modified by coating with electropolymerized films of [Re(CO)3(4‐vinyl,4′‐Mea2,2′‐bipyridine)Cl].
ChemInform Abstract: Dissolution Kinetics of MgO in Aqueous, Acidic Media.
Authors: BUGAJSKI J. , GAMSJAEGER H. + 
Published: May 2016

AbstractThe dissolution kinetics of MgO single crystals (orientation: {100}, {101}, and {111}) in N2‐saturated HClO4/NaClO4 solutions of constant ionic strenghth (I=1.0 mol kg‐1) are studied using the rotating‐disc method.
ChemInform Abstract: Different Strong Metal ‐ Support Interaction (SMSI) Effects on Rh/ TiO2 and Pt/ TiO2 Catalysts
Authors: RESASCO D. E. , FENOGLIO R. J. , SUAREZ M. P. , CECHINI J. O. 
Published: May 2016

Abstracthave been found after reduction at 770 K. The Variation of the benzene hydrogenation reaction with temp. as well as the TPD of benzene suggests that the SMSI causes an increase in the heat of adsorption of benzene for Pt/TiO2 catalysts, whereas no change in heat of adsorption is evident for Rh/TiOg catalysts.
ChemInform Abstract: Catalytic Reactions on Metal‐supported semiconductors. Oxidation of CO over ZnO Films on Silver.
Authors: WEISS E. , FOLMAN M. 
Published: May 2016

AbstractThe kinetics of the Catalytic CO oxidation over Ag‐supported ZnO films (contaminant‐frequniform in thickness and composition, as shown by AES and SEM) have been studied in a gas‐flow system.
ChemInform Abstract: Application of Infrared Spectroscopy to the Measurement of Surface and Bulk Oxidation/Reduction States of MoO3.
Authors: CHUNG J. S. , BENNETT C. O. 
Published: May 2016

AbstractIt is demonstrated that the background transmission at lower wavenumber is mainly sensitive to the surface oxidation/reduction state of MoO3 and at higher wavenumbers to the subsurface layers.
ChemInform Abstract: Correlation Between Hydrodesulphurization (HDS) Activity and Reducibility of Unsupported MoS2‐Based Catalysts Promoted by Group VIII Metals.
Authors: GOEBOELOES S. + , WU Q. , ANDRE O. , DELANNAY F. , DELMON B. 
Published: May 2016

AbstractThe HDS activity of the Co, Ni, or Fe promoted catalysts prepared by homogeneous sulphide precipitation (HSP), inverse HSP, or by coprecipitation, increases in the sequence M0 FeMo CoMo NiMo.
ChemInform Abstract: Multielectron‐Photoinduced Reduction of Chloroplatinum Complexes: Visible Light Deposition of Platinum Metal.
Authors: CAMERON R. E. , BOCARSLY A. B. 
Published: May 2016

AbstractThe four‐electron reduction of a PtClä′ complex in aqueous alcoholic solution using low‐energy visible photons (488 nm) yields either a colloid or a Pt‐mirror depending on the reaction conditiqns.
ChemInform Abstract: Visible Transients in Gas Phase UV Photolysis of Transition Metal Compounds: Experimental and Theoretical Results for Ni(CO)4.
Authors: ROESCH N. + , KOTZIAN M. , JOERG H. + , SCHROEDER H. + , RAGER B. , METEV S. 
Published: May 2016

AbstractAfter photolysis of Ni(CO)4 with a XeCl laser (308 nm) a luminescence spectrum is obtained.
ChemInform Abstract: Fulvenes, Fulvalenes. Part 49. 1H‐ and 13C‐NMR Investigation of Pentafulvenes.
Authors: BOENZLI P. + , OTTER A. , NEUENSCHWANDER M. , HUBER H. , KELLERHALS H. P. 
Published: May 2016

AbstractThe spectra of the title compounds (I) and (II) have been analyzed.
ChemInform Abstract: Solid‐State Structural Chemistry of Lariat Ether and BiBLE Cation Complexes: Metal Ion Identity and Coordination Number Determine Cavity Size.
Authors: GANDOUR R. D. , FRONCZEK F. R. , GATTO V. J. , MINGANTI C. , SCHULTZ R. A. , WHITE B. D. , ARNOLD K. A. , MAZZOCCHI D. , MILLER S. R. , GOKEL G. W. 
Published: May 2016

AbstractX‐ray crystal structure data are determined for the K+ complexes (IV) and (V) along with the related complexes (VI) to (VIII) reported in preliminary form.
ChemInform Abstract: First Structural Characterization of a Boron‐Centered Radical: X‐Ray Crystal Structure of [Li(12‐crown‐4)2]+[BMes3]±
Authors: OLMSTEAD M. M. , POWER P. P. 
Published: May 2016

AbstractThe reaction of BMes3 (I) (Mes: 2,4,6‐Me3C6H2) in THF with lithium powder under rigorously anaerobic and anhydrous conditions yields after addition of 12‐crown‐4 the title compound in 55% yield.
ChemInform Abstract: Structure and Conformation of Heterocycles. Part 3. Reaction of gem‐Dibromoketones with 2‐Methylaminoethanol.
Authors: L'HARIDON P. , LE ROUZIC A. 
Published: May 2016

AbstractThe gem‐dibromoketones (I) react with the alcohol (II) at room temp; to yield bis‐heterocycles of type (III).
ChemInform Abstract: Electrophilic Rearrangement of Trichloroallylic Alcohol.
Authors: GERMAN L. S. , DELYAGINA N. I. 
Published: May 2016

AbstractUnter dem Einfluß von Schwefelsäure lagert sich der Trichlorallylalkohol (I) zu dem Chloracrylsäurechlorid (II) um.
ChemInform Abstract: New Baeyer‐Villiger‐Like Rearrangement Products from Sensitized Photooxidation of Acetylfuran, Methyl‐ and Ethylfuroate.
Authors: KUO Y.‐H. 
Published: May 2016

AbstractSensitized photooxidation of the furans (I) in acetone (II) yields the new Baeyer‐Villiger‐like rearrangement products (III) and the ether (IVa).
ChemInform Abstract: Photoreaction of 1,4‐Naphthoquinone with Chrysene.
Authors: BUNTE R. , GUNDERMANN K. D. , LEITICH J. , POLANSKY O. E. , ZANDER M. 
Published: May 2016

AbstractChrysen (I) reagiert mit 1,4‐Naphthochinon (II) unter Bestrahlung in geringer Ausbeute zu einem Gemisch des dehydrierten Diels‐Alder‐Addukts (IV) und des Chrysen‐substituierten Naphthochinons (III).
ChemInform Abstract: Pyrolytic, Kinetic, and Theoretical Studies on the Isomerization of Me2HSiCH2 to Me3Si*.
Authors: BARTON T. J. , REVIS A. , DAVIDSON I. M. T. , IJADI‐MAGHSOODI S. , HUGHES K. J. , GORDON M. S. 
Published: May 2016

AbstractVacuum flash pyrolysis of the butenylsilane (I) leads to only the two major products (II) and (III) in the product mixture.
ChemInform Abstract: Reductive Deoxygenation of Alcohols via Esters with Triphenylsilane Under Neutral Conditions.
Authors: SANO H. , OGATA M. , MIGITA T. 
Published: May 2016

AbstractVerschiedene Alkohole werden über ihre Essigsäureester (I) unter den angegebenen Bedingungen zu den entsprechenden Kohlenwasserstoffen (II) reduziert.
ChemInform Abstract: Asymmetric Hydrogenation of N‐(α‐Ketoacyl)‐α‐amino Esters.
Authors: TANI K. , TANIGAWA E. , TATSUNO Y. , OTSUKA S. 
Published: May 2016

AbstractAsymmetrische Hydrierung der (S)‐konfigurierten Ketoamide (I) in Gegenwart optisch aktiver Diphosphin‐Rhodium‐Komplexe, wie (II), liefert optisch aktie N‐(oL‐Hyroxyacyl)‐ α‐aminosäureester (IV) in hohen optischen Ausbeuten.
ChemInform Abstract: Reinvestigation of Thesing′s Synthesis of 2‐Pyridones Using 1‐(Methylthio‐thiocarbonylmethyl)pyridinium Iodide.
Authors: ALVAREZ‐BUILLA J. , LOPEZ BENITO J. , QUINTANILLA G. 
Published: May 2016

AbstractSeveral attempts are made to prepare 4,6‐diaryl‐ 2‐pyridothiones Starting from the title compound (I) using Thesing′s procedure for the synthesis of pyridones.
ChemInform Abstract: N‐Acyl‐α‐imino Acid Derivatives. Part 3. Synthesis of N‐Acyl‐α‐oxoaldimines.
Authors: MALASSA I. , MATTHIES D. 
Published: May 2016

AbstractCondensation of the carboxamides (I) with the α‐oxoaldehydes (II) leads to the hemiamidals (III).
ChemInform Abstract: Bis(cyclobutenylium)chalcogenides and ‐dichalcogenides.
Authors: SEITZ G. , KOEHLER K. + 
Published: May 2016

AbstractDie Reaktion des Chlor‐vinamidiniumchlorids (I) mit Thio‐ bzw. Selenodiaminoquadrain (II) führt zu dem Bis‐(cyclobutenylium)‐sulfid‐ bzw. ‐selenid‐Salz (III), währenddie oxidative Dimerisierung von (II) die Disulfid‐ bzw. Diselenid‐Salze (IV) liefert.
ChemInform Abstract: Regioselective Functionalisation of N,N‐Diethyl‐1,6‐methano[10]annulene‐2‐carboxamides.
Authors: NEIDLEIN R. , WIRTH W. 
Published: May 2016

AbstractLithiation of the methanoannulene carboxamide with BuLi[‐ (II)] followed by quenching with the different electrophiles (III), (IV), (VII), (X), (XII), (XIX) or 12 yields the 10‐substituted derivatives (V), (VI), (VIII), (IX), (XIII), (XX) or (XI), respectively.
ChemInform Abstract: Asymmetric Allylation of Prochiral Aldehydes with a New Enantioselective Allylating Agent Prepared from Stannous Triflate, a Chiral Diamine, and Allyldialkylaluminum.
Authors: MUKAIYAMA T. , MINOWA N. , ORIYAMA T. , NARASAKA K. 
Published: May 2016

AbstractDie prochiralen Aldehyde (I) werden unter den angegebenen Bedingungen enantioselektiv in die entsprechenden sekundären Homoallylalkohole (II) übergeführt.
ChemInform Abstract: A Novel and Useful Synthetic Way to Chiral α‐Sulfinyl Cyclic Ketones by the Acid‐ Catalyzed Reaction of Enol Silyl Ethers of Cyclic Ketones with Chiral Sulfinates.
Authors: HIROI K. , MATSUYAMA N. 
Published: May 2016

AbstractDie Silylenolether (I) cyclischer Ketone reagieren mit dem chiralen Sulfinsäureester (II) stereospezifisch unter Inversion der Konfiguration am Schwefel zu den entsprechenden α‐Sul?nylketonen (III).
ChemInform Abstract: Addition of Phthalimidonitrene to Acetylenic Fatty Acid Esters: Synthesis of Long‐ Chain 2‐Phthalimido‐2H‐azirines.
Authors: ANSARI M. H. , AHMAD F. , AHMAD M. 
Published: May 2016

AbstractDie im Titel genannten Verbindungen (III) bzw. (IV) werden auf dem skizzierten Weg hergestellt.
ChemInform Abstract: Chemistry on Metallic Tin Promoted C‐C Bond Formation. Part 5.
Authors: NOKAMI J. , TAMAOKA T. , OGAWA H. , WAKABAYASHI S. 
Published: May 2016

AbstractDie 2‐Ethoxycarbonyl‐allylbromide (I) setzen sich mit den Aldehyden (II) in Gegenwart von metallischem Zinn oder Aluminium im Zweiphasensystem Wasser/Ether zu den Z‐Methylenbutyrolactonen (III) um.
ChemInform Abstract: On the Ambident Reactivity of 2‐Butyl‐6‐chloro‐1,3‐dimethyl‐cyclohepta‐[c]pyrroliumchloride.
Authors: SEITZ G. , THE H. S. 
Published: May 2016

AbstractDas ambidente Reaktionsverhalten des Azaazulen‐Derivates (I) führt bei der Umsetzung mit den Malonsäurederivaten (II) zu den Produkten (III) und/oder den Heptafulvenen (IV).
ChemInform Abstract: N‐Pyrazolyl‐2‐nitrobenzamides with Antifungal Activity.
Authors: DAIDONE G. , PLESCIA S. , RAFFA D. , SPRIO V. , MILICI M. 
Published: May 2016

AbstractDie Aminopyrazole (I) werden mit o‐Nitrobenzoylchlorid?I) zu den N‐Benzoylderivaten (III) umgesetzt, die weiter in die 4‐Nitrosoderivate (IV) übergeführt werden.
ChemInform Abstract: Hexacarbonylmolybdenum‐Induced Reaction of 2‐Isoxazolines. Formation of Pyridine Derivatives.
Authors: KOBAYASHI T. , IINO Y. , NITTA M. 
Published: May 2016

AbstractDie Umsetzung der Diaryloxazoline (I) mit Mo(CO)6 liefert Gemische aus den .Triarylpyridinen (II) mit den Diarylpropanonen (III) und ‐propenonen (IV) sowie den Diazabicyclen (V), den Diarylpyrrolen (VI), den Acetopheno‐ nen (VII) und Benzaldehyd (VIII).
ChemInform Abstract: 2‐Aza‐1,3‐dienes. Part 4. Synthesis and Properties of 1‐Alkylpyrazone‐imines and Their Tautomers.
Authors: LANG M. , LACROIX A. , PONT C. , FLEURY J.‐P. 
Published: May 2016

AbstractReaction of the azadienes (I) with methylamine.(II) yields the imino system (III) whereas the tautomeric amino systems (VI) are obtained from the respective azadienes (IV) and prim. amines (V).
ChemInform Abstract: The Reaction of 2‐Methylthio‐4,6‐diphenyl‐1,3‐thiazin‐1‐ium Perchlorate with Nucleophiles.
Authors: SHIBUYA I. 
Published: May 2016

AbstractPhenylbenzoylacetylen (I) cyclisiert mit den Thioamiden (II) in Gegenwart von starken Säuren (III) zu den Diphenylthiaziniumsalzen (IV).
ChemInform Abstract: Didecalino‐14‐crown‐4. Highly Lithium Ion Selective Extractant.
Authors: KOBIRO K. , MATSUOKA T. , TAKADA S. , KAKIUCHI K. , TOBE Y. , ODAIRA Y. 
Published: May 2016

AbstractDie im Titel genannte Verbindung (III) wird aus dem Diol (I) und 1,3‐Dichlorpropan (II) in Gegenwart von Lithiumperchlorat hergestellt.
ChemInform Abstract: Hydroboration of Unsaturated Amines. Part 11. Regio‐ and Stereoselectivity of the Hydroboration of N‐Alkyl‐N‐propargylphosphoric Amides.
Authors: BENMAAROUF‐KHALLAAYOUN Z. , BABOULENE M. , SPEZIALE V. , LATTES A. 
Published: May 2016

AbstractDie Reaktion der nach zwei literaturbekannten Methoden hergestellten Phosphorsäureamide (I) mit den Boranen (II) führt zu den ß,y‐Addukten (III) mit praktisch vollständiger Z‐ 140 Konfiguration.
ChemInform Abstract: Phosphorylated Adamantanes. Part 6. The Reaction of 1‐Adamantylethylphosphites with Phosphorus Trichloride.
Authors: YURCHENKO R. I. , KLEPA T. I. 
Published: May 2016

AbstractAn der Gleichgewichtsreaktion des Diadamantylethylphosphits (I) mit Phosphortrichlorid beteiligen sich sowohl die Adamantano‐xyals auch die Alkoxy‐Gruppe als Nucleophil.
ChemInform Abstract: Reaction of 2‐Ethyl‐2‐oxo‐1,3‐dibutyl‐4,5‐dimethyl‐1,3,2‐diazaphospholene with Trichlorosilane.
Authors: KIBARDIN A. M. , MIKHAILOV YU. B. , GRYAZNOVA T. V. , PUDOVIK A. N. 
Published: May 2016

AbstractDas Oxophospholen (I) wird mit Trichlorsilan (II) zu dem Phospholen (III) reduziert.
ChemInform Abstract: Formation of Diiron μ‐Alkenyl Complexes from the Reaction of a μ‐Methylidyne Complex with Selected Alkenes.
Authors: CASEY C. P. , MESZAROS M. W. , FAGAN P. J. , BLY R. K. , COLBORN R. E. 
Published: May 2016

AbstractThe stereochemistry of hydrocarbation was studied in the reactions of the methylidyne Complex (I) with substituted alkenes.
ChemInform Abstract: Schmidt Reaction of 3‐Oxocholest‐5‐en‐4α‐yl Acetate and 6β‐Chloro‐5‐hydroxy‐ 5α‐cholestan‐3‐one.
Authors: MUSHFIQ M. , IQBAL N. 
Published: May 2016

AbstractSchmidt reactions of the title compounds (I) and (VII) have been carried out using varying concentrations of hydrazoic acid.
ChemInform Abstract: Enantioselective Synthesis of Cyclopentanoids. Part 2. Asymmetric Synthesis of a Novel Homochiral Prostaglandin Building Unit via Bridgehead Enolates with Bicyclo[3.3.0]octane Skeleton.
Authors: GAIS H.‐J. , LINDNER H. J. , LIED T. , LUKAS K. L. , BALL W. A. , ROSENSTOCK B. , SLIWA H. 
Published: May 2016

AbstractUsing two different procedures, the enantiomerically pure Starting material (I) is reduced to the mixture (II)/ (III), whose components are isolated via recrystallization.
ChemInform Abstract: β‐Lactam Synthesis: Chemospecific Sulfonation and Cyclization of the β‐Hydroxyvaline Nucleus.
Authors: SLUSARCHYK W. A. , DEJNEKA T. , GOUGOUTAS J. , KOSTER W. H. , KRONENTHAL D. R. , MALLEY M. , PERRI M. G. , ROUTH F. L. , SUNDEEN J. E. , WEAVER E. R. , ZAHLER R. , GODFREY J. D. JUN. , MUELLER R. H. , VON LANGEN D. J. 
Published: May 2016

AbstractDas aus der geschützten Aminosäure (Ia) erhaltene Hydroxamat (Ib) wird über die Salze (II) mit Pottasche oder Tetraborat zu einem Gemisch aus den isomeren β‐Lactamen (III) und (IV) cyclisiert, die auch direkt aus (Ib) erhalten werden können.
ChemInform Abstract: Synthesis of a Fluorinated Analog of the Sex Pheromone of the Processionary Moth Thaumetopoea pityocampa (Denis and Schiff).
Authors: CAMPS F. , FABRIAS G. , GUERRERO A. 
Published: May 2016

AbstractThe four‐step synthesis of the title compound, i.e. the fluoro compound (V), is described, the key‐step being the regioselective ring opening of the oxirane (II) by Olah′s reagent to afford the fluoro‐ hydrin (III) as a 1:1 mixture of the erythro and the threo isomers.
ChemInform Abstract: Structure and Magnetization of (ND4)2Ni(SO4)2‐ at 2 K by Neutron Diffraction.
Authors: FENDER B. E. F. , FIGGIS B. N. , FORSYTH J. B. 
Published: May 2016

AbstractThe deuterated title compound crystallizes in the monoclinic system (P21/a, Z=2).
ChemInform Abstract: Comparison of the Crystal Structures of Sodium Orthosilicate, Na4SiO4 (I), and Sodium Orthogermanate, Na4GeO4 (II).
Authors: BAUR W. H. , HALWAX E. , VOELLENKLE H. + 
Published: May 2016

AbstractA reevaluation of already known data con‐ firms the isotypism of the two crystal structures.
ChemInform Abstract: Oxygen Reduction on a Ruthenium Electrode in Acid Electrolytes.
Authors: ANASTASIJEVIC N. A. , DIMITRIJEVIC Z. M. , ADZIC R. R. 
Published: May 2016

AbstractFrom measurements using the disk‐ring method it is concluded that O2 reduction on Ru in acid electrolyte is first order in [O2] and goes predominantly with exchange of four electrons.
ChemInform Abstract: Passive Behaviour of Titanium.
Authors: HURLEN T. , WILHELMSEN W. 
Published: May 2016

AbstractThe anodic and dC Capacitive behaviour of passive Ti electrodes in sulphate, Chloride, and acetate solutions of pH O‐7 is studied by quasi‐stationary and transient polarisation measurement at 25°C. The passive state exhibits itself by a relatively low and essentially potential and anion independent anodic Current over an intermediate potential range and at higher potentials an anodic Current of solution oxidation (eleCtron transfer) appears.
ChemInform Abstract: Electrochemisorption of Hexahydroxyplatinate(IV) on Tin Oxide Films: Electrochemical and UHV Spectroscopic Studies of the Product.
Authors: LAITINEN H. A. , WAGGONER J. R. , CHAN C. Y. , KIRSZENSZTEJN P. , ASBURY D. A. , HOFLUND G. B. 
Published: May 2016

AbstractThe preparation of p1atinized tin oxide surfaces from Na2Pt(OH)6/KOH solutions has been studied as a function of anodic platinization potential (0.0‐1.0 V vs.
ChemInform Abstract: Zinc Sulfate Reactions in Hot Corrosion.
Authors: JONES R. L. , WILLIAMS C. E. 
Published: May 2016

AbstractIn order to investigate the effect of Zn in Zn containing fuel additives on gas turbine hot corrosion, the corrosion of Co‐ CrA1Y spray‐coated with a ZnSO4‐ Na2SO4 mixture or with Na2SO4 alone has been studied by thermobalance experiments, SEM, and X‐ray analysis.
ChemInform Abstract: Poisoning Mechanisms and Structural Analyses on Metallic Contaminated Cathode Catalysts in Chlor‐Alkali Membrane Cell Technology.
Authors: NIDOLA A. , SCHIRA R. 
Published: May 2016

AbstractIn order to study the deactivation mechanism and coating morphologies changes during the electrolytic operation in contaminated caustic soda solutions, the electrochemical behavior of low hydrogen evolution overpotential cathodes (LHEOC) has been investigated in the presence of the following impurities: Fe", Fe(OH); , Ni(OH)3′ , Cr(OH)4′ , HgClj′ , CuCl; , S3′ , S2′, SH′, RNH2, and RSH.
ChemInform Abstract: Molecular structures and Dynamic Behaviour of Two Isomers of [Ru3(μ‐H)‐(μ3‐Me2NC4H4)(CO)9] formed from 1‐Dimethylaminobut‐2‐yne and Containing η2‐Alkene‐1,3‐diyl and η2‐Alkene‐1,2‐diyl Ligands Respectively.
Authors: AIME S. , OSELLA D. , DEEMING A. J. , ARCE A. J. , HURSTHOUSE M. B. , DAWES H. M. 
Published: May 2016

AbstractThe single‐crystal X‐ray structures of the isomeric compounds (III) and (IV) are determined.
ChemInform Abstract: Polarity and Basicity of Solvents. Part 1. A Thermosolvatochromic Comparison Method.
Authors: NICOLET P. , LAURENCE C. 
Published: May 2016

AbstractSome modifications of thermosolvatochromic comparison are presented on the basis of a principle previously proposed tdquantify the polarity, acidity, and basicity of solvents (l4indicators in many solvents).