bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: A New Chemoenzymatic Approach to the Synthesis of Penems.
Authors: ALTAMURA M. , CESTI P. , FRANCALANCI F. , MARCHI M. , CAMBIAGHI S. 
Published: May 2016

AbstractA new synthesis of the valuable penem antibiotics (Xa) and (Xb) uses the selective enzymatic hydrolysis of the intermediate (VI) as the key step, leaving unaffected both the allyl ester in position 3 and the lactam entity.
ChemInform Abstract: Synthesis and Activity of Juvenile Hormone Analogues (JHA). Part 2.
Authors: RODRIGUEZ J. B. , GROS E. G. , STOKA A. M. 
Published: May 2016

AbstractThe biological activity of the title compounds (III), (IV), (VI) and (VIII) towards Triatoma infestans is examined using commercially available Fenoxycarb (IX) as the reference compound.
ChemInform Abstract: Crystal Structure of Na3Ga8Sn3 and Interpretation of Its Chemical Bonding According to Wade′s Rules and the Zintl Concept.
Authors: BLASE W. , CORDIER G. 
Published: May 2016

AbstractThe title compound, prepared from the elements at 870 K, crystallizes in the monoclinic system, space group C2/m with Z=4.
ChemInform Abstract: Effect of Supporting Electrolytes on Photoelectrochemical Properties of n‐SnS and p‐SnSe Electrodes.
Authors: SHARON M. , BASAVASWARAN K. 
Published: May 2016

AbstractSupporting electrolytes such as the sulfates of Li, Na, K, or Cs, are found to suppress the photocorrosion and to enhance the fill‐factor of a photoelectrochemical cell formed with n‐SnS and p‐SnSe electrodes.
ChemInform Abstract: Preparation and Properties of Barium Ferrite Using Hot‐Rolled Mill Scale.
Authors: CHIEN Y.‐T. , PAN H.‐C. , KO Y.‐C. 
Published: May 2016

AbstractBarium ferrite (BaFe12O19) is prepared by solid‐state reaction of hot‐rolled mill scale, primarily consisting of wustite (FeO) and magnetite (Fe3O4), and BaCO3.
ChemInform Abstract: Enhanced Raman Scattering from “Liquid Metal” Films Formed from Silver Sols.
Authors: GORDON K. C. , MCGARVEY J. J. , TAYLOR K. P. 
Published: May 2016

AbstractA convenient method for the preparation of mobile Ag films at the interface between an aqueous Ag sol and solutions of a variety of Cu(I), Fe(II), and Fe(III) complexes (e.g.
ChemInform Abstract: The Thermal Decomposition of Ammonium Strontium cyclo‐Tri‐ (I), cyclo‐Tetra‐ (II), and cyclo‐Hexaphosphate
Authors: TAKENAKA A. , MOTOOKA I. , NARIAI H. 
Published: May 2016

Abstract(III) prepared by a wet method, is investigated by means of TG‐DTA, HPLC‐flow injection analysis, XRD, and IR spectroscopy.
ChemInform Abstract: The Reaction Chemistry of Crystalline Allotropes of Germania
Authors: SEIBLES L. , MITCHELL J. W. , BLITZER L. D. 
Published: May 2016

Abstractis studied in order to investigate the most direct and economically feasible procedures for the conversion of hexagonal (quartz‐type) and tetragonal (rutile‐type) GeO2 into chemically reactive products useful as Ge raw materials.
ChemInform Abstract: A New Lithium Insertion Compound, (Li,Cu)TaO3 with the LiNbO3 Type Structure.
Authors: KUMADA N. , HOSODA S. , MUTO F. , KINOMURA N. 
Published: May 2016

AbstractThe Li insertion reaction shown in the scheme is accompanied by a topotactic transformation from the perovskite‐related structure of CuTa2O6 to the LiNbO3 type of structure.
ChemInform Abstract: New Compounds Ag2HgMX4 with the Wurtzstannite‐Type Structure.
Authors: HAEUSELER H. , HIMMRICH M. 
Published: May 2016

AbstractIn the course of attempts to synthesize new compounds of the composition Ag2HgMX4 four hitherto not reported compounds (I)‐(IV) are obtained by solid state reaction at 700 °C, starting from Ag, Ge(Sn), S(Se), and HgS or HgSe.
ChemInform Abstract: A Conformational Study of Some Secondary 2‐Furancarbothioamides.
Authors: JAGODZINSKI T. S. , DZIEMBOWSKA T. M. , SZCZODROWSKA B. 
Published: May 2016

AbstractAnalysis of the UV, IR, and 1H NMR spectra and of the dipole moments of (I) indicate nonplanarity of the sec. thioamides and a free rotation of the thioamide group around the C‐C bond.
ChemInform Abstract: Synthesis of Optically Active (E)‐1‐Alkoxymethoxybut‐2‐enyl(tributyl)stannanes: Stereochemistry of Their Thermal Reactions with Aldehydes.
Authors: JEPHCOTE V. J. , PRATT A. J. , THOMAS E. J. 
Published: May 2016

AbstractThe optically active diastereomeric stannanes (I) and (IV) possessing the (‐)‐menthol unity as chiral auxiliary react stereoselectively on heating with benzaldehyde (II) to give the enol ethers (III) and (V).
ChemInform Abstract: 2‐Pyridylseleno Group in Organic Synthesis. Part 6. The Stereochemistry of a Substitution Reaction via an Episelenonium Ion: Retention by a 2‐Pyridylseleno Group versus Scrambling by a Phenylseleno Group.
Authors: TOSHIMITSU A. , ITO M. , UEMURA S. 
Published: May 2016

Abstract(R)‐1,2‐Epoxyoctane (I) reacts with the sodium areneselenolates (II) or (VII) to give the alcohols (III) and (VIII) respectively, while (III) is substituted with acetonitrile (IV) to yield the regioisomers (V) and (VI).
ChemInform Abstract: Non‐Photochemical (2 + 2)Cycloadditions of Acyclic Enones and Alkenes.
Authors: ENGLER T. A. , ALI M. H. , VANDER VELDE D. 
Published: May 2016

AbstractTitanium(IV)‐induced (2 + 2)cycloaddition reaction of the styrenes (I) with the enones (II) gives a mixture of the diastereomeric cyclobutanes (III) and (IV) which undergo base‐induced isomerization, producing the isomers (IV) exclusively.
ChemInform Abstract: Diels‐Alder Reaction of in situ‐Generated 2‐Methoxycarbonyl‐p‐quinone with D‐Glucose‐Based Dienes: A New Approach to Forskolin.
Authors: MUKHOPADHYAY A. , ALI S. M. , HUSAIN M. , SURYAWANSHI S. N. , BHAKUNI D. S. 
Published: May 2016

AbstractThe p‐benzoquinonecarboxylate (II), generated in situ by treatment of the hydroquinone (I) with silver oxide, undergoes Diels‐Alder reaction with the protected trihydroxyhepta‐1,3‐dienes (III), forming the tetrahydronaphthoquinones (IV).
ChemInform Abstract: New Cyclopenta(b)pyrroles and ‐pyridines by Reaction of 2‐Azido‐ and 2‐Phosphoranylideneaminocyclopent‐1‐ene‐1‐carbaldehydes with Aliphatic Esters.
Authors: AUBERT T. , TABYAOUI B. , FARNIER M. , GUILARD R. 
Published: May 2016

AbstractThe title compounds of type (IV) and (VIII) are interesting with regard to the chemistry of natural products and the pharmacological properties of several derivatives.
ChemInform Abstract: Synthesis, Protonation Sequence, and NMR Studies of Polyazamacrocyclic Methylenephosphonates.
Authors: GERALDES C. F. G. C. , SHERRY A. D. , CACHERIS W. P. 
Published: May 2016

AbstractMacroscopic and microscopic protonation of the title compounds (I)‐(III), prepared by published methods, is studied using potentiometry and multinuclear magnetic resonance spectroscopy.
ChemInform Abstract: Chemoselective Reduction of an α,β‐Epoxy Ketone Moiety Coexisting with an Enone Function.
Authors: MIYASHITA M. , SUZUKI T. , YOSHIKOSHI A. 
Published: May 2016

AbstractReduction of the epoxy enone (I) with zinc copper couple forms a mixture of the ketols (II) and (III).
ChemInform Abstract: Electrochemical Mono‐ and Difluorination of Benzyl Groups.
Authors: LAURENT E. , MARQUET B. , TARDIVEL R. 
Published: May 2016

AbstractThe monofluorination of the benzyl compounds (Ia) and (Ib) only yields the products (IVa) and (IVb), resp., while in the case of the benzyl derivatives (Ic) and (Id) reaction with the solvent MeCN gives rise to the major products (Vc) and (Vd).
ChemInform Abstract: Sulfur Trioxidation of Acyclic Fluoroallyl Ethers: Synthesis of New Fluorinated Sultones and Their Derivatives.
Authors: MOHTASHAM J. , BRENNEN M. , YU Z. , ADCOCK J. L. , GARD G. L. 
Published: May 2016

AbstractAddition of sulfur trioxide (II) to the perfluoroallyl ethers (I) results in the formation of the β‐sultones (III) which undergo fluoride‐induced cleavage and rearrangement, yielding the α‐fluorosulfonylacyl fluorides (IV).
ChemInform Abstract: Synthesis of 1‐Vinyl‐1‐(α‐aminoalkyl)cycloalkanes from Imines and 1,1‐Polymethyleneallenes via Allylboranes.
Authors: BUBNOV YU. N. , ZHELUDEVA V. I. , RUDASHEVSKAYA T. YU. , KUZNETSOVA T. S. 
Published: May 2016

AbstractThe boranes (I), prepared from 9‐borabicyclo(3.3.1)nonane and the corresponding polymethyleneallene as previously described, react with the Schiff bases (II) to give the amines (III) mentioned in the title.
ChemInform Abstract: Synthesis of Substituted TCNQ Derivatives Using Electrophilic Cyanide Derived from Thiocyanate and Selenocyanate Reagents.
Authors: BRYCE M. R. , HASAN M. , ASHWELL G. J. 
Published: May 2016

AbstractCyanation of the di(cyanomethyl)arenes (I) with the thiocyanate (II) followed by reoxidation of the intermediate dihydrotetracyano‐p‐quinodimethanes using bromine gives the tetracyano‐p‐quinodimethanes (III).
ChemInform Abstract: Structure and Thermal Behavior of Methylcyclopentadiene Dimers.
Authors: THOMMEN W. , PAMINGLE H. , SCHULTE‐ELTE K. H. 
Published: May 2016

AbstractThe multicomponent mixture of isomeric dimers from two sources is analyzed, one resulting from freshly prepared 1‐, 2‐, and 5‐methylcyclopenta‐1,3‐dienes by storage during 7 days at 20 °C and the other being a commercially available product.
ChemInform Abstract: A Barbier Allylation and a Reformatsky Reaction of Carbonyl Compounds Mediated by Indium(I) Iodide.
Authors: ARAKI S. , ITO H. , KATSUMURA N. , BUTSUGAN Y. 
Published: May 2016

AbstractThirteen carbonyl compounds such as (I) are coupled with allyl iodide (II) in the presence of indium(I) iodide to give the homoallylic alcohols (III).
ChemInform Abstract: Binary Antidotes for Organophosphate Poisoning: Aprophen Analogues That are Both Antimuscarinics and Carbamates.
Authors: LEADER H. , SMEJKAL R. M. , PAYNE C. S. , PADILLA F. N. , DOCTOR B. P. , GORDON R. K. , CHIANG P. K. 
Published: May 2016

AbstractThe carbaphens (VI), (VII), (XIII), and (XV), analogues of aprophen (XVI), are synthesized as outlined in the reaction scheme.
ChemInform Abstract: 1,2‐Bis(phenylsulfonyl)alkenes as Versatile Groups in Organic Synthesis: The Preparation of Alkyl‐ and Aryl‐Substituted Norbornadienes via the Diels‐Alder Cycloaddition ‐ Grignard Reaction ‐ Desulfonylation Sequence.
Authors: AZZENA U. , COSSU S. , DE LUCCHI O. , MELLONI G. 
Published: May 2016

AbstractZ‐1,2‐Bis(phenylsulfonyl)chloroethene (II) reacts with cyclopentadiene (I) to form the norbornene (III) which is dehydrochlorinated, yielding 1,2‐bis(phenylsulfonyl)norbornadiene (IV).
ChemInform Abstract: Reaction of Dimethyloxosulfoniummethylide with Oxaziridines ‐ Transformation to Azetidines.
Authors: NADIR U. K. , SHARMA R. L. , KOUL V. K. 
Published: May 2016

AbstractReaction of the oxaziridines (I) with 4 equiv. of ylide (II) offers a new route to azetidines.
ChemInform Abstract: Synthesis and Structure‐Activity Relationships of a Novel Class of 5‐Lipoxygenase Inhibitors. 2‐(Phenylmethyl)‐4‐hydroxy‐3,5‐dialkylbenzofurans: The Development of L‐656,224.
Authors: LAU C. K. , BELANGER P. C. , SCHEIGETZ J. , DUFRESNE C. , WILLIAMS H. W. R. , MAYCOCK A. L. , GUINDON Y. , BACH T. , DALLOB A. L. , DENIS D. , FORD‐HUTCHINSON A. W. , GALE P. H. , HOPPLE S. L. , LETTS L. G. , LUELL S. , MCFARLANE C. S. , MACINTYRE E. , MEURER R. , MILLER D. K. , PIECHUTA H. , RIENDEAU D. , ROKACH J. , ROUZER C. 
Published: May 2016

AbstractCoupling of the substituted 2‐acetylresorcinols (I) with the phenacyl bromide (II) followed by in situ cyclization gives the 2‐benzoylbenzofurans (III).
ChemInform Abstract: The Photochemical (3 + 2)Cycloaddition Reaction of 2,2,3,3‐Tetraarylthiiranes and Tetracyanoethylene Through Electron Donor‐Acceptor Complexes.
Authors: KAMATA M. , MIYASHI T. 
Published: May 2016

AbstractReaction of the thiiranes (Ia) ‐ (Id) with tetracyanoethylene (II) upon irradiation results in the formation of the tetrahydrothiophenes (IIIa) ‐ (IIId).
ChemInform Abstract: Direct Fluoroalkylation of Aromatic Compounds Catalyzed by Tetrakis‐(triphenylphosphine)nickel.
Authors: ZHOU Q.‐L. , HUANG Y.‐Z. 
Published: May 2016

AbstractRegioselective fluoroalkylation of the (het)aromatic compounds (II) or (IV) is achieved with the ω‐chloroperfluoroalkyl iodides (I) in the presence of sodium hydride and tetrakis(triphenylphosphine)nickel.
ChemInform Abstract: Synthesis of Fused Analogues of Dihydroisoindolinium Salts by Base‐Catalyzed Intramolecular Diene Condensation of Dialkyl‐2‐alkenyl(3‐(α‐naphthyl)propargyl)ammonium Salts.
Authors: CHUKHADZHYAN E. O. , CHUKHADZHYAN EL. O. , SHAKHATUNI K. G. , BABAYAN A. T. 
Published: May 2016

AbstractTreatment of the alkenyl(naphthylpropargyl)ammonium bromides (I) with catalytic amounts of potassium hydroxide gives the naphthoisoindolinium bromides (II).
ChemInform Abstract: Synthesis and Antiinflammatory Activity of Some 3‐Amino‐ and 3‐Trifluoroacetylamino‐4,5‐dihydro‐1H‐pyrazoles.
Authors: SAWHNEY S. N. , BHUTANI S. , VIR D. 
Published: May 2016

AbstractThe title compounds (I), (IV) and (V) are prepared from the corresponding hydrazines and α,β‐unsaturated nitriles and transformed to their 3‐trifluoroacetylamino analogues.
ChemInform Abstract: Reactions of 1‐(Phenylethynyl)aziridines with Amines.
Authors: TIKHOMIROV D. A. , PORCHINSKAYA N. M. , EREMEEV A. V. 
Published: May 2016

AbstractReaction of the 1‐phenylethynylaziridines (I) with the amines (II) or (IV) gives the imidazolines (III), (VI), (VIII), and (IX) or the phenylacetamidines (V) depending on the substituents and the reaction conditions.
ChemInform Abstract: Nonsteroidal Cardiotonics. Part 2. The Inotropic Activity of Linear, Tricyclic 5‐6‐5 Fused Heterocycles.
Authors: VON DER SAAL W. , HOELCK J.‐P. + , KAMPE W. , MERTENS A. , MUELLER‐BECKMANN B. + 
Published: May 2016

AbstractSeveral methods for the synthesis of tricyclic heterocycles such as (III), (V), (VIII), and (XIII) are described.
ChemInform Abstract: Synthesis of 1,3,4‐Thiadiazole Derivatives by Reaction of Thiobenzhydrazide with Some Acylacetylenes.
Authors: GLOTOVA T. E. , NAKHMANOVICH A. S. , SIGALOV M. V. 
Published: May 2016

AbstractThiobenzhydrazide (I) is coupled with the acylacetylenes (II) to give the thiadiazoles (III) and (IV).
ChemInform Abstract: Novel Indolecarboxamidotetrazoles as Potential Antiallergy Agents.
Authors: UNANGST P. C. , CONNOR D. T. , STABLER S. R. , WEIKERT R. J. , CARETHERS M. E. , KENNEDY J. A. , THUESON D. O. , CHESTNUT J. C. , ADOLPHSON R. L. , CONROY M. C. 
Published: May 2016

AbstractO‐Alkylation of the enolic indolecarboxylates (I) produces the alkoxy acids (IV).
ChemInform Abstract: Synthesis and Reactions of Phthalazine Derivatives. Part 2. Nucleophilic Substitution and Ring Closure Reactions of 1(2H)‐Oxo‐4‐phenylphthalazine‐2‐acetic Acid Hydrazide.
Authors: EL‐GENDY Z. , ABDEL‐RAHMAN R. M. 
Published: May 2016

AbstractReactions of the hydrazine (I), described in the preceding paper, with halo compounds and reactions of the derivative (VIII) with primary amines are investigated.
ChemInform Abstract: Synthesis and Biological Activity of 4‐Aryl‐1‐benzalhydrazinophthalazines and 3,6‐Diaryl‐1,2,4‐triazolo(3,4‐a)phthalazines.
Authors: RAZVI M. , RAMALINGAM T. , SATTUR P. B. 
Published: May 2016

AbstractThe derivatives (IVa) and (IVf) can alternatively be prepared in one step by reaction of the hydrazines (I) with PhCOOH/POCl3.
ChemInform Abstract: Interaction of Heterothiocumulenes with 2‐Amino‐3‐cyanothiophenes: Formation of Thieno(2,3‐d)pyrimidines.
Authors: SUKUMARAN P. , RAJASEKHARAN K. N. 
Published: May 2016

AbstractThe thiophenes (Ia) and (Ib) react with alkyl and aryl isothiocyanates to give directly the title compounds of type (III) (20 examples).
ChemInform Abstract: Formation of N‐N Bonds by Thermolysis of 5‐(2‐Dimethylaminoethyl)‐5H‐indolo(2,3‐b)quinoxaline.
Authors: BERGMAN J. 
Published: May 2016

AbstractIn contrast to previous investigations, the coupling of the anion (II), generated from the indoloquinoxaline (I), with the chloroethylamine (III) gives a mixture of the isomeric substitution products (IV) and (V).
ChemInform Abstract: A Novel Ring Transformation of 5‐Carbamoyluracils into Barbituric Acids.
Authors: HIROTA K. , SAJIKI H. , KITADE Y. , MAKI Y. 
Published: May 2016

AbstractReaction of the 5‐cyanouracil (I) with excess NaSH (II) leads, via 5‐thiocarbamoyluracil (III) and its rearrangement by an unusual N(1)‐C(2) bond cleavage, to the 4‐thiobarbituric acid (IV).
ChemInform Abstract: On the Condensation of Ethanolamine with Chloro‐sym‐triazines.
Authors: DOVLATYAN V. V. , ELIAZYAN K. A. , PIVAZYAN V. A. , AKOPYAN A. G. 
Published: May 2016

AbstractIn contrast to literature data, reaction of the chlorotriazines (I) with ethanolamine (II) produces the 2‐hydroxyethylaminotriazines (III).
ChemInform Abstract: Lipophilic Thiacrown Ether Derivatives as Neutral Silver Ion Selective Carriers.
Authors: OUE M. , AKAMA K. , KIMURA K. , TANAKA M. , SHONO T. 
Published: May 2016

AbstractThiacrown ethers (III), (V), (VIII), and (XIII) are prepared in order to evaluate their ion selectivities as neutral carriers of polymeric membrane Ag+‐selective electrodes.
ChemInform Abstract: Organic Heterocyclothiazenes. Part 8. 7‐Amino‐1,3,5,2,4,6‐trithiatriazepine (IV) and Related Compounds.
Authors: DUNN P. J. , REES C. W. 
Published: May 2016

AbstractA series of 7‐substituted trithiatriazepines (Ttt's) are prepared.
ChemInform Abstract: Decamethylsilicocene ‐ The First Stable Silicon(II) Compound: Synthesis, Structure, and Bonding.
Authors: JUTZI P. , HOLTMANN U. , KANNE D. , KRUEGER C. + , BLOM R. , GLEITER R. , HYLA‐KRYSPIN I. 
Published: May 2016

AbstractIn the synthesis of the thermally stable, air‐sensitive π‐complex (II) elemental silicon is obtained as a by‐product.
ChemInform Abstract: Unprecedented 1,4‐Methyl Group Migration in a Rhodium‐Catalyzed Hydrosilylation of Ketones by 1,2‐Bis(dimethylsilyl)benzene.
Authors: NAGASHIMA H. , TATEBE K. , ITOH K. 
Published: May 2016

AbstractThe Rh‐catalyzed hydrosilylation of ketones e.g. (I) with the disilylbenzene (II) results in the formation of the expected hydrosilylation products (III) and their rearranged derivatives (IV).
ChemInform Abstract: 4′‐Bromo(azido)‐9,10‐dihydro‐10,10‐dimethyl‐2‐aza‐10‐silaspiro(anthracene‐9,2′‐tetrahydrofuran).
Authors: PROSTAKOV N. S. , VARLAMOV A. V. , KOZM K. , ALIEV A. E. , FOMICHEV A. A. 
Published: May 2016

AbstractStarting with the azasilaanthrone (I), the title compounds (V) and (VIII) are prepared via the allylhydroxy (III) and the dibromopropylhydroxy derivative (IV).
ChemInform Abstract: Phosphonioboratoacetylene, C2 Stabilized by Donor and Acceptor Molecules.
Authors: BESTMANN H. J. , BEHL H. , BREMER M. 
Published: May 2016

AbstractThe title compounds (VII) can be seen as complexed C2 molecules, the bulky donor and acceptor substituents shield the C≡C bond so effectively that (VII) does not react with 1,3‐dipoles.
ChemInform Abstract: Coordination Compounds of Indium. Part 47. Indium(I) and Thallium(I) Derivatives of Alkanedithiols.
Authors: GELOSO C. , MABROUK H. E. , TUCK D. G. 
Published: May 2016

AbstractThe electrochemical oxidation of anodic indium in MeCN solution of a series of alkanedithiols such as (II) gives unusual In(I) compounds of the formulation (III) which are probably cross‐linked homopolymers.
ChemInform Abstract: A Water‐Stable Gadolinium(III) Complex Derived from a New Pentadentate “Expanded Porphyrin” Ligand.
Authors: SESSLER J. L. , MURAI T. , HEMMI G. 
Published: May 2016

AbstractThe general lanthanoid‐binding properties of new monoanionic porphyrin‐like ligands are explored.
ChemInform Abstract: Syntheses, and Crystal and Molecular Structures of Tetraethylammonium (Hexakis(isothiocyanato)lanthanoidates(III)) Including Aromatic Hydrocarbon or Halohydrocarbon: ((C2H5)4N)3(M(NCS)6)·G (M: Er, or Yb; G: Benzene, Fluorobenzene, Toluene, or Chlorobenzene).
Authors: ARAI H. , SUZUKI Y. , MATSUMURA N. , TAKEUCHI T. , OUCHI A. 
Published: May 2016

AbstractThe isomorphous title complexes are synthesized as demonstrated for the benzene monoadducts (III) (space group P21/c, Z=4) in the scheme.
ChemInform Abstract: ansa‐Metallocene Derivatives. Part 17. Racemic and meso‐Diastereomers of Group IV Metallocene Derivatives with Symmetrically‐Substituted, Dimethylsilanediyl‐Bridged Ligand Frameworks. Crystal Structure of R,S‐Me2Si(3‐t‐Bu‐5‐MeC5H2)2ZrCl2.
Authors: WIESENFELDT H. , REINMUTH A. , BARSTIES E. , EVERTZ K. , BRINTZINGER H.‐H. 
Published: May 2016

AbstractReaction of the cyclopentadienyllithium reagents (II) with the dichlorosilane (I) gives the dicyclopentadienylsilanes (III).
ChemInform Abstract: A Ge‐S Double Bond, Stabilized by a N‐Ge Donor Bond.
Authors: VEITH M. , BECKER S. , HUCH V. 
Published: May 2016

AbstractGe compounds (V) (Pbca, Z = 8) and (VII) (P1, Z=1) are prepared via the germanediyl (III) and characterized by X‐ray analyses.
ChemInform Abstract: Reactions of Coordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex (Mo(CCH2tBu)(P(OMe)3)2(η‐C5H5)); Crystal and Molecular Structures of (Mo(η3‐RN=C‐C(CH2tBu)‐C=NR)(CNR)2(η‐C5H5))(R: 2,6‐Me2C6H3), (Mo(C=CHtBu)I(P(OMe)3)2(η‐C5H5)), and Cyclic (Mo(=C(CH2tBu)P(O)(OMe)2)I(P(OMe)3)(η‐C5H5)).
Authors: BAKER P. K. , BARKER G. K. , GILL D. S. , GREEN M. , ORPEN A. G. , WILLIAMS I. D. , WELCH A. J. 
Published: May 2016

AbstractThe diimino‐substituted allyl complexes (III) show temp.‐dependent NMR spectra which are discussed in terms of rotation about the isocyanide bonds and endo/exo isomerism.
ChemInform Abstract: Insertion of Phenylethyne‐thiolate or ‐selenolate into Metal‐Carbene Bonds: Synthons for Coordinated Thioacyl or Selenoacyl Anions and for Anionic Thiocarbene or Selenocarbene Complexes.
Authors: RAUBENHEIMER H. G. , KRUGER G. J. , LINFORD L. , MARAIS C. F. , OTTE R. , HATTINGH J. T. Z. , LOMBARD A. 
Published: May 2016

AbstractThe insertion of (II) into the metal carbene bonds affords complexes such as (III).
ChemInform Abstract: Isolation and Characterization of (MnII(MnIII(salicylhydroximate))4(acetate)2(DMF)6)·2 DMF: An Inorganic Analogue of M2+(12‐crown‐4).
Authors: LAH M. S. , PECORARO V. L. 
Published: May 2016

AbstractThe title complex (IV) (space group P1, Z=2) is obtained by the 1:1 molar reaction shown in the scheme and characterized by X‐ray structure analysis, solid‐state susceptibility measurements and 1H NMR and EPR studies in solution.
ChemInform Abstract: Preparation and Characterization of TcCl3(PPh3)2(MeCN) and Its Reactions with Small π‐Accepting Ligands.
Authors: PEARLSTEIN R. M. , DAVIS W. M. , JONES A. G. , DAVISON A. 
Published: May 2016

AbstractIn analogy to its rhenium congener, the title complex (IV) promises to be a useful starting material for low‐valent technetium chemistry.
ChemInform Abstract: The Triply‐Bonded Complex Tetrachlorobis(bis(diphenylphosphino)methane)dirhenium(II) and Related Species, and Their Use as Reagents in Dirhenium Chemistry.
Authors: WALTON R. A. 
Published: May 2016

Abstract(I) (and its bromide analogue) serve as important precursors to many other dirhenium complexes because of the ability of the bridging diphophines to stabilize the dimetal unit.
ChemInform Abstract: Organic Chemistry of Dinuclear Metal Centers. Part 13. Synthesis, Structure, and Reactivity of (Ru2(CO)4(η5:η5′‐C5H4CH2C5H4)).
Authors: KNOX S. A. R. , MACPHERSON K. A. , ORPEN A. G. , RENDLE M. C. 
Published: May 2016

AbstractThe title complex (III) (space group Pbca, Z=16) is prepared according to the scheme.
ChemInform Abstract: Metallaheteroborane Chemistry. Part 5. Synthesis of closo‐(2,2‐(PR3)2‐1,2‐SePtB10H10) (R3: Et3, nBu3, or Me2Ph) and arachno‐(9,9‐(PMe2Ph)2‐6,9‐SePtB8H10) and Their Characterization by NMR Techniques: The Crystal and Molecular Structures of closo‐(2,2‐(PEt3)2‐1,2‐SePtB10H10) and arachno‐(9,9‐(PMe2Ph)2‐6,9‐SePtB8H10).
Authors: FARIDOON FARIDOON , NI DHUBHGHAILL O. , SPALDING T. R. , FERGUSON G. , KAITNER B. , FONTAINE X. L. R. , KENNEDY J. D. 
Published: May 2016

AbstractThe reaction of the salt (I) with the cis‐dichloro platinum complex (II) yields the closo compound (IIIa) (space group Fdd2, Z=16).