bluuebunny/crossref_metadata_2025_split huggingface dataset:
Penerapan Standar Akuntansi Pemerintahan Dalam Bingkai Metafora Amanah Sebagai Upaya Meningkatkan Kualitas Laporan Keuangan
Authors: Nengsih Sriwahyuni , Sumarlin  , Jannah Raodahtul 
Published: October 2024

Penelitian ini bertujuan untuk mengetahui bagaimana penerapan Standar Akuntansi Pemerintahan (SAP) No. 1 pada BPKAD Kabupaten Jeneponto dalam mewujudkan kualitas laporan keuangan yang baik dengan metafora amanah sebagai acuan untuk kepentingan masyarakan Kabupaten Jeneponto. Metode yang digunakan dalam penelitian ini yaitu penelitian kualitatif pendekatan fenomenologis. Penelitian ini menggunakan data subjek yang diperoleh melalui pengumpulan data melalui wawancara. Hasil penelitian ini menunjukkan bahwa Salah satu upaya meningkatkan kualitas laporan keuangan yang baik maka informasi yang diperoleh dari BPKAD Kabupaten Jeneponto tersebut telah disusun berdasarkan Standar Akuntansi Pemerintahan (SAP) No. 1 dan isinya memberikan informasi tentang pelaksanaan anggaran dan posisi keuangan Pemerintahan. Pemerintahan BPKAD Kabupaten Jeneponto dimana sejak dulu sudah menerapkan konsep amanah di dalam pembuatan laporan keuangan sesuai prinsip akuntabilitas dan transparansi yang diterapkan juga sudah memenuhi indikator kualitas laporan keuangan pemerintah, hal ini dapat dibuktikan dengan adanya laporan keungan yang dibuat sebagai bukti pertanggungjawaban pemerintahan.

This research aims to find out how to implement Government Accounting Standards (SAP) No. 1 at BPKAD Jeneponto Regency in realizing good quality financial reports with the metaphor of trust as a reference for the interests of the people of Jeneponto Regency. The method used in this research is qualitative research with a phenomenological approach. This research uses subject data obtained through data collection through interviews. The results of this research indicate that one of the efforts to improve the quality of good financial reports is that the information obtained from BPKAD Jeneponto Regency has been prepared based on Government Accounting Standards (SAP) No. 1 and its contents provide information about budget implementation and the Government's financial position. The BPKAD government of Jeneponto Regency, which has long implemented the concept of trust in the preparation of financial reports in accordance with the principles of accountability and transparency applied, has also met the quality indicators of government financial reports, this can be proven by the existence of financial reports prepared as proof of government accountability.
GESTÃO DO CAPITAL INTELECTUAL PARA TRANSFERÊNCIA DO CONHECIMENTO EM PROGRAMAS DE DESLIGAMENTO VOLUNTÁRIO EM EMPRESAS BRASILEIRAS: UMA REVISÃO DE LITERATURA
Authors: Silva Alexandre , Giffoni de Carvalho Dutra Frederico 
Published: October 2024

O objetivo do artigo foi investigar as iniciativas para gestão do capital intelectual no processo de transferência de conhecimento em programas de desligamento voluntário e aposentadoria de organizações brasileiras. Do ponto de vista dos procedimentos técnicos, adotou-se a pesquisa bibliográfica, realizada no período de julho a agosto de 2022, no Portal de Periódicos Capes, na Brapci, na base Oasisbr, Anpad Spell e Google Acadêmico. A revisão de literatura permitiu a recuperação de 770 trabalhos. Após a análise dos artigos e aplicação de critérios exclusão, foi possível sintetizar 9 trabalhos, publicados entre 2008 e 2021. Constatou-se que é grande o volume de publicações referentes à transferência do conhecimento, porém ao se tratar do contexto da aposentadoria e desligamento voluntário, o assunto é escasso, com poucas iniciativas propostas pelas empresas brasileiras. Sugere-se como continuidade desta pesquisa uma busca de boas práticas deste tipo de programa em outros países, investigando como as empresas lidam com a perda do capital intelectual.
Constraints Faced by Rural Women in Changing Livelihoods in Bangladesh: A Study on the Impact of Microcredit through PDBF
Authors: Islam M. S. , Alam M. M. , Ali M. S. , Mazumder M. S. , Rahmatullah N. M. 
Published: October 2024

The main purpose of the study is to determine the extent of the constraints faced by the women beneficiaries of Palli Daridro Bimochon Foundation (PDBF) on their socio-economic development and to explore the relationship between the socio-economic characteristics of the beneficiaries and their constraints. A total of 3436 women beneficiaries of three upazilas under 55 districts of PDBF constituted the population of the study. A face-to-face interview survey was conducted to collect data from the randomly selected 346 respondents. Among the 13 selected problem items, ‘high rate of interest’ was ranked first (70.81%), ‘more savings have to be deposited while taking the loan’ was ranked second (68.69%) and third (68.40%) was ‘various income generating activities and social development training are inadequate’ The findings revealed a significant relationship between training exposures, decision-making ability, savings deposit, income-generating activities, communication & network, and constraints faced by PDBF beneficiaries. Therefore, the PDBF authorities should consider significant factors in reducing the constraints faced by rural women to change their livelihoods.
Hybrid Sunscreen for Albinistic Skin Types Augmented by Terminalia Sericea Mediated Silver Doped Zinc Oxide Nanoparticles, Efficacy and Safety Investigation
Authors: Chifamba J , Chifamba C 
Published: October 2024

Albinism is a congenital hypopigmentation disorder characterized by errors in melanisation leading to the partial or complete absence of melanin, the skin’s primary defense against actinic damage. Actinic damage in albinism summarizes all solar induced consequences from freckles to fatal skin cancers. Of the 16 sunscreens approved by regulators, 14 chemical sunscreens were stripped of GRASE (Generally Recognizable as Safe and Effective) status in 2020 by the FDA though Over-the-Counter Monograph M020, the remaining 2 physical sunscreens (ZnO and TiO2) are unaesthetic, leaving unpleasant persistent white casts. The hunt for new, effective and safe sunscreen agents is on and photoprotective polyphenolics from tropical plants including Terminalia sericea, maybe the solution. This study aimed to develop and evaluate the efficacy and safety of a novel sunscreen for albinistic skin, utilizing Terminalia sericea-mediated silver-doped ZnO nanoparticles, so as to leverage the novel sun protection efficacy of aesthetic ZnO-NPs with the antibacterial effects of Ag-NPs as well as the photoprotective effects from T. Sericea polyphenolics. Our observations from the study confirm that T. Sericea possesses abundant polyphenolic compounds capable of mediating bio-reducing and capping of metallic nanoparticles. UV-Vis identified the nanostructures as Ag-ZnONPs, TEM confirmed their cubic and oblong agglomerated morphology. DLS estimated the nanostructures to be between 30 and 40nm. The sunscreen achieved a high SPF of 30, showed significant photoprotective properties, and demonstrated negligible skin sensitization in safety tests following OECD guidelines. It was therefore concluded that the biosynthesis of multifunctional Ag doped ZnONPs mediated by T. Sericea, was feasible and that the resultant safe multifunctional emulsion was efficacious in retarding biomarkers of actinic damage and is a potential pioneering albinistic skin type actinic damage retarding sunscreen.
Respiration of new and old carbon in the surface ocean: Implications for estimates of global oceanic gross primary productivity
Authors: Carvalho Matheus C. , Schulz Kai G. , Eyre Bradley D. 
Published: June 2017

AbstractNew respiration (Rnew, of freshly fixated carbon) and old respiration (Rold, of storage carbon) were estimated for different regions of the global surface ocean using published data on simultaneous measurements of the following: (1) primary productivity using 14C (14PP); (2) gross primary productivity (GPP) based on 18O or O2; and (3) net community productivity (NCP) using O2. The ratio Rnew/GPP in 24 h incubations was typically between 0.1 and 0.3 regardless of depth and geographical area, demonstrating that values were almost constant regardless of large variations in temperature (0 to 27°C), irradiance (surface to ~100 m deep), nutrients (nutrient‐rich and nutrient‐poor waters), and community composition (diatoms, flagellates, etc,). As such, between 10 and 30% of primary production in the surface ocean is respired in less than 24 h, and most respiration (between 55 and 75%) was of older carbon. Rnew was most likely associated with autotrophs, with minor contribution from heterotrophic bacteria. Patterns were less clear for Rold. Short 14C incubations are less affected by respiratory losses. Global oceanic GPP is estimated to be between 70 and 145 Gt C yr−1.
How much runoff originates as snow in the western United States, and how will that change in the future?
Authors: Li Dongyue , Wrzesien Melissa L. , Durand Michael , Adam Jennifer , Lettenmaier Dennis P. 
Published: June 2017

AbstractIn the western United States, the seasonal phase of snow storage bridges between winter‐dominant precipitation and summer‐dominant water demand. The critical role of snow in water supply has been frequently quantified using the ratio of snowmelt‐derived runoff to total runoff. However, current estimates of the fraction of annual runoff generated by snowmelt are not based on systematic analyses. Here based on hydrological model simulations and a new snowmelt tracking algorithm, we show that 53% of the total runoff in the western United States originates as snowmelt, despite only 37% of the precipitation falling as snow. In mountainous areas, snowmelt is responsible for 70% of the total runoff. By 2100, the contribution of snowmelt to runoff will decrease by one third for the western U.S. in the Intergovernmental Panel on Climate Change Representative Concentration Pathway 8.5 scenario. Snowmelt‐derived runoff currently makes up two thirds of the inflow to the region's major reservoirs. We argue that substantial impacts on water supply are likely in a warmer climate.
Decadal changes in Southern Ocean ventilation inferred from deconvolutions of repeat hydrographies
Authors: Ting Yu‐Heng , Holzer Mark 
Published: June 2017

AbstractChanges in Southern Ocean ventilation imprint on dissolved gases, nutrients, radiocarbon, temperature, and salinity. We deconvolve tracer measurements for the distribution,
, of times and locations of last ventilation using a maximum‐entropy approach. Decadal changes of
are quantified by deconvolving hydrographies measured during the early 1990s and again some 15 years later. Our analysis reveals coherent changes across the five meridional sections analyzed: The fraction of water younger than 30 years decreased by ∼20% per decade south of 40°S in circumpolar deep water (CDW) and increased by ∼10% per decade north of ∼40°S in subantarctic mode water (SAMW). Ventilation locations shifted, with more water south of 40°S being ventilated north of the subantarctic front. These ventilation changes impacted CFC uptake, with concentrations south of 40°S less than (and north of 40°S higher than) expected for steady flow. The inferred changes imply increased SAMW formation and CDW upwelling consistent with strengthened westerly winds.
Hydraulic fracturing and permeability enhancement in granite from subcritical/brittle to supercritical/ductile conditions
Authors: Watanabe Noriaki , Egawa Motoki , Sakaguchi Kiyotoshi , Ishibashi Takuya , Tsuchiya Noriyoshi 
Published: June 2017

AbstractHydraulic fracturing experiments were conducted at 200–450°C by injecting water into cylindrical granite samples containing a borehole at an initial effective confining pressure of 40 MPa. Intensive fracturing was observed at all temperatures, but the fracturing characteristics varied with temperature, perhaps due to differences in the water viscosity. At the lowest considered temperature (200°C), fewer fractures propagated linearly from the borehole, and the breakdown pressure was twice the confining pressure. However, these characteristics disappeared with increasing temperature; the fracture pattern shifted toward the formation of a greater number of shorter fractures over the entire body of the sample, and the breakdown pressure decreased greatly. Hydraulic fracturing significantly increased the permeability at all temperatures, and this permeability enhancement was likely to form a productive geothermal reservoir even at the highest considered temperature, which exceeded both the brittle‐ductile transition temperature of granite and the critical temperature of water.
3‐Alkenyltyrosines Accessed by Suzuki–Miyaura Coupling: A Key Intermediate in the Synthesis and Mechanistic Study of Povarov Multicomponent Reactions
Authors: Vasconcelos Stanley N. S. , Menezes da Silva Vitor H. , Braga Ataualpa A. C. , Shamim Anwar , Souza Frederico B. , Pimenta Daniel C. , Stefani Hélio A. 
Published: June 2017

Abstract3‐Vinyl and 3‐stilbenyl tyrosine derivatives, accessed by the Suzuki–Miyaura coupling reaction in good yields, are presented. These synthetic olefins then provided a fast and effective synthesis of functionalized quinolines by a silver‐catalyzed, microwave‐mediated Povarov reaction in just 40 min. In addition, we demonstrate a tandem one‐pot microwave‐mediated Povarov–CuAAC (copper‐catalyzed azide–alkyne cycloaddition) synthesis to provide a 1,2,3‐triazole ring with 35 % overall yield. We propose a Povarov/aromatization mechanism, based on high‐resolution mass spectrometry experiments, combined with computational studies based on density functional theory (DFT) methods.
Katalytische asymmetrische konjugierte Addition von Indolizinen an α,β‐ungesättigte Ketone
Authors: Correia José Tiago Menezes , List Benjamin , Coelho Fernando 
Published: June 2017

AbstractBeschrieben wird eine katalytische asymmetrische konjugierte Addition von Indolizinen an Enone. Die chirale Phosphorsäure (S)‐TRIP aktiviert dabei α,β‐ungesättigte Ketone und ermöglicht die enantioselektive Addition. Unter Verwendung der beschriebenen Methode wurden verschiedene alkylierte Indolizine in guten Ausbeuten und Enantiomerenverhältnissen von bis zu 98:2 synthetisiert.
Switchable Access to Different Spirocyclopentane Oxindoles by N‐Heterocyclic Carbene Catalyzed Reactions of Isatin‐Derived Enals and N‐Sulfonyl Ketimines
Authors: Wang Lei , Li Sun , Blümel Marcus , Puttreddy Rakesh , Peuronen Anssi , Rissanen Kari , Enders Dieter 
Published: June 2017

AbstractA novel NHC‐catalyzed annulation protocol for the asymmetric synthesis of biologically important β‐lactam fused spirocyclopentane oxindoles with four contiguous stereocenters, including two quaternary carbon centers, was developed. Alternatively, spirocyclopentane oxindoles containing an enaminone moiety can be achieved using the same starting materials, isatin‐derived enals, and N‐sulfonyl ketimines, in the presence of a slightly different NHC catalytic system. This switchable annulation strategy enables the selective assembly of both heterocyclic scaffolds with good yields and excellent enantioselectivities for a broad range of substrates.
Mucoadhesive chitosan/OA nanoparticles charged with celecoxib inhibit prostaglandin E2 LPS‐induced in U937 cell line
Authors: Méndez Paula A. , Ortiz Blanca L. , Vásquez Gloria M. , López Betty L. 
Published: June 2017

ABSTRACTThe present study shows the potential of new carriers of celecocib (CEL) for prostaglandin E2 (PGE2) inhibition in U937 cell line. Self‐assembled nanoparticles based on oleic acid‐modified chitosan were covered with hyaluronic acid (HA) obtaining systems with spherical shape and particle size close to 300 nm. CEL was encapsulated and the encapsulation efficiency (%EE) was dependent of the drug solubility in acid media, reaching %EE of 75.5% and 58.2% to strong and weak acid, respectively. The covering with HA increased the mucoadhesive properties and, the cellular binding and cellular uptake in U937 cells. Nanoparticles prepared in strong acid presented zeta potential (ζ) of 43.8 ± 0.4 mV, which become toxic and stimulate the PGE2 production in U937 cells, at the concentration 1 mg/mL. However, nanoparticles prepared in weaker acid presented ζ of 36.5 ± 1.21 mV, showing nontoxic effect and inhibitory effect of PGE2 from 80.8 pg/mL until 43.4 pg/mL. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45288.
A Guide for the Design of Functional Polyaromatic Organophosphorus Materials
Authors: Hindenberg Philip , López‐Andarias Alicia , Rominger Frank , de Cózar Abel , Romero‐Nieto Carlos 
Published: June 2017

AbstractThe impact of integrating six‐membered phosphorus heterocycles into a poly(hetero)aromatic materials is investigated. Mechanistic studies reveal the key synthetic requirements to embed the latter phosphorus heterocycles in polyaromatic molecules. DFT calculations indicate that introducing six‐membered phosphorus rings into π‐extended molecules induces a particular electron distribution over the π‐extended system. Electrochemical investigations confirm that inserting six‐membered phosphacycles into polyaromatics triggers ambipolar redox behavior. Steady‐state spectroscopy reveals that fusing pyrroles with phosphorus‐containing polyaromatic molecules induces fluorescence quantum yields as high as 0.8, whereas transient absorption spectroscopy demonstrates that fusing thiophenes promote the formation of non‐emissive triplet‐excited states. As a whole, the optoelectronic properties of fused phosphorus‐containing materials give rise to promising performances in photoelectrochemical cells. Moreover, X‐ray analyses confirm that the 3D arrangement in the solid state of polyaromatic systems containing six‐membered phosphorus rings can be tailored through post‐functionalization of the phosphorus center. Altogether, this investigation sets the bedrock for the design of a new generation of highly functional polyaromatic organophosphorus materials, keeping control over their electrochemical properties, fluorescence features, photo‐induced excited states, and 3D molecular arrangement.
The effect of antioxidants on the long‐term stability of THC and related cannabinoids in sampled whole blood
Authors: Sørensen Lambert K. , Hasselstrøm Jørgen B. 
Published: June 2017

The stability of cannabinoids is complex and crucial for the assessment of impaired driving caused by cannabis. Therefore, the effect of antioxidants on the long‐term stability of Δ9‐tetrahydrocannabinol (THC), cannabinol (CBN), cannabidiol (CBD), 11‐hydroxy‐Δ9‐tetrahydrocannabinol (THC‐OH), and 11‐nor‐9‐carboxy‐Δ9‐tetrahydrocannabinol (THC‐COOH) in whole blood samples preserved with fluoride citrate (FC) and fluoride oxalate (FX) mixtures was investigated at different temperatures. The measured concentrations of the cannabinoids in authentic whole blood preserved solely with FC or FX mixtures decreased significantly during prolonged storage at −20°C. On average, less than 5% of the initial concentrations of THC and CBD were recovered after 19 weeks of storage interrupted by 5 thawing/freezing cycles. The rate of decrease was greatest in FC‐preserved blood. The repeated thawing/freezing of the samples accelerated the instability progression. At 5°C approximately 60% of the initial concentrations of THC and CBD were recovered after 19 weeks of storage. No significant decrease was observed in samples stored at −80°C during the test period of 5 months. The instability at −20°C was to a great extend avoided by adding 30 mM ascorbic acid (ASC) to the samples before storage. Samples preserved with a combination of the FX mixture and ASC showed no significant decrease in the recovered concentrations during a 5‐month storage period interrupted by 6 thawing/freezing cycles. Samples preserved with a combination of the FC mixture and ASC showed almost similar improvements in cannabinoid stability. Other reducing agents such as sodium metabisulfite and glutathione also improved the stability in FX‐preserved blood stored at −20°C.
High‐efficiency Nitric Acid‐PPy/AQDS Coupling Treated Bioanodes Based Microbial Fuel Cell
Authors: Yin Fuhua , Zhu Nengwu , Lu Yu , Shen Weihang , Wu Pingxiao 
Published: June 2017

AbstractThe properties of anode material are crucial for high performances in microbial fuel cells (MFCs). Herein, we report a biocompatible, conductive, and electron transfer efficient cooperative processing anode, which is fabricated by electrodepositing polypyrrole/anthraquinone‐2, 6‐disulphonic disodium salt (PPy/AQDS) onto nitric acid‐soaked carbon felt. Results showed that the cooperative processing anode outperformed the pristine one in biomass, electrical conductivity, and exchange current density with better performance between 2.4 and 3.3 times. The maximum power density (1060.3 mW m−2) of the MFC equipped with the properties hybridized anode delivered a 2.2‐fold increase over that of the control and thus has great potential to be used as an anode for high‐power MFC. Further investigation revealed that the contributions of biocompatibility (BCB), electrical conductivity (EC), and electron transfer efficiency (ETE) to the performance of carbon felt anodes appeared as cumulative effect rather than summing effect. We propose combined treatment of BCB with EC and ETE to form a properties‐hybridized anode based on thoroughly analyzing the feasibility and effectiveness, and discussed future efforts to be made for realizing more extraordinary high‐performance cooperative processing anodes. This work may also provide a novel approach for the development of other types of anode for high‐performance MFC through combined treating the BCB with EC and ETE simultaneously.
Examining Maternal Psychopathology, Family Functioning and Coping Skills in Childhood Obesity: A Case–Control Study
Authors: Blanco Miriam , Sepulveda Ana R. , Lacruz Tatiana , Parks Melissa , Real Beatriz , Martin‐Peinador Yolanda , Román Francisco J. 
Published: June 2017

AbstractThe shared family environment is an important risk factor in the development of childhood obesity. This study aims to examine differences in maternal psychopathology, family functioning, expressed emotion and coping skills between families of a child with obesity and those with a normal‐weight child. This case–control study consisted of 50 mothers with a child (age 8–12 years) with obesity (p ≥ 97) and a control group of 50 mothers of a child with normal weight (p < 85), matched for age, sex and socio‐economic status. Compared with families with normal‐weight children, those with children with obesity showed significant differences in levels of trait anxiety, criticism and over‐protectiveness, and maladaptive coping skills. Structural equation modelling revealed that the mothers' psychopathology predicted children's body mass index (BMI) z‐scores through expressed emotion and maladaptive coping scores. There were significant direct and indirect relations among maternal BMI, psychopathology, expressed emotion and coping, which all together explained 26.5% of variance of children's BMI z‐scores. Considering this relation between maternal variables and child weight status, childhood obesity intervention programs may benefit from targeting maternal BMI, psychopathology, expressed emotion and coping skills. Copyright © 2017 John Wiley & Sons, Ltd and Eating Disorders Association.