bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Few‐Layer Antimonene by Liquid‐Phase Exfoliation.
Authors: Abellan Gonzalo , et al.  
Published: December 2016

AbstractHighly stable iPrOH/H2O (4:1) suspensions of few‐layer antimonene (FL‐Sb) are prepared by liquid‐phase exfoliation of ground Sb crystals via sonication without the need for surfactants (400 W, 24 kHz, 40 min).
ChemInform Abstract: Ammonothermal Synthesis and Characterization of Cs2[Zn(NH2)4].
Authors: Richter Theresia M. M. , Alt Nicolas S. A. , Schluecker Eberhard , Niewa Rainer 
Published: December 2016

AbstractSingle crystals of the title amidozincate of several centimeters in dimensions are grown under ammonothermal conditions in the cold temperature zone of an autoclave using Zn powder and CsNH2 in a 1:2 molar ratio (stainless steel autoclave, 523→≈423 K, 155 MPa, 12 h).
ChemInform Abstract: The Missing Hydrate AlF3·6H2O = [Al(H2O)6]F3: Ionothermal Synthesis, Crystal Structure and Characterization of Aluminum Fluoride Hexahydrate.
Authors: Wang Guangmei , Mudring Anja‐Verena 
Published: December 2016

AbstractSingle crystals of the title compound are prepared by ionothermal reaction of Al(O‐iPr)3, H3PO4, and 1,3‐diaminopropane in the ionic liquid n‐hexyl‐pyridinium tetrafluoroborate in the molar ratio of 1:6:7.7:36.9 (autoclave, 180 °C, 10 d).
ChemInform Abstract: The Binary Group 4 Azides [PPh4]2[Zr(N3)6] and [PPh4]2[Hf(N3)6].
Authors: Deokar Piyush , Vasiliu Monica , Dixon David A. , Christe Karl O. , Haiges Ralf 
Published: December 2016

Abstract[PPh4]2[M(N3)6] (M: Zr, Hf) are prepared by mixing 1 equiv.
ChemInform Abstract: Na9Sb(Ge2Q6)2 (Q: S, Se): Two New Antimony(III) Quaternary Chalcogenides with Ethane‐Like [Ge2Q6]6‐ Ligands.
Authors: Wu Xiaowen , Hu Yi , Pan Hui , Su Zhi 
Published: December 2016

AbstractAir‐stable crystals of Na9Sb(Ge2S6)2 (I) and Na9Sb(Ge2Se6)2 (II) are prepared by solid state reaction of stoichiometric amounts of the elements (evacuated silica tubes, 600 °C, 72 h; cooling to 300 °C at a rate of 3 °C/h).
ChemInform Abstract: Characterization of Ax[W6I14] as Key Compounds for Ligand‐Substituted A2[W6I8L6] Clusters.
Authors: Hummel Thorsten , Stroebele Markus , Schmid Dominic , Enseling David , Juestel Thomas , Meyer H.‐Juergen 
Published: December 2016

AbstractPolycrystalline Mx[W6I14] (M: Na, K, Rb, Cs) is prepared by solid state reaction of stoichiometric amounts of MI and W3I12 (<95% yield).
ChemInform Abstract: Hydrothermal Synthesis and Magnetic Characterization of the Quaternary Oxide CoMo2Sb2O10.
Authors: Ali Sk Imran , Kremer Reinhard K. , Johnsson Mats 
Published: December 2016

AbstractGreen single crystals of CoMo2Sb2O10 are prepared by hydrothermal reaction of a 1:2:1 molar mixture of CoF2, MoO3, and Sb2O3 in diluted aq.
ChemInform Abstract: [CH3NH3] 2Ag4SnIV2Sn IIS8: An Open‐Framework Mixed‐Valent Chalcogenidostannate.
Authors: Zhang Bo , Li Jun , Du Cheng‐Feng , Feng Mei‐Ling , Huang Xiao‐Ying 
Published: December 2016

Abstract[MeNH3] 2Ag4SnIV2Sn IIS8 is prepared by solvothermal reaction of a 1:1:4 molar mixture of AgCl, Sn, S, and MeNH2 in EtOH (autoclave, 160 °C, 8 d, ≈34% yield).
ChemInform Abstract: Classical/Non‐Classical Polyoxometalate Hybrids.
Authors: Izarova Natalya V. , Santiago‐Schuebel Beatrix , Willbold Sabine , Hess Volkmar , Koegerler Paul 
Published: December 2016

AbstractCs4Na3H4 [Se2Pd4W14O56H] ·18H2O·0.3Cs(OAc)·0.2Na(OAc) (I) and Cs9.5Na2.5 [Se4Pd4W28O108H12] ·30H2O (II) are precipitated with aq.
ChemInform Abstract: Synthesis of a Novel Magnetic Reusable Organocatalyst Based on 4‐Dialkylaminopyridines for Acyl Transformations.
Authors: Panahi Farhad , Dangolani Soheila Khajeh , Khalafi‐Nezhad Ali 
Published: December 2016

AbstractA newly synthesized magnetic nanoparticles‐supported 4‐(dimethylamino)pyridine (DMAP)‐based catalyst is used as a robust heterogeneous organocatalyst in organic transformations as the acylation of hydroxyl and amino functionalized substrates under mild and solvent‐free conditions.
ChemInform Abstract: Enantioselective Amination of Acyclic α‐Alkylated β‐Keto Esters Catalyzed by Chiral Lithium Binaphtholate.
Authors: Kotani Shunsuke , Asano Toshifumi , Moritani Miyuki , Nakajima Makoto 
Published: December 2016

AbstractThe synthesis of optically active α,α‐disubstituted amino acid derivatives is achieved through asymmetric amination of β‐keto esters with azidodicarboxylates using a chiral lithium binaphtholate derived from BBI as catalyst.
ChemInform Abstract: Iridium‐Catalyzed Regio‐ and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles.
Authors: Chen Ming , Hartwig John F. 
Published: December 2016

AbstractThe first Ir‐catalyzed enantioselective allylation of trisubstituted allylic electrophiles is developed.
ChemInform Abstract: Pyrrolidine Derived Thioureas as Organocatalysts in the Michael Reaction of Vinyl Sulfone. Structure—Stereoselectivity Study.
Authors: Jovanovic Predrag , Petkovic Milos , Ivkovic Branka , Savic Vladimir 
Published: December 2016

AbstractStereoselectivity, achieved in the title Michael reaction, is found to be highly dependent on the substitution pattern of the pyrrolidine derived organocatalyst employed.
ChemInform Abstract: Caveat in the Stereochemical Outcome of the Organocatalytic Diels—Alder Reaction in PEG‐400.
Authors: Anitha Pantapalli M. , Mainkar Prathama S. , Kallepu Shivakrishna , Babu V. S. Phani , Reddy Cirandur Suresh , Chandrasekhar Srivari 
Published: December 2016

AbstractDiels—Alder reaction between cinnamaldehydes (I) and cyclopentadiene (II) in the presence of (S)‐pyrrolidine derivative as catalyst and perchloric acid as additive yields cycloaddition products favouring the endo formation (IV).
ChemInform Abstract: Intramolecular Cycloaddition of Azomethine Ylides Activated by Aromatic Rings: Scope and Limitations.
Authors: Xie Hongxiang , Gong Bowen , Zhong Xinran , Cui Hongming , Xiang Jinbao 
Published: December 2016

AbstractThe reactivity of the azomethine ylides in cycloaddition reactions is improved by the presence of electron‐deficient aromatic rings as well as the presence of ortho substituents relative to the aminomethyl group.
ChemInform Abstract: A Convenient Route to Benzimidazole Fused Chiral Heterocyclic Bases.
Authors: Wagh Swapnil J. , Tawde Trupti S. , Sapre Jai V. , Khose Vaibhav N. , Karnik Anil V. 
Published: December 2016

AbstractRacemic thiazolo‐ and pyrrolobenzimidazoles are prepared in good yields.
ChemInform Abstract: Diastereoselective B(C6F5)3‐Catalyzed Reductive Carbocyclization of Unsaturated Carbohydrates.
Authors: Bender Trandon A. , Dabrowski Jennifer A. , Zhong Hongyu , Gagne Michel R. 
Published: December 2016

AbstractSelective carbocyclizations of unsaturated carbohydrates yield cyclopentanes and cyclopropanes via sila‐THF cations as key intermediates.
ChemInform Abstract: Benzannulation of Triynes Initiated by an Alder‐Ene Reaction and Subsequent Trifluoromethylthiolate Addition.
Authors: Karmakar Rajdip , Mamidipalli Phani , Salzman Ryan M. , Hong Seongwon , Yun Sang Young , Guo Wei , Xia Yuanzhi , Lee Daesung 
Published: December 2016

AbstractThe tandem intramolecular cyclization‐thiolation of trienes affords trifluoromethylthiolated benzolactams and ‐benzolactones, respectively.
ChemInform Abstract: One‐Pot Synthesis of N‐tert‐Butylsulfinylimines and Homoallylamine Derivatives from Epoxides.
Authors: Lahosa Alejandro , Foubelo Francisco , Yus Miguel 
Published: December 2016

AbstractThe reaction of epoxides with tert‐butanesulfinamide in the presence of a Lewis acid, such as erbium triflate or boron trifluoride—diethyl ether, in THF as solvent, under microwave or thermal activation, produces N‐tert‐butylsulfinylimines in reasonable yields.
ChemInform Abstract: Access to Constrained Fluoropseudopeptides via Ring‐Closing Metathesis of Fluoroalkenes.
Authors: Guerin David , Dez Isabelle , Gaumont Annie‐Claude , Pannecoucke Xavier , Couve‐Bonnaire Samuel 
Published: December 2016

AbstractThe ring‐closing metathesis of N‐(γ‐fluoroallyl)‐3‐butenamides provides unsaturated fluoro δ‐lactams in high yields, which are suitable synthetic intermediates of fluoro pseudopeptides.
ChemInform Abstract: Iodobenzene Dichloride in the Esterification and Amidation of Carboxylic Acids: In‐situ Synthesis of Ph3PCl2.
Authors: Carle Myriam S. , Shimokura Grace K. , Murphy Graham K. 
Published: December 2016

AbstractA novel in situ synthesis of dichlorotriphenylphosphorane is accomplished upon combining triphenylphosphine and the hypervalent iodine reagent iodobenzene dichloride.
ChemInform Abstract: An Expedient and Convenient Approach for One‐Pot Synthesis of 1H‐Isoindole‐1,3(2H)‐diones.
Authors: Ekhtiari Zeinab , Havasi Forugh , Nikpour Farzad 
Published: December 2016

AbstractThe approach is based on the reaction of cyclic anhydrides with guanidinium hydrochloride as the nitrogen source.
ChemInform Abstract: Lanthanide‐Catalyzed Reversible Alkynyl Exchange by Carbon—Carbon Single‐Bond Cleavage Assisted by a Secondary Amino Group.
Authors: Shao Yinlin , Zhang Fangjun , Zhang Jie , Zhou Xigeng 
Published: December 2016

AbstractLanthanide‐catalyzed alkynyl exchange through C—C single‐bond cleavage assisted by a secondary amino group is reported.
ChemInform Abstract: A Single‐Flask Synthesis of Morita—Baylis—Hillman Adducts from Ethoxyacetylene and Carbonyl Compounds: Synthesis of Subamolides D and E.
Authors: Ng Kevin , Minehan Thomas G. 
Published: December 2016

AbstractLithiation of ethoxyacetylene and sequential addition reaction with aldehydes and/or ketones and BF3·OEt2 leads to 2‐hydroxymethyl enoates in good to excellent overall yields.
ChemInform Abstract: Trifluoromethylthiolation and Trifluoromethylselenolation of α‐Diazo Esters Catalyzed by Copper.
Authors: Matheis Christian , Krause Thilo , Bragoni Valentina , Goossen Lukas J. 
Published: December 2016

AbstractA high yielding conversion of α‐diazoesters to trifluoromethyl thioethers is achieved in the presence of catalytic amounts of CuSCN using Me4NSCF3 as easy to handle and storable reagent.
ChemInform Abstract: A Metal‐Free Synthesis of 2‐Alkyl(or Aryl) Thiomethyl‐2‐cyclohexenones from Cyclic Morita—Baylis—Hillman Bromides.
Authors: Baioui Narjes , Abidi Ahlem , Rezgui Farhat 
Published: December 2016

AbstractMild and metal‐free reaction conditions are attractive features of the entitled synthesis leading to the allyl sulfides (III) in good to moderate yields.
ChemInform Abstract: TfOH Promoted Reactions of Vinyl gem‐Dichlorocyclopropanes with Arenes: Access to Aryl gem‐Dichloropentenes.
Authors: Kazakova Anna A. , Bogomazova Anna A. , Iakovenko Roman O. , Zlotsky Simon S. , Vasilyev Aleksander V. 
Published: December 2016

Abstractgem‐Dichlorocyclopropane (I) reacts with benzene or electron rich methylbenzenes in the presence of superacidic TfOH to afford ring‐opened 3‐arylpent‐1‐enes.
ChemInform Abstract: Selective gem‐Dichlorination of Isonitriles Mediated by (Dichloroiodo)benzene.
Authors: Zhang Haifeng , Shi Dongdong , Ren Shaobo , Jin Hongwei , Liu Yunkui 
Published: December 2016

AbstractA selective gem‐dichlorination of isonitriles is successfully achieved by using (dichloroiodo)benzene as a chlorinating reagent.
ChemInform Abstract: Selective Claisen Rearrangement and Iodination for the Synthesis of Polyoxygenated Allyl Phenol Derivatives.
Authors: Bochicchio Antonella , Cefola Rossella , Choppin Sabine , Colobert Francoise , Di Noia Maria Antonietta , Funicello Maria , Hanquet Gilles , Pisano Isabella , Todisco Simona , Chiummiento Lucia 
Published: December 2016

AbstractThe antibacterial properties of the products are investigated.
ChemInform Abstract: Highly Stereoselective Direct Aldol Reaction of 4‐Formylcoumarins with Acetone Catalyzed by L‐Proline in Water—Acetone Mixtures.
Authors: Holiyachi Megharaja , Shastri Samundeeswari L. , Chougala Bahubali M. , Shastri Lokesh A. , Sunagar Vinay A. 
Published: December 2016

AbstractThe new protocol proceeds highly enantioselectively under green reaction conditions.
ChemInform Abstract: An Efficient Method for the Preparation of Dialkoxymethanes from Dichloromethane with Alcohols Catalyzed by a Cu‐NHC Complex.
Authors: Zhan Lewu , Pan Renming , Xing Ping , Jiang Biao 
Published: December 2016

AbstractThe title synthesis is successfully performed using benzylic, heterobenzylic or aliphatic alcohols as well as phenol or catechol as the substrates.
ChemInform Abstract: Palladium‐Catalyzed Coupling of Benzoyl Halides with Aryltrifluorosilanes Leading to Diaryl Ketones.
Authors: Ogiwara Yohei , Maegawa Yuki , Sakino Daisuke , Sakai Norio 
Published: December 2016

AbstractThe first Hiyama cross‐coupling of acyl halides or pseudohalides with aryltrifluorosilanes is described.
ChemInform Abstract: Nitration‐Oximization of Styrene Derivatives with tert‐Butyl Nitrite: Synthesis of α‐Nitrooximes.
Authors: Chumnanvej Napasawan , Katrun Praewpan , Pohmakotr Manat , Reutrakul Vichai , Soorukram Darunee , Kuhakarn Chutima 
Published: December 2016

AbstractThe simple method proceeds under mild and metal‐free reaction conditions in an environmentally benign solvent.
ChemInform Abstract: Development of a Method for the N‐Arylation of Amino Acid Esters with Aryl Triflates.
Authors: King Sandra M. , Buchwald Stephen L. 
Published: December 2016

AbstractA N‐arylation of α‐ and β‐amino acid esters with aryl triflates is presented utilizing a Pd catalyst under mild reaction conditions with minimal racemization.
ChemInform Abstract: Exploiting the Reactivity of Isocyanide: Coupling Reaction Between Isocyanide and Toluene Derivatives Using the Isocyano Group as an N1 Synthon.
Authors: Liu Zhiqiang , Zhang Xinglu , Li Jianxiong , Li Feng , Li Chunju , Jia Xueshun , Li Jian 
Published: December 2016

AbstractAn oxidative coupling reaction of isocyanides and methylbenzenes using tetrabutylammonium iodide as a catalyst affords the corresponding benzamides.
ChemInform Abstract: Room Temperature Copper‐Catalyzed Oxidative Amidation of Terminal Alkynes for the Synthesis of α‐Ketoamides Using O‐Benzoyl Hydroxylamines as Aminating Reagent and Oxidant.
Authors: Shen Guodong , zhao Lingyu , Wang Yichen , Zhang Tongxin 
Published: December 2016

AbstractThe title reaction only applies to terminal aryl alkynes and tertiary amines.
ChemInform Abstract: Palladium‐Catalyzed Regioselective Direct Cyanation of Acetanilide Derivatives with K4[Fe(CN)6] by C—H Bond Activation.
Authors: Kianmehr Ebrahim , Faghih Nasser , Tanbakouchian Arezoo , Mahdavi Mohammad 
Published: December 2016

AbstractThe high‐yielding method has a good functional group tolerance.
ChemInform Abstract: Regio‐ and Stereoselective Oxysulfonylation of Allenes.
Authors: Huang Zhiyuan , Lu Qingquan , Liu Yichang , Liu Dong , Zhang Jian , Lei Aiwen 
Published: December 2016

AbstractThe oxysulfonylation of aryl‐substituted allenes (I) with arylsulfinic acids (II) proceeds readily leading to 2‐sulfonyl allylic alcohols (III), whilst ester‐substituted allene (VI) reacts with benzenesulfinic acid to afford terminal alkene (VII).
ChemInform Abstract: Iodine‐Mediated Regioselective Synthesis of Vinyl Triflones from Styrenes with CF3SO2Na.
Authors: Hua Li‐Na , Li Huan , Qing Feng‐Ling , Huang Yangen , Xu Xiu‐Hua 
Published: December 2016

AbstractThe unexpected direct C—H triflylation of styrenes (I) with sodium triflinate (II) affording title compounds (III) is reported.
ChemInform Abstract: Bimetallic Pt—Sn/γ‐Al2O3 Catalyzed β‐Alkylation of Secondary Alcohols with Primary Alcohols under Solvent‐Free Conditions.
Authors: Wu Kaikai , He Wei , Sun Chenglin , Yu Zhengkun 
Published: December 2016

AbstractThe catalyst used in the environmentally benign reaction procedure is recycled and reused with decreasing activity over five catalytic cycles.
ChemInform Abstract: Enantioselective Cascade Reaction of α‐Cyano Ketones and Isatylidene Malononitriles: Asymmetric Construction of Spiro[4H‐pyran‐oxindoles].
Authors: Xie Jin , Xing Wei‐Long , Sha Feng , Wu Xin‐Yan 
Published: December 2016

AbstractThe first organocatalytic, enantioselective Michael/cyclization cascade reaction sequence between α‐cyano ketones and isatylidene malononitriles proceeds in the presence of a tertiary amine catalyst which contains multiple hydrogen‐bonding donors.
ChemInform Abstract: Spiro‐Condensation of 5‐Methoxycarbonyl‐1H‐pyrrole‐2,3‐diones with Cyclic Enoles to Form Spiro Substituted Furo[3,2‐c]‐coumarins and Quinolines.
Authors: Dubovtsev Alexey Yu. , Silaichev Pavel S. , Nazarov Mikhail A. , Dmitriev Maksim V. , Maslivets Andrey N. , Rubin Michael 
Published: December 2016

Abstract25 examples
ChemInform Abstract: [2 + 2] Cycloaddition Reactions of Butadienyl Ketene with 1,4‐Diazabuta‐1,3‐dienes: Synthesis of Functionalized Butadienyl‐4‐iminomethyl‐azetidin‐2‐ones and Butenylidene‐butadienyl‐[2,2′‐biazetidine]‐4,4′‐diones.
Authors: Bains Deepak , Kumar Yogesh , Singh Prabhpreet , Bhargava Gaurav 
Published: December 2016

AbstractThe reactions of in situ‐generated butadienylketene with 1,4‐diazabuta‐1,3‐dienes are studied.
ChemInform Abstract: Gold‐Catalyzed Domino Synthesis of Functionalized Benzofurans and Tetracyclic Isochromans via Formal Carboalkoxylation.
Authors: Obata Tomoyuki , Suzuki Sho , Nakagawa Asuka , Kajihara Ryota , Noguchi Keiichi , Saito Akio 
Published: December 2016

AbstractA domino cyclization of α‐alkoxyalkyl ortho‐alkynylaryl ethers and electron‐rich arenes affords benzofurans.
ChemInform Abstract: 2,3‐Diphenylphenanthro[9,10‐b]furan Derivatives as New Blue Fluorophores.
Authors: Kojima Taketo , Kawajiri Ikumi , Nishida Jun‐ichi , Kitamura Chitoshi , Kurata Hiroyuki , Tanaka Mirai , Ikeda Hiroshi , Kawase Takeshi 
Published: December 2016

AbstractThe key step in the synthesis of the entitled compounds (IV) is an extraordinary Wittig reaction of phenanthrene‐9,10‐dione (I) and two equivalents of benzylidenetriphenylphosphoranes (II) followed by a dehydrogenation step using DDQ.
ChemInform Abstract: Pd‐Catalyzed C—S Activation/Isocyanide Insertion/Hydrogenation Enables a Selective Aerobic Oxidation/Cyclization
Authors: Chang Jian , Liu Bangyu , Yang Yang , Wang Mang 
Published: December 2016

Abstractfurnishing access to 5‐hydroxy‐α,β‐unsaturated γ‐lactams (III)
ChemInform Abstract: Simple Primary Amino Amide Organocatalyst for Enantioselective Aldol Reactions of Isatins with Ketones.
Authors: Kwon Eunsang , et al.  
Published: December 2016

AbstractAmong a number of amino acid amide‐derived organocatalysts, L‐tert‐leucine derivative TLA features best efficiency in terms of yield, dia‐ and enantiostereoselectivities in the title reaction, in particular, when 6‐membered saturated (hetero)cyclic ketones are used.
ChemInform Abstract: Diborane‐Mediated Deoxygenation of o‐Nitrostyrenes to Form Indoles.
Authors: Yang Kai , Zhou Fei , Kuang Zhijie , Gao Guoliang , Driver Tom G. , Song Qiuling 
Published: December 2016

AbstractA mild, reductive cyclization of ortho‐nitrostyrenes affords indoles via in situ generated nitroso arenes.
ChemInform Abstract: An Atom‐Economic Approach for Vinylation of Indoles and Phenols Using Calcium Carbide as Acetylene Surrogate.
Authors: Rattanangkool Eakkaphon , Vilaivan Tirayut , Sukwattanasinitt Mongkol , Wacharasindhu Sumrit 
Published: December 2016

AbstractThe catalyst‐free method tolerates variously functionalized indoles and phenols.
ChemInform Abstract: Exploiting the Distal Reactivity of Indolyl Methylenemalononitriles: An Asymmetric Organocatalyzed [4 + 2] Cycloaddition with Enals Enables the Assembly of Elusive Dihydrocarbazoles.
Authors: Rassu Gloria , Curti Claudio , Zambrano Vincenzo , Pinna Luigi , Brindani Nicoletta , Pelosi Giorgio , Zanardi Franca 
Published: December 2016

AbstractPreviously elusive 2,9‐dihydro‐1H‐carbazoles become accessible by a novel enantioselective catalytic [4 + 2] eliminative cycloaddition of indolyl methylenemalononitriles with various cinnamaldehydes.
ChemInform Abstract: Palladium‐Catalyzed Intramolecular Dearomatization of Indoles via Decarboxylative Alkynyl Termination
Authors: Chen Si , Wu Xin‐Xing , Wang Jia , Hao Xin‐Hua , Xia Yu , Shen Yi , Jing Huanwang , Liang Yong‐Min 
Published: December 2016

Abstractleading to tetracyclic indoline derivatives
ChemInform Abstract: Bifunctional‐Phosphine‐Catalyzed Sequential Annulations of Allenoates and Ketimines: Construction of Functionalized Poly‐Heterocycle Rings.
Authors: Li Erqing , Jin Hongxing , Jia Penghao , Dong Xuelin , Huang You 
Published: December 2016

AbstractA highly stereoselective sequential annulation reaction between γ‐substituted allenoates and ketimines is reported.
ChemInform Abstract: Organophosphorus‐Mediated N—N Bond Formation: Facile Access to 3‐Amino‐2H‐indazoles.
Authors: Bel Abed Hassen , Schoene Jens , Christmann Mathias , Nazare Marc 
Published: December 2016

AbstractReductive cyclization of 2‐nitro‐benzamidines (I) and (III) affords title compounds (II) and (IV), resp., in moderate to high yields.
ChemInform Abstract: New Imidazolidineiminothione Derivatives: Synthesis, Spectral Characterization and Evaluation of Antitumor, Antiviral, Antibacterial and Antifungal Activities.
Authors: Moussa Ziad , El‐Sharief Marwa A.M.Sh. , Abbas Samir Y. 
Published: December 2016

AbstractMost of the synthesized compounds (III) show antitumor, antiviral, antibacterial, and antifungal activities.
ChemInform Abstract: Synthesis of Optically Active Trifluoromethyl‐Substituted 2,3‐Dihydroimidazo[2,1‐b]oxazoles.
Authors: Mloston Grzegorz , Wroblewska Aneta , Heimgartner Heinz 
Published: December 2016

AbstractAn intramolecular cyclization of enantiopure N(1)‐(2‐hydroxylpropyl)imidazole N‐oxides, prepared by cyclocondensation of hydroxyethanols, formaldehyde, and α‐ketoximes in the presence of acetic anhydride provides trifluoromethylated 2,3‐dihydroimidazo[2,1‐b]oxazoles with retention of stereochemistry.
ChemInform Abstract: Oxidative Rearrangement Strategy for Synthesis of 2,4,5‐Trisubstituted Oxazoles Utilizing Hypervalent Iodine Reagent.
Authors: Liu Qing , Zhang Xiaohui , He Yang , Hussain Muhammad Ijaz , Hu Wen , Xiong Yan , Zhu Xiangming 
Published: December 2016

AbstractTrisubstituted oxazoles (II) are directly synthesized from 3‐hydroxybut‐2‐enimidates (I) through oxidative rearrangement strategy using diacetoxyiodobenzene as oxidizing agent under mild conditions.
ChemInform Abstract: Highly Enantio‐ and Diastereoselective [4 + 2] Cycloaddition of 5H‐Oxazol‐4‐ones with N‐Maleimides.
Authors: Qiu Shuai , Lee Richmond , Zhu Bo , Coote Michelle L. , Zhao Xiaowei , Jiang Zhiyong 
Published: December 2016

Abstractemploying Takemoto`s chiral tertiary amine‐thiourea as the catalyst
ChemInform Abstract: Insights into the Pummerer Synthesis of Oxazolines.
Authors: Becerra‐Cely Laura , Rueda‐Espinosa Juan , Ojeda‐Porras Andrea , Gamba‐Sanchez Diego 
Published: December 2016

AbstractA simple method to access unnatural 2‐substituted 5‐thio oxazolines (II) from sulfoxides (I) is described.
ChemInform Abstract: Novel Synthesis of Tryptamine Derived 4‐Hydroxy‐4‐arylthiazolidine‐2‐thiones and 4‐Arylthiazole‐2(3H)‐thiones by Multicomponent Reactions.
Authors: Devi Nepram Sushuma , Singh Sarangthem Joychandra , Mahiya Kuldeep , Singh Okram Mukherjee , Choi Hojune , Lee Sang‐Gyeong 
Published: December 2016

AbstractThe operationally simple reaction between tryptamine, carbon disulfide, and phenacyl bromide delivers the title products in high yields.
ChemInform Abstract: A Synthetic Pathway to Substituted Benzofuroxans Through the Intermediacy of Sulfonates: The Case Example of Fluoro‐Nitrobenzofuroxans.
Authors: Jovene Cyril , Marrot Jerome , Jasmin Jean‐Philippe , Chugunova Elena , Goumont Regis 
Published: December 2016

AbstractThe syntheses of 4‐fluoro‐6‐nitrobenzofuroxan and 6‐fluoro‐4‐nitrobenzofuroxan are achieved from a sulfonate intermediate possessing an electron‐donating group that facilitates the key nitration step.
ChemInform Abstract: A Novel Domino Approach for Synthesis of Indolyl Tetrahydropyrano[4,3‐c]pyrazole Derivatives as Anticancer Agents.
Authors: Wang Fu‐Qiang , Yang Hui , He Bin , Jia Yong‐Kang , Meng Shi‐Yao , Zhang Chao , Liu Hong‐Min , Liu Feng‐Wu 
Published: December 2016

AbstractA series of indolyl substituted 1,4,6,7‐tetrahydropyrano[4,3‐c]pyrazole derivatives is synthesized via a domino method based on 1,4:6,7‐dianhydrofructose.