bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Tri‐μ‐bromo‐bis(tribromoruthenate(III)) Salts: A Synthetic, Structural, Spectroscopic, and Electrochemical Study.
Authors: APPLEBY D. , HITCHCOCK P. B. , SEDDON K. R. , TURP J. E. , ZORA J. A. , HUSSEY C. L. , SANDERS J. R. , RYAN T. A. 
Published: May 2016

AbstractThe salts A3(Ru2Br9) with A: Rb, Cs, or 1‐ethyl‐3‐methylimidazolium (emim) are synthesized by a modified literature procedure; usually in low yields typically ranging from 7 to 35%.
ChemInform Abstract: Absolute Configuration of the Product of the Acetolactate Synthase Reaction by a Novel Method of Analysis Using Acetolactate Decarboxylase.
Authors: CROUT D. H. G. , LEE E. R. , RATHBONE D. L. 
Published: May 2016

AbstractAs part of a study of the stereochemistry of enzymatic reactions the absolute configuration of the product of the condensation of (I) with (II) is investigated using acetolactate decarboxylase.
ChemInform Abstract: Synthesis of Medium and Large Rings. Part 27. Chromatographic Separation of the Enantiomeric 3,6‐Heptanophthalides. A Contribution to the Problem of the Absolute Configuration of (n)Paracyclophanecarboxylic Acids.
Authors: TOCHTERMANN W. , OLSSON G. , MANNSCHRECK A. , STUEHLER G. + , SNATZKE G. 
Published: May 2016

AbstractThe partial chromatographic resolution of the racemic title compound (I) is achieved with 40% e.e.
ChemInform Abstract: Some Valenes of Benzoanellated Five‐Membered Heteroarenes ‐ Syntheses and NMR Spectra.
Authors: CHRISTL M. , KRIMM S. , KRAFT A. 
Published: May 2016

Abstract1,3‐Dipolar cycloaddition reactions of the benzvalenylsulfone (I) with compounds such as (II) or (VI) and subsequent elimination reaction of the products (III) or (VIII) give rise to valenes such as (V) or (IX).
ChemInform Abstract: Novel Sulfur Transfer Reaction from 5H‐Benzo(f)‐1,2,3,4‐tetrathiepin or 6H‐Benzo(g)‐1,2,3,4,5‐pentathiocin to Olefins.
Authors: SATO R. , SATOH S. , SAITO M. 
Published: May 2016

Abstract1,2,3,4‐Benzotetrathiepin (BTTP) (II) is suitable as sulfurization reagent releasing an active sulfur species which undergoes (2 + 3), (4 + 2), or (6 + 3)cycloaddition reactions with olefins as outlined in the reaction scheme.
ChemInform Abstract: New Low‐Valent Titanium Reagents for Dicarbonyl Coupling and Their Use in a General Method of Annulation.
Authors: CLIVE D. L. J. , MURTHY K. S. K. , ZHANG C. , HAYWARD W. D. , DAIGNEAULT S. 
Published: May 2016

AbstractThe keto aldehydes and diketones (I), (III), (V), and (VII) are reductively cyclized with a low‐valent titanium reagent to produce the fused cycloalkenes (II), (IV), (VI), or (VIII).
ChemInform Abstract: Dependence of the Triplet Potential of Retinal Homologues on the Chain Length: Resonance Raman Spectroscopy and Analysis of Triplet‐Sensitized Isomerization.
Authors: MUKAI Y. , HASHIMOTO H. , KOYAMA Y. 
Published: May 2016

AbstractThe Raman spectra of triplet species from the all‐trans (I), 7‐cis (II), and 9‐cis isomers of C15‐aldehyde (series a)) and C17‐aldehyde (series b)) are recorded.
ChemInform Abstract: A Mild Reduction of Azomethines with Zinc Borohydride. Synthetic Application to Tandem Alkylation‐Reduction of Nitriles.
Authors: KOTSUKI H. , YOSHIMURA N. , KADOTA I. , USHIO Y. , OCHI M. 
Published: May 2016

AbstractSeven secondary amines such as (II) are prepared by reduction of the corresponding azomethines (I) with zinc borohydride.
ChemInform Abstract: Synthesis and X‐Ray Crystal Structure of (E)‐Alkyl 2‐Cyano‐3‐(2‐hydroxyphenyl)propenoates.
Authors: O'CALLAGHAN C. N. , MCMURRY T. B. H. , CARDIN C. J. 
Published: May 2016

AbstractThe title esters (III) are present as the s‐trans conformers ((IIIc): space group P212121 with Z=4).
ChemInform Abstract: Transannular Deactivation in Tetrafluoro(2.2)paracyclophane. Electrophilic Reactivity of Its Open‐Chain Analogue.
Authors: FILLER R. , GADOMSKI J. E. 
Published: May 2016

AbstractAcetylation of (IV), an open‐chain analogue of 4,5,7,8‐tetrafluoro‐(2.2)paracyclophane (VII), proceeds in contrast to (VII) only at the phenyl ring.
ChemInform Abstract: Gossypol and Hemigossypols. Part 4. Preparation of Methylisopropylnaphthol Derivates via Pd‐Catalyzed Cyclocarbonylation.
Authors: DALLACKER F. , WABINSKI‐WESTEROP K. 
Published: May 2016

AbstractFormylation of thymol (Ia) and carvacrol (Ib) with the dichloromethyl ether (II) gives the aldehydes (III) and (IV).
ChemInform Abstract: Organophosphorus Chemistry. Part 19. Deoxygenative Trimerization of 1,2,3‐Indantrione by Triphenylphosphine.
Authors: MAHRAN M. R. , ABDOU W. M. , ABDEL RAHMAN N. M. 
Published: May 2016

AbstractReaction of the trione (I) with triphenylphosphine (II) gives the deoxygenation products (IV) ‐ (VI) including the hitherto unknown trimer (V).
ChemInform Abstract: Synthesis and Reactivity of 7‐Dimethylaminocoumarin‐3‐isocyanate as a Fluorescent Derivatization Reagent for Alcohols.
Authors: FUJINO H. , EGUCHI M. , GOYA S. 
Published: May 2016

AbstractThe coumarinyl isocyanate (IV), prepared by reaction of the ester (I) with hydrazine hydrate (II) and subsequent diazotization and Curtius rearrangement of the hydrazide (III), is coupled with fourteen alcohols such as (V) to produce the corresponding urethanes (VI).
ChemInform Abstract: Enantioselective Intramolecular Diels‐Alder Reactions of Trienes Synthesized from Monosaccharides.
Authors: HERCZEGH P. , ZSELY M. , BATTA G. , DINYA Z. , BOGNAR R. , SZILAGYI L. , BAJZA I. 
Published: May 2016

AbstractStarting with the tribenzylated xylose (I), the nonatrienes (II) and (III) are synthesized.
ChemInform Abstract: Synthesis and Antibacterial Activity of Some 1‐Aryl‐1,4‐dihydro‐4‐oxocinnoline‐3‐carboxylic Acids.
Authors: RADL S. , MOURAL J. , BENDOVA R. 
Published: May 2016

AbstractAll cinnolines prepared are tested for their in vitro antimicrobial activity.
ChemInform Abstract: New 1(2H)‐Phthalazinones of Potential Antimicrobial Activity.
Authors: KASSEM E. M. , KAMEL M. M. , EL‐ZAHAR M. 
Published: May 2016

AbstractThe synthesis of the phthalazinones (V) is achieved by reaction of 4‐chloro‐2‐phenylphthalazin‐1‐one (I) with 4‐aminoacetophenone (II), followed by semi(thio)carbazone formation of the intermediates (III) with (IV).
ChemInform Abstract: Thieno‐ and Isothiazolo(3,4‐b)quinoxalines: Synthesis, Structure and Pharmacological Study.
Authors: VIERFOND J. M. , LEGENDRE L. , MARTIN C. , RINJARD P. , MIOCQUE M. 
Published: May 2016

AbstractThe title compounds (Ia) and (III) show analgesic and anti‐inflammatory activity.
ChemInform Abstract: Pyrazines. Part 19. A Novel Formation of Alkenynylpyrazines in Palladium‐Catalyzed Reaction of 2‐Chloropyrazine and Its N‐Oxide with Acetylenes.
Authors: SATO N. , HAYAKAWA A. , TAKEUCHI R. 
Published: May 2016

AbstractThe formation of the title alkenynylpyrazines (IV) is explained by codimerization of the products (III) with the alkynes (II).
ChemInform Abstract: Syntheses and Reactions of Cyano‐1,3,5‐triazines.
Authors: MORI Y. , KAWAKAMI S. , HASHIDA Y. 
Published: May 2016

AbstractThe 6‐chloro‐1,3,5‐triazines (I) react with potassium or cuprous cyanide (II) to form the 6‐cyano‐1,3,5‐triazines (III).
ChemInform Abstract: Catalytic Effect of a BH3:N,N‐Diethylaniline Complex in the Formation of Alkenyl Catecholboranes from Alk‐1‐ynes and Catecholborane.
Authors: SUSEELA Y. , PRASAD A. S. B. , PERIASAMY M. 
Published: May 2016

AbstractCatecholborane (I), prepared from catechol and diborane in benzene, undergoes coupling reaction with the terminal alkynes (II) in the presence of the N,N‐diethylaniline‐borane complex, yielding the vinylated catecholboranes (III).
ChemInform Abstract: Application of AMPP‐Pd Catalysts in an Unusual Asymmetric Allylic Coupling Reaction of 1‐(Trimethylsilyl)vinylmagnesium Bromide.
Authors: FOTIADU F. , CROS P. , FAURE B. , BUONO G. 
Published: May 2016

AbstractThe palladium complex catalyzed reaction of trimethylsilylvinylmagnesium bromide (I) with the cyclohexenyl acetate (II) yields the trimethylsilylvinylcyclohexene (III) which can be used as a versatile synthon.
ChemInform Abstract: Studies on N,N‐Disubstituted Dialkyl 2‐Aminoethylphosphonates and Derivatives Thereof.
Authors: XU Y. , JIANG X. , YUAN C. 
Published: May 2016

AbstractThe aminoethylphosphonates (III) are prepared by coupling the bromoethylphosphonate (I) with the amines (II) or by reaction of the aminochloroethanes (IV) with the sodium dialkyl phosphites (V).
ChemInform Abstract: Synthesis, Solid‐State (X‐Ray) and Solution (NMR) Studies of the Hydridocarbido Carbonyl Cluster Anion (Re7H2C(CO)21)‐.
Authors: BERINGHELLI T. , D'ALFONSO G. , CIANI G. , SIRONI A. , MOLINARI H. 
Published: May 2016

AbstractThe protonation product from (I), the title cluster (II) (space group P21/c, Z=4) behaves as a strong acid being completely dissociated in basic solvents.
ChemInform Abstract: Synthesis of (.+‐.)‐17,18‐Dimethoxyhexadehydroyohimbane. A Key Intermediate in the Synthesis of Deserpidine Analogues.
Authors: CHATTERJEE A. , PANDIT U. K. 
Published: May 2016

AbstractCyclization of the diazomethyl ketone (I) gives the indanone (II) which is oxidized, forming the lactone (III) as the key synthon.
ChemInform Abstract: Chemistry of Sulfur Halides. Part 36. Preparation of S7X+MF‐ 6 (X: F, Cl; M: As, Sb) and Vibrational Spectra of the Series S7X+ (X: F, Cl, Br, I).
Authors: MINKWITZ R. , NOWICKI J. 
Published: May 2016

AbstractS7F+MF6‐ and S7Cl+MF6‐ with M: As, Sb are prepared by the same method previously reported for S7X+MF6‐ with X: Br, I (reaction of S82+(MF6‐)2 with NaF or KCl in liq.
ChemInform Abstract: 29Si NMR Characterization of α‐ and β‐Silicon Nitride.
Authors: CARDUNER K. R. , BLACKWELL C. S. , HAMMOND W. B. , REIDINGER F. , HATFIELD G. R. 
Published: May 2016

AbstractThe fine structure of the 29Si NMR spectra of α‐ and β‐Si3N4 is shown to arise from a combination of non‐nearest‐neighbor effects and the presence of 29Si‐14N residual quadrupole‐perturbed dipolar coupling.
ChemInform Abstract: Anodic Functionalization of Olefins in Alcohols in the Presence of Hydrohalic Acid Salts.
Authors: ELINSON M. N. , MAKHOVA I. V. , NIKISHIN G. I. 
Published: May 2016

AbstractElectrolysis of the styrenes (I) in the presence of methanol (II) or the glycols (XI) and sodium bromide predominantly gives the acetals (III) and (XII) respectively.
ChemInform Abstract: Dramatic Rate Accelerations of Diels‐Alder Reactions in 5 M Lithium Perchlorate‐Diethyl Ether: The Cantharidin Problem Reexamined.
Authors: GRIECO P. A. , NUNES J. J. , GAUL M. D. 
Published: May 2016

AbstractDiels‐Alder adducts, which hitherto have been inaccessible via conventional means, can be efficiently obtained through the agency of the medium LiClO4/Et2O. Some examples of reactions are shown in the scheme.
ChemInform Abstract: Convenient Two‐Step Conversion of Acid Chlorides to Terminal Alkynes.
Authors: AITKEN R. A. , SETH S. 
Published: May 2016

AbstractAcylation of ethoxycarbonylmethylenetriphenylphosphorane (II) with the acyl chlorides (I) in toluene gives the keto ylides (III) which are cleaved upon flash vacuum pyrolysis, yielding the alkynes (IV).
ChemInform Abstract: New Synthesis of Angularly Substituted Bicyclic Systems via an Anionic Oxy‐Cope Rearrangement.
Authors: SATHYAMOORTHI G. , THANGARAJ K. , SRINIVASAN P. C. , SWAMINATHAN S. 
Published: May 2016

AbstractA general synthesis of trans bicyclic carbinols (V) with an angular methyl substituent uses the anionic oxy‐Cope rearrangement of the precursors (III).
ChemInform Abstract: Photochemistry and Photophysics of Ketyl Radicals Containing the Anthrone Moiety.
Authors: NETTO‐FERREIRA J. C. , MURPHY W. F. , REDMOND R. W. , SCAIANO J. C. 
Published: May 2016

AbstractTwo‐laser, two‐color techniques are employed to examine the photochemistry of radicals (II) and (III) (generated from (Ia) by way of photolysis in (tBuO)2/Et3SiH).
ChemInform Abstract: Isolation of Conformational Isomers of α‐ and β‐Ionones by Inclusion Complex Formation.
Authors: TODA F. , TANAKA K. , FUJIWARA T. 
Published: May 2016

AbstractComplexation with (I) as host molecule allows isolation of s‐trans‐β‐ionone (IIA) as 2:1 inclusion compound (space group P1 with Z=2), whereas host (III) selectively forms a 1:1 inclusion compound with the s‐cis‐isomer (IIB).
ChemInform Abstract: Reactions of Dialkylmagnesium ‐ Salt Mixtures with Ketones: Increasing the Ratio of Addition to Reduction.
Authors: RICHEY H. G. JUN. , DESTEPHANO J. P. 
Published: May 2016

AbstractThe reaction of ketones such as (I) with dipropylmagnesium (II) gives a mixture of the addition (III) and the reduction product (IV).
ChemInform Abstract: Metathesis of Functionalized Olefins Using the Catalytic System WCl6 ‐ 1,1,3,3‐Tetramethyl‐1,3‐disilacyclobutane.
Authors: BESPALOVA N. B. , BOVINA M. A. 
Published: May 2016

AbstractMetathesis of the olefins (I) or (III) and cometathesis of (I) with (V) or (IX) in the presence of the catalytic system mentioned in the title gives the expected products.
ChemInform Abstract: Generation and Trapping of Thiophen‐2‐ylchlorocarbenes from 2‐Dichloromethylthiophenes and 3‐Chloro‐3‐(thiophen‐2‐yl)diazirine.
Authors: BAIRD M. S. , BRUCE I. 
Published: May 2016

AbstractThe generation and addition of some carbenes to alkenes yielding cyclopropanes such as (III) is investigated.
ChemInform Abstract: Straightforward Synthesis of Isopropylidenediphenylsulfurane and Application to Industrially Viable Stereoselective Synthesis of Deltamethrin Insecticide.
Authors: KRIEF A. , LECOMTE P. , DEMOUTE J. P. , DUMONT W. 
Published: May 2016

AbstractAddition of the α‐lithiated sulfonium salt (II) to the butenolide (I) and the γ‐alkoxycarboxylic acid ester (V) produces stereoselectively the cyclopropanes (III) and (VI) which are both transformed into the cis‐hemicaronate (IV).
ChemInform Abstract: Synthesis and NMR‐Spectral Characterization of N,N‐Dialkyl‐3‐nitroanilines, N,N‐Dialkyl‐1,3‐benzenediamines and Their Acyl Derivatives.
Authors: KATRITZKY A. R. , RACHWAL B. , RACHWAL S. 
Published: May 2016

AbstractThe alkylation of the nitroaniline (I) yields a mixture of mono‐ (III) and dialkylated product (IV).
ChemInform Abstract: Vinyl Carbanions. Part 41. Diastereoselectivity in Center‐Face Interaction of Reactants. Synthesis of Tetronic Acid Derivatives from β‐C‐Lithiated Acrylates and Aldehydes and Methylation of 5‐Deprotonated 4‐Amino‐2(5H)‐furanones.
Authors: JATZKE H. , EVERTZ U. , SCHMIDT R. R. 
Published: May 2016

AbstractThe optically active methyl acrylate (I) reacts with acetaldehyde (II) in the presence of lithium diisopropylamide to produce the methylfuranone (III) as the main product.
ChemInform Abstract: Synthesis and Reaction Behavior of 5‐Azido‐4‐trifluoromethyl‐1,3‐azoles.
Authors: BURGER K. , GEITH K. , HOESS E. + 
Published: May 2016

AbstractThe 5‐fluoro azoles (I) react with the azides (II) and (IV) respectively to produce the corresponding azido azoles (III).
ChemInform Abstract: The Pechmann Reaction and Regioselective Oxidation with Selenium Dioxide. Synthesis of the 12‐Demethoxydefucogilvocarcin Ring System.
Authors: HUA D. H. , SAHA S. , MAENG J. C. , BENSOUSSAN D. 
Published: May 2016

AbstractPechmann reaction of resorcinol (I) or 1,5‐dihydroxynaphthalene (IV) with the ketocarboxylates (II) yields the lactones (III) or (V).
ChemInform Abstract: Synthesis and Biological Activity of 4‐(N‐Arylidenehydrazido)‐1,4‐benzothiazine‐2,3‐diones, Azetidiones and 4‐Thiazolidinones.
Authors: HOGALE M. B. , UTHALE A. C. 
Published: May 2016

AbstractSixteen title compounds of type (V) are prepared and converted to the corresponding azetidinones of type (VII) and thiazolidinones of type (IX).
ChemInform Abstract: Newer Heterocycles of Phenothiazine and Their Antiparkinsonian Activity.
Authors: KHANNA R. , PALIT G. , SRIVASTAVA V. K. , SHANKER K. 
Published: May 2016

AbstractThe phenothiazines (III) are used as starting material for the preparation of a series of derivatives (V) (5 examples), (VII) (9 examples) and (VIII) (4 examples).
ChemInform Abstract: Phosphonic Systems. Part 1. Synthesis and Addition Reactions of 1‐Pentenylphosphonic Diamides.
Authors: MODRO A. M. , DE JONGH C. P. , MODRO T. A. 
Published: May 2016

AbstractThe 1‐pentenylphosphonic diamides (III) are prepared from 2‐chloropentylphosphonic dichloride (I) as shown for the examples (IIIa) and (IIIb).
ChemInform Abstract: Synthesis, Characterization, and Reactivity of a Chromium Tricarbonyl Complex of Phenylsilatrane: Molecular Structure of (C6H5Si(OCH2CH2)3N)Cr(CO)3.
Authors: CHUNG T.‐M. , LEE Y. ‐A , CHUNG Y. K. , JUNG I. N. 
Published: May 2016

AbstractThe synthesized title compound (III) (space group Pbca, Z = 8) is characterized by elemental analysis, IR and NMR spectroscopy, and X‐ray structure analysis.
ChemInform Abstract: Reactions of Coordinated Ligands. Part 48. Reactivity Studies of the Octatrienediylidenedimolybdenum Complexes (Mo2(μ‐C8Me8)(η‐C5H5)2) and (Mo2(μ‐C8H4tBu4)(η‐C5H5)2). Crystal Structures of (Mo2(μ‐C8Me7CH2)(η‐C5H5)2)(CF3SO3), (Mo2(μ‐C8Me8)(μ‐Cl)(η‐C5H5)2)(SbCl4)·CH2Cl2, and (Mo2(μ‐C8H4tBu4)(μMo,C‐H)(η‐C5H5)2)(BPh4)·CH2Cl2.
Authors: BOTT S. G. , BRAMMER L. , CONNELLY N. G. , GREEN M. , ORPEN A. G. , PAXTON J. F. , SCHAVERIEN C. J. , BRISTOW S. , NORMAN N. C. 
Published: May 2016

AbstractDouble protonation of the binuclear Mo compound (I) with an excess of CF3SO3H affords the cationic complex (II) (space group P21/c, Z=8).
ChemInform Abstract: Chemistry and Stereochemistry of the Iridoids. Part 12. Synthesis of Enantiomerically Pure (‐)‐Hypnophilin.
Authors: WEINGES K. , DIETZ U. , OESER T. , IRNGARTINGER H. 
Published: May 2016

AbstractThe bicyclic alcohol (I), available from catalpol according to a literature method, is used as starting material for the preparation of the title compound (VII), a colorless oil which decomposes within a few days.
ChemInform Abstract: Iodonium Ion Promoted Reactions at the Anomeric C‐2 Center of 1‐Methylene Sugars.
Authors: NOORT D. , VEENEMAN G. H. , BOONS G.‐J. P. H. , VAN DER MAREL G. A. , MULDER G. J. , VAN BOOM J. H. 
Published: May 2016

AbstractTreatment of 2,6‐anhydro‐3,4,5,7‐tetra‐O‐benzyl‐1‐deoxy‐D‐glucohept‐1‐enitol (I) with iodonium sym‐dicollidine perchlorate (IDCP) in the presence of water results in the formation of the iodomethyl derivative (II) which undergoes intramolecular cyclization to produce the spiro epoxide (III).
ChemInform Abstract: Demethyl(trifluoromethyl)actinomycins.
Authors: GIENCKE A. , LACKNER H. 
Published: May 2016

AbstractThe synthesis of new (trifluoromethyl)benzoic acid derivatives such as (I) and (II) provides access to various types of the title compounds, e.g. (III), (VII) and (X)‐(XII).
ChemInform Abstract: Creatones A and B. Revision of the Structure for the Product of Oxidation of Creatinine and Creatine.
Authors: NAKAMURA K. , OHIRA C. , YAMAMOTO H. , PFLEIDERER W. , IENAGA K. 
Published: May 2016

AbstractEarlier reports on the oxidation of creatinine (I) assumed the structure (VI) for the oxidation product.
ChemInform Abstract: Tin(IV) Antimonate as a Lead‐Selective Cation Exchanger: Synthesis, Characterization, and Analytical Applications.
Authors: VARSHNEY K. G. , GUPTA U. 
Published: May 2016

AbstractA new lead‐selective cation exchange material with the tentative formula (I), prepared starting from solutions of SnCl4·5 H2O and KSb(OH)6, possesses a good ion exchange capacity (2.4 mequiv/g) and stability.
ChemInform Abstract: Preparation and Crystal Structure of a Potassium Imidonitridosilicate, K3Si6N5(NH)6.
Authors: PETERS D. , PAULUS E. F. , JACOBS H. 
Published: May 2016

AbstractSingle crystals of the title compound are obtained from the reaction of potassium and silicon with supercritical ammonia (K:Si = 1:1, 6 kbar, 500 °C, 3 d).
ChemInform Abstract: Bridgehead‐Bridgehead Communication in Untransannulated ZP(ECH2CH2)3N Systems.
Authors: XI S. K. , SCHMIDT H. , LENSINK C. , KIM S. , WINTERGRASS D. , DANIELS L. M. , JACOBSON R. A. , VERKADE J. G. 
Published: May 2016

AbstractTrigonal‐bipyramidal phosphatranes such as ZP(ECH2CH2)3N+ (Z: H+; E: O, NMe) feature a formal Nax→P bond (ca.
ChemInform Abstract: Use of Potassium Fluoride in the Cyclization of 3‐Hetero‐1,5‐dialdehydes with Nitromethane and Ethyl Nitroacetate.
Authors: SANTOYO GONZALEZ F. , VARGAS BERENGUEL A. 
Published: May 2016

AbstractKF is an efficient catalyst for cyclization reactions of dialdehydes (hemialdals) with nitromethane (II) or with ethyl nitroacetate (IV).
ChemInform Abstract: New Routes to Thioketenes and Propadienethione by Flash Vacuum Thermolysis.
Authors: VALLEE Y. , MASSON S. , RIPOLL J.‐L. 
Published: May 2016

AbstractThe retro‐Diels‐Alder reaction under f.v.p. conditions is applied to the synthesis of simple unstabilized thioketenes (II) and (VIII).
ChemInform Abstract: A Facile Method for Generation of Carbon Oxide Sulfide.
Authors: MIZUNO T. , NISHIGUCHI I. , HIRASHIMA T. , SONODA N. 
Published: May 2016

AbstractDi‐n‐propylamine (I) reacts with carbon monoxide (II) and sulfur (III) in the presence of metallic selenium as the catalyst, forming the carbamothioic acid salt (IV).
ChemInform Abstract: A Novel Asymmetric Synthesis of Chiral Cyclopentanoid Building Blocks by the Use of Chiral Lithium Amide.
Authors: ASAMI M. 
Published: May 2016

AbstractTreatment of 4‐tert.‐butyldimethylsiloxy‐1‐cyclopentene (I) or of its 4‐tetrahydropyranyloxy analogue, which is not given in the scheme, with MCPBA affords separable mixtures of the stereomeric epoxides, e.g. the epoxides (II) and (III) see scheme.
ChemInform Abstract: Chiral Variants of Arylalkyl Sulfur Reagents. (R)‐Camphor Ketimines of o‐Aminothioethers and Oxides.
Authors: DELOGU G. , DE LUCCHI O. , FOIS M. P. , VALLE G. 
Published: May 2016

AbstractKetimines such as (III) are prepared in order to determine the degree of chirality transfer from the chiral auxiliary to the sulfur atom in the formation of the sulfoxides (IV) or to the α‐carbon atom in the reaction of the anion with MeI to yield (VII) (space group P1 with Z=2) and (VIII).
ChemInform Abstract: Synthesis of β‐ and γ‐Hydroxy Sulfones by Regioselective Opening of β,γ‐Epoxy Sulfones.
Authors: NAJERA C. , SANSANO J. M. 
Published: May 2016

AbstractThe epoxy sulfone (I) reacts regioselectively with organo‐Mg compounds such as (II) in the presence of CuBr to afford hydroxysulfones such as (III); in the absence of CuBr, the species (IV) is formed which reacts further with Grignard reagents to yield γ‐hydroxy sulfones such as (VI).
ChemInform Abstract: Oxidation Products of 5‐Ethenyl‐4‐methyl‐3‐pyridinecarbonitrile and 2‐ and 4‐Methylpyridines.
Authors: JAHANGIR JAHANGIR , WANG J. , SMITH R. W. , MACLEAN D. B. , HOLLAND H. L. 
Published: May 2016

AbstractThe anion of the nitrile (I) undergoes oxidative coupling on treatment with dibenzoyl peroxide to give the ethane (II).
ChemInform Abstract: Organometallic Chemistry in Supercritical Fluids: The Generation and Detection of Dinitrogen and Nonclassical Dihydrogen Complexes of Group 6, 7, and 8 Transition Metals at Room Temperature.
Authors: HOWDLE S. M. , HEALY M. A. , POLIAKOFF M. 
Published: May 2016

AbstractUV photolysis of a series of compounds (I)‐(III), dissolved in supercritical Xenon under a high pressure of N2 or H2, leads to the formation of dinitrogen and dihydrogen complexes as demonstrated for (IIa).
ChemInform Abstract: Diphenylantimony Alkoxides and Thiolates as Ligands in Carbonyl Complexes of Chromium and Molybdenum; Crystal Structure of Tris(diphenyl(phenylthiolato)stibane) Molybdenum Tricarbonyl.
Authors: WIEBER M. , HOEHL H. + , BURSCHKA CH. 
Published: May 2016

AbstractThe stibane‐Mo complexes (III) ((IIIa) (R1: Ph): space group P1, Z=4) and (V) (yield 28‐40%) are obtained by reaction of (cycloheptatriene)tricarbonyl‐Mo (I) or (cyclooctadiene)tetracarbonyl‐Mo with corresponding stibane ligand.
ChemInform Abstract: Synthesis, Structure, and Magnetic Properties of a Reactive Complex Containing a Nearly Linear MnIII‐O‐MnIII Core, (Mn2O(5‐NO2saldien)2).
Authors: KIPKE C. A. , SCOTT M. J. , GOHDES J. W. , ARMSTRONG W. H. 
Published: May 2016

AbstractOxidation of the Mn2L2 (L: N,N'‐bis(5‐nitrosalicylidene)‐1,5‐diamino‐3‐azapentane) complex with O2 in MeCN gives the title complex (I) in 54% yield, which crystallizes in P21/c with Z=4.