bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Reactions of Dibenzoylacetylene with N‐Alkyl Nitrones, Heteroaromatic N‐Oxides, Diazo, and Azoxy Compounds.
Authors: EL‐DIN A. M. N. , TAWIK A. E.‐R. M. , MEKAMER R. 
Published: May 2016

AbstractThe nitrones (I) react with dibenzoylacetylene (II) to form the 4‐oxazolines (III).
ChemInform Abstract: A Formylation‐Cyclization Method of Synthesis of Cycloalkenones from Unsaturated Ketones. Part 3. Simple Synthesis of Some Functionalized Angularly Fused Cyclopentenone and Cyclopentanone Derivatives.
Authors: RANU B. C. , CHAKRABORTI R. , GHATAK U. R. 
Published: May 2016

AbstractCyclization of the ketones (I) yields the title cyclopentenone derivatives (II) which are selectively hydrogenated to afford the cyclopentanone derivatives (III).
ChemInform Abstract: One‐Electron Redox Chemistry of Amsacrine, mAMSA (9‐(2‐Methoxy‐4‐methylsulfonylaminoanilino)acridinium), Its Quinone Diimine and an Analogue. A Radiolytic Study.
Authors: ANDERSON R. F. , PACKER J. E. , DENNY W. A. 
Published: May 2016

AbstractUpon one‐electron oxidation both compounds (I) give quinone diimine radicals (I).
ChemInform Abstract: Mannich Reaction with 5,5‐Dimethyl‐3‐phenylamino‐2‐cyclohexen‐1‐one.
Authors: HAMAMA W. S. , HAMMOUDA M. , AFSAH E. M. 
Published: May 2016

AbstractA series of title reactions between (I), formalin (III) and amino compounds, e.g. (II), (V) and (VII), is investigated.
ChemInform Abstract: Umpolung of π‐Allylpalladium Intermediates. A Chemoselective Reductive Elimination of Diols.
Authors: TROST B. M. , TOMETZKI G. B. 
Published: May 2016

AbstractThe unsaturated dicarbonates (I), derived from 1,4‐diols, undergo elimination in the presence of a Pd(0) complex to form the 1,3‐dienes (II).
ChemInform Abstract: α‐Thiosubstituted Ketones as Precursors of Olefins via Oxathiolanes: Benzyl as Protecting Group.
Authors: BROWN M. D. , WHITHAM G. H. 
Published: May 2016

AbstractThe regiospecific synthesis of the tetrasubstituted alkene (VIII) starting from the thiol‐protected ketone (I) involves five steps: a) S‐activated alkylation, b) carbonyl addition of an organometallic reagent, c) deprotection, d) cyclization and e) base‐promoted cycloelimination.
ChemInform Abstract: Pyrylium Compounds. Part 37. Arylbenzenes from 2,4,6‐Triarylpyrylium Salts and Carboxylic Acid Anhydrides.
Authors: ZIMMERMANN T. , FISCHER G. W. 
Published: May 2016

AbstractRefluxing the pyrylium salts (I) with carboxylic acid anhydrides in the presence of basic condensing agents yields triarylbenzenes of type (III) as main products.
ChemInform Abstract: The Synthesis and Novel Structure of Methyl 7‐Phenyldibenza(a,j)anthracene‐14‐carboxylate and Methyl 5‐Phenylbenzo(1,2‐h:5,4‐h′)diquinoline‐3‐carboxylate: Rigid Semi‐Helical Aromatic Spacers with Convergent Functional Groups.
Authors: ZIMMERMAN S. C. 
Published: May 2016

AbstractCyclocondensation of the 1‐tetralones (I) with the 2‐benzylidene‐1‐tetralones (II) gives the pyrylium salts (IV) which react with trimethylphosphonoacetate (V) and NaH to form the pentacyclic esters (VI).
ChemInform Abstract: Silicon‐Functionalized Silyl Enol Ether. Part 2. Silyl Enol Ethers Bearing Stereogenic Silicon Atoms and Chiral Alkoxy Groups: The Effect of These Groups Upon the Facial Selectivity of the Epoxidation of an Enol Double Bond.
Authors: WALKUP R. D. , OBEYESEKERE N. U. 
Published: May 2016

AbstractThe lithium enolates (III), derived from the ketones (I), react with the dichlorosilanes (IV) to produce the chlorosilyl enol ethers (V).
ChemInform Abstract: Synthesis of Aryldichloro‐ and Diarylchlorophosphines.
Authors: KORMACHEV V. V. , VASIL'EVA T. V. 
Published: May 2016

AbstractThe synthesis of the chlorophosphines (III) and (IV) from benzene (I) and phosphorus trichloride in the presence of aluminum trichloride is improved, using bis(2‐chloroethyl) vinylphosphonate or tris(2‐methoxyethyl) phosphate during the work‐up procedure.
ChemInform Abstract: Dinuclear Metal Complexes. Part 8. Effect of Remote Substituents on the Redox Potentials of Mono‐ and Dinuclear Copper(II) Complexes.
Authors: ADHIKARY B. , MANDAL S. K. , NAG K. 
Published: May 2016

AbstractSchiff bases, obtained by condensing 2‐hydroxy‐5‐methylbenzene‐1,3‐dicarbaldehyde with p‐substituted anilines in different amounts, react with Cu acetate to yield the mononuclear complexes (I) or (III) which form dinuclear compounds (II) or (IV) on reaction with Cu perchlorate.
ChemInform Abstract: Synthesis and Study of Some Novel Metal Complexes of Phosphoramidothioic and Phosphorodiamidothioic Ligands.
Authors: SYNGOLLITOU‐KOURAKOU A. S. , TOSSIDIS I. A. 
Published: May 2016

AbstractThe structures of the ten new complexes (I)‐(VII) are assigned on the basis of their elemental analysis, IR and electronic spectra and magnetic properties.
ChemInform Abstract: Thiourea Derivatives of Carbohydrates. Part 12. Syntheses of D‐Ribosylamines, D‐Ribopyranosyl Isothiocyanates, and D‐Ribopyranosylthioureas, and Their Transformations into Heterocyclic Compounds.
Authors: FUENTES MOTA J. , PRADERA ADRIAN M. A. , MELLET C. O. , GARCIA FERNANDEZ J. M. , CABALLERO R. B. , GALBIS PEREZ J. A. 
Published: May 2016

AbstractStarting with D‐ribosylamine (I), the tri‐O‐benzoylribosylamine hydrobromides (VI) and (VII) are synthesized via the ribosylenamines (III) and (IV).
ChemInform Abstract: On the Structure of Hg2I3+ in Dimethylsulfoxide and Aqueous Solution. An X‐Ray Scattering and Raman Spectroscopic Study
Authors: BENGTSSON L. , HOLMBERG B. , PERSSON I. , IVERFELDT A. 
Published: May 2016

Abstractshows that the molecular structure of Hg2I3+ is nearly identical in both solvents.
ChemInform Abstract: Crystal and Molecular Structure of the Mixed‐Valence Ruthenium Dimer Tris(μ‐bromo)bis(triammineruthenium)(2+) Tetrabromozincate(II), ((NH3)3RuBr3Ru(NH3)3)(ZnBr4).
Authors: BEATTIE J. K. , DEL FAVERO P. , HAMBLEY T. W. , HUSH N. S. 
Published: May 2016

AbstractThe title Ru(II)‐Ru(III) dimer (I) crystallizes in the monoclinic space group P21/m with Z=2.
ChemInform Abstract: Hydration Enthalpies of Md3+ and Lr3+.
Authors: BRUECHLE W. + , SCHAEDEL M. + , SCHERER U. W. , KRATZ J. V. , GREGORICH K. E. , LEE D. , NURMIA M. , CHASTELER R. M. , HALL H. L. , HENDERSON R. A. , HOFFMAN D. C. 
Published: May 2016

AbstractThe elution positions of Lr3+ and Md3+ ions (prepared by 18O bombardment of a 249Bk target) from a strongly acidic cation‐exchange resin in buffered ammonium α‐hydroxyisobutyrate solution are determined relative to those of Tm3+, Er3+, and Ho3+.
ChemInform Abstract: Amalgamated Aluminum Electrodes in Acidic Chloroaluminate Molten Salts.
Authors: MOY R. , DONAHUE F. M. 
Published: May 2016

AbstractAmalgamation of aluminum, which is an attractive anode candidate for secondary electrochemical energy conversion devices, is shown to eliminate anodic aluminum passivation in acidic 1‐methyl‐3‐ethyl‐imidazolium chloride‐AlCl3 room temp. molten salt.
ChemInform Abstract: Do Chemical Reactions React Along the Reaction Path?
Authors: HARTKE B. , MANZ J. 
Published: May 2016

AbstractIt is demonstrated that chemical reactions may proceed far away from the minimum energy paths by using classical trajectory simulations and quantum vibrationally near‐adiabatic hyperspherical representations of an exoergic collinear hydrogen‐transfer reaction with two isotopic variants (reaction of F with DBr and MuBr; Mu: muonium).
ChemInform Abstract: Effectiveness of the Cadmium(II) Ion in Promoting Sulfonamide Nitrogen Deprotonation. 113Cd NMR, Polarographic, and pH‐Metric Investigations on the Cadmium(II)‐N‐Tosylglycinate and Cadmium(II)‐N‐Dansylglycinate Systems in Aqueous and Methanolic Solutions.
Authors: BATTISTUZZI GAVIOLI G. , BORSARI M. , PELLACANI G. C. , MENABUE L. , SOLA M. , BONAMARTINI CORRADI A. 
Published: May 2016

AbstractThe investigations, specified in the title, reveal the ability of the Cd2+ ion to substitute the nitrogen‐bound hydrogen of the amino acids, N‐protected by a sulfonic group.
ChemInform Abstract: Acidities of Radical Cations Derived from Remotely Substituted and Phenyl‐Substituted Fluorenes.
Authors: BORDWELL F. G. , CHENG J.‐P. , BAUSCH M. J. 
Published: May 2016

AbstractThe acidities of the radical cations obtained by electrochemical oxidation of fluorene (I) (X: ‐H) and its derivatives are estimated to have pKHA·+ values varying from ‐17 for the parent compound and its 4‐aza and 2‐bromo derivatives to +1 for its 2‐NMe2 derivative in the order given in the scheme.
ChemInform Abstract: Free Energies of Transfer of Carbon Acids and Their Conjugate Carbanions from Water to Me2SO‐Water Mixtures.
Authors: BERNASCONI C. F. , BUNNELL R. D. 
Published: May 2016

AbstractFree energies (or solvent activity coefficients) of transfer of MeNO2, Ph‐CH2‐NO2, Ac‐CH2‐Ac, 1,3‐indandione, 9‐carbomethoxy‐ and 9‐cyanofluorene from H2O to various DMSO‐H2O mixtures are determined from partitioning experiments between heptane and the solvent of interest.
ChemInform Abstract: Reactivity Control by Microencapsulation in Simple Ammonium Ion Vesicles.
Authors: MOSS R. A. , SWARUP S. , ZHANG H. 
Published: May 2016

AbstractWhile normal oxidation of Ellman's anion (I) by iodosobenzoate (II) to Ellman's reagent (III) is quantitatively complete after 2 min and reactions of (I) and (II) occur rapidly on the surface of vesicles of DODAC (IV) (k ca. 0.16‐0.24 s‐1, only a slow (k ca. 2‐7 · 10‐3 s‐1 permeation‐limited oxidation is observed when either (I) or (II) is encapsulated within the DODAC vesicles.
ChemInform Abstract: Photorearrangement of 4‐Alkyl‐4‐alkoxy‐2,5‐cyclohexadienones: Synthesis of 4‐(Alkyldimethoxymethyl)cyclopent‐2‐en‐1‐ones.
Authors: TAVERAS A. G. JUN. 
Published: May 2016

AbstractThe 4‐alkyl‐4‐methoxycyclohexadienones (I) rearrange upon photolysis in methanol (II) to give the (1,1‐dimethoxyalkyl)cyclopentenones (IV) via the intermediates (III).
ChemInform Abstract: Photosensitized Oxygenation of 2,3‐Dihydropyrazines: Unexpected Syntheses of Isonitriles.
Authors: GOLLNICK K. , KOEGLER S. 
Published: May 2016

AbstractPhotosensitized oxygenation of the 2,3‐dihydropyrazines (I) yields the isonitriles (V), probably via the intermediates (II) ‐ (IV).
ChemInform Abstract: Fluorinations with Potassium Tetrafluorocobaltate(III). Part 8. Fluorinations of Toluene and of Phenylacetic Acid.
Authors: BAILEY J. , PLEVEY R. G. , TATLOW J. C. 
Published: May 2016

AbstractVapour phase fluorination of toluene (I) with KCoF4 at 340°C yields the products (II) ‐ (XI) which are isolated using destillation and chromatographic techniques.
ChemInform Abstract: Reaction of Fluoroalkyl‐2‐keto Acids and Their Esters with Acetone.
Authors: SALOUTIN V. I. , PITERSKIKH I. A. , PASHKEVICH K. I. 
Published: May 2016

AbstractThe reaction between the polyfluoroalkylketo esters (I) and acetone (II) proceeds under mild conditions and regioselectively at the 2‐keto function to afford the methyl 2‐hydroxy‐2‐fluoroalkyl‐4‐oxovalerates (III).
ChemInform Abstract: Arene Synthesis by Extrusion Reaction. Part 10. Synthesis of Arenes by Deoxygenation of Endoxides with Cyclopentadienyltitanium Trichloride/ Lithium Aluminum Hydride and Dicyclopentadienyltitanium Dichloride/Lithium Aluminum Hydride.
Authors: WONG C. H. , HUNG C. W. , WONG H. N. C. 
Published: May 2016

AbstractThe 1,4‐endoxides (I) are deoxygenated to form the corresponding arenes (II) using homogeneous low valent titanium which is prepared by treatment of cyclopentadienyltitanium complexes with LiAlH4.
ChemInform Abstract: One‐Pot Synthesis of Tetrakis(alkylthio)ethylenes and 1,3‐Dithiole Derivatives from Bis(methylthio)methane.
Authors: MORADPOUR A. , BITTNER S. 
Published: May 2016

AbstractThe tetrakis(alkylthio)ethylenes (VI) and (VII) are prepared from bis‐(methylthio)methane (I) by consecutive metalation, addition of carbon disulfide (III), and alkylation.
ChemInform Abstract: Cyclization Reactions of Nitriles. Part 25. Synthesis and Reactions of 6‐Amino‐3,5‐dicyanopyridines Containing Chalcogens.
Authors: SHARANIN YU. A. , SHESTOPALOV A. M. , LITVINOV V. P. , KLOKOL G. V. , MORTIKOV V. YU. , DEMERKOV A. S. 
Published: May 2016

AbstractRegioselective condensation of α,β‐unsaturated dinitriles, e.g. (I), bearing a nucleophilic leaving group (alkoxy or amino) at the β‐carbon, with the cyanothio(seleno)acetamides (II) affords the pyridiniumthiolates or ‐selenolates (III), which give the pyridinethiones or ‐selenones (IV) on treatment with acid.
ChemInform Abstract: Chemistry and Positive Inotropic Effect of Pelrinone and Related Derivatives. A Novel Class of 2‐Methylpyrimidones as Inotropic Agents.
Authors: BAGLI J. , BOGRI T. , PALAMETA B. , RAKHIT S. , PESECKIS S. , MCQUILLAN J. , LEE D. K. H. 
Published: May 2016

AbstractThe preparation of a great number of pyrimidones such as (I) and pyrimidines such as (II) is described.
ChemInform Abstract: Synthesis of Si‐Substituted (O→Si)Dimethyl(N‐acetylacetamidomethyl)silanes.
Authors: BELOUSOVA L. I. , GOSTEVSKII B. A. , KALIKHMAN I. D. , VYAZANKINA O. A. , BANNIKOVA O. B. , VYAZANKIN N. S. , PESTUNOVICH V. A. 
Published: May 2016

AbstractThe compound (IIIa) with an intramolecular coordinative Si‐O bond is prepared from the chlorosilane (II) and the acetamide (I).
ChemInform Abstract: Electrochemical Synthesis of Arylphosphinates and Arylphosphine Oxides.
Authors: ROMAKHIN A. S. , BABKIN YU. A. , KHUSAINOVA D. R. , NIKITIN E. V. , KARGIN YU. M. 
Published: May 2016

AbstractAnodic oxidation of the phosphinite (phosphonite) (II) in the presence of the aromatic hydrocarbons (I) gives mixtures of the phosphine oxides (phosphinates) (III) ‐ (V).
ChemInform Abstract: Synthesis and Nuclear Magnetic Resonance Spectroscopy of Geometrical Isomers of 1,3,5‐Trimethyl‐2,4,6‐tris(p‐methylphenoxy)‐2,4,6‐trioxocyclotriphosphazane: X‐Ray Crystal Structure of the trans Isomer.
Authors: KARTHIKEYAN S. , VYAS K. , KRISHNAMURTHY S. S. , CAMERON T. S. , VINCENT B. R. 
Published: May 2016

AbstractThe cis and trans isomers (IIa) and (IIb) are prepared by the thermal rearrangement of the corresponding isomer (Ia) and (Ib) of the trimethoxycyclophosphazene.
ChemInform Abstract: Reorientation of the Alkyne Moiety in the Heterometallic Cluster (FeCo2(CO)9(EtC2Et)), Induced by Phosphine, Phosphite, or Isonitrile Substitution for CO. Crystal Structure of (FeCo2(CO)8(PPh3)(EtC2Et)).
Authors: BOCCARDO D. , BOTTA M. , GOBETTO R. , OSELLA D. , TIRIPICCHIO A. , TIRIPICCHIO‐CAMELLINI M. 
Published: May 2016

AbstractThe spectroscopic and structural data of the parent cluster (I) are compared with those of its monosubstitution derivatives (III) which are formed as shown in the scheme.
ChemInform Abstract: Organo‐Platinum‐Iron Complexes Derived from Allenes. Crystal Structures of ((OC)3Fe(μ‐dppm)(μ‐C(O)CH2C(=CH2))Pt(PPh3)), ((OC)3Fe(μ‐dppm)(μ‐C(=CH2)CH2)Pt(PPh3)), and ((OC)2Fe(μ‐dppm)(η4‐(CH2)(CMe2)CPt(PPh3))).
Authors: FONTAINE X. L. R. , JACOBSEN G. B. , SHAW B. L. , THORNTON‐PETT M. 
Published: May 2016

AbstractTreatment of the diphosphine‐ and CO‐bridged FePt complex (I) with allene (II) at 20 °C in CH2Cl2 gives the insertion product (III).
ChemInform Abstract: A Novel Strategy for the Stereoselective Total Synthesis of C‐17 Spiro Steroids. Total Synthesis of 19‐Norcanrenone, a Formal Total Synthesis of 19‐Norspironolactone.
Authors: NEMOTO H. , FUJITA S. , NAGAI M. , FUKUMOTO K. , KAMETANI T. 
Published: May 2016

AbstractThe intramolecular (4 + 2) cycloaddition of olefinic o‐quinodimethanes of type (V), generated in situ by thermolysis of olefinic benzocyclobutenes of type (IV) (9 examples given) represents the key step in the synthesis of 19‐norcanrenone (X).
ChemInform Abstract: On the Properties of the YBa8Cu4O12+η Phase.
Authors: FJELLVAG H. , KAREN P. , KJEKSHUS A. , GREPSTAD J. K. 
Published: May 2016

AbstractSamples of the title phase with η ranging from ∼ 1 to ∼ 2.8 are studied XRD, neutron diffraction, XPS, and magnetic measurements.
ChemInform Abstract: A Lithosilicat: K3LiSiO4 = K3(LiSiO4),
Authors: HOFMANN R. , HOPPE R. 
Published: May 2016

Abstractobtained by annealing intimate mixtures of the binary oxides KO0.6, Li2O, and SiO2 (closed Ni tube, 8 d, 850 °C; K:Li:Si = 3.5:1.2:1), crystallizes in the monoclinic system, space group P21/c, Z = 8. Chains of edge‐sharing tetrahedra, alternating around Si4+ and Li+, parallel (010), are found to be characteristic for the structure.
ChemInform Abstract: Carbonatization of YBa2Cu3O6+x.
Authors: FJELLVAG H. , KAREN P. , KJEKSHUS A. , KOFSTAD P. , NORBY T. 
Published: May 2016

AbstractThe high Tc superconducting YBa2Cu3O6+x (0 ≦ x ≦ 1) phase reacts with CO2 at a significant rate at temp. > 400 °C. The stability of the title phase towards reaction with CO2 and CO2/O2 mixtures (p(O2) ≈ 1 atm) is established as a function of CO2 pressure and temperature.
ChemInform Abstract: Oxidation of Chloride to Chlorine by Cerium(IV) Ions Mediated by a Microheterogeneous Redox Catalyst.
Authors: MILLS A. , COOK A. 
Published: May 2016

AbstractAt high Cl‐ concentration, the title reaction can be catalyzed by an activated form (annealed at 150‐200 °C, 5 h, air) of ruthenium dioxide hydrate, RuO2·n H2O*.
ChemInform Abstract: Thermodynamics of Vanadyl(IV)‐Carboxylate Complex Formation in Aqueous Solution.
Authors: DI BERNARDO P. , TOMAT G. , ZANONATO P. , PORTANOVA R. , TOLAZZI M. 
Published: May 2016

AbstractThe stability constants and the heats of formation of vanadyl‐acetate, ‐glycolate and ‐glycine complexes are determined by potentiometric and calorimetric measurements.
ChemInform Abstract: Electron Transfer. Part 91. Reactions of Carboxylato‐Bound Chromium(V) with Arenediols.
Authors: GHOSH S. K. , BOSE R. N. , GOULD E. S. 
Published: May 2016

AbstractThe oxo‐Cr(V) complex (I) oxidizes the arenediols (II) and (III) in solutions buffered with the ligand acid, 2‐ethyl‐2‐hydroxybutanoic acid, and its anion.
ChemInform Abstract: Methoxychlorination and Dimethoxylation of Alkenes. The Reactions of Substituted Styrenes with Phenylselenenyl Chloride in Methanol.
Authors: TIECCO M. , TESTAFERRI L. , TINGOLI M. , CHIANELLI D. , BARTOLI D. 
Published: May 2016

AbstractThe addition of 1 equiv. of phenylselenenyl chloride (II) to the styrenes (I) in MeOH (III) is regio‐ and stereospecific to afford the products (IV) resulting from anti methoxyselenenylation.
ChemInform Abstract: Synthesis of Homochiral α‐Alkoxystannanes: Stereospecific Conversion to Cembranolide Precursors.
Authors: MARSHALL J. A. , GUNG W. Y. 
Published: May 2016

AbstractThe stannyl ketone (I) is stereoselectively reduced with the chiral agent (R)‐(+)‐BINAL‐H to yield the (S)‐alcohol (II).
ChemInform Abstract: Metal‐Metal Exchange of α‐Metallo Ketones. Novel Formation of α‐Acyl Anion and α‐Keto Carbonium Ion Equivalents from (Aryl)phenacyl TlIII, PbIV, and HgII Systems.
Authors: MORIARTY R. M. , PENMASTA R. , PRAKASH I. , AWASTHI A. K. 
Published: May 2016

AbstractTreatment of the trimethylsilyl enol ethers (I) with the organometallic compounds (II), (IV), and (VI) gives the α‐metalated ketones (III), (V), and (VII).
ChemInform Abstract: Fluorine Containing Amino Acids. Part 4. Synthesis and Biological Activity of β‐(Polyfluoromethyl)‐Substituted Aromatic Amino Acids.
Authors: KOLYCHEVA M. T. , YAGUPOL'SKII YU. L. , ZAITSEV L. M. , GERUS I. I. , KUKHAR' V. P. , KLEBANOV B. M. 
Published: May 2016

AbstractCoupling of the fluorinated acetophenones (I) with hippuric acid (II) gives the oxazolinones (III) which are reductively cleaved, producing the acids (IV).
ChemInform Abstract: Preparation and Crystal Structure of 3‐(1‐Naphthylmethyl)‐3‐chlorodiazirine.
Authors: LINDEN A. , CAMERON T. S. , LIU M. T. H. , ANAND S. M. 
Published: May 2016

AbstractConversion of 1‐naphthylacetonitrile (I) to the corresponding amidine hydrochloride (III), followed by oxidation with sodium hypochlorite, yields the diazirine (IV).
ChemInform Abstract: A Study of Chemical Carcinogenesis. Part 109. Oxidation of Polynuclear Aromatic Hydrocarbons with Ceric Ammonium Sulfate: Preparation of Quinones and Lactones.
Authors: BALANIKAS G. , HUSSAIN N. , AMIN S. , HECHT S. S. 
Published: May 2016

AbstractOxidation of benzo(k)fluoranthene (I) with ceric ammonium sulfate gives a mixture of the quinones (II) and (III).
ChemInform Abstract: Fluorination of Pyrimidines. Part 2. Mechanistic Aspects of the Reaction of Acetyl Hypofluorite with Uracil and Cytosine Derivatives.
Authors: VISSER G. W. M. , HERDER R. E. , DE KANTER F. J. J. , HERSCHEID J. D. M. 
Published: May 2016

AbstractThe reaction is carried out in H2O, CD3COOD or D2O as well and it is found that a substituent at N‐1 (R1) of uracil (I) has a remarkable effect on the stability of the intermediate dihydrouracils (IV).
ChemInform Abstract: Dopamine Receptor Agonists: New Angularly Annulated Tricyclic Compounds.
Authors: PERRONE R. , BERARDI F. , BETTONI G. , TORTORELLA V. 
Published: May 2016

AbstractThe epoxide (I) is converted to the tetrahydronaphthazirine (IV) which reacts with glycine ethyl ester (V) to give the tricyclic lactam (VI).
ChemInform Abstract: Iminophosphorane‐Mediated Synthesis of Fused (1,2,4)triazines: Preparation of the Novel (1,2,4)Triazino(4,3‐b) (1,2,4,5)tetrazine Ring System.
Authors: MOLINA P. , ALAJARIN M. , VIDAL A. , ELGUERO J. , CLARAMUNT R. M. 
Published: May 2016

AbstractThe iminophosphorane (III) reacts with acyl chlorides to give the desired ring system (VI) in moderate to good yields.
ChemInform Abstract: P2‐ 4 Isomers as Complexing Ligands.
Authors: SCHERER O. J. , SWAROWSKY M. , SWAROWSKY H. , WOLMERSHAEUSER G. + 
Published: May 2016

AbstractThe oxidative addition of white phosphorus P4 (II) to fragments of the complexes (I) results in the quantitative formation of the air‐stable tetraphosphabicyclobutane derivatives (III) containing oxidized M(IV) ions and reduced P42‐ ions.
ChemInform Abstract: Synthesis and Biological Activity of 2‐ or 3‐Dialkoxyphosphorylalkyl Acetates.
Authors: BREL' V. K. , TYURENKOV I. N. , STREL'TSOVA G. V. , MATYUKHOVA N. P. , NAZARENKO V. N. , AGARKOVA N. S. 
Published: May 2016

AbstractPeroxide‐initiated addition reaction of the dialkylphosphites (I) to vinyl or allyl acetate (II) gives the phosphorylalkyl acetates (III).
ChemInform Abstract: Synthesis of Molecular Structure of 2,6‐Di‐tert‐butyl‐4‐methylphenyl N‐(2,4,6‐Tri‐tert‐butylphenyl)imidophosphenite.
Authors: MARKOVSKII L. N. , ROMANENKO V. D. , RUBAN A. V. , DRAPAILO A. B. , CHERNEGA A. N. , ANTIPIN M. YU. , STRUCHKOV YU. T. 
Published: May 2016

AbstractHeating of the chloroamidophosphite (III), prepared from the dichlorophosphite (II) and the silylamide (I), gives the first stable imidophosphenite (IV).
ChemInform Abstract: Oxalato Complexes Directly Formed by the Reaction of Interstitial Carbides with Hydrogen Peroxide.
Authors: KUDO T. , SASAKI Y. , HASHIMOTO M. , MATSUMOTO K. 
Published: May 2016

AbstractThe fact that interstitial carbides such as WC, TiC react with H2O2 in aqueous solutions to give oxalato complexes means that the C‐C bonding is formed by a simple inorganic reaction.
ChemInform Abstract: Electron‐ and Energy‐Transfer Processes Involving Excited States of Lanthanoid Complexes: Evidence for Inner‐Sphere and Outer‐Sphere Mechanisms.
Authors: SABBATINI N. , PERATHONER S. , LATTANZI G. , DELLONTE S. , BALZANI V. 
Published: May 2016

AbstractThe interaction of the luminescent excited states of the aquo‐europium(III) and aquo‐terbium(III) ions, their 2.2.1‐cryptand complexes and the cryptand complexes‐fluoride ion pairs with the complexes M(CN)z6‐ (M: Cr(III), Fe(II), Co(III), Ru(II), Os(II)) is studied in aqueous solution by luminescenc lifetime measurements.
ChemInform Abstract: Reactivity of the Actinoid‐Carbon Bond: Alkyluranium Compounds as Selective Nucleophilic Reagents in Organic Synthesis.
Authors: DORMOND A. , AALITI A. , MOISE C. 
Published: May 2016

AbstractThe alkyluranium compounds (III), (V), and (VII) are synthesized by treatment of the appropriate chlorouranium derivatives such as (I) or (IV) with alkyllithium (II).