bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Electrical Properties of Bulk InP Synthesized by Modified Horizontal Bridgman Method.
Authors: PAK K. , MATSUI M. , FUKUHARA H. , NISHINAGA T. , NAKAMURA T. , YASUDA Y. 
Published: May 2016

AbstractResidual donor impurities of bulk InP are reduced using a modified horizontal Bridgman method (a detailed description is given) for the synthesis.
ChemInform Abstract: Bipolar CdSe/CoS Semiconductor Photoelectrode Arrays for Unassisted Photolytic Water Splitting.
Authors: SMOTKIN E. S. , CERVERA‐MARCH S. , BARD A. J. , CAMPION A. , FOX M. A. , MALLOUK T. , WEBBER S. E. , WHITE J. M. 
Published: May 2016

AbstractThe use of an array of bipolar CdSe/CoS semiconductor photoelectrodes capable of vectorial electron transfer for the unassisted photolytic water splitting with O2 evolved at the semiconductor surface and H2 evolved on a Pt surface is demonstrated.
ChemInform Abstract: The Influence of Crown Ethers on Cation Migration Processes. Part 5. The Acenaphthene Radical Anion.
Authors: FLINT N. J. , TABNER B. J. 
Published: May 2016

AbstractESR investigations (linewidth alternation) of the acenaphthene radical anion/K+ ion pair show cation migration from one side of the molecular plane to the other in THF (energy of activation: 6.6 kJ/mol).
ChemInform Abstract: Cycloaddition of Chloro‐, Cyano‐, Methoxy‐, and (Phenylthio)allene with 1,1‐Dichloro‐2,2‐difluoroethene (1122). Competitive Cyclodimerization and Trapping of the Cyclodimers with 1122.
Authors: PASTO D. J. , YANG S. H. 
Published: May 2016

AbstractThe cycloaddition reactions of the allenes (II) with 1,1‐dichloro‐2,2‐ difluoroethene (I) are investigated.
ChemInform Abstract: Ruthenium‐Catalyzed Synthesis of 2‐Acetoxyallyl Carbonates: A Synthon for Palladium‐Catalyzed 2‐Acetoxyallylation of Carbonucleophiles.
Authors: HORI Y. , MITSUDO T. , WATANABE Y. 
Published: May 2016

AbstractThe propargyl carbonates (I) are treated with acetic acid in the presence of bis(η5‐cyclooctadienyl)ruthenium tricyclohexylphosphine and maleic anhydride to give the 2‐acetoxyallyl carbonates (III) regioselectively.
ChemInform Abstract: Retention of Stereochemistry During Oxidation of (E)‐ and (Z)‐2‐ and 3‐Alkenols to the Corresponding Aldehydes by the Dess‐Martin Reagent.
Authors: SCHWARZ M. , WATERS R. M. , GRAMINSKI G. F. 
Published: May 2016

AbstractThe trisacetoxy benziodoxolone (I) is a useful reagent for the selective oxidation of the alkenols (II), producing the corresponding unsaturated aldehydes (III).
ChemInform Abstract: Synthesis of α‐Phenylthio Enones and Esters of α‐Phenylthio Alkenoic Acids.
Authors: DURMAN J. , GRAYSON J. I. , HUNT P. G. , WARREN S. 
Published: May 2016

AbstractThe bromo esters (I) are converted to the phenylthio compounds (II) and the sulfoxides (IV), which undergo Pummerer elimination to give the phenylthio alkenoic esters (V); the esters (Va) and (Vb) are obtained as Z/E‐mixtures (Z:E = 1:1 to 4:1).
ChemInform Abstract: Reaction of Diazonium Salts with Transition Metals. Part 11. Palladium‐Catalyzed Aryldesilylation of Alkenylsilanes by Arenediazonium Salts.
Authors: IKENAGA K. , KIKUKAWA K. , MATSUDA T. 
Published: May 2016

AbstractUnder Pd(0) catalysis, both the E‐ (I) and the Z‐ (V) trimethylsilylstyrenes are easily aryldesilylated by the diazonium salts (II) or (VI) to give the main products (III) and (IV).
ChemInform Abstract: On the Synthesis and Enantiomeric Purity of (S)‐4‐Acetyl‐2,2‐dimethyl‐ 1,3‐dioxolane.
Authors: TANNER D. , SOMFAI P. 
Published: May 2016

AbstractIn order to prepare optically pure (S)‐(II), two synthetic routes are investigated: treatment of the methyl dioxolane carboxylate (S)‐(I) with a slight excess of methyl lithium yields the desired enantiomer (S)‐(II).
ChemInform Abstract: Synthesis of 3,4,5‐Triphenyloxazolin‐2‐ones.
Authors: HOGALE M. B. , SHELAR A. R. , TARAPURE V. T. , JAGDALE M. H. 
Published: May 2016

AbstractThe triphenyloxazolin‐2‐ones (III) ‐ (V) are prepared from benzoin (I) and phenyl isocyanate (II) depending on the molar ratio.
ChemInform Abstract: Synthesis of 2‐Phenylthiazolidine‐4‐carboxylic Acid Derivatives and Investigation of Their Radioprotective Properties.
Authors: PAVLOVA L. A. , KOMAROVA T. V. , DAVIDOVICH YU. A. , ROGOZHIN S. V. , PUCHKOVA S. M. , TUZHILKOVA T. N. 
Published: May 2016

AbstractThe thiazolecarboxylic acid (I) reacts with di‐tert‐butyl pyrocarbonate (II) to give the tert‐butoxycarbonyl compound (III) which is transformed into the activated ester (V).
ChemInform Abstract: Boron Analogues of Choline. Part 2. Efficient Syntheses of Boron Analogues of Choline, Acetylcholine, and Substituted Acetylcholines.
Authors: SPIELVOGEL B. F. , AHMED F. U. , MCPHAIL A. T. 
Published: May 2016

AbstractAn efficient synthesis of isoelectronic and isostructural boron analogues (IIIa)‐(IIId) of choline and acylcholines from the reaction of the corresponding ester hydrochlorides (II) with Et4NBH4 is described.
ChemInform Abstract: Studies on Borate Esters. Part 4. Structural Analysis of Borate Esters of Polyhydroxycarboxylates in Water Using 13C and 1H NMR Spectroscopy.
Authors: VAN DUIN M. , PETERS J. A. , KIEBOOM A. P. G. , VAN BEKKUM H. 
Published: May 2016

AbstractBorate monoesters, diborate esters, and borate diesters are the possible forms of borate esters of polyhydroxycarboxylates such as (I)‐(VII).
ChemInform Abstract: Silylstannanes in Organic Synthesis. Scope and Limitation of Palladium‐ Catalyzed Reaction with Acetylenes.
Authors: CHENARD B. L. , VAN ZYL C. M. 
Published: May 2016

AbstractThe terminal alkynes (I) react with the silylstannanes (IIb) ‐ (IIf) in the presence of catalytic amounts of the palladium(0) complex (III) to give the addition products (IV) regio‐ and stereoselectively.
ChemInform Abstract: Additions of a Stable Stannylene R2Sn to Vinyl Carbonyl Compounds and 1,2‐Diketones.
Authors: HILLNER K. , NEUMANN W. P. 
Published: May 2016

AbstractThe stable stannylene (I) performs a 1,4‐cycloaddition reaction with the vinyl ketones and aldehydes (II), yielding the corresponding 1‐oxa2‐‐stannacyclopent‐4‐enes (III).
ChemInform Abstract: Preparation and Photochemical Properties of Water‐Soluble Polymers with Pendant Tris(2,2′‐bipyridyl)ruthenium(II) Groups. N‐Ethylated Copolymers of Vinylpyridine and cis‐Bis(2,2′‐bipyridyl)(4‐methyl‐4′‐vinyl‐2,2′‐bipyridyl)ruthenium(II).
Authors: ENNIS P. M. , KELLY J. M. , O'CONNELL C. M. 
Published: May 2016

AbstractCopolymers are prepared by AIBN‐initiated copolymerization of vinylpyridine and the title Ru complex.
ChemInform Abstract: Three‐Fragment Oxidative Addition of Dichloromethane to a Mononuclear Rhodium(I) Complex with Concomitant Formation of a Metal‐Phosphoranide Bond.
Authors: BURNS E. G. , CHU S. S. C. , DE MEESTER P. , LATTMAN M. 
Published: May 2016

AbstractCyclenphosphorane (I) reacts with RhCl(PPh3)3 to yield the four‐coordinate Rh(I) complex (II) in which two PPh3 ligands are displaced by the P atom and one N atom of the open form of cyclenphosphorane.
ChemInform Abstract: Addition of the Os‐CH2 Bond in Os3(CO)11(μ‐CH2) to Pt(PPh3)2 to Give the Spiked Triangular Cluster Os3Pt(μ‐CH2)(CO)11(PPh3)2. An NMR Investigation of the Fluxional Properties of Os3(CO)11(μ‐CH2).
Authors: WILLIAMS G. D. , LIESZKOVSZKY M.‐C. , MIRKIN C. A. , GEOFFROY G. L. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe methylene‐bridged cluster (I) reacts with the Pt(0) complex (II) to give the tetranuclear cluster (III).
ChemInform Abstract: Synthesis and Chemical Characterization of the Chalcogenide Capped Iridium Carbonyl Anions: (Ir3(μ3‐X)2(CO)6)‐ (X: S or Se). Crystal and Molecular Structures of (NMe3(CH2Ph)) (Ir3(μ3‐S)2(CO)6) and (NMe4) (Ir3(μ3‐Se)2(CO)6).
Authors: DELLA PERGOLA R. , GARLASCHELLI L. , MARTINENGO S. , DEMARTIN F. , MANASSERO M. , SANSONI M. 
Published: May 2016

AbstractReaction of Ir4(CO)12 or Ir6(CO)16 in refluxing THF with KXCN, or with K2Sx in MeOH gives the trinuclear title anions which are isolated as their ammonium and phosphonium salts (I).
ChemInform Abstract: Functionalized Isocyanides as Ligands. Part 4. Base‐Promoted Cyclization Reactions of Free and Platinum(II)‐Coordinated o‐(Phosphoniomethyl)phenyl Isocyanide Tetrafluoroborates, o‐(BF‐ 4R3P+‐CH2)C6H4NC. Synthesis and Spectroscopic Characterization of 1‐ and 2‐Platinum(II)‐Substituted Indole Derivatives and X‐Ray Structure of Cyclic trans‐((PPh3)2Pt(CN(H)‐o‐C6H4C(PMe3))Cl)BF4·C2H4Cl2.
Authors: MICHELIN R. A. , FACCHIN G. , BRAGA D. , SABATINO P. 
Published: May 2016

AbstractThe chloromethyl substituent of the isocyanide (I) easily reacts with tert. phosphines in CH2Cl2 or in acetone in the presence of excess LiBr to give quantitatively the phosphonium‐substituted isocyanides (IIa) or (IIb) which are converted into their less hygroscopic tetrafluoroborate salts (IIc).
ChemInform Abstract: A Stereospecific Synthesis of Advanced Precursors of the Dictyol Diterpenes Using the Alicyclic Claisen Rearrangement.
Authors: BEGLEY M. J. , CAMERON A. G. , KNIGHT D. W. 
Published: May 2016

AbstractThe preparation of the perhydroazulenes (VIII) possessing the appropriate functionality for conversion to further members of the dictyol diterpenes, such as dictyol C (IX) is described.
ChemInform Abstract: Synthesis and Antimicrobial Properties of O‐Acylserin Alkyl Esters.
Authors: SMIRNOVA E. A. , DAVIDOVICH YU. A. , CHERNYAVSKAYA A. A. , BELOVA A. S. , ROGOZHIN S. V. 
Published: May 2016

AbstractD,L‐Serin (I) is first esterificated and then acylated at the hydroxy group to produce the title compounds (V).
ChemInform Abstract: Synthesis of a Glycopeptide Containing the Amino Acid Sequence 4 to 7 of the NH2‐Terminus of the Protein Core‐Structure of the Beef‐Skin Proteodermatan Sulfate.
Authors: GARG H. G. , HASENKAMP T. , PAULSEN H. 
Published: May 2016

AbstractCoupling of the protected tetrapeptide (VIII) synthesized as shown in the reaction scheme with the xylose derivative (IX) and subsequent deprotection yield the title compound (Xb).
ChemInform Abstract: Characterization of the Interlayer Water in Niobyl Phosphate Hydrates by IR and NMR Spectroscopies.
Authors: BRUQUE S. , MARTINEZ‐LARA M. , MORENO‐REAL L. , JIMENEZ‐LOPEZ A. , CASAL B. , RUIZ‐HITZKY E. , SANZ J. 
Published: May 2016

AbstractTwo of three types of water molecules identified in lamellar NbOPO4·nH2O coexist in the dihydrate.
ChemInform Abstract: Electrochromism in Iridium Oxide Films Prepared by Thermal Oxidation of Iridium‐Carbon Composite Films.
Authors: SATO Y. , ONO K. , KOBAYASHI T. , WAKABAYASHI H. , YAMANAKA H. 
Published: May 2016

AbstractIr‐C films, obtained by evaporation of Ir from a graphite crucible with an electron gun, are completely oxidized when heated at 225 °C for 60 min or at temp. ≥ 250 °C for 20 min.
ChemInform Abstract: Ternary Chalcogenide‐Based Photoelectrochemical Cells. Part 8. Solution Composition Effects in n‐CuInX2 (X: S, Se) Aqueous Polysulfide and Aqueous Polyiodide Cells.
Authors: DAGAN G. , CAHEN D. 
Published: May 2016

AbstractDark I‐V characteristics have been measured for n‐CuInX2 (X: S, Se) crystals and In2O3 thin films in polysulfide and polyiodide as a function of the type of alkali cation and in polyiodide, in the case of In2O3, as a function of added Cu+ and/or H+.
ChemInform Abstract: Zinc Electrowinning under Periodical Reverse Current (PRC). Behavior of the Anode and Energy Consumption.
Authors: BERUBE L. PH. , PIRON D. L. 
Published: May 2016

AbstractLaboratory scale electrolysis of Zn has been performed using both conventional dc and new PRC techniques and demonstrates the beneficial effect of PRC electrowinning with respect to current efficiency, specific energy consumption, and productivity.
ChemInform Abstract: Electrochemical Studies of FeS2 Electrodes in Various Sulfide‐Containing Molten Salts.
Authors: WANG S. S. , SEEFURTH R. N. 
Published: May 2016

AbstractCyclic voltammetry and galvanostatic charge‐discharge experiments are used to investigate the electrochemical reactions occurring at planar Fe and porous FeS2 electrodes in three electrolytes: K‐free LiF‐LiCl‐LiBr, Li‐rich LiCl‐KCl, and K‐rich LiCl‐KCl (in order of decreasing Li+ activity), all saturated with Li2S. Electrochemical reactions with high overpotential, which are responsible for the high resistance of Li/FeS2 cells, are identified in these electrolytes, whereby the overpotential decreases with increasing Li+ activity.
ChemInform Abstract: Problems Associated with the Electrochemical Reduction of Metal Ions in LiNO3‐KNO3 and LiClO4‐KClO4 Melts. Reduction of Nitrato and Perchlorato Complexes.
Authors: MILES M. H. , MCMANIS G. E. , FLETCHER A. N. 
Published: May 2016

AbstractThe irreversible cathode waves produced by the addition of Cd2+, Pb2+, Zn2+, Tl+, and In3+ to nitrate melts are due to the reduction of nitrato complexes to the metal oxide rather than due to the reduction of the metal ion to the metal.
ChemInform Abstract: Alkenylimmonium Salts as Dienophiles in Diels‐Alder Cycloadditions with High Reactivity and Stereoselectivity.
Authors: JUNG M. E. , BUSZEK K. R. 
Published: May 2016

AbstractThe pyridinium salts (I) react with methyl propiolate (II) to give the isomeric adducts (III) and (IV).
ChemInform Abstract: Selective Reduction by 2‐Amino‐4‐methylpyridine Borane and 2‐Aminopyrimidine Borane.
Authors: OKAMOTO Y. , OSAWA T. , KURASAWA Y. , KINOSHITA T. , TAKAGI K. 
Published: May 2016

AbstractThe boranes (II) are employed in hydrogenation reactions.
ChemInform Abstract: Tetrabutylammonium and Polymer‐Supported Dihydrogentrifluoride: New Reagents for the Hydrofluorination of Activated Acetylenic Bonds.
Authors: COUSSEAU J. , ALBERT P. 
Published: May 2016

AbstractTetrabutylammonium dihydrogenfluoride (II) is prepared by a phase‐transfer procedure from the salt (I).
ChemInform Abstract: The Chlorination of 2‐t‐Butyl‐4,6‐dimethylphenol and 2,6‐Di‐t‐butyl‐4‐methylphenol. The Formation of 5,6‐Dichloro‐4‐methylenecyclohex‐2‐enones.
Authors: HARTSHORN M. P. , JUDD M. C. , ROBINSON W. T. 
Published: May 2016

AbstractChlorination of the phenols (I) or (VI) in AcOH leads to the products shown in the scheme.
ChemInform Abstract: Reactivity of 3‐(ω‐Isocyanatoalkyl)‐4‐(ω‐isocyanatoalkylidene)‐2‐oxetanones (Diisocyanatodiketenes).
Authors: MORMANN W. , HOFFMANN S. 
Published: May 2016

AbstractThe title compounds (I) react with the amines (II) or ammonia (III) under cleavage of the diketene function to give the amides (IV).
ChemInform Abstract: The Reaction of Aliphatic Diazo Compounds with Highly Electrophilic Ethylene Derivatives.
Authors: EICHENAUER U. , HUISGEN R. , MITRA A. , MORAN J. R. 
Published: May 2016

AbstractCycloaddition reaction of the diazo compounds (II) and (V) with tetracyanoethylene (Ia) and tetraethyl ethylenetetracarboxylate (Ib) leads to the formation of the 2‐pyrazolines (III) and (IVa).
ChemInform Abstract: Reactions of Diphenylcyclopropenone with Hydrazine Derivatives: Formation of Pyrazolone Derivatives via 3‐Aminocinnamohydrazides.
Authors: TODA T. , YOSHIDA M. , KATAYAMA T. , MINABE M. 
Published: May 2016

AbstractReaction of the hydrazines (I) with diphenylcyclopropenone (II) under acidic or basic conditions produces mixtures of the compounds (III) and (IV) or (III) ‐ (V).
ChemInform Abstract: Tetrazolylnitromethanes. Part 1. Synthesis of 5‐Tetrazolylnitromethanes and Their Methylation with Diazomethane.
Authors: TERPIGOREV A. N. , TSELINSKII I. V. , MAKAREVICH A. V. , FROLOVA G. M. , MEL'NIKOV A. A. 
Published: May 2016

AbstractThe preparations of the (5‐tetrazolyl)tri‐, ‐di‐ and ‐mononitromethanes and their tetrazolyl‐1‐ and tetrazolyl‐2‐methyl derivatives ‐ i.e. the compounds (II), (III), (V), (VII), (IX) and (XIX) ‐ are described.
ChemInform Abstract: Synthesis of New Spirobenzazolines Including a Furo(3,4‐b)pyran Ring System.
Authors: COUDERT P. , COUQUELET J. M. , TRONCHE P. 
Published: May 2016

AbstractThe dihydrofuropyranone (I) reacts with the orthodianilino or orthoaminohydroxy or orthoaminomercaptobenzene derivatives (II), yielding the spiroheterocycles (III) which show analgesic activity.
ChemInform Abstract: A Photochemistry of 1‐(1‐Phenylvinyl)‐3,4‐dihydroisoquinoline.
Authors: HIRAI Y. , EGAWA H. , WAKUI Y. , YAMAZAKI T. 
Published: May 2016

AbstractThe dihydroisoquinoline (IV), synthesized from the acetic acid (I), is photolyzed to form the spirobenzylisoquinoline (V).
ChemInform Abstract: Furopyridines. Part 6. Preparation and Reactions of 2‐ and 3‐Substituted Furo(2,3‐b)pyridines.
Authors: MORITA H. , SHIOTANI S. 
Published: May 2016

AbstractThe chloronicotinate (I) is cyclized with the glyoxalates (II) to produce the furopyridin‐3(2H)‐ones (III).
ChemInform Abstract: The Reaction of Pyridazinones with Nucleophiles. An Unusual Reaction with Cyanide.
Authors: BADGER E. W. , MOOS W. H. 
Published: May 2016

AbstractThe imidazolylphenylpyridazinone (Ia) is converted to the 4‐amino derivative (Ib) which is also prepared from (Id).
ChemInform Abstract: 6‐Aminopyrimidine‐1‐oxides. Acylation and Methylation.
Authors: SEDOVA V. F. , MAMAEV V. P. 
Published: May 2016

AbstractThe 6‐aminopyrimidine‐N‐oxides (II), synthesized by oxidation of the corresponding pyrimidines (I), are treated with acetic anhydride to give the acetylamino compounds (III), while coupling of (II) with the acyl chlorides (IV) leads to the formation of the N‐acyloxypyrimidinium salts (V).
ChemInform Abstract: Synthesis of Some 7‐Substituted‐2,4,8(1H,3H,7H)Pyrimido(5,4‐d)pyrimidinetriones.
Authors: PENDERGAST W. , HALL W. R. 
Published: May 2016

AbstractEthyl 5‐nitroorotate (I) is reduced to give the amine (II) which is converted to the ethoxymethylene derivative (IV).
ChemInform Abstract: Synthesis of 3‐(α‐Chlorophenylhydrazono)heteroarylmethyl‐2‐oxo‐1,2‐dihydroquinoxalines with Antimicrobial Activity.
Authors: KURASAWA Y. , MURAMATSU M. , YAMAZAKI K. , OKOMOTO Y. , TAKADA A. 
Published: May 2016

AbstractThe hydrazones (I) react with the orthoesters (II) to form the oxadiazole derivatives (III) which equilibrate with the corresponding diazenyl tautomers.
ChemInform Abstract: A Convenient Synthesis and Antifungal Activity of 1‐Aryl‐1H‐ and 1‐Aryl‐3‐heteroaryl‐1H‐pyrazolo(3,4‐b)quinoxalines.
Authors: KURASAWA Y. , MURAMATSU M. , YAMAZAKI K. , TAJIMA S. , OKAMOTO Y. , TAKADA A. 
Published: May 2016

AbstractThe oxodihydroquinoxaline (I) reacts with the diazonium salts (II) to form the hydrazones (III).
ChemInform Abstract: Synthesis of Pyrido(1′,2′:1,2)imidazo(4,5‐b)pyrazines from 2,3‐Dichloro‐5,6‐dicyanopyrazine with 2‐Aminopyridines.
Authors: SUZUKI T. , NAGAE Y. , MITSUHASHI K. 
Published: May 2016

AbstractDiaminomaleonitrile (I) is cyclized by reaction with oxalyl chloride (II) to form (III) which is then chlorinated, producing the dichloropyrazine (IV).
ChemInform Abstract: Synthesis and Reaction of 5‐Amino‐3‐trifluoromethylisoxazole and ‐pyrazole‐4‐carboxylic Acids.
Authors: TANAKA K. , SUZUKI T. , MAENO S. , MITSUHASHI K. 
Published: May 2016

AbstractThe nitrile oxide (II), derived from the hydroximoyl bromide (I), and the nitrile imine (VII), generated from the hydrazone (VI), are the starting products for the synthesis of various 5‐ring heterocycles as demonstrated in the reaction scheme.
ChemInform Abstract: Novel Eight‐Membered Heterocycles. Synthesis of Dithiazolo‐(4,5‐d:5′,4′‐g)(1,3)diazocine Derivatives.
Authors: RAHMAN L. K. A. 
Published: May 2016

AbstractThe cyanoimidothiocarbonates (I) react with 1,3‐dichloroacetone (II) to produce the bis(thiazolyl)ketones (IV) which are reduced to form (V).
ChemInform Abstract: Synthesis of Pyrimidino(4,5‐b)(1,5)benzodiazepin‐2‐ones and Pyrimidino‐(1,6‐a)benzimidazol‐1‐ones from 4‐Ethoxycarbonylamino‐1H‐1,5‐benzodiazepine‐3‐carbonitrile via 4‐(2‐Aminoanilino)pyrimidin‐2(1H)‐one‐5‐carbonitriles.
Authors: TAKAGI K. , AOTSUKA T. , MORITA H. , OKAMOTO Y. 
Published: May 2016

AbstractThe aminobenzodiazepine carbonitrile (I) is acylated to give (II) which reacts with the anilines (III) with ring contraction, producing the benzimidazoles (IV).
ChemInform Abstract: A Convenient Synthesis of Phosphorus and Sulfonyl Substituted N‐Imidazoles (Triazoles) Using the Corresponding Acid Chlorides and N‐Trimethylsilylimidazoles(triazoles).
Authors: DABKOWSKI W. , MICHALSKI J. , SKRZYPCZYNSKI Z. 
Published: May 2016

AbstractThe N‐substituted imidazoles and triazoles (III), (V), (VII), and (IX) are prepared by treating (I) with the corresponding acyl chlorides (II), (IV), (VI), or (VIII).
ChemInform Abstract: Arene Adducts with Weak Interactions: Hexaethylbenzene‐bis(tribromoarsine).
Authors: SCHMIDBAUR H. , BUBLAK W. , HUBER B. , MUELLER G. + 
Published: May 2016

AbstractAsBr3 and hexaethylbenzene react in toluene at 20 °C to give the title compound (I), crystallizing in the space group R3 with Z=3.
ChemInform Abstract: Synthesis of the Four‐Membered Metallacycle (Cp2Ti(AsPh)3) via in situ Reduction of (Cp2TiCl2).
Authors: MERCANDO P. , DIMAIO A.‐J. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe in situ reduction of titanocene dichloride (I) with Mg in the presence of cyclo‐(AsPh)6 in refluxing THF leads to the title compound (II).
ChemInform Abstract: Trimethylphosphine Complexes of Niobium(IV) and Tantalum(IV). Crystal, Molecular, and Electronic Structures of (M2Cl4(μ‐Cl)4(PMe3)4) (M: Nb or Ta).
Authors: BOYD P. D. W. , NIELSON A. J. , RICKARD C. E. F. 
Published: May 2016

AbstractReaction of NbCl4(THF)2 (II) or NbCl4(NCMe)3 (IV) with 3 equiv. of PMe3 gives the seven‐coordinate complex (I).
ChemInform Abstract: Polynuclear Complexes of Cobalt(II) with 2‐Dipicolylamine and 2‐Aminomethylpyridine.
Authors: HUCHITAL D. H. , DEBESIS E. 
Published: May 2016

AbstractThe hypothesis that the blue color of basic anaerobic solutions of Co(II) with the title compounds is due solely to deprotonation of the ligand amine is modified.
ChemInform Abstract: Transition‐Metal Macrocyclic Complexes. Single‐Crystal X‐Ray Structure and Electrochemistry of the Bis‐macrocyclic Complex (Cu(L)2) (ClO4)2·2 H2O (L: 1,4,7‐Triazacyclononane).
Authors: BEVERIDGE A. D. , LAVERY A. J. , WALKINSHAW M. D. , SCHROEDER M. + 
Published: May 2016

AbstractThe title compound is obtained by reaction of Cu(NO3)2 with 1,4,7‐triazacyclononane in ethanol followed by addition of NaClO4 in 60% yield.
ChemInform Abstract: Investigation of Factors Stabilizing Formally Zerovalent Copper Macrocyclic Complexes.
Authors: BOND A. M. , KHALIFA M. A. 
Published: May 2016

AbstractAt platinum, gold, glassy‐carbon and mercury electrodes, two chemically reversible one‐electron reduction processes are observed in CH2Cl2 or Me2CO for complex (I).
ChemInform Abstract: Photoisomerization of Bis(bipyridine)rhodium(III) Complexes; Synthesis of trans‐(Rh(bpy)2YCl)n+ (Y: Cl, H2O).
Authors: KRUEGER G. + , WIELAND S. , VAN ELDIK R. 
Published: May 2016

AbstractThe transformation of the cis‐complexes (I) to the trans‐complexes (II) on a preparative scale is achieved by irradiation.
ChemInform Abstract: Reactivity of Fe3(μ3‐Te)2(CO)9 Towards Pt(PPh3)4.
Authors: MATHUR P. , MAVUNKAL I. J. 
Published: May 2016

AbstractEquimolar reaction of the title cluster (I) and Pt(PPh3)4 leads to the formation of the Pt derivative (II) with loss of a Fe(CO)3 fragment.
ChemInform Abstract: Synthesis of 2‐Deoxy Sugars.
Authors: GIESE B. , GROENINGER K. S. + , WITZEL T. , KORTH H.‐G. , SUSTMANN R. 
Published: May 2016

AbstractA new method for the preparation of 2‐deoxy sugars uses the rapid and irreversible rearrangement of radicals such as (II) (generated from the halide (I)) to the species (III).
ChemInform Abstract: Synthesis of 3‐Amino Sugars of the Daunosamine Type Through Hetero‐ Diels‐Alder Reaction of Enaminones.
Authors: TIETZE L. F. , VOSS E. 
Published: May 2016

AbstractThe vinyl ethers (I) are coupled with N‐acylenaminones (II) to give the isomeric adducts (III) and (IV).
ChemInform Abstract: Synthesis of the Mammea Coumarins. Part 2. Experiments in the Mammea E Series and Synthesis of Mammea E/AC.
Authors: CROMBIE L. , JONES R. C. F. , PALMER C. J. 
Published: May 2016

AbstractThe attempts to synthesize 4‐(1‐acetoxyproyl)dihydroxycoumarins using the same method which has been employed for syntheses in the mammea A, B, C coumarin series meet with limited success.