bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Behavior of 4‐Hydroxy‐4‐methyl‐2‐pentynenitrile in Water in the Presence of Lithium Hydroxide.
Authors: ANDRIYANKOVA L. V. , ABRAMOVA N. D. , MAL'KINA A. G. , SKVORTSOV YU. M. 
Published: May 2016

AbstractTreatment of the hydroxypentynenitrile (I) with aqueous lithium hydroxide gives the 1,3‐dioxolane (II) and the furanone (III) instead of the expected 1,4‐dioxane.
ChemInform Abstract: Photochemical versus Aluminum Chloride Catalyzed Fries Rearrangement of Aryl Hydrogen Succinates. Synthesis of 2(3H)‐Furanones.
Authors: FILLOL L. , MARTINEZ‐UTRILLA R. , MIRANDA M. A. , MORERA I. M. 
Published: May 2016

AbstractThe photochemical and AlCl3‐catalyzed Fries Rearrangement of a series of aryl hydrogen succinates (I), (V) to the corresponding 4‐oxo acids (II), (VI) are compared.
ChemInform Abstract: Generation and Synthetic Use of Alkyl Radicals with (CpFe(CO)2)2 as Mediator.
Authors: THOMA G. , GIESE B. 
Published: May 2016

AbstractPhotolysis of the dinuclear iron complex (I) forms the radicalic intermediate (II) which reacts with the halides (III) under halogen abstraction, producing the carbon radicals (IV) and the complexes (V).
ChemInform Abstract: Reactivities of Methoxycarbonylphenylcarbenes Generated by Flash Vacuum Pyrolysis.
Authors: TOMIOKA H. , OHTAWA Y. , MURATA S. 
Published: May 2016

AbstractPyrolysis of either isomeric diazomethane (I) affords invariably 3‐methylphthalide (III) and the benzocyclobutenone (IV) with yields and (III)/(IV) ratios depending on temp. and educt.
ChemInform Abstract: Single Electron Transfer Initiated Thermal Reactions of Arylmethyl Halides. Part 14. The Reaction of Triphenylmethyl Halides with Tributylphosphine and Tributylamine in Apolar Solvents.
Authors: HUSZTHY P. , IZSO G. , LEMPERT K. , KAJTAR‐PEREDY M. , GYOER M. + , ROCKENBAUER A. , TAMAS J. 
Published: May 2016

AbstractPh3CBr (I) (and similarly, but much slower, Ph3CCl (V)) reacts with Bu3P (II) (and analogously with Bu3N) in aromatic hydrocarbons by single electron transfer.
ChemInform Abstract: Pulse Radiolysis of Monohalogenated Biphenyls. Correlation of Absorption Spectra of the Radical Cations with Photoelectron Spectroscopic Data.
Authors: ANKLAM E. , ASMUS K.‐D. , ROBERTSON L. W. 
Published: May 2016

AbstractThe optical and kinetic properties are compared with corresponding data for (Ph‐Ph)·+ itself.
ChemInform Abstract: 4,3‐Dehydrocyanation of 1‐(N′,N′‐Dimethylhydrazino)‐4‐methyl‐2,2,3,3‐tetracyanocyclopentane.
Authors: ZOLOTOI A. B. , LUKIN P. M. , SHEVERDOV V. P. , PROKHOROV A. I. , KONOVALIKHIN S. V. , NASAKIN O. E. , ATOVMYAN L. O. 
Published: May 2016

AbstractHeating of the title compound (I) in the presence of triethylamine produces the cyclopentene derivative (II).
ChemInform Abstract: Alkylation of Benzene Using an Aqueous Solution of Ethanol.
Authors: LEVESQUE P. , DAO L. H. 
Published: May 2016

AbstractWhen gaseous mixtures of benzene (I) and ethanol (II) are passed over a fixed bed catalyst system at 575‐775 K, the main products identified are ethylbenzene (III) and ethylene (IV) contaminated with diethylbenzene and light olefins.
ChemInform Abstract: Thermal Transformations of Tetrafluoroethylene in the Presence of 1,3‐Cyclopentadiene and Hydrogen Chloride.
Authors: KUSHINA I. D. , FEDURTSA M. U. , GIDA V. M. , BARABANOV V. G. , NEFEDOV O. M. 
Published: May 2016

AbstractThermal transformation of tetrafluoroethylene (I) in the presence of cyclopentadiene (II) or HCl as carbene acceptors produces mainly benzotrifluoride (III) and 1,1,1,2‐tetrafluorochloroethane (IV) respectively.
ChemInform Abstract: Reaction of Nitropentafluoroacetone with Phenols.
Authors: DYACHENKO V. I. , KOLOMIETS A. F. , FOKIN A. V. 
Published: May 2016

AbstractReaction of the (poly)phenols (I) with nitropentafluoroacetone (II) gives the o‐alkylated products (III) via the corresponding phenol ethers.
ChemInform Abstract: Trimethylsilyl Cyanide ‐ A Reagent for Umpolung. Part 17. Diastereoselectivity in Nucleophilic Acylations of α‐Chiral Carbonyl Compounds with α,β‐Unsaturated Aldehydes After Umpolung.
Authors: HUENIG S. + , MARSCHNER C. , PETERS K. , VON SCHNERING H. G. 
Published: May 2016

AbstractDepending on the solvent the silyl ethers (III) react with aldehydes and ketones to give 1:1 adducts, e.g. (V), (VI), (VIII) and (IX) or 2:1 adducts such as (X).
ChemInform Abstract: Silicon in Organosulfur Chemistry. Part 1. Synthesis of Trisulfides.
Authors: CAPOZZI G. , CAPPERUCCI A. , DEGL'INNOCENTI A. , DEL DUCE R. , MENICHETTI S. 
Published: May 2016

AbstractThe thiosulfinates (I) react with bis(trimethylsilyl) sulfide (II) to give the symmetrical trisulfides (III).
ChemInform Abstract: Silicon in Organosulfur Chemistry. Part 2. Synthesis of Unsymmetrical Disulfides.
Authors: CAPOZZI G. , CAPPERUCCI A. , DEGL'INNOCENTI A. , DEL DUCE R. , MENICHETTI S. 
Published: May 2016

AbstractThe thiosulfinates (I) and thiosulfonates (V) react with the trimethylsilyl sulfides (II) to give the unsymmetrical disulfides (III) and (VI) respectively.
ChemInform Abstract: Synthesis of Some New Thiosemicarbazides and Thiosemicarbazones as Possible Antitubercular and Antibacterial Agents.
Authors: VANUGOPAL D. , PANDYA D. , NAIR K. B. 
Published: May 2016

AbstractThe bisamines (I) are consecutively treated with carbon disulfide (II) and hydrazine hydrate (III) to yield the bisthiosemicarbazides (IV).
ChemInform Abstract: Syntheses of Some New β‐Lactams. Azetidin‐2‐ones.
Authors: AHLUWALIA V. K. , MALLIKA N. , SINGH R. P. , MEHTA V. D. 
Published: May 2016

AbstractThe β‐lactams (III) are synthesized via activation of the acid (I) with the Vilsmeier‐type reagent, generated from dimethylformamide and thionyl chloride in benzene, and subsequent reaction with the imines (II).
ChemInform Abstract: The Synthesis and Reactions of 4‐Carbomethoxy β‐Sultams.
Authors: SZYMONIFKA M. J. , HECK J. V. 
Published: May 2016

AbstractMethoxycarbonylmethanesulfonyl chloride (I) reacts with the imines (II) in the presence of pyridine to give the β‐sultams (III).
ChemInform Abstract: A Chelate‐Controlled Route to Disubstituted and Tetrasubstituted γ‐Lactones. Stereoselectivity in Lewis Acid Promoted Additions to Chiral Methyl β‐Formylcarboxylates.
Authors: KUNZ T. , JANOWITZ A. , REISSIG H.‐U. 
Published: May 2016

AbstractThe chelate‐controlled reaction of various chiral β‐formylcarboxylates such as (I) or (V) or other model aldehydes such as (VIII) with allyltrimethylsilane (IV) proceeds with moderate to good diastereoselectivities to give the corresponding trans and cis lactones resp. anti and syn alcohols.
ChemInform Abstract: Synthesis and Growth Retardant Activities of Trialkylammonium Iodides from Piperonal and β‐Naphthol.
Authors: SHARMA M. L. , PAUL Y. , SHARMA R. C. , KALSI P. S. 
Published: May 2016

AbstractThe acids (I) are converted into the ammonium salts (V) via reduction of the amides (III) and subsequent quaternization.
ChemInform Abstract: Dithiocarboxylation of α‐Nitrogen‐Carbanions.
Authors: KINDT P. , DOELLING W. + , AUGUSTIN M. 
Published: May 2016

AbstractDithiocarbamic acid esters such as (I) with an acidic methylene group adjacent to the nitrogen react with CS2 (IV) in the system DMF/2 equiv. NaO‐tBu via the carbanions (II) by subsequent alkylation to give the thiazolinethiones (VI).
ChemInform Abstract: Studies on Synthesis of 2‐(3‐(4‐Acetylaminophenyl)‐2‐aryl‐4‐thiazolidinon‐5‐ylmethyl)‐4,5‐dihydroimidazoles.
Authors: BHATT K. N. , DAVE A. M. , UNDAVIA N. K. , TRIVEDI P. B. 
Published: May 2016

AbstractThe Schiff bases (III), obtained from the aniline (I) and the aldehydes (II), react with thiomalic acid (IV) to give the thiazolidinonylacetic acids (V).
ChemInform Abstract: Reactions of Dithiane Derived Alcohols: Promotion of the Thorpe‐Ingold Effect by Trimethylsilyl and tert.‐Butyl Substituents.
Authors: DAVEY A. E. , PARSONS A. F. , TAYLOR R. J. K. 
Published: May 2016

AbstractA range of 2‐(2‐hydroxyethyl)‐dithianes (I), (III), (VI), (VII), the preparation of which from appropriate dithiane precursors is described, is treated with halogenating agents.
ChemInform Abstract: Studies in Spiroheterocycles. Part 18. Synthesis and Antifertility Activity of New Fluorine‐Containing 4′,5′‐Cycloalkyl‐2′‐phenylspiro(3H‐indole‐3,3′‐(3H)pyrazol)‐2(1H)‐ones.
Authors: JOSHI K. C. , JAIN R. , GARG S. , ARORA S. 
Published: May 2016

AbstractThe isatins (I) are coupled with the cycloalkanones (II) to give the oxocycloalkylideneindolones (III) which react with pentafluorophenylhydrazine (IV), forming the spiropyrazoles (V).
ChemInform Abstract: Design, Synthesis, and Antitumor Activity of Steganacin Aza‐Analogues.
Authors: TOMIOKA K. , KUBOTA Y. , KAWASAKI H. , KOGA K. 
Published: May 2016

AbstractThe amino acid (I) is converted to the amino alcohol (II) and then cyclized with diethyl carbonate (III), yielding the oxazolidinones (IV).
ChemInform Abstract: Vinylboronates β‐Substituted by an Electron Withdrawing Group: Synthesis and Diels‐Alder Reactivity of a New Type of Electron Deficient Olefins.
Authors: MARTINEZ‐FRESNEDA P. , VAULTIER M. 
Published: May 2016

AbstractThe vinylboronates (III), prepared from the alkynes (I) and the borane (II), react with excess acetaldehyde (IV) to form the boronates (V).
ChemInform Abstract: Silyl‐Substituted Diphosphenes. Synthesis, Structure, and Modes of Decomposition.
Authors: COWLEY A. H. , KNUEPPEL P. C. + , NUNN C. M. 
Published: May 2016

AbstractThe first stable silyl‐substituted diphosphenes (VIa) and (VIb) (space group P1, Z=2) are synthesized according to the scheme.
ChemInform Abstract: Preparation and Structure of Aluminum Derivatives of the Extremely Bulky Tris(trimethylsilyl)silyl Group. The Molecular Structure of the (Me3Si)3SiAl(C6H5)2·THF Adduct.
Authors: SIERRA M. L. , DE MEL V. S. J. , OLIVER J. P. 
Published: May 2016

AbstractThe reaction of the Al chlorides (II) with tris(trimethylsilyl)silyl‐Li (I) affords the corresponding silyl‐substituted derivatives (III).
ChemInform Abstract: Oligophosphine Ligands. Part 30. Mono‐ and Bis(dinitrogen)molybdenum(0) Complexes Containing the Tridentate Chelate Phosphine MeP(CH2CH2CH2PMe2)2: Syntheses, Structures, and Reactions with Carbon Dioxide.
Authors: DAHLENBURG L. , PIETSCH B. 
Published: May 2016

AbstractThe reduction of the mer‐complex (I) with highly dispersed sodium in the presence of one equivalent of PMe3 in THF under N2 yields the mixture of the isomeric bis(dinitrogen) complexes (IV) and (V).
ChemInform Abstract: Synthesis and Characterization of Bis(xanthate) Complexes of MoII and WII. Crystal Structure of (W(S2COiPr‐S)(S2COiPr‐SS′)(CO)2(PMe3)2).
Authors: CARMONA E. , CONTRERAS L. , SANCHEZ L. J. , GUTIERREZ‐PUEBLA E. , MONGE A. 
Published: May 2016

AbstractThe Mo(II) complex (I) reacts with two equiv. xanthate (II) to give the bis(xanthate) complexes (III) in which the xanthate groups seem to act as η3‐(S,S',C)pseudo‐allylic ligands and the phosphine ligands are in cis position.
ChemInform Abstract: Technetium Bis(μ‐oxo) Dimers of 1,4,7‐Triazacyclononane‐N,N′,N′′‐triacetate (TCTA). Synthesis and Characterization of ((TCTA)Tc(μ‐O)2Tc(TCTA))n‐ (n = 2, 3) and the Crystal Structure of Ba2((TCTA)Tc(μ‐O)2Tc(TCTA))(ClO4)·9 H2O.
Authors: LINDER K. E. , DEWAN J. C. , DAVISON A. 
Published: May 2016

AbstractThe mixed‐valence Tc(III)/Tc(IV) dimer (Ia) is prepared by treatment of an oxo‐ethylene glycolato‐technetium(V) complex of the heterocyclic ligand with NaBH4 and isolated as its Na or Ba salt.
ChemInform Abstract: Multiple Bonds Between Main‐Group Elements and Transition Metals. Part 71. Open‐Chain and Cyclic Organorhenium Complexes of π‐Aromatic Ligands: Oxygen‐, Sulfur‐, and Selenium‐Containing Derivatives. Strong Static trans Influence in the Crystal and Molecular Structure of Di‐μ‐sulfido‐bis(oxo(η5‐pentamethylcyclopentadienyl)rhenium(V)).
Authors: HERRMANN W. A. , JUNG K. A. , HERDTWECK E. 
Published: May 2016

AbstractThe key compound (II) is synthesized as shown in the scheme.
ChemInform Abstract: Synthesis and Properties of the Bis(μ‐thiosulfato‐S)‐bis(dinitrosylferrate)(2‐) Anion. Crystal and Molecular Structure of Bis(bis(triphenylphosphoranylidene)ammonium) Bis(μ‐thiosulfato‐S)‐bis(dinitrosylferrate).
Authors: GLIDEWELL C. , LAMBERT R. J. , HURSTHOUSE M. B. , MOTEVALLI M. 
Published: May 2016

AbstractThe title anion is obtained as its sodium salt (IVa) by reaction of a 1:2 FeSO4/Na2S2O3 mixture with NO (III) or also with NaNO2.
ChemInform Abstract: The Reaction of (Benzene)(cyclopentadienyl)iron Complexes with Organic Halides and the Ring Expansion of the Chloromethyl Derivatives of (Benzene)(cyclopentadiene)iron and (Cyclohexadienyl)(cyclopentadienyl)iron Complexes.
Authors: HERBERICH G. E. , KLEIN W. 
Published: May 2016

AbstractThe 19‐e complexes (I) react with organic halides to form the salts (III) and the neutral products (IV) and (V).
ChemInform Abstract: Electrochemical Synthesis of “Costa‐Type” Cobalt Complexes.
Authors: SEEBER R. , PARKER W. O. JUN. , MARZILLI P. A. , MARZILLI L. G. 
Published: May 2016

AbstractThe feasibility of electrochemical methods in the synthesis of organocobalt Costa‐type B12 model complexes is examined.
ChemInform Abstract: Transition‐Metal‐Substituted Diphosphenes. Part 17. Dipolar (3 + 2) Cycloadditions of Carbonyl‐Activated Alkynes to (η5‐C5Me5)(CO)2Ru‐P=P‐Aryl (Aryl = 2,4,6‐tBu3C6H2). First Examples of σ/π‐Rearrangements of Diphosphene Ligands.
Authors: WEBER L. , FREBEL M. , BOESE R. 
Published: May 2016

AbstractThe title reaction yields in the case of the methyl 2‐butynoate (II) the five‐membered metallaheterocycle (III) with an (E)‐configurated exocyclic P=P bond.
ChemInform Abstract: Synthesis and Spectroscopic Characterization of Trinuclear (Ru3O(O2CCH3)6(pyrazine)3)0, + Clusters.
Authors: TOMA H. E. , CIPRIANO C. 
Published: May 2016

AbstractHeating at reflux a methanol solution of the corresponding methanol complex with pyrazine and adding aqueous hydrazine after cooling yield the complex (Ia).
ChemInform Abstract: Five‐ and Six‐Coordinate Vinyl‐Ruthenium and ‐Osmium Complexes by Alkyne Insertion from Hydrido‐Metal Precursors.
Authors: WERNER H. , MEYER U. , PETERS K. , VON SCHNERING H. G. 
Published: May 2016

AbstractCarbonyl‐hydrido complexes of the type (I) react with alkynes e.g. (II) by insertion to give five‐coordinate vinyl‐metal compounds of the type (III).
ChemInform Abstract: Disperse and Cationic Dyes from Aminophenyl‐X‐azolopyridines.
Authors: SAVARINO P. , VISCARDI G. , CARPIGNANO R. , BARNI E. , FERRERO G. 
Published: May 2016

AbstractDiazotization of the amines (I) and subsequent coupling with N,N‐diethylaniline (II) yield the azo dyes (IV) which are treated with methyl iodide (V) to form the salts (VI).
ChemInform Abstract: Synthesis of Novel Analogs of Phthalein Dyes with a Chiral Carbon Atom.
Authors: ALI S. , BEG I. M. , GUPTA P. C. 
Published: May 2016

AbstractAcid‐catalyzed reaction of the 2‐aroyl‐3‐nitrobenzoic acids (I) with polyhydroxyarenes such as (II) yields the analogs (III) of phthalein dyes.
ChemInform Abstract: Preparation of Steroid Glycosides Using Cobalt(II) Carbonate.
Authors: RAJANIKANTH B. , SESHADRI R. 
Published: May 2016

AbstractThe glycosidation of cholesterol, β‐sitosterol and stigmasterol using a glycosyl halide and cobalt carbonate catalyst furnishes the corresponding glycoside tetraacetates in 60‐68% yields.
ChemInform Abstract: Oxidative Hydrolysis of Conformationally Restrained Pent‐4‐enyl Glycosides: Formation of N‐Acetyl‐α‐D‐glucopyranosylamines.
Authors: RATCLIFFE A. J. , FRASER‐REID B. 
Published: May 2016

AbstractBoth the α‐ and β‐anomers of the conformationally restrained pentenyl D‐glucopyranosides (I), on treatment with NBS in aqueous MeCN (II), give the N‐acetyl‐α‐D‐glucopyranosylamines (III) as a consequence of MeCN addition to an oxocarbenium ion intermediate and subsequent H2O addition.
ChemInform Abstract: (4 + 2)Cycloaddition Reaction of Bis(trichloroethyl) Azodicarboxylate and Glycals: Preparation of a C1‐C1 2‐Amino Disaccharide.
Authors: LEBLANC Y. , FITZSIMMONS B. J. 
Published: May 2016

AbstractDue to the electron withdrawing trichloroethyl groups, the azodicarboxylate has enhanced reactivity in the photo‐induced cycloaddition reaction with the glycals (I), (VIII), or (XII), yielding the pyrano‐1,3,4‐oxadiazines (III), (IX), or (XIII).
ChemInform Abstract: A Convenient Synthesis of 1‐(β‐D‐Ribofuranosyl)imidazo(4,5‐d)pyridazin‐4(5H)‐one (2‐Aza‐3‐deazainosine) and Its 2′‐Deoxy Counterpart by Ring Closure of Imidazole Nucleosides.
Authors: RAMESH K. , PANZICA R. P. 
Published: May 2016

AbstractThe title compound (IV) and its deoxy analogue (VII) are prepared via glycosylation of the 4,5‐disubstituted imidazole (I) and subsequent cyclization to the imidazo(4,5‐d)pyridazine ring.
ChemInform Abstract: Structure and Synthesis of Gymnopusin, a Novel Phenanthrenediol from the Orchid Bulbophyllum gymnopus.
Authors: HUGHES A. B. , SARGENT M. V. 
Published: May 2016

AbstractThe synthesis of the diols (XIII) and (XV) includes a Pummerer rearrangement of the β‐oxo sulfoxide (XI) as the key step.
ChemInform Abstract: Synthesis and Platelet Aggregation Inhibiting Activity of 1′‐Carboxyl Modified Hydantoin Prostaglandin Analogues.
Authors: BARRACLOUGH P. , CALDWELL A. G. , HARRIS C. J. , JACKSON W. P. , WHITTLE B. J. R. 
Published: May 2016

AbstractThe prostaglandin analogue (Ia) is a potent inhibitor of human platelet aggregation.
ChemInform Abstract: In vitro Photosensitizing Activities of Hydrosoluble Metallonaphthalocyanines.
Authors: MARGARON P. , TEMPETE C. , DENDANE Y.‐M. , GASPARD S. , GIANNOTTI C. , WERNER G.‐H. 
Published: May 2016

AbstractThe complexes (I) in DMSO solution were tested concerning their potential use in photodynamic therapy of human cancers and proved to be inactive.
ChemInform Abstract: Low Pressure Deposition of Doped SiO2 by Pyrolysis of Tetraethylorthosilicate (TEOS). Part 2. Arsenic Doped Films.
Authors: BECKER F. S. , TREICHEL H. , ROEHL S. + 
Published: May 2016

AbstractArsenosilicate glasses (AsSG) with dopant levels up to 15% are prepared using TEOS and triethoxyarsine (TEOA) or triethylarsenate (TEAs).
ChemInform Abstract: Vibrational Spectra and Force Constants for the Molecular Series NH3‐nCln.
Authors: SAWODNY W. , HAERTNER H. + , MINKWITZ R. , BERNSTEIN D. 
Published: May 2016

AbstractTo obtain more reliable results, the IR spectrum of NCl3, hitherto only known in solution, is remeasured in an N2 matrix and reassigned.
ChemInform Abstract: Crystal Structure of a Many‐Fold Connected Complex of Lanthanum in Cs3La(N3)6.
Authors: MAUTNER F. A. , KRISCHNER H. , FRITZER H. P. , KRATKY CH. 
Published: May 2016

AbstractSingle crystals of the title compound, obtained by metathetical reactions (caution: Cs3La(N3)6 can be explosive under grinding or heating]), belong to the triclinic space group P1 with Z=2.
ChemInform Abstract: Crystal Chemistry of BaCa2Ln6O12 (Ln: In, Sc, Y, Dy, Ho, Er, Tm, Yb, Lu) and Luminescence of Europium‐ and Terbium‐Activated BaCa2Y6O12.
Authors: HINTZEN H. T. , VAN HAL H. A. M. , LANGEREIS C. , DENISSEN C. J. M. 
Published: May 2016

AbstractIt is demonstrated that the isomorphous title compounds can be prepared by solid state reactions of BaO, CaO, and Ln2O3 at temp. as low as 1300 °C and 1450 °C. The lattice parameters of the hexagonal structures (space group P63/m, Z=1) vary linearly with the ionic radius of the Ln3+ ion.
ChemInform Abstract: Magnetic Behavior of LnCo4B Compounds with Ln: Ce, Tb, Dy, and Ho
Authors: BURZO E. , PLUGARU N. , CREANGA I. , URSU M. 
Published: May 2016

Abstractis studied in the temp. range 4.2‐700 K. The CeCo4B compounds order ferromagnetically, while the other title compounds show ferrimagnetic ordering.
ChemInform Abstract: A Physico‐Chemical Study of Ga‐ZSM‐5 Zeolite
Authors: HANDRECK G. P. , SMITH T. D. 
Published: May 2016

Abstractis performed in order to study the influence of the Ga3+ content of the ZSM‐5 reaction mixture on the simultaneous formation of silicalite and Ga‐ZSM‐5 and the growth of acid sites in the zeolite.
ChemInform Abstract: Acidity Enhanced Pillared Clay Catalysts. Modification of Exchangeable Sites on Fluor‐tetrasilicic Mica by the Fixed Interlayer Cations.
Authors: SAKURAI H. , URABE K. , IZUMI Y. 
Published: May 2016

AbstractLa3+‐modified pillared fluor‐tetrasilicic mica (TSM) is prepared by ion‐exchange of Na+‐TSM (Na1.00Mg2.63(Si3.94Al0.05Mg0.01)O10.19F1.81) using a La(NO3)3 solution followed by calcination (200‐500 °C, 3 h) and Al‐pillaring.
ChemInform Abstract: Barium Magnesium Titanate, BaMg6Ti6O19, with Magnetoplumbite Structure.
Authors: DROBYSHEVSKAYA N. D. , GINDIN E. I. , KIRILLOVA G. K. , MAGAMADOVA T. A. , POLYAKOV S. M. 
Published: May 2016

AbstractThe hitherto unknown title compound is formed between 1360 and 1380 °C in the system BaO‐MgO‐TiO2.
ChemInform Abstract: Synthesis and Crystal Structure of Nitrosofluorotetrammines of Osmium and Ruthenium.
Authors: SINITSYN M. N. , SVETLOV A. A. , KANISHCHEVA A. S. , MIKHAILOV YU. N. , SADIKOV G. G. , KOKUNOV YU. V. , BUSLAEV YU. A. 
Published: May 2016

AbstractStarting from (MNO(NH3)4OH) (NO2)2 (M: Ru, Os) or from (MNOF5) (NO2)2, whose cations are converted to (MNO(NH3)4F)2+ on treatment with NH4HF2 at 200 °C, the hitherto unknown title compounds (I)‐(IV) are prepared.
ChemInform Abstract: Structure of Ba4PtO6 from Time‐of‐Flight Powder Neutron Diffraction Data.
Authors: WILKINSON A. P. , CHEETHAM A. K. 
Published: May 2016

AbstractA new phase of Ba4PtO6 is obtained by the reaction of BaCO3 and PtO2 in an alumina crucible lined with Pt foil at 1370 K (3 d).
ChemInform Abstract: Structure of Tetrahydrozoline Hydrochloride.
Authors: GHOSE S. , DATTAGUPTA J. K. 
Published: May 2016

AbstractThe structure of the title compound (I) (space group P1 with Z=2) is investigated in order to get informations about the structural differences between phenethylamines and α‐adrenergic imidazoline agonists.
ChemInform Abstract: Structure of 4‐Phenylthiazole‐2(3H)‐thione and Bis(4‐chlorophenacyl) Disulfide, the Product Obtained on Its Gas‐Solid Chlorination.
Authors: NALINI V. , DESIRAJU G. R. 
Published: May 2016

AbstractThe title compound (I) crystallizes in yellow and white modifications from EtOAc and benzene, respectively.
ChemInform Abstract: Structure of an Open‐Ended Cage Compound.
Authors: WATSON W. H. , NAGL A. , MARCHAND A. P. , REDDY G. M. 
Published: May 2016

AbstractIn connection with a study of the synthesis and chemistry of novel, substituted pentacyclo(5.4.0.0.2,6.03,10.05,9)undecanes, the reaction of compound (I) with propionic acid was studied.
ChemInform Abstract: Complex Formation Equilibria of L‐Amino Acid Amides with Copper(II) in Aqueous Solution.
Authors: DALLAVALLE F. , FISICARO E. , CORRADINI R. , MARCHELLI R. 
Published: May 2016

AbstractProtonation and Cu(II) complex formation constants are determined for L‐phenylalaninamide its N‐monomethyl‐ and N,N‐dimethyl derivatives, L‐valinamide and L‐prolinamide.
ChemInform Abstract: Diastereoselectivity in the TiCl4‐Mediated Aldol Reaction of Cyclic Dienylsilyl Ethers.
Authors: BARNER B. A. , LIU Y. , RAHMAN MD. A. 
Published: May 2016

AbstractCyclic dienylsilyl ethers such as (I), derived from (R)‐(+)‐pulegone, undergo TiCl4‐catalyzed crossed aldol reactions with the aldehydes (II) to give the syn and anti hydroxy enones (III) and (IV) with good diastereoselectivity in the most cases.
ChemInform Abstract: Domino and Pincer Cycloadditions with syn‐o,o′‐Dibenzenes: Scope and π‐Facial Stereoselectivity.
Authors: FESSNER W.‐D. , GRUND C. , PRINZBACH H. 
Published: May 2016

AbstractThe dibenzo‐fused cage compounds (I) are subjected to thermally‐induced cycloaddition reactions with the dienophiles (II) and (IV).
ChemInform Abstract: Regioselectivity and Diastereoselectivity in Free‐Radical Macrocyclization.
Authors: PORTER N. A. , LACHER B. , CHANG V. H.‐T. , MAGNIN D. R. 
Published: May 2016

AbstractCyclization of the iodides (I) gives mixtures of the endo products (II) and the exo products (III) with a preference for the endo‐cyclization.