bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Alkylation of Methylenebismalonic and Acetonedicarboxylic Ester by Dihaloalkanes in the Presence of Potassium Carbonate in Dimethyl Sulfoxide.
Authors: ZEFIROV N. S. , SADOVAYA N. K. , KOMBAROVA S. V. 
Published: May 2016

AbstractCondensation of (I) with the α,ω‐dibromoalkanes (II) according to method A) yields the cycloalkanes (III).
ChemInform Abstract: syn/anti‐Stereochemistry of Cyclopentene‐1,2‐dione Dimers.
Authors: BLACKSTOCK W. P. , BROWN R. T. , BROWN S. R. , GILMORE C. J. 
Published: May 2016

AbstractIn refluxing MeOH the title compound (IVa) undergoes isomerization to afford the title dimer (IVb) (yield given in g).
ChemInform Abstract: Synthesis of Substituted 3,5‐Dimethylenecyclohexenes by Dehydroboration of 3‐Borabicyclo(3.3.1)non‐6‐enes.
Authors: BUBNOV YU. N. , GURSKII M. E. , GRANDBERG A. I. 
Published: May 2016

AbstractTreatment of the β‐methylborabicyclononenes (III), prepared from the methoxy compound (I) and the Grignard reagent (II), with butyllithium (IV) and subsequent work‐up with acetyl chloride give mixtures of the (methylenecyclohexenylmethyl)boranes (V) and (VI).
ChemInform Abstract: Trimethylsilyl Group Directed Wagner‐Meerwein Rearrangement of Bicyclo‐(2.2.2)octan‐2‐ol Derivatives.
Authors: ASAOKA M. , TAKEI H. 
Published: May 2016

AbstractThe trimethylsilylcyclohexenone (I) reacts with LDA (II) and trimethylsilyl chloride (IV) to give the enol ether (V).
ChemInform Abstract: Reaction of Fluorinated Magnesium‐Organic Compounds with Diethyl Dicarboxylates.
Authors: DORMIDONTOV YU. P. , SHADRINA L. P. , BELOGAI V. D. , KROKHALEV A. M. , YAKHLAKOVA O. M. 
Published: May 2016

AbstractThe reactions between the fluorinated aryl magnesium halides (Ia)‐(Id) and (II), (IV) or (VI) afford the hydroxyacid esters (III), (V) and (VII) or the oxoacid esters (IX), (X) and (XI).
ChemInform Abstract: Potential Antisecretory Antidiarrheals. Part 1. α2‐Adrenergic Aromatic Aminoguanidine Hydrazones.
Authors: PITZELE B. S. , MOORMANN A. E. , GULLIKSON G. W. , ALBIN D. , BIANCHI R. G. , PALICHARLA P. , SANGUINETTI E. L. , WALTERS D. E. 
Published: May 2016

AbstractAminoguanidines such as (III) are prepared by acid‐catalyzed condensation reaction of aromatic aldehydes or ketones such as (I) with aminoguanidinium salts such as (II).
ChemInform Abstract: A Synthetic Route to the Hexahydrobenzofuran Nucleus of Avermectins via Diazo Ketone Cyclization.
Authors: WHITE J. D. , DANTANARAYANA A. P. 
Published: May 2016

AbstractThe Diels‐Alder adduct (III), obtained from the siloxydiene (I) and maleic anhydride (II), is converted to the tricyclic diazo ketone (VI).
ChemInform Abstract: Benzoylation of the 2,2,4‐Trimethyl‐1,2‐dihydroquinoline Dimer.
Authors: SHMYREVA ZH. V. , SHIKHALIEV KH. S. 
Published: May 2016

AbstractReaction of the dimeric quinoline derivative (I) with benzoyl chloride (II) gives the mono (III) or the dibenzoyl derivative (IV).
ChemInform Abstract: Ethynyltri(isopropoxy)titanium Reactions with Pyrimidinones.
Authors: RISE F. , GRACE D. , UNDHEIM K. 
Published: May 2016

AbstractReaction of the halopyrimidinones (I) with lithium acetylide (II) in the presence of tri(isopropoxy)titanium chloride yields the 6‐ethynyl derivatives (III).
ChemInform Abstract: Unusual Transformations of Methyl β‐Nitropropionate in the Reaction with Silylating Reagents.
Authors: DANILENKO V. M. , IOFFE S. L. , STRELENKO YU. A. , KARPENKO N. F. , KALININ A. V. , TARTAKOVSKII V. A. 
Published: May 2016

AbstractThe β‐nitropropionate (I) reacts with bistrimethylsilylacetamide (II) to give the bis(methoxycarbonylvinyl)hydroxylamine (III).
ChemInform Abstract: 2,4,6‐Tri‐tert‐butylphenyllithium as a Base. Kinetic Deprotonation of Benzyl Methyl Ketone.
Authors: YOSHIFUJI M. , NAKAMURA T. , INAMOTO N. 
Published: May 2016

AbstractThe kinetic deprotonation of benzyl methyl ketone (I) with various lithium bases (II), followed by silylation with (III), is investigated.
ChemInform Abstract: Complexes of Dibenzylsulfoxide with Lanthanoid Nitrate.
Authors: ZULU M. M. , MADAN S. K. 
Published: May 2016

AbstractThe non‐hygroscopic and air‐stable complexes (I) are prepared by the reaction of the hydrated lanthanoid nitrate in t‐butanol with the sulfoxide in the presence of triethyl orthoformate.
ChemInform Abstract: Kinetic trans Effect of Phosphine Ligands in Anation Reactions of Aquocobaloximes.
Authors: DREOS GARLATTI R. , TAUZHER G. 
Published: May 2016

AbstractRate constants for the reaction of (I) with HSO3‐ in aqueous solution are determined at 35 °C. Both electronic and steric effects concur to control the trans effect of the phosphine ligands in the title reaction.
ChemInform Abstract: Lewis Acid Induced Homoallylic C‐Alkylation. A New Approach to C‐Glycosides.
Authors: HERSCOVICI J. , DELATRE S. , ANTONAKIS K. 
Published: May 2016

AbstractCoupling of L‐rhamnal (II) with methallyl 2‐tetrahydropyranyl ether (Ib) is performed in the presence of various Lewis acids.
ChemInform Abstract: Preparative Bioorganic Chemistry. Part 9. Synthesis of Punaglandin 4 by Means of Enzymatic Resolution of the Key Chlorocyclopentene Derivative.
Authors: MORI K. , TAKEUCHI T. 
Published: May 2016

AbstractThe racemic cis/trans‐mixture of the acetates (I) undergoes asymmetric hydrolysis using PPL to give the enantiomerically pure (1S,4R)‐cyclopentenol (II), which is converted to the chiral key intermediate (VI).
ChemInform Abstract: Studies on Tandem Ene/Intramolecular Diels‐Alder Reactions.
Authors: GIGUERE R. J. , NAMEN A. M. , LOPEZ B. O. , AREPALLY A. , RAMOS D. E. , MAJETICH G. , DEFAUW J. 
Published: May 2016

Abstract1,4‐Cyclohexadiene (I) and the alkynes (II) or (IV) give the adducts (III) and (V).
ChemInform Abstract: Properties of Chalcogen‐Chalcogen Bonds. Part 9. The Reagent Diphenyldiselane/Iodine: Not Phenylselenenyliodide (IV) but a CT Complex (III) with Cyclic Units.
Authors: KUBINIOK S. , DU MONT W.‐W. , POHL S. , SAAK W. 
Published: May 2016

AbstractOn crystallization in petroleum ether at ‐14 °C the title reagent (I)/(II) gives a solid which according to the X‐ray analysis (space group P1 with Z=2) has CT structure (III).
ChemInform Abstract: Reduction of 1,2‐Dioxetanes with Thiols as a Possible Protecting Reaction Against Photochemical Damage to Cellular DNA.
Authors: ADAM W. , EPE B. , SCHIFFMANN D. , VARGAS F. , WILD D. 
Published: May 2016

AbstractReaction of the dioxetane (I) with various thioles such as (II) or (V) leads to mixtures of the triol (III) and the disulfides (IV) or (VI); in the case of the simple thiols (V), the splitting products (VII) and (VIII) are formed additionally.
ChemInform Abstract: Surface Modifications with Heteropoly and Isopoly Oxometalates. Part 2. Electrocatalytic Behaviour of Glassy Carbon Surfaces Modified with 17‐Tungsto, 1‐Molybdo‐diphosphate.
Authors: KEITA B. , NADJO L. , SAVEANT J.‐M. 
Published: May 2016

AbstractGlassy carbon electrodes electrochemically modified with K6P2W17MoO62 are investigated by cyclic voltammetry.
ChemInform Abstract: Characterization by 51V Solid‐State NMR, Laser Raman, and X‐Ray Photoelectron Spectroscopy of Vanadium Species Deposited on γ‐Al2O3.
Authors: LE COUSTUMER L. R. , TAOUK B. , LE MEUR M. , PAYEN E. , GUELTON M. , GRIMBLOT J. 
Published: May 2016

AbstractTwo series of V2O5/γ‐Al2O3 catalysts are prepared by impregnation (NH4VO3 solution) at pH 4 or 10. The amount of vanadium species adsorbed on alumina is lower in the catalysts prepared at pH 10, but XPS results of samples prepared at pH 4 indicate a good vanadium dispersion in a monolayer type structure.
ChemInform Abstract: PPh4(As3S3Cl4) and PPh4(As3S3Br4).
Authors: MOHAMMED A. T. , KRUG V. , MUELLER U. + 
Published: May 2016

Abstract(I) reacts with (II) and (III) in CH2X‐CH2X (X: Cl, Br) to yield the title compounds (IV) as the minor products, PPh4(As2SX5) being the main products.
ChemInform Abstract: Determination of Reactivity by MO Theory. Part 51. Theoretical Studies of Solvent Effects on Gas‐Phase Reactions of Methoxide Ion with Substituted Ethylenes.
Authors: LEE I. , LEE B.‐S. , WON J. O. 
Published: May 2016

AbstractCalculations on the gas‐phase reaction of the ethylenes (I) with bare or monosolvated methoxide ion are carried out by the AM1 method.
ChemInform Abstract: Addition of tert‐Butyl Hypoiodite to Selected Olefins.
Authors: HEASLEY V. L. , BERRY B. R. , HOLMES S. L. , HOLSTEIN L. S. III , MILHOAN K. A. , SAUERBREY A. M. , TEEGARDEN B. R. , SHELLHAMER D. F. , HEASLEY G. E. 
Published: May 2016

AbstractThe olefins (I) react with tert‐butyl hypoiodite (II) in the presence of boron trifluoride etherate to form the adducts (III).
ChemInform Abstract: Asymmetric Diels‐Alder Cycloaddition Reactions with Chiral α,β‐Unsaturated N‐Acyloxazolidinones.
Authors: EVANS D. A. , CHAPMAN K. T. , BISAHA J. 
Published: May 2016

AbstractThe chiral α,β‐unsaturated N‐acyloxazolidinones (I) undergo highly diastereoselective Diels‐Alder reactions with cyclopentadiene (II) promoted by Et2AlCl (IV) to give the products (III) or (V).
ChemInform Abstract: Turning the Reactivity of Carbonyl Oxides from Nucleophilic to Electrophilic. A Novel Deoxygenation of Sulfoxides by Electrophilic α,α,α‐Trifluoroacetophenone O‐Oxide.
Authors: ISHIGURO K. , HIRANO Y. , SAWAKI Y. 
Published: May 2016

AbstractDiaryl sulfides (I), e.g. diphenyl sulfide, react with trifluoroacetophenone (II) on irradiation in an oxygen‐saturated solution in the presence of tetraphenylporphyrin to give the ketone (III) and diaryl sulfoxides, e.g. diphenyl sulfoxide (IV).
ChemInform Abstract: One‐Pot Transformation of Carboxylic Acids into Aldehydes Through Stepwise Treatment of Acyloxy‐9‐borabicyclo(3.3.1)nonenes with tert‐Butyllithium and 9‐Borabicyclo(3.3.1)nonane.
Authors: CHA J. S. , KIM J. E. , YOON M. S. , KIM Y. S. 
Published: May 2016

AbstractThe carboxylic acids (I) react with 9‐BBN (II) to give the acyloxyboranes (III) which yield the salts (VI) on treatment with tert‐butyllithium (V).
ChemInform Abstract: Carbocupration of Cyclopropene. A Novel Synthon of Cyclopropanone Enolate and Its Application to (3 + 2) and (3 + 2 + 2) Anellation.
Authors: NAKAMURA E. , ISAKA M. , MATSUZAWA S. 
Published: May 2016

AbstractAddition of the cuprate (II) to the cyclopropenone ketal (I) and subsequent quenching with an electrophile such as (III) yields the cis‐adduct (IV).
ChemInform Abstract: Activation of Carboxylic Acids and Alcohols by Intramolecular Cyclization. Acylation of Trimethylsilylacetylenes and Alkylation of Aromatic Compounds.
Authors: FUKUOKA S. , NANRI H. , KATSUKI T. , YAMAGUCHI M. 
Published: May 2016

AbstractThe mixed anhydrides or ketones (I) are activated with silver salts, producing the intermediates (II).
ChemInform Abstract: Photoreductive Decarboxylation of Carboxylic Acids via Their Benzophenone Oxime Esters.
Authors: HASEBE M. , TSUCHIYA T. 
Published: May 2016

AbstractThe photoreductive decarboxylation of various carboxylic acids is performed via photolysis of their benzophenone oxime esters (III) as outlined in the reaction scheme.
ChemInform Abstract: Synthesis of Methyl 2‐(Methyltrifluoroacetylamino)‐3‐(trimethylsiloxy)alkanoates and N‐Methyl‐N‐trifluoroacetyldidehydroamino Acid Methyl Esters.
Authors: SIMCHEN G. , SCHULZ D. , SEETHALER T. 
Published: May 2016

AbstractSilylation of methyl N‐trifluoroacetylsarcosine (I) generates the ketene acetal (III) which reacts with the aldehydes (IV) in the presence of zinc bromide, yielding the β‐siloxy amino acid derivatives (V).
ChemInform Abstract: Synthesis of Alkyl and Alkenyl Furyl Sulfoxides and Their Behaviour in the Pummerer Reaction.
Authors: LITVINOVA V. V. , FEDOROV N. V. , ANISIMOV A. V. , VIKTOROVA E. A. 
Published: May 2016

AbstractThe alk(en)yl furyl sulfides (I) are oxidized with hydrogen peroxide to give the sulfoxides (II).
ChemInform Abstract: Synthesis and Structure of Non‐Fused Bicyclic Thiazolidin‐4‐one Derivatives.
Authors: LEVSHIN I. B. , CHISTYAKOV V. V. , ANISIMOVA O. S. , SHEINKER YU. N. 
Published: May 2016

Abstract3‐Allylthiazolidinedione (I) is coupled with the iminothiazolidinones (II) to give the thiazolidinylidenethiazoles (III).
ChemInform Abstract: Amino Ketone and Oxazole Synthesis. Part 11. Extension of the Synthesis of Thiazoles from 2‐Aza‐1,4‐diketones or via Electrophilic Substitution of Arenes with 2‐Thiazolin‐5‐ones (Thioazlactones).
Authors: SCHIKETANZ J. , STEFANESCU A. , BALABAN M.‐C. , SCHIKETANZ A. , GHEORGHIU M. D. , BALABAN A. T. 
Published: May 2016

AbstractReaction of the arenes (II) with the 2‐thiazolin‐5‐one (I) in the presence of anhydrous aluminum chloride yields directly the thiazoles (III).
ChemInform Abstract: 4‐ and 5‐Hydroxylaminothiazolidin‐2‐thiones. Rearrangement of Carbamoyl Derivatives into 4‐ and 5‐Ureidothiazolidin‐2‐ones.
Authors: ORLOVA T. I. , EPSHTEIN S. P. , RUKASOV A. F. , TASHCHI V. P. , PUTSYKIN YU. G. 
Published: May 2016

AbstractThe hydroxylaminothiazolidines (I) or (V) are coupled with the isocyanates (II) to give the hydroxyureas (III) or (VI).
ChemInform Abstract: Ring Contraction and Additional Anellation in the Dibenzobullvalone System.
Authors: BANCIU M. , STANESCU M. , FLOREA C. , BALABAN A. T. , CIORANESCU E. 
Published: May 2016

AbstractDibenzobullvalone (I) is converted into the α‐hydroxymethylene ketone (III) which is further transformed into the diazo ketone (V) by treatment with p‐toluenesulfonyl azide (IV)/triethylamine.
ChemInform Abstract: Purines, Pyrimidines, and Fused Systems Thereof. Part 4. Formation of Pyrido(2,1‐f)xanthines from 7‐Aminotheophylline and Ketones.
Authors: KUZ'MENKO V. V. , POZHARSKII A. F. , CHERNYSHEV A. I. , NANAVYAN I. M. 
Published: May 2016

Abstract7‐Aminotheophylline (I) reacts with acetone (IIa) or, in better yields, with mesityl oxide (IIb) to give the pyridoxanthines (IIIa).
ChemInform Abstract: Synthesis of Functionalized β‐Amino α,β‐Unsaturated Esters and Nitriles by Nucleophilic Vinylic Substitution.
Authors: DE ANCOS B. , MAESTRO M. C. , MARTIN M. R. , FARINA F. 
Published: May 2016

AbstractThe reaction of methyl E‐ and Z‐3‐bromo‐4,4‐dimethoxy‐2‐butenoates (I) with the secondary amines (II) gives predominantly the E‐enamines (III), whereas the corresponding nitriles (IV) react with (II) under retention of configuration, yielding the cyanoenamines (V).
ChemInform Abstract: Another Rearrangement During the Photolysis of Lithium 3‐((p‐Tolylsulfonyl)amino)‐1,2,3‐benzotriazin‐4(3H)‐one.
Authors: REINECKE M. G. , BROWN E. S. 
Published: May 2016

AbstractThe benzotriazine (V) is prepared by two different methods from anthranilic acid hydrazide (I) or the benzotriazine (VI).
ChemInform Abstract: Reactions of 4‐Chloro‐1‐nitrobenzene with (3‐Chloro‐4‐methoxyphenyl)acetonitrile and (3,4‐Dimethoxyphenyl)acetonitrile; Synthesis of 8‐Chloro‐1‐methyl (and Methylthiomethyl)‐6‐(3,4‐disubstituted‐phenyl)‐4H‐s‐triazolo(4,3‐a)‐1,4‐benzodiazepines.
Authors: VEJDELEK Z. , HOLUBEK J. , BUDESINSKY M. , RYSKA M. , SVATEK E. , PROTIVA M. 
Published: May 2016

AbstractReaction of the nitrobenzene (I) with the acetonitriles (II) yields the benzisoxazoles (III), which are converted in five steps to the title compounds (X).
ChemInform Abstract: Aminoalkylidene and Aminoalkyl Derivatives of 6,11‐Dihydrodibenzo(b,e)thiepin‐2‐ and ‐9‐carbonitrile and 4,10‐Dihydrothieno(2,3‐c)‐1‐benzothiepin‐6‐carbonitrile; Antidepressants with a New Activity Profile.
Authors: SINDELAR K. , HOLUBEK J. , MATOUSOVA O. , SVATEK E. , VALCHAR M. , DLABAC A. , DLOHOZKOVA N. , HRUBANTOVA M. , PROTIVA M. 
Published: May 2016

AbstractThe title compounds (IVb), (VII)‐(XI), which are the cyano analogues of antidepressants of the prothiadene series, show properties of potential antidepressants and more or less inhibitors of the 5‐hydroxytryptamine uptake in the rat brain; at the same time they are rather strong central cholinolytics.
ChemInform Abstract: The First Spectroscopic Detection of Silaylides in the Reaction of Dimesitylsilylene with P, S, and N Heteroatom‐Containing Substrates. The Stability of Silaylides.
Authors: ANDO W. , SEKIGUCHI A. , HAGIWARA K. , SAKAKIBARA A. , YOSHIDA H. 
Published: May 2016

AbstractPhotolysis of the trisilane (I) and the pyrrolidines (II) at 77 K in a soft matrix leads to the UV‐detection of the ylides (III) resulting from addition of the primary photolysis product (IV) to (II).
ChemInform Abstract: A Simple, Efficient Synthesis of Dibenzyl and Di‐p‐nitrobenzyl 1‐Hydroxyalkanephosphonates.
Authors: HOFMANN M. 
Published: May 2016

AbstractThe 1‐hydroxyalkanephosphonic acids (I) are alkylated by the O‐benzylisoureas (II), forming the title esters (III).
ChemInform Abstract: 1,4,7‐Dioxaselenocins from 1,3‐Oxaselenoles.
Authors: MATOBA K. , YAMAZAKI T. 
Published: May 2016

AbstractReaction of dimedone (I) with selenium dioxide (II) yields the oxaselenole (III) which undergoes ring enlargement with diazomethane (IV) to produce the dioxaselenocin (V).
ChemInform Abstract: Conformationally Constrained Biologically Active Peptides: Tentative Identification of the Antimitogenic Bioactive Conformer of the Naturally Occurring Cyclic Tetrapeptides.
Authors: SHUTE R. E. , KAWAI M. , RICH D. H. 
Published: May 2016

AbstractConcerning the objective denoted in the title, the structure‐activity and conformational aspects of a class of cyclic peptide natural products such as (I) are described.
ChemInform Abstract: Peptide Synthesis. Part 10. Use of Pentafluorophenyl Esters of Fluorenyl Methoxycarbonylamino Acids in Solid Phase Peptide Synthesis.
Authors: ATHERTON E. , CAMERON L. R. , SHEPPARD R. C. 
Published: May 2016

AbstractThe application of the title esters to solid phase peptide synthesis under polar reaction conditions is described.
ChemInform Abstract: Peptide Synthesis. Part 11. A System for Continuous Flow Solid Phase Peptide Synthesis Using Fluorenylmethoxycarbonyl‐amino Acid Pentafluorophenyl Esters.
Authors: DRYLAND A. , SHEPPARD R. C. 
Published: May 2016

AbstractInstrumentation and operating procedures are described for the continuous flow solid phase synthesis of peptides using the title esters.
ChemInform Abstract: 1‐Methyl‐, 1‐Phenyl‐, and 1‐(2‐(2‐Dimethylaminoethoxy)phenyl)‐2,3,4,9‐tetrahydro‐1H‐pyrido(3,4‐b)indole and Their 2‐Substituted Derivatives: Synthesis and Pharmacological Screening.
Authors: HULINSKA H. , TAUFMANN P. , FRYCOVA H. , PROTIVA M. 
Published: May 2016

AbstractThe title compounds (II) are transformed to the 2‐substituted derivatives (VIII) and (X).
ChemInform Abstract: Anodic Oxidation of Hydrogenated Amorphous Silicon and Properties of Oxide.
Authors: HASEGAWA H. , ARIMOTO S. , NANJO J. , YAMAMOTO H. , OHNO H. 
Published: May 2016

AbstractIt is shown that uniform amorphous SiO2 layers of up to 2500 Å thickness can be grown on hydrogenated amorphous silicon (a‐Si:H) at room temp. by anodic oxidation in an ethylene glycol solution of KNO3 at a rate of 5.5 Å/V. The process is stable, reproducible, and electrically controllable.
ChemInform Abstract: Semiconductor Particles in Bilayer Lipid Membranes. Formation, Characterization, and Photoelectrochemistry.
Authors: ZHAO X. K. , BARAL S. , ROLANDI R. , FENDLER J. H. 
Published: May 2016

AbstractBilayer lipid membranes from bovine brain phosphatidylserine, glyceryl monooleate, and (I) are used as matrices for microcrystalline semiconductors (CdS, CuS, Cu2S, PbS, ZnS, HgS, and In2S3), stable for several days, which are generated in situ from appropriate metal ion precursors and H2S injected into the bathing solution on opposite sides of the membrane.
ChemInform Abstract: Vanadium‐51 NMR Line‐Broadening in the Mixture of Dioxovanadium(V) and Oxovanadium(IV) Ions in Perchloric Acid Solution.
Authors: OKAMOTO K. , JUNG W.‐S. , TOMIYASU H. , FUKUTOMI H. 
Published: May 2016

AbstractThe line‐broadening observed in the 51V NMR spectra of a HClO4 solution containing VO2+ and VO2+ ions is attributed to the exchange reaction between VO2+ and a mixed‐valence VO2+‐VO2+ dimeric complex.
ChemInform Abstract: Oxoperoxofluoromolybdate(VI) Complexes. The First Synthesis of Oxodiperoxofluoromolybdate(VI) Complexes.
Authors: CHAKRAVORTI M. C. , BANDYOPADHYAY D. 
Published: May 2016

AbstractThe compounds (IV) and (V) are synthesized and their IR spectra are discussed.
ChemInform Abstract: Synthesis, IR Spectrum, and Crystal Structure of PPh4(OsCl4(NO)(NSCl)).
Authors: FIGGE R. , PATT‐SIEBEL U. , CONRADI E. , MUELLER U. + , DEHNICKE K. 
Published: May 2016

AbstractRed crystals of the title compound are obtained as outlined in the scheme (yields in g).
ChemInform Abstract: Stereospecific Homocondensation of Vinylstannanes Catalyzed by Palladium as a Convenient Method for the Synthesis of Symmetric 1,3‐Dienes.
Authors: TOLSTIKOV G. A. , MIFTAKHOV M. S. , DANILOVA N. A. , VEL'DER YA. L. 
Published: May 2016

AbstractIn the presence of Pd catalyst the functionalized vinylstannanes (I), (III) and (V) undergo elimination of the tributylstannyl group and homocombination of the alkenyl moieties to give the symmetric and functionalized 1,3‐butadienes (II), (IV) or (VI).
ChemInform Abstract: Initiation Mechanisms in Radical Polymerization: Reaction of tert‐Butoxy Radicals with Allyl Acrylate and with Diallyl Ether.
Authors: BUSFIELD W. K. , JENKINS I. D. , THANG S. H. , RIZZARDO E. , SOLOMON D. H. 
Published: May 2016

AbstractThe radical trapping technique employing the species (I) as scavenger is used to study the reaction of tert‐butoxy radicals (generated by thermolysis of the peroxalate (III)) with the title compounds (IIa) and (IIb).
ChemInform Abstract: An Efficient Synthesis of Ethyl (R)‐2‐Hydroxy‐4‐phenylbutyrate: A Useful Intermediate in the Synthesis of Converting Enzyme Inhibitors.
Authors: FLYNN G. A. , BEIGHT D. W. 
Published: May 2016

AbstractThe Grignard compound (IV) reacts with the optically active oxalate (III) to form the α‐keto ester (V) which is reduced with a chiral borane to give the hydroxy ester (VI).
ChemInform Abstract: Enantioselective Synthesis of (3S)‐trans‐4‐(Substituted Methyl)monobactams from 2,3‐O‐Isopropylidene‐D‐glyceraldehyde.
Authors: HERRANZ R. , CONDE S. , FERNANDEZ‐RESA P. , ARRIBAS E. 
Published: May 2016

AbstractThe target compound (VI) is synthesized as shown in the scheme.
ChemInform Abstract: An Efficient Synthetic Method of Jasmone Analogues and 2,5‐Dialkylpyrrolidine Alkaloids Using 1‐Benzyl‐2,5‐dicyanopyrrolidine.
Authors: TAKAHASHI K. , AIHARA T. , OGURA K. 
Published: May 2016

Abstract1‐Benzyl‐2,5‐dicyanopyrrolidine (I) is consecutively coupled with the alkyl halides (II) and (IV) to form the disubstituted products (V).
ChemInform Abstract: Asymmetric Reductive Amination of Cycloalkanones. Part 6. Asymmetric Synthesis of cis‐(4aR,8aR)‐ and cis‐(4aS,8aS)‐Decahydroquinolines.
Authors: OMAR F. , FRAHM A. W. 
Published: May 2016

AbstractCoupling of the chlorocyclohexanone (I) with the Grignard compound (II) forms the ethoxypropyl derivative (III) which reacts with (R)‐ or (S)‐phenylethylamine (IV) to give the imines (V).
ChemInform Abstract: A New Method for the Formation of P‐P Bonds ‐ Synthesis of Cyclic Diphosphine Monosulfides.
Authors: SCHMUTZLER R. , STELZER O. , WEFERLING N. 
Published: May 2016

AbstractThe disecondary phosphine sulfides (I) are converted to the monosulfides of the diphospholanes or diphosphinanes (III), which upon oxidative addition of the benzoquinone (IV) afford the oxyphosphoranes (V) with λ4P‐λ5P bonds.
ChemInform Abstract: Triple‐Decker Sandwich Complexes with cyclo‐P6 as Middle Deck.
Authors: SCHERER O. J. , SCHWALB J. , SWAROWSKY H. , WOLMERSHAEUSER G. + , KAIM W. , GROSS R. 
Published: May 2016

AbstractThe cothermolysis of white phosphorus P4 (II) and the V tetracarbonyl (I) as well as the W complex (IV) affords the triple‐decker sandwich complexes (III).
ChemInform Abstract: Mechanism of the Reaction of (Mo(η‐C6H6)(Me2PCH2CH2PMe2)(η‐C2H4)H)+ with PMe3 Giving (Mo(η‐C6H5Et)(dmpe)(PMe3)H)+: Metal‐to‐Ring Migration of an Ethyl Group.
Authors: BUNTING H. E. , GREEN M. L. H. , NEWMAN P. A. 
Published: May 2016

AbstractThe cis‐ethylenehydride compounds (I) react with trimethylphosphine (II) to give the η6‐ethylbenzene compounds (III).