bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Metallamacrocycles Built from Mercury(II) and Bis((diphenylphosphino)methyl)phenylarsine.
Authors: BALCH A. L. , OLMSTEAD M. M. , ROWLEY S. P. 
Published: May 2016

AbstractThe Hg complex (IV) crystallizes in P1 with Z=2 and (VI) in P1 with Z=1.
ChemInform Abstract: Hexanuclear Iron‐Sulfur Basket Clusters: Topological Isomers of Prismanes. Synthesis, Structure, and Reactions.
Authors: SNYDER B. S. , HOLM R. H. 
Published: May 2016

AbstractA new group of Fe‐S clusters (III), containing the previously unknown basketlike core (Fe6S6)2+ is prepared by different methods starting with (I).
ChemInform Abstract: A Novel Family of Binuclear Cobalt(II) Complexes with Face‐to‐Face Bis(cyclidene) Ligands: Structural Characterization, Unusual Reactions with Dioxygen, and a Distinctive Host‐Guest Complexation with a Bridging Ligand.
Authors: HOSHINO N. , JIRCITANO A. , BUSCH D. H. 
Published: May 2016

AbstractThe title complexes (I) are prepared by the reaction of the macrocyclic ligands (obtained from the corresponding Ni complexes) with Co acetate in MeOH in the presence of Na acetate and isolated as their PF6 salts.
ChemInform Abstract: A Novel “Tent‐Like” Structure of a Copper(I) Aggregate. The Crystal and Molecular Structure of Nona(N‐(diethoxythiophosphoryl)‐N′‐phenylisothioureato)decacopper(I) Perchlorate.
Authors: NIVEN M. L. , KYRIACOU P. , MODRO T. A. 
Published: May 2016

AbstractThe title complex (III) (no yield given) crystallizes in the space group P1 with Z=2.
ChemInform Abstract: Complexes of Osmium, Uranium, Molybdenum, and Tungsten with the Catechol Amines Adrenaline, Noradrenaline, Dopamine, Dopa, and Isoproterenol.
Authors: EL‐HENDAWY A. M. , GRIFFITH W. P. , PUMPHREY C. A. 
Published: May 2016

AbstractNew complexes of the type (II)‐(VII) are prepared from the catechol amines (I) and trans‐K2(OsO2(OH)4), hydrated uranyl acetate, sodium molybdate, or sodium tungstate.
ChemInform Abstract: Glycosyl Imidates. Part 37. Direct O‐Glucosylation of Compounds Containing a PO(OH) Moiety.
Authors: ESSWEIN A. , SCHMIDT R. R. 
Published: May 2016

AbstractGlucosylation of the title phosphorus compounds (II), (VI) and (IX) with the trichloroacetimidates (I), (IV) and (VIII) yields the products (III), (V), (VII) and (X).
ChemInform Abstract: Regio‐ and Enantioselectivity of the Enzymatic Hydrolysis of Isobutyl 3,4‐Anhydro‐2,6‐dideoxy‐β‐DL‐ribo‐hexopyranoside.
Authors: BARILI P. L. , BERTI G. , CATELANI G. , COLONNA F. , MASTRORILLI E. 
Published: May 2016

AbstractThe enzymatic hydrolysis of the title compound (I) is found to be not regiospecific, affording the β‐olivopyranoside (II) predominantly together with smaller amounts of the β‐boivinopyranoside (III).
ChemInform Abstract: Synthesis of a Heavy‐Atom Derivative of Gramicidin S (GS), (D‐Phe(4‐Br)4,4′)‐GS, by a Novel Method.
Authors: AIMOTO S. 
Published: May 2016

AbstractThe crystalline title compound (II) can be synthesized by cyclization of the linear peptide (I) which in turn is prepared by the solid‐phase method starting from the protected Pro unit.
ChemInform Abstract: 2α‐Alkyl Gibberellins A1 and A4.
Authors: FOWLES A. M. , BEALE M. H. , JONES D. N. M. , MACMILLAN J. , WILLIS C. L. 
Published: May 2016

AbstractThe 2α‐alkyl gibberellins A1 (VI) are synthesized starting from the gibberellin A3 ester (I) by reaction with an alkylcopper‐Mg complex, prepared from Grignard compounds (II) and CuI, via the intermediates (III) + (IV) and (V).
ChemInform Abstract: Coating Films of xMgO·(15‐x)B2O3·80 SiO2 by the Sol‐Gel Method.
Authors: TOHGE N. , MINAMI T. 
Published: May 2016

AbstractTransparent xMgO·(15‐x)B2O3·80 SiO2 coatings, which can be applied as passivation layers in electronic devices, are obtained by addition of a relatively large amount of HCl to the ethanolic coating solutions containing Si(OEt)4, B(OBu)3, and Mg(OEt)2 (or MgCl2), dilution with EtOH, coating, and heat treatment.
ChemInform Abstract: Ag2PdCl4, Crystal Structure and the Crystal Chemical Relation to the NaCl Type.
Authors: SCHROEDER L. + , KELLER H.‐L. 
Published: May 2016

AbstractSingle crystals of the title compound, obtained by melting together AgCl and PdCl2 (2:1) in an evacuated quartz ampoule, quenching the melt, and annealing at 565 K (2 weeks), crystallizes in the orthorhombic system, space group Cmca with Z=4.
ChemInform Abstract: Iron(III) Chloride Hydrate in the Vapor Phase.
Authors: RUSTAD D. S. , GREGORY N. W. 
Published: May 2016

AbstractAn extended spectrophotometric study of the FeCl3‐Cl2‐HCl‐H2O system results in vapor‐phase absorbances, which can be explained by assuming 0.5 Fe2Cl6(g) + H2O(g) = Fe(H2O)Cl3(g) to be the dominant equilibrium at temp. < 600 K. The molar absorptivities over the wavelength range 240‐440 nm and values for the standard enthalpy of formation and the standard entropy for Fe(H2O)Cl3(g) at 500 K are derived from equilibrium data.
ChemInform Abstract: Formation of Anodic Oxide Films on Tantalum in the Presence of UV Radiations and Heat Treatment of Anodic Tantalum Oxide Films.
Authors: NIGAM R. K. , KALRA K. C. , KATYAL P. 
Published: May 2016

AbstractThe ionic conduction behavior of anodic oxide films, formed on tantalum in aqueous solutions of citric, tartaric, and acetic acids at constant current density and very high‐field strength in the presence and absence of UV irradiation, is investigated.
ChemInform Abstract: The meta Photocycloaddition of Alkyl‐ and Alkoxy‐Substituted Arenes to Cyclopentene.
Authors: DE VAAL P. , OSSELTON E. M. , KRIJNEN E. S. , LODDER G. , CORNELISSE J. 
Published: May 2016

AbstractUsing FT‐NMR techniques the 1:1 meta adducts of benzene and substituted benzenes such as Ph‐R and Ph‐O‐R (R: ‐Me, ‐Et, ‐iPr, ‐tBu), Ph‐O‐Ph and all di‐ to hexamethylbenzenes with cyclopentene at low conversion are identified.
ChemInform Abstract: Homolytic Rearrangements of Bicyclo(2.2.0)hexane (I) and Bicyclo(3.2.0)heptane (X).
Authors: WALTON J. C. 
Published: May 2016

AbstractResults of the radical reactions of (I) with (tBu‐O)2, Br2, Br‐CCl3 (photoreactions), and Br‐N(SiMe3)2 (AIBN) indicate that free radicals abstract hydrogen from both the bridge and bridgehead sites of (I) to generate (III) (only observable by ESR) and (IV), the latter rearranging by stereoelectronically forbidden β‐scission to give (V).
ChemInform Abstract: Novel Oxidation of 1,2‐Dibenzylhydrazines with Carbon Tetrachloride.
Authors: KANO K. , ANSELME J.‐P. 
Published: May 2016

AbstractThe casual discovered aptitude of CCl4 to oxidize 1,2‐dibenzylhydrazines (I) (during an NMR examination) may be a useful tool for it is running as well in solvents such as Et2O, with added bases such as Et3N to scavenge the HCl formed, and even with the hydrochlorides of hydrazines (I) in H2O/Na2CO3, thus minimizing uncontrolled air oxidation of the free hydrazines (I).
ChemInform Abstract: Aromatic Sulfonation. Part 102. Sulfonation and Sulfation in Reactions of C‐methylated Phenols and Anisoles with Sulfur Trioxide. 4‐Substituted Phenyl Hydrogen Sulfates: Effective Reagents for Transsulfonation.
Authors: GOOSSENS H. D. , LAMBRECHTS H. J. A. , CERFONTAIN H. , DE WIT P. 
Published: May 2016

AbstractThe reaction of phenol and a variety of phenol derivatives such as (I) with SO3 in MeNO2 at 0 °C is studied (directing effects, time dependence).
ChemInform Abstract: Mannich Bases of Ethyl 5‐Substituted‐Benzimidazole‐2‐thioacetates and Their Antiinflammatory and Analgesic Activities.
Authors: KASTURE A. V. , WADODKAR S. G. , JAIN K. P. 
Published: May 2016

AbstractReaction of the benzimidazolylthioacetates (I) with formaldehyde (II) and the secondary amines (III) produces the Mannich bases (IV).
ChemInform Abstract: Synthesis and Thermolysis of 4‐Substituted 5‐Azido‐1‐phenyl‐1,2,3‐triazoles.
Authors: L'ABBE G. , VANDENDRIESSCHE A. , TOPPET S. 
Published: May 2016

AbstractThe triazoles (I), (III), (VII) and (IX) are prepared from the corresponding aminotriazoles which, in turn, are obtained by known procedures.
ChemInform Abstract: Reaction of Ketenes with N,N‐Disubstituted α‐Aminomethylene Ketones. Part 19. Synthesis of N,N‐Disubstituted 4‐Amino‐3‐phenyl‐2H‐furo‐(2,3‐h)‐1‐benzopyran‐2‐ones (4‐Amino‐3‐phenylangelicins). Crystal and Molecular Structure of 3‐Phenylangelicin.
Authors: MOSTI L. , SCHENONE P. , MENOZZI G. , SANCASSAN F. , BACCICHETTI F. , BENETOLLO F. , BOMBIERI G. 
Published: May 2016

AbstractPhenyl chloro ketene (II) reacts with the aminomethylenecycloalkenones (I) to give the cycloadducts (III) which are dehydrochlorinated to yield the olefins (IV), together with (V).
ChemInform Abstract: Active Malonic Esters as Synthons for Heterocycles. A Method for the Preparation of 4‐Hydroxy‐2(1H)‐pyridones.
Authors: KAPPE T. , AJILI S. , STADLBAUER W. 
Published: May 2016

AbstractThe imines (I) undergo cyclocondensation with the bis(trichlorophenyl) malonates (II), producing the pyridones (III) mentioned in the title.
ChemInform Abstract: Preparation of New Nitrogen‐Bridged Heterocycles. Part 18. Facile Formations of 3‐Arylpyrazolo(1,5‐a)pyridines and 1‐Arylindolizines.
Authors: KAKEHI A. , ITO S. , KINOSHITA N. , ABAKA Y. 
Published: May 2016

Abstract20 Derivatives of type (IV) and 24 of type (VI)/(VIII) are prepared by S‐benzylation of pyridinium N‐ylides (I), (V), (VII), followed by base‐catalyzed ring closure via an intermediate of type (III) in the presence or absence of a dehydrogenating agent.
ChemInform Abstract: Reactions of Some 1,3‐Diaminonucleophiles with Azlactones.
Authors: TIKDARI A. M. , TRIPATHY P. K. , MUKERJEE A. K. 
Published: May 2016

AbstractThe azlactones (I), (VI) and (X) react with the isothiouronium halides (II) to give the products (III), (VII) and (XI), respectively.
ChemInform Abstract: Synthesis of Antihypertensive 3‐(1,3,4‐Oxadiazol‐2‐yl)phenoxypropanolamines.
Authors: SCHLECKER R. , THIEME P. C. 
Published: May 2016

AbstractA series of title compounds of type (VIIa)‐(VIId) is synthesized according to the method shown for (VIIa).
ChemInform Abstract: Reactions of Some Conjugated Dienes with an o‐Quinone Monoimide.
Authors: HEINE H. W. , SCHAIRER W. C. , SURIANO J. A. , WILLIAMS E. A. 
Published: May 2016

AbstractThe title imide (I) undergoes Diels‐Alder reaction with the dienes (II), (IV) and (VII) to afford the products (III), (V) and (VI), respectively.
ChemInform Abstract: Contributions to the Chemistry of Silicon‐Sulfur Compounds. Part 51. The Insertion of Sulfur into Si‐Si Bonds of Permethylpolysilanes.
Authors: BECKER B. , WOJNOWSKI W. 
Published: May 2016

AbstractDodecamethylcyclohexasilane (I) and the linear polymeric permethylpolysilanes (X) react with elemental sulfur (II) at higher temperatures to give the cyclic sulfur‐silicon compounds (III) ‐ (IX).
ChemInform Abstract: Reaction of 1,4‐Diketones with Phosphine.
Authors: KALINOV S. M. , ROSTOVSKAYA M. F. , VYSOTSKII V. I. 
Published: May 2016

AbstractThe 1,4‐diketones (I) react with phosphine (II), prepared in situ from magnesium phosphide and hydrochloric acid, to give the dihydrophospholes (III) and the phospholanes (IV).
ChemInform Abstract: Sulfur(IV) Compounds as Ligands. Part 8. Adducts of Tin(IV) Halides with Thiirane 1‐Oxide.
Authors: SCHENK W. A. , KHADRA A. 
Published: May 2016

AbstractThiirane 1‐oxide (II) readily forms the 2:1 adducts (IIIa) and (IIIb), and the 1:1 adduct (IIIc) with the corresponding phenyltin halides (I) as shown.
ChemInform Abstract: Main Group Metal Halide Complexes with Sterically Hindered Thioureas. Part 9. New Complexes of Selected Post‐Transition Metals and 1,3‐Dimethyl‐2(3H)‐imidazolethione and a Structural Investigation of Infrared Peak Shifts Associated with Coordination.
Authors: WILLIAMS D. J. , POOR P. H. , RAMIREZ G. , HEYL B. L. 
Published: May 2016

AbstractThe complexes (I) are prepared by mixing stoichiometric quantities of the appropriate metal halide and the ligand in boiling MeOH, (II)‐(IV) are obtained by literature methods.
ChemInform Abstract: Carbodiphosphane (2,4,6‐t‐Bu3C6H2‐P=)2C: Reaction with Nucleophiles.
Authors: KARSCH H. H. , REISACHER H.‐U. 
Published: May 2016

AbstractCoupling of the carbodiphosphane (III) with the ylide (II) leads to the formation of the compound (I).
ChemInform Abstract: Boar Taint Steroid Derivatives for Immunological Studies. Synthesis of 11α‐Hydroxy‐5α‐androst‐16‐en‐3‐one and Its Hemisuccinate.
Authors: TURNER A. B. , VAN LEERSUM P. T. 
Published: May 2016

AbstractThe off‐flavor of cooked boar meat is thought to be mainly due to the presence of 5α‐androst‐16‐en‐3‐one.
ChemInform Abstract: Reaction of Lead(IV) Acetate with Steroidal Epoxides.
Authors: SHAFIULLAH SHAFIULLAH , PATHAK R. K. 
Published: May 2016

AbstractTreatment of the steroidal epoxides (Ia) and (Ib) with lead(IV) acetate (II) gives the hydroxy acetates (III) and the diacetates (IV).
ChemInform Abstract: Opioid Agonists and Antagonists. Peptides Containing N‐Terminal Allyl Groups and/or a Thiomethylene Linkage in Place of a Peptide Bond.
Authors: BALBONI G. , SALVADORI S. , MARASTONI M. , TOMATIS R. , BOREA P. A. , BIANCHI C. 
Published: May 2016

AbstractPeptides (III), (IV), (IX)‐(XV) containing N‐allyl or N,N‐diallyl groups are synthesized as potential opioid antagonists.
ChemInform Abstract: A Route to Long‐Chain Amino Sugars by Three Substituted Thiazoles as Auxiliaries: Thiazole‐2‐carbonitrile N‐Oxide, 2‐Trimethylsilylthiazole, and 2‐Thiazolylmethylenetriphenylphosphorane.
Authors: DONDONI A. , FANTIN G. , FOGAGNOLO M. , MEDICI A. , PEDRINI P. 
Published: May 2016

AbstractThe cycloadduct (III) from the components (I) and (II) is transformed to the dialdoidofuranose derivatives (X) via the intermediates (VI), (VII), and (VIII).
ChemInform Abstract: Synthesis of Queuine, the Base of Naturally Occurring Hypermodified Nucleoside (Queuosine), and Its Analogues.
Authors: AKIMOTO H. , IMAMIYA E. , HITAKA T. , NOMURA H. , NISHIMURA S. 
Published: May 2016

AbstractThe syntheses of the title compound (IX), its biosynthetic precursor (VIa), and a number of alkyl (cf.
ChemInform Abstract: Preparation and Diels‐Alder Reactions of a Pyranoid Vinyl Glycal: Model Studies for Anthraquinone Aglycone and Carbohydrate Syntheses.
Authors: LIPSHUTZ B. H. , NGUYEN S. L. , ELWORTHY T. R. 
Published: May 2016

AbstractThe title compound (IX) is prepared starting from the α‐D‐glucoside (I).
ChemInform Abstract: Formation and Reactions of 2,3‐Dimethylene‐2,3‐dihydrothiophene.
Authors: VAN LEUSEN A. M. , VAN DEN BERG K. J. 
Published: May 2016

AbstractThe (silylmethyl)ammoniomethylthiophene (I) reacts with fluoride ions to form the reactive dimethylenedihydrothiophene (II) mentioned in the title.
ChemInform Abstract: Cyclization of a Cysteine Conjugate of N‐(3,5‐Dichlorophenyl)succinimide.
Authors: SHIH H.‐C. , RANKIN G. O. 
Published: May 2016

AbstractCysteine methyl ester hydrochloride (II) reacts with the maleimide (I) to give the adduct (III) which rearranges upon treatment with triethylamine in methanol to yield the thiazinone (IV).
ChemInform Abstract: Chalcogenolate Ions and Their Derivatives. Part 17. 2,3,8,9‐Tetraalkoxydibenzo(c,g)‐1,2,5,6‐tetrathiocins.
Authors: WOELKI N. + , KLAR G. 
Published: May 2016

AbstractStarting with the dibromobenzenes (I), the dithiols (IV) are prepared.
ChemInform Abstract: Bis(2,3,4,6,7‐η5‐bicyclo(3.2.2)nona‐2,6,8‐trien‐4‐yl)iron, a Ferrocene Analogue with Separated Allyl and Olefin Systems.
Authors: BLUEMEL J. + , KOEHLER F. H. + , MUELLER G. + 
Published: May 2016

AbstractThe title complex (V) is synthesized according to the scheme and characterized by X‐ray structure analysis (space group P21/n, Z=2), 1H and 13C NMR data, and cyclic voltammetry.
ChemInform Abstract: The Preparation and Characterization of New Thioanthraquinone Dyes.
Authors: HARKER C. , WINNIK F. M. 
Published: May 2016

Abstract1,8‐Dihydroxyanthraquinone (I) is reductively alkylated with the aldehyde (II) in the presence of Na2S2O4 to give the diisobutylanthraquinone (III).
ChemInform Abstract: Total Synthesis of (.+‐.)‐N2‐(Phenylsulfonyl)‐CPI, (.+‐.)‐CC‐1065, (+)‐CC‐1065, ent‐(‐)‐CC‐1065, and the Precise, Functional Agents (.+‐.)‐CPI‐CDPI2, (+)‐CPI‐CDPI2, and (‐)‐CPI‐CDPI2 ((.+‐.)‐(3bR*,4aS*)‐, (+)‐(3bR,4aS)‐, and (‐)‐(3bS,4aR)‐Deoxy‐CC‐1065)
Authors: BOGER D. L. , COLEMAN R. S. 
Published: May 2016

Abstract(compound (I), the left‐hand segment of CC‐1065, compounds (IIa)‐(IIc) and (IIIa)‐(IIIc), respectively; CPI‐CDPI2 is found to possess the precise structural and functional features that are responsible for the CC‐1065 sequence‐selective B‐DNA minor groove association and the resulting expression of potent cytostatic activity.
ChemInform Abstract: Synthesis and Properties of the Perovskites LaNi0.75M0.25O3 (M: Mo, W) and LaNi0.5M0.5O3 (M: Zr, Sn).
Authors: MAKHNACH L. V. , KONONYUK I. F. 
Published: May 2016

AbstractThe title compounds are prepared under air by solid‐phase reactions between 1720 and 1770 K. The first two of the title compounds have cubic and the remaining two have rhombohedrally distorted lattices.
ChemInform Abstract: Electron Transfer and Ion‐Pair Formation. Part 6. ENDOR Spectroscopy in Water: Reductions and Oxidations of Organic Compounds.
Authors: BOCK H. , HIERHOLZER B. 
Published: May 2016

AbstractThe characterization of paramagnetic compounds in H2O by ENDOR spectroscopy is achieved by the use of special capillary tubes and optimal concentrations under O2‐free conditions.
ChemInform Abstract: Ketene Silyl Acetal Chemistry. Diastereofacial Selectivity of 1,3‐Addition of Chiral Nitrones.
Authors: KITA Y. , TAMURA O. , ITOH F. , KISHINO H. , MIKI T. , KOHNO M. , TAMURA Y. 
Published: May 2016

AbstractZn(II)‐catalyzed coupling of the nitrones (I) with the ketene silyl acetals (II) gives the syn‐1,3‐adducts (III) together with the anti‐isomers (IV).
ChemInform Abstract: Reactions of α‐Hydroxy Ketones with Glycerol, 1‐Thioglycerol and meso‐Erythritol.
Authors: FJELDSKAAR I. R. , GRACE D. , ROEMMING C. , SKATTEBOEL L. 
Published: May 2016

AbstractTreatment of the hydroxy ketones (I) with glycerol (II) gives the trans configurated products (III) whereas the trans/cis isomers (V)/(VI) are obtained from (Ia), (Ib) with thioglycerol (IV).
ChemInform Abstract: A Chiral Masked Ketene Synthone, (R)‐(+)‐Ethynyl p‐Tolyl Sulfoxide.
Authors: MAIGNAN C. , BELKASMIOUI F. 
Published: May 2016

AbstractThe optically active sulfoxide (II) reacts with cyclopentadiene (I) to give the isomeric cycloadducts (III) and (IV).
ChemInform Abstract: A Short Formal Synthesis of the Carbapenem Antibiotic (.+‐.)‐PS‐5.
Authors: ODRIOZOLA J. M. , COSSIO F. P. , PALOMO C. 
Published: May 2016

AbstractCycloaddition reaction of the α‐bromo carboxylates (I) with the unsaturated N‐aryl imine (II) yields the N‐(aryl)vinylazetidinones (III) which are converted to the acetyl derivatives (IV) by ozonolysis.
ChemInform Abstract: An Efficient Synthesis of 4‐Benzoyloxyazetidinone: An Important Carbapenem Intermediate.
Authors: TSCHAEN D. M. , FUENTES L. M. , LYNCH J. E. , LASWELL W. L. , VOLANTE R. P. , SHINKAI I. 
Published: May 2016

AbstractThe ketene (II), generated from the acid chloride (I), reacts with the benzoylimine (III) to form the azetidinones (IV) and (V).
ChemInform Abstract: Synthesis of 3‐Hydroxypyridines by Condensation Reaction of Substituted 4‐Methyl‐3‐hydroxyoxazoles with Ethyl β‐Cyanoacrylate.
Authors: ITOV Z. I. , GUNAR V. I. 
Published: May 2016

AbstractThe oxazoles (I) are coupled with the cyanoacrylate (II) to give predominantly the 4‐cyanopyridine (III).
ChemInform Abstract: Substituted 1,8‐Naphthyridines. Part 10. Synthesis of 2‐Methyl‐3‐(5‐phenyl‐ or 1,5‐diphenyl‐2‐pyrazolin‐3‐yl)‐1,8‐naphthyridines.
Authors: CHARY M. T. , MOGILAIAH K. , SREENIVASULU B. 
Published: May 2016

AbstractSince 1,8‐naphthyridines as well as pyrazolines are known to be biologically active substances, a series of title compounds of type (IV) which includes both active moieties is synthesized.
ChemInform Abstract: Boron‐Nitrogen Polymers. Part 3. Nitrogen‐ and Oxygen‐Bridged Compounds.
Authors: PACIOREK K. J. L. , KRATZER R. H. , KIMBLE P. F. , NAKAHARA J. H. , WYNNE K. J. , DAY C. S. 
Published: May 2016

AbstractThe preparation of the title compounds (II) and (IV) is described.
ChemInform Abstract: Synthesis of Organo‐Silicon Compounds Containing Cyano Groups.
Authors: NASAKIN O. E. , LUKIN P. M. , SHEVNITSYN A. L. , SHELUDYAKOV V. D. , CHERNYSHOV E. A. 
Published: May 2016

AbstractPhotoinitiated addition reaction of the bromomalononitriles (II) to the vinylsilanes (I) yields the bromosilyldicyanopropanes (III).
ChemInform Abstract: Synthetic, Structural, and Reactivity Studies of the Reduction and CO Derivatization of Azobenzene Mediated by Divalent Lanthanoid Complexes.
Authors: EVANS W. J. , DRUMMOND D. K. , CHAMBERLAIN L. R. , DOEDENS R. J. , BOTT S. G. , ZHANG H. , ATWOOD J. L. 
Published: May 2016

AbstractThe addition of one equiv. of the Sm compound (II) to azobenzene (I) forms the η2‐N2Ph2‐Sm(III) complex (III).
ChemInform Abstract: New Hydrophobic Host Molecules Containing Multiple Redox‐Active Centres.
Authors: BEER P. D. , TITE E. L. 
Published: May 2016

AbstractResorcinol (I) reacts with ferrocenecarboxaldehyde (II) in an acidic medium to give the macrocycle (IIIa) which is esterified to yield the polyacyloxy derivatives (IIIb) and (IIIc).
ChemInform Abstract: Syntheses and Characterization of Unique Organometallic Nickel(III) Aryl Species. ESR and Electrochemical Studies and the X‐Ray Molecular Study of Square‐Pyramidal (Ni(C6H3(CH2NMe2)2‐o,o′)I2).
Authors: GROVE D. M. , VAN KOTEN G. , MUL P. , ZOET R. , VAN DER LINDEN J. G. M. , LEGTERS J. , SCHMITZ J. E. J. , MURRALL N. W. , WELCH A. J. 
Published: May 2016

AbstractThe oxidation of the Ni(II) species (I) and (IV) by CuX2 (II) or I2 (V) affords the air‐stable, square‐pyramidal Ni(III) aryl species (IIIa) and (IIIb) that are precursors to the NO2 and NO3 analogues (IIIc).
ChemInform Abstract: Formation of Octahedral Iridium(III) Dihydrides from the Reaction of Ortho‐Chelated Aryliridium(I) Compounds with Dihydrogen.
Authors: VAN DER ZEIJDEN A. A. H. , VAN KOTEN G. , LUIJK R. , GROVE D. M. 
Published: May 2016

AbstractThe reaction of the Ir(I) complexes (I) with H2 leading to the quantitative formation of the novel Ir(III) complexes (II) is monitored by 1H NMR spectra.
ChemInform Abstract: Approaches Toward the Synthesis of a 2,9,16,23‐Tetrasubstituted Phthalocyanine as a Pure Isomer.
Authors: GREENBERG S. , LEVER A. B. P. , LEZNOFF C. C. 
Published: May 2016

AbstractTreatment of the phthalonitrile (I) with H2S (II) yields the isomeric thioisoindoline derivatives (III) and (IV) the methylation of which gives rise to the products (V) and (VI).
ChemInform Abstract: A New Class of Phospholipase A2 Substrates: Kinetics of the Phospholipase A2 Catalyzed Hydrolysis of 3‐(Acyloxy)‐4‐nitrobenzoic Acids (I).
Authors: CHO W. , MARKOWITZ M. A. , KEZDY F. J. 
Published: May 2016

AbstractAcids (I) are hydrolyzed by catalytic amounts of phospholipases A2 from a variety of sources.
ChemInform Abstract: Chemistry of Amphotericin B. Degradation Studies and Preparation of Amphoteronolide B.
Authors: NICOLAOU K. C. , CHAKRABORTY T. K. , OGAWA Y. , DAINES R. A. , SIMPKINS N. S. , FURST G. T. 
Published: May 2016

AbstractAmphotericin B is converted to a series of derivatives including useful protections, degradations and oxidative deglycosidation.
ChemInform Abstract: Preparation of Chiral, Highly Functionalized Cyclopentenones.
Authors: OKANO K. , MIZUHARA Y. , SUEMUNE H. , AKITA H. , SAKAI K. 
Published: May 2016

AbstractCyclization reaction of the 1,4‐diketones (I) gives the cyclopentenones (II) or the hydroxycyclopentenones (III) and (IV), depending on the conditions of the chromatographic work‐up.
ChemInform Abstract: Determination of Rare Earth Elements by Ion Pair HPLC with Post‐Column Derivatization Using Arsenazo III
Authors: KUBAN V. , GLADILOVICH D. B. 
Published: May 2016

Abstract(2,7‐bis‐((o‐arsenophenyl)azo)‐1,8‐dihydroxynaphthalene‐3,6‐disulfonic acid).
ChemInform Abstract: Phosphorous Vacancy Nearest Neighbor Hopping (PVNNH) Induced Instabilities in InP Capacitors. Part 1. Experimental. Part 2. Computer Simulation.
Authors: JUANG M. T. , WAGER J. F. , VAN VECHTEN J. A. 
Published: May 2016

AbstractVariable temp. bias‐stress measurements are performed on n‐type InP capacitors.