bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Medium Effects and the Nature of the Rate‐Determining Step in Mannich‐Type Cyclizations.
Authors: MCCANN S. F. , OVERMAN L. E. 
Published: May 2016

AbstractThe effect of solvent and external nucleophiles is studied on the cyclization of the amines (I), (IV) containing a vinyl silane terminator of the amine (VI) containing a butenyl terminator, and of the amines (IX), (XII) containing both a vinyl silane and a butenyl terminator.
ChemInform Abstract: Carbanion Spectroscopy: CH2CN‐.
Authors: MORAN S. , ELLIS H. B. JUN. , DEFREES D. J. , MCLEAN A. D. , ELLISON G. B. 
Published: May 2016

AbstractFrom photoelectron spectra the electron affinities EA(CH2CN) = 1.543 ±0.014 eV and EA(CD2CN) = 1.538 ±0.012 eV are obtained.
ChemInform Abstract: A Phenylcarbene Transfer System.
Authors: CUNICO R. F. , CHU K. S. 
Published: May 2016

AbstractThe (1,1‐dichlorobenzyl)silane (III) is prepared from benzotrichloride (I) and chlorotrimethylsilane (II) in the presence of metallic magnesium and is then treated with potassium fluoride in the presence of a crown ether, forming the chlorophenylcarbene (IV).
ChemInform Abstract: A Facile, Efficient Route to Methyl α‐Hydroxymethylacrylate and Methyl α‐Halomethylacrylates.
Authors: DREWES S. E. , LOIZOU G. , ROOS G. H. P. 
Published: May 2016

AbstractMethyl acrylate (I) is coupled with paraformaldehyde (II) in the presence of diazabicyclooctane to produce a mixture of the hydroxymethylacrylate (III) and the corresponding symmetric ether (IV).
ChemInform Abstract: Synthesis of N‐(E)‐(4‐Methoxystyryl)benzamide (Alatamide).
Authors: GHOSH S. , DATTA D. B. , SEN N. 
Published: May 2016

AbstractIn order to prepare p‐methoxystyrylbenzamide (IX), the imine (I) is allowed to react with benzoyl chloride (II).
ChemInform Abstract: Synthesis of (2‐ or 6‐Thio)‐4‐tert‐butylphenols.
Authors: ZEINALOV A. M. , ASLANOV I. A. , MAMEDOV V. N. , ALIEV A. M. , GUSEINOV R. I. 
Published: May 2016

AbstractThe thioether (II) is obtained by reaction of the phenol (I) with disulfur dichloride and subsequent reduction with zinc.
ChemInform Abstract: Epoxidation Catalyzed by Mn(III) TPPCl Using Dioxygen Activated by a Novel System Containing N‐Hydroxyphthalimide and Styrene.
Authors: MASUI M. , TSUCHIDA K. , KIMATA Y. , OZAKI S. 
Published: May 2016

AbstractMixtures of styrene (I) and cyclohexene (II) are oxidized with molecular oxygen, activated by a system of Mn(III)‐tetraphenylporphyrin chloride, N‐hydroxyphthalimide, and pyridine, to yield styrene oxide (III), benzaldehyde (IV), cyclohexene oxide (V), cyclohexanol (VI), and cyclohexanone (VII).
ChemInform Abstract: Photoaddition of Allylic and Benzylic Groups to 1,1‐Dicyanoethenes Bearing Heterocyclic Substituents by Use of Organic Stannanes.
Authors: MIZUNO K. , TODA S. , OTSUJI Y. 
Published: May 2016

AbstractThe 2‐(2',2'‐dicyanoethenyl)furans or thiophenes (I) are coupled with the allylic stannanes (II) upon photolysis in the presence of phenanthrene to give the homoallylfurans or thiophenes (III).
ChemInform Abstract: Highly Regioselective Synthesis of Trisubstituted Pyrrolidines by 1,3‐Cycloaddition.
Authors: IMAI N. , ACHIWA K. 
Published: May 2016

AbstractThe silylmethylimine (I) is desilylated to form the carbanion salt (II) which undergoes 1,3‐dipolar cycloaddition with the activated olefins (III), yielding the pyrrolidines (IV).
ChemInform Abstract: Cyclic Carbonate Formation from Carbon Dioxide and Oxiranes in the Presence of Organotin Halide‐Complexed Catalysts.
Authors: BABA A. , NOZAKI T. , MATSUDA H. 
Published: May 2016

AbstractThe carboxylation of the oxiranes (I), yielding the cyclic carbonates (III), is investigated in the presence of various catalyst systems consisting of an organotin halide and a phosphorus or antimony compound.
ChemInform Abstract: Studies on 4‐Thiazolidinones. Preparation and Antimicrobial Activity of α‐Phenyl‐2‐(2′,5′‐dihydroxy‐3′‐bromophenyl)‐3‐aryl‐5‐carboxymethyl‐4‐ thiazolidinones, α‐Methyl‐2‐(2′‐hydroxy‐3′‐nitro‐5′‐benzyl)‐3‐aryl‐5‐H/ carboxymethyl‐4‐thiazolidinones, and α‐Methyl‐2‐(2′‐hydroxy‐3′‐nitro‐ 5′‐chlorophenyl)‐3‐aryl‐5‐H/carboxymethyl‐4‐thiazolidinones.
Authors: KALAIYA S. B. , PARIKH A. R. 
Published: May 2016

AbstractThe thiazolidinones (V) are prepared by coupling thioglycolic acid (IVa) or thiomalic acid (IVb) with the anils (III), obtained from the ketones (I) and the aromatic amines (II).
ChemInform Abstract: Synthesis of 3‐Arylcoumarins, 2‐Aroylbenzofurans, and 3‐Aryl‐2H‐1,4‐ benzoxazines Under Phase‐Transfer Catalysis Conditions.
Authors: SABITHA G. , RAO A. V. S. 
Published: May 2016

AbstractThe 2‐hydroxyaryl carbonyl compounds (I) are coupled with the phenacetyl chlorides (II) or the phenacyl bromides (IV) under phase‐transfer conditions to produce the 3‐arylcoumarins (III) or the 2‐aroylbenzofurans (V).
ChemInform Abstract: Synthesis of 6‐(Ethoxymethylenamino)‐1,2,4‐triazolo(3′,4′:5,1)(1,2,4)triazolo(4,3‐a)quinazolin‐7(6H)‐one.
Authors: LIU K.‐C. , HU M.‐K. 
Published: May 2016

AbstractRefluxing the aminohydrazinoquinazoline (I) with triethyl orthoformate (II) yields the title compound (III).
ChemInform Abstract: Chemistry of Silicon‐Sulfur Compounds. Part 47. Protolytic Splitting of the Si‐S Bond of Trialkoxysilanethiols and Preparation of Trialkoxyorganoxysilanes.
Authors: PRZYJEMSKA K. , WOJNOWSKI W. 
Published: May 2016

AbstractThe protolytic splitting of the Si‐S bond of the silanethioles (I) by alcohol (at 20 °C) and phenols (II) (at 70‐100 °C) in the presence of pyridine is investigated.
ChemInform Abstract: Synthesis and Reactivity of Phosphorus Tris(isocyanate).
Authors: KIJIMA I. , WAKESHIMA I. , OSADA T. , HIRADE S. 
Published: May 2016

AbstractPhosphorus tris(isocyanate) (III) is prepared from phosphorus trichloride (I) and sodium cyanate (II) in the presence of various additives.
ChemInform Abstract: Reaction of N,N,N′,N′,N′′,N′′‐Hexamethyl‐N′′′‐trimethylsilylphosphorimidic Triamide with Xenon Difluoride.
Authors: MARTYNOV I. V. , GAFUROV R. G. , USTINOV A. K. , ALEINIKOV N. N. , KASHTANOV S. A. 
Published: May 2016

AbstractReaction of the trimethylsilylphosphorimidic triamide (I) with xenon difluoride (II) gives the N'''‐fluoro compound (III).
ChemInform Abstract: Subvalent Group 14 Metal Compounds. Part 11. Oxidative Addition Reactions of Organic Halides or Acid Anhydrides (Including CH4‐nCln, PhBr, BrN(SiMe3)2, ButCOCl, or (CF3CO)2O) to Some Bivalent Group 14 Metal Amides or Alkyls.
Authors: LAPPERT M. F. , MISRA M. C. , ONYSZCHUK M. , ROWE R. S. , POWER P. P. , SLADE M. J. 
Published: May 2016

AbstractThe tin(II) or germanium(II) amides (I) react with trifluoroacetic anhydride (II), the alkyl(aryl) halides (IV), or the acyl chlorides (VI), forming the adducts (III), (V), or (VII).
ChemInform Abstract: Synthesis, Characterization, and Interconversion of the Niobotungstic Acid Nb2W4O19H3‐, Its Anhydride, and Its Alkyl/Silyl Esters.
Authors: DAY V. W. , KLEMPERER W. G. , SCHWARTZ C. 
Published: May 2016

AbstractProtonation of (I) occurs predominantly at the unique bridging ONb2 O atom and leads to the tetrabutylammonium salt of the title acid (II).
ChemInform Abstract: Oxidation of Molecular Bromine by Uranium Hexafluoride in Acetonitrile. Preparation and Properties of Hexafluorouranates(V) Containing Positive Bromine.
Authors: MCGHEE L. , RYCROFT D. S. , WINFIELD J. M. 
Published: May 2016

AbstractBromine (II) is oxidized with uranium hexafluoride (I) in acetonitrile (III) to form the hexafluorouranate (IV) in which the bromonium ion is bound to an acetonitrile trimere.
ChemInform Abstract: Electrontransfer Barriers in CoN3+ 6/CoN2+ 6 Couples as a Function of the Ligand Structure. Correlations Between the Structure and Redox Reactivity.
Authors: VENTUR D. , WIEGHARDT K. , NUBER B. , WEISS J. 
Published: May 2016

AbstractThe redox reactivity of a series of complexes of the type CoN63+ containing two saturated triamine ligands such as (I)‐(VI) is systematically investigated.
ChemInform Abstract: Dioxygen‐Copper Reactivity: Hydroxylation‐Induced Methyl Migration in a Copper Monooxygenase Model System.
Authors: KARLIN K. D. , COHEN B. I. , JACOBSON R. R. , ZUBIETA J. 
Published: May 2016

AbstractThe addition of O2 to the binuclear Cu(I) complex (III) prepared as shown results in hydroxylation of the ligand with the concomitant migration of the 2‐methyl group on the aromatic ring and loss of one ligand arm giving the isolated complex (IV).
ChemInform Abstract: Rh(III), Pd(II), Pt(IV) and Au(III) Complexes of 2‐Thiopyrimidine Derivatives.
Authors: SANCHEZ SANCHEZ M. P. , SALAS PEREGRIN J. M. , ROMERO MOLINA M. A. 
Published: May 2016

AbstractThe complexes (I)‐(IV) are synthesized by heating at 60 °C equimolar amounts of the ligand with the salts RhCl3·H2O, PdCl2, PtCl4 and HAuCl4, respectively.
ChemInform Abstract: A New Approach to Anellated Butenolides. The Total Synthesis of (.+‐.)‐Isodrimenin (VIII).
Authors: JANSEN B. J. M. , PEPERZAK R. M. , DE GROOT AE. 
Published: May 2016

AbstractThe first synthetic pathway leading to the title compound (±)‐(VIII) follows a literature procedure starting from the decalone (I).
ChemInform Abstract: A Novel Synthesis of Vinblastine Derivatives. Part 4. Synthesis of 20′‐Deethyl‐20′‐deoxyvinblastine and 20′‐Deethyl‐20′‐deoxyvincovaline via 3,Nb‐seco‐Cleavamine Derivatives as Intermediates.
Authors: SCHILL G. , PRIESTER C. U. , WINDHOEVEL U. F. + , FRITZ H. 
Published: May 2016

AbstractThe title intermediates (X) are prepared starting from the diene (I).
ChemInform Abstract: Kalihinols, Multifunctional Diterpenoid Antibiotics from Marine Sponges Acanthella spp.
Authors: CHANG C. W. J. , PATRA A. , BAKER J. A. , SCHEUER P. J. 
Published: May 2016

AbstractThe structures of the kalihinols A‐H and X‐Z, represented by the formulas (I) and (II), are established by physical methods.
ChemInform Abstract: Determination of Surface State Densities from Transient Rotating Ring‐Disc Electrode Measurements Demonstrated on an n‐TiO2 Electrode.
Authors: LINDQUIST S.‐E. , VIDARSSON H. 
Published: May 2016

AbstractIt is demonstrated that the surface state density can be determined by simple ring‐current transient measurements and the equipment for the photoelectrochemical measurements is described in detail.
ChemInform Abstract: Chemistry and Structural Chemistry of Phosphides and Polyphosphides. Part 44. Tricesium Heptaphosphide Cs3P7: Preparation, Structure, and Properties.
Authors: MEYER T. , HOENLE W. + , VON SCHNERING H. G. 
Published: May 2016

AbstractSingle crystals of tricesium heptaphosphide are prepared by annealing stoichiometric mixtures of the elements at 1170 °C (60 h) under argon.
ChemInform Abstract: Absorptiometric and Fluorimetric Study of Solvent Dependence and Prototropism of 2‐Substituted Benzimidazole Derivatives.
Authors: SINHA H. K. , DOGRA S. K. 
Published: May 2016

AbstractA study of the effects of solvents on the absorption and fluorescence spectra of the benzimidazoles (I) and (II) shows that the lowest‐energy transition of (Ia) is of π‐π* character, and that of (Ib) and (II) is of CT character.
ChemInform Abstract: Polymeric Thiolate Complexes of Group 12 Metals. Crystal and Molecular Structures of catena‐(μ‐(3‐Dimethylammonio‐1‐propanethiolate))‐dichlorocadmium(II) and Bis(3‐(dimethylammonio)propyl) Disulfide Tetrabromocadmate(II).
Authors: CASALS I. , GONZALEZ‐DUARTE P. , SOLA J. , FONT‐BARDIA M. , SOLANS J. , SOLANS X. 
Published: May 2016

AbstractThe complexes (III) and (IV) are isolated as a mixture (no yields given).
ChemInform Abstract: The Aluminum‐Bromide‐Catalyzed Adamantane Rearrangement of syn‐ and anti‐Tricyclo(4.2.1.12,5)decane.
Authors: BROSSI M. , GANTER C. 
Published: May 2016

AbstractIn the presence of AlBr3 in CS2 at temperatures below 0 °C, the syn‐tricyclodecane (I) isomerizes exclusively to the anti‐isomer (II) at a higher rate than the latter rearranges to (III).
ChemInform Abstract: Stoichiometry and Kinetics of the Low‐Temperature Oxidation of L2Cu2Cl2 (L: N,N,N′,N′‐Tetraethylethylenediamine) by Dioxygen in Methylene Chloride and Properties of the Peroxocopper Products.
Authors: DAVIES G. , EL‐SAYED M. A. , HENARY M. 
Published: May 2016

AbstractThe products of oxidation of (I) with O2 in CH2Cl2 depend on the reaction temperature.
ChemInform Abstract: Solid State Bromination with the Sulfonium Tribromide Crystals.
Authors: OHASHI T. , MIYOSHI F. , SAWADA Y. 
Published: May 2016

AbstractWhen trans‐stilbene (I) is allowed to react with 1‐methylthianium tribromide (II) in the solid state, meso‐1,2‐dibromo‐1,2‐diphenylethane (III) is formed.
ChemInform Abstract: Olefin Synthesis by Reductive Elimination Reactions of β‐Nitro Sulfides.
Authors: ONO N. , KAMIMURA A. , KAWAI S. , KAJI A. 
Published: May 2016

AbstractThe α‐(nitro)arylalkenes (I) and (III) are converted to the styrenes (II) or stilbenes (IV) by reaction with thiophenol in the presence of sodium sulfide.
ChemInform Abstract: An Extension of the Hurtley Reaction to Heterocyclic Nucleophiles.
Authors: LOWE J. A. III , NEWMAN M. E. 
Published: May 2016

AbstractThe N‐methylisoquinolinedione (I) is coupled with the bromoarenes (II) in the presence of sodium ethoxide and copper powder or copper(I) bromide to produce the 4‐arylisoquinolinediones (III).
ChemInform Abstract: Asymmetric Carbon Dioxide Fixation into Optically Active Propylene Carbonate by the Reactions of Propylene Bromohydrins.
Authors: TAKEICHI T. , OZAKI Y. , TAKAYAMA Y. 
Published: May 2016

AbstractThe bromohydrin (I) is carbonylated in the presence of a chiral cobalt catalyst, yielding the optically active carbonate (III), oxirane (IV), and the regioisomeric bromohydrin (V).
ChemInform Abstract: Synthesis of 2,3,5‐Trihydroxyphenylprop‐1‐ene and Its 4‐Chloro, 6‐Chloro, and 4,6‐Dichloro Derivatives.
Authors: HILL R. A. , MACAULAY G. S. , MACLACHLAN W. S. 
Published: May 2016

AbstractThe starting compounds (I) ‐ prepared from vanillin or 3,5‐dimethoxytoluene ‐ are converted to the phosphonamides (III), which undergo deprotection, cycloelimination and acetylation to give the acetates (Va) and (Vb).
ChemInform Abstract: An Efficient Synthesis of Perfluoroalkyl Ketones Using Perfluoroalkyllithiums.
Authors: UNO H. , SHIRAISHI Y. , SIMOKAWA K. , SUZUKI H. 
Published: May 2016

AbstractThe esters (I) are coupled with perfluoroalkyl iodides (II) in the presence of methyllithium and LiBr to give the perfluoroalkyl ketones (IV) via the intermediates (III).
ChemInform Abstract: α‐Methoxy Ketones by the Reaction of Trimethylsilyl Enol Ethers with Lead Tetraacetate in Methanol.
Authors: MORIARTY R. M. , PRAKASH I. , PENMASTA R. 
Published: May 2016

AbstractThe (het)aryl or tert‐butyl methyl ketones (I) are converted to the corresponding trimethylsilyl enol ethers (III).
ChemInform Abstract: Zinc(0)‐Copper(I) Chloride Promoted Reaction of Methyl Dichlorofluoroacetate with Carbonyl Compounds. A New Efficient Method for the Synthesis of Methyl (Z)‐α‐Fluoro‐α,β‐Unsaturated Carboxylates.
Authors: ISHIHARA T. , KUROBOSHI M. 
Published: May 2016

AbstractMethyl dichlorofluoroacetate (I) and the aldehydes (II) couple in the presence of Zn(0), CuCl, acetic anhydride, and molecular sieves to give the α‐fluoro‐α,β‐unsaturated esters (III).
ChemInform Abstract: α,β‐Unsaturated Orthoesters as Michael Acceptors. The Trityl Salt‐Catalyzed Michael Reaction of α,β‐Unsaturated Orthoesters with Silyl Enol Ethers.
Authors: KOBAYASHI S. , MUKAIYAMA T. 
Published: May 2016

AbstractUnsaturated orthoesters such as (I) are coupled with the silyl enol ethers (II) in the presence of trityl perchlorate as a catalyst to give the adducts (III).
ChemInform Abstract: A New Entry to 1,2,4‐Benzenetriol Congeners.
Authors: OZAKI Y. , KIM S.‐W. 
Published: May 2016

AbstractThe 1‐alken‐3‐ones (Ia) and the α,α‐bis(ethylthio) ester (IIb) or the α,β‐unsaturated esters (Ib) and the bissulfenyl ketone (IIa) undergo cyclocondensation to produce the bis(sulfenyl)cyclohexanediones (III) which are deprotected, forming the trihydroxybenzenes (IV).
ChemInform Abstract: The Effects of Various Additives on the Regioselectivity of the Reactions of Allyl Dithiocarbamate with Aldehydes.
Authors: HAYASHI T. , IKEDA K. , OISHI T. 
Published: May 2016

AbstractThe coupling of the allylic dithiocarbamate (I) with isobutyraldehyde (II) is performed in the presence of various additives to give the hydroxyalkenyl dithiocarbamates (III) and (IV).
ChemInform Abstract: Thermal Decomposition of 7‐Isopropylidene‐2,3‐dioxabicyclo(2.2.1)heptane: Evidence for Allene Oxide and Cyclopropanone Intermediates.
Authors: ERDEN I. , AMPUTCH M. A. 
Published: May 2016

AbstractThermolysis of the bicyclic peroxide (I) produces a mixture of the bridged dioxole (II), the oxirane (III), and the keto aldehyde (IV).
ChemInform Abstract: A Stereoselective Synthesis of cis‐4‐Acetonyl‐1‐benzyl‐3‐ethylpiperidine.
Authors: BONJOCH J. , LINARES A. , GUARDIA M. , BOSCH J. 
Published: May 2016

Abstract1‐Benzyl‐3‐ethyl‐4‐piperidone (III), prepared from the piperidone (I), reacts with diethyl 2‐oxo‐propylphosphonate (IV) to form a mixture of the unsaturated ketones (V) ‐ (VII).
ChemInform Abstract: Diastereoselective Elaboration of the Carbon Skeleton of β‐Hydroxy Esters from Yeast Reductions. Preparation of (2S)‐2‐Hydroxycyclohexane Carboxylic Acids with Three Contiguous Stereogenic Centers.
Authors: SEEBACH D. , HERRADON B. 
Published: May 2016

AbstractThe dioxanone (II), prepared from the carboxycyclohexanol (I) by known methods, reacts with the organocuprates (III) to form the monoalkylated products (IV).
ChemInform Abstract: Reactions of Elemental Sulfur and Selenium with Some Acetylenic Compounds. Formation of Thiophenes and Selenophenes.
Authors: NAKAYAMA J. , YOMODA R. , HOSHINO M. 
Published: May 2016

AbstractTreatment of 3‐butyn‐2‐one (I) with sulfur or selenium leads to the formation of the diacetylthiophenes (IIa) and (IIIa) or the diacetylselenophenes (IIb) and (IIIb).
ChemInform Abstract: A Novel Synthesis of Pyridazinones: Preparation of 3‐(1‐Aryl‐6‐(1H)‐pyridazinon‐3‐yl)‐2(1H)‐quinoxalinones.
Authors: EL ASHRY EL S. H. , EL KILANY Y. , AMER A. 
Published: May 2016

AbstractWittig reaction of the arylhydrazonoglyoxalylquinoxalinones (I) with the phosphorane (II) produces the acrylate derivatives (III).
ChemInform Abstract: A Novel Route for Macroscale Preparation of the Unsubstituted C2B4 Carborane 2,3‐Dicarba‐nido‐hexaborane(8).
Authors: HOSMANE N. S. , ISLAM M. S. , BURNS E. G. 
Published: May 2016

AbstractThe reaction of the nido‐carborane (I) with pure HCl in a 1:3.3 molar ratio in a high‐vacuum stainless steel cylinder produces the known derivative (IV), a mixture of Me3SiCl and (III), and the product (V), which are collected in traps held at ‐45, ‐95, and ‐196 °C. For the separation of the mixture of Me3SiCl and (III) a new procedure is used.
ChemInform Abstract: Cycloaddition Reaction of 2‐Dialkylborylamino‐N‐heterocycles with Ethoxyacetylene.
Authors: DOROKHOV V. A. , KURELLA M. G. , DEKAPRILEVICH M. O. , VORONTSOVA L. G. 
Published: May 2016

AbstractEthoxyacetylene (II) reacts with the dialkylborylaminopyridines (Ia) or the diisopropylborylaminopyrimidine (Ib) to give the (4 + 2)‐cycloaddition products (III).
ChemInform Abstract: Migration of Silicon from Oxygen to Carbon in O‐Trialkylsilyl Ketene Acetals.
Authors: RAUCHER S. , SCHINDELE D. C. 
Published: May 2016

AbstractThe O‐silyl‐O'‐cyclohexyl ketene acetals (III) are prepared from the cyclohexyl acetates (I) and the chlorosilanes (II) in the presence of butyllithium.
ChemInform Abstract: Synthesis of Novel Carbo‐ and Heteropolycycles. Part 6. Reactions of Some Bridgehead‐ and Bridge‐Azides Related to Adamantane with Some Selected Trivalent Phosphorus Compounds.
Authors: EGUCHI S. , TAKEUCHI H. , WATANABE N. 
Published: May 2016

AbstractThe reactivity of the phosphines (IIa) and (IIb) or triethyl phosphite (IIc) towards the bicyclic azides (I) is tested.
ChemInform Abstract: Synthesis and Reactions of (2‐Oxocyclobutyl)diphenylphosphine Oxide.
Authors: OKADA Y. , MINAMI T. , YAHIRO S. , KAKU H. , ISHIYAMA M. 
Published: May 2016

AbstractStarting with the cyclobutenylphosphonium salt (I), the diphenylphosphinylcyclobutanone (IV) is prepared.
ChemInform Abstract: Reductive Telluration of Aliphatic Aldehydes with Hydrogen Telluride. A New Synthesis of Dialkyl Ditellurides.
Authors: KAMBE N. , INAGAKI T. , MIYOSHI N. , OGAWA A. , SONODA N. 
Published: May 2016

AbstractThe (ar)aliphatic aldehydes (Ia) ‐ (If) react with hydrogen telluride generated in situ, producing the ditellurides (III), together with minor amounts of the alcohols (II).
ChemInform Abstract: Dimethylsilylene Insertion into Tantalum‐Hydride Bonds.
Authors: BERRY D. H. , JIANG Q. 
Published: May 2016

AbstractThe dimethylsilyl‐Ta compounds (I) and (II) are obtained by reaction of the hydrides (III), (V), and (VI) with hexamethylsilacyclopropane (IV) according to the scheme.
ChemInform Abstract: Chromium(III) Complexes of N‐Salicylideneamino Acid.
Authors: SHANTHI R. , NAGARAJA K. S. , UDUPA M. R. 
Published: May 2016

AbstractThe reaction of methanolic solution of salicylaldehyde with appropriate DL‐, or DL‐ and L‐amino acids and KOH in water followed by addition of CrCl3 (MeOH, reflux) yields the title complexes (I), containing 0‐2 mol water as hydrate.
ChemInform Abstract: Organometallic Nitrosyl Chemistry. Part 31. Reduction of ((η5‐C5H5)M(NO)I2)2 (M: Mo, W) Dimers by PMe3: Synthesis and Properties of the Novel Complexes M(NO)(PMe3)4I.
Authors: CHRISTENSEN N. J. , HUNTER A. D. , LEGZDINS P. , SANCHEZ L. 
Published: May 2016

AbstractIn the absence of added reducing agent PMe3 reacts with the dimers (I) in a sequential manner leading via the isolable intermediates (V) and (VI) to the new electron‐rich nitrosyl complexes (III).
ChemInform Abstract: Generation of Re2(CO)9(N2) from Re2(CO)10: Identification of Photochemical Intermediates by Matrix Isolation and Liquid‐Noble‐Gas Techniques.
Authors: FIRTH S. , KLOTZBUECHER W. E. + , POLIAKOFF M. , TURNER J. J. 
Published: May 2016

AbstractUV photolysis of Re2(CO)10 in liquid xenon doped with N2 or in an N2 matrix at 20 K generates eq‐Re2(CO)9(N2).
ChemInform Abstract: Dinuclear Complexes of Transition Metals Containing Carbonate Ligands. Part 7. Kinetics and Mechanism of Formation of the (μ‐Carbonato)bis(μ‐hydroxo)bis(triamminecobalt(III)) Ion in Weakly Basic Aqueous Carbonate Solution.
Authors: SADLER G. G. , DASGUPTA T. P. 
Published: May 2016

AbstractThe kinetics of formation of the title complex (III) from the tris‐μ‐hydroxo‐derivative (I) in aqueous buffered carbonate solution is studied spectrophotometrically at 295 nm.
ChemInform Abstract: Synthesis, Structure, and Properties of (CpRu(PR3)2)2(μ‐S2)2+. Effects of Strong π‐Donation in a Disulfur Complex.
Authors: AMARASEKERA J. , RAUCHFUSS T. B. , WILSON S. R. 
Published: May 2016

AbstractThe unusual metathetical replacement of Cl‐ by S results in formation of the title complexes (IIIa)‐(IIIc).
ChemInform Abstract: Enantioselective Methylation of Glycine: Influence of the Structure of the Chiral Nucleofugal.
Authors: DUHAMEL P. , EDDINE J. J. , VALNOT J.‐Y. 
Published: May 2016

AbstractThe lithium enolates (II), prepared from the imino esters (I), react with the optically active methyl sulfates (III) to give α‐alanine (V) via the methylated glycine derivatives (IV).
ChemInform Abstract: Modulated Light Studies of the Electrochemistry of Semiconductors. Theory and Experiment.
Authors: ALBERY W. J. , BARTLETT P. N. , WILDE C. P. 
Published: May 2016

AbstractThe photoelectrochemistry of p‐GaP, n‐CdS, and p‐InP has been studied by using a sinusoidally modulated light source.
ChemInform Abstract: Investigation of SOCl2 Reduction in Prototype Cells by Extraction and Infrared Analysis.
Authors: DAMPIER F. W. , COLE T. A. 
Published: May 2016

AbstractLi/SOCl2 cells have been extracted five times with distilled SOCl2 and the SO2 content of cells discharged at 23 °C, 5 mA/cm2, is determined by quantitative IR analysis to be 86.4% of the theoretically expected SO2 content.
ChemInform Abstract: The Dynamic Behavior of η3‐Allyl Palladium and Platinum Complexes Containing the SnCl3 Ligand.
Authors: GIANOTTI M. , MUSCO A. , SISTI M. , GRASSI M. , GATTI G. 
Published: May 2016

AbstractThe solution behavior of the complexes (I) is studied by 1H, 13C and 31P NMR spectroscopy.