bluuebunny/crossref_metadata_2025_split huggingface dataset:
Photocatalytic properties of PbS/graphene oxide/polyaniline electrode for hydrogen generation
Authors: Shaban Mohamed , Rabia Mohamed , El-Sayed Asmaa M. Abd , Ahmed Aya , Sayed Somaya 
Published: October 2017

AbstractIn this work, roll-graphene oxide (Ro-GO), polyaniline (PANI) nano/microparticles, and PbS nanoparticles were prepared by modified Hammer, oxidative polymerization, and chemical bath deposition methods, respectively. These nano/microstructures were characterized, optimized, and designed to form PbS/Ro-GO/PANI nano/microcomposite. Also, the ratios of PbS and Ro-GO were optimized, and the optimized composition of the used composite was 0.4 g PANI, 0.125 g Ro-GO, and 0.075 g PbS. The band gap values for PANI, PbS, Ro-GO, and PbS/Ro-GO/PANI rocomposite were 3, 1.13, 2.86, (1.16, 2) eV, respectively. Two photoelectrode assemblies, Au/PbS/Ro-GO/PANI and PbS/Ro-GO/PANI/ITO/glass were used for the photoelectrochemical (PEC) hydrogen generation. In the first assembly 45 nm- Au layer was sputtered on the surface of a disk of PbS/Ro-GO/PANI composite. For the second assembly, a disk of PbS/Ro-GO/PANI composite was glued on ITO glass using Ag-THF paste. The lifetime efficiency values were 64.2 and 43.4% for the first and second electrode for 2 h, respectively. Finally, the incident photon-to-current conversion efficiency (IPCE) and photon-to-current efficiency (ABPE) were calculated under monochromatic illumination conditions. The optimum IPCE efficiency at 390 nm was 9.4% and 16.17%, whereas ABPE % efficiency was 1.01% and 1.75% for Au/PbS/Ro-GO/PANI and PbS/Ro-GO/PANI/ITO/glass, respectively.
Electrically Tunable Gap Surface Plasmon-based Metasurface for Visible Light
Authors: Guo Jingjing , Tu Yan , Yang Lanlan , Zhang Ruiwen , Wang Lili , Wang Baoping 
Published: October 2017

AbstractIn this paper, an electrically tunable metasuface is designed for visible regime. The device mainly consists of a V-shaped metallic metasurface, an ITO film, an electro-optic (EO) dielectric and a metal layer fabricated on a silica substrate. A continuous electrical modulation of resonant wavelength has been theoretically demonstrated in the visible range from 555 nm to 640 nm by changing the voltage applied on the EO dielectric from −20 V to 20 V. During the modulation, the steering angle also changes with the selective color. The peak cross-polarized reflectivity is higher than 48% and the bandwidth is narrower than 60 nm. The resonant wavelength shift can be explained by that the refractive index variation of the EO material induces resonance condition changes of the gap surface plasmon (GSP). The results provide a novel design solution for active plasmonic devices, especially for dynamic metadevices.
Impact Of Hypertension versus Diabetes on Cardiovascular and All-cause Mortality in Iranian Older Adults: Results of 14 Years of Follow-up
Authors: Zafari Neda , Asgari Samaneh , Lotfaliany Mojtaba , Hadaegh Amirreza , Azizi Fereidoun , Hadaegh Farzad 
Published: October 2017

AbstractTo evaluate the joint effect of hypertension (HTN) and diabetes (DM) on coronary heart disease (CHD), and stroke event, all-cause, and cardiovascular disease (CVD) mortality in Middle Eastern older adults, 2747 people (1436 women) aged ≥ 50 years, free of CVD at baseline, were categorized into four groups (HTN−/DM−, HTN+/DM−, HTN−/DM+, HTN+/DM+). Multivariate Cox proportional hazard models were run for different outcomes. To compare the impact of HTN versus DM, HTN+/DM− was considered as reference. In a median of 13.9 years, incidence rate of CHD, and stroke event, all-cause and CVD mortality in total population were 19.0, 4.7, 13.5, and 6.4 per 1000 person-years, respectively. The multivariate sex-adjusted hazard ratios (HRs) of HTN−/DM+ for CHD, stroke, all-cause mortality and CVD mortality were 1.19 (confidence interval (CI): 0.9–1.57), 1.07 (CI: 0.63–1.82), 1.62 (CI: 1.2–2.18), and 1.28 (CI: 0.83–1.97); the corresponding HRs for HTN+/DM+ were 1.96 (CI: 1.57–2.46), 1.66 (CI: 1.1–2.52), 2.32 (CI: 1.8–2.98), and 2.6 (CI: 1.85–3.65) respectively. The associations between HTN/DM status with stroke incidence and all-cause mortality were stronger among men than in women (P for interaction <0.05). Compared to HTN+/DM−, HTN−/DM+ increases all-cause mortality by 62%, however, they are not considerably different regarding CHD, stroke incidence and CVD mortality.
Water vapor sorption properties of cellulose nanocrystals and nanofibers using dynamic vapor sorption apparatus
Authors: Guo Xin , Wu Yiqiang , Xie Xinfeng 
Published: October 2017

AbstractHygroscopic behavior is an inherent characteristic of nanocellulose which strongly affects its applications. In this study, the water vapor sorption behavior of four nanocellulose samples, such as cellulose nanocrystals and nanofibers with cellulose I and II structures (cellulose nanocrystals (CNC) I, CNC II, cellulose nanofibers (CNF) I, and CNF II) were studied by dynamic vapor sorption. The highly reproducible data including the running time, real-time sample mass, target relative humidity (RH), actual RH, and isotherm temperature were recorded during the sorption process. In analyzing these data, significant differences in the total running time, equilibrium moisture content, sorption hysteresis and sorption kinetics between these four nanocellulose samples were confirmed. It was important to note that CNC I, CNC II, CNF I, and CNF II had equilibrium moisture contents of 21.4, 28.6, 33.2, and 38.9%, respectively, at a RH of 95%. Then, the sorption kinetics behavior was accurately described by using the parallel exponential kinetics (PEK) model. Furthermore, the Kelvin-Voigt model was introduced to interpret the PEK behavior and calculate the modulus of these four nanocellulose samples.
sRAGE alleviates neutrophilic asthma by blocking HMGB1/RAGE signalling in airway dendritic cells
Authors: Zhang Fang , Su Xin , Huang Gang , Xin Xiao-Feng , Cao E-Hong , Shi Yi , Song Yong 
Published: October 2017

AbstractReceptor for advanced glycation end products (RAGE) plays a role in inflammatory reactions. The soluble form of RAGE (sRAGE) acts as a decoy to inhibit interactions of RAGE with advanced glycation end products such as High mobility group box 1 (HMGB1). We have demonstrated that HMGB1 directs Th17 skewing by regulating dendritic cell (DC) functions in a previous study. However, the protective effects of HMGB1 blockade with sRAGE in the development of neutrophilic asthma remain unclear. Here, we showed that allergen challenge decreased expression of sRAGE in a murine model of neutrophilic asthma, correlating well with neutrophil counts and interleukin (IL)-17 production. When HMGB1 signalling was blocked by intratracheal administration of sRAGE before sensitisation, HMGB1 expression, neutrophilic inflammation, and Th17-type responses were reduced significantly. Anti-asthma effects of sRAGE were achieved by inhibition of RAGE and IL-23 expression in airway CD11c+ antigen-presenting cells. Finally, we showed that sRAGE inhibited Th17 polarisation induced by recombinant HMGB1 (rHMGB1)-activated dendritic cells (DCs) in vitro. Adoptive transfer of rHMGB1-activated DCs was sufficient to restore airway inflammation, whereas transfer of rHMGB1 plus sRAGE-activated DCs significantly reduced neutrophilic inflammation. Thus, sRAGE prevents Th17-mediated airway inflammation in neutrophilic asthma at least partly by blocking HMGB1/RAGE signalling in DCs.
Epigenetics and adaptive phenotypic variation between habitats in an asexual snail
Authors: Thorson Jennifer L.M. , Smithson Mark , Beck Daniel , Sadler-Riggleman Ingrid , Nilsson Eric , Dybdahl Mark , Skinner Michael K. 
Published: October 2017

AbstractIn neo-Darwinian theory, adaptation results from a response to selection on relatively slowly accumulating genetic variation. However, more rapid adaptive responses are possible if selectable or plastic phenotypic variation is produced by epigenetic differences in gene expression. This rapid path to adaptation may prove particularly important when genetic variation is lacking, such as in small, bottlenecked, or asexual populations. To examine the potential for an epigenetic contribution to adaptive variation, we examined morphological divergence and epigenetic variation in genetically impoverished asexual populations of a freshwater snail, Potamopyrgus antipodarum, from distinct habitats (two lakes versus two rivers). These populations exhibit habitat specific differences in shell shape, and these differences are consistent with adaptation to water current speed. Between these same habitats, we also found significant genome wide DNA methylation differences. The differences between habitats were an order of magnitude greater than the differences between replicate sites of the same habitat. These observations suggest one possible mechanism for the expression of adaptive shell shape differences between habitats involves environmentally induced epigenetic differences. This provides a potential explanation for the capacity of this asexual snail to spread by adaptive evolution or plasticity to different environments.
WRKY43 regulates polyunsaturated fatty acid content and seed germination under unfavourable growth conditions
Authors: Geilen Katja , Heilmann Mareike , Hillmer Stefan , Böhmer Maik 
Published: October 2017

AbstractSeed germination and postgerminative growth of Arabidopsis thaliana and various other plant species are arrested in response to unfavourable environmental conditions by signalling events involving the phytohormone abscisic acid (ABA). In this study, we showed that loss of the seed-specific WRKY DNA-BINDING PROTEIN 43 (WRKY43) conferred increased tolerance towards high salt, high osmolarity and low temperature during seed germination in Arabidopsis. The wrky43 loss of function lines displayed increased inhibition of seed germination in response to exogenous ABA; whereas lines overexpressing WRKY43 were more tolerant towards exogenous ABA. Biochemical analysis of fatty acid composition revealed that loss of WRKY43 increased polyunsaturated fatty acid content in seeds, particularly 18:2Δ9,12 and 18:3Δ9,12,15 in triacylglycerols and phospholipids, indicating an important physiological effect on fatty acid desaturation with ramifications for the tolerance of plants to cold and osmotic stress and possibly, for oilseed engineering. Molecular analyses showed that ABA-induced regulation of FUSCA3, ZAT10 and seed storage proteins were absent in the wrky43 mutant. In summary, WRKY43 encodes for a novel positive regulator of ABA-dependent gene regulation and as a potent modulator of fatty acid desaturation and seed filling, which results in increased tolerance to abiotic stress.
Imatinib Alters Agonists-mediated Cytoskeletal Biomechanics in Lung Endothelium
Authors: Wang X. , Bleher R. , Wang L. , Garcia J. G. N. , Dudek S. M. , Shekhawat G. S. , Dravid V. P. 
Published: October 2017

AbstractThe endothelium serves as a size-selective barrier and tightly controls the fluid exchange from the circulation to the surrounding tissues. In this study, a multiplexed microscopy characterization is developed to study the spatio-temporal effects of Abl kinases on endothelial cytoskeletal structure using AFM, SEM, and immunofluorescence. Sphingosine 1-phosphate (S1P) produces significant endothelial barrier enhancement by means of peripheral actin rearrangement. However, Abl kinase inhibition by imatinib reduces rapid redistribution of the important cytoskeletal proteins to the periphery and their association with the cortical actin ring. Herein, it moderates the thickness of the cortical actin ring, and diminishes the increase in elastic modulus at the periphery and cytoplasm. These findings demonstrate that imatinib attenuates multiple cytoskeletal changes associated with S1P-mediated endothelial barrier enhancement and suggest a novel role for Abl kinases in mediating these S1P effects. These observations bridge the gap between molecule dynamics, structure complexity and function connectivity across varied length-scales to improve our understanding on human pulmonary endothelial barrier regulation. Moreover, our study suggests a framework for understanding form-function relationships in other biomechanical subsystems, wherein complex hierarchical organization programmed from the molecular scale to the cellular and tissue levels has an intimate relationship to the overall physiological function.
An early warning system to forecast the close of the spring burning window from satellite-observed greenness
Authors: Pickell Paul D. , Coops Nicholas C. , Ferster Colin J. , Bater Christopher W. , Blouin Karen D. , Flannigan Mike D. , Zhang Jinkai 
Published: October 2017

AbstractSpring represents the peak of human-caused wildfire events in populated boreal forests, resulting in catastrophic loss of property and human life. Human-caused wildfire risk is anticipated to increase in northern forests as fuels become drier, on average, under warming climate scenarios and as population density increases within formerly remote regions. We investigated springtime human-caused wildfire risk derived from satellite-observed vegetation greenness in the early part of the growing season, a period of increased ignition and wildfire spread potential from snow melt to vegetation green-up with the aim of developing an early warning wildfire risk system. The initial system was developed for 392,856 km2of forested lands with satellite observations available prior to the start of the official wildfire season and predicted peak human-caused wildfire activity with 10-day accuracy for 76% of wildfire-protected lands by March 22. The early warning system could have significant utility as a cost-effective solution for wildfire managers to prioritize the deployment of wildfire protection resources in wildfire-prone landscapes across boreal-dominated ecosystems of North America, Europe, and Russia using open access Earth observations.
Differential gene expression of Australian Cricotopus draysoni (Diptera: Chironomidae) populations reveals seasonal association in detoxification gene regulation
Authors: Krosch Matt N. , Bryant Litticia M. , Vink Sue 
Published: October 2017

AbstractUnderstanding the molecular mechanisms of organismal response to human-derived ecosystem change is recognised as a critical tool in monitoring and managing impacts, especially in freshwater systems. Fundamental to this approach is to determine the genes involved in responding to ecosystem change and detect modifications to their expression and activity in natural populations. Potential targets for this approach include well-known detoxification genes that are upregulated in response to stress. Here, we tested whether expression of such genes varied in association with differences in ecosystem health and could be detected in the field. We sampled populations of the freshwater midge, Cricotopus draysoni, from two geographically proximate sites in southeast Queensland, Australia, which differed in their ecosystem health, at multiple time points. We assessed transcriptome-level differential gene expression and predicted greatest differential expression between sites, associated with organismal responses to local physico-chemical factors. In contrast, we observed a clear and dramatic difference in gene expression – including of known detoxification genes – between time points, specifically between periods at the start and end of the austral summer rainfall when in-stream water levels are most different. These data suggest that these waterways experience greatest pollution load when water levels are high following rainfall events.
Compact folded square‐loop antenna for reading near‐field RFID tags in blood sample tracking system
Authors: Lin Y.F. , Liao C.T. , Chen H.M. , Jiang Z.D. 
Published: October 2017

A highly compact (25 × 25 × 0.8 mm3) dual‐band folded square‐loop antenna is proposed for reading near‐field RF identification (RFID) tags. The antenna has a strong and uniform magnetic field in the near‐field zone of the square loop. The side length of the square loop (∼λ/16) generates resonant frequencies in two conventional modes (0.5λ and 1.0λ). Experimental interrogation of a small RFID button tag attached to a blood sample collection tube showed that the antenna has a small interrogation zone (15 × 15 mm2), which avoids unnecessary interrogation. Experiments also showed that with an input power of 25 dBm, the antenna can tag at a distance of up to 40 mm, which confirmed its suitability for reading button‐type RFID tags attached to blood sample collection tubes and other specimen containers.
Compact wideband‐balanced bandpass filter with high‐selectivity and wideband CM suppression
Authors: Shi Jin , Shen Zhidan , Qiang Jun , Cao Qinghua 
Published: October 2017

A wideband‐balanced bandpass filter is presented using two half‐wavelength transmission lines, two coupled lines and one‐stepped impedance stub. Compared to the reported wideband‐balanced bandpass filters, the proposed one shows the advantages of small total length, high‐frequency selectivity and wideband common‐mode (CM) suppression. The bandwidth of CM suppression and differential‐mode transmission, and the positions of transmission zeros are controllable by the parameters. One prototype was designed, fabricated and measured with the total length of 2λg (λg is the guided wavelength at the centre frequency f0), 3 dB fractional bandwidth of 61% and 15 dB CM suppression bandwidth of 3.67f0.
Comparative study on various dielectric barriers and their effect on breakdown voltage
Authors: Foruzan Elham , Akmal Amir A.S. , Niayesh Kaveh , Lin Jeremy , Sharma Desh Deepak 
Published: October 2017

Non‐pressurised air is extensively used as basic insulation medium in high‐voltage equipment. Unfortunately, an inherent property of air‐insulated design is that the system tends to become physically large. On the other hand, the application of dielectric barriers can increase the breakdown voltage and therefore decrease the size of the equipment. In this study, the impact of dielectric barriers on breakdown voltage enhancement is investigated under both direct current (dc) and alternating current (ac) applied voltages. For this purpose, three kinds of dielectric barriers in two different high‐voltage electrode structures are investigated. In the first structure, several experiments are carried out with four different electrode arrangements, keeping the inter‐electrode gap constant while varying the position of the dielectric barrier between the electrodes. In the second structure, the inter‐electrode gap is varied while the high‐voltage electrode is covered with dielectric materials. The influences of different parameters such as inter‐electrode spacing, electric field non‐uniformity factor, and dielectric materials on the breakdown voltage are investigated for applied 50 Hz ac and dc voltages. In addition, a simulation model to approximately calculate the breakdown voltage is proposed and validated with the experimental results.
The diffuse molecular component in the nuclear bulge of the Milky Way
Authors: Riquelme D. , Bronfman L. , Mauersberger R. , Finger R. , Henkel C. , Wilson T. L. , Cortés-Zuleta P. 
Published: October 2017

Context. The bulk of the molecular gas in the central molecular zone (CMZ) of the Galactic center region shows warm kinetic temperatures, ranging from >20 K in the coldest and densest regions (n ~ 104-5 cm-3) up to more than 100 K for densities of about n ~ 103 cm-3. Recently, a more diffuse, hotter (n ~ 100 cm-3, T ~ 250 K) gas component was discovered through absorption observations of H3+. This component may be widespread in the Galactic center, and low density gas detectable in absorption may be present even outside the CMZ along sightlines crossing the extended bulge of the Galaxy.
Aim. We aim to observe and characterize diffuse and low density gas using observations of 3-mm molecular transitions seen in absorption.
Methods. Using the Atacama Large (sub)Millimeter Array (ALMA) we observed the absorption against the quasar J1744-312, which is located toward the Galactic bulge region at (l, b) = (−2°.13, −1°.0), but outside the main molecular complexes.
Results. ALMA observations in absorption against the J1744-312 quasar reveal a rich and complex chemistry in low density molecular and presumably diffuse clouds. We detected three velocity components at ~0, −153, and −192 km s−1. The component at ~0 km s−1 could represent gas in the Galactic disk while the velocity components at −153, and −192 km s−1 likely originate from the Galactic bulge. We detected 12 molecules in the survey, but only 7 in the Galactic bulge gas.
Cervical Intramedullary Schwannoma with Syrinx: Case Report and Review of the Literature
Authors: AlQarni Abdulaziz , AlArifi A. , Alassiri Ali , Kouli Amjed , Abbas M. 
Published: October 2017

AbstractSchwannoma is a nerve sheath tumor originating from the Schwann cell. It is benign in nature and it arises from anywhere where Schwann cells can be found. It is rarely found in the parenchyma of the spinal cord. Intramedullary schwannomas (or neurilemmomas) without evidence of neurofibromatosis are rare spinal cord tumors. Intramedullary schwannoma was first reported in 1932 by Penfield. Our patient presented with neck pain, gradually worsening, weakness in the right upper and lower limbs, numbness in both shoulders, and a decrease in the grasping strength of both hands over a 4-year period. A magnetic resonance imaging of the spine showed a heterogeneously enhancing mass in the cervical spinal cord extending from the C2 to T1 levels with associated hemorrhagic changes. Histologically, the tumor was found to be composed of bland spindle cells with blunt-ended and sometimes wavy nuclei admixed with hyalinized vasculature. Surrounding reactive spinal cord parenchyma with frequent Rosenthal fibers was also observed. Focal Verocay bodies were evident, and with immunohistochemistry, there was diffuse and strong positivity for S100, which is confirmatory for the diagnosis of schwannoma. We report a case of cervical intramedullary schwannoma presented with syringobulbia in a young adult.