bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Double Layer on Silver Single Crystal Electrodes in Contact with Electrolytes Having Anions Slightly Specifically Adsorbed. Part 3. The (111) Surface.
Authors: VALETTE G. 
Published: May 2016

AbstractIn aqueous solutions of NaF, NaClO4 and KPF6, the specific ion adsorption on the (111)surface of silver decreases according to ClO4‐ > F‐ > PF6‐ ≥ O (capacity‐potential measurements).
ChemInform Abstract: Kinetics and Mechanism of “Reduced CO2” Electrooxidation on Electrodispersed Platinum in Different Acid Solutions.
Authors: MARCOS M. L. , GONZALEZ‐VELASCO J. , VARA J. M. , GIORDANO M. C. , ARVIA A. J. 
Published: May 2016

AbstractThe electrooxidation of CO2 electroadsorbates on electrodispersed Pt electrodes is studied in 0.05 M and 1 M HClO4, 0.5 M H2SO4, and 1 M H3PO4 by means of voltammetric and potential step techniques.
ChemInform Abstract: ESR Evidence of Tetracoordinated Mo5+ 4c Species Formed on Reduced Mo/SiO2 Catalysts Prepared by Impregnation
Authors: LATEF A. , AISSI C. F. , GUELTON M. 
Published: May 2016

Abstractwith ammonium heptamolybdate is obtained only after reduction in pure H2 flow at temp. as high as 773 K and subsequent quenching.
ChemInform Abstract: Acid‐Base Dissociation of Surface Hydroxyl Groups on Manganese Dioxide in Aqueous Solutions.
Authors: TAMURA H. , ODA T. , NAGAYAMA M. , FURUICHI R. 
Published: May 2016

AbstractThe surface charge on MnO2 suspended in NaNO3 solutions is measured (titration with HNO3) as a function of pH and ionic strength.
ChemInform Abstract: Structural, Surface, and Catalytic Properties of Bismuth Molybdovanadates Containing Foreign Atoms. Part 4. Surface Characterization and Redox Behavior of Iron‐Containing Bismuth Molybdovanadate Catalysts by X‐Ray Photoelectron Spectroscopy.
Authors: GAZZOLI D. , ANICHINI A. , DE ROSSI S. , INVERSI M. , LO JACONO M. , PORTA P. , VALIGI M. 
Published: May 2016

AbstractThe results of studies of the surface properties and the redox behavior of multicomponent oxide catalysts with scheelite structure having the general formula Bi1‐x/3□x/3‐yMy(V1‐xMox‐yFey)O4 (M: Fe or Bi, □: cation vacancies), before and after exposure to H2, propene, or a propene/O2 mixture, point to different reactivities toward these reactants.
ChemInform Abstract: Fluorescence of Cyclotetrasilanes in Rigid Glass at 77 K, a Remarkably Large Stokes Shift.
Authors: SHIZUKA H. , MURATA K. , ARAI Y. , TONOKURA K. , HIRATSUKA H. , MATSUMOTO H. , NAGAI Y. 
Published: May 2016

AbstractThe fluorescence properties are dependent on the molecular structures, planar (I) and bent forms (II) of the compounds.
ChemInform Abstract: Comments on the Molecular Structure and Bonding in W4Cl(O)(OiPr)9 and W4(O)(OiPr)10; Analogies with Tetranuclear Carbonyl Clusters.
Authors: CHISHOLM M. H. , FOLTING K. , HAMMOND C. E. , HUFFMAN J. C. , MARTIN J. D. 
Published: May 2016

AbstractThe discovery of the 12‐electron clusters (I) (by‐product in the synthesis of W4H2(OiPr)14) and (II) (by‐product in the thermal decomposition of W4(OiPr)12 in hydrocarbon solvents) has afforded insights into the complementary bonding in clusters of early and late transition‐metals with alkoxide and carbonyl ligands, respectively.
ChemInform Abstract: Redox Potentials and Related Thermodynamic Parameters of (Diamino polycarboxylato)metal(III/II) Redox Couples.
Authors: OGINO H. , NAGATA T. , OGINO K. 
Published: May 2016

AbstractTwenty‐three title complexes with the metals V, Cr, Fe and Ru and the diamino polycarbonic acids (I) and (II) are investigated and their electrochemical and thermodynamic data are determined.
ChemInform Abstract: Chlorocarbon Activation: Catalytic Carbonylation of Dichloromethane and Chlorobenzene.
Authors: HUSER M. , YOUINOU M.‐T. , OSBORN J. A. 
Published: May 2016

AbstractCatalytic carbonylation of the type dichloromethane → ketene, and chlorobenzene → benzoic acid esters or benzaldehyde (the last by presence of alcohols or H2) is possible with Pd complexes such as (III), although the turnover numbers are still small.
ChemInform Abstract: α‐Hydroxy Esters as Chiral Reagents: Asymmetric Synthesis of 2‐Arylpropionic Acids.
Authors: LARSEN R. D. , CORLEY E. G. , DAVIS P. , REIDER P. J. , GRABOWSKI E. J. J. 
Published: May 2016

AbstractThe asymmetric transformation of racemic 2‐arylpropionic acids such as ibuprofen (I) into either their (S)‐ or (R)‐enantiomers is reported, the key step being the addition of a chiral alcohol such as (IV) or amine to the ketene (III) derived from the acid.
ChemInform Abstract: 1,2‐Addition of Activated Vinyl Carbanions to α,β‐Unsaturated Carbonyls.
Authors: DREWES S. E. , EMSLIE N. D. , KHAN A. A. , ROOS G. H. P. 
Published: May 2016

AbstractBase‐mediated coupling of the unsaturated aldehydes (I) with methyl acrylate (II) produces moderate yields of the 1,2‐adduts (III).
ChemInform Abstract: A Stereocontrolled Cyclopentenone Synthesis via Cycloaddition.
Authors: TROST B. M. , SEOANE P. , MIGNANI S. , ACEMOGLU M. 
Published: May 2016

AbstractThe palladium‐catalyzed methylenecyclopentanellation of the unsaturated sulfones (I) proceeds with high diastereoselectivity to give the isomers (III) as main products, the deprotected alcohols (V) of which undergo ozonolysis to give the fused cyclopentenones (VI).
ChemInform Abstract: Isomerization of Fluorinated β‐Aminovinylthiones and β‐Aminovinyl Ketones.
Authors: FILYAKOVA V. I. , BUSYGIN I. G. , PASHKEVICH K. I. 
Published: May 2016

AbstractA hitherto unknown and irreversible isomerization of the title compounds (I) with geminal amino and trifluoromethyl groups is observed, which yields the products (II).
ChemInform Abstract: The Photochemical Nucleophile‐Olefin Combination, Aromatic Substitution Reaction: Methanol‐α‐ and β‐Pinene‐1,4‐Dicyanobenzene. The Photo‐NOCAS Reaction. Part 3.
Authors: ARNOLD D. R. , DU X. 
Published: May 2016

AbstractTo get more insight into the mechanism of the photo‐NOCAS reaction studied earlier with 1‐methylcyclohexene as the olefinic substrate, now α‐ (II) and β‐pinene (VI) are used.
ChemInform Abstract: Gas‐Phase Base‐Induced Elimination Reactions in Onium Intermediates. Part 1. Competitive Substitution and Elimination Mechanisms in the Attack of Amines on Diethylmethyloxonium Ions.
Authors: OCCHIUCCI G. , SPERANZA M. , DE KONING L. J. , NIBBERING N. M. M. 
Published: May 2016

AbstractA study using Fourier transform ion cyclotron resonance MS indicates that the branching ratio between elimination and SN2 substitution is enhanced by the increase in the base strength or in the excitation energy of encounter between the oxonium ion (I) and the amine such as (II), NMe3, and NEt3.
ChemInform Abstract: Cyclobutane as a General Ferromagnetic Coupling Unit. Design and Synthesis of a New, Hydrocarbon Quintet.
Authors: NOVAK J. A. , JAIN R. , DOUGHERTY D. A. 
Published: May 2016

AbstractThe synthesis is described by a scheme (no yields, no further details given except that the syn isomer of the adduct obtained from (IV) and (V) is unstable to hydrogenation conditions).
ChemInform Abstract: Synthesis of Quassinoids. Part 8. Swern Oxidation of α‐Ketols to α‐Diketones.
Authors: KAWADA K. , GROSS R. S. , WATT D. S. 
Published: May 2016

AbstractVarious acyloins such as (I) are treated with dimethyl sulfoxide and trifluoroacetic anhydride to form the corresponding diketones such as (II) after quenching with triethylamine.
ChemInform Abstract: Transformation of Compounds Containing C‐N Bonds on Heterogeneous Catalysts. Part 4. Hydrogenolysis of β‐Lactams on Nickel. A New Method for the Preparation of 1,3‐Amino Alcohols.
Authors: BARTOK M. , GERA L. , GOENDOES G. + , MOLNAR A. 
Published: May 2016

AbstractThe fused β‐lactams (I) are reduced with LiAlH4 to produce the azetidines (II).
ChemInform Abstract: Redox Potentials and Charge Transfer Spectra of Catecholate and Semiquinone Adducts of a Cobalt‐Tetraazamacrocyclic Complex.
Authors: BENELLI C. , DEI A. , GATTESCHI D. , PARDI L. 
Published: May 2016

AbstractIn order to determine the conditions under which the different oxidation states of metals and ligands are stabilized, the electrochemistry and electronic spectra of the complexes (I) are investigated.
ChemInform Abstract: Synthesis of Z‐ and E‐3,4‐Dimethylhex‐3‐ene‐1,6‐diols.
Authors: ROBERGE J. Y. , DESLONGCHAMPS P. 
Published: May 2016

AbstractThe starting dibromodimethylbutenes (V) are prepared by either cleavage of the anhydride (I), followed by reduction and substitution of OH for bromide, or by bromination of the butadiene (VI).
ChemInform Abstract: Reaction of the Methyl Esters of Acetylenic Hydroxy Acids with Ammonia.
Authors: MAL'KINA A. G. , SKVORTSOV YU. M. , GRITSA A. I. , GROMKOVA R. A. , TROFIMOV B. A. 
Published: May 2016

AbstractAgainst all expectations the reaction between the title compounds (I) and liquid ammonia (II) proceeds regiospecifically to afford the amides (III) in high yields.
ChemInform Abstract: Synthesis of 2‐Chloroacetyl‐1,3‐cyclohexanediones and Their Reactions with Nucleophilic Reagents.
Authors: PSHENICHNYI V. N. , GULYAKEVICH O. V. , KHRIPACH V. A. 
Published: May 2016

AbstractThe reaction between the 1,3‐cyclohexanediones (I) and chloroacetyl chloride (II) and subsequent AlCl3‐catalyzed rearrangement of the intermediary enol chloroacetates yields the hitherto unknown title compounds (III), whose enolized tautomers are stabilized by strong intramolecular hydrogen bonds as is shown in the scheme.
ChemInform Abstract: A Facile and Direct Conversion of Aryl Acetate to Alkyl Aryl Ether.
Authors: YAMASHITA A. , TOY A. 
Published: May 2016

AbstractIn order to prepare naturally occurring furochromones, the acetoxybenzofurans (I) and (IV) are treated with excess methyl iodide (II) and sodium hydride in the presence of HMPA to yield directly the methoxy analogues (III) and (V) as the main products.
ChemInform Abstract: Novel Reaction of Nitrile Oxides with an Azomethine Fragment.
Authors: ANDRIANOV V. G. , ROZHKOV E. N. , EREMEEV A. V. 
Published: May 2016

AbstractThe reaction between the formaldehyde hydrazone (II) and various nitrile oxides, generated in situ from the chlorooximes (I), affords the open‐chain compounds (III) instead of the expected 1,2,4‐oxadiazoles.
ChemInform Abstract: Facile Preparation of 6‐Bromopyridine‐2‐carboxamide and Pyridine‐2,6‐dicarboxamide: Partial Aminocarbonylation of 2,6‐Dibromopyridine.
Authors: HORINO H. , SAKABA H. , ARAI M. 
Published: May 2016

AbstractThe title compounds (IV) and (V) or (VII) are prepared by the palladium‐catalyzed aminocarbonylation of 2,6‐dibromopyridine (I) with carbon monoxide (III) and the primary amines (II) or (VI).
ChemInform Abstract: (‐)‐α‐Phenylethylamide of 2′,4,4′‐Trinitrobiphenyl‐2‐carboxylic Acid as a Chiral Electron Acceptor.
Authors: IL'INA I. G. , IVANOVA E. V. , ANDRIEVSKII A. M. , POPLAVSKII A. N. , POTAPOV V. M. 
Published: May 2016

AbstractThe hitherto unknown title compound (‐)‐(III) is prepared by Schotten‐Baumann reaction between the aroyl chloride (I) and (‐)‐α‐phenylethylamine (‐)‐(II).
ChemInform Abstract: Alkylation of N‐(1‐Anthraquinonyl)ureas and Their Cyclization into Anthra(1,2‐d)imidazolinones.
Authors: SAVEL'EV V. A. , LOSKUTOV V. A. 
Published: May 2016

AbstractTreatment of the N‐anthraquinonylureas (Ia) ‐ (Ic) in the presence of the alkyl iodides (II) gives the N'‐akylation products (IIIa) ‐ (IIId).
ChemInform Abstract: Preparation, Characterization, and Chemistry of Cyclic F4S=CCF2OSO2.
Authors: WINTER R. , PEYTON D. H. , GARD G. L. 
Published: May 2016

AbstractTreatment of sultone (I) with base F3B·NEt3 under a variety of conditions always leads to the same mixture of (II) + (III) from which (II) can be removed by addition of finely ground and thoroughly dried CsF (IV) (to give salt (V); high chemical and thermal stability; extreme solubility in either acetone or MeCN, but virtual insolubility in CH2Cl2).
ChemInform Abstract: An Easy Approach to Prepare Naphtho(2,3‐b)furan‐4,9‐diones.
Authors: FERREIRA V. F. , PINTO A. V. , PINTO M. C. F. R. , DA CRUZ M. C. , CLARINO A. 
Published: May 2016

AbstractCoupling of the hydroxynaphthoquinone (I) with the butanal (II) gives the butenylated derivative (III).
ChemInform Abstract: Electrochemical Oxidation of 2,3‐Diphenyl‐6‐methylindole in Acetonitrile. General Oxidation Mechanism in a Series of Aryl‐ and Alkyl‐Substituted Indoles.
Authors: LONGCHAMP S. , BARBEY G. , GRANGER P. 
Published: May 2016

AbstractAnodic oxidation of the indole (I) results in the formation of the dimer (II) as one of the reaction products.
ChemInform Abstract: Sulfonium Salts and Sulfonium Ylides of Pyrazoles.
Authors: WENDEBOURG H. H. , HARTKE K. 
Published: May 2016

AbstractThe pyrazolines (I), (IV), and (VII) react with the sulfoxides (II) in the presence of TFA to give the sulfonium ylides (III) or sulfonium salts (VI) and (VIII).
ChemInform Abstract: Synthesis of 1,5‐Disubstituted Imidazoles Including an Imidazole Analogue of Prostaglandin from 4(5)‐Hydroxymethylimidazole.
Authors: AMINO Y. , ETO H. , EGUCHI C. 
Published: May 2016

AbstractThe imidazole (III), prepared by silylation of the hydroxymethylimidazole (I), is deprotonated and subsequently treated with the bromides (IV) to produce a mixture of the N‐alkylated imidazoles (V) and (VI).
ChemInform Abstract: Synthesis of 4‐Amino‐3‐(p‐chlorophenyl)‐5‐(β‐aminoethyl)thioisoxazole.
Authors: DANNHARDT G. , OBERGRUSBERGER I. 
Published: May 2016

AbstractThe dioxime (I) is oxidized with hypochlorite to give the furoxane (II) as the main product.
ChemInform Abstract: Synthesis of Substituted Isoxazolidines from N‐Substituted Hydroxylamines and α,β‐Unsaturated Ketones.
Authors: BEZHAN I. P. , ZELENIN K. N. , SVIRIDOVA L. A. , MOTORINA I. A. , ERSHOV A. YU. , GOLUBEVA G. A. , BUNDEL' YU. G. 
Published: May 2016

AbstractMethyl vinyl ketone (I) is coupled with phenylhydroxylamine (II) to give the hydroxyaminobutanone (III) and the isoxazolidine (IV).
ChemInform Abstract: Facile Regioselective Synthesis of 2‐Methylfuro(3,2‐c)(1)benzopyran‐4‐one and 2‐Methylfuro(2,3‐c)(1)benzopyran‐4‐one.
Authors: MAJUMDAR K. C. , KHAN A. T. , DAS D. P. 
Published: May 2016

AbstractThe furobenzopyranones (II) and (V) are prepared by various methods.
ChemInform Abstract: Electrochemical Coupling of Halogenated N‐Heteroaromatic Compounds with Carbon Dioxide and Acetone in a Diaphragmless Cell.
Authors: ZYLBER N. , DRUILHE A. , ZYLBER J. , PERICHON J. 
Published: May 2016

AbstractBromopyridines such as (I) and chloromethylpyridines such as (IV) are electrochemically coupled with carbon dioxide (II) to give the corresponding carboxylic acids (III) and (V).
ChemInform Abstract: Synthesis and Alkylation of 4,6‐Diphenyl‐3‐thiocarbamoyl‐3,4,5,6‐tetrahydropyridin‐2(1H)‐one and 4,6‐Diphenyl‐3‐thiocarbamoyl‐3,4‐dihydropyridin‐2(1H)‐one.
Authors: KRAUZE A. A. , LIEPIN'SH E. E. , DUBUR G. YA. 
Published: May 2016

AbstractChalcone (I) reacts with monothiomalonic diamide (II) to give the hydroxytetrahydropyridinone (III) which is dehydrated, producing the dihydropyridinone (IV).
ChemInform Abstract: A Facile Synthesis of 1,2,3,4‐Tetrahydroisoquinolines Through Cyclization of O,N‐Acetals. Part 2. Syntheses of Isoquinolinequinone Antibiotics.
Authors: SAITO N. , KAWAKAMI N. , YAMADA E. , KUBO A. 
Published: May 2016

AbstractThe amines (I) and (IX) are converted into the tetrahydroisoquinolines (V) and (XI) by reaction with the aldehydes (II) and the alcohols (III) via the unstable N,O‐acetals (IV) and (X).
ChemInform Abstract: Synthesis and Benzodiazepine Receptor Affinities of Rigid Analogues of 3‐Carboxy‐β‐carbolines: Demonstration that the Benzodiazepine Receptor Recognizes Preferentially the s‐Cis Conformation of the 3‐Carboxy Group.
Authors: DOREY G. , POISSONNET G. , POTIER M.‐C. , PRADO DE CARVALHO L. , VENAULT P. , CHAPOUTHIER G. , ROSSIER J. , POTIER P. , DODD R. H. 
Published: May 2016

AbstractThe (bromomethyl)indolopyridine (I) reacts with KCN (II) to give the corresponding nitrile which is then hydrogenated and cyclized, forming the lactam (III).
ChemInform Abstract: 1,2‐Dioxolane versus 1,2‐Dioxane Formation in the Cyclization of an α,ω‐Diene Hydroperoxide Under Polar and Free Radical Conditions.
Authors: BLOODWORTH A. J. , CURTIS R. J. , MISTRY N. 
Published: May 2016

AbstractThe mesylate (V), prepared from vinyloxirane (I), reacts with hydrogen peroxide to give 3‐hydroperoxymethylhexa‐1,5‐diene (VI).
ChemInform Abstract: 2,4‐Diamino‐5‐benzylpyrimidines and Analogues as Antibacterial Agents. Part 11. Quinolylmethyl Analogues with Basic Substituents Conveying Specificity.
Authors: DAVIS S. E. , RAUCKMAN B. S. , CHAN J. H. , ROTH B. 
Published: May 2016

AbstractAs key precursors of quinolylmethylpyrimidines such as (XI), the aldehydes (VII) are prepared from the quinolones (I) as outlined in the reaction scheme.
ChemInform Abstract: An Inexpensive, Efficient Synthesis of 1‐Methylxanthine.
Authors: BLACK T. H. , GATTO C. 
Published: May 2016

AbstractO‐methylisourea hydrochloride (III), generated from cyanamide (I), undergoes cyclocondensation with the cyanoacetate (IV), forming the iminopyrimidinone (V).
ChemInform Abstract: A Short and Efficient Preparation of 2‐Trimethylsilylmethyl‐2‐propen‐1‐ol.
Authors: AGNEL G. , MALACRIA M. 
Published: May 2016

AbstractPropargyl alcohol (I) is converted to the (bromomethyl)dimethylsilyl ether (III) which undergoes radical‐induced cyclization, forming the intermediate oxasilacyclopentane (IV).
ChemInform Abstract: An Efficient Method for Preparation of Trimethylsilylethylene Oxide and Some Other Trimethylsilyloxiranes.
Authors: JANKOWSKI P. , MASNYK M. , WICHA J. 
Published: May 2016

AbstractThe 1‐(trimethylsilyl)alkenes (I) are consecutively treated with NBS in perchloric acid/dioxane and aqueous sodium hydroxide, forming the epoxysilanes (II).
ChemInform Abstract: Lewis Base Properties of 1,5‐Diphosphadithiatetrazocines: Crystal and Molecular Structures of 1,5‐Ph4P2N4S2Me+CF3SO‐ 3.
Authors: CHIVERS T. , DENES G. Y. , LIBLONG S. W. , RICHARDSON J. F. 
Published: May 2016

AbstractThe behavior of the 1,5‐diphosphadithiatetrazocine (I) toward Lewis and Bronsted acids is investigated.
ChemInform Abstract: Synthesis and Nuclear Magnetic Resonance Spectroscopic Properties of Some 5,10‐Dihydrophenophosphazine Derivatives.
Authors: SKOLIMOWSKI J. J. , QUIN L. D. , HUGHES A. N. 
Published: May 2016

AbstractDiphenylamine (I) reacts with PCl3 (II) to give the phosphazine oxide (IV) after alkaline hydrolysis of the intermediate (III).
ChemInform Abstract: Diarylselenium Trifluoroacetates and Chloro(trifluoroacetates): Preparation and Characterization.
Authors: KHAJURIA R. , SINGH S. , BHASIN K. K. , VERMA R. D. 
Published: May 2016

AbstractThe diarylselenium dichlorides (I) react with silver trifluoroacetate (II) to give the diarylselenium trifluoroacetates (III) or (IV) depending on the ratio of the reactants.
ChemInform Abstract: Organolanthanoids. Part 16. Organometallic Lanthanoid Compounds. Part 51. Coordination of a Novel Organoytterbium(II) Ligand System with Dimethylplatinum(II); Crystal Structure Analysis of the Resulting Heterobimetallic Complex.
Authors: DEACON G. B. , DIETRICH A. , FORSYTH C. M. , SCHUMANN H. 
Published: May 2016

AbstractHeterobimetallic complexes are of interest because interaction of their metal centers can lead to unusual catalytic properties, e.g. in the redox catalysis.
ChemInform Abstract: Molybdenum with Hard‐Soft Donor Ligands. Part 2. Molybdenum(VI), ‐(V), and ‐(IV) Oxo Complexes with Tridentate Schiff Base Ligands.
Authors: PUROHIT S. , KOLEY A. P. , PRASAD L. S. , MANOHARAN P. T. , GHOSH S. 
Published: May 2016

AbstractThe polymeric cis‐dioxo‐Mo(VI) complexes (III) prepared as shown can be converted into the polymeric oxo‐Mo(IV) analogues (VI) by oxo abstraction with PPh3.
ChemInform Abstract: Molybdenum Tricarbonyl Complexes of Tricyclic Trisaminomethane Derivatives; Synthesis and Structural Studies.
Authors: VAN KOUWENBERG S. P. , WONG E. H. , WEISMAN G. R. , GABE E. J. , LEE F. L. , JACKSON P. 
Published: May 2016

AbstractThe unusually stable ligands (I) afford the title compounds (III), which are the first transition‐metal complexes of these triaza ligands.
ChemInform Abstract: Monomeric Rhenium(IV) Phenoxides and Their Development from Mononuclear Rhenium Halides with Oxygen and Sulfur Donor Ligands.
Authors: GARDINER I. M. , BRUCK M. A. , WEXLER P. A. , WIGLEY D. E. 
Published: May 2016

AbstractThe homoleptic phenoxide complexes (IIIa) (space group P21/c, Z=4) and (IIIb) are prepared according to the scheme.
ChemInform Abstract: Complexes with an η2‐μ2‐SiO Bridge. Structure of the Bimetallic Cyclic Complex (Fe(CO)3(μ‐Si(OMe)2OMe)(μ‐dppm)PdCl) (Fe‐Pd).
Authors: BRAUNSTEIN P. , KNORR M. , TIRIPICCHIO A. , TIRIPICCHIO‐CAMELLINI M. 
Published: May 2016

AbstractThe diphosphine‐ and O‐Si‐bridged dinuclear complexes (III) are obtained according to the scheme.
ChemInform Abstract: The Synthesis and X‐Ray Crystal Structure of the Monodentate (S) Thiosemicarbazide and Thiosemicarbazone Complexes (Fe(CO)2L(η5‐C5H5))(PF6).
Authors: CAMPBELL M. J. M. , MORRISON E. , ROGERS V. , BAKER P. K. , POVEY D. C. , SMITH G. W. 
Published: May 2016

AbstractSeven complexes of type (III) and an analogous complex containing the thiosemicarbazide ligand are prepared.
ChemInform Abstract: Novel Chiral Trinuclear and Symmetric Tetranuclear Imidazolate‐Bridged Cobalt(III) Complexes of a Synthetic Analogue of Bleomycin.
Authors: BROWN S. J. , OLMSTEAD M. M. , MASCHARAK P. K. 
Published: May 2016

AbstractAttempts to synthesize the Co(III) complex of the compound (I), a designed ligand that mimics a major portion of the metal‐chelating locus of the antitumor drug Bleomycin, afford the two novel imidazolate‐bridged trimeric and tetrameric complexes (IIIa) (space group R3, Z=12) and (IIIb) (P4/n, Z=2).
ChemInform Abstract: Oxamidato Complexes. Part 1. A Study of the Formation of Complexes Between Copper(II) and H2pmox (H2pmox: N,N′‐Bis(2‐pyridylmethyl)oxamide). Synthesis, Crystal Structure, and Magnetic Properties of the Alternating‐Chain Compound (Cu2(pmox)(H2pmox)(H2O)2)(NO3)2·8 H2O.
Authors: LLORET F. , JULVE M. , FAUS J. , JOURNAUX Y. , PHILOCHE‐LEVISALLES M. , JEANNIN Y. 
Published: May 2016

AbstractThe complexing of Cu(II) by the title ligand H2L is investigated by potentiometry in aqueous solutions.
ChemInform Abstract: Preparation and Characterization of the Monomeric Copper(II) Siloxide Complex Cu(OSi(OCMe3)3)2(py)2.
Authors: MCMULLEN A. K. , TILLEY T. D. , RHEINGOLD A. L. , GEIB S. J. 
Published: May 2016

AbstractThe monomeric copper(II) siloxide complex (I) (space group P21/n; Z=4) is unusual, since copper(II) alkoxides are generally highly associated and insoluble.
ChemInform Abstract: vic‐Dioximate Complexes of Silver(III).
Authors: KIRSCHENBAUM L. J. , PANDA R. K. , BORISH E. T. , MENTASTI E. 
Published: May 2016

AbstractThe bis‐chelate complexes (I) of Ag(III) are prepared by direct mixing (Ag(OH)4)‐ and the dioxime ligands in alkaline solutions and characterized by UV/VIS spectra.
ChemInform Abstract: Clusters Containing Carbene Ligands. Part 6. The Synthesis of Higher Nuclearity Metal Carbene Cluster Complexes by Carbene Ligand Transfer. The Synthesis and Structures of (Ru4(CO)10(C(Ph)NMe2)(μ4‐S)2) and (Ru4(CO)10(C(Ph)NMe2)(μ4‐S)(μ5‐S)(W(CO)5)).
Authors: ADAMS R. D. , BABIN J. E. , WANG J.‐G. 
Published: May 2016

AbstractThe title complexes (III) and (IV) both crystallize in P21/n with Z=4.
ChemInform Abstract: Synthesis of a Key Intermediate in the Total Synthesis of Insect Antifeedant Clerodanes.
Authors: VADER J. , DODDEMA L. L. , PEPERZAK R. M. , DE GROOT A. , SMITS J. M. M. , BEURSKENS P. T. 
Published: May 2016

AbstractThe aldehyde (XV) is considered as the key intermediate in the synthesis of dihydroclerodin (XVI).
ChemInform Abstract: Epoxidation of 3β‐Acetylamino and 3β‐Hydroxy Derivatives of α‐Murolene.
Authors: RUKAVISHNIKOV A. V. , TKACHEV A. V. 
Published: May 2016

AbstractIt is known that the epoxidation of α‐murolene (I) proceeds with neither regio‐ nor stereoselectively.