bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis of a New Family of Water‐Soluble Clusters: Ru3(CO)12‐xLx (x = 1‐3), Os3(CO)10L2, and Ir4(CO)9L3 (L = Trisodium Salt (Hydrated) of Tris(m‐sulfonatophenyl)phosphine).
Authors: FONTAL B. , ORLEWSKI J. , SANTINI C. C. , BASSET J. M. 
Published: May 2016

AbstractThe title clusters are prepared in 70‐95% yield by thermal CO‐substitution of Ru3(CO)12 or Ir4(CO)12 in refluxing MeOH, or by substitution of acetonitrile in M3(CO)12‐x(NCMe)x (M: Ru, x = 1, 2; M: Os, x = 2) at 0 or 40 °C in acetonitrile‐methoxyethanol with stoichiometric amounts of L. Activation of Ru3(CO)12 by Me3NO or (N(PPh3)2)X (X: Cl, OAc) in the presence of L also leads to the Ru cluster (x = 3).
ChemInform Abstract: C‐C Activation of Organic Small Ring Compounds by Rearrangement of Cycloalkylhydridorhodium Complexes to Rhodacycloalkanes. Synthesis of Metallacyclobutanes, Including One with a Tertiary M‐C Bond, by Nucleophilic Addition to π‐Allyl Complexes.
Authors: PERIANA R. A. , BERGMAN R. G. 
Published: May 2016

AbstractGeneration of the coordinatively unsaturated fragment (II) at ‐60 °C in cyclopropane, 1,1‐dimethylcyclopropane, or cyclobutane by thermal decomposition of the hydridoneopentyl‐Rh complex (I) as shown, or by photolysis of Cp*(Me3P)RhH2, results only in C‐H bond insertion to yield the hydridocycloalkyl‐Rh complexes (III).
ChemInform Abstract: Synthesis of 5α‐Androstane‐3β,14β,17β‐triol.
Authors: SCHUBERT G. , TRESSELT D. , WUNDERWALD M. 
Published: May 2016

AbstractThe biologically interesting title compound (IV) is synthesized starting from the steroid (Ia) which is transformed to (Ib) by reaction with phenylisocyanate.
ChemInform Abstract: Reaction of xylo‐Pentodialdo‐1,4‐furanose and 2‐Methyl‐2‐propanethiol.
Authors: APARICIO F. J. L. , BENITEZ F. Z. , GONZALEZ F. S. 
Published: May 2016

AbstractReaction of the furanose (I) with tert‐butylthiol (II) yields various heterocyclic derivatives which are separated by chromatography after acetylation to the acetates (III) ‐ (VI).
ChemInform Abstract: Studies on Heterocyclic Analogues of Azulene. Part 15. Synthesis of Cycloheptimidazole β‐Ribonucleosides and Cyclohepta(b)pyrrole α‐ and β‐Arabinonucleosides.
Authors: NISHIWAKI T. , FUKUI T. 
Published: May 2016

AbstractThe compounds (Va) are prepared by Vorbrüggen's procedure from (I) using a Lewis catalyst.
ChemInform Abstract: Formation and Crystallization in the Yttrium Aluminosilicate Glasses Containing Zinc Oxide.
Authors: MAKISHIMA A. , KUBO H. , KOTANI K. , TSUTSUMI M. , ASAMI M. 
Published: May 2016

AbstractThe glass formation in the Y2O3‐ZnO‐Al2O3‐SiO2 system, particularly at Y2O3:Al2O3 = 1, has been studied and densities, thermal expansion coefficients, and Vickers hardnesses of the glasses have been measured.
ChemInform Abstract: 2p Electron Binding Energies for the Sulfur Atoms in Metal Polysulfides.
Authors: TERMES S. C. , BUCKLEY A. N. , GILLARD R. D. 
Published: May 2016

AbstractThe S(2p) spectra of (NH4)2(Pt(S5)3)·2 H2O and (PPh4)3(Cu3(S4)3) reveal that the structurally distinct sulfur atoms show different electron binding energies.
ChemInform Abstract: Magnetic and Theoretical Studies of the Electronic Structure and Spin State of the Bis(tetrathiomolybdato)iron Trianion, (Fe(MoS4)2)3‐.
Authors: BOWMAKER G. A. , BOYD P. D. W. , SORRENSON R. J. , REED C. A. , MCDONALD J. W. 
Published: May 2016

AbstractMeasurements of the magnetic susceptibility (1.7‐300 K) and low‐temp.
ChemInform Abstract: Influence of Adsorbate‐Adsorbate Interactions on Surface Structure. The Coadsorption of CO and H2 on Rh(100)
Authors: RICHTER L. J. , GURNEY B. A. , HO W. 
Published: May 2016

Abstracthas been studied by TPD, LEED, EELS (electron energy loss spectroscopy) and temp. programmed EELS.
ChemInform Abstract: Kinetics of the Iodine Monochloride Reaction with Iodide Measured by the Pulsed‐Accelerated‐Flow Method.
Authors: MARGERUM D. W. , DICKSON P. N. , NAGY J. C. , KUMAR K. , BOWERS C. P. , FOGELMAN K. D. 
Published: May 2016

AbstractReaction A has been studied under pseudo‐first‐order conditions in aqueous solution with I‐ and Cl‐ in large excess.
ChemInform Abstract: Thermochemical Nitridation of Microporous Silica Films in Ammonia.
Authors: BROW R. K. , PANTANO C. G. 
Published: May 2016

AbstractMicroporous SiO2 films deposited on Si substrates from a tetraethoxysilane solution are nitrided in NH3 in the temp. range 500‐1100 °C. The NH3 treatment of these sol‐gel films results in amorphous, compositionally homogeneous films with up to 40 mol% overall nitrogen content.
ChemInform Abstract: Preparation of Crystalline Aluminum Phosphate by the Reaction Using Boron Phosphate.
Authors: VASOVIC D. , STOJAKOVIC D. , STANKOVIC S. 
Published: May 2016

AbstractThe use of BPO4 in the synthesis of crystalline AlPO4 has been investigated starting with hydrated Al2O3 or AlCl3·6 H2O and carrying out the reaction either in solid state or in the KCl melt.
ChemInform Abstract: Structure of Factor S3, a Metabolite of Propionibacterium shermanii Derived from Uroporphyrinogen I.
Authors: MUELLER G. + , SCHMIEDL J. , SCHNEIDER E. , SEDLMEIER R. , WOERNER G. + , SCOTT A. I. , WILLIAMS H. J. , SANTANDER P. J. , STOLOWICH N. J. , FAGERNESS P. E. , MACKENZIE N. E. , KRIEMLER H.‐P. 
Published: May 2016

AbstractIncubation of cobalt‐deficient cell‐free extracts of the title bacterium with δ‐aminolevulinic acid in the presence of S‐adenosylmethionine yields the isomeric factors S1‐S4.
ChemInform Abstract: The Ionic Hydrogen Bond and Ion Solvation. Part 5. OH···O‐ Bonds. Gas‐Phase Solvation and Clustering of Alkoxide and Carboxylate Anions.
Authors: MEOT‐NER M. , SIECK L. W. 
Published: May 2016

AbstractDissociation energies, ΔH°D, of RO‐·HOR, RCOO‐·HOR, and RCOO‐·HOOCR complexes range from 14 to 29 kcal/mol.
ChemInform Abstract: π‐Facially Controlled Nucleophilic Additions of Chiral Vinylorganometallics to Chiral β,γ‐Unsaturated Ketones. Part 1. Double Diastereoselection Studies Involving 7,7‐Dimethoxy‐5‐norbornen‐2‐one.
Authors: PAQUETTE L. A. , LEARN K. S. 
Published: May 2016

AbstractThe stereochemical outcome is studied for the reactions of organo‐cerium compounds as for example (III), (VI) or (X) (obtained in situ from the respective Li compound, e.g. (II), or the bromo precursors) with the title compound (I).
ChemInform Abstract: Heterocyclic Sulfur Compounds. Part 105. 1,4‐Dihydro‐2H‐3,1,2λ5‐benzothiazaphosphorine‐2,4‐dithiones. A New Synthetic Route to 2‐Arylaminothiobenzamides and to 2‐(2‐Arylaminophenyl)‐4,5‐dihydrothiazoles (or Oxazoles).
Authors: LEGRAND L. , LOZACH N. 
Published: May 2016

AbstractThe benzothiazaphosphorinedithiones (I) are cleaved by amines (II) and alcohols (III) to give the thiobenzamides (IV) and the dithiophosphates (V).
ChemInform Abstract: Nucleophilic Addition to Diazaquinones. Formation and Breakdown of Tetrahedral Intermediates in Relation to Luminol Chemiluminescence.
Authors: MERENYI G. , LIND J. , ERIKSEN T. E. 
Published: May 2016

AbstractNucleophilic addition to the diazaquinones (I)‐(III) is shown to occur at the carbonyl group.
ChemInform Abstract: Kinetics of Ozonation. Part 5. Reactions of Ozone with Carbon‐Hydrogen Bonds.
Authors: GIAMALVA D. H. , CHURCH D. F. , PRYOR W. A. 
Published: May 2016

AbstractOver the range ‐20 to +45 °C the activation energies and the rate constants for the ozonation of ethers such as (I), two aldehydes (i.e.
ChemInform Abstract: Homogeneous Palladium Catalyzed Oxidations: Benzylic Acyloxylation of Alkyl Aromatics Using Mixed Palladium Copper Acetate Catalyst.
Authors: GOEL A. B. 
Published: May 2016

AbstractIt has been found that the use of cupric acetate in conjunction with Pd(O‐Ac)2 in the benzylic acyloxylation of toluene in higher boiling carboxylic acid medium (e.g.
ChemInform Abstract: Electrophilic Heteroaromatic Substitutions. Part 9. Behavior of Halogenopyrroles Towards Hydrogen Halides in Diverse Solvents.
Authors: GIULIANO F. , PENNA M. , SLEITER G. 
Published: May 2016

AbstractIn order to elucidate the mechanism of the halogen‐halogen exchange in pyrroles the reactions of (II), (IV), or (V) are investigated both in aprotic (diethyl ether, CH2Cl2, CCl4) and in protic (AcOH/H2O or CH3OH) solvents.
ChemInform Abstract: Alkylation of Carbon Acids in the Presence of Potassium Carbonate. Part 1. Alkylation of Carbon Acids by Ethyl Bromoacrylate and Its Derivatives.
Authors: VARDAPETYAN A. A. , KHACHATRYAN D. S. , PANOSYAN G. A. , MORLYAN N. M. 
Published: May 2016

AbstractThe alkylation of the malonic ester (II) by ethyl α‐bromoacrylate (I) or by diethyl α‐bromomaleate (IV) in the presence of K2CO3 according to method A) affords the cyclopropanes (III) or (V).
ChemInform Abstract: Alkylation of Carbon Acids in the Presence of Potassium Carbonate. Part 2. Alkylation of Acetylacetone, Acetoacetic and Malonic Ester by 1,4‐Dihalogenbut‐2‐enes.
Authors: VARDAPETYAN A. A. , KHACHATRYAN D. S. , PANOSYAN G. A. , MORLYAN N. M. 
Published: May 2016

AbstractThe alkylations of acetylacetone (Ia) and ethyl acetoacetate (Ib) by the 1,4‐dihalobutenes (II) yield mixtures of the corresponding vinyl cyclopropanes (III), which result from intramolecular C‐alkylations, and the vinyl dihydrofurans (IV), which are formed by intramolecular O‐alkylations.
ChemInform Abstract: Synthesis of Ubiquinones by Oxidative Demethylation of Ubiquinol Monoethers by Ceric Ammonium Nitrate.
Authors: OBOL'NIKOVA E. A. , KOZLOVA I. V. , FILIPPOVA T. M. , SAMOKHVALOV G. I. 
Published: May 2016

AbstractE/Z mixtures of the ubiquinones (II) are obtained by the oxidation of the ubiquinol monoethers (I).
ChemInform Abstract: Cathodic Coupling of Indanones in the Presence of Oxygen. Stereospecificity in the Formation of the Corresponding 1,1′,2,2′‐Tetraol.
Authors: DELAUNAY J. , ORLIAC‐LE MOING A. , LEBOUC A. , SIMONET J. , TOUPET L. 
Published: May 2016

AbstractIn contrast to the reactions of 1‐tetralones, 1‐benzosuberones and unsubstituted indanones electrolysis of the title indanone (I) at ‐1.4 V in the presence of oxygen yields the dimer (III) (space group P1, Z=2).
ChemInform Abstract: Thiono Compounds. Part 7. Oxidation of Thioamides in Relation to Adverse Biological Effects.
Authors: HILLHOUSE J. H. , BLAIR I. A. , FIELD L. 
Published: May 2016

AbstractThioacetamide (I), thioacetamide S‐oxide (IIIa), and thiopivalamide S‐oxide (IIIb) are oxidized with H2O2 in H218O to generate the amides (II) and (IV) with at least 50% 18O‐incorporation.
ChemInform Abstract: Catalytic Arylation of Furfural by Aryldiazonium Salts.
Authors: OBUSHAK N. D. , LESYUK A. I. , GANUSHCHAK N. I. , MEL'NIK G. M. , ZAVALII P. YU. 
Published: May 2016

AbstractContradictory statements are found in the literature about the preparation of 5‐arylfurfurals.
ChemInform Abstract: Bislactonizations of Olefinic Diacids with (Hydroxy(Tosyloxy)iodo)benzene.
Authors: SHAH M. , TASCHNER M. J. , KOSER G. F. , RACH N. L. , JENKINS T. E. , CYR P. , POWERS D. 
Published: May 2016

AbstractThe cyclic (I) or acyclic unsaturated diacids (IV) are converted into the bislactons (III) and (V) respectively by treatment with the iodobenzene (II).
ChemInform Abstract: (2‐Furyl)‐ and (2‐Thienyl)chlorocarbenes as New Carbenes with Heterocyclic Substituents.
Authors: DOLGII I. E. , SHAVRIN K. N. , KRYLOVA I. V. , NEFEDOV O. M. 
Published: May 2016

AbstractThe carbenes mentioned in the title are generated from the dichloromethyl compounds (I) and react with the olefins (II) to give the cyclopropyl derivatives (III).
ChemInform Abstract: Intramolecular Rhodium Carbenoid Insertions into Aromatic C‐H Bonds. Preparation of 1‐Carboalkoxy‐1,3‐dihydrobenzo(c)thiophene 2,2‐Dioxides.
Authors: HRYTSAK M. , ETKIN N. , DURST T. 
Published: May 2016

AbstractThe diazosulfones (I) are cyclized in the presence of rhodium acetate (II) to yield the dihydrobenzothiophenedioxides (III).
ChemInform Abstract: Radical Addition of 2‐Trichloromethyl‐1,3‐dioxolane to Vinyltrimethylsilane.
Authors: TERENT'EV A. B. , MAKAEVA R. M. , MUSAVIROV R. S. 
Published: May 2016

AbstractUsing iron pentacarbonyl‐dimethylformamide as a catalyst, vinyltrimethylsilane (II) attacks the trichloromethyldioxolane (I) exclusively at the C‐Cl bond to form the addition product (III) without changing the dioxolane ring.
ChemInform Abstract: Synthesis of Polyfluoro 1,4,2‐Dioxazolines with Functional Groups.
Authors: TRUSKANOVA T. D. , VASIL'EV N. V. , KOLOMIETS A. F. , SOKOL'SKII G. A. 
Published: May 2016

AbstractThe perfluoromethacrylic acid derivatives (I) react with hydroxylamine to give the hydroxamic acid fluorides (II) which exist in two isomeric forms.
ChemInform Abstract: Synthesis of Trihydroxyphenacylidene Triphenylphosphoranes: A New Access to Dihydroxyflavones (Chrysine, Acacetine...).
Authors: LE FLOC'H Y. , LEFEUVRE M. 
Published: May 2016

AbstractThe phosphoranes (III) are obtained from the trihydroxyaryl ketones (I) and triphenylphosphine (II).
ChemInform Abstract: Claisen Condensation. Behaviour of Esters Towards 3‐Acetyl‐1,2,3,4‐tetrahydro‐2,4‐dioxo‐1‐phenylquinoline.
Authors: ZOOROB H. H. , HAMAMA W. S. 
Published: May 2016

AbstractClaisen condensation of compound (I) with ethyl acetate produces the butanedione derivative (II) which is converted to (III) by a twofold Mannich reaction with paraformaldehyde and benzylamine.
ChemInform Abstract: Unusual Transformation of 2‐Pentafluorophenoxyethyl‐N,N‐diethylamine with Alkyl Bromides and Iodides Involving Formation of Piperazinium Salts and Alkyl Pentafluorophenyl Ethers.
Authors: PLATONOV V. E. , OSINA O. I. , PRESHER D. , ENGLER G. 
Published: May 2016

AbstractThe aminoethyl ether (I) reacts with the alkyl halides (II) to produce the piperazinium salts (III) and the ethers (IV).
ChemInform Abstract: Synthesis and Hydrosilylation of Epoxy‐ and Cyano‐Substituted Allylacetylenes.
Authors: VELIEV M. G. , CHEKRII P. S. , GUSEINOV M. M. , KALECHITS I. V. , TABER A. M. , GARAMANOV A. M. 
Published: May 2016

AbstractThe allylacetylenes (IIIc) and (IIId), prepared from the carbinol (I), are regioselectively hydrosilylated with the silanes (VI) at the triple bond to yield the unsaturated silanes (VII).
ChemInform Abstract: Thiophosphoryl‐Transfer Reactions: A General Synthesis and Configurational Analysis of O‐Substituted (16O,18O)Thiophosphates.
Authors: CULLIS P. M. , IAGROSSI A. , ROUS A. J. 
Published: May 2016

AbstractThe general routes to isotopically chiral (16O,18O)thiophosphate monoesters (I) of either RP or SP absolute configuration are shown in the scheme.
ChemInform Abstract: Phosphinocarbene‐Phosphaalkene Rearrangement and Intramolecular Wittig‐Like Reaction Involving a Phosphorus Vinyl Ylide.
Authors: BACEIREDO A. , IGAU A. , BERTRAND G. , MENU M. J. , DARTIGUENAVE Y. , BONNET J. J. 
Published: May 2016

AbstractPhotolysis of the bis(phosphino)diazomethane (II), prepared as shown, leads to the phosphaalkene (III) in nearly quantitative yield.
ChemInform Abstract: Reaction of Cyanophosphites with Carbonic Acids and Their Anhydrides.
Authors: ROMANOV G. V. , NAZMUTDINOVA V. N. , PUDOVIK A. N. 
Published: May 2016

AbstractDiethyl cyanophosphite (I) reacts with the carboxylic acids (II) to give the mixed anhydrides (III).
ChemInform Abstract: Reaction of Trialkylphosphites with Cyclopentadienones in the Presence of Proton‐Donating Reagents. Part 1. The Reaction of Trimethyl Phosphite and Dimethyl Phenylphosphonite with Tetracyclone in the Presence of Acetic and Trifluoroacetic Acids.
Authors: ARBUZOV B. A. , FUZHENKOVA A. V. , BURMISTROVA I. V. 
Published: May 2016

AbstractThe cyclopentadienone (I) reacts with the phosphite (IIa) or the phosphonite (IIb) in the presence of acetic (IIIa) or trifluoroacetic acid (IIIb) to give mixtures of the compounds (IV) ‐ (IX), depending on the substituents.
ChemInform Abstract: Synthesis, Crystal, and Molecular Structure of O,O‐Dimethyl (p‐Carboran‐2‐yl)phosphonate.
Authors: YANOVSKII A. I. , STRUCHKOV YU. T. , KAMPEL' V. TS. , BREGADZE V. I. , GODOVIKOV N. N. , KABACHNIK M. I. 
Published: May 2016

AbstractThe dicarboranylmercury (I) is irradiated in trimethyl phosphite solution to produce the title compound (III).
ChemInform Abstract: Electrophilic Reactivity of a ββ′‐Bisphosphonioalkyne: Addition of Amines and Thiophenols.
Authors: PLENAT F. , BENNAMARA A. , CHICHE L. , CHRISTOL H. 
Published: May 2016

AbstractThe bisphosphonium diiodide (I) is coupled with the amines (II) at the triple bond to form the enamines (III).
ChemInform Abstract: Phosphonic Acid Lactones as Potential Analogs of D‐Ala‐D‐Ala.
Authors: BARTLETT P. A. , VANMAELE L. J. , KEZER W. B. 
Published: May 2016

AbstractThe mixture of diastereomers (VIc), prepared from (I) by the procedures shown in the scheme, is converted to the amides (VII), and at this stage the individual isomers are separated by column chromatography and HPLC (discussion of 1H NMR data; the ratio of isomers is not specified).
ChemInform Abstract: Synthesis of Eight‐Membered Cyclic Phosphorous Acid Chlorides and Their Derivatives.
Authors: MUKMENEVA N. A. , KADYROVA V. KH. , ZHARKOVA V. M. , CHERKASOVA O. A. , VOSKRESENSKAYA O. V. 
Published: May 2016

AbstractThe cyclic chlorophosphites (II) are synthesized by reacting the diphenylmethanes or the diphenyl sulfides (I) with phosphorus trichloride.
ChemInform Abstract: Steric Structure of 2,5‐Dimethyl‐5‐phenyl‐1,3,5‐dioxaphosphorinanes.
Authors: PATSANOVSKII I. I. , KUDYAKOV N. M. , ZYABLIKOVA T. A. , KOVRIZHNIKOVA I. K. , VITKOVSKII V. YU. , ISHMAEVA E. A. , IL'YASOV A. V. , VORONKOV M. G. , PUDOVIK A. N. 
Published: May 2016

AbstractThe dioxaphosphorinane (III) is synthesized by reacting the phosphine (I) with the acetal (II).
ChemInform Abstract: Antitumor Antibiotics Drug Design. Part 2. Synthesis of 4‐(N‐(5‐(2′‐thienyl)‐thenoyl)aminoethyl)imidazole Iron(II) Complex, a New N2S2‐Metallocycle with a “Built In” Intercalating Moiety which Causes DNA Scissioning in vitro.
Authors: ONG C. W. , LEE H.‐C. 
Published: May 2016

AbstractThe new chelating ligand (V) is synthesized as shown in the scheme.
ChemInform Abstract: “Jellyfish” Type Cobalt(II)porphyrins as a Hemoprotein Model and Their Regulated Dioxygen Affinities by Steric Restrictions on Axial Ligands.
Authors: UEMORI Y. , KYUNO E. 
Published: May 2016

AbstractIn (Ib) and (Ic) the valeryl and pivaloyl groups appended on one side control the orientation of an axial ligand such as 1‐methylimidazole (A) and the ligand binding on the other side of the porphyrin is inhibited by a "strapped" structure as it is the case for (II) having a "strapped" structure on both sides of the plane.
ChemInform Abstract: Sodium 2‐Methyl‐2‐propylthiolate, a Versatile Sulfur Reagent. Preparation of Protected Polysulfur Ligands and Their Nickel(II) Complexes.
Authors: BECHER J. , STIDSEN C. E. , TOFTLUND H. , ASAAD F. M. 
Published: May 2016

AbstractMultisulfur‐containing ligands can conveniently be prepared by nucleophilic substitution of chlorine in various heterocyclic and other aromatic systems (I), (V) and (VII) by the t‐butylthiolate anion, followed by elimination of isobutene from the resulting t‐butylthioethers.
ChemInform Abstract: Differentially Protected α‐Aminoglycine.
Authors: BOCK M. G. , DIPARDO R. M. , FREIDINGER R. M. 
Published: May 2016

AbstractThe glycine (I) reacts with isopropylmercaptane (II) according to the Ben‐Ishai procedure to give the thioether (III) which is substituted with the carbamate (IV) to yield the N,N'‐protected diamino acid (V).
ChemInform Abstract: A New Stereoselective Synthesis of (E,Z,Z)‐4,7,10‐Tridecatrien‐1‐ol Acetate, Component of the Sex Pheromone of Phthorimaea operculella.
Authors: CASSANI G. 
Published: May 2016

AbstractThe title compound (VIII) is prepared starting from the alkyne (I) (in part yields given in g).
ChemInform Abstract: A Synthetic Approach to Polyene Macrolides: Synthesis of the Building Blocks. A Synthetic Approach to Polyene Macrolides: Macrolide and Polyene Generation.
Authors: TROST B. M. , METZ P. , HANE J. T. 
Published: May 2016

AbstractThe building blocks (IV) and (VIII) of polyene macrolides are synthesized from ethylacetoacetate (I) or the cycloalkanone (V).
ChemInform Abstract: Neutron‐ and X‐Ray‐Diffraction Study on the Structure of Amorphous Co25Ti75.
Authors: MUELLER A. + , BUEHLER E. + , LAMPARTER P. , STEEB S. 
Published: May 2016

AbstractAmorphous Co25Ti75‐ribbons have been produced using the melt spin technique within a He‐atmosphere.
ChemInform Abstract: Crystal Structure of BaSiF6 at 180 K.
Authors: SVENSSON G. , ALBERTSSON J. , SVENSSON C. , ELDING L. I. 
Published: May 2016

AbstractIn a series of attempts to prepare solid aqua complexes of Pt(II) with BF4‐ as counterion, well‐grown crystals of the title compound have been found on the inside wall of the glass vessel.
ChemInform Abstract: The Effects of Various Amounts of Alloyed Cerium and Cerium Oxide on the High Temperature Oxidation of Fe‐10 Cr and Fe‐20 Cr Alloys
Authors: RHYS‐JONES T. N. , GRABKE H. J. , KUDIELKA H. 
Published: May 2016

Abstracthave been investigated at 1000 °C in O2/He atmosphere (O2 partial pressure of 0.1315 bar).
ChemInform Abstract: Spectroscopic and Theoretical Investigations of the Interligand Charge Transfer of Nickel(II) Mixed Ligand Complexes with Dithiolate and α‐Diimine Ligands.
Authors: BENEDIX R. , PITSCH D. , SCHOENE K. + , HENNIG H. 
Published: May 2016

AbstractNi(II) mixed ligand complexes (I) or (II) are characterized by an unusual interligand charge transfer band of medium intensity in the visible region.
ChemInform Abstract: NMR Studies and Structure of the (3)Ferrocenophanes Cyclic Fe(η5‐C5H4S3)(η5‐C5H3P(S)Ph2‐1,n) (n = 2 or 3).
Authors: BUTLER I. R. , CULLEN W. R. , HERRING F. G. , JAGANNATHAN N. R. , EINSTEIN F. W. B. , JONES R. 
Published: May 2016

AbstractThe structure of the ferrocenophanes (I) and (II) are determined by X‐ray diffraction.
ChemInform Abstract: Spectroscopic Investigations of the Iron(II) Nitrosodicyanomethanide and Nitrosocarbamoylcyanomethanide Complexes (Fe(NOC(CN)2)2(C5H5)4) and (Fe(NOC(CN)C(O)NH2)2(C5H5N)2).
Authors: SKOPENKO V. V. , GERASIMCHUK N. N. , TYUKHTENKO S. I. , KOEHLER H. + 
Published: May 2016

AbstractThe structures of the title compounds (I) and (II), prepared as described previously, are discussed on the basis of IR, Mößbauer, 13C and 14N NMR spectra and the results of magnetic measurements.
ChemInform Abstract: Radiolytic and Electrochemical Reduction of Ru(bpz)2+ 3 in Aqueous Solution. Stability, Redox, and Acid‐Base Properties of Ru(bpz)+ 3.
Authors: VENTURI M. , MULAZZANI Q. G. , CIANO M. , HOFFMAN M. Z. 
Published: May 2016

AbstractThe pulse and continuous radiolysis show that the reactions between reducing radicals (e‐ aq, CO·‐ 2, and Me2COH) and the title complex (Ru(bpz)3)2+ (bpz: 2,2'‐bipyrazine) are one‐electron transfers, generating initially and quantitatively (Ru(bpz)3)+.
ChemInform Abstract: Retrodienic Reactions. Part 20. Synthesis and Flash Thermolysis of Diels‐Alder Bis‐Adducts: Formation of a Functionalized Triple Bond by Double Cycloreversion.
Authors: LASNE M.‐C. , RIPOLL J.‐L. 
Published: May 2016

AbstractIn order to generate an acetylenic compund by two cycloreversions, the adducts (I), (VIII) and (XII) are synthesized according to known procedures and subjected to flash thermolysis.
ChemInform Abstract: Cyclopentane Construction by Rh2(OAc)4‐Mediated Intramolecular C‐H Insertion: Steric and Electronic Effects.
Authors: TABER D. F. , RUCKLE R. E. JUN. 
Published: May 2016

AbstractFactors which govern the regiospecificity of cyclopentane formation by Rh(II) mediated intramolecular C‐H insertion of α‐diazo β‐keto esters are studied.
ChemInform Abstract: Photochemical and Electrochemical Reduction of Carbon Dioxide to Carbon Monoxide Mediated by (2,2′‐Bipyridine)tricarbonylchlororhenium(I) and Related Complexes as Homogeneous Catalysts.
Authors: HAWECKER J. , LEHN J.‐M. , ZIESSEL R. 
Published: May 2016

AbstractThe investigation of the complexes (I) shows that especially (Ia) is an efficient homogeneous catalyst for the selective photochemical or electrochemical reduction of CO2 to CO.