bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Regioselective Synthesis of 2‐Pyrazolines and Pyrazoles from Ethyl α‐Cyanocinnamates.
Authors: HASSANEEN H. M. , MOUSA H. A. H. , EZMIRLY S. T. , SHAWALI A. S. 
Published: May 2016

AbstractThe cycloaddition of the nitrilimines (III) (in situ generated from the hydrazidoyl chlorides (I)) to the α‐cyano cinnamates (II) or (V) yields the products (IV) or (VII).
ChemInform Abstract: Synthesis of the Antihypertensive Agent 1‐(1‐Methylethyl)‐2‐(2‐(4‐(3‐trifluoromethylphenyl)‐1‐piperazinyl)ethyl)‐1H‐naphth(1,2‐d)imidazole Citrate.
Authors: TOJA E. , TRANI A. 
Published: May 2016

Abstract2‐Nitro‐1‐naphthol (VI) is prepared from the sulfonate (I) by nitrosation, oxidation, and desulfonation.
ChemInform Abstract: Benzocrown Derivatives as Ionophores for Alkali Cations. Part 3. Synthesis of Ring‐Cleaved Analogues of Benzocrown Ethers. A Novel Method for Building Up Crown Ether Rings.
Authors: TOKE L. , BITTER I. , AGAI B. , HELL Z. , LINDNER E. , TOTH K. , HORVATH M. , SZOELLOSY A. + , HARFOUCH S. , PUNGOR E. 
Published: May 2016

AbstractThe ring‐cleaved benzocrown ether (III), prepared by a known procedure, shows some copper selectivity while, in contrast to its ring‐closed analogue, its potassium selectivity is poor.
ChemInform Abstract: Reactivity and Chemoselectivity of Primary Z‐β‐Enamino‐λ5‐phosphazenes Toward Electrophiles.
Authors: BARLUENGA J. , LOPEZ F. , PALACIOS F. , CANO F. H. , FOCES‐FOCES C. 
Published: May 2016

AbstractThe multifunctional character of Z‐β‐enamino‐λ5‐phosphazenes (I) and (VI) toward several electrophiles is shown.
ChemInform Abstract: The Pyridylseleno Group in Organic Synthesis. Part 5. Amidoseleniation of Alkenes.
Authors: TOSHIMITSU A. , HAYASHI G. , TERAO K. , UEMURA S. 
Published: May 2016

AbstractA two‐step amidoseleniation reaction of electron‐rich alkenes or their derivatives such as (I) or (VII) affords the β‐acetamido‐alkyl‐2‐pyridyl selenides (V) or (XII) ((XIIb) (no yield given) exists as a ca. 1:1 cis/trans‐mixture).
ChemInform Abstract: Reactions of Coordinated Dinitrogen. Part 21. Synthesis of Mono(dinitrogen) Complexes of Molybdenum. Formation of Ammonia and Hydrazine.
Authors: GEORGE T. A. , TISDALE R. C. 
Published: May 2016

AbstractReduction of the complex (I) with sodium amalgam in the presence of the phosphine (II) and with a regulated amount of N2 (III) yields the Mo(0) complex (IV).
ChemInform Abstract: “One‐Pot” Fischer Synthesis of (2,3,3‐Trimethyl‐3H‐indol‐5‐yl)acetic Acid. Derivatives as Intermediates for Fluorescent Biolabels.
Authors: SOUTHWICK P. L. , CAIRNS J. G. , ERNST L. A. , WAGGONER A. S. 
Published: May 2016

AbstractCyclocondensation of the hydrazine (I) with the ketone (II) produces the indole derivative (III) mentioned in the title.
ChemInform Abstract: Asymmetric Synthesis. Part 16. Enantiomerically Pure Substituted Cyclopropane Amino Acid Precursors via the CN(R,S) Method.
Authors: AITKEN D. J. , ROYER J. , HUSSON H.‐P. 
Published: May 2016

AbstractThe N‐(cyanomethyl)oxazolidine (I) reacts with LDA and epibromohydrin (II) to give the N‐(cyanocyclopropyl)oxazolidines (III) which are isomerized to produce the bicyclic γ‐lactone (V) and the cyclopropanecarboxylate (VI).
ChemInform Abstract: Novel Phosphorane and Phosphonate Synthons for Vinyl Glycines.
Authors: BICKNELL A. J. , BURTON G. , ELDER J. S. 
Published: May 2016

AbstractThe bromopyruvates (I) and (IX) are converted to the corresponding methyl oxime ethers and then treated with triphenylphosphine (III) or trimethyl phosphite (X), yielding the phosphonium salt (IV) or the phosphonate (XI).
ChemInform Abstract: Facial Selectivity of the Intramolecular SN2′ Cyclization: Stereocontrolled Total Synthesis of Brevianamide B.
Authors: WILLIAMS R. M. , GLINKA T. , KWAST E. 
Published: May 2016

AbstractIn order to get insight in the biogenesis of brevianamide A and related compounds, the synthesis of the title compound is envisaged.
ChemInform Abstract: Insect Growth Regulators. Part 21. Synthesis of Juvenoids with the 5,5‐Dimethylcyclohex‐3‐en‐1‐yl System.
Authors: WAWRZENCZYK C. , LOCHYNSKI S. 
Published: May 2016

AbstractThe alcohol (II) is prepared starting from (+)‐3‐carene (I) via the bromide (VIII).
ChemInform Abstract: The “Normalizing Factor” for the Tomato Mutant chloronerva. Part 30. Synthesis of 3,4‐Seconicotianamine.
Authors: RIPPERGER H. 
Published: May 2016

AbstractThe title compound (IV) is synthesized as shown in the scheme by stepwise reductive alkylation of the methylalanine ester (I) with the compound (II).
ChemInform Abstract: A Novel Synthesis of Cyclobutane Monoterpenes, (.+‐.)‐Grandisol and (.+‐.)‐Lineatin.
Authors: KAMETANI T. , TOYA T. , UEDA K. , TSUBUKI M. , HONDA T. 
Published: May 2016

AbstractThe benzocyclobutene (I) is used as a common material for the synthesis of the ester (VIII) and the pyran (XVI).
ChemInform Abstract: Analytical Electron Microscopic Studies of Doped Dicalcium Silicates.
Authors: CHAN C.‐J. , KRIVEN W. M. , YOUNG J. F. 
Published: May 2016

AbstractCa2SiO4 samples are prepared using different CaO/SiO2 molar ratios (1.8, 2.0, 2.2) to which different amounts of K2O and Al2O3 are added as dopants.
ChemInform Abstract: Pseudorotation in Pentacoordinated Phosphorus Compounds. The Influence of the Conformational Transmission Effect on the Barriers to Pseudorotation in Cyclic Alkoxyphosphoranes
Authors: DE KEIJZER A. E. H. , KOOLE L. H. , BUCK H. M. 
Published: May 2016

Abstract(1H and 31P NMR data as well as variable‐temp.
ChemInform Abstract: Photoisomerization of Some N‐Aryl α,β‐Unsaturated Iminium Salts.
Authors: PANKRATZ M. , CHILDS R. F. 
Published: May 2016

AbstractPhotochemically induced isomerization of the α,β‐unsaturated iminium salts (I) leads to the formation of a photostationary state consisting of the starting material (I) and the three photoisomers (II) ‐ (IV).
ChemInform Abstract: Addition of α‐Chlorobenzyl Benzoate to Alkenes.
Authors: BORODAEV S. V. , LUK'YANOV S. M. 
Published: May 2016

AbstractIn the presence of ZnCl2 the reaction between α‐chlorobenzyl benzoate (I) and the alkenes (II) yields the 1,3‐dioxanium trichlorozincates (III), which can be isolated as oily products.
ChemInform Abstract: Palladium‐Catalyzed Allylic Sulfinate‐Sulfone Rearrangements.
Authors: HIROI K. , MAKINO K. 
Published: May 2016

AbstractThe allylic alcohols (I) react with p‐toluenesulfinyl chloride (II) to give the allylic sulfinates (III) which are rearranged in the presence of a palladium(0) complex to yield mixtures of the allylic sulfones (IV) and (V).
ChemInform Abstract: Calixarenes. Part 22. Synthesis, Properties, and Metal Complexation of Aminocalixarenes.
Authors: GUTSCHE C. D. , NAM K. C. 
Published: May 2016

AbstractCalix(4)arene (I), readily accessible from p‐tert.‐butylcalix(4)arene, reacts smoothly with formaldehyde (III) and various sec. amines, e.g. (II), to yield Mannich bases such as (IV).
ChemInform Abstract: The Synthetic Reactions of Aliphatic Nitro Compounds. Part 25. Formation of 4‐Benzamidoisoxazole Derivatives.
Authors: ZEN S. , HARADA K. , NAKAMURA H. , IITAKA Y. 
Published: May 2016

AbstractReaction of the nitrile oxides (III) (generated in situ from the nitro compounds (I)) with the aziridine (II) yields the title compounds (IV).
ChemInform Abstract: Molecular Recognition in Aqueous Media. Conformationally Restricted Water‐Soluble Cyclophanes Derived from 6H,12H‐5,11‐Methanodibenzo(b,f) (1,5)diazocine.
Authors: COWART M. D. , SUCHOLEIKI I. , BUKOWNIK R. R. , WILCOX C. S. 
Published: May 2016

AbstractThe two water‐soluble cyclophanes (IIIa), (IIIb), the title compounds, are synthesized by condensation of the known bis(sulfonamide) (II) with the dibromides (I) which are available by alkylation of the corresponding dihydroxy compound with 1,2‐dibromoethane.
ChemInform Abstract: Synthesis of the 5,6‐Dihydro‐2‐pyrone Moiety of (+)‐Anamarin.
Authors: GILLARD F. , HEISSLER D. , RIEHL J.‐J. 
Published: May 2016

AbstractThe pyrone derivative (VII) which contains the lactonic moiety of (+)‐anamarin is prepared starting from the known furanose (I).
ChemInform Abstract: Transition‐Metal Mediated Asymmetric Synthesis. Part 6. Organometallic Approaches to the Enantiomer Synthesis of Tridachione: A Role for Planar Chirality in Synthesis Design.
Authors: ALEXANDER R. P. , MORLEY C. , STEPHENSON G. R. 
Published: May 2016

AbstractThe complex (I) is converted by a two‐step synthesis into the acyl‐substituted chiral complex (V), which in its optically active form may serve as an intermediate for the synthesis of the antibiotic tridachione (VI).
ChemInform Abstract: The Al(2P)(SiH4) Complex and the Photoreversible Oxidative‐Addition/Reductive‐Elimination Reaction: Al(2P)(SiH4) ⇄ H3SiAlH.
Authors: LEFCOURT M. A. , OZIN G. A. 
Published: May 2016

AbstractSpectroscopic (UV‐VIS and EPR matrix spectra) and ab initio quantum chemical details for the Al(2P)(SiH4) complex support the view, that the longer, weaker SiH bonds of SiH4 and the existence of low‐lying empty 3d orbitals would open up favorable electronic/structural channels for enhanced interactions with ground state electronic state metal atoms compared to its lighter congener CH4.
ChemInform Abstract: Study of Heteroepitaxy of InP on GaAs by Metalorganic Vapor‐Phase Epitaxy.
Authors: PAK K. , WAKAHARA A. , SATO T. , YOSHIDA A. , YONEZU H. , ITOH N. , TAKAGI Y. 
Published: May 2016

AbstractEpitaxial layers of InP are grown on GaAs by the title method using Me3In and PH3 in H2 as source materials.
ChemInform Abstract: Metal Ion Substitution Chemistry in the YBaCuO System as a Probe of the Superexchange Pathway.
Authors: JONES R. , EDWARDS P. P. , HARRISON M. R. , THANYASIRI T. , SINN E. 
Published: May 2016

AbstractThe effect of substitution for Cu by Al, Ni, and Zn in the 90 K system YBa2Cu3O7‐δ is investigated with the overall aim of elucidating the nature and mechanism of the superconducting path.
ChemInform Abstract: Highly Polydentate Ligands. Part 5. Structures of Alkaline‐Earth Complexes of the Calcium‐Selective Ligand EGTA4‐ (H4EGTA: 3,12‐Bis(carboxymethyl)‐6,9‐dioxa‐3,12‐diazatetradecanedioic Acid).
Authors: SCHAUER C. K. , ANDERSON O. P. 
Published: May 2016

Abstract(I) crystallizes in P1 with Z=2, (II) in Pccn, Z = 8, (III) in Pca21, Z=12 and (IV) in Pna21, Z=4.
ChemInform Abstract: Metal‐Phenoxyalkanoic Acid Interactions. Part 28. Crystal and Molecular Structures of the Sodium, Ammonium, and Magnesium Complexes of (o‐Phenylenedioxy)diacetic Acid.
Authors: KENNARD C. H. L. , SMITH G. , O'REILLY E. J. , REYNOLDS B. J. , MAK T. C. W. 
Published: May 2016

AbstractThe structures of the polymeric sodium compound (I) (space group P1, Z=2), the ionic ammonium salt (II) (Pbcn, Z=4) containing H bridges between NH4+ and the carboxylate O atoms, and the Mg complex (III)·4 H2O (C2/c, Z = 8) are determined by X‐ray analysis.
ChemInform Abstract: Mononuclear Heterocyclic Rearrangements. Part 15. Kinetic Study of the Amine‐Catalyzed Rearrangement of Some Z‐Arylhydrazones of 3‐Benzoyl‐5‐phenylisoxazole into 2‐Aryl‐4‐phenacyl‐5‐phenyl‐1,2,3‐triazoles in Acetonitrile and in Benzene.
Authors: FRENNA V. , BUSCEMI S. , ARNONE C. 
Published: May 2016

AbstractThe pathway of the catalyzed rearrangement of (Ib) in the presence of Et3N, 1,4‐diazabicyclo(2.2.2)octane (DABCO), and piperidine requires only one molecule of amine.
ChemInform Abstract: Cerium(IV)‐Induced Nitration of Cinnamic Acids. Novel Remote Electrophilic Substitution.
Authors: PETERSON J. R. , DO H. D. , DUNHAM A. J. 
Published: May 2016

AbstractTreatment of the cinnamic acid (I) with ceric ammonium nitrate (II) in TFA affords the dinitrostyrene (III) via remote ipso substitution of the COOH group by a nitro group.
ChemInform Abstract: Stereocontrolled Approach to Electrophilic Epoxides.
Authors: METH‐COHN O. , MOORE C. , TALJAARD H. C. 
Published: May 2016

AbstractLi‐tert.‐butyl hydroperoxide (easily generated by addition of an alkyllithium to anhydrous tert.‐butyl hydroperoxide as exemplified in method A)) is a powerful reagent for the epoxidation of electrophilic alkenes under full stereocontrol.
ChemInform Abstract: Purines, Pyrimidines, and Imidazoles. Part 64. Alkylation and Acylation of Some Aminoimidazoles Related to Intermediates in Purine Nucleotide de novo and Thiamine Biosynthesis.
Authors: MACKENZIE G. , WILSON H. A. , SHAW G. , EWING D. 
Published: May 2016

AbstractAlkylation of the aminoimidazoles (I) or (V) gives rise to the products (III) + (IV) or (VI) + (VII), respectively.
ChemInform Abstract: Synthesis and Antiprotozoal Activity of a Series of Arylpropenone Derivatives of 5‐Nitroimidazoles.
Authors: OUATTARA L. , DEBAERT M. , CAVIER R. 
Published: May 2016

Abstract1‐Methyl‐5‐nitro‐2‐imidazolecarboxaldehyde (I) is subjected to condensation reaction with the aryl methyl ketones (II) to give the title compounds (III).
ChemInform Abstract: The Preparation of Optically Active δ2‐Isoxazolines. A Model for Asymmetric Induction in the Non Lewis Acid Catalyzed Reactions of Oppolzer′s Chiral Sultam.
Authors: CURRAN D. P. , KIM B. H. , DAUGHERTY J. , HEFFNER T. A. 
Published: May 2016

AbstractThe optically active isoxazolines (III) and (IV) are obtained by 1,3‐dipolar cycloaddition reaction of the acryloylsultam (I) with the nitrile oxides (II).
ChemInform Abstract: The Preparation and Fungicidal Activity of a Series of Thiazolyl‐ and Isothiazolyl‐diarylcarbinols.
Authors: KATRITZKY A. R. , LAURENZO K. S. , RELYEA D. I. 
Published: May 2016

AbstractThe title compounds (IIIc), (IIIe), (Va) and (Vd) show fungicidal activity in vivo and in vitro.
ChemInform Abstract: Azapropellanes. Part 5. Synthesis of Chiral (Non‐Racemic) 2‐Methyl Azapropellanes.
Authors: MCINTOSH J. M. , ACQUAAH S. O. 
Published: May 2016

AbstractStarting from (S)‐alanine (I), the optically active piperidone (II) is prepared and its transformation into the azapropellane (IX) is described.
ChemInform Abstract: An Approach to the 3,8‐Diazabicyclo(3.2.1)octane Moiety of Naphthyridinomycin and Quinocarcin via 1,3‐Dipolar Cycloaddition of Photochemically Generated Azomethine Ylides.
Authors: GARNER P. , SUNITHA K. , SHANTHILAL T. 
Published: May 2016

AbstractThe imides (III), prepared from the amines (I), react with methyl azide (IV) to give the triazolines (V).
ChemInform Abstract: Addition Compounds of Bis(trifluoromethyl)mercury with Tetraphenylphosphonium and Tetraphenylarsonium Halides and Thiocyanates.
Authors: KORPAR‐COLIG B. , POPOVIC Z. , BRUVO M. , VICKOVIC I. 
Published: May 2016

AbstractThe 1:1 and 1:2 adducts (I) and (II) are isolated from aqueous solutions of Hg(CF3)2 and (Ph4E)Cl or (Ph4E)Cl/KX (X: Br, I, SCN) and identified by elemental analysis and IR spectroscopy as well as conductivity measurements.
ChemInform Abstract: Carbon‐Carbon Bond Formation in the Reductive Coupling of Nitriles at a Multiply Bonded Dirhenium Center.
Authors: ESJORNSON D. , FANWICK P. E. , WALTON R. A. 
Published: May 2016

AbstractThe triply bonded dirhenium(II) complexes (I) react with nitriles to give products in which a metal‐metal bond is retained.
ChemInform Abstract: Reversible Linkage Isomerization of Pentaamminecobalt(III) Complexes of Urea and Its N‐Methyl Derivatives.
Authors: FAIRLIE D. P. , JACKSON W. G. 
Published: May 2016

AbstractSpecific rates and conditions for the observation of hitherto unrecognized urea‐O to urea‐N isomerization reactions are reported.
ChemInform Abstract: Transition Metal Complexes of Ligands Containing 3,5‐Dimethylpyrazolyl Groups and Thioether Functions. The Crystal and Molecular Structure of (1,12‐Bis(3,5‐dimethylpyrazol‐1‐yl)‐2,11‐diaza‐5,8‐dithiadodecane)nickel(II)‐bis(tetrafluoroborate).
Authors: PAAP F. , DRIESSEN W. L. , REEDIJK J. , SPEK A. L. 
Published: May 2016

AbstractThe 1:1 molar reaction of Co, Ni, or Cd salts with the ligand L1 in EtOH/H2O results in formation of the complexes (I).
ChemInform Abstract: Template Reactions of 1,4‐Bis(α‐carboxybenzylidenehydrazino)phthalazine with Cobalt(II), Nickel(II), and Chromium(III).
Authors: OKUR A. I. 
Published: May 2016

AbstractThe title ligand (yield 55%) is prepared from 1,4‐dihydrazinophthalazine and the methyl ester of phenylglyoxalic acid in MeOH under reflux, followed by hydrolysis.
ChemInform Abstract: A Convenient Synthetic Route to the Monocondensation Products of Pentane‐2,4‐dione and Aliphatic α,ω‐Diamines. Synthesis, X‐Ray Structure and Magnetic Properties of a Trinuclear Copper(II) Complex with 8‐Amino‐5‐aza‐4‐methyl‐3‐octene‐2‐one.
Authors: KWIATKOWSKI M. , KWIATKOWSKI E. , OLECHNOWICZ A. , HO D. M. , DEUTSCH E. 
Published: May 2016

AbstractThe tridentate N2O ligands (III) are prepared by 3:1 molar reaction of the diamines (I) and the diketone (II).
ChemInform Abstract: First Complexes of Cyanogen Halides with Silver(I): Crystal Structure of (Ag(NCCl)2) (SbF6).
Authors: ROESKY H. W. , SCHIMKOWIAK J. , JONES P. G. , NOLTEMEYER M. , SHELDRICK G. M. 
Published: May 2016

AbstractThe monomeric bis(cyanogen halide)‐Ag(I) complex salts (III) are obtained by the stoichiometric reaction shown in the scheme.
ChemInform Abstract: Synthesis of Heterodinuclear FeRu(CO)6(R‐DAB(6e)) (R‐DAB: RN=C(H)C(H)=NR). Part 15. Comparison of the Reactivities of Heterodinuclear FeRu(CO)6(R‐DAB(6e)) and Homodinuclear Analogues M2(CO)6(R‐DAB(6e)) (M: Fe, Ru). Single‐Crystal X‐Ray Structures of FeRu(CO)6(iPr‐DAB(6e)) and FeRu(CO)5(iPr‐DAB(4e))(C3H4).
Authors: ZOET R. , VAN KOTEN G. , MULLER F. , VRIEZE K. , VAN WIJNKOOP M. , GOUBITZ K. , VAN HALEN C. J. G. , STAM C. H. 
Published: May 2016

AbstractThe reactions of the 1,4‐diazabutadiene‐tricarbonyl‐Fe complexes (I) with Ru3(CO)12 (II) as well as these of the Ru analogues (IV) with Fe2(CO)9 (V) both afford the binuclear complexes (III).
ChemInform Abstract: Binuclear Rhodium Carbonyl Halide Complexes Containing the 1,1‐Bis(diphenylphosphino)ethene Ligand, and the Crystal Structure of (Rh2Cl2(μ‐CO)(Ph2PC(=CH2)PPh2)2).
Authors: DAWSON R. H. , HARDING M. M. , MAGINN S. , SMITH A. K. 
Published: May 2016

AbstractThe reaction of (I) with the diphosphine (II) is studied and the results are compared with the behavior of similar bis(diphenylphosphino)methane containing complexes.
ChemInform Abstract: Reactivity of Cyclopalladated Compounds. Part 18. Compared Reactivity of the Pd‐C Bonds of Two Closely Related Six‐Membered Palladocyclic Rings with Substituted Alkynes. X‐Ray and Molecular Structures of Cyclic (Pd(C(Ph)=C(R)C(Ph)=C(R)(o‐C6H4N=CMeNHPh))Cl) (R: CO2Et) and Cyclic (Pd(C(R)(C(CO2Me)C(R)=C(R)C(R)=C(R)) (o‐C6H4N=CMe(OH)))Cl) (R: CO2Me).
Authors: DUPONT J. , PFEFFER M. , DARAN J.‐C. , GOUTERON J. 
Published: May 2016

AbstractThe chloride‐bridged cyclopalladated dimers (I) react with alkynes to afford organometallic products in which one, two, or three alkynes are inserted into the Pd‐C bonds; the ratio of alkyne:Pd in the final products being independent of the stoichiometry of the reaction.
ChemInform Abstract: Heterobimetallic Catalysts for the Oxidation of Alcohols: (Os(N)R2(CrO4))‐ (R: CH3, CH2SiMe3).
Authors: ZHANG N. , MANN C. M. , SHAPLEY P. A. 
Published: May 2016

AbstractStudies show that the Os chromate complex (IIIa) prepared according to the scheme catalytically oxidizes a variety of alcohols e.g. (IV) with high selectivity.
ChemInform Abstract: Synthesis and Characterization of trans‐(PMe3)2PtHCl and an Investigation of Its Role in Olefin Hydration Catalysis.
Authors: RAMPRASAD D. , YUE H. J. , MARSELLA J. A. 
Published: May 2016

AbstractThe analytically pure title complex (II) fails to act as an olefin hydration catalyst under the conditions published earlier.
ChemInform Abstract: Metal Complexes with Biologically Important Ligand. Part 47. Copper, Nickel, Palladium, and Platinum(II) Complexes of C‐Allylglycine and of N‐(Diphenylmethylene)‐C‐allylglycine Ester.
Authors: STEINER N. , NAGEL U. , BECK W. 
Published: May 2016

AbstractC‐Allylglycine (I) reacts with Ni, Cu, Pd, and Pt(II) salts ‐ depending on pH ‐ to give the trans‐N,O‐bis(chelate) complexes (IV) or the N,η2‐C,C‐chelate complexes (VII) as demonstrated in the scheme.
ChemInform Abstract: Narcotic Alkylating Agents: Synthesis, Structure, and Biological Activities.
Authors: FRIGOLA J. , COLOMBO A. , MAS J. , PARES J. 
Published: May 2016

Abstract3,6‐Diacetylnormethylmorphine (I) is converted to the chloroethylated derivative (IV) via reaction with ethylene oxide (II), followed by chlorination.
ChemInform Abstract: An Electron Spin Resonance and Optical Study of the Behavior of Cs2(TcNCl5) in Hydrochloric Acid Solutions.
Authors: BALDAS J. , BOAS J. F. 
Published: May 2016

AbstractOn the basis of their UV‐VIS spectra three species are detected in solutions of Cs2(TcNCl5) in aqueous HCl.
ChemInform Abstract: Synthesis and ab initio Structure Determination from X‐Ray Powder Data of Ba2PdO3 with Sevenfold Coordinated Ba2+. Structural Correlations with K2NiF4 and Ba2NiF6.
Authors: LALIGANT Y. , LE BAIL A. , FEREY G. , HERVIEU M. , RAVEAU B. , WILKINSON A. , CHEETHAM A. K. 
Published: May 2016

AbstractBa2PdO3, obtained by solid state reaction in air between BaO2 and Pd, crystallizes in the orthorhombic space group Immm with Z=2.
ChemInform Abstract: Kinetics of Electrochemical Reduction of Oxygen at Rhodium.
Authors: MARTINOVIC J. M. , SEPA D. B. , VOJNOVIC M. V. , DAMJANOVIC A. 
Published: May 2016

AbstractSystematic kinetic studies of the oxygen reduction reaction (OR) at prereduced Rh electrodes in a wide range of pH and oxygen partial pressure using a steady‐state galvanostatic technique are performed aiming at the evaluation of relevant kinetic parameters.
ChemInform Abstract: The Sticking of O2 on a Pt(111) Surface.
Authors: LUNTZ A. C. , WILLIAMS M. D. , BETHUNE D. S. 
Published: May 2016

AbstractDetailed molecular beam measurements of the sticking coefficient at zero coverage for O2 on a Pt(111) surface are performed as a function of initial energy, angle of incidence, and surface temperature.
ChemInform Abstract: Electron Microscopic Study of Submicron Sized Nickel Particles Obtained by Reduction in Organic Media: Influence of the Preparation Conditions on the Particle Size.
Authors: ALPHONSE P. , BRIEU M. , GILLET M. , MAURET P. 
Published: May 2016

AbstractNiBr2 reduction in organic media gives an intermediate complex, whose decomposition leads to Ni particles of nm size.
ChemInform Abstract: Electron Rich Olefins. Part 2. Structure and Electron Transfer Reactivity of the Cyclically σ/π‐Hyperconjugated Carbosilane 3,3,6,6‐Tetrakis(trimethylsilyl)‐1,4‐cyclohexadiene.
Authors: HAUSEN H.‐D. , BESSENBACHER C. , KAIM W. 
Published: May 2016

AbstractAn X‐ray structure analysis of the title compound (I) is carried out (space group P21/c; Z=4).
ChemInform Abstract: Observations on the Intramolecular Palladium(0)‐Catalyzed (3 + 2)Cycloaddition of Diphenylmethylenecyclopropanes.
Authors: LEWIS R. T. , MOTHERWELL W. B. , SHIPMAN M. 
Published: May 2016

AbstractThe unsaturated aldehyde (I) is converted into the dienone (IX) which undergoes Pd(0)‐catalyzed cyclization to form the bicyclo(3.3.0)octanone (X).
ChemInform Abstract: Reducing Characteristics of 4‐(Borane‐dimethylamino)pyridine. Chemoselective Reduction of Aldehydes in the Presence of Ketones.
Authors: KIM S. , YANG S. 
Published: May 2016

AbstractThe different reactivity of ketones, e.g. (I), and aldehydes such as (III) in the presence of the title reagent allows a selective reduction of the aldehydes.
ChemInform Abstract: Charge‐Transfer Complex Formation Between Stilbenes and 7,7,8,8‐Tetracyanoquinodimethane.
Authors: JIN J.‐I. , KIM J.‐S. , KIM J.‐D. 
Published: May 2016

AbstractThe title stilbene derivatives (I) and (II) form 1:1 complexes with the title tetracyanoquinodimethane (TCNQ).
ChemInform Abstract: Synthesis of Chrysenes and Other a‐Fused Phenanthrenes by a Palladium(0) Coupling‐Electrocyclic Ring Closure Sequence.
Authors: GILCHRIST T. L. , SUMMERSELL R. J. 
Published: May 2016

AbstractThe organozinc bromide derived from (I) reacts with several unsaturated halides such as (II) or (V) in the presence of a Pd catalyst to yield the coupling products (III) or (VI), which undergo cyclization on heating in solution to give the fused phenanthrenes (IV) or (VII).