bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Stereoselective Synthesis of Polyol Precursors by Allyl Sulfinyl Anion Addition to Chiral Alkoxy Aldehydes.
Authors: ANNUNZIATA R. , CINQUINI M. , COZZI F. , RAIMONDI L. , STEFANELLI S. 
Published: May 2016

AbstractThe sulfoxide (I) is efficiently used as a synthon for the insertion of an allylic alcohol moiety into the title aldehydes (II).
ChemInform Abstract: Highly Efficient Asymmetric Reduction of α‐Tertiary Alkyl Ketones with Diisopinocampheylchloroborane.
Authors: BROWN H. C. , CHANDRASEKHARAN J. , RAMACHANDRAN P. V. 
Published: May 2016

Abstractα‐Tertiary alkyl ketones (II) are reduced highly stereoselectively using the optically active diisopinocampheylborane (I), forming the S‐configurated alcohols (III).
ChemInform Abstract: Singlet‐Oxygen Ene Reactions of (E)‐4‐Propyl(1,1,1‐2H3)oct‐4‐ene.
Authors: RAUTENSTRAUCH V. , THOMMEN W. , SCHULTE‐ELTE K. H. 
Published: May 2016

AbstractThe sensitized photooxidation of the propyloctene (I) followed by reduction of the hydroperoxides formed gives the products (IIa) + (IIb) + (IIIa) + (IIIb).
ChemInform Abstract: Calcium and Lithium Reductions of Epoxides in Ethylenediamine. A Comparison Study.
Authors: BENKESER R. A. , RAPPA A. , WOLSIEFFER L. A. 
Published: May 2016

AbstractThe epoxides (I), (VII), (IX), and (XII) are reduced with calcium (II) dissolved in ethylenediamine (III) to yield the corresponding alcohols, together with minor amounts of olefins.
ChemInform Abstract: Reactions of a Thieno(3,4‐c)isothiazole with 1,2,4‐Triazoline‐3,5‐diones and Alkynes.
Authors: GOTTHARDT H. , BOEHM F.‐R. + 
Published: May 2016

AbstractThe known dione (I) is readily converted to the thienoisothiazole (II) (literature method).
ChemInform Abstract: Trimethylsilyl Cyanide ‐ A Reagent for Umpolung. Part 15. A Convenient Route to 5‐Methyl‐3,7‐octadienic Acid from 2,4‐Hexadienal via Umpolung and Double Cope Rearrangement.
Authors: FISCHER K. , HUENIG S. + 
Published: May 2016

AbstractCompound (I) is prepared from the corresponding aldehyde by reaction with trimethylsilyl cyanide.
ChemInform Abstract: (2,3)Wittig Rearrangement of 2′‐Alkenyloxyacetic Acid Esters.
Authors: UCHIKAWA M. , KATSUKI T. , YAMAGUCHI M. 
Published: May 2016

AbstractThe alkenyloxyacetates (I) undergo Wittig rearrangement in the presence of LDA and zirconocene dichloride to produce the α‐hydroxyalkenoic esters (II).
ChemInform Abstract: Phosphoniosilylation: An Efficient and Practical Method for the β‐Functionalization of Enones.
Authors: KOZIKOWSKI A. P. , JUNG S. H. 
Published: May 2016

AbstractPhosphoniosilylation of the enones (I) using the triflate (II) and triphenylphosphine (III) yields the phosphonium salts (IV) which produce the silyldienolethers (VI) as a result of Wittig reaction with the aldehydes (V).
ChemInform Abstract: Preparation and Properties of Hexasubstituted Benzenes.
Authors: ROSENTHAL U. , SCHULZ W. 
Published: May 2016

AbstractTwo different procedures are employed for the synthesis of the title compounds: the Ni(0)‐catalyzed trimerization of alkynes (I) to give (II), and treatment of (III) with the sodium salts of (IV) or the benzoates (VI) to afford (V) or (VII).
ChemInform Abstract: Synthesis of Polynitro Compounds. Hexasubstituted Benzenes.
Authors: ATKINS R. L. , HOLLINS R. A. , WILSON W. S. 
Published: May 2016

AbstractStarting with the isomeric dinitrotoluidines (Ia), (IIIa), and (Va) the tetranitrotoluidines (IIa), (IVa), and (VIa) are prepared all of which can be oxidized to give pentanitrotoluene (VII).
ChemInform Abstract: Facile Anhydride Synthesis Using Trichlorotrifluoroacetone Hydrate.
Authors: ABDEL‐BAKY S. , GIESE R. W. 
Published: May 2016

AbstractThe hydrate (II) of trichlorotrifluoroketone (I) reacts with acid chlorides (III) to form the anhydrides (V) via the postulated intermediates (IV).
ChemInform Abstract: Thioacylsulfenyl Bromides: Electrophilic Dithiocarboxylating Reagents.
Authors: KATO S. , ONO Y. , MIYAGAWA K. , MURAI T. , ISHIDA M. 
Published: May 2016

AbstractThe diphenyltin bis(dithiocarboxylates) (I) are brominated with NBS to produce the thioacylsulfenyl bromides (III).
ChemInform Abstract: Synthesis of 3‐Nitro‐1,1‐bis(triisopropylsilyl)‐1H‐cyclopropabenzene and Derivatives of Azocyclopropabenzene.
Authors: NEIDLEIN R. , CHRISTEN D. 
Published: May 2016

AbstractThe disilyl derivative (IV) which is prepared from (I) via the unstable intermediate (III) is nitrated without opening of the three‐membered ring to afford the title compound (V).
ChemInform Abstract: β‐Fur‐2‐yl‐α‐halogenacrylonitriles. Part 5. Preparation of β‐(5‐Nitro‐fur‐2‐yl)‐α‐azidoacrylonitrile and β‐(5‐Nitro‐fur‐2‐yl)‐α‐aminoacrylonitrile.
Authors: JAEHNISCH K. + , GRUENDEMANN E. + 
Published: May 2016

AbstractThe reaction of the α‐chloroacrylonitrile (I) with NaN3 yields an isomeric mixture of the unexpected, α‐substituted title azido compounds (II).
ChemInform Abstract: Photochemical Synthesis of Phenyl‐2‐thienyl Derivatives.
Authors: ANTONIOLETTI R. , D'AURIA M. , D'ONOFRIO F. , PIANCATELLI G. , SCETTRI A. 
Published: May 2016

AbstractThe thiophenes (I), (III), (V), (VII), (VIII) and (X) are prepared from thiophene by literature methods.
ChemInform Abstract: Asymmetric (2,3)Wittig Rearrangement of 2′‐Alkenyloxyacetamide Bearing trans‐2,5‐Bis(methoxymethoxymethyl)pyrrolidine Moiety as a Chiral Auxiliary.
Authors: UCHIKAWA M. , HANAMOTO T. , KATSUKI T. , YAMAGUCHI M. 
Published: May 2016

AbstractThe allyloxyacetamides (I) are converted to the corresponding lithium enolates which undergo Wittig rearrangement, producing the allylated α‐hydroxy amides (II) with predominant syn‐configuration.
ChemInform Abstract: Sulfonioindolides and Sulfoniopyrrolides.
Authors: HARTKE K. , STRANGEMANN D. 
Published: May 2016

AbstractIndole (I) and pyrrole (VII) react with the sulfoxides (II) in the presence of trifluoroacetic anhydride, yielding the indolylsulfonium (III) or pyrrolylsulfonium salts (VIII) and (IX) after treatment with LiClO4.
ChemInform Abstract: Oxidation of 1‐Benzoylpyrrole and 1‐Aroylindoles by Palladium Acetate.
Authors: ITAHARA T. 
Published: May 2016

AbstractThe oxidation of N‐benzoylpyrrole (I) and the N‐acyl‐indoles (VI), (X), and (XIII) by Pd(II) acetate produces a mixture of ring closure, dimerization, and fragmentation products as shown in the reaction scheme.
ChemInform Abstract: Synthesis of 5,5′‐Dialkoxy‐2,2′‐dioxazolylsulfides.
Authors: BOSSIO R. , MARCACCINI S. , PEPINO R. 
Published: May 2016

AbstractReaction of the alkyl isocyanoacetates (I) with sulfur dichloride and treatment of the intermediate αβ‐unsaturated α‐chloro sulfides with a base produce the title compounds (II).
ChemInform Abstract: Metal‐Hydride Reduction of Isoxazoline‐3‐carboxylate Esters.
Authors: CALDIROLA P. , DE AMICI M. , DE MICHELI C. , WADE P. A. , PRICE D. T. , BEREZNAK J. F. 
Published: May 2016

AbstractThe reduction of the title compounds with NaBH4 gives the hydroxymethyl derivatives (II) in varying yields.
ChemInform Abstract: Reaction of (2‐Alkoxy‐vinyl)hetero‐methiniminium Salts with C‐Nucleophiles ‐ an Approach to Functionalized Pyrylium Salts.
Authors: SPITZNER R. , SCHROTH W. 
Published: May 2016

AbstractTreatment of the salts (III) with (IV) and Et3N gives the nitriles (V) whose ring closure in an acidic medium provides the target compounds (VI).
ChemInform Abstract: Synthesis of Complex Pyridine Bases by the Reaction of v‐Cyano‐α‐acetylenes with Acetylene Catalyzed by Cobalt Complexes.
Authors: DZHEMILEV U. M. , SELIMOV F. A. , KHAFIZOV V. R. 
Published: May 2016

AbstractCodimerization of v‐cyano‐α‐acetylenes (Ia), (Ib), or (VIII) with excess acetylene, catalyzed by cobalt 2‐ethylhexanoate, yields mixtures of the compounds (II) ‐ (IV), (V) ‐ (VII), or (IX) ‐ (XIII).
ChemInform Abstract: Phosphorus Pentoxide in Organic Synthesis. Part 29. Synthesis of 4‐Arylamino‐5,6,7,8‐tetrahydro‐1H‐pyrazolo(3,4‐b)quinolines and the Corresponding N‐Mannich Bases.
Authors: NIELSEN S. V. , PEDERSEN E. B. 
Published: May 2016

AbstractHeating of the aminopyrazolecarboxylates (I) with cyclohexanone (II) and the arylamino hydrochlorides (III) gives the title compounds (IV), the condensation of which with the amines (V) and formaldehyde affords the Mannich bases (VI).
ChemInform Abstract: Liquid‐Crystalline Heterocycloalkanes. Part 2. Sytheses and Liquid‐Crystalline Properties of Substituted 1‐Phenylpiperazines.
Authors: SUESSE M. + , SKUBATZ R. , DEMUS D. , ZASCHKE H. 
Published: May 2016

AbstractThe piperazines (II) are prepared by two procedures from the anilines (I); further derivatization of (IIa), (IIb) and (IIe) gives the elongated compounds (VII) (yields and experimental details in some instances not given).
ChemInform Abstract: Synthesis of a Water‐Soluble Derivative of Cyclohexatriacontane‐ 1,2,13,14,25,26‐hexone.
Authors: MANDEVILLE W. H. , WHITESIDES G. M. 
Published: May 2016

AbstractThe cycloalkynes (I) are trimerized to give the benzene derivatives (II) which yield mixtures of cyclic diketones (III) and cyclic hexaketones (IV) as a result of ozonolysis.
ChemInform Abstract: Studies in Spiroheterocycles. Part 9. A New Elegant Synthesis and Reactions of Some Novel Fluorine‐Containing Spiro(3H‐indole‐3,2′‐tetrahydro‐1,3‐thiazine)‐2,4′(1H)‐diones.
Authors: JOSHI K. C. , DANDIA A. , AHMED N. 
Published: May 2016

AbstractCondensation of the indolediones (I), anilines (II), and the mercaptopropanoic acid (III) yields the title compounds (IV), which are converted into the derivatives (V) by acylation or Mannich reaction.
ChemInform Abstract: Reaction of Tetraalkyldihydrodisiloxanes with Cyano‐Containing Compounds of the Ethylene Series.
Authors: RUSTAMOV K. M. , SULTANOV R. A. 
Published: May 2016

AbstractThe dihydrodisiloxanes (I) are coupled with acrylonitrile (II) in the presence of chloroplatinic acid to give the α‐cyanoethyl compounds (III).
ChemInform Abstract: Syntheses and Studies on Conformation of Selenium Analogues of Metallocene Dithiolene Chelates Cp2M(Se2C6H4).
Authors: KOEPF H. + , KLAPOETKE T. + 
Published: May 2016

AbstractThe benzene 1,2‐diselenolate (I) is coupled with the metallocene dichlorides (II) or cyclopentadienyl titanium trichloride (IV) to yield the chelate complexes (III) and (V) respectively.
ChemInform Abstract: Oxidation of Methyl Podocarpate and Methyl 12‐Hydroxyabietan‐8,11,13‐trien‐18‐oate with Thallium(III) Perchlorate.
Authors: NAKANO T. , HERNANDEZ M. I. , POLACHINI J. M. , AVILA PENA D. , COROTHIE E. , ROJAS A. , MCPHAIL A. T. 
Published: May 2016

AbstractTo obtain biologically active derivatives the title compounds (I) (methyl podocarpate) and (IV) are oxidized.
ChemInform Abstract: Mechanism of Formation of Natural Cyclopropanes: Synthesis of Postulated Intermediates in Presqualene and Chrysanthemyl Alcohol Biosynthesis.
Authors: BOULTON K. , SHIRLEY I. , SMITH I. H. , WHITING D. A. 
Published: May 2016

AbstractAnion formation by the E‐ester (I) at ‐25 °C results in isomerization to give the E‐ and Z‐βγ‐unsaturated esters (II) and (III), which are separated by chromatography.
ChemInform Abstract: Functionalization of Saturated Hydrocarbons. Part 7. On the Mechanism of the Degradation of the Cholesterol Side‐Chain to 20‐Ketone by Oxidation with the Gif System.
Authors: BARTON D. H. R. , BOIVIN J. , CRICH D. , HILL C. H. 
Published: May 2016

AbstractThe 3α‐acetoxy steroids (Ia) and (Ib) ‐ both obtained in several steps from lithocholic acid acetate (Ic) ‐ are converted to the ketones (II), which undergo double dehydrogenation to give the dienones (III).
ChemInform Abstract: NMR of 31P Heteroatoms in Paramagnetic One‐Electron Heteropoly Blues. Rates of Intra‐ and Intercomplex Electron Transfers. Factors Affecting Line Widths.
Authors: KOZIK M. , HAMMER C. F. , BAKER L. C. W. 
Published: May 2016

AbstractRelatively sharp 31P NMR lines are observed at room temp. from the heteroatoms in the paramagnetic one‐electron reduction products of α‐(PW12O40)3‐ and α‐(P2W18O62)6‐. The electron exchange rates between the paramagnetic one‐electron reduced species and their fully oxidized diamagnetic isomorphs are evaluated from the line widths of the 31P NMR signal.
ChemInform Abstract: Rate Constant Determination of the Reaction of Metastable N(2D,2P) with NO2 Using Moderated Nuclear Recoil Atoms
Authors: IWATA R. , FERRIERI R. A. , WOLF A. P. 
Published: May 2016

Abstractto generate thermalized metastable atomic nitrogen, 2D and 2P, at a (NO2)/(N) ratio of 1013.
ChemInform Abstract: Synthesis and Characterization of (N2H5)2SiF6 (I) and Thermal Analysis of (N2H5)2SiF6 and N2H6SiF6 (II).
Authors: GANTAR D. , RAHTEN A. 
Published: May 2016

AbstractColourless crystals of (I) have been obtained from an aqueous solution of (II) and hydrazinium hydrate (pH 5).
ChemInform Abstract: X‐Ray Structure of Tetrameric 1‐Lithio‐3‐methoxypropane.
Authors: KLUMPP G. W. , GEURINK P. J. A. , VAN EIKEMA HOMMES N. J. R. , DE KANTER F. J. J. , VOS M. , SPEK A. L. 
Published: May 2016

AbstractX‐ray analysis indicates the crystals of the title compound to consist of a distorted (CH2)4Li4 cube, four parallel edges of which are spanned by CH2CH2OMe chains (space group C2/c, Z=4).
ChemInform Abstract: Synthesis and Cardiovascular Activity of Pyridinio(2,1‐c)triazinium and Imidazo(1,2‐a)pyridinium Salts.
Authors: RANDRIATSOA J. , MAYRARGUE J. , MIOCQUE M. , WEPIERRE J. , DUPONT C. 
Published: May 2016

AbstractReaction of the pyridinium bromide (I) with various hydrazines (II), (IV) or (VII) leads to the fused pyridines (III), (V), (VI) or (VIII).
ChemInform Abstract: Photochemical Reactions of 1‐Acetyl‐3‐methylbicyclo(1.1.0)butane.
Authors: CERFONTAIN H. , GEENEVASEN J. A. J. 
Published: May 2016

AbstractThe photochemistry of the title compound (I) in various solvents using 254 and 300 nm radiation has been studied.
ChemInform Abstract: Acylation of Active Methylene Compounds via Palladium Complex‐Catalyzed Carbonylative Cross‐Coupling of Organic Halides.
Authors: KOBAYASHI T. , TANAKA M. 
Published: May 2016

AbstractThe halogenides (I) react with carbon monoxide (II) and the activated esters (III) in the presence of the Pd‐catalysts (IV) to produce the carbonyl compounds (V).
ChemInform Abstract: Stereo‐ and Regiospecific Synthesis of Trisubstituted Alkenes via the Palladium‐Catalyzed Cross‐Coupling Reaction of Diisopropyl (E)‐(1‐Alkyl‐1‐alkenyl)boronates with Organic Halides.
Authors: SATOH M. , MIYAURA N. , SUZUKI A. 
Published: May 2016

AbstractThe bromoacetylenes (I) are converted to the bromoboronates (III) which are debrominated to form the vinylboronates (IV).
ChemInform Abstract: Synthesis and Mesomorphic Properties of 4‐Alkoxy‐4′‐formyl‐azobenzenes.
Authors: BURMISTROV V. A. , KAREEV V. YU. , KORZHENEVSKII A. B. , KOJFMAN O. I. 
Published: May 2016

Abstract4‐Hydroxy‐4'‐formylazobenzene (III) and its alkyl ethers (V) are obtained by standard methods, as shown in the formula scheme.
ChemInform Abstract: Photochemical and Chemical Reduction of Nitroalkenes Using Viologens as an Electron Phase‐Transfer Catalyst.
Authors: TOMIOKA H. , UEDA K. , OHI H. , IZAWA Y. 
Published: May 2016

AbstractThe nitroalkenes are converted to the oximes (III) and/or the ketones (IV) by photolytical reaction with sodium dithionite and electron acceptors such as the viologen (II).
ChemInform Abstract: Reaction of αββ‐Trifluorostyrene with Aryldiazonium Tetrafluoroborates in the Presence of Potassium Thiocyanate.
Authors: BILAYA E. E. , GANUSHCHAK I. I. , OBUSHAK N. D. , GRUSHCHUK B. D. , PAZDERSKII YU. A. , BEL'FERMAN A. L. 
Published: May 2016

AbstractThe title reaction of (I) and (II) produces the trifluorodiphenylthiocyanatoethanes (III).
ChemInform Abstract: Selective Epoxidation of Chiral 2‐Methyl‐3,4‐Unsaturated Aldehyde Acetals.
Authors: HONDA Y. , ORI A. , TSUCHIHASHI G. 
Published: May 2016

AbstractThe optically active acetals (I) react with tert‐butylhydroperoxide in the presence of organometallic compounds such as ethylaluminum dichloride or trichlorotitanium isopropylate to produce the epoxides (II) and the chlorohydrins (III).
ChemInform Abstract: Syntheses and Analgesic/Antiinflammatory Activities of Novel 2‐(5‐Aroyl‐pyrrolo)alkanoic Acids.
Authors: CHANG M. N. , BIFTU T. , BOULTON D. A. , FINKE P. E. , HAMMOND M. L. , PESSOLANO A. A. , ZAMBIAS R. A. , BAILEY P. , GOLDENBERG M. , RACKHAM A. 
Published: May 2016

AbstractReaction of the cyanopyridine (I) with the pyrrole (II) under Houben‐Hoesch conditions gives the ketone (III), which is converted to the nicotinyl derivative (IVa); a similar procedure leads to the picolinyl derivative (IVb).
ChemInform Abstract: Stable Configuration of Ester‐Stabilized Azomethine Ylides. Stabilization of anti‐Form by 1,5‐Dipolar Interaction and of syn‐Form by Hydrogen Bonding.
Authors: TSUGE O. , KANEMASA S. , OHE M. , YOROZU K. , TAKENAKA S. , UENO K. 
Published: May 2016

AbstractThe glycine derivatives (I) react with the aldehydes (II) to form the azomethine ylides (III).
ChemInform Abstract: Compounds with Antitumor Activities. Part 4. Synthesis and Antileucemic Activities of 1‐Aryl‐N,N′‐bis(2‐(1,3,4)thiadiazolyl)methylenediamines.
Authors: GRASSO S. , CHIMIRRI A. , MONFORTE P. , FENECH G. , ZAPPALA M. 
Published: May 2016

Abstract2‐Amino‐1,3,4‐thiadiazole (I) reacts with the benzaldehydes (II) to produce the methylene diamines (III).
ChemInform Abstract: Synthesis and Properties of Some Derivatives of 2H‐4,6‐Dimethylpyrido‐(3,2‐d)isothiazolin‐3‐one‐1,1‐dioxide.
Authors: ZAWISZA T. , MALINSKA W. 
Published: May 2016

AbstractThe isothiazole (I) is oxidized to produce mixtures of the sulfone (II) and the carbonamidosulfonic acid (III).
ChemInform Abstract: A New Application of S,S‐Dialkyl Dithiocarbonates as a Convenient Source for Alkanethiols: Synthesis of 2,4‐Bis(alkylamino)‐6‐alkylthio‐S‐ triazines.
Authors: DEGANI I. , FOCHI R. , REGONDI V. 
Published: May 2016

AbstractThe compounds (III) mentioned in the title are prepared from the diamino‐chlorotriazines (I) and the dithiocarbonates (II).
ChemInform Abstract: Ring Expansion of Cyclic α‐Ethynyl Sulfonium Ylides by (2,3)‐Sigmatropic Rearrangement: Formation of Thiocine, Thionine, and Thiecine Derivatives.
Authors: SASHIDA H. , TSUCHIYA T. 
Published: May 2016

AbstractTreatment of the cyclic thioethers (I) with N‐chlorosuccinimide (NCS) and the alkynyl magnesium bromides (II) produces the ethynyl derivatives (III) ‐ (V) which are converted to the sulfonium salts (VII) ‐ (IX).
ChemInform Abstract: Stereoselective Synthesis of Trifluoromethylated Olefin and Diene.
Authors: HANZAWA Y. , KAWAGOE K. , KIMURA N. , KOBAYASHI Y. 
Published: May 2016

AbstractThe allylic alcohols (II) react with ethyl orthoacetate under acidic conditions to yield the rearranged esters (III).
ChemInform Abstract: Reaction of Phosphorus Pentachloride with p‐Benzoquinone.
Authors: KUTYREV A. A. , FOMIN S. G. , MOSKVA V. V. 
Published: May 2016

AbstractPhosphorous pentachloride reacts vigorously with the benzoquinones (I), producing the tris‐(p‐hydroxyphenoxy)dichlorophosphoranes (II).
ChemInform Abstract: Nucleophilic Substitution at the Biocoordinated Phosphorus Atom in P‐(Amino)methylenephosphines.
Authors: MARKOVSKII L. N. , ROMANENKO V. L. , RUBAN A. V. , POLYACHENKO L. K. 
Published: May 2016

AbstractThe methylenephosphine (I) reacts with the lithium organyls (II) to give the corresponding phosphines (III) by nucleophilic substitution of the bistrimethylsilylamino group.
ChemInform Abstract: Tricyclic 1,3,2λ5,4λ5‐Diazadiphosphetidines.
Authors: KOZHUSHKO B. N. , SILINA E. B. , DOROSHENKO V. V. , MIKHAILYUCHENKO N. K. , SHOKOL V. A. 
Published: May 2016

AbstractThe title compounds (III) are obtained by reacting the dialkyl (di‐ aryl)isocyanato phosphites (I) with the alkyl(aryl) isocyanates (II).
ChemInform Abstract: Chemistry of (W(PMe3)4(η2‐CH2PMe2)H): Synthesis of Hydroxy‐hydrido, Fluoro‐hydrido, and Silyl‐hydrido Derivatives and the Dimerisation of Ethylene and Propene Giving η4‐Diene Derivatives. Crystal Structure of (W(PMe3)4H2(OH2)F)F.
Authors: GREEN M. L. H. , PARKIN G. , CHEN M. , PROUT K. 
Published: May 2016

AbstractThe syntheses of the compounds (I), (III)‐(XII) are described.
ChemInform Abstract: Dialkoxyethylidene and η2‐1,2‐Dialkoxyethylene Iron Compounds as C2 Templates for Generating Acetaldehyde and a Glycolaldehyde Ether.
Authors: CRAWFORD E. J. , BODNAR T. W. , CUTLER A. R. 
Published: May 2016

AbstractCoordinated ligand reactions that use the methoxyacetyl ligand on (I) as a template for generating other C2 ligands and their free organic derivatives are presented.
ChemInform Abstract: Manganese(II), Nickel(II) and Copper(II) Complexes with Schiff Bases Containing Sulphonic or Phosphonic Groups.
Authors: GUERRIERO P. , AJO D. , VIGATO P. A. , CASELLATO U. , TAMBURINI S. 
Published: May 2016

AbstractReaction of the sodium salts of the Schiff bases, preformed by condensation of 2,6‐diformyl‐4‐chlorophenol with the appropriate aminoalkanesulfonic or phosphonic acids in the presence of NaOH, with corresponding metal acetates or chlorides leads to the binuclear products (I).
ChemInform Abstract: Transmetalation of Tetranuclear Copper Complexes. Part 9. Stoichiometry and Kinetics of Transmetalation of (μ4‐O)(NCu)4X6 Complexes by M(NS)2 Reagents in Aprotic Solvents.
Authors: DAVIES G. , EL‐SAYED M. A. , EL‐TOUKHY A. 
Published: May 2016

AbstractThe tetranuclear Cu(II) complexes (I) are stoichiometrically transmetalated by one mol of structurally characterized metal(II) reagents (II) in aprotic solvents giving the chromatographically isolated equimolar products (III) and (IV).
ChemInform Abstract: η3‐Allyl Rhodium Complexes with Azolate Ligands. Crystal Structures of the Trinuclear 1,2,4‐Triazolate (tz) Complexes (Rh3(μ‐tz)3(η3‐C3H5)6) and (Rh3(μ3‐tz)(μ‐Cl)Cl(η3‐C3H5)2(CO)4)·0.5 C2H4Cl2.
Authors: ORO L. A. , PINILLOS M. T. , TEJEL C. , FOCES‐FOCES C. , CANO F. H. 
Published: May 2016

AbstractReaction of the η3‐allyl Rh compound (I) with azole ligands gives the new azolate complexes (II) or (III).
ChemInform Abstract: Bromination of Tris(1,1,1‐trifluoro‐2,4‐pentanediono)rhodium(III).
Authors: CARDWELL T. J. , LORMAN T. H. 
Published: May 2016

AbstractBromination of the title compound is performed at room temp. (complete within 6 d) using excess bromine in CHCl3.
ChemInform Abstract: Synthesis and X‐Ray Structural Studies of Some Dinuclear Platinum(III) Complexes of Pyrimidine‐2‐thione and 2‐Thiouracil.
Authors: GOODGAME D. M. L. , ROLLINS R. W. , SLAWIN A. M. Z. , WILLIAMS D. J. , ZARD P. W. 
Published: May 2016

AbstractReaction of pyrimidine‐2‐thione with PtX42‐ (X: ‐Cl, ‐Br) in aqueous EtOH or MeOH following a known method gives the Pt(III) compounds (I) and (IIa).
ChemInform Abstract: Hydrogen Distribution Around Eu2+ and Gd3+ Probes in Samarium Hydrides.
Authors: WORTMANN G. , THAL W. , MUSTACHI A. , NOWIK I. 
Published: May 2016

AbstractDilute 153Eu and 155Gd probe atoms formed by radioactive decay of 153Sm and 155Eu, resp., in SmH2+x (0 ≤ x ≤ 1) in the temp. range 4.1‐20 K have been studied by Mößbauer spectroscopy.
ChemInform Abstract: A Novel Metastable Compound with a Hitherto Unknown Structure Type, BaNi2In8O15,
Authors: SCHIFFLER ST. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

Abstractis prepared by reacting an intimate mixture of BaCO3, basic NiCO3, and In2O3 at > 1800 °C (CO2‐laser‐technique).
ChemInform Abstract: The Sensitivity of IVR in Benzene to Bend‐Stretch Potential Energy Coupling.
Authors: LU D.‐H. , HASE W. L. , WOLF R. J. 
Published: May 2016

AbstractQuasiclassical trajectory calculations have been performed to study intramolecular vibrational energy redistribution (IVR) from CH overtone states in benzene.
ChemInform Abstract: Stereochemistry of Dihydropinol and 1,8‐Cineol Derivatives. Part 7. Anomalous Nucleophilic Substitution of 2‐Tosyloxy Derivative.
Authors: SZALKOWSKA‐PAGOWSKA H. , PIATKOWSKI K. 
Published: May 2016

AbstractThe azidolysis of the tosylate (Ib) (obtained from the dihydropinol (Ia)) in DMF or NMP gives a racemic azide (II)/(III) and an optically active azide (IV) whereas in HMPA (IV) is formed exclusively.