bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Diels‐Alder Cycloaddition: Synthesis and Oxa‐di‐π Rearrangement of Tricyclo(5.2.2.02,6)undecadienone.
Authors: SINGH V. K. , DEOTA P. T. , RAJU B. N. S. 
Published: May 2016

AbstractThe cyclohexadienone (II), obtained by retro‐Diels‐Alder cleavage of the dimer (I), undergoes cycloaddition reaction with the cyclopentadienes (III) to produce the adducts (IV) which are deacetylated, yielding the keto alcohols (V).
ChemInform Abstract: An Efficient Asymmetric Synthesis of Trisubstituted Cyclohexenones and Trisubstituted Cyclopentenones from Chiral 2,2‐Dialkyl 1,4‐ and 1,5‐Diketones.
Authors: MEYERS A. I. , LEFKER B. A. 
Published: May 2016

AbstractThe bicyclic γ‐lactam (II), prepared by stepwise alkylation of (I), reacts with the organolithium compounds (IIIa) and (IIIb) to give the adducts (IV) which are dehydrated, yielding the olefins (V).
ChemInform Abstract: Reaction of Tricyclo(4.1.0.02,7)heptyl‐1‐lithium with Iodotrifluoromethane.
Authors: VASIN V. A. , BOLUSHEVA I. YU. , TANASEICHUK B. S. 
Published: May 2016

AbstractThe reaction of the title compound (II) with CF3I affords the iodo derivative (III) instead of the expected trifluoromethyl derivative.
ChemInform Abstract: A General Synthesis of Allenic Sulfones from Acetylenes Using Selenosulfonation.
Authors: BACK T. G. , KRISHNA M. V. , MURALIDHARAN K. R. 
Published: May 2016

AbstractThe terminal acetylenes (I) react with the selenosulfonates (II) in the presence of AIBN to produce the adducts (III).
ChemInform Abstract: Synthesis and Mesomorphous Properties of Some Derivatives of Cyclohexanecarboxylic Acid.
Authors: BEZBORODOV V. S. 
Published: May 2016

AbstractThe title compounds, i.e. the cis‐ or trans‐methoxyphenylcyclohexanecarboxylic acids (XI), (XIV), (XX) and (XXI) and their p‐cyanophenyl esters (XII), (XV), (XXII) and (XXIII) are prepared.
ChemInform Abstract: Aromatic Carbon‐Hydrogen Bond Activation. Novel Synthesis of 1‐Naphthol Derivatives by Palladium Catalyzed Cyclocarbonylation of Cinnamyl Compounds.
Authors: KOYASU Y. , MATSUZAKA H. , HIROE Y. , UCHIDA Y. , HIDAI M. 
Published: May 2016

AbstractThe cinnamyl derivatives (I) react with carbon monoxide (II) and acetic anhydride (III) in the presence of a palladium catalyst to produce the acetoxynaphthalenes (IV).
ChemInform Abstract: Nuclear vs. Side‐Chain Reactivity in the Anodic Oxidation of 2‐(4‐Alkylphenoxy)ethanol Derivatives. An Interesting Effect of the 2‐Hydroxyethyl Group.
Authors: CAPPARELLI M. P. , DESCHEPPER R. S. , SWENTON J. S. 
Published: May 2016

AbstractElectrochemical oxidation of the hydroxyethyl aryl ethers (Ia) ‐ (Id) and (V) is performed in a methanolic solution of potassium fluoride, yielding the methoxydienone acetals (III) and (VI) which are hydrolyzed to give the methoxydienones (IV) and (VII).
ChemInform Abstract: A Convenient Synthesis of Phenanthrene Analogues: Photolytic Reaction of Aromatic Compounds Having Bis(phenylthio)methyl Group.
Authors: SUGIMOTO A. , OKADA M. , YONEDA S. 
Published: May 2016

AbstractOn irradiation the title compounds (I) and (III) react to give the polycyclic products (II) and (IV), resp., while the alkene (VI) is obtained from the reaction of the thioether (V).
ChemInform Abstract: Diels‐Alder Reaction of Furfuryl‐N‐arylamines with Acrylonitrile.
Authors: LEKHOK K. C. , KANDOLI J. C. , PRAJAPATI D. , SANDHU J. S. 
Published: May 2016

AbstractThe title reaction between (I) and (II) furnishes the Diels‐Alder adducts (III) together with minor amounts of the isomers (IV).
ChemInform Abstract: Recyclization of Pyrrolo(1,2‐a)isoquinolines into Benz(g)indoles.
Authors: SHKIL' G. P. , TERENIN V. I. , DORDINA E. L. , ATAVIN E. G. , BUNDEL' YU. G. , SAGITULLIN R. S. 
Published: May 2016

AbstractThe 7‐nitropyrroloisoquinolines (I) isomerize on heating with potassium hydroxide to give the benz(g)indoles (II).
ChemInform Abstract: Efficient (4+1) Syntheses of Highly Functionalized Cyclopentenes.
Authors: NANTZ M. H. , RADISSON X. , FUCHS P. L. 
Published: May 2016

AbstractThe phenylsulfonylcyclopentenes (III) are prepared from the cis‐1,4‐dihalo‐2‐butenes (I) and the activated methyl phenyl sulfones (II).
ChemInform Abstract: Synthesis and Antiviral Activity of 4‐(Arylhydrazono)‐3‐methyl‐1‐(3,5‐dinitrobenzoyl)‐2‐pyrazolin‐5‐ones.
Authors: PANDE A. , SAXENA V. K. 
Published: May 2016

AbstractThe title compounds (IV) are synthesized as shown and tested for their antiviral activity against tobacco mosaic virus(TMV) and Ranikhet disease virus(RDV).
ChemInform Abstract: Azoles. Part 6. A Convenient Synthesis of Polysubstituted Imidazoles from 1‐Protected 2,4,5‐Tribromoimidazoles.
Authors: IDDON B. , KHAN N. 
Published: May 2016

AbstractThe title tribromoimidazole (I) (neurotoxic]) is converted to (IV), (VI), (IX) and (X).
ChemInform Abstract: Simple Preparations of Some Hydantoins of Phenylalanine and α‐MePhe and Their Chiral Stability During N‐3 Alkylation. A Route to the Synthesis of Chiral Amines.
Authors: ANTEUNIS M. J. O. , SPIESSENS L. , DE WITTE M. , CALLENS R. , REYNIERS FR. 
Published: May 2016

AbstractThe title hydantoins (III) are prepared starting from the amino acids (I) and (IV).
ChemInform Abstract: Synthesis of Thiazolidines of the Indole Series from 2‐Chloro‐1‐(indol‐3‐yl)ethanone and Its Derivatives.
Authors: POVALYAEVA O. S. , KURKOVSKAYA L. N. , VIGDORCHIK M. M. , SUVOROV N. N. 
Published: May 2016

AbstractThe reactions of the 3‐indolyl chloromethyl ketones (I) with biologically active amines ‐ homoveratrylamine (II), cysteamine, applied as its hydrogen tartrate (IV) and cystamine (IX) or its hydrochloride (VII) ‐ are studied.
ChemInform Abstract: Synthesis of Thiazolyl‐pyrazolines and Isoxazolines from Acrylothiazoles and Their Microbial Activity.
Authors: GAWANDE N. G. , SHINGARE M. S. 
Published: May 2016

AbstractThe thiazoles (III) (no yields given) serve as starting material for the synthesis of the desired title compounds (V) and (VII).
ChemInform Abstract: A Stereoselective Construction of the Adjacent Tertiary and Quaternary Carbons by the Michael Addition.
Authors: YAMAGUCHI M. , HAMADA M. , NAKASHIMA H. , MINAMI T. 
Published: May 2016

AbstractThe cyclopentenylcarboxamides (I) are converted to the enolates and then coupled with the acrylates or crotonates (II), yielding the isomers (III) and (IV).
ChemInform Abstract: Synthesis of Benzo(1,2‐b;5,4‐b′)dipyran Derivatives. Part 2.
Authors: GOHAR A.‐K. M. N. , ABDEL‐LATIF F. F. 
Published: May 2016

AbstractIn order to obtain biologically interesting ring systems which are related to chromone the compound (III) is synthesized as starting material.
ChemInform Abstract: Synthesis of 3‐Methyl‐6‐(2′‐hydroxyethyl)‐7‐formyl‐1,8‐diethoxyisoquinoline: A Key Synthon for Fredericamycin A.
Authors: RAO A. V. R. , REDDY D. R. 
Published: May 2016

AbstractReaction of the acetylene (I) with the ethoxyoxazole (II) yields the furan ester (III) which is transformed into the dimethyl isophthalate (VII) by cycloaddition with the allene (IV) and subsequent reduction and ozonolysis.
ChemInform Abstract: Synthesis of 9‐Substituted‐oxy Acridine and 1, 2, 3, 4‐Tetrahydroacridine Derivatives as Potential Biodynamic Agents.
Authors: ASTHANA P. , PRASAD M. , RASTOGI S. N. 
Published: May 2016

AbstractA series of title compounds is prepared by common methods.
ChemInform Abstract: Brominations of Cyclic Acetals from α‐Amino Acids and α‐ or β‐Hydroxy Acids with N‐Bromosuccinimide.
Authors: ZIMMERMANN J. , SEEBACH D. 
Published: May 2016

AbstractBromination of the dioxolane (I), derived from (S)‐lactic acid, gives a single bromide (II), from which the (S)‐configurated pyruvic acid derivative (III) is prepared.
ChemInform Abstract: Ring Closure of ortho‐Blocked 4‐Aryl‐1,2,4‐triaza‐1,3‐dienes via 1,6‐Electrocyclization Followed by Diels‐Alder Dimerization.
Authors: TRAVE R. , GARANTI L. , ZECCHI G. 
Published: May 2016

AbstractTreatment of the hydrazines (III) with MnO2 affords the bridged heterocyclic compounds (IV) along with the isonitrile (V), whose formation is observed in each of the reactions.
ChemInform Abstract: Studies on as‐Triazine Derivatives. Part 9. Synthesis of 5‐Substituted 1,2,4‐Triazine Derivatives Through an Addition Reaction and Subsequent Oxidation.
Authors: KONNO S. , OHBA S. , SAGI M. , YAMANAKA H. 
Published: May 2016

AbstractThe reduction of the chlorotriazine (I) under controlled conditions yields the triazine (II), which is substituted by various nucleophiles such as cyanide or the methylene compounds (VIa) ‐ (VIc) to give the triazine derivatives (III), (IV), (V), or (VIIa) ‐ (VIIc).
ChemInform Abstract: Unusual Reactions between 1,4‐Dihydropyridines and 1,2,4,5‐Tetrazines in the Presence of K‐10/Fe(III) Clay Catalyst.
Authors: BALOGH M. , LASZLO P. , SIMON K. 
Published: May 2016

AbstractThe dihydropyridine (I) reacts with the tetrazines (II) in the presence of a K‐10/Fe(III) clay catalyst to give a mixture of the pyridazines (III) and the dihydrotetrazines (IV).
ChemInform Abstract: Reaction of Azines with Aromatic Ketones. Synthesis of α,β‐Unsaturated Azines and 5,6‐Dihydro‐4H‐1,2‐diazepines.
Authors: BARLUENGA J. , IGLESIAS M. J. , GOTOR V. 
Published: May 2016

AbstractTreatment of the azines (II) with lithium diisopropylamide, followed by reaction with the aromatic ketones (I), yields the monohydroxyazines (III) and the dihydroxyazines (V).
ChemInform Abstract: Bridged Diquaternary Salts from 3,3′‐Bipyridine.
Authors: SINGH S. K. , SUMMERS L. A. , HICK L. A. 
Published: May 2016

AbstractThe bipyridine (I) reacts with α,ω‐dibromoalkanes such as (II) to give the bridged diquaternary salts (III).
ChemInform Abstract: Reduction and Oxidation of Carbon‐Carbon Double Bonds of 1,1,4,4‐Tetrakis(trimethylsilyl)butatriene.
Authors: KUSUMOTO T. , HIYAMA T. 
Published: May 2016

AbstractCatalytic hydrogenation of the tetrasilylbutatriene (I) yields Z/E‐mixtures of the olefin (III) via the allene (II).
ChemInform Abstract: Synthesis and Properties of Organo(isopropylideneaminooxy)isocyanatosilanes.
Authors: FEDOTOV N. S. , ABRAMOV A. V. , SHELUDYAKOV V. D. 
Published: May 2016

AbstractThe title compounds (III) are synthesized from the silanes (I) and the isocyanate (II) or urea (IV).
ChemInform Abstract: Palladium Catalyzed Double Silylation of Bis(trimethylsilyl)butadiyne by Means of Disilanes.
Authors: KUSUMOTO T. , HIYAMA T. 
Published: May 2016

AbstractReaction of 1,4‐bis(trimethylsilyl)butadiyne (I) with the methylated chlorodisilanes (II) in the presence of Pd catalysts and subsequent treatment with excess methylmagnesium bromide (III) yield tetrakis(trimethylsilyl)butatriene (IV) and the enyne (V) as the main products, together with the disilacyclohexadienes (VI) and (VII).
ChemInform Abstract: Synthesis and Structure of Polyspirocyclodimethylsiloxanes.
Authors: ZACHERNYUK A. B. , ZHDANOV A. A. , SHKLOVER V. E. 
Published: May 2016

AbstractHydrolysis of the cyclosiloxanes (I) or (III) with a stoichiometric amount of water in the presence of pyridine leads to the formation of the polyspirocyclosiloxanes (II) and (IV) respectively.
ChemInform Abstract: Synthesis and Structure of 4,4‐Dimethyl‐1‐thia‐4‐sila‐2,3,5,6‐bis(1′,2′‐o‐ carborano)cyclohexane.
Authors: ZAKHARKIN L. I. , SHEMYAKIN N. F. , POLYAKOV A. V. , YANOVSKII A. I. , STRUCHKOV YU. T. 
Published: May 2016

AbstractThe title compound (II) is prepared from the dilithium compound (I) and sulfur dichloride.
ChemInform Abstract: p‐Methoxyphenacyl Esters as Photodeblockable Protecting Groups for Phosphates.
Authors: EPSTEIN W. W. , GARROSSIAN M. 
Published: May 2016

AbstractReaction of α‐diazo‐p‐methoxyacetophenone (I) with the hydrogen phosphates (II) yields the p‐methoxyphenacyl phosphates (III) which are cleaved by photolysis to form the radicalic intermediates (IV) and (V).
ChemInform Abstract: Complexes of 2,2′,2′′‐Nitrilotriphenol. Part 4. Cage Compounds with Phosphorus(III) and Phosphorus(V).
Authors: MUELLER E. + , BUERGI H.‐B. + 
Published: May 2016

Abstract(III) and (VI), resp., are prepared as well as the hydrolysis product (VIII) of (III).
ChemInform Abstract: Thio‐ and Selenoacrylamide Derivatives from Ynamines and Transition Metal‐Coordinated Thio‐ and Selenoaldehydes and ‐ketones.
Authors: FISCHER H. , TIRILIOMIS A. , GERBING U. , HUBER B. , MUELLER G. + 
Published: May 2016

AbstractReaction of the chromium or tungsten thio‐ or selenocarbonyl complexes (I) with the diethylaminopropyne (II) gives the adducts (III) which are cleaved to form the acrylamide derivatives (IV) by treatment with carbon monoxide.
ChemInform Abstract: Symmetrization of Cyclic σ‐Telluranes.
Authors: SADEKOV I. D. , RIVKIN B. B. , MASLAKOV A. G. , MINKIN V. I. 
Published: May 2016

AbstractReaction of 5,5‐dichlorodibenzotellurophene (I) with tellurium tetrachloride gives the bis(trichlorotelluryl)biphenyl (II) which is reduced with sodium metabisulfite, forming dibenzotellurophene (III) and the polymeric ditelluride (IV).
ChemInform Abstract: Complexes with Phosphinomethane and ‐methanide Ligands. Part 13. ((μ‐(Me3Si)C(PMe2)2)2Ge2)2GeCl2, a Germanediyl Donor‐Germanediyl Acceptor Complex with a Mixed‐Valent Ge5 Chain.
Authors: KARSCH H. H. , DEUBELLY B. , RIEDE J. , MUELLER G. + 
Published: May 2016

AbstractThe crystalline title complex (III) containing a Ge(I)‐Ge(I)‐Ge(II)‐Ge(I)‐Ge(I) chain is obtained as shown.
ChemInform Abstract: Neighboring Group Participation in Organometallic Chemistry: Internal Exchange in (Diarylalkane)tricarbonylchromium Complexes.
Authors: TRAYLOR T. G. , GOLDBERG M. J. 
Published: May 2016

AbstractComplexation of a phenyl group of the arenes (I) by a Cr(CO)3 moiety to yield (III) causes an upfield shift in both aromatic and benzylic protons associated with the complexed ring, as well as a lowered acidity for these protons vs.
ChemInform Abstract: 4‐Vinyl‐, 6‐Vinyl‐, and 4′‐Vinyl‐2,2′:6′,2′′‐terpyridinyl Ligands: Their Synthesis and the Electrochemistry of Their Transition‐Metal Coordination Complexes.
Authors: POTTS K. T. , USIFER D. A. , GUADALUPE A. , ABRUNA H. D. 
Published: May 2016

AbstractThe compound (IVa), prepared in an important improvement over published methods from (I) in an "one‐pot" reaction, reacts via the derivatives (IVb) and (IVc) to give one of the title ligands, (VII).
ChemInform Abstract: Formation of Luminescent, Bent Ir‐Tl‐Ir and Ir‐Pb‐Ir Chains Through the Binding of Thallium(I) and Lead(II) to the Iridium Metallomacrocycle Ir2(CO)2Cl2(μ‐(Ph2PCH2)2AsPh)2.
Authors: BALCH A. L. , NAGLE J. K. , OLMSTEAD M. M. , REEDY P. E. JUN. 
Published: May 2016

AbstractThe title complex (I) reacts with Tl(I) and Pb(II) nitrate (II) to give the new trinuclear complexes (III) that are luminescent in solution at room temperature.
ChemInform Abstract: Second Sphere Coordination of Tetraammineplatinum(II) by a Macropolycyclic Crown Ether Bisamide Receptor.
Authors: ALSTON D. R. , SLAWIN A. M. Z. , STODDART J. F. , WILLIAMS D. J. , ZARZYCKI R. 
Published: May 2016

AbstractThe preparation of the macropolycyclic crown ether bisamide (VIII) occurs in eight steps according to the scheme.
ChemInform Abstract: Macrobicyclic Polyethers as Second Sphere Ligands for Tetraammineplatinum(II).
Authors: ALSTON D. R. , SLAWIN A. M. Z. , STODDART J. F. , WILLIAMS D. J. , ZARZYCKI R. 
Published: May 2016

AbstractX‐ray structure analysis confirms that a T‐arrangement of two benzene rings contributes ‐ aside from H‐bridges between all the NH3 ligands and the ether‐O atoms ‐ to the stabilization of the 2:1 adduct (Ia) of the corresponding tetramethyl‐substituted macrobicyclic polyether and (Pt(NH3)4)2+ in the solid state (space group P21/c, Z=2).
ChemInform Abstract: Platinacyclobutane Chemistry: Platinacyclobutanes from Bicyclo (X.1.0) Hydrocarbons.
Authors: PARSONS E. J. , JENNINGS P. W. 
Published: May 2016

AbstractReaction of the bicyclic compounds (I) with Zeise's dimer (II) gives the platinacyclobutanes (III).
ChemInform Abstract: Studies in the Chemical Constituents of Azadirachta indica A. Juss (Meliaceae). Part 10. Isolation and Structure Elucidation of Isonimolicinolide, the First 17‐Acetoxy Tetranortriterpenoid and Nimolicinoic Acid, the First Hexanortriterpenoid with an Apoeuphane (Apotirucallane) Skeleton.
Authors: SIDDIQUI S. , MAHMOOD T. , FAIZI S. , SIDDIQUI B. S. 
Published: May 2016

AbstractThe title compounds (I) and (II) are isolated from the title species.
ChemInform Abstract: A Novel Preparation of Amino Acid Diphenylmethyl Esters and Their Application in Peptide Synthesis.
Authors: BARLOS K. , KALLITSIS J. , MAMOS P. , PATRIANAKOU S. , STAVROPOULOS G. 
Published: May 2016

AbstractThe amino acid derivatives (V), prepared from (I) and (II), are coupled with the active esters (VI) to give the dipeptide derivatives (VII).
ChemInform Abstract: Application of Cinnamyloxycarbonyl (Coc) Protection During the Synthesis of Coc‐Pro‐MePhe‐MeAla‐OMe. Chain Rupture of the Tripeptide on Chromatography.
Authors: SHARMA N. K. , ANTEUNIS M. J. O. 
Published: May 2016

AbstractCoupling of the dipeptide (V) with the protected amino acid (IV) yields a mixture of the title tripeptide (VIII) and the cyclic dipeptide (IX).
ChemInform Abstract: Practical Synthesis of (R)‐γ‐Amino‐β‐hydroxybutanoic Acid (GABOB) from (R)‐Epichlorohydrin.
Authors: TAKANO S. , YANASE M. , SEKIGUCHI Y. , OGASAWARA K. 
Published: May 2016

AbstractThe betaine (R)‐(VI) is prepared from (R)‐epichlorohydrin (I) as shown in the reaction scheme.
ChemInform Abstract: Regioselective Acylation of Secondary Hydroxyl Groups in Sugars Catalyzed by Lipases in Organic Solvents.
Authors: THERISOD M. , KLIBANOV A. M. 
Published: May 2016

AbstractTransesterification between the C‐6 blocked glucose (I) and the butyrate (II) in the presence of some commercially available lipases proceeds either at the C‐3 or C‐2 hydroxyl group to give the products (III) and/or (IV).
ChemInform Abstract: The Question of Chair‐Twist Equilibria for the Phosphate Rings of Nucleoside Cyclic 3′,5′‐Monophosphates. 1H NMR and X‐Ray Crystallographic Study of the Diastereomers of Thymidine Phenyl Cyclic 3′,5′‐Monophosphate.
Authors: NELSON K. A. , BENTRUDE W. G. , SETZER W. N. , HUTCHINSON J. P. 
Published: May 2016

AbstractThe cis‐ and trans‐thymidine monophosphates (VIb) and (VIII) are prepared starting from thymidine (I) via the phosphoramide (III) and the cis‐phosphites (V).
ChemInform Abstract: Mechanistic Studies on Dopamine β‐Monooxygenase Catalysis: N‐Dealkylation and Mechanism‐Based Inhibition by Benzylic‐Nitrogen‐Containing Compounds. Evidence for a Single‐Electron‐Transfer Mechanism.
Authors: WIMALASENA K. , MAY S. W. 
Published: May 2016

AbstractDopamine β‐monooxygenase (DBM) readily catalyzes oxidative N‐dealkylation of (I) to anilines (II) and aminoaldehyde (III).
ChemInform Abstract: Structure of FR 900482, a Novel Antitumor Antibiotic from a Streptomyces.
Authors: UCHIDA I. , TAKASE S. , KAYAKIRI H. , KIYOTO S. , HASHIMOTO M. , TADA T. , KODA S. , MORIMOTO Y. 
Published: May 2016

AbstractThe title compound is shown to be an epimeric mixture of (Ia) and (IIa) (ca.
ChemInform Abstract: Chemomechanical Polishing and Etching of GaAs:In and GaAs in Aqueous Solutions of NaOCl.
Authors: KHOUKH A. , KRAWCZYK S. K. , OLIER R. , CHABLI A. , MOLVA E. 
Published: May 2016

AbstractIt is shown that the In concentration in alloyed GaAs crystals has a strong influence on polishing and etching in aqueous NaOCl.
ChemInform Abstract: Voltammetry of Cadmium in Sodium Hydroxide Solutions Containing Sodium Sulphide.
Authors: SAIDMAN S. B. , VILCHE J. R. , ARVIA A. J. 
Published: May 2016

AbstractDuring anodization of Cd in a solution of low Na2S content, a complex cadmium oxide hydroxide and CdS layer is formed, whereas at high Na2S concentration, a CdS layer in the thickness range of a few monolayers is formed.
ChemInform Abstract: Aqueous Electrochemistry of Cuprate‐Based High Tc Superconductors.
Authors: ROSAMILIA J. M. , MILLER B. , SCHNEEMEYER L. F. , WASZCZAK J. V. , O'BRYAN H. M. JUN. 
Published: May 2016

AbstractThe open‐circuit (spontaneous) dissolution and resulting potentials of Ba2YCu3O7 (Tc = 93 K) (I) and La1.8Sr0.2CuO4 (Tc = 36.2 K) (II) have been studied in 1 M NaCl solutions containing 1‐10 mM HCl by using the rotating ring‐disk electrode technique.
ChemInform Abstract: Photochemistry of Multiply Bonded Dimolybdenum Phosphate Complexes in Acidic Solution: Photoinduced Two‐Electron Oxidation of Mo2(HPO4)4‐ 4 Ion.
Authors: CHANG I‐J. , NOCERA D. G. 
Published: May 2016

AbstractThe dimers Mo2(HPO4)44‐ (I) and Mo2(HPO4)43‐ (II) have been prepared and spectroscopically (EPR, resonance Raman and absorption spectroscopy) and electrochemically characterized.
ChemInform Abstract: Synthesis of CdTe by Means of Fused Salt Electrolysis and Its Characterization.
Authors: MINOURA H. , KITAKATA M. , SUGIURA T. , MURAYAMA M. , UENO Y. 
Published: May 2016

AbstractCubic CdTe layers have been deposited potentiostatically on graphite cathodes by means of fused salt electrolysis using CdCl2 and TeO2/Na2TeO3 in an eutectic LiCl‐KCl melt at 450 °C. XRD and SEM results show that these layers grow with a preferred orientation along the (111) direction and that the surface morphology depends significantly on the applied potential.
ChemInform Abstract: On NaMn3F10.
Authors: WANDNER K.‐H. , HOPPE R. 
Published: May 2016

AbstractBrownish red single crystals of the hitherto unknown title compound are obtained by thermal decomposition of a mixture of Na2MnF6 and MnF3 at 600 °C during 7 d (Au‐tube, under Ar).
ChemInform Abstract: Temperature and Solvent Dependence of Scalar Coupling Constants in Salts of trans‐HFe(CO)3PR‐ 3.
Authors: ASH C. E. , DARENSBOURG M. Y. , HALL M. B. 
Published: May 2016

AbstractVariable NMR parameters depending on temp. and solvent (THF, acetone, DMSO, CD3CN) are observed for the anions (I).
ChemInform Abstract: The Reaction of Trimethylchloro‐ and Trimethylbromosilane‐Dimethyl Sulfoxide Reagent Systems on Alkenes. Synthesis of 2‐Chloroalkyl and 2‐Chlorocycloalkyl Methyl Sulfides.
Authors: BELLESIA F. , GHELFI F. , PAGNONI U. M. , PINETTI A. 
Published: May 2016

AbstractThe title synthesis under reaction conditions A) proceeds via formation of a sulfonium species (III) or (IV) and subsequent addition of Me‐S‐Cl to an olefinic double bond.
ChemInform Abstract: Alkoxycarbonylnitrenes as Selective Intramolecular CH‐Insertion Reagents in Alicyclic Chemistry.
Authors: MARAIS P. C. , METH‐COHN O. 
Published: May 2016

AbstractNitrenoformates, e.g. (IV), are generated a) by thermolysis (vapour‐phase (spray) pyrolysis or solution thermolysis) of azidoformates such as (Ia)/(Ib), (Ie), (If), (IXa), (IXb), (XIVa), (XIVb) or b) by photolysis of respective tetrachlorothienyl S,N‐ylides such as (Ic)/(Id).
ChemInform Abstract: Oxidative Rearrangement of Aryl Ethyl Ketones to Alkyl 2‐Arylpropanoates by Lead(IV) Acetate.
Authors: YAMAUCHI T. , NAKAO K. , FUJII K. 
Published: May 2016

AbstractOxidative rearrangement of the propiophenones (I) in trialkyl orthoformate (II) proceeds via 1,2‐aryl migration to give the esters (III).
ChemInform Abstract: Gas Phase Chemistry of CH·‐ 2.
Authors: DEPUY C. H. , BARLOW S. E. , VAN DOREN J. M. , ROBERTS C. R. , BIERBAUM V. M. 
Published: May 2016

AbstractBy electron impact on either ethylene or methane, a variety of negative ions are produced among which the CH·‐ 2 in the tandem flowing afterglow‐selected ion flow tube used can be generated, separated, injected, and detected.
ChemInform Abstract: Kinetic Resolution in the Directed Hydrogenation of N‐Substituted α‐(Aminoalkyl)acrylates, Precursors of Optically Active β‐Amino Acids.
Authors: BROWN J. M. , JAMES A. P. , PRIOR L. M. 
Published: May 2016

AbstractThe 2‐(hydroxyalkyl)acrylates (I) are converted to the aminoalkyl derivatives (IV) by known methods.
ChemInform Abstract: Coadsorption as a Probe of Mechanism: Cyclic Sulfides and Straight Chain Thiols on Mo(110).
Authors: ROBERTS J. T. , FRIEND C. M. 
Published: May 2016

AbstractCoadsorbed cyclic sulfides CnH2nS (n = 3, 4) and linear thiols CmH2m+1SH (m = 2, 3, 4) react during a temp.‐programmed reaction experiment to form alkanes CnH2n+2 and CmH2m+2.