bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Nitrated Confined Imidodiphosphates Enable a Catalytic Asymmetric Oxa‐Pictet—Spengler Reaction.
Authors: Das Sayantani , Liu Luping , Zheng Yiying , Alachraf M. Wasim , Thiel Walter , De Chandra Kanta , List Benjamin 
Published: December 2016

AbstractUsing chiral nitrated iminodiphosphoric acid‐derived catalyst BPI, title reaction between m‐hydroxyphenylethanols and aldehydes give the 6‐hydroxy‐3,4‐dihydrobenzo[c]pyrans in high yields and excellent enantioselectivities.
ChemInform Abstract: Highly Selective and Modular Synthesis of 3‐Aryl‐4‐(arylethynyl)‐2H‐chromen‐2‐ones from 2‐Iodoaryl 2‐Arylacetates Through a Carbonylative Sonogashira Coupling‐Intramolecular Aldol Cascade Reaction.
Authors: Chandrasekhar Attoor , Ramkumar Venkatachalam , Sankararaman Sethuraman 
Published: December 2016

AbstractA modular method for the synthesis of the title chromenones is developed based on a carbonylative Sonogashira coupling‐intramolecular aldol cascade reaction starting from iodoaryl arylacetates.
ChemInform Abstract: Bi(OTf)3‐Catalyzed Addition of Isocyanides to 2H‐Chromene Acetals: An Efficient Pathway for Accessing 2‐Carboxamide‐2H‐chromenes.
Authors: Lyu Longyun , Jin Ming Yu , He Qijie , Xie Han , Bian Zhaoxiang , Wang Jun 
Published: December 2016

AbstractAn efficient Bi(OTf)3‐catalyzed addition reaction for accessing 2H‐chromene‐2‐carboxamide derivatives is reported.
ChemInform Abstract: KH2PO4 Promoted Practical and Environmentally Friendly Preparation of Coumarin‐3‐carboxylic Acids under Solvent‐Free Condition.
Authors: Lv Chengwei , Gao Shuangqiu , Xiao Di , Yang Ying , Wei Xiaoyue , Sun Sai , Lang Jian 
Published: December 2016

AbstractA green Knoevenagel‐intramolecular cyclization cascade reaction of Meldrum′s acid with ortho‐hydroxybenzaldehydes affords 3‐coumarincarboxylic acids in good to high yields.
ChemInform Abstract: A Mixed Ligand Approach for the Asymmetric Hydrogenation of 2‐Substituted Pyridinium Salts.
Authors: Renom‐Carrasco Marc , Gajewski Piotr , Pignataro Luca , de Vries Johannes G. , Piarulli Umberto , Gennari Cesare , Lefort Laurent 
Published: December 2016

AbstractThe title reaction gives 2‐substituted piperidines with full conversion and good enantioselectivity using iridium as catalyst and a mixed ligand of a chiral monodentate phosphoramidite and an achiral phosphine.
ChemInform Abstract: A Green, Solvent‐Free One‐Pot Synthesis of Disubstituted Quinolines via A3‐Coupling Using 1 mol% FeCl3.
Authors: Jeena Vineet , Naidoo Shivani 
Published: December 2016

AbstractA three‐component coupling reaction of anilines with aldehydes and terminal alkynes affords quinolines in moderate to good yields under solvent‐free, microwave irradiation conditions.
ChemInform Abstract: Experimental and Theoretical Observations on the Intramolecular Nucleophilic Addition of α‐Amino Carbanions to Arynes: Synthesis of 1‐Aryl‐1,2,3,4‐tetrahydroisoquinolines.
Authors: Kaur Manjot , Sharma Esha , Singh Amritpal , Singh Paramjit , Singh Kamal Nain 
Published: December 2016

AbstractA new method involving an intramolecular nucleophilic addition of α‐amino carbanions to in‐situ‐generated arynes in N‐Boc‐protected amine substrates is presented for the synthesis of aryltetrahydroisoquinolines.
ChemInform Abstract: Synthesis of Isoquinolinium via Rhodium(III)‐Catalyzed Oxidative Annulation Between Aldimines and Alkynes.
Authors: Dong Lin , Su Fu , Wang Cheng‐Qi , Zhang Wei , Lin Hui 
Published: December 2016

AbstractA cyclization of aldehyde imines with alkynes yields isoquinolinium triflates efficiently.
ChemInform Abstract: Copper(II) Trifluoromethanesulfonate Catalyzed Hydroamination Cyclization—Dimerization Cascade Reaction of Homopropargylic Amines for the Construction of Complex Fused Nitrogen‐Containing Tetracycles.
Authors: Liu Lingyan , Wang Chan , Liu Qiangqiang , Kong Yuanfang , Chang Weixing , Li Jing 
Published: December 2016

AbstractIn the case of N,4‐bisarylhomopropargylamines, the reaction proceeds with high diastereoselectivity affording octahydro‐dipyrroloquinolines.
ChemInform Abstract: Efficient Three‐Component Synthesis of Diversely Substituted Tetrahydro‐1H‐cyclopenta[c]quinolines.
Authors: Nino Patricia , Caba Marta , Aguilar Nuria , Terricabras Emma , Albericio Fernando , Fernandez Joan‐Carles 
Published: December 2016

AbstractThe title compounds are prepared by Parov reaction of cyclopentadiene, anilines, and benzaldehydes.
ChemInform Abstract: Regioselective Synthesis of Functionalized [1,6]‐Naphthyridines by KF/Basic Alumina as a Recyclable Catalyst and a Brief Study of Their Photophysical Properties.
Authors: Nandi Sibaji , Islam Mullah Muhaiminul , Saha Mithu , Mitra Sivaprasad , Khatua Snehadrinarayan , Pal Amarta Kumar 
Published: December 2016

AbstractAn efficient, regioselective synthesis of functionalized naphthyridines (IV) (16 examples) via a KF‐Al2O3 catalyzed multicomponent reaction under solvent‐free conditions is developed.
ChemInform Abstract: Selective Synthesis of New Tetracyclic Coumarin‐Fused Pyrazolo[3,4‐b]pyridines and Pyrazolo[3,4‐b]pyridin‐6(7H)‐ones.
Authors: Liu Meilin , Yin Guodong , Zhu Can , Yao Chaochao 
Published: December 2016

AbstractDepending on the reaction conditions, the three‐component reaction of (I), (III), and an aldehyde affords three different compounds, i.e.
ChemInform Abstract: Fluoride‐Assisted Synthesis of 1,4,5,6‐Tetrahydropyridazines via [4 + 2] Cyclodimerization of in situ‐Generated Azoalkenes Followed by a C—N Bond Cleavage.
Authors: Shelke Anil M. , Suryavanshi Gurunath 
Published: December 2016

AbstractA series of 1,4,5,6‐tetrahydropyridazines (II) is prepared by homo‐cyclodimerization of α‐halo acylhydrazones (I) in the presence of K2CO3 and CsF (16 examples, however, the halogen in starting α‐halo acylhydrazones is specified only for 3 examples).
ChemInform Abstract: Highly Fluorescent 1,2‐Dihydropyrimido[1,6‐α]indole: An Efficient Metal Free Synthesis and Photophysical Study.
Authors: Das Tapas , Kayet Anirban , Mishra Ruchika , Singh Vinod K. 
Published: December 2016

AbstractTitle compounds (III) are formed via a base catalyzed aldol condensation of indole‐carbaldehydes (I) and arylideneglycinates (II) followed by an intramolecular Mannich‐type reaction.
ChemInform Abstract: One‐Pot Synthesis of Novel 2,8‐Dithioxopyrano[2,3‐d:6,5‐d′]dipyrimidine‐4,6(1H)‐dione Catalyzed by p‐Toluenesulfonic Acid.
Authors: Mahmoodi N. O. , Sharifzadeh B. , Mamaghani M. , Tabatabaeian K. , Shoja S. 
Published: December 2016

AbstractTitle compounds (III) are prepared by TosOH‐catalyzed reaction of aromatic aldehydes with (substituted) thiobarbituric acid.
ChemInform Abstract: Heck Reaction as Key Step in the Synthesis of Hydrogenated 2‐Benzazepin‐1‐ones.
Authors: Quick Matthias P. , Wuensch Bernhard 
Published: December 2016

AbstractUsing 2‐iodobenzoic acid as common starting material, two 2‐benzazepin‐1‐one derivatives (VIII) and (XII) are prepared.
ChemInform Abstract: Iron‐Catalyzed Hydroboration: Unlocking Reactivity Through Ligand Modulation.
Authors: Espinal‐Viguri Maialen , Woof Callum R. , Webster Ruth L. 
Published: December 2016

AbstractA new catalytic system without the requirement of external reducing agents or activators is developed which is applied to the hydroboration of a broad range of alkenes, including terminal alkyl and styrene derivatives, internal alkenes and dialkenes.
ChemInform Abstract: Lewis Acid Catalysis: Catalytic Hydroboration of Alkynes Initiated by Piers′ Borane.
Authors: Fleige Mirco , Moebus Juri , vom Stein Thorsten , Glorius Frank , Stephan Douglas W. 
Published: December 2016

AbstractTerminal and internal alkynes are efficiently hydroborated to (E)‐alkenyl pinacol boronic esters with excellent yields and selectivities using a Lewis acid catalyst.
ChemInform Abstract: One‐Pot Synthesis of New Highly Substituted Allylic Phosphorodiamidates.
Authors: Bahri Leila , Barhoumi‐Slimi T. , Mallek R. , Sanhoury M. A. K. , Crousse B. , Ben Dhia M. T. 
Published: December 2016

AbstractThe title phosphorodiamidates are obtained in mixtures of Z and E isomers by phosphorylation of the corresponding alcohols followed by aminolysis.
ChemInform Abstract: Ring Annulation versus Alkylation of Pyrrole with α‐Phosphoryl‐α,β‐unsaturated Ketones.
Authors: Tasgin Dilek Isik , Unaleroglu Canan 
Published: December 2016

AbstractA facile and convenient route for the synthesis of (het)aryl and phosphoryl substituted pyrrolizines through Sc(OTf)3 catalyzed reaction of α‐phosphoryl‐α,β‐unsaturated ketones with pyrrole is developed.
ChemInform Abstract: Metal‐Free Arylation to Access Distinct Anthracenylphosphonates and Anticancer Activities for These and Allied Phosphonates.
Authors: Baig M. Zubair K. , Pallikonda Gangaram , Trivedi Prakruti , Tulichala R. N. Prasad , Ghosh Balaram , Chakravarty Manab 
Published: December 2016

AbstractCompound (IIId) shows promising anti‐cancer activity.
ChemInform Abstract: Regioselective, Solvent‐ and Metal‐Free Chalcogenation of Imidazo[1,2‐a]pyridines by Employing I2/DMSO as the Catalytic Oxidation System.
Authors: Rafique Jamal , Saba Sumbal , Rosario Alisson R. , Braga Antonio L. 
Published: December 2016

AbstractVarious diaryl or dialkyl diselenides or disulfides are used for the regioselective C‐3 chalcogenation of imidazo[1,2‐a]pyridines.
ChemInform Abstract: Combretins A and B, New Cycloartane‐Type Triterpenes from Combretum fragrans.
Authors: Dawe Amadou , Kapche Gilbert Deccaux Wabo Fotso , Bankeu Jean Jules Kezetas , Fawai Yakai , Ali Muhammad Shaiq , Ngadjui Bonaventure Tchaleu 
Published: December 2016

Abstractisolation and structure elucidation
ChemInform Abstract: New Highly Oxidized Formamidobisabolene‐Derived Sesquiterpenes from a Hainan Sponge Axinyssa variabilis
Authors: Liu Hai‐Li , Xue Duo‐Qing , Chen Si‐Han , Li Xu‐Wen , Guo Yue‐Wei 
Published: December 2016

Abstractisolation and structure determination
ChemInform Abstract: New Labdane Diterpenoids from Croton laui and Their Antiinflammatory Activities.
Authors: Yang Li , Zhang Yu‐Bo , Chen Li‐Feng , Chen Neng‐Hua , Wu Zhong‐Nan , Jiang Si‐Qi , Jiang Lin , Li Guo‐Qiang , Li Yao‐Lan , Wang Guo‐Cai 
Published: December 2016

AbstractNine new title products are isolated, namely compound (I—IV) and diastereomers thereof, some of which show interesting anti‐inflammatory activities.
ChemInform Abstract: Fmoc‐OASUD: A New Reagent for the Preparation of Fmoc‐Amino Acids Free from Impurities Resulting from Lossen Rearrangement.
Authors: Rao B. Leela Maheswara , Nowshuddin Shaik , Jha Anjali , Divi Murali K. , Rao M. N. A. 
Published: December 2016

AbstractThe novel reagent (II) reacts with amino acids under mild conditions to give Fmoc‐protected amino acids in high yields and purity.
ChemInform Abstract: A Mild Method for Regioselective De‐O‐methylation of Saccharides by Co2(CO)8/Et3SiH/CO System.
Authors: Zhao Yue‐tao , Huang Lu‐bai , Li Qing , Li Zhong‐jun 
Published: December 2016

AbstractThis de‐O‐methylation method shows regioselectivity in different protected monosaccharides.
ChemInform Abstract: Lyciumaside and Lyciumate: A New Diacylglycoside and Sesquiterpene Lactone from Lycium shawii.
Authors: Rehman Najeeb Ur , Hussain Hidayat , Al‐Riyami Samia Ahmed , Csuk Rene , Khiat Mohammed , Abbas Ghulam , Al‐Rawahi Ahmed , Green Ivan R. , Ahmed Ishtiaq , Al‐Harrasi Ahmed 
Published: December 2016

AbstractPreliminary evaluations demonstrated that lyciumaside (I) possesses strong antioxidant activity while it is inactive in α‐glucosidase and urease enzymes assays.
ChemInform Abstract: Isocassiaoccidentalin B, a New C‐Glycosyl Flavone Containing a 3‐Keto Sugar, and Other Constituents from Cassia nomame.
Authors: Syed Ahmed Shah , Akram Muhammad , Bae Ok‐Nam , Kim Chul Young 
Published: December 2016

Abstractisolation, structure elucidation, and free radical scavenging activity
ChemInform Abstract: Total Synthesis of Actinophenanthroline A via Double Doebner—Miller Reaction.
Authors: Ghosh Suman Kr , Nagarajan Rajagopal 
Published: December 2016

AbstractThe total synthesis of actinophenanthroline A, a marine actinomycete within the family of Streptomycetaceae (strain CNQ‐149) is reported.
ChemInform Abstract: Three New Alkaloids from Myrioneuron faberi.
Authors: Cao Ming‐Ming , Zhang Yu , Huang Sheng‐Dian , Peng Zong‐Gen , Jiang Jian‐Dong , Hao Xiao‐Jiang 
Published: December 2016

AbstractStructures of secomyrionamide (I), isomyrionine (II) and 12‐oxomyriberine A (III) are elucidated.
ChemInform Abstract: Two New Alkaloids from the Seeds of Cassia alata and Their Bioactivities.
Authors: Wang Jia‐Qiang , Zhu Dong‐Lai , Yang Pei‐Song , Zhang Wei , Shen Xiao‐Feng , Wang Xin‐Lin , Li Chao , Gong Xiao‐Wei , Zheng Xu‐Dong 
Published: December 2016

AbstractThe new benzo[de]quinolinone alkaloids (Ia) and (Ib) are isolated from the seeds of Cassia alata together with four known alkaloids, and their molecular structures are elucidated.
ChemInform Abstract: Application of a Palladium‐Catalyzed C—H Functionalization/Indolization Method to Syntheses of cis‐Trikentrin A and Herbindole B.
Authors: Leal Raul A. , Bischof Caroline , Lee Youjin V. , Sawano Shota , McAtee Christopher C. , Latimer Luke N. , Russ Zachary N. , Dueber John E. , Yu Jin‐Quan , Sarpong Richmond 
Published: December 2016

AbstractFormal syntheses of racemic cis‐trikentrin A and herbindole B ((I) and (II), resp.) are reported starting from the acetonide of cis‐5,6‐dihydroxy‐endo‐norborn‐2‐ene with Buchwald‐Hartwig amination and novel C(sp3)‐H amination/indole formation as the key steps.
ChemInform Abstract: Strepoxazine A, a New Cytotoxic Phenoxazin from the Marine Sponge‐Derived Bacterium Streptomyces sp. SBT345.
Authors: Cheng Cheng , Othman Eman M. , Fekete Agnes , Krischke Markus , Stopper Helga , Edrada‐Ebel RuAngelie , Mueller Martin J. , Hentschel Ute , Abdelmohsen Usama Ramadan 
Published: December 2016

AbstractStrepoxazine A (I) exhibits cytotoxic activity against leukemia HL‐60 cells.
ChemInform Abstract: Flavonoids and Biphenylneolignans with Antiinflammatory Activity from the Stems of Millettia griffithii.
Authors: Ye Hao‐Yu , et al.  
Published: December 2016

AbstractFive new flavonoids, griffinones A—E ((I)—(V)), and a new biphenylneolignan, griffilignan A are isolated together with ten known compounds.
ChemInform Abstract: Three New Derivatives and Others Constituents from the Roots and Twigs of Trilepisium madagascariense DC.
Authors: Ango Yves P. , Kapche Gilbert D. W. F. , Kuete Victor , Mapitse Renameditswe , Yeboah Samuel O. , Ngadjui Bonaventure T. 
Published: December 2016

AbstractAmong the new compounds, trilepisflavene (I), trilepisdepsidone (II) and daturadiol stearate (III), compound (I) exhibits moderate to weak antimicrobial activity.
ChemInform Abstract: Mechanistic Understanding of Alkyne Cyclotrimerization on Mononuclear and Dinuclear Scaffolds: [4 + 2] Cycloaddition of the Third Alkyne onto Metallacyclopentadienes and Dimetallacyclopentadienes
Authors: Yamamoto Keishi , Nagae Haruki , Tsurugi Hayato , Mashima Kazushi 
Published: December 2016

AbstractReview: 108 refs.
ChemInform Abstract: Visible‐Light‐Driven CO2 Photo‐Catalytic Reduction of Ru(II) and Ir(III) Coordination Complexes
Authors: Liao Wei‐Ming , Zhang Jian‐Hua , Hou Ya‐Jun , Wang Hai‐Ping , Pan Mei 
Published: December 2016

AbstractReview: 66 refs.
ChemInform Abstract: Synthesis, Properties, and Optical Applications of Low‐Dimensional Perovskites
Authors: Zhang Yupeng , Liu Jingying , Wang Ziyu , Xue Yunzhou , Ou Qingdong , Polavarapu Lakshminarayana , Zheng Jialu , Qi Xiang , Bao Qiaoliang 
Published: December 2016

AbstractReview: 136 refs.
A Bioinspired Nanofibrous Titania/Silicon Composite as an Anode Material for Lithium‐Ion Batteries
Authors: Jia Dongling , Chen Yunhua , Huang Jianguo 
Published: December 2016

AbstractA hierarchical nanofibrous titania/silicon composite composed of anatase titania nanoparticles anchored as a thin coating layer on the surface of a silicon nanofiber was synthesized by employing natural cellulose substance (e.g., commercial laboratory filter paper) as a template. It was obtained through magnesiothermic reduction of the titania/silica replica of a cellulose substance prepared by a sol–gel process. When used as an anode material for lithium‐ion batteries, it showed improved electrochemical performances that were superior to those of the bare silicon counterpart, and which improved with increasing titania content in the composites. For the composite with 54.3 wt % titania and titania nanoparticles with sizes of about 12 nm, it delivered a specific capacity of 498.9 mA h g−1 after 200 charge/discharge cycles at a current density of 200 mA g−1. The enhanced electrochemical performances of the composite are attributed to its unique network structure, as well as the buffering effect of the titania coating layer for huge volume changes to the silicon fiber during repeated lithiation and delithiation processes.
Development of a Novel Index for Analysis of Electronically Excited States
Authors: Alipour Mojtaba , Damiri Samaneh 
Published: December 2016

AbstractConcerning the major factors in the context of excited states analyses, namely charge centroids of the orbitals involved in the excitations, the distance between orbital centroids, and overlap integrals, a new metric—the Ω index—is proposed to assign the character and optical properties of electronically excited states. Using several molecules from different classes and also a well‐studied standard database for time‐dependent density functional theory (TD‐DFT) studies as benchmark criteria, accountability of the developed index is numerically assessed for local, charge transfer, and Rydberg excitations. It is shown that the nature of excited states can be discriminated using the Ω index, where its superior performance for those situations in which the previous descriptors were not helpful is also unveiled. Relationships are also examined between the Ω index and optical properties of some molecules under study in the framework of the sum‐over‐state approach. It is observed that there are correlations between the proposed index and computed hyperpolarizabilities based on the sum‐over‐state scheme. These findings offer the possibility of estimating excited‐state properties of large systems from simple descriptors without explicitly performing calculations of high‐order response functions.
Embedded electronic circuits for cryptography, hardware security and true random number generation: an overview
Authors: Acosta Antonio J. , Addabbo Tommaso , Tena‐Sánchez Erica 
Published: December 2016

SummaryWe provide an overview of selected crypto‐hardware devices, with a special reference to the lightweight electronic implementation of encryption/decryption schemes, hash functions, and true random number generators. In detail, we discuss the hardware implementation of the chief algorithms used in private‐key cryptography, public‐key cryptography, and hash functions, discussing some important security issues in electronic crypto‐devices, related to side‐channel attacks (SCAs), fault injection attacks, and the corresponding design countermeasures that can be taken. Finally, we present an overview about the hardware implementation of true random number generators, discussing the chief electronic sources of randomness and the types of post‐processing techniques used to improve the statistical characteristics of the generated random sequences. Copyright © 2016 John Wiley & Sons, Ltd.
New approach for spacing of movement joints in reinforced and unreinforced masonry veneer walls / Neue Bemessungsmethode für die Abstände von Dehnungsfugen in bewehrten und unbewehrten Verblendmauerwerksschalen
Authors: Martens Dirk R.W. 
Published: December 2016

AbstractThe first part of the paper, published in issue 4 [3] and dealing with the spacing of movement joints, described the design method for unreinforced masonry veneer walls. This paper focuses on increasing the spacing of movement joints by applying bed joint reinforcement. The proposed approach enables manufacturers of bed joint reinforcement to provide recommendations for the spacing of movement joints for bed joint reinforced veneer walls dependent upon the allowable crack width, the reinforcement type, the diameter and the vertical spacing of the reinforcement.
Quantitative analysis of single‐nucleotide polymorphisms by pyrosequencing with di‐base addition
Authors: Pu Dan , Pan Rongfang , Liu Wenbin , Xiao Pengfeng 
Published: December 2016

We have developed and validated a novel method for quantitative detection of SNPs by using pyrosequencing with di‐base addition (PDBA). Based on the principle that the signal intensity is proportional to the template concentration within a linear concentration range, linear formula (Y = AX + B) for each genotype is established, and the relationship between two genotypes of a single SNP can be resolved by corresponding linear formulas. Here, PDBA assays were developed to detect variants rs6717546 and rs4148324, and the linear formulas for each genotype of rs6717546 and rs4148324 were established. The method allowed to quantitatively determine each genotype and showed 100% accordant results against a panel of defined mixtures. A set of 24 template fragments containing variants rs6717546 or rs4148324 was tested to evaluate the method. Our results showed that allele frequency of each genotype was accurately quantified, with results comparable to those of conventional pyrosequencing. Furthermore, this method was capable of detecting alleles with frequencies as low as 3%, which was more sensitive than ∼5 to ∼7% level detected by conventional pyrosequencing. This method offers high sensitivity, reproducibility, and relatively low costs, and thus could provide a much‐needed approach for quantitative analysis of SNPs in clinical samples.
Oblique aggradation: a novel explanation for sinuosity of low‐energy streams in peat‐filled valley systems
Authors: Candel Jasper H.J. , Makaske Bart , Storms Joep E.A. , Wallinga Jakob 
Published: December 2016

AbstractLow‐energy streams in peatlands often have a high sinuosity. However, it is unknown how this sinuous planform formed, since lateral migration of the channel is hindered by relatively erosion‐resistant banks. We present a conceptual model of Holocene morphodynamic evolution of a stream in a peat‐filled valley, based on a palaeohydrological reconstruction. Coring, ground‐penetrating radar (GPR) data, and 14C and OSL dating were used for the reconstruction. We found that the stream planform is partly inherited from the Late‐Glacial topography, reflecting stream morphology prior to peat growth in the valley. Most importantly, we show that aggrading streams in a peat‐filled valley combine vertical aggradation with lateral displacement caused by attraction to the sandy valley sides, which are more erodible than the co‐evally aggrading valley‐fill. Owing to this oblique aggradation in combination with floodplain widening, the stream becomes stretched out as channel reaches may alternately aggrade along opposed valley sides, resulting in increased sinuosity over time. Hence, highly sinuous planforms can form in peat‐filled valleys without the traditional morphodynamics of alluvial bed lateral migration. Improved understanding of the evolution of streams provides inspiration for stream restoration. Copyright © 2016 John Wiley & Sons, Ltd.