bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Luminescence and Metal‐Metal Interactions in Binuclear Gold(I) Compounds.
Authors: KING C. , WANG J.‐C. , KHAN MD. N. I. , FACKLER J. P. JUN. 
Published: May 2016

AbstractSince the complex (I) is strongly luminescent in solution, an SCF‐Xα‐SW MO study of the model compound (Au(H2PCH2PH2))22+ in the chair conformation is undertaken to determine the nature of the orbitals involved.
ChemInform Abstract: Structural Aspects of Stable Dibenzyl Triselenides. The Crystal Structures of Bis(2,4‐dichlorobenzyl) Triselenide and Bis(2,6‐dichlorobenzyl) Triselenide.
Authors: HANSEN F. , HENRIKSEN L. , LARSEN S. , TEUBER L. 
Published: May 2016

AbstractAccording to their behavior on heating eighteen substituted dibenzyl diselenides and triselenides are classified.
ChemInform Abstract: Failure of Azo Coupling by Ion Pairing of 4′‐Diethylamino‐α‐cyano‐stilbene‐4‐diazonium Tetraphenylboranates in Water.
Authors: WALKOW F. , REHOREK D. 
Published: May 2016

AbstractAccording to UV/VIS spectra, ion pairing of (I) is dependent on concentration and solvent.
ChemInform Abstract: Asymmetric Hydrogenation of α‐Arylpropenoic Acids Catalyzed by Rhodium(I) Complexes of Chiral Ligands Derived from Some Monosaccharides.
Authors: SUNJIC V. , HABUS I. , COMISSO G. , MOIMAS F. 
Published: May 2016

AbstractThe prochiral precursors (V) or (VII) of (+)‐ketoprofen (VI) or (+)‐naproxen (VIII) are hydrogenated in the presence of various Rh(I) complexes of chiral diphenylphosphines and diphenylphosphinites such as (I)‐(IV).
ChemInform Abstract: Synthesis of Natural (S)‐(‐)‐Tulipalin B Starting from L‐Malic Acid as a Chiral Pool.
Authors: MURAOKA O. , TOYOOKA N. , OHSHIMA Y. , NARITA N. , MOMOSE T. 
Published: May 2016

AbstractAcid‐catalyzed cyclization of the protected dihydroxycarboxylic acid ester (VII), prepared from dimethyl (S)‐(‐)‐maleate (I), yields (S)‐(‐)‐tulipalin B (VIII) as the main product.
ChemInform Abstract: 2,3‐Bis(2‐pyridyl)‐5,8‐quinoxalinediones with Metal‐Chelating Properties: Synthesis and Biological Evaluation.
Authors: GIORGI‐RENAULT S. , GEBEL‐SERVOLLES P. , HELISSEY P. , RENAULT J. , BERNIER J.‐L. , HENICHART J.‐P. , CROS S. 
Published: May 2016

AbstractVarious derivatives of the bis(2‐pyridyl)quinoxalinediones (IV) are synthesized as outlined in the reaction scheme.
ChemInform Abstract: New Atypical Antidepressants: An Efficient Process for Preparing cis‐1,3,4,6,7,11b‐Hexahydro‐2‐methyl‐7‐aryl‐2H‐pyrazino(2,1‐a)isoquinolines.
Authors: SCHMIESING R. J. , MATZ J. R. 
Published: May 2016

AbstractStarting with the ketopiperazine (I), the amino ketone (III) is synthesized.
ChemInform Abstract: Heterocyclic Syntheses with Malonyl Chloride. Part 15. 7‐Chloro‐3,4‐dihydro‐4,5‐dioxo‐3‐aryl(or‐alkyl)‐2‐thio‐2H,5H‐pyrano(3,4‐2‐e)‐1,3‐oxazine from Aryl or Alkyl Isothiocyanates and Their Degradation with Morpholine and Ethanol.
Authors: AL‐RAWI J. M. A. , MAHMOOD A.‐H. TH. 
Published: May 2016

AbstractThe title oxazine derivatives (VI) react with morpholine (VII) and EtOH (X) via substitution and ring opening to give products of type (VIII), (IX) and (XI).
ChemInform Abstract: A New Method for the Synthesis of Zinc Tetrakis‐(3‐methylpyridyloxy)phthalocyanine and the Physical Properties of Dimers Formed by Complexation of the Cationic Phthalocyanine with Anionic Porphyrins.
Authors: GASPARD S. , THU‐HOA‐TRAN‐THI THU‐HOA‐TRAN‐THI 
Published: May 2016

AbstractThe photophysical properties of the cationic phthalocyanine (VII) upon complexation with the two different anionic porphyrins (VIIIa) and (VIIIb) are described.
ChemInform Abstract: Preparation and Structural Characterization of Methylmercury(II) Complexes of 8‐Azaadenine and 9‐Methyl‐8‐azaadenine.
Authors: SHELDRICK W. S. , BELL P. 
Published: May 2016

AbstractThe title complexes (I)‐(IX) are isolated from aqueous solutions of the bases and Me‐Hg‐OH at 50‐60 °C in the pH range 1‐10 and characterized by 1H NMR spectroscopy, crystal structures are determined for (IX) (Pc, Z=2) and (VI) (P21/c, Z=4).
ChemInform Abstract: Facile Shifts of Bromine Atom on C‐3 Position of Guaiazulene and Synthesis of Variously Functionalized Azulenes Using These Reactions.
Authors: NOZOE T. , ISHIKAWA S. , SHINDO K. 
Published: May 2016

AbstractGuaiazulene (I) is treated with NBS in hexane to yield at first the 3‐brominated product (II).
ChemInform Abstract: Preparation and Vibrational Spectra of 35Cl/37Cl Labelled Fluoro‐Chloro‐Platinates(IV).
Authors: ERLHOEFER P. + , PREETZ W. 
Published: May 2016

AbstractAll components of the two series Cs2(PtFn35Cl6‐n) and Cs2(PtFn37Cl6‐n), including the pairs of geometric isomers for n = 2, 3, 4, are prepared by reaction of K2(Pt35Cl6) and K2(Pt37Cl6) (both synthesized in 95% yield based on Pt) with BrF3 and subsequent ion exchange chromatography on DEAE cellulose.
ChemInform Abstract: Current‐Voltage Characteristics of Heavily Doped p‐Si in Aqueous KOH.
Authors: PALIK E. D. , GLEMBOCKI O. J. , RINKO J. D. , HEARD I. JUN. 
Published: May 2016

AbstractEtch rates and I‐V curves are determined in 2 M and 11.5 M KOH for boron‐doped p(100) Si samples with doping densities in the range 3·1016‐2·1020 cm‐3.
ChemInform Abstract: Flux Growth of CuInS2 from CuxIn1‐x Melts.
Authors: FLEMING J. G. , FEARHEILEY M. L. , LEWERENZ H. J. 
Published: May 2016

AbstractThe stoichiometry of CuInS2 grown from InxCu1‐x melts (0.3 ≦ x ≦ 1.0) containing a CuInS2 powder source can be controlled to some degree by varying x in the initial melt.
ChemInform Abstract: Reactions of BrF5 with the Azide, Nitrite, and Sulfate Anions.
Authors: CHRISTE K. O. , WILSON W. W. , SCHACK C. J. 
Published: May 2016

AbstractThe reactions of bromine pentafluoride (I) with cesium sulfate (II) and azide (V) and the nitrites (VIII) or (XIV) are investigated.
ChemInform Abstract: Selective and Sequential Reduction of Polyhalosilanes with Alkyltin Hydrides.
Authors: D'ERRICO J. J. , SHARP K. G. 
Published: May 2016

AbstractThe reactions outlined in the scheme as well as similar reactions performed with Et3SnH and Me2SnH2 demonstrate that alkyltin hydrides have selective, stepwise reducing (i.e.
ChemInform Abstract: Soluble Polychalcogenide Chemistry of Indium. Synthesis and Characterization of (In2Se21)4‐, the First Indium Polyselenide.
Authors: KANATZIDIS M. G. , DHINGRA S. 
Published: May 2016

AbstractThe compound (IV) crystallizes in the triclinic space group P1 with Z=1.
ChemInform Abstract: Modelling of Micellar Effects Upon Substitution Reactions with Moderately Concentrated Hydroxide Ion.
Authors: GERMANI R. , PONTI P. , SAVELLI G. , SPRETI N. , BUNTON C. A. , MOFFATT J. R. 
Published: May 2016

AbstractThe cationic surfactants CTACl or the analogous bromide enhance the rates for the hydrolysis of (I) and (III).
ChemInform Abstract: The Use of Dichloromaleic and Bromomaleic Anhydrides in the Synthesis of Lactones by the Intramolecular Diels‐Alder Reaction.
Authors: BATCHELOR M. J. , MELLOR J. M. 
Published: May 2016

AbstractReaction of the pentadienol (I) with the anhydride (II) gives an unstable triene (III) which on heating undergoes an intramolecular Diels‐Alder cyclization to give exclusively the cis adduct, viz.
ChemInform Abstract: A New Method for the Preparation of β‐(Alkylamino)carbonyl Compounds by Rearrangement of β‐Chloroimines via Azetidine Intermediates.
Authors: SULMON P. , DE KIMPE N. , SCHAMP N. 
Published: May 2016

AbstractThe reaction of β‐chloroimines such as (I) with methoxide leads to the β‐amino carbonyl compounds (III).
ChemInform Abstract: Dynamics of the Wolff Rearrangement of Six‐Membered Ring o‐Diazo Ketones by Laser Flash Photolysis.
Authors: TANIGAKI K. , EBBESEN T. W. 
Published: May 2016

AbstractA ketene of type (III) is formed in a multi‐step rearrangement of (I) and analogously of (VI) and (VII) as is shown in the nanosecond laser flash photolysis.
ChemInform Abstract: Ring Expansions of (2 + 2) Photoadducts. Potential Applications in the Synthesis of Triquinane and Taxane Skeletons.
Authors: LANGE G. L. , DECICCO C. P. , WILLSON J. , STRICKLAND L. A. 
Published: May 2016

AbstractIrradiation of the unsaturated cyclic keto esters (II) in the presence of the cyclopentene (I) yields the diastereomeric adducts (III) and (IV).
ChemInform Abstract: The Gas‐Phase Smiles Rearrangement: A Heavy Atom Labeling Study.
Authors: EICHINGER P. C. H. , BOWIE J. H. , HAYES R. N. 
Published: May 2016

AbstractThe use of collisional activation mass spectra and heavy atom (13C and 18O) labeling shows that the products (III) and (IV) from (I) are formed through Smiles intermediates (II).
ChemInform Abstract: Selective Reduction of α,β‐Unsaturated Carbonyl Compounds with Carbon Monoxide and Water Assisted by Selenium.
Authors: NISHIYAMA Y. , MAKINO Y. , HAMANAKA S. , OGAWA A. , SONODA N. 
Published: May 2016

AbstractThe carbon‐carbon double bond of α,β‐unsaturated carbonyl compounds can be selectively reduced with hydrogen selenide, generated in situ from Se/H2O/CO in the presence of a strongly basic tertiary amine (DBU or N‐methylpyrrolidine).
ChemInform Abstract: A New Method for the Deprotection and Reduction of Dithioacetals.
Authors: SHIGEMASA Y. , OGAWA M. , SASHIWA H. , SAIMOTO H. 
Published: May 2016

AbstractThe dithioacetals (I) are treated with P2I4 in acetic anhydride to form exclusively the corresponding ketones (II).
ChemInform Abstract: Aryliminodimagnesium Reagents. Part 26. Formation of o‐Hydroxyazoarenes by Condensation with o‐Hydroxynitroarenes. Favorable Role of o‐Hydroxyl Group in the Reaction.
Authors: OKUBO M. , NAKASHIMA T. , SHIKU H. 
Published: May 2016

AbstractHydroxy‐azoxyarenes such as (II) as well as hydroxy‐azoarenes such as (III) are formed by condensation of, e.g., the aryliminodimagnesium species (V) with o‐, m‐, and p‐hydroxynitrobenzenes (I); nuclear substitution takes place as a minor or a major pathway.
ChemInform Abstract: Ferric Ion Sequestering Agents. Part 21. Synthesis and Spectrophotometric and Potentiometric Evaluation of Trihydroxamate Analogues of Ferrichrome.
Authors: NG C. Y. , RODGERS S. J. , RAYMOND K. N. 
Published: May 2016

AbstractTwo trihydroxamate analogues (V) of the microbial iron chelator ferrichrome are prepared as shown for the example (Va).
ChemInform Abstract: Reaction of Hexafluoropropylene Oxide with Triethyl Phosphite.
Authors: KADYROV A. A. , ROKHLIN E. M. , GALAKHOV M. V. , MYSOV E. I. 
Published: May 2016

AbstractTreatment of hexafluoropropylene oxide (I) with triethyl phosphite (II) does not give phosphorus‐containing compounds, but the diethoxydiene (III) and the unsaturated ester (IV) are formed.
ChemInform Abstract: Novel Synthesis of Carbamate Ester from Carbon Dioxide, Amines, and Alkyl Halides.
Authors: YOSHIDA Y. , ISHII S. , WATANABE M. , YAMASHITA T. 
Published: May 2016

AbstractAn novel synthesis of carbamate esters such as (IV) uses CO2 (I) as a direct material and the corresponding compounds (II) and (III) as reaction components.
ChemInform Abstract: Application of Elementoorganic Compounds of the Fifteenth and Sixteenth Groups in Organic Synthesis. Part 67. Tributylstibine‐Mediated Synthesis of 1,1,2‐Trisubstituted Cyclopropanes.
Authors: CHEN C. , LIAO Y. , HUANG Y.‐Z. 
Published: May 2016

AbstractA novel method for the synthesis of 1,1,2‐trisubstituted cyclopropanes such as (III) or (V) and (VI) is reported, which is promoted by Bu3Sb.
ChemInform Abstract: (3.3.3)Propelladienedicarbonitriles.
Authors: QUAST H. , ROESCHERT H. + , PETERS E.‐M. , PETERS K. , VON SCHNERING H. G. 
Published: May 2016

AbstractStarting from diketone (I) some precursors of 2,6‐dicyanosemibullvalene are prepared.
ChemInform Abstract: Synthesis of 1‐Substituted 1‐Vinylcycloalkanes by Allylboration of Carbonyl Compounds and Ethoxyacetylene with Diorganylborylethylidenecyclopentane and Diorganylborylethylidenecyclohexane.
Authors: BUBNOV YU. N. , ZHELUDEVA V. I. , IGNATENKO A. V. 
Published: May 2016

AbstractHydroboration reaction of the allenes (I) with the borabicyclononane (II) produces the cycloalkylidenethylborabicyclononanes (III) which are coupled with the carbonyl compounds (IV) or ethoxyacetylene (VI), forming the 1‐substituted 1‐vinylcycloalkanes (V) and (VII) respectively.
ChemInform Abstract: Ene‐Type Reactions of Non‐Activated Olefins with “Activated” Sulfoxides and Some Properties of the Sulfonium Salts Formed.
Authors: MOISEENKOV A. M. , DRAGAN V. A. , VESELOVSKII V. V. 
Published: May 2016

AbstractThe methylpentene (Ia), citronellyl acetate (Ib), or geranyl acetate (Ic) react with DMSO (II) in the presence of trifluoroacetic anhydride (III) to give the sulfonium trifluoroacetates (IV).
ChemInform Abstract: 7‐Methyl‐ and 7‐Phenylcyclohepta‐1,3,5‐trienes from Benzvalene via 3,3a,4,5,6,6a‐Hexahydro‐4,5,6‐methenocyclopentapyrazoles and Tetracyclo(4.1.0.02,4.03,5)heptanes.
Authors: CHRISTL M. , BRUNN E. , ROTH W. R. , LENNARTZ H.‐W. 
Published: May 2016

AbstractUsing benzvalene (I) as benzene equivalent, a three‐step procedure is developed for the preparation of the 7,7‐disubstituted cycloheptatrienes (V).
ChemInform Abstract: Transannular Interactions in Hexacyclo(6.6.0.02,6.03,13.04,11.05,9)tetradecane‐10,14‐dione.
Authors: CHOW T. J. , WU T.‐K. 
Published: May 2016

AbstractIrradiation of the hexacyclic dione (I) mentioned in the title in tetrahydrofuran gives the cage diol (III) and the related bisacetal (IV) or the hydroxypropyldioxolane (V).
ChemInform Abstract: Synthesis and Polymerization of 2,5‐Disubstituted Phenylacetylenes Containing Trifluoromethyl Groups.
Authors: NISHIDA M. , HOSOKAWA K. , UEDA T. , AOKI T. , MURAMATSU H. 
Published: May 2016

AbstractThe key‐steps in the synthesis of the acetylenes (X) mentioned in the title are the alkylation of arylmetal compounds, derived from the bromides (VII), with 1,1‐dichloro‐2,2‐difluoroethene (VIII) and subsequent dehalogenation with butyllithium.
ChemInform Abstract: The Cleavage of Two Carbon‐Carbon Bonds in a Wolff‐Kishner Reduction.
Authors: LEMIEUX R. P. , BEAK P. 
Published: May 2016

AbstractThe bisspirocyclic 2‐indanone (I) is subjected to Wolff Kishner reduction, forming spiro(cyclopropane‐1,1'‐indan).
ChemInform Abstract: Five‐Membered 2,3‐Dioxoheterocycles. Part 13. Synthesis and Properties of 2‐Acylmethylenehydrazones of 5‐Aryl‐2,3‐dihydrofuran‐2,3‐diones.
Authors: ZALESOV V. V. , PULINA N. A. , ANDREICHIKOV YU. S. 
Published: May 2016

AbstractSince nothing is known to date about the reaction between triphenylphosphazines of aliphatic diazo compounds and 5‐arylfuran‐2,3‐diones, this reaction is now investigated.
ChemInform Abstract: A Very Simple Synthesis of Divinyl Ketones.
Authors: BARLUENGA J. , AZNAR F. , CABAL M. P. , VALDES C. 
Published: May 2016

AbstractThe 2‐(1‐morpholinyl)butadienes (I) are coupled with the aldehydes (II) in the presence of magnesium bromide etherate to give the divinyl ketones (III).
ChemInform Abstract: Anchimeric Assistance with Intermediary N‐Alkoxyaziridinium Salts. Formation of Vicinal Amino Alcohols and Derivatives.
Authors: WILLIAMS D. R. , OSTERHOUT M. H. , MCGILL J. M. 
Published: May 2016

AbstractThe N‐alkoxypyrrolidinyliodobutanoates (I) or (IV) are cyclized in the presence of triethylamine to form the lactones (II) or (V) as the main products, together with the N‐alkoxypiperidines (III) and (VI) due to ring expansion.
ChemInform Abstract: Pyrazoles by Cyclization of Benzoin Phenylhydrazones with Aldehydes.
Authors: GNICHTEL H. , BROCKMANNS M. , SALEM W. I. , LUGER P. 
Published: May 2016

AbstractFusing either (E)‐ or (Z)‐benzoin phenylhydrazone and the aldehydes (II) or (IV) yields 3‐substituted 1H‐pyrazoles.
ChemInform Abstract: Decarboxylation of 1‐Aminocyclopropanecarboxylic Acid and Its Derivatives.
Authors: VAIDYANATHAN G. , WILSON J. W. 
Published: May 2016

Abstract1‐Aminocyclopropanecarboxylic acid (Ia) reacts with the trione (II) to give the imine (III) via decarboxylation.
ChemInform Abstract: A New Route to 4‐Oxygenated Isoxazolines. Application to the Synthesis of 2‐Deoxy‐2‐aminobutose Derivatives.
Authors: WADE P. A. , PRICE D. T. 
Published: May 2016

AbstractCoupling of nitromethane (I) with chloroacetaldehyde (II) and dihydropyran (III) forms the carbinol ether (IV).
ChemInform Abstract: Di‐tert‐butylthioketene S‐Bis(alkoxycarbonyl)methylide: Formation, Reactions, and Its Equilibrium with the Isomeric 2‐Alkylidene‐1,3‐oxathiole.
Authors: TOKITOH N. , SUZUKI T. , ITAMI A. , GOTO M. , ANDO W. 
Published: May 2016

AbstractRhodium‐catalyzed reaction of di‐tert‐butylthioketene (I) with an excess of the diazomalonates (II) gives the ylides (III), whereas (I) and equimolar amounts of (IIa) produce the monoadduct (IV) which is converted to the bisadducts (IIIa) and (V).
ChemInform Abstract: Oxidative Deprotonation of Carbonyl Compounds by Fe(III) Salts.
Authors: CITTERIO A. , CERATI A. , SEBASTIANO R. , FINZI C. , SANTI R. 
Published: May 2016

AbstractThe methylmalonate (I) is treated with various Fe(III) salts to perform oxidative deprotonation, followed by radical reactions, producing the oxy‐substituted compounds (III), (V), and (VI), or the dimers (VII) and (VIII).
ChemInform Abstract: Potential Antitumor Agents. Part 58. Synthesis and Structur‐Activity Relationships of Substituted Xanthenone‐4‐acetic Acids Active Against the Colon 38 Tumor in vivo.
Authors: REWCASTLE G. W. , ATWELL G. J. , BAGULEY B. C. , CALVELEY S. B. , DENNY W. A. 
Published: May 2016

AbstractA series of xanthenones is prepared by different methods.
ChemInform Abstract: 2‐Ethoxymethylene‐5‐phenyl‐1,3‐dithiane 1,1,3,3‐Tetroxide and Its Conversions.
Authors: BAZAVOVA I. M. , ESIPENKO A. N. , NEPLYUEV V. M. , LOZINSKII M. O. 
Published: May 2016

AbstractThe title compound (III) is prepared for the first time and its reactivity toward nucleophiles is investigated.
ChemInform Abstract: Benzodiazepine Receptor Ligands. Synthesis and in vitro Binding Activity of Some 6‐Substituted‐3‐Aryl‐1,2,4‐triazolo(3,4‐a)phthalazines.
Authors: TARZIA G. , OCCELLI E. , BARONE D. 
Published: May 2016

AbstractStarting with the ethylsulfonyltriazolophthalazine (I), the hydroxymethyltriazolophthalazines (VI) are synthesized.
ChemInform Abstract: Benzodiazepine Receptor Ligands. Synthesis and Preliminary Pharmacological Evaluation of 2‐Aminoalkyl‐8‐chloro‐ and 2‐Aryl‐1,2,4‐triazolo‐(3,4‐a)phthalazin‐3(2H)‐ones.
Authors: TARZIA G. , OCCELLI E. , CORSICO N. , GALLICO L. , LUZZANI F. , BARONE D. 
Published: May 2016

AbstractThe chlorophthalazine (I) is coupled with phenylhydrazines (II) to give the arylhydrazinophthalazines (III) which are cyclized with urea (IV), forming the triazolophthalazinones (V).
ChemInform Abstract: Porphyrins and Their Derivatives. Part 7. Synthesis and Properties of Novel Crown Porphyrins.
Authors: ZHILINA Z. I. , MEL'NIK V. I. , ANDRONATI S. A. , ABRAMOVICH A. E. 
Published: May 2016

AbstractThe preparation of a series of novel representatives of crown porphyrins, e.g. (I), is described.
ChemInform Abstract: A Barium‐Selective Macrocyclic Tetralactam with Dimethylenoxy Moieties.
Authors: CAZAUX L. , DURIEZ M.‐C. , PICARD C. , TISNES P. 
Published: May 2016

AbstractThe oxo‐bridged bis(acetyl chloride) (IIIa) and the corresponding diamide (IIIb) are cyclized with the diamine (IV) under high dilution conditions to give the macrocyclic tetraprotected tetralactam (Vb).
ChemInform Abstract: Synthesis of Sodium Tetrakis(3,5‐di(trifluoromethyl)phenyl)borate.
Authors: GOL'DBERG YU. SH. , ABELE E. M. , LIEPIN'SH E. E. , SHIMANSKAYA M. V. 
Published: May 2016

AbstractThe title compound (III), prepared by a novel procedure and in improved yield, is applied as a catalyst in phase‐transfer catalyses.
ChemInform Abstract: Reaction of Diphenyl Diselenide with Peroxodisulfate Ions in Methanol: A Convenient Procedure to Effect the Methoxyselenenylation of Alkenes.
Authors: TIECCO M. , TESTAFERRI L. , TINGOLI M. , CHIANELLI D. , BARTOLI D. 
Published: May 2016

AbstractA mixture of diphenyl diselenide (II) and peroxodisulfate in methanol (III) reacts with various olefins to form β‐methoxy phenyl selenides.
ChemInform Abstract: Activation of Hydroxyl Groups in Sugars Using Bis(tributyltin) Oxide: Retention of the Organotin Residues to give Biologically Active Products.
Authors: JACQUES P. P. L. , POLLER R. C. 
Published: May 2016

AbstractTreatment of the cyclic anhydrides (I) with tributyltin ethoxide (II) gives the tributylstannyl ethyl esters (III) of succinic, maleic, or phthalic acid.
ChemInform Abstract: Organotin Biocides. Part 13. C‐Triorganostannylimidazoles, ‐benzoxazoles, and ‐benzothiazoles.
Authors: MOLLOY K. C. , WATERFIELD P. C. , MAHON M. F. 
Published: May 2016

AbstractThe 2‐triorganostannyl heterocycles (III) and (V) are prepared by treatment of the 2‐lithio heterocycles (I) or (IV) with triorganotin chlorides (II).
ChemInform Abstract: Vanadium(III) Tetrahydroborates. Preparation, Reaction Chemistry, and Crystal Structures of V(BH4)3(PMe3)2 and the Oxo Dimer (V(BH4)2(PMe3)2)2O.
Authors: JENSEN J. A. , GIROLAMI G. S. 
Published: May 2016

AbstractSolutions of the anion of (IV) may also be obtained in Et2O or THF from VOCl3, VCl4(THF)2, VCl3(THF)3 and LiBH4, but in these cases the product could not be crystallized.
ChemInform Abstract: Synthesis and Properties of Nitrosyl Complexes of Molybdenum and Tungsten Containing Halide and PMe3 Ligands. Crystal and Molecular Structures of MoCl3(NO)(PMe3)3 and MoCl(NO)(S2CPMe3‐S,S′,C)(PMe3)2.
Authors: CARMONA E. , GUTIERREZ‐PUEBLA E. , MONGE A. , PEREZ P. J. , SANCHEZ L. J. 
Published: May 2016

AbstractThe 18‐electron Mo(II) species (III) are reduced to give the corresponding metal(0) derivatives (V).
ChemInform Abstract: Structurally Diverse Manganese(III) Schiff Base Complexes: Chains, Dimers, and Cages.
Authors: BONADIES J. A. , KIRK M. L. , LAH M. S. , KESSISSOGLOU D. P. , HATFIELD W. E. , PECORARO V. L. 
Published: May 2016

AbstractThe complex (IV) (Pnma, Z=4) consists of an infinite chain which shows an anti‐anti configuration for the bridging acetate.
ChemInform Abstract: Effects of Conformational Change in the Acceptor on Intramolecular Electron Transfer.
Authors: CHEN P. , CURRY M. , MEYER T. J. 
Published: May 2016

AbstractIn order to resolve the question of the role of ring‐ring dihedral angle changes in bipyridinium‐based chromophore‐quencher complexes the structure of the complex (I) is determined (P21/a, Z=4) and the dihedral angle is shown to be 47° in the crystal.
ChemInform Abstract: Chiral Heterocyclic Ligands. Part 6. (4S,7R)‐7,8,8‐Trimethyl‐4,5,6,7‐tetrahydro‐4,7‐methano‐1H(2H)‐indazole and X‐Ray Structure of a Copper(II) Complex.
Authors: WATSON A. A. , HOUSE D. A. , STEEL P. J. 
Published: May 2016

AbstractThe title ligand prepared from (+)‐camphor as previously described reacts as its 2‐H tautomer with Cu(II) chloride dihydrate in ethanol to give the trans complex (I).
ChemInform Abstract: Open Cluster Configurations of (1,1‐(PPh3)2‐1‐H‐1,2,4‐IrC2B8H10) and Other Formally Wadian 24‐Electron 11‐Vertex Species.
Authors: NESTOR K. , FONTAINE X. L. R. , GREENWOOD N. N. , KENNEDY J. D. , PLESEK J. , STIBR B. , THORNTON‐PETT M. 
Published: May 2016

AbstractIn order to establish the suggestion arising from the assignment of the cluster 11B and 1H NMR shielding behavior, namely, that the title compound (I) is not a closo species, a single‐crystal X‐ray diffraction analysis is carried out (space group P21/c, Z=4).
ChemInform Abstract: Synthesis and Characterization of (Pt2/μ‐S)(μ‐dppm)(η1‐dppm)2) (dppm: Ph2PCH2PPh2) and Its Use in Formation of Tetranuclear Platinum Complexes with μ4‐S Ligands.
Authors: HADJ‐BAGHERI N. , PUDDEPHATT R. J. 
Published: May 2016

AbstractThe title complex (III) is synthesized according to the scheme.
ChemInform Abstract: Synthesis and Properties of 21‐Thioalkanoic Esters of Corticosteroids.
Authors: PSHENICHNYI V. N. , MIKHAL'CHUK A. L. , BORISOV E. V. , KHRIPACH V. A. 
Published: May 2016

AbstractCondensation of the tosylates (I) with sodium methyl mercaptoacetate (II), in situ derived from methyl mercaptoacetate and NaOMe, affords the title compounds (III).