bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Formation of Metformin Complexes with Some Transition Metal Ions: Their Biological Activity.
Authors: ABU‐EL‐WAFA S. M. , EL‐RIES M. A. , AHMED F. H. 
Published: May 2016

AbstractMetformin reacts with ethanolic solutions of the appropriate metal ions after addition of KOH to yield the complexes (I) which are characterized by elemental analysis, IR, electronic, 1H NMR and EPR spectra and conductivity measurements.
ChemInform Abstract: Near‐IR Absorbing Methine Dyes Based on Dicyanovinyl Derivatives of Indane‐1,3‐dione.
Authors: BELLO K. A. , CHENG L. , GRIFFITHS J. 
Published: May 2016

AbstractThe condensation of the benzaldehyde (IIa) with the bisdicyanovinylindane (VI) requires acetic anhydride as solvent.
ChemInform Abstract: Some Chemical Reactions of 5‐Vinyluracil and 2′‐Deoxy‐5‐vinyluridine.
Authors: JONES A. S. , SLATER M. J. , WALKER R. T. 
Published: May 2016

AbstractThe title uridine (IV) is active against HSV‐1 and HSV‐2 viruses and inhibits the growth of L 1210 leukaemia cells.
ChemInform Abstract: Free Energy Increments for Hydrogen Bonds in Nucleic Acid Base Pairs.
Authors: TURNER D. H. , SUGIMOTO N. , KIERZEK R. , DREIKER S. D. 
Published: May 2016

AbstractThermodynamic parameters for duplex formation by self‐complementary oligomers ICCGGC, CGGCCI, ICCGG, and GGCCI are reported.
ChemInform Abstract: Determination of Integral Intensity of the ν6 Band of CF235Cl2 (Freon‐12) According to the Data of Diode Laser Spectroscopy.
Authors: VOITSEKHOVSKAYA O. K. , KOSICHKIN YU. V. , MAKUSHKIN YU. S. , NADEZHDINSKII A. I. , STEPANOV E. V. , TISHCHENKO A. YU. , TRIFONOVA N. N. , CHEREPANOV V. N. 
Published: May 2016

AbstractFrom the analysis of all the calculated and experimental values of absorption coefficients and line intensities the integrated intensity of the ν6 band of CF235Cl2 is determined to be 292 cm‐2 atm‐1.
ChemInform Abstract: Molybdena‐Alumina Catalysts. Part 12. MoS2 Surface Coverage from CO2 Adsorption.
Authors: ZMIERCZAK W. , QADER Q. , MASSOTH F. E. 
Published: May 2016

AbstractCO2 adsorption is shown to be a good technique for assaying the surface coverage of the MoS2 in alumina catalysts since it does not adsorb on the MoS2 phase.
ChemInform Abstract: Absorption, Emission, and Photophysical Properties of Copper(I) Pyrazole Complexes and Their Carbonyl Adducts.
Authors: SORRELL T. N. , BOROVIK A. S. 
Published: May 2016

AbstractIn order to understand the origins of observed electronic and photophysical transitions and to determine how changes in the coordination environment around the copper(I) ion affect these transitions, the spectroscopic properties for the complexes (I)‐(V) with various ligand sets are examined.
ChemInform Abstract: Thermodynamics of Base and Dioxygen Binding to the Cobalt(II) Schiff Base Complex Co(4,6‐CH3Osal‐4‐CF3oph).
Authors: LESLIE K. S. , DRAGO R. S. , GRIFFIS A. B. , HAMILTON D. E. , O'CONNOR C. J. 
Published: May 2016

AbstractEquilibrium constants for the base (1‐methylimidazole, Py, tetrahydrothiophene and DMSO) and dioxygen binding to the title complex (V), prepared as shown, are reported.
ChemInform Abstract: Reactions with Aziridines. Part. 42. The Regioselectivity of the Ring Opening of Activated 2,2‐Dimethylaziridines by Carbanions of the β‐Dicarbonyl Type. Influence of the Size of the Nucleophile.
Authors: BUCHHOLZ B. , STAMM H. 
Published: May 2016

AbstractThe treatment of the aziridines (I) with the compounds (II) or (III) causes, in the most cases, an initial ring‐opening leading mostly to the final pyrrolidine products shown in the scheme.
ChemInform Abstract: Octacarbonyldicobalt‐Induced (1,3) H Shifts in 1‐Methylallenecarboxylates and Allenic Lactones.
Authors: TRIFONOV L. S. , ORAHOVATS A. S. , HEIMGARTNER H. 
Published: May 2016

AbstractThe allene carboxylates (Ia,b), found to be stable on heating in benzene, show carbonyl‐induced (1,3) H shifts with subsequent highly selective Diels‐Alder cycloaddition to give (III) via (II) in the presence of Co2(CO)8.
ChemInform Abstract: Organosulfide Group Transfer Reactions of Transition‐Metal Carbonyl Radicals: Electronic and Steric Effects.
Authors: LEE K.‐W. , BROWN T. L. 
Published: May 2016

AbstractThe initial product for each photochemical reaction shown in the scheme is RSM(CO)4L (L: CO, PMe3) formed by RS group transfer from (II) to the M(CO)4L· radical generated by photolysis.
ChemInform Abstract: Oxidation of Olefins with Benzenetellurinic Anhydride.
Authors: KAMBE N. , TSUKAMOTO T. , MIYOSHI N. , MURAI S. , SONODA N. 
Published: May 2016

AbstractBenzenetellurinic anhydride (II) in acetic acid is employed in the conversion of the olefins (I) and (V) to the vicinal diacetates (III) and (VI).
ChemInform Abstract: One‐Step Vinylic Chlorination with Benzeneseleninyl Chloride.
Authors: KAMIGATA N. , SATOH T. , YOSHIDA M. , KOBAYASHI M. 
Published: May 2016

AbstractReaction of benzeneseleninyl chloride (II), prepared by ozonolysis of the selenenyl chloride (I), with the styrenes (III) in the presence of Lewis acids such as AlCl3 gives the vinyl chlorides (IV).
ChemInform Abstract: 2‐Vinyloxyalkoxy Ethyl Acylals ‐ Analogues of Vinyloxy Acrylates.
Authors: NEDOLYA N. A. , KHIL'KO M. YA. , TROFIMOV B. A. 
Published: May 2016

AbstractThe unsaturated carboxylic acids (II) add to the divinyl ethers (I) to yield the monoadducts (III) or the bis‐adducts (IV), depending on the molar ratios of the reactants (I) and (II).
ChemInform Abstract: Modern Friedel‐Crafts Chemistry. Part 14. On the Cyclization of Selected Aryl Hydroxyalkyl Sulfides.
Authors: EL‐KHAWAGA A. M. , EL‐ZOHRY M. F. , ISMAIL M. T. , ABDEL‐WAHA A. A. , KHALAF A. A. 
Published: May 2016

AbstractThe reaction of the thioethers (I) and (II) in the presence of various Friedel‐Crafts catalysts are investigated.
ChemInform Abstract: Fluoride‐Promoted Epoxidation of α,β‐Unsaturated Compounds.
Authors: MIYASHITA M. , SUZUKI T. , YOSHIKOSHI A. 
Published: May 2016

AbstractThe epoxidation of α,β‐unsaturated carbonyl compounds is achieved with hydrogen peroxide or tert‐butyl hydroperoxide in the presence of tetrabutylammonium fluoride.
ChemInform Abstract: A Novel C‐C Coupling of Benzazoles Mediated by Dichlorocarbene. Formation of Bisbenzazoles.
Authors: RO J. S. , IYENGAR D. S. , BHALERAO U. T. , RAO S. N. 
Published: May 2016

AbstractDimerization of the benzazoles (I), yielding the bis(benzazoles) (II), is promoted by dichlorocarbene which is generated from chloroform or sodium trichloroacetate in refluxing dioxane.
ChemInform Abstract: Synthesis of Perfluorinated Sulfimides, RfN=SO2, and Their Stabilisation by Tertiary Amines.
Authors: JAEGER U. + , SUNDERMEYER W. , PRITZKOW H. 
Published: May 2016

AbstractPerfluorosulfimides, which are stabilized by amines, as e.g. the compounds (IV), (VIII) and (XIII), can be obtained by two ways: via the sulfamoyl chlorides (II) or (VII), which react with a bulky, but low reactive amine as e.g. quinuclidine (III) or by direct reaction of N‐sulfinylamines as e.g. (IX) or (XI) with amine oxides, as e.g. quinuclidine N‐oxide (X) or trimethylamine N‐oxide (XII).
ChemInform Abstract: Novel Heterocyclic Systems. Part 26. The Synthesis and 13C‐NMR Assignment of 1,8‐Diazaphenoxathiin.
Authors: LINDSY C. M. , SMITH K. , MARTIN G. E. 
Published: May 2016

Abstract3‐Chloro‐4‐nitropyridine 1‐oxide (I) is coupled with the hydroxypyridinethione (II) to produce the diazaphenoxathiin (III), together with the isomeric by‐product (IV).
ChemInform Abstract: Pyrazoles Derived from Dihydralazine.
Authors: AMER A. , RASHED N. , ABDEL RAHMAN M. M. , ZIMMER H. 
Published: May 2016

AbstractReaction of dihydralazine (I) with the diketones (II), (IV), and (VII) gives the pyrazole derivatives (III), (V), and (VIII).
ChemInform Abstract: Pyrimidines. Part 8. Chlorination of 6‐Methyluracil with Phosphorus Oxychloride in the Presence of Trialkylamines.
Authors: GERSHON H. , GREFIG A. , CLARKE D. D. 
Published: May 2016

AbstractThe effect of the amines (II) on the chlorination of 6‐methyluracil (I) with phosphorus oxychloride is investigated and the yields of the products (III) ‐ (V) are determined.
ChemInform Abstract: Reactions with Phosphacumulenes: Synthesis of Pyran Derivatives from the Reaction of N‐Phenyliminoketenylidene Triphenylphosphorane with α,β‐Unsaturated Carbonyl Compounds.
Authors: SOLIMAN F. M. , KHALIL KH. M. 
Published: May 2016

AbstractThe iminoketenylidene phosphorane (I) is coupled with the benzylidene derivatives (IIa) ‐ (IIc) to produce the pyran‐substituted phosphoranes (III).
ChemInform Abstract: Base‐Catalyzed Condensation of Bis(diethylphosphonomethyl)phosphinic Amides with Aldehydes.
Authors: GILMORE W. F. , PARK J. S. 
Published: May 2016

AbstractTreatment of the phosphinyl chloride (I) with the amines (II) gives the phosphonic amides (III) which undergo Arbuzov reaction with triethyl phosphite (IV) to yield the amides (V).
ChemInform Abstract: Reaction of Triisobutylaluminum and Isobutylalumoxanes with Organo‐Silicon Compounds Containing Hydroxyl Groups.
Authors: KORNEEV N. N. , SHCHERBAKOVA G. I. , KOLESOV V. S. , SAKHAROVSKAYA G. B. , SHEVCHENKO E. I. , NIKITIN V. S. , BAZHENOVA L. N. , NIKISHINA I. S. 
Published: May 2016

AbstractTriisobutylaluminum (II) or tetraisobutyldialumoxane (IX) react with triphenylsilanol (III) and diphenylsilanediol (V) to give the products shown in the reaction scheme, depending on the reaction conditions and the molar ratio.
ChemInform Abstract: Macrocyclic Reagents for the Kinetic Control of Chelate Extraction Selectivities of Lanthanoids.
Authors: CHANG C. A. , MANCHANDA V. K. , PENG J. 
Published: May 2016

AbstractPrevious studies using (II) as the extractant for various lanthanoid ions at low pH, e.g. pH 4, have shown that (III) are the extracted species.
ChemInform Abstract: Unsaturated Silicon and Germanium Compounds. Part 22. Silicon Compounds and Their Group Homologues. Part 74. Storage of Silan‐ and Germanimines Me2E=NR (E: Si, Ge) by Way of Sila‐ or Germadihydrotetrazoles.
Authors: WIBERG N. , KARAMPATSES P. , KIM C.‐K. 
Published: May 2016

AbstractSilanimines such as (IV) (generated by thermolysis of siladihydrotriazoles such as (III) which, in turn, are formed from the dibromide (I)) react with azides such as (II) by (2 + 3) cycloaddition to form mainly silatetrazoles such as (VIa): the analogues (VIb)‐(VIf) are similarly obtained.
ChemInform Abstract: Cr(III) Complexes with Thioamides.
Authors: BURNS G. R. , DE ROO C. A. , HALL D. W. , OLIVER A. R. 
Published: May 2016

AbstractStarting with CrCl3(THF)3, the two thioamide complexes (I) and (II) are prepared by reaction in refluxing THF.
ChemInform Abstract: New Synthesis of Seven‐coordinate Complexes of Molybdenum(II) and Tungsten(II) Containing Bidentate Phosphorus Ligands, (MI2(CO)3(Ph2P(CH2)nPPh2)) (n = 1‐6).
Authors: BAKER P. K. , FRASER S. G. 
Published: May 2016

AbstractThe title compounds (III) are prepared by reaction of the easily obtainable acetonitrile complexes (I) with an equimolar amount of the bidentate diphosphine ligands (II).
ChemInform Abstract: Stereoselective Electron‐Transfer Reactions of (Ethylenediaminetetraacetato)cobaltate(III), (Propylenediaminetetraacetato)cobaltate(III), and (1,2‐Cyclohexanediaminetetraacetato)cobaltate(III) with Tris(ethylenediamine)cobalt(II).
Authors: GESELOWITZ D. A. , HAMMERSHOEI A. , TAUBE H. 
Published: May 2016

AbstractThe title reactions are studied in aqueous solution and in DMSO by means of investigating the optical purity of the (Co(en)3)3+ product.
ChemInform Abstract: Solution Confirmations of Hydroporphyrin Complexes. Synthesis and Properties of cis‐ and trans‐Octaethylchlorin Complexes.
Authors: STOLZENBERG A. M. , STERSHIC M. T. 
Published: May 2016

Abstractcis‐Octaethylchlorin (Ia) (7% yield) is prepared by a modification (chromatographic purification in a drybox) of the p‐toluenesulfonohydrazide reduction of octaethylporphyrin.
ChemInform Abstract: Asymmetric Syntheses via Heterocyclic Intermediates. Part 35. Optically Active α‐Arylglycine Esters by Friedel‐Crafts Alkylation with the Chiral Cation of the Bislactim Ether of cyclo‐(L‐Val‐Gly).
Authors: SCHOELLKOPF U. + , GRUETTNER S. + , ANDERSKEWITZ R. , EGERT E. , DYRBUSCH M. 
Published: May 2016

AbstractArylation of the chiral bislactim chloride (I) yields diastereomeric mixtures of the aryldihydropyrazines (III) and (IV) (in the case of (IIIc) and (IVc) additionally minor amounts of the 2‐methoxyphenyl substituted regioisomers are formed); hydrolysis of the major isomers (IIIa)‐(IIIc) affords the (R)‐configurated arylglycine esters (V).
ChemInform Abstract: Prostanoids. Part 19. Synthesis of 14C‐Labeled Cloprostenol.
Authors: MIFTAKHOV M. S. , VOSTRIKOV N. S. , KUZNETSOV O. M. , KUVATOV YU. G. , MURINOV YU. I. , TOLSTIKOV G. A. 
Published: May 2016

AbstractThe title compound (XIII) is prepared.
ChemInform Abstract: Reactions of N‐Halogenobenzylmethylamines with Triethylamine in Acetonitrile. Effect of Leaving Group Upon the Imine‐Forming Transition State.
Authors: CHO B. R. , NAMGOONG S. K. , KIM T. R. 
Published: May 2016

AbstractEliminations from (I) are quantitative and regiospecific.
ChemInform Abstract: Mapping the Molecular Pathway During Photoaddition of Guest Acetophenone and p‐Fluoroacetophenone to Host Deoxycholic Acid as Studied by X‐Ray Diffraction in Systems Undergoing Single‐Crystal‐to‐Single‐Crystal Transformation.
Authors: CHANG H. C. , POPOVITZ‐BIRO R. , LAHAV M. , LEISEROWITZ L. 
Published: May 2016

AbstractThe structures of the partially reacted crystals of the two complexes (5:2) deoxycholic acid (DCA)‐acetophenone and (8:3) DCA‐p‐fluoroacetophenone are determined by low‐temp.
ChemInform Abstract: Formation of 4,6‐Dinitro‐2‐nitrosoaniline (III) by Intramolecular Redox Reaction of Esters and Amides of 2‐(2,4,6‐Trinitroaniline) Carboxylic Acids.
Authors: MACHACEK V. , HASSANIEN M. M. M. , STERBA V. , LYCKA A. 
Published: May 2016

AbstractTitle compound (III) is formed in the reaction of glycine or alanine esters (I) with MeO‐ in MeOH.
ChemInform Abstract: Unusual Synthesis of 1,1,4,4‐Tetraarylbutatrienes.
Authors: MEDVEDEVA A. S. , CHICHKAREVA G. G. , DEMINA M. M. , VYAZANKIN N. S. 
Published: May 2016

AbstractTreatment of the butynedioles (I) with sulfuric acid in ethanol produces the tetraarylcumulenes (II).
ChemInform Abstract: New Generation and Intramolecular Diels‐Alder Reaction of Isobenzofurans: An Efficient Furan Ring‐Transfer Reaction and a Synthetic Entry into the Polycyclic Ring Systems.
Authors: YAMAGUCHI Y. , YAMADA H. , HAYAKAWA K. , KANEMATSU K. 
Published: May 2016

AbstractThe isobenzofuran derivatives (II) and (III) are obtained by intramolecular Diels‐Alder reaction of the furfuryl propargyl ethers (I).
ChemInform Abstract: Synthesis and Antimicrobial Activity of Substituted 3,4‐Dihydro‐2H‐1‐benzopyrans.
Authors: AHLUWALIA V. K. , NAYAL L. , KALIA N. , BALA S. , TEHIM A. K. 
Published: May 2016

AbstractReaction of the benzopyrans (I) with the aldehydes (II) yields products of type (III) which are hydrogenated to give type (IV).
ChemInform Abstract: Cinnolines. Part 1. Widman‐Stoermer Reactions of Functionalized 2‐Phenylbut‐2‐enes to Give Cinnolinecarbaldehydes.
Authors: BARTON J. W. , PEARSON N. D. 
Published: May 2016

AbstractThe preparation of cinnoline‐3,4‐dicarbaldehyde (X), a hitherto unknown compound, is described.
ChemInform Abstract: Selective Ring Openings of Isomeric Fused Thiazolium Salts with Nucleophiles.
Authors: HAJOS GY. , MESSMER A. , KORITSANSZKY T. 
Published: May 2016

AbstractThe angularly fused thiazoloquinolinium salt (I) reacts with morpholine (II), producing the adduct (III), whereas the isomeric salt (IV) gives the enamine (V), which is cyclized on treatment with fluoroboric acid to yield the salt (VI).
ChemInform Abstract: Chemistry of Cationic Zirconium(IV) Benzyl Complexes. One‐Electron Oxidation of d0 Organometallics.
Authors: JORDAN R. F. , LAPOINTE R. E. , BAJGUR C. S. , ECHOLS S. F. , WILLETT R. 
Published: May 2016

AbstractReaction of the dibenzyl‐Zr compound (I) with AgBPh4 in MeCN leads to the cationic benzyl complex (III) in which the benzyl ligand is bonded to Zr in an η2 fashion through both the methylene‐C atom and the phenyl π system (no yield given).
ChemInform Abstract: Synthesis and Structure of (OC)4Fe=Si(OtBu)2·HMPA, a Donor‐Stabilized Silanediyl (“Silylene”) Complex.
Authors: ZYBILL C. , MUELLER G. + 
Published: May 2016

AbstractThe title complex (V), the first stable silanediyl complex, is obtained as shown via its THF analogue.
ChemInform Abstract: Formation of Imidates, Amides, Amines, Carbamates, and Ureas from the μ3‐NPh Ligands of Fe3(μ3‐NPh)2(CO)9.
Authors: WILLIAMS G. D. , WHITTLE R. R. , GEOFFROY G. L. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe bis(nitrene) cluster (I) reacts with LiR1 (II), NaOMe (IV), and Li(BHEt3) (V) to form the acyl clusters (III).
ChemInform Abstract: Photoelectrochemical Properties of Semiconductor Diamond.
Authors: PLESKOV YU. V. , SAKHAROVA A. YA. , KROTOVA M. D. , BOUILOV L. L. , SPITSYN B. V. 
Published: May 2016

AbstractThe photoelectrochemical properties of synthetic diamond are investigated for the first time by measurements of the photocurrent, differential capacity, and dark current vs.
ChemInform Abstract: Interaction of Br with Ag(110): Comparison of Electrochemical and Gas‐Phase Adsorption Measurements.
Authors: BANGE K. , STRAEHLER B. , SASS J. K. , PARSONS R. 
Published: May 2016

AbstractMeasurements of the work function change of Ag(110) under UHV (ultra‐high vacuum) conditions with adsorption of Br alone or together with H2O suggest that the charge separation perpendicular to the surface between Br and the metal is very small and that the net orientation of H2O is relatively small.
ChemInform Abstract: Hydrogen Photoevolution at p‐Type Silicon Electrodes Coated with Discontinuous Metal Layers.
Authors: NAKATO Y. , YANO H. , NISHIURA S. , UEDA T. , TSUBOMURA H. 
Published: May 2016

AbstractA p‐Si electrode, coated with a uniform layer of Au or Pt using the vacuum evaporation technique, loses its photoactivity and behaves just like a simple metal electrode (nearly ohmic metal/p‐Si contact).
ChemInform Abstract: Production of (R)‐1‐(1,3‐Dithian‐2‐yl)propan‐2‐ol by Microbial Reduction.
Authors: BERNARDI R. , CARDILLO R. , GHIRINGHELLI D. , VAJNA DE PAVA O. 
Published: May 2016

AbstractThe reduction of the carbonyl compounds (I) with Streptomyces species, Aspergillus niger and Geotrichum candidum is studied.
ChemInform Abstract: Enantioselective Carbon‐Carbon Bond Formation by Chiral Organo‐Titanium Compounds. Methyltitanium (S)‐N‐Acylpyrrolidinylmethoxide Diisopropoxides.
Authors: TAKAHASHI H. , KAWABATA A. , HIGASHIYAMA K. 
Published: May 2016

AbstractThe chiral auxiliaries (I), (III), (V), (VII), and (IX) are prepared as outlined in the reaction scheme starting with the corresponding S‐prolin derivatives.
ChemInform Abstract: The Direct Conversion of Epoxides into Alkenes via Iodohydrins by in situ Generated HI.
Authors: GARLASCHELLI L. , VIDARI G. 
Published: May 2016

AbstractEpoxides are easily converted to iodohydrins and alkenes are obtained from either epoxides or iodohydrins in good to excellent yields (60‐95%) by treatment with HI, generated in situ from Ph3P·I2 in moist MeCN (iodohydrin: PPh3: I2 = 1.0:0.6:0.1).
ChemInform Abstract: Synthesis, X‐Ray Crystal Structure, and Cation Transfer Properties of a Calix(4)arene Tetraketone, a New Versatile Molecular Receptor.
Authors: FERGUSON G. , KAITNER B. , MCKERVEY M. A. , SEWARD E. M. 
Published: May 2016

AbstractThe tetrahydroxycalix(4)arene (Ia) reacts with bromoacetone (II) in the presence of a base to give the calix(4)arene tetraketone (Ib).
ChemInform Abstract: Methyl 3‐Benzenesulfonylorthopropionate: An Efficient Reagent for the Synthesis of γ‐Lactones and Butenolides.
Authors: CARRETERO J. C. , DE LOMBAERT S. , GHOSEZ L. 
Published: May 2016

AbstractMethyl 3‐benzenesulfonylorthopropionate (I) reacts with butyllithium and the aldehydes and ketones (II), yielding the β‐sulfonyl alcohols (III).
ChemInform Abstract: Reactions of Quaternary Ammonium Salts Containing Polyfluoroalkyl. Part 2. Thermal Ring Opening Reactions of 1‐(Polyfluoroalkyl)‐4‐aza‐1‐ azoniabicyclo(2.2.2)octane Salts.
Authors: KUWABARA M. , FUKUNISHI K. , NOMURA M. , YAMANAKA H. 
Published: May 2016

AbstractThe 1‐fluoroalkyl diazobicyclooctane ammonium salts (I) are thermally cleaved, yielding the piperazine derivatives (II) and (III) depending on the temperature.
ChemInform Abstract: 1,3λ3‐Thiaphospholes.
Authors: MAERKL G. + , ECKL E. , JAKOBS U. , ZIEGLER M. L. , NUBER B. 
Published: May 2016

AbstractThe mesoionic dithiolium derivatives (I) react with the phosphaalkene (II), producing the thiaphospholes (IV) after cleavage of the intermediate adducts (III).
ChemInform Abstract: The First Stable Germene: A Compound with a Germanium‐Carbon Double Bond.
Authors: COURET C. , ESCUDIE J. , SATGE J. , LAZRAQ M. 
Published: May 2016

AbstractThe dehydrofluorination of (I) leads to the stable and highly air‐sensitive germene (III), which can be isolated in part quantitatively as the adducts (IV) which exhibit thermochromism between ‐100 and 85 °C. Protic reagents such as H2O, MeOH, LiAlH4, or dimethyl disulfide add quantitatively to the double bond of (IVa) to give products such as (Va) or (Vb).
ChemInform Abstract: Coordination of Small Molecules by Manganese(II) Phosphine Complexes. Reaction of Some (MnX2L) (X: Cl, Br, or I; L: PPr3, PMe2Ph, or PPh3) Complexes with Tetracyanoethylene.
Authors: GOTT G. A. , MCAULIFFE C. A. 
Published: May 2016

AbstractReaction of the title complexes (I) with 1.5 equiv. of tetracyanoethylene (II) in toluene slurries leads to the 1:1 adducts (III).
ChemInform Abstract: The Efficient Consecutive β‐Carboxylation and α‐Alkylation of Cyclic α,β‐Enones. A New Route to Sarkomycin.
Authors: OTERA J. , NIIBO Y. , AIKAWA H. 
Published: May 2016

AbstractThe cycloalkenones (I) react with the lithiated methoxy(phenylthio)silylmethane (II) and the alkyl halides (III) to produce the trans‐substituted cycloalkanones (IV).
ChemInform Abstract: Substitution Reactions and Luminescence Spectra of the Mixed Complexes (ReClxBr6‐x)2‐.
Authors: FLINT C. D. , LANG P. F. 
Published: May 2016

AbstractRapid precipitation of Cs(SnCl6) from aqueous solutions containing (ReBr6)2‐ and HCl produces homogeneous crystalline solids, which luminesce strongly under blue or UV excitation.
ChemInform Abstract: Ozone and Oxygen Evolution on PbO2 Electrodes in Acid Solution.
Authors: KOETZ E. R. + , STUCKI S. 
Published: May 2016

AbstractBased on voltammetric results at various electrolyte temp. and compositions a mechanism for the anodic reaction on PbO2 in acid electrolytes is proposed involving at least three parallel processes, two of which lead to O2 and one to the intended product O3.
ChemInform Abstract: Lamellar Inorganic Ion Exchangers. Proton‐Copper(II) Ion Exchange in γ‐Titanium Bis(hydrogenphosphate).
Authors: ALVAREZ C. , LLAVONA R. , GARCIA J. R. , SUAREZ M. , RODRIGUEZ J. 
Published: May 2016

AbstractStudies of ion exchange of Cu2+ into γ‐Ti(HPO4)2·2 H2O (exchange isotherms and pH curves at 25, 40, and 55 °C) indicate the formation of the half‐exchanged phases (Ia)‐(Ic) with interlayer distances of 12.4, 10.7, and 9.4 Å, respectively.
ChemInform Abstract: Reaction Between Trioxodinitrate and the Pentaamminenitrosylruthenium(II) Cation.
Authors: AKHTAR M. J. , BONNER F. T. , HUGHES M. N. , LU C.‐S. , WALLIS H. L. , WIMBLEDON P. E. 
Published: May 2016

AbstractThe reaction between N2O32‐ and Ru(NH3)5NO3+, which is investigated over the pH range 6‐14, results at pH ∼ 10 in rapid formation of NO followed by much slower development of N2O and N2, in relative proportions that vary with pH.
ChemInform Abstract: A Novel Periodate: On the Structure of K9Li3I2O13 = K9Li3O(IO6)2.
Authors: UNTENECKER H. , HOPPE R. 
Published: May 2016

AbstractWeakly dichroitic single crystals of the title compound are prepared for the first time by annealing intimate mixtures of KIO4, KO0.68, and Li2O (1:1:1.5, 800 °C, 42 d).