bluuebunny/crossref_metadata_2025_split huggingface dataset:
LVB-jongeren in de ZSM-procedure
Authors: Teeuwen M. 
Published: December 2017

Young MBID suspects in the ZSM-procedure in the Netherlands. On vulnerability and risk of recidivism
In recent years, there are signs that young people with a (mild) intellectual disability are overrepresented in the criminal justice system. It turns out that especially a large majority of the repeated offenders have an intellectual disability. Therefore it would be relevant to know whether and when an intellectual disability is recognized by professionals in the criminal procedure. What is the impact of not recognizing the specific disability on the offender in the criminal justice procedure and on recidivism? The author focuses on a rather new accelerated out-of-court settlement of criminal cases, the so-called ZSM method. She concludes that the high speed of this procedure increases the vulnerability of suspects with a (mild) intellectual disability, especially because the various professionals involved in this procedure seem to lack substantial awareness of the problem. This situation increases the risk of false confessions and witnessing and might also contribute to recidivism.
Graphene-modified nickel foam electrode for cathodic degradation of nitrofuranzone: Kinetics, transformation products and toxicity
Authors: Ma Ya , Tang Yanhong , Yin Kai , Luo Shenglian , Liu Chengbin , Liu Tian , Yang Liming 
Published: December 2017

Simple, efficient, and durable electrodes are highly demanded for practical electro­chemical process. In this study, a reduced graphene oxide modified nickel foam electrode (GR‑Ni foam) was facilely prepared via one-step cyclic voltammetry electrodeposition of gra­phene oxide suspension onto the Ni foam. The electrochemical degradation of nitrofuran­zone (NFZ, a kind of typical antibiotics) was studied on the GR-Ni foam cathode. The cyclic voltammetry and electrochemical impedance spectra analysis confirmed that presence of GR loading accelerated the electron transfer from the cathode surface to NFZ. With the applied cathode potential of −1.25 V (vs. Ag/AgCl), the removal efficiency of NFZ (C0 = 20 mg L−1) at the GR-Ni foam electrode reached up to 99 % within 30 min, showing a higher reaction rate constant (0.1297 min−1) than 0.0870 min−1 at the Pd-Ni foam and 0.0186 min−1 at the Ni foam electrode. It was also found that the pH, dissolved oxygen and NFZ initial concentration have slight effect on NFZ degradation at the GR-Ni foam electrode. The reactions first occurred at nitro groups (-NO2), unsaturated C=N bonds and N-N bonds to generate furan ring-containing products, and then these products were transformed into linear diamine products. The direct reduction by electrons was mainly responsible for NFZ reduction at the GR-Ni foam electrode. Even after 18 cycles, the removal efficiency of NFZ still reached up to 98 % within 1 h. In addition, the cathodic degradation process could eliminate the antibacterial activity of NFZ. The GR-Ni foam electrode would have a great potential in electrochemical process for treating wastewater containing furan antibiotics.
1966: O ANO EM QUE FOUCAULT VENDEU COMO PÃEZINHOS
Authors: Ribeiro Guilherme Almeida 
Published: December 2017

<p>O artigo examina os efeitos da publicação de <em>As palavras e as coisas</em> em 1966, no que se refere às polêmicas em torno do momento francês do estruturalismo. Nesse sentido, são discutidos os diferentes diagnósticos proferidos por Foucault acerca do sentido difuso do estruturalismo no cenário filosófico francês do pós-guerra, especialmente quanto ao esgotamento das narrativas do humanismo marxista e fenomenológico. Trata-se também de apontar a singularidade da estratégia de Foucault quanto ao que ele compreendia serem as potências renovadoras do estruturalismo naquelas circunstâncias políticas e acadêmicas.<br /> </p>
O HOMEM E A CRÍTICA EM AS PALAVRAS E AS COISAS: KANT, NIETZSCHE, FOUCAULT E ALÉM
Authors: Alves Marco Antônio Sousa 
Published: December 2017

<p>RESUMO</p><p>O artigo pretende colocar na luz dois temas centrais em <em>As palavras e as coisas</em>: a questão do nascimento e da morte do homem e a reflexão sobre o que caracteriza uma filosofia crítica. E ao olhar para esses dois grandes eixos, duas referências incessantes no pensamento de Foucault terão maior destaque: Kant e Nietzsche. O artigo pretende acompanhar a presença desses filósofos em <em>As palavras e as coisas</em>, destacando a importância deles no desenho do projeto arqueológico. Além disso, o artigo defenderá que <em>As palavras e as coisas</em> pode ser lida como uma autêntica experiência de pensamento que exemplifica a postura crítica da “ontologia do presente”, encarnando o <em>ethos</em> filosófico que no final de sua vida Foucault chamará de “atitude de modernidade”.</p><p>PALAVRAS-CHAVE: Homem. Crítica. Foucault. Kant. Nietzsche. <strong> </strong></p>
EPISTEMOLOGIA BARROCA DE TRISTE FIGURA: DOM QUIXOTE COMO PERSONAGEM EMBLEMÁTICO DA TRANSFORMAÇÃO DA EPISTÈMÊ DO SÉCULO XVII A PARTIR DE "AS PALAVRAS E AS COISAS" DE FOUCAULT
Authors: Fianco Francisco 
Published: December 2017

O presente texto tem como tema a representação do personagem e da obra de Cervantes, <em>Dom Quixote</em>, dentro da reflexão de Michel Foucault sobre a transformação dos modelos epistemológicos da civilização ocidental na passagem do Renascimento para o Classicismo presente nos primeiros capítulos de sua obra <em>As Palavras e as Coisas. </em>Para tanto, usaremos, além do texto já citado de Foucault, um conto do escritor argentino Jorge Luís Borges referido por Foucault, <em>El Idioma Analítico de John Wilkins</em>, bem como o livro de Jean Calmon <em>O Dom Quixote de Foucault. </em>
A PRIMEIRA FIGURA DE EXCEÇÃO: O GÊNIO NO PENSAMENTO NIETZSCHIANO
Authors: Oliveira Eduardo Marcos Silva 
Published: December 2017

<p class="EDCorpodeTexto">O presente artigo ocupa-se com a apresentação do pensamento do jovem Nietzsche, descrevendo o gênio na arte trágica na perspectiva de <em>O nascimento da tragédia</em>, tendo-a como primeira experimentação filosófica de Nietzsche. Dessa forma, optamos por desenvolver este artigo enfatizando a definição de uma das figuras de exceção em sua produção filosófica, o gênio.<em> </em>Expressão que sintetiza a primeira busca por uma nova concepção de valores em sua filosofia. Analisando este primeiro período de produção do filósofo, o texto se desenvolve sobre a constatação feita pelo autor de gênio apolíneo e gênio dionisíaco, e como essa definição é descrita na formação da cultura ocidental e é realçada na sociedade moderna.</p><div><div><h1> </h1></div></div>
ESSE ESTRANHO/ESTRANGEIRO CONHECIDO QUE NOS HABITA
Authors: Flecha Renata Dumont 
Published: December 2017

<p>A Psicanálise se debruça, ao longo de sua história, sobre a temática do estrangeiro, ou ainda, do estranho, que, é ao mesmo tempo um conhecido que nos habita desde sempre. Assim, para encaminhar as reflexões aqui propostas nos remeteremos, inicialmente, a um texto de Freud, de 1919, de nome “Das unheimliche”, ou “O Estranho”. O Estranho se articula com o inconsciente e suas manifestações, que produzem no sujeito um sentimento de ultrapassagem, como se fora atropelado por um outro sujeito que ele desconhece, um estranho, que se impõe em seu discurso. Uma outra manifestação do estranho, em sua, digamos, radicalidade se apresenta através da loucura. O estranho se vincula ao desejo que para a Psicanálise remete a uma ordem simbólica. Ele sempre demarca uma falta e não para um objeto que possa ser empiricamente considerado. Assim, deslocando de objeto em objeto, o desejo desliza em numa série infinita, numa satisfação nunca atingida e para sempre adiada. Freud nos ensinou que o objeto do desejo é um objeto perdido, uma falta, e que esse objeto perdido para sempre, mantém sua presença como falta. A falta é, assim, a condição fundamental do sujeito e de sua humanidade. </p>
A NOIVA ARIADNE: ENTRE A DIVERSIDADE E A DIFERENÇA
Authors: Vitkowski José Rogério 
Published: December 2017

<p align="left"> </p><p>RESUMO: Este artigo, de natureza filosófica, tem como objeto de estudo as noções de diversidade e diferença. A pesquisa bibliográfica tem como horizonte teórico a filosofia da multiplicidade, com foco no legado do filósofo Gilles Deleuze. Propõe-se nesse texto explorar cartograficamente algumas linhas de composição da ontologia deleuzeana na qual os conceitos de diversidade e diferença se apresentam como operadores singulares que se distinguem e que permitem entrever os contornos da noiva Ariadne, ou seja, da Diferença. Dito de outro modo contornos do Ser como Diferença. Nesse cenário se situa o problema da domesticação da diferença perpassado pelo registro da representação, que tem origem em Platão, até se chegar a Nietzsche, ao novo modo de pensar a diferença, como diferença não submetida ao mesmo. </p><pre> </pre><p> </p>
POLÍTICAS PÚBLICAS PARA A DIVERSIDADE
Authors: Gomes Nilma Lino 
Published: December 2017

A partir do século XXI, as mudanças tecnológicas, a aproximação das fronteiras via mundo virtual, as imigrações, as desigualdades, a globalização capitalista, os fundamentalismos, a luta pela terra e pela igualdade de direitos assumem outros contornos. Nesse processo, o termo diversidade começou a ser mais usado, no campo das políticas, para nomear as diferentes formas de “ser diferente”, bem como os dilemas e avanços dessa questão no contexto das relações de poder. Este artigo apresenta e analisa as mudanças ocorridas no Estado brasileiro, a partir da implementação das políticas públicas para a diversidade, com ênfase nas ações do governo federal no período de 2003 a 2016. Discute o relevante papel das pressões e reivindicações dos movimentos sociais de caráter emancipatório e dos coletivos sociais diversos transformados em desiguais, nessa mudança. Adverte sobre o perigo de retrocesso dessas políticas devido ao atual momento histórico e político de avanço das forças conservadoras e do realinhamento da direita e do capitalismo no Brasil e em outros países do mundo.
La «dimensión religiosa» de la fenomenología de la donación de J.-L. Marion
Authors: Roggero Jorge Luis 
Published: December 2017

¿Puede hablarse de un «giro teológico» respecto de la fenomenología de Jean-Luc Marion? ¿La acusación de Dominique Janicaud es pertinente? ¿Mantiene aún alguna vigencia? Habría que responder que el diagnóstico de Janicaud es acertado y, al mismo tiempo, que no lo es. Existe una «dimensión religiosa» en la fenomenología de la donación, pero ésta no debe leerse como un obstáculo para la tarea fenomenológica. Este artículo se propone establecer de qué modo opera esta «dimensión religiosa» en la propuesta de Marion.
Quentin Meillassoux, Después de la finitud. Ensayo sobre la necesidad de la contingencia
Authors: Rossi Gastón Ricardo 
Published: December 2017

Reseña de Después de la finitud, el primer libro publicado por Quentin Meillassoux (discípulo de Alain Badiou) y un ensayo que ha cobrado relevancia por ser la semilla del reciente movimiento filosófico llamado “realismo especulativo”.
Is habitat important? Morphology and genome size of Epipactis helleborine (L.) Crantz (Orchidaceae) growing in anthropogenic and natural habitats
Authors: Rewicz Agnieszka , Rewers Monika , Jędrzejczyk Iwona , Rewicz Tomasz , Kołodziejek Jeremi , Jakubska-Busse Anna 
Published: December 2017

Background. The process of apophytism or spreading native species to human-made habitats is one of the main elements in the creation of plant cover in anthropogenic areas. Lately, an increase of anthropogenic localities with valuable flora (rare and law protected species) has been observed. Apophytes are also members of the family Orchidaceae, especially from the genus Epipactis. The aim of the study was to i) determine and compare the phenotypic variation of E. helleborine plants in anthropogenic and natural habitats, ii) compare the genome size estimation of plants growing in natural and anthropogenic habitats. The results reported in this study may indicate that a habitat influences morphological characteristics of plant species.
Methods. The research was carried out in Poland from 2011 to 2013. The study sites were located in three different geographical regions: from the Białowieża Primeval Forest, Northern East Poland, through Central Poland, to the Lower Silesia Province, Southern West Poland. We investigated eight populations of E. helleborine: four from natural habitats and four from anthropogenic habitats. Biometrical analyses were performed on shoots and flowers. The flowers were characterised by 25 biometric features and measured using a Nikon SMZ 800 binocular, microscopic Moticam-1SP cameras and the MIPlus07 program (Conbest Co.). The nuclear DNA content was determined in fresh and young leaves of E. helleborine, collected from eight populations.
Results. We observed that in anthropogenic populations: i) shoots were higher than shoots from natural populations, ii) flowers differed significantly in terms of ten biometric features between habitats, iii) the genome size differed significantly between the plants growing in natural and anthropogenic habitats.
Discussion. According to some researchers, the presence of phenotypic plasticity and the occurrence of ecotypes are adaptation strategies of plants to environmental changes. In our opinion, in the case of the studied anthropogenic habitats (roadside) in which the E. helleborine populations grew, we can talk about ecofen due to the often repeated set of characteristic features. i.e.: high shoots, long inflorescence and long, broad leaves. We agree, however, that it is difficult to isolate a taxonomic unit for ecofen due to the lack of experimental research.
Theta Burst Stimulation Protocols for Schizophrenia
Authors: Kishi Taro , Ikuta Toshikazu , Sakuma Kenji , Hamanaka Shun , Nishii Yasufumi , Hatano Masakazu , Kito Shinsuke , Iwata Nakao 
Published: October 2024

ImportanceTo date, several theta burst stimulation (TBS) protocols, such as intermittent TBS (iTBS), have been proposed; however, previous systematic reviews have revealed inconsistent efficacy findings in individual TBS studies for schizophrenia.ObjectiveTo examine which TBS protocols are associated with the most favorable and acceptable outcomes in adults with schizophrenia.Data SourcesThe Cochrane Library, PubMed, and Embase databases were searched for studies published before May 22, 2024.Study SelectionThe inclusion criteria were as follows: (1) published and unpublished randomized clinical trials (RCTs) of any TBS treatment and (2) RCTs including individuals with schizophrenia spectrum disorders, other psychotic disorders, or both.Data Extraction and SynthesisThis study followed the Cochrane standards for data extraction and data quality assessment and used the Preferred Reporting Items for Systematic Reviews and Meta-Analyses guideline for reporting. The risk of bias of individual studies was assessed using the second version of the Cochrane risk of bias tool, and the Confidence in Network Meta-Analysis application was used to rate the certainty of evidence for meta-analysis results. At least 2 authors double-checked the literature search, data transfer accuracy, and calculations.Main Outcomes and MeasuresThe primary outcome of this study was improvement in scores related to negative symptoms. Our frequentist network meta-analysis used a random-effects model. The standardized mean difference (SMD) or odds ratio for continuous or dichotomous variables, respectively, was calculated with 95% CIs.ResultsA total of 30 RCTs of 9 TBS protocols, with 1424 participants, were included. Only iTBS over the left dorsolateral prefrontal cortex (L-DLPFC) was associated with reduced negative symptom scores (SMD, −0.89; 95% CI, −1.24 to −0.55), overall symptom scores (SMD, −0.81; 95% CI, −1.15 to −0.48), Positive and Negative Syndrome Scale general subscale scores (SMD, −0.57; 95% CI, −0.89 to −0.25), depressive symptom scores (SMD, −0.70; 95% CI, −1.04 to −0.37), and anxiety symptom scores (SMD, −0.58; 95% CI, −0.92 to −0.24) and improved overall cognitive impairment scores (SMD, −0.52; 95% CI, −0.89 to −0.15) compared with a sham. However, positive symptom score changes, all-cause discontinuation rate, discontinuation rate due to adverse events, headache incidence, and dizziness incidence did not significantly differ between any TBS protocols and sham.Conclusions and RelevanceIn this network meta-analysis, iTBS over the L-DLPFC was associated with improved scores for negative, depressive, anxiety, and cognitive symptoms in individuals with schizophrenia and was well tolerated by the participants. Other forms of TBS were not associated with benefit. Further research is needed to assess the potential role of TBS in the treatment of schizophrenia.
Injectable Gene/Fiber‐Plexes Reverse Adipose Niche Senescence via Mito‐TERT Activation by Endogenous Mitochondrial Translocation
Authors: Zhang Yixiang , He Jiahao , Ling Shifeng , Xie Yun , Xiong Wei , Wang Juan , Du Yawei , Cui Wenguo , Li Qingfeng 
Published: October 2024

AbstractAddressing adipose niche senescence is crucial for preventing obesity‐related aging. Telomerase reverse transcriptase (TERT) is a promising target for gene therapy, but traditional methods lack precision and safety. A novel mitochondrion‐located TERT (mito‐TERT) activating approach is presented by injectable gene/short‐fiber complexes (gene/fiber‐plexes) to safely reverse adipose niche senescence from mitochondrial enhancement. The gene/fiber‐plexes are prepared from polydopamine‐coated short‐fibers to adsorb cationic dendrimers (PAMAM G3, PG3) carrying TERT plasmids and Coenzyme Q10 (CoQ10), termed PG3‐TERT@CoQ10. Upon intraperitoneal injection, the gene/fiber‐plexes adhere to the peritoneum and release PG3‐TERT@CoQ10, precisely targeting the adipose niche. Transient active oxygen scavenging by CoQ10 activates TERT transfection and endogenous mitochondrion translocation sequentially, enhancing mitochondrial function. In vitro and in vivo studies shows that gene/fiber‐plexes effectively targeted visceral adipose tissue, increased mito‐TERT levels and restored mitochondrial function. In an obese mouse model, they restored adipose tissue homeostasis and metabolic stability. RNA sequencing indicated reduced senescence‐related genes and restored cell cycle. This mito‐TERT activation strategy shows great promise for treating premature aging and metabolic diseases linked to adipose tissue senescence.
Synergistic Alkaline Hydrogen Evolution Catalysis over MoC Triggered by Doping Single Ru Atoms
Authors: Yin Jingwen , Lu Tingyu , Li Jing , Liu Jiayi , Lin Yingzi , Sun Dongmei , Xu Lin , Zhao Qun , Pang Huan , Zhang Songtao , Tang Yawen 
Published: October 2024

AbstractThe rational design of single atom‐based catalysts and precise elucidation of the synergistic interaction between the metal site and substrate are pivotal to identifying the real active sites and explicating the catalytic mechanisms at the atomic scale, thus contributing to the development of high‐performance catalysts for diverse industrial implementations. Herein, a Ru single‐atom doping strategy is developed to activate the MoC substrate with superior hydrogen evolution reaction (HER) activity in an alkaline medium. The atomically dispersed Ru sites are elaborately doped into MoC nanoparticles loaded on 3D N‐doped carbon nanoflowers (Ru‐SAs@MoC/NCFs hereafter). The experimental results and theoretical calculations manifest that the atomically isolated Ru dopants can effectively trigger the Mo sites with thermodynamically favorable water adsorption/dissociation energies and facilitate the OH− desorption on Ru sites and H adsorption on N sites, thus synergistically expediating the overall alkaline HER kinetics. As such, the well‐designed Ru‐SAs@MoC/NCFs demonstrate extraordinary HER activity with a low overpotential of 16 mV at 10 mA cm−2 in 1.0 m KOH electrolyte, outperforming Pt/C benchmark and a vast of molybdenum/ruthenium‐based HER catalysts reported to date. These findings disclose the alkaline HER mechanistic induced by the atomic doping modulation and suggest a design principle of high‐efficiency electrocatalysts via the atomic‐level manipulation leverage.
Synthetic Control of Water‐Stable Hybrid Perovskitoid Semiconductors
Authors: Kim Jiyoon , Ghosh Soumyadeep , Smith Nicholas W. G. , Liu Sunhao , Dou Yixuan , Slebodnick Carla , Khodaparast Giti A. , Qian Jin , Quan Lina 
Published: October 2024

AbstractHybrid metal‐halide perovskites and their derived materials have emerged as the next‐generation semiconductors with a wide range of applications, including photovoltaics, light‐emitting devices, and other optoelectronics. Over the past decade, numerous single‐crystalline perovskite derivatives have been synthesized and developed. However, the synthetic methods for these derivatives mainly rely on acidic crystallization conditions. This approach leads to crystals comprising metal halide building blocks, which show problematic stability when directly exposed to water. In this study, a methodology is developed for synthesizing hybrid metal‐halide compounds using lead iodide and the zwitterionic bifunctional molecule cysteamine (CYS), to form various perovskitoid structures under a broad pH range. Interestingly, the different pH conditions alter the coordination environment of lead halides, leading to lead‐sulfide and lead‐nitride covalent bond formation. This modification significantly enhances their stability when in direct contact with water, lasting for months. Photoluminescence measurements and first principal density functional theory (DFT) calculations reveal that the perovskitoids synthesized under basic and acidic pH conditions exhibit a direct bandgap nature, while those synthesized under neutral conditions display an indirect bandgap. This approach opens new avenues for manipulating synthetic methods to develop water‐stable hybrid semiconductors suitable for a wide range of applications, such as solid‐state light emitters.
A Multi‐Functional New Acceptor for Ultra‐Broad Multiple Emission, Long‐Persistence Thermally Activated Delayed Fluorescence and Room Temperature Phosphorescence
Authors: Andruleviciene Viktorija , Leitonas Karolis , Bernard Ronit Sebastine , Woon Kai Lin , Volyniuk Dmytro , Sini Gjergji , Grazulevicius Juozas Vidas 
Published: October 2024

AbstractAiming to design new efficient organic triplet emitters, here a new electron‐accepting moiety 11,13‐dihydro‐12H‐dibenzo[a,c]imidazo[4,5‐i]phenazin‐12‐one (BIPO) are reported. Three new BIPO derivatives containing long alkyl chains, namely DBIPO (acceptor only), DBIPOBr (acceptor containing bromine atoms), and DBIPOAc with acridan moieties in a donor‐acceptor‐donor configuration, are designed and investigated. Efficient room temperature phosphorescence (RTP) is detected for the three compounds, stemming from a high‐lying (anti‐Kasha type) triplet emission occurring in the acceptor moiety. Additionally, the tetrahydrofuran‐ and dichloromethane DBIPOAc solutions show (i) a dual‐band photoluminescence profile stemming from anti‐Kasha emissions from high‐lying charge‐transfer (1CT) and locally excited (1LE) states, and (ii) a thermally activated delayed fluorescence (TADF) from the same high‐lying 1CT state. Importantly, DBIPOAc doped in rigid nonpolar polymer Zeonex simultaneously exhibits both TADF and RTP, with the emission quantum yield reaching 69.6%. Due to these properties, the BIPO derivatives constitute promising candidates as multi‐functional new emitters for the preparation of active layers of electroluminescent devices and optical oxygen/pressure sensors. The reasons for these interesting properties are discussed in detail.