bluuebunny/crossref_metadata_2025_split huggingface dataset:
Neurology training in sub‐Saharan Africa: A survey of people in training from 19 countries
Authors: Mateen Farrah J. , Clark Sarah J. , Borzello Mia , Kabore Jean , Seidi Osheik 
Published: March 2016

ObjectiveTo provide a comprehensive understanding of neurology training from the sub‐Saharan African perspective.MethodsA 40‐question survey was distributed to attendees of the 7th annual sub‐Saharan African neurology teaching course in Khartoum, Sudan (2015). Themes included the student body, faculty, curriculum, assessment and examinations, technology, and work hours and compensation.ResultsOf 19 responding countries, 10 had no formal neurology training programs; Burkina Faso, Cameroon, Republic of the Congo, and Mozambique had an adult neurology program; Ethiopia, Madagascar, Nigeria, Senegal, and South Africa had adult and pediatric neurology programs (training duration range = 3–6 years). There was a median of 2.5 full‐time neurologists on the teaching faculty at the respondents' training institutions (neurologists on‐faculty:in‐country ratio = 0.48), with the lowest ratios in Sudan and Nigeria. Neurology was perceived to be a competitive specialty for entrance in 57% of countries, with 78% of respondents reporting a requisite entrance examination. Ninety‐five percent had access to a personal smartphone, 62% used the Internet more than occasionally, and 60% had access to online neurology journals. The average number of weekly work hours was 51 (range = 40–75), and average monthly salary among those earning income was 1,191 USD (range = 285–3,560). Twenty percent of respondents reported paying for training. The most common barriers to neurology postgraduate education were few training programs and lack of training in neurodiagnostic tests. Among 17 reporting countries, there is an estimated average of 0.6 neurologists per million people.InterpretationNeurology training programs in sub‐Saharan Africa are relatively limited in number and have several unmet needs including a small cadre of faculty and an opportunity to standardize curricula and financing of programs. Ann Neurol 2016;79:871–881
Surface modification of polypropylene by the entrapping method using the short‐chained stearyl‐alcohol poly(ethylene oxide) ether modifier
Authors: Guo Haofei , Huang Juexin , Ye Yuansong , Huang Jian , Wang Xiaolin 
Published: March 2016

ABSTRACTOn the basis of the short‐chained modifier of stearyl‐alcohol poly(ethylene oxide) ether (AEO), an entrapping modification was carried out on the polypropylene (PP) surface for hydrophilic improvement. A swelling layer was confirmed locating in the amorphous region on the PP surface, from which the modifiers could penetrate into the surface. The AEO‐8 modifier achieved the optimal hydrophilic modification on the surface with a contact angle of 20.6° and modifier coverage of 19.2%. A microphase separation was speculated to occur between the poly(ethylene oxide) (PEO) chain of AEO and the PP substrate in the entrapping surface, after which surface‐enriched PEO chains could improve surface hydrophilicity, simultaneously, reserved stearyl chains in the surface could approach modifier fixation. Water immersion durability of the modified surface could be improved by establishing a covalent linkage in the surface‐fixed structure. This work gives more comprehensive insights in the entrapping modification on the semi‐crystalline PP surface based on the short‐chained and block modifier. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43607.
Chiral Phosphorus–Olefin Ligands for the RhI‐Catalyzed Asymmetric Addition of Aryl Boronic Acids to Electron‐Deficient Olefins
Authors: Chen Qian , Li Liang , Zhou Guangli , Ma Xiaoli , Zhang Lu , Guo Fang , Luo Yi , Xia Wujiong 
Published: March 2016

AbstractNew chiral phosphorus–olefin hybrid ligands derived from the rigid “privileged” l‐proline have been conveniently prepared and applied in the rhodium‐catalyzed asymmetric arylation of electron‐deficient olefins with arylboronic acids at room temperature; this reaction provides the desired products in excellent yields and high enantioselectivities. The origin of observed stereoselectivity has been investigated by density functional theory (DFT) calculations.
Generation of Hydroxyl Radicals in the Reaction of Dihydrogen with AuNbO4+ Cluster Cations
Authors: Jiang Li‐Xue , Li Xiao‐Na , Li Hai‐Fang , Zhou Zhen‐Xun , He Sheng‐Gui 
Published: March 2016

AbstractA molecular‐level insight into the nature of reactive oxygen species involved in dihydrogen (H2) dissociation is of great importance to understand gold catalysis. In this study, laser ablation generated and mass‐selected AuNbO4+ oxide cluster cations could dissociate H2 in an ion‐trap reactor. The reaction has been characterized by time‐of‐flight mass spectrometric experiments and density functional calculations. The lowest energy isomer of AuNbO4+ contains two lattice oxygen (O2−) and one superoxide (O2.−) species. The gold atom anchors the H2 molecule in the first step and then delivers one hydrogen atom to the O2− ion in H2 dissociation. At the same time, O2.− is reduced into a peroxide unit that can accept the second hydrogen atom of H2 with the generation of a hydroxyl radical as the main product. In this study, the important roles of the O2.− unit in the dissociation of H2 have been identified.
Fabrication of Nitrogen‐Doped Mesoporous‐Carbon‐Coated Palladium Nanoparticles: An Intriguing Electrocatalyst for Methanol and Formic Acid Oxidation
Authors: Ray Chaiti , Dutta Soumen , Sahoo Ramkrishna , Roy Anindita , Negishi Yuichi , Pal Tarasankar 
Published: March 2016

AbstractInspired by the attractive catalytic properties of palladium and the inert nature of carbon supports in catalysis, a concise and simple methodology for in situ nitrogen‐doped mesoporous‐carbon‐supported palladium nanoparticles (Pd/N‐C) has been developed by carbonizing a palladium dimethylglyoximate complex. The as‐synthesized Pd/N‐C has been exfoliated as a fuel cell catalyst by studying the electro‐oxidation of methanol and formic acid. The material synthesized at 400 °C,namely, Pd/N‐C‐400,exhibitssuperior mass activity and stability among catalysts synthesized under different carbonization temperaturesbetween300 and 500 °C. The unique 1D porous structure in Pd/N‐C‐400 helps better electron transport at the electrode surface, which eventually leads to about five times better catalytic activity and about two times higher stability than that of commercial Pd/C. Thus, our designed sacrificial metal–organic templatedirected pathway becomes a promising technique for Pd/N‐C synthesis with superior catalytic performances.
Exploring Coordination Modes: Late Transition Metal Complexes with a Methylene‐bridged Macrocyclic Tetra‐NHC Ligand
Authors: Altmann Philipp J. , Weiss Daniel T. , Jandl Christian , Kühn Fritz E. 
Published: March 2016

AbstractA tetranuclear silver(I) N‐heterocyclic carbene (NHC) complex bearing a macrocyclic, exclusively methylene‐bridged, tetracarbene ligand was synthesized and employed as transmetalation agent for the synthesis of nickel(II), palladium(II), platinum(II), and gold(I) derivatives. The transition metal complexes exhibit different coordination geometries, the coinage metals being bound in a linear fashion forming molecular box‐type complexes, whereas the group 10 metals adapt an almost ideal square planar coordination geometry within the ligand's cavity, resulting in saddle‐shaped complexes. Both the AgI and the AuI complexes show ligand‐induced metal–metal contacts, causing photoluminescence in the blue region for the gold complex. Distinct metal‐dependent differences of the coordination behavior between the group 10 transition metals were elucidated by low‐temperature NMR spectroscopy and DFT calculations.
Films Consisting of Innumerable Tapered Nanopillars of Mesoporous Silica for Universal Antireflection Coatings
Authors: Miyata Hirokatsu , Kitamura Shin , Watanabe Masatoshi , Takahashi Masahiko 
Published: March 2016

AbstractFilms with a fine structure consisting of innumerable nanopillars of mesoporous silica (MPS) are formed by a reactive ion etching process with a fluorine‐containing gas. Each nanopillar has a tapered shape with a uniform height, which effectively suppresses reflection by the formation of an ideal graded refractive index structure. The nanopillars are spontaneously formed under low‐pressure conditions, wherein locally deposited Al−F compounds, originating from an alumina plate in the etching chamber, work as a fine etching mask. The high etching rate of the MPS film allows a very high aspect ratio of the nanopillars. The refractive index of the MPS nanopillars can be universally tuned by a controlled incorporation of TiO2 into the mesopores, which results in effective reduction of reflectance on a given substrate. The outstanding antireflection performance is experimentally demonstrated for glass substrates with a wide refractive index range.
Laser power dependence of mechanoluminescence in metals
Authors: Sonwane V. D. , Gour Anubha S. , Jha Piyush 
Published: March 2016

AbstractMechanoluminescence (ML) glow is produced on the back side when the front of a metal sample is irradiated with infrared Nd:YAG laser pulses. An incident laser beam with a power density below the plasma‐flare onset threshold causes a rise in temperature in the studied metal. As the incident laser power density increases, the intensity of the ML glow signal also increases. On the basis of the laser power density‐induced temperature, an expression is derived for the temperature‐induced thermal stress. An expression is derived for the correlation between thermal stress and laser power density, which indicates that the temperature‐induced thermal stress is directly related to the incident laser power density. In the region of plastic deformation, temperature‐induced thermal stress is related to the strain and, consequently, to the emitted ML intensity. Finally, an expression is derived for the laser power dependence of the ML intensity, and good agreement is found between the theoretical and experimental results. Copyright © 2016 John Wiley & Sons, Ltd.
Shuttle‐like Porous Carbon Rods from Carbonized Metal–Organic Frameworks for High‐Performance Capacitive Deionization
Authors: Xu Xingtao , Li Jinliang , Wang Miao , Liu Yong , Lu Ting , Pan Likun 
Published: March 2016

AbstractOne of the most challenging issues in developing capacitive deionization (CDI) technologies is the rational design and synthesis of active electrode materials with favorable morphologies and high surface areas. Here, for the first time, shuttle‐like porous carbon rods (sPCRs) were prepared through a high temperature pyrolysis step and a subsequent etching step by using rod‐like metal–organic frameworks, MIL‐88 (Fe), as the precursor. The correlation between the carbonization temperature of sPCRs and their electrosorption performance was investigated, and it was found that, owing to their unique shuttle‐like rod structure and high specific surface area, sPCRs obtained at 900 °C exhibit a superior electrosorption capacity of 16.2 mg g−1 with excellent cycling stability, showing that sPCRs could be a promising electrode material for highly efficient CDI.
Electrodeposition of Sea Urchin and Cauliflower‐like Nickel‐/Cobalt‐Doped Manganese Dioxide Hierarchical Nanostructures with Improved Energy‐Storage Behavior
Authors: Biswal Avijit , Minakshi Manickam , Tripathy Bankim Chandra 
Published: March 2016

AbstractTransforming the existing Zn–MnO2 primary battery into a secondary battery with enhanced storage behavior and a low cost is of significant interest. Such technology could underpin future energy‐storage development. To acquire this, doped electrolytic manganese dioxide (EMD) with hierarchical nanoarchitectures have been employed as a cathode in the Zn–MnO2 system. EMD is synthesized from manganese sulfate in a sulfuric acid bath with in situ doping of nickel and cobalt ions individually. Sea‐urchin‐shaped EMD has been obtained with nickel as a dopant, whereas cauliflower‐ and pyramidal‐shaped hierarchical nanostructures are observed with cobalt as a dopant, using a facile galvanostatic method without employing any template or surfactant. The structural studies indicated that all EMD samples (in the absence and presence of dopants) are predominantly composed of gamma‐type manganese dioxide; however, the peak intensity increased with increasing concentration of the dopants. The electrochemical results revealed that the Co‐doped EMD composite played a crucial role in increasing the storage capacity of the Zn–MnO2 battery, whereas the Ni‐doped EMD composite resulted in improved longevity compared the Co‐doped and undoped counterparts. The EMD composites individually doped with Ni and Co resulted in improved storage behaviors of 395 and 670 mA h g−1, respectively, against the undoped sample which is 220 mA h g−1, implying that the presence of Co3O4 and mesoporous nanostructured surfaces enhanced the fast kinetics of electrochemical reactions.
RhI‐Catalyzed Cyclizative Addition Reaction of 1,6‐Enyne and Sulfonyl Chloride by Carbophilic Activation
Authors: Dang Mengyao , Hou Longlei , Tong Xiaofeng 
Published: March 2016

AbstractThe π‐acid‐catalyzed cyclizations of 1,n‐enynes by carbophilic activation have been extensively studied and appear as highly attractive processes, yet the cases within a catalytic cycle based on redox principle are rare. Herein, we report the cyclizative addition reactions of 1,6‐enynes and sulfonyl chlorides by using a [Rh(cod)Cl/dppf] (dppf=1,1′‐bis(diphenylphosphino)ferrocene) catalyst system. The process features the involvement of oxidative addition of sulfonyl chloride to RhI catalyst, which generates [(dppf)(RSO2)RhCl2] as a π‐acid species to trigger cyclizative addition in a 6‐endo‐dig manner by carbophilic activation. Moreover, the catalytic protocol is also applicable to 1,6‐diene analogues.
Hierarchically Self‐Assembled Star‐Shaped ZnO Microparticles for Electrochemical Sensing of Amines
Authors: Du Jianping , Huang Xiaoxi , Zhao Ruihua , Li Jinping , Asefa Tewodros 
Published: March 2016

AbstractNovel, hierarchically nanostructured, star‐shaped ZnO (SSZ) microparticles are synthesized by a hydrothermal synthetic route. The SSZ microparticles serve as effective platforms for electrochemical detection of amines in solution. The morphology and structure of the materials are characterized by X‐ray diffraction, scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and UV/Vis spectroscopy. The as‐synthesized SSZ microparticles comprise self‐assembled hexagonal prisms that possess nanometer and micrometer pores in their structure and on their surfaces—structural features that are conducive to sensing applications. An electrode fabricated by using the hierarchically nanostructured SSZ materials serve as a sensitive electrochemical sensor for detection of low concentrations of ethylenediamine, with a sensitivity of 2.98×10−2 mA cm−2 mm−1, a detection limit of 2.36×10−2 mm, and a short response time of 8 s.
Forging Unsupported Metal–Boryl Bonds with Icosahedral Carboranes
Authors: Saleh Liban M. A. , Dziedzic Rafal M. , Khan Saeed I. , Spokoyny Alexander M. 
Published: March 2016

AbstractIn contrast to the plethora of metal‐catalyzed cross‐coupling methods available for the installation of functional groups on aromatic hydrocarbons, a comparable variety of methods are currently not available for icosahedral carboranes, which are boron‐rich three‐dimensional aromatic analogues of aryl groups. Part of this is due to the limited understanding of the elementary steps for cross‐coupling involving carboranes. Here, we report our efforts in isolating metal‐boryl complexes to further our understanding of one of these elementary steps, oxidative addition. Structurally characterized examples of group 10 M−B bonds featuring icosahedral carboranes are completely unknown. Use of mercurocarboranes as a reagent to deliver M−B bonds saw divergent reactivity for platinum and palladium, with a Pt−B bond being isolated for the former, and a rare Pd−Hg bond being formed for the latter.
Cross‐Electrophile Coupling of Vinyl Halides with Alkyl Halides
Authors: Johnson Keywan A. , Biswas Soumik , Weix Daniel J. 
Published: March 2016

AbstractAn improved method for the reductive coupling of aryl and vinyl bromides with alkyl halides that gave high yields for a variety of substrates at room temperature with a low (2.5 to 0.5 mol %) catalyst loading is presented. Under the optimized conditions, difficult substrates, such as unhindered alkenyl bromides, can be coupled to give the desired olefins with minimal diene formation and good stereoretention. These improved conditions also worked well for aryl bromides. For example, a gram‐scale reaction was demonstrated with 0.5 mol % catalyst loading, whereas reactions at 10 mol % catalyst loading completed in as little as 20 minutes. Finally, a low‐cost single‐component pre‐catalyst, (bpy)NiI2 (bpy=2,2′‐bipyridine) that is both air‐ and moisture‐stable over a period of months was introduced.
Ammonium Aminodiboranate: A Long‐Sought Isomer of Diammoniate of Diborane and Ammonia Borane Dimer
Authors: Chen Weidong , Yu Haibo , Wu Guotao , He Teng , Li Zhao , Guo Zaiping , Liu Huakun , Huang Zhenguo , Chen Ping 
Published: March 2016

AbstractAmmonium aminodiboranate ([NH4][BH3NH2BH3]) is a long‐sought isomer of diammoniate of diborane ([NH3BH2NH3][BH4]) and ammonia borane (NH3BH3) dimer. Our results show that [NH4][BH3NH2BH3] is stable in tetrahydrofuran at −18 °C and decomposes rapidly to NH3BH2NH2BH3 and H2 at elevated temperatures. The decomposition pathway is dictated by the dihydrogen bonding between Hδ+ on NH4+ and Hδ− on BH3, as confirmed by theoretical calculations. This is in contrast to the interconversion between [NH3BH2NH3][BH4] and (NH3BH3)2, although all three have dihydrogen bonds and the same stoichiometry.
ChemInform Abstract: POLYMORPHISM OF TRITHALLIUM(I) SODIUM SULFITE
Authors: ODDON YVES , COFFY GEORGES , TRANQUARD AYMOND 
Published: March 2016

AbstractRöntgenographisch und durch DTA wird bei verschiedenen Drücken für die im Titel genannte Verbindung eine Enantiotropie und eine Monotropie nachgewiesen.
ChemInform Abstract: CATHODIC REACTION OF AN IRON DISULFIDE ELECTRODE IN POTASSIUM CHLORIDE‐LITHIUM CHLORIDE EUTECTIC ELECTROLYTE
Authors: ABE KATSUSHI , CHIKU TAKEWO 
Published: March 2016

AbstractIm Hinblick auf eine Anwendung in Sekundärbatterien wird versucht, die Entladungsreaktion von F e82 in einer eutektischen KCl‐LiCl‐Schmelze (400°C) durch Kombination des Polarisationsverhaltens mit Röntgenstrukturanalysen aufzuklären.
ChemInform Abstract: FORMATION AND PROPERTIES OF POROUS SILICON AND ITS APPLICATION
Authors: WATANABE Y. , ARITA Y. , YOKOYAMA T. , IGARASHI Y. 
Published: March 2016

AbstractSi‐Einkristalle werden durch Anodisierung in konzentrierter HF bei unterkritischen Stromdichten in poröse Si‐Filme umgewandelt.
ChemInform Abstract: ENTROPIES, ENERGIES, AND HEATS OF VAPORIZATION OF POLAR ORGANIC COMPOUNDS AND THE HILDEBRAND RULE
Authors: NATH JAGAN , YADAVA M. L. 
Published: March 2016

AbstractDie Werte werden für C6‐ Cls‐ n ‐ Alkylamine, C3‐ C13‐ Alkanone‐(2) und Methylbenzole auf der Basis von Dampfdruckdaten aus der Literatur ermittelt.
ChemInform Abstract: VINYL ACETATES FROM VINYL BROMIDES
Authors: KLUMPP G. W. , BOS H. , SCHAKEL M. , SCHMITZ R. F. , VRIELINK J. J. 
Published: March 2016

AbstractAus Cu(II)‐acetat wird nach verschiedenen Verfahren, z.B. mit Hydrazin‐hydrat, Cu(I)‐acetat hergestellt, das mit Vinylbromiden glatt zu den entsprechenden Vinyl‐acetaten reagiert.
ChemInform Abstract: CYCLOADDITION OF DIAZOMETHANE TO MONOSUBSTITUTED ACETYLENES. REACTION MECHANISM AND ORIENTATION
Authors: STEPHAN E. , VO‐QUANG L. , VO‐QUANG Y. 
Published: March 2016

AbstractDie Cycloaddition von Diazomethan (II) an die Alkohole (Ia) bzw. die Äther (Ib) führt zu den isomeren Pyrazolen (III) und (IV).
ChemInform Abstract: STEREOSELECTIVE FORMATION OF SOME THIETANE 1,1‐DIOXIDES VIA SULFENES BY THE REACTION OF DIAZO COMPOUNDS WITH SULFUR DIOXIDE
Authors: TANABE T. , SHINGAKI T. , NAGAI T. 
Published: March 2016

AbstractAus den Diazoverbindungen (I) und Schwefeldioxid erhält man‐unter Eliminierung von Stickstoff die Sulfene (II), die mit dem Enamin (III) die Thietan‐1,1‐dioxide (IV) geben.
ChemInform Abstract: EFFECTS OF CONCENTRATION OF AMINE AND OF MEDIUM IN PHOTOREDUCTION OF KETONES BY AMINES
Authors: PAROLA ABRAHAM H. , ROSE ANITA W. , COHEN, SAUL G. 
Published: March 2016

AbstractDie Photoreduktion von Benzophenon durch Cyclohexylamin in Benzol und tert.‐Butanol‐ und von 4‐Benzoylbenzoat durch Triäthylamin und Butyl‐(2)‐amin in wäßrigem Pyridin werden untersucht und die Quantenausbeuten und die Kinetik bestimmt.
ChemInform Abstract: FORMATION OF ANTHRONYLIDENE CARBENE AND REACTION SEQUENCES OF THE TWO SPIN MULTIPLICITY STATES IN HYDROCARBON MEDIA. I. PHOTOLYSIS OF DIAZOANTHRONE
Authors: CAUQUIS GEORGES , REVERDY GILBERT 
Published: March 2016

AbstractDie Photolyse der Titelverbindung (I) in den Lösungsmitteln (II) ergibt in jedem Fall das Bianthronyl (III) sowie die Anthrone (IV), die sich in den aromatischen Lösungsmitteln (IIa) zum Chinon (V) (Ausbeute 15%) bzw. zum Hydroperoxid (VI) autoxidieren.
ChemInform Abstract: REACTIVITY OF 1,2,5‐TRIENES TOWARDS PERACIDS. III. PRODUCTS RESULTING FROM THE EVOLUTION OF ALLENE OXIDE WITHOUT THE PARTICIPATION OF THE OLEFINIC SYSTEM
Authors: GRIMALDI JACQUES , MALACRIA MAX , BERTRAND MARCEL 
Published: March 2016

AbstractUnter den Produkten, die aus Trienen wie z.B. (I) und (IV) durch Oxidation mit p‐Nitro‐perbenzoesäure in Methylenchlorid ohne Beteiligung des Olefinsystems gebildet werden, sind die Lactone (II) bzw. (V) als Hauptprodukte zu nennen.
ChemInform Abstract: NEW ′GABRIEL′ SYNTHESES OF AMINES
Authors: HENDRICKSON J. B. , BERGERON R. , STERNBACH D. D. 
Published: March 2016

AbstractDas Prinzip der allgemeinen Gabriel‐Synthese von Aminen (a) partieller Schutz der N‐Funktion b) Alkylierung c) Abspaltung der Schutzgruppe) wird unter Einführung von 2 neuen Schutzgruppen zur Darstellung verschiedener Amine angewandt: l. Schutz der Amine (I) mit dem Reagenz (II), Alkylierung der Derivate (III) mit entsprechenden Halogeniden (IV) und Schutzgruppenabspaltung aus den Produkten (V) liefern z.B. sek. Amine (VI).
ChemInform Abstract: ALIPHATIC THIO KETONES. THEIR PROPERTIES
Authors: COUTURIER RENE , PAQUER DANIEL , VIBET ALAIN 
Published: March 2016

AbstractDialkylthioketone, wie (I), reagieren mit den Malonsäurederivaten (II) unter Kondensation zu Olefinen, wie (III), mit Aryl‐ bzw. Aroylchloriden, wie (IV), (in der Enolform) unter Substitution zu Sulfiden, wie (V), addieren (als Enole) die Ketene (VI) zu Thioestern, wie (VII), und CS2 bzw. COS zu Tri‐ bzw. Dithiokohlensäure‐monoestern,die zu den Diestern (VIII) methyliert werden.
ChemInform Abstract: ENTRY INTO THE CYCLOPROPENE SYSTEM VIA VINYLSILANES
Authors: CHAN T. H. , MASSUDA D. 
Published: March 2016

AbstractAus den Silyl‐olefinen (I) entstehen die geminalen Dihalogen‐Verbindungen (II), aus denen unter Eliminierung der Halogensilane (IV) die Cyclopropene (III) erhalten werden.
ChemInform Abstract: BASE‐PROMOTED REARRANGEMENT OF CAGE α‐HALO KETONES. II. 12‐OXA‐3,5,9,10‐TETRACHLOROHEXACYCLO(5.4.1.02,6.03,10.05,9.08,11)DODECANE‐4‐ONE
Authors: MARCHAND A. P. , CHOU TEH‐CHANG 
Published: March 2016

AbstractDie Titelverbindung (V) wird durch Reduktion des Pentacycloundecandions (I) zum Diol (II) [Nebenprodukt (III)], nachfolgender Cyclisierung zum Oxahexacyclododecan (IV) und anschließender Behandlung mit Schwefelsäure dargestellt.
ChemInform Abstract: FACILE FORMATION OF TRICYCLO(4.4.1.03,8)UNDECANE RING SYSTEM FROM 2,4‐DEHYDROHOMOADAMANTANE
Authors: YAMAGUCHI R. , KAWANISI M. 
Published: March 2016

Abstract2,4‐Dehydro‐homoadamantan (I) reagiert mit Brom oder Jod in Gegenwart von Silberacetat zu den beiden Spaltprodukten (IIa) und (IIIä) neben einem noch nicht identifizierten Diacetat.