bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis of 2,2‐Dimethyl‐3,4‐chromandiones: Condensation with o‐Diaminopyridines.
Authors: VINOT N. , MAITTE P. 
Published: May 2016

AbstractThe condensation of the title diones, e.g. (II), with the pyridines (III) and (VI) leads to mixtures of isomers.
ChemInform Abstract: Synthesis and Evaluation of the Analgesic and Antiinflammatory Activities of N‐Substituted Salicylamides.
Authors: DAIDONE G. , RAFFA D. , PLESCIA S. , MATERA M. , CARUSO A. , LEONE V. , AMICO‐ROXAS M. 
Published: May 2016

AbstractCoupling of phenyl salicylate (I) with the (het)aromatic amines (II) yields the salicylamides (III).
ChemInform Abstract: New Pyridazino(3,4‐b)azocines by Intramolecular (4 + 2)Cycloaddition with Reversed Electron Demand.
Authors: SEITZ G. , RICHTER J. 
Published: May 2016

AbstractThe (alkynylamino)(methylthio)tetrazine (IIIa), prepared from 3,6‐bis‐(methylthio)‐1,2,4,5‐tetrazine (I), is oxidized to produce the sulfoxide (IIIb) and the sulfone (IIIc).
ChemInform Abstract: Organic Phosphorus Compounds. Part 3. Synthesis of 5‐Fluorosubstituted Benzothiazolylbenzylphosphonates.
Authors: YOSHINO K. , HORI N. , HORI M. , MORITA T. , TSUKAMOTO G. 
Published: May 2016

AbstractThe title compounds (VII) are synthesized as demonstrated for the example (VIIa).
ChemInform Abstract: Studies on the Synthesis of Phosphorus Heterocycles. Part 1. (1,4,3)Thiazaphosphorino(3,4‐b)(1,3,2)benzodiazaphosphorine 12‐Oxides.
Authors: CHEN R. , BAO R. 
Published: May 2016

AbstractThe isatoic anhydrides (I) are converted to the oxazolines (III) which react with phosphorus trichloride (IV), forming the benzodiazaphosphorines (VI) after basic hydrolysis.
ChemInform Abstract: Regio‐ and Stereoselective Preparation of Enolates from Ketones by Means of Sodium Bis(trimethylsilyl)amide.
Authors: DAUDEMAR M. , BELLASSOUED M. 
Published: May 2016

AbstractThe benzylic ketones (I) or (X) are subjected to enolization with the metal amides (II) or (VI) under kinetically or thermodynamically controlled conditions.
ChemInform Abstract: Reactivity of Neodymium(III) Isopropoxide Derivatives: Synthesis, Characterization and Crystal Structure of (Nd4(μ3‐OH)2(μ2,μ1‐acac)6(acac)4).
Authors: PONCELET O. , HUBERT‐PFALZGRAF L. G. 
Published: May 2016

AbstractThe reaction between Nd chips and iPrOH (I) leads to the tetramer (III).
ChemInform Abstract: Copper(II) Promoted Desulfurization of N‐Phenylthiourea. The Synthesis and X‐Ray Structure of ((Cu(bipy)(pc)2)2) (bipy: 2,2′‐Bipyridine, pc: Phenylcyanamide).
Authors: BRADER M. L. , AINSCOUGH E. W. , BAKER E. N. , BRODIE A. M. 
Published: May 2016

AbstractThe title complex (IV) (yield in g) crystallizes in P21/c with Z=2.
ChemInform Abstract: Intramolecular Energy Transfer in a Chromophore‐Quencher Complex.
Authors: BOYDE S. , STROUSE G. F. , JONES W. E. JUN. , MEYER T. J. 
Published: May 2016

AbstractMLCT excitation of the complex (Ib) is followed by an intramolecular energy transfer to one of the chemically attached anthryl groups to give an anthryl triplet with a lifetime of 6 μs in MeCN at 295 K. Oxidative quenching occurs at this triplet and is followed by rapid intramolecular electron transfer to give the Ru(III) complex.
ChemInform Abstract: A New Synthetic Route to (.+‐.)‐Forskolin.
Authors: BEGLEY M. J. , CHESHIRE D. R. , HARRISON T. , HUTCHINSON J. H. , MYERS P. L. , PATTENDEN G. 
Published: May 2016

AbstractThe key intermediate (VIII) is prepared from the mixture (IV) via a novel stereoselective intramolecular radical‐mediated cyclization reaction (using Co(I) generated electrochemically from vitamin B12, bis(trimethylstannyl)benzopinacolate or hexaphenylditin) in tandem with an intramolecular Mukaiyama aldolization.
ChemInform Abstract: Free‐Radical Addition to Di‐ and Tripeptides Containing Dehydroalanine Residues.
Authors: CRICH D. , DAVIES J. W. 
Published: May 2016

AbstractA variety of di‐ and tripeptides such as (I) containing the dehydroalanine unity ‐ available by DABCO treatment of the corresponding chloroalanines ‐ is subjected to the alkylmercury halide/NaBH4 method to give the saturated peptides (III) with good chemical yield, but low diastereoselectivity.
ChemInform Abstract: New Efficient Syntheses of 3,3,3‐Trifluoroalanine, 2‐Deutero‐3,3,3‐trifluoroalanine, and Their N‐Protected Derivatives.
Authors: BURGER K. , HOESS E. + , GAA K. 
Published: May 2016

AbstractAddition of the amides or urethanes (II) to the α‐keto ester (I) yields the adducts (III) which are converted to the acylimines (IV) by treatment with trifluoroacetic acid anhydride in pyridine.
ChemInform Abstract: The Chemistry of D‐Gluconic Acid. Part 3. Convenient Syntheses of 1,2‐Anhydro‐3,4:5,6‐di‐O‐isopropylidene‐D‐glucitol and ‐D‐mannitol.
Authors: REGELING H. , CHITTENDEN G. J. F. 
Published: May 2016

AbstractTreatment of the 3,4:5,6‐di‐O‐isopropylidene‐D‐glucitol (I) with tosyl chloride (II) produces the corresponding tosylate (III) which is converted into 1,2‐anhydro‐3,4:5,6‐di‐O‐isopropylidene‐D‐glucitol (IV) by reaction with sodium methoxide.
ChemInform Abstract: A Novel Method for the Synthesis of Anomerically Allylated C‐Glycofuranosides. An Unusual Lewis Acid‐Catalyzed Rearrangement of an Oxetanosyl‐N‐glycoside to Furanosyl‐C‐glycosides.
Authors: KATO K. , MINAMI T. , TAKITA T. , NISHIYAMA S. , OHGIYA T. , YAMAMURA S. 
Published: May 2016

AbstractThe reaction of the protected oxetanocin (I) with allyltrimethylsilane (II) in the presence of Lewis acids yields the C‐allyl furanosides (III).
ChemInform Abstract: Synthesis and Antitumor Activity of New Alkylphospholipids Containing Modifications of the Phosphocholine Moiety.
Authors: UKAWA K. , IMAMIYA E. , YAMAMOTO H. , MIZUNO K. , TASAKA A. , TERASHITA Z. , OKUTANI T. , NOMURA H. , KASUKABE T. , HOZUMI M. , KUDO I. , INOUE K. 
Published: May 2016

AbstractThe hydroxyalkylammonium tosylates (III) are prepared either by quaternization of the ω‐dimethylamino alcohols (I) with methyl tosylate (II) or by reaction of the diol monotosylates (VI) with trimethylamine (VII).
ChemInform Abstract: Silicon Polytungstate (SiW12O40)4‐‐Derivatized Titanium Dioxide (TiO2)/Electrolyte Interfaces
Authors: WU W.‐T. , MCEVOY A. J. 
Published: May 2016

Abstractare studied in order to test the validity of previously published data that indicate that a prolonged cathodic polarization of a (SiW12O40)4‐‐modified TiO2 surface induces a permanent anodic displacement of the flatband potential of the semiconductor.
ChemInform Abstract: Crystal Growth and Physical Properties of Two Compounds of the Series SnS2‐xSex: SnS2 and SnSSe.
Authors: KATTY A. , FOTOUHI B. , LE NAGARD N. 
Published: May 2016

AbstractSingle crystals of a phosphorus doped SnS2 (< 5% P) and SnSSe are grown by CVD and Bridgman techniques.
ChemInform Abstract: Polycrystalline Boron Phosphide Semiconductor Electrodes.
Authors: GOOSSENS A. , KELDER E. M. , SCHOONMAN J. 
Published: May 2016

AbstractPolycrystalline BP films can be deposited onto Al2O3 substrates by conventional thermally activated CVD at 940 °C in a H2 environment using BBr3 and PBr3 as reactants.
ChemInform Abstract: Electroless Growth of Aluminum Dendrites in NaCl‐AlCl3 Melts.
Authors: LI Q. , HJULER H. A. , BERG R. W. , BJERRUM N. J. 
Published: May 2016

AbstractThe spontaneous growth of aluminum dendrites after aluminum electrodeposition is observed in NaCl‐AlCl3 melts.
ChemInform Abstract: Cyclic Voltammetry Studies of the Lithiumthioborate Glass‐Indium Interface.
Authors: RUDOLPH B. , BURCKHARDT W. , STAIKOV G. 
Published: May 2016

AbstractLithium conducting glasses of general composition xMm+Sm/2‐y Li2S‐(1‐x‐y) LiI (M: B, Ge, Si, P, As, Sb) are of importance as solid electrolytes in "all‐solid‐state" batteries.
ChemInform Abstract: Copper Photodeposition on TiO2 Studied with HREM and EXAFS.
Authors: JACOBS J. W. M. , KAMPERS F. W. H. , RIKKEN J. M. G. , BULLE‐LIEUWMA C. W. T. , KONINGSBERGER D. C. 
Published: May 2016

AbstractThe possibility of direct selective surface activation of photosensitive TiO2 substrates by photodeposition of autocatalytic Cu particles from an alkaline electroless copper bath (CuSO4/NaOH/KNaC4H4O6, HCHO) is studied.
ChemInform Abstract: IR Spectroscopy Study of Carbon Monoxide Adsorption on α‐Chromia Surfaces: Probing Oxidation States of Coordinatively Unsaturated Surface Cations.
Authors: ZAKI M. I. , KNOEZINGER H. + 
Published: May 2016

AbstractIt is demonstrated that coordinatively unsaturated (cus) Cr3+ cationic sites, most probably in 3‐coordinated and to a much less extent 5‐coordinated states, are the CO adsorption sites on H2‐reduced Cr2O3.
ChemInform Abstract: Solution Properties and Reactivity of the Aqua Ion of the MoIV 3 Incomplete Cuboidal Mo/S Cluster (Mo3S4(H2O)9)4+.
Authors: OOI B.‐L. , SYKES A. G. 
Published: May 2016

AbstractThe title ion (II), prepared as shown in the scheme, is stable in acidic solutions of pH < 1 and, unlike the μ‐oxo analogue (Mo3O4(H2O)9)4+, does not react with O2 and ClO4‐.
ChemInform Abstract: Gas‐Phase Reactions. Part 76. Generation and Ionization Pattern of the Iso(valent)electronic Compounds ClP(=O)2 and ClP(=S)2.
Authors: MEISEL M. , BOCK H. , SOLOUKI B. , KREMER M. 
Published: May 2016

AbstractThe title compounds (V) may be regarded as a missing link in the series of planar 24‐electron compounds such as Cl3B, ClNO2 and SO3.
ChemInform Abstract: X‐Ray Structure Analysis of α‐Lithiophenylacetonitrile‐Lithium Diisopropylamide·2 Tetramethylethylenediamine ‐ A “Quasi‐Dianion Complex”.
Authors: ZARGES W. , MARSCH M. , HARMS K. , BOCHE G. 
Published: May 2016

AbstractThe structure analysis of the title complex (I) (space group P1, Z=2) is the first structural characterization of an adduct formed between a monoanion and a base, in this case formed by reaction of phenylacetonitrile and two equiv. LDA.
ChemInform Abstract: Asymmetric Synthesis. Part 7. Double Stereodifferentiation in Allylation of Ketimines Bearing Two Chiral Auxiliaries. Application to Enantioselective Synthesis of α‐Allylglycine.
Authors: JIANG Y. , ZHOU CH. , PIAO H. 
Published: May 2016

AbstractCondensation reaction of the ketones (I) with the glycinates (II) yields the ketimines (III) which bear at least one asymmetric carbon atom.
ChemInform Abstract: The Structure of a 2‐Oxoperhydro‐1,3,5‐triazine (IV), the Cycloaddition Product of Diphenyl‐N‐(p‐tolyl)ketenimine and Chlorosulfonyl Isocyanate.
Authors: ROEMMING C. , SKATTEBOEL L. 
Published: May 2016

AbstractAs reported (1973), cycloaddition of (II) + (III) gives an unstable product from which the chlorosulfonyl group is reductively removed.
ChemInform Abstract: Stereoselective Preparation of Bicyclo(3.3.0)octanones from the Products of Aprotic Conjugate Addition of Lithiated Allylic Sulfoxides to Cyclopent‐2‐enone and Enolate Trapping with Methyl Cyanoformate.
Authors: HAYNES R. K. , KATSIFIS A. G. 
Published: May 2016

AbstractThe products (IV) and (VII) of the title reaction are transformed to the target compounds (V) and (VIII) by cyclization of the corresponding sulfides in the presence of SnCl4.
ChemInform Abstract: Valence Isomers of 10π C11H10 Hydrocarbons. Bisnorcaradiene: Intermediacy and Trapping.
Authors: DUERR H. + , PAULY K.‐H. , SCHEIDHAUER P. , FISCHER K. 
Published: May 2016

AbstractThe photoreaction of the spironorcaradienes (I) leads to the products (V)‐(VII) via the intermediates (II), (IV) and the valence isomers (III).
ChemInform Abstract: Gas‐Phase Base‐Induced Elimination Reactions in Onium Intermediates. Part 2. Stereochemistry and Orientation in Alkene Formation from Gaseous Halonium Ions.
Authors: ANGELINI G. , LILLA G. , SPERANZA M. 
Published: May 2016

AbstractThe 1‐butene (V) is formed via (II) through a transition state with an anti configuration.
ChemInform Abstract: Cobalt(II) Chloride‐Catalyzed Addition of Alcohols to Vinyl Ethers: A Convenient Synthesis of Mixed Acetals.
Authors: IQBAL J. , SRIVASTAVA R. R. , GUPTA K. B. , KHAN M. A. 
Published: May 2016

AbstractThe vinyl ethers (II), (VI), or (VIII) are treated with the alcohols (I) in the presence of cobalt dichloride to produce the mixed acetals (III), (VII), or (IX).
ChemInform Abstract: Synthesis of cis‐ and trans‐1‐Methylcyclohexane‐1,4‐diols and Their 4‐Hemisuccinate Esters.
Authors: BUSHWELLER J. H. , ANZALONE L. , SPENCER T. A. 
Published: May 2016

AbstractThe monoprotected diketone (I) is subjected to Grignard reaction with methylmagnesium iodide (II), producing an equilibrating mixture of the conformers of the alcohol (III).
ChemInform Abstract: New Synthesis from β‐Pinene of Tetracyclo(6.2.1.01,6.06,10)undecanes, an Unusual Ring System.
Authors: THOMAS A. F. , REY F. 
Published: May 2016

AbstractReaction of β‐pinene (I) with acryloyl chloride (II) produces the tricyclic ketones (III) and (IV).
ChemInform Abstract: Bicyclo(3.3.1)nonanes as Synthetic Intermediates. Part 15. Ring Enlargement of Bicyclo(3.3.1)nonane‐2,6‐dione and Bicyclo(3.3.1)nonan‐2‐one. Revision of the Literature.
Authors: MOMOSE T. , MURAOKA O. , MASUDA K. 
Published: May 2016

AbstractThe main product of the reaction of the bicyclononanedione (I) with diazomethane (II) is shown to be the isotwistane (III) and not the tricyclodecane (VI) as previously published.
ChemInform Abstract: Reaction of Olefins with Sulfuryl Chloride and Cyclic Ethers: An Efficient Synthesis of α‐Chloroalkyl ω‐Chloroalkyl Ethers.
Authors: JOSEPH S. P. , KESHAVAMURTHY K. S. , DHAR D. N. 
Published: May 2016

AbstractThe alkenes (I) are treated with the cyclic ethers (II), (IV), or (VII) and sulfuryl chloride to produce the α‐chloroalkyl ω‐chloroalkyl ethers (III), (V), or (VIII).
ChemInform Abstract: The Synthesis and Chemistry of Azolenines. Part 14. The Combination of 3H‐ and 2H‐Pyrroles with N‐Phenylmaleimide: Diels‐Alder Reactions and Michael Additions.
Authors: LUI K.‐H. , LAI T.‐F. , SAMMES M. P. 
Published: May 2016

AbstractThe 3H‐pyrroles (I) react with N‐phenylmaleimide (II) in benzene, at room temp. or under reflux, to give the endo Diels‐Alder adducts (III); the adducts (IV) are similarly obtained.
ChemInform Abstract: Ethylene Analogues of Tetrathiafulvalene and Tetraselenafulvalene: New Donors for Organic Metals.
Authors: SUGIMOTO T. , AWAJI H. , SUGIMOTO I. , MISAKI Y. , KAWASE T. , YONEDA S. , YOSHIDA Z. , KOBAYASHI T. , ANZAI H. 
Published: May 2016

AbstractThe ethylene analogues (I) and (II) as well as a wide range of substituted derivatives are synthesized (1H, 13C NMR, electronic spectra, redox behavior, PPP‐SCF‐CI calculations).
ChemInform Abstract: Synthesis of 1H‐Pyrrolo(1,2‐c)imidazoles.
Authors: MUSICKI B. , MALLEY M. F. , GOUGOUTAS J. Z. 
Published: May 2016

AbstractReaction of the formylpyrroles (I) with ammonium acetate (II) results in the formation of the pyrroloimidazoles (III).
ChemInform Abstract: Antibacterials. Synthesis and Structure‐Activity Studies of 3‐Aryl‐2‐oxooxazolidines. Part 1. The “B” Group.
Authors: GREGORY W. A. , BRITTELLI D. R. , WANG C.‐L. J. , WUONOLA M. A. , MCRIPLEY R. J. , EUSTICE D. C. , EBERLY V. S. , BARTHOLOMEW P. T. , SLEE A. M. , FORBES M. 
Published: May 2016

AbstractReaction of the phenyl isocyanates (I) with the epoxides (II) yields the oxazolidinones (III).
ChemInform Abstract: Ring Transformations of Semicyclic 1,3‐Diarbonyl Heteroanalogs. Part 1. Synthesis of Semicyclic N‐Acyl‐ and N‐(Aminocarbonyl)amidine Derivatives and Their Ring Transformation to 5‐(ω‐Aminoalkyl)‐1,2,4‐triazoles.
Authors: LIEBSCHER J. , PAETZEL M. + , KELBORO Y. F. 
Published: May 2016

AbstractThe lactames (I) are converted to the N‐(thio)acyl amidines (III) and (IV) which are further transformed into triazoles such as (VII) and (XI) via methyl thioimidates, e.g. (IX), or chloroimidates.
ChemInform Abstract: Cycloaddition of Benzonitrile Oxide to Heterocyclic β‐Enaminonitriles.
Authors: CORSARO A. , PERRINI G. , PUGLISI G. , PURRELLO G. 
Published: May 2016

AbstractThe heterocyclic enaminonitriles (I) and (IV) add benzonitrile oxide (II) (generated in situ from benzhydroximic acid) exclusively at their C≡N triple bond to give oxadiazole derivatives (III) or (V).
ChemInform Abstract: Synthesis of 2,3‐Dideoxy‐4‐O‐(p‐methoxybenzyl)‐L‐erythro‐hex‐2‐enono‐1,5‐lactone.
Authors: MARCO J. L. , RODRIGUEZ B. 
Published: May 2016

AbstractThe chiral amide (I) is converted to the α‐keto O,S‐acetal (III) and then reduced, yielding the α‐hydroxy acetals (IVa) and (Va).
ChemInform Abstract: Preparation of Some Chromans Substituted at the 3‐ or 4‐Position by an Aryl or Benzyl Group, by the Rhodium‐Catalyzed Intramolecular Nucleophilic Substitution of the Corresponding 3‐(2‐Fluorophenyl)propan‐1‐ols.
Authors: HOUGHTON R. P. , SHERVINGTON L. A. 
Published: May 2016

AbstractThe Rh(III) complex catalyzed cyclization reaction of o‐fluorophenylpropanols such as (I) gives rise to chroman derivatives such as (II).
ChemInform Abstract: Studies on Synthesis and Stereochemistry of 3‐Methyloctahydroisocoumarins and 1‐Methyloctahydro‐3H‐2‐benzopyran‐3‐ones.
Authors: FUJIWARA Y. , OKAMOTO M. 
Published: May 2016

AbstractThe four diastereomeric lactones (V), (VI), (VIII), and (IX) and the two diastereomeric lactones (XIII) and (XIV) are prepared as outlined in the reaction scheme.
ChemInform Abstract: Alkylation and Acylation of 2‐Hydroxy‐9(10H)‐acridinone and 2‐Hydroxy‐9(10H)‐thioacridinone.
Authors: DHIF D. , GALY J.‐P. , VINCENT E.‐J. , BARBE J. 
Published: May 2016

AbstractThe thallous salt of the hydroxyacridinone (I) is coupled with the dicarboxylic dichlorides (II) to give the esters (III) or (IV).
ChemInform Abstract: Stereochemical Studies on 7‐ and 9‐Substituted 3‐Azabicyclo(3.3.1)nonanes (3‐ABNs).
Authors: JEYARAMAN R. , MANOHARAN M. 
Published: May 2016

AbstractCyclohexanone (I) reacts with ammonium acetate (II) and benzaldehyde (III) to give the azabicyclononanone (IV) and dibenzylidenecyclohexanone (V).
ChemInform Abstract: Synthesis of New 5‐Nitrotetrahydro‐1,3‐oxazine Derivatives via Electron‐Transfer Reactions.
Authors: CROZET M. P. , VANELLE P. 
Published: May 2016

AbstractA useful approach to tetrahydro‐1,3‐oxazines with a substituted double bond, e.g. (III), (VI), (X) is demonstrated.
ChemInform Abstract: Fifty‐Two Membered Macromonocyclic Polyamine Possessing Twelve Nitrogen Atoms in the Ring: Cyclic Spermine Tetramer.
Authors: IWATA M. , KUZUHARA H. 
Published: May 2016

AbstractChain elongation of the α,ω‐bis(tosylamines) (I) and analogues is achieved by coupling with the phthalimido‐substituted electrophiles (II), followed by reduction, deprotection, and tosylation.
ChemInform Abstract: Kinetically Stable Complexes of Alkali Cations with Rigidified Calix(4)arenes: Synthesis, X‐Ray Structures, and Complexation of Calixcrowns and Calixspherands.
Authors: DIJKSTRA P. J. , BRUNINK J. A. J. , BUGGE K.‐E. , REINHOUDT D. N. , HARKEMA S. , UNGARO R. , UGOZZOLI F. , GHIDINI E. 
Published: May 2016

AbstractSome members of the title compounds such as the calixcrown (Ia) or the calixspherand (Ib) are prepared by common methods and the kinetic and thermodynamic stabilities of their alkali cation complexes are measured.
ChemInform Abstract: An Unexpected Synthesis of the 1,4‐Dithiepinofuran‐2‐one System.
Authors: FETIZON M. , GOULAOUIC P. , HANNA I. , PRANGE T. 
Published: May 2016

AbstractThe cyclohexyl‐substituted dithiepin‐fused furanone (IV) is obtained by base‐mediated rearrangement of the cyclohexanoyl(methoxycarbonylmethyl)dithiane (III).
ChemInform Abstract: Polymer‐Supported Bases. Part 10. Synthesis of Phosphatidylcholines Using Polymer‐Supported or Free Acylimidazoles.
Authors: TOMOI M. , INOMATA K. , KAKIUCHI H. , TOKUYAMA S. 
Published: May 2016

AbstractL‐α‐Glycerophosphorylcholine (I) is treated with the palmitoylimidazoles (II) in the presence of DBU to form the dipalmitoylphosphatidylcholine (III).
ChemInform Abstract: Facile Synthesis of 2‐(5‐Isopropyl‐5‐methyl‐4‐oxo‐2‐imidazolin‐2‐yl)phenyl Phosphonates.
Authors: TAKENAKA H. , HAYASE Y. 
Published: May 2016

AbstractCyclocondensation of benzoyl chloride (I) with the aminodimethylbutanamide (II) yields the imidazolinone (III) which is coupled with diethyl chlorophosphate (IV) to give the phosphonate (V).
ChemInform Abstract: Organocerium(III) Reagent from Pyrimidine in Carbon Bond‐Forming Reactions.
Authors: ZHENG J. , UNDHEIM K. 
Published: May 2016

AbstractThe reactions shown in the scheme confirm that the organo‐Ce(III) chloride (III) exhibits a high specificity for 1,2 addition to α,β‐unsaturated CO derivatives such as (IV).
ChemInform Abstract: Two Novel Polyoxomolybdates Containing the (MoNO)3+ Unit: (Mo5Na(NO)O13(OCH3)4)2‐ and (Mo6(NO)O18)3‐.
Authors: GOUZERH P. , JEANNIN Y. , PROUST A. , ROBERT F. 
Published: May 2016

AbstractThe first polyoxomolybdates with an Mo(II)NO group instead of an Mo(IV)O group, the title compounds (IV) and (V) (for both space group P21/a, Z=4) are prepared by reductive nitrosylation of complex (I) with hydroxylamine in methanol and transformation of (IV) into (V) on dissolution.
ChemInform Abstract: Fluoride‐Assisted Stabilization of Manganese(III) in Aqueous Medium. A General Approach to the Synthesis of Mixed‐Ligand Fluoro Complexes of Manganese(III).
Authors: BHATTACHARJEE M. N. , CHAUDHURI M. K. , PURKAYASTHA R. N. D. 
Published: May 2016

AbstractSynthesis and characterization of a number of the Mn(III) title complexes are reported.
ChemInform Abstract: Heterobimetallic Au‐Pt Phosphine Complexes. X‐Ray Crystal and Molecular Structures of ((PPh3)Pt(AuPPh3)6)(NO3)2 and ((PPh3)(CO)Pt(AuPPh3)6)(PF6)2.
Authors: ITO L. N. , SWEET J. D. , MUETING A. M. , PIGNOLET L. H. , SCHOONDERGANG M. F. J. , STEGGERDA J. J. 
Published: May 2016

AbstractThe seven‐nuclear title cluster (IIa) (space group P1, Z=2) is obtained from the trinuclear complex (I) as shown.
ChemInform Abstract: Asymmetric Reductive Amination of Cycloalkanones. Part 9. Asymmetric Synthesis of GABA‐Related Cycloaliphatic Amino Acids.
Authors: OMAR F. , FRAHM A. W. 
Published: May 2016

AbstractThe cyclic ketones (I) react with the chiral auxiliary amine (II) to form the imines (III) which are hydrogenated in the presence of Raney nickel, yielding the amines (IV).
ChemInform Abstract: The Chemistry of O‐Silylated Ketene Acetals: Synthesis of N‐Benzoyl‐L‐daunosamine.
Authors: KITA Y. , ITOH F. , TAMURA O. , KE Y. Y. , MIKI T. , TAMURA Y. 
Published: May 2016

AbstractThe key steps in the synthesis of the daunosamine (X) are the stereoselective 1,3‐addition of the ketene silyl acetal (V) to the nitrones (IV) and subsequent transsilylation, yielding the siloxyamines (VI) and (VII).
ChemInform Abstract: Tris‐N,N′,N′′‐(3′,4′,5′‐trimethoxyphenethyl)‐1,3,5‐hexahydrotriazine, a Methylenemescaline Trimer: Characterization and Selective Cyclization to Anhalinine Under Non‐Aqueous Conditions.
Authors: CHRISEY L. A. , BROSSI A. 
Published: May 2016

AbstractCyclocondensation of mescaline (I) with aqueous formaldehyde (II) gives the 1,3,5‐hexahydrotriazine (III) which undergoes ring cleavage and recyclization upon treatment with hydrochlorid acid, producing a mixture of mescaline (I) and anhalinine hydrochloride (IV).
ChemInform Abstract: Crystallographic and Magnetic Structure of Ternary Carbides of the Type Nd2Fe17Cx.
Authors: HELMHOLDT R. B. , BUSCHOW K. H. J. 
Published: May 2016

AbstractA polycrystalline sample of Nd2Fe17C0.5 is investigated by neutron diffraction at 300 and 4.2 K. The structure of this carbide is closely related to that of the parent compound Nd2Fe17 (Th2Zn17‐type, space group R3m), with the C atoms located at the empty 9(e) sites.
ChemInform Abstract: The Luminescence of Some Tin‐Activated Alkaline‐Earth Orthophosphates
Authors: DONKER H. , SMIT W. M. A. , BLASSE G. 
Published: May 2016

Abstract(β‐Ca3(PO4)2, α‐Sr3(PO4)2, α‐Ba3(PO4)2, Ba2.85Mg0.15(PO4)2, and M2.55Mg0.45(PO4)2 with M: Ca, Sr) is studied down to 4.2 K. The luminescence of the tin‐activated orthophosphates is explained by assuming the presence of two different Sn2+ centers in the lattices.
ChemInform Abstract: Positive Voltage Shift in C‐V Curves by a Combination Oxide of Dry SiO2 and Sputtered SiO2.
Authors: BHAN R. K. , CHAUDHURY P. K. , BASU P. K. , CHHABRA K. C. 
Published: May 2016

Abstract"Combination oxides" consisting of thermally grown dry SiO2 and sputter deposited SiO2 are grown on p‐ and n‐type silicon.