bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Electroorganic Chemistry. Part 116. Electrochemical Transformation of Aldoximes to Nitriles Using Halogen Ions as Mediators: Intermediary Formation of Nitrile Oxides.
Authors: SHONO T. , MATSUMURA Y. , TSUBATA K. , KAMADA T. , KISHI K. 
Published: May 2016

AbstractThe aldoximes (I) are electrochemically transformed into the nitriles (III) via the nitrile oxides (II) by passing electricity (2.5 to 5 F/mol) through a methanolic solution of (I) containing sodium chloride in an undivided cell.
ChemInform Abstract: Functionalized Chloroenamines in Aminocyclopropane Synthesis. Part 3. Synthesis and Assignment of Configuration of Two Isomeric Morpholinobicyclo(3.1.0)hexane Derivatives.
Authors: VILSMAIER E. , ADAM R. , TETZLAFF C. , CRONAUER R. 
Published: May 2016

AbstractPrevious studies concerning the utility of a morpholino substituent as a 1H NMR stereoindicator for the exo/endo position in bicyclic compounds are now extended to systems of type (V) and (VIII) possessing a bridgehead substituent.
ChemInform Abstract: Investigations on the Formation of 6‐Hydroxyindole in the Nenitzescu Reaction. Part 2. Cyclization of N‐(Quinonylalkyl)enaminone Derivatives.
Authors: KUCKLAENDER U. + , ULMER P. , ZERTA G. 
Published: May 2016

AbstractA previous report concerning the formation of 6‐hydroxyindoles in the Nenitzescu reaction suggested that this (intermolecular) transformation may proceed via primary 1,4‐addition of the enaminone nitrogen to p‐benzoquinone.
ChemInform Abstract: Observation of Novel Photochemistry in the Multiphoton Ionization of Mo(CO)6 van der Waals Clusters.
Authors: PEIFER W. R. , GARVEY J. F. 
Published: May 2016

AbstractStudies of 248 nm multiphoton ionization dynamics of Mo(CO)6 van der Waals clusters, generated in pulsed supersonic molecular beams, furnish evidence for a striking photochemical behavior, heretofore unobserved in the multiphoton ionization of transition‐metal carbonyls.
ChemInform Abstract: Benzylidenisophorone Dimer and Its Photoproduct.
Authors: FIELDS E. K. , DUNLAP R. W. , BRUCK M. , PODIAS A. , HALL H. K. JUN. 
Published: May 2016

AbstractIrradiation of benzylidenisophorone dimer leads to the formation of the photoproduct (II) which is derived from (I) by intramolecular (2 + 2)cycloaddition.
ChemInform Abstract: Palladium‐Catalyzed Intermolecular Vinylation of Cyclic Alkenes.
Authors: LAROCK R. C. , GONG W. H. 
Published: May 2016

AbstractIntermolecular cross‐coupling of the vinylic compounds (I), (IV), (IX), and (XI) with the cyclic alkenes (II), (V), and (VII) in the presence of catalytic amounts of palladium acetate leads to the formation of the 1,4‐dienes shown in the reaction scheme.
ChemInform Abstract: Chlorination of Bicyclo(1.1.1)pentane Derivatives.
Authors: ROBINSON R. E. , MICHL J. 
Published: May 2016

AbstractPhotochemical chlorination of the bridgehead‐substituted bicyclo‐(1.1.1)pentanes (I), (V), and (VI) with chlorine produces the 2,2‐dichloro derivatives (II) and (VII).
ChemInform Abstract: Synthesis of Chiral 12‐Phenyl(2H)dodecanoic Acids: Useful Metabolic Probes for the Biosynthesis of 1‐Alkenes from Fatty Acids.
Authors: GOERGEN G. + , BOLAND W. , PREISS U. , SIMON H. 
Published: May 2016

AbstractThe synthesis of the optically active deuterated phenyldodecanoic acids (VII) and (VIII) is described.
ChemInform Abstract: A Novel Synthesis of Isothiocyanates from Ammonium Dithiocarbamates Using Triphenylphosphine‐Carbon Tetrachloride.
Authors: FURUKAWA I. , ABE N. , HASHIMOTO S. 
Published: May 2016

AbstractThe isothiocyanates (III) are obtained from the amines (I) by consecutive treatment with carbon disulfide (II) and triphenylphosphine/tetrachloromethane.
ChemInform Abstract: Asymmetric Alkylation of β‐Keto Esters with Optically Active Sulfonium Salts.
Authors: UMEMURA K. , MATSUYAMA H. , WATANABE N. , KOBAYASHI M. , KAMIGATA N. 
Published: May 2016

AbstractThe cyclic β‐keto esters (I) and (V) undergo asymmetric alkylation with optically active sulfonium salts such as (II).
ChemInform Abstract: Fries Rearrangement of 9‐(Acyloxy)anthracene.
Authors: TAMANO M. , NAKABAYASHI M. , KOKETSU J. 
Published: May 2016

AbstractReaction of anthrone (I) with acetyl chloride (II) yields the acetyloxyanthracene (III) which is rearranged in the presence of several Lewis acid catalysts, producing 10‐acetylanthrone (IV) and the starting material (I).
ChemInform Abstract: Substituent Effects on the Regio‐ and Stereoselectivity of Gas‐Phase Acid‐Induced Ring Opening in 1‐Arylcyclohexene Oxides.
Authors: CECCHI P. , PIZZABIOCCA A. , RENZI G. , CHINI M. , CROTTI P. , MACCHIA F. , SPERANZA M. 
Published: May 2016

AbstractWith regard to the more complex arene oxides as intermediates in the carcinogenesis, the ring‐opening of the simpler models (I) is studied (for (I) with Ar: ‐Ph already published).
ChemInform Abstract: Synthesis and Reactivity of β‐Lactones Derived from L‐Threonine and Related Amino Acids.
Authors: PANSARE S. V. , VEDERAS J. C. 
Published: May 2016

AbstractThe threonine derivatives (Ia) and (Ib) undergo Mitsunobu reaction to give stereoselectively the anti‐elimination products (II).
ChemInform Abstract: Nitration of 2‐Carbonyl‐3,4‐dichlorofuran Derivatives.
Authors: YAMAMOTO K. , KOYANAGI J. , TANAKA A. , HORIE I. , ICHIKAWA M. , SWAMINATHAN S. , HATCHER J. F. , BRYAN G. T. 
Published: May 2016

AbstractNitration of the furans (I) leads to the formation of the corresponding 5‐nitrofurans (III).
ChemInform Abstract: Synthesis of Some Substituted Benzimidazoles with Potential Antimicrobial Activity.
Authors: LABOUTA I. M. , HASSAN A. M. M. , ABOULWAFA O. M. , KADER O. 
Published: May 2016

AbstractTitle compounds of type (II) (8 examples) and (III) (5 examples), bearing a heterocyclic substituent in 2‐position, and the title compounds (VI) are prepared in order to test their antimicrobial activity.
ChemInform Abstract: Photochemical Synthesis of Cyclic 2‐(2,2‐Dimethylpropylidene)‐1,3‐dicarbonyl Compounds.
Authors: HOBEL K. , MARGARETHA P. 
Published: May 2016

AbstractPhotolysis of (b)‐fused bi‐ and tricyclic pyrandiones such as (III) affords title compounds such as (IV) in good yields along with small amounts of spiroalkanediones such as (V).
ChemInform Abstract: Studies on Condensed Polycyclic Aromatic Compounds Having Photochromic Properties. Part 3. Synthesis and Photochromic Properties of Anellated Benzo(1,2,3‐kl:4,5,6‐k′l′)dixanthenes and Their Endoperoxides.
Authors: TOKITA S. , ARAI T. , OHOKA M. , NISHI H. 
Published: May 2016

AbstractThe red benzodixanthene (III) is prepared in two steps from the anthraquinone (I) and 2‐naphthol (II).
ChemInform Abstract: Hydrolysis of the Vinyl Ether Functional Group in a Model for Prostacyclin in which the Carboxyl Group has been Replaced by a Pyridine Ring.
Authors: BERGMAN N.‐A. , HALVARSSON T. 
Published: May 2016

AbstractHydrolysis of the vinyl ether group in the three isomeric vinyl ether compounds (VI) ‐ (VIII), obtained from 5‐chloro‐2‐pentanone (I) as shown in the reaction scheme, leads to the formation of 6‐(2‐pyridyl)‐2‐hexanone (IX) and has been studied in acetic acid, hydrochloric acid, and biphosphate ion buffer solutions.
ChemInform Abstract: The Urea Connection. Intramolecular Diels‐Alder Reactions of Ureas.
Authors: KRAUS G. A. , BOUGIE D. , JACOBSON R. A. , SU Y. 
Published: May 2016

AbstractThe ureas (IV), prepared by coupling the indoles (I) with the isocyanates (II) and subsequent treatment with the bromides (III), undergo intramolecular Diels‐Alder reaction, forming the adducts (V).
ChemInform Abstract: Addition of the Lithium Derivatives of 4‐Alkyl‐3‐morpholinones to Carbonyl Compounds.
Authors: DOBREV A. , NECHEV L. , IVANOV C. 
Published: May 2016

AbstractThe addition of the lithium derivative of the morpholinone (I) to carbonyl compounds (II) affords racemic alcohols of type (III) (27 examples).
ChemInform Abstract: A Convenient Synthesis of N‐Substituted Benzoxazepines and Benzoxazines.
Authors: SHARMA I. , AGARWAL M. , RAY S. 
Published: May 2016

AbstractImproved methods are developed for the preparation of the benzoxazepine (V) via (III) and the benzoxazepines (VIII) and benzoxazines (X) from the analogues (VI) of (III).
ChemInform Abstract: Protecting Groups for the Synthesis of Diazacyclophanes by the Rigid‐Group Principle.
Authors: FUNKE U. , GRUETZMACHER H.‐F. + 
Published: May 2016

AbstractA variety of aliphatic dicarbonyl dichlorides are probed as protecting groups in the preparation of the di‐ and monothiadiazaparacyclophanenes (VI) and (VII).
ChemInform Abstract: Effect of Silica Gel on the Benzenesulfinic Acid‐Catalyzed Isomerization of Vinylsilanes. Formation of Silyl Benzenesulfinate.
Authors: OCHIAI M. , TAKAOKA Y. , UKITA T. , NAGAO Y. , FUJITA E. 
Published: May 2016

AbstractThe Z‐vinylsilanes (I) are isomerized to form the E‐configurated analogues (II) by treatment with benzenesulfinic acid in the presence of silica gel.
ChemInform Abstract: Synthesis and Reactivity of (LMn(CO)3)+: Kinetics and Mechanism of Its Formation and the Crystal Structure of (LMn(CO)3)3(PF6)2Br·2 H2O (L: 1,4,7‐Trithiacyclononane).
Authors: ELIAS H. , SCHMIDT G. , KUEPPERS H.‐J. + , SAHER M. , WIEGHARDT K. , NUBER B. , WEISS J. 
Published: May 2016

AbstractThe formation mechanism of (III) is discussed.
ChemInform Abstract: Bi‐ and Polynuclear Complexes with Short‐Bite Ligands Bridging Metal Atoms. ((η5‐C5H5)Rh(μ‐CH3O2CC2CO2CH3)(μ‐Ph2Ppy)Rh(CO)(μ‐Cl))2: Synthesis, X‐Ray Crystal Structure, Structural Dynamics, and Reactions with CO and SO2.
Authors: ROTONDO E. , LO SCHIAVO S. , BRUNO G. , ARENA C. G. , GOBETTO R. , FARAONE F. 
Published: May 2016

AbstractCompound (I) reacts with acetylenes, activated by electron‐withdrawing groups, to give the tetranuclear complexes (III), which are at low temp. in equilibrium with the corresponding binuclear compounds (1H, 31P NMR evidence).
ChemInform Abstract: Terpenes. Part 299. Sesquiterpene Lactones of Cephalophora aromatica (Hook.) Schrader and Their Deterrent Activity. The Stereostructure of Geigerinin (III).
Authors: BLOSZYK E. , DUDEK A. , KOSTURKIEWICZ Z. , RYCHLEWSKA U. , DANIEWSKI W. M. , GUMULKA M. , NAWROT J. , BUDESINSKY M. , VASICKOVA S. , HOLUB M. 
Published: May 2016

AbstractAlong with already described sesquiterpene lactones helenalin (Ia), mexicanin I (IIa), its O‐acetate linifolin A, and a mixture of aromatin (Ib) and aromaticin (IIb), geigerinin (III) (space group P21 with Z=4) is identified.
ChemInform Abstract: Synthesis and Muscarinic Activity of a Series of Tertiary and Quaternary N‐Substituted Guvacine Esters Structurally Related to Arecoline and Arecaidine Propargyl Ester.
Authors: WOLF‐PFLUGMANN M. , LAMBRECHT G. , WESS J. , MUTSCHLER E. 
Published: May 2016

AbstractArecoline (I) is N‐demethylated by consecutive treatment with phosgene and hot water to give guvacoline which is isolated as its hydrobromide (II).
ChemInform Abstract: Synthesis of New Dihydropyrano‐1,3‐diphenylprop‐2‐enones: Revision of the Structure of Flemistrictin‐F.
Authors: PARMAR V. S. , SHARMA V. K. , MALHOTRA S. 
Published: May 2016

AbstractDuring the attempted synthesis of the title compound, isolated from Flemingia stricta and assigned to have structure (V), a series of new products are obtained.
ChemInform Abstract: Superacid Cyclodehydration of Ketones in the Production of Tricyclic Antihistamines.
Authors: SCHUMACHER D. P. , MURPHY B. L. , CLARK J. E. , TAHBAZ P. , MANN T. A. 
Published: May 2016

AbstractLoratadine (XII), a potent long‐acting antihistamine without CNS side effects, is synthesized as outlined in the reaction scheme.
ChemInform Abstract: Reduction of Aromatic Nitro Compounds with Bakers′ Yeast.
Authors: TAKESHITA M. , YOSHIDA S. , KIYA R. , HIGUCHI N. , KOBAYASHI Y. 
Published: May 2016

AbstractThirty‐six nitrobenzenes such as (I) and (III) are reduced with bakers' yeast to give the corresponding anilines (II) or (IV).
ChemInform Abstract: Electrosynthesis and Photoelectrochemical Characterization of Zinc Selenide Doped with Thallium.
Authors: SINGH K. , RAI J. P. 
Published: May 2016

AbstractTl‐doped ZnSe semiconductor electrodes, prepared by electrochemical codeposition, exhibit photoresponsivities significantly higher than that of undoped ZnSe electrodeposits prepared under similar conditions.
ChemInform Abstract: Improved Synthesis, Redox Chemistry, and Magnetism of the Mixed Valence Isopolyanion V10O4‐ 26.
Authors: BAXTER S. M. , WOLCZANSKI P. T. 
Published: May 2016

AbstractAddition of stoichiometric amounts of vanadyl(IV) ion to V2O5 and Bu4NOH in Me2CO/H2O provides a convenient route to the known mixed‐valence compound (IV) in moderate yield.
ChemInform Abstract: Intercalation Reactions of the Neptunyl(VI) Dication with Hydrogen Uranyl Phosphate and Hydrogen Neptunyl Phosphate Host Lattices.
Authors: DORHOUT P. K. , KISSANE R. J. , ABNEY K. D. , AVENS L. R. , ELLER P. G. , ELLIS A. B. 
Published: May 2016

AbstractThe strong parallels existing between neptunyl and uranyl intercalation chemistry are reported.
ChemInform Abstract: Alkali Metal Manganese Chalcogenides A2MnX2 with A: K, Rb, or Cs and X: S, Se, or Te
Authors: BRONGER W. , BALK‐HARDTDEGEN H. , SCHMITZ D. 
Published: May 2016

Abstractare synthesized as outlined in the scheme with the chalcogens being charged in a H2 stream (yields not given).
ChemInform Abstract: Solution Studies of the Cobalt(II) N‐rac‐ and N‐meso‐CoL2+ Isomers and Molecular and Crystal Structures of the Low‐Spin, Five‐Coordinate Cobalt(II) Macrocyclic Complexes N‐rac‐(CoL(H2O))(ClO4)2·0.6 H2O and N‐rac‐(CoL(OClO3))ClO4 (L: 5,7,7,12,14,14‐Hexamethyl‐1,4,8,11‐tetraazacyclotetradeca‐4,11‐diene).
Authors: SZALDA D. J. , SCHWARZ C. L. , ENDICOTT J. F. , FUJITA E. , CREUTZ C. 
Published: May 2016

AbstractThe title complex (Ia) crystallizes in Pbcn with Z=20, and (Ib) in P21/c with Z=4.
ChemInform Abstract: Catalysis of Diels‐Alder Reactions by Low Oxidation State Transition‐Metal Lewis Acids: Fact and Fiction.
Authors: BONNESEN P. V. , PUCKETT C. L. , HONEYCHUCK R. V. , HERSH W. H. 
Published: May 2016

AbstractIn order to determine the potential of transition‐metal Lewis acids as catalysts, complexes such as (I)‐(III) are investigated.
ChemInform Abstract: Kinetics and Mechanism of the Thermal Rearrangement of Some (Chloromethyl)silanes.
Authors: CLARKE M. P. , DAMRAUER R. , DAVIDSON I. M. T. , SIMON R. 
Published: May 2016

AbstractThe gas‐phase pyrolysis of the title compounds in a stirred flow reactor is studied kinetically indicating that the rearrangements are probably concerted in the gas phase.
ChemInform Abstract: Photoisomerization of Oxime Ethers and Efficiency of Triplet Formation via Exciplexes.
Authors: TAKEDA Y. , MISAWA H. , SAKURAGI H. , TOKUMARU K. 
Published: May 2016

AbstractThe DCA‐sensitized photoisomerization of (I) proceeds via its triplet under steady irradiation in benzene to give a photostationary state isomer ratio (59:41) which is nearly the same when starting with the Z isomer (II).
ChemInform Abstract: Ruthenium‐Catalyzed Aldol and Michael Reactions of Activated Nitriles.
Authors: NAOTA T. , TAKI H. , MIZUNO M. , MURAHASHI S.‐I. 
Published: May 2016

AbstractThe reactions of nitriles, activated by ruthenium catalysts, lead to a variety of products such as the aldol adducts (III) or the Michael adducts (IV) and (VIII).
ChemInform Abstract: Generation of an N‐Sodioazomethine Ylide and Its Cycloadditions with α,β‐Unsaturated Esters.
Authors: KANEMASA S. , YOSHIOKA M. , TSUGE O. 
Published: May 2016

AbstractIn previous studies, the reaction of (II) with a title ylide generated from (I) and NaI/Et3N had yielded a 1:2.7 mixture of (IV) and (VIII); an analogous reaction using LiBr/Et3N had given (IV) exclusively.
ChemInform Abstract: The Effect of Phenyl Ring Torsional Rigidity on the Photophysical Behavior of Tetraphenylethylenes.
Authors: SHULTZ D. A. , FOX M. A. 
Published: May 2016

AbstractThe photophysical properties of the tethered tetraphenylethylenes (VII) change dramatically with the length of the (CH2)n‐tethers.
ChemInform Abstract: Methyl α‐Acyloxy‐γ‐methylene‐β‐tetronate. Preparation and Use as a Building Block for the Synthesis of the Spirotetronic Acid Structure of Chlorothricolide.
Authors: OKUMURA K. , OKAZAKI K. , TAKEDA K. , YOSHII E. 
Published: May 2016

AbstractThe methylenetetronates (IV) mentioned in the title undergo Diels‐Alder reaction with the triene (VI), yielding mixtures of the diastereomeric cycloadducts (VIII) and (IX) and their regioisomers (X).
ChemInform Abstract: Photochemical Synthesis of Thiazolyl‐thiophene Derivatives.
Authors: D'AURIA M. , DE MICO A. , D'ONOFRIO F. , PIANCATELLI G. 
Published: May 2016

AbstractA new class of compounds, represented by (I), (V), (VII) and (IX), is synthesized in order to obtain products which show a higher selectivity than the phototoxic α‐terthiophene.
ChemInform Abstract: 1,3‐Dipolar Cycloadditions with Methyl 4‐Oxo‐ and 4‐Hydroxy‐2‐butynoates (II). Synthesis of Functionalized Pyrazoles (III), (IV), (VI), (VII) and Triazoles (IX), (X).
Authors: FARINA F. , FERNANDEZ P. , FRAILE M. T. , MARTIN M. V. , MARTIN M. R. 
Published: May 2016

Abstract1,3‐Dipolar Cycloadditions with Methyl 4‐Oxo‐ and 4‐Hydroxy‐2‐butynoates (II).
ChemInform Abstract: Facile Decomposition of 9‐Substituted 9‐Xanthydrols in Basic Media. Dependence of Reaction Behavior on Structure and Metal Ion.
Authors: KARAMAN R. , BADEJO I. T. , FRY J. L. 
Published: May 2016

AbstractSome puzzling observations had been made in the synthesis of the title compound (I); e.g., (I) is obtained from xanthone (II), Li metal, 4,4'‐di‐tert.‐butylbiphenyl in THF followed by addition of tropyl halide in more than 80% yield, but use of Na metal leads to recovery of xanthone (II) with no alcohol formed.
ChemInform Abstract: Synthesis of 2‐Methyl‐4‐phenyl‐1,2,3,4‐tetrahydroisoquinolin‐4‐ol Derivatives by a Novel Insertion Reaction of Arylnickel Complexes.
Authors: KIHARA M. , NAKANISHI A. , KOBAYASHI S. 
Published: May 2016

Abstract2‐Iodo‐N‐methylbenzylamine (I) is coupled with the phenacyl bromides (II) to give the o‐iodobenzylaminoacetophenones (III) which undergo cyclization in the presence of zerovalent nickel, producing the 4‐hydroxytetrahydroisoquinolines (IV).
ChemInform Abstract: Cyclohepta(b) (1,4)benzoxazines. Part 3. The Reaction of 6‐Bromocyclohepta(b) (1,4)benzoxazine with o‐Aminophenol.
Authors: NOZOE T. , OKAI H. , WAKABAYASHI H. , ISHIKAWA S. 
Published: May 2016

AbstractPrevious studies had shown that (I) reacts with (III) to give a complex mixture of products.
ChemInform Abstract: Synthesis and Reactivity of 2‐Alkyl‐ and 2‐Aryl‐4H‐pyrido(3,2‐e)‐1,3‐thiazin‐4‐ones.
Authors: COUTURE A. , GRANDCLAUDON P. , HUGUERRE E. 
Published: May 2016

AbstractThe title thiazine derivatives (III) and (V) are synthesized for the first time.
ChemInform Abstract: Preparation and Pharmacological Activity of Amido Derivatives of 3‐Methyl‐3,4‐dihydrobenzo‐ and ‐pyrido‐1,2,4‐triazin‐3‐ylacetic Acids.
Authors: BOIDO A. , NOVELLI F. , SAVELLI F. , SPARATORE F. , RUSSO S. , FILIPPELLI W. , SUSANNA V. , MARMO E. 
Published: May 2016

AbstractCoupling of the 2‐nitroarylhydrazines (I) with the acetoacetamides (II) yields the hydrazones (III) which are hydrogenated and oxidized to form the title compounds (V).
ChemInform Abstract: Reaction of N‐Vinyliminophosphoranes. Part 10. Reaction of N‐Vinyliminophosphoranes with 2,4,6‐Cyclooctatrienone. Intermediate Formation of 8‐Azabicyclo(5.3.1)undeca‐2,4,7,9‐tetraene Ring System.
Authors: NITTA M. , KANOMATA N. 
Published: May 2016

AbstractIn an attempt to synthesize the 8‐azabicyclo(5.3.1)undeca‐2,4,7,9‐tetraene skeleton, the dehydrogenation of which is expected to give the desired compound (I), the reactions of the phosphoranes (III) and (VI) with 2,4,6‐cyclooctatrienone (II) are investigated.
ChemInform Abstract: Synthesis of the Racemate and the Enantiomers of 1,1′‐Binaphthyl‐2,2′‐phosphoric Acid.
Authors: KNABE J. 
Published: May 2016

AbstractThe racemic title compound (III) is obtained by an improved method which consists in dimerization of β‐naphthol (I) and subsequent coupling with phosphorus oxychloride (II).
ChemInform Abstract: Reaction of Hexafluoroacetonimine with PH‐Acids.
Authors: MARTYNOV I. V. , AKSINENKO A. YU. , CHEKHLOV A. N. , SOKOLOV V. B. 
Published: May 2016

AbstractThe acetonimine (II) reacts with the phosphonite (Ia) or the phosphinous acids (Ib) and (Ic) to produce the phosphinate (IIIa) or the phosphine oxides (IIIb) and (IIIc).
ChemInform Abstract: Stepwise Reduction of Acetonitrile in (Tp′(CO)(PhCCMe)W(NCCH3)) (BF4).
Authors: FENG S. G. , TEMPLETON J. L. 
Published: May 2016

AbstractSequential hydride and proton addition is the way to reduce the coordinated acetonitrile in the title complex (IV) to ethylamine and to isolate the intermediate metal complexes at each stage of the reduction.
ChemInform Abstract: The Contrasting Roles of the Various Chalcogens in the Synthesis of Mixed Metal Complexes (CO)6Fe2(μ3‐E)2M(PPh3)2 (E = Te, Se, S; M = Ni, Pd, Pt).
Authors: MATHUR P. , MAVUNKAL I. J. , RUGMINI V. 
Published: May 2016

AbstractThe iron carbonyl chalcogen clusters (I) react with tetrakis(triphenylphosphine)palladium or the corresponding platinum complex (II), yielding the mixed metal complexes (III) as the main products.
ChemInform Abstract: Synthesis and Spectral and Redox Properties of Three Triply Bridged Complexes of Ruthenium.
Authors: LLOBET A. , CURRY M. E. , EVANS H. T. , MEYER T. J. 
Published: May 2016

AbstractThe phosphato‐, carbonato‐, and acetato‐bridged μ‐oxo‐diruthenium complexes (III) and (IV) (yield 59/62%) are synthesized by reaction of the trichloride (I) with 0.1 M solution of phosphate buffer, sodium carbonate, or sodium acetate.
ChemInform Abstract: Influence of Remote Substituents on the Properties of Bis(terpyridyl)ruthenium(II) Complexes.
Authors: THUMMEL R. P. , HEGDE V. , JAHNG Y. 
Published: May 2016

AbstractThe complexes (I) are prepared from RuCl3 and the ligands in EtOH/H2O (reflux, N2, 15 h, yield not given).
ChemInform Abstract: Coordination Chemistry of N‐(Methylthio‐thiocarbonyl)pyruvic Acid Hydrazone.
Authors: THOMAS P. , SEIDEL A. , LEIBNITZ U. , SZARGAN R. , UHLIG I. , HENNIG H. 
Published: May 2016

AbstractThe title hydrazone (III) is prepared by a modified known method.
ChemInform Abstract: Structure, Synthesis, and Characterization of Chiral Secondary Diphosphine Platinum(II) Mono‐ and Dimeric Complexes: Molecular Structure of (Pt2Cl4(SMe2)2((R*,R*)‐μ‐HtBuPCH2PtBuH)).
Authors: HUFFMAN J. C. , LLOYD B. R. 
Published: May 2016

AbstractReaction of the Pt(II) complex (I) in greater than a 2‐fold excess with a 1:1 mixture of the diphosphines (IVa) and (IVb) leads to the isolation of the two new complexes (II) and (III) (no yields given).
ChemInform Abstract: Chemistry of the Burseraceae. Part 11. X‐Ray Diffraction Studies on Some Tirucall‐7‐ene Triterpenes from Aucoumea klaineana (Burseraceae).
Authors: LIANG G.‐Y. , GRAY A. I. , PATALINGHUG W. C. , SKELTON B. W. , WATERMAN P. G. , WHITE A. H. 
Published: May 2016

AbstractThree new triterpenes intimately related to flindissol are isolated: flindissol lactone (I), flindissone (II) (perhaps a mixture of 21‐hydroxy epimers in solution, cannot be obtained in crystalline state), and flindissone lactone (III).
ChemInform Abstract: Glycosyl Imidates. Part 41. 6‐O‐Benzyl‐Protected Muramic Acid as Glycosyl Acceptor. ‐ Synthesis of the GlcNAc‐β(1 → 4)MurNAc Disaccharide.
Authors: TERMIN A. , SCHMIDT R. R. 
Published: May 2016

AbstractThe trichloroacetimidate (I) as glucosamine donor and the 6‐O‐benzyl‐protected muramic acid (II) as acceptor yield the β‐connected disaccharide (III), which is transformed into the β‐anomer of the title disaccharide (V); the corresponding α‐anomer can be obtained by NaOMe treatment of (V) and reacetylation.
ChemInform Abstract: An Improved Synthesis of Glycinamide Ribonucleotide.
Authors: BOSCHELLI D. H. , POWELL D. , SHARKY V. , SEMMELHACK M. F. 
Published: May 2016

AbstractStarting with the commercially available ribose derivative (I), the biologically important glycinamide ribonucleotide (GAR) (XIV) is synthesized as outlined in the reaction scheme.