bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis and Antiinflammatory Activity of Alkenylphenylpropionic Acids.
Authors: AMANO T. , YOSHIKAWA K. , OGAWA T. , SANO T. , OHUCHI Y. , TANAMI T. , OTA T. , HATAYAMA K. , HIGUCHI S. , AMANUMA F. , SOTA K. 
Published: May 2016

AbstractThe 4‐alkenylchlorobenzenes (I), prepared from p‐chlorobenzene or 4‐chloromethylchlorobenzene by normal alkylation reactions with organometallic compounds, undergo Grignard reaction with (II), yielding the title compounds (III).
ChemInform Abstract: Studies on the Metabolites of Penicillium diversum var. aureum. Part 2. Synthesis and Cytotoxic Activity of Trihydroxytetralones.
Authors: FUJIMOTO Y. , SATOH M. 
Published: May 2016

AbstractJuglone (I) is reduced to give the isomers (II) and (III) which are separated by reaction with acetone dimethylketal.
ChemInform Abstract: Pyrazolone Derivatives. Part 13. Syntheses of 1‐Substituted 4‐Arylhydrazono‐3‐methyl‐2‐pyrazolin‐5‐ones and 1‐Substituted 4‐Arylazo‐3,5‐dimethylpyrazoles as Potential Antiinflammatory Agents.
Authors: ISMAIEL A. M. , YOUSIF M. Y. , METWALLY M. A. , EL‐KERDAWY M. 
Published: May 2016

AbstractThe title compounds (VI), (VIII) and (X) are synthesized as indicated in the scheme.
ChemInform Abstract: A New Approach to 5‐Arylidenethiazolin‐4‐ones.
Authors: RUDORF W.‐D. , SCHWARZ R. 
Published: May 2016

AbstractThe 3‐arylpropynamides (I) and (IV) are coupled with the isothiocyanates (II) under various reaction conditions to give the iminothiazolidinones (III) and (V).
ChemInform Abstract: Heterocycles. Part 20. Reactions of 2′′‐Methoxymethoxychalcone Epoxides Under Acidic Conditions.
Authors: TAKAHASHI H. , KUBOTA Y. , LIN F. , LI S. , ONDA M. 
Published: May 2016

AbstractThe chalcones (III), prepared by coupling the aldehydes (II) with the acetophenones (I), are epoxidized with alkaline hydrogen peroxide to give (IV).
ChemInform Abstract: Partially Fluorinated Heterocyclic Compounds. Part 23. Thermolysis Reactions of 1,3,4,5,6,7,8‐Heptafluoro‐2‐naphthyl‐prop‐2‐enyl Sulphide and 1,3,4,5,7,8‐Hexafluoro‐2,6‐di(prop‐2‐enylthio)naphthalene in N,N‐Diethylaniline and Related Reactions with 1,3,4,5,6,7,8‐Heptafluoro‐1‐(prop‐2‐enyl)naphthalen‐2‐one and 2,3,4,5,6‐Pentafluoro‐4‐(prop‐2‐ enyl)‐2,5‐cyclohexadienone.
Authors: BROOKE G. M. , PLEWS G. 
Published: May 2016

AbstractThe polyfluoronaphthalene sulphide derivatives (III) and (IV) are synthesized from octafluoronaphthalene (I) by reaction with sodium hydrosulphide and propenyl bromide (II).
ChemInform Abstract: Ipso‐Substitution Reactions of 2‐ and 4‐Sulfonylpyridines with Grignard Reagents.
Authors: FURUKAWA N. , TSURUOKA M. , FUJIHARA H. 
Published: May 2016

AbstractThe methylsulfonylpyridines (II) and (X) are converted to the pyridylmethylsulfonylpyridine (III) and (XI) respectively in the presence of phenylmagnesium bromide (Id).
ChemInform Abstract: Studies on 2(1H)‐Quinolinone Derivatives as Gastric Antiulcer Active Agents. Synthesis and Antiulcer Activity of the Metabolites of 2‐(4‐ Chlorobenzoylamino)‐3‐(2(1H)‐quinolinon‐4‐yl)propionic Acid.
Authors: UCHIDA M. , TABUSA F. , KOMATSU M. , MORITA S. , KANBE T. , NAKAGAWA K. 
Published: May 2016

AbstractThe quinolinonylpropionic acid (I), which is a gastric antiulcer agent, produces the metabolites (II) ‐ (IV).
ChemInform Abstract: Synthesis of 1,3‐Dioxin‐4‐ones and Their Use in Synthesis. Part 13. Synthesis of 5‐Halo‐1,3‐dioxin‐4‐ones and Their Conversion of 5‐Alkyl Derivatives.
Authors: SATO M. , YONEDA N. , KANEKO C. 
Published: May 2016

AbstractThe formylacetate (I) is converted to the 5‐methyldioxinone (II).
ChemInform Abstract: Solid State Photodimerization Reaction of Some 3‐Styrylisoxazolo‐(3,4‐d)pyridazin‐7(6H)‐ones.
Authors: CHIMICHI S. , CICIANI G. , DAL PIAZ V. , DE SIO F. , SARTI‐FANTONI P. , TORROBA T. 
Published: May 2016

AbstractIrradiation of the solid arylhetarylalkenes (I), prepared from aromatic aldehydes and the corresponding trimethyl heterocycle, produces the dimers (II) which are oxidized to yield the diacids (III).
ChemInform Abstract: Synthesis of 2/9‐Substituted Indophenazine‐6‐acetic Acid α‐Aryl/methylbenzylidenehydrazides, 4‐Aryl‐1‐(indophenazine‐6‐methylcarbonyl)‐3‐thiosemicarbazides and 6‐(4‐Aryl‐5‐mercapto‐4H‐1,2,4‐triazol‐3‐ylmethyl)indophenazines as CNS Active and Antiinflammatory Agents.
Authors: MOHAN R. R. , AGARWAL R. , MISRA V. S. 
Published: May 2016

AbstractTitle compounds of type (VI), (VIII) and (IX) are synthesized starting from the hydrazides (IV) and screened for their toxicity, and gross CNS and antiiflammatory activity.
ChemInform Abstract: A New Synthesis of Imidazo(5,1‐c)(1,4)benzoxazines via Their Corresponding Reissert‐Type Compounds.
Authors: BARTSCH H. , SCHWARZ O. , NEUBAUER G. 
Published: May 2016

AbstractAcylation of the aniline (I), acid‐catalyzed cyclization and subsequent substitution yield the acyldihydrobenzoxazine carbonitriles (V) which are transformed into the imidazobenzoxazines (VI).
ChemInform Abstract: Heterocyclization Reactions with Carbodiimides: Synthesis of Fused 1,2,4‐Triazoles.
Authors: MOLINA P. , ALAJARIN M. , FERAO A. 
Published: May 2016

AbstractThe fused mesoionic 1,2,4‐triazoles (IV) and (VI) are obtained by coupling the diarylcarbodiimides (I) with the N‐amino heterocycles (II) and (V).
ChemInform Abstract: Thiazyl(bis(trifluoromethyl)nitroxide) and Tris(thiazyl(bis(trifluoromethyl)nitroxide)).
Authors: HARTMANN G. , MEWS R. , SHELDRICK G. M. , ANDERSKEWITZ R. , NIEMEYER M. 
Published: May 2016

AbstractThe thiazyl compound (I) is irradiated to give the trimeric derivative (II).
ChemInform Abstract: Formation of 2‐Oxa‐8,9‐diazabicyclo(3.3.1)nona‐3,6‐diene Derivatives from Pyrimidine: Utility for Tetrahydropyrimidine Synthesis.
Authors: AKIBA K. , SAKAGUCHI A. , YAMAMOTO Y. 
Published: May 2016

AbstractPyrimidine (I) is activated with trimethylsilyl triflate (II) and subsequently transformed into the hydroxytetrahydropyrimidines (IVa) and (IVb) by reaction with the enol silyl ethers (IIIa) and (IIIb).
ChemInform Abstract: Synthesis and Crystal Structure of B10H10(C6H11)S(CH3)2CNH(t‐C4H9).
Authors: HERNANDEZ D. M. , HUFFMAN J. C. , TODD L. J. 
Published: May 2016

AbstractThe reaction of the dimethyl sulfide (S‐B5)‐9‐cyclohexyl‐nido‐decaborane(11) (I) with the isocyanide (II) yields the title compound (III) as the major product.
ChemInform Abstract: First Demonstration of Solvolytic Generation of a Simple Silicenium Ion (R3Si+). Access via 1,2‐Methyl Migration.
Authors: APELOIG Y. , STANGER A. 
Published: May 2016

AbstractAs a starting point ab initio calculations predict that solvolytically produced α‐silylcarbenium ions are generally less stable than the isomeric silicenium ions generated via a 1,2‐methyl migration of these carbenium ions.
ChemInform Abstract: Allylic Rearrangement of Cyanophosphates. Part 3. Reaction of Acyclic Enone Cyanophosphates.
Authors: KURIHARA T. , MIKI M. , SANTO K. , HARUSAWA S. , YONEDA R. 
Published: May 2016

AbstractThe vinylic ketones (I) and the aldehydes (XIV) are cyanophosphorylated with diethyl phosphorocyanidate (II), producing the allylic phosphates (III) or (XV).
ChemInform Abstract: An Inelastic Electron Tunneling Spectroscopic Investigation of the Interaction of Molybdenum Hexacarbonyl with an Aluminum Oxide Surface.
Authors: GAJDA G. J. , GRUBBS R. H. , WEINBERG W. H. 
Published: May 2016

AbstractThe vibrational spectra show a transient complex formed between Mo(CO)6 and a fully hydroxylated alumina surface.
ChemInform Abstract: Reactivity of Bulky Alkyldichlorostibines and Alkyldichlorobismuthines Toward (W(CO)5)2‐: Synthesis of Compounds Containing Stibinidene, Bismuthinidene, and Dibismuth Ligands.
Authors: ARIF A. M. , COWLEY A. H. , NORMAN N. C. , PAKULSKI M. 
Published: May 2016

AbstractThe reaction of the stibine (II) with the W carbonyl compound (I) affords the stibinidene complex (III), whose "open" (that is non metal‐metal bonded) structure is confirmed by X‐ray crystallography (space group C2/c, Z=4).
ChemInform Abstract: Insertion of Carbon Dioxide into Metal Alkoxide Bonds. Synthesis and Structure of Tungsten Tetracarbonyl Carbonate.
Authors: DARENSBOURG D. J. , SANCHEZ K. M. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe recently prepared aryl oxide tungsten complexes (I) react with CO2 yielding the aryl carbonate pentacarbonyl species (II) which on hydrolysis accompanied by loss of a CO ligand leads to the title compound (III) (no yield given).
ChemInform Abstract: Aluminium Chloride Induced Cleavage of Diphosphaferrocenes in Aromatic Hydrocarbons; the Synthesis of η6‐Arene η5‐Phosphacyclopentadienyl Iron(II) Cations.
Authors: ROBERTS R. M. G. , WELLS A. S. 
Published: May 2016

AbstractThe reactivity of the diphosphaferrocenes (I) toward AlCl3 in aromatic solvents is investigated.
ChemInform Abstract: Models for Methemocyanin Derivatives: Structural and Spectroscopic Comparisons of Related Azido‐Coordinated (N‐ 3) Mono‐ and Dinuclear Copper(II) Complexes.
Authors: KARLIN K. D. , COHEN B. I. , HAYES J. C. , FAROOQ A. , ZUBIETA J. 
Published: May 2016

AbstractModel complexes for methemocyanin complexes are synthesized containing an azide ligand which is used as a probe of the dinuclear copper active site in the dioxygen‐transport hemocyanin.
ChemInform Abstract: Substitution Reactions of Ruthenium(II) Complexes Containing 2,2′‐Bipyridine and 1,10‐Phenanthroline.
Authors: ALLEN L. R. , CRAFT P. P. , DURHAM B. , WALSH J. 
Published: May 2016

AbstractThe substitution rates of complexes of type (I) with various ligands (CH3CN, Py, acetylpyridines) at 25 °C in aqueous solution are examined.
ChemInform Abstract: Photochemical Oxidation Reaction of Tribromobis(diethyl sulfide)nitrosylruthenium(II), (Ru(NO)Br3(Et2S)2): Reaction and Structural Chemistry.
Authors: COLL R. K. , FERGUSSON J. E. , MCKEE V. , PAGE C. T. , ROBINSON W. T. , KEONG T. S. 
Published: May 2016

AbstractThe title complex (Ia) undergoes a photochemical oxidation from which the compounds (II) and (III) are isolated.
ChemInform Abstract: Platinum(II) Complexes Containing 1‐(Diphenylphosphino)‐2‐methoxyethane. 31P NMR and Catalytic Studies in the Presence of Tin(II) Chloride and the Crystal and Molecular Structure of Cyclic (Pt(Ph2PCH2CH2OMe)(Ph2PCH2CH2OMe)Cl)ClO4.
Authors: ANDERSON G. K. , COREY E. R. , KUMAR R. 
Published: May 2016

AbstractThe complexes (PtCl2‐n(Ph2P‐CH2‐CH2‐OMe)2)n+ (n = 0, 1, 2) react with SnCl2 in Me2CO or CHCl3 to produce (II) besides a series of tin‐containing Pt(II) anions.
ChemInform Abstract: 20,20‐Dimethoxy‐16α,17α‐epiminopregnolone in the cis‐Opening Reaction of the Aziridine Cycle by Acetic Acid.
Authors: KAMERNITSKII A. V. , TURUTA A. M. , ISTOMSINA Z. I. 
Published: May 2016

AbstractThe oxazolinopregnenediolone hydrazone (IVa) is the main product in the ring opening reaction of the aziridino steroid (Ia) in acetic acid in the presence of ethoxycarbonylhydrazine (II).
ChemInform Abstract: The Synthesis of Methyl N‐(Protected)‐O‐(Acetamido‐O‐acetyl‐deoxy‐α‐D‐hexopyranosyl)‐L‐serinates.
Authors: SMIATACZ Z. , PASZKIEWICZ E. 
Published: May 2016

AbstractThe reduction of the hydroxyimine (Ia) followed by acetylation gives the acetamides (IIa) + (IIb) in low yield and with little stereodifferentiation.
ChemInform Abstract: Model Studies of Histrionicotoxin. The Synthesis of the 1‐Azaspiro(5.5)undecane Rings System from Carbohydrate Starting Materials.
Authors: BREWSTER K. , HARRISON J. M. , INCH T. D. , WILLIAMS N. 
Published: May 2016

AbstractThe aldehyde (I), readily available by a four‐step synthesis from mannose, is transformed to the nitrocyclitol (III).
ChemInform Abstract: Preparation of Y3Al5O12‐Based Phosphor Powders.
Authors: YAN M. F. , HUO T. C. D. , LING H. C. 
Published: May 2016

AbstractCe‐doped Y3Al5O12 garnet powders have been prepared by freeze drying of a homogenously mixed aqueous solution of (NH4)2Ce(NO3)6, Y2(SO4)3, and Al2(SO4)3, as well as by mechanically mixing the constituent oxide powders.
ChemInform Abstract: Decomposition Potentials of Crystalline Silicon as Related to the Photocurrent Stability of p‐n Junction Silicon Semiconductor Electrodes.
Authors: NAKATO Y. , UEDA T. , EGI Y. , TSUBOMURA H. 
Published: May 2016

AbstractThe onset potentials, Uox, for Si oxidation have been measured at highly doped n+‐ and p+‐type Si wafers in aqueous solutions of various pH's. The Uox values are significantly more positive (0.8‐1.1 V) than the thermodynamic redox potentials ε(SiO2/Si) (‐0.857 V vs.
ChemInform Abstract: Effect of PF‐ 6 Anion on the Properties of Lithium‐Polypyrrole Battery During Polypyrrole Film Formation.
Authors: OSAKA T. , NAOI K. , SAKAI H. , OGANO S. 
Published: May 2016

AbstractThe charging‐discharging efficiency of the Li/LiClO4‐PC/PPy (PC: propylene carbonate, PPy: polypyrrole) battery with a rough PPy film formed with LiPF6 is higher than that of an analogous battery with a PPy film formed with LiClO4.
ChemInform Abstract: Mixed Oxides La2/3‐xLi3xTiO3
Authors: BELOUS A. G. , NOVITSKAYA G. N. , POLYANETSKAYA S. V. , GORNIKOV YU. I. 
Published: May 2016

Abstractwith 1/24 < x < 1/6 are obtained by precipitation of the components from solutions and subsequent heating to 1250‐1330 °C for 2‐3 h. The title compounds possess a perovskite type structure within the range of x given above.
ChemInform Abstract: Synthesis and Investigation of the Binary Arsenates of Tin(IV) and Alkali Metals.
Authors: CHERNORUKOV N. G. , SIBRINA G. F. 
Published: May 2016

AbstractThe novel title compounds MSn2(AsO4)3 (M: Li, Na, K, Rb, Cs) are prepared by heating mixtures of anhydrous MCl and Sn(HAsO4)2 to 300‐360 °C for 2 h, and then to 580‐650 °C. They are studied by X‐ray analysis and IR spectrometry.
ChemInform Abstract: Physical Chemical Study of Strontium Hexachlorotechnetate.
Authors: ZAITSEVA L. L. , KRUGLOV A. A. , KOSTYUKOV AN. S. , TETERIN E. G. 
Published: May 2016

AbstractThe hitherto unknown title compound is prepared from SrO, which is dissolved in HTcO4 and subsequently refluxed in 32% HCl for 6 h. The title compound has a rhombic, space‐centered lattice, as found by an X‐ray analysis.
ChemInform Abstract: Carbon Acidity. Part 70. Equilibrium Ion Pair Acidities in Tetrahydrofuran of Benzylic Carbon Acids Stabilized by an Adjacent Cyano, Carboalkoxy, and Sulfonyl Substituent. Delocalization and Aggregation of Ion Pairs.
Authors: KAUFMAN M. J. , GRONERT S. , BORS D. A. , STREITWIESER A. JUN. 
Published: May 2016

AbstractThe pKa values of (I) are determined with the aid of transmetalation equilibria, using indicators such as (IV).
ChemInform Abstract: Methylphosphonic Dichloride as Reagent for the Determination of the Enantiomeric Excess of Chiral Thiols. Scope and Limitations.
Authors: STRIJTVEEN B. , FERINGA B. L. , KELLOGG R. M. 
Published: May 2016

AbstractTreatment of a chiral thiol, e.g. (I), with a phosphorus reagent of type (II) yields a d,l/meso mixture of diastereomers (III), whose composition is determined by 31P NMR spectroscopy.
ChemInform Abstract: Lanthanoids in Organic Synthesis. Part 6. Stereocontrolled Cyclization Reactions Mediated by Samarium Diiodide.
Authors: MOLANDER G. A. , ETTER J. B. , ZINKE P. W. 
Published: May 2016

AbstractStereocontrolled cyclization of the ketoamides (I), (III) or ketoesters (VI), (XI) induced by SmI2 leads to the products (II), (IV), (VII) + (VIII), (XII) + (XIII), mostly in excellent yields.
ChemInform Abstract: The Stereoselectivity of Ketal Claisen Rearrangements with Ketals of Simple Cyclic Ketones.
Authors: DAUB G. W. , GRIFFITH D. A. 
Published: May 2016

AbstractThe allylic alcohols (I) are coupled with the acetals (II) derived from cyclic ketones, yielding mixtures of the isomers (III) and (IV).
ChemInform Abstract: Electronic Absorption Spectra and Photochemical Reactivity of Group 5 Metal Alkyl Compounds: Photochemical α‐Hydrogen Abstraction.
Authors: CHAMBERLAIN L. R. , ROTHWELL I. P. 
Published: May 2016

AbstractThe electronic spectra of the compound (I) are dominated by an intense ligand‐to‐metal charge‐transfer band, the energy of which is strongly dependent on the substituent X. The observed photochemistry of (I), in some cases leading to the efficient and almost quantitative photosynthesis of alkylidene functional groups, is investigated.
ChemInform Abstract: Palladium‐Catalyzed, One‐Pot Carbonylation of Heterocyclic Compounds into Their Esters, in the Presence of Mercury Salts.
Authors: JAOUHARI R. , DIXNEUF P. H. , LECOLIER S. 
Published: May 2016

AbstractThe Pd‐catalyzed carbonylation of the 5‐ring heterocycles (I) in the presence of the alcohols (II) and Hg(II) salts yields the carboxylates (III).
ChemInform Abstract: A Simplified Procedure for the Preparation of 1,2‐Dichloro‐1‐(N,N‐dialkylamino)ethenes and 2‐Chloro‐1,1‐bis(dialkylamino)ethenes.
Authors: VAN DER HEIDEN R. , BRANDSMA L. 
Published: May 2016

AbstractDichloroacetylene (III) prepared from trichloroethene (I) and lithium dialkylamide reacts with the amines (II) in situ to yield the dichloroaminoethenes (IV) which produce the chlorodiaminoethenes (V) on heating.
ChemInform Abstract: N,N‐Dialkyl(aryl)‐(N′,N′‐diethylthiocarbamoylthio)‐acetamides as Additives to Lubricating Oils.
Authors: KULIEV A. B. , DZHAVADOV M. M. , ABUSHOVA B. A. 
Published: May 2016

AbstractThe title compounds (III) are prepared.
ChemInform Abstract: A Novel Synthesis of Clonidine, an Anti‐Hypertensive Drug from o‐Chloronitrobenzene.
Authors: AYYANGAR N. R. , BRAHME K. C. , SRINIVASAN K. V. 
Published: May 2016

Abstract2‐Chlorophenylhydroxylamine (II), prepared from o‐chloronitrobenzene (I) by partial transfer‐hydrogenation, is converted to the N‐formyl derivative (III).
ChemInform Abstract: Cyclic Carbalkoxy Aminimides. Synthesis and Thermal Decomposition to Give N,N‐Dimethylamino Isocyanate.
Authors: SENET J.‐P. , VERGNE G. , WOODEN G. P. 
Published: May 2016

Abstract1,1‐Dimethylhydrazine (I) reacts with the chloroalkyl chloroformates (II), yielding the carbazates (III) which are cyclized to form the salts (IV).
ChemInform Abstract: Intramolecular Carbonyl Oxide‐Ester Cycloaddition. Structure of a Novel Alkoxy Ozonide.
Authors: BUNNELLE W. H. , SCHLEMPER E. O. 
Published: May 2016

AbstractTreatment of the ester (Ia) with ozone affords the ozonide (IIa) which can be reduced with PPh3 to the ketone (IIIa).
ChemInform Abstract: A Rapid, Efficient and Selective Conversion of Aldehydes and Acetals to Their 1,3‐Dithiane Derivatives with 2,2‐Dimethyl‐2‐sila‐1,3‐dithiane.
Authors: SODERQUIST J. A. , MIRANDA E. I. 
Published: May 2016

Abstract2,2‐Dimethyl‐2‐sila‐1,3‐dithiane (I) is converted to the dithianes (IV) by reaction with the aldehydes (II) or the corresponding acetals (III) in the presence of BF3.
ChemInform Abstract: The Reactions of Benzylmalononitriles with Hydrazine and Hydroxylamine. Synthesis of Pyrazoles, Isoxazoles, and Pyrazolo(1,5‐a)pyrimidine Derivatives.
Authors: VAQUERO J. J. , FUENTES L. , DEL CASTILLO J. C. , PEREZ M. I. , GARCIA J. L. , SOTO J. L. 
Published: May 2016

AbstractReaction of the benzylmalononitriles (I) with hydrazine or hydroxylamine yields the diaminopyrazoles (II) and the isoxazoles (III) respectively.
ChemInform Abstract: Studies on Phenothiazines: Synthesis of Phenothiazines via Smiles Rearrangement.
Authors: GUPTA R. R. , KUMAR R. 
Published: May 2016

AbstractReaction of the mononitrotribromobenzene (II) with the aminobenzenethiols (I) yields the diphenyl sulfides (III) which are formylated to give (V).
ChemInform Abstract: Organic Heterocyclothiazenes. Part 2. Reaction of Tetrasulfur Tetranitride with Phenylacetylene and Diphenylacetylene.
Authors: DALEY S. T. A. K. , REES C. W. 
Published: May 2016

AbstractThe reaction of S4N4 (II) with diphenylacetylene (Ia) in the presence of AlCl3 gives rise to the new heterocyclic system (III); in the reaction of (II) with (Ia) in the presence of dimorpholino disulfide, the major product (IV) is formed and (III) as well.
ChemInform Abstract: Synthetic Approaches Toward Mitomycins. Part 1. Stereoselective Synthesis of a Tetracyclic Intermediate.
Authors: FUKUYAMA T. , YANG L. 
Published: May 2016

Abstract2,6‐Dimethoxytoluene (I) is converted to the chalcon (VI) which is coupled with the trimethylsiloxyfuran (VII) to produce (VIII).
ChemInform Abstract: Synthesis, Crystal and Molecular Structure of O(Si(CH2CH2CH2)3N)2, an Oxygen‐Bridged Bis(tricarbasilatrane).
Authors: JURKSCHAT K. , TZSCHACH A. , MEUNIER‐PIRET J. , VAN MEERSSCHE M. 
Published: May 2016

AbstractThe disiloxane‐like bis(silatrane) (II) mentioned in the title is prepared by hydrolysis of the chlorosilatrane (I).
ChemInform Abstract: Complexes of Ligands Providing Endogenous Bridges. Part 1. The Syntheses and Crystal Structures of Barium and Lead(II) Complexes of Macrocyclic Schiff Bases Derived from Heterocyclic Dicarbonyls and 1,n‐Diamino‐n′‐hydroxyalkanes (n,n′= 3,2; 4,2; or 5,3).
Authors: ADAMS H. , BAILEY N. A. , FENTON D. E. , GOOD R. J. , MOODY R. , RODRIGUEZ DE BARBARIN C. O. 
Published: May 2016

AbstractThe reaction of 1,3‐diamino‐2‐hydroxypropane with 2,6‐diacetylpyridine in the presence of Ba2+ salts gives the complexes (I).
ChemInform Abstract: Diastereoselective Complexation of Benzyl Alcohols by Chromium Hexacarbonyl. Different Reactivities of the Diastereomers in an Acidic Medium.
Authors: BROCARD J. , LEBIBI J. , PELINSKI L. , MAHMOUDI M. 
Published: May 2016

AbstractThe benzylic alcohols (I) react with chromium hexacarbonyl, producing the isomeric chromocarbonyl compounds (III) and (IV).
ChemInform Abstract: Aroylhydrazones as Chelating Agents. Part 8. Synthesis and Spectroscopic Characterization of Complexes of Co, Ni, Cu, Zn, and Cd with 2,6‐Diacetylpyridine Bis(salicyloylhydrazone); X‐Ray Crystal Structure of Dichloro(2,6‐diacetylpyridine‐bis(salicyloylhydrazone))cadmium(II)‐Chloroform‐Methanol (1/1/1).
Authors: PELIZZI C. , PELIZZI G. , VITALI F. 
Published: May 2016

AbstractThe complexes (I) and (II) are prepared by the 1:1 molar reaction of the title ligand H2L with corresponding metal chlorides or acetates in refluxing EtOH/H2O or CHCl3/MeOH and isolated partly as hydrates with high yields.
ChemInform Abstract: Syntheses, Spectroscopic, and Electrochemical Properties of Dinuclear Copper(II) Complexes Bridged by a Single Thiolate Sulphur Atom; X‐Ray Crystal Structures of (Cu2(L1)2(SC6H4Cl‐4))(PF6) and (Cu2(L2)2(SC6H4CH3‐4))(ClO4).
Authors: AOI N. , MATSUBAYASHI G. , TANAKA T. 
Published: May 2016

AbstractThe preparation of the title complexes (III) is described.
ChemInform Abstract: Bis(dialkylphosphino)methane Complexes of Palladium(II) and the Molecular Structure of (Pd2Cl3(μ‐iPrPCH2PiPr2)(μ‐iPr2PCH2PHiPr))·2 CHCl3 Containing an Unusual Phosphidophosphine Bridging Ligand.
Authors: MANOJLOVIC‐MUIR L. , LLOYD B. R. , PUDDEPHATT R. J. 
Published: May 2016

AbstractThe mononuclear chelate complexes (I) are prepared by reaction of Pd(II) acetate/CF3COOH or PdCl2(NCPh)2 with corresponding bis(dialkylphosphino)methane compounds in acetone.
ChemInform Abstract: Synthesis, Characterization, and Reactivity of α‐Ketoacyl Complexes of Platinum(II) and Palladium(II). Crystal Structures of trans‐Pt(PPh3)2(Cl)(COCOPh) and cis‐Pt(PPh3)2(COPh)(COOMe).
Authors: SEN A. , CHEN J.‐T. , VETTER W. M. , WHITTLE R. R. 
Published: May 2016

AbstractThe ketoacyl complexes (II) are prepared by oxidative addition of the corresponding ketoacyl chlorides to the M(PPh3)4 compounds in benzene.
ChemInform Abstract: Bimetallic Systems. Part 16. Formation of Group 6 Metal(0)‐Platinum(II) Hydride Complexes, by Ring Opening of fac‐ or mer‐(M(CO)3(dppm‐PP′)(dppm‐P)) (M: Cr, Mo, or W; dppm: Ph2PCH2PPh2). Reactions of ((CO)3Mo(μ‐dppm)2PtH(Cl)).
Authors: BLAGG A. , SHAW B. L. 
Published: May 2016

AbstractTreatment of the title complexes (I) or (IV) with the Pt(II) complexes (II) gives the heterobimetallic complexes (III).
ChemInform Abstract: Synthesis and Electron‐Transfer Rates of Coplanar Diporphyrins: Models for (Heme) Protein‐Protein Electron‐Transfer Reactions.
Authors: HEILER D. , MCLENDON G. , ROGALSKYJ P. 
Published: May 2016

AbstractIn order to mimic intramolecular electron transfer in protein systems, models such as (V) are prepared by Zn‐mediated, acid‐catalyzed coupling of (III) with (IV) and subsequent oxidation (no yields are given).