bluuebunny/crossref_metadata_2025_split huggingface dataset:
Micro Thin-Layer Chromatography Fingerprints of Selected Basil Species and Their Chemometric Analysis
Authors: Hawrył Mirosław A , Świeboda Ryszard , Hawrył Anna , Niemiec Małgorzata , Waksmundzka-Hajnos Monika 
Published: June 2017

Abstract
The dried aerial parts of 12 plants of Ocimum spp. were extracted with the Soxhlet apparatus using dichloromethane and methanol as solvents. A micro-TLC system with silica and a normal-phase solvent system (propan-2-ol–n-heptane–formic acid) was used for the chemometric analysis of 12 selected basil methanolic extracts. Some indices of similarity (Pearson's correlation coefficient, determination coefficient, congruence coefficient, and Euclidean, Manhattan (city-block), Chebyshev, and Hausdorff distances) were calculated on the basis of thin-layer chromatograms using ImageJ software. Principal component analysis was also performed. The method allowed the comparison of the analyzed extracts and confirmed the identities of two selected unknown plants.
The Thin-Layer Microchromatography (μTLC) and TLC–FID Technique as a New Methodology in the Study of Lubricating Oils
Authors: Nowak Paulina , Kosińska Judyta , Glinka Marta , Kamiński Marian 
Published: June 2017

Abstract
This paper concerns the possibility of using TLC coupled with a flame ionization detector (FID) and micro-TLC (μTLC) as precursors for microfluidized devices of analytical techniques to identify and determine the presence and content of the petroleum/vegetable oil base in the lubricating oils applied in cutting devices (chainsaws). This research is related to the problem of ensuring, in compliance with the requirements of environmental protection, a sufficient level of biodegradability of lubricating oils emitted to the environment during operation of equipment lubricated with these oils. Such oils include those mainly used in cutting devices and emitted in the form of a mist into the environment during the operation of those devices. When oil components are eco-toxic, contamination of the environment occurs. New methodologies for the identification and determination of the petroleum oil base, which is very difficult to biodegrade, as well as the easily biodegradable ingredients of vegetable origin in the lubricating oils, are presented. The described procedures indicate in an indisputable way whether the oil contains the oil base originating from crude oil and whether it contains adequate enriching additives. The procedures also allow the assessment of the content of particular groups of constituents (μTLC) or the determination of the group composition (TLC–FID).
Quantum Dots as Components of Electrochemical Sensing Platforms for the Detection of Environmental and Food Pollutants: a Review
Authors: Pedrero María , Campuzano Susana , Pingarrón José M 
Published: June 2017

Abstract
The determination of organic and inorganic environmental and food pollutants is a key matter of concern in analytical chemistry due to their effects as a serious threat to human health. Focusing on this issue, several methodologies involving the use of nanostructured electrochemical platforms have been recently reported in the literature. Among these methods, those employing the use of quantum dots (QDs) stand out because of features such as signal amplification, good reproducibility and selectivity, and the possibility for multiplexed detection, and because they preserve the outstanding characteristics of electrochemical methodologies with respect to simplicity, ease-of-use, and cost-effective instrumentation. This review describes recent electrochemical strategies, in which design QDs play a key role, for the determination of pollutants in food and environmental samples. The particular role of QDs in the reported methodologies, their preparation, and the electrochemical platform design, as well as the advantages that QDs provide in the analysis of target analytes, are critically discussed.
Advances in the Analysis of Water and Wastewater Samples Using Various Sensing Protocols and Microfluidic Devices Based on PAD and μTAS Systems
Authors: Piaskowski Krzysztof , Świderska-Dąbrowska Renata , Kaleniecka Aleksandra , Zarzycki Paweł K 
Published: June 2017

Abstract
The main goal of this review is to summarize practical approaches concerning the application of microfluidic systems for the analysis of various biomarkers and pollutants, as well as microbes, in water and wastewater matrixes. This problem involves multidisciplinary expertise combining research knowledge from various areas, including wet chemistry, biochemistry, physical chemistry, molecular biology, genetics, signal processing, microelectronics material science, and separation science. It has been documented that fairly primitive but fast and inexpensive screening methods involving paper-based analytical devices (PADs) and micro total analytical systems (μTAS) can be considered as serious alternatives to their more advanced counterparts such as GC, HPLC, and capillary electrophoresis coupled to various sophisticated detectors (e.g., multiwavelength spectrophotometers such as UV-Vis/DAD and mass spectrometers). The main advantage of PAD- and μTAS-driven technology is that such sensing devices may work under on-site and real-time conditions and measure a number of physical parameters and chemical factors simultaneously. Moreover, hybrid miniaturized analytical systems may combine sensing and data acquisition modules with common mobile phones and electronic devices working with global positioning systems and communicating through the Internet.
Critical Zone services as environmental assessment criteria in intensively managed landscapes
Authors: Richardson Meredith , Kumar Praveen 
Published: June 2017

AbstractThe Critical Zone (CZ) includes the biophysical processes occurring from the top of the vegetation canopy to the weathering zone below the groundwater table. CZ services provide a measure for the goods and benefits derived from CZ processes. In intensively managed landscapes, cropland is altered through anthropogenic energy inputs to derive more productivity, as agricultural products, than would be possible under natural conditions. However, the actual costs of alterations to CZ functions within landscape profiles are unknown. Through comparisons of corn feed and corn‐based ethanol, we show that valuation of these CZ services in monetary terms provides a more concrete tool for characterizing seemingly abstract environmental damages from agricultural production systems. Multiple models are combined to simulate the movement of nutrients throughout the soil system, enabling the measurement of agricultural anthropogenic impacts to the CZ's regulating services. Results indicate water quality and atmospheric stabilizing services, measured by soil carbon storage, carbon respiration, and nitrate leaching, among others, can cost more than double that of emissions estimated in previous studies. Energy efficiency in addition to environmental impact is assessed to demonstrate how the inclusion of CZ services is necessary in accounting for the entire life cycle of agricultural production systems. These results conclude that feed production systems are more energy efficient and less environmentally costly than corn‐based ethanol.
Occurrence rate of whistler waves in the magnetotail reconnection region
Authors: Huang S. Y. , Yuan Z. G. , Sahraoui F. , Fu H. S. , Pang Y. , Zhou M. , Fujimoto K. , Deng X. H. , Retinò A. , Wang D. D. , Yu X. D. , Li H. M. 
Published: June 2017

AbstractIt has long been suggested that whistler waves play an active role during magnetic reconnection. However, all previous observations were based on case studies and could not give a detailed picture as to where the whistler waves occur in the reconnection region. In this paper, a statistical study by using the Cluster data is performed to investigate the spatial distribution and the occurrence rate of whistler waves in the magnetotail reconnection region. It is found that the occurrence rate of the whistler waves is large in the separatrix region (|Bx/B0| > 0.4) and in the pileup region (|Bx/B0| < 0.2, |θ| > 45°, where θ = arctan(Bz/Bx)), but is very small in the vicinity of the X‐line. These statistical results are well consistent with recent kinetic simulations and with previous observational case studies.
Black Sea thermohaline properties: Long‐term trends and variations
Authors: Miladinova S. , Stips A. , Garcia‐Gorriz E. , Macias Moy D. 
Published: June 2017

AbstractThe current knowledge about spatial and temporal dynamics of the Black Sea's thermohaline structure is incomplete because of missing data and sparse distribution of existing measurements in space and time. This study presents 56 year continuous simulations of the Black Sea's hydrodynamics using the 3D General Estuarine Transport Model (GETM), without incorporating any relaxation toward climatological or observational data fields. This property of the model allows us to estimate independent temporal trends, in addition to resolving the spatial structure. The simulations suggest that the intermediate layer temperature is characterized by a weak positive trend (warming), whereas the surface temperature does not show a clear linear trend. Different salinity trends have been established at the surface (negative), upper (weaker negative) and main halocline (positive). Three distinct dynamic periods are identified (1960–1970, 1970–1995, 1995–2015), which exhibit pronounced changes in the Black Sea's thermohaline properties and basin circulation. Strengthening of the main cyclonic circulation, accompanied by intensification of the mesoscale anticyclonic eddy formation is found. Both events strongly affect the sea surface salinity but contribute in opposing directions. Specifically, strong composite large‐scale circulation leads to an increase in sea surface salinity, while enhanced formation of mesoscale anticyclones decreases it. Salinity evolution with time is thus the result of the competition of these two opposing yet interdependent processes.
Congo Basin precipitation: Assessing seasonality, regional interactions, and sources of moisture
Authors: Dyer Ellen L. E. , Jones Dylan B. A. , Nusbaumer Jesse , Li Harry , Collins Owen , Vettoretti Guido , Noone David 
Published: June 2017

AbstractPrecipitation in the Congo Basin was examined using a version of the National Center for Atmospheric Research Community Earth System Model (CESM) with water tagging capability. Using regionally defined water tracers, or tags, the moisture contribution from different source regions to Congo Basin precipitation was investigated. We found that the Indian Ocean and evaporation from the Congo Basin were the dominant moisture sources and that the Atlantic Ocean was a comparatively small source of moisture. In both rainy seasons the southwestern Indian Ocean contributed about 21% of the moisture, while the recycling ratio for moisture from the Congo Basin was about 25%. Near the surface, a great deal of moisture is transported from the Atlantic into the Congo Basin, but much of this moisture is recirculated back over the Atlantic in the lower troposphere. Although the southwestern Indian Ocean is a major source of Indian Ocean moisture, it is not associated with the bulk of the variability in precipitation over the Congo Basin. In wet years, more of the precipitation in the Congo Basin is derived from Indian Ocean moisture, but the spatial distribution of the dominant sources is shifted, reflecting changes in the midtropospheric circulation over the Indian Ocean. During wet years there is increased transport of moisture from the equatorial and eastern Indian Ocean. Our results suggest that reliably capturing the linkages between the large‐scale circulation patterns over the Indian Ocean and the local circulation over the Congo Basin is critical for future projections of Congo Basin precipitation.
Propagation and arrest of dikes under topography: Models applied to the 2014 Bardarbunga (Iceland) rifting event
Authors: Urbani S. , Acocella V. , Rivalta E. , Corbi F. 
Published: June 2017

AbstractDikes along rift zones propagate laterally downslope for tens of kilometers, often becoming arrested before topographic reliefs. We use analogue and numerical models to test the conditions controlling the lateral propagation and arrest of dikes, exploring the presence of a slope in connection with buoyancy and rigidity layering. A gentle downslope assists lateral propagation when combined with an effective barrier to magma ascent, e.g., gelatin stiffness contrasts, while antibuoyancy alone may be insufficient to prevent upward propagation. We also observe that experimental dikes become arrested when reaching a plain before opposite reliefs. Our numerical models show that below the plain the stress field induced by topography hinders further dike propagation. We suggest that lateral dike propagation requires an efficient barrier (rigidity) to upward propagation, assisting antibuoyancy, and a lateral pressure gradient perpendicular to the least compressive stress axis, while dike arrest may be induced by external reliefs.
Unprecedented springtime retreat of Antarctic sea ice in 2016
Authors: Turner John , Phillips Tony , Marshall Gareth J. , Hosking J. Scott , Pope James O. , Bracegirdle Thomas J. , Deb Pranab 
Published: June 2017

AbstractDuring austral spring 2016 Antarctic sea ice extent (SIE) decreased at a record rate of 75 × 103 km2 d−1, which was 46% faster than the mean rate and 18% faster than in any previous spring season during the satellite era. The decrease of sea ice area was also exceptional and 28% greater than the mean. Anomalous negative retreat occurred in all sectors of the Antarctic but was greatest in the Weddell and Ross Seas. Record negative SIE anomalies for the day of year were recorded from 3 November 2016 to 9 April 2017. Rapid ice retreat in the Weddell Sea took place in strong northerly flow after an early maximum ice extent in late August. Rapid ice retreat occurred in November in the Ross Sea when surface pressure was at a record high level, with the Southern Annular Mode at its most negative for that month since 1968.
Quantifying black carbon deposition over the Greenland ice sheet from forest fires in Canada
Authors: Thomas J. L. , Polashenski C. M. , Soja A. J. , Marelle L. , Casey K. A. , Choi H. D. , Raut J.‐C. , Wiedinmyer C. , Emmons L. K. , Fast J. D. , Pelon J. , Law K. S. , Flanner M. G. , Dibb J. E. 
Published: June 2017

AbstractBlack carbon (BC) concentrations observed in 22 snowpits sampled in the northwest sector of the Greenland ice sheet in April 2014 have allowed us to identify a strong and widespread BC aerosol deposition event, which was dated to have accumulated in the pits from two snow storms between 27 July and 2 August 2013. This event comprises a significant portion (57% on average across all pits) of total BC deposition over 10 months (July 2013 to April 2014). Here we link this deposition event to forest fires burning in Canada during summer 2013 using modeling and remote sensing tools. Aerosols were detected by both the Cloud‐Aerosol Lidar with Orthogonal Polarization (on board CALIPSO) and Moderate Resolution Imaging Spectroradiometer (Aqua) instruments during transport between Canada and Greenland. We use high‐resolution regional chemical transport modeling (WRF‐Chem) combined with high‐resolution fire emissions (FINNv1.5) to study aerosol emissions, transport, and deposition during this event. The model captures the timing of the BC deposition event and shows that fires in Canada were the main source of deposited BC. However, the model underpredicts BC deposition compared to measurements at all sites by a factor of 2–100. Underprediction of modeled BC deposition originates from uncertainties in fire emissions and model treatment of wet removal of aerosols. Improvements in model descriptions of precipitation scavenging and emissions from wildfires are needed to correctly predict deposition, which is critical for determining the climate impacts of aerosols that originate from fires.
Solute mixing regulates heterogeneity of mineral precipitation in porous media
Authors: Cil Mehmet B. , Xie Minwei , Packman Aaron I. , Buscarnera Giuseppe 
Published: June 2017

AbstractSynchrotron X‐ray microtomography was used to track the spatiotemporal evolution of mineral precipitation and the consequent alteration of the pore structure. Column experiments were conducted by injecting CaCl2 and NaHCO3 solutions into granular porous media either as a premixed supersaturated solution (external mixing) or as separate solutions that mixed within the specimen (internal mixing). The two mixing modes produced distinct mineral growth patterns. While internal mixing promoted transverse heterogeneity with precipitation at the mixing zone, external mixing favored relatively homogeneous precipitation along the flow direction. The impact of precipitation on pore water flow and permeability was assessed via 3‐D flow simulations, which indicated anisotropic permeability evolution for both mixing modes. Under both mixing modes, precipitation decreased the median pore size and increased the skewness of the pore size distribution. Such similar pore‐scale evolution patterns suggest that the clogging of individual pores depends primarily on local supersaturation state and pore geometry.
Statistical study of particle acceleration in the core of foreshock transients
Authors: Liu Terry Z. , Angelopoulos Vassilis , Hietala Heli , Wilson III Lynn B. 
Published: June 2017

AbstractSeveral types of foreshock transients upstream of Earth's bow shock possessing a tenuous, hot core have been observed and simulated. Because of the low dynamic pressure in their cores, these phenomena can significantly disturb the bow shock and the magnetosphere‐ionosphere system. Recent observations have also demonstrated that foreshock transients can accelerate particles which, when transported earthward, can affect space weather. Understanding the potential of foreshock transients to accelerate particles can help us understand shock acceleration at Earth and at other planetary and astrophysical systems. To further investigate foreshock transients' potential for acceleration, we conduct a statistical study of ion and electron energization in the core of foreshock transients. We find that electron energies typically increase there, evidently due to an internal acceleration process, whereas, as expected, ion energies most often decrease to support transient formation and expansion. Nevertheless, ion energy enhancements can be seen in some events suggesting an internal ion acceleration process as well. Formation conditions of foreshock transients are related to weak solar wind magnetic field strength and fast solar wind speed. Ion and electron energization are also positively correlated with solar wind speed.
Efficiency of coseismic ionospheric perturbations in identifying crustal deformation pattern: Case study based on Mw 7.3 May Nepal 2015 earthquake
Authors: Bagiya Mala S. , Sunil A. S. , Sunil P. S. , Sreejith K. M. , Rolland Lucie , Ramesh D. S. 
Published: June 2017

AbstractThe amplitude asymmetry and initial polarity of seismic induced ionospheric perturbations around the epicenter are considered to be important in providing information about the rupture propagation and related vertical surface deformation. To comprehend this, we study ionospheric perturbations related to the 12 May 2015, Mw 7.3 Nepal earthquake. We model the coseismic slip associated with the event using the interferometric synthetic aperture radar derived surface deformation data. The ionospheric perturbations associated with the obtained surface deformation are explained in terms of rupture propagation, favorable geomagnetic field‐wave coupling, and satellite geometry effects. We discuss the effects of phase cancelation on the perturbation evolution for various receiver satellite line‐of‐sight configurations invoking an elementary version of satellite geometry factor. The present study thus elucidates further the role of nontectonic forcing mechanisms while identifying ground source pattern using the associated ionospheric perturbations.
Electron temperature anisotropy associated to field‐aligned currents in the Earth's magnetosphere inferred from Rosetta MIP‐RPC observations during 2009 flyby
Authors: Béghin C. , Hamelin M. , Lebreton J. P. , Vallieres X. , Moré J. , Henri P. 
Published: June 2017

AbstractA new approach is proposed for data interpretation of the Mutual Impedance Probe (MIP) instrument from the Rosetta Plasma Consortium (RPC) during the 2009 Earth's flyby gravity assist through the magnetosphere, from dusk to dawn regions. The spacecraft trajectory of ±8 RE (Earth's radius) was crossing several structures of field‐aligned currents (FACs) and radiations belts on both legs of the closest approach (CA, 2.450 km altitude). As routinely revealed by several pioneering space missions, natural and forced electrostatic wave emissions called Fqs were observed over ±3 RE at around CA using a dedicated mode of the MIP instrument. These emissions are lying between consecutive harmonics of the electron‐cyclotron frequency, and their wavelength is perpendicular to the magnetic field lines. Provided that the Fq's wavelengths projected along the MIP antenna might be estimated, it is shown that the local value of the Larmor radius can be deduced; hence, the electron temperature component perpendicular to the magnetic field is subsequently derived. On the other hand, during the time of Fq's observations, the presence of VLF hiss emissions usually observed in these regions gives us the possibility to determine the electron temperature anisotropy associated to the electrostatic electron anisotropy instability according to the theoretical model proposed by Gary and Cairns (JGR, vol. 104, 1999). Significant dynamic constraints revealed by crossing successive series of FACs tubes are shown being controlled by this anisotropy, and the fact that the magnetic pressure is significantly larger than the thermal pressure suggests that the FACs lobes are nonforce free.
Midnight flash model of energetic neutral atom periodicities at Saturn
Authors: Carbary J. F. , Mitchell D. G. 
Published: June 2017

AbstractThe Ion Neutral Camera on the Cassini spacecraft made images of energetic H atoms (25–55 keV) over a 3 day span in 2017. The images were projected onto the equatorial plane of Saturn, and a keogram was made by interpolating the projections in local time at 9 RS (1 RS = 60268 km). The keogram intensities show strong periodicities near the 10.79 h period of Saturn's energetic particles and exhibit a slope commensurate with corotation at that period. These periodic fluxes intensify near midnight but are weaker near noon. A “midnight flash” model can explain this behavior in terms of a searchlight rotating at 10.79 h that intensifies in the midnight sector. The model can also describe similar activity in Saturn's kilometric radiation and magnetic fields, although the “flash” must be shifted to the dawn‐to‐noon sector.