bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: GENESIS, BONDING MODE AND REACTION WITH CARBON MONOXIDE OF AN OXYMETHYLENE UNIT BRIDGING TWO METAL ATOMS
Authors: GAMBAROTTA S. , FLORIANI C. , CHIESI‐VILLA A. , GUASTINI C. 
Published: May 2016

AbstractDas Hydridochlorozirconocen ( l) absorbiert unter "Lichtausschluß 0.5 Mol CO/Zr unter Bildung des u‐Oxymethylen‐Zweikernkomplexes (II).
ChemInform Abstract: COFACIAL ASSEMBLY OF PARTIALLY OXIDIZED METALLAMACROCYCLES AS AN APPROACH TO CONTROLLING LATTICE ARCHITECTURE IN LOW‐DIMENSIONAL MOLECULAR SOLIDS. CHEMICAL, STRUCTURAL, OXIDATION STATE, TRANSPORT, MAGNETIC, AND OPTICAL PROPERTIES OF HALOGEN‐DOPED (M(PHTHALOCYANINATO)O)N MACROMOLECULES, WHERE M = SI, GE, AND SN
Authors: DIEL B. N. , INABE T. , LYDING J. W. , SCHOCH K. F. JUN. , KANNEWURF C. R. , MARKS T. J. 
Published: May 2016

AbstractDie Oxidation der Titelpolymeren mit Halogenen speziell mit Iod wird mittels chemischer und physikochemischer Methoden (Raman, IR‐, Elektronen‐, 13C‐NMR‐ und EPR‐Spektren, magnetische Suszeptibilitäten, Leitfähigkeitsmessungen) untersucht.
ChemInform Abstract: ASYMMETRIC SYNTHESIS OF (+)‐2,2,3‐TRIMETHYLHEX‐4‐ENAL VIA NUCLEOPHILIC ATTACK ON η3‐1,3‐DIMETHYLALLYL COMPLEXES OF MOLYBDENUM
Authors: FALLER J. W. , CHAO K.‐H. 
Published: May 2016

AbstractDer nucleophile Angriff auf Gemische von endo‐ und exo‐Isomeren der wie aufgezeichnet synthetisierten Mo‐Komplexe (III) ist ein einfacher Syntheseweg für optisch reine Allyl‐substituierte Olefine.
ChemInform Abstract: PREPARATION AND REACTIVITY OF A DIMERIC RUTHENIUM μ‐METHYLENE COMPLEX WITH NO METAL‐METAL BOND: CRYSTAL AND MOLECULAR STRUCTURE OF ((η5‐C5H5)RU(CO)2)2(μ‐CH2)
Authors: LIN Y. C. , CALABRESE J. C. , WREFORD S. S. 
Published: May 2016

AbstractDer bei ‐35°C stabile p‐Methylen‐Titelkomplex (II), der wie aufgezeichnet synthetisiert wird (keine AusbnAngabe), besitzt eine große Reaktivität. Seine Struktur wird durch Röntgenanalyse bestimmt und durch Elementaranalyse, 1H‐ sowie 13C‐NMR‐ spektroskopische Daten bestätigt.
ChemInform Abstract: PHOSPHINE LIGANDS FOR THE CONSTRUCTION OF POLYNUCLEAR COMPLEXES. I. BIS(DIPHENYLPHOSPHINOMETHYL)PHENYLPHOSPHINE COMPLEXES OF PALLADIUM(II) AND RHODIUM(I)
Authors: GUIMERANS R. R. , OLMSTEAD M. M. , BALCH A. L. 
Published: May 2016

AbstractDer Titelligand bildet bei der Umsetzung mit Dichloro‐bis‐[benzonitril]‐Pd in Methylenchlorid bzw. mit Chlorodicarbonyl‐Rh‐Dimeren in Methylenchlorid/Methanol den vierfach‐koordinierten, monomeren Komplex (I) mit zweizähnig gebundenem Triphosphin bzw. den kationischen Dreikernkomplex (II) mit zwei dreizähnig gebundenen Triphosphinen.
ChemInform Abstract: CLUSTER SYNTHESIS. 1. THE USE OF SULFIDO LIGANDS IN THE SYNTHESIS OF HIGH NUCLEARITY TRANSITION METAL CLUSTER COMPOUNDS. THE SYNTHESIS AND CRYSTAL AND MOLECULAR STRUCTURES OF OS6(CO)17(μ4‐S)2 AND OS6(CO)16(μ4‐S)(μ3‐S)
Authors: ADAMS R. D. , HORVATH I. T. , YANG L.‐W. 
Published: May 2016

AbstractDer pentagonal‐bipyramidale Hexaosmiumcluster (III) wird durch Umsetzung der beiden Triosmiumcluster (1) und (II) gebildet.
ChemInform Abstract: PHOTOCHEMICAL SYNTHESIS OF OLEFIN‐CARBONYLOSMIUM COMPLEXES: SERENDIPITOUS FORMATION OF A 1,2‐DIOSMACYCLOBUTANE DERIVATIVE
Authors: BURKE M. R. , TAKATS J. , GREVELS F.‐W. , REUVERS J. G. A. 
Published: May 2016

AbstractDie Bestrahlung des Os‐Carbonyls (I) in Gegenwart eines großen Überschusses des Olefins (II) führt zu einer Mischung von zwei Verbindungen.
ChemInform Abstract: INTERCONVERSION OF METHYLENE AND KETENE LIGANDS ON A TRIOSMIUM CLUSTER. CRYSTAL AND MOLECULAR STRUCTURE OF THE KETENE COMPLEX DODECACARBONYL(η2(C,C),μ‐KETENE)TRIOSMIUM, (OS3(CO)12(η2(C,C),μ‐CH2CO))
Authors: MORRISON E. D. , STEINMETZ G. R. , GEOFFROY G. L. , FULTZ W. C. , RHEINGOLD A. L. 
Published: May 2016

AbstractDer methylenverbrückte Triosmium‐Komplex (I) addiert zwei CO‐Moleküle unter Bildung des neuen Keten‐Komplexes (11).
ChemInform Abstract: THERMAL SIGMATROPIC REARRANGEMENTS OF VINYLALLENES LEADING TO 11‐CIS‐RETINOIDS AND THE NOVEL PROPERTIES OF 9‐CIS,11‐CIS,13‐CIS‐RETINAL AND 11‐CIS,13‐CIS‐RETINAL
Authors: KNUDSEN C. G. , CHANDRARATNA R. A. S. , WALKEAPAEAE L. P. + , CHAUHAN Y. S. , CAREY S. C. , COOPER T. M. , BIRGE R. R. , OKAMURA W. H. 
Published: May 2016

AbstractDas aus der Cuprat‐Spezies (IV) und der Verbindung (I) [‐+ (Va)] nach Behandlung v.on (Va) mit Tetrabutylammoniumfluorid/THF zugängliche Vinylallen (Vb) liefert bei der Thermolyse ein Gemisch der isomerenRetinoide(VIa) + (VIb) + (VIIa) sowie infolge Weiterreaktion des instabilen vierten Isomeren (VIIb) die tricyclische Verbindung (VIII).
ChemInform Abstract: CHROMOPEPTIDES FROM PHYCOERYTHRINS. STRUCTURE AND LINKAGE OF A PHYCOERYTHROBILIN TRYPTIC TRIPEPTIDE DERIVED FROM A B‐PHYCOERYTHRIN
Authors: SCHOENLEBER R. W. , LEUNG S.‐L. , LUNDELL D. J. , GLAZER A. N. , RAPOPORT H. 
Published: May 2016

AbstractDurch enzymatischen Abbau von B‐Phycoerythrin (aus Porphyridium cruentum) mit Trypsin wird das og‐B‐Phycoerythrobilitripeptid (I) ‐ das kleinste der Trypsin‐Fragmente aus der α‐Untereinheit von B‐Phycoerythrin ‐ erhalten, das eingehend 1H‐NMR‐analytisch untersucht wird.
ChemInform Abstract: NEW 17‐SPIROSTEROIDS. III. SYNTHESIS OF STEROID‐17‐SPIRO‐5′‐(1′,2′,3′‐OXATHIAZOLIDINE) 2′‐OXIDES
Authors: SOLYOM S. , SZILAGYI K. , TOLDY L. 
Published: May 2016

AbstractAus den Steroiden (I)‐(IV) werden unter Einsatz der Reagenzien (V), (VIII) bzw. (XI) die Steroid‐Spirooxathiazolidin‐S‐oxide (VI), (VII) (29% exo‐ I54 Diastereomeres +67% Diastereomerengemisch), (IX), (X) (Ausb.‐Angabe in g) bzw. (XII) dargestellt.
ChemInform Abstract: THE PICTET‐SPENGLER REACTION IN CARBOHYDRATE CHEMISTRY. REACTIONS OF SUGARS WITH BIOGENIC AMINES
Authors: MACLEAN D. B. , SZAREK W. A. , KVARNSTROEM I. + 
Published: May 2016

AbstractD‐Glucose (II) und die aus dem Amin (IV) zugängliche 2,5‐Anhydro‐D‐mannose reagieren mit Dopaminhydrochlorid (I) zu den Verbindungen (III) und (V).
ChemInform Abstract: Oxocompostelline and Oxocularine, Structure and Synthesis.
Authors: BOENTE J. M. , CASTEDO L. , DE LERA A. R. , SAA J. M. , VIDAL M. C. 
Published: May 2016

AbstractDas aus (Ia) durch saure Debenzylierung erhaltene Phenol (Ib) sowie die analoge Dimethyl‐Verbindung (Ic) werden mit Dimsyl‐Natrium zu Gemischen aus (II) und (III) cyelisiert.
ChemInform Abstract: DIMETHYLEICOSATRIENOIC ACIDS: INHIBITORS OF THE 5‐LIPOXYGENASE ENZYME
Authors: PERCHONOCK C. D. , FINKELSTEIN J. A. , UZINSKAS I. , GLEASON J. G. , SARAU H. M. , CIESLINSKI L. B. 
Published: May 2016

AbstractDas Phosphoniumsalz (I) wird mit mono‐geschütztem Dimethyl‐malondialdehyd (II) zu (III) kondensiert und durch weitere Wittigreaktion die Trien‐carbonsäure (IV) hergestellt.
ChemInform Abstract: STEREOCONTROLLED SYNTHESIS OF A CIS‐CARBAPENEM ANTIBIOTIC (‐)‐CARPETIMYCIN A
Authors: IIMORI T. , TAKAHASHI Y. , IZAWA T. , KOBAYASHI S. , OHNO M. 
Published: May 2016

AbstractDie Darstellung der Titelverbindung (lXc) erfolgt ausgehend vom Halbester (I); dieser wird über die angegebenen Stufen′ zum bicyclischen Ketoester (VII) umgesetzt, der durch Überführung ins Vinylphosphat nach bekannter Methode und durch nachfolgende Behandlung mit dem Silbersalz von E‐2‐Acetamido‐1‐mercapto‐ethen/DMF die Verbindung (VIII) liefert.
ChemInform Abstract: SYNTHESIS OF (2E,4E,6S,7R,10E,12E,14S,15R)‐6,7,14,15‐TETRAMETHYL‐8,16‐DIOXA‐2,4,10,12‐CYCLOHEXADECATETRAENE‐1,9‐DIONE. A MODEL SYSTEM FOR ELAIOPHYLIN
Authors: SUTTER M. A. , SEEBACH D. 
Published: May 2016

AbstractDie Titelverbindung (Ia), ein Modellsystem für das Antibioticum Elaiophylin (Ib), wird ausgehend von dem (R)‐(‐)‐Hydroxy‐buttersäureester (II) über die angegebenen Stufen (z.T.
ChemInform Abstract: ENANTIOSELECTIVE SYNTHESIS OF THE CARBOCYCLIC NUCLEOSIDES (‐)‐ARISTEROMYCIN AND (‐)‐NEPLANOCIN A BY A CHEMICOENZYMATIC APPROACH
Authors: ARITA M. , ADACHI K. , ITO Y. , SAWAI H. , OHNO M. 
Published: May 2016

Abstract1. Die Synthese von (‐)‐ Aristeromycin (I) geht vom Monoester (IIb) aus, der aus dem Diester (IIa) auf enzymatischem Weg zugänglich ist, und führt sukzessiv über die angegebenen Stufen zur Verbindung (Vc), die dann in einem (bekannten) 3stufigen Verfahren zu (I) umgesetzt wird.
ChemInform Abstract: NEW SYNTHESIS OF PENEMS VIA A REDUCTIVE CYCLIZATION REACTION OF OXALIMIDES WITH TRIALKYL PHOSPHITE
Authors: YOSHIDA A. , HAYASHI T. , TAKEDA N. , OIDA S. , OHKI E. 
Published: May 2016

AbstractAus dem β‐Lactam (I) erhält man durch Reaktion mit Triethylphosphit ein Gemisch des Cyclisierungsprodukts (II) und des Phosphorylids (III).
ChemInform Abstract: METHODS FOR THE SYNTHESES OF NITROGEN‐CONTAINING COMPOUNDS BY THE CARBONYLATION OF NITRO COMPOUNDS BY CARBON MONOXIDE
Authors: MANOV‐YUVENSKII V. I. , NEFEDOV B. K. 
Published: May 2016

AbstractReview: Aromatische Amine lassen sich durch Carbonylierung mit Kohlenmonoxid in Gegenwart von Palladium‐, Ruthenium‐, Rhodium‐, Eisencarbonyl‐ und Selenkatalysatoren zu Isocyanaten, Carbamaten, Azoverbindungen, Harnstoffen, Schiffschen Basen, Amiden, Imiden und Aminen umsetzen.
Stopping the Babylonian Confusion: An Updated Nomenclature for Process Analyzers in PAT Applications
Authors: Minnich Clemens , Hardy Sonja , Krämer Stefan 
Published: May 2016

AbstractThe different use of the classifiers inline, online, atline, and offline in the process analytical technology (PAT) and automation communities regularly induces unambiguity in communication. Therefore, the available definitions of the classifiers are summarized and merged. An updated nomenclature targeting the intended function of the analyzer rather than its features is suggested.
Prostate tumor DNA methylation is associated with cigarette smoking and adverse prostate cancer outcomes
Authors: Shui Irene M. , Wong Chao‐Jen , Zhao Shanshan , Kolb Suzanne , Ebot Ericka M. , Geybels Milan S. , Rubicz Rohina , Wright Jonathan L. , Lin Daniel W. , Klotzle Brandy , Bibikova Marina , Fan Jian‐Bing , Ostrander Elaine A. , Feng Ziding , Stanford Janet L. 
Published: May 2016

BACKGROUNDDNA methylation has been hypothesized as a mechanism for explaining the association between smoking and adverse prostate cancer (PCa) outcomes. This study was aimed at assessing whether smoking is associated with prostate tumor DNA methylation and whether these alterations may explain in part the association of smoking with PCa recurrence and mortality.METHODSA total of 523 men had radical prostatectomy as their primary treatment, detailed smoking history data, long‐term follow‐up for PCa outcomes, and tumor tissue profiled for DNA methylation. Ninety percent of the men also had matched tumor gene expression data. A methylome‐wide analysis was conducted to identify differentially methylated regions (DMRs) by smoking status. To select potential functionally relevant DMRs, their correlation with the messenger RNA (mRNA) expression of corresponding genes was evaluated. Finally, a smoking‐related methylation score based on the top‐ranked DMRs was created to assess its association with PCa outcomes.RESULTSForty DMRs were associated with smoking status, and 10 of these were strongly correlated with mRNA expression (aldehyde oxidase 1 [AOX1], claudin 5 [CLDN5], early B‐cell factor 1 [EBF1], homeobox A7 [HOXA7], lectin galactoside‐binding soluble 3 [LGALS3], microtubule‐associated protein τ [MAPT], protocadherin γ A [PCDHGA]/protocadherin γ B [PCDHGB], paraoxonase 3 [PON3], synaptonemal complex protein 2 like [SYCP2L], and zinc finger and SCAN domain containing 12 [ZSCAN12]). Men who were in the highest tertile for the smoking‐methylation score derived from these DMRs had a higher risk of recurrence (odds ratio [OR], 2.29; 95% confidence interval [CI], 1.42‐3.72) and lethal disease (OR, 4.21; 95% CI, 1.65‐11.78) in comparison with men in the lower 2 tertiles.CONCLUSIONSThis integrative molecular epidemiology study supports the hypothesis that smoking‐associated tumor DNA methylation changes may explain at least part of the association between smoking and adverse PCa outcomes. Future studies are warranted to confirm these findings and understand the implications for improving patient outcomes.Cancer2016;122:2168–77. ©2016 American Cancer Society.
Molecular Property Optimizations with Boundary Conditions through the Best First Search Scheme
Authors: De Vleeschouwer Freija , Geerlings Paul , De Proft Frank 
Published: May 2016

AbstractThe front cover artwork is provided by the General Chemistry group of the Free University of Brussels. The image shows how information gathered from single‐property optimizations can be exploited to effectively, efficiently, and rationally design novel compounds with multiple desired properties, especially when constraints are applicable. Read the full text of the Concept at 10.1002/cphc.201501189.
Catalytic Transfer Hydrogenation of Furfural to Furfuryl Alcohol over Nitrogen‐Doped Carbon‐Supported Iron Catalysts
Authors: Li Jiang , Liu Jun‐ling , Zhou Hong‐jun , Fu Yao 
Published: May 2016

AbstractIron‐based heterogeneous catalysts, which were generally prepared by pyrolysis of iron complexes on supports at elevated temperature, were found to be capable of catalyzing the transfer hydrogenation of furfural (FF) to furfuryl alcohol (FFA). The effects of metal precursor, nitrogen precursor, pyrolysis temperature, and support on catalytic performance were examined thoroughly, and a comprehensive study of the reaction parameters was also performed. The highest selectivity of FFA reached 83.0 % with a FF conversion of 91.6 % under the optimal reaction condition. Catalyst characterization suggested that iron cations coordinated by pyridinic nitrogen functionalities were responsible for the enhanced catalytic activity. The iron catalyst could be recycled without significant loss of catalytic activity for five runs, and the destruction of the nitrogen–iron species, the presence of crystallized Fe2O3 phase, and the pore structure change were the main reasons for catalyst deactivation.
Factorization of 3‐Point Static Structure Functions in 3D Yukawa Liquids
Authors: Magyar P. , Hartmann P. , Kalman G.J. , Golden K. I. , Donkó Z. 
Published: May 2016

AbstractIn many‐body systems the convolution approximation states that the 3‐point static structure function, S(3)(k1, k2), can approximately be “factorized” in terms of the 2‐point counterpart, S(2)(k1). We investigate the validity of this approximation in 3‐dimensional strongly‐coupled Yukawa liquids: the factorization is tested for specific arrangements of the wave vectors k1 and k2, with molecular dynamics simulations. With the increase of the coupling parameter we find a breakdown of factorization, of which a notable example is the appearance of negative values of S(3)(k1, k2), whereas the approximate factorized form is restricted to positive values. These negative values – based on the quadratic Fluctuation‐Dissipation Theorem – imply that the quadratic part of the density response of the system changes sign with wave number. Our simulations that incorporate an external potential energy perturbation clearly confirm this behavior. (© 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Usage of Ray Tracing Transfer Matrix to Mitigate the Stray Light for ITER Spectroscopy
Authors: Kajita S. , Veshchev E. , Barnsley R. , Walsh M. 
Published: May 2016

AbstractStray light formed by the reflection of photons on inner wall from a bright divertor region can be a serious issue in spectroscopic measurement systems in ITER. In this study, we propose a method to mitigate the influence of stray light using a ray tracing analysis. Usually, a ray tracing simulation requires a time consuming runs. We constructed transfer matrices based on the ray tracing simulation results and used them to demonstrate the influence of stray light. It is shown that the transfer matrix can be used to reconstruct the emission profile by considering the influence of the stray light without any additional ray tracing runs. Mitigation of the stray light in ITER divertor impurity monitor was demonstrated, and a method of prediction of the stray light level for the scrape off layer spectroscopy from divertor region was proposed. (© 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Fire management strategies to maintain species population processes in a fragmented landscape of fire‐interval extremes
Authors: Tulloch Ayesha I. T. , Pichancourt Jean‐Baptiste , Gosper Carl R. , Sanders Angela , Chadès Iadine 
Published: May 2016

AbstractChanged fire regimes have led to declines of fire‐regime‐adapted species and loss of biodiversity globally. Fire affects population processes of growth, reproduction, and dispersal in different ways, but there is little guidance about the best fire regime(s) to maintain species population processes in fire‐prone ecosystems. We use a process‐based approach to determine the best range of fire intervals for keystone plant species in a highly modified Mediterranean ecosystem in southwestern Australia where current fire regimes vary. In highly fragmented areas, fires are few due to limited ignitions and active suppression of wildfire on private land, while in highly connected protected areas fires are frequent and extensive. Using matrix population models, we predict population growth of seven Banksia species under different environmental conditions and patch connectivity, and evaluate the sensitivity of species survival to different fire management strategies and burning intervals. We discover that contrasting, complementary patterns of species life‐histories with time since fire result in no single best fire regime. All strategies result in the local patch extinction of at least one species. A small number of burning strategies secure complementary species sets depending on connectivity and post‐fire growing conditions. A strategy of no fire always leads to fewer species persisting than prescribed fire or random wildfire, while too‐frequent or too‐rare burning regimes lead to the possible local extinction of all species. In low landscape connectivity, we find a smaller range of suitable fire intervals, and strategies of prescribed or random burning result in a lower number of species with positive growth rates after 100 years on average compared with burning high connectivity patches. Prescribed fire may reduce or increase extinction risk when applied in combination with wildfire depending on patch connectivity. Poor growing conditions result in a significantly reduced number of species exhibiting positive growth rates after 100 years of management. By exploring the consequences of managing fire, we are able to identify which species are likely to disappear under a given fire regime. Identifying the appropriate complementarity of fire intervals, and their species‐specific as well as community‐level consequences, is crucial to reduce local extinctions of species in fragmented fire‐prone landscapes.
Influence of oil type on formation, structure, thermal, and physical properties of monoglyceride‐based organogel
Authors: Valoppi Fabio , Calligaris Sonia , Barba Luisa , Šegatin Nataša , Poklar Ulrih Nataša , Nicoli Maria Cristina 
Published: May 2016

This research studied the possible relation between oil properties and structure and physical properties of saturated monoglyceride (MG)‐based organogels. To this aim different oils (castor, cod liver, corn, extra virgin olive, flax‐seed, peanut and sunflower oil, and mixture of medium chain triacylglycerols (MCT)) were used to prepare organogels by adding 10% w/w of monoglycerides. The fatty acid composition, viscosity, and dielectric properties of oils were measured. Then, organogels were characterized for crystallization induction time, dielectric properties, firmness, rheological behavior, thermal properties, crystal morphology by polarized light microscopy, and crystal polymorphism by synchrotron X‐ray diffraction (XRD) analysis.Results acquired showed that the addition of MG in different types of oils led to the formation of organogels with different properties. In all cases, β polymorph formed in the system irrespective of oil type. Regarding oils containing long chain fatty acids, gel firmness, and other structural parameters correlated well with the dielectric constant and/or viscosity of oils: increasing oil viscosity or decreasing oil dielectric constant, firmness and rheological parameters linearly increased. On the other hand, these correlations cannot be found including in the statistical analysis castor oil or MCT, probably due to the higher ability of these oils to make dipole–dipole rotation as well as the higher solubility of MG in castor oil.Practical applications: Oil gelation (organogelation) is a relative novel strategy to convert liquid oils into structured systems that has attracted food scientists and industry managers looking for solutions to reduce saturated/trans fats, deliver bioactive molecules, and minimize oil migration in foods. Results acquired in this research highlight that the choice of oil to be structured by means of saturated monoglycerides could affect the final gel structure. These findings could be useful in the attempt to applied organogels in different food products having different physical properties.This research studies the effect of oil properties on structure and physical properties of saturated monoglyceride‐based organogels. Results show that only the dielectric constant and/or viscosity of long chain fatty acid oils correlated well with gel firmness and other structural parameters.
Distribution of glucosinolates in camelina seed fractions by HPLC‐ESI‐MS/MS
Authors: Yuan Deyun , Shim Youn Young , Shen Jianheng , Jadhav Pramodkumar D. , Meda Venkatesh , Reaney Martin J. T. 
Published: May 2016

High glucosinolate concentrations were detected and identified in camelina (Camelina sativa L. Crantz.) seed fractions using reversed phase high performance liquid chromatography‐electrospray ionization‐mass spectrometry (HPLC‐ESI‐MS) in multiple reaction monitoring mode. Total glucosinolate quantitation was performed using proton nuclear magnetic resonance spectrometry using N,N‐dimethylformamide as an internal standard. Individual glucosinolate concentrations were determined by analysis on extracted ion chromatograms generated by a MS detector. Distribution of glucosinolates in C. sativa seed fractions during pressing is reported.Practical applications: HPLC‐ESI‐MS and HPLC‐ESI‐MS/MS using monolithic HPLC columns were used to detect, quantify, and identify the three major glucosinolates in Camelina sativa L. and fractions of C. sativa produced by processing. Quantitative extracted ion MS chromatograms afforded excellent quantitation of individual glucosinolates. The use of monolithic HPLC columns enabled rapid analysis of these samples.Schematic of a proposed dehulling system for Camelina sativa seed.