bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Titanium(0)‐Arene Complexes: Synthesis and X‐Ray Crystal Structure of ((η6‐C10H8)Ti(tBuSi(CH2PMe2)3)).
Authors: GARDNER T. G. , GIROLAMI G. S. 
Published: May 2016

AbstractAn unusually strong metal‐arene back‐bonding characterizes the bonding in the title complex (III).
ChemInform Abstract: Comparative Reactivities of Anionic Group 6 Alkyl, Silyl, and Stannyl Pentacarbonyl Metalates Toward Carbon Dioxide and Sulfur Dioxide. Crystal Structure of (PPN) (W(CO)5Si(CH3)3).
Authors: DARENSBOURG D. J. , BAUCH C. G. , REIBENSPIES J. H. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe silyl and stannyl pentacarbonylmetalates (III) are synthesized as shown for the example (IIIa).
ChemInform Abstract: Modelling the Ammoxidation of Propylene to Acrylonitrile: The Conversion of an Allylimido(2‐) Ligand to an Allylideneamido(1‐) Ligand.
Authors: MAATTA E. A. , DU Y. 
Published: May 2016

AbstractThe allylimido‐W(VI) complex (IV) is obtained according to the scheme.
ChemInform Abstract: Reactivity of 2‐(2‐Hydroxyphenyl)benzothiazoline with the Oxotetrahalometalate(V) Complexes (MOX4)‐ (M: Tc, Re; X: Cl, Br). Synthesis and Characterization of New Oxo‐M(V) Complexes Containing 2‐(2‐Hydroxyphenyl)benzothiazole. Crystal Structure of Tetraphenylarsonium Oxotrichloro(2‐(2‐hydroxyphenyl)benzothiazolato)technetate(V).
Authors: DUATTI A. , MARCHI A. , ROSSI R. , MAGON L. , DEUTSCH E. , BERTOLASI V. , BELLUCCI F. 
Published: May 2016

AbstractThe benzothiazoline (III), the condensation product from (I) and (II), is converted into its oxidized form (IV) by interaction with the five‐coordinate tetrahalooxometalate(V) complexes (VI).
ChemInform Abstract: Ferric Ion Sequestering Agents. Part 19. Synthesis of N‐Alkyl‐3‐hydroxy‐2(1H)‐pyridinones and Coordination Complexes with Iron(III).
Authors: SCARROW R. C. , RAYMOND K. N. 
Published: May 2016

AbstractThe amidation of (I) followed by acid‐catalyzed rearrangements yields the pyridinone (IV), which crystallizes in P21/n with Z=4.
ChemInform Abstract: Binuclear Nickel(II) and Cobalt(II) Complexes of Sexadentate (N6) Phthalazine Ligands. Crystal and Molecular Structures of (μ‐1,4‐Bis((6‐methylpyridine‐2‐carboxaldimino)amino)phthalazine‐N4,N3,μ‐N# 1,μ‐N1A,N3A,N4A)(μ‐chloro)tetraaquodicobalt(II) Trichloride‐4.3‐Water, Co2C22H28Cl4N8O4·4.3 H2O, and (μ‐1,4‐Bis((6‐methylpyridine‐2‐carboxaldimino)amino)phthalazine‐N4,N3,μ‐N# 1,μ‐N1A,N3A,N4A)(μ‐chloro)tetraaquodinickel(II) Trichloride‐4.6‐Water, Ni2C22H28Cl4N8O4·4.6 H2O.
Authors: WEN T. , THOMPSON L. K. , LEE F. L. , GABE E. J. 
Published: May 2016

AbstractThe complexes (I) are prepared from the ligand and metal halogenides in MeOH at reflux temperature.
ChemInform Abstract: Displacement of Carbon‐Bonded Chloranilate from the (Pd(C‐CA)Cl2)2‐ Ion by Hydrochloric Acid.
Authors: JEONG W.‐Y. , HOLWERDA R. A. 
Published: May 2016

AbstractAs part of mechanistic studies of Pd‐C bond cleavage reactions, kinetic measurements on the protonolysis reaction of (I) with HCl (II) at 50 °C are carried out.
ChemInform Abstract: Oxidative Addition of Thiols to a Coordinatively Unsaturated Triplatinum Cluster Complex.
Authors: JENNINGS M. C. , PUDDEPHATT R. J. 
Published: May 2016

AbstractThe 1:1 molar reaction of the μ3‐CO‐bridged triplatinum cluster (I) with the thiols (II) results in the elimination of CO and formation of the μ3‐thiolate‐bridged derivatives (III).
ChemInform Abstract: Verrucarins and Roridins. Part 47. Synthesis of New Unnatural Macrocyclic Trichothecenes: 4‐Epiverrucarin A.
Authors: JEKER N. , TAMM C. 
Published: May 2016

AbstractVerrucarol (I) is converted to 4‐epiverrucarol (III) as shown.
ChemInform Abstract: Metal‐Ion‐Selective Exchange Resins by Matrix Imprint with Methacrylates.
Authors: KUCHEN W. , SCHRAM J. 
Published: May 2016

AbstractCu2+ ions can be removed from waste water selectively and down to levels below the limit of detection with ion‐exchange resins in which Cu(II) methacrylates have been used for their synthesis.
ChemInform Abstract: FTIR Matrix Isolation Study on Gaseous Calcium Dihalide Molecules.
Authors: RAMONDO F. , BENCIVENNI L. , NUNZIANTE CESARO S. , HILPERT K. 
Published: May 2016

AbstractFTIR spectra of CaF2, CaCl2, CaBr2, and CaI2 vapors (1100‐1700 K), trapped in argon and krypton matrices, are interpreted on the basis of polarizable ion model calculations.
ChemInform Abstract: Four Crystal Structures of Dehydrated Ag+ and Tl+ Exchanged Zeolite A, Ag12‐xTlx‐A, x = 2, 3, 4, and 5.
Authors: KIM D. S. , SONG S. H. , KIM Y. 
Published: May 2016

AbstractThe Ag+ and Tl+ ion exchanged zeolite A crystals are prepared in flowing streams of mixed AgNO3/TlNO3 aqueous solution, followed by dehydration at 350 °C and 2·10‐6 torr (2 d).
ChemInform Abstract: Diffusion Process in Crystalline and Vitreous Li0.75Th0.25F1.75 by NMR Investigations.
Authors: PULCINELLI S. H. , SENEGAS J. 
Published: May 2016

Abstract7Li and 19F NMR results obtained in the temp. range 273‐400 K show that there is no fluorine diffusion in crystalline Li3ThF7.
ChemInform Abstract: NMR Study of the Intermetallic Phase Li2Ga7.
Authors: TILLARD‐CHARBONNEL M. , BELIN C. , HERZOG‐CANCE M. H. 
Published: May 2016

Abstract7Li NMR lineshape and relaxation times are measured over the temp. range 133‐445 K. The spin‐lattice relaxation curves of the Li‐deficient compound Li2Ga7 exhibit two minima characteristic of low and high temp. motion modes for Li with activation energies of 0.11 and 0.27 eV, respectively.
ChemInform Abstract: An Ellipsometric and RRDE Study of Iron Passivation and Depassivation in Carbonate Buffer
Authors: SOUTHWORTH P. , HAMNETT A. , RILEY A. M. , SYKES J. M. 
Published: May 2016

Abstractat pH 9.2 shows the passive film to be a mixture of an inner Fe(II)‐rich region and an outer region containing primarily Fe(III).
ChemInform Abstract: An AC Impedance Study of the De‐Alloying of Fe‐Ni Alloys, and Its Relevance to Chloride SCC of Stainless Steels.
Authors: NEWMAN R. C. , MEHTA A. 
Published: May 2016

AbstractElectrochemical studies in chloride and sulfate solutions at pH 1 and 80 °C provide evidence for porous de‐alloyed layers in chloride solution but not in sulfate solution.
ChemInform Abstract: Iron ⇌ Calcium Ion Exchange Reaction in Cement Hydration Phase, 11 Å Tobermorite.
Authors: LABHASETWAR N. , SHRIVASTAVA O. P. 
Published: May 2016

AbstractTobermorite, a calcium silicate hydrate close to Ca5Si6O18H2·4 H2O, which is formed during the hydration reaction of cements, is shown to act as ion exchanger for iron.
ChemInform Abstract: Structure of A2(HgO2) (A: K, Rb), Rb2(NiO2), and Rb1,4K0.6(NiO2).
Authors: HOPPE R. , BAIER R. , CARL W. , GLAUM H. , UNTENECKER H. 
Published: May 2016

AbstractColorless or dichroitic single crystals of the title mercurates and niccolates are prepared as outlined in the scheme ((V), (VIII), and (XI) for the first time).
ChemInform Abstract: Electrochemical 1,2‐Addition of Trifluoromethyl and Acetamide Groups to Methyl Methacrylate.
Authors: UNEYAMA K. , NANBU H. 
Published: May 2016

AbstractElectrolysis of methyl methacrylate (I) with an excess of trifluoroacetic acid (II) and acetonitrile (III) results in the trifluoroalkylation and amination, producing polyfluoroacetamino acid esters (IV) and (V).
ChemInform Abstract: Stereochemistry of the Epoxidation of Z,E‐Isomeric 1,1‐Dimethoxy‐3‐hexen‐5‐ols and 1,1‐Dimethoxy‐4‐hexen‐3‐ols. Synthesis of 2,6‐Dideoxy‐D,L‐hexose Dimethyl Acetals.
Authors: RAIFEL'D YU. E. , ARSHAVA B. M. , ZIL'BERG L. L. , MAKIN S. M. 
Published: May 2016

AbstractThe stereochemistry of the epoxidation of the title compounds (I), (IV), (VII) and (X) is investigated.
ChemInform Abstract: Influence of Methoxy‐ and Methyl‐Aromatic Substituents on Stereochemistry of the Products in the Acid‐Catalyzed Cyclization of 2‐(2‐Arylethyl)‐1,3,3‐trimethylcyclohexanols: Stereocontrolled Total Synthesis of (.+‐.)‐Nimbidiol and (.+‐.)‐Nimbiol.
Authors: BANIK B. K. , GHOSH S. , GHATAK U. R. 
Published: May 2016

AbstractThe cyclization of the compounds (IIIa), (IIIb) affords, as known, exclusively the trans compounds (IVa), (IVb); (IVc) is now similarly prepared by the method A) from (IIIc), which in turn is accessible from the readily prepared ketone (I).
ChemInform Abstract: Effect of a Clay Support on the Catalytic Epoxidation Activity of a Manganese(III)‐Schiff Base Complex.
Authors: DIXIT P. S. , SRINIVASAN K. 
Published: May 2016

AbstractThe epoxidation of cyclohexene by tert.‐butyl hydroperoxide in the presence of Mn((salen)(H2O))PF6 is accompanied by a free‐radical allylic oxidation, induced by the homolytic decomposition of (II).
ChemInform Abstract: Reactions of Unsaturated Compounds with Iodine and Bromine on γ‐Alumina.
Authors: PAGNI R. M. , KABALKA G. W. , BOOTHE R. , GAETANO K. , STEWART L. J. , CONAWAY R. , DIAL C. , GRAY D. , LARSON S. , LUIDHARDT T. 
Published: May 2016

AbstractIodine or bromine on activated alumina are used for halogenation in the solid state.
ChemInform Abstract: 1,3‐Benzodithiole Tetroxide as a CH2‐ 2 Synthon.
Authors: KUENDIG E. P. + , CUNNINGHAM A. F. JUN. 
Published: May 2016

AbstractTwofold alkylation of the title compound (I) yields the disubstituted derivatives (VI), which undergo reductive ring‐opening to give the dialkylmethylenes (VII).
ChemInform Abstract: α,α‐Dichloroaldehydes and α,α‐Dichlorocarboxylic Acids from Long Chain 1‐Alkanols. Improved Chlorination in the System DMF‐CHCl3‐MgCl2.
Authors: DE BUYCK L. , CASAERT F. , DE LEPELEIRE C. , SCHAMP N. 
Published: May 2016

AbstractThe presence of MgCl2 prevents the formation of alkyl alkanoate side products in the title chlorination reaction of the alkanols (I).
ChemInform Abstract: Reduced Copper‐Catalyzed Conversion of a Mixture of Primary Alcohols and Secondary Alcohols into Esters and Ketones.
Authors: TAKESHITA K. , KAWAMOTO K. , SUGA T. 
Published: May 2016

AbstractA primary and a secondary alcohol, e.g. (I) and (II), are treated with a copper catalyst at higher temperatures, yielding a complex mixture of oxidation products.
ChemInform Abstract: Exceptional Reactivity of the Aromatic Ring in 8‐Substituted 1‐Naphthol Derivatives. Ready Reduction to Tetralins.
Authors: KIRBY A. J. , PERCY J. M. 
Published: May 2016

AbstractThe peri‐substituted derivative (V) can be prepared only in a poor yield from the methoxynaphthalene (I) via the lithio intermediate (IV).
ChemInform Abstract: Total Synthesis of Sesquiterpenes via Intramolecular Ketene Cycloadditions: Isocomene and α‐cis‐ and α‐trans‐Bergamotenes, an Approach to Seychellene.
Authors: SNIDER B. B. , BEAL R. B. 
Published: May 2016

AbstractThe acid chlorides (II) and (VIII), synthesized from the enones (I) and (VII), cyclize in the presence of a base, forming the cyclobutanones (III) and (IX).
ChemInform Abstract: Amino Derivatives of N,N′‐Di(salicylidene)‐o‐phenylenediamine.
Authors: MEN'SHIKOV S. YU. , KOLENKO I. P. , PETROV L. A. , KODESS M. I. 
Published: May 2016

AbstractA novel and convenient method of preparation of the title compounds (IV) is described.
ChemInform Abstract: Bismuth Trichloride as a New Efficient Catalyst in the Aldol Reaction.
Authors: OHKI H. , WADA M. , AKIBA K. 
Published: May 2016

AbstractThe silyl enol ethers (I) are coupled with the aldehydes (II) in the presence of BiCl3 to form the adducts (III) and (IV).
ChemInform Abstract: Strained Ketenes from α‐Bromoacyl Phosphates. (Tricyclo(4.4.1.01,6)undeca‐3,8‐dien‐11‐ylidene)methanone and Its Heptacyclic Dimer: A Dispirobridged Dipropellane (1,1′′,4,4′′,5,5′′,8,8′′‐Octahydrodispiro((4a,8a)methanonaphthalene‐9,1′‐cyclobutane‐3′,9′′‐(4a,8a)methanonaphthalene)‐2′,4′‐dione).
Authors: HOFFMANN H. M. R. , GESCHWINDER P. M. , HOLLWEGE H.‐P. , WALENTA A. 
Published: May 2016

AbstractThe reaction of the acids (I) and (IV) with phosphorochloridate (II) yields mixed anhydrides, which are dehalogenated to give ketene intermediates.
ChemInform Abstract: Fluoroindenes. Part 10. Cycloaddition of Difluorocarbene to Perfluoro‐3‐methylindene and Perfluoro‐1‐methyleneindan. Thermolysis and Bromination of the Cyclopropane Derivatives Formed.
Authors: CHUIKOV I. P. , KARPOV V. M. , PLATONOV V. E. , YAKOBSON G. G. 
Published: May 2016

AbstractThe perfluoromethylindene (I) and the perfluoromethyleneindan (VI) react with difluorocarbene, generated in situ from perfluoropropylene oxide (II), to give the cyclopropanes (III) and (VII).
ChemInform Abstract: A Novel Darzens‐Type Condensation Using α‐Chloro Ketimines.
Authors: SULMON P. , DE KIMPE N. , SCHAMP N. , DECLERCQ J.‐P. , TINANT B. 
Published: May 2016

AbstractThe lithium salts of the α‐chloro ketimines (I) combine with the carbonyl compounds (II) to yield the imidoyl epoxides (III).
ChemInform Abstract: Chemistry of Oxaziridines. Part 11. (Camphorylsulfonyl)oxaziridine, Synthesis and Properties.
Authors: DAVIS F. A. , TOWSON J. C. , WEISMILLER M. C. , LAL S. , CARROLL P. J. 
Published: May 2016

AbstractBoth stereoisomeric oxaziridines (+)‐(VI) (space group P212121 with Z=4) and its (‐)‐(2S,8aR) counterpart are synthesized from (+)‐(I) and (‐)‐camphorsulfonic acid, respectively.
ChemInform Abstract: Benzotriazoles. Part 15. The Preparation of 1‐(1‐Alkenyl)benzotriazoles.
Authors: KATRITZKY A. R. , OFFERMAN R. J. , CABILDO P. , SOLEIMAN M. 
Published: May 2016

AbstractTwo methods are described for the preparation of the title compounds such as (VII) or (XII).
ChemInform Abstract: Nucleophilic Thionation of Polyfluorinated β‐Dicarbonyl Compounds.
Authors: PASHKEVICH K. I. , SALOUTIN V. I. , BOBROV M. B. , YUFIT D. S. , STRUCHKOV YU. T. 
Published: May 2016

AbstractTreatment of the polyfluorinated β‐diketones (I) with P4S10 (II) in the presence of K2CO3 affords the Z‐configurated 2H‐thiopyrans (III).
ChemInform Abstract: 2,4,6‐Tris(dialkylamino)pyrylium Salts and Related Systems, Synthesis and Reaction Behaviour.
Authors: SCHROTH W. , SPITZNER R. , KLEINPETER E. 
Published: May 2016

AbstractTetrachlorodivinyl ketone (I) reacts with trimethylsilylamines (II) to give the monosubstitution products (III) which are treated with water or H2S (IV) to yield the (thio)amides (V).
ChemInform Abstract: Synthesis of Pyrimidines from Vinyl Chlorides and Nitriles by the Ritter Reaction.
Authors: BORODAEV S. V. , ZUBKOVA O. V. , LUK'YANOV S. M. 
Published: May 2016

AbstractIn the presence of CF3SO3H the vinylic chloroalkenes (I) react with nitriles, e.g. benzonitrile (II) or acetonitrile (IV) to afford the substituted pyrimidines (III) or (V).
ChemInform Abstract: Preparation of Hydrogenated Azepino(3,2,1‐hi)indoles.
Authors: KATAYAMA H. , MAEDA K. , KANEKO K. 
Published: May 2016

AbstractStarting with the tetrahydrobenzazepines (I), the hydrogenated azepino‐(3,2,1‐hi)indoles (VIII) and (IX) are prepared as outlined in the reaction scheme.
ChemInform Abstract: Noncataleptic Neuroleptic Agents: 2‐(4‐(2‐(2‐Chloro‐10,11‐dihydrodibenzo(b,f)thiepin‐10‐yloxy)ethyl)piperazine‐1‐yl)ethanol and Some Related Compounds.
Authors: JILEK J. , VALCHAR M. , HOLUBEK J. , DLOHOZKOVA N. , POMYKACEK J. , MATOUSOVA O. , METYSOVA J. , PROTIVA M. 
Published: May 2016

AbstractThe dibenzothiepin (I) is converted into various piperazinyl analogues such as (Va) and (Vb); esterification of the alcohol (Va) yields (Vc).
ChemInform Abstract: Silicon Compounds with Strong Intramolecular Sterical Interactions. Part 23. Cycloaddition of a Silylene and a Disilene to 2,2′‐Bipyridyl.
Authors: WEIDENBRUCH M. , SCHAEFER A. + , MARSMANN H. 
Published: May 2016

AbstractHexa(tert‐butyl)cyclotrisilane (I) is photolyzed in the presence of 2,2'‐bipyridyl (II) to give the cycloadduct (III), the structure of which is determined by NMR spectroscopy.
ChemInform Abstract: Lewis Base Properties of 1,3‐Diphosphadithiatetrazocines: Crystal and Molecular Structures of 1,3‐Ph4P2N4S2Me+CF3SO‐ 3.
Authors: CHIVERS T. , LIBLONG S. W. , RICHARDSON J. F. , ZIEGLER T. 
Published: May 2016

AbstractThe behavior of the diphosphadithiatetrazocine (I) toward Lewis and Bronsted acids is investigated.
ChemInform Abstract: Trimethylgermylation and Trimethylsilylation of N,N‐Dialkylacetamides and Application of Their Anions to the Peterson‐Type Reaction.
Authors: URAYAMA S. , INOUE S. , SATO Y. 
Published: May 2016

AbstractConsecutive treatment of the acetamides (I) with lithium diisopropylamide and chlorotrimethylsilane (IIa) or the corresponding germane (IIb) gives the (trimethylsilyl)‐ or (trimethylgermyl)acetamides (III).
ChemInform Abstract: Polysulfonyl Amines. Part 9. Trimethyl(dimesylamino)stannane: Solid State Structure and Reactions with Covalent Chlorides.
Authors: BLASCHETTE A. , SCHOMBURG D. , WIELAND E. 
Published: May 2016

AbstractThe polymeric title compound (I) is prepared from Me3SnOH and HN(SO2Me)2 in aqueous solution or from Me3SnCl and AgN(SO2Me)2 in MeCN (78% yield).
ChemInform Abstract: Spectroscopic, Structural, Electrochemical, and Kinetic Studies of Ligand Substitution in the 33e Dinuclear Radical Fe2(CO)7(μ‐PPh2) and the 34e Analogues (Fe2(CO)7(μ‐PPh2))‐ and FeCo(CO)7(μ‐PPh2).
Authors: BAKER R. T. , CALABRESE J. C. , KRUSIC P. J. , THERIEN M. J. , TROGLER W. C. 
Published: May 2016

AbstractThe 33e dinuclear radical (I) undergoes rapid CO ligand substitution with a variety of tert. phosphorus ligands to give mono‐ and disubstituted products, which are characterized by elemental analysis and IR and ESR spectroscopy.
ChemInform Abstract: Structure Properties of Dicyanamide and Tricyanmethanide Complexes of Copper(II), Nickel(II), and Cobalt(II) with Ligands of Pyrazole Type Nucleophilic Addition Reactions in Some of the Studied Systems.
Authors: HVASTJOVA M. , KOHOUT J. , KOEHLER H. + , ONDREJOVIC G. 
Published: May 2016

AbstractThe reaction of the metal nitrates with KN(CN)2 or KC(CN)3 and pyrazole or its derivatives in water gives complexes (I) and (II).
ChemInform Abstract: Oxidation of Guaiazulene with Peracetic Acid in Acetic Acid.
Authors: MATSUBARA Y. , MATSUI S. , TAKEKUMA S. , YAMAMOTO H. , NOZOE T. 
Published: May 2016

AbstractMild oxidation of guaiazulene (I) with peracetic acid yields the dimeric azulenes (II) ‐ (IV) as the main products.
ChemInform Abstract: Carbon‐Transfer Reactions with Heterocycles. Part 3. Synthetic Equivalence of Oxazolidines with Carbonyl Compounds.
Authors: SINGH H. , SARIN R. 
Published: May 2016

AbstractOxazolidines such as (II) or (V) are found to transfer their C‐2 carbon units at carbonyl group oxidation level to appropriate binucleophiles such as (I) or (IV) to form heterocycles such as (III) or (VI), among them the alkaloids eleagnine (IIIa), norcryptosyline I (VIa) and norcryptosyline II (VIb).
ChemInform Abstract: Acyclic Nucleotide Analogues. Part 4. Phosphonylmethoxyalkyl and Phosphonylalkyl Derivatives of Adenine.
Authors: ROSENBERG I. , HOLY A. , MASOJIDKOVA M. 
Published: May 2016

AbstractFor structure‐activity studies of the antiviral effect in a series of acyclic nucleotides a series of ca. 50 novel members such as (IV), (VI), (VII) or (VIII) is synthesized with variations in the character of the heterocyclic base, the aliphatic side chain and the presence, character and bonding of the phosphonyl group.
ChemInform Abstract: Synthesis of O‐2′ Non‐Protected Pyrimidine Nucleosides from Cyclic C‐1‐C‐2 Sulfites.
Authors: GAGNIEU C. H. , GUILLER A. , ACHECO H. 
Published: May 2016

AbstractCyclic 1,2‐disulfites such as (I) are coupled with the bis(trimethylsilyl)uracil (II) to form the monosilylated nucleoside (III) which is hydrolyzed to give the nucleoside (IV).
ChemInform Abstract: Electrosynthesis of Porphyrins from a,c‐Biladienes.
Authors: JEYAKUMAR D. , SNOW K. M. , SMITH K. M. 
Published: May 2016

AbstractFor the first time it is shown that the Cu(II) oxidant commonly used to cyclize biladienes to porphyrins can be eliminated by use of electrochemical oxidation at 0.8 V. From (Ia) the porphyrin (IIIa) is obtained (yield 42%) and the Zn(II) complex of (Ia) yields the Zn(II) porphyrin of (IIIa) (40%).
ChemInform Abstract: Ion Beam Assisted Deposition of Thin Carbonaceous Films. Part 2. Adhesion Characteristics in Aqueous and Cathodically Delaminating Conditions.
Authors: TAYLOR S. R. , CAHEN G. L. JUN. , STONER G. E. 
Published: May 2016

AbstractAdhesion tests under dry, wet, and cathodically delaminating conditions show that the adhesion of ion assisted coatings (prepared from a 1,3‐butadiene target gas using ion beams of various gases, e.g., H, He, C2H6) is many orders of magnitude greater than that of conventional coatings (epoxy‐polyamide, polyurethane, vinyl).
ChemInform Abstract: Properties of Barium Chlorophosphate (Apatite) Luminophors Activated by Divalent Europium.
Authors: YU X. E. , HARTL H. , SCHULZ H.‐J. , THIEDE M. 
Published: May 2016

AbstractA series of luminophors having the experimental formula (I) are synthesized by dry‐blending analytical‐grade BaCO3, CaCO3, MgO, BaCl2·2 H2O, Eu2O3, (NH4)2HPO4, and H3BO3 followed by firing in a reducing atmosphere (1000 °C, 2 h, Al container).
ChemInform Abstract: Electrochemical Production and Corrosion Testing of Amorphous Ni‐P.
Authors: CARBAJAL J. L. , WHITE R. E. 
Published: May 2016

AbstractThe electrochemical conditions for the electrodeposition of amorphous Ni‐P alloys are investigated and a variety of alloys, ranging from Ni‐15 P to Ni‐25 P, are prepared from plating solutions containing NiSO4, NiCl2, and H3PO4.
ChemInform Abstract: Chemistry of Phosphorus. Part 190. Alkali Metal Tetraphosphinoborates, MIB(PH2)4 (MI: Li, Na).
Authors: BAUDLER M. , BLOCK C. 
Published: May 2016

AbstractThe title compounds (III) and (V), formed by the reactions outlined in the scheme, are the first phosphinoborates with unsubstituted PH2 groups.
ChemInform Abstract: Electronic and Steric Effects in Closely Related Heteronuclear Clusters. Selective Pathways in Synthetic and Catalytic Bimetallic Chemistry.
Authors: BENDER R. , BRAUNSTEIN P. , DE MERIC DE BELLEFON C. 
Published: May 2016

AbstractThe isolobal analogy concept is very powerful in helping to understand the structure of complex molecules and in predicting the possible existence of others.
ChemInform Abstract: Reactions of Heterocyclic Aromatic Acetals Over γ‐Alumina, Aluminum Phosphate and Aluminum Sulfate.
Authors: RAJA S. , XAVIER N. , ARULRAJ S. J. 
Published: May 2016

AbstractThe reaction of twelve heterocyclic aromatic acetals such as (I)‐(IV) over solid catalysts such as γ‐alumina, aluminum phosphate and aluminum sulfate is studied.
ChemInform Abstract: Cycloaddition of 4‐Phenyl‐4H‐1,2,4‐triazole‐3,5‐dione (PTAD) to 7‐Alkylidene‐2,3‐benzonorbornadienes.
Authors: ADAM W. , LUCCHINI V. , PETERS E.‐M. , PETERS K. , PASQUATO L. , VON SCHNERING H. G. , SEGUCHI K. , WALTER H. , WILL B. 
Published: May 2016

AbstractA series of alkylidenebenzonorbornadienes such as (I) and (IV) ‐ prepared from benzyne and the corresponding fulvenes ‐ is subjected to cycloaddition with PTAD (II).
ChemInform Abstract: Ozonolyses of 1‐Methylcyclopentene, 1‐Methylcyclobutene, 5‐Hexen‐2‐one, and Natural Rubber in the Presence of Methanol.
Authors: GRIESBAUM K. , KIESEL G. 
Published: May 2016

AbstractOzonolysis of the cycloalkenes (I) in MeOH (II) proceeds in both possible directions to yield the methoxyperoxides (III) or (IV), which undergo intramolecular cyclization to give the peroxyhemiacetals (V) and (VI) as cis/trans mixtures (cis/trans ratio = 25:75 for (Va), 2:7 for (VIa), not determined for (Vb) and (VIb)).
ChemInform Abstract: Reduction of Organic and Organometallic Carbonyl Derivatives with Niobiocene Trihydride Cp2NbH3.
Authors: LEBOEUF J.‐F. , LEBLANC J.‐C. , MOISE C. 
Published: May 2016

AbstractThe title compound NIO is shown to be an excellent reducing agent for carbonyl compounds of very different structure.
ChemInform Abstract: Chemistry of Organic Halogenic Molecules. Part 94. The Effect of Fluorine on Photochemical Carbon‐Halogen Bond Cleavage in Z‐ and E‐1‐Fluoro‐2‐halo‐1,2‐diphenylethylenes.
Authors: GREGORCIC A. , ZUPAN M. 
Published: May 2016

AbstractPhotochemical reduction of the ethylenes (I) and (II) mentioned in the title gives rise to cis/trans isomerization and formation of the dehalogenated fluoroalkenes (III) and (IV) and diphenylacetylene (V).