bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis, Characterization and Structure of Cationic Hydrides of Rhodium(III). Part 2. Crystal Structure of Dihydrido(1,4‐biscyclohexyl‐diaza‐1,3‐butadiene)bis(tris(4‐fluorophenyl)phosphine)rhodium(III) Perchlorate.
Authors: IGLESIAS M. , DEL PINO C. , NIETO J. L. , GARCIA‐BLANCO S. , MARTINEZ CARRERA S. 
Published: May 2016

AbstractThe cationic dihydrido(diazabutadiene)bis(tert.phosphine)‐Rh(III) complexes (I) are prepared as demonstrated in the scheme for the title complex (Ia).
ChemInform Abstract: Triaquo(benzene)ruthenium(II) and Triaquo(benzene)osmium(II): Synthesis, Molecular Structure, and Water‐Exchange Kinetics.
Authors: STEBLER‐ROETHLISBERGER M. + , HUMMEL W. , PITTET P.‐A. , BUERGI H.‐B. + , LUDI A. , MERBACH A. E. 
Published: May 2016

AbstractThe salts (I) of the title compounds are obtained by reaction of (MCl2(η6‐C6H6))2 with Ag2SO4 or AgOTos in aqueous solution or of (Ru(OH2)6)(OTos)2 with cyclohexadiene in ethanol.
ChemInform Abstract: Synthesis and Reactivity of Ph2PCH2PPh2‐ (dppm‐) Stabilized Pd‐Co and Pd‐Pt‐Co Clusters. Effect of Platinum versus Palladium on the Neighboring Palladium Center.
Authors: BRAUNSTEIN P. , DE MERIC DE BELLEFON C. , RIES M. 
Published: May 2016

AbstractThe quantitative and regioselective synthesis of the mixed‐metal cluster (IIIa) occurs according to the scheme.
ChemInform Abstract: Synthesis and Characterization of the Bis(diselenolene) Complexes (M(Se2C2(CF3)2)2)z (M: Pt, z: 0, ‐1, ‐2; M: Au, z: ‐1) and Crystal Structure of ((C6H5)4P) (Pt(Se2C2(CF3)2)2).
Authors: HEUER W. B. , TRUE A. E. , SWEPSTON P. N. , HOFFMAN B. M. 
Published: May 2016

AbstractThe new diselenolene title complexes (Ia)‐(Id) are prepared from PdCl2(PPh3)2 (II) or AuCl(PPh3) (IV) according to the scheme.
ChemInform Abstract: Enantioselectivity in the Biotransformation of Mono‐ and Bicyclic Monoterpenoids with the Cultured Cells of Nicotiana tabacum.
Authors: HAMADA H. 
Published: May 2016

AbstractThe alcohols (I), (III) and (V), but not their enantiomers, are oxidized by the title cells to give the corresponding ketones.
ChemInform Abstract: Nuclear Alkylation of 1,4‐Diaminoanthraquinone. Synthesis of Chiral 6,11‐Diaminoanthracyclinones Related to Ametantrone from Carbohydrates.
Authors: MILLS S. K. , MINCHER D. J. , SHAW G. 
Published: May 2016

AbstractCoupling of the leuco‐1,4‐diaminoanthraquinone (I) with the aldehydes (II) and (IV) followed by oxidation with air gives the alcohols (III) and (V).
ChemInform Abstract: Controlled Payne Rearrangements of 2,3‐Epoxy Alcohols in an Aprotic Media: An Enantioselective Total Synthesis of (+)‐exo‐Brevicomin.
Authors: PAGE P. C. B. , RAYNER C. M. , SUTHERLAND I. O. 
Published: May 2016

AbstractLithiation of the epoxy alcohol (I) gives a mixture of the isomeric alkoxides (III) and (IV) which are substituted with the cuprates (V), producing predominantly the cis‐1,2‐diols (VI).
ChemInform Abstract: Effect of Sintering Conditions on the Microstructure and Optical Properties of Cd1‐xZnxS Films.
Authors: PARK K. C. , IM H. B. 
Published: May 2016

AbstractCd1‐xZnxS coatings on amorphous glass substrates are produced using a (1‐x)CdS/xZnS slurry and sintering in N2 or N2 containing ZnCl2 vapor.
ChemInform Abstract: A New TiO2‐Attached Rhodium Metal Catalyst. Catalyst Characterization and Non‐SMSI Behavior.
Authors: ASAKURA K. , IWASAWA Y. , KURODA H. 
Published: May 2016

AbstractThe catalyst is prepared by reaction of a rhodium‐π‐allyl complex, Rh(η3‐C3H5)3, with surface OH groups of TiO2 and subsequent H2 treatments at different temperatures.
ChemInform Abstract: Enhanced Kinetic Resolution and Enzyme‐Like Shape Selectivity.
Authors: CARLIER P. R. , MUNGALL W. S. , SCHROEDER G. + , SHARPLESS K. B. 
Published: May 2016

AbstractThe influence of steric and electronic effects on the kinetic resolution of sec. allylic alcohols by epoxidation (a reaction known, e.g., for (I); kf/ks = 138) is studied.
ChemInform Abstract: Gas‐Phase Bronsted versus Lewis Acid‐Base Reactions of 6,6‐Dimethylfulvene. A Sensitive Probe of the Electronic Structures of Organic Anions.
Authors: BRICKHOUSE M. D. , SQUIRES R. R. 
Published: May 2016

AbstractThe gas‐phase reactions of (I) with a wide range of over 30 different negative ions such as (II) in a flowing afterglow apparatus at 298 ± 2 K are investigated.
ChemInform Abstract: Synthesis and Antimicrobial Activity of p,p′‐Bis(N‐arylureido/thioureidocarbonylmethylamino)diphenylsulfones.
Authors: MESHKATALSADAT M. H. , SHAHSAFI M. A. , PAREKH H. 
Published: May 2016

AbstractWith a view to achieving better therapeutic activity, 26 urea and 26 thiourea derivatives of type (IIIa) and (IIIb), resp., are synthesized (yield: 40‐90%).
ChemInform Abstract: Palladium‐Catalyzed Vinylation of Phenylpropioloyl Chloride.
Authors: KASAHARA A. , IZUMI T. , KUDOU N. 
Published: May 2016

AbstractThe title compound (I) reacts with the terminal alkenes (II) in the presence of Pd(II) acetate as a catalyst to yield the E‐configurated enynes (III).
ChemInform Abstract: Preparation, Vibrational Spectra, and Crystal Structure of Tris(trimethyltin) Tetrathiophosphate (Me3SnS)3PS.
Authors: SHIHADA A.‐F. , WELLER F. 
Published: May 2016

AbstractReaction of bis(trimethyltin) sulfide (I) with thiophosphoryl chloride (II) gives the title compound (III).
ChemInform Abstract: Pyrylocyanines. Part 25. Steric Structure of 2‐Pyrylomonomethine Cyanines and Their Heteroanalogues.
Authors: KUDINOVA M. A. , KURDYUKOV V. V. , TOLMACHEV A. I. 
Published: May 2016

AbstractStarting with the α‐pyrone (I), the monomethine dyes Z,Z‐(VIII), E,Z‐(X), and E,E‐(XII) are prepared by common methods.
ChemInform Abstract: Dependence of the Curie Temperature on the Cationic Ordering in the A2BNb5O15 and AA′BNb5O15 Ferroelectric Tetragonal Tungsten Bronze Phases: a Comparative Study.
Authors: THORET J. , RAVEZ J. 
Published: May 2016

AbstractThe following ferroelectric ceramics are annealed at 750 or 920 °C for three months: (KSr)SrNb5O15, Pb2KNb5O15, Ba2AgNb5O15, Pb2AgNb5O15, and ABaCaNb5O15, ABaSrNb5O15 (A: K, Tl).
ChemInform Abstract: Lithium Cycling Efficiencies in LiAlCl4‐SO2 and LiAlCl4‐SO2Cl2 Electrolytes
Authors: WALKER C. W. JUN. , BINDER M. 
Published: May 2016

Abstract(LiAlCl4‐1.6 SO2, LiAlCl4‐3 SO2, 1 M LiAlCl4‐SO2Cl2, and LiAlCl4‐3 SO2 containing SO2Cl2).
ChemInform Abstract: Asymmetric Nitrogen. Part 70. Geminal Systems. Part 44. Trialkoxyamines (Ortho Nitrites). Synthesis and Properties.
Authors: RUDCHENKO V. F. , IGNATOV S. M. , CHERVIN I. I. , KOSTYANOVSKY R. G. 
Published: May 2016

AbstractThe chlorination of dialkoxyamines such as (I) or (IX) with tBuOCl (II) results in the formation of unstable N‐chloro‐N,N‐dialkoxyamines such as (III) or (X).
ChemInform Abstract: Preparation of (S)‐(‐)‐4‐Methyl‐2‐cyclohexen‐1‐one: A Useful Chiral Building Block.
Authors: HUA D. H. , VENKATARAMAN S. 
Published: May 2016

AbstractReduction of (S)‐(+)‐carvone (I) yields the trans‐substituted cyclohexanone (II) as the main product, together with the corresponding cis‐isomer.
ChemInform Abstract: Chemistry of Novel Compounds with Multifunctional Carbon Structure. Part 3. Synthesis of α‐Azido‐α‐fluoro‐α‐(phenylthio and ethylthio)acetates.
Authors: TAKEUCHI Y. , ASAHINA M. , HORI K. , KOIZUMI T. 
Published: May 2016

AbstractThe synthesis of various tri‐ and tetrafunctional carbon compounds such as (III), (IV) or (VI) is described.
ChemInform Abstract: Chemotherapeutic Agents with an Imidazole Moiety. Part 2. Synthesis and Biological Activities of New 1,4‐Diarylimidazoles.
Authors: PORRETTA G. C. , CERRETO F. , FIORAVANTI R. , SCALZO M. , FISCHETTI M. , RICCARDI F. , CAPEZZONE DE JOANNON A. , DE FEO G. , MAZZANTI G. , TOLU L. 
Published: May 2016

AbstractThe nitrophenacylanilines (I), prepared from the corresponding anilines and nitrophenacyl bromides, are cyclized with potassium thiocyanate (II) to give the 2‐mercaptoimidazoles (III).
ChemInform Abstract: Synthesis of New Linearly Annulated Tricycles as Rigid Dopamine Congeners.
Authors: PERRONE R. , BERARDI F. , BETTONI G. , TORTORELLA V. 
Published: May 2016

AbstractThe epoxide (I) reacts with propylamine (II) to give the amino alcohol (III) which is cyclized, forming the aziridine (IV).
ChemInform Abstract: The Coordination of Small Molecules by Manganese(II) Phosphine Complexes. Part 12. The Synthesis of Some Tetrahydrofuran/Long Chain Tertiary Phosphine Complexes of Manganese(II) Halides, MnX2
Authors: BARRATT D. S. , GOTT G. A. , MCAULIFFE C. A. 
Published: May 2016

Abstract(phosphine)(THF), and Their Reaction with Molecular Oxygen.
ChemInform Abstract: (Dialkylamino)phosphorus Metal Carbonyls. Part 5. Chemical Reactivity of the Phosphorus‐Bridging Carbonyl Group in Carbonylbis((diisopropylamino)phosphido)hexacarbonyldiiron.
Authors: KING R. B. , WU F.‐J. , HOLT E. M. 
Published: May 2016

AbstractTreatment of the title compound (I) with NaBH4 in MeOH results in reduction of the P‐bridging CO group to give the corresponding sec. alcohol (IIa).
ChemInform Abstract: Mononuclear and Binuclear Copper(II) Complexes of 3,5‐Diisopropylsalicylic Acid.
Authors: GREENAWAY F. T. , NORRIS L. J. , SORENSON J. R. J. 
Published: May 2016

AbstractThe Cu(II) complexes (I) of the title acid and a variety of ligating solvents are prepared and studied by elemental analysis, IR, electronic, and EPR spectroscopy.
ChemInform Abstract: Small and Medium‐Sized Rings. Part 68. 4,6,6‐Trimethyl‐4‐cyclohexene‐1,2,3‐trione, a Contribution to the Biogenesis of Norcarotinoids.
Authors: DETERING J. , MARTIN H.‐D. 
Published: May 2016

AbstractThe title compound (III) is obtained as a sticky, deep red substance which, upon exposure to air, immediately deliquesces to form the hydrate (V).
ChemInform Abstract: Synthetic Radical Chemistry. Total Synthesis of (.+‐.)‐Isoamijiol.
Authors: BEGLEY M. J. , PATTENDEN G. , ROBERTSON G. M. 
Published: May 2016

AbstractThe synthesis of the racemic title compound (XII), a constituent of Dictyota linearis, starts from cyclopentanone (I) and includes seven carbon‐to‐carbon bond forming reactions, four of which involve free radical intermediates.
ChemInform Abstract: Salts of Halogenophosphoric Acids. Part 16. 31P NMR Studies of 1,2‐Difluoro‐thiodiphosphates.
Authors: NEELS J. , GRIMMER A. R. , MEISEL M. , WOLF G.‐U. , CALOV U. , JANCKE H. 
Published: May 2016

AbstractThe chemical shifts and coupling constants of the 1,2‐difluoro‐oxothiodiphosphates obtained by gradual hydrolysis of (I) in MeCN are determined from 31P NMR spectra.
ChemInform Abstract: 17O NMR of Seven‐Valent Neptunium in Aqueous Solution.
Authors: APPELMAN E. H. , KOSTKA A. G. , SULLIVAN J. C. 
Published: May 2016

AbstractThe 17O NMR results obtained for Np(VII) in 17O‐enriched alkaline solutions are interpreted in terms of a six‐coordinated Np(VII) anion, (NpO4(OH)2)3‐, in which four O‐atoms are present in a square plane around the Np and two OH‐groups are located at the vertices of a tetragonal bipyramid.
ChemInform Abstract: Electroorganic Synthesis. Part 40. Cyclic Olefins by Anodic Oxidation of β‐(Trimethylsilyl)carboxylic Acids. β‐(Trimethylsilyl)acrylic Acid Derivatives as Acetylene Equivalents in Diels‐Alder Reactions.
Authors: HERMELING D. , SCHAEFER H. J. + 
Published: May 2016

AbstractThe dienophile (II) reacts with the dienes (I) or (VI) to give the silyl substituted carboxylic acids (III) or (VII) which are converted to the hydrogenation products (IV) or (VIII).
ChemInform Abstract: Synthesis of Substituted 1,3‐Dienes by the Reaction of Alkenesulfonyl Chlorides with Olefins Catalyzed by a Ruthenium(II) Complex.
Authors: KAMEYAMA M. , SHIMEZAWA H. , SATOH T. , KAMIGATA N. 
Published: May 2016

AbstractThe alkenesulfonyl chlorides (II) react with vinylarenes such as (III) in the presence of a ruthenium catalyst to give, depending on the reaction temperature, either the chlorosulfones (I) or the (E,E)‐dienes (IV).
ChemInform Abstract: Alkali Triazaphosphininolates ‐ Synthesis and Reactions.
Authors: MEYER M. , KLINGEBIEL U. 
Published: May 2016

AbstractReaction of the dihalo‐bis(trifluoromethyl)‐1,3,5,2λ5‐triazaphosphinines (I) or (VII) with the alkali metal reagents (II) affords the derivatives (III) or (VIII).
ChemInform Abstract: The Element‐Nitrogen Double Bond in Cations of Cyclic Bis(amino)phospha‐, ‐arsa‐, ‐stiba‐, and bismuthines.
Authors: VEITH M. , BERTSCH B. , HUCH V. 
Published: May 2016

AbstractIn the case of (Ia) the electronic balance is accomplished by intramolecular backbonding from the neighboring N‐atoms (space group Pnma, Z = 8).
ChemInform Abstract: Photochemistry of Pyridine N‐Oxides.
Authors: LOHSE C. , HAGEDORN L. , ALBINI A. , FASANI E. 
Published: May 2016

AbstractPhotolysis of (Ia) in aqueous basic (NaOH, NH3) solution via nitrene (IIa) (lifetime 63 ms) yields the anion (IIIa).
ChemInform Abstract: A Simple One‐Step Alkylation of Orcinol Derivatives (II).
Authors: BAEK S.‐H. 
Published: May 2016

AbstractOrcinol (IIa) and its mono‐ (IIb) and dimethyl ethers (IIc) are alkylated by 1‐methyl‐2‐cyclohexenol (I); orcinol (IIa) is alkylated analogously by 2‐cyclohexenol (yield 30, 46, 5%).
ChemInform Abstract: 3‐Bromo‐2‐propenenitriles as Novel Captodative Ethylenes Derived from gem‐Dicyano Epoxides.
Authors: KHAMLICHE L. , ROBERT A. 
Published: May 2016

AbstractThe α‐cyano‐β‐bromo enolates generated from ring opening of the epoxides (I) are trapped by MesCl (II) to give the Z‐ and E‐ethylenic derivatives (III) and (IV) substituted at the same carbon by the releasing O‐Mes and the withdrawing CN group.
ChemInform Abstract: N,N,N′,N′‐Octamethylimidodiphosphortetramide. Reexamination of Its Synthesis and Studies of Its Reactivity as Nucleophile.
Authors: DELPUECH J.‐J. , FASAN G. , RODEHUESER L. + , RUBINI P. , SELVE C. 
Published: May 2016

AbstractStarting with PCl5 (I) and ammonium sulfate (II), an efficient synthesis of the title compound (VII) is performed as shown in the reaction scheme.
ChemInform Abstract: Reaction of Diaryl Isocyanatophosphites with C,N‐Diaryl Nitrilimines.
Authors: PANEVIN A. S. , TRISHIN YU. G. , CHISTOKLETOV V. N. , GALISHEV V. A. , PETROV V. A. 
Published: May 2016

AbstractCycloaddition reaction of the corresponding nitrilimines, prepared in situ from the benzenecarbohydrazonoyl chlorides (I) and triethylamine, with the isocyanatophosphites (II) gives the triazaphosphorines (III).
ChemInform Abstract: A Novel n‐Doped Metallomacrocyclic Conductor.
Authors: FERRARA J. D. , TESSIER‐YOUNGS C. , YOUNGS W. J. 
Published: May 2016

AbstractThe combination of (I) with its dianion in a 3:1 ratio leads to a powder giving a conductivity of 2·10‐3 Ω‐1·cm‐1.
ChemInform Abstract: The Use of Molybdates Combined with Etidronic Acid (I) as Corrosion Inhibitors for Iron.
Authors: AIREY K. , ARMSTRONG R. D. , HANDYSIDE T. 
Published: May 2016

AbstractIt is shown that the use of ZnMoO4 together with the calcium salt of (I) provides a system with an acceptable corrosion rate.
ChemInform Abstract: The Hydrogenation of Cyclohex‐2‐en‐1‐one: A Possible Case of a Reaction Catalyzed by a Heterometallic Cluster.
Authors: PIACENTI F. , MATTEOLI U. , BIANCHI M. , FREDIANI P. , MENCHI G. 
Published: May 2016

AbstractThe highly selective formation of (II) is observed only in the presence of the heterometallic cluster (case C).
ChemInform Abstract: Synthesis of Monofluoro Substituted Compounds from Substances with a 1,2,2,2‐Tetrafluoroethyl Group.
Authors: BOGOLYUBSKII A. V. , SKRYNNIKOVA A. A. , IL'CHENKO A. YA. , POPOV V. I. , YAGUPOL'SKII L. M. 
Published: May 2016

AbstractIt is known that treatment of compounds with a 1,2,2,2‐tetrafluoroethyl group with NaOMe converts this group into a 1‐fluoro‐2,2,2‐trimethoxy group.
ChemInform Abstract: Direct Lithiation of Chalcogenachromones, ‐flavones, and ‐pyranones. The Interconversion and Electrophilic Capture of Ring‐Opening and Ring‐Closed Anions.
Authors: DETTY M. R. , MCGARRY L. W. 
Published: May 2016

AbstractThe chalcogenaflavones (Ia) ‐ (Ic) are lithiated and then treated with methyl triflate (II) to yield the 3‐methylated derivatives (III) as the main products.
ChemInform Abstract: Chemistry and Structural Chemistry of Phosphides and Polyphosphides. Part 49. Formation and Structure of the Henicosaphosphide (Li(12‐Crown‐4)2)3P21(THF)2.
Authors: FRITZ G. , SCHNEIDER H.‐W. , HOENLE W. + , VON SCHNERING H. G. 
Published: May 2016

AbstractThe reaction of Li3P7(DME)3 with six equiv. 12‐crown‐4 and one equiv. (cycloheptatriene)tricarbonyl‐Cr in THF affords red crystals of the title compound, red crystals of Li2P16(12‐crown‐4)x(THF)2 as well as an unidentified yellow substrate.
ChemInform Abstract: Electronic and Molecular Structure of OTeF‐ 5.
Authors: MILLER P. K. , ABNEY K. D. , RAPPE A. K. , ANDERSON O. P. , STRAUSS S. H. 
Published: May 2016

AbstractSalts of the title anion (syntheses are described) are studied by XRD, IR and Raman spectroscopy and the experimental results are compared with ab initio Hartree‐Fock calculations on the .OTeF5 radical, NaOTeF5, and the singlet and triplet states of the free anion.
ChemInform Abstract: Stereochemistry of Iodoarsenates(III). Preparation and Crystal Structures of (Bu4N)2(As2I8) (I), (pyH) (AsI4) (II), and (Et3NH)4(As8I28) (III).
Authors: SHELDRICK W. S. , HAEUSLER H.‐J. + , KAUB J. 
Published: May 2016

AbstractThe title compounds are prepared by reaction of AsI3 with the iodide of the respective nitrogen base in MeCN ((I) 82%, (II) 74%, (III) 82%).
ChemInform Abstract: Catalytic and 27Al MAS NMR Investigations of Thermally Treated Products of ZSM‐5 Synthesis.
Authors: UNGER B. , RESCHETILOWSKI W. , WENDLANDT K.‐P. , FREUDE D. 
Published: May 2016

AbstractThe Si/Al ratio of as‐prepared ZSM‐5 zeolite is found to increase monotonically with time during annealing at 600 °C. A constant degree of dealumination of 27.2% is reached after 20 h annealing.
ChemInform Abstract: Chemiluminescence of Tb(IV) Reduction in Solution and Sensitization Thereof with UO2+ 2 Ions.
Authors: KAZAKOV V. P. , RYKOVA V. V. , KHAMIDULLINA L. A. , AFONITCHEV D. D. 
Published: May 2016

AbstractChemiluminescence resulting from an excited (Tb3+)* ion is observed during the reduction of Tb4+ by water.
ChemInform Abstract: A Novel Rearrangement of 2(5H)‐Furanones.
Authors: MACK R. A. , DECORY T. R. , GEORGIEV V. ST. 
Published: May 2016

AbstractThe biologically interesting class of 2,5‐dihydro‐2‐oxofuran‐3‐carboxamides, e.g. (I) and (III), can be synthesized by reaction of 3(2H)‐furanones (II) and (IV) with aromatic amines.
ChemInform Abstract: Directed Reduction of β‐Hydroxy Ketones Employing Tetramethylammonium Triacetoxyborohydride.
Authors: EVANS D. A. , CHAPMAN K. T. , CARREIRA E. M. 
Published: May 2016

AbstractThe title compound is a mild reducing agent which reduces acyclic β‐hydroxy ketones such as (I), (IV), (VI), (VIII) (= selected examples from several tables) to their corresponding anti diols with high diastereoselectivity (e.g.
ChemInform Abstract: 4‐(β‐Hydroxyalkyl)‐2,6‐ditert‐butylphenols by Reaction of 2,6‐Ditert‐butylphenol with Epoxides in the Presence of Caustic Soda.
Authors: KHALIKOVA N. U. , KRYSIN A. P. 
Published: May 2016

AbstractThe reaction between the phenol (I) and the epoxides (II), in 4 to 5 molar excess, affords the title compounds (III) as the main products along with minor amounts of phenol ethers produced by O‐alkylation of the phenol (I) and trace amounts of further products.
ChemInform Abstract: Oxoiminium Ions for N‐Demethylation: 1‐Oxo‐2,2,6,6‐tetramethylpiperidinium Chloride.
Authors: HUNTER D. H. , RACOK J. S. , REY A. W. , PONCE Y. Z. 
Published: May 2016

AbstractThe N‐alkyl‐N‐methylanilines (III) are treated with the reagent (II) mentioned in the title to form mainly the N‐demethylated secondary phenylamines (IV), together with minor amounts of the formanilides (V).
ChemInform Abstract: Synthesis and Photolysis of 4‐Thioxoazetidin‐2‐ones.
Authors: SAKAMOTO M. , TANAKA M. , FUKUDA A. , AOYAMA H. , OMOTE Y. 
Published: May 2016

AbstractThioxoazetidinones are useful synthetic precursors for β‐lactams related to antibiotics.
ChemInform Abstract: A Convenient Synthesis of Pyrido(3,4‐g)isoquinoline via ortho‐Directed Metalation/Dimerization.
Authors: BOLITT V. , MIOSKOWSKI C. , REDDY S. P. , FALCK J. R. 
Published: May 2016

AbstractDimerization of N,N‐diethylnicotinamide (I) proceeds via lithiation to yield the diazaanthraquinone (II) which is reduced with hydriodic acid.
ChemInform Abstract: New Chiral Auxiliary Groups: Formation of a Phenylaza Analogue of Camphanic Acid After Change of N/O‐Regioselectivity of a Ring‐Contraction Reaction.
Authors: WANNER K. TH. 
Published: May 2016

AbstractTreatment of the α‐bromoimide (I) with NaOMe (II) affords the lactam (III) via sequential ring cleavage/N‐alkylation/contractive ring closure.
ChemInform Abstract: Formation and Stability of Monohalogenated β‐Ether Carbenoids.
Authors: TARHOUNI R. , KIRSCHLEGER B. , VILLIERAS J. 
Published: May 2016

AbstractLithiation of the dihalo ethers (I) produces the intermediates (III) which are hydrolyzed to give the products (IV)‐ (VI).
ChemInform Abstract: Oxidative Coupling of Phosphinomethanides at a Metal Centre: P‐P vs. C‐C Bond Formation and the Molecular Structure of the Novel Bis‐Ylide (Me3Si)2C=PMe2‐PMe2=C(SiMe3)2.
Authors: KARSCH H. H. , DEUBELLY B. , MUELLER G. + 
Published: May 2016

AbstractTreatment of the lithium phosphinomethanides (I) and (III) with bismuth trichloride or nickel dichloride results in P‐P or C‐C coupling reactions, forming the bisphosphorane (II) or the bisphosphine (IV).
ChemInform Abstract: Perfluoroalkyl Tellurium Compounds: Preparation of ((CF3)2TeX)+ Cations and ((CF3)2TeX2+n)n‐ Anions (X: F, Cl, Br).
Authors: NAUMANN D. , WILKES B. 
Published: May 2016

Abstract(CF3)2TeX2 (I) forms with M1X (II) the isolable salts (III), but no evidence for the formation of hexa‐coordinated tellurates M1 2((CF3)2TeX4) is found.
ChemInform Abstract: New Ferrocenyl Sulfides and Selenides: Preparation and Application as Efficient Selective Hydrogenation Catalysts.
Authors: OKOROAFOR M. O. , SHEN L.‐H. , HONEYCHUCK R. V. , BRUBAKER C. H. JUN. 
Published: May 2016

AbstractA series of new ferrocenyl sulfides (9 compounds) such as (III) are synthesized, following a modified procedure, and characterized by spectroscopic methods.
ChemInform Abstract: Decamethylosmocene and Decamethylosmocenium: UV and X‐Ray Photoelectron, Magnetic, and Electronic Studies. Crystal and Molecular Structure of (Os(C5Me5)2).+(BF4)‐.
Authors: O'HARE D. , GREEN J. C. , CHADWICK T. P. , MILLER J. S. 
Published: May 2016

AbstractDecamethylosmocene (I), prepared in 60% yield according to a literature route, is oxidized with AgBF4 to give (II), which crystallizes in C2/m with Z=2.
ChemInform Abstract: Structure‐Odor Correlation. Part 7. Synthesis and Olfactive Properties of Theaspirane Analogues.
Authors: WEYERSTAHL P. , BUCHMANN B. , MARSCHALL‐WEYERSTAHL H. 
Published: May 2016

AbstractThe title compounds (IV), (VII), (X), (XIII), (XV), (XVIII) and (XIX) are synthesized as outlined in the scheme.
ChemInform Abstract: Constituents of Marine Opisthobranchia. Part 2. Structures of the New Diacylglyceryl Ether and Cholesteryl Ester Mixture, and of Three Nucleosides from Fertilized Eggs of the Sea Hare Aplysia kurodai.
Authors: MIYAMOTO T. , HIGUCHI R. , FUNATSU M. , SEIKE H. , NOHARA T. , KOMORI T. 
Published: May 2016

AbstractThe title ether and ester mixtures (I) and (II), resp., and the title nucleosides (III) are isolated from freshly fertilized eggs and the structures are confirmed by chemical and spectral evidence.
ChemInform Abstract: Stability of the Ordered Pd8V Phase in a Proton‐Irradiated Pd‐15 at.% V Alloy.
Authors: CHENG J. , ARDELL A. J. 
Published: May 2016

AbstractThe maximum temp. at which the ordered Pd8V phase forms in the Pd‐15% V alloy irradiated by 400 keV protons is determined to lie in the range 350‐420 °C. Post‐irradiation annealing experiments indicate that Pd8V is a thermodynamically stable equilibrium phase having a critical ordering temp. slightly below 400 °C. Interstitial dislocation loops are prevalent in the microstructure of samples irradiated at low temp. (200 °C), whereas more widely extended stacking fault ribbons are observed at higher temp. (420 °C).