bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis of Steroidal Extranucleo N‐Phenyloxazolidones of Androstane Series.
Authors: SIDDIQUI A. H. , RAO K. V. , REDDY K. V. 
Published: May 2016

AbstractThe androstenes (I) react consecutively with hydrazine hydrate (II) and the isocyanate (III) to give the semicarbazones (IV).
ChemInform Abstract: Synthesis of Steroidal Extranucleo Thiazolidones of Cholestane Series.
Authors: SIDDIQUI A. H. , RAO K. V. , RAO R. K. 
Published: May 2016

AbstractThe cholestane (I) reacts with hydrazine hydrate (II) and subsequently with ammonium thiocyanate (III) to yield the thiosemicarbazone (IV).
ChemInform Abstract: Propyl Derivatives of Enalapril as Potential Angiotensin Converting Enzyme Inhibitors.
Authors: CIABATTI R. , TARZIA G. , BATTAGLIA F. , BARONE D. , BALDOLI E. 
Published: May 2016

AbstractThe proline ester (I) is alkylated with the bromo esters (II) and the diastereomeric diesters (III) are separated.
ChemInform Abstract: Stereoselective C‐C Bond Formation of Carbohydrates by Radical Cyclization Reactions. Part 2.
Authors: DE MESMAEKER A. , HOFFMANN P. , ERNST B. 
Published: May 2016

AbstractThe glycal (I) is converted to the iodinated propargylic ethers (III) which undergo radical‐induced cyclization, forming the bicyclic methylene acetals (IV).
ChemInform Abstract: Semisynthetic Macrolide Antibacterials Derived from Tylosin. Synthesis of 23‐O‐Demycinosyltylosin and Related Compounds.
Authors: MALLAMS A. K. , ROSSMAN R. R. 
Published: May 2016

AbstractTylosin (Ia) is transformed to 23‐O‐demycinosyltylosin (Ic) (23‐DMT) and a number of 23‐DMT acyl derivatives, e.g. (V), and 23‐DMT hydrazones such as (VII).
ChemInform Abstract: Fermi Level Pinning of Semiconductor Electrodes in Aqueous and Non Aqueous Electrolytes: Influence of the Modification of the Electrode Surface.
Authors: SAVADOGO O. 
Published: May 2016

AbstractThe photoelectrochemical behavior of several semiconductors (n‐ and p‐GaAs, n‐ and p‐InP, n‐ and p‐Si, and n‐GaP) modified with H4SiW12O40·nH2O is studied.
ChemInform Abstract: Preparation of WO3/TiO2 and WO3/Al2O3 and Characterization by Temperature‐Programmed Reduction.
Authors: VERMAIRE D. C. , VAN BERGE P. C. 
Published: May 2016

AbstractThe title catalysts are prepared by means of an equilibrium adsorption technique using tungstate solutions of varying pH values and concentrations to control the tungsten loading.
ChemInform Abstract: The Role of Tellurium and Antimony in PtTe/Al2O3 and PtSb/Al2O3 Reforming Catalysts
Authors: CHENG C. H. , DOOLEY K. M. , PRICE G. L. 
Published: May 2016

Abstractis studied using the n‐hexane isomerization, aromatization, and hydrocracking reactions at 673 K and the cyclohexane dehydrogenation at 573 K as test reactions.
ChemInform Abstract: A Study of Phosphate‐Modified TiO2 (Anatase)
Authors: HADJIIVANOV K. I. , KLISSURSKI D. G. , DAVYDOV A. A. 
Published: May 2016

Abstractby means of IR, XPS, X‐ray phase analysis, SEM, AAS shows strongly surface bonded phosphate anions, which are stable even at the temp. of anatase‐rutile transition.
ChemInform Abstract: Photoredox Processes in the 254‐nm Photochemistry of Chromium(III) Ammine Complexes.
Authors: RUMINSKI R. R. , HEALY M. H. , COLEMAN W. F. 
Published: May 2016

AbstractThe factors influencing the formation of Cr(VI) products during the charge‐transfer photolysis of six Cr(III)‐ammine complexes are studied (e.g.
ChemInform Abstract: Synthesis and Characterization of New Hydrazinium(2+) and Hydrazinium(1+) Hexafluorophosphates and Hydrazinium(1+) Hexafluoroarsenate.
Authors: GANTAR D. , RAHTEN A. , VOLAVSEK B. 
Published: May 2016

AbstractThe IR spectra of the compounds (III), (IV), (V), (VI), and (VIII) are reported.
ChemInform Abstract: Molecular and Crystal Structure of 1‐(4‐Chlorophenyl)‐5‐(2‐dimethylaminovinyl)‐1H‐tetrazole: a Vinylogous 5‐Amino‐1H‐tetrazole Derivative
Authors: SIELER J. , MAARTMANN‐MOE K. , FISCHER G. W. 
Published: May 2016

Abstract(i.e.
ChemInform Abstract: Bonding in Tris(η5‐cyclopentadienyl) Actinoid Complexes. Part 3. Interaction of π‐Neutral, π‐Acidic, and π‐Basic Ligands with (η5‐C5H5)3U.
Authors: BURSTEN B. E. , RHODES L. F. , STRITTMATTER R. J. 
Published: May 2016

AbstractQuantitative investigations of the electronic structure of the title compound via Xα‐SW MO calculations are given.
ChemInform Abstract: 1,2‐Bond Shift Isomerization of Oxiranes on Copper‐Graphimet.
Authors: MOLNAR A. , MASTALIR A. , BARTOK M. 
Published: May 2016

AbstractTreatment of 2,2,3,3‐tetramethyloxirane (I) with various catalysts, e.g., copper intercalated graphite, Raney‐type copper, copper on colloidal silica, or solely silica, results in formation of the olefins (II) and (III), tert‐butyl methyl ketone (IV), and 2,3‐dimethylbut‐3‐en‐2‐ol (V).
ChemInform Abstract: Alkylation of Ethyl 4,4,4‐Trifluoroacetoacetate. First Example of a Reversible O‐Alkylation Process Leading to C‐Alkylation.
Authors: BEGUE J.‐P. , CHARPENTIER‐MORIZE M. , NEE G. 
Published: May 2016

AbstractEthyl 4,4,4‐trifluoroacetoacetate (I) reacts with the alkyl halides (II) to give the C‐alkylation products (III) and (IV), together with the enol ethers (V).
ChemInform Abstract: Cyclophanes. Part 28. Syn‐ and anti‐(2.2)Orthometacyclophane.
Authors: BODWELL G. , ERNST L. , HAENEL M. W. , HOPF H. 
Published: May 2016

AbstractThermolysis of the disulfone (III) yields the title compound (VI) together with the cycloheptadienes (IV) and (V).
ChemInform Abstract: Intramolecular Ene Approach to Stereocontrol Over Three Contiguous Chiral Centers.
Authors: MIKAMI K. , TAKAHASHI K. , NAKAI T. 
Published: May 2016

AbstractThe four isomeric diallyl ethers (I), (VI), (VIIa), and (VIIb) are cyclized at 200°C to form the diastereomeric vinyltetrahydrofurans (II) ‐(V).
ChemInform Abstract: NMR Spectra of Cyclic Nitrones. Part 4. Synthesis and 13C NMR Spectra of 4H‐Imidazole N‐Oxides and N,N‐Dioxides.
Authors: GRIGOR'EV I. A. , KIRILYUK L. A. , VOLODARSKII L. B. 
Published: May 2016

AbstractOxidation of the 1‐hydroxy‐3‐imidazoline 3‐oxides (I) or the 1‐hydroxy‐3‐imidazolines (IIIa) and (IIIc) gives the dioxides (II) or the 4H‐imidazole 3‐monoxides (IVa) and (IVc).
ChemInform Abstract: An Unusual Transformation of Aminoazidofurazan into the 1‐Hydroxy‐5‐cyanotetrazole Sodium Salt.
Authors: CHURAKOV A. M. , IOFFE S. L. , KUZ'MIN V. S. , STRELENKO YU. A. , STRUCHKOV YU. T. , TARTAKOVSKII V. A. 
Published: May 2016

AbstractAminoazidofurazan (I) reacts with sodium nitrite (II) to give the 1‐hydroxy‐5‐cyanotetrazole sodium salt (III).
ChemInform Abstract: New Stable Nitroxyl Radicals in the Hydroquinoline Series.
Authors: SHIKHALIEV KH. S. , SHAPIRO A. B. , SUSKINA V. I. , SHMYREVA ZH. V. , ZALUKAEV L. P. 
Published: May 2016

AbstractThe trityldihydroquinoline (III), prepared from the dihydroquinoline (I) and trityl alcohol (II), is oxidized to produce the nitroxyl (IV).
ChemInform Abstract: A New Synthetic Method for the Preparation of 5‐Deazaflavins and 5‐Deaza‐10‐oxaflavins.
Authors: CHEN X. , NAGATA M. , TANAKA K. , YONEDA F. 
Published: May 2016

AbstractThe o‐aminobenzyl alcohols (II) are cyclized with 3‐methyl‐6‐chlorouracil (Ia) to give the methyldeazaflavins (III).
ChemInform Abstract: Synthesis of 3‐Amino and 3‐Alkylamino‐Substituted Isofervenulins. The First Direct Amination of the 1,2,4‐Triazine Ring in Position 3.
Authors: POZHARSKII A. F. , GULEVSKAYA A. V. , KUZ'MENKO V. V. 
Published: May 2016

AbstractIsofervenulin (I) is coupled with the amines (II) in the presence of a permanganate to give the 3‐amino derivatives (III).
ChemInform Abstract: 1,3‐Dipolar Addition of Benzonitrile Oxides to 4(7)‐Methyl‐ and 5(6)‐Methyl‐2‐chloromethyl‐1H‐benzimidazoles ‐ Synthesis of Some New 4‐Aryl‐1H‐(1,2,4)oxadiazino(4,5‐a)benzimidazoles.
Authors: REDDY P. S. N. , RAO B. R. , MOHIUDDIN G. 
Published: May 2016

AbstractIn order to understand the effect of a methyl substituent on the benzimidazole‐benzonitrile oxide addition reaction, the reactions of the benzimidazoles (I) and (V) with the chlorides (II) are investigated.
ChemInform Abstract: Enantioselective Synthesis of Oxa‐Spiro Compounds.
Authors: DESMAELE D. , D'ANGELO J. 
Published: May 2016

AbstractThe chiral imines (III), derived from the alkoxycyclohexanones (I), undergo Michael addition to the α,β‐unsaturated carbonyl compounds (IV), yielding the adducts (V).
ChemInform Abstract: Synthesis of an Oxygen‐Bridged Hydroxy(15)annulenone: The Effects of Introducing One Hydroxy Group into the Flexible Segment of a 14π Perimeter.
Authors: OGAWA H. , INOUE M. , IMOTO T. , MIYAMOTO I. , KATO H. , TANIGUCHI Y. , NOGAMI Y. , KOGA T. 
Published: May 2016

AbstractBromination of the annulenone (I) with N‐bromosuccinimide and subsequent substitution of the bromide (II) with the sodium alkoxide (III) yield the alkoxyannulenone (IV).
ChemInform Abstract: The Chemistry of α‐Silylcarbonyl Compounds. Part 19. A Regio‐ and Stereoselective Synthesis of Z‐Enol Methyldiphenylsilyl Ethers.
Authors: LARSON G. L. , BERRIOS R. , PRIETO J. A. 
Published: May 2016

AbstractThe esters (I) are α‐silylated and then treated with the Grignard agents (IV) to form the α‐silyl ketones (V).
ChemInform Abstract: A New Family of Aromatic Polyimine Chelates Substituted with Two Diphenylphosphines.
Authors: ZEISSEL R. 
Published: May 2016

Abstract2,7‐Dichloronaphthyridine (I) reacts with lithium diphenylphosphide (II) to yield the bis(diphenylphosphino)naphthyridine (III).
ChemInform Abstract: Comparison Between Alkylseleno, Arylseleno and Arylthio Substituents Stabilizing Alkyllithium Compounds.
Authors: KRIEF A. , DUMONT W. , CLAREMBEAU M. , BADAOUI E. 
Published: May 2016

AbstractThe chemoselective cleavage of C‐Se bonds in selenoacetals by treatment with butyl‐Li compounds is studied for various α‐methyl and α‐phenylselenoacetals and compared to C‐S bond cleavage in analogous S,Se acetals.
ChemInform Abstract: Complexation of 137Cs by the Cap Dyes of the Cep (Cerocomus badius).
Authors: AUMANN D. C. , CLOOTH G. , STEFFAN B. , STEGLICH W. 
Published: May 2016

AbstractInvestigations on the radionuclide content of mushrooms after the reactor accident of Tschernobyl have shown that the cep (Cerocomus badius) contained much more 137Cs than the closely related edible bolete (Boletus edulis).
ChemInform Abstract: New Types of Organometallic Oxo Complexes Containing Molybdenum and Tungsten.
Authors: LEGZDINS P. , PHILLIPS E. C. , SANCHEZ L. 
Published: May 2016

AbstractThe thermally stable title complexes of type (II) are obtained by treatment of the 16‐electron compounds (I) with excess O2 or, as shown for the example of (IIb), with H2O2 in stoichiometric amounts to prevent further conversion of the product to its oxo analogue such as (III).
ChemInform Abstract: Alkylcobalt Carbonyls. Part 9. Alkoxy‐, Silyloxy‐, and Hydroxy‐Substituted Methyl‐ and Acetylcobalt Carbonyls. Reduction of Formaldehyde to Methanol by Hydridocobalt Tetracarbonyl.
Authors: SISAK A. , SAMPAR‐SZERENCSES E. , GALAMB V. , NEMETH L. , UNGVARY F. , PALYI G. 
Published: May 2016

AbstractThe preparative routes leading to the title complexes are outlined in the scheme.
ChemInform Abstract: Novel Trinor‐Eremophilanes (Dendryphiellin B, C, and D), Eremophilanes (Dendryphiellin E, F, and G), and Branched C9‐Carboxylic Acids (Dendryphiellic Acid A and B) from the Marine Deuteromycete Dendryphiella salina (Sutherland) Pugh et Nicot
Authors: GUERRIERO A. , D'AMBROSIO M. , CUOMO V. , VANZANELLA F. , PIETRA F. 
Published: May 2016

Abstract(i.e.
ChemInform Abstract: N‐(Deoxyguanosin‐8‐yl)aniline from the in‐vitro Reaction of N‐Acetoxyaniline with Deoxyguanosine and DNA.
Authors: FAMULOK M. , BOCHE G. 
Published: May 2016

AbstractN‐Acetoxyaniline (III), the isolation and characterization of which is described for the first time, reacts with both pure deoxyguanosine and deoxyguanosine bound on DNA to give the adduct (IV).
ChemInform Abstract: Synthesis of N‐Acetoxy‐2‐aminonaphthalene, an Ultimate Carcinogen of the Carcinogenic 2‐Naphtylamine, and Its in vitro Reactions with (Bio)‐Nucleophiles.
Authors: FAMULOK M. , BOSOLD F. , BOCHE G. 
Published: May 2016

Abstract2‐Naphthylhydroxylamine (I) is treated with the acyl cyanides (II) to form the acetoxy‐ or pivaloyloxyaminonaphthalenes (III) which are aminolyzed with N‐methylaniline (IV) to give the substitution products (V) ‐ (VII).
ChemInform Abstract: Field‐Forced Antiferroelectric‐to‐Ferroelectric Switching in Modified Lead Zirconate Titanate Stannate Ceramics.
Authors: PAN W. , ZHANG Q. , BHALLA A. , CROSS L. E. 
Published: May 2016

AbstractIn the family of modified Pb‐Zr‐Ti‐Sn switchable antiferroelectric ceramics, a maximum field‐induced longitudinal strain of 0.85% and volume expansion of 0.95% is observed for the composition Pb0.97La0.02(Zr0.66Ti0.09Sn0.25)O3 at room temperature.
ChemInform Abstract: Preparation and Properties of Hot‐Pressed YBa2Cu3O7‐x.
Authors: LOEHMAN R. E. , HAMMETTER W. F. , VENTURINI E. L. , MOORE R. H. , GERSTLE F. P. JUN. 
Published: May 2016

AbstractMixtures of Y2O3, Ba(NO3)2, and CuO are reacted at 925 °C in air and the resulting YBa2Cu3O7‐x powders are hot‐pressed in air or O2 (6.9 MPa, 950 °C, 30 min).
ChemInform Abstract: Preparation of Bi‐Sr‐Ca‐Cu‐O Thin Films by Sputtering Under a Variable Magnetic Field.
Authors: NAGATA H. , TAKANO A. , KAWASAKI M. , YOSHIMOTO M. , KOINUMA H. 
Published: May 2016

AbstractThin films (∼100 nm) having compositions close to Bi2Sr2Ca2Cu3Ox are deposited on Mg(100) by plasma‐controlled sputtering.
ChemInform Abstract: Composition and Structure of a Novel Solid Electrolyte: the Non‐Stoichiometric Triple Oxide Fluoride of Sodium, Magnesium and Titanium.
Authors: FILIPENKO O. S. , ATOVMYAN L. O. , NALBANDYAN V. B. , BIKYASHEV E. A. 
Published: May 2016

AbstractIn the course of investigations of the system Na2O‐MgO‐TiO2 the title compound is obtained as a by‐product.
ChemInform Abstract: Free Radical Addition of Alkanals to Acrolein Diacetate.
Authors: OGIBIN YU. N. , MOLOKANOV A. N. , NIKISHIN G. I. 
Published: May 2016

AbstractThe aldehydes (II) are coupled with acrolein diacetate (I) to give the 1,1‐diacetoxyalkan‐4‐ones (III), the protected form of 1,4‐dicarbonyl compounds.
ChemInform Abstract: Cocatalysis by an Internal Carboxyl Group and by α‐Cyclodextrin. The Debromination of 4‐Bromo‐4‐methyl‐2,5‐cyclohexadienone‐2‐carboxylic Acid.
Authors: TAKASAKI B. K. , TEE O. S. 
Published: May 2016

AbstractThe debromination of (II) by the cyclodextrin‐Br‐ complex is enhanced by a factor of 12·106 compared with the reaction of (I) with Br‐.
ChemInform Abstract: Oxychlorination of Alkenes by Chlorochromate Reagents: a Facile Preparation of α‐Chloro Ketones, and Competition by Substituent‐Directed Oxidation.
Authors: GUERRERO A. F. , KIM H. , SCHLECHT M. F. 
Published: May 2016

AbstractOxychlorination of alkenes with pyridinium chlorochromate is performed at reflux in methylene chloride, yielding α‐chloro ketones.
ChemInform Abstract: Reaction of Ethyl (N‐(Diethoxyphosphoryl))formamidate with Grignard Reagents: A New Approach to Electrophilic Amination.
Authors: ZAWADZKI S. 
Published: May 2016

AbstractReaction of the phosphoramidate (I) with the orthoformate (II) yields the formimidate (III) which is treated with Grignard agents such as (IV).
ChemInform Abstract: Synthesis and NMR Spectroscopy of Stable Isotope‐Labeled Phenols and L‐Tyrosines.
Authors: WINKEL C. , AARTS M. W. M. M. , VAN DER HEIDE F. R. , BUITENHUIS E. G. , LUGTENBURG J. 
Published: May 2016

AbstractThe syntheses of (17O)phenol from (17O)water, (18O)phenol from (18O)water, (1‐13C)‐ and (4‐13C)phenol from (2‐13C)acetone, and (2‐13C)‐ and (3‐13C)phenol from (1‐13C)acetone are described.
ChemInform Abstract: Mechanistic and Preparative Studies of the Intramolecular Photocyclization of Methylated 2‐(4‐Pentenyl)tropones.
Authors: FELDMAN K. S. , COME J. H. , KOSMIDER B. J. , SMITH P. M. , ROTELLA D. P. , WU M.‐J. 
Published: May 2016

AbstractIrradiation of the 2‐(4‐pentenyl)tropones (I), (IV), and (VIII) at 350 nm leads to the formation of the regioisomeric (6π + 2π)cycloadducts (II) and (III), (V) and (VI), or (IX) and (X), together with the (8π + 2π)cycloadducts (VII) and (XI).
ChemInform Abstract: An Efficient, Highly Regioselective Synthesis of Substituted (1‐Cyclo‐hexenyl)acetic Acid Derivatives via Ionization/Elimination of β‐Lactones.
Authors: BLACK T. H. , MALULEKA S. L. 
Published: May 2016

AbstractThe β‐hydroxycarboxylic acids (III), prepared from cyclohexanone (I) and the dilithiocarboxylates (II), react with phenylsulfonyl chloride in pyridine to form the spirocyclic propiolactones (IV).
ChemInform Abstract: 2‐Azetidinones: Reaction of α‐Silylcarbanions with Carbonyl Compounds.
Authors: GUERTLER S. + , OTTO H.‐H. 
Published: May 2016

AbstractThe silylated β‐lactams (I) are lithiated and then coupled with the carbonyl compounds (IV) to yield the 3‐methylene‐β‐lactams (V) and (VI).
ChemInform Abstract: Intramolecular Cyclization of Dicobalt Hexacarbonyl Complexes of Allyl Propargyl Ethers on the Surface of Adsorbents. A Convenient Route for the Preparation of Substituted 3‐Oxabicyclo(3.3.0)octenes and 4‐Hydroxymethylcyclopentenones.
Authors: SMIT V. A. , SIMONYAN S. O. , TARASOV V. A. , GYBIN A. S. , MIKAELYAN G. L. , SHASHKOV A. S. , MAMYAN S. S. , IBRAGIMOV I. I. , KEIPL R. 
Published: May 2016

AbstractThe cobalt carbonyl complexes (I), prepared by common methods, are cyclized on wet silica gel in the presence of oxygen to give the oxabicyclooctanones (II).
ChemInform Abstract: Chemotherapeutic Agents. Part 15. Synthesis of 4‐Amino‐3‐pyrazolo‐1,2,4‐triazoles as Antimicrobial Agents.
Authors: RAM V. J. , MISHRA L. , KUSHWAHA D. S. 
Published: May 2016

AbstractThe triaminoguanidine (II) undergoes cyclization with the carboxylic acids (I) to give the aminohydrazinotriazoles (III) which form the aminopyrazolyltriazoles (V) upon cyclocondensation with the ethoxyacrylnitriles (IV).
ChemInform Abstract: Synthesis and Biological Activity of Some New 8‐Hydroxyquinolinesulfonamide Derivatives.
Authors: ABDEL HAFEZ A. A. , AWAD I. M. A. , HASSAN K. M. 
Published: May 2016

AbstractCoupling of the sulfonyl hydrazide (I) with the aromatic aldehydes (II) yields the sulfonyl hydrazones (III) which react with ketene to form the β‐lactams (V).
ChemInform Abstract: Substituent‐Directed Oxidation: The syn‐Stereochemistry of Addition of High‐Valent Oxochromium Reagents to Alkenes.
Authors: SCHLECHT M. F. , KIM H. 
Published: May 2016

AbstractReaction of tetramethylzirconium (II) with cyclooct‐4‐en‐1‐one (I) leads to the formation of 1‐methylcyclooct‐4‐en‐1‐ol (III) which undergoes regiospecific cyclization upon oxidation with pyridinium chlorochromate to form the oxabicyclo(4.2.1)nonanone (IV).
ChemInform Abstract: A Convenient Route from Alkenylboranes to Alkenylstannanes.
Authors: WRACKMEYER B. , WAGNER K. 
Published: May 2016

AbstractAlkenylboranes such as (I) (7 examples) react in hexane with the stannane (II) (or its diethylamino analogue) in the presence of a catalytic amount of a lithium amide to give (besides the aminodialkylboranes) the alkenylstannanes (III) with retention of the configuration at the C=C double bond.
ChemInform Abstract: Stereoselectivity in the Reduction of (Co(ox)3)3‐ by (Co(en)3)2+ and Its Derivatives.
Authors: MARUSAK R. A. , OSVATH P. , KEMPER M. , LAPPIN A. G. 
Published: May 2016

AbstractThe oxidation of Co(II) by tris(oxalato)cobaltate(III) in 1,2‐diaminoethane proceeds by parallel inner‐sphere and outer‐sphere pathways leading to (I) and (II).
ChemInform Abstract: Synthesis, Characterization, and X‐Ray Structure of the Octahedral Nickel(II) Complex of a Pentadentate Hexaaza Macrobicyclic Ligand: Chloro(9‐(methoxymethyl)‐1,4,6,9,11,14‐hexaazabicyclo(12.2.1)heptadecane)nickel(II) Perchlorate.
Authors: SUH M. P. , CHOI J. , KANG S.‐G. , SHIN W. 
Published: May 2016

AbstractThe template condensation reaction in the mole ratios given in the scheme produces the title complex (VI) as a first example of a hexaaza macrocycle which serves as a pentadentate ligand.
ChemInform Abstract: Triple‐Decker Complexes. Part 11. (η3‐Allyl)nickel(μ,η5‐2,3‐dihydro‐1,3‐diborolyl)nickel(η3‐allyl)# (η1‐allyl) Triple‐Decker Complexes.
Authors: BRODT G. , KUHLMANN T. , SIEBERT W. 
Published: May 2016

Abstract(IIIb) is obtained analogously to (IIIa) in Et2O at ‐40 °C. The bonding in (III) is elucidated by 1H and 13C NMR data.
ChemInform Abstract: Novel Basic Ligands for the Homogeneous Catalytic Methanol Carbonylation. Part 21. Synthesis and Properties of (Ether‐Phosphane) Platinum Complexes.
Authors: LINDNER E. , SPEIDEL R. 
Published: May 2016

AbstractThe ether‐phosphane‐Pt(II) complexes (III) are prepared according to the scheme; they can also be obtained similarly starting with PtCl2(cod).
ChemInform Abstract: Preparation and X‐Ray Structure of (dbuH) (PtBr5(PPh3)).
Authors: MOTEVALLI M. , HURSTHOUSE M. B. , KELLY P. F. , WOOLLINS J. D. 
Published: May 2016

AbstractIn contrast to analogous complexes of smaller phosphines, which react with bromine to give Pt(IV) dibromo species, the Pt(II) complex (I) reacts with Br2 to afford PtBr2(PPh3)2 and PtBr4(PPh3)2 and, if performed in the presence of the hydrochloride of DBU, the title complex (IV).
ChemInform Abstract: C‐Glycosides. Part 7. Stereospecific C‐Glycosylation of Aromatic and Heterocyclic Rings.
Authors: CZERNECKI S. , VILLE G. 
Published: May 2016

AbstractReaction of the D‐glucopyranolactone (I) with the aryl and hetaryl lithium compounds (II) gives anomeric mixtures of the D‐glucopyranoses (III) which are stereospecifically reduced with triethylsilane to form the β‐glycosides (IV).
ChemInform Abstract: Thiazole Route to Carbohydrates: Synthesis of Building Blocks or Precursors to Carbohydrates with the Use of Functionally‐Substituted Thiazoles as Auxiliaries. Part 1. Iterative, Stereoselective Homologation of Chiral Polyalkoxy Aldehydes Employing 2‐(Trimethylsilyl)thiazole as a Formyl Anion Equivalent. The Thiazole Route to Higher Carbohydrates.
Authors: DONDONI A. , FANTIN G. , FOGAGNOLO M. , MEDICI A. , PEDRINI P. 
Published: May 2016

AbstractAddition of 2‐trimethylsilylthiazole (II) to the chiral aldehydes (I) leads to the formation of the intermediates (III) which give the anti‐(α‐hydroxyalkyl)thiazoles (IV) with high diastereofacial selectivity after desilylation.
ChemInform Abstract: Chromenes. Part 7. Product Stabilization in Condensations with 7‐Methoxy‐2,2‐dimethylchroman‐4‐one.
Authors: ANASTASIS P. , BROWN P. E. , ISLAM Q. , MARCUS W. Y. 
Published: May 2016

AbstractThe condensation of the enolate anion of compound (I) with the aldehydes (II) leads to stable products only in the presence of ZnCl2.
ChemInform Abstract: FXeOIOF4 and Xe(OIOF4)2: Preparation and Study by 129Xe and 19F NMR Spectroscopy and Raman Spectroscopy and NMR Characterization of LXeOIOF4 (L: ‐OTeF5, ‐OSO2F).
Authors: SYVRET R. G. , SCHROBILGEN G. J. 
Published: May 2016

AbstractThe 129Xe and 19F NMR results obtained for solutions containing varying amounts of IO2F3 and XeF2 in SO2ClF, CFCl3, and BrF5 solvents show that IO2F3 inserts into the Xe‐F bond of XeF2 to yield the pseudooctahedral cis‐ and trans‐OIF4O oxygen bonded Xe(II)‐derivatives (I)‐(V); their relative amounts depend on both temp. and solvent polarity.
ChemInform Abstract: Photocatalytic Hydrogen Evolution from Aqueous Solutions of Sodium Sulfite Using Platinum‐Loaded CdS1‐xSex Mixed Crystal Powder.
Authors: UCHIHARA T. , ABE H. , MATSUMURA M. , TSUBOMURA H. 
Published: May 2016

AbstractCdS1‐xSex (x = 0‐1.0) powders are prepared in order to reduce the band gap of CdS and to broaden the effective wavelength range of the photocatalyst.
ChemInform Abstract: Effect of Inert Gas Flow Rate on the Inorganic Bromate Oscillator.
Authors: ADAMCIKOVA L. , SEVCIK P. 
Published: May 2016

AbstractThe oscillation behavior of a purely inorganic oscillator (Belousov‐Zhabotinsky‐type: NaBrO3‐NaH2PO2‐Mn(II)‐H2SO4) is investigated, using various flow rates of an inert carrier gas (N2) to remove the gaseous products.