bluuebunny/crossref_metadata_2025_split huggingface dataset:
Hearing Loss, Incident Parkinson Disease, and Treatment With Hearing Aids
Authors: Neilson Lee E. , Reavis Kelly M. , Wiedrick Jack , Scott Gregory D. 
Published: October 2024

ImportanceThe risk of developing Parkinson disease (PD) after objective hearing loss is unknown. PD studies using self-reported hearing loss are insensitive, and objective data are lacking.ObjectiveTo examine the association of hearing loss with incident PD in US veterans and its effect modification by well-established prodromal conditions and hearing aids.Design, Setting, and ParticipantsThis cohort study analyzed electronic health record data from the US Department of Veterans Affairs for veterans who had an audiogram from January 1, 1999, to December 30, 2022. Individuals with data missing or a preexisting PD diagnosis were excluded.ExposureAudiogram-confirmed hearing loss.Main Outcomes and MeasuresCumulative incidence of PD was calculated with adjustment for competing risk of death.ResultsAmong 7 296 051 veterans with an audiogram, 3 596 365 were included. They were mostly male (n = 3 452 898 [96%]) and had a mean (SD) age of 67 (10.3) years. A total of 750 010 individuals (20.8%) had normal hearing at the time of audiometry examination; among those with hearing loss, 1 080 651 (30.0%), 1 039 785 (28.9%), 568 296 (15.8%), and 157 623 (4.3%) individuals had mild (20-&amp;lt;35 dB), moderate (35-&amp;lt;50 dB), moderate to severe (50-&amp;lt;65 dB), and severe to profound (65-120 dB) hearing loss, respectively. Age, gender, and smoking history were balanced between all exposed and unexposed groups with further adjustment for race, ethnicity, and frailty. At 10 years after the baseline audiogram, the numbers of additional cases of PD were 6.1 (95% CI, 4.5-7.79, 15.8 (95% CI, 12.8-18.8), 16.2 (95% CI, 11.9-20.6), and 12.1 (95% CI, 4.5-19.6) among veterans with mild, moderate, moderate to severe, and severe to profound hearing loss, respectively, compared with those with normal hearing. When combined with established prodromal conditions, hearing loss was associated with 5.7 (95% CI, 2.2-9.2) additional cases of PD at 10 years compared with either condition alone. With prompt hearing aid dispensation, incident cases of PD decreased by 21.6 cases (95% CI, 19.5-23.6) at 10 years.Conclusions and RelevanceHearing loss appears to be an independent risk factor for later development of PD. Hearing aids attenuate this risk, and therefore widespread screening for hearing loss and appropriate use of hearing aids may reduce the incidence of PD. Additional studies are needed to examine the mechanisms underlying the association between hearing loss and PD.
Comparing greenhouse and field biocrust cultivation methods in the Sonoran Desert
Authors: Antoninka A. , Rowe H. , Weser J. , Langenfeld D. , Brady J. , Sprague T. , Day N. 
Published: October 2024

Abstract

Developing methods to use biocrusts in restoration is becoming more important as land use and climate change impact the health and intactness of high‐stress ecosystems. Methods of cultivation to maximize the production of biocrusts for use in restoration activities are necessary because salvage opportunities are limited. Our objective for this research was to determine an optimal method for scalable biocrust cultivation.

We tested two Field and one Greenhouse cultivation methods. The Field cultivation methods had a base layer of weed cloth, soil and irrigation with either (1) shade cloth immediately over the surface (Quesadilla method) or (2) with shade cloth over a 1 m tall hoophouse (Hoophouse method). The Greenhouse method had nested basins with water wicking up to the soil surface and biocrust from below, with shade cloth attached to basins. We crossed these methods with the addition of native soil or sand and with and without a base of jute using salvaged biocrusts from the Sonoran Desert.

All methods led to at least doubling biocrust cover in 11 weeks. The Greenhouse method led to the highest cover of cyanobacteria and mosses, whereas the field Quesadilla method and the addition of native soil in all cultivation methods led to higher abundance of lichens. There were interactions of cultivation method and soil type, with Greenhouse cultivation and native soil promoting the highest cyanobacteria cover and chlorophyll a. We measured exopolysaccharide sheaths (EPS) in native soil and all cultivation conditions, finding no differences for tightly bound sheath fractions, but higher quantities of the loosely bound EPS in the Greenhouse. We also quantified native and non‐native plants in cultivation, finding few plants in Greenhouse cultivation, but high abundance in both Field methods, and particularly with native soil and without jute for native plants.

Practical implication: Together, these results demonstrate that all three cultivation methods are successful for bulking biocrust materials for restoration, and preference should be given to the method that is the easiest and most accessible for practitioners.
Deciphering the Influence of Effective Shear Modulus on Neuronal Network Directionality and Growth Cones’ Morphology via Laser‐Assisted 3D‐Printed Nanostructured Arrays
Authors: Flamourakis George , Dong Qiangrui , Kromm Dimitri , Teurlings Selina , van Haren Jeffrey , Allertz Tim , Smeenk Hilde , de Vrij Femke M. S. , Tas Roderick P. , Smith Carlas S. , Brinks Daan , Accardo Angelo 
Published: October 2024

AbstractIn the present study, the influence of topographic and mechanical cues on neuronal growth cones (NGCs) and network directionality in 3D‐engineered cell culture models is explored. Two‐photon polymerization (2PP) is employed to fabricate nanopillar arrays featuring tunable effective shear modulus. Large variations in mechanical properties are obtained by altering the aspect ratio of the nanostructures. The nanopillar arrays are seeded with different neuronal cell lines, including neural progenitor cells (NPCs) derived from human induced pluripotent stem cells (iPSCs), I3Neurons, and primary hippocampal neurons. All cell types exhibit preferential orientations according to the nanopillar topology, as shown by neurites creating a high number of oriented orthogonal networks. Furthermore, the differentiation and maturation of NPCs are affected by the topographic and mechanical properties of the nanopillars, as shown by the expression of the mature neuronal marker Synapsin I. Lastly, NGCs are influenced by effective shear modulus in terms of spreading area, and stochastic optical reconstruction microscopy (STORM) is employed to assess the cytoskeleton organization at nanometric resolution. The developed approach, involving laser‐assisted 3D microfabrication, neuro‐mechanobiology, and super‐resolution microscopy, paves the way for prospective comparative studies on the evolution of neuronal networks and NGCs in healthy and diseased (e.g., neurodegenerative) conditions.
Effective Upcycling of Degraded NCM Cathode Materials Assisted by Surface Engineering for High‐Performance Lithium‐Ion Batteries
Authors: Chen Long , Xing Chunxian , Yang Zhuoli , Tao Shuqiang , Zhang Yucheng , Wang Guangren , Yang Peng , Song Jiapeng , Chen Jiaqi , Fei Linfeng 
Published: October 2024

AbstractLithium‐ion batteries (LIBs) with ternary oxide cathode materials are the prevalent energy storage devices for electric vehicles, and the huge amounts of spent LIBs pose severe challenges in terms of environmental impact and resource management. Particularly, the proper handling of degraded cathode materials is of central importance for the sustainable and closed‐loop development of LIBs industry. In this context, direct regeneration of degraded ternary oxides toward reusable high‐performance cathode materials is environmentally and economically favorable in contrast to present metallurgical recycling methods. In this work, a simple and effective two‐step method is demonstrated to regenerate the degraded NCM 622 (LiNi0.6Co0.2Mn0.2O2) materials by elemental compensation and structural restoration. Moreover, a multi‐functional LTO (Li4Ti5O12) surface coating is simultaneously designed to guarantee rapid Li+ diffusion and stable surface of the regenerated product. Therefore, the regenerated LTO‐coated NCM materials show excellent electrochemical performance; specifically, the initial discharge capacity (183.0 mAh g−1 at 0.1 C), rate capability (90.0 mAh g−1 at 10 C), and cycling stability (79.3% capacity retention after 200 cycles) are even comparable with those of fresh materials. The as‐established upcycling strategy may shed light on the value‐added recycling of degraded cathode materials and thereby a virtuous cycle of LIBs.
Stability‐Enhanced Variable Stiffness Metamaterial with Controllable Force‐Transferring Path
Authors: Yi Jixuan , Lyu Ronghao , Li Yiwen , Wan Chao , Zhang Kai 
Published: October 2024

AbstractSelf‐contact variable stiffness (SVS) metamaterial offers specific patterns of elastic strain energy storage by changing its force‐transferring path. The change of the elastic strain energy storage patterns further influences the stiffness variation of the SVS metamaterials. However, challenges still arise because typically fabricated SVS metamaterials inevitably contain structural irregularities, eccentricities, and defects. These microstructural imperfections impede the stable generation of designed strain energy storage patterns in the metamaterial, implying that the SVS metamaterials cannot achieve expected stiffness variations. To address this burning question, an SVS metamaterial/meta‐structure design paradigm with eccentric unit designs is proposed, which can realize both stable stiffness variations and high load‐bearing. The theoretical, simulation, and experimental results demonstrate that the SVS chain meta‐structure achieves ≈110 times stiffness variation between the low and high loading conditions. Its load‐bearing can reach more than 1500 N when the meta‐structure falls into the high stiffness stage. Furthermore, some typical functions are demonstrated using the stability‐enhanced SVS metamaterial, including customized mechanical protections for human joints and information transformation regulated by remote mechanical input signals. The results can provide a useful solution for generating a more feasible stability‐enhanced SVS metamaterial/meta‐structure and promote their potential applications in aerospace, medical devices, and robotics.
Tuning the Sensitivity of Photonic Sensors Toward Alkanes Through the Textural Properties of Hybrid Xerogel Coatings
Authors: Rosales‐Reina Beatriz , López‐Torres Diego , Cruz‐Quesada Guillermo , Espinal‐Viguri Maialen , Elosúa César , Reinoso Santiago , Garrido Julián J. 
Published: October 2024

AbstractThis work exemplifies how incorporating organosilane modifiers into silica matrices allows for tuning the optical response of reflection photonic sensors through customizing the textural properties of hybrid xerogel sensing films. Xerogels with propyl molar percentages 0, 5, and 10% are used to construct photonic probes (OFS0pTEOS, OFS5pTEOS and OFS10pTEOS, respectively) by dip‐coating upon optimizing film deposition parameters. The time response of these probes toward a battery of volatile organic compounds (VOCs) comprising species with different functionality, size‐shape, and polarity is systematically analyzed through ON/OFF experiments, revealing that a low propyl content makes the poor‐responding OFS0pTEOS film highly sensitive toward non‐aromatic, large molecules with low‐polar or non‐polar character in OFS5pTEOS. This sensor is particularly sensitive toward alkanes, with globular cyclohexane (cyHex) outperforming elongated n‐hexane. Variable‐temperature calibration curves obtained from step‐by‐step experiments and adsorption–desorption cycles corroborate these observations and allow hysteresis to be quantified. The response to cyHex closely follows VOC concentration changes with the most stable signal among analytes, leading to well‐defined curves with low‐to‐negligible hysteresis. The isosteric enthalpies of cyHex adsorption are obtained for both the bulk material and the sensor, demonstrating labile adsorbate‐adsorbent interactions ruling the sensor response and becoming more exothermic for larger VOC concentrations.
Direct Ink Writing of Cephalopod Skin‐Like Core‐Shell Fibers From Cholesteric Liquid Crystal Elastomers and Dyed Solutions
Authors: Li Shangsong , Yu Kun‐Hao , Garcia Isabel , Nah So Hee , Chui Hiu Ning Tiffany , Tian Ziting , Yang Shu 
Published: October 2024

AbstractDirect ink writing (DIW) of core‐shell structures allows for patterning hollow or composite structures for shape morphing and color displays. Cholesteric liquid crystal elastomers (CLCEs) with liquid crystal mesogens assembled in a helix superstructure are attractive for generating tunable iridescent structural colors. Here, by fine‐tuning the rheology of the core and shell materials, respectively, this study creates droplets or a continuous filament in the core from the precursors of polydimethylsiloxane (PDMS) or poly(vinyl alcohol), whereas CLCE forms the outer shell. By introducing a dye in the droplets, the skin structures of cephalopods, consisting of chromatophores and iridocytes, are mimicked for enhanced color saturation, lightness, and camouflage. After removal of the core material, a CLCE hollow fiber is obtained, which can switch colors upon mechanical stretching and pneumatic actuation, much like papilla along with iridocytes. Further, liquid crystal mesogens assembled in the bulk of the fiber are in polydomain. Thus, the skin appears opalescent at room temperature, much like how leucophores enhance reflectins. Upon heating above the nematic to isotropic transition temperature, the skin becomes transparent. Lastly, a cephalopod model is constructed, where different parts of the model can change colors independently based on different mechanisms.
Investigation on the Necessity of Low Rates Activation toward Lithium‐Sulfur Batteries
Authors: Li Chen , Wang Su , Wang Zhaokun , Li Zuohang , Zhang Chenchen , Ma Yue , Shi Xixi , Zhang Hongzhou , Song Dawei , Zhang Lianqi 
Published: October 2024

AbstractLow rate activation process is always used in conventional transition metal oxide cathode and fully activates active substances/electrolyte to achieve stable electrochemical performance. However, the related working mechanism in lithium‐sulfur (Li‐ battery is unclear due to the multiple complex chemical reaction steps including the redox of sulfur and the dissolution of polysulfides intermediate. Hence, the influencing mechanism of activation process on Li‐S battery is explored by adopting different current densities of 0.05, 0.2, and 1 C in initial three cycles before long‐term cycling tests at 0.2 C (denoted by 0.05, 0.2, and 1‐battery). 0.05‐battery presents the highest initial capacity in activation process, while 0.2‐battery presents superior electrochemical performances after 150 cycles. The similar trend can be found in more long‐term cycling rates such as 0.02, 0.1, 0.5, and 1 C. Potentiostatically Li2S precipitation test demonstrates that rapid generation of Li2S is achieved at higher current density, and S8‐Li2Sn‐Li2S conversion is accelerated according to Tafel plots. However, interfacial electrochemical and physical characterizations suggest that serious lithium dendrite growth will be induced under high current density. Therefore, considering the reaction kinetics and interfacial properties, low rate activation process is unnecessary when cycling current lower than 1 C for Li‐S battery.
Synergetic Combination of Bio‐Electrolytes and Bio‐Fluidic Channels as a Novel Resource of Sustainable Energy
Authors: Nath Nabamallika , Bora Barsha Rani , Gogoi Raktim , Raidongia Kalyan 
Published: October 2024

AbstractExploration for sustainable energy resources is essential to minimize the dependence on fossil fuels and to improve environmental parameters. Here, the possibility of utilizing bio‐waste‐derived electrolytes as an electrical energy resource by placing them across semipermeable membranes prepared through parallel stacking of coir fibers is examined. The nanofluidic membrane (d‐CF‐V) prepared by modifying the inner walls of the bio‐fluidic channels with atomically thin layers of vanadium pentoxide (VO) shows excellent perm‐selectivity (t+ = 0.87, with 1000‐fold concentration difference) and electricity conversion efficiency (≈ 28.2%). With simulated sea and river water, the d‐CF‐V yields output energy up to 2.4 W m−2, similarly with mineral acid bases (0.5 m HCl and 0.01 m NaOH), the d‐CF‐V shows an energy output of 11.8 W m−2. The sun‐dried Garcinia morella (Kuji thekera), and charred peels of Musa balbisiana (banana) are used as sustainable sources of bio‐electrolytes, which in combination with permselective d‐CF‐V yielded a power density of ≈1.4 W m−2. By replacing standard Ag/AgCl electrodes with nanomaterials exhibiting contrasting charge transfer activities, oxidized carbon nanotube membrane (o‐CNT) and polyaniline (PANI) membrane the output voltage is enhanced from –127 to –568 mV and current output is increased from 10.2 to 51.5 µA.
Tailoring the Charge Transfer‐Driven Oxidation in van der Waals Ferroelectric NbOI2 Through Hetero‐Interface Engineering
Authors: Wang Rui , Yuan XiaoJia , Lin Shui , Wang JiaPeng , Liu Yue , He Wen , Shao WenZhu , Sun ZhaoYuan , Fang YuQiang , Cai Jun , Liu Zhi , Xu Cheng‐Yan , Huang FuQiang , Zhen Liang , Zhang ShengLi , Li Yang 
Published: October 2024

Abstract2D transition metal halide oxides (TMHOs) have attracted much interest due to their intriguing ferroelectrics and excellent nonlinear optics, however, their susceptibility to oxidation makes their basic research and practical application a challenge. Therefore, it is crucial to understand the oxidation mechanism and explore effective strategies for protection. Here, taking van der Waals (vdWs) ferroelectric NbOI2 as an example, oxidation mechanisms and tuning the oxidation behaviors of NbOI2 and its heterostructures by a variety of in situ experiments and first‐principles calculations are discovered. The ambient‐pressure X‐ray photoelectron spectra reveal a self‐limiting oxidation in isolated NbOI2, driven by spontaneously formed iodine vacancies that react with oxygen molecules due to their lower formation and adsorption energies. For the heterostructures with a lower Fermi level (such as WSe2) than transition state VI@NbOI2 (NbOI2 rich in I‐vacancies), the charge transfer from NbOI2 to WSe2 drives the continuous and complete oxidation of NbOI2 flakes. Moreover, the heterostructures with a higher Fermi level (such as graphene) than VI@NbOI2 can weaken the oxidation of NbOI2. By linking the energy band structures to oxidation behavior, the work offers a new oxidation mechanism of 2D air‐sensitive materials and a crucial strategy for improving their chemical stability.
Direct and Inverse Photoelectron Spectroscopy Evidence for a Revised Picture of Electronic States of Negative Polarons in n‐Doped C60
Authors: Ren Yutong , Sun Qi , Kuila Suman , Tang Kan , Li Hong , Barlow Stephen , Marder Seth R. , Brédas Jean‐Luc , Kahn Antoine 
Published: October 2024

AbstractDetermining the electronic levels associated with polarons, the fundamental charge carriers in organic semiconductors, is key to understanding the charge transport properties of these materials. Recent findings challenge the traditional view of these electronic levels by highlighting the importance of intra‐molecular Coulomb interactions in polarons. Experimental evidence was previously presented for a revised model of the negative polaron in the case of the polymer semiconductor poly(NDI2OD‐T2); there, the addition of an excess electron was seen to lead to the emergence of a singly occupied state within the energy gap of the undoped material and an unoccupied state above the edge of the conduction states. Here, focus is on a small‐molecule semiconductor, C60, and spectral evidence is provided of a similar picture for the new states appearing upon polaron formation. Specifically, direct and inverse photoemission spectroscopy is used to investigate the density of states in C60 films n‐doped with two dimeric dopants. The Coulomb interaction energy (Hubbard U) of the C60 anion is experimentally determined to be ≈1.1 eV, a value that aligns closely with theoretical predictions.
High‐Accuracy Liquid Flow Monitoring via Triboelectric Nanogenerator Combined with Bionic Design and Common‐Mode Interference Suppression
Authors: He Siyang , Yang Zheng , Wang Jianlong , Wang Xinxian , Zhang Jiacheng , Guo Xin , Li Hengyu , Cheng Tinghai , Wang Zhong Lin , Cheng Xiaojun 
Published: October 2024

AbstractIn the development of smart cities, accurate liquid flow monitoring is essential for the efficient operation of water supply systems. Current flow sensors often face limitations in sensitivity and environmental adaptability, affecting measurement accuracy, and restricting their application in smart city infrastructure. To address these challenges, this study proposes a high‐accuracy flow monitoring method. Specifically, by combining the bionic design with advanced signal processing techniques, the sensitivity and anti‐interference ability are improved, respectively, to enhance the measurement accuracy. Based on this method, a self‐powered flow sensor (SPFS) is developed using noncontact triboelectric nanogenerators (NC‐TENGs) as the sensing unit. The SPFS achieves a sensitivity of 2.07 Hz L−1 min−1 and improves the signal‐to‐noise ratio by more than 13 times over the initial sensing signal. In addition, an intelligent system is developed to accurately measure water resources. The maximum flow rate error rate is less than 0.97% compared to commercial flow sensors. The SPFS demonstrates higher sensitivity and accuracy compared to the existing TENG flow sensors. This study addresses the limitations of existing flow sensors and pioneers a novel solution for enhanced water resource management in smart cities.
Multifunctional Strategies of Advanced Electrocatalysts for Efficient Urea Synthesis
Authors: Ge Riyue , Huo Juanjuan , Lu Peng , Dou Yuhai , Bai Zhongchao , Li Wenxian , Liu Huakun , Fei Bin , Dou Shixue 
Published: October 2024

AbstractThe electrochemical reduction of nitrogenous species (such as N2, NO, NO2−, and NO3−) for urea synthesis under ambient conditions has been extensively studied due to their potential to realize carbon/nitrogen neutrality and mitigate environmental pollution, as well as provide a means to store renewable electricity generated from intermittent sources such as wind and solar power. However, the sluggish reaction kinetics and the scarcity of active sites on electrocatalysts have significantly hindered the advancement of their practical applications. Multifunctional engineering of electrocatalysts has been rationally designed and investigated to adjust their electronic structures, increase the density of active sites, and optimize the binding energies to enhance electrocatalytic performance. Here, surface engineering, defect engineering, doping engineering, and heterostructure engineering strategies for efficient nitrogen electro‐reduction are comprehensively summarized. The role of each element in engineered electrocatalysts is elucidated at the atomic level, revealing the intrinsic active site, and understanding the relationship between atomic structure and catalytic performance. This review highlights the state‐of‐the‐art progress of electrocatalytic reactions of waste nitrogenous species into urea. Moreover, this review outlines the challenges and opportunities for urea synthesis and aims to facilitate further research into the development of advanced electrocatalysts for a sustainable future.