bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Addition of β‐Dicarbonyl Compounds to 2‐Acetyl‐p‐benzoquinone.
Authors: KUCKLAENDER U. + , HERWEG‐WAHL U. , MASSA W. , BAUM G. 
Published: May 2016

AbstractThe structure of the adducts from the quinone (I) and the acetoacetates (II) is revised to be (III).
ChemInform Abstract: Preparation of 3‐Acetylbenzofuran‐2(3H)‐ones and 3‐Acetylnaphthofuran‐ 2(3H)‐ones via Intramolecular Rhodium Carbenoid Insertion.
Authors: HRYTSAK M. , DURST T. 
Published: May 2016

AbstractThe diazo esters (I) undergo ring closure in the presence of rhodium(II) acetate to give the benzofurans (II).
ChemInform Abstract: Asymmetric Dihydroxylation of β‐Substituted N‐(α,β‐Enoyl)bornane‐10,2‐sultams.
Authors: OPPOLZER W. , BARRAS J.‐P. 
Published: May 2016

AbstractOxidation of the title compounds (I) followed by acetalization stereospecifically yields the products (III).
ChemInform Abstract: Synthesis of N‐(Sulfonylamidomethyl)lactames and ‐imides Using the Silyl Method.
Authors: SERGEEV V. N. , SHAPOVALENKO E. P. , BAUKOV YU. I. 
Published: May 2016

AbstractReaction of the N‐chloromethylsulfonamide (I) with N‐trimethylsilyllactams(imides) (II) or of the inversely substituted derivatives (IV) and (V) gives the compounds (III) and (VI) mentioned in the title.
ChemInform Abstract: A Direct Synthesis of γ‐, δ‐, and ε‐Lactones Utilizing SmI2‐Induced Barbier‐Type Reaction in the Presence of Hexamethylphoshoric Triamide (HMPA).
Authors: OTSUBO K. , KAWAMURA K. , INANAGA J. , YAMAGUCHI M. 
Published: May 2016

AbstractThe ω‐bromoalkanecarboxylates (I) undergo ring closure with the ketones (II), (VI), and (X) or the aldehydes (IV) or (VIII) in the presence of samarium diiodide to produce the lactones (III), (V), (VII), (IX), or (XI).
ChemInform Abstract: Oxidative Phosphonylation of Aromatics with Ammonium Cerium(IV) Nitrate.
Authors: KOTTMANN H. , SKARZEWSKI J. , EFFENBERGER F. 
Published: May 2016

AbstractOxidative phosphonylation of the arenes (I) with diethyl phosphite (II) or triethyl phosphite (VI) and cerium ammonium nitrate yields the isomeric arylphosphonates (III) ‐ (V).
ChemInform Abstract: Synthesis and Properties of 3,6‐Diorgano‐3,6‐dithio‐1,2,4,5,3,6‐tetrathiadiphosphorinanes; a New Possibility of Forming S‐S Bonds.
Authors: HAHN J. , NATANIEL T. 
Published: May 2016

AbstractDMSO treatment of the silyl esters (I) affords the six‐membered heterocycles (II).
ChemInform Abstract: Element‐Organic Amine/Imine Compounds. Part 30. η2‐Coordinated σ3‐Phosphazenes.
Authors: SCHERER O. J. , WALTER R. , BELL P. 
Published: May 2016

AbstractStarting with complexes such as (III) with a side‐on coordinated aminoiminophosphine ligand, products with phosphazene ligands in different modes of coordination or with η2 → η1 change in coordination are obtained as shown in the scheme.
ChemInform Abstract: Monohalogenobenzoylhydrazones. Part 3. Synthesis and Structural Studies of Pt(II),Pd(II) and Rh(III) Complexes of Di‐(2‐pyridyl)ketonechlorobenzoyl Hydrazones.
Authors: TOSSIDIS I. A. , BOLOS C. A. , ASLANIDIS P. N. , KATSOULOS G. A. 
Published: May 2016

AbstractThe reactions of PdCl2, K2PtCl4, and RhCl3·3 H2O with the ligands in ethanol yield the stable, diamagnetic 1:1 complexes (I) and (II), respectively.
ChemInform Abstract: Syntheses of the Methyl Glycosides of Curacin, A‐B Fragment Found in Avilamycin‐A and ‐C, Curamycin‐A, Flambamycin and Everninomicin‐2, and of Its Artificial Regioisomer Isocuracin.
Authors: JUETTEN P. + , DORNHAGEN J. , SCHARF H.‐D. 
Published: May 2016

AbstractThe methyl glycoside (III) of curacin, which is the chromophoric A‐B terminus of orthomycins, is synthesized by esterification of the arabino hexopyranoside (Ia) with the acid chloride (II) followed by hydrogenolytic debenzylation.
ChemInform Abstract: Ionic Conductivity, Structural, IR, and Raman Spectroscopic Data of Olivine, Sr2PbO4, and Na2CuF4 Type Lithium and Sodium Chlorides Li2ZnCl4 and Na2MCl4 (M: Mg, Ti, Cr, Mn, Co, Zn, Cd).
Authors: LUTZ H. D. , WUSSOW K. , KUSKE P. 
Published: May 2016

AbstractThe ternary title compounds are prepared by melting together stoichiometric amounts of the halides MCl2 and NaCl or LiCl, slow‐cooling, and subsequent heating (1‐4 weeks).
ChemInform Abstract: Thermal Decomposition of Highly Concentrated Nitric Acid.
Authors: HORN E.‐M. , KEISER H. , SCHOELLER K. 
Published: May 2016

AbstractIn the course of investigations concerning the corrosion resistance of aluminum materials in highly concentrated nitric acid the thermal decomposition of this acid is observed at atmospheric pressure between 0 and 60 °C for up to 273 d. The reversible decomposition reaction, which is shown in the scheme, is second order with respect of HNO3.
ChemInform Abstract: Gaseous Negative Ions from Neutral Molecules and Positive Ions: New Information for Neutralization‐Reionization Mass Spectrometry.
Authors: FENG R. , WESDEMIOTIS C. , MCLAFFERTY F. W. 
Published: May 2016

AbstractCollisional electron transfer to mass‐selected cations or neutrals as an alternative route to negative ions is studied; the resulting mass spectra contain novel information on the structures and chemistry of the precursor cations and neutrals, as well as the product anions.
ChemInform Abstract: Polymerizable Dienoyl Lipids as Spectroscopic Bilayer Membrane Probes.
Authors: TYMINSKI P. N. , PONTICELLO I. S. , O'BRIEN D. F. 
Published: May 2016

AbstractThe UV spectral properties of the unpolymerized dienoyl lipids (I) and (II) in isotropic media and molecular assemblies are measured (tabulated).
ChemInform Abstract: One‐Pot Chemoselective Reductive Alkylation of Nitroarenes: A New General Method of Synthesis of Alkylanilines.
Authors: BARTOLI G. , BOSCO M. , DALPOZZO R. , PETRINI M. 
Published: May 2016

AbstractA new facile and general synthesis of alkylanilines such as (III) or (V) by one‐pot reductive alkylation of nitroarenes such as (II) or (IV) with Grignard compounds such as (I) is reported.
ChemInform Abstract: Stereoselective Syntheses of Substituted Enynes, Dienes, and Alkenes via Stannylation of 1‐Trimethylsilyl 1,3‐Diynes.
Authors: ZWEIFEL G. , LEONG W. 
Published: May 2016

AbstractTreatment of the diyne (I) with the stannylcopper reagent (II) yields the (E)‐alkenynes (III), which undergo a series of lithiation and alkylation or protonation reactions to give the stereodefined enynes (VI), (VIII) or (IX) containing the easily manipulable (trimethylsilyl)ethynyl moiety.
ChemInform Abstract: Models for Reactions of Acetylene on Platinum(111): The μ3‐η2‐Acetylene Derivative.
Authors: DOUGLAS G. , MANOJLOVIC‐MUIR L. , MUIR K. W. , RASHIDI M. , ANDERSON C. M. , PUDDEPHATT R. J. 
Published: May 2016

AbstractThe reaction of (I) with acetylene to give (IIIa) is very rapid, CO loss to yield (IVa) occurs more slowly, excess CO reacts rapidly with (IVa) to give back (IIIa).
ChemInform Abstract: The 1,2‐Didehydronaphthalene to 1H‐Indenylidenecarbene Rearrangement: Formation of 7‐Methyl‐1H‐indenylideneethenone and Its Rearrangement to Acenaphthylen‐4‐ol in a Flash Vacuum Pyrolytic Reaction.
Authors: BROWN R. F. C. , COULSTON K. J. , DOBNEY B. J. , EASTWOOD F. W. , FALLON G. D. 
Published: May 2016

Abstract7‐Methyl‐1H‐indenone generated from (I) via dehydrobromination of (II) is trapped by cyclopentadiene (III) to give the endo adduct (IV), which undergoes transformation into the (E)‐ and (Z)‐esters (VI) and (VII); the structure of (VI) is determined by an X‐ray analysis (space group P21/n, Z=4).
ChemInform Abstract: Synthesis of α‐Iodo Ketones.
Authors: SHA C.‐K. , YOUNG J.‐J. , JEAN T.‐S. 
Published: May 2016

AbstractThe ketones (I) are converted to the α‐iodo derivatives (III) and (IV) by consecutive treatment with hexamethyldisilazane, iodotrimethylsilane (II), sodium iodide, and MCPBA.
ChemInform Abstract: Selective Carbometalation of α,β‐Unsaturated Carbonyl Compounds and Substituted Oxacyclopropanes with Zirconium‐Diene Complexes.
Authors: AKITA M. , MATSUOKA K. , ASAMI K. , YASUDA H. , NAKAMURA A. 
Published: May 2016

AbstractThe cis‐isoprene zirconium complex (I) reacts with the unsaturated ketones (II) and esters (V), forming a C‐C bond between the first atom of the isoprene moiety and the carbonyl group.
ChemInform Abstract: The Wittig Reaction of 2‐t‐Butoxycarbonyl‐1‐methoxycarbonylethylidenetriphenylphosphorane: A Surrogate for the Stobbe Reaction.
Authors: RIZZACASA M. A. , SARGENT M. V. 
Published: May 2016

AbstractThe aldehydes (I), (VI) and (IX) undergo reaction with the phosphorane (IV) and hydrolysis to give the acid esters (II), (VII) and (X), which are cyclized to the naphthalenes (III) and (VIII) or to the dibenzofuran (XI).
ChemInform Abstract: Ketene‐S,N‐acetals as Synthetic Intermediates for Heterocycles. New Synthesis of Multisubstituted Pyridine‐2‐thiones.
Authors: TAKAHATA H. , WANG E.‐C. , NAKAJIMA T. , YAMAZAKI T. 
Published: May 2016

AbstractCoupling of malodinitrile (II) with the ketene‐S,N‐acetals (I) and (V) yields the β‐dicyanomethylene thioamides (III) and (VI) which are cyclized under basic conditions to form the pyridinethiones (IV) or (VII).
ChemInform Abstract: Aryl‐Substituted Purines. Part 1. Synthesis of 7‐Phenylguanine and of 2‐Substituted 7‐Arylhypoxanthines.
Authors: VERKOYEN C. , GOLOVINSKY E. , MUELLER G. + , KOELBEL M. + , NORPOTH K. 
Published: May 2016

AbstractThe synthesis of 7‐phenylguanine (III) is described.
ChemInform Abstract: Synthesis of Some New 2‐(4‐Tolyl)‐3‐(aroyl/4‐aminobenzoyl/4‐arylideneaminobenzoyl)‐4‐oxo‐4H‐2,3‐dihydro‐1,3‐benzoxazines as Possible Anticonvulsants.
Authors: HUSAIN, M I. , AMIR M. 
Published: May 2016

AbstractReaction of the hydroxybenzamide (I) with the tolylaldehyde (II) produces the benzoxazinone (III) which is coupled with the acyl chlorides (IV) to give the N‐aroyloxazinones (Va) ‐ (Ve).
ChemInform Abstract: Stereoselective Syntheses of Alcohols. Part 25. Generation of Enol Borates and Their Addition to Aldehydes.
Authors: HOFFMANN R. W. , DITRICH K. , FROECH S. + 
Published: May 2016

AbstractThe enol borates (VIa) or (VIc) are synthesized by oxidation of the precursors (V) (in turn obtained starting from the butyne (I)) or (VII) with Me3NO.
ChemInform Abstract: Synthesis of 1,2‐Benzoquinones by the Oxidation of 1,4‐Benzodioxins by Peroxide Derivatives.
Authors: KASHIMA C. , TOMOTAKE A. , OMOTE Y. 
Published: May 2016

AbstractDi‐tert‐butyl‐1,4‐benzodioxin (I) is oxidized by m‐chloroperbenzoic acid (II) in methylene chloride to give the quinone (III), together with the anhydride (IV) and the ester (V) in varying yields.
ChemInform Abstract: Intramolecular Michael and anti‐Michael Additions of Thiolate to Conjugated Acetylenic Ketones.
Authors: RUDORF W.‐D. , SCHWARZ R. 
Published: May 2016

AbstractThe α,β‐acetylenic ketones (I) are coupled with carbon disulfide (II), yielding the dithiocarboxylates (III) and (IV) which cyclize to form the thiopyranones (V) and the thiophene derivatives (VI).
ChemInform Abstract: Michael Condensation of β‐(2‐Tetroyl)acrylic Acids and Hetero‐Ring Formation via Reaction of 3‐(2‐Tetralyl)‐6‐acetyl‐5‐oxo‐3‐cyclohexene‐1‐ carboxylic Acid with Some Nucleophilic Reagents.
Authors: ATTIA I. A. , SOLIMAN E. A. 
Published: May 2016

AbstractThe 6‐acetylcyclohexenone (III) is transformed into the heterocycles (IV), (V), and (VII) by standard reactions.
ChemInform Abstract: Cycloaddition Reaction of Heterocumulenes and Ester Enolates: A Novel Synthesis of 4‐Alkylideneazetidin‐2‐ones.
Authors: BATTAGLIA A. , CAINELLI G. , GIACOMINI D. , MARTELLI G. , PANUNZIO M. 
Published: May 2016

AbstractThe ketenimines (II) and the ester enolates (I) form the intermediate adducts (III) which are converted to the 4‐alkylideneazetidinones (IV) upon warming to room temperature.
ChemInform Abstract: Reactions of a Phosphoranimine Anion with Some Organic Electrophiles.
Authors: ROY A. K. , WETTERMARK U. G. , SCHEIDE G. M. , WISIAN‐NEILSON P. , NEILSON R. H. 
Published: May 2016

AbstractThe anion, generated in situ from the N‐silyltrifluoroethoxyphosphoranimine (I) and BuLi, reacts with the electrophiles (II) to give the phosphoranimine derivatives (III).
ChemInform Abstract: Novel Syntheses of γ‐Selenobutyrates from Geminally Diactivated Cyclopropane Derivatives.
Authors: KRIEF A. , TRABELSI M. 
Published: May 2016

AbstractThe cyclopropanedicarboxylic acid derivatives (I) are cleaved with the reagents (II) or (IV) ‐ (VI), yielding the 2‐(methylselenenylalkyl)malonic ester derivatives (III).
ChemInform Abstract: Unprecedented Bonding of a Coordinated Polyenyl Ligand. Synthesis and Molecular Structures of fac‐Trialkyltricarbonyliron Compounds Containing the η3‐Nonafluorocycloocta‐2,5‐diene‐1,4,7‐triyl Ligand and Its Derivatives.
Authors: CARL R. T. , HUGHES R. P. , JOHNSON J. A. , DAVIS R. E. , KASHYAP R. P. 
Published: May 2016

AbstractThe reaction of the complex (I) with PMe3 (II) to yield (III) proceeds with retention of the Fe(CO)3 moiety and bonding of PMe3 to the fluorinated ring rather than to the metal.
ChemInform Abstract: Synthesis of a Catechol Covalently Bound to a Tris(bipyridyl) Complex of Ruthenium: A Fluorescent Potential Hapten.
Authors: LEPOITTEVIN J.‐P. , MATTES H. , BENEZRA C. 
Published: May 2016

AbstractThe ω‐(hydroxypentyl)dimethoxybenzene (Ia) is converted to the bromide (Ib) which is coupled with the monolithiated derivative (II) of 4,4'‐dimethyl‐2,2'‐bipyridyl to produce the compound (III).
ChemInform Abstract: The Structure and Synthesis of the Novel Orchid Pigments Dengibsin and Dengibsinin.
Authors: SARGENT M. V. 
Published: May 2016

AbstractA series of chemical investigations including the direct synthesis of the title compounds confirms unequivocally the structures (VIII) (dengibsinin) and (XV) (dengibsin) for these constituents of Dendrobium gibsonii Lindl.
ChemInform Abstract: Crystal Structure of α‐TlSm(WO4)2.
Authors: MUMM H.‐C. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractSingle crystals of the title compound are obtained by heating a mixture of Tl2WO4, WO3, and Sm2O3 to 900 °C (5:2:1, Pt crucible, 24 h; the excess tungstate is used as a flux).
ChemInform Abstract: Electrolyte‐Induced Changes in Charge Transport Rates Across the CuInSe2 Interface.
Authors: MENEZES S. 
Published: May 2016

AbstractThe role of electrochemical parameters (particular electrolyte pH) in the formation, composition, and photoconductivity of films on the CuInSe2 surface, and their effect on the charge transfer kinetics and on the quantum efficiency, have been investigated by combining a variety of optoelectrochemical methods.
ChemInform Abstract: New Iron(II) Spin‐Crossover Complexes with Heterocyclic Amine‐Derived Ligands and STEPS Experiments on Photogenerated Metastable High‐Spin States.
Authors: ADDISON A. W. , BURMAN S. , WAHLGREN C. G. , RAJAN O. A. , ROWE T. M. , SINN E. 
Published: May 2016

AbstractCationic complexes (I)‐(IV) are prepared by reaction of ligand and Fe2+ in hot MeOH and isolated as Cl‐, ClO4‐ or BF4‐ salts (yields partially given).
ChemInform Abstract: An Unexpected Course of the Meisenheimer Reaction: Aryl Phosphates in the Reaction of Phosphoryl Chloride with 2,3‐Diphenylquinoxaline‐N1‐oxide.
Authors: NASIELSKI J. , HEILPORN S. , NASIELSKI‐HINKENS R. , GEERTS‐EVRARD F. 
Published: May 2016

AbstractThe influence of experimental conditions (e.g.
ChemInform Abstract: Synthesis of Linear Aliphatic Compounds. Part 3. The Synthesis of Paraffins with Very Long Chains.
Authors: BIDD I. , HOLDUP D. W. , WHITING M. C. 
Published: May 2016

AbstractThe routes from C12 starting materials to the long‐chain paraffins derived in the preceding paper are modified to increase the purities and yields of the intermediates.
ChemInform Abstract: Strained Hydrocarbon Skeletons: Pentacyclo(6.4.0.02,4.03,10.07,9)dodecanes by (2 + 2 + 2)Cycloadditions to Substituted Dihydrobullvalenes.
Authors: KIRCHMEYER S. , DE MEIJERE A. 
Published: May 2016

AbstractReaction of the dihydrobullvalenes (Ia)‐(Ic) with tetracyanoethylene (II) yields the title compound (III).
ChemInform Abstract: Base and Acid Catalyzed Reactions of Phenylazo 1‐Naphthyl Ether, a New Reactive Diazoether. Reply to the Kekule Mechanism for the Diazo Coupling Reaction.
Authors: TEZUKA T. , SASAKI K. , ANDO S. 
Published: May 2016

AbstractPhenylazo 1‐naphthyl ether (I) is cleaved with bases or acids to give the products (II) ‐ (V).
ChemInform Abstract: Synthesis, Stereochemistry and Isomeric Conversions of Tetracyclo(10.3.0.02,607,11)pentadecane.
Authors: VOROB'EVA N. S. , PEKHK T. I. , ZEMSKOVA Z. K. , PETROV AL. A. 
Published: May 2016

AbstractCondensation of cyclopentylidenecyclopentanone (I) with cyclopentanone (II) according to a known procedure yields tris(trimethylene)benzene (III) whose hydrogenation affords a mixture (IV) of seven stereoisomers.
ChemInform Abstract: Electrophilic Substitution in Indoles. Part 15. The Reaction Between Methylenediindoles and p‐Nitrobenzenediazonium Fluoroborate.
Authors: JACKSON A. H. , PRASITPAN N. , SHANNON P. V. R. , TINKER A. C. 
Published: May 2016

AbstractThe diazonium tetrafluoroborate (II) reacts under aqueous conditions with the di‐indoles (I) to give the azo compounds (III).
ChemInform Abstract: Synthesis and Transformations of Urazoles Derived from 7,7‐Dicarboxynorcaradiene: Formation of 2,4‐Dioxohexahydro‐1,3,5‐triazines by an Unusual Base‐Catalyzed Rearrangement.
Authors: ADAM W. , GRABOWSKI S. , HINZ R. F. , LUCCHINI V. , PETERS E.‐M. , PETERS K. , REBOLLO H. , VON SCHNERING H. G. 
Published: May 2016

AbstractReaction of the triene (I) with the dione (II) yields the endo‐urazole (III) (no yield given).
ChemInform Abstract: One‐Pot Synthesis of Diaryl Alkyl Carbinols and Substituted Derivatives Through Carbon Monoxide Insertion Reactions into Aryllithiums.
Authors: VITALE A. A. , DOCTOROVICH F. , NUDELMAN N. S. 
Published: May 2016

AbstractThe diaryl alkyl carbinols (IV) are prepared by carbonylation of phenyllithium (I) in THF in the presence of the alkyl bromides (II).
ChemInform Abstract: Intramolecular Cycloaddition of Azoalkenes Derived from Terminal Alkenoic and Alkynoic Acids.
Authors: GILCHRIST T. L. , WASSON R. C. , KING F. D. , WOOTTON G. 
Published: May 2016

AbstractThe azoalkenes (II), (V) or (VIII) derived from (I), (IV) or (VII) undergo cyclization to give the fused pyridazines (IIIa), (VI) and (IX).
ChemInform Abstract: Pteridines. Part 51. A New and Unequivocal Route to C‐6 Carbon‐Substituted Pterins and Pteridines.
Authors: TAYLOR E. C. , RAY P. S. 
Published: May 2016

AbstractReaction of the acetylenes (II) with the bromopyrazine (Ib) gives the 5‐ethynyl derivatives (III) which are cyclized with guanidine hydrochloride (IV) to yield the pteridines (V).
ChemInform Abstract: Synthesis of Macrocyclic Acetals Containing Lipophilic Substituents.
Authors: BRADSHAW J. S. , KRAKOWIAK K. E. , LINDH G. C. , IZATT R. M. 
Published: May 2016

AbstractReaction of the alcohols (I) with the aldehydes (II) yields the ditosylates (III), which undergo cyclization with the diols (IV) to give the title compounds (V).
ChemInform Abstract: Phosphorylation of N‐Methyldiacetamide.
Authors: DMITRICHENKO M. YU. , ROZINOV V. G. , DONSKIKH V. I. , DOLGUSHIN G. V. , FESHIN V. P. , KALABINA A. V. 
Published: May 2016

AbstractN‐Methyldiacetamide (I) reacts with PCl5 to give the bisphosphorylated diene (III) which cyclizes to produce the 1,4‐azaphosphorinium salt (IV) upon heating.
ChemInform Abstract: Synthesis and Isomerization of 2‐Hydroxyalkyloxy‐2‐oxo‐1,3,2‐dioxaarsolanes.
Authors: GAMAYUROVA V. S. , NIYAZOV N. A. , KHALITOV F. G. , ARKHIPOV V. P. 
Published: May 2016

AbstractThe trialkyl arsenates (I) and (IV) react with the diols (II) to give the dioxaarsolanes (III).
ChemInform Abstract: Ultrasound in Organic Synthesis. Part 12. In situ Generation and Uses of Butyllithium Reagents in Several Synthetic Reactions.
Authors: EINHORN J. , LUCHE J.‐L. 
Published: May 2016

AbstractLarge‐scale preparation of the lithium amides (III) is performed by treatment of the corresponding amines (I) with lithium and butyl chloride (II) under ultrasonic irradiation.
ChemInform Abstract: Subvalent Group 14 Metal Compounds. Part 10. Syntheses and Structures of Some Bis(metallo)plumbylenes (Pb(Mo(R)(CO)3)2(OC4H8)) (R: η‐C5H5, η‐C5H3(SiMe3)2‐1,3, or η‐C5Me5); X‐Ray Crystal Structures of (Pb(Mo(η‐C5Me5)(CO)3)2(OC4H8)) and ((Pb(Mo(η‐C5Me5)(CO)3) (Mo(η‐C5Me5)(CO)2(μ‐CO)))2).
Authors: HITCHCOCK P. B. , LAPPERT M. F. , MICHALCZYK M. J. 
Published: May 2016

AbstractTreatment of the lead(II) amide (I) with two equiv. of the appropriate Mo hydrides (II) in THF (III) results in the formation of the three‐coordinate Pb(II) complexes (IV) ((IVc) decomposes within 1 d at 25 °C).
ChemInform Abstract: Monometallic, Homo‐ and Hetero‐bimetallic Complexes Based on Redox Active Tris(3,5‐dimethylpyrazolyl)borato Molybdenum and Tungsten Nitrosyls. Part 6. Synthesis and Electrochemistry of Complexes Containing Saturated Heterocyclic Amide Ligands. X‐Ray Crystal and Molecular Structure of ((Mo(NO)(HB(Me2pz)3)Cl)2(NC4H8N)).
Authors: AL OBAIDI N. , HAMOR T. A. , JONES C. J. , MCCLEVERTY J. A. , PAXTON K. 
Published: May 2016

AbstractThe reaction of the appropriate dichloro complexes with an excess of the cyclic amines leads to the coordinatively unsaturated complexes (I).
ChemInform Abstract: Synthesis, Reactions, and Dynamic NMR Studies of η2‐Vinyl Complexes of Molybdenum and Tungsten, (M(η3‐C(CF3)C(CF3)(L‐L))(CF3CCCF3)(η3‐C5H5)) (L‐L: MeCO‐ 2, Me2PS‐ 2, Et2NCS‐ 2, or Me2NCS‐ 2).
Authors: DAVIDSON J. L. 
Published: May 2016

AbstractReactions of the bis(hexafluorobut‐2‐yne) complexes (I) with acetate (II), dimethyldithiophosphinate or N,N‐dialkyldithiocarbamates (IV) give adducts which exhibit a bis(alkyne) structure containing a monodentate ligand such as (III) (major product) or an isomeric η2‐vinyl structure (V) in which the ligand forms a bridge between the metal and the η2‐vinyl ligand.
ChemInform Abstract: Heteronuclear Complexes Containing Group 6 Transition Metals; Chemical, Spectroscopic, and Theoretical Studies on Some Binuclear Complexes and the X‐Ray Crystal Structure Determination of (WNi(CO)3(PPh3)2(η5‐C5H5)).
Authors: CARLTON L. , LINDSELL W. E. , MCCULLOUGH K. J. , PRESTON P. N. 
Published: May 2016

AbstractReactions of the anions (I) with the Ni complex (II) afford the paramagnetic bimetallic complexes (III).
ChemInform Abstract: Rhodium(I)‐Iron(0) Carbonyl Complexes Containing One Bridging Ph2PCH2PPh2 Ligand, Including the Formation of a Tetranuclear Cluster from a Heterobimetallic Precursor: Crystal Structures of ((OC)4Fe(μ‐Ph2PCH2PPh2)RhCl(CO)) and (Fe2Rh2(μ‐Ph2PCH2PPh2)2(CO)8).
Authors: JACOBSEN G. B. , SHAW B. L. , THORNTON‐PETT M. 
Published: May 2016

AbstractTreatment of the Fe complexes (I) with the dimer (II) gives the complexes (III) which are converted with lithium acetate to the tetranuclear clusters (IV).
ChemInform Abstract: The Chemistry of Tetraphenylcyclopentadienone Complexes of Ruthenium and Rhodium: The X‐Ray Crystal Structure of (Ru(η5‐C5Ph4OC(O)CH(OMe)Ph)(CO)2Cl).
Authors: BAILEY N. A. , JASSAL V. S. , VEFGHI R. , WHITE C. 
Published: May 2016

AbstractThe title complexes (I) and (V) react with L‐(‐)‐(II) with ligand substitution to give (IIIa) or (VI) rather than to form Schiff‐base complexes.
ChemInform Abstract: Preparation and Spectroscopic Study of Functionally Substituted Cyclopentadienides of Thallium(I), Potassium, Rhodium(I), and Iridium(I).
Authors: ARTHURS M. , AL‐DAFFAEE H. K. , HASLOP J. , KUBAL G. , PEARSON M. D. , THATCHER P. , CURZON E. 
Published: May 2016

AbstractA 13C and 1H NMR study is carried out on the compounds (I) (some preparations are described).
ChemInform Abstract: Photochemical Synthesis of Halleridone, Hallerone, Rengyol and Derivatives.
Authors: BRETON J. L. , LLERA L. D. , NAVARRO E. , TRUJILLO J. 
Published: May 2016

Abstract1O2 oxidation of p‐hydroxyphenethyl alcohol (Ia) yields halleridone (II) whereas the same oxidation of the acetate (Ib) leads to the epoxide (III) and hallerone (IV), the latter being transformed to halleridone acetate on standing.
ChemInform Abstract: On the Existence of Discrete TeCl‐ 5 Ions.
Authors: SCHOENHERR T. + 
Published: May 2016

AbstractSolid pentachlorotellurate compounds ATeCl5 (A: Et3NH, Et4N, Bu4N, Ph4P) are prepared by stoichiometric titration of TeCl4 in CH2Cl2 with the corresponding chloride solutions (no yields given).