bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Automatic Assignment of 13C NMR Signals. Part 4. 13C Chemical Shift/Charge Density Linear Relationship Reinvestigated.
Authors: BANGOV I. P. , STEIGER TH. , RADEGLIA R. 
Published: May 2016

AbstractCharge densities calculated by a series of quantum chemical methods such as HMO, EHT, INDO, MNDO are used for automatic assignment.
ChemInform Abstract: Simultaneous Primary and Secondary Coordination of a Neutral Ligand in a Macrocyclic Rh(III) Complex.
Authors: FERGUSON G. , MATTHES K. E. , PARKER D. 
Published: May 2016

AbstractReaction of a macrocyclic polyether with RhCl3 in boiling MeOH, followed by addition of NH4PF6 affords the title complex (I) (no yield given), which crystallizes in the space group P21/n with Z=4.
ChemInform Abstract: Generation and (4 + 3) Cycloaddition of Oxallyl Intermediates from 2‐Bromo‐3‐pentanone and Pentachloroacetone in 2,2,3,3‐Tetrafluoro‐1‐propanol.
Authors: FOEHLISCH B. + , GEHRLACH E. , GEYWITZ B. 
Published: May 2016

AbstractThe bromopentanone (II) reacts with the dienes (I), (VII) or (XI) to give the corresponding (4 + 3) cycloadducts in low to high yields.
ChemInform Abstract: 4,5‐Dihydroisoxazoles. Part 7. Rearrangement Reactions to Cycloadducts from 5‐Amino‐4,5‐dihydro‐4‐methyleneisoxazoles and Cyclopentadienones: Synthesis of 2‐Azatetracyclo(4.3.0.02,4.03,7)nonane Derivatives.
Authors: BALLABIO M. , DESTRO R. , FRANZOI L. , GELMI M. L. , POCAR D. , TRIMARCO P. 
Published: May 2016

AbstractThe isoxazole (I) reacts with the dienes (II) to afford the products (III)‐(VI).
ChemInform Abstract: Organoboranes for Synthesis. Part 7. An Improved General Synthesis of Primary Amines from Alkenes via Hydroboration‐Organoborane Chemistry.
Authors: BROWN H. C. , KIM K.‐W. , SREBNIK M. , SINGARAM B. 
Published: May 2016

AbstractHydroboration of the alkenes (I) with Me2BH generated in situ from (II) yields the monoorganyldimethylboranes (III), which are converted to the amines (V) by treatment with (IV).
ChemInform Abstract: Conversion of 3‐Acetoxy‐6‐acetoxymethyl‐2H‐pyran‐2‐one to Cyclopentenone Derivatives and 1,3‐Cyclopentanedione.
Authors: TAJIMA K. 
Published: May 2016

AbstractThe α‐pyrone (I) reacts with methanol (II) in the presence of 4‐(dimethylamino)pyridine to give the cyclopentenone (III).
ChemInform Abstract: A Reactivity Umpolung Route to Cyclic Homoenolate Aldol Products via α‐Alkoxyorganocuprate Conjugate Additions.
Authors: LINDERMAN R. J. , GODFREY A. , HORNE K. 
Published: May 2016

AbstractThe α‐alkoxyorganocuprates (IV), prepared from the stannanes (I), react with the cyclic enones (V) and (VII) to produce the adducts (VI) or (VIII).
ChemInform Abstract: Preparation and Reaction of γ‐Ethoxy and (Phenylthio)allenylstannanes.
Authors: TAKEDA T. , OHSHIMA H. , INOUE M. , TOGO A. , FUJIWARA T. 
Published: May 2016

AbstractThe alkynes (I) are coupled with the tributylstannylmethyl compounds (II) to give the stannylallenes (III).
ChemInform Abstract: A Novel Synthetic Approach to Biphenyls.
Authors: HO T.‐I. , SHU C.‐S. , YEH M.‐K. , CHEN F.‐C. 
Published: May 2016

AbstractThe halomethylxylenes (I) and (VIII) undergo Wittig‐Horner reaction with the formylxylenes (II) or (IX), yielding the stilbenes (III) or (X).
ChemInform Abstract: Interactions Between Non‐Conjugated Chromophores. Part 28. Regioselective Electrophilic Additions of Bicyclo(2.2.n)alk‐2‐enes Controlled by Remote Epoxide Functions.
Authors: CLARET F. , CARRUPT P.‐A. , VOGEL P. 
Published: May 2016

AbstractThe addition of the sulfenyl chloride (III) to the epoxides (I) and (IV) is regioselective only in the case of (I).
ChemInform Abstract: Z‐s‐Z‐Enaminones and Enaminothiones with a Semicyclic C=C Bond.
Authors: DANNHARDT G. , GEYER Y. , OBERGRUSBERGER R. , ZIEREIS K. 
Published: May 2016

AbstractThe 2‐alkyl cycloimines (I) are lithiated and then coupled with the carboxylates (II), yielding the enaminones (III).
ChemInform Abstract: Fragmentation and Rearrangement of Carbonyl‐Bridged Compounds. Synthesis and Crystal Structure of New Spirocycles Containing Azetidine Rings.
Authors: BOCELLI G. , CHIUSOLI G. P. , COSTA M. , FAMBRI L. 
Published: May 2016

AbstractThe diketones (Ib) and (Ic) undergo decarbonylation and rearrangement in the presence of a base to produce the spiro ketones (IIb) and (IIc).
ChemInform Abstract: Synthesis of Optically Active Olefinic Building Blocks from D‐Ribonolactones: Isopropylidene Derivatives of D‐erythro‐Pentenediol and ‐triol (cis‐4‐Substituted 5‐Vinyldioxolanes).
Authors: JAEGER V. + , HAEFELE B. + 
Published: May 2016

AbstractStarting with the lactone (I) mentioned in the title, various acetonides are synthesized as shown in the reaction scheme.
ChemInform Abstract: Synthesis of Bis(1‐alkyl‐2‐substituted‐benzimidazol‐5‐yl) Ketones and Their Filaricidal Activity.
Authors: CHAUHAN P. M. S. , BHAKUNI D. S. 
Published: May 2016

AbstractThe benzophenone (I) serves as starting material for the synthesis of the compounds (III) which are transformed to title benzimidazoles of type (V).
ChemInform Abstract: Investigation of Diastereoselective C,C‐Bond Formation in the 1‐Position of 1,2,3,4‐Tetrahydroisoquinolines. Part 2. EPC‐Synthesis of Tetrahydroisoquinolines by Diastereoselective Alkylation at the 1‐Position of Phenylalanine‐Derived Precursors. Synthesis of the Alkaloid (+)‐Corlumine.
Authors: HUBER I. M. P. , SEEBACH D. 
Published: May 2016

AbstractA series of alkylation reactions of the carboxylic acids (I), (VI), (IX) and (XI) is investigated.
ChemInform Abstract: Reactions of Diastereomeric Aminobicycloalkyl Meldrum′s Acid Derivatives. Sterically Controlled Transformations at the (4.1.0)‐Bicyclic System.
Authors: BENZING M. , VILSMAIER E. 
Published: May 2016

AbstractInteraction of the amines (II) with the Meldrum's acid derivative (I) causes a displacement of the exo‐amino moiety to give (III).
ChemInform Abstract: Cycloaddition Reactions of Cyclic Ketene N,S‐Acetals with 1,2,4,5‐Tetrazines.
Authors: MARCELIS A. T. M. , VAN DER PLAS H. C. 
Published: May 2016

AbstractThe tetrazines (I) react with the cyclic ketene N,S‐acetals (II) or (III) to give the cycloadducts (IV) and (V).
ChemInform Abstract: α‐Halo Ketoximes in Heterocyclic Synthesis: Polyfunctional Azoles and Azines from α‐Bromo Ketoximes.
Authors: MOHAREB R. M. , HABASHI A. , HAFEZ E. A. A. , SHERIF S. M. 
Published: May 2016

AbstractThe bromo oxime (III) reacts with potassium cyanide (II) to give the isoxazole (I).
ChemInform Abstract: Tricyclic 2,4‐Diaminovinamidines ‐ Readily Accessible, Very Strong CHN‐Bases.
Authors: SCHWESINGER R. 
Published: May 2016

AbstractThe salt (IIIa) is prepared from (I) in a one‐pot reaction; base treatment of (IIIa) yields the free base (IVa).
ChemInform Abstract: Diaza‐nido‐hexaboranes, a Novel Class of Azaboranes.
Authors: BOESE R. , KROECKERT B. + , PAETZOLD P. 
Published: May 2016

AbstractThe diborylamines (III), prepared as shown by the haloboration of the iminoboranes (I), yield, on dehalogenation by Na/K‐alloy, either the novel diaza‐nido‐hexaboranes (IV) or in the case of the sterically demanded (IIId) the azadiboriridine (V).
ChemInform Abstract: Synthesis and Crystal Structure of a Lithium(trimethylacetoxy‐di‐tert‐butylsilanolate).
Authors: DIPPEL K. , KEWELOH N. K. , JONES P. G. , KLINGEBIEL U. , SCHMIDT D. 
Published: May 2016

AbstractWhereas the silanediol (I) reacts with acyl chlorides (II) to give the chlorosilanol (III) and the carboxylic acids (IV), the Li salt (V) when reacted with acid chloride (IIc) forms the title lithium salt (VI) which on reaction with acid chloride (VII) yields the mixed dicarboxyl‐silane (VIII).
ChemInform Abstract: Reaction of Pummerer Rearrangement Intermediate with Aromatic Compounds: A Novel Synthesis of 1‐Substituted‐Aryl‐1‐(methylthio)methanephosphonates.
Authors: KIM T. H. , KIM D. Y. , OH D. Y. 
Published: May 2016

AbstractThe methylsulfinylmethanephosphonate (II), prepared by oxidation of the corresponding methylsulfenyl compound (I), is coupled with the arenes (III) in the presence of trifluoroacetic anhydride and tin tetrachloride to produce the 1‐aryl‐1‐(methylthio)methanephosphonates (IV).
ChemInform Abstract: Study of the Coupling Reaction of Aryldiazonium Salts with Dimethoxyphosphorylacetaldehyde.
Authors: SOKOLOV M. P. , MAVRIN G. V. , GAZIZOV I. G. , IVANOVA V. N. , PAVLOV V. A. , LIORBER B. G. 
Published: May 2016

AbstractThe diazonium salts (II) react with the phosphorylacetaldehyde (I) to give the hydrazones (III).
ChemInform Abstract: Lithium‐Tellurium Exchange. Novel Access to Organo‐Lithium Compounds.
Authors: HIIRO T. , KAMBE N. , OGAWA A. , MIYOSHI N. , MURAI S. , SONODA N. 
Published: May 2016

AbstractThe conversion of the tellurides (I) with butyl‐Li (II) affords the title compounds (III) which are trapped as the alcohols (VI).
ChemInform Abstract: ((η5‐C5Me5)2Ti2P6), a Distorted Dimetallaphospha Cubane.
Authors: SCHERER O. J. , SWAROWSKY H. , WOLMERSHAEUSER G. + , KAIM W. , KOHLMANN S. 
Published: May 2016

AbstractThe title compound (II) is obtained by copyrolysis of the titanocene (I) with white phosphorus.
ChemInform Abstract: Reactions of Tetraphenyltitanium with Organic Acids.
Authors: RAZUVAEV G. A. , VYSHINSKAYA L. I. , VASIL'EVA G. A. 
Published: May 2016

AbstractTetraphenyltitanium (I) reacts with the dicarboxylic acids (II) to give the thermally stable titanium(III) complexes (IV) via the intermediates (III).
ChemInform Abstract: Organoelemental Furan Derivatives. Part 60. Conversion of Dimethyldi(2‐ furyl)germane Under Conditions of Catalytic Hydrogenation.
Authors: LUKEVITS E. , IGNATOVICH L. M. , YUSKOVETS ZH. G. , GOLENDER L. O. , SHIMANSKAYA M. V. 
Published: May 2016

AbstractBoth hydrogenation and hydrogen transfer from hydrogen donors in the presence of Raney‐nickel, palladium on carbon, or rhodium‐black produce mixtures of the compounds (II) ‐ (VI) from the difuryldimethyl germane.
ChemInform Abstract: Arene Complexes with a Half‐Sandwich Structure: The 1:1 Complexes of Mesitylene with SbCl3, SbBr3, BiCl3, and BiBr3.
Authors: SCHMIDBAUR H. , WALLIS J. M. , NOWAK R. , HUBER B. , MUELLER G. + 
Published: May 2016

AbstractMesitylene (I) forms with the halides (II) the stable complexes (III).
ChemInform Abstract: Complexing Ability of Some γ‐Lactone Derivatives. Thermal, Magnetic and Spectral Studies on Cobalt(II), Nickel(II) and Copper(II) Complexes and Their Base Adducts.
Authors: EL‐DISSOUKY A. , FAHMY A. , AMER A. 
Published: May 2016

AbstractThe reaction of an ammoniacal solution of hydrated Co, Ni or Cu chloride with an ethanolic solution of the corresponding lactone under reflux gives the complexes (I) (no yields given), containing 2 or 3 mol of water being partially hydrogen‐bonded to the coordinated ligands.
ChemInform Abstract: Si Heterojunction Bipolar Transistors with Single‐Crystalline β‐SiC Emitters.
Authors: SUGII T. , ITO T. , FURUMURA Y. , DOKI M. , MIENO F. , MAEDA M. 
Published: May 2016

AbstractThe electrical characteristics of β‐SiC are investigated and discussed in terms of the applicability to heterojunction bipolar transistors (HBT).
ChemInform Abstract: The Specific Heat of a High‐Tc Perovskite Superconductor YBa2Cu3O8‐δ
Authors: SHAVIV R. , WESTRUM E. F. JUN. , SAYER M. , YU X. , BROWN R. J. C. , HEYDING R. D. , WEIR R. D. 
Published: May 2016

Abstract(δ = 1.5), prepared by solid‐state reaction of Y2O3, BaO, and CuO at 910 °C, has been measured from 5.3 to 345 K by adiabatic calorimetry.
ChemInform Abstract: Reaction of 4‐Phenyl‐1,2,4‐triazoline‐3,5‐dione with Substituted Butadienes. A Nonconcerted Diels‐Alder Reaction.
Authors: JENSEN F. , FOOTE C. S. 
Published: May 2016

AbstractThe reaction of the butadienes (I) with the title compound (II) in CH2Cl2 yields the expected Diels‐Alder adducts (III) with high stereospecificity (> 200:1).
ChemInform Abstract: 2‐(Phenylsulfonyl)‐1,3‐dienes as Versatile Synthons in Organic Transformations. Multicoupling Reagents and Diels‐Alder Dienes with a Dual Electron Demand.
Authors: BAECKVALL J. E. + , JUNTUNEN S. K. 
Published: May 2016

AbstractThe phenylsulfonyldienes (I), (V) or (X) are stereo‐ and regioselectively functionalized via Michael addition of nucleophiles such as (II) or (VI) to give the allylic sulfones (III), (VII) or (XI).
ChemInform Abstract: General Synthesis of 2‐Hydroxy‐, 3‐Hydroxy‐, and 4‐Hydroxyalkyldimethylsulfonium Salts from Cyclic Ethers.
Authors: OKUMA K. , NAKAMURA S. , OHTA H. 
Published: May 2016

AbstractThe cyclic ethers (I) and (VII) or ethylene carbonate (IX) are cleaved by dimethyl sulfide (II) and trifluoromethanesulfonic acid (III), yielding the hydroxyalkyldimethylsulfonium salts (IV) and (V), (VIII), or (X).
ChemInform Abstract: Electrophilic Cyclization via Stannic Triflate Induction. Synthesis of (.+‐.)‐trans‐Tetrahydroactinidiolide.
Authors: GNONLONFOUN N. , ZAMARLIK H. 
Published: May 2016

AbstractIn general, homogeranic acid cyclizes in the presence of Lewis acids such as SnCl4 to give mixtures of the diastereomers (II) and (III).
ChemInform Abstract: 5‐Acyl 3‐Substituted Benzofuran‐2(3H)‐ones as Potential Antiinflammatory Agents.
Authors: CHAKRABARTI J. K. , EGGLETON R. J. , GALLAGHER P. T. , HARVEY J. , HICKS T. A. , KITCHEN E. A. , SMITH C. W. 
Published: May 2016

AbstractThe acylhydroxyphenylacetic acids (III) are prepared, e.g. by Friedel‐ Crafts acylation of the esters (I) and subsequent saponification.
ChemInform Abstract: Synthesis of 1′‐Methylspiro(3H‐indole‐3,n′‐piperidines) from 1‐Methyl‐ n‐piperidinecarbaldehydes.
Authors: BENITO Y. , CANOIRA L. , MARTINEZ‐LOPEZ N. , RODRIGUEZ J. G. , TEMPRANO F. 
Published: May 2016

AbstractThe isomeric pyridinecarbaldehydes (I) are converted to the dioxolanyl N‐methylpiperidines (VI) as outlined in the reaction scheme.
ChemInform Abstract: Polyaza Cavity Shaped Molecules. Part 13. A Versatile New Terpyridine Synthesis.
Authors: HEGDE V. , JAHNG Y. , THUMMEL R. P. 
Published: May 2016

Abstract8‐Morpholino‐5,6‐dihydroquinoline (I) is coupled with the aldehydes (II) to give the intermediate diones (III) which react with ammonium acetate, yielding the anellated terpyridines (IV).
ChemInform Abstract: Pyrrolo(3,2‐c)piperidines.
Authors: BORISOVA T. N. , VARLAMOV A. V. , SERGEEVA N. D. , SOLDATENKOV A. T. , ZVOLINSKII O. V. , ASTAKHOV A. A. , PROSTAKOV N. S. 
Published: May 2016

AbstractThe 4‐piperidone oximes (I) are cyclized with acetylene (II) to give the pyrrolopiperidines (III) ‐ (V).
ChemInform Abstract: Heterocyclic Diazocarbonyl Derivatives. Part 6. Intramolecular Reaction of 2‐Methoxycarbonyl‐3‐diazoacetylquinoline.
Authors: CHAPYSHEV S. V. , KARTSEV V. G. 
Published: May 2016

AbstractThe methoxycarbonyl(diazoacetyl)quinoline (III), prepared from the carboxylic acid (I) and diazomethane (II) via the acyl chloride, cyclizes in acidic solution to give the anellated quinoline (IV).
ChemInform Abstract: Synthesis and Some Reactions of α‐Phenyl‐β‐9‐anthroylpropionic Acid.
Authors: SOLIMAN E. A. , SALEM M. A. I. , EL‐SHAHED F. A. 
Published: May 2016

AbstractThe anthroylacrylic acid (I) reacts with benzene (II) to produce the title compound (III) which is cyclized, forming the lactone (IV).
ChemInform Abstract: Diazabicycloalkanes with Bridgehead Nitrogen Atoms. Part 15. Reactions of Monoquaternary Salts of Benzo(b)‐1,4‐diazabicyclo(2,2,2)octene with Nucleophilic Reagents.
Authors: LUK'YANCHUK N. P. , SAGALAEVA N. I. , SOBOLEVA V. K. , SHISHKIN G. V. 
Published: May 2016

AbstractMonoalkylation of the diazabicyclooctene (I) gives the quaternary salts (III) which are treated with the nucleophiles (IV), producing the tetrahydroquinoxalines (V).
ChemInform Abstract: Reactions with 2,3‐Dihydro‐3‐oxothieno(3,4‐d)isothiazole 1,1‐Dioxide (Thiophenesaccharin).
Authors: UNTERHALT B. , BODINKA F. , BRUNISCH F. 
Published: May 2016

AbstractThiophenesaccharin (III) reacts with methanol (II)/hydrochloric acid to give the sulfonamide (I).
ChemInform Abstract: Synthesis, Conformation, and Dopaminergic Activity of 5,6‐Ethano‐Bridged Derivatives of Selective Dopaminergic 3‐Benzazepines.
Authors: WEINSTOCK J. , OH H.‐J. , DEBROSSE C. W. , EGGLESTON D. S. , WISE M. , FLAIM K. E. , GESSNER G. W. , SAWYER J. L. , KAISER C. 
Published: May 2016

AbstractStarting with 2,3‐dimethoxycinnamic acid (I), the aminomethylindan (VII) is synthesized as outlined in the reaction scheme.
ChemInform Abstract: Reactions of Bromoacetic Acid with Hexamethyldisilazane and Trimethyl‐(alkylamino)silanes in the Presence of Methanol.
Authors: VORONKOV M. G. , VVEDENSKII V. YU. 
Published: May 2016

AbstractBromoacetic acid (I) reacts with the disilazane (II) in the presence of methanol to give the tris(siloxycarbonylmethyl)amine (III) and the silyl bromoacetate (IV).
ChemInform Abstract: Chemistry of Tri(tert‐butoxy)silyl Isocyanide. Ab initio Calculations of Silyl Cyanide/Isocyanide Energies.
Authors: HERTLER W. R. , DIXON D. A. , MATTHEWS E. W. , DAVIDSON F. , KITSON F. G. 
Published: May 2016

AbstractΔG = 2.7 ±1.1 kcal/mol, ΔH = 2.6 ±1.1 kcal/mol, and ΔS = 0 ±0.6 eu.
ChemInform Abstract: Phosphorylated Acetals.
Authors: MOSKVA V. V. , GUSEINOV F. I. , ISMAILOV V. M. 
Published: May 2016

AbstractThe phosphorylated acetals (III) are prepared either by reaction of the phosphorylated aldehydes (I) with ethyl orthoformate (II) or from the chloral acetal (V) and the phosphites (IV).
ChemInform Abstract: C‐Acylation of Diazomethane with Diethoxyphosphorylacetyl Chloride.
Authors: MIKITYUK A. D. , KASHEMIROV B. A. , KHOKHLOV N. S. 
Published: May 2016

AbstractThe phosphorylated diazoketone (III) is prepared by reaction of the phosphorylacetyl chloride (I) with diazomethane (II) using the Arndt‐ Eistert method.
ChemInform Abstract: Synthesis and Structural Investigation of Biologically Active Complexes of N‐Alkylphenothiazines with Dioxouranium(VI).
Authors: KESHAVAN B. , SEETHARAMAPPA J. 
Published: May 2016

AbstractUranylacetate dihydrate reacts with aqueous solutions of the six phenothiazines to yield the complexes (I).
ChemInform Abstract: Further Studies of a Synthetic Dicopper(I) Oxygen Carrier and Comparison with Hemocyanin.
Authors: LI N. C. , TZOU J. R. , CHEN S. W. , WANG S. M. , CHOU Y. C. , LIANG N. T. , LIN H. J. 
Published: May 2016

AbstractThe synthetic dicopper(I) oxygen carrier (I), prepared by a literature method, serves as an active‐site model of hemocyanin.
ChemInform Abstract: Aldosterone Antagonists. Part 2. New 7α‐(Acetylthio)‐15,16‐methylene Spirolactones.
Authors: NICKISCH K. , BITTLER D. , LAURENT H. , LOSERT W. , CASALS‐STENZEL J. , NISHINO Y. , SCHILLINGER E. , WIECHERT R. 
Published: May 2016

AbstractReaction of the steroid (I) with propargyl alcohol (II) produces the compound (III).
ChemInform Abstract: Intermolecular Rhodium Carbenoid Insertions into the N‐H Bond of β‐Lactams. Synthesis of O‐2‐Isocephems.
Authors: HRYTSAK M. , DURST T. 
Published: May 2016

AbstractThe protected azetidinone (I) and tert‐butyl 2‐diazo‐3‐oxobutyrate (II) undergo a rhodium‐catalyzed coupling reaction, producing the enol (III) which is transformed into the O‐2‐isocephem (IV) by acid‐catalyzed deprotection and subsequent intramolecular ring closure.
ChemInform Abstract: Pyrolysis Products of Bi2(SO4)3. Crystal Structures of Bi26O27(SO4)12 and Bi14O16(SO4)5.
Authors: AURIVILLIUS B. 
Published: May 2016

AbstractBi34(2/3)O36(SO4)16 crystallizes in the monoclinic space group C2/c with Z=1.
ChemInform Abstract: Electron Paramagnetic Resonance Study of the Reactions of Tetrathiomolybdate with Roussin Salts and Esters, and with Some Related Iron Nitrosyls.
Authors: BUTLER A. R. , GLIDEWELL C. , JOHNSON I. L. , WALTON J. C. 
Published: May 2016

AbstractThe (MoS4)2‐ ion reacts in DMF solution with Roussin esters Fe2(SR)2(NO)4 (R: Me, Et, Pr, iPr, Bu, tBu, n‐C5H11) to yield the paramagnetic nitrosyls (I), (II), and the known (Fe(NO)2(SR)2)‐ (III).
ChemInform Abstract: Electrical Conduction in Trivalent Chromium and Nickel Molybdate.
Authors: GAUR K. , LAL H. B. 
Published: May 2016

AbstractResults of measurements of the electrical conductivity σ and the Seebeck coefficient S of the orthorhombic Cr and Ni molybdates at 500‐1200 K are indicative of phase transitions at 780 and 740 K, respectively.
ChemInform Abstract: Evaluation of the Ionicity of the Bonds in the Ionic Conductors: MFeCl4 (M: Alkali Metal) and LiFeBr4.
Authors: CERISIER J. , PALVADEAU P. , ELHAIDOURI A. , DURAND J. , COT L. 
Published: May 2016

AbstractIt is demonstrated that the dielectric model of Levine can be successfully applied to evaluate the bond ionicity within the title compounds.
ChemInform Abstract: Photo‐Inhibition of Passivity Breakdown on Nickel.
Authors: LENHART S. , URQUIDI‐MACDONALD M. , MACDONALD D. D. 
Published: May 2016

AbstractIt is shown that the passivity breakdown on polycrystalline Ni in buffered (pH 9.2) NaCl solution is inhibited by incident white light.
ChemInform Abstract: Crystallographic and Magnetic Properties of a New Series RFe10SiC0.5 (R: Ce, Pr, Nd, Sm).
Authors: LE ROY J. , MOREAU J. M. , BERTRAND C. , FREMY M. A. 
Published: May 2016

AbstractThe title compounds are prepared by arc melting and induction techniques starting from stoichiometric amounts of the binary compounds.
ChemInform Abstract: X‐Ray Crystal Structure of a Macrocyclic Copper Chelate Stable Enough for Use in Living Systems: Copper(II) Dihydrogen 6‐(p‐Nitrobenzyl)‐1,4,8,11‐tetraazacyclotetradecane‐1,4,8,11‐tetraacetate.
Authors: MOI M. K. , YANUCK M. , DESHPANDE S. V. , HOPE H. , DENARDO S. J. , MEARES C. F. 
Published: May 2016

AbstractWith the goal of radioimmunotherapy using 67Cu attached to monoclonal antibodies, the title complex (I) is shown to retain the copper ion for days under physiological conditions.
ChemInform Abstract: A Novel Photochemical Ring Contraction of 4H‐Pyrans. A New Route to Selectively Substituted Cyclobutenes.
Authors: ARMESTO D. , HORSPOOL W. M. , MARTIN N. , RAMOS A. , SEOANE C. 
Published: May 2016

AbstractPhotolytic cleavage of the 4H‐pyrans (I) yields 3‐phenylpropynonitrile (II), together with the α‐cyano enamides (III) and the dicyanocyclobutenylcarboxamides (IV).
ChemInform Abstract: Hexacarbonylmolybdenum(0)‐Induced Desulfonylation of Allylic Sulfones: Nucleophilic Substitution and Reductive Desulfonylation.
Authors: MASUYAMA Y. , YAMADA K. , KURUSU Y. 
Published: May 2016

AbstractThe reaction of α‐ and γ‐substituted allylic sulfones (I) and (VI) with Mo(CO)6 and carbon nucleophiles (II) results in substitution at the α‐position to yield (III), (V), and/or at the γ‐position to give (IV), (VII).
ChemInform Abstract: Tandem Arylation‐Reduction of Acyl Heterocycles. Convenient Synthesis of Benzyl Heterocycles.
Authors: HALL S. S. , FARAHAT S. E. 
Published: May 2016

AbstractHetaryl aldehydes and ketones, e.g. (I), (X), and (XII), are coupled with the phenyllithium compounds (II) and then directly reduced with lithium in liquid ammonia to yield the corresponding benzylic derivatives such as (III), (XI), and (XIII).
ChemInform Abstract: Homolytic Transformations of Alcohol and Glycol Formates.
Authors: NURBERDIEV R. , KHEKIMOV YU. K. , ROL'NIK L. Z. , ZLOTSKII S. S. , RAKHMANKULOV D. L. 
Published: May 2016

AbstractThe radicalic decarboxylation of the monoformates (I), the diformate (IV), and the triformates (VII) and (XI) is studied.
ChemInform Abstract: Palladium‐Hydroquinone Catalyzed Electrochemical 1,4‐Oxidation of Conjugated Dienes.
Authors: BAECKVALL J. E. + , GOGOLL A. 
Published: May 2016

AbstractElectrochemical oxidation of cyclohexa‐1,3‐diene (I) in acetic acid (II) yields predominantly the trans‐diacetoxycyclohexene (IIIa).
ChemInform Abstract: A Convenient Method for the Stereoselective Synthesis of 3‐Phenyl‐1‐alkynes.
Authors: CAPORUSSO A. M. , POLIZZI C. , LARDICCI L. 
Published: May 2016

AbstractThe bromoallenes (I) are coupled with the organomagnesium cuprates (II), yielding a mixture of the acetylenes (III) and the trisubstituted allenes (IV).
ChemInform Abstract: Isolation of a Substituted Benzyltoluene from Trifluoromethanesulfonic Acid‐Catalyzed Acylation of Methylcyclohexene.
Authors: ROUSSEL C. , SHAIMI L. 
Published: May 2016

Abstract2,6‐Dichlorobenzoyl chloride (I) is coupled with 1‐methylcyclohexene (II) in the presence of an acid to give the dichlorobenzyltoluene (III).