bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Hydrothermal Synthesis of Sodium Tungstates.
Authors: REIS K. P. , RAMANAN A. , WHITTINGHAM M. S. 
Published: May 2016

AbstractIt is shown that tungsten trioxide structures containing intercalated sodium ions (NaxWO3+δ) can be prepared in either the hexagonal or the cubic pyrochlore structure by careful control of the pH during hydrothermal acid hydrolysis of Na2WO4·2 H2O (pH 4.5‐1.5 adjusted with 1 M HCl, 155 °C, autogeneous pressure (∼5 atm), stainless steel acid digestion bombs, 3 d; ∼20% yield).
ChemInform Abstract: The UV‐Visible Absorption and Fluorescence of Some Substituted 1,8‐Naphthalimides and Naphthalic Anhydrides.
Authors: ALEXIOU M. S. , TYCHOPOULOS V. , GHORBANIAN S. , TYMAN J. H. P. , BROWN R. G. , BRITTAIN P. I. 
Published: May 2016

AbstractUV/VIS and fluorescence properties in abs.
ChemInform Abstract: Intramolecular Charge Transfer in Donor‐Acceptor Molecules.
Authors: SLAMA‐SCHWOK A. , BLANCHARD‐DESCE M. , LEHN J.‐M. 
Published: May 2016

AbstractThe photophysical properties of two series of push‐pull polyenes (I)/(III)/(V)/(VII) and (II)/(IV)/(VI)/(VIII) are reported.
ChemInform Abstract: Diastereoselective Reduction of α,α‐Difluoro β‐Hydroxy Ketones to syn‐ and anti‐2,2‐Difluoro‐1,3‐diols.
Authors: KUROBOSHI M. , ISHIHARA T. 
Published: May 2016

AbstractThe reduction of difluoro hydroxy ketones such as (I) with DIBAL gives mixtures of syn‐ and anti‐diols, e.g. (II) + (III), in varying ratios.
ChemInform Abstract: Stereoselective Synthesis of All Four Geometric Isomers of Internal 1,3‐Butadienes by the Condensation Reaction of Aldehydes with the γ‐Trimethylsilyl‐Substituted Allylboranes.
Authors: WANG K. K. , GU Y. G. , LIU C. 
Published: May 2016

AbstractHydroboration of the allene (I) with the boranes (II) or (VIII) produces the corresponding γ‐trimethylsilyl‐substituted allylboranes which condense smoothly with aldehydes such as (III) to afford, after desilylation by either basic or acidic work‐up, the dienes (IV)‐(VII).
ChemInform Abstract: Asymmetric Catalyses. Part 55. Optically Active Deltacyclanes and Deltacyclenes by Enantioselective Catalysis.
Authors: BRUNNER H. , MUSCHIOL M. , PRESTER F. 
Published: May 2016

AbstractThe reaction of norbornadiene (I) with acrylonitrile in the presence of a NORPHOS‐containing catalyst demands drastic conditions and leads to diastereomeric mixtures of deltacyclanes with a small optical induction.
ChemInform Abstract: The Hydrolysis of Azetidinyl Amidinium Salts. Part 1. The Unimportance of Strain Release in the Four‐Membered Ring.
Authors: PAGE M. I. , WEBSTER P. , GHOSEZ L. 
Published: May 2016

AbstractThe alkaline hydrolysis of the salts (I), (V), and (VIII) is examined with respect to the effect of structural changes within the amidinium moiety.
ChemInform Abstract: New Methodology for Conjugate Additions of Allylic Ligands to α,β‐Unsaturated Ketones: Synthetic and Spectroscopic Studies.
Authors: LIPSHUTZ B. H. , ELLSWORTH E. L. , DIMOCK S. H. , SMITH R. A. J. 
Published: May 2016

AbstractMichael additions of allylic ligands to a variety of α,β‐unsaturated ketones such as (I), (IV), or (VII) can be effected in synthetically useful yields with in situ generated allylcopper reagents such as (II), (V), (VIII) in the presence of trimethylchlorosilane.
ChemInform Abstract: Transition Structures of the Lewis Acid Catalyzed Diels‐Alder Reaction of Butadiene with Acrolein. The Origins of Selectivity.
Authors: BIRNEY D. M. , HOUK K. N. 
Published: May 2016

AbstractFour transition structures for the Diels‐Alder reaction of CH2=CH‐CH=CH2 + CH2=CH‐CHO complexed with BH3 are located with ab initio calculations at the RHF/3‐21G level, and activation energies are calculated with the 6‐31G* basis set.
ChemInform Abstract: 1,3‐Dipolar Cycloadditions of 2‐Ethoxy‐ and 2‐(Ethylthio)‐1‐azetines with Nitrilimines.
Authors: LUHESHI A.‐B. N. , SMALLEY R. K. , KENNEWELL P. D. , WESTWOOD R. 
Published: May 2016

AbstractDiarylnitrilimines, generated in situ from the corresponding hydrazonyl halides (II), (V), or (VIII), undergo cycloaddition reaction with the ethoxy‐ and ethylthioazetines (Ia) and (Ib) to form the primary cycloadducts expected.
ChemInform Abstract: Catalytic Asymmetric Aldol Reaction of Silyl Enol Ethers with Aldehydes by the Use of Chiral Diamine‐Coordinated Tin(II) Triflate.
Authors: MUKAIYAMA T. , KOBAYASHI S. , UCHIRO H. , SHIINA I. 
Published: May 2016

AbstractUsing the complex of the chiral diamin (I) with tin(II) triflate as the catalyst, highly enantioselective aldol reaction of the silyl enol ether (II) with the aldehydes (III) is performed.
ChemInform Abstract: Photochromism of Spiropyrans in Aluminosilicate Gels.
Authors: PRESTON D. , POUXVIEL J.‐C. , NOVINSON T. , KASKA W. C. , DUNN B. , ZINK J. I. 
Published: May 2016

AbstractThe photochromism of spiropyrans (I) is studied by transient absorption and luminescence spectroscopy.
ChemInform Abstract: Superoxide Oxidation: A Novel Route to Aromatic 1,2‐Dicarboxylic Acids.
Authors: SOTIRIOU C. , LEE W. , GIESE R. W. 
Published: May 2016

AbstractPotassium superoxide and 18‐crown‐6 in an aprotic medium represent a reagent system for the mild oxidative cleavage of cyclic ketones fused to aromatic rings or phenols.
ChemInform Abstract: Telomerization of Vinylidene Fluoride with CCl4 and R‐CCl3.
Authors: BOUTEVIN B. , FURET Y. , LEMANACH L. , VIAL‐REVEILLON F. 
Published: May 2016

AbstractReaction of vinylidene fluoride (II) with tetrachloromethane (Ia), 2,2,2‐trichloroethanol (Ib), or methyl trichloroacetate (Ic), is induced by radical or redox systems to give the telomers (III).
ChemInform Abstract: A Facile and Convenient Synthetic Route to 1‐Amino‐4,4‐bis(trifluoroacetyl)‐ and 1‐Amino‐4‐trifluoroacetyl‐1,3‐butadienes.
Authors: HOJO M. , MASUDA R. , OKADA E. 
Published: May 2016

AbstractThe dihydropyran (I) is cleaved with secondary amines such as (II) to give the 1‐amino‐4,4‐bis(trifluoracetyl)‐1,3‐butadienes (III).
ChemInform Abstract: Studies of the Synthetic Application of the Elemento‐Organic Compounds of Groups 15 and 16. Selective Acetalization of Aldehydes with Trialkoxystibine Using Allyl Bromide.
Authors: LIAO Y. , HUANG Y.‐Z. , ZHU F.‐H. 
Published: May 2016

AbstractThe aldehydes (I) are converted to the acetals (III) by treatment with the trialkoxystibines (II) in the presence of allyl bromide.
ChemInform Abstract: Synthesis of Functionally Substituted 1,3‐Diaza‐1,3‐butadienes.
Authors: MAZUMDAR S. N. , MAHAJAN M. P. 
Published: May 2016

AbstractDiazabutadienes such as (III) and (V) mentioned in the title are prepared by reaction of the corresponding thiourea derivatives (I) and (IV) with methyl iodide (II).
ChemInform Abstract: Intermolecular Carbon‐Carbon Bond Forming Reactions Involving Allylic Sulfones.
Authors: HARVEY I. W. , PHILLIPS E. D. , WHITHAM G. H. 
Published: May 2016

AbstractVinyl acetate (I) and the alkenes (IVa) ‐ (IVc) undergo C‐C coupling reaction with the sulfones (II) under free‐radical conditions to produce the unsaturated sulfones (III) or (Va) ‐ (Vc).
ChemInform Abstract: Synthesis of Multi‐Bridged Cyclophanes by Means of (2 + 2)Photocycloaddition. Stereocontrol of Cyclobutane‐Linkage by Methoxyl Group.
Authors: OKADA Y. , SUGIYAMA K. , WADA Y. , NISHIMURA J. 
Published: May 2016

AbstractThe α,ω‐bis(p‐hydroxyphenyl)alkanes (I) are converted to the tetravinyl compounds (VII) in a five‐step reaction sequence as outlined in the reaction scheme.
ChemInform Abstract: Ethynologues of Triphenylmethane Dyes. Part 9. 3,6‐Bis(dimethylamino)fluorenylium Dye Ethynologues: New Highly Coloured π‐Electron Systems.
Authors: NAKATSUJI S. , NAKAZUMI H. , FUKUMA H. , YAHIRO T. , NAKASHIMA K. , IYODA M. , AKIYAMA S. 
Published: May 2016

Abstract3,6‐Bis(dimethylamino)fluorenone (I) is coupled with the potassium arylacetylides (II) to produce the arylalkynylfluorenols (III) which are converted into the fluorenylium salts (V) by treatment with perchloric or tetrafluoroboric acid (IV).
ChemInform Abstract: Stabilisation of the Thromboxane Ring System by Electron‐Withdrawing Substituents. Mechanism and Reactivity in the Hydrolysis of Alkyl and Aryl Oxetane Acetals.
Authors: KIRBY A. J. , RYDER H. , MATASSA V. 
Published: May 2016

AbstractInterested in stabilising the oxetane acetal ring system in thromboxane, kinetics of acid‐catalysed hydrolysis are measured as a function of pH for eleven oxetane acetals such as (III), (V), and (VII).
ChemInform Abstract: Cyclization of Imine Radicals Derived from Sulfenylimines: A Simple Access to δ1‐Pyrrolines.
Authors: BOIVIN J. , FOUQUET E. , ZARD S. Z. 
Published: May 2016

AbstractThe γ,δ‐unsaturated aldehyde (I) reacts with the sulfenamide (II) to give the sulfenylimine (III) which is converted to a mixture of cis‐and trans‐isomers of Δ1‐pyrroline (IV) on treatment with tri‐n‐butylstannane.
ChemInform Abstract: Formation of 3‐Amino‐1,5,6,7‐tetrahydro‐4H‐indol‐4‐ones from 2‐(2‐Oxo‐2‐arylethyl)‐1,3‐cyclohexanediones and N,N‐Disubstituted Hydrazines.
Authors: NAGARAJAN K. , SHAH R. K. 
Published: May 2016

AbstractThe phenacyldimedones (I) react with the disubstituted hydrazines (II) forming the tetrahydroindolones (III).
ChemInform Abstract: 4‐ and 5‐Trifluoromethylimidazoles. Novel Cyclization of Trifluoroacetylated Aldehyde Dimethylhydrazones.
Authors: KAMITORI Y. , HOJO M. , MASUDA R. , OHARA S. , KAWASAKI K. , KAWAMURA Y. , TANAKA M. 
Published: May 2016

AbstractDimethylhydrazones, e.g. (IIIa), undergo cyclization to give mixtures of the title imidazoles such as (IVa) and (Va).
ChemInform Abstract: Addition of N‐Methylnitrone to 1‐Bromo‐1‐perfluoroalkylethene. A Two Step 1,3‐Dipolar Cycloaddition Reaction.
Authors: FAYN J. , CHAMBON A. 
Published: May 2016

AbstractReaction of the 1‐bromo‐1‐perfluoroalkylethenes (I) with in situ generated N‐methylnitrone in an alcoholic solution gives the 5‐alkoxy‐2‐methyl‐5‐perfluoroalkylisoxazolidines (IV).
ChemInform Abstract: Application of Phase‐Transfer Catalysis in Reactions with Some Rhodanine Derivatives.
Authors: EL‐SHAFEI A. K. , EL‐SAYED A. M. , SULTAN A. , ABDEL‐GHANY H. 
Published: May 2016

AbstractA series of substitution, addition and condensation reactions using the thionothiazolidinone (I) in solid‐liquid two‐phase systems are reported.
ChemInform Abstract: Synthesis of 2‐Aryl(1,2,4)triazolo(5,1‐b)benzoxazoles by Oxidative Cyclization of N‐(Benzoxazol‐2‐yl)benzamidines.
Authors: SAMBAIAH T. , REDDY K. K. 
Published: May 2016

AbstractThe aminobenzoxazoles (I) are coupled with the benzonitriles (II) in the presence of tin tetrachloride to produce the benzamidines (III).
ChemInform Abstract: Superoxide Dismutase‐Like Activity of 1,2,3‐Triazole Derivatives.
Authors: BIAGI G. , LIVI O. , RAMACCIOTTI G. L. , SCARTONI V. , BAZZICHI L. , MAZZONI M. R. , LUCACCHINI A. 
Published: May 2016

AbstractThe 1,2,3‐triazole (III) is prepared by cycloaddition reaction of the azide (I) with vinyl acetate (II), followed by bromination.
ChemInform Abstract: Potential Non‐Steroidal Estrogens and Antiestrogens. Part 2. Ylids of Heterocycles. Part 10. A New and Efficient Synthesis of Coumestan and Coumestrol.
Authors: LASCHOBER R. , KAPPE T. 
Published: May 2016

AbstractThe hydroxycoumarins (I) are coupled with the diacetoxyiodobenzenes (II) to give the iodonium ylides (III).
ChemInform Abstract: Model Synthetic Studies for the Construction of 5H‐Phenanthro(4,5‐bcd)pyran and Pyrone Systems.
Authors: MAJUMDER P. L. , SARKAR A. K. 
Published: May 2016

AbstractIsovanillyl alcohol (I) is coupled with the benzyl bromide (II) to give the ether (III) which is converted to the chloride (IV).
ChemInform Abstract: A Simple Synthesis of Dihydroxybipyridyls.
Authors: NAUMANN C. , LANGHALS H. 
Published: May 2016

AbstractThe 2‐bromo‐3‐hydroxypyridines (I) are coupled with the Zn/Ni reagent, prepared in situ from zinc powder and NiCl2, in the presence of triphenylphosphine to produce the title compounds (II).
ChemInform Abstract: Potential Antidepressants and Tranquillizers: Synthesis of Some 9‐(Aminoalkoxy)‐2,3,6,7‐tetrahydro‐1H,5H‐benzo(ij)quinolizines and 1‐(Substituted Amino)‐3‐(1‐naphthoxy)‐2‐propanols.
Authors: VEJDELEK Z. , PROTIVA M. 
Published: May 2016

AbstractDemethylation of 9‐methoxyjulolidine (I) according to a novel procedure affords the desired 9‐hydroxyjulolidine hydrobromide (II) in quantitative yield.
ChemInform Abstract: New Intermolecular Benzyne Cycloaddition Approach to Benzophenanthridines.
Authors: MEIRAS D. P. , GUITIAN E. , CASTEDO L. 
Published: May 2016

AbstractThe pyrones (I) react with dehydrobenzene (II), generated in situ from benzenediazonium‐2‐carboxylate by thermal decomposition, to give the polycyclus (III).
ChemInform Abstract: Synthesis of 4‐Oxo‐4H‐pyrido(3′,2′:4,5)furo(3,2‐d)‐1,3‐oxazines.
Authors: WAGNER G. , PRANTZ J. 
Published: May 2016

AbstractThe 2‐pyridone derivatives (I) are O‐alkylated with ethyl chloroacetate (II) to yield the pyridyl ethers (III) which are cyclized, forming the furo(2,3‐b)pyridine derivatives (IV).
ChemInform Abstract: A New Method for the Preparation of 6‐Methyl‐1,2,3‐oxathiazine‐4(3H)‐one 2,2‐Dioxide Potassium Salt (Acesulfame K).
Authors: LINKIES A. , REUSCHLING D. B. 
Published: May 2016

AbstractDiketene (I) is coupled with triethylammonium amidosulfonate (II) to produce the acetoacetamide‐N‐sulfonic acid (III) which is cyclized upon treatment with SO3 and subsequently converted into the artificial sweetener (V) by treatment with KOH (IV).
ChemInform Abstract: Research on Psychotropic Agents. Part 3. Antidepressant Activity and Neuropsychobehavioural Effects of New 5H‐Pyrrolo(1,2‐b)(1,2,5)benzotriazepine Derivatives.
Authors: STEFANCICH G. , ARTICO M. , SILVESTRI R. , PANTALEONI G. C. , GIORGI R. , PALUMBO G. 
Published: May 2016

AbstractThe benzotriazepines (III) and (VIII) are prepared from the anilines (II) and (VII) by reaction with the aldehydes (I).
ChemInform Abstract: Reaction of 1,1‐Dicyano‐2,2‐bis(trifluoromethyl)ethylene with Arylamines.
Authors: KOMAROV K. V. , CHKANIKOV N. D. , GALAKHOV M. V. , KOLOMIETZ A. F. , VOKIN A. V. 
Published: May 2016

AbstractThe course of C‐alkylation of activated arylamines, e.g. (II), with 1,1‐dicyano‐2,2‐bis(trifluoromethyl)ethylene (I) is investigated.
ChemInform Abstract: Convenient Stereoselective Syntheses of 6E‐ and 6Z‐5,6‐Dimethyl‐8‐silyl‐6‐octenals.
Authors: ASAO K. , IIO H. , TOKOROYAMA T. 
Published: May 2016

AbstractThe Z‐enol phosphate (IV) is produced by consecutive reaction of the dianion of the β‐keto ester (I) with the butyl bromide (II) and the chlorophosphate (III).
ChemInform Abstract: The Addition of Sodium Hydrogen Telluride to Unactivated Carbon‐Carbon Double Bonds.
Authors: BARTON D. H. R. , BOHE L. , LUSINCHI X. 
Published: May 2016

AbstractAddition reaction of sodium hydrogen telluride with the unactivated alkenes (Ia) and (Ib) yields predominantly the Markovnikov‐type adducts (III) and (IV).
ChemInform Abstract: 2‐Alkyl‐5,5‐dimethyl‐1,3,2‐dioxaphosphorinan‐2‐ones α‐Lithiated Carbanions. Synthesis, Stability, and Conformation.
Authors: PATOIS C. , RICARD L. , SAVIGNAC P. 
Published: May 2016

AbstractThe formation of the desired compound by the action of an alkyl lithium reagent upon the parent phosphate cannot be performed owing to a higher electrophilicity of the phosphorus center.
ChemInform Abstract: Arene Derivatives of Zirconium(II) and Hafnium(II).
Authors: CALDERAZZO F. , PALLAVICINI P. , PAMPALONI G. 
Published: May 2016

AbstractIn a search for Zr and Hf organometallics in oxidation states lower than four, the title compounds are tried to prepare as olefin polymerization precursors.
ChemInform Abstract: A New Type of Organocobalt Complex with a Buckled Equatorial Ligand.
Authors: CHOO P. L. , MULICHAK A. M. , JONES R. W. JUN. , BACON J. W. , PETT V. B. , ZACHARIAS D. E. 
Published: May 2016

AbstractStarting with the Schiff base condensation product (I) (yield 68%) from 2,3‐butanedione monooxime and 1,4‐diaminobutane the Co(III) complexes (III) and (VI) with unusual steric properties are prepared as model compounds according to the scheme.
ChemInform Abstract: Evidence for Some Pentadentate Coordination in Ethylenediamine‐N,N′‐diacetato‐N,N′‐di‐3‐propionatonickelate(II).
Authors: FRANK T. , EVILIA R. F. 
Published: May 2016

AbstractThe 1H and 13C contact shifted NMR spectra of the title complex are reported as a function of temperature.
ChemInform Abstract: Amine Nickel Complexes. Part 6. Synthesis, Structure, and Reactivity of (tmeda)Ni(C2F4).
Authors: KASCHUBE W. , SCHROEDER W. + , POERSCHKE K. R. + , ANGERMUND K. , KRUEGER C. + 
Published: May 2016

AbstractThe title complex (IV) (space group P21/n, Z=4) is prepared by reaction of Ni(cod)2 (I), (trans,trans,trans‐1,5,9‐cyclododecatriene)‐Ni or tris(ethylene)‐Ni with tmeda (II) and tetrafluoroethene (III) in 91‐97% yield.
ChemInform Abstract: Syntheses and Reactivity of Acetylide‐Containing Clusters of Group 1B Metals. Part 7. Preparation and Possible Structures of the Novel Pentanuclear (Au3Ag2(C2Ph)6)‐, (Ag5(C2Ph)6)‐, and (Ag4Cu(C2Ph)6)‐ Clusters. The Reactivity of the Polymer Complexes ((AuAg(C2Ph)2)n) and ((AuCu(C2Ph)2)n).
Authors: ABU‐SALAH O. M. , AL‐OHALY A. R. A. , MUTTER Z. F. 
Published: May 2016

AbstractThe pentanuclear title clusters (III) are obtained as shown.
ChemInform Abstract: Synthesis of Dinuclear Gold(I)‐, ‐(II), and ‐(III) Complexes Containing Ylide Ligands ((RO2C)CHPPh2CH(CO2R))‐ (R: Me or Et) and Trinuclear Gold(I) Complexes Containing Ylide Ligands ((RO2C)CPPh2CH(CO2R))2‐ (R: Me or Et).
Authors: VICENTE J. , CHICOTE M.‐T. , SAURA‐LLAMAS I. 
Published: May 2016

AbstractThe dinuclear Au(I) complexes (III), synthesized from the Ag analogues (I), are halogenated with equivalent amounts of PhI·Cl2 (IV) or I2 to give the Au(II) derivatives (V) and with an excess of Cl2 or I2 to yield the Au(III) complexes (VI).
ChemInform Abstract: Reactions of Ruthenium(II)‐Coordinated Phenyl Phosphines: Synthesis and X‐Ray Crystal Structures of the Orthometalated Complexes Cyclic (Ru(C6H4PR1R2)(CH2SiMe3)(η6‐C6Me6)) (R1 = R2: Ph; R1: Ph, R2: Me; R1 = R2: Me) and of ((Ru(CH2SiMe3)2(.mu±sigma.,η6‐PMe2Ph))2) Containing Bridging Dimethylphenylphosphine Ligands.
Authors: DIVERSI P. , INGROSSO G. , LUCHERINI A. , MARCHETTI F. , ADOVASIO V. , NARDELLI M. 
Published: May 2016

AbstractThe dichloro(tert.‐phosphine)(η6‐benzene)‐Ru(II) compounds (I) and (IV) react with an excess of the silylmethyl‐Mg compound (II) followed by hydrolysis to give the corresponding orthometalated complexes (III) (space group P21/c, Z=4) as well as (V) (P21/a, Z=4) and (VI) (P1, Z=2).
ChemInform Abstract: Secondary Phosphine Chalcogenides. Part 11. The Reaction of the Bis(2,4‐pentanedionato) Complexes of the Nickel Triade with Secondary Phosphane Sulfides, R2P(S)H (R: Ph, tBu). Crystal Structure of (Pd2(μ‐SPt‐Bu2)2(η2‐SP‐tBu2)2). A Comparison of the η2‐ and the μ‐Coordination Mode of the R2PS‐ Ligand.
Authors: WALTHER B. , HARTUNG H. , MESSBAUER B. , BAUMEISTER U. , MASCHMEIER M. , DARGATZ M. , HETZKE I. 
Published: May 2016

AbstractDepending on the P substituent the title reactions lead to bis(μ‐thiophosphinito)bis(η2‐thiophosphinito) complexes in the cis (III) or trans arrangement (IV) (yield 70/66%).
ChemInform Abstract: Synthesis and Characterization of (Pt(CN)(AuCN)(AuPPh3)8)(NO3) and Pt(CO)(AuPPh3)6(AuCN)2. Crystal Structure of (Pt(CN)(AuCN)(AuPPh3)8)(NO3).
Authors: BOUR J. J. , SCHLEBOS P. P. J. , KANTERS R. P. F. , BOSMAN W. P. , SMITS J. M. M. , BEURSKENS P. T. , STEGGERDA J. J. 
Published: May 2016

AbstractThe cationic title cluster (III) (space group P21/n, Z=4) can be prepared by an oxidative addition reaction with (Au(CN)2)‐ (II) as shown.
ChemInform Abstract: First Chelate Complexes of 4‐Mercapto‐1‐methylpiperidine. Synthesis and Characterization of ((M(μ‐SC5H9NMe)X)2) (M: PdII, X: Cl, Br, or I; M: PtII, X: Br or I). Crystal and Molecular Structure of ((Pt(μ‐SC5H9NMe)Br)2).
Authors: AYLLON J.‐A. , GONZALEZ‐DUARTE P. , MIRAVITLLES C. , MOLINS E. 
Published: May 2016

AbstractThe title complexes (III) are synthesized by the two methods shown in the scheme.
ChemInform Abstract: Structural Variations on N‐Acetylneuraminic Acid. Part 16. A Convenient Approach to 3‐Deoxy‐D‐glycero‐D‐galacto‐nonulosonic Acid (KDN), 5‐Azido‐5‐deoxy‐KDN and 5‐Deoxy‐KDN, and Their 4‐Methylumbelliferyl 2α‐Glycosides.
Authors: SCHREINER E. , ZBIRAL E. 
Published: May 2016

AbstractThe reaction of the N‐acetylneuraminic acid ester (I) with nitrosyl acetate (II) affords a syn/anti mixture of the nitroso derivative (III), which is transformed into the KDN derivatives (V), (VII) or (VIII).
ChemInform Abstract: Ylides of Heterocycles. Part 11.Potential Estrogens and Antiestrogens. Part 3. Palladium‐Catalyzed Ring Closure Reactions to Benzofurans: A New and Effective Approach to Azacoumestrols.
Authors: STADLBAUER W. , LASCHOBER R. , KAPPE T. 
Published: May 2016

AbstractCyclization of the iodoquinolones (IVa) or (IVb) provides the title compounds (Va) or (Vb).
ChemInform Abstract: Chiral Tolans: A New Family of Ferroelectric Liquid Crystals. Synthesis and Mesomorphic Properties.
Authors: SETO K. , SHIMOJITOSHO H. , IMAZAKI H. , MATSUBARA H. , TAKAHASHI S. 
Published: May 2016

AbstractDiphenylacetylene homologues such as (III) having a chiral alkyl group are synthesized by a palladium‐catalyzed coupling reaction.
ChemInform Abstract: ULSI Quality Silicon Epitaxial Growth at 850 °C.
Authors: SILVESTRI V. J. , NUMMY K. , RONSHEIM P. , BENDERNAGEL R. , KERR D. , PHAN V. T. , BORLAND J. O. , HANN J. 
Published: May 2016

AbstractULSI (ultra large scale integration) quality silicon epitaxial films are grown in a commercially available cylindrical epi reactor at temp. as low as 850 °C and pressures as low as 10 torr using Si2H6 as silicon source.
ChemInform Abstract: Revision of the Structure of Zirconium Triiodide. The Presence of Metal Dimers.
Authors: LACHGAR A. , DUDIS D. S. , CORBETT J. D. 
Published: May 2016

AbstractZrI3 single crystals, which are not trilled or twinned, are obtained from vapor phase transport reactions of ZrI4 and Zr in the presence of AlI3 at 800 °C and their XRD data are reported.
ChemInform Abstract: Na10(Li2(MnO4)4), a Compound with LiO4 and MnO4 Tetrahedra which Form Chains of Six‐ and Eight‐Membered Rings.
Authors: FISCHER D. , HOPPE R. 
Published: May 2016

AbstractThe title compound is obtained in an attempt to prepare Na2(Li(MnO4)) by reaction of Na2O2 and LiMnO4 (Na:Mn = 2.8:1, 580 °C, 30 d, Ag‐bomb).
ChemInform Abstract: A Neutron Diffraction Study of Zr3PD3‐x.
Authors: AHLZEN P.‐J. , ANDERSSON Y. , RUNDQVIST S. , TELLGREN R. 
Published: May 2016

AbstractZr3P crystallizes in the Ti3P‐type structure, space group P42/n. Its reaction with H2 or D2 yields a primary solid solution at lower H(D) concentrations.
ChemInform Abstract: Some Factors Affecting the Cycle Lives of LaNi5‐Based Alloy Electrodes of Hydrogen Batteries.
Authors: SAKAI T. , OGURO K. , MIYAMURA H. , KURIYAMA N. , KATO A. , ISHIKAWA H. , IWAKURA C. 
Published: May 2016

AbstractThe influence of electric, mechanical, and crystallographic properties of simple ternary alloys of general formula LaNi5‐xMx (M: Ni, Mn, Cu, Cr, Al, Co) on their cycle life in hydrogen batteries.
ChemInform Abstract: Encapsulation of the Platinum and Neighboring Metals Within Cluster Iodides of Rare‐Earth Elements.
Authors: PAYNE M. W. , CORBETT J. D. 
Published: May 2016

AbstractThe new phases Pr7I12M (M: Cu, Ru, Rh, Pd, Re, Os, Ir, Pt) and Gd7I12M (M: Ni, Cu, Ru, Rh, Pd, Os, Ir, Pt, Au) are prepared via reactions of stoichiometric amounts of LnI3, Ln (Ln: Pr, Gd) and either elemental M or its iodide in Nb‐containers at 750‐1000 °C (most of the compounds are obtained in ≥ 80% yield at 800‐950 °C).
ChemInform Abstract: Asymmetric Diels‐Alder Reactions. Part 4. Influence of Anomeric Configuration and 2′‐ and 6′‐O‐Benzyl Substitution on the Diastereofacial Reactivity of (E)‐3‐(tert.‐Butyldimethylsiloxy)‐1‐(2′,3′,4′,6′‐tetra‐O‐acetyl‐β‐D‐glucop# yranosyloxy)buta‐1,3‐diene.
Authors: LARSEN D. S. , STOODLEY R. J. 
Published: May 2016

AbstractThe 2'‐ and 6'‐O‐benzyl analogues (VII) of the title compound as well as their α anomers (VI) are prepared and reacted with N‐phenylmaleimide.