bluuebunny/crossref_metadata_2025_split huggingface dataset:
Synchronizing the Greenland ice core and radiocarbon timescales over the Holocene – Bayesian wiggle-matching of cosmogenic radionuclide records
Authors: Adolphi F. , Muscheler R. 
Published: January 2016

Abstract. Investigations of past climate dynamics rely on accurate and precise chronologies of the employed climate reconstructions. The radiocarbon dating calibration curve (IntCal13) and the Greenland ice core chronology (GICC05) represent two of the most widely used chronological frameworks in paleoclimatology of the past  ∼  50 000 years. However, comparisons of climate records anchored on these chronologies are hampered by the precision and accuracy of both timescales. Here we use common variations in the production rates of 14C and 10Be recorded in tree-rings and ice cores, respectively, to assess the differences between both timescales during the Holocene. Compared to earlier work, we employ a novel statistical approach which leads to strongly reduced and yet, more robust, uncertainty estimates. Furthermore, we demonstrate that the inferred timescale differences are robust independent of (i) the applied ice core 10Be records, (ii) assumptions of the mode of 10Be deposition, as well as (iii) carbon cycle effects on 14C, and (iv) in agreement with independent estimates of the timescale differences. Our results imply that the GICC05 counting error is likely underestimated during the most recent 2000 years leading to a dating bias that propagates throughout large parts of the Holocene. Nevertheless, our analysis indicates that the GICC05 counting error is generally a robust uncertainty measurement but care has to be taken when treating it as a nearly Gaussian error distribution. The proposed IntCal13-GICC05 transfer function facilitates the comparison of ice core and radiocarbon dated paleoclimate records at high chronological precision.
Implementation of the Community Earth System Model (CESM) version 1.2.1 as a new base model into version 2.50 of the MESSy framework
Authors: Baumgaertner A. J. G. , Jöckel P. , Kerkweg A. , Sander R. , Tost H. 
Published: January 2016

Abstract. The Community Earth System Model (CESM1), maintained by the United States National Centre for Atmospheric Research (NCAR) is connected with the Modular Earth Submodel System (MESSy). For the MESSy user community, this offers many new possibilities. The option to use the Community Atmosphere Model (CAM) atmospheric dynamical cores, especially the state-of-the-art spectral element (SE) core, as an alternative to the ECHAM5 spectral transform dynamical core will provide scientific and computational advances for atmospheric chemistry and climate modelling with MESSy. The well-established finite volume core from CESM1(CAM) is also made available. This offers the possibility to compare three different atmospheric dynamical cores within MESSy. Additionally, the CESM1 land, river, sea ice, glaciers and ocean component models can be used in CESM1/MESSy simulations, allowing the use of MESSy as a comprehensive Earth system model (ESM). For CESM1/MESSy set-ups, the MESSy process and diagnostic submodels for atmospheric physics and chemistry are used together with one of the CESM1(CAM) dynamical cores; the generic (infrastructure) submodels support the atmospheric model component. The other CESM1 component models, as well as the coupling between them, use the original CESM1 infrastructure code and libraries; moreover, in future developments these can also be replaced by the MESSy framework. Here, we describe the structure and capabilities of CESM1/MESSy, document the code changes in CESM1 and MESSy, and introduce several simulations as example applications of the system. The Supplements provide further comparisons with the ECHAM5/MESSy atmospheric chemistry (EMAC) model and document the technical aspects of the connection in detail.
First implementation of secondary inorganic aerosols in the MOCAGE version R2.15.0 chemistry transport model
Authors: Guth J. , Josse B. , Marécal V. , Joly M. , Hamer P. 
Published: January 2016

Abstract. In this study we develop a secondary inorganic aerosol (SIA) module for the MOCAGE chemistry transport model developed at CNRM. The aim is to have a module suitable for running at different model resolutions and for operational applications with reasonable computing times. Based on the ISORROPIA II thermodynamic equilibrium module, the new version of the model is presented and evaluated at both the global and regional scales. The results show high concentrations of secondary inorganic aerosols in the most polluted regions: Europe, Asia and the eastern part of North America. Asia shows higher sulfate concentrations than other regions thanks to emission reductions in Europe and North America. Using two simulations, one with and the other without secondary inorganic aerosol formation, the global model outputs are compared to previous studies, to MODIS AOD retrievals, and also to in situ measurements from the HTAP database. The model shows a better agreement with MODIS AOD retrievals in all geographical regions after introducing the new SIA scheme. It also provides a good statistical agreement with in situ measurements of secondary inorganic aerosol composition: sulfate, nitrate and ammonium. In addition, the simulation with SIA generally gives a better agreement with observations for secondary inorganic aerosol precursors (nitric acid, sulfur dioxide, ammonia), in particular with a reduction of the modified normalized mean bias (MNMB). At the regional scale, over Europe, the model simulation with SIA is compared to the in situ measurements from the EMEP database and shows a good agreement with secondary inorganic aerosol composition. The results at the regional scale are consistent with those obtained from the global simulations. The AIRBASE database was used to compare the model to regulated air quality pollutants: particulate matter, ozone and nitrogen dioxide concentrations. Introduction of the SIA in MOCAGE provides a reduction in the PM2.5 MNMB of 0.44 on a yearly basis and up to 0.52 for the 3 spring months (March, April, May) when SIAs are at their maximum.
Spatio-temporal assessment of WRF, TRMM and in situ precipitation data in a tropical mountain environment (Cordillera Blanca, Peru)
Authors: Mourre L. , Condom T. , Junquas C. , Lebel T. , E. Sicart J. , Figueroa R. , Cochachin A. 
Published: January 2016

Abstract. The estimation of precipitation over the broad range of scales of interest for climatologists, meteorologists and hydrologists is challenging at high altitudes of tropical regions, where the spatial variability of precipitation is important while in situ measurements remain scarce largely due to operational constraints. Three different types of rainfall products – ground based (kriging interpolation), satellite derived (TRMM3B42), and atmospheric model outputs (WRF – Weather Research and Forecasting) – are compared for 1 hydrological year in order to retrieve rainfall patterns at timescales ranging from sub-daily to annual over a watershed of approximately 10 000 km2 in Peru. An ensemble of three different spatial resolutions is considered for the comparison (27, 9 and 3 km), as long as well as a range of timescales (annual totals, daily rainfall patterns, diurnal cycle). WRF simulations largely overestimate the annual totals, especially at low spatial resolution, while reproducing correctly the diurnal cycle and locating the spots of heavy rainfall more realistically than either the ground-based KED or the Tropical Rainfall Measuring Mission (TRMM) products. The main weakness of kriged products is the production of annual rainfall maxima over the summit rather than on the slopes, mainly due to a lack of in situ data above 3800 m a. s. l.  This study also confirms that one limitation of TRMM is its poor performance over ice-covered areas because ice on the ground behaves in a similar way as rain or ice drops in the atmosphere in terms of scattering the microwave energy. While all three products are able to correctly represent the spatial rainfall patterns at the annual scale, it not surprisingly turns out that none of them meets the challenge of representing both accumulated quantities of precipitation and frequency of occurrence at the short timescales (sub-daily and daily) required for glacio-hydrological studies in this region. It is concluded that new methods should be used to merge various rainfall products so as to make the most of their respective strengths.
Effects of cultivation and reforestation on suspended sediment concentrations: a case study in a mountainous catchment in China
Authors: Fang N. F. , Chen F. X. , Zhang H. Y. , Wang Y. X. , Shi Z. H. 
Published: January 2016

Abstract. Understanding how sediment concentrations vary with land use/cover is critical for evaluating the current and future impacts of human activities on river systems. This paper presents suspended sediment concentration (SSC) dynamics and the relationship between SSC and discharge (Q) in the 8973 km2 Du catchment and its sub-catchment (4635 km2). In the Du catchment and its sub-catchment, 4235 and 3980 paired SSC–Q samples, respectively, were collected over 30 years. Under the influence of the Household Contract Responsibility System and Grain-for-Green projects in China, three periods were designated, the original period (1980s), cultivation period (1990s) and reforestation period (2000s). The results of a Mann–Kendall test showed that rainfall slightly increased during the study years; however, the annual discharge and sediment load significantly decreased. The annual suspended sediment yield of the Du catchment varied between 1.3  ×  108 and 1.0  ×  1010 kg, and that of the sub-catchment varied between 6.3  ×  107 and 4.3  ×  109 kg. The SSCs in the catchment and sub-catchment fluctuated between 1 and 22400 g m−3 and between 1 and 31800 g m−3, respectively. The mean SSC of the Du catchment was relatively stable during the three periods (±83 g m−3). ANOVA (analysis of variance) indicated that the SSC did not significantly change under cultivation for low and moderate flows, but was significantly different under high flow during reforestation of the Du catchment. The SSC in the sub-catchment was more variable, and the mean SSC in the sub-catchment varied from 1058 ± 2217 g m−3 in the 1980s to 1256 ± 2496 g m−3 in the 1990s and 891 ± 1558 g m−3 in the 2000s. Reforestation significantly decreased the SSCs during low and moderate flows, whereas cultivation increased the SSCs during high flow. The sediment rating curves showed a stable relationship between the SSC and Q in the Du catchment during the three periods. However, the SSC–Q of the sub-catchment exhibited scattered relationships during the original and cultivation periods and a more linear relationship during the reforestation period.
Assessing changes in urban flood vulnerability through mapping land use from historical information
Authors: Boudou M. , Danière B. , Lang M. 
Published: January 2016

Abstract. This paper presents an appraisal of the temporal evolution of flood vulnerability of two French cities, Besançon and Moissac, which were largely impacted by floods in January 1910 and March 1930, respectively. Both flood events figure among the most significant events recorded in France during the 20th century, in terms of certain parameters such as the intensity and severity of the flood and spatial extension of the damage. An analysis of historical sources allows the mapping of land use and occupation within the areas affected by the two floods, both in past and present contexts, providing an insight of the complexity of flood risk evolution at a local scale.
Aggregation in environmental systems – Part 1: Seasonal tracer cycles quantify young water fractions, but not mean transit times, in spatially heterogeneous catchments
Authors: Kirchner J. W. 
Published: January 2016

Abstract. Environmental heterogeneity is ubiquitous, but environmental systems are often analyzed as if they were homogeneous instead, resulting in aggregation errors that are rarely explored and almost never quantified. Here I use simple benchmark tests to explore this general problem in one specific context: the use of seasonal cycles in chemical or isotopic tracers (such as Cl−, δ18O, or δ2H) to estimate timescales of storage in catchments. Timescales of catchment storage are typically quantified by the mean transit time, meaning the average time that elapses between parcels of water entering as precipitation and leaving again as streamflow. Longer mean transit times imply greater damping of seasonal tracer cycles. Thus, the amplitudes of tracer cycles in precipitation and streamflow are commonly used to calculate catchment mean transit times. Here I show that these calculations will typically be wrong by several hundred percent, when applied to catchments with realistic degrees of spatial heterogeneity. This aggregation bias arises from the strong nonlinearity in the relationship between tracer cycle amplitude and mean travel time. I propose an alternative storage metric, the young water fraction in streamflow, defined as the fraction of runoff with transit times of less than roughly 0.2 years. I show that this young water fraction (not to be confused with event-based "new water" in hydrograph separations) is accurately predicted by seasonal tracer cycles within a precision of a few percent, across the entire range of mean transit times from almost zero to almost infinity. Importantly, this relationship is also virtually free from aggregation error. That is, seasonal tracer cycles also accurately predict the young water fraction in runoff from highly heterogeneous mixtures of subcatchments with strongly contrasting transit-time distributions. Thus, although tracer cycle amplitudes yield biased and unreliable estimates of catchment mean travel times in heterogeneous catchments, they can be used to reliably estimate the fraction of young water in runoff.
Climatic controls and climate proxy potential of Lewis Glacier, Mt. Kenya
Authors: Prinz R. , Nicholson L. I. , Mölg T. , Gurgiser W. , Kaser G. 
Published: January 2016

Abstract. The Lewis Glacier on Mt. Kenya is one of the best studied tropical glaciers and has experienced considerable retreat since a maximum extent in the late 19th century (L19). From distributed mass and energy balance modelling, this study evaluates the current sensitivity of the surface mass and energy balance to climatic drivers, explores climate conditions under which the L19 maximum extent might have been sustained, and discusses the potential for using the glacier retreat to quantify climate change. Multi-year meteorological measurements at 4828 m provide data for input, optimization, and evaluation of a spatially distributed glacier mass balance model to quantify the exchanges of energy and mass at the glacier–atmosphere interface. Currently the glacier loses mass due to the imbalance between insufficient accumulation and enhanced melt, because radiative energy gains cannot be compensated by turbulent energy sinks. Exchanging model input data with synthetic climate scenarios, which were sampled from the meteorological measurements and account for coupled climatic variable perturbations, reveals that the current mass balance is most sensitive to changes in atmospheric moisture (via its impact on solid precipitation, cloudiness, and surface albedo). Positive mass balances result from scenarios with an increase of annual (seasonal) accumulation of 30 % (100 %), compared to values observed today, without significant changes in air temperature required. Scenarios with lower air temperatures are drier and associated with lower accumulation and increased net radiation due to reduced cloudiness and albedo. If the scenarios currently producing positive mass balances are applied to the L19 extent, negative mass balances are the result, meaning that the conditions required to sustain the glacier in its L19 extent are not reflected in today's meteorological observations using model parameters optimized for the present-day glacier. Alternatively, a balanced mass budget for the L19 extent can be achieved by changing both climate and optimized gradients (used to extrapolate the meteorological measurements over the glacier) in a manner that implies a distinctly different coupling between the glacier's local surface-air layer and its surrounding boundary layer. This result underlines the difficulty of deriving palaeoclimates for larger glacier extents on the basis of modern measurements of small glaciers.
Sea ice cover in Isfjorden and Hornsund, Svalbard (2000–2014) from remote sensing data
Authors: Muckenhuber S. , Nilsen F. , Korosov A. , Sandven S. 
Published: January 2016

Abstract. A satellite database including 16 555 satellite images and ice charts displaying the area of Isfjorden, Hornsund, and the Svalbard region has been established with focus on the time period 2000–2014. 3319 manual interpretations of sea ice conditions have been conducted, resulting in two time series dividing the area of Isfjorden and Hornsund into "fast ice" (sea ice attached to the coastline), "drift ice", and "open water". The maximum fast ice coverage of Isfjorden is  >  40 % in the periods 2000–2005 and 2009–2011 and stays  <  30 % in 2006–2008 and 2012–2014. Fast ice cover in Hornsund reaches  >  40 % in all considered years, except for 2012 and 2014, where the maximum stays  <  20 %. The mean seasonal cycles of fast ice in Isfjorden and Hornsund show monthly averaged values of less than 1 % between July and November and maxima in March (Isfjorden, 35.7 %) and April (Hornsund, 42.1 %), respectively. A significant reduction of the monthly averaged fast ice coverage is found when comparing the time periods 2000–2005 and 2006–2014. The seasonal maximum decreases from 57.5 to 23.2 % in Isfjorden and from 52.6 to 35.2 % in Hornsund. A new index, called "days of fast ice" (DFI), is introduced for quantification of the interannual variation of fast ice cover, allowing for comparison between different fjords and winter seasons. Considering the time period from 1 March until end of the sea ice season, the mean DFI values for 2000–2014 are 33.1 ± 18.2 DFI (Isfjorden) and 42.9 ± 18.2 DFI (Hornsund). A distinct shift to lower DFI values is observed in 2006. Calculating a mean before and after 2006 yields a decrease from 50 to 22 DFI for Isfjorden and from 56 to 34 DFI for Hornsund. Fast ice coverage generally correlates well with remote-sensing sea surface temperature and in situ air temperature. An increase of autumn ocean heat content is observed during the last few years when the DFI values decrease. The presented sea ice time series can be utilized for various climate effect studies linked to, e.g. glacier dynamics, ocean chemistry, and marine biology.
Composition and microstructure alteration of triticale grain surface after processing by enzymes of cellulase complex
Authors: Kuznetsova Elena , Motyleva Svetlana , Mertvischeva Maria , Zomitev Vladislav , Brindza Jan 
Published: January 2016

It is found that the pericarp tissue of grain have considerable strength and stiffness, that has an adverse effect on quality of whole-grain bread. Thereby, there exists the need for preliminary chemical and biochemical processing of durable cell walls before industrial use. Increasingly used in the production of bread finds an artificial hybrid of the traditional grain crops of wheat and rye - triticale, grain which has high nutritional value. The purpose of this research was to evaluate the influence of cellulose complex (Penicillium canescens) enzymes on composition and microstructure alteration of triticale grain surface, for grain used in baking. Triticale grain was processed by cellulolytic enzyme preparations with different composition (producer is Penicillium canescens). During experiment it is found that triticale grain processing by enzymes of cellulase complex leads to an increase in the content of water-soluble pentosans by 36.3 - 39.2%. The total amount of low molecular sugars increased by 3.8 - 10.5 %. Studies show that under the influence of enzymes the microstructure of the triticale grain surface is changing. Microphotographs characterizing grain surface structure alteration in dynamic (every 2 hours) during 10 hours of substrate hydrolysis are shown. It is found that the depth and direction of destruction process for non-starch polysaccharides of grain integument are determined by the composition of the enzyme complex preparation and duration of exposure. It is found, that xylanase involved in the modification of hemicelluloses fiber having both longitudinal and radial orientation. Hydrolysis of non-starch polysaccharides from grain shells led to increase of antioxidant activity. Ferulic acid was identified in alcoholic extract of triticale grain after enzymatic hydrolysis under the influence of complex preparation containing cellulase, xylanase and β-glucanase. Grain processing by independent enzymes containing in complex preparation (xylanase and β-glucanase) shows that more significant role in polysaccharide complex composition and grain surface microstructure alteration belongs to xylanase. Grain processing by independent of cellulolytic enzymes may decrease the strength of pericarp tissue of grain and improved sensory characteristics of the bread.
Redistribution of mineral elements in wheat grain when applying the complex enzyme preparations based on phytase
Authors: Kuznetsova Elena , Cherepnina Ludmila , Motyleva Svetlana , Brindza Ján 
Published: January 2016

Biogenic minerals play an important role in the whole human nutrition, but they are included in the grain of the phytates that reduces their bioavailability. Whole wheat bread is generally considered a healthy food, but the presence of mineral elements in it is insignificant, because of weak phytate degradation. From all sources of exogenous phytase the most productive are microscopic fungi. To accelerate the process of transition hard mineral elements are mobilized to implement integrated cellulolytic enzyme preparation based on the actions of phytase (producer is Penicillium canescens). Phytase activity was assessed indirectly by the rate of release of phosphate from the substrate. It has been established that the release rate of the phosphoric acid substrate is dependent on the composition of the drug and the enzyme complex is determined by the presence of xylanase. The presented experimental data shows that a cellulase treatment of the grain in conjunction with the β-glucanase or xylanase leading to an increase in phytase activity could be 1.4 - 2.3 times as compared with the individual enzymes. As a result of concerted action of enzymes complex preparation varies topography grain, increase the pore sizes in seed and fruit shells that facilitate the penetration of the enzyme phytase in the aleurone layer to the site of phytin hydrolysis and leads to an increase in phytase activity. In terms of rational parameters of enzymatic hydrolysis, the distribution of mineral elements in the anatomical parts of the grain after processing complex enzyme preparation with the help of X-ray detector EMF miniCup system in a scanning electron microscope JEOL JSM 6390 were investigated. When processing enzyme preparation wheat trend in the distribution of mineral elements, characteristic of grain - the proportion of these elements in the aleurone layer decreases, and in the endosperm increases. Because dietary fiber and phytate found together in the peripheral layers of fiber-rich grains, it is difficult to separate the effects of degradation processes nonstarch polysaccharides and fiberphytate redistribution of polyvalent metal ions. However, studies have shown that phytase - an effective mechanism for regulating mineral nutrient diet. Application of phytase in grain bakery technology will increase the biological value of the product.