bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: An Efficient Synthesis of a New, Chiral 2′,6′‐Pipecoloxylidide Local Anaesthetic Agent.
Authors: FEDERSEL H.‐J. , JAKSCH P. , SANDBERG R. 
Published: May 2016

AbstractStarting from the (±)‐pipecoloxylidide (I), the preparation of ropivacaine·HCl·H2O (V) is effected in three steps.
ChemInform Abstract: Azetes from Fluorinated 1,2,3‐Triazines.
Authors: CHAMBERS R. D. , TAMURA M. , SHEPHERD T. , LUDMAN C. J. 
Published: May 2016

AbstractPhotolysis of the perfluoro‐1,2,3‐triazines (I) at a low temperature leads to the formation of the azetes (II) which are not isolated.
ChemInform Abstract: A New Versatile Synthesis of Isoquinolines by Condensation of Iminophosphoranes with o‐Phthalaldehyde.
Authors: AUBERT T. , FARNIER M. , HANQUET B. , GUILARD R. 
Published: May 2016

AbstractThe azidomethyl ketones (I) react with triphenylphosphine (II) to form the iminophosphoranes (III) which undergo in situ cyclocondensation with o‐phthalaldehyde (IV), producing the 3‐acylisoquinolines (V).
ChemInform Abstract: Polycarbonyl Heterocyclics. Part 5. Synthesis of Pyrrolo(3,4‐c)pyridine and Furo(3,4‐c)pyridine Derivatives by the Ring Transformation of Thiazolidin‐4‐one Derivatives.
Authors: ZALESKA B. 
Published: May 2016

AbstractThe reaction between (I) and morpholine (II) affords the complexes (III) (no yield given for (IIIb) and (IIIe)).
ChemInform Abstract: Reaction of Dialkyl Phosphites with 1,1‐Dicyano‐3,3,3‐trichloropropylene.
Authors: KHASKIN B. A. , RYMAREVA T. G. , GOLOSOV S. N. 
Published: May 2016

AbstractTreatment of the dicyanotrichloropropene (I) with an excess of the dialkyl phosphites (II) gives the phosphonates (III).
ChemInform Abstract: Reaction of 2‐Acetyl‐5‐methyl‐1,2,3‐diazaphosphole with 9‐Diazofluorene.
Authors: ARBUZOV B. A. , DIANOVA E. N. , GALIASKAROVA R. T. , CHERNOV P. P. , LITVINOV I. A. , NAUMOV V. A. 
Published: May 2016

AbstractReaction of 9‐diazofluorene (I) with the diazaphosphole (II) leads under 1,3‐dipolar cycloaddition to the formation of the diazaphospholodiazaphosphole (III) and a small amount of the bicyclic phosphirane (IV).
ChemInform Abstract: A Designed, Enantiomerically Pure, Fused Cyclopentadienyl Ligand with C2 Symmetry: Synthesis and Use in Enantioselective Titanocene‐Catalyzed Hydrogenations of Alkenes.
Authors: HALTERMAN R. L. , VOLLHARDT K. P. C. , WELKER M. E. , BLAESER D. + , BOESE R. 
Published: May 2016

AbstractThe enantiomerically pure, chiral cyclopentadienyl ligand (VII) is prepared from the trans‐cyclohexenol (I) via optical resolution with (+)‐camphorsulfonyl chloride (III).
ChemInform Abstract: Monomeric versus Dimeric Vanadium(III) Aryloxide Formation. Syntheses and Crystal Structures of ((O‐2,6‐ArMe2)2(μ‐O‐2,6‐ArMe2)V(III))2·THF and ((O‐2,6‐ArMe2)3V(III)(py)2)2 (O‐2,6‐ArMe2: 2,6‐Dimethylphenoxide).
Authors: GAMBAROTTA S. , VAN BOLHUIS F. , CHIANG M. Y. 
Published: May 2016

AbstractReaction of the V(II) complex (I) with an excess 2,6‐dimethylphenol (II) gives the title dimer (III).
ChemInform Abstract: Pulse Radiolysis: A New Way to Study Molecular Oxygen Activation. Application to a Vanadium Complex, VCl3(4‐pic)3.
Authors: LE MOTAIS B. , KOULKES‐PUJO A. M. , HUBERT‐PFALZGRAF L. G. 
Published: May 2016

AbstractThe title compound is shown to coordinate oxygen to give a labile dimeric V‐oxygen adduct, a mixed‐valence species.
ChemInform Abstract: Reactions of Tantalocene Trihydride (η5‐C5H5)2TaH3 with the Second Group Metal Halides. Crystal and Molecular Structure of (η5‐C5H5)2TaH(μ2‐H)2ZnCl2·C4H8O.
Authors: ARKHIREEVA T. M. , BULYCHEV B. M. , SOKOLOVA T. A. , SOLOVEICHIK G. L. , BEL'SKII V. K. , BOIKO G. N. 
Published: May 2016

AbstractThe title reactions in all cases lead to the complexes (I)‐(IV) with a 1:1 ratio of Ta to the other metal.
ChemInform Abstract: Synthesis, 95Mo NMR Spectra and X‐Ray Crystal Structure of MoO2(C14H11N2O)2(C2H5OH)1 and Mo2O5(C14H11N2O)2(C2H5OH)1(H2O)1.
Authors: PIGGOTT B. , WONG S. F. , CAPPARELLI M. V. 
Published: May 2016

AbstractCrystal structures are determined for the two title complexes (I) and (II), formed from 2‐α‐hydroxybenzylbenzimidazole as its sodium salt and MoO2Cl2 by a literature method.
ChemInform Abstract: Synthesis and Characterization of (C5H5)3M3(CO)6As and (C5H5)2M2(CO)4As2 and Derivatives of the Arsanetriyl Tetrahedrane.
Authors: ZIEGLER M. L. , BLECHSCHMITT K. , NUBER B. , ZAHN T. 
Published: May 2016

AbstractThe cluster compounds (III) and (IV) are prepared from (I) and elemental arsenic in a simple reaction, the new complexes (IV) are the only members lacking until now in the homologous series AsnM4‐n (n = 1‐4).
ChemInform Abstract: Activation of Carbon‐Fluorine Bonds by Oxidative Addition.
Authors: RICHMOND T. G. , OSTERBERG C. E. , ARIF A. M. 
Published: May 2016

AbstractIt is demonstrated that chelate‐assisted oxidative addition of a phenyl‐fluoride bond occurs in high yield to afford a stable tungsten(II) metallacycle such as (V) with the cleaved fluorine atom bound to the metal center.
ChemInform Abstract: Iron‐Oxo Aggregates. Crystal Structures and Solution Characterization of 2‐Hydroxy‐1,3‐xylylenediaminetetraacetic Acid Complexes.
Authors: MURCH B. P. , BRADLEY F. C. , BOYLE P. D. , PAPAEFTHYMIOU V. , QUE L. JUN. 
Published: May 2016

AbstractThe functional groups of the binucleating ligands (I) provide a coordination environment with high affinity for iron(III).
ChemInform Abstract: Synthesis and Reactivity of Dienylmetal Compounds. Part 29. Protonation of C5H5FeC6H7 to Cyclohexadiene and Consequent Reactions.
Authors: KUHN N. , SCHUMANN H. , WINTER M. , ZAUDER E. 
Published: May 2016

AbstractThe complex (I) is obtained quantitatively from the title compound and HBF4·Et2O in CH2Cl2 at ‐50 °C. It is persistent for several hours under these conditions.
ChemInform Abstract: Metal Complexes with Tetrapyrrole Ligands. Part 48. Vilsmeier Formylation of Metal Porphyrins of Co(II), Ni(II), Pd(II), Pt(II), Cu(II), Zn(II), Co(III), Cr(III), Mn(III), Fe(III), Al(III), Si(IV), and Pt(IV) and Its Dependence on the Central Metal.
Authors: BUCHLER J. W. , DREHER C. , HERGET G. 
Published: May 2016

AbstractVilsmeier formylation of tetra‐p‐tolylporphyrin complexes such as (I) or (III) yields the 2‐formyl derivatives, e.g. (II), (IV).
ChemInform Abstract: Synthesis of D,L‐γ‐Hydroxyphosphinothricin, a Potent New Inhibitor of Glutamine Synthetase.
Authors: WALKER D. M. , MCDONALD J. F. , LOGUSCH E. W. 
Published: May 2016

AbstractN‐Protection of D,L‐homoserine (I), subsequent lactonization and esterification yield the alcohol (IV) which undergoes Swern oxidation to give the aldehyde (V).
ChemInform Abstract: Synthesis of the Novel Monocyclic β‐Lactam Proclavaminic Acid.
Authors: BAGGALEY K. H. , SIME J. T. , NICHOLSON N. H. , ELSON S. W. , GILLETT J. , HOLLAND S. , WORONIECKI S. R. 
Published: May 2016

AbstractCoupling of the azetidinone (I) with the azidopropionaldehyde (II) and subsequent hydrogenation produce proclavaminic acid (IV).
ChemInform Abstract: Application of the Two‐Directional Chain Synthesis Strategy to the First Stereochemical Assignment of Structure to Members of the Skipped‐Polyol Polyene Macrolide Class: Mycoticin A and B.
Authors: SCHREIBER S. L. , GOULET M. T. 
Published: May 2016

AbstractThe tetraacetonide (VI) is prepared from the achiral precursor (I); the key step being the conversion of (II) to (V).
ChemInform Abstract: Pheromones. Part 65. Identification of the Volatile Components of the Mandibular Gland Secretion of the Ant Manica rubida: Structure Elucidation, Synthesis, and Absolute Configuration of Manicone.
Authors: BESTMANN H. J. , ATTYGALLE A. B. , GLASBRENNER J. , RIEMER R. , VOSTROWSKY O. , GOMES CONSTANTINO M. , MELIKIAN G. , MORGAN E. D. 
Published: May 2016

AbstractManicone (Ia) is identified as the main component of the title species.
ChemInform Abstract: Na2PrO3 (I) and Na2TbO3 (II).
Authors: WOLF R. , HOPPE R. 
Published: May 2016

AbstractSingle crystals of the title compounds are prepared by reaction of Na2O with Li8TbO6 (750 °C, 30 d) and Li8PrO6 (700 °C, 23 d), respectively.
ChemInform Abstract: Study of Copper Contamination in Air or Nitrogen Containing Hydrogen Sulfide and Nitrogen Dioxide.
Authors: SIMON D. , PERRIN C. , MOLLIMARD D. 
Published: May 2016

AbstractIt is shown that the rate of copper sulfidation is much greater in air containing 0.1 ppm H2S (925 Å of Cu2S after 72 h in dry air) than in dry or humid nitrogen containing 0.1 ppm H2S (116 Å after 72 h in humid N2; 70 Å in dry N2).
ChemInform Abstract: A Zintl Phase with Isolated SnSb8‐ 4 Anions, Na8SnSb4
Authors: EISENMANN B. , KLEIN J. 
Published: May 2016

Abstract, is prepared by annealing a stoichiometric mixture of the elements (700 °C, 2 h, sealed silica tube coated with glassy carbon, no yield given).
ChemInform Abstract: Manufacture and Hydriding Characteristics of Unidirectionally Solidified LaNi5‐Ni Eutectic Alloys with Disintegration Resistance.
Authors: OGAWA T. , OHNISHI K. , MISAWA T. 
Published: May 2016

AbstractUnidirectionally solidified LaNi5‐Ni eutectic alloys are successfully prepared and their microstructural variation, disintegration resistance and hydrogen absorption characteristics are reported.
ChemInform Abstract: Free‐Energy Dependence of the Ion Yield of Photo‐Induced Electron‐Transfer Reactions in Solution.
Authors: VAUTHEY E. , SUPPAN P. , HASELBACH E. 
Published: May 2016

AbstractThe photoinduced ET reactions in MeCN with 9,10‐dicyanoanthracene as acceptor and 21 electron donors such as Ph‐Ph, p‐xylene, Ph‐O‐Me, fluorene, durene, 1,4‐di‐, 1,2,3‐, 1,2,4‐, 1,3,5‐trimethoxybenzene, aniline, N,N‐dimethyl‐, ‐diethylaniline, and Et3N are studied by use of transient photoconductivity measurements.
ChemInform Abstract: Reduction of n‐C5H11N3 Catalyzed by Single Cubane Clusters with Mo‐Fe‐S and Fe‐S Cores, Mediated with Methyl Viologen in Aqueous Micellar Solutions.
Authors: TANAKA K. , MORIYA M. , UEZUMI S. , TANAKA T. 
Published: May 2016

AbstractIn the cubane cluster (I), formed in polar organic solvents by dissociation of a Mo‐Fe‐S double cubane cluster, the solvent molecule L coordinated to Mo is easily substituted by the azide (III).
ChemInform Abstract: An Efficient Synthesis of Optically Pure (S)‐(‐)‐3‐Methylcyclohexanone.
Authors: THURKAUF A. , HILLERY P. , JACOBSON A. E. , RICE K. C. 
Published: May 2016

AbstractOptically active 3‐methylpiperidine (S)‐(I) is cleaved to give the dibromide (II) which reacts with methyl methylsulfinylmethyl sulfide (III), producing the methylcyclohexanone dithioacetal mono‐S‐oxide (IV).
ChemInform Abstract: Amidation of Chloroalkenes Catalyzed by Tertiary Phosphine Complexes of Palladium(0).
Authors: NICHOLAS P. P. 
Published: May 2016

AbstractAmidation of vinyl chloride (I) with the amines (II) and carbon monoxide (III) in the presence of a palladium(0) catalyst results in the formation of the amides (IV).
ChemInform Abstract: Synthesis and Stereodynamics of N‐Acylamidines.
Authors: ZOBOVA N. N. , AGANOV A. V. , KLOCHKOV V. V. , NAZYROVA A. Z. 
Published: May 2016

AbstractReaction of the dimethylamides (I) with dichloroacetyl isocyanate (II) gives the amidines (IIIa) or (IIIb) and/or the oxadiazines (IVb) and (IVc).
ChemInform Abstract: Asymmetric Oxidation of Chiral Enolates in the Preparation of Acyclic Tertiary α‐Hydroxy Amides in High Optical Purity.
Authors: DAVIS F. A. , ULATOWSKI T. G. , HAQUE M. S. 
Published: May 2016

AbstractThe lithium enolates of the carboxylic acid derivatives (I) are oxidized with the chiral oxaziridine (II) to give the optically active α‐hydroxy carboxylates or carboxamides (III).
ChemInform Abstract: Cobalt‐Catalyzed Reaction of Nitric Oxide with Aryl‐Substituted Olefins in the Presence of Tetrahydroborate Ion.
Authors: OKAMOTO T. , KOBAYASHI K. , OKA S. , TANIMOTO S. 
Published: May 2016

AbstractReductive nitrosation of the olefins (I) in the presence of a cobalt catalyst yields the oximes (IIIa) ‐ (IIId).
ChemInform Abstract: 4‐(Dimethylamino)pyridine as a Catalyst for Carbon Acylation. Part 2. Control of Carbon vs. Oxygen Acylation in Benzofuranones.
Authors: BLACK T. H. , ARRIVO S. M. , SCHUMM J. S. , KNOBELOCH J. M. 
Published: May 2016

AbstractThe enolate anion of 3‐phenylbenzofuranone (I) undergoes O‐acylation with the chloroformates (II) to yield the benzofuryl carbonates (III) which are easily rearranged in the presence of 4‐(dimethylamino)pyridine, producing the 3‐benzofuranonecarboxylates (IV).
ChemInform Abstract: Synthesis of Some Polyhydroxylated Pyrrolidine Derivatives.
Authors: SETOI H. , KAYAKIRI H. , TAKENO H. , HASHIMOTO M. 
Published: May 2016

AbstractCyclization of the carbamate (I) gives the protected pyrrolidine (IIa) which is converted into the polyhydroxypyrrolidines (III) and (V).
ChemInform Abstract: Stereoselection in the Reaction of Acid Halides and Vinylogous Urethanes.
Authors: SCHLESSINGER R. H. , TATA J. R. , SPRINGER J. P. 
Published: May 2016

AbstractThe vinylogous urethane (I) is lithiated and then coupled with trimethylsilyl chloride (II) to yield the ketene acetal (III).
ChemInform Abstract: Condensed Heterotricycles. Synthesis and Reactions of b‐Fused 1(2H)‐Isoquinolinones with Unusual Enamine Properties.
Authors: NAGARAJAN K. , RAO V. R. , SHAH R. K. , SHENOY S. J. , FRITZ H. , RICHTER W. J. , MULLER D. 
Published: May 2016

AbstractThe heterocycles (III), (V) (obtained from the reaction of the respective compounds (I) + (II) or (IV)) exhibit marked enamine character.
ChemInform Abstract: Practical Enantioselective Synthesis of a Homotyrosine Derivatives and (R,R)‐4‐Propyl‐9‐hydroxynaphthoxazine, a Potent Dopamine Agonist.
Authors: MELILLO D. G. , LARSEN R. D. , MATHRE D. J. , SHUKIS W. F. , WOOD A. W. , COLLELUORI J. R. 
Published: May 2016

AbstractThe Grignard compound (I) reacts with the oxalic ester (II), yielding the corresponding keto ester which is hydrolyzed to give the acid (III).
ChemInform Abstract: Substituent Effects in the Aliphatic Claisen Rearrangement of Substituted (1‐Methyl‐3‐oxahexa‐1,5‐dienyl)amines: Synthesis of Substituted 2‐Aminopent‐4‐enals. Alternative (1,3)‐Sigmatropic Shifts in Related Aromatic Systems.
Authors: BARLUENGA J. , AZNAR F. , LIZ R. , BAYOD M. 
Published: May 2016

AbstractThe propargylic ethers (I) and (V) are coupled with the amines (II) or (VI) in the presence of mercury salts to give the enamines (III) and (VII) which undergo sigmatropic rearrangement upon heating to yield the α‐amino aldehydes (IV) or (VIII).
ChemInform Abstract: Synthesis and Fungitoxicity of New 1,3,4‐Oxadiazolo(3,2‐a)‐s‐triazine‐5,7‐diones and Their Thione Analogues.
Authors: SINGH H. , MISRA A. R. , YADAV L. D. S. 
Published: May 2016

AbstractThe title compounds (V), (VII), (X), (XII) and the intermediates (IV), (IX) are tested for their antifungal activity using Dithane M‐45 as standard.
ChemInform Abstract: Intramolecular Cyclization Products from Alkanolamines and Epichlorohydrin.
Authors: BURIKS R. S. , LOVETT E. G. 
Published: May 2016

AbstractThe ethanolammonium chloride (I) reacts with epichlorohydrin (II) to give the ammonium salt (III) which is converted into the epoxide (IV).
ChemInform Abstract: Fluoro(nitrile)xenon(II) Cations, RCN‐XeF+ AsF6‐ (R = H, CH3, CH2F, C2H5, C2F5, C3F7, or C6F5); Novel Examples of Xenon‐Nitrogen Bonds and 129Xe‐13C, 129Xe‐1H, and 129Xe‐14N Nuclear Spin‐Spin Couplings.
Authors: EMARA A. A. A. , SCHROBILGEN G. J. 
Published: May 2016

AbstractHydrogen cyanide and the nitriles (I) react with the xenon salts (II) or (IV) to produce the adducts (III).
ChemInform Abstract: New Chiral Bicyclic Phosphoramides Derived from L‐Glutamic Acid.
Authors: PEYRONEL J.‐F. , SAMUEL O. , FIAUD J. C. 
Published: May 2016

AbstractCyclocondensation of the chiral diamines (I) with the phosphoramidic dichlorides (II) or (IV) gives the hexahydropyrrolodiazaphospholes (III) and (V).
ChemInform Abstract: Reaction of o‐ and m‐Carborane with Elemental Selenium.
Authors: RYS E. G. , BALEMA V. P. , GODOVIKOV N. N. 
Published: May 2016

AbstractThe AlCl3‐promoted reaction of o‐carborane (IIIa) or m‐carborane (IIIb) with selenium (II) under inert gas gives the selenols (I).
ChemInform Abstract: Synthesis, Reactivity, and Crystal Structure of CpV(CO)3tht (tht = Tetrahydrothiophene). A Mild‐Condition Synthetic Pathway to Substitution Derivatives of CpV(CO)4 and Preparation and X‐Ray Characterization of cis‐CpV(CO)2bpy (bpy = 2,2′‐Bipyridine).
Authors: GAMBAROTTA S. , CHIESI‐VILLA A. , GUASTINI C. 
Published: May 2016

AbstractThe isolable title complex (III) is obtained according to the scheme.
ChemInform Abstract: Oxygen Atom Transfer Reaction to Metal Carbonyls. Kinetics and Mechanism of CO‐Substitution Reactions of Mo(CO)5L in the Presence of (CH3)3NO.
Authors: GAO Y.‐C. , SHI Q.‐Z. , KERSHNER D. L. , BASOLO F. 
Published: May 2016

AbstractThe CO‐substitution in (I) is first order with respect to both (I) and the amine oxide but zero order with respect to (II).
ChemInform Abstract: Transition‐Metal‐Promoted Cyclization Reactions of Isocyanide Ligands. Synthesis of Cyclic Diaminocarbenes from Isocyanide Complexes of Palladium(II) and Platinum(II) and X‐Ray Structure of Cyclic cis‐Br2Pt(CN(C6H4‐p‐Me)CH2CH2N(H))(PPh3).
Authors: MICHELIN R. A. , ZANOTTO L. , BRAGA D. , SABATINO P. , ANGELICI R. J. 
Published: May 2016

AbstractElectrophilic isocyanide ligands in cationic complexes (I) are converted to the 5‐membered cyclic title complexes (III) as shown in the scheme.
ChemInform Abstract: Improved Procedure for Attachment of Amino Acids to Polymer in Peptide Synthesis by Liquid‐Phase Method.
Authors: RAHMAN S. A. , HATTABA A. A. 
Published: May 2016

AbstractProtected amino acids are converted to their cesium salts which are esterified with p‐bromomethylbenzoyl hydrazide under mild conditions without racemization.
ChemInform Abstract: Syntheses of Sandwicoline and Its Diastereomers.
Authors: HAIDER S. I. , AHMAD S. S. , SIDDIQUI S. 
Published: May 2016

AbstractReduction of sandwicine (Ia) followed by methylation yields the desired sandwicoline (IIIa), a constituent of Rauwolfia serpentina Benth.
ChemInform Abstract: Chelate Selectivity in Chelation‐Controlled Allylations. A New Synthesis of Castanospermine and Other Bioactive Indolizidine Alkaloids.
Authors: HAMANA H. , IKOTA N. , GANEM B. 
Published: May 2016

AbstractCoupling of the aldehyde (I) with allylmagnesium chloride (II) or allyltrimethylsilane (IV) yields the homoallylic alcohols (III).
ChemInform Abstract: Enantioselective Synthesis of Monocyclic β‐Lactams Related to Nocardicins via a (2+2) Cycloaddition Reaction.
Authors: NAKAGUCHI O. , OKU T. , TAKENO H. , HASHIMOTO M. , KAMIYA T. 
Published: May 2016

AbstractCycloaddition reaction of a ketene with formamidines, both of them in generated in situ, gives the β‐lactams (III) as the main products.
ChemInform Abstract: The Crystal Structure of Nonachlorodimolybdenum(V) Heptachlorodioxodimolybdate(V).
Authors: EDWARDS A. J. , SLIM D. R. 
Published: May 2016

AbstractThe compound Mo2Cl8O, obtained as a minor product of the interaction of SOCl2 with molybdic acid, crystallizes in the monoclinic system, space group P2/c, Z=2.
ChemInform Abstract: Characterization of Se‐Loaded Molecular Sieves A, X, Y, AlPO‐5, and Mordenite
Authors: PARISE J. B. , MACDOUGALL J. E. , HERRON N. , FARLEE R. , SLEIGHT A. W. , WANG Y. , BEIN T. , MOLLER K. , MORONEY L. M. 
Published: May 2016

Abstractby combining EXAFS and solid‐state NMR spectroscopy with optical absorption experiments.
ChemInform Abstract: Electrical Conduction in γ‐Irradiated and Unirradiated Zinc‐Iron Ferrites.
Authors: MOUSA M. A. , AHMED M. A. 
Published: May 2016

AbstractElectrical conductivity data of irradiated and unirradiated ZnxFe3‐xO4 spinels with x ≤ 0.79, measured between 9 and 900 K, can be explained by a hopping mechanism (electron exchange between Fe2+/Fe3+ on octahedral sites).
ChemInform Abstract: The Thermochemistry of Ammonium Compounds and the Energy Barrier Opposing Ammonium Ion Reorientation.
Authors: JOHNSON D. A. 
Published: May 2016

AbstractA good linear correlation between the energy barrier opposing cation reorientation in a compound (NH4)nX and the quantity (Xn‐) = 1/n(ΔHf°((NH4)nX,s) ‐ ΔHf°(RbnX,s)) is discussed and used to predict thermodynamic properties of both known and unknown compounds.
ChemInform Abstract: Electrochemical Overcharge Protection of Rechargeable Lithium Batteries. Part 2. The Effect of Lithium Iodide‐Iodine Additives on the Behavior of Lithium Electrode in LiAsF6‐THF Solutions
Authors: BEHL W. K. , CHIN D.‐T. 
Published: May 2016

Abstractis investigated with the rotating disk and potentiostatic transient techniques.
ChemInform Abstract: Synthesis and Characterization of Na2Ti2Se8, a New One‐Dimensional Solid‐State Polyselenide.
Authors: KANG D. , IBERS J. A. 
Published: May 2016

AbstractThe title compound, prepared by reaction of Ti metal with a Na2Se/Se flux in an evacuated Si tube (∼ 10‐5 torr) at 345 °C (100 h, yield ∼ 18%), crystallizes in the monoclinic system, space group C5 2h‐P21/c, Z=4 at ‐160 °C. Its structure is composed of infinite, one‐dimensional Ti/Se chains running parallel to c. In these chains, which are isolated from one another by the Na+ cations, the Ti centers are seven‐coordinate.
ChemInform Abstract: Synthesis and Ion‐Exchange Behavior of New Three‐Component Ion‐Exchange Material: Zirconium(IV) Iodomolybdate.
Authors: QURESHI S. Z. , RAHMAN N. 
Published: May 2016

AbstractAmong various samples of zirconium(IV) iodomolybdate, synthesized under varying conditions at pH 1, the most stable sample is chosen for detailed investigations.
ChemInform Abstract: Synthesis, Structure, and 31P and 183W NMR Spectra of P4W14O12‐ 58.
Authors: THOUVENOT R. , TEZE A. , CONTANT R. , HERVE G. 
Published: May 2016

AbstractThe structural characteristics of the title polyanion in the solid state (XRD) and in solution (31P and 183W NMR) are investigated.
ChemInform Abstract: The First X‐Ray Crystalline Structure of the Bis(monoazacrown ether) Complex. A Bis(crown ether) or a Lariat Ether?
Authors: HE G.‐X. , KIKUKAWA K. , OHE H. , MACHIDA M. , MATSUDA T. 
Published: May 2016

AbstractThe crystal structure of the KSCN complex of 1,5‐bis(N‐monoaza‐15‐crown‐5)‐3‐oxapentane (BOA15C5) is investigated and discussed in detail.
ChemInform Abstract: Use of Ir4(CO)11 to Measure the Lengths of Organic Molecules with a Scanning Transmission Electron Microscope.
Authors: FURUYA F. R. , MILLER L. L. , HAINFELD J. F. , CHRISTOPFEL W. C. , KENNY P. W. 
Published: May 2016

AbstractStudies show that small Ir4(CO)11 clusters are useful for scanning transmission electron microscopy labeling.
ChemInform Abstract: Reaction of Singlet Oxygen with Thiirane: Peroxysulfenic Acid Intermediate as a New Oxidizing Species.
Authors: AKASAKA T. , KAKO M. , SONOBE H. , ANDO W. 
Published: May 2016

AbstractPhotooxygenation of cyclohexene sulfide (I) yields the thiirane oxide (III) via the persulfoxide (II).
ChemInform Abstract: Carbanion Intermediates in the Photodecarboxylation of Benzanellated Acetic Acids in Aqueous Solution.
Authors: MCAULEY I. , KROGH E. , WAN P. 
Published: May 2016

AbstractResults are reported which show that the photodecarboxylation of benzanellated acetic acids (I) and (III) proceeds via carbanion intermediates and in addition, that eight‐electron (4n) carbanions (in a conjugated cyclic π‐system) are better accommodated than six‐electron (4n + 2) carbanions in the excited singlet state.
ChemInform Abstract: Photochemical and Thermal Transformations of 3‐Benzyl‐2(3H)‐furanones and Related Substrates.
Authors: GOPIDAS K. R. , CYR D. R. , DAS P. K. , GEORGE M. V. 
Published: May 2016

AbstractDirect irradiation of the title compounds (I) in benzene or methanol yields the diphenylfurans (II) and/or the β,γ‐unsaturated phenyl ketones (III).
ChemInform Abstract: Reaction of Phosphorus Ylides with Elemental Selenium: Generation of Selenoaldehydes and Selenium‐Catalyzed Ph3P=CHR Cleavage to Give RHC=CHR and Triphenylphosphine.
Authors: ERKER G. , HOCK R. , NOLTE R. 
Published: May 2016

AbstractThe phosphoranes (I) react with gray selenium via a Wittig olefination‐type reaction of the intermediate selenoaldehydes (II) to give the products (III) and (IV).