bluuebunny/crossref_metadata_2025_split huggingface dataset:
Proton‐Coupled Reduction of an Iron Cyanide Complex to Methane and Ammonia
Authors: Rittle Jonathan , Peters Jonas C. 
Published: September 2016

AbstractNitrogenase enzymes mediate the six‐electron reductive cleavage of cyanide to CH4 and NH3. Herein we demonstrate for the first time the liberation of CH4 and NH3 from a well‐defined iron cyanide coordination complex, [SiPiPr3]Fe(CN) (where [SiPiPr3] represents a tris(phosphine)silyl ligand), on exposure to proton and electron equivalents. [SiPiPr3]Fe(CN) additionally serves as a useful entry point to rare examples of terminally‐bound Fe(CNH) and Fe(CNH2) species that, in accord with preliminary mechanistic studies, are plausible intermediates of the cyanide reductive protonation to generate CH4 and NH3. Comparative studies with a related [SiPiPr3]Fe(CNMe2) complex suggests the possibility of multiple, competing mechanisms for cyanide activation and reduction.
Alpha‐Helical Fragaceatoxin C Nanopore Engineered for Double‐Stranded and Single‐Stranded Nucleic Acid Analysis
Authors: Wloka Carsten , Mutter Natalie Lisa , Soskine Misha , Maglia Giovanni 
Published: September 2016

AbstractNanopores are used in single‐molecule DNA analysis and sequencing. Herein, we show that Fragaceatoxin C (FraC), an α‐helical pore‐forming toxin from an actinoporin protein family, can be reconstituted in sphingomyelin‐free standard planar lipid bilayers. We engineered FraC for DNA analysis and show that the funnel‐shaped geometry allows tight wrapping around single‐stranded DNA (ssDNA), resolving between homopolymeric C, T, and A polynucleotide stretches. Remarkably, despite the 1.2 nm internal constriction of FraC, double‐stranded DNA (dsDNA) can translocate through the nanopore at high applied potentials, presumably through the deformation of the α‐helical transmembrane region of the pore. Therefore, FraC nanopores might be used in DNA sequencing and dsDNA analysis.
Growth characteristics of the endangered thick‐shelled river mussel (Unio crassus) near the northern limit of its natural range
Authors: Helama Samuli , Valovirta Ilmari , Nielsen Jan Kresten 
Published: September 2016

Abstract

The thick‐shelled river mussel, Unio crassus (Bivalvia: Unionoida), is one of Europe's most‐threatened mussels. Finnish populations of U. crassus lie close to the northern limit of its natural distribution. Extirpation of these populations will reduce the range of this endangered species.
Growth characteristics of U. crassus were measured in a river running through the Helsinki metropolitan area. Shell dimensions (size‐at‐age data) and annual shell growth increments were used to reconstruct growth rate and its variation during the lifespan of individual mussels and to investigate the relationship between growth rate and longevity (age‐at‐death).
Reconstructed growth rates compared well with size‐at‐age data conventionally used to study individual growth in natural populations, and fitted von Bertalanffy growth functions very well. Based on the same function, reconstruction and size‐at‐age methods resulted in similar estimates of growth rate.
Shell weight explained the body size more reliably than age, suggesting that growth rate varied significantly among individuals. Comparison of individual growth histories revealed a negative correlation between age‐at‐death and growth rate, i.e. slow‐growing mussels lived longer, and vice versa.
In comparison with populations from central and southern Europe, U. crassus populations in the north of its range grew more slowly but lived longer, a phenomenon most likely explained by latitudinal changes in ambient temperature.
Although northern populations are expected to benefit from a relatively high number of reproductive periods and lower juvenile mortality, the individuals studied here died earlier and suffered higher mortality than expected and an elevated conservative status is identified. Any management programme should take into account the life‐history traits essential to the recognition of management units of U. crassus.
Copyright © 2016 John Wiley & Sons, Ltd.
Querkraftversuche an Spannbetonträgern mit carbontextilbewehrter Spritzmörtelverstärkung unter zyklischer Beanspruchung
Authors: Herbrand Martin , Claßen Martin , Hegger Josef 
Published: September 2016

AbstractViele Autobahnbrücken in Deutschland weisen rechnerische Defizite bezüglich der Querkrafttragfähigkeit auf. Dies betrifft sowohl den Nachweis unter statischen als auch unter zyklischen Lasten. Aufgrund des zusätzlich schlechten Zustands vieler Brücken werden daher zukünftig vermehrt Verstärkungsmaßnahmen erforderlich werden. Zur Querkraftverstärkung von Brücken existieren unterschiedliche Verfahren mit individuellen Vor‐ und Nachteilen. In zwei am Institut für Massivbau der RWTH Aachen durchgeführten Tastversuchen an Spannbetonträgern wurde die Wirksamkeit einer carbontextilbewehrten Spritzmörtelverstärkung auf den Stegen auf die Querkrafttragfähigkeit untersucht. Die Ergebnisse wurden mit Ermüdungsversuchen an zwei baugleichen, nicht verstärkten Trägern verglichen. Es stellte sich heraus, dass die Verstärkungsmaßnahme zu einem deutlich höheren Querkrafttrag widerstand, sowohl hinsichtlich der zyklischen Belastung als auch der statischen Resttragfähigkeit, führt.
Entwicklung von Hochleistungsaerogelbeton
Authors: Schnellenbach‐Held Martina , Welsch Torsten , Fickler Silvia , Milow Barbara , Ratke Lorenz 
Published: September 2016

AbstractAufgrund der Anforderungen an den Wärmeschutz ist die Ausführung einschaliger Außenwände aus Normalbeton bereits seit einigen Jahrzehnten nicht mehr praktikabel. Um den bauphysikalischen Anforderungen gerecht zu werden, sind in der Regel zusätzliche Maßnahmen wie die Anbringung von Wärmedämmverbundsystemen oder die Ausführung als zweischalige Wandkonstruktion mit Kerndämmung erforderlich, aus denen gestalterische, konstruktive oder wirtschaftliche Nachteile resultieren können. Bisherige Versuche, einschalige Außenwände aus Leichtbetonen herzustellen, erfordern wegen der verhältnismäßig geringen Druckfestigkeiten oder der im Vergleich zu anderen Außenwandkonstruktionen noch immer höheren Wärmeleitfähigkeiten stets sehr große Wanddicken. Das Institut für Massivbau (IfM) der Universität Duisburg‐Essen hat in Zusammenarbeit mit dem Institut für Werkstoff‐Forschung des Deutschen Zentrums für Luft und Raumfahrt (DLR) durch Einbettung von Quarzglas‐Aerogelgranulat in UHPC‐Matrizen einen Hochleistungsaerogelbeton entwickelt, der ein sehr günstiges Verhältnis zwischen Druckfestigkeit und Wärmeleitfähigkeit aufweist [1]. Nachfolgend werden die mechanischen und bauphysikalischen Eigenschaften des neuen Werkstoffs vorgestellt.
Synthesis, photophysics, electrochemistry, thermal stability and electroluminescent performances of a new europium complex with bis(β‐diketone) ligand containing carbazole group
Authors: Liu Jian , Liang Quan‐Bin , Wu Hong‐Bin 
Published: September 2016

AbstractWe synthesized a new europium complex [Eu(ecbpd)3(Phen)] with bis(β‐diketone) ligand containing a carbazole group, in which ecbpd and Phen are dehydro‐3,3′‐(9‐ethyl‐9H‐carbazole‐3,6‐diyl)bis(1‐phenylpropane‐1,3‐dione) and 1,10‐phenanthroline, respectively. Its UV/vis and photoluminescent spectra, quantum yield, luminescence lifetime, electrochemistry, thermal stability and electroluminescent performances were studied. This europium complex showed low efficiency luminescence, which is probably due to the mismatching energy levels of its ligand and Eu3+, as well as the double Eu3+ core resonance.
Significant difference in active metabolite levels of ginseng in humans consuming Asian or Western diet: The link with enteric microbiota
Authors: Wan Jin‐Yi , Wang Chong‐Zhi , Zhang Qi‐Hui , Liu Zhi , Musch Mark W. , Bissonnette Marc , Chang Eugene B. , Li Ping , Qi Lian‐Wen , Yuan Chun‐Su 
Published: September 2016

AbstractAfter ingestion of ginseng, the bioavailability of its parent compounds is low and enteric microbiota plays an important role in parent compound biotransformation to their metabolites. Diet type can influence the enteric microbiota profile. When human subjects on different diets ingest ginseng, their different gut microbiota profiles may influence the metabolism of ginseng parent compounds. In this study, the effects of different diet type on gut microbiota metabolism of American ginseng saponins were investigated. We recruited six healthy adults who regularly consumed different diet types. These subjects received 7 days' oral American ginseng, and their biological samples were collected for LC‐Q‐TOF‐MS analysis. We observed significant ginsenoside Rb1 (a major parent compound) and compound K (a major active metabolite) level differences in the samples from the subjects consuming different diets. Subjects on an Asian diet had much higher Rb1 levels but much lower compound K levels compared with those on a Western diet. Since compound K possesses much better cancer chemoprevention potential, our data suggested that consumers on a Western diet should obtain better cancer prevention effects with American ginseng intake compared with those on an Asian diet. Ginseng compound levels could be enhanced or reduced via gut microbiota manipulation for clinical utility.
Antimetastatic activity of novel ruthenium (III) pyridine complexes
Authors: Gu Liwei , Li Xiaodong , Ran Qingsen , Kang Chen , Lee Canghai , Shen Jianying 
Published: September 2016

AbstractRuthenium‐based complexes have emerged as promising anticancer, especially antimetastatic agents. Among them, NAMI‐A (trans‐[Ru(III)Cl4 (DMSO)(Im)][ImH], Im = imidazole, DMSO = dimethyl sulfoxide) was well studied. In this study, we studied the antimetastatic activities of two novel NAMI‐A derivatives containing pyridine, G26b and G94a, using cultured cells and tumor‐bearing mice. Same to NAMI‐A, these two complexes displayed little direct cytotoxicity to the cancer cells in vitro and in vivo, but they, especially G26b, significantly reduced the occurrence and development of lung metastases in mice bearing the 4T1 mammary carcinoma. In vitro, these two complexes displayed significant suppressive effect on invasion and migration of cells and tube formation of human umbilical vein endothelial cell, to the same extent of NAMI‐A. The transcription of important molecules involved in metastasis, matrix metalloproteinase 2 and 9 (MMP‐2 and ‐9), and vascular endothelial growth factor, was suppressed by the two complexes, as well as NAMI‐A. Plasma atomic emission spectrometer showed G26b had a longer Ru‐elimination time in lung, which may be a reason for better antimetastatic effect of G26b than NAMI‐A. Our results have demonstrated that G26b is a more effective antimetastatic agent than NAMI‐A.
Reconstruction of massive full‐thickness abdominal wall defect: successful treatment with nonabsorbable mesh, negative pressure wound therapy, and split‐skin grafting
Authors: Aydin Dogu , Paulsen Ida Felbo , Bentzen Vibeke Egerup , Asadzadeh Sami , Hölmich Lisbet Rosenkrantz 
Published: September 2016

Key Clinical MessageWe demonstrate that it is possible to use a nonabsorbable mesh for abdominal wall reconstruction after total wound rupture and successfully split‐skin graft directly on the mesh. Sufficient granulation tissue formation prior to skin grafting was obtained with long‐term use of negative pressure wound therapy (NPWT).
Partial splenectomy for a giant epidermoid cyst of the spleen
Authors: Valverde Martinez Amparo , Roldan Ortiz Susana , Fornell Ariza Mercedes , Castro Santiago Maria Jesús 
Published: September 2016

Key Clinical MessageThe splenic epidermoid cysts are rare benign tumors, and a definitive treatment remains unclear. Although some spleen‐preserving approaches have been reportedly used, splenic cyst recurrence usually occurs in true cyst cases, wherein the cyst is incompletely removed. In our case, partial splenectomy was performed and the giant cyst was completely removed.
Marked ST‐segment elevation during permanent pacemaker implantation
Authors: Tobushi Tomoyuki , Kashihara Soichiro , Kadokami Toshiaki 
Published: September 2016

Key Clinical MessageSome acute complications are known during permanent pacemaker implantation such as pneumothorax, lead perforation, lead dislodgement, and hemorrhage. ST‐segment elevation in electrocardiogram during implantation is rare, but it might indicate critical complication like myocardial ischemia or ventricular perforation. Physicians should pay attention about ST‐segment change during pacemaker implantation.
Ruthenium Complexes of 2,2′‐Bipyridine‐6,6′‐diphosphonate Ligands for Water Oxidation
Authors: Kamdar Jayneil M. , Marelius David C. , Moore Curtis E. , Rheingold Arnold L. , Smith Diane K. , Grotjahn Douglas B. 
Published: September 2016

AbstractTwo novel ruthenium complexes, [Ru(2,2′‐bipyridine‐6,6′‐diphosphonato)(pic)2] (2) (pic=4‐picoline) and [Ru(6,6′‐diisopropyl‐2,2′‐bipyridine‐6,6′‐diphosphonato)(pic)2] (3) bearing phosphonate groups have been synthesized and characterized by NMR spectroscopy, elemental analyses, X‐ray crystallography, cyclic voltammetry, and UV/Vis spectroscopy. Both complexes show catalytic water oxidation activity by electrochemistry. At pH 7, the RuII/III redox couple of 2 is observed at a lower potential than that of 3, yet significantly, 3 oxidizes water at a lower onset potential. At pH 1 however, 2 and 3 have comparable catalytic reactivity using sacrificial oxidant CeIV. We propose that water oxidation activities of 2 and 3 are influenced by overall charges. For example, in oxidizing from RuII to RuIII at pH 7, 2 acquires a −1 overall charge whereas 3 acquires a +1 charge. Charge‐dictated electrostatic effects may govern binding of a water molecule to the metal site.
Bicatalytic Multistep Reactions En Route to the One‐Pot Total Synthesis of Complex Molecules: Easy Access to Chromene and 1,2‐Dihydroquinoline Derivatives from Simple Substrates
Authors: Giorgi Pascal D. , Miedziak Peter J. , Edwards Jennifer K. , Hutchings Graham J. , Antoniotti Sylvain 
Published: September 2016

AbstractBy combining nanocatalysis with base catalysis, a novel one‐pot multistep process was found for the synthesis of substituted heterocycles of biological relevance from simple substrates. The process is based on the initial Au/O2 oxidation of allylic alcohols, which is followed by base‐catalyzed tandem hetero‐Michael/aldolization/crotonization with ortho‐hydroxy‐ or ortho‐aminobenzaldehydes. The flexibility of the reaction even allowed the benzaldehyde partner to be prepared in situ in an example of a one‐pot/five‐step process.
Computational Study of the Palladium‐Catalyzed Carbonylative Synthesis of Aromatic Acid Chlorides: The Synergistic Effect of PtBu3 and CO on Reductive Elimination
Authors: Quesnel Jeffrey S. , Moncho Salvador , Ylijoki Kai E. O. , Torres Gerardo Martin , Brothers Edward N. , Bengali Ashfaq A. , Arndtsen Bruce A. 
Published: September 2016

AbstractWe describe herein computational studies on the unusual ability of Pd(PtBu3)2 to catalyze formation of highly reactive acid chlorides from aryl halides and carbon monoxide. These show a synergistic role of carbon monoxide in concert with the large cone angle PtBu3 that dramatically lowers the barrier to reductive elimination. The tertiary structure of the phosphine is found to be critical in allowing CO association and the generation of a high energy, four coordinate (CO)(PR3)Pd(COAr)Cl intermediate. The stability of this complex, and the barrier to elimination, is highly dependent upon phosphine structure, with the tertiary steric bulk of PtBu3 favoring product formation over other ligands. These data suggest that even difficult reductive eliminations can be rapid with CO association and ligand manipulation. This study also represents the first detailed exploration of all the steps involved in palladium‐catalyzed carbonylation reactions with simple phosphine ligands, including the key rate‐determining steps and palladium(0) catalyst resting state in carbonylations.
Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer RhIII Complexes
Authors: Ito Jun‐ichi , Ubukata Shino , Muraoka Shun , Nishiyama Hisao 
Published: September 2016

AbstractA direct asymmetric alkynylation of ketones with new chiral CCN Rh catalysts containing N‐heterocyclic carbene and oxazoline hybrid ligands is described. The catalytic reaction of fluoroalkyl‐substituted ketones, ArCOCF2X (X=F, Cl, H), with aromatic and aliphatic alkynes yielded the corresponding chiral propargyl alcohols with high enantioselectivity. Control and kinetic experiments suggested a bis(alkynyl) Rh intermediate as the active species for the C−C bond‐forming step.
Synthesis of Cycloparaphenylenes Bearing Furan‐2,5‐diyl or 2,2’‐Bifuran‐5,5’‐diyl Units in the Macrocyclic Structures
Authors: Farajidizaji Behzad , Thakellapalli Haresh , Li Shuangjiang , Huang Changfeng , Baughman Notashia N. , Akhmedov Novruz G. , Popp Brian V. , Petersen Jeffrey L. , Wang Kung K. 
Published: September 2016

AbstractSynthetic pathways to furan‐containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan‐2,5‐diyl or 2,2’‐bifuran‐5,5’‐diyl units have been developed. The X‐ray structures of a partially hydrogenated bifuran‐containing CPP precursor and the corresponding fully aromatized bifuran‐containing CPP were obtained to allow the determination of their conformational arrangements in the crystal lattice. The optical and electrochemical properties of the furan‐containing CPPs were investigated.
Cobalt(III)‐Catalyzed Intramolecular Cross‐Dehydrogenative C−H/X−H Coupling: Efficient Synthesis of Indoles and Benzofurans
Authors: Ghorai Jayanta , Reddy Angula Chandra Shekar , Anbarasan Pazhamalai 
Published: September 2016

AbstractAn efficient cobalt(III)‐catalyzed intramolecular cross‐dehydrogenative C−H/N−H coupling of ortho‐alkenylanilines has been developed utilizing O2 as a terminal oxidant. The developed reaction tolerates various reactive functional groups and allows the synthesis of diverse indole derivatives in good to excellent yields. The method was successfully extended to the synthesis of benzofurans through the intramolecular cross‐dehydrogenative C−H/O−H coupling of ortho‐alkenylphenols.
Exceptionally High Rates of Biological Hydrogen Production by Biomimetic In Vitro Synthetic Enzymatic Pathways
Authors: Kim Eui‐Jin , Wu Chang‐Hao , Adams Michael W. W. , Zhang Y.‐H. Percival 
Published: September 2016

AbstractHydrogen production by water splitting energized by biomass sugars is one of the most promising technologies for distributed green H2 production. Direct H2 generation from NADPH, catalysed by an NADPH‐dependent, soluble [NiFe]‐hydrogenase (SH1) is thermodynamically unfavourable, resulting in slow volumetric productivity. We designed the biomimetic electron transport chain from NADPH to H2 by the introduction of an oxygen‐insensitive electron mediator benzyl viologen (BV) and an enzyme (NADPH rubredoxin oxidoreductase, NROR), catalysing electron transport between NADPH and BV. The H2 generation rates using this biomimetic chain increased by approximately five‐fold compared to those catalysed only by SH1. The peak volumetric H2 productivity via the in vitro enzymatic pathway comprised of hyperthermophilic glucose 6‐phosphate dehydrogenase, 6‐phosphogluconolactonase, and 6‐phosphogluconate dehydrogenase, NROR, and SH1 was 310 mmol H2/L h−1, the highest rate yet reported. The concept of biomimetic electron transport chains could be applied to both in vitro and in vivo H2 production biosystems and artificial photosynthesis.
ChemInform Abstract: Large‐Scale Synthesis of Highly Luminescent Perovskite‐Related CsPb2Br5 Nanoplatelets and Their Fast Anion Exchange.
Authors: Wang Kun‐Hua , Wu Liang , Li Lei , Yao Hong‐Bin , Qian Hai‐Sheng , Yu Shu‐Hong 
Published: September 2016

AbstractHighly luminescent CsPb2Br5 nanoplatelets are prepared by a scalable precipitation reaction from mixtures of PbBr2, CsBr, hexylammonium bromide, DMF, and toluene (yield given in g).
ChemInform Abstract: BaCu2Sn(S,Se)4: Earth‐Abundant Chalcogenides for Thin‐Film Photovoltaics.
Authors: Shin Donghyeop , Saparov Bayrammurad , Zhu Tong , Huhn William P. , Blum Volker , Mitzi David B. 
Published: September 2016

AbstractPolycrystalline BaCu2SnSexS4‐x (x = 0, 1, 2, 3, 4) samples are prepared by solid state reaction of stoichiometric amounts of BaS, SnS, CuS, BaSe, SnSe, and CuSe (evacuated quartz tubes, 650 °C10—15 h).
ChemInform Abstract: Combining Optimized Particle Morphology with a Niobium‐Based Coating for Long Cycling‐Life, High‐Voltage Lithium‐Ion Batteries.
Authors: Gabrielli Giulio , Axmann Peter , Diemant Thomas , Behm Rolf Juergen , Wohlfahrt‐Mehrens Margret 
Published: September 2016

AbstractMorphologically tailored LiNi0.5Mn1.5O4 particles (obtained by a continuous co‐precipitation synthesis) are coated with a LiNbO3 film.
ChemInform Abstract: Scandium‐Substituted Na3Zr2(SiO4)2(PO4) Prepared by a Solution‐Assisted Solid‐State Reaction Method as Sodium‐Ion Conductors.
Authors: Ma Qianli , Guin Marie , Naqash Sahir , Tsai Chih‐Long , Tietz Frank , Guillon Olivier 
Published: September 2016

AbstractPolycrystalline Na3+xScxZr2‐x(SiO4)2 (PO4) (NSZSPx, x = 0—0.6) are fabricated on a laboratory scale (10 g—1 kg) by precipitation from stoichiometric aqueous solutions of NaNO3, Sc2O3, ZrO(NO3)2, Si(O‐Ac)4, and NH4H2PO4 followed by calcination (800 °C, 3 h), ball milling (2 d), and final sintering (1250—1300 °C, 5 h).
ChemInform Abstract: [Ni(OH)3W6O18 (OCH2)3CCH2OH]4‐: The First Tris‐Functionalized Anderson‐Type Heteropolytungstate.
Authors: Gumerova Nadiia I. , Roller Alexander , Rompel Annette 
Published: September 2016

AbstractThe title compound, Na2(Me4N)2 [Ni(OH)3W6O18 (OCH2)3CCH2OH]·9H2O is synthesized from an aqueous solution of Na2WO4, Ni(NO3)2, and HNO3 (pH 6.5, 25 °C, 10 d) followed by addition of C(CH2‐OH)4 (reflux, 80 °C, 5 h), and Me4NCl (55% yield).
ChemInform Abstract: Difluorocarbene Addition to Alkenes and Alkynes in Continuous Flow.
Authors: Rulliere Pauline , Cyr Patrick , Charette Andre B. 
Published: September 2016

AbstractA scalable difluorocyclopropanation of a broad range of alkenes is developed, including alkyl and aryl 1‐substituted, 1,1 and 1,2‐disubstituted as well as trisubstituted derivatives.
ChemInform Abstract: Trifluoroethylation of Alkynes: Synthesis of Allylic‐CF3 Compounds by Visible‐Light Photocatalysis.
Authors: Roh Geum‐bee , Iqbal Naeem , Cho Eun Jin 
Published: September 2016

AbstractTwo types of allylic trifluoromethylated compounds are synthesized.
ChemInform Abstract: N‐Heterocyclic Carbene‐Based Microporous Organic Polymer Supported Palladium Catalyst for Carbon—Carbon Coupling Reaction.
Authors: Wang Chang‐An , Li Yan‐Wei , Hou Xian‐Ming , Han Yin‐Feng , Nie Kun , Zhang Jian‐Ping 
Published: September 2016

AbstractHighly dispersed Pd(0) nanoparticles are successfully immobilized into stable N‐heterocyclic carbene‐based microporous organic polymer via a simple post‐treatment.
ChemInform Abstract: 2‐(Phenylseleno)ethanesulfon‐amide as a Novel Protecting Group for Aniline That Can Be Deprotected by a Radical Reaction.
Authors: Kihara Nobuhiro , Mitsuhashi Yuji , Sato Makoto , Hirose Shun‐ichi , Goudo Erika , Uzawa Yoshinori , Shirai Natsumi , Hamamoto Sari , Iwasaki Ryo , Fujioka Akane 
Published: September 2016

AbstractA novel sulfonamide, 2‐(phenylseleno) ethanesulfonamide as an effective protecting group for aniline derivatives is reported.
ChemInform Abstract: Catalytic One‐Pot Oxetane to Carbamate Conversions: Formal Synthesis of Drug Relevant Molecules.
Authors: Guo Wusheng , Laserna Victor , Rintjema Jeroen , Kleij Arjan W. 
Published: September 2016

AbstractA new method for the formation of highly functionalized carbamates based on the coupling of oxetanes, primary/secondary amines, and CO2 in the presence of an Al‐based catalyst is reported.