bluuebunny/crossref_metadata_2025_split huggingface dataset:
A Single Excitation‐Duplexed Imaging Strategy for Profiling Cell Surface Protein‐Specific Glycoforms
Authors: Wu Na , Bao Lei , Ding Lin , Ju Huangxian 
Published: March 2016

AbstractThis work develops a site‐specific duplexed luminescence resonance energy transfer system on cell surface for simultaneous imaging of two kinds of monosaccharides on a specific protein by single near‐infrared excitation. The single excitation‐duplexed imaging system utilizes aptamer modified upconversion luminescent nanoparticles as an energy donor to target the protein, and two fluorescent dye acceptors to tag two kinds of cell surface monosaccharides by a dual metabolic labeling technique. Upon excitation at 980 nm, only the dyes linked to protein‐specific glycans can be lit up by the donor by two parallel energy transfer processes, for in situ duplexed imaging of glycoforms on specific protein. Using MUC1 as the model, this strategy can visualize distinct glycoforms of MUC1 on various cell types and quantitatively track terminal monosaccharide pattern. This approach provides a versatile platform for profiling protein‐specific glycoforms, thus contributing to the study of the regulation mechanisms of protein functions by glycosylation.
Time‐dependent combinatory effects of active mechanical loading and passive topographical cues on cell orientation
Authors: Wang Qian , Huang Hanyang , Wei Kang , Zhao Yi 
Published: March 2016

ABSTRACTMechanical stretching and topographical cues are both effective mechanical stimulations for regulating cell morphology, orientation, and behaviors. The competition of these two mechanical stimulations remains largely underexplored. Previous studies have suggested that a small cyclic mechanical strain is not able to reorient cells that have been pre‐aligned by relatively large linear microstructures, but can reorient those pre‐aligned by small linear micro/nanostructures if the characteristic dimension of these structures is below a certain threshold. Likewise, for micro/nanostructures with a given characteristic dimension, the strain must exceed a certain magnitude to overrule the topographic cues. There are however no in‐depth investigations of such “thresholds” due to the lack of close examination of dynamic cell orientation during and shortly after the mechanical loading. In this study, the time‐dependent combinatory effects of active and passive mechanical stimulations on cell orientation are investigated by developing a micromechanical stimulator. The results show that the cells pre‐aligned by linear micro/nanostructures can be altered by cyclic in‐plane strain, regardless of the structure size. During the loading, the micro/nanostructures can resist the reorientation effects by cyclic in‐plane strain while the resistive capability (measured by the mean orientation angle change and the reorientation speed) increases with the increasing characteristic dimension. The micro/nanostructures also can recover the cell orientation after the cessation of cyclic in‐plane strain, while the recovering capability increases with the characteristic dimension. The previously observed thresholds are largely dependent on the observation time points. In order to accurately evaluate the combinatory effects of the two mechanical stimulations, observations during the active loading with a short time interval or endpoint observations shortly after the loading are preferred. This study provides a microengineering solution to investigate the time‐dependent combinatory effects of the active and passive mechanical stimulations and is expected to enhance our understanding of cell responses to complex mechanical environments. Biotechnol. Bioeng. 2016;113: 2191–2201. © 2016 Wiley Periodicals, Inc.
GPER expressed on microglia mediates the anti‐inflammatory effect of estradiol in ischemic stroke
Authors: Zhao Tian‐Zhi , Ding Qian , Hu Jun , He Shi‐Ming , Shi Fei , Ma Lian‐Ting 
Published: March 2016

AbstractBackgroundStroke could lead to serious morbidity, of which ischemic stroke counts for majority of the cases. Inflammation plays an important role in the pathogenesis of ischemic stroke, thus drugs targeting inflammation could be potentially neuroprotective. Estradiol was shown to be neuroprotective as well as anti‐inflammatory in animal models of ischemic stroke with unclear mechanism. We hypothesize that the anti‐inflammatory and neuroprotective effect of estradiol is mediated by the estradiol receptor G protein‐coupled estrogen receptor 1 (GPER) expressed on microglia.MethodsWe have generated the rat global cerebral ischemic model and the primary microglia culture to study the neuroprotective and anti‐inflammatory effect of estradiol. We have further used pharmacological methods and siRNA knockdown approach to study the underlying mechanism.ResultsWe found that estradiol reduced the level of proinflammatory cytokines including IL‐1β and TNF‐α, both in vivo and in vitro. We also found that the specific GPER agonist G1 could reduce the level of IL‐1β (P = 0 P = 0.0017, one‐way ANOVA and post hoc test) and TNF‐α (P < 0.0001) in the primary microglia culture. Moreover, the specific GPER antagonist G15 was able to abolish the anti‐inflammatory effect of estradiol. Estradiol failed to reduce the level of IL‐1β (P = 0.4973, unpaired Student's t‐test) and TNF‐α (P = 0.1627) when GPER was knocked down.ConclusionsOur studies have suggested that GPER expressed on microglia mediated the anti‐inflammatory effect of estradiol after ischemic stroke. Our studies could potentially help to develop more specific drugs to manage inflammation postischemic stroke.
Application of Sustainable Habitat: What is the Appropriation and Utilisation of Equipment After Energy‐Saving Renovations in Social Housing?
Authors: Wittenberg Inga , Fleury‐Bahi Ghozlane 
Published: March 2016

AbstractTo reduce energy consumption, technical equipment alone is not sufficient. Adjustment of behaviours so that equipment is used appropriately is also necessary. Numerous studies have shown how difficult it is to change behaviours and how many factors are involved. The aim of this study is to identify the psychosocial factors facilitating or inhibiting energy‐saving behaviours in the appropriation of energy‐saving equipment by residents. Forty‐one semi‐directive interviews were conducted with tenants of terraced houses (12 people) and flats (29 people) located in the same residential area in a French city. The blocks of flats and terraced houses are managed by a proprietor of social housing. The results of a categorical content analysis highlight the importance of the relationship between tenants and proprietor and tenants' low motivation concerning the energy‐saving renovations. Consequently, we argue for the importance of favouring active participation by tenants in order to promote acceptance and appropriation of the new equipment. Furthermore, both the social and physical contexts of residents must be taken into account and energy saving must be integrated into other types of environmental behaviours in the neighbourhood in order to improve coherence and credibility. Copyright © 2016 John Wiley & Sons, Ltd.
Coordination Chemistry Inside Polymeric Nanoreactors: Interparticle Metal Exchange and Ionic Compound Vectorization in Phosphine‐Functionalized Amphiphilic Polymer Latexes
Authors: Chen Si , Gayet Florence , Manoury Eric , Joumaa Ahmad , Lansalot Muriel , D'Agosto Franck , Poli Rinaldo 
Published: March 2016

AbstractStable latexes of hierarchically organized core‐cross‐linked polymer micelles that are functionalized at the core with triphenylphosphine (TPP@CCM) have been investigated by NMR spectroscopic analysis at both natural (ca. pH 5) and strongly basic (pH 13.6) pH values after core swelling with toluene. The core–shell interface structuring forces part of the hydrophilic poly(ethylene oxide) (PEO) chains to reside inside the hydrophobic core at both pH values. Loading the particle cores with [Rh(acac)(CO)2] (acac=acetylacetonate) at various Rh/P ratios yielded polymer‐supported [Rh(acac)(CO)(TPP)] (TPP=triphenylphosphine). The particle‐to‐particle rhodium migration is very fast at natural pH, but slows down dramatically at high pH, whereas the size distribution of the nanoreactors remains unchanged. The slow migration at pH 13.6 leads to the generation of polymer‐anchored [Rh(OH)(CO)(TPP)2], which is also generated immediately upon the addition of NaOH to the particles with a [Rh(acac)(CO)] loading of 50 %. Similarly, treatment of the same particles with NaCl yielded polymer‐anchored [RhCl(CO)(TPP)2]. Interparticle coupling occurs during these rapid processes. These experiments prove that the major contribution to metal migration is direct core–core contact. The slow migration at the high pH value, however, must result from a pathway that does not involve core–core contact. The facile penetration of the polymer cores by NaOH and NaCl results from the presence of shell‐linked poly(ethylene oxide) methyl ether functions both outside and inside the polymer core–shell interface.
Porphyrin–Alkaline Earth MOFs with the Highest Adsorption Capacity for Methylene Blue
Authors: Hou Yuxia , Sun Junshan , Zhang Daopeng , Qi Dongdong , Jiang Jianzhuang 
Published: March 2016

AbstractA series of four porphyrin–alkaline earth metal– organic frameworks [Mg(HDCPP)2(DMF)2]n⋅(H2O)7 n (1), [Ca(HDCPP)2(H2O)2]n(DMF)1.5 n (2), [Sr(DCPP)(H2O)(DMA)]n (3), and [Ba(DCPP)(H2O)(DMA)]n (4) was isolated for the first time from solvothermal reaction between metal‐free 5,15‐di(4‐ carboxyphenyl)porphyrin (H2DCPP) and alkaline earth ions. Single‐crystal X‐ray diffraction analysis reveals the 2D and 3D supramolecular network with periodic nanosized porosity for 1/2 and 3/4, respectively. The whole series of MOFs, in particular, compounds 1 and 2 with intrinsic low molecular formula weight, exhibit superior adsorption performance for methylene blue (MB) with excellent capture capacity as represented by the thus far highest adsorption amount of 952 mg g−1 for 2 and good selectivity, opening a new way for the potential application of the main group metal‐based MOFs.
Visible‐Light‐Driven Photocatalytic Activation of Inert Sulfur Ylides for 3‐Acyl Oxindole Synthesis
Authors: Xia Xu‐Dong , Lu Liang‐Qiu , Liu Wen‐Qiang , Chen Dong‐Zhen , Zheng Yu‐Han , Wu Li‐Zhu , Xiao Wen‐Jing 
Published: March 2016

AbstractBicarbonyl‐substituted sulfur ylide is a useful, but inert reagent in organic synthesis. Usually, harsh reaction conditions are required for its transformation. For the first time, it was demonstrated that a new, visible‐light photoredox catalytic annulation of sulfur ylides under extremely mild conditions, permits the synthesis of oxindole derivatives in high selectivities and efficiencies. The key to its success is the photocatalytic single‐electron‐transfer (SET) oxidation of the inert amide and acyl‐stabilized sulfur ylides to reactive radical cations, which easily proceeds with intramolecular C−H functionalization to give the final products.
Survival of the Fittest Nanojar: Stepwise Breakdown of Polydisperse Cu27−Cu31 Nanojar Mixtures into Monodisperse Cu27(CO3) and Cu31(SO4) Nanojars
Authors: Ahmed Basil M. , Szymczyna Blair R. , Jianrattanasawat Sarut , Surmann Stuart A. , Mezei Gellert 
Published: March 2016

AbstractInvited for the cover of this issue is the team led by Gellert Mezei at Western Michigan University. The image depicts “ammonia” selectively breaking down nano jar mixtures into pure nanojar species, but one resists! Read the full text of the article at 10.1002/chem.201600271.
ChemInform Abstract: CONSIDERATION OF THE VSEPR MODEL BY A LOCALIZED MOLECULAR ORBITAL STUDY OF THE GEOMETRY OF H2O
Authors: NALEWAY CONRAD A. , SCHWARTZ MAURICE E. 
Published: March 2016

AbstractDas H2O‐Molekül wird als Funktion des HOH‐Winkels durch ab initio‐LCAO‐SCF‐ MO‐Berechnungen mit erweiterten Basisreihen untersucht.
ChemInform Abstract: ON THE CRYSTAL STRUCTURE OF (PB4(OH)4)3(CO3)(CLO4)10.6H2O
Authors: HONG SAM‐HYO , OLIN AKE 
Published: March 2016

AbstractDie Titelverbindung kristallisiert nach Röntgenbeugungsdaten hexagonal mit a = 14,121 ; c = 16,316 Å, Z=2 in P63/m. Im Kristall liegen diskrete [Pb4(OH)4]′" ‐Einheiten vor.
ChemInform Abstract: IONIC EQUILIBRIA IN MIXED SOLVENTS PART 10, HYDROLYSIS OF NICKEL(II) ION IN DIOXAN‐WATER MIXTURES
Authors: KAWAI TAKAYOSHI , OTSUKA HARUKO , OHTAKI HITOSHI 
Published: March 2016

AbstractIn Wasser und Wasser‐Dioxan‐Gemischen bei 25°C und Gegenwart von 3m LiClO4 tritt als einziger Hydrolysekomplex des Ni(II)‐Ions Ni4(OH)2" auf.
ChemInform Abstract: IONIC CONDUCTIVITY OF LIQUID NH4CL FROM TRIPLE POINT TO CRITICAL POINT
Authors: BUBACK M. , FRANCK E. U. 
Published: March 2016

AbstractDie elektrische Leitfähigkeit von flüssigem NH4Cl wurde in einem Hochdruckautoklaven entlang der Dampfdruckkurve vom Tripelpunkt (5 20°C) bis 30°C unterhalb des kritischen Punkts (TK1 882°C, PK 1635 bar) gemessen, Flüssiges NH4Cl ist noch bei 850°C ‐ vollständig in Ionen dissoziiert.
ChemInform Abstract: KINETICS OF HYDROGEN ELECTRODE REACTION ON MERCURY PART 2, EXPERIMENTAL PART, ELUCIDATION OF NON‐STEADY STATE BY CONSTANT POTENTIAL AND LINEAR POTENTIAL‐SWEEP METHODS
Authors: KATAYAMA AKIKO , KITA HIDEAKI 
Published: March 2016

AbstractPotentiostatische und potentiodynamische Messungen an der Hg‐Elektrode in lm HCl, HBr oder HJ wurden zur Untersuchung der Übergangserscheinungen im elektrochemischen Mechanismus der Wasserstoffelektrodenreaktion vorgenommen.
ChemInform Abstract: MODELS FOR LATTICE DEFECTS IN OXIDE LAYERS ON PASSIVATED IRON AND NICKEL
Authors: WAGNER CARL 
Published: March 2016

AbstractDie Passivität von Fe in sauren Lösungen ist einem dünnen Film von Magnetit mit F e‐Defizit und den Grenzzusammensetzungen Fe3O4 und Fe2,67O4 zuzuschreiben.
ChemInform Abstract: THE KINETICS OF OXIDATIVE SUBSTITUTION IN BROMOPENTAAMMINECOBALT(III) ION BY CHLORINE, HYPOCHLOROUS AND HYPOBROMOUS ACIDS
Authors: MALIN J. M. , TOMA H. E. , GIESBRECHT E. 
Published: March 2016

AbstractDie Kinetik der unter Oxidation des Bromoliganden zu Br, verlaufenden Reaktionen des Komplexions (I) mit wäßrigen Lösungen von C12, HOCl und HOBr wird mit stopped‐flow‐Methoden untersucht.
ChemInform Abstract: THE CHEMICAL BEHAVIOR OF LOW VALENCE SULFUR COMPOUNDS PART 8, THE OXIDATION OF SODIUM THIOSULFATE WITH OZONE
Authors: TAKIZAWA MASAHIRO , OKUWAKI AKITSUGU , OKABE TAIJIRO 
Published: March 2016

AbstractIn neutralen Na2S2O3‐ Lösungen wird das Thiosulfation beim Durchleiten von O3 /O2‐ Gemischen zu S03′ ‐, 830% ′‐ Ionen oxidiert, wobei die Sulfatausbeute‐nur 40% des Gesamtschwefels beträgt.
ChemInform Abstract: POLAROGRAPHISCHE UNTERSUCHUNG ALKYLSUBSTITUIERTER IMIDAZOLDICARBONSAEURE‐(4,5)‐DIAMIDE
Authors: KHROMOV‐BORISOV N. V. , MIKHAILOVA T. A. 
Published: March 2016

AbstractDer Verlauf der polarographischen Reduktion von Imidazoldicarbonsäurediamiden wie z.B. (I) und (II) an der Hg‐Tropfelektrode in wäßrigen Lösungen vom pH 1,85, 6,40 und 7,00 wird untersucht.
ChemInform Abstract: ELECTROCHEMICAL REDUCTION OF (+)‐(2S,4S)‐2,4‐DIBROMOPENTANE
Authors: FRY A. J. , BRITTON W. E. 
Published: March 2016

AbstractAus dem Diol (I) erhält man über das mit (II) entstandene Borinan (III) durch dessen Antipodentrennung das (‐)‐(2R,4R)‐Diol (IV) und weiter das (+)‐(2S,4S)‐Dibromid (V).
ChemInform Abstract: THE NUCLEOPHILIC RING‐OPENING REACTIONS OF ALPHA,ALPHA′‐DINITROCYCLOALKANONES
Authors: KOBAYASHI YOSHINARI 
Published: March 2016

AbstractWährend die Cyclohexanone (III) mit prim. Alkoxiden wie z.B. (II) in den entsprechenden Alkoholen unter Ringöffnung zu Dinitrocarbonsäureestern, z.B. (I), reagieren, werden sie mit sek. oder tert. Alkoxiden wie z.B. (IV) zu Di‐aci‐nitronaten, z.B. (V), umgesetzt.
ChemInform Abstract: RELATIVE MIGRATORY APTITUDES IN THE REARRANGEMENT OF N,N‐DICHLOROCARBINAMINES BY ALUMINIUM CHLORIDE
Authors: WHITE R. E. , NAZARENO M. B. , GLEISSNER M. R. , KOVACIC P. 
Published: March 2016

AbstractDie Umlagerung der N,N‐Dichlor‐tert.‐amine (I) unter der Einwirkung von Aluminiumchlorid wird untersucht und diskutiert.
ChemInform Abstract: PHOTOSUBSTITUTION DES CHLORS IN MONO‐ UND DICHLORANILINEN DURCH CYANGRUPPEN
Authors: KUL'BITSKAYA O. V. , FROLOV A. N. , EL'TSOV A. V. 
Published: March 2016

AbstractBei Reaktionen der Chloraniline (I) mit KCN unter der Einwirkung von UV‐Licht in wäßrigem tert.‐Butanol bei 20‐40°C entstehen die Aminobenzonitrile (II); die Geschwindigkeit dieser Photosubstitution nimmt in der angegebenen Reihenfolge der Reste R ab.
ChemInform Abstract: MECHANISMUS DER PHOTOISOMERISIERUNG AROMATISCHER AZOXYVERBINDUNGEN
Authors: NEIMAN L. A. , SMOLYAKOV V. S. , SALUVERE T. A. 
Published: March 2016

AbstractDas "N‐Azoxybenzol (I) geht in Äthanol unter der Einwirkung von Hg‐Licht in ein Gemisch seines cis‐Isomeren (II) mit dem o‐Hydroxy‐azobenzol (III) über; keine der beiden Isomerisierungsreaktionen verläuft über die Stufe eines Oxadiaziridin‐Intermediären.
ChemInform Abstract: PHOTOCHEMICAL BEHAVIOR OF 1,1‐DIPHENYLETHYLENE IN POLYCHLORALKANE SOLVENTS, PREFERENTIAL ABSTRACTION OF CHLORINE ATOM
Authors: MATSUNAGA KINJIRO , KAWANISI MITUYOSI 
Published: March 2016

AbstractDie Bestrahlung von 1,1‐Diphenyläthylen z.B. in Tetrachlorkohlenstoff oder Chloroform liefert neben wenig 2‐Chlor‐l ,l‐diphenyl‐äthan hauptsächlich 2‐Chlor‐l,l‐diphenyl‐äthylen.
ChemInform Abstract: PHOTOCHEMISTRY OF EPOXY OLEFINS PART 2, THE PHOTOSENSITIZED GEOMETRIC ISOMERIZATION AND REARRANGEMENT OF THE ISOMERIC 4,5‐EPOXY‐2‐HEXENES
Authors: PAULSON D. R. , TANG F. Y. N. , SLOAN R. B. 
Published: March 2016

AbstractDie Photolyse der isomeren, photolytisch im Gleichgewicht stehenden 2,4‐Hexadienmonoxide (I)‐(IV) liefert die ungesättigten Ketone (V) und (VI).
ChemInform Abstract: REAKTION VON DICHLORCARBEN MIT SUBSTITUIERTEN BENZYLIDENANILINEN
Authors: KOSTIKOV R. R. , KHLEBNIKOV A. F. , OGLOBLIN K. A. 
Published: March 2016

AbstractAus Chloroform unter der Einwirkung von K‐tert.‐butylat in Petroläther‐Cyclohexan bei 0°C entstehendes Dichlorcarben reagiert mit den Schiffschen Basen (I) zu den Diaryldichloraziridinen (II); die Reaktivität der Azomethine (I) wird vergleichend untersucht.
ChemInform Abstract: REKOMBINATION VON BENZOPHENON‐ANIONRADIKALEN
Authors: STRELETS T. R. , IOFFE D. V. 
Published: March 2016

AbstractBei der Rekombination des durch Reaktion von Benzophenon mit Li in Tetrahydrofuran bei ‐70°C erhaltenen Anionradikals (I) in Gegenwart von Bromwasser bildet sich offenbar ein Gemisch von Benzpinakon (II) mit dem Isobenzpinakon (III).
ChemInform Abstract: RADICAL FORMATION INITIATED BY THE BIPHOTONIC EXCITATION OF ACRIDONE
Authors: MIYASHITA YOSHIKATSU , NIIZUMA SHIGEYA , KOKUBUN HIROSHI , KOIZUMI MASAO 
Published: March 2016

AbstractEs wird die Erzeugung von Lösungsmittelradikalen an Lösungen der Titelverbindung in Äthanol bei 77°Kbzw.
ChemInform Abstract: CUMYLESTER DER TRIAETHYLSILYL‐PERESSIGSAEURE
Authors: BREVNOVA T. N. , RACHKOVA O. F. , KOSHELEVA O. I. , VYAZANKIN N. S. 
Published: March 2016

AbstractDer Triäthylsilyl‐peressigsäure‐cumylester (I) zerfällt bei 120‐1250 unter Ausschluß von Luft in die Radikale′(II) und (III).
ChemInform Abstract: PROTONENRESONANZSPEKTROMETRISCHE UNTERSUCHUNG DER PROTONIERUNG DER ALPHA‐ENAMINE VON LACTAMEN
Authors: GRANIK V. G. , KOSTYUCHENKO N. P. , SMIRNOVA V. G. , SHEINKER YU. N. , GLUSHKOV R. G. 
Published: March 2016

AbstractBei der Protonierung der Enamine (I) mit Trifluoressigsäure entstehen zunächst nebeneinander die N‐ und C‐Protonierungsprodukte (II) bzw. (III).
ChemInform Abstract: REDUCTIVE ALKYLATION OF MONOAROMATIC KETONES
Authors: NARISADA M. , WATANABE F. 
Published: March 2016

AbstractAcetophenon (I) liefert bei der Reduktion mit Metallen in Ammoniak neben Enolat (II) Phenyläthanol (III) und das dimere Diphenylbutandiol (IV).
ChemInform Abstract: THE ACTIVATION OF BIVALENT SULFUR COMPOUNDS WITH CUPRIC CHLORIDE AND ZINC CHLORIDE, THE BENZYLATION AND ACYLATION OF AROMATIC COMPOUNDS WITH SULFIDES AND THIOL ESTERS
Authors: MAEKAWA KAZUO , NARASAKA KOICHI , MUKAIYAMA TERUAKI 
Published: March 2016

AbstractDie Umsetzung der Sulfide (II) mit Anisol (I) in Gegenwart von äquimolaren Gemischen aus Cu(II)‐ und Zn‐chlorid ergibt nach 5‐stündigem Rückflußkochen die Benzylderivate (III).
ChemInform Abstract: NITRAMINE 4. MITT. AMINOMETHYL‐NITRAMINE
Authors: UNTERHALT B. , THAMER D. 
Published: March 2016

AbstractDurch Umsetzung von Natrium‐nitramiden (I) mit α‐Chlormethylaminen (II) in Acetonitril werden Aminomethyl‐nitramine (III) in guten Ausbeuten erhalten.
ChemInform Abstract: ZWEIFACHE KATALYTISCHE WIRKUNG ORGANISCHER PHOSPHINSAEUREN BEI DER REAKTION VON BENZOYLCHLORID MIT PRIMAEREN AMINEN
Authors: TITSKII G. D. , STENKO O. P. , LITVINENKO L. M. 
Published: March 2016

AbstractDie Kinetik der durch Dibutylphosphinsäure oder Phenylphosphonsäuremonophenylester katalysierten Bildung der Benzanilide (III) aus Benzoylchlorid (I) und den Anilinen (II) in Benzol bei 25°C wird untersucht.
ChemInform Abstract: THE REACTION OF POLYSUBSTITUTED AROMATICS PART 33, NITRATION OF POLYALKYLBENZENES IN ACETONITRILE, ANOTHER VIEW ON SIDE‐CHAIN ACETAMIDATION
Authors: SUZUKI HITOMI , HANAFUSA TERUKIYO 
Published: March 2016

AbstractDie Nitrierung von Hexamethylbenzol (I) mit überschüssiger rauchender HNO3 in Acetonitril liefert als Hauptprodukt das Amid (II).
ChemInform Abstract: STEREOSELECTIVE SYNTHESIS OF CONJUGATED TRANS‐ENYNES READILY CONVERTIBLE INTO CONJUGATED CIS,TRANS‐DIENES AND ITS APPLICATION TO THE SYNTHESIS OF THE PHEROMONE BOMBYKOL
Authors: NEGISHI E. , LEW G. , YOSHIDA T. 
Published: March 2016

AbstractDie Umsetzung des Borans (I) mit den Acetylenen (II) in Tetrahydrofuran bei 0°C liefert die Addukte (III), die mit den Lithiumacetyliden (IV) in Tetrahydrofuran/Hexan bei ‐50°C zu den Boranen (V) reagieren.
ChemInform Abstract: STRUKTUR UND POLYFUNKTIONALES REAKTIONSVERHALTEN VON NITROMALONALDEHYD UND SEINEM ANION
Authors: KVITKO S. M. , PEREKALIN V. V. , MAKSIMOV YU. V. 
Published: March 2016

AbstractNitromalonaldehyd liegt nach IR‐ und H‐NMR‐Spektrum in der stark polarisierten Struktur (I) mit stabilisierender innermolekularer H‐Bindung vor.
ChemInform Abstract: UMSETZUNG VON DIFLUOR‐NITRO‐ESSIGSAEUREFLUORID MIT KETONEN
Authors: FOKIN A. V. , UZUN A. T. 
Published: March 2016

AbstractDurch Einwirkung von Difluor‐nitro‐essigsäurefluorid (I) auf Ketone, z.B. Aceton oder Äthylmethyl‐keton (II),während 24 Stdn. bei Zimmertemperatur werden 1,1‐ Difluor‐1‐nitro‐2,4‐diketone (III) erhalten.
ChemInform Abstract: REDUCTION OF GEM‐BROMOFLUOROCYCLOPROPANES WITH ORGANOSILICON HYDRIDES
Authors: ANDO TEIICHI , HOSAKA HIROKAZU , FUNASAKA WATARU , YAMANAKA HIROKI 
Published: March 2016

AbstractDie Reduktion der stereoisomeren Bromfluorcyclopropane (I) mit Bu2SiH2 oder Bu3SiH liefert in Gegenwart geringer Mengen Radikal‐Initiatoren [Azobisisobutyronif/′ tril (AIBN) oder Di‐tert.‐butylperoxid (DTBP)] die entsprechenden Monofluorcyclopropane (II).
ChemInform Abstract: EFFECT OF P‐METHOXYBENZONITRILE ON THE COURSE OF THE STOICHIOMETRIC HYDROFORMYLATION OF CYCLOPENTENE
Authors: CLARK A. C. , ORCHIN M. 
Published: March 2016

AbstractIn Gegenwart von Nitrilen wie p‐Methoxybenzonitril (I) erfolgt die Hydroformylierung von Olefinen wie Cyclopenten (II) wesentlich rascher.
ChemInform Abstract: ISOMERIZATION OF 4‐HYDROXY‐2‐(PROP‐2‐ENYL)CYCLOPENT‐2‐ENONES TO 2‐N‐PROPYLCYCLOPENT‐2‐ENE‐1,4‐DIONES
Authors: PATTENDEN G. , STORER R. 
Published: March 2016

AbstractDie Alkenyl‐hydroxy‐cyclopentenone (I) ergeben bei der Behandlung mit Pyridinhydrochlorid die Alkyl‐cyclopentendione (II).
ChemInform Abstract: A TRANSITION METAL CATALYSED PHOTOREACTION, FERROCEN‐SENSITIZED PHOTOALKOXYCARBONYLATION OF AZULENE
Authors: ISHIGAMI T. , AKIYAMA T. , WATANABE H. , KATO T. , SUGIMORI A. 
Published: March 2016

AbstractDie Belichtung (7x = 313 oder 365 nm) von Ferrocen (I) und Azulen (II) in Tetrachlorkohlenstoff/Äthanol in Gegenwart von Natriumacetat ergibt den Azulencarbonsäure= äthylester (III), in Abwesenheit von Natriumacetat entsteht das Chlorazulen (IV).