bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Charge Storage and Transport in Thermal Ruthenium Oxide Thin Films. In situ Detection of Local pH Changes and Asymmetries in Charge‐Discharge Cycles at the Oxide/Aqueous Electrolyte Interphase.
Authors: JANG G.‐W. , TSAI E. W. , RAJESHWAR K. 
Published: May 2016

AbstractApplying voltammetry and a novel thin‐layer spectroelectrochemical technique to study the kinetic and reversibility of the charge‐discharge cycle in RuOx electrodes, deposited pyrolytically on Ti and Au supports.
ChemInform Abstract: Electrochemical Techniques for Corrosion Rate Determination in Ceramics.
Authors: DIVAKAR R. , SESHADRI S. G. , SRINIVASAN M. 
Published: May 2016

AbstractCorrosion rates of single phase α‐SiC and reaction‐sintered SiC containing 8‐13 wt.% free silicon are measured by DC polarization measurements in HCl, HNO3, H3PO4, and aqua regia.
ChemInform Abstract: Selective Metal Oxidation by Dissociative Chemisorption of CO: Reactivity of Nd Overlayers and Nd/Cu Alloy Films on Cu(100).
Authors: NIX R. M. , LAMBERT R. M. 
Published: May 2016

AbstractThe initial dissociative chemisorption of CO on Nd and Nd/Cu films is accompanied by substantial structural rearrangements in the surface region and the formation of a disordered oxide which is oxygen deficient relative to Nd2O3.
ChemInform Abstract: Reactions of Ruthenium(III) and ‐(IV) Chloro Complexes with Nitrogen Oxides NO and NO2.
Authors: ZARHLOUL R. , DUC G. , DELOUME J.‐P. 
Published: May 2016

AbstractThe reactions of the chloro complexes (I)‐(III) in aqueous solution as well as of blue ruthenium(II) solutions with either NO or NO2 yield products containing the complex RuNO3+ with Ru in the oxidation state IV in all conditions (ambient and boiling temp., 0.5 and 3 M HCl).
ChemInform Abstract: Preparation, Characterization and Thermal Studies of the Paramolybdates of Some Cobaltammine Complexes.
Authors: SOUAYA E. R. , HANNA W. G. , MILAD N. E. 
Published: May 2016

AbstractThe five cobaltammine‐paramolybdate ion‐pair complexes (I)‐(V) are prepared at a pH slightly below 7.0.
ChemInform Abstract: Electron Affinities of Substituted Nitrobenzenes.
Authors: CHOWDHURY S. , KISHI H. , DILLOW G. W. , KEBARLE P. 
Published: May 2016

AbstractThe electron affinities of 14 substituted nitrobenzenes including nitrobiphenyls are determined by measurement of electron transfer equilibria in the gase phase with a pulsed high pressure mass spectrometer.
ChemInform Abstract: Indoloquinolizidine Iminium Species Formed Under the Modified Polonovski Reaction Conditions.
Authors: TAMMINEN T. , JOKELA R. , TIRKKONEN B. , LOUNASMAA M. 
Published: May 2016

AbstractFour different starting compounds ((I) and their 2,3‐dihydro derivatives) are studied with respect to the regioselectivity in the formation of different iminium species, generated by the modified Polonovski reaction (dehydration of N‐oxides by (CF3CO)2O at ‐17 °C).
ChemInform Abstract: From 2,5‐Dihydropyrazines to 2H‐1,4‐Diazepines and from Benzodihydroarenes to Benzocycloheptene Derivatives, Structural Variants of the Antidepressant Protriptyline.
Authors: SCHOELLKOPF U. + , MITTENDORF J. 
Published: May 2016

AbstractBase treatment of 7 dihydropyrazines such as (I) and (IV) results in the formation of ring‐enlarged products of type (II)/(VII) and/or (III).
ChemInform Abstract: Rearrangement of 1,3‐Thiazolidine Sulfoxides to Dihydro‐1,4‐thiazines.
Authors: LEE W. S. , HAHN H. G. , MAH H.‐D. 
Published: May 2016

AbstractCatalyzed by TosOH, both the cis and trans sulfoxides (II) and (III) are transformed via the sulfenic acid (IV) to the dihydro‐1,4‐thiazines (V).
ChemInform Abstract: Photochemistry of Bichromophoric Aromatic Diketones: The Effect of Methylene Chain.
Authors: ITO Y. , UOZU Y. , ARAI H. , MATSUURA T. 
Published: May 2016

AbstractPhotocyclization of the diketones (V), prepared according to the reaction scheme, produces the benzocyclobutenols (VI).
ChemInform Abstract: Rapid Cleavage Reactions of Haloaromatic Radical Anions Measured with Fast‐Scan Cyclic Voltammetry.
Authors: WIPF D. O. , WIGHTMAN R. M. 
Published: May 2016

AbstractThe radical anion generated at the electrode surface (micrometer dimensions) is found to have a half‐life ranging from less than 100 ns in the case of p‐bromoacetophenone to 70 ms for m‐nitrobenzyl chloride.
ChemInform Abstract: Diazotization Mechanism of Heteroaromatic Amines. Diazotization of 2‐Aminothiazole as an Equilibrium.
Authors: DIENER H. , GUELEC B. + , SKRABAL P. , ZOLLINGER H. 
Published: May 2016

AbstractThe rate of diazotization of the title compound is measured in aqueous H2SO4, the kinetic solvent isotope effect of the diazotization in 72% D2SO4/D2O is determined.
ChemInform Abstract: Synthetic Methods and Reactions. Part 140. One‐Pot Preparation of Crowded Olefins from Hindered Ketones with Alkyllithiums and Thionyl Chloride.
Authors: OLAH G. A. , WU A. , FAROOQ O. 
Published: May 2016

AbstractThe hindered ketones (I) are coupled with the alkyllithiums (II) to give intermediate lithium alkoxides which react with thionyl chloride, forming the crowded olefins (III).
ChemInform Abstract: The Invention of Radical Reactions. Part 18. Decarboxylative Radical Addition to Arsenic, Antimony, and Bismuth Phenylsulfides. A Novel Synthesis of Noralcohols from Carboxylic Acids.
Authors: BARTON D. H. R. , BRIDON D. , ZARD S. Z. 
Published: May 2016

AbstractThe reaction of a wide range of thiohydroxamate esters such as (I) with the tris(phenylsulfide) (II) is studied.
ChemInform Abstract: Influence of Enolate Geometry and Structure on the Stereochemistry of the Asymmetric Oxidation of Prochiral Ketone Enolates to Optically Active α‐Hydroxy Ketones.
Authors: DAVIS F. A. , SHEPPARD A. C. , LAL G. S. 
Published: May 2016

AbstractThe ketones (I) are treated with LDA in THF to form the lithium enolates (III) which are oxidized with an optically active oxaziridine to form the chiral α‐hydroxy ketones (IV).
ChemInform Abstract: Zinc Chloride‐Catalyzed Rearrangements of 1,2‐Dialkynyl‐1,2‐dihydroxy‐3,6‐dimethoxy‐3,5‐cyclohexadienes to Bicyclo(2.2.2)octadienones and Bicyclo(3.2.1)octadienones.
Authors: FERNANDEZ M. , CHANG S. , ZILLER J. , DOEDENS R. J. , MOORE H. W. 
Published: May 2016

AbstractHeating of the dialkynylcyclohexadiene diol (I) in the presence of zinc dichloride results in rearrangement, forming the (2.2.2)bicyclooctadienone (II), whereas the corresponding monosiloxy analogs (III) produce the (3.2.1)bicyclooctadienones (IV) under similar conditions.
ChemInform Abstract: Arenesulfonate Derivatives of Homochiral Glycidol: Versatile Chiral Building Blocks for Organic Synthesis.
Authors: KLUNDER J. M. , ONAMI T. , SHARPLESS K. B. 
Published: May 2016

AbstractAsymmetric epoxidation of allyl alcohol (I) yields the enantiomerically enriched (S)‐glycidol (II) which is in situ converted to the arenesulfonates (IV).
ChemInform Abstract: Intramolecular Addition Reactions During Heteroatom Directed Photoarylation.
Authors: DITTAMI J. P. , RAMANATHAN H. , BREINING S. 
Published: May 2016

Abstract3‐Ethoxycyclohexenone (I) reacts consecutively with the Grignard compound (II), basic hydrogen peroxide, and 2‐naphthalenethiolate (III) to give the naphthyl vinyl sulfide (IV) which is irradiated, forming the fused thiophenes (V) or (VI) depending on the reaction temperature.
ChemInform Abstract: Reactions of 2‐Lithio‐1,3‐benzodithiole with Carbon Disulfide: Forth and Back Processes.
Authors: GIMBERT Y. , MORADPOUR A. , BITTNER S. , JORDIS U. 
Published: May 2016

Abstract1,3‐Benzodithiole (I) is consecutively treated with butyllithium, carbon disulfide (II), bases, and methyl iodide (III) to give the bis(methylthio)methylene derivative (IV), together with the 2‐methylated compound (V).
ChemInform Abstract: Synthesis of 2,2‐Disubstituted Succinimides and Their Regioselective Thiocarbonylation Reaction.
Authors: KOSUGI Y. , KOSUGI M. , HAMAGUCHI F. 
Published: May 2016

AbstractThe dibromosuccinimide (I) reacts with alkoxides and thiolates such as (II) or (IV), forming the 2,2‐disubstituted succinimides (III).
ChemInform Abstract: 2‐Chloro‐4,5‐dihydroimidazole. Part 4. Reaction with Aroyl Isothiocyanates.
Authors: SACZEWSKI F. 
Published: May 2016

AbstractIsothiocyanates such as (II) having an electron‐withdrawing group react with azomethines to afford cycloadducts of type (III), which are extremely unstable at room temp. and decompose completely within 1 h. Hydrolysis with cold water yields the hydrochlorides of (IV), which are immediately converted into the free bases.
ChemInform Abstract: Synthesis and Ring‐Opening of 4‐((2′,3′‐Diphenyl‐5′‐methoxy‐6′‐indolyl)methylene)‐ and 4‐((2′3′‐Diphenyl‐1′‐methyl‐5′‐methoxy‐6′‐indolyl)methylene)‐2‐phenyloxazolin‐5‐ones.
Authors: KANDEEL E. M. , ABD EL RAHMAN A. H. , KHODEIR M. N. 
Published: May 2016

AbstractThe title oxazolinones (III) react with various reagents to give new compounds, whose structures are confirmed by IR and 1H NMR spectra.
ChemInform Abstract: Imidazo(2,1‐b)benzothiazoles. Part 1.
Authors: EL‐SHORBAGI A.‐N. , SAKAI S. , EL‐GENDY M. A. , OMAR N. , FARAG H. H. 
Published: May 2016

AbstractHeating of 2‐aminobenzothiazole (I) with the phenacyl bromides (II) yields the N‐alkylated compounds (III) which are cyclized upon acidic treatment to give the imidazobenzothiazoles (IV).
ChemInform Abstract: Synthesis of Bis(alkylthio)bipyridyls by Nickel Mediated Homo Coupling of Halopyridyl Alkyl Sulfides.
Authors: TIECCO M. , TINGOLI M. , TESTAFERRI L. , BARTOLI D. , CHIANELLI D. 
Published: May 2016

AbstractOnly the homo coupling of tert.‐butyl sulfides, e.g. (I), (V) and (VIII), leads to the formation of bipyridyls.
ChemInform Abstract: Thermal Reactions of Chromium Aminocarbene Complexes with Alkynes. Synthesis of Bicyclo(3.1.0) Lactams.
Authors: HEGEDUS L. S. , MILLER D. B. JUN. 
Published: May 2016

AbstractThe methylenechromium pentacarbonyl complex (I) undergoes thermally‐induced coupling with diphenylacetylene (II) to give an intermediate enamino ketene which is directly subjected to cycloaddition reaction with the imines (III) to form the bicyclic lactams (IV).
ChemInform Abstract: Highly Reactive and Stereoselective (R)‐ and (S)‐3‐(N,N‐Dimethylcarbamoyl)‐1,2,4‐trimethyl‐1,4‐dihydropyridines for NADH‐NAD+ Mimicry.
Authors: DE KOK P. M. T. , BASTIAANSEN L. A. M. , VAN LIER P. M. , VEKEMANS J. A. J. M. , BUCK H. M. 
Published: May 2016

AbstractThe base‐catalyzed condensation reaction of the enamine (I) with crotonaldehyde (II) furnishes the intermediate carbinolamine (III) from which water is removed by azeotropic distillation to give the dihydropyridine (IV).
ChemInform Abstract: A Facile Synthesis of 2‐Aryl‐ and 2‐Heteroaryl‐Substituted 4‐Aminoquinolines.
Authors: STREKOWSKI L. , KONG S.‐B. , CEGLA M. T. , HARDEN D. B. 
Published: May 2016

AbstractThe azomethines (III), prepared by reaction of 2‐cyanoaniline (I) with the aryl methyl ketones (II), are cyclized upon treatment with LDA, forming the quinolines (IV).
ChemInform Abstract: The Chemistry of Vicinal Tricarbonyl Compounds. Applications in the Synthesis of Isoquinoline Alkaloids.
Authors: WASSERMAN H. H. , AMICI R. , FRECHETTE R. , VAN DUZER J. H. 
Published: May 2016

AbstractCoupling of the benzoyl chlorides (I) with the tert‐butoxycarbonylmethylenephosphorane (II), followed by ozonolysis, produces the α,β‐diketo esters (IV).
ChemInform Abstract: Magnesium Ion Assisted Highly Regio‐ and Chemoselective Reduction of 5H‐Pyrrolo(3,4‐b)pyridine‐5,7(6H)‐diones with Sodium Borohydride. A Convenient Synthesis of 6,7‐Dihydro‐7‐hydroxy‐5H‐pyrrolo(3,4‐b)pyridin‐5‐ones.
Authors: GOTO T. , KONNO M. , SAITO M. , SATO R. 
Published: May 2016

AbstractThe reduction of the title diones (I) yields the 7‐hydroxy lactams (II) as major products which are useful precursors for the preparation of biologically active compounds.
ChemInform Abstract: Reaction of the Fluoroborate of 2‐Benzoyl‐1,2‐dihydro‐isoquinaldonitrile with α,β‐Ethylenic Esters: Acrylic, Fumaric and Maleic Ester. Competition Between (3 + 2) and (4 + 2) Cycloaddition Reactions.
Authors: SCHMITT G. , LAUDE B. , VEBREL J. , RODIER N. , THEOBALD F. 
Published: May 2016

AbstractOnly Diels‐Alder adducts have been formed in the reactions of the Reissert salt (I) with alkenes.
ChemInform Abstract: Studies on Heterocyclic Compounds. Part 9. Synthesis and Antiallergic Activity of Furo(2,3‐b)(1,8)naphthyridine‐3,4(2H,9H)‐diones and 4H‐Furo(2,3‐d)pyrido(1,2‐a)pyrimidine‐3,4(2H)‐diones.
Authors: KUO S.‐C. , TSAI S.‐Y. , LI H.‐T. , WU C.‐H. , ISHII K. , NAKAMURA H. 
Published: May 2016

AbstractThe synthesis of the title compounds (IV) and (V) is accomplished by subjecting the 2‐aminopyridines (I) to coupling with the ethoxydihydrofuranone (II) and subsequent thermally induced cyclization.
ChemInform Abstract: Pyridazines with Heteroatom Substituents in Position 3 and 5. Part 1. 5‐Hydroxy‐3(2H)‐pyridazinone and Its Derivatives.
Authors: WAGNER U. G. , KRATKY C. , KAPPE T. 
Published: May 2016

AbstractThe title compound (V) is prepared by a novel procedure and in improved yield.
ChemInform Abstract: Photochemistry of Conjugated Nitrogen‐Thiocarbonyl Systems. Part 6. Photoaddition of Olefins to 2‐Thiouracil and 2‐Thioquinazoline‐2,4‐(1H,3H)‐dione.
Authors: SATO E. , IKEDA Y. , HASEBE M. , NISHIO T. , MIURA T. , KANAOKA Y. 
Published: May 2016

AbstractIrradiation of 2‐thiouracil (I), in the presence of the olefins (II), yields a mixture of the 2‐substituted pyrimidones (III), the insertion and addition products (IV), and/or the (2 + 2)cycloadducts (V).
ChemInform Abstract: Studies on Quinolizine Derivatives. Part 22. Syntheses and Properties of 2‐Phenylazacycl(3.3.3)azine Derivatives.
Authors: MATSUDA Y. , GOTOU H. , ONIYAMA Y. , KATOU K. , MATSUMOTO H. 
Published: May 2016

AbstractThe arylazacyclazines (III) are prepared by reaction of the iminoquinolines (I) with the mixed carbonic anhydrides (II).
ChemInform Abstract: A Simple Bis‐anellation Route to 3,4,5,6‐Tetrahydropyrido(3,2‐c)quinolin‐2‐ones.
Authors: VINICK F. J. , DESAI M. C. , JUNG S. , THADEIO P. 
Published: May 2016

AbstractThe o‐cyano‐ω‐chloroalkanoic anilides (Ia) ‐ (Ic) are treated with lithium tetramethylpiperidide to form the cyclopropanecarboxamide (II) or the fused quinolones (IIIb) and (IIIc).
ChemInform Abstract: Dihydroazepines from Ring‐Closure Reaction of α‐Allylaminodienenitriles.
Authors: FANG J.‐M. , YANG C.‐C. , WANG Y.‐W. 
Published: May 2016

AbstractThe α‐allylaminodienenitriles (III) and (IV) are prepared as mixtures of E‐ and Z‐isomers as depicted in the reaction scheme.
ChemInform Abstract: Synthesis of 4‐(Dimethylphenylsilyl)buta‐2,3‐dien‐1‐ol and Its Use in Alkylation.
Authors: TROST B. M. , TOUR J. M. 
Published: May 2016

AbstractTreatment of dimethylphenylsilyllithium (I) with diethylaluminum chloride generates the corresponding silylalane which undergoes addition reaction with epoxybutyne (II) to give the allene (IIIa) mentioned in the title.
ChemInform Abstract: A Very Simple One‐Pot Synthesis of 2‐Chlorophosphinines.
Authors: LE FLOCH P. , MATHEY F. 
Published: May 2016

AbstractDichloromethyldichlorophosphine (I) is dehydrochlorinated with triethylamine to give the intermediate phosphaalkene (II) which is trapped with the dienes (III), forming the cycloadducts (IV).
ChemInform Abstract: (1‐Alkene)(trimethylphosphine)zirconocenes: Preparation, Characterization and Reactivity.
Authors: BINGER P. , MUELLER P. + , BENN R. , RUFINSKA A. , GABOR B. , KRUEGER C. + , BETZ P. 
Published: May 2016

AbstractThe mixture of the rotamers (IV) and (V) is a good starting material to other alkene (or alkyne) Zr complexes (VII) and (IX)/(X).
ChemInform Abstract: Synthesis and Structural Characterization of Group 4 ansa‐Metallocene Complexes Containing a 1‐Sila‐3‐metallacyclobutane Ring.
Authors: KABI‐SATPATHY A. , BAJGUR C. S. , REDDY K. P. , PETERSEN J. L. 
Published: May 2016

AbstractThe 1‐sila‐3‐metallacyclobutanes (III) are prepared by reaction of the dichlorides (I) with the oligomeric Grignard agents (II).
ChemInform Abstract: A Novel Synthesis and Properties of N‐Trifluoromethylgermaimine, CF3N=GeH2.
Authors: ANG H. G. , LEE F. K. 
Published: May 2016

AbstractReaction of nitrosotrifluoromethane (I) with germane (II) yields the germaimine (III) which reacts with hydrogen iodide to give the adduct (IV).
ChemInform Abstract: Complexation of Tin(II) by the Iridium Metallomacrocycle Ir2(CO)2Cl2(μ‐Ph2PCH2As(Ph)CH2PPh2)2. A Novel Receptor and Sensor of Tin(II).
Authors: BALCH A. L. , OLMSTEAD M. M. , ORAM D. E. , REEDY P. E. JUN. , REIMER S. H. 
Published: May 2016

AbstractSnCl2 reacts with (I) to give (IIIa), which can be converted into the BPh4 salt (94% yield) by anion metathesis.
ChemInform Abstract: Intramolecular Cyclization of Allylic Propiolates Mediated by the Addition of Stannyl Radicals: A New Synthetic Route to α‐Methylene‐γ‐butyrolactones.
Authors: LEE E. , KO S. B. , JUNG K. W. , CHANG M. H. 
Published: May 2016

AbstractReaction of the allylic propiolates (I) with the stannanes (II) in the presence of AIBN gives the methylenelactones (III), together with the acyclic adducts (IV).
ChemInform Abstract: 1,5‐Stereocontrol via (η6‐Arene)tricarbonylchromium Complexes.
Authors: UEMURA M. , MINAMI T. , HIROTSU K. , HAYASHI Y. 
Published: May 2016

AbstractComplexation of the arene compounds (I) using the tricarbonylchromium complex (II) proceeds diastereoselectively via ligand‐exchange reaction, yielding predominantly the arenechromium complexes (III).
ChemInform Abstract: Pentacarbonyliron Used for Isomerization of Functionalized 1,5‐Dienes.
Authors: RODRIGUEZ J. , BRUN P. , WAEGELL B. 
Published: May 2016

AbstractTreatment of the 4‐vinylcyclohexene derivatives (I), available from cyclohexenecarboxaldehyde, with pentacarbonyliron (II) results in isomerization to give a mixture of the tricarbonyliron complexes (III) ‐(V).
ChemInform Abstract: Synthetic Analogue Approach to Cobalt(III)‐Bleomycin: Synthesis, Crystal and Solution Structures and Redox Properties of Bis(N‐(2‐(4‐imidazolyl)ethyl)pyrimidine‐4‐carboxamido)cobalt(III) Perchlorate·2.25 H2O.
Authors: MUETTERTIES M. , MASCHARAK P. K. , COX M. B. , ARORA S. K. 
Published: May 2016

AbstractAerobic oxidation of mixtures of N‐(2‐(4‐imidazolyl)ethyl)pyrimidine‐4‐carboxamide, a peptide ligand that contains three of the five proposed donor centers of the metal‐chelating portion of the antitumor drug bleomycin, and Co(II) salts (ratio 2:1) in water or methanol affords the corresponding Co(III) complex isolated as the perchlorate (I) or the tetrafluoroborate.
ChemInform Abstract: Synthesis, Characterization, and Electron‐Transfer Reactivity of Norbornyl Complexes of Cobalt in Unusually High Oxidation States.
Authors: BYRNE E. K. , THEOPOLD K. H. 
Published: May 2016

AbstractThe reaction of CoCl2 with 1‐norbornyllithium in THF affords the anionic Co(III) complex (I), while the same reaction in pentane yields the previously reported tetrahedral Co(IV) complex (II), which crystallizes in Pmn21 with Z=2.
ChemInform Abstract: New Silver Cluster Compounds Containing Dithiobenzoate Ligands.
Authors: SCHUERMAN J. A. , FRONCZEK F. R. , SELBIN J. 
Published: May 2016

AbstractThe three new Ag4 cluster compounds (I), (II), and (III) are obtained by 1:1 molar reaction of the corresponding tetrapropylammonium dithiobenzoate with Ag(I) nitrate in DMF followed by pyridine addition, and in the case of (III) by corresponding 2:1 molar reaction.
ChemInform Abstract: Bonding Studies of Nitrogen Heterocyclic Ligands to (η5‐Cyclopentadienyl)ruthenium Cation: A Novel Nitrogen to π Rearrangement.
Authors: FISH R. H. , KIM H.‐S. , FONG R. H. 
Published: May 2016

AbstractThe reaction of the title cation (I) with excess Py provides (III), containing three N‐bonded ligands.
ChemInform Abstract: Preparation and Characterization of Ruthenium(II) Porphyrins.
Authors: MASSOUDIPOUR M. , PANDEY K. K. 
Published: May 2016

AbstractThe (meso‐tetraphenylporphyrinato)‐Ru(II) complex (I) is prepared by reaction of tetraphenylporphyrin with ruthenium carbonyl in situ obtained in refluxing ethyl glycol of RuCl3 in the presence of formaldehyde.
ChemInform Abstract: CH2=PPh and CH2=AsPh as Ligands Coordinated to Rhodium. Crystal and Molecular Structure of C5Me5Rh(η2‐CH2PPh)(CO) and C5Me5(CO)Rh(AsPh)3.
Authors: WERNER H. , PAUL W. , WOLF J. , STEINMETZ M. , ZOLK R. , MUELLER G. + , STEIGELMANN O. , RIEDE J. 
Published: May 2016

AbstractThe (η2‐CH2EPH)‐Rh complexes (III) are obtained according to the scheme.
ChemInform Abstract: Reactivity of the Homoleptic Osmium Aryl Os(2‐MeC6H4)4: Ligand‐Induced Reductive Coupling, σ‐ to π‐Rearrangement, and Ortho‐Hydrogen Activation.
Authors: ARNOLD J. , WILKINSON G. , HUSSAIN B. , HURSTHOUSE M. B. 
Published: May 2016

AbstractStudies of the reactivity of (I) toward Lewis bases show that reductive coupling occurs on treatment with PMe3 or CO leading to η6‐biaryl derivatives (III) via σ‐ to π‐rearrangement.
ChemInform Abstract: Synthesis of 11‐ and 12‐Methylestrones via the Thermal Elimination of β‐Keto Sulfoxides.
Authors: KUROSAWA T. , TOHMA M. 
Published: May 2016

AbstractThe 12‐methylestrone (VII) is prepared via dehydrative cyclization of the key intermediate (IV) which is available from the β‐keto sulfoxide (I) and the diketone (III).
ChemInform Abstract: Regioselective De‐O‐benzylation with Lewis Acids.
Authors: HORI H. , NISHIDA Y. , OHRUI H. , MEGURO H. 
Published: May 2016

AbstractThe anhydrotri‐O‐benzyl‐D‐mannopyranose (I) is subjected to debenzylation by treatment with SnCl4 or TiCl4, yielding the regioisomeric di‐O‐benzyl derivatives (II) and (III).
ChemInform Abstract: Studies on the Formation of Oxindoles from Their Indoloazabicyclo‐(3.3.1)nonane Counterparts and Implications for the Biogenesis of Alstonisine.
Authors: HOLLINSHEAD S. P. , GRUBISHA D. S. , BENNETT D. W. , COOK J. M. 
Published: May 2016

AbstractTreatment of the fused azabicyclononane (I) with tert‐butyl hypochlorite and subsequent acidic hydrolysis give the oxindole (II).
ChemInform Abstract: A General Method for the Synthesis of Glycerophospholipids and Their Analogues via H‐Phosphonate Intermediates.
Authors: LINDH I. , STAWINSKI J. 
Published: May 2016

AbstractThe dipalmitoyl glycerol (I) is converted to the phosphonate (III) which reacts with hydroxylic components such as the N‐protected ethanolamine (IV) in the presence of a condensing agent to form the diester (V).
ChemInform Abstract: Total Enantiospecific Synthesis of (9S)‐ and (9R)‐9‐Hydroxyeicosatetraenoic Acid (9‐HETE‐) Methyl Esters.
Authors: SANIERE M. , LE MERRER Y. , BARBE B. , KOSCIELNIAK T. , DUMAS J. , MICAS‐LANGUIN D. , DEPEZAY J.‐C. 
Published: May 2016

AbstractThe title compound (9S)‐(XI) is obtained via the key intermediate (S)‐(VIII) starting from the diepoxide (I) which is available from D‐mannitol.
ChemInform Abstract: Synthesis of Novel Functionalized Monocyclic 2‐Azetidinones from N,N′‐Diaryl‐α‐diimines and Lithium Ester Enolates.
Authors: ALCAIDE B. , GOMEZ A. , PLUMET J. , RODRIGUEZ‐LOPEZ J. 
Published: May 2016

AbstractThe reaction of the diimines (I) with the enolates (II) and (VI) yields the title azetidinones (III) and (VII), respectively.
ChemInform Abstract: Evidence for an Ordered Pd7Sm Phase in Pd‐Sm Alloys.
Authors: SAKAMOTO Y. , TAKAO K. , TAKEDA S. , TAKEDA T. 
Published: May 2016

AbstractAn ordered phase in the form of a Pd7Sm superlattice is observed in annealed Pd‐Sm alloys containing 5‐15 at.% Sm.
ChemInform Abstract: Crystal Structural Analyses of 1:3 (Lu,In)(OH)3 and 1:3 (Yb,In)(OH)3.
Authors: MULLICA D. F. , SAPPENFIELD E. L. , GABLE D. R. , TIMS T. A. 
Published: May 2016

AbstractThe title compounds are prepared by hydrothermal treatment of 1:3 mixtures of Lu2O3‐In2O3 and Yb2O3‐In2O3, resp. (30 N NaOH, 503 K, 5‐6 d, Teflon bomb).
ChemInform Abstract: Magnetic Properties of (Nd,Y)2Fe14B and (Nd,Gd)2Fe14B
Authors: ZHANG Z.‐D. , HUANG Y.‐K. , SUN X. K. , CHUANG Y. C. , YANG F.‐M. , DE BOER F. R. , RADWANSKI R. J. 
Published: May 2016

Abstractare studied for (Nd1‐xLnx)2Fe14B (Ln: Y,Gd) samples with x = 0.0, 0.2, 0.4, 0.6, 0.8, and 1.0.