bluuebunny/crossref_metadata_2025_split huggingface dataset:
Effect of high-temperature annealing for single-Ni-layer gate in AlGaN/GaN high-electron-mobility transistors
Authors: Nanjo Takuma , Imai Akifumi , Kurahashi Kenichiro , Matsuda Takashi , Suita Muneyoshi , Yagyu Eiji 
Published: April 2016

Abstract
AlGaN/GaN high-electron-mobility transistors (HEMTs) with Schottky gate contacts are strong candidates for high-power applications with high-frequency operation. The existence of interfacial traps between Schottky gate contacts and an AlGaN surface is one of the issues causing relatively high gate leakage current in these HEMTs. High-temperature gate annealing, which reduces the density of traps owing to the interfacial reaction between Schottky gate contacts and an AlGaN surface, was investigated using a single-Ni-layer gate structure to prevent the alloying of conventional stacked metal layers such as Ni/Au and Pt/Au. As a result, a strong gate annealing temperature dependence of Schottky characteristics was observed and this dependence also caused drain current collapse. In addition, it was confirmed that 700 °C is the optimal gate annealing temperature for improving both the Schottky characteristics and drain current collapse. These results are attributed to the change in the density of interfacial trap states.
Comparison of subthreshold swing in SrTiO3-based all-solid-state electric-double-layer transistors with Li4SiO4 or Y-stabilized-ZrO2 solid electrolyte
Authors: Tsuchiya Takashi , Ochi Masanori , Higuchi Tohru , Terabe Kazuya 
Published: April 2016

Abstract
SrTiO3 (STO)-based all-solid-state electric-double-layer transistors (EDLTs) with a Li4SiO4 (LSO) lithium ion conductor (i.e., electrolyte) or Y-stabilized-ZrO2 (YSZ) proton conductor were fabricated. While the LSO device showed significant drain current enhancement at room temperature, the YSZ device needed high temperature to achieve comparable drain current enhancement due to the difference in ionic conductivity between the two electrolytes. Subthreshold swing (S), which is a parameter used to evaluate the steepness of drain current enhancement in field-effect transistors (FETs), was calculated to be 66 and 227 mV/dec, respectively, for LSO and YSZ EDLTs. The 66 mV/dec is very close to the theoretical limit (60 mV/dec) for conventional FETs, indicating that LSO is more suitable for STO-based EDLTs and that the type of solid electrolyte used greatly affects EDLT switching characteristics.
Tratamiento exitoso de linfohistiocitosis hemofagocítica y coagulación intravascular diseminada secundarios a histoplasmosis en un paciente con VIH/sida
Authors: Nieto John Fredy , Gómez Sandra Milena , Moncada Diana Carolina , Serna Lina Maria , Hidrón Alicia Inés 
Published: April 2016

<p>La linfohistiocitosis hemofagocítica es un síndrome poco frecuente que resulta de una activación no controlada de los macrófagos y linfocitos, donde se produce un compromiso multiorgánico que es potencialmente fatal sin el tratamiento oportuno. Puede ser de causa hereditaria o secundaria a procesos infecciosos, neoplásicos o autoinmunes. Presentamos el caso de un paciente con VIH/sida que desarrolló linfohistiocitosis hemofagocítica más coagulación intravascular diseminada asociados a histoplasmosis y que fue exitosamente tratado con anfotericina B, esteroides y soporte dialítico transitorio. </p>
Effects of Task Interruption and Background Speech on Word Processed Writing
Authors: Keus van de Poll Marijke , Sörqvist Patrik 
Published: April 2016

SummaryTask interruptions and background speech, both part of the everyday situation in office environments, impair cognitive performance. The current experiments explored the combined effects of background speech and task interruptions on word processed writing—arguably, a task representative of office work. Participants wrote stories, in silence or in the presence of background speech (monologues, halfalogues and dialogues), and were occasionally interrupted by a secondary task. Writing speed was comparably low during the immediate period after the interruption (Experiments 1 and 2); it took 10–15 s to regain full writing speed. Background speech had only a small effect on performance (Experiment 1), but a dialogue was more disruptive than a halfalogue (Experiment 2). Background speech did not add to the cost caused by task interruptions. However, subjective measures suggested that speech, just as interruptions, contributed to perceived workload. The findings are discussed in view of attentional capture and interference‐by‐process mechanisms.© 2016 The Authors. Applied Cognitive Psychology published by John Wiley & Sons, Ltd.
Formulation of a novel soybean protein‐based wood adhesive with desired water resistance and technological applicability
Authors: Fan Bo , Zhang LeiPeng , Gao ZhenHua , Zhang Yuehong , Shi Junyou , Li Jianzhang 
Published: April 2016

ABSTRACTA novel soybean protein‐based wood adhesive with good bond strength, excellent water resistance, and the desired technological applicability was formulated by combining thermal alkali degradation, thermal acid treatment, and crosslinking. The characterization results indicated that thermal alkali degradation could effectively improve the technological applicability, thermal acid treatment could positively improve the water resistance, and appropriate crosslinking modification could significantly enhance the bond strength and water resistance of the soybean protein adhesive. The crosslinker species, crosslinker level, and ratio of thermal alkali‐degraded soybean protein (DSP) to thermal acid‐treated soybean protein (TSP) had important effects on the primary properties of the soybean protein adhesives. The modified polyamide aqueous solution was the most preferable crosslinker because of its low viscosity, good crosslinking efficiency, and excellent miscibility with soybean protein solution. The optimal soybean protein adhesive that was formulated from 20 wt % modified polyamide as the crosslinker and a DSP/TSP ratio of 1:3 had a solid content of more than 35 wt %, suitable viscosity (∼2180 mPa s), a long work life (>16 h), good dry bond strength (2.94 MPa), and 28 h of boiling–dry–boiling cycled wet strength (1.29 MPa) that met the required values for structural use according to JIS K6806‐2003 commercial standards. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43586.
Influence of support layer and PDMS coating conditions on composite membrane performance for ethanol/water separation by pervaporation
Authors: Naik Parimal V , Bernstein Roy , Vankelecom Ivo F. J 
Published: April 2016

ABSTRACTA systematic study was performed on the combination of support properties and polydimethylsiloxane (PDMS) coating conditions for the lab‐scale preparation of a defect‐free, thin film composite membrane for organophilic pervaporation. Support layers having comparable surface porosities were prepared from three polymers with different chemical composition (PVDF, PSF, PI). Their exact role on the deposition of the PDMS coating (i.e., wetting and intrusion) and the final membrane performance (i.e., effect on mass transfer of the permeants) was studied. The crosslinking behavior of dilute PDMS solutions was studied by viscosity measurements to optimize the coating layer thickness, support intrusion and wetting. It was found essential to pre‐crosslink the PDMS solution for a certain time prior to the coating. Dip time for coating the PDMS solution on the supports was varied by using automated dip coating machine. The performance of the synthesized membranes was tested in the separation of ethanol/water mixtures by pervaporation. Both flux and selectivity of the membranes were clearly influenced by the support layer. Resistance of the support layers increased by increasing the polymer concentration in the casting solutions of the supports. Increasing the dip time of the PDMS coating solution led to increased selectivity of the composite membranes. Scanning Electron Microscopy analysis of the composite membranes showed that this leads to a minor increase in the thickness of the PDMS top layer. Top layer thickness increased linearly with the square root of the dip time (t0.5) at a constant withdrawal speed of the support. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43670.
Estimation of train dwell time at short stops based on track occupation event data: A study at a Dutch railway station
Authors: Li Dewei , Daamen Winnie , Goverde Rob M. P. 
Published: April 2016

SummaryTrain dwell time is one of the most unpredictable components of railway operations, mainly because of the varying volumes of alighting and boarding passengers. However, for reliable estimations of train running times and route conflicts on main lines, it is necessary to obtain accurate estimations of dwell times at the intermediate stops on the main line, the so‐called short stops. This is a great challenge for a more reliable, efficient and robust train operation. Previous research has shown that the dwell time is highly dependent on the number of boarding and alighting passengers. However, these numbers are usually not available in real time. This paper discusses the possibility of a dwell time estimation model at short stops without passenger demand information by means of a statistical analysis of track occupation data from the Netherlands. The analysis showed that the dwell times are best estimated for peak and off‐peak hours separately. The peak‐hour dwell times are estimated using a linear regression model of train length, dwell times at previous stops and dwell times of the preceding trains. The off‐peak‐hour dwell times are estimated using a non‐parametric regression model, in particular, the k‐nearest neighbor model. There are two major advantages of the proposed estimation models. First, the models do not need passenger flow data, which is usually impossible to obtain in real time in practice. Second, detailed parameters of rolling stock configuration and platform layout are not required, which makes the model more generic and eases implementation. A case study at Dutch railway stations shows that the estimation accuracy is 85.8%–88.5% during peak hours and 80.1% during off‐peak hours, which is relatively high. We conclude that the estimation of dwell times at short stop stations without passenger data is possible. Copyright © 2016 John Wiley & Sons, Ltd.
HuR‐regulated lncRNA NEAT1 stability in tumorigenesis and progression of ovarian cancer
Authors: Chai Yiqing , Liu Jie , Zhang Zhikun , Liu Liwei 
Published: April 2016

AbstractLong noncoding RNAs (lncRNAs) have recently emerged as pivotal regulators in governing fundamental biological processes, as well as in tumorigenesis. The nuclear paraspeckle assembly transcript 1 (NEAT1) is one of the most highly regulated lncRNAs in recent genomic datasets, however, its biological role and regulatory mechanism in ovarian cancer (OC) development and progression are poorly defined. In this study, we identified that NEAT1 was up‐regulated in OC patients and cell lines, and its expression was associated with the FIGO stage and lymph node metastasis. Furthermore, the ectopic expression of NEAT1_1 in OVCAR‐3 cell lines promoted cell proliferation and invasion, whereas knockdown of NEAT1_1 did the opposite. Furthermore, NEAT1_1 was stabilized by an RNA‐binding protein HuR, but suppressed by miR‐124‐3p in OC cells. Accordingly, the increased HuR mRNA and decreased miR‐124‐3p levels were observed in OC patients. These results suggested that lncRNA NEAT1, whose expression was collaboratively controlled by HuR and miR‐124‐3p, could regulate ovarian carcinogenesis and may serve as a potential target for antineoplastic therapies.
ChemInform Abstract: EPR EXAMINATION OF IRON(III) COPRECIPITATED WITH SOME RARE EARTH OXIDES
Authors: SARASWAT I. P. , VAJPEI A. C. , GARG V. K. , SOOTHA G. D. , GUPTA S. K. 
Published: April 2016

AbstractX‐Band‐EPR‐Spektren von Fe(III)‐Ionen in La‐, Pr‐ und Nd‐oxid‐Gittem (Darstellung durch gemeinsame Fällung aus wäßrigen Lösungen von 3 Gew.‐% Fe(III) und 97 Gew.‐% La(III) mit NH3 und Wärmebehandlung des Niederschlags (600°C, 24 h)) werden bei 80 K aufgenommen.
ChemInform Abstract: LOW‐POWER‐PULSED CARBON DIOXIDE‐LASER‐INDUCED CHEMISTRY OF SULFUR HEXAFLUORIDE‐SENSITIZED DIBORANE. EVIDENCE FOR THERMAL STEERING
Authors: RILEY C. , SHATAS R. 
Published: April 2016

AbstractDie SFG‐sensibilisierte (BH)n‐Bildung durch Bestrahlung von BzHö , die auf 2 getrennten Wegen stattfindet, von denen einer relativ schnell abläuft, wird mit Hilfe eines mechanisch zerhackten oder elektrisch gepulsten Lasers untersucht.
ChemInform Abstract: OXIDATION OF COPPER SULFIDES IN AQUEOUS AMMONIA. I. FORMATION OF SULFUR
Authors: FILMER A. O. , PARKER A. J. , WADLEY L. G. B. 
Published: April 2016

AbstractDie Oxidation von CuS oder Cu2S in ammoniakalischer wäßriger Lösung verläuft unter geeigneten Reaktionsbedingungen unter Bildung großer Anteile an elementarem S. Das Molverhältnis NH3/lösliches Cu muß > 10:1 sein, die Lösung muß nahe pH 10.3 gepuffert sein ( ;z.B. mit (NH4)2SO4),die Temp. muß unter 40°C liegen und der O2‐Partialdruck sollte so hoch wie praktikabel liegen.
ChemInform Abstract: METAL‐RARE GAS INTERACTION. A NEW BOND?
Authors: DEMUYNCK J. , KOCHANSKI E. , VEILLARD A. 
Published: April 2016

AbstractDie Wechselwirkung zwischen den Pentacarbonylen M(CO)5 (M: Cr und Mo) und Edelgasatomen X (X: Ar, Kr, Xe) wurde mittels ab‐initio‐Berechnungen an dem SCF‐ und Dispersionsenergie‐Niveau untersucht.
ChemInform Abstract: AQUEOUS SOLUTION EQUILIBRIUMS INVOLVING THE LIGAND 2,2,4‐TRIMETHYL‐1,5,9‐TRIAZACYCLODODECANE AND NICKEL(II), COPPER(II), AND ZINC(II)
Authors: RENFREW R. W. , JAMISON R. S. , WEATHERBURN D. C. 
Published: April 2016

AbstractDie zwischen dem Titelliganden L′ und Ni(II), Cu(II) und Zn(II) in wäßriger Lösunggebildeten Komplexe (I)‐(IV) werden potentiometrisch und spektrophotometrisch untersucht.
ChemInform Abstract: BILIRUBIN ACIDITY. TITRIMETRIC AND CARBON‐13 NMR STUDIES
Authors: HANSEN P. E. , THIESSEN H. , BRODERSEN R. 
Published: April 2016

AbstractBei der acidimetrischen indirekten Titration in überschüssiger NaOH‐Lösung verbraucht Bilirubin IX‐oz Zwei Äquivalente NaOH zur Neutralisation der beiden Carboxylgruppen (pK 7).
ChemInform Abstract: ARYLCYCLOPROPANE PHOTOCHEMISTRY. SUBSTITUENT EFFECTS ON THE PHOTOCHEMICAL CYCLOPROPYLCARBINYL‐HOMOALLYL REARRANGEMENT OF 2‐ARYLCYCLOPROPYLCARBINYL ACETATES
Authors: HIXSON S. S. , GERE J. A. , FRANKE L. A. 
Published: April 2016

AbstractBestrahlung der substituierten Acetate (Ia) und (Ic) bzw. der Ester (Ib) und (Id) in Acetonitril führt [außer für X: m‐OMe] zu den entsprechenden homoallylischen Verbindungen (II), während bei der Bestrahlung von (Ic) und (Id) in Methanol zusätzlich die Methylether (IIIc) und (IIId) als prim. Photoprodukte gebildet werden.
ChemInform Abstract: MATRIX ISOLATION OF A TRIPLET BIRADICAL FROM A CARBENE PRECURSOR
Authors: PLATZ M. S. 
Published: April 2016

AbstractDie Photolyse der durch HgO‐Oxidation des entsprechenden Naphthaldehyd‐Hydrazons leicht zugänglichen Diazoverbindung (I) in Perfluorbenzol bei 77 Kliefert das Titelradikal (III) (ESR‐Spektrum).
ChemInform Abstract: SYNTHESIS AND BIOLOGIC DISTRIBUTION OF MERCAPTO DERIVATIVES OF PALMITIC ACID
Authors: LIVNI E. , DAVIS M. A. , WARNER V. D. 
Published: April 2016

AbstractDie Palmitinsäure (II) und Dicarbonsäure (VI), deren Herstellung im Formelschema beschrieben ist, sowie 2‐Mercaptopalmitinsäure werden auf ihre Verteilung in Ratten als 35S‐markierte Verbindungen untersucht.
ChemInform Abstract: SELECTIVITY IN THE ENE REACTION OF HEXAFLUOROTHIOACETONE. THE PREPARATION OF ALLYLIC SULFIDES
Authors: INOUYE Y. , BURTON D. J. 
Published: April 2016

AbstractDie Olefine (I) reagieren mit Hexafluorthioaceton (II) in einer En‐Reaktion zu den Allylsulfiden (III) und (IV).
ChemInform Abstract: SMALL RINGS. PART 31. TRIMETHYLENECYCLOBUTANE
Authors: MARTIN H.‐D. , MAYER B. 
Published: April 2016

AbstractAus a,a‐Dibrom‐glutarsäureester erhält man mit Cyanessigsäureester nach Hydrolyse glatt die Cyclobutantricarbonsäure (Ia), aus der das Tris‐säurechlorid (Ib), weiter das Amid (Ic) und das Tris‐dimethylaminomethylcyclobutan (Id) erhalten werden.
ChemInform Abstract: POTENTIAL ANTICANCER AGENTS. XV. NEW AROMATIC NITROGEN MUSTARDS ABLE TO BE COUPLED WITH PROTEINS
Authors: NICULESCU‐DUVAZ I. , TOMA A. , ROTARU M. , IONESCU D. , BARACU I. , BOTEZ G. , TARNAUCEANU E. , DOBRE V. 
Published: April 2016

AbstractAus den Anilinen (I) werden mit Ethylenoxid (II) die Bis‐ β‐hydroxyethylaniline (III) erhalten, die mit SOCl2 oder PCl3 zu den Bis‐β‐chlorethylanilinen (IV) reagieren.
ChemInform Abstract: SYNTHESIS OF HYDROXY‐ AND AMINO‐SUBSTITUTED BENZOHYDROXAMIC ACIDS: INHIBITION OF RIBONUCLEOTIDE REDUCTASE AND ANTITUMOR ACTIVITY
Authors: VAN'T RIET B. , WAMPLER G. L. , ELFORD H. L. 
Published: April 2016

AbstractAus (I) erhält man in alkalischem Medium mit Hydroxylamin und in Gegenwart von Natriumsulfit, das eine Oxidation des Benzoats verhindert, die Hydroxamate (II) und nach Ansäuern die Hydroxamsäuren (III).
ChemInform Abstract: SYNTHESES WITH NITRILES, 52: REACTIVITY OF THE NEW CODIMER FROM MALONONITRILE, CYANOACETATE AND DIMER CYANOACETATE WITH BENZILS
Authors: THIERRICHTER B. , JUNEK H. 
Published: April 2016

AbstractKondensation der Benzile (I) mit den Cyancrotonsäurederivaten (II) gibt die Pyrroline (III), von denen sich (IIIa), (IIIb) und (IIId) mit NaOH oder besser in verdünnter Na‐alkoholatlösung zu den Pyrrolidinonen (IV) umlagem.
ChemInform Abstract: REACTIONS OF 2,2,2‐TRIFLUORODIAZOETHANE WITH CARBON‐NITROGEN AND CARBON‐OXYGEN MULTIPLE BONDS
Authors: FIELDS R. , TOMLINSON J. 
Published: April 2016

Abstract2,2 ,2‐Trifluorodiazoethan (I) reagiert mit den Trihalogenoacetonitrilen (II) zu den l ,2,3‐Triazolen (III).
ChemInform Abstract: SYNTHESIS AND PLATELET AGGREGATION INHIBITORY ACTIVITY OF 6‐ISOBUTYL‐α‐METHYL‐3‐PYRIDINEACETIC ACID
Authors: RYNBRANDT R. H. , TIFFANY B. D. , BALGOYEN D. P. , NISHIZAWA E. E. , MENDOZA A. R. 
Published: April 2016

AbstractDas Nitril (I) wird über (II)‐(V) in das Epoxid (VI) umgewandelt, das aber nicht in die gewünschte Verbindung (VII) übergeführt werden kan Letztere ist dagegen ausgehend von (I) über den Enolether (X) zugänglich, der sich oxidativ in den Carbonsäureester (XI) umlagern läßt. Die Chlorcarbonsäure (XII) wird zur Verbindung (XIII) verestert und dechloriert.
ChemInform Abstract: REACTION WITH 6‐ACETYL‐3,5‐DIARYLCYCLOHEXEN‐1‐ONES SYNTHESIZED BY MICHAEL REACTION OF ACETYLACETONE WITH DICHLOROCHALCONES
Authors: SAMMOUR A. , ELZAWAHRY M. , ELHASHASH M. , NAGY A. 
Published: April 2016

AbstractDas Chalcon (I) reagiert mit Ace‐′ tylaceton (II) in der Kälte zu dem Adduk‐t (III), während in der Hitze neben den Bisaddukten (V) die Cyclohexenone (IV) gebildet werden.
ChemInform Abstract: NEW SYNTHESIS AND MASS SPECTRA OF 4‐ARYL‐2,3,1‐BENZOXAZONES
Authors: FAHMY A. F. M. , ALY N. , ORABY M. 
Published: April 2016

AbstractAus den Aroylbenzoesäureaziden (I) werden mit Hydroxylamin die Benzoxazone (II) synthetisiert.
ChemInform Abstract: 1,6‐DIAZABICYCLO(4.4.4)TETRADECANE AND ITS OXIDIZED IONS
Authors: ALDER R. W. , SESSIONS R. B. 
Published: April 2016

AbstractDie drei Oxidationszustände (IV), (V) und (III) der Titelverbindung werden isoliert, und ihre Eigenschaften und Strukturen werden untersucht.
ChemInform Abstract: PROPELLANES. I. 3,6,10,13‐TETRATHIA(4,5,11,12‐TRANS‐DICYCLOHEXANO)‐(6.6.1)PROPELLANE
Authors: JAMROZIK J. 
Published: April 2016

AbstractKondensation des Tetrabrommethylcyclopropans (I) mit dem trans‐ Dimercaptocyclohexan (II) führt zum neuen Propellan (III).
ChemInform Abstract: A NOVEL HETEROCYCLIC SYSTEM (PERHYDRO‐1,2,5,6‐DITHIADIAZOCINE‐4,7‐DIONE)
Authors: MAHMOOD A. A. , FAYADH J. M. 
Published: April 2016

AbstractMercaptoessigsäureester (I) reagiert mit Hydrazin (II) zu dem Diacylhydrazin (III), welches mit Dinitrofluorbenzol (IV) das Bisulfid (V) liefert.
ChemInform Abstract: REACTION OF DIAZOACETIC ACID ESTERS WITH SILYL‐SUBSTITUTED ACETYLENES AND PREPARATION OF 1‐H‐ AND 1,2‐DI‐H‐CYCLOPROPENE‐3‐CARBOXYLIC ACIDS AND THEIR ESTERS
Authors: DOLGII I. E. , OKONNISHNIKOVA G. P. , NEFEDOV O. M. 
Published: April 2016

AbstractLäßt man auf Diazoessigsäure‐methylester (I) bei 100 ‐ 110°C den 8‐fachen Überschuß von Methyl‐trialkylsilyl‐acetylen (II) einwirken (Katalysator: Kupfer oder Kupfersulfat), so entstehen die 1‐Methyl‐2‐trialkylsilyl‐cyclopropen‐3‐carbonsäuremethylester (III) mit Ausbeuten bis 54%.
ChemInform Abstract: CYCLO‐HYDROSILYLATION: A NOVEL ROUTE TO SILOXETANES AND SILANONES
Authors: LANE T. H. , FRYE C. L. 
Published: April 2016

AbstractDie aus (III) erhaltenen Hydrosilylierungsprodukte (V) und (VII)‐(IX) lassen die intermediäre Entstehung des Silanons (VI) vermuten.
ChemInform Abstract: REACTION OF DIISOPROPYL HYDROGEN DITHIOPHOSPHATE WITH CARBOXYLIC ACID NITRILES
Authors: PUDOVIK A. N. , CHERKASOV R. A. , ZIMIN M. G. , ZABIROV N. G. 
Published: April 2016

AbstractDer Dithiophosphorsäure‐0,0‐diisopropylester (II) setzt sich mit den Nitrilen der Benzoesäure (Ia), Phenylessigsäure (Ib) bzw. Cyanessigsäureethylester (Ic) bei 20°C während 10 ‐ 15 Tagen über die Anlagerungsverbindungen (III), die N‐(O,O‐Diisopropyl‐thiophosphoryl)‐thioalkylamide (IV) und mehrere weitere Zwischenstufen und Umlagerungen zu den Thioalkylamiden (V) und Tetraisopropyl‐trithiopyrophosphat (VI) um.
ChemInform Abstract: TETRATHIAFULVALENE; PHOTOCHEMICAL FORMATION OF HETEROFULVALENES AND DITHIOLENE COMPLEXES
Authors: FANGHAENEL E. , POLESCHNER H. 
Published: April 2016

AbstractDie Dithiolthione (I), das Thiaselenolthion (IIIa) bzw. das Diselenolthion (IIIb) geben bei UV‐Bestrahlung unter Schwefeleliminierung die Heterofulvalene (II), (IVa) bzw. (IVb); (IVa) bzw. (IVb) werden alternativ aus (IIIa) über das Salz (V) bzw. aus dem Diselenolselon (VI) und Ph3P synthetisiert.
ChemInform Abstract: SYNTHESIS OF TIN(IV)‐OXYGEN AND ‐SULFUR HETEROCYCLES AND THEIR TRANSFORMATION TO TIN(II) ANALOGS
Authors: HONNICK W. D. , ZUCKERMAN J. J. 
Published: April 2016

AbstractDurch Kondensation von Diorganozinnoxiden mit Diolen, Carbonsäuren und Thiolen in Benzol wurden die heterocyclischen Verbindungen (I) bis (IV) und durch Umsetzung mit N,N′‐Ethylen‐bis‐[salicylidenamin] der Sn(IV)‐ Komplex (V) dargestellt.
ChemInform Abstract: CYCLOPENTADIENYLACTINOID(IV) POLY(PYRAZOL‐1‐YL)BORATES
Authors: BAGNALL K. W. , BEHESHTI A. , EDWARDS J. , HEATLEY F. , TEMPEST A. C. 
Published: April 2016

AbstractDie Titelkomplexe wurden mit Hydrido‐tris‐[pyrazolyl]‐borat, einem potentiell dreizähnigen Liganden, und Dihydrido‐bis‐[pyrazolyl]‐borat, einem potentiell zweizähnigen Liganden, dargestellt und im Hinblick auf ihre Stabilität verglichen.
ChemInform Abstract: DISPROPORTIONATION OF A NEUTRAL METAL‐FORMYL COMPLEX AND SYNTHESIS OF A STABLE HYDROXYMETHYL‐METAL COMPOUND
Authors: CASEY C. P. , ANDREWS M. A. , MCALISTER D. R. 
Published: April 2016

AbstractDer Formyl‐Re‐Komplex (I) als reines Öl disproportioniert sich Canizzaro‐ähnlich bei Raumtemp. unter Stickstoff zu dem Zweikernkomplex (II).
ChemInform Abstract: SYNTHESIS, CRYSTAL STRUCTURE, AND STEREOCHEMICAL NONRIGIDITY OF μ‐(1‐Σ:1‐2‐η‐2‐CARBOXYLATO‐1‐ETHYLBUT‐1‐ENYL‐O(2FE))BIS(TRICARBONY# LIRON)(FE‐FE), A NEW COMPLEX OBTAINED FROM IRON CARBONYLS UNDER APOLAR CONDITIONS
Authors: AIME S. , MILONE L. , SAPPA E. , TIRIPICCHIO A. , TIRIPICCHIO CAMELLINI M. 
Published: April 2016

AbstractDie Titelverbindung (I) wird neben anderen bekannten Komplexen durch die Umsetzung von Dodecacarbonyltrieisen mit Hexin‐(3) in siedendem n‐Heptan unter N2 gebildet und IR‐, massen‐ sowie NMR‐spektroskopisch charakterisiert.
ChemInform Abstract: REACTIONS OF CYCLOPENTADIENYL(TRIBUTYLPHOSPHINE)COPPER(I) AND NICKELOCENE WITH SOME α‐BROMO ACIDS
Authors: MANSSON J.‐E. , OLSSON T. , WENNERSTROEM O. 
Published: April 2016

AbstractNickelocen (I) reagiert ohne oder in Gegenwart von Triphenylphosphin mit den α‐Bromsäuren (II) zu den α‐Cyclopentadienylsäuren (III) unter Eliminierung von Bromo‐cyclopentadienyl‐Ni (IV) bzw. seinem Triphenylphosphin‐Addukt.