bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Preparation of Thin (0.6 um) Continuous Monocrystalline Silicon over SiO2.
Authors: JASTRZEBSKI L. , CORBOY J. F. , PAGLIARO R. JUN. , SOYDAN R. 
Published: May 2016

AbstractThin (0.6 um), acceptably smooth, Continuous silicon over and between SiO2 layers can be obtained in an economically viable fashion if CVD growth is combined with thinning by oxidation.
ChemInform Abstract: A New Crown Heteropolyanion, K28Li5H7P8W48O184·92 H2O: Synthesis, Structure, and Properties.
Authors: CONTANT R. , TEZE A. 
Published: May 2016

AbstractThe title compound spontaneously crystallizes from solutions of K,2H2P2W,2O48 in lithium acetate‐acetic acid buffer.
ChemInform Abstract: Chemistry and Spectroscopy of Binuclear Platinum Diphosphite Complexes.
Authors: CHE C.‐M. , BUTLER L. G. , GRUNTHANER P. J. , GRAY H. B. 
Published: May 2016

AbstractThe preparation procedure of K4[Pt2(pop)4].2 H2O (pop: P2O5H2) is modified in order to obtain material that is not contaminated by partially oxidized Pt species.
ChemInform Abstract: Calcium and Magnesium Binding to γ‐Carboxyglutamate and β‐Carboxyaspartate Residues: Structures of Calcium and Magnesium Complexes of Methylmalonic Acid.
Authors: CURRY M. E. , EGGLESTON D. S. , HODGSON D. J. 
Published: May 2016

AbstractThe reaction of Calcium or magnesium hydroxide in warm water with a solution of α‐methylmalonic acid in methanol yields the complexes (I) and (II) (no yields given), whose structures were determined by crystallographic measurements.
ChemInform Abstract: Synthesis of Aromatic Schiff Base Oligomers at the Air/Water Interface.
Authors: ENGEL A. K. , YODEN T. , SANUI K. , OGATA N. 
Published: May 2016

AbstractWhen dialkylterephthalaldimines (dihexyl, didodecyl, dioctadecyl) were spread onto acidic solutions of p‐phenylenediamine, aromatic Schiff base Oligomers were formed at the air‐water interface.
ChemInform Abstract: Electrochemical Reduction of Trichloromethylbenzene. Part 2. Reduction in the Presence of Electrophiles.
Authors: GISSELBRECHT J.‐P. , LUND H. 
Published: May 2016

AbstractElectrochemical reduction of the title compound (I) in the presence of acetic anhydride yields the 1,2‐diacetoxy derivative (III) as the main product.
ChemInform Abstract: On the Steric Course of the Reduction of 2‐Alkoxy‐4‐pyranones: A Remarkable Demonstration of Anomeric Control.
Authors: DANISHEFSKY S. , LANGER M. E. 
Published: May 2016

AbstractEs wird der sterische Verlauf der Reduktion von 2‐Methoxy‐4‐pyranonen untersucht.
ChemInform Abstract: Reaction of 2,2‐Dichloromalonamides and 2,2‐Dichloromalonamoyl Chlorides with Nucleophilic Reagents.
Authors: RIED W. , NENNINGER J. 
Published: May 2016

AbstractReaction of ZJ‐dichloromalonamides (I) with mononucleophilic reagents such as 4‐nitrophenol, 4‐chlorothiophenol or amines leads to Substitution of both chlorine atoms giving (II).
ChemInform Abstract: Alicyclic Reaction Mechanisms. Part 7. Solvolysis Reactions and Force Field Calculations with Epimeric Cyclohexane Derivatives.
Authors: SCHNEIDER H.‐J. , SCHMIDT G. 
Published: May 2016

AbstractSolvolysis of the epimeric tosylates (I) and (V) with the weakly nucleophilic solvent forms the ethers (III) and (IV).
ChemInform Abstract: Alicyclic Reaction Mechanisms. Part 8. Solvolyses of 17‐(Tosyloxy)androstanes in Hexafluoroisopropyl Alcohol.
Authors: SCHNEIDER H.‐J. , BECKER N. 
Published: May 2016

AbstractDue to a difference in enthalpy of activation of ca. 7 kcal/mol, the ratio of rate constants for epimeric solvolysis is much higher for (Ia)/(IVa) than for (Ib)/(IVb) or the cyclopentanes (Va)/(Vb).
ChemInform Abstract: exo‐Selective Peripheral Cycloaddition Reactions of Pyrido[2,1‐a]isoindole.
Authors: KAJIGAESHI S. , MORI S. , FUJISAKI S. , KANEMASA S. 
Published: May 2016

AbstractThe title compound (III), which is prepared from (Ia) via (Ib) and (II), cycloadds to ole‐ ?nic dipolarophiles (IV) and (Va) in a highly exo‐selective manner to give the kinetically controlled (labile) cycloadducts (VIIa), (VIIb) + (VIIc), or (VIId) (not isolated), which gradually isomerize to give the Michael adducts (VIIIa) [from (VIIa) or (VIIb)/(VIIc)] and (VIIIb) [from (VIId)].
ChemInform Abstract: Preparation and Conformational Study of Partially Saturated 3,l‐Benzoxazines, 3,1‐Benzoxazin‐2‐ones and 3,1‐Benzoxazin‐2‐thiones.
Authors: BERNATH G. , STAJER G. , SZABO E. A. , FUELOEP F. + , SOHAR P. 
Published: May 2016

AbstractMit cis‐ und trans‐2‐Amino‐4‐cyclohexen‐1‐carbonsäuren (I) werden die im Formelschema aufgeführten Reaktionen durchgeführt.
ChemInform Abstract: The Role of Norcaradiene Intermediates in the Thermal Rearrangement of Norbornadien‐7‐one Acetals.
Authors: SUNKO D. E. , LOVRIC Z. , VANCIK H. 
Published: May 2016

AbstractDer aus dem Anhydrid (I) zugängliche Diester (III) lagert sich spontan über Norcaradien (IV) und Cycloheptatrien (V) in den Triester (VI) um.
ChemInform Abstract: Nickelocene‐Lithium Aluminium Hydride. A New Effective Desulphurization Reagent.
Authors: CHAN M.‐C. , CHENG K.‐M. , LI M. K. , LUH T.‐Y. 
Published: May 2016

AbstractDurch Nickelocen/Lithiumaluminiumhydrid werden die C‐S‐Bindungen in den Mercaptanen (I) und (VI) sowie Thioethern (IV) und (VIII) und im Disulfid (III) reduktiv gespalten.
ChemInform Abstract: Activation of CO2 in the Reaction with Butadiene Catalyzed by Palladium Complexes.
Authors: DZHEMILEV U. M. , KUNAKOVA R. V. , SIDOROVA V. V. 
Published: May 2016

AbstractDie Palladium‐katalysierte Carboxylierung von Butadien (I) führt in Abhängigkeit von Molverhältnis der Komponenten, von der Katalysatormenge und von den Reaktionsbedingungen zu wechselnden Gemischen der Octatri‐ encarbonsäuren (II) und (III) mit dem Lacton (IV).
ChemInform Abstract: Olefin Synthesis by Reaction of Stabilized Carbanions with Carbene Equivalents.
Authors: PEARLMAN B. A. , PUTT S. R. , FLEMING J. A. 
Published: May 2016

AbstractDie Nitrile (I) werden mit Tributyl‐iodmethyl‐zinn (II) zu (III) substituiert und dann mit Methyllithium/Lithiumbromid zu den Olefinen (IV) gespalten.
ChemInform Abstract: Chemistry of Organic Fluorine Compounds. Part 28. Reactivity of 2,2‐Difluoro‐ 3‐methyl‐3‐butenal Toward Some O‐, N‐ and C‐Nucleophiles.
Authors: VESELY I. , DEDEK V. 
Published: May 2016

AbstractTitle compound (I) displays a marked tendency to polymerization; (II) and (IV) are two of the few N‐ and O‐nucleophiles that react with (I) to give the expected products (III) and (V) in moderate yields.
ChemInform Abstract: Conformational Control of Enolate Geometry: A Short Synthesis of Germacrene‐D.
Authors: SCHREIBER S. L. , HAWLEY R. C. 
Published: May 2016

AbstractAus dem Cyclohexenon (I) wird Germacren D (VIII) hergestellt und in Mintsul‐ ?d (IX) bzw. β‐Bourbonen (X) übergeführt.
ChemInform Abstract: A Facile Synthesis of 1,4‐Benzoquinones Having a Hydroxyalkyl Side Chain.
Authors: GOTO G. , OKAMOTO K. , OKUTANI T. , IMADA I. 
Published: May 2016

AbstractZunächst werden entsprechend den Umsetzungen des Formelschemas auf verschiedenen Wegen die (o‐Acetoxyalkansäuren (III) dargestellt und in die Säurechloride (XII) übergeführt.
ChemInform Abstract: Sulfur Extrusion from 3H‐1,2‐Dithiol‐3‐imines: Isolation and Molecular Structure of 2‐(Arylimino)‐2H‐thietes.
Authors: GOERDELER J. , YUNIS M. , PUFF H. , ROLOFF A. 
Published: May 2016

AbstractThe 1,2‐dithiol‐3‐imines (IV) are obtained from (I).
ChemInform Abstract: F‐Acids ‐ Precursors of Urofuranic Acids.
Authors: SCHOEDEL R. + , DIETEL P. , SPITELLER G. 
Published: May 2016

AbstractThe excretion of the pentylurofuranic acid (I) in human urine strongly increases after intake of a sample of F‐acid methyl ester (II).
ChemInform Abstract: Carbon Dioxide: A Reagent for the Protection of Nucleophilic Centres and the Simultaneous Activation of Alternative Locations to Electrophilic Attack.
Authors: KATRITZKY A. R. , AKUTAGAWA K. 
Published: May 2016

AbstractIndol kann unter Verwendung von Li‐Salzen und Kohlendioxid zum Schutz der N‐Funktion mit zahlreichen elektrophilen Reagentien (II) in einfacher Weise in die entsprechenden Substitutionsprodukte (III) übergeführt werden.
ChemInform Abstract: The Influence of Steric and Electronic Effects on the Stability of Aldonitrones and on Their Conversion into Isoxazolidines.
Authors: AURICH H. G. , EIDEL J. , SCHMIDT M. 
Published: May 2016

AbstractThe nitrones (III) were isolated from the reaction of the hydroxylamine (Ia) with aldehydes (IIa)‐(IIg).
ChemInform Abstract: 2H‐Thiopyrans as Intermediates in the Rearrangement of Thiophenium Bisalkoxycarbonylmethylides to Thiophene‐2‐malonates: The Crystal and Molecular Structures of 2,2‐Bis‐tert‐butoxycarbonyl‐5‐bromo‐2H‐thiopyran and 2,2‐Bis‐tert‐butoxycarbonyl‐6‐bromo‐2H‐thiopyran.
Authors: BOWLES T. , JONES R. , PORTER A. E. A. , RECHKA J. A. , RZEPA H. S. , WILLIAMS D. J. 
Published: May 2016

AbstractDas aus 2‐Brom‐thiophen (I) und dem Diazomalonester (II) erhaltene Thiopheniummethylid (III) lagert sich thermisch in das Thiopyran (IV) um.
ChemInform Abstract: Nitrogen‐bridged Heterocycles. Part 5. Preparation of Pyrido‐ and Azepino‐fused Cycl[3.2.2]azines.
Authors: NOGUCHI M. , TANIGAWA N. , KAJIGAESHI S. 
Published: May 2016

AbstractThe title compounds (V) are obtained from the reaction of electron‐deficient alkynes (IV) with the heterocycles (IIc).
ChemInform Abstract: A One‐Step Synthesis of 1,4‐Benzodiazepines: Synthetic Studies on Neothramycin.
Authors: MORI M. , KIMURA M. , UOZUMI Y. , BAN Y. 
Published: May 2016

AbstractAus den 2‐Halogen‐anilinen (I) erhält man unter Carbonylierungs‐Bedingungen mit den Glycin‐Derivaten (II) die Benzodiazepindione (III) neben den Hydantoinen (IV).
ChemInform Abstract: Addition of Monobromo‐ and Dibromomalonic Ester to Vinyltrimethylsilane.
Authors: AMRIEV R. A. , VINOGRADOVA L. V. , VELICHKO F. K. 
Published: May 2016

AbstractDie Malonester (I) lagern sich in Gegenwart von Dibenzoylperoxid an Vinyltrimethylsilan (II) unter Bildung der Addukte (III) an.
ChemInform Abstract: Molecular Building Blocks for the Synthesis of Ceramic Materials: (Si8O12)(OCH3)8.
Authors: DAY V. W. , KLEMPERER W. G. , MAINZ V. V. , MILLAR D. M. 
Published: May 2016

AbstractThe title compound (Ia) prepared as shown is designed to serve as a building block for the synthesis of silicas based on [Sigolzlog/z subunits by hydrolysis followed by condensation.
ChemInform Abstract: Pyrophosphate Formation via a Phosphoramidate Intermediate in Polyammonium Macrocycle/Metal Ion‐Catalyzed Hydrolysis of ATP.
Authors: YOHANNES P. G. , MERTES M. P. , MERTES K. B. 
Published: May 2016

AbstractDer Einfluß von Mg‐, Caund Zn‐dibromid auf die Hydrolysegeschwindigkeit von ATP in Gegenwart des Makrocyclus (Ia) bei pH 7.6 und 70°C sowie auf die Konzentration des Phosphoramidat‐Zwischenprodukts (Ib) wird mittels 31P‐NMR‐Spektroskopie untersucht.
ChemInform Abstract: Highly Reactive Organolanthanides. Synthesis, Chemistry, and Structures of 4f Hydrocarbyls and Hydrides with Chelating Bis(polymethylcyclopentadienyl) Ligands.
Authors: JESKE G. , SCHOCK L. E. , SWEPSTON P. N. , SCHUMANN H. , MARKS T. J. 
Published: May 2016

AbstractDie wie aufgezeichnet synthetisierten Li‐dimethylsilylen‐bis‐(tetramethylcyclopentadienyl)‐lanthanide (II) reagieren mit Bis‐[trimethylsilyl]‐methyl‐Li zu den Disilylmethyl‐Derivaten (III).
ChemInform Abstract: Synthetic, Structural, Spectroscopic, and Theoretical Studies of Decamethylvanadocene Arylnitrenes.
Authors: OSBORNE J. H. , RHEINGOLD A. L. , TROGLER W. C. 
Published: May 2016

AbstractDie Titelverbindungen (I) werden wie aufgezeichnet aus Decamethylvanadocen (II) und den Arylaziden erhalten.
ChemInform Abstract: Synthesis, Structure, and Reactivity of the {[(η5‐C5H5)2U]2(μ‐κ2O‐TiW5O19)2}4‐ Anion.
Authors: DAY V. W. , EARLEY C. W. , KLEMPERER W. G. , MALTBIE D. J. 
Published: May 2016

AbstractThe reaction of the potential tridendate ligand ClTiwsOifg" , prepared from TiCl4 and W02" , with (C5H5)3UCI yields, instead of the expected adduct, the stable title complex anion (I).
ChemInform Abstract: Mixed‐Valence Dialkylbiferrocenium Salts: An Explanation for the Observed Temperature Dependence of Electron‐Transfer Rates.
Authors: DONG T.‐Y. , HENDRICKSON D. N. , IWAI K. , COHN M. J. , GEIB S. J. , RHEINGOLD A. L. , SANO H. , MOTOYAMA I. , NAKASHIMA S. 
Published: May 2016

AbstractData are presented to indicate that the rate of intramolecular electron transfer in mixed‐valence biferrocenium triiodide (Ia) and mixed‐valence dialkyl‐substituted biferronium triiodide salts (Ib) , (Ic) is controlled by dynamics in the solid state.
ChemInform Abstract: Valence‐Detrapping Modes for Electron Transfer in the Solid State of Mixed‐Valence, Oxo‐Centered, Trinuclear Iron Acetate Complexes: X‐Ray Structure and Physical Data for [Fe3O(O2CCH3)6 (4‐Et‐py)3](4‐Et‐py).
Authors: OH S. M. , HENDRICKSON D. N. , HASSETT K. L. , DAVIS R. E. 
Published: May 2016

AbstractTemp.‐dependent Mössbauer spectra of the complexes (I) and (II) and the X‐ray structure of the title compound (Ic) at 163 and 298 K (both C2/c, Z=4), which indicate more symmetric of the Fe3 triangle at the higher temp., are determined and discussed.
ChemInform Abstract: Solution Equilibria Between C‐Bonded CO and Π‐CO Ligands in Four‐Iron Clusters and Cleavage of the Π‐CO Ligand.
Authors: HORWITZ C. P. , SHRIVER D. F. 
Published: May 2016

AbstractThe interaction of the Lewis acids [R3PAu] , [LCu] and [MeHg]+ with the tetrahedral cluster [Fe4(CO),3]2" produces an equilibrium mixture of the tetrahedral isomer (I) and the butterfly isomer (II) with a I′l‐ CO ligand between the wingtips in solution.
ChemInform Abstract: (Carbonylbis((dialkylamino)phosphido))hexacarbonyldiiron Complexes: Migration of a Carbonyl Group from Iron to Phosphorus.
Authors: KING R. B. , WU F.‐J. , SADANANI N. D. , HOLT E. M. 
Published: May 2016

AbstractDas Tetracarbonylferrat (I) in Form seines Dioxan‐Sesquisolvats reagiert mit den Aminodichlorophosphinen (II), die sperrige N‐Substituenten enthalten, unter Bildung der Titelkomplexe (III).
ChemInform Abstract: Pentamethylcyclopentadienyl Transition Metal Complexes. Part 10.
Authors: KOELLE U. + , FUSS B. 
Published: May 2016

AbstractDie Ethylenabspaltung aus dem Co(I)‐Komplex (I) in siedendem Hexan in Gegenwart der Acetylene (II) liefert neben den Acetylentrimerisierungsprodukten (IIIa)‐(IIIc) für (IIc) die Komplexe (IV) und (V) und für (IId) den neuen Komplextyp (VI).
ChemInform Abstract: Multiple Metal Exchange for μ3‐Methylidyne Tricobalt Clusters.
Authors: BLUMHOFER R. , FISCHER K. , VAHRENKAMP H. 
Published: May 2016

AbstractAuf die Titelkomplexe (I) werden die bekannten Metallaustausch‐Reagentien (II)‐(IV) angewendet.
ChemInform Abstract: Activation of Methane by Photoexcited Copper Atoms and the Photochemistry of Methylcopper Hydride in Solid Methane Matrices.
Authors: PARNIS J. M. , MITCHELL S. A. , GARCIA‐PRIETO J. , OZIN G. A. 
Published: May 2016

AbstractThe mechanism of the photoactivation of methane by Cu atoms to form MeCuH is discussed.
ChemInform Abstract: Transition Metal Fulvene Complexes. Part 24. Synthesis and Structure of (μ‐η5:η1‐6,6‐Diphenylfulvene)diruthenium(Ru ‐ Ru)‐ and ‐diiron(Fe ‐ Fe) Complexes.
Authors: TOEFKE S. + , HAUPT E. T. K. , BEHRENS U. 
Published: May 2016

AbstractDie Reaktion des (u‐n52113‐Diphenylfulven)‐diruthenium‐Komplexes (IIa) mit den entsprechenden Liganden wie aufgezeichnet führt zu den Titelkomplexen (Ia)‐(Ic) (M: Ru).
ChemInform Abstract: Preparation and Structure of New Six‐membered Metallaheterocycles.
Authors: ROESKY H. W. , GRIES T. , HOFMANN H. , SCHIMKOWIAK J. , JONES P. G. , MEYER‐BAESE K. + , SHELDRICK G. M. 
Published: May 2016

AbstractNitrogen and Sulfur ‐ Nitrogen Bonds.
ChemInform Abstract: Triterpenes. Part 71. Oxidation of 19β,28‐Epoxy‐18α‐oleanan‐3‐one and ‐1‐one with Peracids.
Authors: SEJBAL J. , KLINOT J. , HRNCIROVA D. , VYSTRCIL A. 
Published: May 2016

AbstractOxidation of (I) with peracids leads to the lactone (II), which is converted to A‐seco acids (III) or (VIa) and their esters (V) or (VIb) and (VIc).
ChemInform Abstract: A New Route to Unsymmetrical Ketones from Thioimidates via Ketenimines.
Authors: EL JAZOULI M. , MASSON S. , THUILLIER A. 
Published: May 2016

AbstractDie aus (I) zugänglichen N‐lithiierten Enamine (IV) ergeben über Imine (V) die unsymmetrischen Ketone (VI).
ChemInform Abstract: Reaction of 2l‐Bromo‐17α‐methoxy‐20‐ketopregnenes with Sodium Methoxide or Potassium Acetate.
Authors: NUMAZAWA M. , NAGAOKA M. 
Published: May 2016

AbstractDie Reaktion des 2l‐Bromsteroids (Ia) mit Methylat führt neben den Hydroxyverbindungen (Ib) und (Ic) zum Aldehyd (IIa), der auch als Acetat (IIb) charakterisiert wird.
ChemInform Abstract: Muramyl Peptides. Part l. Stereochemically Pure Derivatives of Muramic and Isomuramic Acids.
Authors: GROSS P. H. , RIMPLER M. 
Published: May 2016

AbstractAn improved, large‐scale preparation of the (R)‐(VIIIc) and (S)‐(VIIId) muramic acid derivatives is described, starting from the glucose derivative (I) via the intermediates (III), (V) and (VIIIa) + (VIIIb) [subsequent hydrolysis gives (VIIIc) and (VIIId)].
ChemInform Abstract: Transformation of Azido‐deoxy‐hex‐5‐enopyranosides into Carbocyclic Compounds.
Authors: PELYVAS I. , SZTARICSKAI F. , BOGNAR R. , NESZMELYI A. 
Published: May 2016

AbstractDurch Ferrier‐Umlagerung erhält man aus dem Pyranosid (I) das Cyclohex‐ 2‐enon‐Derivat (II) und aus dem isomeren Pyranosid (III) das Cyclohexanon‐Deri‐ 174 vat (IV).
ChemInform Abstract: On the Use of the Imine‐Diene Cyclocondensation Reaction in the Synthesis of Yohimbine Congeners.
Authors: DANISHEFSKY S. , LANGER M. E. , VOGEL C. 
Published: May 2016

AbstractDas aus dem Cyclohexenon‐carbonsäureester (II) erhaltene Keten‐acetal (IV) reagiert mit den bekannten Dihydro‐β‐carbolinen (I) zu den Addukten (V), aus (Va) entsteht das Yohimbin (VI).
ChemInform Abstract: Studies on the Chemical Constituents of Rutaceous Plants. Part 60.
Authors: ISHII H. , ICHIKAWA Y. , KAWANABE E. , ISHIKAWA M. , ISHIKAWA T. , KURETANI K. , INOMATA M. , HOSHI A. 
Published: May 2016

AbstractAusgehend von den Tetralonen (I) werden über die Amine (II) sowie die aliphatischen und aromatischen Formamide (III) bzw. (IV) die im Titel genannten Alkaloide (V) dargestellt.
ChemInform Abstract: Synthesis of Virginiamycin S1 and Virginiamycin S4.
Authors: KESSLER H. , KUEHN M. + , LOESCHNER T. + 
Published: May 2016

AbstractZwei Synthesen von Virginiamycin S. (VIIIa) und eine Synthese von Virginiamycin S4 (VIIIb) werden beschrieben: l. Das aus den Komponenten (I) und (II) (Dicyclohexylammoniumsalz) erhältliche Depsipeptid (IIIa) wird deblockiert [‐ (IIIb)] und nachfolgend mit dem Baustein (IV) über die Stufe (Va) in deren Deblockierungsprodukt (Vb) übergeführt.
ChemInform Abstract: Antibiotics from Gliding Bacteria. Part 28. Biosynthesis of Myxothiazol (I) in Myxococcus fulvus Mxf16.
Authors: TROWITZSCH‐KIENAST W. , WRAY V. , GERTH K. , REICHENBACH H. , HOEFLE G. + 
Published: May 2016

Abstract(TROWITZSCH‐KIENAST , W.; WRAY, V.; GERTH, K.; REICHENBACH, H.; HÖFLE, G.; Liebigs Ann.
ChemInform Abstract: Preparations of Chiral Hydroxyester Synthons via Stereoselective Porcine Pancreatic Lipase‐Catalysed Hydrolyses of meso‐Diesters.
Authors: KASEL W. , HULTIN P. G. , JONES J. B. 
Published: May 2016

AbstractAus den Diestern (I) erhält man über eine PPL‐katalysierte Hydrolyse zu (II) und Folgereaktionen das Lacton (III).
ChemInform Abstract: Determination of Flat‐Band Position of CdS Crystals, Films, and Powders by Photocurrent and Impedance Techniques.
Authors: FINLAYSON M. F. , WHEELER B. L. , KAKUTA N. , PARK K.‐H. , BARD A. J. , CAMPION A. , FOX M. A. , WEBBER S. E. , WHITE J. M. 
Published: May 2016

AbstractThe ?at‐band potential has been measured for three different forms of CdS and by three different methods.
ChemInform Abstract: Conductivity and Dielectric Relaxation in Calcium Nitrate Tetrahydrate and Sodium Thiosulfate Pentahydrate near Tg.
Authors: MACFARLANE D. R. , WONG D. K. Y. 
Published: May 2016

AbstractAdmittance data for Ca(NO3)2 ‐ 4 H2O (1) and Na2S2O3 ‐ 5 H2O (I) at temp. in the vicinity of the glass transition temp. (T3) are reported.
ChemInform Abstract: Chemistry of Colloidal Manganese Dioxide. Part 1. Mechanism of Reduction by an Organic Radical (A Radiation Chemical Study).
Authors: LUME‐PEREIRA C. , BARAL S. , HENGLEIN A. , JANATA E. 
Published: May 2016

AbstractThe preparation of colloidal MnOz by radiation Chemical reduction of KMnO4 in alkaline solution is described.
ChemInform Abstract: Oxidation of Sulphur Dioxide in Molten Alkali Nitrates.
Authors: LARDINOIS P. , GLIBERT J. , CLAES P. 
Published: May 2016

AbstractThe influence of some physical parameters (flow and dilution of the gas, volume of the solvent) on the oxidation of SO2 in molten alkali nitrates (reaction A) is determined.
ChemInform Abstract: Thallium(III) Oxidation of Oxovanadium(IV).
Authors: CHIMATADAR S. A. , NANDIBEWOOR S. T. , RAJU J. R. 
Published: May 2016

AbstractKinetic data for the Tl(III) oxidation of oxovanadium(IV) in H2SO4/Na2SO4 medium at constant ionic strength of 5 Mand 70°C are in accord with a two‐step mechanism with participation of T1(II).
ChemInform Abstract: Electrochemistry and Spectroelectrochemistry of Gallium(III) Porphyrins.
Authors: KADISH K. M. , BOISSELIER‐COCOLIOS B. , COUTSOLELOS A. , MITAINE P. , GUILARD R. 
Published: May 2016

AbstractAll of the compounds could be oxidized or reduced in C6H6 by single‐electron‐transfer steps in which the initial step yields the monocation or monoanion.
ChemInform Abstract: Kinetics and Mechanisms of Nucleophilic Displacements with Heterocycles as Leaving Groups.
Authors: MUSUMARRA G. , BRUNO M. , KATRITZKY A. R. , SAKIZADEH K. , ALUNNI S. , CLEMENTI S. 
Published: May 2016

AbstractThe tricyclic compounds (IIIa), prepared from (I) with the corresponding amines, undergo Substitution with piperidine and give pseudo‐first‐order rate constants (0.45‐ 126)‐ 1O′5/s. The analogously obtained pentacyclic compounds (VIa) react faster with the cyclic amine.
ChemInform Abstract: α‐Ketodicarboxylic Acid Chloride Imide Chlorides in the Synthesis of Heterocycles.
Authors: CAPUANO L. , HELL W. , WAMPRECHT C. 
Published: May 2016

AbstractThe title compounds (III), (V) and (VII) are prepared by α‐addition of the dicarboxylic acid dichlorides (II), (IV) and (VI) to the isocyanides (I).
ChemInform Abstract: Reactions of Perfluorinated Benzocyclobutene and 1‐Methylbenzocyclobutene with Fluoro‐olefins in the Presence of SbF5.
Authors: KARPOV V. M. , MEZHENKOVA T. V. , PLATONOV V. E. , YAKOBSON G. G. 
Published: May 2016

AbstractDie Umsetzung von Perfluorbenzocyclobuten (I) mit den Perfluorolefinen (II) führt über die Monoadditionsverbindungen (III) zu den Bisaddukten (IV) bzw. (V).
ChemInform Abstract: Ring Transformation of Isoxazoles into Furan and Pyran Derivatives.
Authors: CILLER J. A. , MARTIN N. , SEOANE C. , SOTO J. L. 
Published: May 2016

AbstractThe isoxazoles (I) undergo ring transformations to give the pyranes (VI) and (VIII) byring opening with Na ethoxide, treatment of the obtained α‐acyl nitriles (II) with the corresponding aldehydes (III) [to afford the unsaturated α‐cyano‐ketones (IV) and (VII)] and cyclocondensation with malodinitrile.
ChemInform Abstract: Oxygenation of Aromatic and Aliphatic Hydrocarbons by a New Reagent System, Fe(CH3CN)62+‐H2O2‐Ac2O : An Effective Model Reagent for Mono‐Oxygenase.
Authors: KOTANI E. , KOBAYASHI S. , ISHII Y. , TOBINAGA S. 
Published: May 2016

AbstractMit dem ausEisenperchlorat, Acetonitril, H2O2 und Acetanhydrid gebildeten Reagens werden aromatische und cycloaliphatische Kohlenwasserstoffe wie (I), (V) und (IXa) zu entsprechenden Acetaten und Diacetaten oxidiert.
ChemInform Abstract: Asymmetric Synthesis Using Chirally Modified Borohydrides. Part 4. Enantioselective Reduction of Ketones and Oxime Ethers with the Reagent Prepared from Borane and Polymer‐supported (S)‐(‐)‐2‐Amino‐3‐(p‐hydroxyphenyl)‐1,1‐diphenylpropan‐1‐ol.
Authors: ITSUNO S. , NAKANO M. , ITO K. , HIRAO A. , OWA M. , KANDA N. , NAKAHAMA S. 
Published: May 2016

AbstractThe polymer‐supported chiral amino alcohol (III) has been prepared by the reaction of chloromethylated polystyrene resin (II) and the (S)‐(‐)‐alcohol (I).