bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: A New Asymmetric Route to (+)‐Vincamine.
Authors: TAKANO S. , SATO S. , GOTO E. , OGASAWARA K. 
Published: May 2016

AbstractDas durch asymmetrische Aldolcyclisierung in literaturbekannter Weise erhaltene optisch aktive Endion (I) wird ge‐ mäß Formelschema in die Verbindung (XVI) umgewandelt, dievauf literaturbekannte Weise in das im Titel genannte Alkaloid (XVII) übergelührt werden kann.
ChemInform Abstract: A Simple Diastereoselective Synthesis of (±)‐Eldanolide.
Authors: FRAUENRATH H. , PHILIPPS T. 
Published: May 2016

AbstractThe key step in the synthesis of the title pheromone (X) is the acid‐catalyzed ring contraction of the dioxepin (IV), giving the cis compound (V) as (he main product.
ChemInform Abstract: Colouring of Amorphous WO3 with Hydrogen Penetrated Through an LaNi5 Thin Film.
Authors: ADACHI G. Y. , SAKAGUCHI H. , SHIMOGOHRI T. , SHIOKAWA J. 
Published: May 2016

AbstractBy applying a hydrogen pressure of 2.0‐ 10°C Pa to a transparent amorphous WO3 film, which is coated with a LaNi5 thin film, in a stainless steel vessel at 350 K (l0min), the colour of the amorphous WO3 becomes blue.
ChemInform Abstract: Reactions of r.f.‐Sputtered Copper Layers with Cd, Ga, Ge, Sn, and Zn.
Authors: SIMIC V. , MARINKOVIC Z. 
Published: May 2016

AbstractDuring r.f. sputtering of Cu layers on different metal Substrates, reactions at the Substrate‐ ‐layer interface lead to formation of the intermetallic compounds Cu4Cd3, CuGa, Cu9Ga4, Cu3Ge, Cu5Ge, Cuösns, Cu3Sn, CuZn4, and Cu5Zn3.
ChemInform Abstract: Interactions Between Functional Groups. Part 3. The Structure of N,N‐Dimethyl‐8‐nitro‐1‐naphthaleneamine in Seven Crystalline Environments.
Authors: EGLI M. , WALLIS J. D. , DUNITZ J. D. 
Published: May 2016

AbstractThe title compound (I) has been observed in seven different crystal environments.
ChemInform Abstract: The Photochemistry of Some Methoxy and Dimethylamino Derivatives of Azoxybenzene.
Authors: ALBINI A. , FASANI E. , MORONI M. , PIETRA S. 
Published: May 2016

AbstractDie Photolyse der Azoxybenzole (I) in Alkoholen und Benzol führt in Abhängigkeit vom Solvens zu verschiedenen Produkten.
ChemInform Abstract: Preparation of 1,3‐Dialkynyladamantanes and Their Aluminum Bromide‐Mediated Cycloaddition Adducts.
Authors: BROXTERMAN Q. B. , HOGEVEEN H. , KINGMA R. F. 
Published: May 2016

Abstract1‐Brom‐adamantan (I) reagiert mit Vinylbromid (II) in Gegenwart von Aluminiumtribromid zum Dibrom‐ethyl‐Derivat (III), das zum l‐Ethinyl‐ adamantan (IVa) dehydrobromiert und weiter zu (IVb) methyliert wird.
ChemInform Abstract: Chemistry of Micelles. Part 2. Cascade Molecules: Synthesis and Characterization of a Benzene[9]3‐Arborol.
Authors: NEWKOME G. R. , YAO Z. , BAKER G. R. , GUPTA V. K. , RUSSO P. S. , SAUNDERS M. J. 
Published: May 2016

AbstractDie Titelverbindung (Va) wird wie beschrieben synthetisiert und u.a. anhand ihres Derivats (Vb) charakterisiert.
ChemInform Abstract: A New Synthesis of 2H‐Pyran‐2‐ones.
Authors: STETTER H. , KOGELNIK H.‐J. 
Published: May 2016

AbstractNach Veresterung der Diethylphosphonoalkancarbonsäuren (I) mit den Enolketonen (II) zu (III) führt die intramolekulare Olefinierung unter Cyclisierung zu Pyronen (IV).
ChemInform Abstract: Benzo[h]naphthyridine‐Maleic Acid Adducts Formed by Hydrogen Bond Interaction.
Authors: POSTAWKA A. , SLIWA W. 
Published: May 2016

Abstract1,5‐ and 1,6‐benzo[h]naphthyridines react with maleic acid to form the l :l adducts (I) or (II).
ChemInform Abstract: Complexes of Macrocyclic Polyethers and Neutral Guest Molecules: A Systematic Approach to the Complexation of Water Molecules by 2,6‐Pyridinium Crown Ethers.
Authors: GROOTENHUIS P. D. J. , UITERWIJK J. W. H. M. , REINHOUDT D. N. , VAN STAVEREN C. J. , SUDHOELTER E. J. R. + , BOS M. , VAN EERDEN J. , KLOOSTER W. T. , KRUISE L. , HARKEMA S. 
Published: May 2016

AbstractpKa determinations of 2,6‐pyridinium crown ethers (I) and openchain analogues (IV) [obtained from (II)] in different solvent systems show that the acidity of these ligands depends on ring size and solvent.
ChemInform Abstract: Reactions of Dioxaphospholanes with Carbonylethylenes Directed to the Formation of Ylides or Phosphoranes.
Authors: EL MANOUNI D. , LEROUX Y. , BURGADA R. 
Published: May 2016

AbstractDie Michael‐Verbindungen (I) reagieren mit den trivalenten basischen Phosphorverbindungen (IIa) und (IIb) zu den Yliden (III), während die Dioxaphospholane (IV) zu einem Diastereomerengemisch der Spirophosphorane (V) reagieren, die teilweise in die Spirophosphorane (VI) umlagern.
ChemInform Abstract: First Synthesis and Structural Assessment of Alkali‐metal Carbonatodioxoperoxouranate(VI) Monohydrates, A2[UO2(O2)(CO3)]·H2O, and Carbonatooxodiperoxovanadate(V) Trihydrates, A3[VO(O2)2(CO3)]·3 H2O (A: Na, K).
Authors: BASUMATARY J. K. , CHAUDHURI M. K. , PURKAYASTHA R. N. D. , HIESE Z. 
Published: May 2016

AbstractThe title complexes (II) and (V) are synthesized.
ChemInform Abstract: Structural Dependence of an Electron‐Transfer Process: Nature of the Products of One‐Electron Oxidation of the Lacunar Cyclidene Complexes of Nickel(II) and Cobalt(II).
Authors: CHAVAN M. Y. , MEADE T. J. , BUSCH D. H. , KUWANA T. 
Published: May 2016

AbstractThe lacunar Ni(II) and Co(II) complexes (Ia) and the unbridged (Ib) are electrochemically oxidized to generate the corresponding metal (III) complexes by a one‐electron process, the nature of which is studied by ESR, UV and visible spectroscopy and by magnetic measurements.
ChemInform Abstract: Doubly and Triply Bridged Dihapto Phenylethynyl Triosmium Clusters by Oxidative Addition of Phenylethynyl Gold Compounds.
Authors: DEEMING A. J. , DONOVAN‐MTUNZI S. , HARDCASTLE K. 
Published: May 2016

AbstractOxidative addition of the gold complex (II) to the osmium Cluster (I) gives the compounds (IIIa) and (IIIb) (space group PI, Z=2).
ChemInform Abstract: Synthesis of Furo[3,2‐d]pyrimidine Nucleosides: A Novel C‐Nucleoside Isostere of Adenosine.
Authors: BHATTACHARYA B. K. , LIM M.‐I. , OTTER B. A. , KLEIN R. S. 
Published: May 2016

AbstractAus dem Dimethylamino‐acrylnitril (Ia) erhält man nach Hydrolyse zu (Ib) mit Chloracetonitril der Ether (Ic), der mit LDA zu einem Gemisch der 0cund β‐Isomeren (II) cyclisiert wird.
ChemInform Abstract: (D,L)‐(S)‐{2‐[N‐3‐(2‐Oxo‐tetrahydrothienyl)acetamido]}‐thioglycolic Acid: A Novel Mucolytic Agent of the Class of Homocysteine Thiolactone Derivatives.
Authors: GOBETTI M. , PEDRAZZOLI A. , BRADAMANTE S. 
Published: May 2016

AbstractAusgehend vom Homocysteinthiolacton (I) werden durch Acylierung mit a‐ oder β‐Halogencarbonsäurehalogeniden (II) die Thiolactone (III) hergestellt, die durch Umsetzung mit den Thioglykolsäureestern (IV) in die Derivate (V) übergeführt werden, die sich wegen ihrer mucolytischen Eigenschaften zur Behandlung von Bronchitis eignen.
ChemInform Abstract: Protection of n‐Si Photoanode Against Photocorrosion in Photoelectrochemical Cell for Water Electrolysis.
Authors: KAINTHLA R. C. , ZELENAY B. , BOCKRIS J. O'M. 
Published: May 2016

Abstractn‐Si photoelectrodes can be stabilized against photocorrosion under the conditions of O2 evolution for illumination times of more than 650h by chemically depositing a thin film of manganese oxide.
ChemInform Abstract: A 12% Efficient Photoelectrochemical Cell Based on Polycrystalline n‐CuInSe2 Electrodes.
Authors: RAZZINI G. , PERALDO BICELLI L. , SCROSATI B. , ZANOTTI L. 
Published: May 2016

AbstractA CulnSez preparation procedure is described that results in a very homogeneous n‐CulnSez polycrystalline material with an average grain size of l‐2 mm.
ChemInform Abstract: Reductive Carbon‐Carbon Cleavage in Caged Systems. A New General Synthesis of Linearly Fused cis‐syn‐cis‐Triquinanes.
Authors: MEHTA G. , RAO K. S. 
Published: May 2016

AbstractAus Cyclopentadien (I) und dem Chinon (II) entsteht in bekannter Weise das Kä?g‐Dion (III), das einer Vielzahl chemischer Umwandlungen, die z.Tl. im Formelschema angedeutet sind, unterworfen wird.
ChemInform Abstract: Steric Consequence of the Diastereoselective Addition of Chiral Lithium 2‐(1‐Dimethylaminoethyl)phenyl Cuprates to Some Enones.
Authors: ANDERSSON S. , JAGNER S. , NILSSON M. , URSO F. 
Published: May 2016

AbstractDie Adddition des chiralen Cuprates (II) an die Enone (III) liefert die Sß‐kon?gurierten Addukte (IV).
ChemInform Abstract: Comparison of Methods of Phthalic Anhydride Esterification to Butyl Benzyl Phthalate.
Authors: MAJNUSZ‐MYSLIWIEC M. , NOWAK D. , HERZOG G. , CHROMIAK E. 
Published: May 2016

AbstractThe conversion of (I) to (II) with BuOH and PhChzCl is carried out under a range of conditions to establish the optimum procedure.
ChemInform Abstract: Synthesis and Properties of the Cyclohexa[cd]perylenium Tetrafluoroborate.
Authors: YAMAMURA K. , MIYAKE H. , MURATA I. 
Published: May 2016

AbstractAus Perylen (Ia) erhält man über den Aldehyd (Ib) und die Dicarbonsäureester (Ic) und (Id) die Monocarbonsäure (Ie), die mit Phosphorpentachlorid und Zinntetrachlorid zu den Ketonen (II) und (III) cyclisiert wird.
ChemInform Abstract: Novel Preparation of 5,6,7,8‐Tetrahydroquinazolin‐4(3H)‐ones.
Authors: FUELOEP F. + , BERNATH G. 
Published: May 2016

AbstractDas Cyclohexanoncarboxamid (I) reagiert mit den Aldehyden (II) in Gegenwart von Ammoniak zu den Hexahydrochinazolonen (III), die zu den entsprechenden Tetrahydroverbindungen (IV) dehydriert werden.
ChemInform Abstract: Low Temperature‐Liquid Phase‐Fluorination of (C6F5)2Te: Formation of (C6F5)2Te2, (C6F5)2Te4 and (C6F11)2TeF4.
Authors: KLEIN G. , NAUMANN D. 
Published: May 2016

AbstractBis‐pentafluorphenyltellur (I) wird mit Xenondifluorid zu (II) sowie mit elementarem Fluor stufenweise über (II) zu (III) und (IV) fluoriert.
ChemInform Abstract: Aluminum Alkoxide Chemistry Revisited: Synthesis, Structures, and Characterization of Several Aluminum Alkoxide and Siloxide Complexes.
Authors: WENGROVIUS J. H. , GARBAUSKAS M. F. , WILLIAMS E. A. , GOING R. C. , DONAHUE P. E. , SMITH J. F. 
Published: May 2016

AbstractThere are two groups of A1 alkoxide (siloxide) β‐diketonate complexes, whose general properties and structures are quite different from each other.
ChemInform Abstract: Chemical Reactivity of Tetraisobutyldialuminum Towards Ethers, Nitrogen Lewis Bases, Aluminumtrimethyl, Borontrichloride and Ethylene.
Authors: SCHRAM E. P. , MILLER M. M. 
Published: May 2016

AbstractTreatment of the title compound A12iBu4 with THF or Et2O results in partial decomposition to afford A1 metal while reaction with γ‐picoline produces a bis‐adduct of limited stability.
ChemInform Abstract: Novel Fulvalene Derivatives of Zirconium: a Facile Entry into Organozirconium(III) Chemistry.
Authors: ASHWORTH T. V. , CUENCA AGREDA T. , HERDTWECK E. , HERRMANN W. A. 
Published: May 2016

AbstractThe reduction of zirconocene dichloride (I) with sodium amalgam, leads to the highly reactive, but isolable fulvalene Zr(III) complex (II).
ChemInform Abstract: The First Example of [2 + 2]Cycloaddition of Me4Ge2 to Multiple Bonds.
Authors: NEFEDOV O. M. , EGOROV M. P. , GAL'MINAS A. M. , KOLESNIKOV S. P. , KREBS A. , BERNDT J. 
Published: May 2016

AbstractDas durch Thermolyse gebildete Germen (II) reagiert mit dem Thiacycloheptin (III) unter Bildung des Thiadigermabicyclononens (IV).
ChemInform Abstract: Preparation and Properties of 4‐Picolylamine Derivatives of Pentacyanoferrate(II): Sodium Salts of Mononuclear [Fe(CN)5(4‐picolylamine)3‐, [Fe(CN)5(4‐picolylammonium)]2‐ and Binuclear, 4‐Picolylamine Bridged [Fe2(CN)10(4‐picolylamine)]6‐.
Authors: WILLIAMS P. A. M. , AYMONINO P. J. 
Published: May 2016

AbstractT0 obtain the mononuclear complex (I) an excess of pure ligand was mixed with an aqueous solution of Na3[Fe(CN)5(NH3)].
ChemInform Abstract: Preparation of Tetrakis(arylisocyanide)trialkylphosphitecobalt(I) Complexes with Sterically‐hindered Arylisocyanides.
Authors: BECKER C. A. L. , SINGER W. D. , TOWLER E. M. 
Published: May 2016

AbstractThe Complexes (II) are prepared by trialkyl phosphite Substitution reactions in (I) as shown.
ChemInform Abstract: Copper(I) ‐ Phenoxide Complexes: Synthesis and Ligand‐Induced Transformations of the Copper(I) ‐ Phenoxo Functionality.
Authors: FIASCHI P. , FLORIANI C. , PASQUALI M. , CHIESI‐VILLA A. , GUASTINI C. 
Published: May 2016

AbstractTo establish both the stability of the [Cu ‐ OAr] unit and the bonding mode of the ArO′ group, synthesis and structural characteristics of copper(I) complexes containing the [Cu ‐ OAr] unit are reported.
ChemInform Abstract: Oligophosphane Ligands. Part 16. Metal Dependence of Cyclometalation and Aren C‐H Activation in the Photolysis of cis‐H2M[P(CH2CH2CH2PMe2)3] (M: Fe, Ru) in Benzene.
Authors: ANTBERG M. , DAHLENBURG L. 
Published: May 2016

AbstractThe photolysis of the Fe title complex (IIa) leads to the cyclometalated compound (I).
ChemInform Abstract: High‐Valent Schiff‐Base Complexes of Osmium. X‐Ray Crystal Structure of trans‐[Os(IV)(salen)(SPh)2].
Authors: CHE C.‐M. , CHENG W.‐K. , MAK T. C. W. 
Published: May 2016

AbstractThe diamagnetic Os(VI) Schiff‐base complex (II) prepared as shown reacts with PPh3/ROH or PhSH to form the air‐stable diamagnetic 135 Os(IV) derivatives (III).
ChemInform Abstract: A Short Synthesis of Elasnin.
Authors: SHONE R. L. , DEASON J. R. , MIYANO M. 
Published: May 2016

AbstractDie Hexansäureester (I) werden alkalisch zu den β‐Ketoestern (II) kondensiert und nach Metallierung mit dem Imidazolid (III) weiter zu (IV) acyliert.
ChemInform Abstract: Total Synthesis of (±)‐11‐Desoxydaunomycinone and D‐Ring Modified Analogues.
Authors: ABDALLAH A. A. , GESSON J.‐P. , JACQUESY J.‐C. , MONDON M. 
Published: May 2016

AbstractThe desired title compound (IV) is obtained together with its 7‐epimer (V) starting from the tetracycle (I).
ChemInform Abstract: ESR Study of the Radicals Formed by UV Irradiation of TiO2 in the Presence of Sulfur Dioxide and Oxygen.
Authors: GONZALEZ‐ELIPE A. R. , SORIA J. 
Published: May 2016

AbstractThe SO2‐ radical can be formed on the surface of TiO2 by heating the sample in ,the presence of SO2 at 573 K and quenching at 77 K or by UV irradiation of TiO2 at 77 K in the presence of SO2.
ChemInform Abstract: Heterojunction Photoelectrodes. Part 3. Cyclic Voltammetry at Indium Tin Oxide‐ Coated Silicon/Aqueous Redox Electrolyte Interfaces.
Authors: CHYAN O. M.‐R. , HO S.‐I. , RAJESHWAR K. 
Published: May 2016

AbstractThe applicability of the cyclic Voltammetry (CV) technique for the analysis of heterojunction photoelectrodes is demonstrated using the Si/Sn‐doped indium oxide (ITO) as a model coating material and both p‐type as well as n‐type Si Substrates.
ChemInform Abstract: The Electrochemistry of Chromium(III) in Molten KSCN.
Authors: POTTER R. J. , SCHIFFRIN D. J. 
Published: May 2016

AbstractThe reduction of Cr3+ in molten KSCN (200°C) is quasi‐reversible, with a formal rate constant of 4‐7·10‐4cm s‐1.
ChemInform Abstract: Preparation, Crystal Structure and Raman Spectrum of Tetrachloro Phosphonium Tetrachloroiodate (PCl4)(ICl4).
Authors: SHAMIR J. , SCHNEIDER S. , BINO A. , COHEN S. 
Published: May 2016

Abstract[PC14][IC14] has been prepared by reaction of PCls and I2 in CH2Cl2 at 20°C or in POCl3 at 90°C (in situ preparation of I2Cl6).
ChemInform Abstract: Anhydrous Cerium(III) Perchlorate and Perchloratocerates(III) of Cesium.
Authors: SKOGAREVA L. S. , BABAEVA V. P. , ROSOLOVSKII V. YA. 
Published: May 2016

AbstractAnhydrous Ce(ClO4)3 is obtained by two methods: dehydration of Ce(ClO4)3‐9 H2O at 165‐170°C for 40h in vacuum or by reaction of CeCl3 with anhydrous HClO4 containing lO‐ 15% Cl2O7 at ‐ 10°C. The IR spectrum and the thermal behaviour of Ce(ClO4)3 are discussed.
ChemInform Abstract: Complexes of Hydroxamates. Part 1. Interaction of Methioninehydroxamic Acid with Iron(III) in Aqueous Solution.
Authors: EL‐EZABY M. S. , MARAFIE H. M. , HASSAN M. M. , ABU SOUD H. M. 
Published: May 2016

AbstractThe title reaction was studied spectrophotometrically at 25°C to define the equilibria and their reaction kinetics.
ChemInform Abstract: Chiral Ligands Containing Heteroatoms. (S)‐Proline and (1R)‐Menthylamine as Precursors of Modified Lithium Aluminium Hydride Reagents.
Authors: FALORNI M. , LARDICCI L. , GIACOMELLI G. 
Published: May 2016

AbstractThe title compounds (IV) and (Vb) are synthesized starting from the protected proline (I).
ChemInform Abstract: Cycloaddition Reactions of 5H‐Benzocycloheptene with Singlet Oxygen and with 4‐Phenyl‐1,2,4‐triazoline‐3,5‐dione, and the Chemistry of the 5H‐Benzocycloheptene Endoperoxides.
Authors: ATASOY B. , BALCI M. 
Published: May 2016

AbstractThe cycloaddition of singlet oxygen to the cycloheptatriene (II) yields the peroxide (III), the sec. products (IV) and (Va), and the aldehyde (Vb), which is formed from (IV) during the chromatographic workup.
ChemInform Abstract: Study on the Influence of Unsaturations on the Formation of C‐11, C‐12, C‐13 and C‐ 14 Membered Rings.
Authors: BRILLON D. , DESLONGCHAMPS P. 
Published: May 2016

AbstractDie intramolekulare Alkylierung der langkettigen Allylund Propargylchloride (I) in verdünnten Lösungen liefert neben offenkettigen Polymerisationsprodukten Gemische der chromatographisch trennbaren cyclischen Monomeren (II) und der Cyclodimeren (III).
ChemInform Abstract: Cyclizations of Some Furyl Acid Chlorides.
Authors: WALSH E. J. JUN. , STONE G. B. 
Published: May 2016

AbstractDurch intramolekulare Friedel‐ Crafts‐Acylierung der beiden isomeren Furylbuttersäurechloride (I) und (III) werden die Bicyclen (II) und (IV) erhalten.
ChemInform Abstract: Chemistry of Naturally Occurring Polyamines. Part 9. Synthesis of Spermidine and Spermine Photoaffinity Labeling Reagents.
Authors: NAGARAJAN S. , GANEM B. 
Published: May 2016

AbstractSpermidin liefert mit Formaldehyd das Cycloaddukt (Ia), das zu (Ib) substituiert und dann zum acyclischen Amin (IIa) gespalten werden kann.
ChemInform Abstract: Reactivity of Sulfurdioxide‐Anion Radical Against Reducible Substrates.
Authors: KNITTEL D. 
Published: May 2016

AbstractThe title anion radical, which is prepared in situ in an aprotic solvent saturated with S02, can be used for dehalogenation of α‐haloketones or polyhalides such as (I) or (III).
ChemInform Abstract: Direct Synthesis of Ethylene Glycol from Carbon Monoxide and Hydrogen by the Use of Cobalt Catalyst.
Authors: MASUDA T. , MURATA K. , KOBAYASHI T. , MATSUDA A. 
Published: May 2016

AbstractDie Bildung von Ethylenglykol (II) durch Reaktion von Kohlenoxid/ Wasserstoff mit Ethylen (I) unter verschiedenen Bedingungen (Temperatur," Lösungsmittel, Druck) in Gegenwart von Kobaltkatalysatoren wird untersucht.
ChemInform Abstract: Reaction of Dimethylsulfite with Dimethylaminomethyl Derivatives.
Authors: BAIRES S. V. , IVANOV V. B. , IVANOV B. E. , KROKHINA S. S. , EFREMOV YU. YA. , KORSHUNOV R. L. 
Published: May 2016

AbstractBei der Umsetzung von Dimethylsulfit (II) mit den Dimethylaminomethyl‐ Verbindungen (I) erhält man, vergleichbar mit der Arbusov‐Reaktion, das Betain (III).
ChemInform Abstract: Regioselective Sulfenylation of Oxime Dianions. A Novel and Useful Method for the Regioselective Ring Cleavage.
Authors: HIROI K. , OTSUKA M. , SATO S. 
Published: May 2016

AbstractAcetonoxim (I) kann über sein O,C‐Dianion zu (II) substituiert und dann weiter über die Dianionen (III) mit Diphenyldisulfid (IV) zu (V) substituiert werden.
ChemInform Abstract: 5‐β‐Nitroalkyl‐ and 5‐β,β‐Dinitroalkyltetrazoles.
Authors: PODGURSKII A. I. , ZLOTIN S. G. , LUK'YANOV O. A. 
Published: May 2016

Abstractβ‐Nitro‐propionitril (I) reagiert mit Aluminiumazid zu S‐(B‐NitrOethyl)‐tetrazol (II).
ChemInform Abstract: Synthesis and Psychotropic Activity of 2‐Aminonicotinic Acid Amides.
Authors: AKHUNDOV R. A. , ZHMURENKO L. A. , GLOZMAN O. M. , VORONINA T. A. , ZAGOREVSKII V. A. 
Published: May 2016

AbstractDie im Titel genannten Verbindungen (III) werden aus den 2‐Chlor‐nicotinamiden (I) durch Chlor‐Austausch mit den sekundären Aminen (II) hergestellt.
ChemInform Abstract: Synthesis of 4‐Hydroxy‐N‐[5‐(hydroxymethyl)‐3‐isoxazolyl]‐2‐methyl‐2H‐1,2‐benzothiazine‐3‐carboxamide 1,1‐Dioxide and [(5‐Methyl‐3‐isoxazolyl)amino]oxoacetic Acid. Major Metabolites of Isoxicam.
Authors: SIRCAR J. C. , CAPIRIS T. , BOBOVSKI T. P. , SCHWENDER C. F. 
Published: May 2016

AbstractDas entzündungshemmende Isoxicam (I) liefert beim Menschen oder bei der Ratte die Metaboliten (II) bzw. (III).
ChemInform Abstract: Synthesis of 1,2‐Bis(cyclosiloxanyl)ethanes.
Authors: ZHADANOV A. A. , KOTOV V. M. , PRYAKHINA T. A. 
Published: May 2016

AbstractDie Hydrosilylierung des Vinylcyclotrisiloxans (V) mit den aus dem Trisiloxan (I) und dem gilan (III) zugänglichen Cyclotetrasiloxanen (IV) führt zu den Bis‐cyclosiloxanylethanen (VI).
ChemInform Abstract: On the Reaction of 2,5‐Diphenyl‐1,2,3‐diazaarsole with 2‐Diazopropane.
Authors: ARBUZOV B. A. , DIANOVA E. N. , GALEEVA I. Z. , SHAGIDULLIN R. R. , EFREMOV YU. YA. , CHERNOV P. P. 
Published: May 2016

AbstractDas Diazaarsol (I) reagiert mit Diazopropan (II) über das Addukt (III) zu dem Diazaarsabi‐ cyclohexen (IW.
ChemInform Abstract: Pentacoordinated Molecules. Part 64. Synthesis and Molecular Structure of Five‐Coordinated Pheny1‐Substituted Anionic Germanium(IV) Complexes.
Authors: HOLMES R. R. , DAY R. O. , SAU A. C. , POUTASSE C. A. , HOLMES J. M. 
Published: May 2016

AbstractThe title complexes (I)‐(III) were synthesized from phenylgermanium trichloride and a catechol or thiocatechol ligand in benzene in the presence of NEt3.
ChemInform Abstract: Metal Complexes of Tetrapyrrole Ligands. Part 39. Effects of Steric Crowding on Porphyrin Conformation.
Authors: LAY K.‐L. , BUCHLER J. W. , KENNY J. E. , SCHEIDT W. R. 
Published: May 2016

AbstractThe free porphyrin base, bis(acetylacetonato)iron(II) and phenol were refluxed for 10min and gave the title compound (yield 63%), which has a nearly eclipsed arrangement of the two porphinato cores when viewed along the nearly linear Fe‐ U‐Fe spine.
ChemInform Abstract: Synthesis of cis‐[Co(en)2(MF6)2]MF6 (M: As or Sb): Cobalt(III) Complexes Containing η1‐MF6‐ Characterizable by 19F NMR.
Authors: DEAN P. A. W. 
Published: May 2016

Abstract(I) reacts in liquid SO2 with three mols of (II) to give products, which are assigned to have the structure (III) (yield near‐quantitative).
ChemInform Abstract: [Cu(Ph2PCH2CH2PEt2)2]Cl : A Chelated Copper(I) Complex with Tetrahedral Stereochemistry.
Authors: BERNERS PRICE S. J. , BREVARD C. , PAGELOT A. , SADLER P. J. 
Published: May 2016

AbstractThe air‐stable, water‐soluble title Complex (I) has been prepared by reaction of the diphosphine in CHCl3 with solid CuCl.
ChemInform Abstract: Metal Complexes of Purine‐N‐Oxides. Part 3. Proton Magnetic Resonance Investigation of Cu(II) Complexes of Adenine‐Nl‐Oxides.
Authors: NERDAL W. , SLETTEN E. 
Published: May 2016

AbstractAdenine‐N′‐oxide is shown to undergo a two‐step hydrolysis at pH 0.2.
ChemInform Abstract: Ecdysteroids. Selective Protections and Synthesis of Potential Tools for Biochemical Studies.
Authors: GUEDIN‐VUONG D. , NAKATANI Y. , OURISSON G. 
Published: May 2016

AbstractThe diol groups of cyasterone (Ia) can be selectively protected as shown in the scheme; analogous protections can be achieved for β‐ecdysone (II).
ChemInform Abstract: Conformationally Restricted Cyclic Nonapeptides Derived from L‐Cysteine and LL‐3‐Amino‐2‐piperidone‐6‐carboxylic Acid (LL‐Acp), a Potent β‐Turn‐Inducing Dipeptide Analogue.
Authors: KEMP D. S. , MCNAMARA P. E. 
Published: May 2016

AbstractDie Cyclo‐nonapeptide (I)‐(III) werden nach üblichen Verfahren hergestellt.
ChemInform Abstract: Chemical Etching of Ion Implanted Amorphous Silicon Carbide.
Authors: EDMOND J. A. , PALMOUR J. W. , DAVIS R. F. 
Published: May 2016

AbstractAmorphous SiC reacts completely and readily in a HF:HNO3 (l :l) solution at ä 318 K, while crystalline SiC does not react.
ChemInform Abstract: Aluminum Clusters: Magnetic Properties.
Authors: COX D. M. , TREVOR D. J. , WHETTEN R. L. , ROHLFING E. A. , KALDOR A. 
Published: May 2016

AbstractThe magnetic moments of gas phase Al‐clusters (2‐25 atoms) have been measured using spatially resolved photoionization timemf‐?ight MS.