bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: (3+2)‐ and (5+2)‐Cycloadditions of the Cyclohepta‐2,4‐dienyl Cation.
Authors: HEILMANN W. , KOSCHINSKY R. , MAYR H. 
Published: May 2016

AbstractThe cyclohepta‐2,4‐dienyl cation (II), generated in situ from the cycloheptadiene (I), undergoes (3+2)‐cycloaddition with the alkyne (III) to form a 1:1 mixture of the bicyclononenes (IV) and (V).
ChemInform Abstract: Solid‐Phase Reactivity of Pure Methyl Viologen Upon Thermolysis and Photolysis: A Vibrational and Electronic Study.
Authors: POIZAT O. , GIANNOTTI C. , SOURISSEAU C. 
Published: May 2016

AbstractWarming solid methyl viologen dichloride, MV2+(Cl‐)2, over 50 °C yields Cl‐MV+·Cl· via an intracomplex electron‐transfer process; warming to 180 °C yields 4,4'‐bipyridine and CH3Cl, probably via a second intracomplex charge‐transfer process.
ChemInform Abstract: Acylation of 1,3‐Butadiene by Acetyl Fluorosulfonate.
Authors: GAVRISHOVA T. N. , SHASTIN A. V. , BALENKOVA E. S. , NOVIKOV N. A. 
Published: May 2016

AbstractAcetyl fluoride (I) reacts with SO3 to give the acetyl fluorosulfonate mentioned in the title.
ChemInform Abstract: Kinetics and Mechanism of the Reactions of Superoxide Ion in Solution. Part 6. Interaction of Superoxide Ion with Adriamycin in Aprotic and Protic Media.
Authors: AFANAS'EV I. B. , POLOZOVA N. I. 
Published: May 2016

AbstractSuperoxide ion O‐· 2 reacts with adriamycin by one‐electron transfer in both aprotic and protic media due to irreversible transformation of the adriamycine semiquinone via dimerization and deglycosation.
ChemInform Abstract: A New Synthetic Entry into the Tricyclo(3.3.0.03,7)octane Skeleton.
Authors: CAMPS P. , IGLESIAS C. , LOZANO R. , MIRANDA M. A. , RODRIGUEZ M. J. 
Published: May 2016

AbstractThe diketones (I) react with potassium cyanide to give the corresponding cyanohydrines which are dehydrated to form the isomeric dinitriles (II) and (III).
ChemInform Abstract: Low‐Temperature Amidation of Carboxylic Acids by Aromatic Carbodiimides.
Authors: VOVK M. V. , DOROKHOV V. I. , SAMARAI L. I. 
Published: May 2016

AbstractThe reaction between the carboxylic acids (I) and the carbodiimides (II) proceeds at relatively low temp. to give the amides (III) in near to quantitative yields.
ChemInform Abstract: Synthesis of Some Thiazolylthiosemicarbazides, Triazoles, Oxadiazoles, Thiadiazoles and Their Microbial Activity.
Authors: GAWANDE N. G. , SHINGARE M. S. 
Published: May 2016

AbstractThe thiosemicarbazides (III) are synthesized by reaction of the thiazoles (I) with the isocyanates (II).
ChemInform Abstract: N1‐(7‐Flavonyloxy/chromonyloxy)acetyl‐N4‐arylthiosemicarbazides: Synthesis and Antibacterial and Antifungal Activities.
Authors: AHLUWALIA V. K. , GOYAL M. , JAIN A. , MEHTA V. D. 
Published: May 2016

AbstractTitle compounds of type (VI) are synthesized as shown and screened for their antibacterial and antifungal activity.
ChemInform Abstract: Synthesis and Biological Activities of 1,3,4‐Trisubstituted‐3,4‐dehydropiperidines.
Authors: GUPTA K. A. , SAXENA A. K. , JAIN P. C. , ANAND N. 
Published: May 2016

AbstractThe isoquinoline derivative (VII) is synthesized as shown and tested together with the intermediates (IV) and (VI) for antiamoebic and antileishmanial activity.
ChemInform Abstract: Synthesis, Pharmacological Activities and Physico‐Chemical Properties of 4‐(Substituted amino/N4‐arylpiperazinyl/aminocarbonyl)‐2,3‐polymethylenequinolines.
Authors: BINDRA J. S. , RASTOGI S. N. , PATNAIK G. K. , ANAND N. , RAO K. G. G. , DWIVEDI P. C. , RAO C. N. R. 
Published: May 2016

AbstractA large number of title compounds as well as some N‐substituted aminoacridines are synthesized according to known procedures in moderate to good yields and tested for their pharmacological activity.
ChemInform Abstract: Transformation of Sulfur Analogs of β‐Carboline by Nucleophiles.
Authors: STUPNIKOVA T. V. , KIRILASH A. R. , KLYUEV N. A. 
Published: May 2016

AbstractReaction of the benzothienopyridinium salt (I) with methylamine gives the anhydrobase (II) or the benzothienopyridine (III) depending on the reaction conditions.
ChemInform Abstract: Synthesis of N‐Nitrosamines by Cleavage of Aminals with Nitrosyl Chloride.
Authors: ALLAYAROV S. R. , BARKALOV I. M. , BAZHMUTOV YU. L. , GOL'DANCKII V. I. 
Published: May 2016

AbstractN‐Nitrosooxazolidine (IIa) and N‐nitrosotetrahydrooxazine (IIb) are prepared from the corresponding formaldehyde aminals (I) and nitrosyl chloride.
ChemInform Abstract: Phosphorylated β‐Dicarbonyl Compounds.
Authors: LIORBER B. G. , TARZIVOLOVA T. A. , PAVLOV V. A. , ZYKOVA T. V. , KISILEV V. V. , TUMASHEVA N. A. , SLIZKII A. YU. , SHAGVALEEV F. SH. 
Published: May 2016

AbstractThe phosphites (I) react with the malonic monochlorides (II) to give the phosphonic esters (III).
ChemInform Abstract: Synthesis of 2‐Oxo‐2‐alkoxy‐1,4,2‐dioxaphospholanes.
Authors: NOVIKOVA Z. S. , ODINETS I. L. , LUTSENKO I. F. 
Published: May 2016

AbstractThe phosphonites (I) react with the aldehydes (II) to give the ylenes (IV) via the phosphoranes (III).
ChemInform Abstract: Synthesis of 1,3,4‐Thiazaphospholes from 1‐Phenoxy‐2‐thiocyanatoethene.
Authors: DMITRICHENKO M. YU. , ROZINOV V. G. , BYCHKOVA T. I. , DONSKIKH V. I. , DOLGUSHIN G. V. , RATOVSKII G. V. , SERGIENKO L. M. 
Published: May 2016

AbstractThe thiocyanate (I) reacts with PCl5 to give the cyclic phosphonium salt (II).
ChemInform Abstract: Symmetric Dyes. Derivatives of Naphtho(1,8‐b,c)thiophene.
Authors: VASILENKO N. P. , MIKHAILENKO F. A. , MAIDANNIK A. G. 
Published: May 2016

AbstractCleavage of the 1,3‐dioxanedione derivative (I) with p‐toluenesulfonic acid gives the 2‐methylnaphthothiolium salt (II) which is coupled with the 2‐methylmercaptonaphthothiolium salt (III), producing the monomethine dye (IV).
ChemInform Abstract: Reaction of δ5,6‐Steroids with PhIO/NaN3/CH3COOH, Synthesis of 7a‐Azidosteroids.
Authors: MORIARTY R. M. , KHOSROWSHAKI J. S. 
Published: May 2016

AbstractThe Δ5,6‐steroid acetates (I) react with iodosobenzene and sodium azide in acetic acid to produce the allylic azides (II).
ChemInform Abstract: Synthetic Experiments in Lignans. Part 11. Use of Pyridinium Chlorochromate as a Regioselective Reagent in the Synthesis of 1‐Phenylnaphthalene Lactones.
Authors: ANJANEYULU A. S. R. , SASTRY CH. V. M. , UMASUNDARI P. , SATYANARAYANA P. 
Published: May 2016

AbstractIn contrast to bispyridinesilver permanganate which affords retro lactones of type (III) as main products, use of PCC renders possible a regioselective synthesis of the normal lactones (II) from the diols (I).
ChemInform Abstract: Cu(II) Coordination Chemistry of Amine Oxidases: Pulsed EPR Studies of Histidine Imidazole, Water, and Exogenous Ligand Coordination.
Authors: MCCRACKEN J. , PEISACH J. , DOOLEY D. M. 
Published: May 2016

AbstractPulsed EPR spectroscopy utilizing the electron spin echo envelope modulation technique is used to study the Cu(II) binding sites in porcine kidney and bovine plasma amine oxidases.
ChemInform Abstract: Stereospecific Syntheses and Spectroscopic Properties of Isomeric 2,4,6,8‐Undecatetraenes. New Hydrocarbons from the Marine Brown Alga Giffordia mitchellae. Part 4.
Authors: BOLAND W. , SCHROER N. , SIELER C. , FEIGEL M. 
Published: May 2016

AbstractAs shown for (IIIa) and (IIIb) or (VIIa) and (VIIb), various stereochemically pure enynes (III) and (VII) (purity > 98%, except for (VIIc): purity 90%) are prepared by non‐stereoselective Wittig reaction and subsequent chromatographic separation of the resulting E/Z‐pairs.
ChemInform Abstract: FTIR Spectra of Hydroxylamine‐Hydrogen Fluoride Complexes in Solid Argon.
Authors: LASCOLA R. , ANDREWS L. 
Published: May 2016

AbstractCodeposition of HF and NH2OH in excess argon at 12 K produces new IR absorption bands corresponding to perturbed acid and base submolecule vibrations for a 1:1 complex.
ChemInform Abstract: Hypervalent Iodine Iodinative Decarboxylation of Cubyl and Homocubyl Carboxylic Acids.
Authors: MORIARTY R. M. , KHOSROWSHAHI J. S. , DALECKI T. M. 
Published: May 2016

AbstractCyclopentanone is converted to the bromohomocubylcarboxylic acid (I) which reacts with diacetoxyiodobenzene and iodine under photolytic conditions to give the iodide (II).
ChemInform Abstract: Acylation of Benzimidazole According to Regel‐Buechel. Part 2. Deacylation and Dissociation of 1‐Methyl‐3‐acyl‐2‐(1‐methylbenzimidazol‐2‐yl)benzimidazolin‐4‐ones.
Authors: KHRISTICH B. I. , BONDARENKO E. V. 
Published: May 2016

AbstractAcylation of the benzimidazoles (I) with the acyl halogenides (II) in the presence of triethylamine gives the (3‐acylbenzimidazolyl)benzimidazolin (III).
ChemInform Abstract: Preparation of Alkyl‐ and Phenyl‐Substituted Pyrimidines.
Authors: MARTINEZ A. G. , FERNANDEZ A. H. , ALVAREZ R. M. , VILAR E. T. , FRAILE A. G. , BARCINA J. O. , IGLESIAS L. P. 
Published: May 2016

AbstractThe vinyl triflates (II), prepared from the ketones (I), react with an excess of the nitriles (III), yielding the pyrimidines (IV) as the main products.
ChemInform Abstract: Synthesis of Amino‐Substituted 2‐Methylcoumarans, ‐Chromans, ‐Benzoxepanes, and Their N‐Alkylaminoacyl Derivatives.
Authors: DAUKSHAS V. K. , PYATRAUSKAS O. YU. , PURVANYATSKAS G. V. 
Published: May 2016

AbstractNitration of 2‐methylcoumaran (Ia), chroman (Ib), and benzoxepane (Ic) with acetyl nitrate gives mixtures of the isomeric nitro derivatives (II) and (III) which are reduced, forming mixtures of the corresponding amines (IV).
ChemInform Abstract: Di‐2‐pyridyl Ketone Complexes of Copper(I): Efficient Photocatalysts for Norbornadiene‐Quadricyclane Conversion.
Authors: BASU A. , SAPLE A. R. , SAPRE N. Y. 
Published: May 2016

AbstractThe structure of the title complexes (III) and (V) is assigned on the basis of spectroscopic data.
ChemInform Abstract: Synthesis of Nα‐(Arylsulfonylglycyl)‐3‐amidinophenylalanine Esters as Fairly Specific Active Inhibitors of the Factor Xa.
Authors: VIEWEG H. , WAGNER G. 
Published: May 2016

AbstractThe sodium salt (I) reacts with the sulfonylglycyl chlorides (II) to give the amides (III) which are converted into the amidine carboxylic acids (V) via the thioamides (IV).
ChemInform Abstract: A New Synthesis of 3‐Amino‐2‐alkenoates. Novel Synthetic Route to Amino Sugars N‐Benzoyl‐L‐daunosamine and ‐L‐acosamine.
Authors: HIYAMA T. , KOBAYASHI K. , NISHIDE K. 
Published: May 2016

AbstractCoupling of the nitriles (I) with the magnesium enolate derived from (II) affords the aminoalkenoates (III).
ChemInform Abstract: Effect of Solvent on the Rate Constant for the Radiative Deactivation of Singlet Molecular Oxygen (1δgO2).
Authors: SCURLOCK R. D. , OGILBY P. R. 
Published: May 2016

AbstractMeasurements of the relative rate constants for the radiative deactivation (kr) of singlet molecular oxygen (3∑g‐ O2 ← 1ΔgO2) in 15 solvents (e.g.
ChemInform Abstract: Ethyl 2‐((5,6‐Dihydro‐7‐(1H‐imidazol‐1‐yl)‐2‐naphthalenyl)oxy)‐2‐methylpropanoate as a New Potent Oxyisobutyrate Hypolipidemic with Unusual Features.
Authors: COZZI P. , BRANZOLI U. , CARGANICO G. , CHIARI A. , LOVISOLO P. P. , SEVERINO D. 
Published: May 2016

AbstractThe 1‐hydroxy‐2‐imidazolyltetralins (I) are converted to the dihydronaphthalenes (II) which are coupled with the bromoisobutyrate (III), yielding the imidazolyldihydronaphthalenyloxyisobutyrates (IV).
ChemInform Abstract: Stereospecificity of the Photorearrangement of Nitronate Anions and Its Utilization for Stereospecific Cleavage of Cyclic Compounds.
Authors: YAMADA K. , KISHIKAWA K. , YAMAMOTO M. 
Published: May 2016

AbstractIrradiation of the nitrocyclohexanes (I), (III), or (VI) with a low pressure mercury lamp results in ring‐enlargement, producing the N‐hydroxyazepines (II), (IV), or (VII).
ChemInform Abstract: Synthesis and Properties of (Phthalocyaninato)cobalt(II) Adducts with Nitrogen Bases.
Authors: METZ J. , HANACK M. 
Published: May 2016

Abstractα‐ or β‐Phthalocyaninatocobalt(II) (I) reacts with nitrogen bases to yield different adducts depending on the reaction conditions.
ChemInform Abstract: Isolation and Crystal and Molecular Structures of Two Geometric Isomers of a 3N,2S‐Pentacoordinate Copper(II) Complex.
Authors: GLASS R. S. , SABAHI M. , HOJJATIE M. , WILSON G. S. 
Published: May 2016

AbstractThe 1:2 molar reaction of Cu(II) tetrafluoroborate monohydrate with 1‐methyl‐2‐(2‐(methylthio)ethyl)imidazole in EtOH yields the dicationic, penta‐coordinated tris(ligand)‐Cu(II) complex in 55% yield which crystallizes in the two geometric forms, the green, square‐pyramidal one (IA) and the blue, trigonal‐bipyramidal one (IB).
ChemInform Abstract: Synthesis, Reactivity, and Variable‐Temperature NMR Studies of Transition‐Metal Complexes Containing the 2,3‐Dihydrothiophene Ligand.
Authors: SAUER N. N. , ANGELICI R. J. 
Published: May 2016

AbstractThe title complexes (III), (VII), (IX), and (XI) containing the S‐bound ligand (II), a proposed intermediate in thiophene hydrodesulfurization, are prepared as shown in the scheme.
ChemInform Abstract: Synthesis of Homofarnesenes: Trail Pheromone Components of the Fire Ant, Solenopsis invicta.
Authors: ALVAREZ F. M. , VANDER MEER R. K. , LOFGREN C. S. 
Published: May 2016

AbstractGeraniol (I) serves as starting material for the synthesis of the homofarnesene isomers (VII) and (VIII).
ChemInform Abstract: High‐Pressure Synthesis and Structural Studies of Rare Earth (R) Compounds RCuAl.
Authors: TSVYASHCHENKO A. V. , FOMICHEVA L. N. 
Published: May 2016

AbstractThe title compounds with R: Sm, Gd, Tb, Dy, Tm, Yb, and Lu are prepared from stoichiometric mixtures of the powdered metals (7.7 GPa, annealing at 1450‐1500 °C or rapid quenching of the melt).
ChemInform Abstract: Equilibria and UV Spectra of Mono‐ and Polynuclear Molybdenum(VI) Species.
Authors: CRUYWAGEN J. J. , HEYNS J. B. B. 
Published: May 2016

AbstractMo(VI) equilibria have been investigated in the pH range 2.3‐6.1 by spectrophotometric titrations in 1.0 M and 0.1 M NaCl.
ChemInform Abstract: Chemical Transport of MnCl2 with ACl3 (A: Al, Ga, In).
Authors: KRAUSZE R. , OPPERMANN H. 
Published: May 2016

AbstractThe transport behavior of MnCl2 with ACl3 as the transportation agent has been calculated using the solubilities in the gas phase and taking into account the gaseous complexes MnACl5, MnA2Cl8, and MnA3Cl11.
ChemInform Abstract: Extending Surface‐Enhanced Raman Spectroscopy to Transition‐Metal Surfaces: Carbon Monoxide Adsorption and Electrooxidation on Platinum‐ and Palladium‐Coated Gold Electrodes.
Authors: LEUNG L.‐W. H. , WEAVER M. J. 
Published: May 2016

AbstractThin (1‐3 monolayers) films of Pt and Pd electrodeposited on electrochemically roughened Au electrodes yield surface‐enhanced Raman (SER) spectra for adsorbed CO.
ChemInform Abstract: Formation of Spinel from Organometal Compounds.
Authors: YAMAGUCHI O. , TAGUCHI H. , SHIMIZU K. 
Published: May 2016

AbstractSimultaneous hydrolysis of magnesium acetylacetonate and aluminum isopropoxide yields an amorphous Mg‐Al product which can be used to form a magnesium aluminate spinel by slowly heating (10 °C min‐1) the product to 700‐1250 °C. The amorphous hydrolysis product is found to be a Mg‐substituted, γ‐Al2O3‐like material.
ChemInform Abstract: Synthesis of Rare Earth Metal Trichlorides by Chemical Transport with Aluminum Trichloride.
Authors: GUNSILIUS H. , URLAND W. , KREMER R. 
Published: May 2016

AbstractThe compounds LnCl3 with Ln: La‐Tb have been prepared by reaction of the corresponding oxide, Ln2O3, with Al2Cl6 and subsequent chemical vapor transport (500 → 400 °C for Ln: La‐Nd, Tb; 400 → 310 °C for Ln: Sm‐Tb).
ChemInform Abstract: Synthesis of 3‐Amino‐4‐hydroxylaminothiazolidine‐2‐thiones and 2,3‐Dimethyl‐4a,5‐dihydro‐7‐thioxothiazolo(3,4‐b)‐1,2,4‐triazines.
Authors: EPSHTEIN S. P. , ORLOVA T. I. , RUKASOV A. F. , TASHCHI V. P. , PUTSYKIN YU. G. 
Published: May 2016

AbstractThe dimeric nitrosochloroalkanes (I) react with dithiocarbazinic acid potassium salt (II) to give the N‐aminothiazolidinethiones (III) which rearrange upon acidic treatment, producing the thiadiazinethiones (IV).
ChemInform Abstract: Polycycles from 1,5‐Cyclooctadiene and Chlorocyanoketene.
Authors: DEHMLOW E. V. , BIRKHAHN M. 
Published: May 2016

AbstractChlorocyanoketene derived by method A) from (V) adds to cyclohexene (I) or cyclooctene (VI) stereoselectively to give (II) or (VII), both of which undergo Favorskii reaction to yield the bicyclic acids or esters (III)/(IV) or (VIII).
ChemInform Abstract: Rearrangement and Ring Cleavage of 3‐ and 5‐Methylbicyclo(2.1.1)hex‐2‐yl Cations.
Authors: KIRMSE W. , KAMPMANN K.‐H. , ZELLMER V. 
Published: May 2016

AbstractReduction of the ketones (Ia) or (IVa), (IVb) (from (III)) affords the epimeric alcohols (IIa)/(IIb) or (VIIa)/(VIIb) or (Xa)/(Xb).
ChemInform Abstract: A New Synthesis of Optically Active trans‐β‐Amino Alcohols by Asymmetric Ring‐Opening of Symmetrical Oxiranes.
Authors: YAMASHITA H. 
Published: May 2016

AbstractCyclohexene oxide (Ic) reacts with aniline (II) in the presence of zinc (2R,3R)‐tartrate to give the optically active product (III), which is subsequently methylated, oxidized, and converted to the optically active cyclohexenol (VI).
ChemInform Abstract: Diisophorone and Related Compounds. Part 17. Synthesis and Nucleophilic Reactions of 4,8‐Dibromodiisophorones.
Authors: KURZER F. , PATEL J. N. 
Published: May 2016

AbstractBromination of diisophorone (I) affords a stereoisomeric mixture of the dibromo adducts (II), both of which can be separated as their acetates (VII).
ChemInform Abstract: Synthesis and Structure of Longitudinally Twisted Polycyclic Aromatic Hydrocarbons.
Authors: PASCAL R. A. JUN. , MCMILLAN W. D. , VAN ENGEN D. , EASON R. G. 
Published: May 2016

AbstractThe phencyclones (III) ((IIIa) and (IIIb) already known) when pyrolized neat or as a 1:1 mixture with 9‐bromophenanthrene (as a precursor of 9,10‐phenanthryne), yield the 9,18‐diphenyltetrabenzanthracenes (IV), the central aromatic rings of which are twisted by 22‐25°.
ChemInform Abstract: Synthesis of Azetidin‐3‐ones. Structure of N‐Tosyl‐2‐ethylazetidin‐3one.
Authors: ALIEV Z. G. , ATOVMYAN L. O. , SIPYAGIN A. M. , KARTSEV V. G. , DOBROKHOTOVA O. V. 
Published: May 2016

AbstractA general method for the preparation of arylsulfonylazetidinones (II) from the diazo ketones (I) is described.
ChemInform Abstract: Methylation of 2‐Phenylamino‐1,3,4‐thiadiazole. A Structure Debated.
Authors: BUCCHERI F. , CUSMANO G. , NOTO R. , RAINIERI R. , WERBER G. 
Published: May 2016

Abstract2‐Phenylamino‐1,3,4‐thiadiazole (I) is methylated and then treated with sodium hydroxide to give the isomeric heterocycles (II) and (III).
ChemInform Abstract: Alkylation of Position C‐5 of Triacetic Acid Lactone by (2,3) Sigmatropic Rearrangement of Sulfonium Ylides.
Authors: DE MARCH P. , MORENO‐MANAS M. , RIPOLL I. 
Published: May 2016

AbstractThe rhodium‐ or copper‐catalyzed reaction of the (phenylthiomethyl)pyranones (I) with the diazo compounds (III) or (IV) gives the pyrones (IIa)‐(IIc), which are functionalized at the difficultly accessible C‐5 position.
ChemInform Abstract: Intramolecular Catalytic Cyclization of Substituted 2‐Alkenylanilines.
Authors: ABDRAKHMANOVA I. B. , MUSTAFIN A. G. , TOLSTIKOV G. A. , DZEHMILEV U. M. 
Published: May 2016

AbstractThe methylbutenyl‐substituted anilines (I) are cyclized by palladium chloride catalysts to give a mixture of quinolines (II) and indoles (III).
ChemInform Abstract: Amidomethylation of Indoles and Cyclizations to Spiro(pyrrolo‐(4,3,2‐de)isoquinoline‐3,4′‐piperidines).
Authors: CARTER C. , FRETER K. R. , KRIWACKI R. W. , LEONARD S. F. , PITNER T. P. 
Published: May 2016

AbstractThe (aminomethyl)indoles (III) and (IV) are obtained by coupling the indole (I) with the N‐hydroxymethyl amide (II) and subsequent hydrolysis.
ChemInform Abstract: Synthesis and Antimalarial Activity of a Series of 2,4‐Diamino‐6‐((Nalkylanilino)methyl)quinazolines.
Authors: WERBEL L. M. , ELSLAGER E. F. , NEWTON L. S. 
Published: May 2016

AbstractThe aminocyanotoluene (IIb), prepared from (I), is cyclized with cyanoguanidine (III) to produce the quinazolines (IV) which are converted to the aminomethyl derivatives (VIII) as shown in the reaction scheme.
ChemInform Abstract: Synthesis of Thiabenzene Oxides and Azathiabenzene Oxides.
Authors: TOMINAGA Y. , HIDAKI S. , MATSUDA Y. 
Published: May 2016

AbstractThe bis(methylthio)methylenebenzothiophene 1,1‐dioxide (I) reacts with trimethylsulfoxonium iodide (II) in the presence of NaH to give the fused thiabenzene oxide (III).
ChemInform Abstract: Reactions with 2‐Phenylhydrazono‐4‐thiazolidinone.
Authors: ABD ALLAH S. O. , ELMOGHAYAR M. R. H. , EAD H. A. 
Published: May 2016

AbstractThe thiazolidinone (I) reacts with acrylonitrile (II), yielding the N‐cyanoethyl derivative (III).
ChemInform Abstract: Palladium‐Mediated Homo‐Coupling of 4,6‐Disubstituted 2‐Iodo‐1,3,5‐triazines.
Authors: KITAJIMA H. , TAKAHASHI T. , MINETA K. , KEUMI T. 
Published: May 2016

AbstractHomo‐coupling of the iodide (I) to give the bitriazolyl (II) occurs at 100°C in the presence of catalytic amounts of palladium(II) acetate and equimolar amounts of triethylamine.
ChemInform Abstract: Proton‐Ionizable Crown Compounds. Part 9. Synthesis and Structural Studies of New 14‐Crown‐4 Compounds Containing a Pyridine or 4‐Pyridone Subcyclic Unit.
Authors: BRADSHAW J. S. , GUYNN J. M. , WOOD S. G. , WILSON B. E. , DALLEY N. K. , IZATT R. M. 
Published: May 2016

AbstractThe 4‐oxaheptanediols (I) react with tosyl chloride (II) to form the ditosylates (III) and (IV).
ChemInform Abstract: On the Hydrolytic Stability of the Phosphorus‐Perfluoroalkyl Bond in Alkyl Chloromethylperfluoroalkylphosphinates. Synthesis of N‐(Phosphonomethyl)glycine.
Authors: GOLOVANOV A. V. , MASLENNIKOV I. G. , SHUBINA T. V. , KIRICHENKO L. N. , LAVRENT'EV A. N. 
Published: May 2016

AbstractThe P‐Rf bond of the perfluoroalkylphosphinates (I) is instable under alkaline hydrolysis conditions.
ChemInform Abstract: The Effect of Divalent Metal Ions on the Rate and Transition‐State Structure of Phosphoryl‐Transfer Reactions.
Authors: HERSCHLAG D. , JENCKS W. P. 
Published: May 2016

AbstractKinetic measurements for the title reaction of (I) and (V) with (II) and for the hydrolysis of (I), (IIIa), and (V) in the presence and absence of Mg2+ or Ca2+ indicate the formation of 1:1 complexes with the metal ions.
ChemInform Abstract: A Versatile New Reagent (Ph3GeCH2COGePh3) as Acetate Equivalent. BF3·OEt2 Mediated Aldol Reaction.
Authors: KIYOOKA S. , SHIOTA F. , SHIBUYA T. 
Published: May 2016

AbstractTriphenylgermyllithium (II) reacts with ethyl bromoacetate (I) to give the new triphenylgermylacetyltriphenylgermane (III) as an acetate equivalent.
ChemInform Abstract: Isolation and Characterization of Copper Methylene (CuCH2) via FTIR Matrix Isolation Spectroscopy.
Authors: CHANG S.‐C. , KAFAFI Z. H. , HAUGE R. H. , BILLUPS W. E. , MARGRAVE J. L. 
Published: May 2016

AbstractThe reactions of copper atoms with CH2N2 in argon and nitrogen matrices at 12 K are investigated.
ChemInform Abstract: Nucleophilic Addition and Various Species Formed in the Cu(II)‐NCO‐‐3(5)‐Methylpyrazole System.
Authors: KOHOUT J. , HVASTIJOVA M. 
Published: May 2016

AbstractTwo isomers of the pseudooctahedral complexes differing in their polyhedron distortion are obtained by reaction of Cu(NO3)2·2 H2O with KNCO in aqueous solution at 5 or 40 °C. Four isomers of bis(carbamoylmethylpyrazolato)‐Cu(II) are formed by reaction of Cu(NCO)2(2,4‐lutidine) with 3‐methylpyrazole in MeOH at room temp. and following transformations.
ChemInform Abstract: Copper(II) Complexes of 3‐Aminopropanols. Synthesis and Structure of 3‐Aminopropanol(3‐aminopropanolato)copper(II) Iodide.
Authors: SILLANPAEAE R. + , LINDGREN T. , HILTUNEN L. 
Published: May 2016

AbstractThe 1:2:1 molar reaction of Cu(II) trifluoromethanesulfonate, 3‐aminopropanol, and LiI in ethanol leads to the polymeric title complex whose structure (I) is confirmed by X‐ray analysis (space group P21/c, Z=4).
ChemInform Abstract: Synthesis and Spectroscopic Studies of Platinum(II) Complexes of N,N′‐Dicyclohexylethylenediamine.
Authors: PUNIYANI S. , SRIVASTAVA T. S. 
Published: May 2016

AbstractTreatment of K2PtCl4 with an excess of KI and equimolar amount of the title diamine in aqueous solution leads to the diiododiamine complex (Ia).