bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Structural Consequences of Electron‐Transfer Reactions. Part 15. Mixed‐Valent Cations of Dinuclear Chromium Aryl Complexes: Electrochemical, Spectroscopic, and Structural Considerations.
Authors: VAN ORDER N. JUN. , GEIGER W. E. , BITTERWOLF T. E. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe oxidation of the dinuclear chromium carbonyl complexes (I)‐(IV) is studied by electrochemistry, IR and ESR spectroscopy and X‐ray crystallography.
ChemInform Abstract: Reaction of Bulky Monosubstituted Phosphorus(III) Halides with Disodium Tetracarbonylferrate. Steric and Electronic Factors in the Synthesis of Fe(CO)4 Complexes of Diphosphene and Phosphinidene Ligands.
Authors: BARTLETT R. A. , DIAS H. V. R. , FLYNN K. M. , OLMSTEAD M. M. , POWER P. P. 
Published: May 2016

AbstractThe products of the title reactions (see scheme), depending on the substituent at P, are compared with those from analogous reactions using Na2Cr(CO)5.
ChemInform Abstract: Claisen Rearrangements with Mesityl Oxide Dimethyl Ketal. Synthesis of Ipsdienone, E‐ and Z‐Ocimenone, 2,6‐Dimethyl‐2,7‐octadien‐4‐one and 2,6‐Dimethyl‐2,7‐octadien‐4‐ol.
Authors: BAECKSTROEM P. + , STRIDH K. , LI L. , NORIN T. 
Published: May 2016

AbstractMannich reaction of the propynol (I) yields the amine (IV), which is converted to the precursor (VII).
ChemInform Abstract: Stereoselective Syntheses of Alcohols. Part 24. Synthesis of 2,6‐Dideoxy‐L‐hexoses.
Authors: HOFFMANN R. W. , METTERNICH R. , LANZ J. W. 
Published: May 2016

AbstractAddition of the Z/E‐isomeric boronates (IIa), (IIb) to the aldehyde (I) leads to isomeric hexenes (III) which are benzylated to the separable pairs (IVa)/(IVd) and (IVc)/(IVb), respectively.
ChemInform Abstract: Synthesis and Stereochemistry of Indolactam Congeners. Conformational Behavior of the Nine‐Membered Lactams.
Authors: ENDO Y. , HASEGAWA M. , ITAI A. , SHUDO K. 
Published: May 2016

AbstractIndolactam‐V, an active fragment of the tumor‐promoting teleocidins, exists in two conformational states in solution.
ChemInform Abstract: Characterization of an Endogenous Factor Controlling the Cell Cycle of Complex Tissues.
Authors: LYNN D. G. , JAFFE K. , CORNWALL M. , TRAMONTANO W. 
Published: May 2016

AbstractThe Paal‐Knorr condensation of the chiral lactone (I) of L‐homoserine leads to the (R)‐(+)‐(III) which inhibits the trigonelline‐induced G2 cellular arrest as does the endogenous factor isolated from the roots of 10‐day old seedlings of Pisum sativum.
ChemInform Abstract: Syntheses of Hydroxylated 2,2′‐Bipyridines. Part 1. Orellanine, the Poison of a Toadstool.
Authors: DEHMLOW E. V. , SCHULZ H.‐J. 
Published: May 2016

AbstractThe title compound (Vb) is synthesized starting from the N‐oxide (I) (obtainable from the respective pyridine by peracid oxidation (64%)) via the intermediates (III), (IVa), and (Va).
ChemInform Abstract: 1,3‐Dipolar Cycloaddition of Phenyl Azide to 3‐(2‐R‐Phenoxy)‐1‐propynes, and IR and PMR Spectra of 1,2,3‐Triazole Isomers.
Authors: ABDUGAFUROV I. A. , MAKHSUMOV A. G. , MADIKHANOV N. 
Published: May 2016

AbstractThe 1,3‐dipolar cycloaddition of phenyl azide (II) to the aryloxypropynes (I) affords mixtures of the 1,4‐ and 1,5‐isomeric 1,2,3‐triazoles (III) and (IV).
ChemInform Abstract: A New Synthesis of 1,7‐Dioxaspiro(5.5)undec‐4‐enes via Metallated Allenol Ethers. A Formal Synthesis of Talaromycins A and B.
Authors: WHITBY R. , KOCIENSKI P. 
Published: May 2016

AbstractThe α‐iodo‐ω‐siloxyalkanes (I) are coupled with the allenol ether (II) to produce the methoxysiloxyalkylallenes (III).
ChemInform Abstract: Synthesis of Some New 4‐Quinazolinone‐2‐carboxy Esters, ‐2‐carboxamides, ‐2‐carboxyhydrazides and Their Tosyl Derivatives Having Potential Biological Activity.
Authors: JOSHI V. , CHAUDHARI R. P. 
Published: May 2016

AbstractReaction of the amides (I) with the diester (II) yields the esters (III) which are transformed to their derivatives (IV), (VII) and (IX).
ChemInform Abstract: The Transformation of Tryptophan to Aspartic Acid in Peptides.
Authors: RANGANATHAN S. , RANGANATHAN D. , BHATTACHARYYA D. 
Published: May 2016

AbstractThe tryptophan derivative (I) is cleaved upon treatment with a Ru(VIII) reagent, generated in situ, to form the optically aspartic acid monoester (II) under retention of the configuration at the asymmetric carbon atom.
ChemInform Abstract: Strength Improvement in Transformation‐Toughened Alumina by Selective Phase Transformation.
Authors: CUTLER R. A. , BRIGHT J. D. , VIRKAR A. V. , SHETTY D. K. 
Published: May 2016

AbstractAl2O3‐15 vol.% ZrO2 bar‐shaped ceramic specimens are prepared in the green state in such a manner that the outer regions consist of Al2O3 and unstabilized ZrO2, whereas the inner region contains ZrO2 partially stabilized with Y2O3.
ChemInform Abstract: Ring‐Opening of Alkyl‐Substituted Cyclopropanes in the Presence of Hydrogen on Copper.
Authors: BARTOK M. , PALINKO I. , MOLNAR A. 
Published: May 2016

AbstractThe alkyl‐substituted cyclopropanes (I), (V), and (VIII) are treated with hydrogen on a copper/silica catalyst system under various conditions to yield mixtures of the cleavage and hydrogenation products (II) ‐ (IV), or (II), (III), (VI), (VII), or (IX) ‐ (XII).
ChemInform Abstract: 8‐(Heptafulven‐8‐yl)‐p‐tropoquinone Methide.
Authors: TAKAHASHI K. , NAMEKATA N. , TAKASE K. , SUZUKI T. 
Published: May 2016

AbstractWittig reaction of the formyltroponolate (I) with the cycloheptatrienylphosphorane (II) yields the cycloheptatrienylvinyltropolone (III).
ChemInform Abstract: New Iptycenes Using 2,3‐Naphtho(b)triptycene as a Synthon.
Authors: LUO J. , HART H. 
Published: May 2016

AbstractNaphthalene 1,4‐endoxide (Ia) reacts with the diene (II) to give the cycloadduct (III) which undergoes acid‐catalyzed dehydration, double bond isomerization, and thermolysis to yield the title compound (IV).
ChemInform Abstract: Derivatives of Barbituric Acid. Part 37. Racemates and Enantiomers of Barbiturates with a Basic Side Chain on Nitrogen.
Authors: KNABE J. , LAMPEN P. 
Published: May 2016

AbstractThe barbiturates (I) are alkylated with the β‐chloroalkylamines (II), yielding the monoalkylated products (III).
ChemInform Abstract: Borate Esters. Part 7. Borate Esters of Some 1,3‐Diones.
Authors: VAN DUIN M. , PETERS J. A. , SINNEMA A. , KIEBOOM A. P. G. , VAN BEKKUM H. 
Published: May 2016

AbstractAccording to an NMR study, the formation of borate diesters (IV) is preferred to that of borate monoesters (III).
ChemInform Abstract: Transformation of Fluoronitroacetic Acid Esters.
Authors: MARTYNOV I. V. , UVAROV V. I. , BREL' V. K. , TSYGANOVA G. I. 
Published: May 2016

AbstractBromination of fluoronitroacetic acid esters (I) in alkaline solution gives the bromofluoronitroacetic acid esters (II).
ChemInform Abstract: Reaction of Phenylbenzoxazole with Phenyl Glycidyl Ether.
Authors: KORSHAK V. V. , SURIKOVA M. A. , KOMAROVA L. I. , BEKASOVA N. I. 
Published: May 2016

AbstractThe title reaction, performed in the presence of catalytical amounts of sodium benzoate at elevated temperature, gives the N‐disubstituted o‐aminophenol (III).
ChemInform Abstract: Synthesis of Novel Carbo‐ and Heteropolycycles. Part 5. Reactivity of Some Intramolecular Aza‐Wittig Reactions.
Authors: EGUCHI S. , TAKEUCHI H. , ESAKI T. 
Published: May 2016

AbstractThe azides (III) and (VI) are prepared by treatment of the corresponding chlorides (I) or (V) or the olefinic compound (IV) with sodium azide (II).
ChemInform Abstract: Asymmetric Conjugate Additions of an Hydroxyethyl Carbanion Equivalent. Synthesis of (+)‐A Factor.
Authors: POSNER G. H. , WEITZBERG M. , JEW J. 
Published: May 2016

AbstractThe chiral tolylsulfinylbutenolide (S)‐(+)‐(IV) is coupled with the lithiated bisether which is prepared from benzyloxymethyl chloride (I) and the hydroxymethylstannane (II) by lithium tin exchange.
ChemInform Abstract: The Reaction of Meldrum′s Acid with Aldehydes and Phloroglucinol: A Synthesis of Dihydrocoumarins.
Authors: NAIR V. 
Published: May 2016

AbstractMeldrum's acid (II) is coupled with the aldehydes (III) and phloroglucinol (I) in pyridine to form the pyridinium dihydrocoumarincarboxylates (IV).
ChemInform Abstract: The Synthesis of 3‐(4‐Aminotetrafluorophenyl)‐3‐ethylpiperidine‐2,6‐dione: A Fluorinated Derivative of Aminoglutethimide.
Authors: PLEVEY R. G. , SAMPSON P. 
Published: May 2016

AbstractThe title compound (IX) is prepared from hexafluorobenzene (I) in order to investigate the role of the amino function of the drug aminoglutethimide (X) in the inhibition of the cholesterol side‐chain cleavage enzyme system desmolase and the estrogen‐forming system aromatase.
ChemInform Abstract: Hydrosilylation, Hydrogermylation, and Hydrostannylation of Some Organo‐Silicon Derivatives of Ethylene and Acetylene.
Authors: VORONKOV M. G. , ADAMOVICH S. N. , KHRAMTSOVA S. YU. , SHTERENBERG B. Z. , RAKHLIN V. I. , MIRSKOV R. G. 
Published: May 2016

AbstractThe title reactions are studied with the methyl(dialkoxy)vinylsilane (I), the alkinylsilatrane (V), and trimethoxysilylphenylacetylene (VII).
ChemInform Abstract: Electrooxidative Cleavage of Carbon‐Carbon Bonds. Part 4. Conversion of Cyclic Aziridines and 2‐Amino‐1‐cycloalkanols to Keto Nitriles by Using Electrogenerated Reactive Halogen Species.
Authors: TORII S. , INOKUCHI T. , TAKAGISHI S. , SATO E. , TSUJIYAMA H. 
Published: May 2016

AbstractThe fused aziridines (III), prepared from the cyclic oximes (I) and methyl Grignard reagent (II), are oxidatively cleaved with electrogenerated reactive halogen to give a mixture of the keto aldehydes (IV) and the keto nitriles (V).
ChemInform Abstract: Thiophilic Addition of Alkyllithium to Dithiocarboxylic Acid Anions: Synthesis of 2‐(Bis(alkylthio)methylene)‐1,3‐dithioles.
Authors: MORADPOUR A. , BITTNER S. 
Published: May 2016

AbstractThe dithiole (I) is lithiated and then treated with carbon disulfide (III) to produce the dithiocarboxylate (IV).
ChemInform Abstract: Perhydropyrrolo(2,1‐b)thiazolones: Synthesis and Investigations of Their Chemical and Pharmacological Properties.
Authors: BURGEMEISTER T. , DANNHARDT G. , GRAF E. , OBERGRUSBERGER R. 
Published: May 2016

AbstractThe pyrrolines (I) react with the mercaptoacetate (II) to form the pyrrolothiazolones (III).
ChemInform Abstract: Prototropic Migration During the Phosphorylation of Imidoyl Chlorides Containing Hydrogen at the N‐α‐Carbon Atom. Part 3. Phosphorylation of Substituted N‐Benzylbenzimidoyl Chlorides with Triethyl Phosphite.
Authors: ONYS'KO P. P. , KIM T. V. , KISELEVA E. I. , SINITSA A. D. 
Published: May 2016

AbstractThe reaction of the imidoyl chlorides (I) with triethyl phosphite (II) gives the imidoyl phosphonates (III) which isomerize irreversibly, producing the phosphorylated azomethines (IV).
ChemInform Abstract: Degradation of Silicon Carbide by Molten Lithium.
Authors: CREE J. W. , AMATEAU M. F. 
Published: May 2016

AbstractAfter exposure to lithium at > 600 °C as‐fired and as‐ground SiC both undergo a decrease in strength, whereas for temp. up to 600 °C little change in strength is observed and the fracture is controlled by preexisting surface flaws on the specimen surface or edges.
ChemInform Abstract: Identifying Acid Salts of Magnesium.
Authors: PLUMB R. , THIVIERGE R. F. JUN. , XU W. W. 
Published: May 2016

AbstractA new technique has been developed for the delineation of the solidus boundary of ternary mixtures using friability tests and it has been applied to the MgSO4‐H2SO4‐H2O. Magnesium acid salt hydrates with compositions on the solidus boundary can be readily identified.
ChemInform Abstract: Photosynthetic Production of H2O2 from Water at n‐TiO2 Electrodes in a Photoelectrochemical Cell: Influence of Electrolyte pH and Pt Electrodeposition.
Authors: TAFALLA D. , SALVADOR P. 
Published: May 2016

AbstractPhotocurrent transients and rotating ring‐disk electrode measurements are used to study the electroreduction of photogenerated and/or dissolved O2 to H2O2 at polycrystalline n‐TiO2 electrodes.
ChemInform Abstract: Molecular Design of Calixarene‐Based Uranophiles Which Exhibit Remarkably High Stability and Selectivity.
Authors: SHINKAI S. , KOREISHI H. , UEDA K. , ARIMURA T. , MANABE O. 
Published: May 2016

AbstractThe complexes of UO22+ with the cyclic pentamers (Ib) and hexamers (Ic) have remarkably large stability constants Kuranyl = 1018.4‐19.2 M‐1, whereas the tetramers (Ia) have only Kuranyl = 103.1‐3.2 M‐1.
ChemInform Abstract: Synthesis, Structure, and Reactivity of 4‐Acetylamino‐9a‐acetoxy‐ 1,9,10‐anthracenetrione.
Authors: FARINA F. , PAREDES M. C. , STEFANI V. 
Published: May 2016

AbstractOxidation of the acetylaminohydroxyanthraquinone (I) with lead tetraacetate (II) gives the 4a‐acetoxy derivative (III) which is converted to the 3‐substituted anthraquinones (V).
ChemInform Abstract: Benzothiet‐2‐ones: Synthesis, Reactions, and Comparison with Benzoxet‐ 2‐ones and Benzazetin‐2‐ones.
Authors: WENTRUP C. , BENDER H. , GROSS G. 
Published: May 2016

AbstractFlash vacuum pyrolysis of the benzo‐ or naphthothiophenediones (I) yields the fused thietones (II) which are identified by spectroscopic investigations at low temperature.
ChemInform Abstract: High‐Pressure Diels‐Alder Reactions of 2‐Methylthio‐ and 2‐Acetoxyfuran. An Efficient Entry to 4‐Hydroxycyclohexanones.
Authors: KOTSUKI H. , MORI Y. , OHTSUKA T. , NISHIZAWA H. , OCHI M. , MATSUOKA K. 
Published: May 2016

Abstract2‐Acetoxyfuran (Ia) and 2‐methylthiofuran (Ib) react with the alkenes (II) at a high pressure, yielding the Diels‐Alder adducts (III).
ChemInform Abstract: Cardiotonic Agents. Part 2. (Imidazolyl)aroylimidazolones, Highly Potent and Selective Positive Inotropic Agents.
Authors: HAGEDORN A. A. III , ERHARDT P. W. , LUMMA W. C. JUN. , WOHL R. A. , CANTOR E. , CHOU Y.‐L. , INGEBRETSEN W. R. , LAMPE J. W. , PANG D. , PEASE C. A. , WIGGINS J. 
Published: May 2016

AbstractNucleophilic displacement of fluoride in the fluorobenzoyl compounds (I) with the imidazoles (II) gives the title compounds (III) with an imidazol‐1‐yl group.
ChemInform Abstract: Nonsteroidal Cardiotonics. Part 1. 2‐Pyridyl‐6,7‐dihydro‐3H,5H‐pyrrolo‐(2,3‐f)benzimidazol‐6‐ones, a Novel Class of Cardiotonic Agents.
Authors: MERTENS A. , MUELLER‐BECKMANN B. + , KAMPE W. , HOELCK J.‐P. + , VON DER SAAL W. 
Published: May 2016

AbstractThe tricyclic heterocycles (VI) are prepared by the general routes outlined in the reaction scheme.
ChemInform Abstract: Carbostyril Derivatives Having Potent β‐Adrenergic Agonist Properties.
Authors: MILECKI J. , BAKER S. P. , STANDIFER K. M. , ISHIZU T. , CHIDA Y. , KUSIAK J. W. , PITHA J. 
Published: May 2016

AbstractThe carbostyril derivatives (XI) mentioned in the title are prepared from the hydroxymethylhydroxyquinoline (I) as shown in the reaction scheme.
ChemInform Abstract: Specific Dopamine D‐1 and DA1 Properties of 4‐(Mono‐ and ‐dihydroxyphenyl)‐1,2,3,4‐tetrahydroisoquinoline and Its Tetrahydrothieno(2,3‐c)pyridine Analogue.
Authors: RIGGS R. M. , NICHOLS D. E. , FOREMAN M. M. , TRUEX L. L. , GLOCK D. , KOHLI J. D. 
Published: May 2016

AbstractTreatment of the aromatic aldehydes (I) with trimethylsilyl cyanide (II) and reduction of the intermediate cyanohydrin yield the aminoethanol derivatives (III).
ChemInform Abstract: Regioselective Syntheses of 2‐Amino‐4,5‐dialkylthiophene‐3‐carboxylates and Their Conversion to 3,4‐Dihydro‐4‐oxothieno(2,3‐d)pyrimidine‐2carboxylates.
Authors: MADDING G. D. , THOMPSON M. D. 
Published: May 2016

AbstractThe activated nitriles (III), easily prepared from the ketone (I) and ethyl cyanoacetate (II), cyclize in the presence of sulfur to produce the isomeric thiophenes (IV) and (V).
ChemInform Abstract: An Unexpected Reaction between 2,3‐Dihydro‐2,2,4‐trimethyl‐1H‐1,5‐benzodiazepine and Mercaptoacetic Acid.
Authors: CHIMIRRI A. , GRASSO S. , OTTANA R. , ROMEO G. , VALLE G. , ZAPPALA M. 
Published: May 2016

AbstractReaction of the trimethyldihydrobenzodiazepine (I) with mercaptoacetic acid (II) yields the tetrahydrooxothienyl derivative (III) and the thiazolobenzimidazole (IV) due to cleavage of the 7‐ring of (I).
ChemInform Abstract: Chemistry of Organic Metals: Synthesis of Bis(diselenoalkyl) Tetrathiafulvalene, Mixed Sulfur‐Selenium Analogues of BEDT‐TTF.
Authors: LEE V. Y. 
Published: May 2016

AbstractThe tetrathiafulvalene (I) is converted into the silylethoxymethyl (SEM)‐protected tetraseleno or tetratelluro compounds (III).
ChemInform Abstract: The First Practical Niobium(III) Reagent in Organic Synthesis. A Convenient Route to 2‐Amino Alcohols via the Coupling of Imines with Aldehydes or Ketones Promoted by NbCl3(DME).
Authors: ROSKAMP E. J. , PEDERSEN S. F. 
Published: May 2016

AbstractThe title reagent (III) which is prepared by the addition of NbCl5 to a solution of tributyltin hydride in DME is an efficient reagent for promoting the coupling of imines such as (IV) with ketones, e.g. (V), or aldehydes, e.g. (VII), to give after hydrolysis aminoalcohols such as (VI) or (VIII).
ChemInform Abstract: Cyclometalation of 2,6‐Di‐tert‐butylphenoxide Ligands by Tantalum Aryl Groups: Aliphatic Carbon‐Hydrogen Bond Activation and Aryl Isomerization via Benzyne (o‐Phenylene) Intermediates.
Authors: CHAMBERLAIN L. R. , KERSCHNER J. L. , ROTHWELL A. P. , ROTHWELL I. P. , HUFFMAN J. C. 
Published: May 2016

AbstractAlkylation of the halides (I) with 3 equiv. phenyllithium (II) leads to the monocyclometalated compounds (III) directly along with the formation of benzene.
ChemInform Abstract: Transition‐Metal‐Catalyzed Cyclization of Alkynoic Acids to Alkylidene Lactones.
Authors: CHAN D. M. T. , MARDER T. B. , MILSTEIN D. , TAYLOR N. J. 
Published: May 2016

AbstractThe alkynoic acids (IV) can be effectively cyclized to the exocyclic enol lactones (V) with the new rhodium complex (III), which is prepared from (I).
ChemInform Abstract: Orthometalation Reactions of Substituted Benzylideneamines by Palladium(II) Chloride.
Authors: NAVARRO‐RANNINGER M. C. , ALVAREZ‐VALDES A. , CAMAZON M. J. , ROMAN J. , LOZANO R. 
Published: May 2016

AbstractThe σ‐bonded palladium complexes (III), synthesized from the substituted benzylideneamines (I) and PdCl2 (II), are studied by spectroscopic methods and thermogravimetric analysis.
ChemInform Abstract: α‐Hydroxyamidoxime Derivatives of Sugars.
Authors: TRONCHET J. M. J. , ZOSIMO‐LANDOLFO G. , BERNARDINELLI G. , ARRIZABALAGA P. , GEOFFROY M. 
Published: May 2016

AbstractTreatment of the cyanohydrin (I) with hydroxylamine gives the α‐hydroxyamidoxime (II) which is converted into the derivatives (IV).
ChemInform Abstract: Chiral Intermediates in Thiamin Catalysis. The Stereochemical Course of the Decarboxylation Step in the Conversion of Pyruvate to Acetaldehyde.
Authors: KLUGER R. , KARIMIAN K. , KITAMURA K. 
Published: May 2016

AbstractThe stereochemical course of the nonenzymic decarboxylation of 2‐(lact‐2‐yl)thiamin (II), the adduct of pyruvate and thiamin, is determined.
ChemInform Abstract: Adsorption and Reaction of NO on Ni(100)
Authors: SHEN S. , FEULNER P. , UMBACH E. , WURTH W. , MENZEL D. 
Published: May 2016

Abstractis studied by XPS, UPS, XAES, ΔΦ, TPD, and LEED measurements between 80 and 1300 K. Molecular adsorption of NO on Ni(100) is shown to occur at low temperatures.
ChemInform Abstract: Synthesis and Characterization of New Mixed Oxohalides of Antimony and Tellurium.
Authors: JEREZ A. , PICO C. , VEIGA M. L. , ALONSO J. A. 
Published: May 2016

AbstractSbTeO3Cl (I) can be prepared by solvolysis of a 1:1 mixture of TeCl4 and SbCl3 in H2O, aqueous NH3, or aqueous HCl.
ChemInform Abstract: Structural and Spectroscopic Characterization of the Dirhenium Octakis(isothiocyanato) Salt (Ph4As)2Re2(NCS)8·2 L (L: (CH3)2CO, C5H5N). A Unique Case of Axial Coordination in M2X8 Compounds.
Authors: COTTON F. A. , MATUSZ M. 
Published: May 2016

AbstractThe molecular structures of the title compounds (VII), prepared in high yield from (I) by a ligand‐exchange reaction, are established by X‐ray crystallography.
ChemInform Abstract: Exchange Interaction Through Extended Molecular Bridges: Magnetic Properties of μ‐4,4′‐Bipyridine and μ‐Pyrazine Copper(II) Binuclear Complexes and Crystal Structures of (μ‐4,4′‐Bipyridine)bis((diethylenetriamine)(perchlorato)copper(II)) Perchlorate and Aquo(4,4′‐bipyridine)(diethylenetriamine)copper(II) Perchlorate.
Authors: JULVE M. , VERDAGUER M. , FAUS J. , TINTI F. , MORATAL J. , MONGE A. , GUTIERREZ PUEBLA E. 
Published: May 2016

AbstractFor the three compounds (I)‐(III) the magnetic susceptibilities are investigated in the 50‐4.2 K temp. range.
ChemInform Abstract: Partitioning of Ferrocenium Ions Between Multiple Redox Sites on Spinach Plastocyanin.
Authors: PLADZIEWICZ J. R. , BRENNER M. S. 
Published: May 2016

AbstractKinetic investigations of the oxidation of plastocyanin by the iron complexes (I) in the presence of the redox‐inactive inhibitors (II)‐(IV) as a function of pH are carried out.
ChemInform Abstract: Exceptionally Slow Reduction of Phenylmalonic Acid by Borane‐THF via Cyclic (Phenylmalonoxy)borane.
Authors: CHOI Y. M. , EMBLIDGE R. W. , KUCHARCZYK N. , SOFIA R. D. 
Published: May 2016

AbstractThe reaction times required for the complete reduction of the carboxylic acids (I) and phenylmalonic acid (III) with borane in THF are compared.
ChemInform Abstract: Electrogenerated Acid (EG Acid)‐Catalyzed Sulfenylation of Aldehydes, Ketones, Acetals, and Enones with Thiotrimethylsilanes.
Authors: INOKUCHI T. , TAKAGISHI S. , YAMASHITA H. , TORII S. 
Published: May 2016

AbstractThe title reaction effects thioacetalization of aldehydes (I) and ketones (IV) or (VII) (selective attack at C‐3), methoxy/phenylthio exchange of acetals (e.g.
ChemInform Abstract: An Efficient and Practical Synthesis of Bicyclo(3.3.1)nonane‐2,4‐diones.
Authors: YAMAZAKI T. , MATOBA K. , ITOOKA T. , CHINTANI M. , MOMOSE T. , MUROAKA O. 
Published: May 2016

AbstractStarting with the cyclohexanedicarboxylic acids (I), the acetylcyclohexylcarboxylates (V) are prepared.
ChemInform Abstract: 2‐Substituted Tetralin Derivatives as Conformationally Restricted Butyrophenone Analogues.
Authors: CHAN C. C. , FARMER P. S. , MCKENZIE G. , ROBERTSON H. 
Published: May 2016

AbstractStarting with the 1‐tetralone (I), the carbinols (II) and (V) are synthesized using conventional methods.
ChemInform Abstract: Multistep Redox Systems. Part 50. Adducts from N,N′‐Dicyanoquinone Diimines with Tetrathiafulvalenes ‐ A New Class of CT Complexes with Electrical Conductivity.
Authors: AUMUELLER A. + , ERK P. , HUENIG S. + , MEIXNER H. , VON SCHUETZ J. U. + , WERNER H.‐P. 
Published: May 2016

AbstractFrom 26 dicyanoquinone diimines such as (I) (only 2,3‐Cl2 and 2,6‐Cl2 not given in the scheme) with 0‐3 substituents (only (Ih) having 3) and tetrathiafulvalene (II) 19 CT (1:1) complexes such as (III) are obtained.
ChemInform Abstract: Synthesis of 1‐(Arylideneaminoethyl)‐2‐phenyl‐4‐(3′,5′‐dibromo‐2′‐hydroxybenzylidene)imidazolin‐5‐ones.
Authors: DAVE A. M. , BHATT K. N. , UNDAVIA N. K. , TRIVEDI P. B. 
Published: May 2016

AbstractThe benzylideneoxazolinone (I) reacts with ethylenediamine (II) to form the imidazolinone (III).
ChemInform Abstract: α‐Oximino‐β‐phenylhydrazones of Aroylacetarylamides and Their Cyclization into 1,2,3‐Triazoles.
Authors: PATEL D. M. , DESAI V. C. , PATEL M. M. , PATEL M. R. 
Published: May 2016

AbstractThe oximinoaroylacetanilides (I) are coupled with phenylhydrazine (II) to produce the α‐oximinohydrazones (III) which are cyclized upon treatment with thionyl chloride to give the triazoles (IV).
ChemInform Abstract: The Demethylation Chemistry of 3‐Substituted 2‐Methoxypyridines.
Authors: BALKO T. W. , BRINKMEYER R. S. 
Published: May 2016

Abstract2‐Methoxy‐3‐nitropyridine (I) is reduced to form the amine (II) which is converted to the N‐substituted derivatives (V).
ChemInform Abstract: Tandem Intramolecular Michael Addition and 1,3‐Dipolar Cycloaddition Reactions of Oximes. Versatile New Carbon‐Carbon Bond Forming Methodology.
Authors: ARMSTRONG P. , GRIGG R. , SURENDRAKUMAR S. , WARNOCK W. J. 
Published: May 2016

AbstractThe unsaturated keto esters (I) and (V) are converted into nitrones such as (II) which perform cycloaddition reactions with N‐methyl maleimide (III) to give the polycyclic oxazolidine derivatives (IV), (VI), and (VII).