bluuebunny/crossref_metadata_2025_split huggingface dataset:
E3 Ubiquitin ligase RNF126 regulates the progression of tongue cancer
Authors: Wang Lina , Wang Xin , Zhao Yuehan , Niu Weidong , Ma Guowu , Yin Wei , Shi Chun 
Published: May 2016

AbstractThis study aims to analyze the role of RNF126 in the oncogenesis of tongue cancer. The cell proliferation and viability of human tongue cancer cells, SCC25 and SCC9 cells, were determined by cell counting and MTT assay, respectively. The effect of RNF126 on regulating AKT signaling pathway was analyzed through western blotting. The transplantation tumor model of nude mice was used to evaluate the tumorigenecity of RNF126. Knockdown of RNF126 inhibited the proliferation and viability of SCC9 and SCC25 cells. Inhibition of RNF126 also decreased the activity of AKT1 as well as its downstream molecules. Furthermore, RNF126 regulated the tumor volume on mice model. These data suggested that RNF126 might be related to the progression of tongue cancer through regulating AKT signaling pathway.
ChemInform Abstract: Microstructure and Dielectric Properties of Lead Magnesium Niobate (PMN)‐Pyrochlore Diphasic Mixtures.
Authors: CHEN J. , HARMER M. P. 
Published: May 2016

AbstractThe detrimental pyrochlore second phase within perovskite‐type PMN is found to be present as isolated grains in the microstructure.
ChemInform Abstract: Irradiation Effects on Passive Films Formed on a 304 Type Stainless Steel.
Authors: GORSE D. , RONDOT B. , DA CUNHA BELO M. 
Published: May 2016

AbstractPhotoelectrochemical and impedance measurements show that α‐particle irradiation (241Am) modifies the electronic structure of the oxide film on the stainless steel surface.
ChemInform Abstract: An Auger Electron Spectroscopy Study of the Fluorination of Al‐7075 Alloy.
Authors: SANIGER J. M. , COTA L. 
Published: May 2016

AbstractThe Al‐Zn‐Mg alloy Al‐7075 is exposed to gaseous fluorine at room temp. for 300 h. This exposure results in the formation of an aluminum fluoride layer and two sublayers consisting of fluorocarbon compounds and aluminum oxyfluoride, respectively.
ChemInform Abstract: Solution Chemistry in Non‐Coordinating Solvents (CH2Cl2, CHCl3) of Nickel(II) and Nickel(III) Complexes of the Lipophilic Macrocycle 1‐Hexadecyl‐1,4,8,11‐tetraazacyclotetradecane. The Emphasized Role of the Anion Coordination.
Authors: DI CASA M. , FABBRIZZI L. , MARIANI M. , SEGHI B. 
Published: May 2016

AbstractNi(II) complexes of the title ligand dissolve in non‐coordinating solvents forming complex types (I) and (II) with different spin state and different color depending on the coordinating tendencies of the anions.
ChemInform Abstract: A Facile Synthesis of Trifluoroacetaldehyde by Electroreduction of CF3Br in Dimethylformamide.
Authors: SIBILLE S. , PERICHON J. , CHAUSSARD J. 
Published: May 2016

AbstractThe diacetyl acetal (V) of the target aldehyde is obtained by electrochemical reduction of trifluoromethyl bromide (I) in excess DMF (II) and subsequent treatment with acetic anhydride (IV).
ChemInform Abstract: Pauson‐Khand Cycloadditions of Polymer‐Linked Substrates.
Authors: SCHORE N. E. , NAJDI S. D. 
Published: May 2016

AbstractDirect covalent attachment of an alkyne to a solid support is found to improve essentially the yields in Pauson‐Khand cycloaddition reactions which are found to produce only low yields under the usual homogeneous conditions ((IV): 26%, (V): trace, (VII) and (VIII): 10%).
ChemInform Abstract: X=Y‐ZH Systems as Potential 1,3‐Dipoles. Part 25. Intramolecular Cycloaddition Reactions of Pyridoxal Imines of ε‐Alkenyl α‐Amino Esters. A Possible New Approach to Pyridoxal Enzyme Inhibition.
Authors: GRIGG R. , ARMSTRONG P. 
Published: May 2016

AbstractThe pyridoxal imines (III) undergo intramolecular cycloaddition via an intermediate azomethine ylide to the compounds (IV) on keeping at room temp. for a prolonged period of time.
ChemInform Abstract: Preparation of the Trianions of Acetylacetone and Acetoacetanilide and Their Reactions with Selected Electrophilic Reagents for the Synthesis of New Heterocyclic Compounds and Related Materials.
Authors: BEAM C. F. , HINES M. A. , MAZAT C. L. , DUNCAN D. C. , BECKMAN D. D. , LACHICOTTE R. J. , TUMMONS R. C. , HEINDEL N. 
Published: May 2016

AbstractThe trianion salt (IV), prepared by reaction of acetylacetone (I) with NaH (II) and excess LDA (III), reacts with benzophenone (V) to give the dihydroxy diketone (VI).
ChemInform Abstract: Diastereoselective Reduction of 9‐Oxo‐13‐tetradecanolide and 10,10‐Dimethyl‐9‐oxo‐13‐tetradecanolide.
Authors: KELLER T. H. , WEILER L. 
Published: May 2016

AbstractThe stereoselectivity of the reduction of title substrates (Va) or (Vb) with NaBH4 is poor yielding the diastereomeric alcohols (VI), (VII) or (VIII), (IX).
ChemInform Abstract: Montmorillonite‐Supported Borohydride: A New Reducing Agent for Reductions Under Phase‐Transfer Conditions.
Authors: SARKAR A. , RAO B. R. , KONAR M. M. 
Published: May 2016

AbstractThe reduction of the aldehyde (Ia) and the ketones (Ib) ‐ (Ie) to give the corresponding alcohols (II) is performed using sodium borohydride either absorbed on a clay such as montmorillonite also containing a phase‐transfer catalyst or in the presence of a montmorillonite‐supported phase‐transfer catalyst.
ChemInform Abstract: 1,4‐Reductions of α,β‐Unsaturated Ketones and Aldehydes via in situ Generated Hydridocuprates.
Authors: LIPSHUTZ B. H. , UNG C. S. , SENGUPTA S. 
Published: May 2016

AbstractA hydridocuprate, generated from tributylstannane and cuprous iodide, reduces olefinic double bonds in carbonyl compounds as outlined in the reaction scheme.
ChemInform Abstract: Triformylmethane: An Efficient Preparation, Some Derivatives, and Spectra.
Authors: BUDESINSKY M. , FIEDLER P. , ARNOLD Z. 
Published: May 2016

AbstractThe reaction of bromoacetic acid (I) with dimethylformamide (II) and phosphoryl chloride yields an iminium salt which is isolated as the bisperbromide (III).
ChemInform Abstract: Synthesis of Trimethylsilyl Dienol Ethers from Carboxylic Acids.
Authors: INABA T. , WATANABE S. , SAKAMOTO M. , FUJITA T. 
Published: May 2016

AbstractThe trimethylsilyl dienol ethers (IV) and (V) are prepared by regioselective reaction of the carboxylic acids (I) with the Grignard compound (II) and subsequent quenching with the chlorosilane (III) or by silylation of the enones (VII).
ChemInform Abstract: Reformatskii Reaction Using Zn/Ag Couple.
Authors: BORTOLUSSI M. , SEYDEN‐PENNE J. 
Published: May 2016

AbstractThe aldehydes and ketones (I) undergo Reformatskii reaction with the α‐bromocarboxylates (II) in the presence of zinc silver couple to produce the β‐hydroxy esters (III).
ChemInform Abstract: Generation and Trapping of Vinylcarbenes at Ambient Temperature: A Route to Functionalized Vinyl‐ and Allylidenecyclopropanes.
Authors: AL DULAYYMI J. R. , BAIRD M. S. 
Published: May 2016

Abstract1,2‐Dehalogenation of the readily available tetrachloropropane (I) with MeLi leads to the cyclopropene (II) which reacts with electron‐rich and electron‐poor alkenes such as (III) via the vinylcarbene (IV) to give cyclopropanes such as (V).
ChemInform Abstract: Cyclopropenes as C3 Building Blocks: Cyclopentenols and Large Rings from 2‐Aminobicyclo(2.1.0)pentane Derivatives via Ring‐Enlargement Reactions.
Authors: FRANCK‐NEUMANN M. , MIESCH M. , KEMPF H. 
Published: May 2016

AbstractMethyl 3,3‐dimethylcyclopropene‐1‐carboxylate (I) reacts with the enamines (II) or (V) to form the (2 + 2)cycloadducts (III) and (VI) which are converted to the cyclopentenols (IV) and (VII) by treatment with acids.
ChemInform Abstract: Reaction of Trifluoromethanesulfonyl Chloride with Alkenes Catalyzed by a Ruthenium(II) Complex.
Authors: KAMIGATA N. , FUKUSHIMA T. , YOSHIDA M. 
Published: May 2016

AbstractThe alkenes (I) react with trifluoromethanesulfonyl chloride (II) in the presence of a ruthenium complex to give the chlorotrifluoroalkyl derivatives (III) under release of sulfur dioxide.
ChemInform Abstract: Facile Palladium‐Catalyzed Cross‐Coupling of Monoorganozinc Halides with 3‐Iodoanthranilonitriles.
Authors: CAMPBELL J. B. JUN. , WAWERCHAK FIROR J. , DAVENPORT T. W. 
Published: May 2016

Abstract3‐Iodoanthranilonitrile (I) undergoes substitution reaction with the organozinc bromides (II), generated from the corresponding Grignard or organolithium agents and zinc dibromide in the presence of a Pd(II) phosphine complex catalyst, to yield the C‐C coupling products (III).
ChemInform Abstract: Synthesis of Anthranilonitriles by Fragmentation of Isatin Oxime Triflates.
Authors: CAMPBELL J. B. JUN. , DAVENPORT T. W. 
Published: May 2016

AbstractThe isatin oxime triflates (III), generated from the corresponding oximes (I), undergo base‐induced cleavage and decarboxylation, forming the o‐aminobenzonitriles (IV).
ChemInform Abstract: A Facile Electroreductive Hydrocoupling of Imines in an Undivided Cell.
Authors: TANAKA H. , NAKAHARA T. , DHIMANE H. , TORII S. 
Published: May 2016

AbstractElectrolysis of the N‐benzylimines (Ia) and (Ib) in the presence of trifluoroacetic acid and lead dibromide results in the formation of the 1,2‐diamines (IIa) and (IIb).
ChemInform Abstract: A Convenient Route to 1,2‐Dibenzoyl‐1‐arylethylenes.
Authors: MAITRA S. , SINGH R. , SINHA A. , LAHIRI S. 
Published: May 2016

AbstractThe (benzoylvinyl)naphthalenes (III) are prepared by condensation reaction of the aldehydes (I) with acetophenone (II).
ChemInform Abstract: An Improved Procedure for Bromomethylation of Aromatics Using Phase‐Transfer Catalysis. Rapid Bishaloalkylation.
Authors: MITCHELL R. H. , IYER V. S. 
Published: May 2016

AbstractTreatment of the benzenes (I) and naphthalenes (VI) with 1 equivalent of 1,3,5‐trioxane (II) and 48% hydrogen bromide results in bromomethylation to produce the bromides (III) or (VII).
ChemInform Abstract: Folding Strain Control for Remote Stereocontrol: Diastereoselectivity in the Ring Closure Reactions of 2‐(6′‐Trimethylsilylhex‐4′‐enyl)cyclohex‐2‐enones with Alkyl Groups at Various Positions in the Side Chain.
Authors: TOKOROYAMA T. , OKADA K. , IIO H. 
Published: May 2016

AbstractTiCl4‐catalyzed cyclization of the silylalkenylcyclohexenones (I) gives the β‐methyl compounds (III) as the main products.
ChemInform Abstract: A New Synthesis of Anthraquinones Using Dihydrooxazoles and Grignard Reagents Derived from Mg(Anthracene) (THF)3.
Authors: NICOLETTI T. M. , RASTON C. L. , SARGENT M. V. 
Published: May 2016

AbstractIn order to develop a new method to prepare anthraquinones under mild conditions to preclude the possibility of Hayashi rearrangement, the benzylbenzoic acid (III) is cyclized and oxidized to give a title compound (IV).
ChemInform Abstract: Light‐Induced Conversion of 4,6,7,8‐Tetrahydro‐2H‐benzopyran‐2,5(3H)‐diones into 3,5,6,7‐Tetrahydrobenzofuran‐4(2H)‐ones in Methanol.
Authors: HOBEL K. , MARGARETHA P. 
Published: May 2016

AbstractThe photochemical conversion of the benzopyran derivative (I) into the benzofuran derivative (IIIa) in methanol (IIa) does not ‐ as previously assumed ‐ proceed by decarbonylation of a primarily formed acylvinyloxy biradical (VIII).
ChemInform Abstract: Diisobutylaluminum Hydride Reduction of Unsaturated Silylcyanohydrins: A New Entry to Confertifolin.
Authors: JOMMI G. , PAGLIARIN R. , SISTI M. , TAVECCHIA P. 
Published: May 2016

AbstractThe α‐(phenylthiomethylene)cyclohexanones (I) are converted to the cyanohydrin silyl ethers (III) and then subjected to reduction with di‐(isobutyl)aluminum hydride, yielding the 2‐(phenylthiomethyl)cyclohexenecarbaldehydes (IV).
ChemInform Abstract: Lead Tetraacetate Mediated Oxidative Cyclizations of Isoquinoline Alkyl Substituted Methylene Urethanes (Enamides) to Isoquinoline Hydroxyoxazolidinones.
Authors: LENZ G. R. 
Published: May 2016

AbstractThe structure of the oxidation products is confirmed by the crystal structure of (IIa) (space group: P21/a, Z=4).
ChemInform Abstract: Disilylated Compounds as Precursors of Heterocycles: A New and Easy Oxadiazole Synthesis.
Authors: RIGO B. , FASSEUR D. , CAULIEZ P. , COUTURIER D. 
Published: May 2016

AbstractThe diacylhydrazines (Ia) ‐ (Id) are treated with chlorotrimethylsilane (II) in refluxing triethylamine to produce mainly the O,O‐disilylated derivatives (III), together with the oxadiazoles (IVc) and (IVd) due to cyclization.
ChemInform Abstract: Two Directions of Cyclization of α‐Diazo‐β‐dithioamides. New Rearrangements of 1,2,3‐Triazole‐4‐carbothiamides.
Authors: BAKULEV V. A. , LEBEDEV A. T. , DANKOVA E. F. , MOKRUSHIN V. S. , PETROSYAN V. S. 
Published: May 2016

AbstractThe cyclization processes are studied of diazomalonodithioamides such as (III), (VI), (X), generated by five different methods two of which are shown in the scheme.
ChemInform Abstract: Synthesis and Properties of 1,7‐Dithiaperylene: A New Pericondensed Weitz Type Donor.
Authors: NAKASUJI K. , ODA A. , MURATA I. , IMAEDA K. , INOKUCHI H. 
Published: May 2016

AbstractThe polysulfide (I) is reductively cleaved and then coupled with chloroacetic acid (II) to yield the diacid (III).
ChemInform Abstract: Stereoregulation in the Preparation of 1‐ and 3‐Monosubstituted 1,2,3,4,6,7,12,12b‐Octahydroindolo(2,3‐a)quinolizines.
Authors: LOUNASMAA M. , JOKELA R. , TIRKKONEN B. , TAMMINEN T. 
Published: May 2016

AbstractA recently developed method is successfully applied to the preparation of the title compounds (IV)/(V), (VI)/(VII) and (X)/(XI) possessing the cis or trans relationship at C(12b)H‐C(1)H or C(12b)H‐C(3)H. Whereas direct hydrogenation of the unsaturated precursors gives mainly or exclusively the cis products, hydrogenation of the corresponding Boc analogues affords the trans products.
ChemInform Abstract: Lewis Acid‐Induced π‐Cyclization of Glycine‐Cation Equivalents to Substituted Pipecolic Acid Derivatives.
Authors: ESCH P. M. , BOSKA I. M. , HIEMSTRA H. , SPECKAMP W. N. 
Published: May 2016

AbstractTreatment of the E‐N‐alkenyl carbamates (I) with tin tetrachloride results in cyclization, yielding the hydroxypiperidines (II) or the chloropiperidines (III), depending on the temperature of the work‐up process.
ChemInform Abstract: Furo(3,4‐d)pyrimidine‐2,4‐dione Derivatives with Antihypertensive Activity. Analogues of Thienopyrimidine‐2,4‐diones.
Authors: PRESS J. B. , MCNALLY J. J. , KEISER J. A. , OFFORD S. J. , KATZ L. B. , GIARDINO E. , FALOTICO R. , TOBIA A. J. 
Published: May 2016

AbstractThe potency of the most active title compounds (III) is similar to that of the thiophene isosters.
ChemInform Abstract: Synthesis and Antibronchospastic Activity of Theophylline Thioacetal Derivatives.
Authors: GROSA G. , CAPUTO O. , CERUTI M. , BIGLINO G. , FRANZONE J. S. , CIRILLO R. 
Published: May 2016

AbstractThe antibronchospastic activity of the title compounds, e.g. (III), is tested.
ChemInform Abstract: Fused Imidazoles: A Novel Synthesis of Imidazo(1,2‐b)(1,2,4)triazole and Imidazo(5,1‐f)(1,2,4)triazine Derivatives.
Authors: MOLINA P. , LORENZO A. , ALLER E. 
Published: May 2016

AbstractThe imidazotriazoles (V) are prepared from 1‐amino‐2‐methylthio‐4‐phenylimidazole (I) by coupling with isothiocyanates (II) followed by methylation and cyclization.
ChemInform Abstract: Pyrrole Studies. Part 41. Reactivity of 3,4‐Diformyl‐2,5‐dimethylpyrrole with Diaminoalkanes. An Unusual Formation of 2‐Azafulvenes.
Authors: TAHERI S. A. N. , JONES R. A. , BADESHA S. S. , HANIA M. M. 
Published: May 2016

AbstractThe reaction of the title pyrrole (III) with diamines leads to 2:2 and 1:1 adducts which exist predominantly in the 2‐azafulvene forms (I), (V) and (VII).
ChemInform Abstract: Atropisomeric Sulfur Reagents in Organic Synthesis: Diastereoselective Preparation and Reactions of 2‐Benzoyldinaphto(2,1‐d:1′,2′‐f)(1,3)dithiepine and Its S‐Oxide.
Authors: DELOGU G. , DE LUCCHI O. , MAGLIOLI P. 
Published: May 2016

AbstractThe binaphthalenedithiol (I) reacts with the diethoxyacetophenone (II) in the presence of a Lewis acid to give the benzoyldinaphthodithiepine (III) which is reduced with lithium alanate or coupled with methylmagnesium iodide (V) to produce the alcohols (IV).
ChemInform Abstract: Silica‐Supported Tetrabutylammonium Fluoride as a Catalyst for the Silylation of Carbonyl and Hydroxy Compounds with Ethyl Trimethylsilylacetate.
Authors: GAMBACORTA A. , TURCHETTA S. , BOTTA M. 
Published: May 2016

AbstractThe ketones (I) and (V) are treated with the silylacetate (II) in the presence of tetrabutylammonium fluoride on silica to form the silyl enol ethers (III) and (IV) or (VI) and (VII) with predominance of the isomer with the less substituted double bond.
ChemInform Abstract: Chiral Organosilicon Compounds. Part 1. Synthesis of Chiral Silyl Enol Ethers.
Authors: KAYE P. T. , LEARMONTH R. A. 
Published: May 2016

AbstractThe chiral alcohols (I) and (VIII) are treated with one equivalent of dichlorodimethylsilane (II) to yield the chlorodimethylsilyl ethers (III) or (IX).
ChemInform Abstract: Formation of Cyclic Carbosilanes in the Pyrolysis of Octamethyltrisilane.
Authors: BORTOLIN B. N. , DAVIDSON I. M. T. , LANCASTER D. , SIMPSON T. , WILD D. A. 
Published: May 2016

AbstractThe mechanism of breakdown of polysilanes is of interest because of their importance as photoresists and as potential precursors to new polycarbosilane polymers.
ChemInform Abstract: Lithiated Di‐t‐butylfluorosilylmesitylphosphane ‐ From the Phosphane to the Phosphide.
Authors: ANDRIANARISON M. , STALKE D. , KLINGEBIEL U. 
Published: May 2016

AbstractThe derivative (III) (P21/c, Z=4), a fluorosilylphosphide, can be interpreted as a contact ion pair.
ChemInform Abstract: Ring Transformations of Phosphorus‐Containing Heterocycles. Part 5. The Formation of Phosphepine 1‐Oxides in the Reaction of Dihydrophosphinine 1‐Oxides with Dichlorocarbene.
Authors: KEGLEVICH G. , PETNEHAZY I. , TOEKE L. + , JANKE F. , BRLIK J. , TOTH G. 
Published: May 2016

AbstractAddition of dichlorocarbene, generated from trichloromethane (III), to the chloro‐1‐methoxydihydrophosphinine oxides (I) and (II) gives a mixture of the phosphepin oxide (VI) and the phosphabicyclooctadiene oxide (VII) via the phosphabicycloheptenes (IV) and (V).
ChemInform Abstract: Tetraformyltetraselenafulvalene (TFTSeF): Synthesis and Some Uses as a Precursor of Polyfunctionalized Tetraselenafulvalenes.
Authors: SALLE M. , GORGUES A. , FABRE J.‐M. , BECHGAARD K. , JUBAULT M. , TEXIER F. 
Published: May 2016

AbstractThe alkyne (I) undergoes ring closure with the cyclic triselenocarbonate (II) to give the selone (III) which is dimerized by treatment with octacarbonyldicobalt, producing a mixture of the isomeric tetraselenafulvalenes (IV).
ChemInform Abstract: Synthesis of Mixed Diaryltin(IV) Complexes Using an Arylmercury Compound. Crystal and Molecular Structure of Cyclic (Sn(2‐C6H4N=NPh)(Ph)Cl2).
Authors: VICENTE J. , CHICOTE M. T. , RAMIREZ‐DE‐ARELLANO M. C. , PELIZZI G. , VITALI F. 
Published: May 2016

AbstractThe transmetalation reaction between (II) and (I) leads to the synthesis of the mixed diaryltin complex (III) (space group P1 with Z=2).
ChemInform Abstract: Synthesis and Structural Characterization of (Sn(1,2‐O2C6H3NO2‐4)(C4H8O))n ‐ A Tin(II) Catechol Complex.
Authors: MACHELL J. C. , MINGOS D. M. P. , STOLBERG T. L. 
Published: May 2016

AbstractThe title complex, prepared from 4‐nitrocatechol and Sn(O‐Me)2 in THF and crystallizing in P1 with Z=2, has a chain polymeric structure based on distorted square‐pyramidal SnO5 moieties linked by oxygen bridges from the catechol ligands.
ChemInform Abstract: Germanium and Tin Compounds. Part 5. Reaction Pathways of Sterically Congested Stannanes.
Authors: WEIDENBRUCH M. , SCHAEFERS K. + , PETERS K. , VON SCHNERING H. G. 
Published: May 2016

AbstractThe reaction products (III), obtained at different temp. in petroleum ether, both show restricted rotation about the Sn‐C(Ar) bond at 20 °C. Reductive elimination of Cl from (IIIa) yields the distannane (IV), whereas a similar reaction of (IIIb) only results in decomposition.
ChemInform Abstract: Convenient Synthesis of β‐Trichlorostannyl Ketones from α,β‐Unsaturated Ketones and Their Facile Conversion to β‐Trialkylstannyl Ketones.
Authors: NAKAHIRA H. , RYU I. , OGAWA A. , KAMBE N. , SONODA N. 
Published: May 2016

AbstractHydrotrichlorostannation of α,β‐unsaturated ketones such as (III) with HSnCl3 generated in situ from (I)·2 H2O and Me3SiCl (II) provides a convenient procedure for the preparation of β‐trichlorostannyl ketones e.g. (IV).
ChemInform Abstract: Protonation Reactions of Dinitrogen Complexes of Molybdenum and Tungsten with PMe3 as Coligand. X‐Ray Structure of the Hydrazidium Complex (WCl(NNH3)(PMe3)4)Cl2.
Authors: GALINDO A. , HILLS A. , HUGHES D. L. , RICHARDS R. L. , HUGHES M. , MASON J. 
Published: May 2016

AbstractThe reaction of the cis‐bis(dinitrogen)‐Mo complex (I) with two equiv. HCl or Me3SiI/MeOH gives the hydrazido(‐2) complexes (II) as intermediate products.
ChemInform Abstract: The Versatility of the Dihydrogenobis(1‐pyrazolyl)borate Ligand, H2B(pz)‐ 2: Novel Anionic Complexes with Chromium(II), Chromium(III), and Manganese(II). X‐Ray Structure of (AsPh4)(MnCl(H2B(pz)2)2).
Authors: DI VAIRA M. , MANI F. 
Published: May 2016

AbstractNew five‐coordinate, high‐spin complexes with the ligand (I) are prepared as shown in the scheme for the example of (III) ( P21/n, Z=4).
ChemInform Abstract: Synthesis and Reactivity of the μ(1,n)‐Alkanediyl Complexes ((OC)5M(CH2)nM(CO)5) (M: Mn, n = 4‐6; M: Re, n = 3 or 4).
Authors: MAPOLIE S. F. , MOSS J. R. 
Published: May 2016

AbstractThe title compounds (II) and (V) are synthesized either by thermal decarbonylation of the corresponding μ‐diacyl compounds e.g. (I) or, in the case of (Va), by reaction of Na(Re(CO)5) with Tf‐O‐(CH2)3‐O‐Tf (IV).
ChemInform Abstract: Reactivity of μ3‐Carbynecarbonyltriiron Clusters: CO Substitution, Thermolysis to μ2‐Carbyne Complexes, and Addition of Alkynes with Formation of η6‐Ferracyclopentadienone Ligands.
Authors: BUCHHOLZ D. , HUTTNER G. , IMHOF W. , ZSOLNAI L. , GUENAUER D. + 
Published: May 2016

AbstractThe carbyne cluster (II) undergoes thermolysis with loss of one Fe(CO)3 group to give the μ2‐carbynediiron compound (I) (space group Pna21, Z=4).
ChemInform Abstract: Piano‐Stool Acylcyclopentadienyl Iron Complexes: Photolytic Syntheses and X‐Ray Crystal Structure of (Fe(η5‐C5H4COMe)(dppe)(NCMe))PF6.
Authors: RUIZ J. , GONZALEZ M. A. , ROMAN E. , GARLAND M. T. 
Published: May 2016

AbstractThe complexes (IIIb) and (IIIc) are prepared in the presence of other two‐electron ligands in solvent mixtures of low electron donicity.
ChemInform Abstract: Structure of a Carboxylate‐Bridged Tetraazamacrocyclic Complex of Cobalt(III).
Authors: DELDONNO T. A. , MATSUMOTO N. , BUSCH D. H. , ALCOCK N. W. 
Published: May 2016

AbstractA new macrocyclic ligand, containing a carefully selected pendant group and the title Co(III) complex (VIII) of it are prepared.
ChemInform Abstract: Synthesis, Characterization, Reactivity, and X‐Ray Structure of cis‐Carbonylchlorobis(1‐methyl‐3‐(pyridin‐2‐yl)‐1,2,4‐triazole‐N4N′)ruthenium Hexafluorophosphate.
Authors: FORSTER R. J. , BOYLE A. , VOS J. G. , HAGE R. , DIJKHUIS A. H. J. , DE GRAAFF R. A. G. , HAASNOOT J. G. , PRINS R. , REEDIJK J. 
Published: May 2016

AbstractThe reaction of RuCl3 with the pyridyltriazole ligand (DMF, reflux) gives a mixture of coordination isomers (85% yield) from which the isomer (I) ( P21/n, Z=4) is obtained by crystallization techniques.
ChemInform Abstract: Reactions of Transition‐Metal σ‐Acetylide Complexes. Part 14. Cyclobutenyl, Butadienyl, and Allyl Complexes of Ruthenium Derived from 1,1‐Dicyano‐2,2‐bis(trifluoromethyl)ethene. X‐Ray Structures of Cyclic Ru(C=CPhC(CF3)2C(CN)2)(CO)(PPh3)(η‐C5H5), Ru(C(=C(CN)2)CX=C(CF3)2)(CO)(PPh3)(η‐C5H5) (X: Me, Ph), and Ru(η3‐C(CF3)2CPhC=C(CN)2)(PPh3)(η‐C5H5).
Authors: BRUCE M. I. , HAMBLEY T. W. , LIDDELL M. J. , SNOW M. R. , SWINCER A. G. , TIEKINK E. R. T. 
Published: May 2016

AbstractThe title ethene (II) reacts with the acetylide‐Ru complexes (I) to give the σ‐cyclobutenyl complexes (III) ((IIId): space group P212121, Z=4).