bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis and Structural Characterization of a Thiolate Coordination Complex of a Mixed‐Valence Mo(V)/Mo(VI) Polyoxomolybdate, (Mo10O28(SCH2CH2O)2(HOCH3)2)4‐, and of Its Decomposition Product (Mo4O6(SCH2CH2O)5)2‐.
Authors: LIU S. , SUN X. , ZUBIETA J. 
Published: May 2016

AbstractThe decanuclear polyoxomolybdate complex (IV) crystallizes in P21/n with Z=2 and presents a number of unusual structural features.
ChemInform Abstract: A New Class of Homoleptic 12‐Electron Molybdenum and Tungsten Alkoxide Clusters of Formula (M4(OR)12).
Authors: CHISHOLM M. H. , FOLTING K. , HAMMOND C. E. , HAMPDEN‐SMITH M. J. 
Published: May 2016

AbstractThe alkoxide clusters (III) are prepared according to the scheme and characterized by elemental analysis and 1H and 13C NMR spectra.
ChemInform Abstract: Reduction of Hydrogen Peroxide by the Ferrous Iron Chelate of Diethylenetriamine‐N,N,N′,N′′,N′′‐pentaacetate.
Authors: RAHHAL S. , RICHTER H. W. 
Published: May 2016

AbstractThe title reaction in neutral aqueous solution yields an oxidizing species which exhibits properties different from those of the hydroxyl radical.
ChemInform Abstract: A Solution to the in,out‐Bicyclo(4.4.1)undecan‐7‐one Problem Inherent in Ingenane Total Synthesis.
Authors: FUNK R. L. , OLMSTEAD T. A. , PARVEZ M. 
Published: May 2016

AbstractA synthetic procedure starting from (+)‐carene (I) is presented for the in,out‐macrobicyclic lactone (XII) which then can be transformed to the rearrangement product (XIV) related to ingenol.
ChemInform Abstract: Model Studies Directed Toward Forskolin: 1,9‐Dideoxyforskolin from a Bicyclic Precursor.
Authors: SCHERKENBECK J. , BOETTGER D. + , WELZEL P. 
Published: May 2016

AbstractOn a series of reactions, carried out with the bicyclic labdane derivative (I), only the sequence shown in the scheme leads to the desired result, i.e. the construction of the silyl ether (VIa).
ChemInform Abstract: Studies Directed Toward the Total Synthesis of Dicyclopenta(a,d)cyclooctane Terpenoids.
Authors: DE GREGORI A. , JOMMI G. , SISTI M. , GARIBOLDI P. , MERATI F. 
Published: May 2016

AbstractPhotocyclization reaction of the compound (VII) yields the products (VIII)/(IX) (inseparable mixture), (X) and (XI) (yields given in g).
ChemInform Abstract: Enzymochemical Regioselective Oxidation of Steroids Without Oxidoreductases.
Authors: RIVA S. , KLIBANOV A. M. 
Published: May 2016

AbstractTwo commercially available enzymes (out of 8 tested), namely lipase (bio‐agent1) and subtilisin (bio‐agent2) are found not only to esterify the model steroid diol (I) but moreover with opposite regioselectivity and in gram quantities.
ChemInform Abstract: The Hydrocyanation Route to β‐ and γ‐Amino Acids. A Synthesis of α‐Methylene‐β‐alanine.
Authors: JACKSON W. R. , PERLMUTTER P. , SMALLRIDGE A. J. 
Published: May 2016

AbstractNi(0)‐catalyzed addition reaction of hydrogen cyanide (II) to the alkynes (I) leads to the formation of a mixture of the unsaturated nitriles (III) and (IV).
ChemInform Abstract: α‐Metalation of 1‐(tert‐Butoxycarbonyl)‐1,2‐dihydropyridines.
Authors: COMINS D. L. , WEGLARZ M. A. , O'CONNOR S. 
Published: May 2016

AbstractLithiation of the dihydropyridines (I) and subsequent reaction with the electrophiles (II) give the substituted dihydropyridines (III) which are dehydrogenated with chloranil to yield the pyridine (IV).
ChemInform Abstract: Thermochemistry of Rare‐Earth‐Metal‐Alkaline‐Earth‐Metal‐Copper Oxide Superconductors.
Authors: MORSS L. R. , SONNENBERGER D. C. , THORN R. J. 
Published: May 2016

AbstractThe enthalpies of formation of La2CuO4, La1.85Sr0.15CuO4, and YBa2Cu3O6+y (y: 0.25‐0.93) are determined at 298.15 K by solution calorimetry.
ChemInform Abstract: Electrical and Mechanical Breakdown of Anodic Films on Tungsten in Aqueous Electrolytes.
Authors: DI QUARTO F. , PIAZZA S. , SUNSERI C. 
Published: May 2016

AbstractThe anodic behavior of tungsten is studied in H2SO4 and HNO3 and a model is proposed to explain the electrical breakdown of passive films on valve metals.
ChemInform Abstract: Influence of Surface Segregation on Wetting of Liquid Metal Alloys.
Authors: BOZACK M. J. , BELL A. E. , SWANSON L. W. 
Published: May 2016

AbstractIt is demonstrated that wetting of transition metal boride and arsenide molten metal alloys (Ni55B45, Pd72B28, Pt72B28, Pd2As) is strongly influenced by surface segregation of low level bulk impurities in the alloy.
ChemInform Abstract: Rare‐Earth‐Metal Iodide Clusters Centered by Transition Metals: Synthesis, Structure, and Bonding of R7I12M Compounds (R: Sc, Y, Pr, Gd; M: Mn, Fe, Co, Ni).
Authors: HUGHBANKS T. , CORBETT J. D. 
Published: May 2016

AbstractThe title compounds (IV) crystallize in the Sc(Sc6Cl12B)‐type structure (space group R3, Z=3‐) with a transition metal atom at the cluster center.
ChemInform Abstract: Hydride Binding Energies of Boranes. ‐ Endothermic hydride transfer reactions between mass‐selected, translationally excited borohydride ions such as BH‐ 4, HBEt‐ 3, B2H‐
Authors: WORKMAN D. B. , SQUIRES R. R. 
Published: May 2016

Abstract7, and BH3CN‐ and CO2 as a convenient reference H‐‐acceptor compound are observed.
ChemInform Abstract: Allo Compounds with Unusual Behavior in Gas Chromatography Using Chiral Stationary Phase
Authors: KUESTERS E. + , RAHMEN W. 
Published: May 2016

Abstract(separation of enantiomers of D,L‐allo‐threoninol on Chirasil‐L‐Val; reversed order of elution as expected due to the different importance of the asym.
ChemInform Abstract: Reactions of 2‐Alkoxy‐1,3‐dienes with Nitrile Oxides and Aryl Azides.
Authors: KHERUZE YU. I. , GALISHEV V. A. , PETROV A. A. 
Published: May 2016

AbstractThe chemoselectivity of the 1,3‐dipolar addition reactions between the title compounds (Ia)‐(Id) and benzonitrile oxide ‐ derived in situ from the hydroxamic acid chloride (II) ‐ benzoylnitrile oxide, derived from the chloride (IV), the aryl azide (VIII) and the aroyl azide (XII) is investigated.
ChemInform Abstract: Fragmentation of 2,3‐Bis(Element(Si,Ge))‐Substituted‐cyclopropanones and α‐Silylated Episulfones.
Authors: ZAITSEVA G. S. , LIVANTSOVA L. I. , FEDORENKO E. N. , KISIN A. V. , SHIPOV A. G. , BAUKOV YU. I. 
Published: May 2016

AbstractThermolysis or photolysis of the cyclopropanones (III), prepared from the silyldiazomethanes (I) and the ketenes (II), leads under decarbonylation to the formation of the 1,2‐disubstituted ethylenes (IV) with predominance of the Z‐isomers.
ChemInform Abstract: Enamine Rearrangement of Pyridinium Salts. Part 8. Effect of Nucleophilic Reagent on Pyridinium Salts.
Authors: FADDA A. A. , KHALIL A. M. , EL‐MORSY S. G. , EL‐HABBAL M. M. 
Published: May 2016

AbstractThe reaction of the pyridinium salts (I) according to A) yields the anilines (II) and the pyridines (III).
ChemInform Abstract: Stereoselectivity in the Outer‐Sphere Reduction of Nickel(IV) Bis(oxime‐imine) Complexes by (Co(phen)3)2+.
Authors: LAPPIN A. G. , MARTONE D. P. , OSVATH P. , MARUSAK R. A. 
Published: May 2016

AbstractThe kinetics and mechanism of oxidation of (I) by the Ni(IV) complexes (IV) and (V) are studied at 25 °C by stopped flow spectrophotometry.
ChemInform Abstract: Trisubstituted (Stannylmethyl)lithium as a Methylene Double Anion Equivalent. Reaction with Esters.
Authors: SATO T. , MATSUOKA H. , IGARASHI T. , MINOMURA M. , MURAYAMA E. 
Published: May 2016

AbstractCarboxylic esters such as (I) or the protected amino esters (VII) react with stannylmethyllithium compounds to form methyl ketones, e.g. (III) and (VIII), as the main products.
ChemInform Abstract: Samarium Diiodide Promoted Intramolecular Pinacolic Coupling Reactions.
Authors: MOLANDER G. A. , KENNY C. 
Published: May 2016

AbstractSamarium diiodide promotes the intramolecular ring closure of the 2‐(3‐oxopropyl)‐1,3‐dicarbonyl compounds (I), forming stereoselectively the dihydroxycyclopentane derivatives (II).
ChemInform Abstract: Reaction of 1‐Chloro‐1‐methylcyclohexane with Phenyl‐ and Benzyltrimethylsilanes in the Presence of AlCl3.
Authors: BOLESTOVA G. I. , PARNES Z. N. , VOL'PIN M. E. 
Published: May 2016

AbstractThe reaction between 1‐chloro‐1‐methylcyclohexane (I), which forms methylcyclohexylcarbocations under Friedel‐Crafts conditions, and phenyltrimethylsilane (II) or benzyltrimethylsilane (IV) is investigated.
ChemInform Abstract: Enzymatic Resolution of Bicyclo(4.2.0)oct‐2‐en‐7‐ol and the Preparation of Some Polysubstituted Bicyclo(3.3.0)octan‐2‐ones via Highly Strained Tricyclo(4.2.0.01,5)octan‐8‐ones.
Authors: COTTERILL I. C. , FINCH H. , REYNOLDS D. P. , ROBERTS S. M. , RZEPA H. S. , SHORT K. M. , SLAWIN A. M. Z. , WALLIS C. J. , WILLIAMS D. J. 
Published: May 2016

AbstractTreatment of the bromobicyclo(4.2.0)cyclooctanones (I) with bases results in intramolecular cyclization, producing the tricyclo(4.2.0.0)octanones (II).
ChemInform Abstract: New Syntheses of Phenanthrenes and of Related Systems by Intramolecular Annulation Processes.
Authors: GHERA E. , MAURYA R. , BEN‐DAVID Y. 
Published: May 2016

Abstractα‐Bromination of the benzene derivatives (I) with NBS yields the bromides (II) which undergo base‐promoted twofold intramolecular cyclization to yield the tricyclic systems (III).
ChemInform Abstract: Vinyl Ethers with an Epoxy Group. Part 16. Reaction of the Vinyloxyethyl Ether of Glycidol with Acetals.
Authors: NEDOLYA N. A. , KHIL'KO M. YA. , TROFIMOV B. A. , SIGALOV M. V. 
Published: May 2016

AbstractThe reaction between vinyl epoxy ethers, e.g. (I) and acetals, e.g. (II) affords the branched acetal (III) with an epoxy function, which represents the first specimen of this class of compounds.
ChemInform Abstract: Chemistry of Oxaziridines. Part 9. Synthesis of 2‐Sulfonyl‐ and 2‐Sulfamoyloxaziridines Using Potassium Peroxymonosulfate (Oxone).
Authors: DAVIS F. A. , CHATTOPADHYAY S. , TOWSON J. C. , LAL S. , REDDY T. 
Published: May 2016

AbstractThe N‐sulfonylimines (I) are oxidized with oxone to form the oxaziridines (II).
ChemInform Abstract: Remote Induction of the Condensation of p‐Nitrobenzaldehyde on the Methylene Group of 5‐Hydroxy‐2‐coumaranone.
Authors: BARBIER M. 
Published: May 2016

Abstract2‐Coumaranone (Ia) and p‐nitrobenzaldehyde (II) react to give a mixture of the p‐nitrobenzylidene derivatives (IIIa) and (IVa).
ChemInform Abstract: Organometallic Compounds with o‐Phenylene Substituents. Part 15. Hexamethoxy‐tetrachalcogena‐tetrahydropentacenes.
Authors: BERGES P. , KLAR G. 
Published: May 2016

AbstractModified Adams‐Ferretti reaction of (I) and (II) yields the trimer (III), which is converted to the title compounds (IV) and (V).
ChemInform Abstract: Photochemical Addition Reaction of 2‐Aminoethanethiol Hydrochloride and 2‐(Diethylamino)ethanethiol to Triorganyl(vinyl)‐ and Triorganyl(ethynyl)silanes.
Authors: ZHILA G. YU. , YAROSH O. G. , VLASOVA N. N. , ALBANOV A. I. , VORONKOV M. G. 
Published: May 2016

AbstractMixtures of the ethenylsilanes (I) or the ethynylsilanes (VI) with 2‐mercaptoethylamine hydrochloride (II) are irradiated to give the adducts (III) or (VII).
ChemInform Abstract: Phenalene‐Phosphazene Complexes: Effect of Exocyclic Charge Densities on the Cyclotriphosphazene Ring System.
Authors: HADDON R. C. , CHICHESTER‐HICKS S. V. , MAYO S. L. 
Published: May 2016

AbstractThe 1,9‐diamino‐substituted phenalene complexes (IV) of the cyclotriphosphazene ring system are prepared according to the scheme.
ChemInform Abstract: An Unstable Manganese(III) Complex Incorporating Ligand Donor Types Proposed for an Acid Phosphatase from Sweet Potato: (p‐Nitrobenzenethiolato)(N,N′‐ethylenebis(salicylideneaminato))manganese(III).
Authors: GOHDES J. W. , ARMSTRONG W. H. 
Published: May 2016

AbstractThe Mn(III) complex (III) containing mimics for all the proposed donors in the sweet potato acid phosphatase including a monodentate thiolate group is prepared according to the scheme and characterized by X‐ray structure analysis (space group P21/n, Z=4) and several physical methods.
ChemInform Abstract: Molecular Structure and Magnetic Properties of the Dimeric N,N′‐Ethylenebis(salicylaminato)Fe(III)‐μ‐methoxo‐N,N′‐ethylene(o‐hydroxylbe# nzylglycine)salicylaminato‐Fe(III): A Complex with a μ‐Monodentate Acetato Bridge.
Authors: SPARTALIAN K. , BONADIES J. A. , CARRANO C. J. 
Published: May 2016

AbstractThe title complex (I) is obtained by equimolar reaction of N,N'‐ethylenebis(salicylamine) with monochloroacetic acid in aqueous solution at 60 °C and treating this reaction mixture with an excess of FeCl3 in MeOH.
ChemInform Abstract: Synthesis and Structure of the First Three‐Membered Ring Containing Arsenic, Phosphorus and Platinum.
Authors: EDELMANN F. , SPANG C. , ROESKY H. W. , JONES P. G. 
Published: May 2016

AbstractThe three‐membered ring system (V) containing Pt(II), P(III), and As(III) is synthesized via the arsaphosphene (III) according to the scheme.
ChemInform Abstract: Amino Acids and Peptides. Part 204. Synthesis of the Carboxy‐Terminal Octapeptide of Cholecystokinin (CCK‐8) Based on Incorporation of O4‐Sulfotyrosine by Enzymatically Catalyzed Formation of Peptide Bonds.
Authors: CEROVSKY V. , HLAVACEK J. , SLANINOVA J. , JOST K. 
Published: May 2016

AbstractThe title peptide (III) is prepared by the papain‐catalyzed condensation of the protected 1‐2 fragment (I) possessing the O4‐sulfotyrosine moiety with the 3‐8 fragment (II) and subsequent deprotection.
ChemInform Abstract: Evaluation of the 2 NH2A‐T Pair in Hybridization. Part 1. Synthesis of the DNA/RNA Hybrid Oligomers Containing 2‐Aminoadenosines.
Authors: KIKUCHI K. , TANIYAMA Y. , MARUMOTO R. 
Published: May 2016

AbstractThe fully protected ribonucleotide (VII) is prepared from 2‐aminoadenosine (I) in 5 steps.
ChemInform Abstract: Synthesis of Premtorin and Its Isomers.
Authors: BHARDWAJ D. K. , GUPTA A. K. , JAIN A. , SHRAWAT V. K. 
Published: May 2016

AbstractThe structure of the title compound (III), a constituent of Abrus precatorius, is confirmed by its unambiguous synthesis from the acetophenone (I) and the aldehyde (II).
ChemInform Abstract: Photodynamics of a Nickel Hydrocorphinoid Model of F430.
Authors: CRAWFORD B. A. , FINDSEN E. W. , ONDRIAS M. R. , SHELNUTT J. A. 
Published: May 2016

AbstractThe resonance Raman spectra of the ground‐state complex (I) and its six‐coordinate analogues with two axially ligated MeOH or piperidine ligands, generated within 10 ns of direct photoexcitation of the visible π‐π* transition of the macrocycle, are reported.
ChemInform Abstract: The Chemistry in Air of the Rare‐Earth‐Metal Sesquioxides. Comparative Study of Hexagonal and Cubic Neodymia Samples.
Authors: BERNAL S. , BOTANA F. J. , GARCIA R. , RODRIGUEZ‐IZQUIERDO J. M. 
Published: May 2016

AbstractIt is found that aging of cubic Nd2O3 occurs faster than that of the hexagonal sample.
ChemInform Abstract: (Fe2S2(MoS4)2)4‐: The First Complex with Two MoS2‐ 4 Ions Coordinated to a Ferredoxin Type Central Unit.
Authors: MUELLER A. + , HILDEBRAND A. , PENK M. , BOEGGE H. + , BILL E. , TRAUTWEIN A. 
Published: May 2016

AbstractSynthesis of the title anion and precipitation as compound (IV) is achieved in the course of a study of the iron‐molybdenum cofactor of nitrogenase, which previously is shown to contain an Fe‐Mo‐S cluster of unknown structure.
ChemInform Abstract: Cycloaddition Reactions of Silyloxyacetylenes with Ketenes: Synthesis of Cyclobutenones, Resorcinols, and δ‐6‐Tetrahydrocannabinol.
Authors: KOWALSKI C. J. , LAL G. S. 
Published: May 2016

AbstractCycloaddition reaction of ketene (II) with the silyloxyacetylenes (I) yields the cyclobutenones (III); (IIIa) is further converted to the compounds (IV) or (VI).
ChemInform Abstract: The Adamantane Rearrangement of syn‐ and anti‐Tricyclo(4.2.1.1.12,5)decane. Part 2. Rearrangements Initiated by Regioselective Formation of Carbocations at C(3) and C(9).
Authors: BROSSI M. , GANTER C. 
Published: May 2016

AbstractTreatment of the exo‐alcohol (I) with BF3/Et3SiH (ionic hydrogenation) gives the anti‐hydrocarbon (II) as virtually the sole product which is likewise obtained from the endo‐alcohol (III) under the same conditions.
ChemInform Abstract: Ruthenium Carbonyl Catalyzed Reductive Carbonylation of Aromatic Nitro Compounds. A Selective Route to Carbamates.
Authors: CENINI S. , CROTTI C. , PIZZOTTI M. , PORTA F. 
Published: May 2016

AbstractThe nitrobenzenes (I) are carbonylated in the presence of methanol (III), a ruthenium carbonyl catalyst, and tetraethylammonium chloride to produce the aryl carbamates (IV) as the main products.
ChemInform Abstract: Structure‐Activity Profile of a Series of Novel Triazoloquinazoline Adenosine Antagonists.
Authors: FRANCIS J. E. , CASH W. D. , PSYCHOYOS S. , GHAI G. , WENK P. , FRIEDMANN R. C. , ATKINS C. , WARREN V. , FURNESS P. , HYUN J. L. , STONE G. A. , DESAI M. , WILLIAMS M. 
Published: May 2016

AbstractThe iso(thio)cyanatobenzonitriles (I) undergoes double cyclization with the furoic acid hydrazides (II) to yield the furyltriazoloquinazolinones (III).
ChemInform Abstract: 2,4‐Diamino‐6,7‐dimethoxyquinoline Derivatives as α1‐Adrenoceptor Antagonists and Antihypertensive Agents.
Authors: CAMPBELL S. F. , HARDSTONE J. D. , PALMER M. J. 
Published: May 2016

AbstractAmidines such as (III) are synthesized by various methods, e.g. from the aminobenzonitrile (I).
ChemInform Abstract: Oxidation and Reduction Chemistry of Bis(η‐arene)niobium Compounds: X‐Ray Crystal Structure of Bis(η‐toluene)(trimethylphosphine)niobium Tetrafluoroborate.
Authors: BANDY J. A. , PROUT K. , CLOKE F. G. N. , DE LEMOS H. C. , WALLIS J. M. 
Published: May 2016

AbstractCyclic voltammetry shows that bis(η‐toluene)‐Nb (I) undergoes both one‐electron reversible reduction and oxidation.
ChemInform Abstract: Novel Triple Cubane‐Type Organometallic Oxide Clusters: (MCp*MoO4)4·nH2O (M: Rh and Ir; Cp*: C5Me5; n = 2 for Rh and 0 for Ir).
Authors: HAYASHI Y. , TORIUMI K. , ISOBE K. 
Published: May 2016

AbstractThe title clusters (III), possessing a novel triple cubane framework, are characterized by elemental analysis, mol.
ChemInform Abstract: Methylarsane Substituted Hydroxycarboxylic Acid Esters.
Authors: ASLANIDIS P. , KOBER F. 
Published: May 2016

AbstractReaction of the aminoarsanes (I), (V), and (VII) with the α‐hydroxy‐ or α‐mercaptocarboxylates (II) results in cleavage of the As‐N bond, producing the substituted arsanes (III), (VI), and (VIII), together with dimethylamine (IV).
ChemInform Abstract: Synthesis of N‐(Arylmethylene)dehydroalanine Methyl Esters and Their Application as Building Blocks in the Synthesis of Amino Acids.
Authors: WULFF G. , BOEHNKE H. + , KLINKEN H. T. 
Published: May 2016

AbstractThe derivatives (I), which are readily available from L‐serine, are converted to the dehydro compounds (IV) by elimination reaction of the intermediate urethane (III).
ChemInform Abstract: A Facile Synthesis of (S)‐Isoserine from (S)‐Malic Acid.
Authors: MAEDA H. , SUZUKI M. , SUGANO H. , MATSUMOTO K. 
Published: May 2016

AbstractTreatment of the (S)‐malic acid monoester (I) with diphenoxyphosphoryl azide (II) gives the (S)‐oxazolidinonecarboxylate (III) via Curtius rearrangement of the intermediate isocyanate.
ChemInform Abstract: 8‐Aza‐7‐deaza‐2′,3′‐dideoxyguanosine: Deoxygenation of Its 2′‐Deoxy‐β‐D‐ribofuranoside.
Authors: SEELA F. , DRILLER H. 
Published: May 2016

AbstractThe solid‐liquid phase‐transfer glycosylation of the N‐heterocycle (I) is found to be superior to the liquid‐liquid method (57% of product (III) instead of 47%).
ChemInform Abstract: Synthetic Methods and in vitro Iron Binding Studies of the Novel 1‐Alkyl‐2‐ethyl‐3‐hydroxypyrid‐4‐one Iron Chelators.
Authors: KONTOGHIORGHES G. J. , SHEPPARD L. , BARR J. 
Published: May 2016

AbstractThe novel Fe chelators (III) are prepared from ethyl maltol (I) in a known one‐step reaction.
ChemInform Abstract: Electrochemical Reduction of Carbon Dioxide at in situ Electrodeposited Copper.
Authors: COOK R. L. , MACDUFF R. C. , SAMMELLS A. F. 
Published: May 2016

AbstractHigh faradaic efficiencies and current densities for the electrochemical reduction of CO2 to both CH4 and C2H4 are achieved at Cu deposited in situ on glassy carbon from an aqueous CuSO4/KHCO3 electrolyte.
ChemInform Abstract: Moderately Strong Intramolecular Magnetic Exchange Interaction Between the Copper(II) Ions Separated by 11.25 Å in (L2Cu2(OH2)2(μ‐terephthalato))(ClO4)2 (L: 1,4,7‐Trimethyl‐1,4,7‐triazacyclononane).
Authors: CHAUDHURI P. , ODER K. , WIEGHARDT K. , GEHRING S. , HAASE W. , NUBER B. , WEISS J. 
Published: May 2016

AbstractA long distance (11.3 Å) moderately strong antiferromagnetic coupling between Cu(II) atoms in the title complex (I) is reported.
ChemInform Abstract: The Preparation of Chiral Monofluoromethylated Molecules by Use of Immobilized Enzyme for Asymmetric Hydrolysis.
Authors: KITAZUME T. , OKAMURA N. , OHNOGI T. , ASAI M. , YAMAZAKI T. 
Published: May 2016

AbstractAsymmetric hydrolysis of the acetates (I) yields the (S) alcohols (II).
ChemInform Abstract: Diastereoselective Addition of Organozinc Compounds to (‐)‐Menthyl Phenylglyoxalate.
Authors: BOIREAU G. , DEBERLY A. , ABENHAIM D. 
Published: May 2016

AbstractThe chiral phenylglyoxalate (I) reacts with dialkylzinc compounds which are prepared in situ from zinc chloride and the Grignard compounds (II) to form the hydroxy esters (III).
ChemInform Abstract: Phenanthrene‐4,5‐quinones: A Synthesis of Morphenol.
Authors: HEWGILL F. R. , STEWART J. M. 
Published: May 2016

AbstractNew routes to phenanthrene‐4,5‐quinones are investigated; the parent system is hitherto unknown and up to now all attempts to prepare phenanthrene‐4,5‐quinones by oxidation of the corresponding 4,5‐diols failed.
ChemInform Abstract: The Absolute Configuration of Rimiterol, a Sympathomimetic Bronchodilator. The Crystal Structure of (R,R)‐Ethoxy(3,4‐dihydroxyphenyl)(2‐piperidinyl)methane Hydrochloride.
Authors: AASEN A. J. , HANSEN L. K. 
Published: May 2016

AbstractTreatment of (+)‐rimiterol (I), obtained by optical resolution of the racemate with (+)‐tartaric acid, with EtOH/HCl yields the ethoxy derivative (‐)‐(III) together with small amounts of the diastereomer (IV) (isolated as a crude 1:1 mixture of (‐)‐(III) and (IV)).
ChemInform Abstract: Autoxidation of 3‐Hydroxyanthranilic Acid.
Authors: MANTHEY M. K. , PYNE S. G. , TRUSCOTT R. J. W. 
Published: May 2016

AbstractAutoxidation of 3‐hydroxyanthranilic acid (I) at alkaline pH yields the p‐quinone dimer (II) as the major product.
ChemInform Abstract: Synthesis and Structural Characterization of Pt‐Si Dimers with Unusually Short Cross‐Ring Silicon‐Silicon Interactions.
Authors: ZARATE E. A. , TESSIER‐YOUNGS C. A. , YOUNGS W. J. 
Published: May 2016

AbstractThe preparation of cocrystallized mixture of the three air‐stable Pt‐silyl dimers (IV) occurs according to the scheme.
ChemInform Abstract: Thermochemistry of Uranium Compounds. Part 16. Calorimetric Determination of the Standard Molar Enthalpy of Formation at 298.15 K, Low‐Temperature Heat Capacity, and High‐Temperature Enthalpy Increments of UO2(OH)2·H2O (Schoepite).
Authors: TASKER I. R. , O'HARE P. A. G. , LEWIS B. M. , JOHNSON G. K. , CORDFUNKE E. H. P. 
Published: May 2016

AbstractThe molar thermodynamic properties mentioned in the title are determined by three precise calorimetric methods (low‐temp.
ChemInform Abstract: Easy Michael Addition by Solid‐Liquid Phase‐Transfer Catalysis ‐ Abnormal Reaction of N‐Acetylaminomalonate.
Authors: BRAM G. , SANSOULET J. , GALONS H. , MIOCQUE M. 
Published: May 2016

AbstractDiethyl acetylaminomalonate (I) is coupled with the electron‐deficient olefins (II) in the presence of bases and a phase‐transfer catalyst to produce the 2‐alkyl‐2‐acetylaminomalonates (III).
ChemInform Abstract: Hydrogen Fluoride Abstraction from Vicinal Difluoroalkanes: Reaction Conditions and syn/anti‐Stereoselectivity.
Authors: MATSUDA H. , HAMATANI T. , MATSUBARA S. , SCHLOSSER M. 
Published: May 2016

AbstractTowards NaO‐Me/MeOH, vic‐difluoroalkanes such as (I) are as inert as monofluoroalkanes.