bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: A Facile Preparation of 3‐Substituted 2‐Thioxotetrahydroquinazolin‐4‐ones by the Reaction of Anthranilamide with Isothiocyanates.
Authors: CHAN C.‐H. , SHISH F.‐J. , LIU K.‐C. , CHERN J.‐W. 
Published: May 2016

AbstractAnthranilamide (II) undergoes ring closure with the isothiocyanates (Ia) to give the 2‐(thioxo)tetrahydroquinazolin‐4‐ones (IIIa).
ChemInform Abstract: Chemical Reactivity of Alkylguanines. Part 1. Methylation of O6‐Methylguanine Derivatives.
Authors: KOHDA K. , BABA K. , KAWAZOE Y. 
Published: May 2016

AbstractThe methylation of the methylguanine (I) is performed under various conditions, producing the methyl derivatives (III) ‐ (V) or (VI) and (VII).
ChemInform Abstract: Studies on as‐Triazine Derivatives. Part 10. Addition Reaction of Phenylmagnesium Bromide with 1,2,4‐Triazines.
Authors: KONNO S. , SAGI M. , YOSHIDA N. , YAMANAKA H. 
Published: May 2016

AbstractReaction of 1,2,4‐triazine (I) with the Grignard compound (II) gives the unstable phenyldihydrotriazine (III) which undergoes aromatization upon treatment with potassium ferricyanide, producing 5‐phenyl‐as‐triazine (IV).
ChemInform Abstract: Synthesis of 2‐Methyl‐1,2,3,4,4a,5,9,10,16,16a‐decahydro(1)benzazepino‐(3,2,1‐jk)pyrido(3,4‐b)(1)benzazepine: A Conformationally Rigid Imipramine Analog.
Authors: DUNBAR P. G. , MARTIN A. R. 
Published: May 2016

Abstracto‐Lithiation of the N,N‐dialkylnicotinamides (II) followed by coupling with the dibenzazepinecarboxaldehyde (I) gives the hydroxymethylnicotinamides (III).
ChemInform Abstract: Reactivity of Hypervalent Species: Reactions of Anionic Penta‐Coordinated Silicon Complexes Towards Nucleophiles.
Authors: BOUDIN A. , CERVEAU G. , CHUIT C. , CORRIU R. J. P. , REYE C. 
Published: May 2016

AbstractThe title compounds (I) can be reduced by different procedures to yield silanes (II).
ChemInform Abstract: Low‐Coordinated Phosphorus Compounds. Part 59. 2,4,6‐Tri‐(tbutyl)phenylphosphaketene, a Synthon for Substituted Phospha‐Carba‐Polyenes.
Authors: APPEL R. , FOELLING P. + , JOSTEN B. , SCHUHN W. , WENZEL H. V. , KNOCH F. 
Published: May 2016

AbstractThe title compound (I) is used to prepare the phospha‐carba‐polyenes (III), (V) and (VII); (IIIa) is converted to the chloro derivative (X).
ChemInform Abstract: Metal/Sulfide/Thiolate Chemistry for an Early 3d Transition Metal: Variation of Product Identity as a Function of V:S Reaction Ratio and Structure and Redox Properties of Discrete V/S/edt Complexes.
Authors: MONEY J. K. , HUFFMAN J. C. , CHRISTOU G. 
Published: May 2016

AbstractThe reactions in the VCl3/elemental S/disodium ethanedithiolate systems in MeCN are described.
ChemInform Abstract: Redox Properties of Aquo Complexes of Ruthenium(II) Containing the Tridentate Ligands 2,2′:6′,2′′‐Terpyridine and Tris(1‐pyrazolyl)methane.
Authors: LLOBET A. , DOPPELT P. , MEYER T. J. 
Published: May 2016

AbstractA series of complexes containing either the facial tridentately coordinating ligand (VII) or the meridional tridentately coordinating ligand terpyridine are prepared.
ChemInform Abstract: Novel Mitomycin C Amidines: Synthesis and Their Reactions with Amines.
Authors: VYAS D. M. , CHIANG Y. , BENIGNI D. , DOYLE T. W. 
Published: May 2016

AbstractMitomycin C (I) reacts with dimethylformamide dimethyl acetal (II) to produce either the monoamidine (III) or the bisamidines (IVa) and (IVb).
ChemInform Abstract: Crystal Structures of Three Phases of Tetramethylammonium Trichlorocuprate(II).
Authors: WILLETT R. D. , BOND M. R. , HAIJE W. G. , SOONIEUS O. P. M. , MAASKANT W. J. A. 
Published: May 2016

AbstractDSC studies indicate phase transitions of the title compound at 319 and 373 K. The structures of the three corresponding phases are deformed members of the hexagonal perovskite family (2L).
ChemInform Abstract: High‐Resolution 29Si NMR in the Y‐Si‐O‐N System
Authors: DUPREE R. , LEWIS M. H. , SMITH M. E. 
Published: May 2016

Abstractis used to determine the 29Si chemical shifts for the complete range of mixed tetrahedral coordinations SiOxN4‐x (0 ≤ x ≤ 4).
ChemInform Abstract: Equilibrium Isotope Effects on the Hydration of Gas‐Phase Ions. The Effect of Hydrogen Bond Formation on Deuterium Isotopic Fractionation Factors for H3O+, H5O+ 2, F(H2O)‐, and Cl(H2O)‐.
Authors: LARSON J. W. , MCMAHON T. B. 
Published: May 2016

AbstractThe equilibrium constants for isotope exchange reactions between gaseous water molecules and L3O+, L5O2+, (L2O)F‐, and (L2O)Cl‐ (L: H, D) are determined by ion cyclotron resonance experiments (both conventional drift and pulsed modes).
ChemInform Abstract: Synthesis and Characterization of a New Double Perovskite: LaCaMnCoO6.
Authors: VALLET‐REGI M. , GARCIA E. , GONZALEZ‐CALBET J. M. 
Published: May 2016

AbstractThe new mixed title oxide is prepared by the so‐called "liquid mix" technique starting from stoichiometric amounts of La(NO3)3, Co(NO3)2, MnCO3, and CaCO3 (solvent: citric acid; precipitation by the aid of glycol; 723 K, 16 h; 823 K in air).
ChemInform Abstract: Preparation of Pd(S2N2H)(Br)(PMe2Ph) via a Facile Bromine‐Phosphine Exchange Reaction.
Authors: KELLY P. F. , WOOLLINS J. D. 
Published: May 2016

AbstractOrange crystals of the title compound (IV) are obtained by reaction of (I) and (II) which involves proton transfer and halogen‐phosphine exchange (yield not given).
ChemInform Abstract: UV Spectral Study of Ion‐Ligand Interactions: Alkali and Alkaline Earth Cation Binding to N‐Methyl‐8‐quinolone.
Authors: CIGNITTI M. , SOCCORSI L. 
Published: May 2016

AbstractThe electronic absorption spectra of the title ligand in acetonitrile and in acetonitrile containing Li and Mg ions provide evidence for the base‐hard acids interaction.
ChemInform Abstract: A Highly Efficient Synthesis of Optically Pure γ‐Iodo Allylic Alcohols and Their Conversion into Various Optically Active Allylic Alcohols.
Authors: KITANO Y. , MATSUMOTO T. , WAKASA T. , OKAMOTO S. , SHIMAZAKI T. , KOBAYASHI Y. , SATO F. , MIYAJI K. , ARAI K. 
Published: May 2016

AbstractThe γ‐iodo allylic alcohols (IVa) ‐ (IVd) are obtained by insertion of acetylene (II) into the acyl chlorides (I), followed by iodination and reduction.
ChemInform Abstract: Mild and Efficient Method for the Preparation of N‐Tosyl Amides and Lactams.
Authors: TANNER D. , SOMFAI P. 
Published: May 2016

AbstractThe amides (III) and (V) can be prepared easily and under mild conditions from the components (I) + (II) or (IV) + (II), resp.; similarly, the lactams (VII), (IX), or (XI) are obtained by intramolecular condensations.
ChemInform Abstract: Novel Photoisomerization of 9‐tert.‐Butyl‐10‐cyanoanthracene (II) Involving 1,2‐Transfer of Methyl Group.
Authors: MENG J. , YAO X. , WING H. , MATSUURA T. , ITO Y. 
Published: May 2016

AbstractTitle compound (II) (photoinert in the solid state) when irradiated in MeCN under N2 gives the dibenzonorbornadiene (I) (space group P21/n with Z=4).
ChemInform Abstract: Reduction of Organic Compounds with Rare‐Earth Intermetallics Containing Absorbed Hydrogen.
Authors: IMAMOTO T. , MITA T. , YOKOYAMA M. 
Published: May 2016

AbstractThe alkenes (I) and (III), the acetylenes (VI), and the carbonyl compounds (VIII) are hydrogenated with the intermetallic hydride LaNi5H6 to yield the saturated hydrocarbons (II) and (VII), the partly hydrogenated derivative (IV), or the alcohols (IX).
ChemInform Abstract: Aerosol Direct Fluorination: Orthoesters, Syntheses of Perfluoromethyl Orthocarbonate, and Perfluoroethylene Orthocarbonate.
Authors: ADCOCK J. L. , ROBIN M. L. , ZUBERI S. 
Published: May 2016

AbstractDirect fluorination of tetramethyl orthocarbonate (I) with an F2‐helium aerosol yields the corresponding perfluorinated orthocarbonate (II) and perfluorotrimethyl orthoformate (III) as the isolated products.
ChemInform Abstract: Lactols in Stereoselection. Part 2. Stereoselective Synthesis of Disubstituted Cyclic Ethers.
Authors: TOMOOKA K. , MATSUZAWA K. , SUZUKI K. , TSUCHIHASHI G. 
Published: May 2016

AbstractThe lactols (I) are alkylated with the organometallic compounds (II) in the presence of boron trifluoride etherate, yielding the tetrahydrofurans and pyrans (III) with strong predominance of the trans‐substituted isomers.
ChemInform Abstract: Asymmetric Conjugate Addition of Zincates or Cuprates Containing an Optically Active Azaenolate of erythro‐Isopropylidene‐2‐methoxy‐1,2‐diphenylamine to 2‐Cycloalkenones.
Authors: YAMAMOTO K. , KANOH M. , YAMAMOTO N. , TSUJI J. 
Published: May 2016

AbstractThe lithium azaenolates (III), generated from the chiral imines (I), are converted to the cuprates (V) or zincates (VII).
ChemInform Abstract: Zinc ‐ Copper(I) Chloride or ‐ Silver(I) Acetate Promoted Aldol Reaction of Chlorodifluoromethyl Ketones with Carbonyl Compounds. A General and Effective Route to α,α‐Difluoro β‐Hydroxy Ketones.
Authors: KUROBOSHI M. , ISHIHARA T. 
Published: May 2016

AbstractCoupling of the aldehydes (I) with the chlorodifluoromethyl ketones (II) in the presence of zinc and copper(I) chloride yields the β‐hydroxy α,α‐difluoro ketones (III).
ChemInform Abstract: Observation of a Competitive Path in the Nucleophilic Addition of Fluoroolefins: The Bromophilic Reaction of the Adduct Carbanion Intermediate.
Authors: JIANG X.‐K. , JI G.‐Z. , SHI Y.‐Q. 
Published: May 2016

AbstractReaction of the alkoxides (I) with bromotrifluoroethene (II) results in the formation of the adducts (III) and the enol ethers (IV), together with the dibromotrifluoroethyl ethers (V) and traces of trifluoroethene (VI).
ChemInform Abstract: The Pyrolysis of 3‐Oxa‐11‐chloroeicosafluoroundecanesulfinate and ‐sulfonate Salts.
Authors: HU C. , DU X. , ZHOU H. , XU Z. , HUANG W. 
Published: May 2016

AbstractPyrolysis of the sulfinate (I) and subsequent treatment with methanol (II) yield a mixture of the products (III) ‐ (VII), whereas analogous conversion of the potassium sulfonate (VIII) results in the formation of 8‐chlorotetradecafluorooctanoate (IV) as the only product.
ChemInform Abstract: A Convenient Synthesis of Ethyl 3,3,3‐Trifluoropropanoate and Its 2‐Bromo Derivative.
Authors: MOLINES H. , WAKSELMAN C. 
Published: May 2016

AbstractStarting with the bromodifluorohalomethanes (Ia) or (Ib), the ethyl 3,3,3‐trifluoropropanoate (VII) and the corresponding α‐brominated ester (IX) are synthesized as outlined in the reaction scheme.
ChemInform Abstract: Synthesis and Carbene Decomposition of Functionally Substituted Diazoacetic acid Esters. Part 5. 2‐Butylthioethyl Diazoacetate.
Authors: SHAPIRO E. A. , ROMANOVA T. N. , DOLGII I. E. , NEFEDOV O. M. 
Published: May 2016

AbstractGlycine 2‐butylthioethyl ester, prepared in situ from glycine (I) and 2‐butylthioethanol (II), is diazotized to give the title compound (IV).
ChemInform Abstract: Synthesis, Characterization and Complexation Studies with K+ and Ca2+ Cations of trans‐1,2‐Cyclohexanedioxydiacetamides.
Authors: LIN W. O. , DE SOUZA M. C. B. V. , ALT H. G. 
Published: May 2016

AbstractThe title amides (IVa)‐(IVc) form 2:1 complexes with K+ and Ca2+ ions.
ChemInform Abstract: Fluorination of Pentacyclo(5.4.0.02,6.03,10.05,9)undecane‐8,11‐dione by Sulfur Tetrafluoride.
Authors: ALEKSANDROV A. M. , SOROCHINSKII A. E. , PETRENKO A. E. , KUKHAR' V. P. 
Published: May 2016

AbstractThe reaction of the title compound (I) with SF4 may afford the difluoro derivative (II) or the tetrafluoro derivative (III), depending on the molar ratio chosen for (I)/SF4 and on the reaction conditions.
ChemInform Abstract: Condensation Reaction of Aryl Bromides with Styrenes Catalyzed by Nickel Complexes in the Presence of Zinc.
Authors: LEBEDEV S. A. , LOPATINA V. S. , SOROKINA R. S. , BERESTOVA S. S. , PETROV E. S. , BELETSKAYA I. P. 
Published: May 2016

AbstractThe nickel‐catalyzed reaction of the aryl bromides (I) or (IV) with the styrenes (II) in the presence of elemental zinc gives the E‐stilbene derivatives (III) and (V) respectively.
ChemInform Abstract: (Trihalogenomethyl)carbinols. Part 3. Reaction of Aryl(trichloromethyl)carbinols with Cyanoacetic Ester.
Authors: GUKASYAN A. O. , GALSTYAN L. KH. , KHANAMIRYAN A. KH. , AVETISYAN A. A. 
Published: May 2016

AbstractThe reaction between the title compounds (I) and (II) in the system KOH/DMF affords the unstable adducts (III), which are characterized by 1H NMR and IR spectral data.
ChemInform Abstract: The Preparation of Anthraquinones and Anthracyclinones via the Reaction of Haloarenes and Cyanophthalides Under Aryne‐Forming Conditions.
Authors: KHANAPURE S. P. , REDDY R. T. , BIEHL E. R. 
Published: May 2016

AbstractBase‐induced coupling of the cyanophthalide (Ia) with the o‐bromoanisoles (II) yields the anthraquinone derivatives (III) via aryne intermediates, generated by dehydrohalogenation of (II).
ChemInform Abstract: Polyhaloaromatics. Part 1. 4,5,6,7‐Tetrachloro‐1,1,3,3‐tetrafluoro‐1,3‐dihydroisobenzofuran and Related Compounds from the Reaction of Tetrachlorophthalic Anhydride with Sulfur Tetrafluoride.
Authors: DMOWSKI W. , WIELGAT J. 
Published: May 2016

AbstractFluorination of tetrachlorophthalic anhydride (I) or tetrachlorophthalic acid hemihydrate (IV) with excess SF4 yields the dihydroisobenzofuran derivative (II), together with the benzoyl fluoride (III).
ChemInform Abstract: Synthesis and Molecular Structure of 6H‐Anthra(9,1‐cd)isothiazol‐6‐one Derivatives.
Authors: GORELIK M. V. , ALIMOVA R. A. , TAFEENKO V. A. , MEDVEDEV S. V. , SHTEINMAN V. YA. 
Published: May 2016

AbstractThe title compounds (III), (IV) and (V) are prepared for the first time.
ChemInform Abstract: Synthesis and Reactivity of 2‐(1′,3′‐Dithian‐2′‐yl)indoles.
Authors: RUBIRALTA M. , CASAMITJANA N. , GRIERSON D. S. , HUSSON H.‐P. 
Published: May 2016

AbstractThe title compounds (IIIa) and (IIIb) are prepared from the reaction of the anions derived from (I) with the chlorodithiane (II).
ChemInform Abstract: Reaction of the 8‐Bromo‐3‐methylxanthine Potassium Salt with Dihaloalkanes.
Authors: ROMANENKO N. I. , FEDULOVA I. V. , PRIIMENKO B. A. , CHERVINSKII A. YU. 
Published: May 2016

AbstractCoupling of the xanthine potassium salt (I) with the haloalkanes (II) gives the xanthin‐7‐yl derivatives (III), (IV), or (VI) depending on the molar ratio.
ChemInform Abstract: Studies on Prodrugs. Part 7. Synthesis and Antimicrobial Activity of 3‐Formylquinolone Derivatives.
Authors: KONDO H. , SAKAMOTO F. , KAWAKAMI K. , TSUKAMOTO G. 
Published: May 2016

AbstractThe aminoquinolonecarboxylic acids (I) undergo reductive decarboxylation, yielding (II), followed by formylation with ethyl formate (III) and oxidation to give the bisformyl compounds (V).
ChemInform Abstract: Chemistry of O‐Silylated Ketene Acetals: An Efficient Synthesis of α‐Thio‐N‐Heterocycles from ω‐Amido Sulfoxides by a Novel Intramolecular Pummerer‐Type Rearrangement.
Authors: KITA Y. , TAMURA O. , MIKI T. , TAMURA Y. 
Published: May 2016

AbstractThe 2‐(methylsulfinyl)benzamide (I) is cyclized in the presence of a O‐silyl ketene acetal and zinc iodide to produce the thiazinone derivative (II).
ChemInform Abstract: Iminophosphorane‐Mediated Transformation of Tertiary Alcohols into tert‐Alkylamines and Their N‐Phosphorylated Derivatives.
Authors: KOZIARA A. , ZWIERZAK A. 
Published: May 2016

AbstractThe tertiary alcohols (I) are converted to the azides (III) which react with triethyl phosphite (IV) to give the iminophosphoranes (V).
ChemInform Abstract: Unusually Coordinated Phosphorus Compounds. Part 24. Methylidynephosphane (HCP), a Novel Partner for 1,3‐Dipolar Cycloaddition Reactions.
Authors: FUCHS E. P. O. , HERMESDORF M. , SCHNURR W. , ROESCH W. + , HEYDT H. , REGITZ M. , BINGER P. 
Published: May 2016

AbstractFlash vacuum thermolysis of the phosphaalkyne (I) or pyrolytic dehydrochlorination of dichloro(methyl)phosphane (III) yields the unstable title compound (II) which is trapped by cycloaddition reaction with the diazoacetate (IVb), methyl azide (VII), benzonitrile oxide (IX), or the munchnone (XI), producing phosphorus‐containing five‐ring heterocycles.
ChemInform Abstract: Interconversions of Titanocene‐Methylene Complexes.
Authors: VAN DE HEISTEEG B. J. J. , SCHAT G. , AKKERMAN O. S. , BICKELHAUPT F. 
Published: May 2016

AbstractTitanocene dichloride (I) and the bis‐Grignard compound (II) form the bicyclic dititanium magnesium derivative (V) via the intermediate (III).
ChemInform Abstract: Structural Evidence for Non‐Reactivity Towards Dehydrohalogenation in a Bis‐t‐butylamine‐t‐butylimido Complex of Tungsten(V). The Preparation and X‐Ray Crystal Structure of (W(NCMe3)Cl3(NH2CMe3)2).
Authors: CLARK G. R. , NIELSON A. J. , RICKARD C. E. F. 
Published: May 2016

AbstractThe title complex (III) is prepared as shown in low yield (no data given) and characterized by the IR spectrum and a single‐crystal X‐ray analysis (space group C2/c; Z=4).
ChemInform Abstract: Two Reactions of (Re2Cl8)2‐ with Diphosphines that Lead to Re‐Re Bond Cleavage.
Authors: COTTON F. A. , DANIELS L. M. 
Published: May 2016

AbstractThe reactions of (I) with (II) were carried out in order to obtain products of the type Re2Cl6L2 (L: diphosphine).
ChemInform Abstract: Ferriodithiocarboxylic Acid.
Authors: MAYR A. , STOLZENBERG H. , FEHLHAMMER W. P. 
Published: May 2016

AbstractThe first complexes containing the dithiocarboxylic ligand in (η1)‐terminal and bridging positions are synthesized: reaction of the iron complex (I) with CS2 (II) yields the dithiocarboxylic acid complex (III).
ChemInform Abstract: Mixed‐Ligand Schiff Base Cobalt(III) Complexes with Phenolaldehydes or Phenolketones as Ligands.
Authors: FUKUHARA C. , MATSUDA S. , KATSURA K. , MORI M. , MATSUMOTO K. , OOI S. , YOSHIKAWA Y. 
Published: May 2016

AbstractThe reaction of the Schiff base complexes (I) with an additional ligand (II) in MeOH at room temp. or at 55 °C gives dependent on the stability the title complexes (III) and/or (IV).
ChemInform Abstract: Perthiocarboxylate Complex. Synthesis, Structure and Spectroscopic Characterization of the Tetrameric Copper(I) o‐Tolylperthiocarboxylate, (Cu(S)SSCC7H7)4.
Authors: MANOTTI LANFREDI A. M. , TIRIPICCHIO A. , MARSICH N. , CAMUS A. 
Published: May 2016

AbstractThe title complex (III) is prepared by different methods.
ChemInform Abstract: Syntheses and Structure of Re(NAuCl)Cl2(PMe2Ph)3, a Complex with a Nitrido Bridge Between Rhenium(V) and Gold(I).
Authors: BEUTER G. , ENGLERT U. , STRAEHLE J. + 
Published: May 2016

AbstractThe Re atom of the title complex (III) (space group P21/c with Z=4) is pseudo‐octahedrally coordinated.
ChemInform Abstract: A Convenient Method for the Preparation of Antitumor Carboxylato(1,2‐diaminocyclohexane)platinum(II) Complexes.
Authors: KHOKHAR A. R. , LUMETTA G. , DORAN S. L. 
Published: May 2016

AbstractThe carbonato‐Pt(II) complex (III) obtained as shown reacts with monocarboxylic or dicarboxylic acids e.g. (IV) to form carboxylato(1,2‐diaminocyclohexane)‐Pt(II) complexes such as (V).
ChemInform Abstract: Substituted Catecholato(1,2‐diaminocyclohexane)platinum(II) Compounds.
Authors: HOWELL B. A. , RASHIDIANFAR R. , GLASS J. R. , HUTCHINSON B. J. , JOHNSON D. A. 
Published: May 2016

AbstractThe title compounds (VI) are prepared from the appropriate ligands (V) (synthesis described) and (IIIb).
ChemInform Abstract: Synthesis and Properties of Nα‐Di‐tert‐butoxycarbonyl and Nα‐Benzyloxycarbonyl‐tert‐butoxycarbonyl Amino Acids.
Authors: GUNNARSSON K. , GREHN L. , RAGNARSSON U. 
Published: May 2016

AbstractThe title amino acids (III), (V), (VII) with a bis‐protected N‐terminus are prepared by the three methods outlined in the scheme starting from benzyl‐(I), 9‐fluorenylmethyl‐(IV) or allyl esters (VI).
ChemInform Abstract: Synthesis and Biological Properties of α‐Mono‐ and α‐Difluoromethyl Derivatives of Tryptophan and 5‐Hydroxytryptophan.
Authors: SCHIRLIN D. , GERHART F. , HORNSPERGER J. M. , HAMON M. , WAGNER J. , JUNG M. J. 
Published: May 2016

AbstractFischer synthesis, performed with the N‐protected amino aldehydes (I), yields the indoles (III).
ChemInform Abstract: Synthesis of 6‐(Z‐2,7‐Octadienyl)‐α‐D‐galactopyranose.
Authors: ZAKHARKIN L. I. , GUSEVA V. V. , SULAIMANKULOVA D. D. , KORNEVA G. M. 
Published: May 2016

AbstractThe preparation of the title compound (IV) is reported.
ChemInform Abstract: The 3,4‐Dimethoxybenzyl Group: A Protective Group for New 2‐Iminoimidazolidine Derivatives.
Authors: HUBER D. , LECLERC G. , EHRHARDT J. D. , ANDERMANN G. 
Published: May 2016

AbstractThe O‐protected diamino alcohol (II) reacts with 3,4‐dimethoxybenzaldehyde (I) to form the bisimine (III) which is reductively transformed into the di(benzylamino) derivative (IV).
ChemInform Abstract: Methyl 5‐O‐tert‐Butyldiphenylsilyl‐2‐deoxy‐α,β‐D‐threo‐pentofuranoside as a Divergent Intermediate for the Synthesis of 3′‐Substituted‐2′,3′‐dideoxynucleosides: Synthesis of 3′‐Azido‐3′‐deoxythymidine, 3′‐Deoxy‐3′‐fluorothymidine and 3′‐Cyano‐3′‐deoxythymidine.
Authors: FLEET G. W. J. , SON J. C. , DEROME A. E. 
Published: May 2016

AbstractSyntheses of the nucleosides (XV), relevant compounds in the field of chemotherapeutical treatment of AIDS, and its α‐anomers (XVI) are described.
ChemInform Abstract: Ozonolysis of Alkenes and a Study of the Reactions of Polyfunctional Compounds. Part 33. Synthesis of (Z)‐7‐Oxo‐10‐hexadecen‐1‐ol and Its nor Analogue.
Authors: ODINOKOV V. N. , BOTSMAN L. P. , NAGAEVA N. A. , TOLSTIKOV G. A. 
Published: May 2016

AbstractThe syntheses of the title compound (VIIIb) and of its nor analogue (VIIIa) are described.
ChemInform Abstract: Diastereoselective Synthesis of a Component of the Sexual Pheromone from the “Californian Red Scale Insect” (Aonidiella aurantii): (3S,6R)‐6‐Isopropenyl‐3‐methyl‐9‐decenyl Acetate.
Authors: BAUDOUY R. , MALIVERNEY C. 
Published: May 2016

AbstractThe title pheromone (IV) is prepared with 96% optical purity from the silyl enol ether (I) of (‐)‐dihydrocarvone; the key step being the regioselective ozonolysis of (I), which preserves both chiral centers.
ChemInform Abstract: Characterization of Hydrous Species in Minerals by High‐Speed 1H MAS‐NMR.
Authors: YESINOWSKI J. P. , ECKERT H. , ROSSMAN G. R. 
Published: May 2016

Abstract20 different hydrogen‐bearing minerals are characterized by 1H MAS NMR at 200 and 500 MHz and at high spinning speeds of up to 8.8 kHz.
ChemInform Abstract: New A0.50A′0.50F3 Ferroelastic Phases with VF3 Structure (A, A′ : Al, Ti, Cr, In, Tl).
Authors: GUELIN J. , YACOUBI A. , RAVEZ J. , GRANNEC J. 
Published: May 2016

AbstractA reversible rhombohedral‐cubic transition is detected for InF3 and some of the title phases by micro‐DTA, microcalorimetry, and XRD.
ChemInform Abstract: Kinetics and Mechanism of Decomposition of Hydrogen Peroxide Catalyzed by Co2+ Adsorbed on Alumina.
Authors: TIWARI S. K. , SINGH R. N. 
Published: May 2016

AbstractDecomposition of H2O2 in the presence of Co2+ adsorbed on alumina shows nearly first order dependence in (H2O2).
ChemInform Abstract: The First Oxocobaltates(II) with Dinuclear Anion, Rb2Na4(Co2O5) and K2Na4(Co2O5),
Authors: HOPPE R. , BIRX J. 
Published: May 2016

Abstractare prepared by annealing intimate mixtures of Rb2O(K2O), Na2O, and "CoO" (1:2:1; Ag tube; 600 °C, 14 d).
ChemInform Abstract: Cyclopentadienyl Iron Xanthate Complexes. Crystal and Molecular Structure and Electrochemical Reduction of η‐C5R5Fe(CO)2(η1‐SC(S)OEt) (R: H or CH3).
Authors: MORAN M. , CUADRADO I. , MASAGUER J. R. , LOSADA J. , FOCES‐FOCES C. , CANO F. H. 
Published: May 2016

AbstractIn order to analyze the influence of the electronic factors on the structure and reactivity of the title compounds (I) their crystal structures are determined ((Ia): P212121, Z=4; (Ib): Pbca, Z = 8).
ChemInform Abstract: Nucleophilic Attacks on Carbon‐Carbon Double Bonds. Part 36. Stereochemistry of Substitution of Good Nucleofuges at the Stereoconvergence Region as a Tool for Investigating the Rapid Step of Nucleophilic Vinylic Substitution.
Authors: AVRAMOVITCH B. , RAPPOPORT Z. 
Published: May 2016

AbstractFive nitrocinnamates are prepared and separated into their (E)‐isomers (Ia)‐(Ic) and (Z)‐isomers (IIa).