bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Single‐Crystal X‐Ray Structure of the High‐Temperature Superconductor Ba2YCu3O7‐x.
Authors: GARBAUSKAS M. F. , ARENDT R. H. , KASPER J. S. 
Published: May 2016

AbstractThe title material, which becomes superconducting at temp. < 90 K, crystallizes in the orthorhombic system, space group Pmmm, Z=1.
ChemInform Abstract: Dependence of Film Thickness on Electrochemical Kinetics of Polypyrrole and on Properties of Lithium/Polypyrrole Battery.
Authors: OSAKA T. , NAOI K. , OGANO S. , NAKAMURA S. 
Published: May 2016

AbstractThe charging‐discharging behavior of a Li/LiClO4/polypyrrole battery has been investigated as a function of the thickness of the polypyrrole film cathode and its formation potential.
ChemInform Abstract: Catalytic Oxidation of CO on Co3O4 Supported on γ‐Al2O3.
Authors: EL‐SHOBAKY G. A. , FAGAL G. A. , SABER T. M. H. 
Published: May 2016

AbstractThe influence of Co3O4 content and calcination temp. on the catalytic activity of Co3O4/Al2O3 has been studied.
ChemInform Abstract: Interactions in the System CaSe‐In2Se3.
Authors: GULIEV T. N. , RUSTAMOV P. G. , YAGUBOV N. I. 
Published: May 2016

AbstractMixtures of CaSe and In2Se3 are heated to 1000 K for 4 h and then left at 850 K for 500 h. The formation of the compounds CaIn2Se4 (I) and CaIn4Se7 (II) is observed.
ChemInform Abstract: Kinetic Determination of Selectivity Constants of Anion Extraction in Phase‐Transfer Catalytic Systems.
Authors: DE LA ZERDA J. , SASSON Y. 
Published: May 2016

AbstractA kinetic method is developed based on the study of the poisoning effect in the isomerization of (I) in the presence of catalytic amounts of added Na salts or of alkoxides formed in situ in the presence of alcohols such as (III).
ChemInform Abstract: Complex‐Induced Proximity Effects: Remote Lithiations of Carboxamides.
Authors: BEAK P. , HUNTER J. E. , JUN Y. M. , WALLIN A. P. 
Published: May 2016

AbstractThe reactions of the unsaturated amide (Ia) (= condition B)) provides the Li intermediate (III) which reacts with various electrophiles such as (IIa)‐(IId) or (VIa), (VIb) to give the products (V) and/or (IV), or (VIII), respectively.
ChemInform Abstract: Regioselective Deoxygenation of Chloramphenicol and of (1R,2R)‐(+)‐2Amino‐1‐phenyl‐1,3‐propanediol.
Authors: RAMAIAH P. , RAO A. S. 
Published: May 2016

AbstractThe N‐acylamino diol (Ia) reacts with 2‐acetoxybenzoyl chloride (II) to form the 1‐chloro‐3‐acetoxy derivative (IIIa).
ChemInform Abstract: Bi(3,5‐dimethyl‐5‐(hydroxymethyl)‐2‐oxomorpholin‐3‐yl) (DHM‐3 Dimer). A Water‐Soluble, One‐Electron Reducing Agent.
Authors: GAUDIANO G. , KOCH T. H. 
Published: May 2016

AbstractThe dimer (IV) mentioned in the title is prepared by irradiation of the dihydrooxazinone (III), obtained by cyclocondensation of the diol (I) with the ester (II).
ChemInform Abstract: Asymmetric Hydrogenation of Unsaturated Carboxylic Acids Catalyzed by BINAP‐Ruthenium(II) Complexes.
Authors: OHTA T. , TAKAYA H. , KITAMURA M. , NAGAI K. , NOYORI R. 
Published: May 2016

AbstractThe α,β‐unsaturated carboxylic acids (I) are hydrogenated in the presence of a chiral ruthenium catalyst, yielding the optically active saturated acids (II).
ChemInform Abstract: Selective Reactions of Isocyanatocarboxylic Chlorides with Silylated Alcohols and Amines: A Simple Synthesis of Isocyanatocarboxylic Acid Esters and Amides.
Authors: MORMANN W. , HISSMANN E. 
Published: May 2016

AbstractThe trimethylsilyl ethers (III), prepared from the alcohols (I), react with the isocyanates (IV) to give the isocyanato esters (V).
ChemInform Abstract: Selective Liquid‐Phase Hydrogenation of 2,6‐Dinitrotoluene with Platinum Catalysts.
Authors: KUT O. M. , YUECELEN F. + , GUT G. 
Published: May 2016

AbstractAn ethanolic solution of 2,6‐dinitrotoluene (I) is hydrogenated in the presence of commercial powder catalysts, such as Pt or Pd on C, or Pt on Al2O3.
ChemInform Abstract: A One‐Step Preparation of 4‐Bromomethyl‐2,3,5,6‐tetrabromophenol.
Authors: GUO W. , WU G. 
Published: May 2016

AbstractHeating p‐cresol (I) with excess bromine in the presence of aluminum trichloride yields 4‐bromomethyl‐2,3,5,6‐tetrabromophenol (II) which is a starting material for the preparation of several flame retardants.
ChemInform Abstract: Three New Products from Methyl 3,4‐Diphenyl‐5‐nitro‐2‐furoate by Catalytic Reduction.
Authors: YAMAMOTO K. , TANAKA A. , ICHIKAWA M. , SWAMINATHAN S. , BRYAN G. T. 
Published: May 2016

AbstractThe diphenylnitrofuroate (I) is subjected to catalytic hydrogenation, yielding the hydroxylaminofuroate (II) as the main product, together with the aminofuroate (III) and minor amounts of the cyanobutyrate (IV).
ChemInform Abstract: Remote Electronic Control in the LiAlH4 Reduction of Tricyclic p‐Tolylsulfonylmethyl Enones.
Authors: KLUNDER A. J. H. , CRUL M. J. F. M. , HOUWEN‐CLAASSEN A. A. M. , KOOY M. G. , ZWANENBURG B. 
Published: May 2016

AbstractThe bicyclic sulfone (I) is reduced with lithium alanate or diisobutylaluminum hydride to give the olefin (II) or the alcohol (III).
ChemInform Abstract: Synthesis and Separation of Diastereomeric Imino Alcohol Derivatives of Chiral Phthalides: A Method for Assignment of Phthalide Absolute Configurations.
Authors: PIRKLE W. H. , SOWIN T. J. 
Published: May 2016

AbstractThe racemic lactones (I) are sulfurized with Lawesson's reagent to form the thio derivatives (II).
ChemInform Abstract: Highly Stereoselective Reactions of Carbanions of Dithiabicyclo(3.1.0)hexane Derivatives.
Authors: OKAZAKI R. , O‐OKA M. , AKIYAMA T. , INAMOTO N. , NIWA J. , KATO S. 
Published: May 2016

AbstractThe heterobicylic compounds (Va) and (Vb) are prepared from the cyclopropane (I) as shown in the scheme; the deuterated analogue (Vd) of the known tricyclus (Vc) is prepared analogously.
ChemInform Abstract: Heterocycles. Part 60. Condensation of 5‐Phenyl‐1,2,4‐triazole‐3‐thiol with Monochloroacetaldehyde.
Authors: SIMITI I. , MARIE A. , COMAN M. , POP R. D. , DEMIAN H. , MAGER S. 
Published: May 2016

AbstractThe triazolylthione (I) reacts with chloroacetaldehyde (II) to give (III) which cyclizes reversibly, forming the tetrahydrotriazolothiazole (IV).
ChemInform Abstract: Asymmetric Functionalization at a Prochiral Carbon Center by the Aid of Sulfinyl Chirality: A Selective Formation of 6‐Substituted (3R,Ss)and (3S,Ss)‐3‐Hydroxymethyl‐3,4‐dihydro‐5‐(p‐tolyl)sulfinyl‐2H‐pyrans.
Authors: IWATA C. , FUJITA M. , MORITANI Y. , SUGIYAMA K. , HATTORI K. , IMANISHI T. 
Published: May 2016

AbstractThe iodomethyl‐1,3‐dioxane (IV) and the chiral sulfones (VII), prepared as shown in the reaction scheme, are coupled and then cyclized to form the bicyclic sulfinyldioxanes (IX).
ChemInform Abstract: Phenyl Isothiocyanate‐Mediated Condensation of Aceturic/2‐Acetylaminocinnamic Acid with Aromatic Aldehydes.
Authors: JAIN A. , MUKERJEE A. K. 
Published: May 2016

AbstractThe benzaldehydes (I) undergo ring‐closure with 2‐(acetylamino)cinnamanilide (II) to give the 2‐styryl‐2‐imidazolin‐5‐ones (III) which are also prepared by reaction of 2‐(acetylamino)cinnamic acid (IX) with the aromatic aldehydes (I) and phenyl isothiocyanate (V).
ChemInform Abstract: Synthesis of New Benzofuranylpyridine and Benzofuranylpyrano(2,3‐c)pyrazole Derivatives.
Authors: HISHMAT O. H. , ABDEL GALIL F. M. , FARRAG D. S. 
Published: May 2016

AbstractThe benzofuranylmethylidenemalononitriles (Ia) and (Ib) react with the carbonyl compounds (II) under cyclization, producing the pyridine derivatives (III), (IV), or (V).
ChemInform Abstract: Synthesis of Indolizines Starting from Pyrylium Salts.
Authors: DINCULESCU A. , BALABAN T.‐S. , BALABAN A. T. 
Published: May 2016

AbstractTrimethylpyrylium perchlorate (I) and the acetals (II) of aminoacetaldehyde produce the pyridinium salts (III) and (IVa).
ChemInform Abstract: Synthesis and Spectroscopic Investigations of 1,4‐Benzothiazepine Derivatives.
Authors: SZABO J. , BERNATH G. , KATOCS A. , FODOR L. , SOHAR P. 
Published: May 2016

AbstractThe sodium thiophenolate (I) reacts with 2‐bromoethylamine (II) to yield (III) which is acylated and then cyclized, forming the benzothiazepine derivatives (VI).
ChemInform Abstract: Convenient Preparation of Acyltrimethylsilanes from Carboxylic Acid Derivatives.
Authors: KANG J. , LEE J. H. , KIM K. S. , JEONG J. U. , PYUN C. 
Published: May 2016

AbstractThe acyl chlorides and anhydrides (II) react with the lithium tetrasilylaluminate (Ia) in the presence of copper(I) cyanide to produce the trimethylsilyl ketones (III).
ChemInform Abstract: Silicon Compounds and Its Homologues. Part 77. Unsaturated Silicon Compounds. Part 25. Reactivity of the Labile Silaethene Me2Si=C(SiMe3)2, Stored as Ph2C=NSiMe3 Adducts.
Authors: WIBERG N. , PREINER G. , WAGNER G. , KOEPF H. + 
Published: May 2016

AbstractThe silaethene (II), stored as the Ph2C=N(SiMe3) adduct (I) and regenerated from this at about 100 °C as a reaction intermediate, combines with a lot of reactants.
ChemInform Abstract: Pentaalkoxyphosphoranes in the Reaction of Alkylene (1,1,3‐Trihydroperfluoropropyl) Phosphites with Chloral and Bromal.
Authors: KONOVALOVA I. V. , OFITSEROV E. N. , SINYASHINA T. N. , MIRONOV V. F. , PUDOVIK A. N. 
Published: May 2016

AbstractThe cyclic phosphites (III), prepared from the chlorophosphites (I) and the tetrafluoropropanol (II), are coupled with the trihaloacetaldehydes (IV) to give mixtures of the spirophosphoranes (V) and (VI).
ChemInform Abstract: Complexes of Copper(II) with Substituted Benzylideneamines.
Authors: NAVARRO‐RANNINGER M. C. , ALVAREZ‐VALDES A. , CAMAZON M. J. , MASAGUER J. R. 
Published: May 2016

AbstractCuCl2 reacts with the ligands in 1,2‐dichloroethane to yield the complexes (I) (no yields given).
ChemInform Abstract: Preparation of Two New Bis(2‐pyridyl)silane Ligands and the Copolymerization of MeSi(2‐pyridyl)2(CH=CH2) with Styrene and Divinylbenzene.
Authors: WRIGHT M. E. 
Published: May 2016

Abstract2‐Lithiopyridine (II), generated in situ from 2‐bromopyridine (I), is coupled with the dichlorosilanes (III) to give the bis(2‐pyridyl)silanes (IV).
ChemInform Abstract: Synthesis and NMR Spectra of Platinum Compounds with Thiourea Derivatives.
Authors: ROCHON F. D. , BARIYANGA J. , DE LA CHEVROTIERE C. 
Published: May 2016

AbstractThe thiourea‐Pt(II) complexes (III) are prepared as shown and characterized by IR, 1H and 13C NMR spectra.
ChemInform Abstract: Liquid Secondary Ionization Mass Spectrometric Characterization of Two Synthetic Phosphotyrosine‐Containing Peptides.
Authors: GIBSON B. W. , FALICK A. M. , BURLINGAME A. L. , NADASDI L. , NGUYEN ANN CAC NGUYEN ANN CAC , KENYON G. L. 
Published: May 2016

AbstractWith the use of the protected amino acid (IV) the title peptides (V) and (VI) are prepared via solid‐phase synthesis and characterized by LSIMS.
ChemInform Abstract: Synthesis of Oligosaccharide Structures Unique to Pituitary Glycoprotein Hormones.
Authors: VANDANA VANDANA , HINDSGAUL O. , BAENZIGER J. U. 
Published: May 2016

AbstractThe trisaccharide (VIe) and its sulfate ester (VIf) are synthesized: 1. The component (IVb) is prepared starting from the glucopyranose derivative (Ia) via the intermediates (Ib), (Ic), (IIIa), (IIIb), and (IVa).
ChemInform Abstract: Cycloadditions. Part 33. Stereospecific Synthesis and Stereochemical Structure Confirmation of Dumetorine.
Authors: AMARASEKARA A. S. , HASSNER A. 
Published: May 2016

AbstractThe acetoacetate (I) undergoes Reformatsky reaction with allyl bromide (II) to yield the hydroxyalkenoate (III).
ChemInform Abstract: Total Synthesis of Leukotriene B4 Analogues: 3‐Thia‐LTB4 and 3‐Thia‐20,20,20‐trifluoro‐LTB4.
Authors: GUINDON Y. , DELORME D. 
Published: May 2016

AbstractThe title compounds (XVIII) are prepared starting from the C‐furanosides (I) as masked dienic precursor of the intermediate (Xc).
ChemInform Abstract: The Formation and Structure of CVD W Films Produced by the Si Reduction of WF6
Authors: GREEN M. L. , ALI Y. S. , BOONE T. , DAVIDSON B. A. , FELDMAN L. C. , NAKAHARA S. 
Published: May 2016

Abstractin the temp. range 210‐700 °C have been investigated by Rutherford backscattering spectroscopy and transmission electron microscopy.
ChemInform Abstract: Dry Etching of Silicon Materials in SF6 Based Plasmas. Roles of N2O and O2 Gas Additives.
Authors: TZENG Y. , LIN T. H. 
Published: May 2016

AbstractThe silicon etch rate has been measured as a function of gas feed composition (SF6/N2O and SF6/O2 mixtures), gas pressure, and RF power, and the etched surfaces have been characterized by XPS.
ChemInform Abstract: Concerning Potassium Arsenites in the Three‐Component System K2O‐As2O3‐H2O. Preparation and Crystal Structure of K3(HAs2O4)(As2O4)·3/2 H2O.
Authors: SHELDRICK W. S. , HAEUSLER H.‐J. + 
Published: May 2016

AbstractSlow evaporation of H2O at 40 °C from a solution containing As2O3 and KOH yields the title compound.
ChemInform Abstract: High Temperature Behavior of Unstable EuPd2Si2 and Reference MPd2Si2 Compounds (M: All Rare Earths and Alkaline Earths).
Authors: PALENZONA A. , CIRAFICI S. , CANEPA F. 
Published: May 2016

AbstractAll the title compounds have been prepared by annealing mixtures of the elements at 1150 K for ten days.
ChemInform Abstract: Ba4MgTa10O30 and Ba4NiTa10O30 Compounds Related to the Tetragonal Tungsten Bronze and the NaNb6O15F‐Type.
Authors: BRANDT R. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractThe title compounds have been prepared by high temp. reaction of BaCO3, Ta2O5, and MgO (Ni‐oxalate, resp., 4:5:2, CO2 laser, 1300 °C, 3 d).
ChemInform Abstract: Theoretical and Spectroscopic Studies on Imino‐Carbon Palladated Pyridine‐2‐carbaldimines.
Authors: CROCIANI B. , GRANOZZI G. 
Published: May 2016

AbstractAb initio LCAO MO‐SCF calculations on the model compounds (I) and (II) indicate that the E‐trans conformation shown is favored over the E‐cis one by 16.9 kJ mol‐1 for (I) and by 25.0 kJ mol‐1 for (II).
ChemInform Abstract: Trifluoromethanesulfonic Acid as a Catalyst for the Ethylation of Benzene.
Authors: BOOTH B. L. , AL‐KINANY M. , LAALI K. 
Published: May 2016

AbstractAt room temp. and a pressure of ethene of 1 atm, anhydrous CF3SO3H is a more effective catalyst than AlCl3, FSO3H, and anhydrous H2SO4.
ChemInform Abstract: Studies on Chromone Derivatives. Novel 1,3 Dipolar Cycloadditions of 4‐Oxo‐1‐benzopyran‐3‐carbaldehyde Imines and Imine Oxides.
Authors: BARUAH A. K. , PRAJAPATI D. , SANDHU J. S. 
Published: May 2016

AbstractThe chromone imines (III) are prepared from 3‐formylchromone (I) and the aromatic amines (II).
ChemInform Abstract: Cyclocodimerization of 1,3‐Butadiene Derivatives with Non‐Activated Terminal Acetylenes Catalyzed by Cationic Rhodium(I) Complex.
Authors: MATSUDA I. , SHIBATA M. , SATO S. , IZUMI Y. 
Published: May 2016

AbstractThe 2‐substituted 1,3‐butadienes (I) are coupled with the terminal alkynes (II) in the presence of a Rh(I) catalyst, yielding a mixture of the dihydrobenzenes (III) ‐ (VI) and the benzenes (VII).
ChemInform Abstract: Activation Barriers in the α‐Cleavage Processes of Acetaldehyde.
Authors: MALAR E. J. P. , CHANDRA A. K. 
Published: May 2016

AbstractThe energy profiles for the decomposition of the lowest triplet state of acetaldehyde via reactions (1) Me‐CHO* → Me‐CO· + H· and (2) Me‐CHO* → Me· + CHO· are computed by using the recently developed SCF MO methods.
ChemInform Abstract: Photochemical Reactions of Nitrile Compounds. Part 2. Photochemistry of an α,β‐Unsaturated γ,δ‐Epoxy Nitrile and a γ,δ‐Cyclopropyl Nitrile.
Authors: ISHII K. , ABE M. , SAKAMOTO M. 
Published: May 2016

AbstractIrradiations of the title nitriles (Ia) and (XIV) are investigated under various conditions.
ChemInform Abstract: DBP Ylides: Wittig Reagents for Synthesis of E‐Alkenes from Aldehydes.
Authors: VEDEJS E. , MARTH C. 
Published: May 2016

AbstractCyclization and lithiation of tetraphenylphosphonium bromide (I) yield the lithiodibenzophosphole (II) which reacts with 2 equivalents of the alkyl iodides (III) to form the ylides (IV).
ChemInform Abstract: Horner‐Wittig Reactions of β‐Aminoalkyl‐ and β‐N‐Acylaminoalkyldiphenylphosphine Oxides: Synthesis of N‐Allyl Amines and Amides and 5‐Diphenylphosphinoyl‐2‐phenyl‐5,6‐dihydro‐4H‐1,3‐oxazines.
Authors: CAVALLA D. , CRUSE W. B. , WARREN S. 
Published: May 2016

AbstractThe lithium derivatives of the amines (I) or the amide (VII) undergo Horner‐Wittig reaction with the aldehydes (II) or (VIII) to give mixtures of the erythro‐adducts (III) or (IX) and the threo‐adducts (IV) or (XI).
ChemInform Abstract: Reactions of Tertiary Allylamines with Dimethyl Acetylenedicarboxylate.
Authors: KANDEEL K. A. , VERNON J. M. 
Published: May 2016

AbstractThe reaction between the tertiary allylamines (I) and dimethyl acetylenedicarboxylate (II) in acetonitrile yields the 1:1‐adducts (III).
ChemInform Abstract: Alkane Functionalization on a Preparative Scale by Mercury Photosensitization.
Authors: BROWN S. H. , CRABTREE R. H. 
Published: May 2016

AbstractCyclohexane (I) reacts with methanol (IIa) or the trioxane (IIb) or the silane (IIc) under irradiation in the presence of mercury to yield the cross‐dimerization products (IV), together with the homodimers (III) and (V).
ChemInform Abstract: Epoxidation of Alkenes by Dimethyldioxirane: Evidence for a Spiro Transition State.
Authors: BAUMSTARK A. L. , MCCLOSKEY C. J. 
Published: May 2016

AbstractDimethyldioxirane (Ia) and its hexadeutero derivative (Ib) are employed as reagents for the epoxidation of the olefins (II) to give the oxiranes (IV) and the acetone (III).
ChemInform Abstract: Flash Vacuum Thermolysis of Oxazolidines: A New Way to Reactive Azomethine Ylides. Ring Closure to Aziridines.
Authors: JOUCLA M. , MORTIER J. , BUREAU R. 
Published: May 2016

AbstractFlash vacuum pyrolysis of the oxazolidines (I) yields the aziridines (IV) via the intermediates (II).
ChemInform Abstract: Stereocontrolled Entry to 1‐Oxapenams and 1‐Oxacephems from Carbohydrates.
Authors: CHMIELEWSKI M. , KALUZA Z. , ABRAMSKI W. , BELZECKI C. 
Published: May 2016

AbstractThe carbohydrate derivatives (Ia) and (IIa), prepared from the corresponding glycals, are converted into the β‐lactams (IV) or (V) as outlined in the scheme.
ChemInform Abstract: Studies in Spiroheterocycles. Part 10. Reactions of Diazomethane with 3‐Aroylmethyleneindol‐2‐ones and Synthesis of Some Novel Fluorine Containing Spiro(cyclopropane‐1,3′(3H)‐indol)‐2′(1′H)‐ones
Authors: JOSHI K. C. , JAIN R. , ARORA S. 
Published: May 2016

AbstractBase‐catalyzed aldol condensation of the indolediones (I) with the acetophenones (II) yields the 3‐hydroxy‐3‐phenacylindolinones (III) which are dehydrated to form the chalcones (IV).
ChemInform Abstract: Polarized Ketene Dithioacetals. Part 50. Reactions of α‐Aroyl‐α‐bromoketene Dithioacetals with Hydrazine Hydrate: Formation of Rearranged Pyrazoles.
Authors: SINGH G. , ILA H. , JUNJAPPA H. 
Published: May 2016

AbstractReaction of the dithioacetals (Ia)‐(Ic) according to A) yields the corresponding pyrazoles (II)‐(IV), whereas in the case of (Id) only type (II) and (IV) is formed.
ChemInform Abstract: Pyrylium Derivatives of N‐Aryl‐2‐pyrazolines.
Authors: ORLOV V. D. , VAKULA V. N. , GELLA I. M. 
Published: May 2016

AbstractThe reaction between the 2,6‐diarylsubstituted pyrylium perchlorates (I) and the 3‐substituted 1,5‐diphenyl‐2‐pyrazolines (II) proceeds at the para position of the N‐phenyl group to yield the novel title compounds (III), which are dyes absorbing between 564 and 640 nm.
ChemInform Abstract: Vinyl Monomers Containing 1,2‐Thia‐, ‐Selena‐, and ‐Tellurazole Systems, Their Polymers and Copolymers.
Authors: LUCCHESINI F. , BERTINI V. , DE MUNNO A. , POCCI M. , PICCI N. , LIGUORI M. 
Published: May 2016

AbstractThe Grignard compound (I) is coupled with acetic anhydride (II) to give 5‐hexen‐3‐yn‐2‐one (III) which is cyclized by reaction with hydroxylamine‐O‐sulfonic acid and chalcogenides, yielding the methylvinylchalcogenazoles (IV).
ChemInform Abstract: Polynuclear Metal Complexes with Bridging Carbene of Carbyne Ligands. Part 65. Reactions of the Complexes (FeW(μ‐CR)(CO)5(η‐C5Me5)) and (Fe2W(μ3‐CR)(μ‐CO)(CO)8(η‐C5Me5)) (R: C6H4Me‐4) with Alkynes R′C2R′ (R′: Me or Ph); Crystal Structures of (FeW(μ‐C(R)C(O)C(Me)C(Me))(CO)5(η‐C5Me5))·CH2Cl2 and (FeW(μ‐C(R)C(Et)C(H)C(Me)C(Me))(μ‐CO)(CO)3(η‐C5Me5)).
Authors: HEIN J. , JEFFERY J. C. , SHERWOOD P. , STONE F. G. A. 
Published: May 2016

AbstractBoth the title cluster (I) and (IV) react with PhC≡CPh (II) to give the insertion product (IIIa).
ChemInform Abstract: Synthesis and Reactivity of E,Z‐Butadiene Iron Tricarbonyl Complexes.
Authors: MOREY J. , GREE D. , MOSSET P. , TOUPET L. , GREE R. 
Published: May 2016

AbstractThe butadiene iron tricarbonyl complex (I) is converted to the isomeric alcohols (II) and (IV), the aldehyde (V), and the secondary carbinols (VII) and (VIII).
ChemInform Abstract: Thermal Investigation and Stereochemical Studies of Some Cyclic Diamine Complexes of Nickel(II), Zinc(II), and Cadmium(II) in the Solid State.
Authors: SINGH L. K. , MITRA S. 
Published: May 2016

AbstractThe complexes (I)‐(IV) are prepared from corresponding metal(II) thiocyanates and cyclic diamines in ethanol.
ChemInform Abstract: Preparation, Characterization, and Photophysical Properties of Covalently Linked Binuclear and Tetranuclear Ruthenium Bipyridyl Complexes.
Authors: WACHOLTZ W. F. , AUERBACH R. A. , SCHMEHL R. H. 
Published: May 2016

AbstractUsing the covalently linked bipyridine ligand (II), the complexes (III) which serve as starting material for the preparation of the complexes (IV) and (VI) are obtained.
ChemInform Abstract: Reactivity of PPh3 Towards Ru2Cl(O2CR)4 (R: Me, Ph) in Alcoholic Medium: A Novel Decarbonylation Process Mediated by a Diruthenium Compound.
Authors: MANDAL S. K. , CHAKRAVARTY A. R. 
Published: May 2016

AbstractThe title reaction in refluxing methanol, ethanol, and butanol is studied by IR and 1H NMR spectroscopy.
ChemInform Abstract: Structural, ESR and Electrochemical Properties of Two (Rh2(ap)4)+ Geometric Isomers (ap = 2‐anilinopyridinate). A True Mixed‐Valent Rhodium(II)‐Rhodium(III) Complex.
Authors: BEAR J. L. , LIU L.‐M. , KADISH K. M. 
Published: May 2016

AbstractThe compound (I) is obtained by a literature method.
ChemInform Abstract: Platinum(II) Complexes with Ligands (RO)2PCH2P(OR)2 (R: Me, Et, Ph, or C6H4Me‐4); Crystal Structure of cis,cis‐(Pt2Me4(μ‐(EtO)2PCH2P(OEt)2)2).
Authors: MANOJLOVIC‐MUIR L. , JOBE I. R. , MAYA B. J. , PUDDEPHATT R. J. 
Published: May 2016

AbstractReaction of the ligands (II) with the dimeric dimethyl‐Pt(II) compound (I) or with the monomeric dihalogeno‐Pt(II) compounds (V) gives the corresponding complexes (IIIa)‐(IIId) and (IVb), respectively.
ChemInform Abstract: Transformations of Heterocyclic N‐Oxides into Derivatives of α‐Heteroaryl Substituted α‐Amino Acids and Dipeptides.
Authors: STANOVNIK B. , DROFENIK I. , TISLER M. 
Published: May 2016

AbstractThe phenyloxazolidinone (II) reacts with the azine N‐oxides (I) to yield the oxazolinylideneazines (III).
ChemInform Abstract: Fungal Products. Part 13. Isolation and Structures of Dithiosilvatin (I) and Silvathione (II), Novel Dioxopiperazine Derivatives from Aspergillus silvaticus.
Authors: KAWAHARA N. , NOZAWA K. , NAKAJIMA S. , KAWAI K. 
Published: May 2016

AbstractThe structures of the title compounds are established by usual methods.
ChemInform Abstract: ′Ene′‐Type Reaction of the Pummerer Rearrangement Product Derived from 4‐Chlorophenyl Methyl Sulfoxide: Synthesis of Some Insect Sex Pheromones.
Authors: ISHIBASHI H. , KOMATSU H. , IKEDA M. 
Published: May 2016

AbstractThe ene‐type reaction of the thionium ion generated from (III) with olefins (IV) yields the sulfides (V), giving the dienes (VI) following desulfuration.