bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Captodative Rate Enhancements in the Methylenecyclopropane Rearrangement.
Authors: CREARY X. , MEHRSHEIKH‐MOHAMMADI M. E. 
Published: May 2016

AbstractThe diazoesters (III) prepared from the α‐ketoesters (I) react with the allene (IV) under irradiation, producing the methylenecyclopropanes (V) which are thermally rearranged to form the isomers (VI).
ChemInform Abstract: A Novel Type of Cycloalkylation of Styrenes. Formation of Substituted Tetralines from 2‐Methyl‐3‐aryl‐2‐butenes.
Authors: BODRIKOV I. V. , SHEBELOVA I. YU. , SOKOVA F. M. , GATILOV YU. V. , NISNEVICH G. A. , MAMATYUK V. I. , BARKHASH V. A. 
Published: May 2016

AbstractThe styrenes (I) are converted to the tetralins (II) in the presence of the system AlCl3/MeNO2.
ChemInform Abstract: Reaction of Acenaphthene Phosphorus Ylides with 4‐Formylpyridine and Investigation of the Reaction Products.
Authors: MIKAILU V. G. , LABA V. I. , SHEVCHUK M. I. 
Published: May 2016

AbstractThe ylides (IV), (IX), and (XI), obtained by common methods, react with 4‐formylpyridine (V) to give the Wittig products (VI), (X), or (XII) respectively.
ChemInform Abstract: Regio‐ and Diastereoselective Reactions of Dithio‐Substituted Crotyllithium and Aldehydes.
Authors: FANG J.‐M. , LIAO L.‐F. , HONG B.‐C. 
Published: May 2016

AbstractThe reaction of the lithiated dithiane (III) with the aldehydes (IV) proceeds with regio‐ and threo‐selectivity, forming the adducts (V) which are hydrolyzed to produce the trans‐substituted lactones (VI).
ChemInform Abstract: Thieno(3,4‐f)‐2,1‐benzisothiazole. Synthesis and Physical Properties of a Novel Fused 14π Heteroarene as well as Its Thermal Cycloaddition Reactions with N,N‐Double Bond Systems.
Authors: GOTTHARDT H. , BOEHM F.‐R. + 
Published: May 2016

AbstractThe dione (I) reacts with P4S10 to give the (thermally stable) title compound (II) which contains three masked dipolar systems, represented by the limiting formulas α, β and γ.
ChemInform Abstract: Unusual Rearrangement Products in the Cycloaddition of 4‐Phenyl‐4H‐1,2,4‐triazoline‐3,5‐dione (PTAD) to Substituted 7‐Methylenenorbornenes.
Authors: ADAM W. , LUCCHINI V. , PASQUATO L. , PETERS E.‐M. , PETERS K. , VON SCHNERING H. G. , SEGUCHI K. 
Published: May 2016

AbstractThe reaction of the dione (IV) with the norbornenes (Ia), (Ib), prepared by Wittig reaction from 7‐norbornenone, yields the (2 + 2) cycloadducts (IIIa), (IIIb).
ChemInform Abstract: Regio‐ and Stereoselective Dehydrogenation of α,ω‐Diols Catalyzed by a Rhodium Hydride Complex.
Authors: ISHII Y. , SUZUKI K. , IKARIYA T. , SABURI M. , YOSHIKAWA S. 
Published: May 2016

AbstractThe diols (I) are dehydrogenated in the presence of the hydrogen acceptor (II) and the rhodium complex (III) to form the lactones (IV) and (V).
ChemInform Abstract: An Approach to Pseudomonic Acids from Acetylenic Precursors: Synthesis of 2‐(Hydroxymethyl)‐3‐butyn‐1‐ol.
Authors: BATES H. A. , FARINA J. , TONG M. 
Published: May 2016

AbstractSeveral synthetic routes to the masked hydroxymethylbutynol (V) are evaluated.
ChemInform Abstract: Reactions of 1,5‐Diketones. Part 47. Alkaline Condensation of Methyl(phenyl)‐bis(2‐oxocyclohexyl)methanes and 2‐Hydroxy‐8‐methyl(phenyl)tricyclo(7.3.1.02,7)tridecan‐13‐ones with Aromatic Aldehydes and the Properties of the 4α‐Hydroxy‐5‐arylidene‐9‐methyl(phenyl)‐1,2,3,4,4α,5,6,7,8,9α# ‐decahydroxanthenes Obtained.
Authors: MINAEVA N. N. , TILICHENKO M. N. 
Published: May 2016

AbstractThe decahydroxanthenes (III) mentioned in the title are prepared in two ways.
ChemInform Abstract: Organic Syntheses via Transition Metal Complexes. Part 16. A Novel Route to δ‐Carbolines via Template Induced Multiple Cyclization of Alkenyl‐, Dienyl‐, or Thienylcarbene Complexes with Aryl Isocyanides.
Authors: AUMANN R. , HEINEN H. , KRUEGER C. + , TSAY Y.‐H. 
Published: May 2016

AbstractThe reaction of the complex (I) with the isocyanide (II) yields the δ‐carbolinone (V) via the intermediates (III) and (IV).
ChemInform Abstract: Synthesis and Reactions of Some New Isoquinoline‐1‐carbonitrile Derivatives.
Authors: KHALIL A. M. , HABIB O. M. O. , ABD EL‐GAWAD I. I. , ETMAN H. A. 
Published: May 2016

AbstractThe α‐cyano dihydronaphthylideneacetate (I) is coupled with the aromatic aldehydes (II) to produce the isoquinolinone nitriles (III).
ChemInform Abstract: Reactions of Cotarnine and Hydrastinine with NH Acidic Compounds.
Authors: MOEHRLE H. + , GRIMM B. 
Published: May 2016

AbstractHydrastinine (Ia) reacts with the N‐nucleophiles (II) to produce the Schiff bases (III), equilibrating with their cyclic isomers (IVa) and (IVb).
ChemInform Abstract: Naphtho(2,3‐c)pyrans and Benz(g)isoquinolines from 6‐Methoxy‐2H‐pyran‐ 3(6H)‐one.
Authors: EIDEN F. , WUENSCH B. + 
Published: May 2016

AbstractThe cycloaddition reaction of the isobenzofuran (I) with the pyranone (II) yields the exo/endo‐mixture (III).
ChemInform Abstract: Quinazolinones. Part 5. Syntheses of 3‐(Chloroacylamino)‐2‐methyl‐ 4(3H)‐quinazolinone Derivatives with Anticonvulsant and Hypnotic Activities.
Authors: BUEYUEKTIMKIN S. + 
Published: May 2016

AbstractAcylation of the quinazolinone derivatives (I) yields the N‐substituted compounds (III).
ChemInform Abstract: Synthesis and Some Chemical Properties of 8‐Methyl‐3‐hydroxy‐6‐oxo‐2H‐ 3,4,5,6‐tetrahydropyrimido(2,1‐b)(1,3)thiazines.
Authors: FASKHUTDINOV R. M. , PASHKUROV N. G. , REZNIK V. S. 
Published: May 2016

AbstractThe hydroxytetrahydropyrimidothiazine (IV) is prepared from mercaptouracil (I) and 1,3‐dibromopropanol‐2 (II) or epichlorohydrin (III).
ChemInform Abstract: Synthesis of a 1,3‐Bridged β‐Lactam: A Novel, Anti‐Bredt β‐Lactam.
Authors: WILLIAMS R. M. , LEE B. H. 
Published: May 2016

AbstractEthyl acetoacetate (I) is converted to the N‐methoxy amide (VI), which undergoes cyclization according to Miller followed by reductive cleavage of the NO‐bond to give the β‐lactam (VIII).
ChemInform Abstract: 12‐Organyldibenz(b,g)azocine‐5,7‐diones.
Authors: HELLWINKEL D. , ITTEMANN P. 
Published: May 2016

AbstractThe title compounds (III) or (VII) are synthesized best by cyclization (intramolecular ester condensation) of the precursors (II) or (VI) which, in turn, are accessible from the compound (Ia) (or (Ib)) or (IV), respectively.
ChemInform Abstract: Asymmetric Michael Reactions of 3,5‐Dihydro‐4H‐dinaphth(2,1‐c:1′,2′‐e)azepine with Methyl Crotonate.
Authors: HAWKINS J. M. , FU G. C. 
Published: May 2016

AbstractThe dibromide (I) is converted to the secondary amines (II).
ChemInform Abstract: Reactions of Silylated Cyclotetraphosphanes with Lithium Alkyls.
Authors: FRITZ G. , STOLL K. 
Published: May 2016

AbstractReaction of the cyclotetraphosphanes (I), (VII) or (IX) with lithium alkyls such as (II) or (V) in THF at ‐50 to ‐25 °C results in the formation of prim. and sec. n‐tetraphosphides, which are trapped by reaction with Me3SiCl (IIIa) or MeCl (IIIb) to give stable phosphane derivatives such as (IV), (VI), (VIII) or (X)‐(XII).
ChemInform Abstract: Asymmetric Reactions Catalyzed by Chiral Metal Complexes. Part 22. Preparation of New Chiral Pyrrolidinebisphosphines as Highly Effective Ligands for Catalytic Asymmetric Synthesis of R‐(‐)‐Pantolactone.
Authors: TAKAHASHI H. , HATTORI M. , CHIBA M. , MORIMOTO T. , ACHIWA K. 
Published: May 2016

AbstractThe 4‐hydroxypyrrolidine carboxylate (I) is converted to the optically active bisphosphines (IX) and (XI) as outlined in the reaction scheme.
ChemInform Abstract: 1‐R‐1,3λ3‐Azaphospholes.
Authors: MAERKL G. + , DORFMEISTER G. 
Published: May 2016

AbstractThe N‐substituted azaphosphole derivatives (III) and (VII) mentioned in the title are prepared by various methods: first, by oxygen phosphorus exchange of the oxazolium salts (I) with tris(trimethylsilyl)phosphine (II), second, by the cycloaddition reaction of the betaines (IV) and the phosphalkene (V), followed by CO2‐elimination or third, by reacting the salts (VIII) with (II).
ChemInform Abstract: Synthesis of Phosphoranates with White Phosphorus.
Authors: KABACHNIK M. I. , LOBANOV D. I. , MATROSOVA N. V. , PETROVSKII P. V. 
Published: May 2016

AbstractThe phosphoranes (III) and subsequently the phosphoranates (IV) are prepared from the substituted pyrocatechols (I), the corresponding o‐benzoquinones (II), and elementary white phosphorus by several variants.
ChemInform Abstract: The Reaction of Ethyldichlorophosphine with N,N‐Dibutyl‐2,3‐butanediimine.
Authors: KIBARDIN A. M. , MIKHAILOV YU. B. , GRYAZNOVA T. V. , PUDOVIK A. N. 
Published: May 2016

AbstractThe diimine (I) reacts with ethanephosphonous acid dichloride (II) to produce the phosphonium salt (III).
ChemInform Abstract: Synthesis of Ammonium 1,3,5,2‐Dioxaphosphaboratinanes.
Authors: ARBUZOV B. A , ERASTOV O. A. , NIKONOV G. N. , KARASIK A. A. 
Published: May 2016

AbstractThe title compounds (IV) may be obtained either from bis‐α‐hydroxyalkylphenylphosphines (I) and diphenylboronic acid isobutylester (II) in excess amine (III) or from diphenylphosphine (V) and the aldehydes (VI), the ester (II), and the amine (IIIa).
ChemInform Abstract: Unsaturated Silicon and Germanium Compounds. Part 14. Compounds of Silicon and Its Homologues. Part 66. Generation and Evidence of the Germaethene Me2Ge=C(SiMe3)2.
Authors: WIBERG N. , KIM C.‐K. 
Published: May 2016

AbstractBromination of the germaethane (Ia) gives the dibromide (Ib), which is converted to the bromogermyl compounds (Ic)‐(Ih).
ChemInform Abstract: Induced Redox Reactivity of Tetrathiovanadate(V): Synthesis of the Vanadium(IV) Dimer V2(μ‐S2)2(i‐Bu2NCS2)4 and Its Structural Relationship to the V/S Mineral Patronite.
Authors: HALBERT T. R. , HUTCHINGS L. L. , RHODES R. , STIEFEL E. I. 
Published: May 2016

AbstractTreatment of a solution of tris‐(tricaprylmethylammonium)tetrathiovanadate, the metathesis product of (I), with solid tetraisobutylthiuram disulfide followed by silica gel chromatography affords the title compound (II).
ChemInform Abstract: Kinetics of Ligand Substitution and Oxidation Reactions of the (((Phosphonomethyl)imino)diacetato)aquooxovanadium(IV) Ion: Role of the Hydrogen Bond Between the Coordinated Water and the Phosphonate Arm.
Authors: WANG B. , SASAKI Y. , OKAZAKI K. , KANESATO K. , SAITO K. 
Published: May 2016

AbstractThe protonation constant for the phosphonate oxygen and the deprotonation constant for the coordinated water of the new complex (I) (prepared by reaction of dimeric acetylacetonatooxovanadium with (phosphonomethyl)iminodiacetic acid, yield given in g) are determined.
ChemInform Abstract: Formation of Zwitterionic Ligands, ROC‐(+PMe3)S‐ 2, by Nucleophilic Attack of PMe3 on Coordinated Xanthates. X‐Ray Structure of MoO(S2C(PMe3)O‐i‐Pr‐S,S′)(CS2CO‐i‐Pr‐S,S′,C).
Authors: CARMONA E. , GALINDO A. , GULTIERREZ‐PUEBLA E. , MONGE A. , PUERTA C. 
Published: May 2016

AbstractThe 1:2 molar reaction of the Mo and W complexes (I) with potassium xanthates leads to the new oxo complexes (II).
ChemInform Abstract: Complexes of Diphosphaferrocenes with Lewis Acids and Cu(I), Ag(I) Salts.
Authors: ROBERTS R. M. G. , SILVER J. , WELLS A. S. 
Published: May 2016

AbstractComplexes of the diphosphaferrocenes (I)‐(IV) and of the phosphaferrocene (V) are prepared using the Lewis acids BF3·Et2O and AlCl3 or Cu(I) and Ag(I) salts.
ChemInform Abstract: Linear Oligophosphaalkanes. Part 15. Tetradentate Phosphanes in Tetrahedral and Octahedral Complexes: Zinc(II) and Iron(II) Complexes of the Linear Tetraphosphaalkanes Me2P‐(CH2)3‐PMe‐(CH2)n‐PMe‐(CH2)3‐PMe2 (n = 2, 3).
Authors: HIETKAMP S. , STELZER O. 
Published: May 2016

AbstractThe linear tetraphosphaalkanes (II), obtained by lithiation/methylation, react with FeCl2 to form the diamagnetic neutral Fe complexes (III).
ChemInform Abstract: Dinuclear Complexes of Transition Metals Containing Carbonate Ligands. Part 6. Synthesis, Characterization, and Thermodynamic Studies of Dinuclear Complexes of Cobalt(III) Containing Bridging Hydroxide and Carbonate in Acidic Aqueous Solution.
Authors: SADLER G. , DASGUPTA T. P. 
Published: May 2016

AbstractA series of title complexes containing carbonate as bridging group is prepared.
ChemInform Abstract: Cobalt(II) Bis(1,4,7‐trithiacyclononane): A Low‐Spin Octahedral Complex.
Authors: WILSON G. S. , SWANSON D. D. , GLASS R. S. 
Published: May 2016

AbstractCobalt(II) forms a cationic 1:2 complex with 1,4,7‐trithiacyclononane with an unprecedentedly large overall formation constant.
ChemInform Abstract: Azide‐, Thiocyanate‐ or Cyanate‐Bridged Di‐ and Trinuclear Copper(II) Complexes with N,N,N′,N′‐Tetramethylethylenediamine, N,N‐Diethylethylenediamine, 2,2′‐Bipyridyl or 1,10‐Phenanthroline.
Authors: NAKAO Y. , NAKAMURA H. , MORI W. , SAKURAI T. , SUZUKI S. , NAKAHARA A. 
Published: May 2016

AbstractThe copper complexes (I)‐(VII) (no yields given) are synthesized by reaction of Cu(ClO4)·6 H2O or Cu(NO3)2·3 H2O with the nitrogen ligands and NaX (X: N3, CNS or CNO) in the corresponding molar ratios.
ChemInform Abstract: Copper and Zinc Mixed gem‐Dimetallic Organic Compounds Synthesis and Reactivity. Part 3.
Authors: KNOCHEL P. , NORMANT J. F. 
Published: May 2016

AbstractAllyl zinc bromide (I) is coupled with the organometallic olefins (II) to produce geminal dimetallic derivatives (III) which form the complexes (IV) with CuCN.
ChemInform Abstract: Thiaketocyanine Dyes with an ortho‐Phenylene Bridge in the Chromophore.
Authors: SOSNOVSKII G. M. , LUGOVSKII A. P. 
Published: May 2016

AbstractCondensation of the quaternary 2‐methylbenzothiazolium tosylates (I) with 1,3‐bis(dimethylaminomethylene)indanone (II) affords the meso‐acetoxy substituted tricarbocyanine dyes (III), which are hydrolyzed to give the title compounds (IV).
ChemInform Abstract: The Isolation of a Spiran in the Rearrangement of an α‐Bromo‐αβ‐Unsaturated Steroidal Ketone.
Authors: KOGA T. , NOGAMI Y. 
Published: May 2016

AbstractThe 3‐bromo‐cholest‐2‐en‐4‐one (I) rearranges on acetolysis, producing mixtures of the spiran (II) and the aromatic compounds (III).
ChemInform Abstract: Synthesis of a Conformationally Rigid Etorphine Analogue.
Authors: KIM K. J. , HAHN S. J. , LYU H. S. 
Published: May 2016

AbstractReaction of thebaine (I) and the acetylene (II) yields the Diels‐Alder adduct (III), which is reduced to give the lactone (IV).
ChemInform Abstract: Molecular Geometry and Fluxionality in the AX6E System ClF‐ 6.
Authors: MACDOUGALL P. J. 
Published: May 2016

AbstractThe analysis of the calculated charge distribution and corresponding Laplacian distributions of the ClF6‐ ion in both its equilibrium geometry (C3v) and its fluxional transition state geometry (C2v) confirms the suggestion that AX6E systems should distort from Oh symmetry because of the presence of a stereochemically active lone pair.
ChemInform Abstract: Temperature Dependence of 29Si NMR Linewidths in Aqueous Silicate Solutions and Their Effect on Exchange Rate Determinations.
Authors: GRIFFITHS L. , CUNDY C. S. , PLAISTED R. J. 
Published: May 2016

AbstractAlkali silicate solutions exhibit a reversible temp.‐dependent line broadening in their 29Si NMR spectra, which is ascribed partly to silicate anion exchange reactions and partly to a temp. dependence of the spin‐spin relaxation time.
ChemInform Abstract: Mass Spectral Studies on the Thermal Decomposition of S4N4 and the Mechanism for Formation of (SN)x.
Authors: BESENYEI E. , EIGENDORF G. K. , FROST D. C. 
Published: May 2016

AbstractThe mechanism for the polymerization of (SN)x proposed on the basis of the MS results of the thermal decomposition of S4N4 in the presence and the absence of Ag wool includes two important steps, the fragmentation of S4N4 to S2N2 and the transformation of S2N2 to (SN)2, which is found to be the starting material for the polymer.
ChemInform Abstract: Electrochromic Film Derived from Cathodic Deposition of Polyoxometalates.
Authors: YAMASE T. , SASAKI Y. , MOTOWAKI T. 
Published: May 2016

AbstractPotentiostatic reduction of (W10O32)4‐ in MeCN results in the deposition of a blue film on the indium‐tin oxide (ITO) electrode.
ChemInform Abstract: Electron Spin Resonance Studies of Free and Supported 12‐Heteropoly Acids. Part 4. Reduction of H3+n(PVnMo12‐nO40)·xH2O and the Influence of Supports on Their Properties.
Authors: FRICKE R. , JERSCHKEWITZ H.‐G. , OEHLMANN G. + 
Published: May 2016

AbstractH2 reduction (30 Torr, 273‐773 K) of the title heteropoly acid (HPA) with n = 1‐3 has been studied by ESR.
ChemInform Abstract: Photoelectric Behavior of Sintered TiO2 Electrodes.
Authors: YOON K. H. , KIM J. S. 
Published: May 2016

AbstractThe photoelectrochemical characteristics of TiO2 (rutile) ceramic electrodes, whose fabrication and qualitative doping is easily controlled, have been studied as a function of electrode purity, H2 reduction conditions, light intensity, and the wavelength of the incident light.
ChemInform Abstract: The Sorption of Strontium Ions on α‐FeOOH
Authors: VANEK K. , JEDINAKOVA V. 
Published: May 2016

Abstractin 0.1 M NaNO3 solution is studied in an extended concentration range of Sr2+ ions and a constant concentration of sorbent so that crel = csorbent/csorbate is 101‐104.
ChemInform Abstract: Behavior of Surface Peroxo Species in the Photoreactions at TiO2.
Authors: ULMANN M. , DE TACCONI N. R. , AUGUSTYNSKI J. 
Published: May 2016

AbstractThe results of cyclic voltammetry show that the same surface peroxo titanium species are formed when an illuminated TiO2 film electrode immersed in an aqueous NaOH solution is subjected to an anodic bias or left in open circuit both in the presence and in the absence of oxygen.
ChemInform Abstract: Vanadium‐Sensitized Photochemistry of Heteropoly Compounds. Mixed Molybdo‐ and Tungstovanadates.
Authors: ARGITIS P. , PAPACONSTANTINOU E. 
Published: May 2016

AbstractThe photochemistry of (PV(V)2Mo10O40)5‐ and (PV(V)2W10O40)5‐ has been studied.
ChemInform Abstract: Conversion of SO2 to SO3 Facilitated by in situ UV Photolysis of H2CO and SO2 in an O2 Matrix at 12 K.
Authors: GREEN M. , LEE E. K. C. 
Published: May 2016

AbstractThe photooxidation product distribution observed in UV (270‐420 nm) photolysis of H2CO, SO2, and H2CO·SO2 complexes in solid O2 are compared.
ChemInform Abstract: Convenient Synthesis of Thiazyl Hexafluoroarsenate(V), (SN)+(AsF6)‐, and Small Quantities of Thiazyl Fluoride, NSF.
Authors: APBLETT A. , BANISTER A. J. , BIRON D. , KENDRICK A. G. , PASSMORE J. , SCHRIVER M. , STOJANAC M. 
Published: May 2016

AbstractThe title compound (III) has been prepared as shown in the scheme and purified by sublimation.
ChemInform Abstract: Cubic Eu‐Doped Hafnia Ultrafine Particles Crystallized Under Hydrothermal Conditions.
Authors: SOMIYA S. , YOSHIMURA M. , TORAYA H. , FUSHII Y. 
Published: May 2016

AbstractCoprecipitation of amorphous HfO2/Eu2O3 mixtures of 80:20 and 70:30 weight ratio by NH4OH from HfOCl2 and EuCl3 solution followed by hydrothermal treatment at 300 °C (10 MPa, 3 h) yields a single phase cubic (fluorite‐type) solid solution, Hf1‐xEuxO2‐x/2 (x = 0.230 and 0.339).
ChemInform Abstract: BaNiYb2O5: A Novel Compound not Crystallizing in the BaNiLn2O5‐Type and a Contribution about BaCuSm2O5.
Authors: SCHIFFLER ST. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractSingle crystals of the title compounds are prepared by melting (CO2‐laser) pressed pellets of BaCO3‐NiCO3‐Yb2O3 and BaCO3‐CuO‐Sm2O3 mixtures, respectively.
ChemInform Abstract: Captodative Substituent Effects. Part 26. Allylic Radicals with Captodative Substitution: Easy Homolysis of 1,5‐Hexadienes.
Authors: VAN HOECKE M. , BORGHESE A. , PENELLE J. , MERENYI R. , VIEHE H. G. 
Published: May 2016

AbstractThe equilibration of allyl radicals such as (I) with captodative substitution and their 1,5‐hexadiene dimers such as (II) is investigated.
ChemInform Abstract: Asymmetric Synthesis of Functionalized Tertiary Homoallyl Alcohols by Diastereoselective Allylation of Chiral α‐Keto Amides Derived from (S)‐Proline Esters. Control of Stereochemistry Based on Saturated Coordination of Lewis Acid.
Authors: SOAI K. , ISHIZAKI M. 
Published: May 2016

AbstractThe (S)‐proline derivative (I) can be allylated with high diastereoselectivity to form predominantly the isomers (IV) which readily give the cyclized products (VI) on work‐up.
ChemInform Abstract: Reaction of Trichloroacetonitrile with Conjugated Diene Hydrocarbons and the Structure of the Adducts Obtained.
Authors: SHVEKHGEIMER G. A. , KOBRAKOV K. I. , POPANDOPULO N. G. , PROMONENKOV V. K. 
Published: May 2016

AbstractThe reaction of the dienes (I) with trichloroacetonitrile (II) leads to the 1,4‐adducts (III) or (IV).
ChemInform Abstract: Direct Introduction of Azoloazine Groups into Resorcine.
Authors: RUSINOV V. L. , PILICHEVA T. L. , MYASNIKOV A. V. , KLYUEV N. A. , CHUPAKHIN O. N. 
Published: May 2016

AbstractThe azolopyrimidines and azolotriazines (I) react with resorcine (II) to give the derivatives (III).
ChemInform Abstract: Regioselective Cleavage of 2‐Methyltetrahydrofuran: A Versatile Synthesis of 1‐Halo‐4‐pentanols and 4‐Halo‐1‐pentanols.
Authors: YADAV V. K. , FALLIS A. G. 
Published: May 2016

AbstractThe reaction of 2‐methyltetrahydrofuran (V) with the tetraalkylammonium salts (III) in the presence of equimolar amounts of boron trifluoride etherate (IV) produces exclusively modest yields of the 1‐halo‐4‐pentanols (I).
ChemInform Abstract: Absorption Kinetics of Photochemical Reactions of 2,4,6‐Triisopropylbenzophenone and Its Derivatives in Benzene at Room Temperature Studied by Nanosecond Spectroscopy. Part 2. Laser Chemistry, Molecular Dynamics, Collisions, and Energy Transfer.
Authors: NAKAYAMA T. , KURAMOTO T. , HAMANOUE K. , TERANISHI H. 
Published: May 2016

AbstractCharacteristic absorption bands due to the highly hindered triplet states are observed around 600 ∼ 800 nm.
ChemInform Abstract: Organic Photochemistry. Part 63. Photolytic Cleavage of Remote Functional Groups in Polyfunctional Molecules. Photolysis of exo‐ and endo‐ Benzobicyclo(2.2.2)octen‐2‐yl Chloride.
Authors: MORRISON H. , MUTHURAMU K. , PANDEY G. , SEVERANCE D. , BIGOT B. 
Published: May 2016

AbstractThe photolysis of the chlorides (II) or (III), which can be performed as shown, gives mixtures of the products (IV) ‐ (VIII) and (I) in methanol.
ChemInform Abstract: Vapor‐Phase Chemistry of Arenes. Part 11. Autoxidation of Chlorobenzene Between 500‐1100 K. Mechanisms of Formation of Chlorophenols and Phenol.
Authors: MULDER P. , LOUW R. 
Published: May 2016

AbstractThe autoxidation of (I) is induced by additives forming OH· radicals such as tert. butyl hydroperoxide, H2O2, cyclohexa‐1,3‐diene, and cyclohexane with and without nitroethane, as well as by flash‐vacuum techniques (FVT).
ChemInform Abstract: KMnO4 Revisited: Oxidation of Aldehydes to Carboxylic Acids in the tert‐Butyl Alcohol‐Aqueous NaH2PO4 System.
Authors: ABIKO A. , ROBERTS J. C. , TAKEMASA T. , MASAMUNE S. 
Published: May 2016

AbstractThe aldehyde (I) reacts with permanganate in the presence of dihydrogen phosphate to produce the carboxylic acid (II).
ChemInform Abstract: Oxidation of Cyclobutanones to γ‐Butyrolactones with Hydrogen Peroxide in 2,2,2‐Trifluoroethanol.
Authors: MATSUMOTO M. , KOBAYASHI H. 
Published: May 2016

AbstractThe cyclobutanones (I), (III), (VI), and (VIII) are converted to the corresponding γ‐lactones (II), (IV), (VII), or (IX) by hydrogen peroxide in trifluoroethanol.
ChemInform Abstract: Hydroxylation of Indolines and Indoles by Hydrogen Peroxide in Superacids.
Authors: BERRIER C. , JACQUESY J.‐C. , JOUANNETAUD M.‐P. , RENOUX A. 
Published: May 2016

AbstractThe indoline (Ia) reacts with hydrogen peroxide in superacidic media to yield the hydroxy compounds (Ib) and (Ic).
ChemInform Abstract: Reactions with Aziridines. Part 37. N,N′‐Substituted 1,1‐Dimethylethylenediamines by Highly Regioselective Ring Opening of Activated 2,2‐Dimethylaziridines Through Aliphatic Amines.
Authors: BUCHHOLZ B. , ONISTSCHENKO A. , STAMM H. 
Published: May 2016

AbstractThe strongly activated aziridines (I) react with the amines (II) to afford the diamines (III), while the weakly activated aziridines (IV) yield the diamines (V).