bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Studies on Borate Esters. Part 8. Interactions of Cations with Oxyacid Anion‐Bridged Esters of D‐Glucarate in Alkaline Media.
Authors: VAN DUIN M. , PETERS J. A. , KIEBOOM A. P. G. , VAN BEKKUM H. 
Published: May 2016

AbstractCation coordination is studied in aqueous cation/borate/D‐glucarate systems using 11B NMR spectroscopy.
ChemInform Abstract: Electrochemical Reactions of Dichlorobis(aryl isocyanide)platinum(II) Complexes.
Authors: YAMAMOTO Y. , TAKAHASHI K. , MATSUDA K. , YAMAZAKI H. 
Published: May 2016

AbstractElectrochemical reduction of (Ia) and (Ic) produces (II) or (III) depending on the charge consumed and reduction potential.
ChemInform Abstract: Electrochemical Reactivity of Manganese(II) Porphyrins. Effects of Dioxygen, Benzoic Anhydride, and Axial Ligands.
Authors: CREAGER S. E. , MURRAY R. W. 
Published: May 2016

AbstractCurrents for electrochemical reductions of Mn(III) porphyrins in oxygenated, aprotic media correspond to passage of between one and two electrons per porphyrin, depending on the experimental time scale, the axial base (Py, N‐methylimidazole) present, and the particular porphyrin (tetraphenyl‐, ‐mesityl‐, and ‐p‐methoxyphenylporphyrin).
ChemInform Abstract: Electrochemistry of (μ‐Porphinato)bis(dicarbonylrhodium(I)) Complexes. Oxidative Conversion of (P)(Rh(CO)2)2 to ((P)Rh)+, Where P: Octaethyl‐ or Tetraphenylporphyrin.
Authors: YAO C.‐L. , ANDERSON J. E. , KADISH K. M. 
Published: May 2016

AbstractThe electrochemistry of the title complexes (I), in which the Rh(I) ions are on opposite sides of the porphyrin plane, is investigated in benzonitrile and methylene chloride.
ChemInform Abstract: Electrophilic Aromatic Substitution. Part 36. Protiodetritiation of Some Annelated meta‐Cyclophanes: Effect of Ring‐Buckling on Reactivity, and the First Example of Electrophilic Substitution Through a Hole.
Authors: LAWS A. P. , NEARY A. P. , TAYLOR R. 
Published: May 2016

AbstractThe partial rate factors of the protiodetritiation of (Ia) with trifluoroacetic acid at 70 °C increase when the size of the bridge decreases due to the loss of ground‐state aromaticity of the ring containing the alkyl chain.
ChemInform Abstract: Preparation and Solvolysis of trans,trans,trans‐Tricyclo(7.3.1.05,13)tridecan‐3‐yl Toluene‐p‐sulfonates in Acetic Acid and Aqueous Hexafluoropropan‐2‐ol. The Role of Non‐Chair Conformers and the Question of Internal Return in the Limiting SN1 Solvolytic Mechanism.
Authors: COLES C. J. , MASKILL H. 
Published: May 2016

AbstractAn improved cyclization of (I) leads to the ether (II), which is reduced by a modified Birch reduction to give the two main products (III) and (IV).
ChemInform Abstract: Kinetic Study of the Homogeneous Methanolysis of Tetraphosphorus Decasulfide.
Authors: BOURDAUDUCQ P. , DEMARCQ M. C. 
Published: May 2016

AbstractThe multistep reaction is studied at 0‐35 °C for various MeOH:P4S10 molar ratios (8:1‐80:1).
ChemInform Abstract: Reactions of 2‐Alkyl‐, 2‐Phenyl‐, and 2‐Alkoxy‐1,2‐oxaborolanes with (Dichloromethyl)lithium. A Novel Synthesis of 1,4‐Alkanediols.
Authors: DING H. , ZHOU W. , BAI J. 
Published: May 2016

AbstractThe 1,2‐oxaborolanes (I) react with dichloromethyllithium (II) to give the intermediate salts (III) which are converted to the 1,2‐oxaborinanes (IV) at room temperature.
ChemInform Abstract: Synthesis of New Diheterocyclic Imidazole Derivatives with Antiparasitic Activity.
Authors: QUATTARA L. , DEBAERT M. , CAVIER R. 
Published: May 2016

AbstractCondensation of the heteroaromatic aldehydes (I) with 2‐amino‐3,3‐dichloroacrylonitrile (II) yields the azomethines (III), which are cyclized to form the diheterocyclic aldehydes (IV).
ChemInform Abstract: Ligand Field Photochemistry of trans‐Tetraamminechromium(III) Complexes with One Strong‐Field and One Weak‐Field Axial Ligand.
Authors: RICCIERI P. , ZINATO E. , DAMIANI A. 
Published: May 2016

AbstractThe ligand field photolysis of the three complexes (I) is studied in acidic aqueous solution.
ChemInform Abstract: Selectivity of Radical Formation in the Reaction of Carbonyl Compounds with Manganese(III) Acetate.
Authors: MIDGLEY G. , THOMAS C. B. 
Published: May 2016

AbstractThe competitive oxidation of the acids and anhydrides (I) and (II) in the presence of the olefin (III) leads to the acids (IVa) and (IVb), indicating a reaction facilitated by methyl substitution (combined selectivity of initiation by Mn3+ and chain propagation).
ChemInform Abstract: Additive Effects on the CIDNP, Cage Effect, and Exit Rate of Micellized Radical Pairs.
Authors: TURRO N. J. , ZIMMT M. B. , LEI X. G. , GOULD I. R. , NITSCHE K. S. , CHA Y. 
Published: May 2016

AbstractThe effect of additives such as Fremy's salt, CsCl, NaCl, benzyl alcohol, or 1,10‐decanethiol on the recombination efficiency and exit rates of micellized benzyl radicals derived from the dibenzyl ketones (I) are studied by steady‐state CIDNP, steady‐state product analysis, and time‐resolved optical absorption techniques.
ChemInform Abstract: A New Source for Generation of Benzyne and Pyridyne: Reactions of o‐Halophenyl (or 3‐Bromo‐4‐pyridyl) Phenyl Sulfoxides with Grignard Reagents.
Authors: FURUKAWA N. , SHIBUTANI T. , FUJIHARA H. 
Published: May 2016

AbstractThe 2‐halophenyl sulfoxides (I) react with the Grignard compounds (II) to yield the sulfoxides (IV) and the halophenylmagnesium bromides (III).
ChemInform Abstract: Biohydrogenation of Unsaturated Compounds by Saccharomyces cerevisiae. Part 1. Stereochemical Aspects of the Reaction and Preparation of Useful Bifunctional Chiral Synthons.
Authors: FERRABOSCHI P. , GRISENTI P. , CASATI R. , FIECCHI A. , SANTANIELLO E. 
Published: May 2016

AbstractThe olefinic esters(III) are prepared as an E/Z mixture from the compounds (I) and (II) with different E/Z ratios depending on the base used.
ChemInform Abstract: Carbonylation of Benzyl Halides Using CoCl2/NaBH4/CO/NaOH Reagent System.
Authors: SATYANARAYANA N. , PERIASAMY M. 
Published: May 2016

AbstractTetracarbonyl cobaltate (III), prepared by treatment of cobalt dichloride (I) with sodium boranate and carbon monoxide (II), is coupled with the benzyl bromides (IV) in the presence of (II) to give the arylacetic acids (VI) after hydrolysis.
ChemInform Abstract: A Simple Synthesis of 1‐Trimethylsilyl‐2,3‐dienes.
Authors: NATIVI C. , RICCI A. , TADDEI M. 
Published: May 2016

AbstractThe trimethylsilyltributylstannylalkenols (I) are treated with trifluoromethanesulfonic acid to form the silylmethylallenes (II).
ChemInform Abstract: Reaction of Polyhalogenofunctionalized Compounds with Metals and Electrophilic Reagents. Part 7. Reaction of Bromal with Zinc in the Presence of Carboxylic Acid Chlorides or α‐Chloroethers.
Authors: SHCHEPIN V. V. , RUSSKIKH N. YU. , LAPKIN I. I. 
Published: May 2016

AbstractThe Reformatsky reaction of carbonyl compounds with a tribromomethyl group has never been the subject of a detailed study.
ChemInform Abstract: A Simple Way to Some Ketone Homoenolates.
Authors: CUVIGNY T. , JULIA M. , JULLIEN L. , ROLANDO C. 
Published: May 2016

AbstractThe potassium homoenolates (I) react with butyllithium and the alkyl halides (II) under various conditions to yield mixtures of the ketones (III) ‐ (VIII).
ChemInform Abstract: α‐Trifluoromethyl‐α‐hydroxycarboxylic Acids.
Authors: SOLOSHONOK V. A. , GERUS I. I. , YAGUPOL'SKII YU. L. , KUKHAR' V. P. 
Published: May 2016

AbstractA novel method for the preparation of the title compounds (IV) is reported.
ChemInform Abstract: Nitroacetylene Equivalents. Preparation and Cycloadditions of 2‐Phenylsulfinyl‐1‐nitroalkenes.
Authors: JUNG M. E. , GROVE D. D. 
Published: May 2016

AbstractReaction of the N‐acylimidazoles (I) with the sodium salt (II) derived from nitromethane gives the nitro ketones (III) which are transformed into a mixture of the (phenylthio)nitroalkenes (VI) and (VII) via the nitro dithioacetals (V).
ChemInform Abstract: A Dual Regiocontrol in the Copper‐Catalyzed Grignard Reaction with Primary Allylic Acetates.
Authors: BAECKVALL J.‐E. + , SELLEN M. 
Published: May 2016

AbstractReaction of the allylic acetates (Ia) and (Ib) with the Grignard compound (II) yields mixtures of the adducts (III) and (IV).
ChemInform Abstract: The First Acid and Ester Enols: 2,2‐Bis(pentamethylphenyl)ethene‐1,1diol and 1‐tert‐Butoxy‐2,2‐bis(pentamethylphenyl)ethenol, and Their Oxidation to Stable Free Radicals.
Authors: O'NEILL P. , HEGARTY A. F. 
Published: May 2016

AbstractThe diarylacetic acid (I) and the diaryl ketene (VII) are converted to the trimethylsilyl enol ethers (V) and (X) which undergo fluoride induced desilylation, forming the enols (VI) or (XI).
ChemInform Abstract: The Silicon‐Modified Metal Ammonia Reduction of Aromatic Compounds.
Authors: RABIDEAU P. W. , KARRICK G. L. 
Published: May 2016

AbstractBirch reduction of the 1‐trimethylsilylnaphthalenes (I) yields predominantly the 1,4‐dihydro derivatives (II), together with minor amounts of the 3,4‐dihydro compounds (III) and the tetralins (IV).
ChemInform Abstract: 3‐Oxiranylprop‐2‐enals as Synthetic Building Blocks. A Facile Route to (.+‐.)‐Aucantene and Other Selectively Functionalized Cyclohexenes.
Authors: JAEKEL E. + , SCHNEIDER M. P. 
Published: May 2016

AbstractEpoxidation of but‐2‐enal followed by Wittig reaction gives the racemic methyloxiranylpropenal (II) which reacts with buta‐1,3‐diene (I) to form the cycloadduct (III).
ChemInform Abstract: ortho‐Functionalization of Aryl Ketones with Alkenes. Synthesis of 3‐Methylindene‐2‐carboxylates and 3‐Substituted 2‐Acetylthiophenes from η2‐(o‐Acetylaryl)tetracarbonylmanganese Compounds with Alkenes in the Presence of Palladium(II).
Authors: GOMMANS L. H. P. , MAIN L. , NICHOLSON B. K. 
Published: May 2016

AbstractPalladium(II)‐promoted cyclization of the o‐acetylarylmanganese compounds (I) and (IV) with methyl acrylate (II) gives the indenecarboxylic acid esters (III) or the bicyclic thiophene (V).
ChemInform Abstract: Thermal Rearrangement of 3H‐Pyrroles by Competitive (1,5)‐Sigmatropic Shifts, and the Reversibility of the 3H‐ to 2H‐Pyrrole Interconversion.
Authors: CHIU P.‐K. , SAMMES M. P. 
Published: May 2016

AbstractThe diketo esters (I) react with liquid ammonia, forming the dihydropyrroles (II) and (III) which are converted to the derivatives (IV) ‐ (VI) by dehydration on alumina.
ChemInform Abstract: The Reactions of Electron‐Rich Heterocycles with Derivatives of Orthocarboxylic Acids. Part 8. Proton Acid‐Catalyzed Acylation of Indoles by 2‐Alkoxy‐1,3‐dioxolanes.
Authors: AKGUEN E. + , TUNALI M. , PINDUR U. 
Published: May 2016

AbstractThe acid‐catalyzed reactions of the 3‐unsubstituted indoles (II) with the 2‐alkoxydioxolanes (I) form the tris(indolyl)methanes (III), the bis(indolyl)ethenes (IV), or the 3‐benzoylindoles (V), depending on the substitution patterns.
ChemInform Abstract: Synthesis and Antifungal Activities of N‐Arylideneaminoimidazole Derivatives.
Authors: COCCO M. T. , CONGIU C. , PLUMITALLO A. , SCHIVO M. L. , PALMIERI G. 
Published: May 2016

AbstractThe title compounds (VI) are synthesized by reacting the acetylamidrazones (I) with the α‐halo ketones (II).
ChemInform Abstract: Photosensitized Single Electron Transfer Oxidation of Hydroxylamines: A Convenient Synthesis of Cyclic Nitrones.
Authors: PANDEY G. , KUMARASWAMY G. , KRISHNA A. 
Published: May 2016

AbstractThe cyclic hydroxylamines (I) are irradiated in the presence of 1,4‐dicyanonaphthalene to give the nitrones (II) which are not isolated but trapped with dimethyl fumarate (III) to yield the adducts (IV).
ChemInform Abstract: Stereoselective Radical Reactions with Enolones.
Authors: GIESE B. , WITZEL T. 
Published: May 2016

AbstractThe stereochemistry of the radical‐induced coupling of the cyclic enolones (II) or (VIII) with the alkyl iodides (I) is investigated: (II) and (Ia) yield a mixture of the diastereomeric tetrahydropyranones (III) and (IV) which undergo an elimination reaction to form the enolone (Va).
ChemInform Abstract: The cis‐Cyclooct‐4‐enyl Radical is Reluctant to Rearrange.
Authors: BLOODWORTH A. J. , CRICH D. , MELVIN T. 
Published: May 2016

AbstractThe O‐acyl thiohydroxamate (Id) is prepared from the bromide (Ia) via the nitrile (Ib) and the acid (Ic).
ChemInform Abstract: Intramolecular Alkylations of Aromatic Compounds. Part 18. Synthesis of 3,4‐Dihydro‐1′‐methylspiro(naphthalene‐1(2H),4′‐piperidines).
Authors: REIMANN E. , SPECKBACHER J. , LOTTER H. 
Published: May 2016

AbstractCyclization of the tetrahydropyridines (VI), prepared from the pyridinecarbonitriles (I) and the Grignard reagents (II), yields the spiro compounds (VII) stereoselectively.
ChemInform Abstract: Semi‐Rigid Models of Butyrophenones: trans‐Phenyl(2‐(1‐piperidinylmethyl)cyclopentyl)methanone.
Authors: CAAMANO O. , EIRIN A. , FERNANDEZ F. , URIARTE E. 
Published: May 2016

AbstractStarting with cyclopentanone (I) and piperidine hydrochloride (II), the title compound (IX) is synthesized as outlined in the reaction scheme.
ChemInform Abstract: Base‐Initiated Reactions of N‐Fluoropyridinium Salts. A Novel Cyclic Carbene Proposed as a Reactive Species.
Authors: UMEMOTO T. , TOMIZAWA G. 
Published: May 2016

AbstractN‐Fluoropyridinium triflate (I) reacts with triethylamine in the presence of dichloro‐ or dibromomethane (II) to give the 2‐substituted pyridines (III) ‐ (V).
ChemInform Abstract: Synthesis and Pharmacological Activity of Stereoisomeric trans‐Decahydroquinoline Derivatives.
Authors: FISHCHUK E. V. , PRALIEV K. D. , ARAKELOVA V. V. , SOKOLOV D. V. , FILIMONOVA L. A. , KONDRATENKO E. L. , UTENBERGENOVA R. K. , KADYROVA D. M. , NURAKHOVA T. G. 
Published: May 2016

AbstractN‐Alkylation and subsequent O‐benzoylation of the decahydroquinolinols (I) give the derivatives (V).
ChemInform Abstract: Reactions of Heterocycles Containing the 2‐Acyl‐2‐propenone Structure. Part 4. Synthesis of Pyridine Derivatives from 4‐Hydroxy‐2‐oxo‐2H‐chromene‐3‐carbaldehydes and Enamines.
Authors: HEBER D. 
Published: May 2016

AbstractThe coumarin‐3‐carbaldehydes (I) react with the cyanoenamine (II) to give the pyridocoumarins (III).
ChemInform Abstract: Synthesis and Biological Activity of 6‐Methoxy‐1H‐1,2‐diazaphenalene Derivatives.
Authors: ELISEVICH D. M. , OKOLELOVA M. S. , KAZAKOV A. L. , DROGOVOZ S. M. , POROKHNYAK L. A. , ROGOZHIN B. A. 
Published: May 2016

AbstractThe diazaphenalene derivatives (III) are prepared by cyclization of the hydroxy ketones (I) with the hydrazines (II).
ChemInform Abstract: Synthesis and Antiviral Activity of 2‐(3‐Aryloxy‐ and 2‐(3‐Arylamino‐2‐hydroxypropylamino)pyrimidines and Their Acyclic Analogues.
Authors: STANKYAVICHENE L. M. M. , STANKYAVICHYUS A. P. , SAPRAGONENE M. S. , RISYALIS S. P. , TERENT'EV P. B. , AZHAMI KH. S. , VLADYKO G. V. , KOROBCHENKO L. V. , BORENKO E. I. 
Published: May 2016

AbstractCoupling of the substituted guanidines (I) with acetylacetone (II) gives the corresponding pyrimidines (III).
ChemInform Abstract: Trichomonacidal Agents. Part 3. Aryloxychloro‐1,3,5‐triazines.
Authors: KREUTZBERGER A. , ROSE U. 
Published: May 2016

AbstractReaction of the dichlorotriazine (I) with the phenols (IIa) ‐ (IIc) at low temperature leads to the formation of the monoaryloxytriazines (III).
ChemInform Abstract: α‐(1H‐Imidazol‐1‐ylmethylene) Ketones with Antimycotic Activity.
Authors: MOSTI L. , SCHENONE P. , MENOZZI G. , PESCE SCHITO A. , DEBBIA E. 
Published: May 2016

AbstractStarting with the heterocyclic α‐hydroxymethylene ketones (I), the title compounds (III) are prepared by reaction with 1,1'‐carbonyldiimidazole (II).
ChemInform Abstract: Synthesis and Antispasmodic Activity of New Derivatives of Dibenzo‐18‐ crown‐6.
Authors: IVANOV E. I. , POLISHCHUK A. A. , KARASEVA T. L. , IVANOVA R. YU. 
Published: May 2016

AbstractThe crown ethers (II), (III), (V), and (VI) anellated by heterocycles are prepared from the amino substituted dibenzo‐18‐crown‐6 (Ia) by known methods.
ChemInform Abstract: Utilization of Me3SiI Prepared in situ for the Preparation of 1,3‐Bis‐(trimethylsilyloxy)diene.
Authors: BABOT O. , CAZEAU P. , DUBOUDIN F. 
Published: May 2016

AbstractSilylation of the diketones (I) with trimethylsilyl iodide, which is prepared in situ from Me3SiCl (II) and NaI, yields the bis(silyl ethers) (III).
ChemInform Abstract: Silicon‐Nitrogen Compounds. Part 163. Compounds with BNSi Structure Fragments.
Authors: WANNAGAT U. , BOETTCHER B. + , SCHMIDT P. , EISELE G. 
Published: May 2016

AbstractSome formerly unknown compounds with BNSi structure fragments such as (IV), (VI), (IX), (XI), (XIV), (XVI), (XVIII), and (XXI) are prepared according to the scheme.
ChemInform Abstract: Solution Phase Photochemical Hydrosilylation of Silylacetylenes.
Authors: STEINMETZ M. G. , MAYES R. T. , UDAYAKUMAR B. S. 
Published: May 2016

AbstractIrradiation of the disilaalkynes (I) gives the cyclization products (IIa) and (III) and the dihydro derivative (IVb).
ChemInform Abstract: Fluorination of Trimethylsilyl Phosphites and Their Structural Analogues by Sulfuryl Chloride Fluoride. A Facile Preparation of Phosphorofluoridates and Related Compounds.
Authors: DABKOWSKI W. , MICHALSKI J. 
Published: May 2016

AbstractThe phosphorofluoridates (III) are prepared by treatment of the trimethylsilyl esters (I) with sulfuryl chloride fluoride (II).
ChemInform Abstract: Remarkable Enantioselective 1,4‐Addition Reactions of Chiral Allylphosphonyl Anions (Ambident Nucleophiles) with Cyclic Enones (Ambident Electrophiles).
Authors: HUA D. H. , CHAN‐YU‐KING R. , MCKIE J. A. , MYER L. 
Published: May 2016

AbstractThe anions of the chiral allyl phosphonyl compounds (III), (IV) and (VI), (VII) (prepared from the components (I) and (II) or (V), respectively) undergo enantioselective 1,4‐addition reactions with cyclic enones such as (IX) to give the compounds (VIIIa), (VIIIb) (from (III)), (VIIIc), (VIIId) (from (VI)), (Xa), (Xb) (from (IV)), or (Xc), (Xd) (from (VII)).
ChemInform Abstract: Synthesis and Reactions Behavior of 2,2‐Dithiophospholes and 2,2‐Dithiophosphorinanes.
Authors: DONATH CH. , MEISEL M. 
Published: May 2016

AbstractThe preparation of the five‐ or six‐membered cyclic dithiophosphates (I) and (II) occurs by 1:1 molar reaction of the dithiophosphoric acid chloride betaine (III) with corresponding bifunctional aromatic or aliphatic nucleophiles in the presence of a tert. amine such as demonstrated for some examples.
ChemInform Abstract: Synthesis, Properties and NMR Spectroscopic Studies of 2,4‐Dithioxo‐2,4‐dimercapto‐1,3‐diaza‐2λ5,4λ5‐diphosphetidines.
Authors: PRIHODA J. , GROSSMANN G. , OHMS G. , MEISEL M. 
Published: May 2016

AbstractThe 1:1 molar reaction of the phosphoric acid halide betaines (I) with hexamethyl disilazane (II) yields the pyridinium salt (III) of the disilylated title compound.
ChemInform Abstract: 1‐Chloro‐1‐phosphiranes.
Authors: MAERKL G. + , HOELZL W. + , TROETSCH‐SCHALLER I. + 
Published: May 2016

Abstract(3 + 2)‐Cycloaddition of 1‐chloro‐2‐phenyl‐2‐trimethylsilyl‐1‐phosphaethene (I) with the disubstituted diazomethanes (II) produces the cycloadducts (III) which release nitrogen, forming the 1‐chloro‐1‐phosphiranes (IV).
ChemInform Abstract: Reaction of the Superacid HGeCl3 with Aromatic Compounds. Part 5. Hydrogermylation of Benzene, Toluene, m‐Xylene and Mesitylene Under High Pressure.
Authors: KOLESNIKOV S. P. , LYUDKOVSKAYA I. V. , POVAROV S. L. , MAKAROVA Z. G. , ZHULIN V. M. , NEFEDOV O. M. 
Published: May 2016

AbstractMesitylene (I), m‐xylene (V), toluene (VIII), and benzene (XI) react with trichlorogermane (II) under high pressure to give the bis‐ and tris(trichlorogermyl)cyclohexenes, e.g. (III), or the corresponding cyclohexanes which are converted to the permethylated products (IV), (VI), (VII), (IX), (X), (XII), (XIII), and (XIV) after isolation or in situ by reaction with methylmagnesium bromide.
ChemInform Abstract: The Diastereoselective Functionalization of Arene Tricarbonylchromium Complexes Containing a Benzylic Heteroatom Substituent.
Authors: BLAGG J. , DAVIES S. G. , GOODFELLOW C. L. , SUTTON K. H. 
Published: May 2016

AbstractTreatment of (S)‐(I) with BuLi or tBuLi gives rise to highly regioselective ortho deprotonation via coordination of the base to the benzylic N atom.
ChemInform Abstract: Transition Metal Mediated Organic Synthesis: The Synthesis of Moracin M.
Authors: CLOUGH J. M. , MANN I. S. , WIDDOWSON D. A. 
Published: May 2016

AbstractThe halobenzofuran (Ia) is coupled with the tricarbonylchromium metalloarene (IIa) in the presence of Pd(0) to yield the complexed benzofuranylarene (IIIa).
ChemInform Abstract: Preparation, Chemical and Structural Characterization of Tungsten(III) Coordination Compounds: WCl3Pic3, WCl3Pic3·1/2 Pic, and (Pic)2HWCl4Pic2 (Pic: 4‐Methylpyridine).
Authors: BRENCIC J. V. , CEH B. , LEBAN I. 
Published: May 2016

AbstractThe complex (II) (no yield given) crystallizes in the space group P1 with Z=2.
ChemInform Abstract: Preparation and Characterization of Mononuclear Organoimido Complexes of Tungsten: X‐Ray Crystal Structures of (WCl4(NC6H4Me‐p)(thf)), (P(CH2Ph)Ph3) (WCl5(NC6H4Me‐p)), and (WCl2(NPh)2(bipy)).
Authors: BRADLEY D. C. , ERRINGTON R. J. , HURSTHOUSE M. B. , SHORT R. L. , ASHCROFT B. R. , CLARK G. R. , NIELSON A. J. , RICKARD C. E. F. 
Published: May 2016

AbstractThe mononuclear organoimido‐W(VI) complexes (I)‐(IV) are prepared according to the scheme and characterized by spectroscopic (IR, 1H, 13C NMR) data as well as by X‐ray structure analysis of the title complexes (Ia) (space group P21/n, Z=4), (IIa) (P21/a, Z=4), and (IIIa) (P1, Z=4).
ChemInform Abstract: Alkylation of Tricarbonyliron Complexes by Trimethylsilyl Cyanide: Synthetic and Kinetic Studies.
Authors: ALEXANDER R. P. , JAMES T. D. , STEPHENSON G. R. 
Published: May 2016

AbstractTrimethylsilyl cyanide (II) is a synthetically useful reagent for the alkylation of the complexes (I) and (IV), particularly in cases where the reactive terminus of the dienyl system bears an alkyl substituent.
ChemInform Abstract: Homolytic Displacement at Carbon Centres. Part 7. Regiospecific Formation of N‐Allyl and N‐Cyclopropylcarbinyl Sulfonamides and of Allylic and Cyclopropyl Halides in the Reaction of N‐Halogeno Compounds with Organocobaloximes.
Authors: JOHNSON M. D. , LAMPMAN G. M. , KOOPS R. W. , GUPTA B. D. 
Published: May 2016

AbstractReaction of the alkenylcobaloximes (I), (IV), or (VI) with the N‐chlorosulfonamides (II) yields the N‐cyclopropylmethylsulfonamides (III), the N‐allyl derivatives (V), or the N‐alkynyl derivatives (VII).
ChemInform Abstract: Chalcogenolates. Part 179. Copper(I) Thioxanthates and Thioxanthatocuprates(I).
Authors: GATTOW G. , MUELLER H. + 
Published: May 2016

AbstractCu(I) thioxanthates (I) are prepared by reaction of aqueous Cu(II) salt solutions with the corresponding alkalimetalthioxanthates or by reaction of CuI with excess thioxanthate ions in abs.
ChemInform Abstract: Redox‐State‐Dependent Preferential Solvation of Ruthenium(II) and Ruthenium(III) Ammine Complexes. Implications for Electron‐Transfer Processes in Mixed Solvents.
Authors: ENNIX K. S. , MCMAHON P. T. , DE LA ROSA R. , CURTIS J. C. 
Published: May 2016

AbstractPreferential solvation of the asym.
ChemInform Abstract: Generation of Mono‐ and Dianions of 1,4‐Diphenyl‐2‐tetrazene by Nonoxidative N‐N Bond Formation. A Novel Route to a 2‐Tetrazene, a Silacyclotetrazene, and the Tetrazenide Complex (1,4‐Diphenyltetrazenido)bis(triethylphosphine)‐palladium.
Authors: LEE S. W. , MILLER G. A. , CAMPANA C. F. , MACIEJEWSKI M. L. , TROGLER W. C. 
Published: May 2016

AbstractThe complex (III) (yield in g) serves as a convenient source of PhN4Ph dianion.
ChemInform Abstract: Synthesis and Reactions of Palladium‐Iron Carbonyl Complexes Containing Bridging Ph2PCH2PPh2 Ligands.
Authors: JACOBSEN G. B. , SHAW B. L. 
Published: May 2016

AbstractIn THF generated FeI2 (I) reacts with two equiv. of the diphosphine (II) under an atmosphere of CO (III) to give the trans,mer‐Fe complex (IV).