bluuebunny/crossref_metadata_2025_split huggingface dataset:
Modeling Cities and Regions as Complex Systems
Authors: White Roger , Engelen Guy , Uljee Inge 
Published: May 2016

The theory and practice of modeling cities and regions as complex, self-organizing systems, presenting widely used cellular automata-based models, theoretical discussions, and applications.
Cities and regions grow (or occasionally decline), and continuously transform themselves as they do so. This book describes the theory and practice of modeling the spatial dynamics of urban growth and transformation. As cities are complex, adaptive, self-organizing systems, the most appropriate modeling framework is one based on the theory of self-organizing systems—an approach already used in such fields as physics and ecology. The book presents a series of models, most of them developed using cellular automata (CA), which are inherently spatial and computationally efficient. It also provides discussions of the theoretical, methodological, and philosophical issues that arise from the models. A case study illustrates the use of these models in urban and regional planning. Finally, the book presents a new, dynamic theory of urban spatial structure that emerges from the models and their applications.
The models are primarily land use models, but the more advanced ones also show the dynamics of population and economic activities, and are integrated with models in other domains such as economics, demography, and transportation. The result is a rich and realistic representation of the spatial dynamics of a variety of urban phenomena. The book is unique in its coverage of both the general issues associated with complex self-organizing systems and the specifics of designing and implementing models of such systems.
Make It New
Authors: Katz Barry M. 
Published: May 2016

The role of design in the formation of the Silicon Valley ecosystem of innovation.
California's Silicon Valley is home to the greatest concentration of designers in the world: corporate design offices at flagship technology companies and volunteers at nonprofit NGOs; global design consultancies and boutique studios; research laboratories and academic design programs. Together they form the interconnected network that is Silicon Valley. Apple products are famously “Designed in California,” but, as Barry Katz shows in this first-ever, extensively illustrated history, the role of design in Silicon Valley began decades before Steve Jobs and Steve Wozniak dreamed up Apple in a garage.
Offering a thoroughly original view of the subject, Katz tells how design helped transform Silicon Valley into the most powerful engine of innovation in the world. From Hewlett-Packard and Ampex in the 1950s to Google and Facebook today, design has provided the bridge between research and development, art and engineering, technical performance and human behavior. Katz traces the origins of all of the leading consultancies—including IDEO, frog, and Lunar—and shows the process by which some of the world's most influential companies came to place design at the center of their business strategies. At the same time, universities, foundations, and even governments have learned to apply “design thinking” to their missions. Drawing on unprecedented access to a vast array of primary sources and interviews with nearly every influential design leader—including Douglas Engelbart, Steve Jobs, and Don Norman—Katz reveals design to be the missing link in Silicon Valley's ecosystem of innovation.
Comprehensive Evaluation for Obesity: Beyond Body Mass Index
Authors: Cetin Derrick , Lessig Bailey A. , Nasr Elie 
Published: May 2016

Abstract
Many factors contribute to the diagnosis of obesity in a patient. Anthropometric measurements, such as the waist circumference and percentage of body fat, are used in the newly released obesity algorithm to risk stratify patients. Staging methods, which use the identification of comorbidities and disease burden to assess the severity of obesity, can result in treating a patient sooner than if the traditional body mass index is used. Obesity is a growing concern in the medical field, and providing additional avenues through which to diagnose obesity and address obesity-related health risks can improve prevention efforts and lead to expedited weight management. Obesity is a growing concern in the medical field, and providing additional avenues through which to diagnose obesity and address obesity-related health risks can improve prevention efforts and lead to expedited weight management.
Melt‐rock interactions and fabric development of peridotites from North Pond in the Kane area, Mid‐Atlantic Ridge: Implications of microstructural and petrological analyses of peridotite samples from IODP Hole U1382A
Authors: Harigane Yumiko , Abe Natsue , Michibayashi Katsuyoshi , Kimura Jun‐Ichi , Chang Qing 
Published: May 2016

AbstractNorth Pond is an isolated sedimentary pond on the western flank of the Kane area along the Mid‐Atlantic Ridge. Drill‐hole U1382A of IODP Expedition 336 recovered peridotite and gabbro samples from a sedimentary breccia layer in the pond, from which we collected six fresh peridotite samples. The peridotite samples came from the southern slope of the North Pond where an oceanic core complex is currently exposed. The samples were classified as spinel harzburgite, plagioclase‐bearing harzburgite, and a vein‐bearing peridotite that contains tiny gabbroic veins. No obvious macroscopic shear deformation related to the formation of a detachment fault was observed. The spinel harzburgite with a protogranular texture was classified as refractory peridotite. The degree of partial melting of the spinel harzburgite is estimated to be ∼17%, and melt depletion would have occurred at high temperatures in the uppermost mantle beneath the spreading axis. The progressive melt–rock interactions between the depleted spinel harzburgite and the percolating melts of Normal‐Mid Ocean Ridge Basalt (N‐MORB) produced the plagioclase‐bearing harzburgite and the vein‐bearing peridotite at relatively low temperatures. This implies that the subsequent refertilization occurred in an extinct spreading segment of the North Pond after spreading at the axis. Olivine fabrics in the spinel and plagioclase‐bearing harzburgites are of types AG, A, and D, suggesting the remnants of a mantle flow regime beneath the spreading axis. The initial olivine fabrics appear to have been preserved despite the later melt–rock interactions. The peridotite samples noted above preserve evidence of mantle flow and melt–rock interactions beneath a spreading ridge that formed at ∼8 Ma.
Resolution dependence of precipitation statistical fidelity in hindcast simulations
Authors: O'Brien Travis A. , Collins William D. , Kashinath Karthik , Rübel Oliver , Byna Suren , Gu Junmin , Krishnan Hari , Ullrich Paul A. 
Published: May 2016

AbstractNumerous studies have shown that atmospheric models with high horizontal resolution better represent the physics and statistics of precipitation in climate models. While it is abundantly clear from these studies that high‐resolution increases the rate of extreme precipitation, it is not clear whether these added extreme events are “realistic”; whether they occur in simulations in response to the same forcings that drive similar events in reality. In order to understand whether increasing horizontal resolution results in improved model fidelity, a hindcast‐based, multiresolution experimental design has been conceived and implemented: the InitiaLIzed‐ensemble, Analyze, and Develop (ILIAD) framework. The ILIAD framework allows direct comparison between observed and simulated weather events across multiple resolutions and assessment of the degree to which increased resolution improves the fidelity of extremes. Analysis of 5 years of daily 5 day hindcasts with the Community Earth System Model at horizontal resolutions of 220, 110, and 28 km shows that: (1) these hindcasts reproduce the resolution‐dependent increase of extreme precipitation that has been identified in longer‐duration simulations, (2) the correspondence between simulated and observed extreme precipitation improves as resolution increases; and (3) this increase in extremes and precipitation fidelity comes entirely from resolved‐scale precipitation. Evidence is presented that this resolution‐dependent increase in precipitation intensity can be explained by the theory of Rauscher et al. (), which states that precipitation intensifies at high resolution due to an interaction between the emergent scaling (spectral) properties of the wind field and the constraint of fluid continuity.
ChemInform Abstract: Cs2TlBr5 ‐ a Pentabromothallate(III) with Tetrahedral TlBr4 ‐ and Octahedral TlBr3‐ 6 Anions.
Authors: ZIMMERMANN K. , THIELE G. 
Published: May 2016

AbstractAddition of CsBr and HBr to an aqueous solution of TlBr3 yields Cs3Tl2Br9, which transforms within 1‐2 d into Cs2TlBr5 (yield in g).
ChemInform Abstract: The Influence of Substitution by Ions Having the Same Charge on the Luminescence‐Optical Properties of Ba0.9Eu0.1Mg2Al16O27.
Authors: NOETZOLD D. + , HERZOG G. , BRITZ A. 
Published: May 2016

AbstractIn the title phosphor, Sr has been substituted for Ba, Zn and/or Ca for Al, and Y or Gd for Al and the emission and excitation spectra of the substituted phosphors have been recorded.
ChemInform Abstract: Divalent Samarium: Synthesis and Crystal Structures of Sm4OCl6 (I) and KSm2Cl5 (II).
Authors: SCHLEID T. , MEYER G. 
Published: May 2016

AbstractSingle crystals of (I) and (II) have been prepared by metallothermic reductions of SmCl3 with Li (in the presence of Sm2O3 or SmOCl) and K, resp., in sealed tantalum tubes (I: 900 °C, 4 d, 750 °C, 6 d; II: 900 °C, 3 d, 750 °C, 4 d; fast cooling).
ChemInform Abstract: Applications of Cadmium NMR to Polycadmium Compounds. Part 5. Digonally Coordinated Halide Whithin an Octametal Cage. Crystal and Solution Structures of (XCd8(SCH2CH2OH)12X3), X: Cl, Br, I.
Authors: DANCE I. G. , GARBUTT R. G. , CRAIG D. C. 
Published: May 2016

AbstractThe iodo compound (IV) is known.
ChemInform Abstract: Promoter Effect of Iron on Olefin Hydroformylation Catalyzed by SiO2‐Supported Rhodium‐Iron Bimetallic Carbonyl Clusters: Rh‐Fe3+ Bimetallic Activation of Catalytic CO Insertion.
Authors: FUKUOKA A. , ICHIKAWA M. , HRILJAC J. A. , SHRIVER D. F. 
Published: May 2016

AbstractBimetallic Rh‐Fe3+ ensembles appear to be generated from the Rh‐Fe carbonyl clusters (I)‐(IV) supported on SiO2.
ChemInform Abstract: Electrocyclic Opening of 2,3‐Benzo‐ and 2,3;7,8‐Dibenzobicyclo(4.2.0)octa‐2,4,7‐triene; Benzoanellated Transition States.
Authors: GRIMME W. , LEX J. , SCHMIDT T. 
Published: May 2016

AbstractThe tricyclic compound (IV) is prepared in accordance with the scheme and isomerizes to give (VI).
ChemInform Abstract: A Photochemical Approach to the Bicyclo(5.3.1)undecane Ring System of Taxane Diterpenes.
Authors: BENCHICK‐LE‐HOCINE M. , DO KHAC DUC DO KHAC DUC , FETIZON M. , HANNA I. , ZEGHDOUDI R. 
Published: May 2016

AbstractThe bicyclic 1,3‐dione (I) undergoes addition reaction with allene (II) on irradiation in methanol to give the regioisomeric adducts (III) and (IV) which are formed via the enol of (I).
ChemInform Abstract: Question of 1,4‐Diradical Intermediates in the Di‐π‐methane Rearrangement of Benzobicyclo(3.2.1)octadienes: Azoalkanes as Mechanistic Probes.
Authors: ADAM W. , DOERR M. + , KRON J. , ROSENTHAL R. J. 
Published: May 2016

AbstractNitrogen extrusion of the azo compounds (I) gives as major products (II); the minor products (III) and (IV) on irradiation also give the benzocyclooctenes (II).
ChemInform Abstract: Carbene Rearrangements. Part 23. Reactions of 2,2,4,4‐Tetramethyl‐3‐methylenecyclobutylidene (V); Thermal Rearrangements of a 2‐Methylenebicyclo(2.1.0)pentane (VIII).
Authors: BRINKER U. H. , ERDLE W. 
Published: May 2016

AbstractThe mechanism and course of the pyrolysis (and photolysis as well, leading to the major compounds (VII) and (VIII) in yields of 40 and 35%, resp.) of the diazo compound (IV) (half‐life ca. 6700 s at 31.5 °C) is studied; the hydrocarbons (VII)‐(XIII) are obtained in a total yield of 72%.
ChemInform Abstract: Phase‐Transfer Permanganate Oxidation of Unfunctionalized Benzylic Positions.
Authors: GANNON S. M. , KRAUSE J. G. 
Published: May 2016

AbstractThe benzylic methylene groups in (I) and the benzylic alcohols (III) are oxidized with potassium permanganate under phase‐transfer conditions to give the ketones (II).
ChemInform Abstract: Selective Reduction of Conjugated Ethylenic Linkage in the Presence of Ion‐Exchange Resin Bound Borohydride.
Authors: NAG A. , SARKAR A. , SARKAR S. K. , PALIT S. K. 
Published: May 2016

AbstractSodium borohydride fixed on a polystyrene resin is employed as a reagent for the hydrogenation of the α,β‐unsaturated esters (I), yielding the saturated esters (II).
ChemInform Abstract: Kinetics and Mechanisms of Metal Reduction by Hemoglobin. Part 1. Reduction of Iron(III) Complexes.
Authors: EGUCHI L. A. , SALTMAN P. 
Published: May 2016

AbstractThe kinetics of the reduction of Fe(III) complexes of cyanide, nitrilotriacetate, citrate, EDTA, 2,3‐diphosphoglyceric acid and inorganic pyrophosphate by deoxyhemoglobin present in equilibrium with oxyhemoglobin can be described by two possible electron‐transfer mechanisms.
ChemInform Abstract: Gas Phase Reactions. Part 60. Methanimines RR′C=NR′′: Preparation and Photoelectron Spectra.
Authors: BOCK H. , DAMMEL R. 
Published: May 2016

AbstractAll 6 methanimines (IVa) and the hitherto unknown cyclopropanimine (IVb) are prepared by consecutive chlorination of gaseous alkylamines (I) and dehydrochlorination of the resulting N‐chloroamines (II) (isolable in high purity (yields up to 80%) but explosive in condensed phase) in one step (two‐bed flow reactor; yields up to 96%) and/or by pyrolyses of azides (III).
ChemInform Abstract: Pyridine N‐Oxides as Catalysts for Thione‐Thiol Rearrangement.
Authors: HARANO K. , SHINOHARA I. , MURASE M. , HISANO T. 
Published: May 2016

AbstractThe O,S‐dialkyl dithiocarbonates (I) rearrange in the presence of pyridine N‐oxide, yielding the S,S‐dialkyl dithiocarbonates (II).
ChemInform Abstract: Methylenecyclopropanes. Part 9. Methylenecyclopentanes by Metal‐Catalyzed (3 + 2) Cycloaddition of 1‐Methylene‐2‐(trimethylsilyl)cyclopropane with Electron‐Deficient Olefins.
Authors: BINGER P. , STERNBERG E. , WITTIG U. 
Published: May 2016

AbstractThe palladium‐catalyzed (3 + 2) cycloaddition between the title compound (I) and the electron‐deficient olefins (II), (VI) or (X) leads to the cyclopentanes (III), (IV), (VII), (VIII), (XI) and (XII) together with minor amounts of the regioisomers (V), (IX) and (XIII) ((IX) and (XIII) are single isomers with regard to the stereochemistry of the SiMe3 group).
ChemInform Abstract: Double Diastereoselection Operative During π‐Facially Selective Addition of Chiral 1‐Cyclopentenyllithium Reagents to (7R*)‐7‐Methyl‐7‐vinylbicyclo(3.2.0)hept‐2‐en‐6‐one.
Authors: PAQUETTE L. A. , LEARN K. S. , ROMINE J. L. 
Published: May 2016

AbstractThe vinylbicycloheptenone (I) is allowed to react with the cyclopentenyllithium compounds (II), (V), and (VIII), yielding the fused cyclooctenones (III) and (IV), (VI) and (VII), or (IX) and (X).
ChemInform Abstract: A Simple Synthesis of Macrocyclic Hydrocarbons by Metathesis of Cycloolefins.
Authors: WARWEL S. , KAETKER H. + 
Published: May 2016

AbstractThe macrocyclic dienes (II) are obtained by metathesis of the cycloalkenes (I) using rhenium heptoxide on alumina, activated by tetramethyltin.
ChemInform Abstract: Generation and (4 + 3) Cycloaddition of Cyclopentenylium‐2‐olate from 2‐Chlorocyclopentanone Under Alcoholysis Conditions.
Authors: FOEHLISCH B. + , JOACHIMI R. 
Published: May 2016

AbstractThe chlorocyclopentanone (Ia) undergoes methanolysis or trifluoroethanolysis to form the cyclopentanones (Ib) or (Ic).
ChemInform Abstract: Synthesis of Alkene‐Substituted Pentacyclo(5.4.0.02,6.03,10.05,9)undecanes. Part 2. Photoelectron Spectra and Electronic Structures of Substituted Pentacyclo(5.4.0.02,6.03,10.05,9)undecanes.
Authors: MARCHAND A. P. , HUANG C. , KAYA R. , BAKER A. D. , JEMMIS E. D. , DIXON D. A. 
Published: May 2016

AbstractPhotoelectron spectra are obtained for all (I).
ChemInform Abstract: An Efficient Route to Aminoanthraquinones and Derivatives via a Diels‐ Alder Reaction.
Authors: CHIGR M. , FILLION H. , ROUGNY A. 
Published: May 2016

AbstractThe 5‐hydroxynaphthoquinone derivatives (I) react with the aminodienes (II) to give the isomeric adducts (III) and (IV).
ChemInform Abstract: Preparation of an α,β‐Type of Ter‐ and Septithiophenes.
Authors: NAKAYAMA J. , MURABAYASHI S. , HOSHINO M. 
Published: May 2016

Abstract2‐Chloroacetylthiophene (III), prepared from thiophene (I), is transformed into the terthiophene (VIIa) by substitution reaction with sodium sulfide (IV), followed by reductive cyclization and acid‐catalyzed dehydration.
ChemInform Abstract: A Novel Synthesis of Benzofuran and Related Compounds. Part 4. The Vilsmeier Reaction of 3,5‐Dimethoxyphenylthiomethyl Compounds.
Authors: HIROTA T. , TASHIMA Y. , SASAKI K. , NAMBA T. , HAYAKAWA S. 
Published: May 2016

AbstractAlkylation of 3,5‐dimethoxythiophenol (I) with the halides (II) gives the phenylthiomethyl derivatives (III) which cyclize under Vilsmeier reaction conditions to produce a mixture of the benzothiophenes (V) ‐ (VII) or (VIII).
ChemInform Abstract: Methylthio‐ and Ethanediyldithio‐Substituted 1,6‐Dithiapyrenes and Their Charge‐Transfer Complexes: New Organic Molecular Metals.
Authors: NAKASUJI K. , SASAKI M. , KOTANI T. , MURATA I. , ENOKI T. , IMAEDA K. , INOKUCHI H. , KAWAMOTO A. , TANAKA J. 
Published: May 2016

AbstractThe bis(methylthio)dithiapyrene (I) gives 1:1 complexes with (IIa) (semiconductor), with (IIb) (metallic, sharp M‐I transition at 240 K, space group P1 with Z=1), with (IIc) (metallic, sharp M‐I transition at 125 K), with (III) and with (IV) (two crystalline phases; β‐form metallic, space group P1 with Z=1; α‐form semiconductor, space group P21/c with Z=4).
ChemInform Abstract: Reactions of Trialkyl(2‐ or 4‐quinolyl)borates.
Authors: ISHIKURA M. , ODA I. , KAMADA M. , TERASHIMA M. 
Published: May 2016

Abstract2‐Bromoquinoline (I) is lithiated and then allowed to react with the trialkylboranes (II) to yield the 2‐alkylquinolines (III) after work‐up with a basic hydrogen peroxide solution.
ChemInform Abstract: Basic Hydrolysis of Thioacetals: New Convenient Preparation of Acyl Meldrum′s Acid.
Authors: HUANG X. , CHEN B. 
Published: May 2016

AbstractHydrolysis of the methylthioalkylidene Meldrum's acids (II), readily prepared from (I) by a procedure published in a previous paper, yields the acyl Meldrum's acids (III).
ChemInform Abstract: Azo Bridges from Azines. Part 7. Diels‐Alder Reactions with Inverse Electron Demand Between Isopyrazoles and Cycloalkenes or Cycloalkadienes. ‐ A Comparison of Acid Catalysis and Acceleration by Pressure.
Authors: BECK K. , HUENIG S. + , KLAERNER F.‐G. + , KRAFT P. , ARTSCHWAGER‐PERL U. 
Published: May 2016

AbstractThe acid‐catalyzed reaction of the isopyrazoles (Ia) and (Ib) with cycloalkenes such as (II), (IV), (VII), (X) or (XIII) yields the expected azo‐bridged cycloadducts as exemplified in the scheme for the products (III), (V), (VIII), and (XI) from (Ia).
ChemInform Abstract: 4‐(Phenylthio)pyrrole‐3‐carboxylic Acid Esters.
Authors: EIDEN F. , GRUSDT U. 
Published: May 2016

AbstractThe furancarboxylate (I) is transformed into a diastereomeric mixture of the dimethoxyfuran (III) which releases methanol upon distillation to yield the methoxyfuran (IV).
ChemInform Abstract: Synthesis and Reactivity of 1‐(8‐Amino‐1‐naphthyl)‐1H‐1,2,3‐triazoles.
Authors: NAGAWA Y. , HONDA K. , NAKANISHI H. 
Published: May 2016

AbstractThe azidonaphthyltriazoles (I), prepared from 1,8‐diazidonaphthalene by cycloaddition with the corresponding acetylenecarboxylates, are hydrogenated and then reductively methylated to form the dimethylamino derivatives (IV).
ChemInform Abstract: Conformational Properties of the THYME Polyethers. The Bis‐THYME Cylinder: A Three‐Dimensional Analogue of 18‐Crown‐6.
Authors: WALBA D. M. , RICHARDS R. M. , HERMSMEIER M. , HALTIWANGER R. C. 
Published: May 2016

AbstractThe title compound (II) is characterized by molecular mechanics calculations and as the free ligand, as the toluene solvate, and as a novel cascade complex (K2(OH2)·(III))2+(PtCl3·DMSO)22‐ by means of crystal structures (space group of (II)·toluene: P1, Z=1 and P21/c, Z=2 for the other two cases).
ChemInform Abstract: Synthesis of α‐Telluro Ketones.
Authors: STEFANI H. A. , COMASSETO J. V. , PETRAGNANI N. 
Published: May 2016

AbstractThe ketones (I) undergo substitution reaction with p‐methoxyphenyltellurium trichloride (II) in refluxing benzene to form the α‐telluro ketone (III).
ChemInform Abstract: Synthesis, Structure, and Properties of 1,1,2,2‐Tetrahalo‐1,2‐digermacyclobut‐3‐ene Derivatives. The First Representatives of a New Class of Heterocycles.
Authors: KOLESNIKOV S. P. , EGOROV M. P. , GAL'MINAS A. M. , STRUCHKOV YU. T. , KREBS A. , NEFEDOV O. M. 
Published: May 2016

AbstractReaction of the thiacycloheptyne (I) with the dihalogermylenes (II) or (III) gives the fused digermacyclobutenes (IV).
ChemInform Abstract: Synthesis and Characterization of the Zwitter Ion S2C‐C(NMe2)2; a Transition Metal Induced C‐C Coupling. Complex Chemistry of the Zwitter Ions S2C‐C(NR2)2.
Authors: ZIEGLER M. L. , WEBER H. , NUBER B. , SERHADLE O. 
Published: May 2016

AbstractThe zwitter ion (III), prepared by the title reaction together with the unstable complex (IV), reacts with the Mo complexes (V) or (VIII) to give the dithiocarbamato complex (VIa) or (VIa) together with the novel cationic compound (IXa).
ChemInform Abstract: Multiple Bonds Between Main Group Elements and Transition Metals. Part 51. Alkyne Complexes of Rhenium in Intermediate Oxidation States; Synthesis and Molecular Structure of a Rhenium(V)‐Allylidene Complex.
Authors: HERRMANN W. A. , FISCHER R. A. , HERDTWECK E. 
Published: May 2016

AbstractThe Re(IV) complex (I) undergoes disproportionation on reaction with 2‐butyne (IIIa) to give the allylidene‐Re(V) complex (II) and the alkyne‐Re(III) complex (IVa) (yields given in mg).
ChemInform Abstract: Organyl Complexes of (η5‐Cyclopentadienyl)(triorganophosphane)iron.
Authors: LEHMKUHL H. , MEHLER G. , BENN R. , RUFINSKA A. , SCHROTH G. , KRUEGER C. + , RAABE E. 
Published: May 2016

AbstractA series of organyliron complexes of the type (I) are prepared either from the corresponding (η5‐cyclopentadienyl)bis(tert‐phosphane)iron chlorides and organomagnesium compounds or from (η5‐cyclopentadienyl)(1,5‐cyclooctadiene)‐FeLi, organic halide, and tert‐phosphane in very different yields.
ChemInform Abstract: Synthesis and Molecular Structure of a Dinuclear Quadruply Bridged Cobalt(II) Compound with a Short Metal‐Metal Bond, Co2((p‐CH3C6H4)NNN(p‐C6H4CH3))4.
Authors: COTTON F. A. , POLI R. 
Published: May 2016

AbstractThe diamagnetic title compound (I) is obtained as its THF solvate (I)·7 THF by 1:2 molar reaction of CoCl2 with the corresponding Li triazenide prepared in situ (THF, ‐78 °C).
ChemInform Abstract: Kinetics of 1,3‐Dipolar Cycloadditions of Dimethylacetylenedicarboxylate to Cobaloxime‐Azide, LCo(DH)2N3, Complexes.
Authors: HSIEH B. T. , TAKACH N. E. , MILOSAVLJEVIC E. B. , NELSON J. H. , KEMMERICH T. , BECK W. , BRESCIANI‐PAHOR N. , RANDACCIO L. , BROWER K. R. 
Published: May 2016

AbstractThe kinetics of the title reactions are studied by IR spectroscopy.
ChemInform Abstract: Metal Complexes as Ligands. Part 14. A New FeCu2 Heterotrinuclear Complex (Fe(Cuprp2en)2(ClO4)2(H2O)2). Definitive Evidence for a cis‐Octahedral Configuration and an Isosceles Triangular Arrangement of Metal Atoms.
Authors: BREWER G. A. , SINN E. 
Published: May 2016

AbstractThe synthesis of the trinuclear title complex (III) is carried out according to literature methods by reacting equimolar amounts of the complex ligand (I) with the iron perchlorate (II) (no yield given).