bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Structure of Phosphorus Oxynitride Glasses
Authors: BUNKER B. C. , TALLANT D. R. , BALFE C. A. , KIRKPATRICK R. J. , TURNER G. L. , REIDMEYER M. R. 
Published: May 2016

Abstracthas been investigated using a combination of solid‐state 31P, 15N, and 23Na NMR and Raman spectroscopy.
ChemInform Abstract: Nonlinear Electrical Properties of Grain Boundaries in an Oxygen‐Ion Conductor (CeO2·Y2O3).
Authors: TANAKA J. , BAUMARD J.‐F. , ABELARD P. 
Published: May 2016

AbstractThe well‐known impedance spectroscopy has been extended to the nonlinear region and a theoretical analysis of the ac response in the nonlinear region is presented.
ChemInform Abstract: Magnetic Properties of a Series of Novel Ternary Intermetallics (LnFe10V2).
Authors: DE BOER F. R. , HUANG Y. K. , DE MOOIJ D. B. , BUSCHOW K. H. J. 
Published: May 2016

AbstractThe ternary title compounds with Ln: Y, Nd, Sm, Gd‐Tm, Lu have been prepared by arc‐melting of a mixture of the elements and subsequent annealing at 850‐900 °C for two weeks.
ChemInform Abstract: Metal Carbonate Equilibria. Part 15. Beryllium(II)‐Water‐Carbon Dioxide(g) System in Acidic 3.0 mol dm‐3 Perchlorate Media.
Authors: BRUNO J. , GRENTHE I. , SANDSTROEM M. + , FERRI D. 
Published: May 2016

AbstractFrom e.m.f. measurements it is concluded that the predominant mixed complexes formed in the title system in the acid to neutral pH range have the stoichiometry (I) and (II), while (III) and (IV) are minor species (stability constants).
ChemInform Abstract: Electrochemical Redox Intercalation of Copper(I) Cation for CuxMo6S8 Superconductor Accompanied with a Reversible Structure Change.
Authors: INOUE T. , YAMASE T. 
Published: May 2016

AbstractElectrochemical polarization of CuxMo6S8 (I) electrodes (prepared by annealing mixtures of MoS2, Mo, and CuS) results in intercalation and deintercalation of Cu(I) which causes a deformative change in the crystal structure of the Chevrel phases.
ChemInform Abstract: Magnesium‐Based Hydrogen‐Storage Materials: Solvated Mg‐Ni by Metal Vapour Deposition.
Authors: IMAMURA H. , MURATA Y. , TSUCHIYA S. 
Published: May 2016

AbstractIt is demonstrated that solvated Mg‐Ni alloy (88‐94 wt.% Mg, 0.6‐6 wt.% Ni), prepared by dispersing metal atoms in a frozen organic matrix by metal vapor deposition, exhibits an exceptionally active hydrogenation capability under mild conditions.
ChemInform Abstract: Conformational Analysis for the Pseudooctahedral Complexes (η5‐C5H5)Fe(CO)(PPh3)CH2R (R: Me, Et, i‐Pr, t‐Bu, SiMe3, (PMe3)+, (PPh3)+, Mesityl, Ph, Vinyl, 1‐Naphthyl): X‐Ray Crystal Structures of (η5‐C5H5)Fe(CO)(PPh3)CH2R (R: Me, SiMe3).
Authors: DAVIES S. G. , DORDOR‐HEDGECOCK I. M. , SUTTON K. H. , WHITTAKER M. 
Published: May 2016

Abstract1H NMR spectroscopic analysis, including variable temp. studies, indicates for the complexes (Ia)‐(Id) where R is nonplanar that only one conformation, that where the R group resides in the space between the cyclopentadienyl ligand and the CO ligand, is populated.
ChemInform Abstract: Surface‐Specific Cleavage of a Cationic Carbonate‐Functionalized Vesicular Surfactant.
Authors: MOSS R. A. , BHATTACHARYA S. , SCRIMIN P. , SWARUP S. 
Published: May 2016

AbstractVesicles created at pH 4 from the surfactant (VIII) give rapid partial p‐nitrophenol release at pH 8, attributed to site‐specific hydrolysis of exovesicular p‐nitrophenyl carbonate moieties.
ChemInform Abstract: One‐Electron Oxidation Equilibria for Acylated Hydrazines.
Authors: NELSEN S. F. , BLACKSTOCK S. C. , PETILLO P. A. , AGMON I. , KAFTORY M. 
Published: May 2016

AbstractVertical ionization potentials (measured by photoelectron spectroscopy) and formal oxidation potentials (cyclic voltammetry) are reported for (I)‐(VI); X‐ray crystal structures are given for (III) (space group P2/n with Z=2) and (V) (space group P21/n), ESR data are given for the cation radicals of (IV)‐(VI).
ChemInform Abstract: Catalytic Hydrodeoxygenation of Dibenzofuran.
Authors: LAVOPA V. , SATTERFIELD C. N. 
Published: May 2016

AbstractDibenzofuran (I) dissolved in C16‐paraffin and hydrogen gas at 350 ‐ 390°C and 7 MPa are passed through a tube with a fixbed catalyst of NiMo/Al2O3.
ChemInform Abstract: Are Aroylnitrenes Ground‐State Singlets? Photochemistry of β‐Naphthoyl Azide.
Authors: AUTREY T. , SCHUSTER G. B. 
Published: May 2016

AbstractBoth direct‐irradiation and triplet‐sensitized photolyses of Ar‐CO‐N3 (Ar: β‐naphthyl) give (Ar‐CO‐N:)‐derived products indicative of reaction only from the singlet state of (Ar‐CO‐N:).
ChemInform Abstract: An Unexpected Synthesis of Enamines: E‐4‐Aryl‐1‐dialkylamino‐1‐butenes.
Authors: ELMASMODI A. , BARBRY D. , HASIAK B. , COUTURIER D. 
Published: May 2016

AbstractThe 2,2‐dialkylhexahydro‐2‐benzazocinium halides (III), obtained from the 2‐methylhexahydrobenzazocines (I) by alkylation, react with sodium amide in liquid ammonia under ring‐opening to form the enamines (IV).
ChemInform Abstract: Lactones. Part 15. 1H‐NMR Spectroscopy and Stereochemistry of α‐ and β‐Amino‐γ,γ‐diphenyl‐γ‐butyrolactone.
Authors: LEHMANN J. , GOSSEN A. 
Published: May 2016

AbstractThe isomeric ammonium chlorides (II) and (V) derived from α or β‐amino butyrolactones are prepared as shown in the reaction scheme, either by deacylation of the N‐benzoyl aminodihydrofuranone (I) or by ammonolysis of the furanone (III).
ChemInform Abstract: MO‐LCAO‐Calculations of Sulfur‐Containing π‐Electronic Systems. Part 51. Synthesis and Electronic Structure of Potentially Valence Isomeric 1,2‐Dithiolium‐4‐olates.
Authors: MAYER R. , FABIAN J. , VIOLA H. , JAKISCH L. 
Published: May 2016

AbstractIn order to study the relation between the 1,2‐dithiolium‐4‐olates (III) and their valence isomers such as (VI), some of these derivatives are prepared.
ChemInform Abstract: Cleavage Reactions of 4‐Thiazolidinone‐2‐thiones: Reactions with 5‐Arylhydrazono‐4‐thiazolidinone‐2‐thiones.
Authors: ABDALLAH S. O. , HAMMOUDA H. A. , METWALLI N. H. 
Published: May 2016

AbstractThe arylhydrazono‐4‐thiazolidinone‐2‐thiones (I) undergo conversion as shown in the reaction scheme.
ChemInform Abstract: Synthesis and Some Reactions of α‐(3‐Flavonyloxy)‐ω‐bromoalkanes.
Authors: SODANI R. S. , BHANDARI R. B. , VERMA B. L. 
Published: May 2016

AbstractReaction of the flavonols (I) with the α,ω‐dibromoalkanes (II) yields mixtures of the bisflavonyl compounds (III) and α‐(3‐flavonyloxy)‐ω‐ bromoalkanes (IV).
ChemInform Abstract: Photolysis of Organopolysilanes. The Reaction of Photochemically Generated Dimethylsilylene with 1‐Hexyne in the Presence of Dichlorobis(triethylphosphine)palladium(II).
Authors: ISHIKAWA M. , FUKUI T. 
Published: May 2016

AbstractWith a view to obtaining informations concerning the formation of a silylene transition metal complex the title reaction of the compounds (I) and (II) is investigated.
ChemInform Abstract: Facile Insertion of Nitriles into Paramagnetic Chromium(III) Alkyls. Crystal Structure of a μ2‐Ketimino Complex.
Authors: RICHESON D. S. , MITCHELL J. F. , THEOPOLD K. H. 
Published: May 2016

AbstractThe electron deficient alkyl complexes (III), prepared in good yield as shown in the scheme, on addition of excess acetonitrile (V) form β‐diketimino complexes as seen for example for (IV), whose proposed structure is confirmed by an independent synthesis from (IIIa) with (VI).
ChemInform Abstract: Molybdenum and Tungsten Derivatives of 2,6‐Diphenylphenoxide: Chelation via Metal‐Carbon σ‐Bonds or Metal‐π‐Arene Interactions.
Authors: KERSCHNER J. L. , FANWICK P. E. , ROTHWELL I. P. 
Published: May 2016

AbstractThe preparation of the title complexes (III) and (V) is described.
ChemInform Abstract: Chemical and Electrochemical Oxidation of CpRe(PAr3)2H2 Complexes to Give Stable 17‐Electron Radical Cations. Disproportionation to Diamagnetic Species via Electron‐Transfer Catalysis.
Authors: DETTY M. R. , JONES W. D. 
Published: May 2016

AbstractElectrochemical oxidations of (I) in both MeCN and CH2Cl2 give stable 17‐electron radical monocations as determined by controlled‐potential thin‐layer coulometry and double‐potential step chronocoulometry.
ChemInform Abstract: Tobacco Chemistry. Part 66. (5R,6S,7E,9S)‐7‐Megastigmene‐5,6,9‐triol, A New Constituent of Greek Tobacco.
Authors: WAHLBERG I. , EKLUND A.‐M. , ENZELL C. R. , BERG J.‐E. 
Published: May 2016

AbstractThe structure of the title compound (I) is established by chemical and physical methods as well as by X‐ray analysis of its (9R)‐epimer (space group: P41; Z=4).
ChemInform Abstract: Polymer‐Bound Mixed Carboxylic Dithiocarbamic Anhydrides. A New Class of Selective and Recyclable Solid‐Phase Acylating Reagents.
Authors: HARIDASAN V. K. , AJAYAGHOSH A. , PILLAI V. N. R. 
Published: May 2016

AbstractStarting with Merrifield's resin (I), the mixed dithiocarbamic anhydrides (VI) are synthesized as outlined in the reaction scheme.
ChemInform Abstract: Glycosidation. Part 7. Development of Selective Cytostatica for Cancer Therapy Synthesis of Acetal‐β‐glucosides from Cytotoxic Aldehydes.
Authors: TIETZE L. F. , FISCHER R. , GUDER H. J. , NEUMANN M. 
Published: May 2016

AbstractIn order to obtain a non‐toxic transport form of aldehydes, which are protected against desactivation caused by fast binding to serum proteins, acetal‐β‐glucosides such as (III) are synthesized by reaction of the components (Ia) and (II) in the presence of catalytic amounts of trimethylsilyl triflate.
ChemInform Abstract: A Novel Two‐Step Conversion of 3′,5′‐Di‐O‐tosylthymidine to 5′‐Amino5′‐deoxythymidine Analogues with Inversion of the 3′‐Hydroxyl Group.
Authors: ELLIOTT R. D. , MONTGOMERY J. A. , RIORDAN J. M. 
Published: May 2016

AbstractReaction of 3',5'‐di‐O‐tosylthymidine (Ib) with methylamine (V) or ammonia gives the imino‐bridged nucleosides (IV).
ChemInform Abstract: Toughening Behavior Involving Multiple Mechanisms: Whisker Reinforcement and Zirconia Toughening.
Authors: BECHER P. F. , TIEGS T. N. 
Published: May 2016

AbstractFrom theoretical considerations it is expected that the toughness of a whisker‐reinforced ceramic matrix with added ZrO2 particles should be greater than that achieved by either mechanism.
ChemInform Abstract: Inhibition of Electron‐Hole Recombination in Substitutionally Doped Colloidal Semiconductor Crystallites.
Authors: MOSER J. , GRAETZEL M. + , GALLAY R. 
Published: May 2016

AbstractThe important finding of laser photolysis and EPR measurements concerns the drastic retardation (from ca. 30 ns to minutes and hours) in the electron‐hole recombination rate by doping TiO2 semiconductor particles (120 Å) with 0.5% Fe(III).
ChemInform Abstract: Microscopic Observation of Tl2O3 Electrodeposition at N‐Type WSe2 Electrode.
Authors: MINOURA H. , INAGAKI M. , WATANABE A. , SUGIURA T. , UENO Y. 
Published: May 2016

AbstractTl2O3 is anodically deposited on n‐WSe2 electrodes from Tl2SO4 solution in the dark and under illumination.
ChemInform Abstract: 1.6‐Diaminohexane as Template in the Synthesis of Zeolite ZSM‐5.
Authors: LERMER H. , UNGER K. K. 
Published: May 2016

AbstractThe reaction of a mixture characterized by the molar ratios H2O:SiO2 = 20, SiO2:Al2O3 = 120, Na2O:SiO2 = 0.3 and 1.6‐diaminohexane (DAH) as template at 182 °C, yields ZSM‐5 besides α‐quartz.
ChemInform Abstract: Preparation and Characterization of U2O2F7.
Authors: ASADA K. , EMA K. , IWAI T. 
Published: May 2016

AbstractThe title compound has been prepared by reaction of UO2F2 with UF5 at 400 °C using a UF6‐pressure of 3 atm over the UF5 melt to prevent its disproportionation.
ChemInform Abstract: Cyclic Voltammetry and Resonance Raman Studies of the (Pyridine‐2‐carbaldoxime)tetracyanoferrate(II) Complex: Evidence of a Nitroso‐Oxime Equilibrium.
Authors: TOMA H. E. , SANTOS P. S. 
Published: May 2016

AbstractCyclic voltammograms of the complex (I) show that above pH 7 a systematic decrease in the peak currents exists with concomitant growing of a new wave.
ChemInform Abstract: Reaction of Alkenynamines with Esters of Aliphatic and Aromatic Carboxylic Acids.
Authors: KORMER M. V. , TOLCHINSKII S. E. , MARETINA I. A. 
Published: May 2016

AbstractThe ynamines (I) undergo regiospecific (2 + 2)‐cycloaddition at the acetylenic bond to the ester carbonyl bond of ethyl acetate (IIa) or methyl benzoate (IIb) to give oxete intermediates, whose spontaneous cleavage yields the products (III).
ChemInform Abstract: A Tandem Oxidation‐Intramolecular Diels‐Alder Reaction.
Authors: WU H.‐J. , PAN K. 
Published: May 2016

AbstractFuran (I) is coupled with propylene oxide (II) to form the 2‐(hydroxypropyl)furan (III) which is converted to the 5‐methylthio derivative and then O‐tosylated to give (VI).
ChemInform Abstract: Carbanion Rearrangements by Intramolecular 1,ω‐Proton Transfer. Part 5. Carbanion Rearrangements of ω‐Phenyl‐ω‐(trimethylsilyl)alkyllithium Compounds: Intramolecular Reactions of Benzyltrimethylsilanes with a Carbon‐Lithium Bond.
Authors: MAERCKER A. , STOETZEL R. + 
Published: May 2016

Abstractω‐Phenyl‐ω‐(trimethylsilyl)alkyllithium compounds such as (I) show form out of five theoretically conceivable possibilities for intramolecular stabilization depending on the solvent and on the chain length n. While transmetalation of a methyl group at the Si atom by a 1,(n+2) proton transfer is observed in any case, the intramolecular 1,n shift of the benzylic proton does only take place with n ≫ 4. The main reaction, however for n = 3 and 4 only, is represented by the 1,n trimethyl silyl shift via a cyclic ate complex as an intermediate which partly splits off MeLi yielding the corresponding silacycloalkane derivatives.
ChemInform Abstract: Transannular Ring Expansion in the Acid‐Catalyzed Reaction of the Oxirane Derived from Spirocyclopropane‐Substituted Bicyclo(3.2.1)octene.
Authors: ADAM W. , CRAEMER E. + , LUCCHINI V. , PETERS E.‐M. , PETERS K. , VON SCHNERING H. G. , STAAB E. 
Published: May 2016

AbstractReaction of the readily accessible spiro compounds (I) + (II) (mixture), (Va), or (Vb) with the arenesulfenyl chlorides (IV) affords regioand stereoselectively the adducts (IIIa), (IIIb), (VIa), (VIb), (VIc) (X‐ray analysis: P21/n; Z=4) along with the side product (VII).
ChemInform Abstract: Photochemistry of Ketones in Solution. Part 80. Irradiation of 3,4‐Dimethyl‐4‐(trichloromethyl)‐2,5‐cyclohexadienone in Methanolic Solutions.
Authors: SCHUSTER D. I. , BRISIMITZAKIS A. C. 
Published: May 2016

AbstractPhotolysis of the dimethyltrichloromethylcyclohexadienone (I) in acidic methanol yields the cyclopentenones (II) and (III), together with the compounds (IV) ‐ (XI).
ChemInform Abstract: Conversion of Olefins to Ditriflates by μ‐Oxobis((trifluoromethanesulfonato)(phenyl)iodine).
Authors: HEMBRE R. T. , SCOTT C. P. , NORTON J. R. 
Published: May 2016

AbstractTriflic anhydride (I) inserts 2 equiv. of iodosobenzene (II) to form Zefirov's reagent (III) which undergoes addition reaction with ethylene (IVa), propylene (IVb), and cyclohexene (VI), producing the 1,2‐ditriflates (V) or (VII).
ChemInform Abstract: The Reaction of Tetrachlorocyclopropene with Trimethylsiloxydienes: A ′One‐Pot′ Diels‐Alder Route to Trichlorotropones and ‐tropolones.
Authors: BANWELL M. G. , KNIGHT J. H. 
Published: May 2016

AbstractCycloaddition reaction of tetrachloropropene (II) with the trimethylsiloxydienes (I), (IV), (VI), and (VIII) yields directly the tropone derivatives (III), (V), (VII), and (IX).
ChemInform Abstract: Polyspiranes. Part 13. Cascade Rearrangements. Part 8. Pentacyclo(11.3.0.01,5.05,9.09,13)hexadecane ((4.5)Coronane).
Authors: FITJER L. , QUABECK U. 
Published: May 2016

AbstractThe tetraspiroketone (V) is obtained from bis(cyclobutylidene) (I) and trimethyleneketene generated in situ.
ChemInform Abstract: Palladium‐Catalyzed Alkoxycarbonylation of Phenols to Benzoic Acid Esters.
Authors: DOLLE R. E. , SCHMIDT S. J. , KRUSE L. I. 
Published: May 2016

AbstractThe methoxycarbonylation of the phenols (I), yielding the methyl benzoates (III), is achieved by treatment of the corresponding triflates (II) with carbon monoxide (V) and methanol (VI) in the presence of a Pd catalyst.
ChemInform Abstract: Ortho‐Alkylation of o‐, m‐ and p‐Cresol by Cyclohexene in the Presence of Aluminum Cresolates.
Authors: KOZLIKOVSKII YA. B. , KOSHCHII V. A. , BUTOV S. A. , SOKOLOVA A. V. 
Published: May 2016

AbstractThe reaction between p‐cresol (I) and cyclohexene (II) in the presence of aluminum p‐cresolate, molar ratio 3:1:0.1, affords the o‐alkylation products (III) and (IV) as the main components along with minor amounts of ethers resulting from alkylation of the hydroxy group.
ChemInform Abstract: Asymmetric Reactions Catalyzed by Chiral Metal Complexes. Part 25. Synthesis and Application of a Novel Bisphosphine Ligand, (‐)‐DIOCP, as an Unsymmetrized DIOP to Prove the General Utility of a New Designing Concept.
Authors: CHIBA M. , TAKAHASHI H. , TAKAHASHI H. , MORIMOTO T. , ACHIWA K. 
Published: May 2016

AbstractThe optically active bisphosphine (XI) is prepared from the diol (I) as shown in the reaction scheme.
ChemInform Abstract: Intramolecular Ring Closure of α,β‐Unsaturated 3‐Acylindoles.
Authors: BERGMAN J. , VENEMALM L. 
Published: May 2016

AbstractThe indole Grignard reagent (I) is coupled with the alkenoyl chlorides (II), producing the 2‐alkenoylindoles (III).
ChemInform Abstract: Syn‐Bromination of 2‐Cyclohexen‐1‐ol Benzoates. Isolation of a trans‐3‐ Bromocyclohexano‐cis‐1,2‐(2′‐anisyl‐1′,3′‐dioxolan‐2′‐ylium) Intermediate.
Authors: BELLUCCI G. , BIANCHINI R. , VECCHIANI S. 
Published: May 2016

AbstractAddition of bromine to the cyclohexenyl benzoates (I) gives the expected trans‐dibromides (II) and (III), together with the cis‐dibromides (IV) and (V).
ChemInform Abstract: Synthesis and Antifilarial Activity of 5(6)‐Phosphoramidobenzimidazole‐2‐carbamates and 5(6)‐Cycloalkylaminophosphonamidobenzimidazole‐2‐carbamates.
Authors: DIVAKAR K. J. , RAO M. K. , SHRIVASTAVA R. , REDDY A. B. 
Published: May 2016

AbstractSince 5(6)‐substituted benzimidazole‐2‐carbamates have been reported to possess excellent antifilarial activity, type (V) which has novel substituents at the 5(6)‐position is synthesized.
ChemInform Abstract: Synthesis and Carbodemetalation Reactions of 4‐Methyl‐ and 5‐Aryl‐2‐ (trimethylsilyl)oxazoles. C‐C Bond Formation at C2 of the Oxazole Ring.
Authors: DONDONI A. , FANTIN G. , FOGAGNOLO M. , MEDICI A. , PEDRINI P. 
Published: May 2016

AbstractThe oxazoles (I) are treated consecutively with BuLi and trimethylsilyl chloride (II) to give the silylated oxazoles (III), together with minor amounts of the ring‐opened products (IV).
ChemInform Abstract: Synthesis and Pharmacological Activity of Analogues of the Hypotensive Agent Foridon.
Authors: KASTRON V. V. , VITOLIN'A R. O. , DUBUR G. YA. , SKRASTIN'SH I. P. , KIMENIS A. A. 
Published: May 2016

AbstractThe dihydropyridine derivatives (Ia) ‐ (If) are prepared by known cyclization procedures.
ChemInform Abstract: Structure of 1,5‐Benzodioxepines, the Reaction Products of 2‐Hydroxy2,3‐dihydro‐2‐phenyl‐1,4‐benzodioxin and Phenacyl Bromide.
Authors: DZVINCHUK I. B. , LOZINSKII M. O. , SEREDA S. V. , ANTIPIN M. YU. , STRUCHKOV YU. T. , BOLDESKUL I. E. 
Published: May 2016

AbstractIn the reaction of phenacyl bromide (III) and the benzodioxin (I) which equilibrates with the pyrocatechol ether (II), the benzodioxepine E‐(IV) is the only reaction product.
ChemInform Abstract: Synthesis and Antiphlogistic Activity of Acyl‐Substituted Benzoxa‐ and Benzodioxaheterocycles and Their Acyclic Analogues.
Authors: DAUKSHAS V. K. , GAIDYALIS P. G. , PYATRAUSKAS O. YU. , UDRENAITE E. B. , GASPERAVICHENE G. A. , RAGUOTENE N. V. 
Published: May 2016

AbstractFriedel‐Crafts acylation of the (cyclic) phenol ethers (I) gives the ketones (III).
ChemInform Abstract: Synthesis and Pharmacological Study of Polyfunctional Macroheterocycles. Part 3. Synthesis and Antimicrobial Activity of Some Nitrogen‐ and Sulfur‐Containing Macrocycles.
Authors: VORONKOV M. G. , MALKOVA T. I. , KNUTOV V. I. , BUTIN M. K. 
Published: May 2016

AbstractReaction of the dimercaptothiadiazole (I) with the aziridine (II) gives the bisaminoethylmercapto derivative (III) which is cyclized with phthaloyl chloride (IV), forming the macrocyclic compound (V).
ChemInform Abstract: Nucleophilic Substitution at Silicon: Synthesis of Sterically‐Hindered Bis(2,6‐di‐tert‐butylaryloxy)silanes.
Authors: PASTOR S. D. , HESSELL E. T. 
Published: May 2016

AbstractReaction of the phenols (I) with the dichlorosilanes (II) yields the disubsituted silanes (III).
ChemInform Abstract: Studies on the Reactivity of 2‐Furylhydroxymethylphosphonates: Synthesis of 1‐Oxo‐4‐hydroxycyclopent‐2‐en‐5‐ylphosphonates.
Authors: CASTIGNINO E. , D'AURIA M. , DE MICO A. , D'ONOFRIO F. , PIANCATELLI G. 
Published: May 2016

AbstractThe furylhydroxymethylphosphonates (Ia) and (Ib) are cleaved upon acidic hydrolysis, yielding the β‐ketophosphonates (IV) and (V) respectively.
ChemInform Abstract: Properties of O,O‐Dialkylselenophosphoric Acid Chlorides.
Authors: MEL'NIK YA. I. , PROTS D. I. , KOLODII YA. I. 
Published: May 2016

AbstractThe selenophosphoric acid chlorides (I) react with the amines (II), the alkoxides (IV), potassium hydroxide, or potassium hydrogen sulfide, yielding the substitution products (III), (V), and (VI) respectively.
ChemInform Abstract: Et3B‐Induced Stereoselective Radical Addition of Ph3GeH to Acetylenes and Its Application to Isomerization of Olefins.
Authors: ICHINOSE Y. , NOZAKI K. , WAKAMATSU K. , OSHIMA K. , UTIMOTO K. 
Published: May 2016

AbstractThe acetylenes (I) are coupled with triphenylgermane (II) in the presence of triethylboron to give the alkenylgermanes (III).
ChemInform Abstract: (Fe4Te4(TePh)4)3‐: The First Telluride‐Tellurolate Complex.
Authors: SIMON W. , WILK A. , KREBS B. , HENKEL G. 
Published: May 2016

AbstractIn the search for the first number of a new class of cubane clusters with pure tellurium coordination the compound (III) is synthesized a shown.
ChemInform Abstract: MLCT Photodissociation of Low‐Spin Ferrous Bis(dioximate) Complexes. Comparison of Ground‐ and Excited‐State Reactivity.
Authors: STYNES D. V. , CHEN X. 
Published: May 2016

AbstractThe photochemical axial ligand substitution reactions of the title complexes (I) are shown to proceed via a dissociative mechanism in toluene solution.
ChemInform Abstract: Bromine Oxidation of a Nickel(II) Bis(oxime‐imine) Complex. Evidence for a Single‐Step Outer‐Sphere Two‐Electron Transfer?
Authors: LAPPIN A. G. , OSVATH P. , BARAL S. 
Published: May 2016

AbstractKinetics and mechanism of the two‐electron oxidation of (Ia) by Br2 are investigated in bromide ion medium between pH 3.1 and 7.6 at 25 °C. In the presence of excess of Br2 or Ni(II), oxidation is monophasic leading to the initial product (Ib), a formal Ni(IV) species, which undergoes subsequent reactions to an unknown product or the Ni(III) complex (Ic), depending on the reaction conditions.
ChemInform Abstract: Synthesis and Structure of Os3(CO)6(P(OMe)3)6.
Authors: ALEX R. F. , EINSTEIN F. W. B. , JONES R. H. , POMEROY R. K. 
Published: May 2016

AbstractThe title cluster (III) is prepared by UV irradiation of the tetrakis(phosphite) analogue (I) and excess trimethylphosphite (II), and characterized by X‐ray structure analysis at ‐60 °C (space group R3, Z = 9).
ChemInform Abstract: 1,8‐Naphthalene‐Linked Cofacial Dimeric Phthalocyanines.
Authors: LEZNOFF C. C. , LAM H. , NEVIN W. A. , KOBAYASHI N. , JANDA P. , LEVER A. B. P. 
Published: May 2016

AbstractReaction of the dihydroisoindole (VI) with (V) (obtained as given in the scheme) leads to the cofacial dinuclear phthalocyanine (VIIIa) (positions of the O‐Npe substituents not exactly defined) which on heating with CoCl2 (VII), Cu(OAc)2, or Zn(OAc)2 forms the complexes (VIIIb), (VIIIc), and (VIIId), respectively.
ChemInform Abstract: Enantioselective Synthesis of Methylfuranosides of Unnatural 3,6‐Dideoxy‐3‐methylaldohexoses from Lactates by Homoaldol Reactions.
Authors: HOPPE D. , TARARA G. , WILCKENS M. , JONES P. G. , SCHMIDT D. , STEZOWSKI J. J. 
Published: May 2016

AbstractThe title furanosides (V) and (VII) are prepared starting from the aldehyde (I).