bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: 1‐Halosilatranes.
Authors: VORONKOV M. G. , BARYSHOK V. P. , PETUKHOV L. P. , RAKHLIN V. I. , MIRSKOV R. G. , PESTUNOVICH V. A. 
Published: May 2016

AbstractSeveral methods for the synthesis of the four 1‐halosilatranes (II), (V), (VI), and (VII) are described.
ChemInform Abstract: Reactions of Bis(trifluoromethyl)nitroxyl with Germane.
Authors: ANG H. G. , LEE F. K. 
Published: May 2016

AbstractThe title reaction yields bis(trifluoromethyl)nitroxygermane (III), together with N,N‐bis(trifluoromethyl)hydroxylamine (IV).
ChemInform Abstract: Intramolecular, Base‐Induced Formation of a Metal‐Metal Bond in (L2MoIII 2(μ‐OH)(μ‐CH3CO2)2)3+ (L: 1,4,7‐Trimethyl‐1,4,7‐triazacyclononane). Crystal Structures of (L2MoIII 2(μ‐OH)(μ‐CH3CO2)2)(ClO4)3·H2O and (L2MoIII 2(μ‐O)(μ‐CH3CO2)2)(ClO4)(BF4)·H2O and of the Mixed‐Valence Complex (L2MoIIIMoIV(μ‐O)(μ‐CH3CO2)2)(ClO4)3·H2O.
Authors: WIEGHARDT K. , BOSSEK U. , NEVES A. , NUBER B. , WEISS J. 
Published: May 2016

AbstractHydrolysis of the complex (I) in the presence of ammonium acetate (II) under anaerobic conditions yields the paramagnetic μ‐hydroxo complex (III).
ChemInform Abstract: Structure‐Activity Studies of β‐Carbolines. Part 4. Crystal and Molecular Structures of tert.‐Butyl β‐Carboline‐3‐carboxylate and 2‐(Methoxycarbonyl)canthin‐6‐one.
Authors: CODDING P. W. , SZKARADZINSKA M. B. , ROSZAK A. W. , AHA L. J. , HAGEN T. J. , COOK J. M. 
Published: May 2016

AbstractThe crystal structures of the title compounds (I) and (II), i.e. of two ligands for the benzodiazepine receptor, are investigated by X‐ray analyses (both space group P21/c with Z=4).
ChemInform Abstract: Hexamethylphosphoramide‐Catalyzed Conversion of Carbonyl Compounds into geminal‐Dichlorides with Thionyl Chloride.
Authors: KHURANA J. M. , MEHTA S. 
Published: May 2016

AbstractThe conversion of carbonyl compounds such as (I) and (III) to gem.‐dichlorides, which are potential intermediates for allenes, alkenes, acetylenes and norcamphor derivatives, is easily achieved according to conditions A).
ChemInform Abstract: Grignard Reagents as Powders: Preparation and Reactivity.
Authors: BOUDIN A. , CERVEAU G. , CHUIT C. , CORRIU R. J. P. , REYE C. 
Published: May 2016

AbstractChelating of the Grignard reagents (I) with the amine (II) leads to the solid complexes (III).
ChemInform Abstract: Synthesis of Substituted 2‐Decalones from 1‐Acetylcyclohexenes and α‐Trimethylsilyl α,β‐Unsaturated Carbonyl Compounds by Two‐Fold Michael Reactions. Synthesis of (.+‐.)‐Khusitone.
Authors: HAGIWARA H. , AKAMA T. , OKANO A. , UDA H. 
Published: May 2016

AbstractThe acetylcyclohexenes (I) or their kinetically stable silyl enol ethers (V) undergo cyclocondensation with the α‐silyl enones (II), yielding the decalones (III) as the main products, together with minor amounts of the bisadducts (IV).
ChemInform Abstract: Intramolecular Diels‐Alder Cycloadditions of Substituted Furfuryl E‐2‐(Phenylsulfonyl)acrylates.
Authors: JUNG M. E. , TRUC V. C. 
Published: May 2016

AbstractThe key reaction described in this paper is the intramolecular Diels‐Alder reaction of the furfuryl 2‐(phenylsulfonyl)acrylates (V), yielding the oxanorbornene‐fused γ‐lactones (VI) and (VII).
ChemInform Abstract: Synthesis of Substituted Pyrimidinediones, Thiazolidinones and Triazinoindoles.
Authors: HIREMATH S. P. , ULLAGADDI A. , PUROHIT M. G. 
Published: May 2016

AbstractTitle compounds of type (V) (6 examples), (VII) (6 examples), (X) (9 examples) and (XII) (6 examples) are prepared starting from the corresponding indole‐2‐carbohydrazides.
ChemInform Abstract: Acid‐Catalyzed Condensation of Phenolic Compounds with Cinnamyl Alcohol. Synthesis of Flavans and Linear Pyranocoumarins.
Authors: AHLUWALIA V. K. , MANN R. R. , SINGH S. B. 
Published: May 2016

AbstractCoupling of 2‐methylresorcinol (I) with cinnamyl alcohol (II) in the presence of orthophosphoric acid leads to the formation of a mixture of the compounds (III) ‐ (V).
ChemInform Abstract: Studies on the Molybdenum Cofactor: Model Synthetic Routes Directed at Form B.
Authors: TAYLOR E. C. , SABB A. L. 
Published: May 2016

AbstractChlorination of the pyrazine 1‐oxide (I) with phosphorus oxychloride gives the corresponding 6‐chloropyrazine which is coupled with triphenylphosphine (II), producing the triphenylphosphonium chloride (III).
ChemInform Abstract: Studies in Synthesis of Amidoxime. Synthesis of Hexahydro‐2H‐azepin‐2‐one Oxime.
Authors: THAKORE P. V. 
Published: May 2016

AbstractMethylation of caprolactam (I) with dimethyl sulfate (II) produces the 2‐methoxyazepine derivative (III).
ChemInform Abstract: Formation of a Phosphaalkyne via Migration of the Phenyl Group from Phosphorus to Carbon.
Authors: YOSHIFUJI M. , NIITSU T. , INAMOTO N. 
Published: May 2016

AbstractThe phosphaethylene (I) reacts with two equivalents of tert‐butyllithium (II) at lower temperatures to form a greenish solution of the Li salt (III) which is trapped with methyl iodide (IV) to yield the methyl compound (V).
ChemInform Abstract: Synthesis of an Ambient Temperature Stable, High Spin Density Organic Solid with an Anomalously Small Interspin Coupling.
Authors: CHIANG L. Y. , JOHNSTON D. C. , GOSHORN D. P. , BLOCH A. N. 
Published: May 2016

AbstractTriplet dicationic (I) molecules (otherwise found to be stable only below the cryogenic temp.), after reaction of (I) with an organic acceptor ((II) is found to be an optimum one, giving a ((I)2·(II)) complex) and a doping process in the solid complex with gaseous AsF5, can be stabilized in the solid state at ambient temp. to form novel organic charge‐transfer salts ((I)2·(II)·(AsF5,5)y (y = 2.0‐8.4) possessing a high spin density with an anomalously small interspin coupling.
ChemInform Abstract: Cyclizations of Ene Radicals. Imidoyl Radicals as Intermediates in the Synthesis of Heterocyclic Compounds.
Authors: BACHI M. D. , DENENMARK D. 
Published: May 2016

AbstractThe cyclizations of the selenoimidates (I) or (V) affording the chroman (II) along with the cyanide (III) or, after aromatization, the chromanoquinolines (V), resp., proceed via imidoyl radical intermediates.
ChemInform Abstract: Reduction of Conjugated Cyclohexenone Oximes with Aluminum Hydride.
Authors: ZAIDLEWICZ M. , UZAREWICZ I. G. 
Published: May 2016

AbstractThe reduction of the conjugated cyclohexenone oximes (I)‐(V) with AlH3 in THF yields 2‐cyclohexenylamines and saturated aziridines ‐ 7‐azabicyclo(4.1.0)heptane derivatives ‐ as main products.
ChemInform Abstract: New Heterocyclic Derivatives of Benzimidazole with Germicidal Activity. Part 5. Synthesis and Activity of New, Asymmetric 2,5‐Bis(2‐benzimidazolyl)furans.
Authors: PEDINI M. , BISTOCCHI G. A. , DE MEO G. , RICCI A. , BASTIANINI L. , SPOSINI T. , JACQUIGNON P. 
Published: May 2016

AbstractThe title compounds (III), prepared by cyclocondensation of the 2‐(2‐benzimidazolyl)furan‐5‐carboxaldehyde (I) with the o‐phenylenediamines (II), are evaluated for their germicidal and fungicidal activities.
ChemInform Abstract: A Simple Regiospecific Synthesis of Substituted Pyridines from 2‐Aza 1,3‐Dienes.
Authors: BARLUENGA J. , JOGLAR J. , GONZALEZ F. J. , GOTOR V. , FUSTERO S. 
Published: May 2016

AbstractRing closure reaction of the N‐vinyl imines (I) with the aromatic aldehydes (II) in the presence of trifluoroacetic acid gives the 2‐arylpyridines (III).
ChemInform Abstract: On the Condensation of 2,4‐Dioxocarboxylates (β‐Acylpyruvates) with Urea. An Example of the Utility of Selective Heteronuclear 13C(1H) NOE Difference Spectroscopy in Structure Elucidation.
Authors: HENRIE R. N. II , CREEKMORE R. W. , YEAGER W. H. 
Published: May 2016

AbstractThe 2,4‐dioxocarboxylates (I) undergo cyclocondensation with urea (II) and the alcohols (III) to give the (fused) pyridine derivatives (IV).
ChemInform Abstract: Transannular Bond Formation Between the Antimony and the Nitrogen Atoms in the Dibenz(c,f)(1,5)azastibocine System. Formation of X‐Sb‐X and X‐Sb‐N+ Hypervalent Bonds.
Authors: OHKATA K. , OHNISHI M. , AKIBA K. 
Published: May 2016

AbstractStarting with the o‐bromobenzoic acid (I), the organo‐silicon compounds (VIc) and (IX) are synthesized via the intermediate (VIb), as outlined in the reaction scheme.
ChemInform Abstract: Stable Binuclear o‐ and p‐Semiquinone Complexes of (Ru(bpy)2)2+. Radical Ion versus Mixed Valence Dimer Formulation.
Authors: ERNST S. , HAENEL P. + , JORDANOV J. , KAIM W. , KASACK V. , ROTH E. 
Published: May 2016

AbstractThe paramagnetic binuclear complexes (III) and (V) are obtained as redox‐active yet stable species.
ChemInform Abstract: Amides of Rhodium and Iridium Derived from 2‐Aminothiophenol and Diaminonaphthalene: X‐Ray Crystal Structure of Rh2(μ‐1,8‐(NH)2C10H6)(CO)4.
Authors: FERNANDEZ M. J. , MODREGO J. , ORO L. A. , APREDA M.‐C. , CANO F. H. , FOCES‐FOCES C. 
Published: May 2016

AbstractThe dimeric cyclooctadiene‐Rh and ‐Ir complexes (Va) and (VI) bridged by 2‐aminothiophenolate or diaminonaphthalinate dianions react subsequently with CO (III) and PPh3 (IV) to give via corresponding tetracarbonyl analogues such as (VII) the mixed‐substituted derivatives (Vb) and (VIII), respectively.
ChemInform Abstract: Chain Elongation of Carbohydrates: Synthesis of C‐Glycosides and C‐Nucleosides from Glyconic and Glycaric Acids.
Authors: KLEIN U. , STEGLICH W. 
Published: May 2016

AbstractChain elongation of the peracetylated glyconic acid (I) via the C‐phenylglycine method followed by ring closure and rearrangements yields the allyl compounds (III) which are used for the preparation of C‐nucleosides of type (VI) and (IX) and C‐glycosides, e. g. (XII).
ChemInform Abstract: X‐Ray Diffraction and Raman Studies of Zinc(II) Chloride Hydrate Melts, ZnCl2·nH2O (n = 1.8, 2.5, 3.0, 4.0, and 6.2)
Authors: YAMAGUCHI T. , HAYASHI S. , OHTAKI H. 
Published: May 2016

Abstractperformed at 25 °C reveal that tetrahedral species of formula (ZnClx(OH2)4‐x)(2‐x)+ are predominantly formed and that the average number of Zn‐Cl interaction changes from ∼ 2.4 for the solution with n = 6.2 to ∼ 3.4 for the saturated solution (n = 1.8).
ChemInform Abstract: Synthesis of a New Tetracyclic System Related to Aptazapine (CGS 7525A) by One‐Pot Double Anellation.
Authors: MASSA S. , MAI A. , CORELLI F. 
Published: May 2016

Abstract2‐Pyrrolylbenzylamine (I) undergoes a two‐step substitution reaction with chloroacetyl chloride (II) and the aminoacetaldehyde acetal (III) to form the amide (IV) which is cyclized upon acidic treatment, yielding the tetracyclic piperazinone (V).
ChemInform Abstract: Reactions of (CH3)3Si‐N=C=N‐Si(CH3)3 with Trimethylaluminum, Trimethylgallium, and Trimethylindium.
Authors: LECHLER R. , HAUSEN H.‐D. , WEIDLEIN J. 
Published: May 2016

AbstractBis(trimethylsilyl)carbodiimide (I) forms the 1:1 adducts (III) with trimethylindium and trimethylgallium (II), whereas trimethylaluminum (IV) reacts with (I) to give the insertion product (V) which has C2v symmetry and a planar AlN2C skeleton.
ChemInform Abstract: Metal Atom Synthesis of Metallaboron Clusters. Part 11. Synthesis and Characterization of (η‐C5R5)cobaltathiaborane Clusters (R: H, Me).
Authors: KANG S. O. , CARROLL P. J. , SNEDDON L. G. 
Published: May 2016

AbstractThe reaction of cobalt vapor with the thiaborane (I) and the cyclopentadienes (III) results in hydrogen loss and cobalt insertion to form the known complex (IVa) and its analogue (IVb).
ChemInform Abstract: Thermal Solid‐Solid Interaction Between CuO and Pure Al2O3 Solids.
Authors: EL‐SHOBAKY G. A. , FAGAL G. A. , AMIN N. H. 
Published: May 2016

AbstractDTA, TG, DTG, and XRD studies of CuO/Al2O3 mixed oxides, obtained by treatment of powdered Al‐hydroxide samples with solutions containing Cu(NO3)2·3 H2O, followed by drying and heating in air at 500‐1000 °C, reveal that CuO interacts with the Al2O3 support to produce CuAl2O4 at temp. starting from 650 °C. In the presence of excess Al2O3 this aluminate remains stable up to 1100°C, but, partly decomposes to CuAlO2 in the case of equimolar mixed solids.
ChemInform Abstract: A New Compound of the M5TiB2O10 Type with Ordered Metal Distribution, Ni5SnB2O10,
Authors: BLUHM K. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

Abstractis prepared from a flux of excess B2O3 with NiO:SnO2 = 5:1 at 1450 °C (30 min).
ChemInform Abstract: Stereocontrolled Preparation of Cyclohexane Amino Alcohols Utilizing a Modified Mitsunobu Reaction.
Authors: SAMMES P. G. , THETFORD D. 
Published: May 2016

AbstractDepending on the diacylamine (II) used, the title reaction leads either to N‐alkylated (III) or O‐alkylated products (IV).
ChemInform Abstract: Vinyl Ethers with Epoxy Groups. Part 18. Reactions with Carboxylic Acids.
Authors: NEDOLYA N. A. , ZINOV'EVA V. P. , TROFIMOV B. A. 
Published: May 2016

AbstractIn the presence of catalytic amounts of perfluorobutyric acid the reaction between the vinyloxyepoxy derivative (I) and the aliphatic and aromatic acids (II) proceeds regiospecifically at the vinyl moiety to yield the epoxyacylals (III).
ChemInform Abstract: Sulfur Heterocycles. Part 6. Convenient Synthesis of 5‐Substituted Benzo(b)thiophene Derivatives and a Facile Entry to the Thieno(2,3‐g)indole System.
Authors: DATTA S. , DE A. 
Published: May 2016

AbstractThe title compounds (III), (IV) and (VIII) are prepared since many biologically active benzo(b)thiophenes are found to be 5‐substituted derivatives.
ChemInform Abstract: Potential Cardiotonica Agents. Part 1. Synthesis and Pharmacological Properties of 3‐Cyano‐2‐oxaalkylamino‐5‐(4‐pyridyl)pyridines.
Authors: HAGEN V. , HAGEN A. , HEER S. , MITZNER R. , NIEDRICH H. 
Published: May 2016

Abstract2‐Chloro‐3‐cyano‐5‐(4‐pyridyl)pyridine (I) reacts with amines such as (II) to give the corresponding 2‐aminopyridines (III).
ChemInform Abstract: Preparation of Oxazolo(4,3‐a)phthalazin‐3‐ones by Use of Reissert Compounds.
Authors: UFF B. C. , HO Y.‐P. , HUSSAIN F. , HAJI M. S. 
Published: May 2016

AbstractThe Reissert nitrile (I) (prepared in 80% yield from phthalazine, Me3SiCN, and Ph‐CO‐Cl in the presence of AlCl3) is transformed to its conjugate base and then condensed with aldehydes (II) to give, after hydrolysis, the methanols (IV).
ChemInform Abstract: Various Synthetic Routes to Imidazo(1,2‐c)thieno(3,2‐e)pyrimidines and Pyrimido(1,2‐c)thieno(3,2‐e)pyrimdines in Some Cases Anellated.
Authors: LEISTNER S. , GUETSCHOW M. + , VIEWEG H. , WAGNER G. , STROHSCHEIDT T. , GRUPE R. 
Published: May 2016

AbstractThe thieno‐fused pyrimidines (III) are prepared by reaction of the thiazinethiones (I) with the diamines (II).
ChemInform Abstract: Hypolipidemic 2‐(4‐(1,1‐Dimethylethyl)phenyl)‐4H‐3,1‐benzoxazin‐4‐ones. Structure‐Activity Relationships of a Novel Series of High‐Density Lipoprotein Elevators.
Authors: FENTON G. , NEWTON C. G. , WYMAN B. M. , BAGGE P. , DRON D. I. , RIDDELL D. , JONES G. D. 
Published: May 2016

AbstractCoupling of the anthranilic acids (I) with the aroyl chlorides (II) leads to the formation of the amides (III) which undergo cyclization in boiling acetic anhydride to form the benzoxazin‐4‐ones (V).
ChemInform Abstract: Reactions of Alkylthiophosphines with Aldehydes.
Authors: SINYASHIN O. G. , GORSHUNOV I. YU. , MUSIN R. Z. , BATYEVA E. S. , PUDOVIK A. N. 
Published: May 2016

AbstractThe alkylthiophosphines (I) are coupled with the aldehydes (II) to give the hydroxyalkyldithiophosphonites (IIIa) and (IIIb) or the hydroxyalkylthiophosphinite (IIIc).
ChemInform Abstract: Symmetric Sterically Hindered Phthalocyanines.
Authors: MIKHALENKO S. A. , SOLOV'EVA L. I. , LUK'YANETS E. A. 
Published: May 2016

AbstractThe tetralindicarbonitrile (I), prepared from 1,1,4,4,6,7‐hexamethyltetralin by common methods, is treated with sodium isoamylate to give the phthalocyanine (II).
ChemInform Abstract: Photoionization Spectra of Cesium and Cesium Oxide Clusters.
Authors: LIMBERGER H. G. , MARTIN T. P. 
Published: May 2016

AbstractSeven cesium and 86 oxidized cesium clusters, CsnOm (0 < m < n; n = 3‐14), are ionized in a one‐photon process by means of a tunable cw dye laser and detected in a mass spectrometer.
ChemInform Abstract: The Permanganate Oxidation of Mn(II) in Aqueous Acidic Solutions in the Presence of Oxalate and Pyrophosphate.
Authors: POWELL R. T. , OSKIN T. , GANAPATHISUBRAMANIAN N. 
Published: May 2016

AbstractThe rate of the rapid oxidation of Mn(II) to Mn(III) by MnO4‐ in aqueous acidic solutions containing C2O42‐ or P2O74‐ is shown to be first order with respect to (MnO4‐), whereas the reaction order with respect to (Mn(II)) increases from first to second with increasing (Mn(II)).
ChemInform Abstract: Phenyl‐ and Mesitylynol: The First Generation and Direct Observation of Hydroxyacetylenes in Solution.
Authors: CHIANG Y. , KRESGE A. J. , HOCHSTRASSER R. , WIRZ J. 
Published: May 2016

AbstractThe cyclopropenones (I) and (V) photodecarbonylate to give title compounds (II) and their methyl ethers (VI), respectively.
ChemInform Abstract: Oxidative Decarboxylation of Cyclic Amino Acids and Dehydrogenation of Cyclic Secondary Amines with Iodosobenzene.
Authors: OCHIAI M. , INENAGA M. , NAGAO Y. , MORIARTY R. M. , VAID R. K. , DUNCAN M. P. 
Published: May 2016

AbstractL‐Proline (Ia) and pipecolic acid (Ib) are decarboxylated upon treatment with 2.2 equivalents of iodosobenzene, producing the lactams (II).
ChemInform Abstract: Reaction of Arylmethylsilanes and Tetraarylsilanes with Xenon Difluoride in the Presence of Fluoride Ions.
Authors: BARDIN V. V. , STENNIKOVA I. V. , FURIN G. G. , LESHINA T. V. , YAKOBSON G. G. 
Published: May 2016

AbstractThe polyfluoroaryl(hetaryl)silanes (I), (V), (VI), and (VII) react with xenon difluoride in the presence of cesium fluoride to give the desilylation products (II) and (VIII), together with the biaryls (III) and (IX).
ChemInform Abstract: Regioselectivity in the Diels‐Alder Reactions of 2‐Vinylindoles and Pyrano(3,4‐b)indol‐3‐ones with CC‐Dienophiles.
Authors: PINDUR U. , EITEL M. , ABDOUST‐HOUSHANG E. 
Published: May 2016

AbstractThe 2‐vinylindoles (I) and (IV) undergo regioselective Diels‐Alder reaction with the dienophiles (II) and (V), producing the tetrahydrocarbazoles (III) and (VI).
ChemInform Abstract: A New Synthesis of Dihydrothiopyrans.
Authors: KUNAKOVA R. V. , MUSTAFINA E. M. , BAIBULATOVA N. Z. , DZEHMILEV U. M. , TOLSTIKOV G. A. 
Published: May 2016

AbstractDi‐n‐octyl sulfoxide (I) reacts with butadiene (II) in the presence of a Ni or Pd catalyst to give the heptyldihydrothiopyrane (III).
ChemInform Abstract: The Furan Approach to Higher Monosaccharides. A Concise Total Synthesis of (+)‐KDO.
Authors: MARTIN S. F. , ZINKE P. W. 
Published: May 2016

AbstractThe reaction sequence shown in the scheme represents a facile total synthesis of (+)‐KDO (IXb), the essential ketosidic component which links the carbohydrate and lipid subunits of lipopolysaccharides of Gram‐negative bacteria.
ChemInform Abstract: Synthesis of Oligodeoxynucleoside Phosphorodithioates via Thioamidites.
Authors: BRILL W. K.‐D. , TANG J.‐Y. , MA Y.‐X. , CARUTHERS M. H. 
Published: May 2016

AbstractSixteen synthons of type (IV) are prepared and reacted with deoxynucleoside (V) covalently attached to a silica support.
ChemInform Abstract: The Effect of Hydrostatic Pressure on the Corrosion of Nickel in Slightly Alkaline Solutions Containing Cl‐ Ions
Authors: BECCARIA A. M. , FIORDIPONTI P. , MATTOGNO G. 
Published: May 2016

Abstract(0.58 M NaCl and sea water, pH 8.2; 1, 10, 100, and 300 atm, 20 °C).
ChemInform Abstract: Diastereoselectivity, Diastereofacial Selectivity and Regioselectivity in the Reactions of Cinnamyl Chloride with Aldehydes Mediated by Tin and Aluminum.
Authors: COXON J. M. , VAN EYK S. J. , STEEL P. J. 
Published: May 2016

AbstractThe reaction of the title chloride (I) with aldehydes of type (II) is regioselective and threo diastereoselective.
ChemInform Abstract: Diels‐Alder Reactions Involving cis‐1,2‐Isopropylidenedioxycyclohexa‐3,5‐diene and Enzymatic Resolution of One of the Adducts.
Authors: COTTERILL I. C. , ROBERTS S. M. , WILLIAMS J. O. 
Published: May 2016

AbstractThe acetal (I), prepared from cis‐1,3‐cyclohexadiene‐5,6‐diol and 2,2‐dimethoxypropane, undergoes cycloaddition with numerous dienophiles, as outlined in the reaction scheme.
ChemInform Abstract: Heterocycles from Nitrile Oxides: Synthesis and Reactions of 2‐Thenoylhydroxamoyl Chloride.
Authors: ABDELHAMID A. O. , KHALIFA F. A. , GHABRIAL S. S. 
Published: May 2016

AbstractThe hydroxamoyl chloride (I) reacts with the heteroaromatic amines (II) to give the fused nitroso compounds (IIIa) ‐ (IIId).
ChemInform Abstract: Photoinduced Single Electron Transfer (SET) Initiated Oxidative Cleavage of Benzylic Ethers Protecting Group: A Mild and Efficient Procedure.
Authors: PANDEY G. , KRISHNA A. 
Published: May 2016

AbstractThe p‐methoxybenzyl ethers (III), prepared from the alcohols (I) and the chloride (II), are irradiated in the presence of 1,4‐dicyanonaphthalene to regain the alcohols (I), together with anisaldehyde (IV).
ChemInform Abstract: Enantioselective Synthesis of 2‐Benzyloxy Alcohols and 1,2‐Diols via Alkylation of Chiral Glycolate Imides. A Convenient Approach to Optically Active Glycerol Derivatives.
Authors: CARDILLO G. , ORENA M. , ROMERO M. , SANDRI S. 
Published: May 2016

AbstractAlkylation of the chiral enolates of the glycolate imides (Ia) and (Ib) proceeds in a highly diastereoselective manner to give substituted products such as (III).
ChemInform Abstract: Stereoselectivity of Reactions Between α‐Methylbut‐2‐enylstannanes and Aldehydes.
Authors: HULL C. , MORTLOCK S. V. , THOMAS E. J. 
Published: May 2016

AbstractStannanes, e.g. (I) and (VII), react stereoselectively with aldehydes to give anti‐Z‐alkenes of type (III) and (VIII).
ChemInform Abstract: Reaction of Phenolates with Polyfluoro Carbonyl Compounds.
Authors: DYACHENKO V. I. , KOLOMIETS A. F. , FOKIN A. V. 
Published: May 2016

AbstractReaction of the alkali phenolates (I) or (V) with perfluoroacetone (II) gives the o‐monoalkylated compounds (III), the p‐monoalkyl derivatives (IV), or the bisalkylated products (VI) and (VII) depending on the polarity of the solvent used, the cation, and the molar ratio.
ChemInform Abstract: Reaction of Chlorosulfonyl Isocyanate with 1,2‐Diols: Rearrangement and Formation of Carbonates.
Authors: JOSEPH S. P. , DHAR D. N. 
Published: May 2016

AbstractVarious vicinal diols are treated with chlorosulfonyl isocyanate (II) to form intermediate carbamates such as (III) which are cleaved and rearranged upon heating, producing ketones and carbonates as the main products.
ChemInform Abstract: Homodimerization of Spiro(bicyclo(2.2.1)hepta‐2,5‐diene‐7,1′‐cyclopropane) Catalyzed by Group VIII Transition Metal Complexes.
Authors: DZHEMILEV U. M. , KHUSNUTDINOV R. I. , MUSLIMOV Z. S. , NEFEDOV O. M. , TOLSTIKOV G. A. 
Published: May 2016

AbstractTreatment of the spiro(norbornadiene‐7,1'‐cyclopropane) (I) with group VIII transition metal‐containing catalysts gives the dimers (II) ‐ (VI) and (VIII) ‐ (X).
ChemInform Abstract: Photooxygenation of Cyanoanthracenes via Their Radical Anions.
Authors: MIZUNO K. , TAMAI T. , NAKANISHI I. , ICHINOSE N. , OTSUJI Y. 
Published: May 2016

AbstractPhotooxidation of 1,4‐dicyanoanthracene (II) in the presence of biphenyl (I) in acetonitrile gives benzoic acid (III) and anthraquinone (IV).
ChemInform Abstract: 1,3‐Dimethylindole: NMR Spectroscopy and Reactivity Toward Ethyl Carbonate in the Presence of Butyl Lithium.
Authors: AVENDANO C. , DE DIEGO C. , ELGUERO J. 
Published: May 2016

AbstractMetalation of 1,3‐dimethylindole (I) with BuLi, followed by reaction with diethyl carbonate (II), affords the unstable carbinol (III).
ChemInform Abstract: Nucleophilic Tele‐Substitution in 2‐Chloro‐3‐formylindoles via Ring Opening‐Ring Closure.
Authors: PLUTA K. , ANDERSEN K. V. , JENSEN F. , BECHER J. 
Published: May 2016

AbstractThe 2‐chloro‐3‐formylindoles (I) react with sodium azide (II) in hot dimethyl sulfoxide to give the 5‐azido‐3‐cyanoindoles (III).