bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Biomimetic Approach to Biflavonoids: Oxidative Coupling of 2′‐Hydroxychalcones with I2 in Alkaline Methanol.
Authors: ALI S. M. , ILYAS M. 
Published: May 2016

AbstractThe chalcones (I), prepared from anisaldehyde and the corresponding acetophenones, are treated with iodine in methanolic potassium hydroxide to yield different coupling products: (Ia) produces the 3,5'‐bichalcone (II), whereas (Ib) is converted to the symmetrical derivative (III).
ChemInform Abstract: Chiral Isoprenyl Ethers from 3‐Ethoxy‐2‐methylacrolein by Vinylogous Transesterification and Wittig Alkenylation.
Authors: MAIER M. S. , BREITMAIER E. 
Published: May 2016

AbstractThe title ether (IIIb), synthesized starting from the reaction of the ketone (I) with the chiral alcohol (II), may be used as starting material for the preparation of cyclic terpenes.
ChemInform Abstract: Synthesis and Diuretic Activity of Imidazo(2,1‐b)thiazole Acetohydrazones.
Authors: ANDREANI A. , RAMBALDI M. , MASCELLANI G. , RUGARLI P. 
Published: May 2016

AbstractThe title compounds, represented in the scheme by (V), are prepared by Vilsmeier formylation of (I), followed by reaction with the hydrazide (IV).
ChemInform Abstract: 3,3′‐Di(1,3‐thiazolidin‐4‐one) System. Part 2. Anti‐Inflammatory and Anti‐Histaminic Properties in New Substituted Derivatives.
Authors: PREVITERA T. , BASILE M. , VIGORITA M. G. , FENECH G. , OCCHIUTO F. , CIRCOSTA C. , COSTA DE PASQUALE R. 
Published: May 2016

AbstractThe title compounds (IVa) and (VI)/(VII) and their ethylene‐linked analogues (IX)/(X) are prepared by identical procedures; some of the products are then subjected to oxidation to yield the corresponding sulfones (e.g.
ChemInform Abstract: Regiospecific Synthesis of 5‐Alkyl‐1‐(phenoxycarbonyl)‐1,2‐dihydropyridines.
Authors: COMINS D. L. , MANTLO N. B. 
Published: May 2016

AbstractThe N‐phenoxycarbonyl dihydropyridine (I) is formylated and then reduced to yield the 5‐hydroxymethyl derivative (II).
ChemInform Abstract: Thermal Extrusion of Sulfur from ω‐(4‐(2,6‐Dimethylpyrimidinyl)thio)acetophenones.
Authors: SINGH H. , MALHOTRA N. , AGGARWAL S. 
Published: May 2016

AbstractUnder the conditions A), the title compounds (I) undergo thermal sulfur extrusion to give the enaminones (III).
ChemInform Abstract: Synthesis and Some Reactions of Hexaazatriphenylenehexacarbonitrile, a Hydrogen‐Free Polyfunctional Heterocycle with D3h Symmetry.
Authors: KANAKARAJAN K. , CZARNIK A. W. 
Published: May 2016

AbstractThe title compound (III) is prepared as shown in the reaction scheme and converted to the hexacarboxylic acid, the hexacarboxamide and the corresponding trianhydride by usual methods.
ChemInform Abstract: Electrophilic Properties of Substituted 6H‐1,3‐Thiazines.
Authors: TEA G. , PRADERE J.‐P. , BUJOLI B. , QUINIOU H. , TOUPET L. 
Published: May 2016

AbstractReaction of the title thiazines (I) with the amines (II) or with H2S, the mercaptan (VIII) or H2O yields the products (III)‐(VII) and (IX) (in the case of (IXd) no yield is given).
ChemInform Abstract: Synthesis of (E)‐(2‐Arylethenyl)silanes by Palladium‐Catalyzed Arylation of Vinylsilanes in the Presence of Silver Nitrate.
Authors: KARABELAS K. , HALLBERG A. 
Published: May 2016

AbstractArylation of the vinylsilanes (II) with the aryl iodides (I) in the presence of Pd(II) acetate and silver nitrate yields exclusively the arylethenylsilanes (III).
ChemInform Abstract: Synthesis of Carbofunctional Silicon‐Containing Methyladamantanes.
Authors: FEDOTOV N. S. , GRISHINA E. V. , SHELUDYAKOV V. D. , BAGRII E. I. 
Published: May 2016

AbstractThe peroxide‐catalyzed reaction of 1,3‐dimethyladamantane (I) with the unsaturated silyl compounds (II) gives the addition products (III) and (IV).
ChemInform Abstract: Synthesis of Bis(9‐o‐ and 9‐m‐carboranyl)diselenides by Electrophilic Substitution of o‐ and m‐Carboranes with Selenium Chlorides Under the Action of AlCl3, and Their Transformations.
Authors: ZAKHARKIN L. I. , PISAREVA I. V. , ANTONOVICH V. A. 
Published: May 2016

AbstractThe carboranes (I) react with selenium chlorides or selenium dioxide in the presence of aluminum trichloride to give the 9‐substituted carboranes (II), (IV), or (IX) which are further transformed as shown in the reaction scheme.
ChemInform Abstract: Reaction of Organo‐Aluminum Compounds with Orthoformates.
Authors: VOLKOV A. A. , ZLOTSKII S. S. , KRAVETS E. KH. , RAKHMANKULOV D. L. 
Published: May 2016

AbstractOrthoformates such as (I), (IX), or (XII) react with the alanes (II), (IV), or (VIII) to give the corresponding acetals and, in some cases, alkylation products.
ChemInform Abstract: Syntheses of Isocyanides at the Metal. Part 10. Radical Alkylation of Cyano Complexes. Part 3. α‐Halogenoalkyl Isocyanides.
Authors: FEHLHAMMER W. P. , DEGEL F. , BECK G. 
Published: May 2016

AbstractThe cyano chromium complexes (I) and (IV) are alkylated via a radical mechanism initiated by aryldiazonium ions to give the α‐halogenoalkyl isocyanides (III), (VI) or (VIII).
ChemInform Abstract: Copper(II) Hemocyanin Models. Part 2. Synthesis and Characterization of Binuclear Copper(II) Complexes of a Heptadentate Ligand.
Authors: BERENDS H. P. , STEPHAN D. W. 
Published: May 2016

AbstractThe title ligand (I) is prepared by reaction of 2,6‐bis(chloromethyl)‐p‐cresol with the appropriate sec. amine in refluxing MeOH.
ChemInform Abstract: Synthesis and 31P and 1H NMR Characterization of Two New Chiral Ruthenium Hydrides Containing the trans‐1,2‐Bis((diphenylphosphino)methyl)cyclobutane Ligand (TBPC): cis‐H2Ru(TBPC)2 and trans‐HRuCl(TBPC)2.
Authors: MASSONNEAU V. , LE MAUX P. , DABARD R. , SIMONNEAUX G. , AVIRON‐VIOLET P. , DANG T. P. 
Published: May 2016

AbstractDichloro‐cyclooctadieneruthenium and the R isomer of the optically active diphosphine ligand react in refluxing EtOH containing an excess of NEt3 to give the complex (I).
ChemInform Abstract: 7β‐Ethynylnorlongifolane from Carbon Tetrachloride Adduct of Longifolene: Synthesis and Reactions.
Authors: DALAVOY V. S. , DEODHAR V. B. , NAYAK U. R. 
Published: May 2016

AbstractDechlorination of the compound (Ia) yields the desired title compound (Ib) together with the olefins (II) and (III).
ChemInform Abstract: A Short Efficient Synthesis of Trichodiene.
Authors: VANMIDDLESWORTH F. L. 
Published: May 2016

AbstractThe ester (IV), formed from the alcohol (II) and the carboxylic acid (III), is subjected to an ester enolate Claisen rearrangement to give the silyl ester (V) which is converted to a separable mixture of the alcohols (VI) and (VIIa).
ChemInform Abstract: Preparation of the Lamorolide Lactone and Its Antitumor Activity.
Authors: ABDUAZIMOV B. KH. , YUNUSOV A. I. , SIDYAKIN G. P. , ALIMOV R. A. , SAIDKHODZHAEV A. , HAZMITDINOVA G. G. 
Published: May 2016

AbstractStarting with deacetyllaurenobiolide (I), isolated from the nonpolar fraction of the lactones of Tanacetopsis mucronata, and morpholine (II), the title compound (III) is obtained and screened for inhibition of tumor growth.
ChemInform Abstract: Characterization of a Self‐Aligned Cobalt Silicide Process
Authors: MORGAN A. E. , BROADBENT E. K. , DELFINO M. , COULMAN B. , SADANA D. K. 
Published: May 2016

Abstractby AES, TEM, electron diffraction, spreading resistance, I‐V characteristics, surface photovoltaic measurements, SIMS.
ChemInform Abstract: Improvement of the Current Efficiency of an Al‐Zn‐In Anode by Heat‐Treatment.
Authors: LIN J. C. , SHIH H. C. 
Published: May 2016

AbstractThe current efficiency of an Al anode (containing 4.6 wt.% Zn and 0.02 wt.% In) depends on its heat‐treatment.
ChemInform Abstract: The Double Sulfide SmYb2S4.
Authors: LOBACHEVSKAYA N. I. , BAMBUROV V. G. , FINKEL'SHTEIN L. D. , EFREMOVA N. N. 
Published: May 2016

AbstractHeating a mixture of SmS and Yb2S3 to 1000‐1300 °C for 3‐5 h under vacuum affords the novel title compound with bivalent and trivalent Yb and trivalent Sm.
ChemInform Abstract: Hydroxy Complexes of Gold. Part 2. Calcium Aurates.
Authors: JONES P. G. , SCHELBACH R. , SCHWARZMANN E. 
Published: May 2016

AbstractTwo calcium aurate phases have been obtained as single crystals, phase (I), Ca2(OH)3(H2O)4(Au(OH)4), from HAuCl4 and Ca(OH)2 (aqueous solution 1:8, reflux, 5 h) and phase (II) (composition not determined, probably Ca(Au(OH)4)2) from NaAu(OH)4 and Ca(ClO4)2 (darkness, 2 months).
ChemInform Abstract: Thioketyls. Part 9. ESR Studies and Semi‐Empirical MO Calculations on Mono‐ and Dithiosemidione Radical Anions.
Authors: BUDDENSIEK D. , KOEPKE B. + , VOSS J. 
Published: May 2016

AbstractCoupling constants of the 13C and 33S nuclei are determined from the ESR spectra of specifically labelled monothiosemidione (I)·‐ and dithiosemidione (II)·‐ radical anions.
ChemInform Abstract: Equilibrium and Enthalpy Measurements on the Complex Formation Between Silver(I) and Tri‐ and Dialkylphosphines and Tributylstibine in Pyridine Solution
Authors: HULTEN F. , PERSSON I. 
Published: May 2016

Abstract(potentiometric and calorimetric measurements of the stabilities for the silver complex formation with PBu3, SbBu3, P(C6H11)3 and PH(C6H11)2.
ChemInform Abstract: Regioselectivity of Diels‐Alder Additions of 1‐Acetylvinyl Arenecarboxylates.
Authors: AGUILAR R. , REYES A. , TAMARIZ J. , BIRBAUM J.‐L. 
Published: May 2016

AbstractThe acetylvinyl derivatives (I) react with isoprene (II) to yield the cycloadducts (III) and (IV) with preference of (III).
ChemInform Abstract: Stereoselective Synthesis of Functionalized, Tetra‐ and Penta‐Substituted 1,3‐Butadienes by Allene Claisen Rearrangements.
Authors: EGERT E. , BECK H. , SCHMIDT D. , GONSCHORREK C. , HOPPE D. 
Published: May 2016

AbstractReaction of the alkoxyallenyl carbaminates (I) with the enamine (II) yields the isomeric butadienyl derivatives (III) and (IV) as the main products as a result of a sigmatropic rearrangement of the primary adducts.
ChemInform Abstract: Radiolytic Oxidation of 1,2,4‐Benzenetriol. An Application of Time‐Resolved Resonance Raman Spectroscopy to Kinetic Studies of Reaction Intermediates.
Authors: QIN L. , TRIPATHI G. N. R. , SCHULER R. H. 
Published: May 2016

AbstractIn acidic solution, the triol is rapidly oxidized by ·OH or ·N3 to form a mixture of neutral 2,4‐ and 3,4‐dihydroxyphenoxyl radicals.
ChemInform Abstract: Kinetics of the Gas‐Phase Reactions of NO3 Radicals with a Series of Alkynes, Haloalkenes, and α,β‐Unsaturated Aldehydes.
Authors: ATKINSON R. , ASCHMANN S. M. , GOODMAN M. A. 
Published: May 2016

AbstractThe rate constants are determined at 298 ±2 K using a relative rate technique.
ChemInform Abstract: Studies on Epoxy Compounds. Part 52. Synthesis of Amino‐β‐diols and Their NMR Spectra.
Authors: PANSEVICH‐KOLYADA V. I. , MARCHIK E. F. , DOGADINA A. V. 
Published: May 2016

AbstractThe epoxide (II), prepared from the unsaturated tertiary alcohol (I) and peracetic acid, reacts with the amines (III) to give the aminodiols (IV).
ChemInform Abstract: Oxidative Dimerization of 4‐(3,5‐Ditert.‐butyl‐4‐hydroxyphenyl)butan‐2‐one.
Authors: TITOVA T. F. , KRYSIN A. P. 
Published: May 2016

AbstractTreatment of the title compound (Ia) or of its methyl analogue (Ib) with K3(Fe(CN)6) in the presence of KOH causes oxidative dimerization to yield the methylene quinones (IIa) as a mixture of diastereomers or (IIb) as a single compound.
ChemInform Abstract: Schiff Bases from (+)‐threo‐(4‐Aminophenyl)‐2‐dimethylamino‐1,3‐propanediol.
Authors: POTAPOV V. M. , DEM'YANOVICH V. M. , ZAITSEV V. P. , SHARIPOVA S. KH. 
Published: May 2016

AbstractThe Schiff bases (V) are prepared by condensation of the title compound (III) with the aromatic aldehydes (IV), in order to examine the influence on the spectral properties exerted by the substituents of aromatic nuclei.
ChemInform Abstract: Syntheses and Configurations of Some Heterocyclic Amidoximes. X‐Ray Crystal Structure of 3‐Phenyl‐5,6‐dihydro‐2(1H)‐O‐methyloxime.
Authors: JOHNSON J. E. , MAIA J. A. , TAN K. , GHAFOURIPOUR A. , DE MEESTER P. , CHU S. S. C. 
Published: May 2016

Abstractα‐Methoxyphenylacetonitrile (I), prepared from benzaldehyde, reacts with hydroxylamine to give the amidoxime (II) which is methylated and then converted to the chlorooxime (IV).
ChemInform Abstract: Intramolecular Substitution of the o‐Nitro Group in 2,6‐Dinitrobenzene Derivatives. Part 1. Formation of Nitrobenzofurans by Intramolecular Cyclization of Dinitroaryl Derivatives of β‐Dicarbonyl Compounds.
Authors: ONYS'KO P. P. , PROKLINA N. V. , PROKOPENKO V. P. , GOLOLOBOV YU. G. 
Published: May 2016

AbstractUsing a known procedure, the 4‐substituted 2,6‐dinitrochlorobenzenes (I) are reacted with the carbanions of the β‐dicarbonyl compounds (II) to yield the dinitroaryl derivatives (III).
ChemInform Abstract: Diastereoselective Synthesis of trans‐4,5‐Disubstituted Oxazolidin‐2ones and Vicinal Amino Alcohols Through Alkylation of N‐Acyliminium Ion Intermediates.
Authors: KANO S. , YUASA Y. , SHIBUYA S. 
Published: May 2016

AbstractThe oxazolidin‐2‐ones (III) and (IX), derived from the hydroxy esters (II) and (VIII) or the oxazolidinediones (IV), are allylated with the silanes (V), yielding the allyl derivatives (VI) and (X).
ChemInform Abstract: One‐Pot Synthesis of Tetrahydrofuran Derivatives from Allylic Alcohols and Vinyl Ethers by Means of Palladium(II) Acetate.
Authors: FUGAMI K. , OSHIMA K. , UTIMOTO K. 
Published: May 2016

AbstractThe allylic alcohols (I), (IV), (VI), (VIII), and (X) are coupled with vinylic ethers such as (II), yielding vinylic tetrahydrofuran derivatives such as (III), (V), (VII), (IX), and (XI).
ChemInform Abstract: K2(Pd(C6F5)4)‐Catalyzed Cyclotrimerization of Malononitrile.
Authors: LOPEZ G. , SANCHEZ G. , GARCIA G. , GALVEZ J. 
Published: May 2016

AbstractThe title complex (III), which is easily prepared by arylation of potassium tetrachloropalladate (I) with pentafluorophenyl magnesium bromide (II), proves to be an efficient catalyst for the cyclotrimerization of malodinitrile (IV), yielding the pyridine derivative (V).
ChemInform Abstract: Palladium Catalyzed Coupling of 5‐Hydroxyuracil Trifluoromethanesulfonates (Triflates) with Alkenes and Alkynes.
Authors: HIROTA K. , KITADE Y. , ISOBE Y. , MAKI Y. 
Published: May 2016

AbstractThe 5‐hydroxyuracil triflates (I) are coupled with the alkenes (II) or the alkynes (IV) in the presence of Pd‐catalysts to give the 5‐alkenyl or 5‐alkynyl derivatives (III) and (V) respectively.
ChemInform Abstract: Acidic Hydrolysis of 2‐Methylthio‐7‐chloro‐5‐phenyl‐1,3,4‐benzotriazepines.
Authors: SCHLEUDER M. , BUTZKI S. , RICHTER P. , SOKOLOV A. 
Published: May 2016

AbstractThe hydrolysis of the compounds (I), (V), and (VI) in hydrochloric acid is influenced by temperature and yields either (II), (III), (IV), or (VII).
ChemInform Abstract: Thermal Decomposition of α‐Diazo‐α‐(trialkylsilyl)alkanones. Intramolecular C/H Insertion of Siloxyalkylidenecarbene Intermediates.
Authors: BRUECKMANN R. + , MAAS G. 
Published: May 2016

AbstractVarious diazo(trialkylsilyl)alkanones such as (III) are prepared by silylation of the diazoketones (I) with the triflates (II).
ChemInform Abstract: Ethylenamidophosphites of Glycerol Derivatives. Part 7. Synthesis of Novel Amidophosphate Analogues of Phosphatidyl(Thiophosphatidyl)cholines.
Authors: PREDVODITELEV D. A. , MALENKOVSKAYA M. A. , NIFANT'EV E. E. 
Published: May 2016

AbstractA novel and simple synthesis of the title compounds (IV) is described, which starts from the easily accessible amidophosphate (Ia) or its thio analogue (Ib).
ChemInform Abstract: 2,6‐Di‐tert‐butyl‐4‐methylphenyl Ester of N‐(2,4,6‐Tri(tert‐butyl)phenyl)imidophosphenous Acid.
Authors: ROMANENKO V. D. , RUBAN A. V. , DRAPAILO A. B. , POVOLOTSKII M. I. , MARKOVSKII L. N. 
Published: May 2016

AbstractThe title compound (IV) is synthesized from the dichlorophosphite (I) and the silylamide (II) via the amidophosphite (III).
ChemInform Abstract: Syntheses of Methylenediphosphine Oxides and Carbamoylmethylphosphine Oxides Using O‐Trimethylsilyl Phosphinites.
Authors: CHAUZOV V. A. , STUDNEV YU. N. , IZNOSKOVA M. G. , FOKIN A. V. 
Published: May 2016

AbstractThe phosphine oxides (V) are prepared from the phosphinous acids (I) via the trimethylsilyl esters (III).
ChemInform Abstract: Organo‐Germanium Compounds: Synthesis, Structure, and Properties of Masked‐Carboxyethylgermanium Sesquioxide (GE‐132) and Related Compounds with One Triethanolamine Component.
Authors: KAKIMOTO N. , SATO K. , TAKADA T. , AKIBA M. 
Published: May 2016

AbstractThe carboxyethylgermanium sesquioxides (I) react with triethanolamine (II) to produce the trioxazagermaspirododecanones (III).
ChemInform Abstract: S‐S Photohomolysis at Dimolybdenum(V) RSS‐ and S2‐ 2 Bridges.
Authors: NOBLE M. E. 
Published: May 2016

AbstractDimolybdenum(V) complexes of the general form (I) (SMo2SSR) and (II) (SMo2S2Mo2S) photolyze under fluorescent lighting to give products characteristic of S‐S homolysis.
ChemInform Abstract: Synthesis of Six‐ and Seven‐Coordinate Molybdenum and Tungsten(II) Dicarbonyl Complexes Containing Monodentate Phosphine Ligands.
Authors: BRISDON B. J. , HODSON A. G. W. 
Published: May 2016

AbstractOn passing a stream of dry N2 gas through a solution of the tricarbonyls (I) in MeCN, the monomeric seven‐coordinate dicarbonyls (II) are formed.
ChemInform Abstract: Synthesis, Structures, and Properties of the Tris(catecholato)rhenium(VI) Complexes Re(O2C6H2(tBu)2)3 and Re(O2C6Cl4)3.
Authors: DELEARIE L. A. , HALTIWANGER R. C. , PIERPONT C. G. 
Published: May 2016

AbstractDi‐tert‐butyl‐1,2‐benzoquinone and Re2(CO)10 react in anisole under irradiation with polychromatic light to give the complex (Ia).
ChemInform Abstract: Reactivity of the Polyhydride Complexes (ReH5(PPh3)3), (ReH3(dppe)2) (dppe: Ph2PCH2CH2PPh2), (ReH3(PPh3)3L), and (ReH4(PPh3)3L)PF6 (L: MeCN or tBuNC) Towards Electrophiles and Nucleophiles.
Authors: MOEHRING G. A. , WALTON R. A. 
Published: May 2016

AbstractProtonation of the pentahydride (I) leads to the cationic hexahydride (II).
ChemInform Abstract: Rhenium Carbonyl Fluorides: Preparation of (Re(CO)6) (ReF6) and Some Reactions of (Re(CO)5F·ReF5).
Authors: HOLLOWAY J. H. , SENIOR J. B. , SZARY A. C. 
Published: May 2016

AbstractThe extremely moisture sensitive title compound (II) is prepared from Re(CO)5F·ReF5 (I) and CO or from Re2(CO)10 (III) and XeF2 as shown.
ChemInform Abstract: A Comparative Synthetic and Structural Study of μ‐Oxo and μ‐Sulfido Derivatives of N,N′‐Ethylenebis(acetylacetoneiminato)iron(III), Including the Synthesis and Structural Characterization of the Parent Compound.
Authors: CORAZZA F. , FLORIANI C. , ZEHNDER M. 
Published: May 2016

AbstractThe Fe(II) complex (I) is obtained by treating anhydrous FeCl2·1.5 THF with N,N'‐ethylenebis(acetylacetoneimine) in the presence of NaOMe.
ChemInform Abstract: Crystal and Molecular Structure and Magnetic Properties of the Adducts of Copper(II) Hexafluoroacetylacetonate with the Nitroxide Ligand 2‐Phenyl‐4,4,5,5‐tetramethylimidazoline‐1‐oxyl 3‐Oxide.
Authors: GATTESCHI D. , LAUGIER J. , REY P. , ZANCHINI C. 
Published: May 2016

AbstractStable 1:1 and 1:2 adducts (yield in g) are isolated from the reaction of bis(hexafluoroacetylacetonato)copper(II) and the free radical ligand in pentane (20 min reflux).
ChemInform Abstract: Synthesis, Antitumor Activity, and X‐Ray Structure of Bis(imidazolium) (Imidazole)pentachlororuthenate(III), (ImH)2(RuImCl5).
Authors: KEPPLER B. K. , WEHE D. , ENDRES H. , RUPP W. 
Published: May 2016

AbstractThe water‐soluble, heterocycle‐coordinated title complex is prepared by an improved synthesis with 27% yield and is characterized by X‐ray structural analysis (space group Bm21b with Z=4).
ChemInform Abstract: Dirhodium Complexes with Axially and Equatorially Nonequivalent Rhodium Atoms. Characterization of Rh2(tcl)4(tclH) and Rh2(tcl)4(CO) (tcl = ω‐Thiocaprolactamate).
Authors: LIFSEY R. S. , CHAVAN M. Y. , CHAU L. K. , AHSAN M. Q. , KADISH K. M. , BEAR J. L. 
Published: May 2016

AbstractThe polar dirhodium complex (III) crystallizes in the space group P21/n with Z=4.
ChemInform Abstract: Synthesis and Characterisation of (N(PPh3)2)(RuRh5(CO)16) by X‐Ray Crystallography and by Natural‐Abundance Carbon‐13 Nuclear Magnetic Resonance Spectroscopy.
Authors: PURSIAINEN J. , PAKKANEN T. A. , SMOLANDER K. 
Published: May 2016

AbstractThe title cluster (I) is prepared by reaction of (Rh(CO)4)‐ with (Ru(CO)3Cl2)2 in THF followed by treatment with phosphoric acid and addition of N(PPh3)2Cl.
ChemInform Abstract: Synthesis of o‐Nitrophenylplatinum(IV) Complexes; Crystal and Molecular Structure of Dichlorobis(2‐nitrophenyl‐C′O)platinum(IV).
Authors: VICENTE J. , CHICOTE M.‐T. , MARTIN J. , JONES P. G. , FITTSCHEN C. 
Published: May 2016

AbstractThe oxidative addition of halogens or MeI to the Pt(II) complex (I) leads to the Pt(IV) trans‐complexes (II) and the cis‐complex (III).
ChemInform Abstract: Syntheses of Methyl‐4‐O‐(β‐D‐Curacosyl)‐α‐D‐curamicoside, the Glycoside of the Disaccharide Moiety E‐F of Flambamycin and Isomers.
Authors: THIEM J. , DUCKSTEIN V. , PRAHST A. , MATZKE M. 
Published: May 2016

AbstractSilver triflate‐mediated condensation of (I) and (II) affords the disaccharide (IIIa) ‐ a derivative of the disaccharide moiety E‐F of flambamycin ‐ or its regioisomer (IIIb).
ChemInform Abstract: Nucleophilic Acylation of 3,4‐Dihydroisoquinolinium Salts. Diastereoselective Synthesis of the Protoberberine Alkaloid (.+‐.)‐Corydaline (IVa) and of Analogous Compounds.
Authors: TIETZE L. F. , BRILL G. 
Published: May 2016

AbstractA series of nucleophilic acylations of salts of type (I) with lithiated enol ethers such as (II) are carried out leading to the corresponding adducts.
ChemInform Abstract: Synthesis of (.+‐.)‐Isoprosopinines A and B.
Authors: BIRKINSHAW T. N. , HOLMES A. B. 
Published: May 2016

AbstractThe bromoethylpiperidine (V), prepared as shown in the reaction scheme, is coupled with the sulfonylketones (IX), obtained from the hydrazones (VI), yielding the piperidine derivatives (X).
ChemInform Abstract: (2‐Cyano‐1,1‐dimethylethoxy)bis(diethylamino)phosphine: a Convenient Reagent for the Synthesis of DNA Fragments.
Authors: MARUGG J. E. , NIELSEN J. , DAHL O. , BURIK A. , VAN DER MAREL G. A. , VAN BOOM J. H. 
Published: May 2016

AbstractThe phosphitylating title reagent proves to be very effective for the in situ preparation of d‐nucleoside phosphoramidites.
ChemInform Abstract: Thermal Stability and Acid Resistivity of Glasses Based on ZnO‐Al2O3‐SiO2.
Authors: SHIMBO M. 
Published: May 2016

AbstractThe glass formation range in the title system has been investigated and the acid (2.5% HNO3, 1% citric acid) resistivity of the (PbO stabilized) glasses has been determined by weight‐loss measurements.
ChemInform Abstract: Superconductivity Above Liquid Nitrogen Temperature: Preparation and Properties of a Family of Perovskite‐Based Superconductors.
Authors: ENGLER E. M. , LEE V. Y. , NAZZAL A. I. , BEYERS R. B. , LIM G. , GRANT P. M. , PARKIN S. S. P. , RAMIREZ M. L. , VAZQUEZ J. E. , SAVOY R. J. 
Published: May 2016

AbstractSingle‐phase YBa2Cu3Oy and a variety of new, single‐phase high‐temp.
ChemInform Abstract: Photoinduced Oxygen Uptake in Aqueous Suspensions of ZnO.
Authors: DOMENECH J. , ANDRES M. , MUNOZ J. 
Published: May 2016

AbstractThe main source of O2 produced under UV irradiation in aqueous suspensions of ZnO containing Hg(II), Ag(I), and CrO42‐ ions as conduction band acceptors, is shown to be the water oxidation.
ChemInform Abstract: Magnetic Anisotropy Induced by Stress‐Annealing of Co‐Rich Amorphous Metals.
Authors: EHRHARDT A. , GONSER U. 
Published: May 2016

AbstractThe influence of the annealing parameters Ta, ta, σa and of the material constant λS (magnetostriction constant) on the magnetic anisotropy is investigated using the magnetoresistance method.
ChemInform Abstract: Preparation and Characterization of Carbon‐Based Fuel‐Cell Electrodes with Platinum‐Group Bimetallic Catalysts.
Authors: RAMESH K. V. , SARODE P. R. , VASUDEVAN S. , SHUKLA A. K. 
Published: May 2016

AbstractIt is demonstrated that carbon electrodes with platinum‐group bimetallic catalysts viz., Pt + Ru, Pt + Pd, and Pd + Ru, can show higher electrochemical activities than those of the individual components.