bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Spectroelectrochemistry of (p‐Oxo)bis[(phthalocyaninato)iron(III)].
Authors: BOTTOMLEY L. A. , ERCOLANI C. , GORCE J.‐N. , PENNESI G. , ROSSI G. 
Published: May 2016

AbstractThe electroehemical behaviour of the title complex was studied in neat pyridine at a Pt‐button electrode.
ChemInform Abstract: Energy Barriers to the Diels‐Alder Cycloadditions and Cycloreversions of Cation‐ Radicals in the Gas Phase.
Authors: TURECEK F. , HAVLAS Z. 
Published: May 2016

AbstractThe retro‐Diels‐Alder reaction of the symmetrical or slightly unsymmetrical radical cations derived from (V)‐(VII) takes place at the thermochemical threshold in contrast to the decomposition of the highly unsymmetrical (III)+ ′ which proceeds in two steps (barrier 58‐67 kJ/mol).
ChemInform Abstract: A Clear Demonstration of the Stereoelectronic Effect of Nitrogen in Chloride Ion loss by (E)‐ and (Z)‐Hydroximoyl Chlorides.
Authors: HEGARTY A. F. , MULLANE M. 
Published: May 2016

AbstractIn contrast to the corresponding hydroximoyl chlorides the (Z)‐esters (I) can be photoisomerized to give the (E)‐esters (II).
ChemInform Abstract: Cyclobutyl‐cyclopropylcarbinyl Type Rearrangement of 1‐Oxaspirohexane Derivatives.
Authors: TOBE Y. , SATO J. , SORORI T. , KAKIUCHI K. , ODAIRA Y. 
Published: May 2016

AbstractDie Epoxide (Ia) und (Ib) lagern unter saurer Katalyse über die Zwischenstufen (II) und (III) zu den homologen Norcaranon‐Derivaten (IVa) und (IVb) um, während (Ic) in nicht de?nierbarer Weise reagiert.
ChemInform Abstract: A Novel Lithium Iodide‐Promoted Vinylcyclopropane‐Cyclopentene Rearrangement: Efficient Synthesis of Bicyclo[3.3.0]oct‐6‐en‐2‐one, Versatile Building Block for Polycyclopentanoid Natural Products.
Authors: HASHIMOTO S. , SHINODA T. , IKEGAMI S. 
Published: May 2016

AbstractAus Cyclopentenon‐2‐carbonsäureester (I) werden nach gängigen Methoden die Derivate (II)‐(IV) hergestellt; aus (IV) entstehen in Gegenwart von Pd‐Katalysatoren die isomeren Bicyclo[3.l.O]hexane (V), die beim Erhitzen mit Li‐Salzen zu dem Bicyclooctenonester (VI) umgelagert und anschließend zu (VII) decarboxyliert werden können.
ChemInform Abstract: Novel Rearrangement of exo‐Epoxide of Norbornene.
Authors: KAS'JAN L. A. , GNEDENKO L. Y. , GALAFEEVA M. F. , KORNILOV M. Y. , KRASUTSKY P. A. , AVERINA N. V. , ZEFIROV N. S. 
Published: May 2016

AbstractAus dem exo‐Epoxid (I) erhält man bei der Behandlung mit Acetanhydrid und Schwefelsäure je nach Bedingungen unterschiedliche Mengen der beiden Oxatricyclooctane (II) und (III).
ChemInform Abstract: 3‐Alkoxypropenals as Precursors in the Synthesis of Conjugated and Semiconjugated Polyenes: Methy1‐Substituted Octa‐ and Nona‐tetraenes.
Authors: SPANGLER C. W. , MCCOY R. K. , KARAVAKIS A. A. 
Published: May 2016

AbstractThe vinylic or allylic Grignard reagents (I) or (IV) react with the ethoxypropenals (II) to produce the conjugated and semiconjugated dienals (III) or (V).
ChemInform Abstract: A Novel Reaction of 1‐Phosphonyloxy‐F‐1‐alkenephosphonates: Highly Effective Method for the Synthesis of α,β‐Unsaturated F‐Carboxylic Acid Derivatives.
Authors: ISHIHARA T. , YAMASAKI Y. , ANDO T. 
Published: May 2016

AbstractTetrabutylammoniumfluorid spaltet die im Titel genannten Verbindungen (I) zu den Ketenen (II), die ohne Isolierung mit nucleophilen Reagentien (III) zu den Estern bzw. Amiden (IV) reagieren.
ChemInform Abstract: A Novel Synthesis of α,β‐Unsaturated γ‐Hydroxy Carbonyl Compounds from Enones with Carbon Homologation.
Authors: SATOH T. , MOTOHASHI S. , YAMAKAWA K. 
Published: May 2016

AbstractCyclohexenon (I) reagiert mit dem α‐Chlorsulfoxid (II) zu dem Addukt (III), aus dem über das Epoxid (IV) und das Thiophenylketon (V) nach Persäureoxidation und alkalischer Hydrolyse schließlich das Benzoylcyclohexenol (VII) erhalten wird.
ChemInform Abstract: Asymmetric Induction in the Palladium‐Catalyzed Sulfonylation of Allylic Sulfinates and Acetates with Chiral Phosphine Ligands.
Authors: HIROI K. , MAKINO K. 
Published: May 2016

AbstractDie Umlagerung der racemischen Allylsulfonate (I) in Gegenwart von Tetrakis‐(triphenylphosphin)‐palladium und der chiralen Phosphinliganden (I I) führt zu den optisch aktiven Allylsulfonen (III).
ChemInform Abstract: Cycloadditions in Syntheses. Part 28. 2‐Azabicyclo[2.2.0]hexane‐3,5‐dione and Its Derivatives: Synthesis and Transformation to Azetidin‐2‐ones.
Authors: KATAGIRI N. , SATO M. , YONEDA N. , SAIKAWA S. , SAKAMOTO T. , MUTO M. , KANEKO C. 
Published: May 2016

AbstractPhotolysis of the pyridones (I) gives the bicyclic enones (II) [the synthesis of (IIa) and (IIb) is described in an earlier work], which are converted to the title compounds (III).
ChemInform Abstract: Cyclisation of 3‐Amino‐3‐[thienyl‐3]‐propionic Acid to Aminocyclopentathiophenes.
Authors: DALLEMAGNE P. , RAULT S. , CUGNON DE SEVRICOURT M. , HASSAN KH. M. , ROBBA M. 
Published: May 2016

AbstractAus der 3‐Thienyl‐amino‐propionsäure (Ia) werden die Acylverbindungen (Ib)‐(Ie) erhalten, mit denen keine Cyclisierung möglich ist.
ChemInform Abstract: Azocoupling and Aminomethylation of 2,5‐Diphenylpyrrole and Its Derivatives.
Authors: GRINEV A. N. , MEZENTSEVA M. V. , KULESHOVA E. F. , ALEKSEEVA L. M. 
Published: May 2016

AbstractDie Kupplung des Diphenylpyrrols (I) mit den Phenyldiazoniumsalzen (II) führt zu den Monoarylazo‐ (III) oder den Phenylhydrazono‐phenylazo‐pyrrolen (IV).
ChemInform Abstract: Electrochemical Oxidation of Aromatic Ethers. Part 11. The Synthesis of Phenanthropyrrolidines.
Authors: BIRD P. , BLACK G. G. , LLOYD H. , SAINSBURY M. , SCOPES D. I. C. 
Published: May 2016

AbstractThe recently described dihydrophenanthrofurandione (II), obi tained by anodic oxidation of the isochromanone (I) (with rearrangement of the primary oxidation product), is reduced to give the alcohol (IV) and the ketone (III).
ChemInform Abstract: On the Reaction of N‐Vinyliminophosphoranes. A Novel Route to 1‐Azaazulene Ring System Utilizing Aza‐Wittig Reaction.
Authors: NITTA M. , KOBAYASHI T. 
Published: May 2016

Abstractα‐Azidostyrol (I) reagiert mit Triphenylphosphin zu dem N‐Vinyliminophosphoran (II), das mit den Troponen (IIIa)‐(IIIc) zu den anellierten Produkten (IV) reagiert, die mit Nickeldioxid zu den 1‐Azaazulenen (V) oxidiert werden.
ChemInform Abstract: Reaction of Polyfluorinated β‐Ketoesters and Their α‐Halogenated Derivatives with Tetraphosphorus Decasulfide and 2,4‐Bis(methoxyphenyl)‐ 2,4‐dithioxo‐PV,PV‐ 1,3,2,4‐dithiodiphosphetane.
Authors: BOBROV M. B. , SALOBUTIN V. I. , PASHKEVICH K. I. 
Published: May 2016

AbstractDie Poly?uoracylessigsäureester (I) reagieren mit Lawesson Reagens (II) zu den Dithiolenthionen (III), wobei aus den Chlor‐ bzw. Bromessigsäurederivaten (Ib) und (Ic) neben den Verbindungen (IIIb) und (IIIc) auch die Dehalogenierungsprodukte (IIIa) entstehen.
ChemInform Abstract: Antibacterial Active Substances. Part 11. The Aminomethinylation of CH2‐Acidic Isonitriles.
Authors: KREUTZBERGER A. , KOLTER K. 
Published: May 2016

AbstractAus den Isonitrilen (I) werden durch Deprotonierung und anschlie‐ βende Umsetzung mit dem Triazin (II) die 4‐substituierten Imidazole (III) erhalten.
ChemInform Abstract: On Triazoles. Part 5. Synthesis of 1‐ and 2‐R1‐3‐R2,R3‐Amino‐5‐amino‐1,2,4‐triazoles.
Authors: REITER J. , PONGO L. , SOMORAI T. , DVORTSAK P. 
Published: May 2016

AbstractDie Umsetzung zwischen den Isothioharnstoff‐Derivaten (I) und den Hydrazinen (II) kann zu den verschiedenen Diamino‐triazolen (III) bis (VIII) führen.
ChemInform Abstract: Oxidation of Heterocyclic Nitrogen Ylids to Nitro Heterocycles.
Authors: COBURN M. D. 
Published: May 2016

AbstractBei der Oxidation mit Trifluorperessigsäure erhält man aus dem Furazan (I) ein Gemisch aus der Nitro‐ (II) und der Azoxyverbindung (III).
ChemInform Abstract: 4‐Hydroxy‐6‐methyl‐2‐pyrone (Triacetic Acid Lactone) and Its 3‐Phenylthiomethyl Derivative Towards Aldehydes in the Presence of Piperidine.
Authors: MORENO‐MANAS M. , PAPELL E. , PLEIXATS R. , RIBAS J. , VIRGILI A. 
Published: May 2016

AbstractTriessigsäurelacton (I) reagiert mit den Aldehyden (II)′über die Kondensationsprodukte (III) in Gegenwart von Piperidin (IV) zu den Mannich‐Verbindungen (V), die auch aus (I) und den Iminiumsalzen (VI) erhalten werden können.
ChemInform Abstract: Pyridinethiones. Part 11. Diastereoselective Aldol Condensations with 2(1H)‐Pyridones, 2(1H)‐Pyridinethiones, and the Crystal Structure of 3‐(1‐Hydroxy‐2‐methyl‐3‐oxo‐3‐(4‐chlorophenyl)propyl)‐1‐isopropyl‐2(1H)‐pyridinethione.
Authors: BECHER J. , ASAAD F. M. , JOHANSEN T. , HANSEN J. , LARSEN S. , HANSEN F. 
Published: May 2016

AbstractZunächst wird die Aldol‐Kondensation zwischen den 3‐Formyl‐pyridin‐ Derivaten (I) und den Ketonen (II) hinsichtlich der Stereochemie der gebildeten Alkohole (III) bzw. (IV) untersucht; mit (IIb) werden ausschließlich die erythro‐Isomere (IV) gebildet.
ChemInform Abstract: σ‐Adduct Formation between Azines and Liquid Ammonia. Part 44. Amination of 3,6‐Dinitro‐1,8‐naphthyridines.
Authors: WOZNIAK M. , VAN DER PLAS H. C. 
Published: May 2016

AbstractDie Aminierung der im Titel genannten Verbindungen (I) durch Behandlung mit Kaliumpermanganat in flüssigem Ammoniak wird untersucht.
ChemInform Abstract: Diaminopyridazines from Diaminocyclopropenylium Salts and Diazomethyl Compounds.
Authors: HEYDT H. , EISENBARTH P. , FEITH K. , REGITZ M. 
Published: May 2016

AbstractTetrachlorcyclopropen (I) wird nach Friedel‐Crafts in das Phenyl‐trichlorcyclopropen (II) und anschließend mit Aminen in die Cyclopropenyliumsalze (III) übergeführt.
ChemInform Abstract: Intramolecular Reactions of N‐Nitrenes with Alkynes: Conformational Anchoring in Spiro‐fused 2H‐fused 2H‐Azirines.
Authors: ATKINSON R. S. , GRIMSHIRE M. J. 
Published: May 2016

AbstractThe compounds (I) or (IV) are oxidized according to A) to give the azirines (II) or (W, (VII) and (VIII).
ChemInform Abstract: Amino Acids as Synthons for Pyrrolo[1,2‐a] and [2,3‐d] Anellated Heterobicycles.
Authors: SINAMBELA J. M. , ZIMMERMANN W. , ROTH H. J. , EGER K. 
Published: May 2016

AbstractAus den Ketonen (I) und den Aminosäuren (II) erhält man über die Ketoamine (III) mit Malodinitril (IV) die Pyrrole (V) bzw. ihre Cyclisierungsprodukte (VI).
ChemInform Abstract: Synthesis and Antitumor Evaluation of Some 1,3‐Disubstituted Tetrahydropyrimido[4,5‐c]isoquinolines.
Authors: GANGJEE A. , OHEMENG K. A. , LIN F.‐T. , KATOH A. A. 
Published: May 2016

AbstractSynthesis and Antitumor Evaluation of Some 1,3‐Disubstituted Tetrahydropyrimido[4,5‐clisoquinolines.
ChemInform Abstract: Synthesis of Novel 3‐(α‐Arylhydrazono‐1,3,4‐oxadiazol‐2‐ylmethyl)‐2‐oxo‐1,2‐dihydroquinoxalines and Their Characteristic Tautomerism between the Hydrazone Imine and Diazenyl Enamine Forms.
Authors: KURASAWA Y. , MURAMATSU M. , OKAMOTO Y. , TAKADA A. 
Published: May 2016

AbstractAus den Arylhydrazonen (I) erhält man bei der Behandlung mit den Orthoestern (II) über Zwischenstufen die Oxadiazole (III), die mit den Tautomeren (IV) im Gleichgewicht stehen.
ChemInform Abstract: On the Amination of Pteridines by Liquid Ammonia‐Potassium Permanganate.
Authors: SLADOWSKA H. , DE MEESTER J. W. G. , VAN DER PLAS H. C. 
Published: May 2016

AbstractAus den substituierten Pteridinen (I) erhält man bei der Oxidation in flüssigem Ammoniak über die Derivate (II) die Aminierungsprodukte (III), die z.Tl. salzsauer zu (IV) hydrolysiert werden.
ChemInform Abstract: Oxidative Rearrangement of N‐Aminopyrazoles to 1,2,3‐Triazines.
Authors: BOULTON A. J. , FRUTTERO R. , SAKA J. D. K. , WILLIAMS M. T. 
Published: May 2016

AbstractThe pyrazole (I) is aminated with ′SN‐enriched chloroamine (II) to give the amine (III), which is oxidized to form the triazine (IV).
ChemInform Abstract: Chemical and Electrochemical Reductions of Benzopyrano‐1‐as‐triazines.
Authors: BELLEC C. , VINOT N. , MAITTE P. 
Published: May 2016

AbstractDie Benzopyranotriazine (I) werden elektrochemisch zu (II) und (III) sowie weiter unter Ringverengung zu den Imidazolonen (IV) reduziert.
ChemInform Abstract: Fused s‐Triazino Heterocycles. Part 13. 1,3,7,10,11c‐Pentaazabenz[de]anthracene and 1,3,7,10,11,13,13d‐Heptaazabenz[de]cyclopenta[h]anthracene, Two New Ring Systems.
Authors: SHAW J. T. , ACCIAI G. F. , BABIN J. E. , SENSENIG L. A. 
Published: May 2016

Abstract2,6‐Diamino‐pyridin (I) reagiert mit dem Dicyanoenolether (II) zu dem Kondensationsprodukt (III), das mit Pivalinsäurechlorid zu dem Tricyclus (IV) cyclisiert werden kann.
ChemInform Abstract: Synthesis of Lipophilic Crown Ethers with Pendant Carboxylic Acid Groups.
Authors: CZECH B. P. , CZECH A. , SON B. , LEE H. K. , BARTSCH R. A. 
Published: May 2016

AbstractDie Herstellung der makrocyclischen Polyether (VII) und (XI)‐(XVII) mit lipophilen Seitengruppen, speziell Carboxylresten, wird ausführlich beschrieben.
ChemInform Abstract: Synthesis of Hydroxymethyl‐Functionalized Diazacrowns and Cryptands.
Authors: BABB D. A. , CZECH B. P. , BARTSCH R. A. 
Published: May 2016

AbstractAus dem Diol (Ia) werden das Säurechlorid (Ic) sowie das Bis‐mesylat (Ie) in üblicher Weise hergestellt.
ChemInform Abstract: Reductive Hydrosilylation of Quinones Catalyzed by Tris(triphenylphosphine)chlororhodium(I).
Authors: BAKOLA‐CHRISTIANOPOULOU M. N. 
Published: May 2016

AbstractDie p‐Chinone (I) reagieren mit den Hydrosilanen (II) unter Katalyse durch den Rhodium‐Phosphan‐Komplex (III) über die Hydrochinonmonosilylether (IV) zu den Bis‐silylethern (V).
ChemInform Abstract: Aziridinolysis Patterns of (NPCl2)3 and (NPCl2)4; Crystal Structures of trans‐ N3P3(NC2H4)2Cl4 and 2,trans‐4‐ N4P4(NC2H4)2Cl6.
Authors: VAN DER HUIZEN A. A. , VAN DE GRAMPEL J. C. , RUSCH J. W. , WILTING T. , VAN BOLHUIS F. , MEETSMA A. 
Published: May 2016

AbstractThe sec. amine aziridine Haz shows a peculiar competi‐tion between geminal and non‐geminal Substitution in its reactions with the cyclophosphazenes (I) and (III).
ChemInform Abstract: Quaternized Cyclic and High Polymeric Phosphazenes and Their Interactions with Tetracyanoquinodimethane.
Authors: ALLCOCK H. R. , LEVIN M. L. , AUSTIN P. E. 
Published: May 2016

AbstractSmall‐molecule cyclotri‐ or cyclotetraphosphazenes and their linear high polymeric analogues bearing amino, phosphino, or organohalogeno side groups have been quaternized by treatment with methyl iodide or triphenylphosphine.
ChemInform Abstract: A Simple Preparation of Tervalent Phosphirenes.
Authors: LOCHSCHMIDT S. , MATHEY F. , SCHMIDPETER A. 
Published: May 2016

AbstractDie Dichlorphosphine (I) reagieren mit den Alkinen (II) zu den Phosphirenium‐Salzen (III), die mit Tributyl‐ phosphin zu den Phosphirenen (IV) reduziert werden.
ChemInform Abstract: Synthesis and Crystal Structure of the Dimer Bis[[bis(trimethylsilylmethyl)arsino]diphenylgallane].
Authors: WELLS R. L. , PURDY A. P. , MCPHAIL A. T. , PITT C. G. 
Published: May 2016

AbstractDas aus A5203 und der Silylmethyl‐Grignard‐Verbindung (I) zugängliche Bis‐(trimethylsilylmethyl)‐chlorarsin (II) läßt sich mit Zn/Cu/Hg zu dem Arsin (III) reduzieren.
ChemInform Abstract: Pentacoordinated Molecules. Part 65. Discrete, Dimeric, and Polymeric Structures of Triphenyltin Esters of Chlorobenzoic Acids.
Authors: HOLMES R. R. , DAY R. O. , CHANDRASEKHAR V. , VOLLANO J. F. , HOLMES J. M. 
Published: May 2016

AbstractThe 1:2 molar reaction of bis(triphenylphosphine) oxide with p‐ or o‐chlorobenzoic acid leads to the formation of the monomeric ester (I), and the polymeric carboxylato‐bridged ester (II).
ChemInform Abstract: Influence of Isomeric Form, Chelated Ring Size, and the Metal on the Oxidation of Facial and Meridional Chromium, Molybdenum, and Tungsten Tricarbonyl Bis(bis(diphenylphosphino)methane) and Bis(1,2‐bis(diphenylphosphino)ethane) Complexes.
Authors: BOND A. M. , COLTON R. , MCGREGOR K. 
Published: May 2016

AbstractThe complexes (Ib) or (Ic) have been prepared from the tricarbonylcyclohepta‐1,3,5‐triene metal complexes and the diphosphine in CHZCI; at room temp. (2 h) or under reflux (4 h), resp., the other Compounds were prepared according to literature methods.
ChemInform Abstract: Solvent‐Extraction Complex of Uranium(VI) with cis,syn,cis‐Dicyclohexano‐18‐crown‐6.
Authors: WANG W.‐J. , CHEN B. , ZHENG P. , WANG B. , WANG M. 
Published: May 2016

AbstractOn the extraction of U(VI) from 4 N HCl ‐ 0.025 M UO2Cl2 aqueous solution with an equal volume of 0.1 Mcis,syn,cis‐dicyclohexano‐18‐crown‐6 in 1,2‐dichloroethane a crystalline Complex with composition (I) is formed, isolated, and characterized by IR spectra and X‐ray structural analysis (space group C2/c, Z=4).
ChemInform Abstract: New Heterobinuclear p‐Oxo‐bridged Dimer Complexes: Synthesis, Characterization and Structural Studies.
Authors: YANG C.‐H. , GOEDKEN V. L. 
Published: May 2016

AbstractAseries of heterobinuclear u‐oxo‐bridged complexes are formed by the reaction of the Ti = Obond in (I) with other Ti‐complexes and with other oxophilic metal complexes (no yield given).
ChemInform Abstract: Multiple‐Equilibria Model Describing the Axial Ligand Dependence of the Dioxygen Affinity of an Iron(II) Lacunar Complex.
Authors: GOLDSBY K. A. , BEATO B. D. , BUSCH D. H. 
Published: May 2016

AbstractThe dioxygen‐binding behaviour of the title Complex (I) in l‐methylimidazole/acetonitrile is desCribed, where O2 itself has been used to labilize the axial Chloride, giving the O2 adduct wi‐th l‐methylimidazole as the axial base.
ChemInform Abstract: Dialkylamino Phosphorus Metal Carbonyls. Part 2. Bis(diisopropylamino)phosphido and (Diisopropylamino)phosphinidene Metal Carbonyl Complexes from Reactions of Manganese and Cobalt Carbonyls with Bis(diisopropylamino)phosphine.
Authors: KING R. B. , FU W.‐K. , HOLT E. M. 
Published: May 2016

AbstractPhotolysis of PH(NiPr2)2 with Mn2(CO)", in THF yielded the air‐stable sublimable complex (Ia), which crystallizes in the space group P2,/ a with Z=4.
ChemInform Abstract: Electron‐Transfer Barriers in Cobalt(III) and Cobalt(II) Bis Complexes of 1,4,7‐Triazacyclononane (tacn) and 1,4,7‐Trithiacyclononane (ttcn). Crystal Structures of [Co(II)(tacn)2]I2 . 2 H2O and of [Co(III)(ttcn)2](ClO4)3.
Authors: KUEPPERS H.‐J. + , NEVES A. , POMP C. , VENTUR D. , WIEGHARDT K. , NUBER B. , WEISS J. 
Published: May 2016

AbstractThe cobalt complexes (I), (II), (IV) and (VII) have been prepared previously and their electronic spectra have been reported.
ChemInform Abstract: Efficient Nickel Based Catalyst for the Homogeneous Reduction of Aromatic Nitro Compounds.
Authors: GIANNOCCARO P. , PANNACCIULLI E. 
Published: May 2016

AbstractThe reduction of aromatic nitro Compounds under CO pressure (40 at) at 180°C in the presence of Ni(II) complexes as catalysts precursor is investigated.
ChemInform Abstract: Binuclear Molecules Incorporating Small Molecules as Bridging Ligands.
Authors: O'CONNOR C. J. , FIRMIN D. , PANT A. K. , BABU B. R. , STEVENS E. D. 
Published: May 2016

AbstractStoichiometric amounts of the ligand, prepared by condensation reaction of 2‐formyl‐4‐methylsalicylaldehyde with 2‐aminomethyl‐pyridine, react with Cu(ClO4)2, CuBr2 and Cu(NO3)2 in methanol to the complexes (I).
ChemInform Abstract: Exchange Interaction in Multinuclear Transition‐Metal Complexes.
Authors: CHIARI B. , HELMS J. H. , PIOVESANA O. , TARANTELLI T. , ZANAZZI P. F. 
Published: May 2016

AbstractThe condensation of N‐methyl‐1,3‐propanediamine in anhydrous ethanol with the appropriate 5‐substituted 2‐hydroxybenzaldehyde yields the tridentate Schiff base ligands which react with copper acetate monohydrate to give the new complexes (I).
ChemInform Abstract: A Cu ‐ (μ‐H) Bond Can Be Stronger Than an Intramolecular P→Cu Bond. Synthesis and Structure of Cu2(μ‐H)2(η2‐CH3C(CH2PPh2)3)2.
Authors: GOEDEN G. V. , HUFFMAN J. C. , CAULTON K. G. 
Published: May 2016

AbstractThe hydrogenolysis of (I) in the prescence of the tripod‐ligand yields the thermally unstable complex (II).
ChemInform Abstract: Formation and Photophysical Properties of Tetranuclear Bipyridyl Complexes of the Type {[(bpy)2Ru(L‐L)]3Fe}.
Authors: SCHMEHL R. H. , AUERBACH R. A. , WACHOLTZ W. F. , ELLIOTT C. M. , FREITAG R. A. , MERKERT J. W. 
Published: May 2016

AbstractStarting with 4,4′‐dimethyl‐2,2′‐bipyridine, the synthesis of the ligands (I) with alkyl linkages is described.
ChemInform Abstract: Nucleophilic Attack at the Carbon Atom of a Dithiocarbene Ligand by Coordinated Carbon Disulphide: The Molecular Structure of [(dppe)IPt(μ‐C(S)SC(SMe)2)Pt(dppe)]+ I‐ (dppe: 1,2‐bis(diphenylphosphino)ethane).
Authors: MYRVOLD S. , NASSIF O. A. , SEMELHAGO G. , WALKER A. , FARRAR D. H. 
Published: May 2016

AbstractReaction of the complex (I) with excess methyl iodide results in the formation of the dimeric title complex (II).
ChemInform Abstract: The Synthesis and Proton Nuclear Magnetic Resonance Study of Some Nitro‐ and Amino‐Unsymmetrically m‐Substituted Tetraphenylporphyrins.
Authors: SUN Y. , MARTELL A. E. , TSUTSUI M. 
Published: May 2016

AbstractDie Cokondensation zwischen Benzaldehyd (I), m‐Nitrobenzaldehyd (II) und Pyrrol (III) liefert ein Gemisch der gewünschten Mononitroverbindung (IVa) mit den Verbindungen (IVb)‐(IVe), das an Silicagel in die Einzelkomponenten getrennt werden kann.
ChemInform Abstract: Studies in Terpenoids. Part 65. Synthesis of 4‐(2′‐Methoxy‐5′‐methylphenyl)‐6‐methylheptan‐2‐one, a seco‐Sesquiterpene Structural Analogue of Sesquichamaenol and Himasecolone.
Authors: SARMA M. S. P. , RAO G. S. K. 
Published: May 2016

AbstractThe title compound (III) is synthesized in one step as shown in the scheme (no yield given).
ChemInform Abstract: A Cellular Ligand‐field Study of the CuCl42‐ Ion in Cs2(CuCl4)
Authors: DEETH R. J. , GERLOCH M. 
Published: May 2016

Abstract[shows that the ligand‐field trace, expressed as the sum of local, diagonal ligand‐field matrix elements, in Cs2[CuCl4] is anomalous compared with those collected in the present paper for 26 complexes of Cu(II), Ni(II), and Co(II).
ChemInform Abstract: Characterisation of CrO2Br2 and CrO2BrCl by Matrix‐isolation Infrared Spectroscopy.
Authors: HOPE E. G. , LEVASON W. , OGDEN J. S. , TAJIK M. 
Published: May 2016

AbstractCrO2Br2 (prepared from HBr and CrO2Cl2) and CrO2BrCl (existing in mixtures of CrO2Br2 and CrO2Cl2) are found to be isostructural with the previously known chromyl halides.
ChemInform Abstract: Vibrational Study of Lithium Sulfate Based Fast Ionic Conducting Borate Glasses.
Authors: KAMITSOS E. I. , KARAKASSIDES M. A. , CHRYSSIKOS G. D. 
Published: May 2016

AbstractCombined Raman and IR results for xLizO ‐ yLi2SO4‐ B203 fast ionic conducting glasses with compositions probing the whole glass‐forming region (x = 0.20, 0.56; y = O‐O.50) show that Li2SO4 additions induce the formation of B04 tetrahedra.
ChemInform Abstract: Crystallographic and Spectroscopic Behaviour of Some Mixed Phosphate/Vanadate Fluoroapatites.
Authors: LAVAT A. E. , ETCHEVERRY S. B. , BARAN E. J. 
Published: May 2016

AbstractX‐ray powder diffraction data show that in the series M",(PO6)6‐"(VO4)"F2 (M: Ca, Sr, Ba; x: 1‐3) the unit cell dimensions (P63/ m) increase with increasing x. IR and Raman spectra indicate that theVOä′ incorporation has a negligible effect on the P‐Obond strength, although a slight bond weakening for both tetrahedral oxoanions is observed as the unit cell volume increases.
ChemInform Abstract: Bipolar TiO2/Pt Semiconductor Photoelectrodes and Multielectrode Arrays for Un‐ assisted Photolytic Water Splitting.
Authors: SMOTKIN E. , BARD A. J. , CAMPION A. , FOX M. A. , MALLOUK T. , WEBBER S. E. , WHITE J. M. 
Published: May 2016

AbstractBipolar TiO2/Pt photoelectrodes, fabricated by anodization of thin Ti foils onto which Pt has been previously sputter‐deposited are shown to be capable of a vectorial charge transfer.
ChemInform Abstract: Reaction of N2O5 with H2O on Carbonaceous Surfaces.
Authors: BROUWER L. , ROSSI M. J. , GOLDEN D. M. 
Published: May 2016

AbstractThe interaction of gaseous N2O5 with a carbonaceous surface, in both the absence and presence of H2O, is investigated in relation to its possible atmospheric importance (collision between gas molecules and particles in a highly polluted urban environment).