bluuebunny/crossref_metadata_2025_split huggingface dataset:
Immunomodulation of inflammatory leukocyte markers during intravenous immunoglobulin treatment associated with clinical efficacy in chronic inflammatory demyelinating polyradiculoneuropathy
Authors: Dyer Wayne B. , Tan Joanne C. G. , Day Timothy , Kiers Lynette , Kiernan Matthew C. , Yiannikas Con , Reddel Stephen , Ng Karl , Mondy Phillip , Dennington Peta M. , Dean Melinda M. , Trist Halina M. , dos Remedios Cristobal , Hogarth P. Mark , Vucic Steve , Irving David O. 
Published: July 2016

AbstractObjectiveThe objective of the study was to profile leukocyte markers modulated during intravenous immunoglobulin (IVIg) treatment, and to identify markers and immune pathways associated with clinical efficacy of IVIg for chronic inflammatory demyelinating polyradiculoneuropathy (CIDP) with potential for monitoring treatment efficacy.MethodsResponse to IVIg treatment in newly diagnosed IVIg‐naïve and established IVIg‐experienced patients was assessed by changes in expression of inflammatory leukocyte markers by flow cytometry. The adjusted INCAT disability and Medical Research Council sum scores defined clinical response.ResultsIntravenous immunoglobulin modulated immunopathogenic pathways associated with inflammatory disease in CIDP. Leukocyte markers of clinical efficacy included reduced CD185+ follicular helper T cells, increased regulatory markers (CD23 and CD72) on B cells, and reduction in the circulating inflammatory CD16+ myeloid dendritic cell (mDC) population and concomitant increase in CD62L and CD195 defining a less inflammatory lymphoid homing mDC phenotype. A decline in inflammatory CD16+ dendritic cells was associated with clinical improvement or stability, and correlated with magnitude of improvement in neurological assessment scores, but did not predict relapse. IVIg also induced a nonspecific improvement in regulatory and reduced inflammatory markers not associated with clinical response.ConclusionsClinically effective IVIg modulated inflammatory and regulatory pathways associated with ongoing control or resolution of CIDP disease. Some of these markers have potential for monitoring outcome.
Isoflavone Content in Subterranean Clover Germplasm from Sardinia
Authors: Tava Aldo , Stochmal Anna , Pecetti Luciano 
Published: July 2016

Subterranean clover (Trifolium subterraneum) is an important pasture legume, and Sardinia is known as a major centre of diversification of this species. As other legumes, this clover produces biologically active flavonoids including the subclass of isoflavones that are natural phytoestrogens with positive health effects. Present sources of isoflavones for medical/nutraceutical treatments are red clover (Trifolium pratense) and soybean (Glycine max). This study assessed the content and composition of flavonoids in 14 subterranean clover genotypes from Sardinia, grown ex‐situ in comparison with two red clover ecotypes, to acquire information on the potential of the species as an alternative source of isoflavones for possible exploitation. Twenty compounds were tentatively identified across the two clovers after HPLC and LC/ESI‐MS analyses, including clovamide, four flavonols, and 15 isoflavones. Most compounds were present as glucosides or glucosyl malonates. Subterranean clover extracts mainly comprised of derivatives of the isoflavones genistein, biochanin A, and formononetin. Compared to red clover, subterranean clover had higher content of total isoflavones and lower concentration of total flavonols. The isoflavone concentration in subterranean clover was higher than literature data for soybean or red clover. The existing genotypic variation warrants the possibility of selecting varieties with high isoflavone concentration for nutraceutical or pharmaceutical purposes.
Grasses andRhodococcuserythropolisBacteria for Bioremediation of Naturally Polluted Soils with Hydrocarbons
Authors: Mirzakhani Elnaz , Nejad Forogh Mortazaei 
Published: July 2016

AbstractA combination of grasses, Kentucky bluegrass and Bermuda grass, withRhodococcuserythropolisbacteria was hypothesized for bioremediation of naturally polluted soils with hydrocarbons. A 90‐day greenhouse experiment as a factorial design with twelve treatments including soil inoculation with bacteria as well as soil sterilization using both plants in three replicates was performed. Both grasses significantly decreased the concentration of soil hydrocarbons compared with the control polluted soil, with Kentucky grass being the more effective one. The bacteria enhanced the bioremediation abilities of both plants, especially of Kentucky grass. Soil sterilization substantially reduced the rate of hydrocarbons in the soil. The positive effects of bacteria on the process of bioaugmentation make this method of bioremediation strongly recommendable.
Study of Hydrogen Peroxide Reactions on Manganese Oxides as a Tool To Decode the Oxygen Reduction Reaction Mechanism
Authors: Ryabova Anna S. , Bonnefont Antoine , Zagrebin Pavel , Poux Tiphaine , Paria Sena Robert , Hadermann Joke , Abakumov Artem M. , Kéranguéven Gwénaëlle , Istomin Sergey Y. , Antipov Evgeny V. , Tsirlina Galina A. , Savinova Elena R. 
Published: July 2016

AbstractHydrogen peroxide has been detected as a reaction intermediate in the electrochemical oxygen reduction reaction (ORR) on transition‐metal oxides and other electrode materials. In this work, we studied the electrocatalytic and catalytic reactions of hydrogen peroxide on a set of Mn oxides, Mn2O3, MnOOH, LaMnO3, MnO2, and Mn3O4, that adopt different crystal structures to shed light on the mechanism of the ORR on these materials. We then combined experiment with kinetic modeling with the objective to correlate the differences in the ORR activity to the kinetics of the elementary reaction steps, and we uncovered the importance of structural and compositional factors in the catalytic activity of the Mn oxides. We concluded that the exceptional activity of Mn2O3 in the ORR is due to its high catalytic activity both in the reduction of oxygen to hydrogen peroxide and in the decomposition of the latter, and furthermore, we proposed a tentative link between crystal structure and reactivity.
Palladium Nanoparticles Supported on Three‐Dimensional Graphene Nanosheets: Superior Cathode Electrocatalysts
Authors: Kabir Sadia , Serov Alexey , Zadick Anicet , Artyushkova Kateryna , Atanassov Plamen 
Published: July 2016

AbstractThe oxygen reduction reaction taking place in the cathode compartment of alkaline exchange membrane fuel cells plays a crucial role in optimizing the electrochemical energy conversion efficiency of the cell. It has therefore become imperative to design electrocatalysts that can efficiently catalyze the electroreduction of oxygen in alkaline media. In this work, palladium nanoparticles were synthesized by using a surfactant‐free method and deposited on 3D graphene nanosheets (Pd/3D‐GNSs) with morphologies modified by sacrificial templating. The Pd nanoparticles dispersed on the 3D‐GNSs have a face‐centered cubic crystalline structure with an average particle size of 4–5 nm. By using various surface analysis techniques, it was shown that the porous 3D‐GNS supports were highly graphitized and facilitated the dispersion of Pd nanoparticles. By using cyclic voltammetry, it was demonstrated that, relative to Pd nanoparticles supported on commercial carbon black (Vulcan XC‐72R), the Pd/3D graphene nanocomposites had increased electrochemically accessible surface areas and significantly higher catalytic activity towards the four‐electron reduction of oxygen, with an onset potential closer to theoretical values and minimal hydrogen peroxide yields (3–4 %). Overall, the 3D graphene nanosheets significantly enhanced the performance of Pd nanoparticles in alkaline exchange membrane fuel cells by improving their dispersion, increasing the active surface area, and enhancing mass‐transport kinetics through its porous 3D morphology.
A Molecular Relay‐Modified CdS‐Sensitized Photoelectrochemical Cell for Overall Water Splitting
Authors: Shen Chao , Chua Chin Sheng , Lim Yee‐Fun , Liu Jie , Wang Xingzhu , Liu Bin , Wang Qing 
Published: July 2016

AbstractA novel approach to enhance the photocurrent and photostability of semiconductor‐sensitized photoelectrochemical cells (PECs) with a nonsacrificial electrolyte by grafting the CdS surface with a molecular relay, 4‐(N,N‐diphenylamino)benzoic acid (DPABA) is reported. Using this modification, the PECs are able to perform overall water splitting instead of only hydrogen generation. The probable reasons for the improvement are that the photogenerated holes in the CdS valence band could be rapidly removed by DPABA, which facilitates charge separation and thus suppresses the photocorrosion process. The use of such a method might further improve the performance of overall water splitting, together with superior light‐absorption sensitizers and more suitable molecular relays with better oxygen evolution reaction catalytic properties.
ChemInform Abstract: Crystal Structures and Magnetic Properties of Iron Borates Containing Lanthanides Sr6LnFe(BO3)6 (Ln: La, Pr, Nd, Sm—Lu).
Authors: Inoue Hiroki , Doi Yoshihiro , Hinatsu Yukio 
Published: July 2016

AbstractThe polycrystalline iron borates of title are prepared by firing stoichiometric amounts of SrCO3, Ln2O3 resp.
ChemInform Abstract: Non‐Rare‐Earth BaMgAl10‐2xO17:xMn4+,xMg2+: A Narrow‐Band Red Phosphor for Use as a High‐Power Warm w‐LED.
Authors: Wang Bo , Lin Hang , Huang Feng , Xu Ju , Chen Hui , Lin Zebin , Wang Yuansheng 
Published: July 2016

AbstractBaMgAl10‐2xO17:xMn4+, xMg2+ (x = 0.005—0.05) samples are prepared by firing and sintering stoichiometric amounts of BaCO3, MgO, Al2O3, and MnCO3 in air (1.
ChemInform Abstract: High Thermopower with Metallic Conductivity in p‐Type Li‐Substituted PbPdO2.
Authors: Lamontagne Leo K. , Laurita Geneva , Gaultois Michael W. , Knight Michael , Ghadbeigi Leila , Sparks Taylor D. , Gruner Markus E. , Pentcheva Rossitza , Brown Craig M. , Seshadri Ram 
Published: July 2016

AbstractPolycrystalline PbPd1‐xLixO2 (x = 0—0.8) are prepared by repeated heating of stoichiometric amounts of PbCO3, PdO, and Li2CO3 (Al2O3 crucible, 700 °C, 12 h).
ChemInform Abstract: Peculiarities of Thermoelectric Half‐Heusler Phase Formation in Gd‐Ni‐Sb and Lu‐Ni‐Sb Ternary Systems.
Authors: Romaka V. V. , Romaka L. , Horyn A. , Rogl P. , Stadnyk Yu , Melnychenko N. , Orlovskyy M. , Krayovskyy V. 
Published: July 2016

AbstractPhase equilibria in the Gd—Ni—Sb and Lu—Ni—Sb systems are studied at 873 K by powder XRD and microstructure analyses.
ChemInform Abstract: Synthesis, Crystal Structure, and Electrochemical Properties of a Simple Magnesium Electrolyte for Magnesium/Sulfur Batteries.
Authors: Zhang Yuegang , et al.  
Published: July 2016

Abstract[Mg(THF)6][AlCl4]2 is prepared by reaction of MgCl2 and AlCl3 in 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid (95 °C, 1 d) to which THF is given.
ChemInform Abstract: Reduced Graphene‐Wrapped MnO2 Nanowires Self‐Inserted with Co3O4 Nanocages: Remarkable Enhanced Performances for Lithium‐Ion Anode Applications.
Authors: Zhu Qi , Li Yunhui , Gao Ying , Wang Xiao , Song Shuyan 
Published: July 2016

AbstractMnO2 nanowires are prepared by preparing MnO2 nanowires by hydrothermal reaction of a 1:1 molar mixture of aqueous KMnO4 and NH4Cl (autoclave, 200 °C, 1 d) followed by attaching a zeolitic imidazole framework (ZIF‐76) to the wires by an aqueous solution of ethylene imine polymer.
ChemInform Abstract: Substitution of Lithium for Magnesium, Zinc, and Aluminum in Li15Si4: Crystal Structures, Thermodynamic Properties, as well as 6Li and 7Li NMR Spectroscopy of Li15Si4 and Li15‐xMxSi4 (M: Mg, Zn, and Al).
Authors: Baran Volodymyr , van Wuellen Leo , Faessler Thomas F. 
Published: July 2016

AbstractSingle crystals of Li14MgSi4 (I) and Li14.05Zn0.95Si4 (II) are prepared by solid state reaction of Si, Si/Mg2Si powder or Zn, and Li (Ta ampoules in silica jackets, 750 °C, 1 h, controlled cooling).
ChemInform Abstract: Counteranion‐Stabilized Titanium(IV) Isopolyoxocationic Clusters Isolated from Water.
Authors: Zhang Guanyun , Hou Jie , Li Mingzhong , Tung Chen‐Ho , Wang Yifeng 
Published: July 2016

AbstractCompounds (II) and (IV) are characterized by single crystal XRD and vibrational and NMR spectroscopy.
ChemInform Abstract: A5RE4X[TO4]4 Crystal Growth: Fluoride Flux Synthesis of Na5Ln4F[GeO4]4 (Ln: Pr, Nd), the First Quaternary Germanate Oxyfluorides.
Authors: Latshaw Allison M. , Wilkins Branford O. , Morrison Gregory , Smith Mark D. , zur Loye Hans‐Conrad 
Published: July 2016

AbstractCrystals of the title compounds are prepared from mixtures of Ln2O3 (Ln: Pr, Nd), Na2CO3, and GeO2 using eutectic NaF/NaCl as flux (Ag crucible, 800 °C, 24 h).
ChemInform Abstract: Synthesis and Characterization of ReS2 and ReSe2 Layered Chalcogenide Single Crystals.
Authors: Jariwala Bhakti , Voiry Damien , Jindal Apoorv , Chalke Bhagyashree A. , Bapat Rudheer , Thamizhavel Arumugam , Chhowalla Manish , Deshmukh Mandar , Bhattacharya Arnab 
Published: July 2016

AbstractSingle crystals of ReS2 (I) and ReSe2 (II) are grown by a modified Bridgman method from the constituent elements (evacuated quartz tubes, 1100 °C, 24 h; cooling to 900 °C at a rate of 1 °C/h).
ChemInform Abstract: Synthesis, Structure, and Magnetic Properties of the Perovskite La0.3Sm0.2Sr0.5Ti0.5 Fe0.5O3.
Authors: Singh Devinder , Sharma Narayan Dutt , Mahajan Arun , Singh Suram 
Published: July 2016

AbstractPolycrystalline La0.3Sm0.2Sr0.5Ti0.5 Fe0.5O3 is prepared by a citrate‐gel reaction starting with stoichiometric amounts of La2O3, Sm2O3, SrCO3, Ti(O‐iPr)4, and Fe(NO3)3 in aq.
ChemInform Abstract: Sponge‐Like Silver Obtained by Decomposition of Silver Nitrate Hexamethylenetetramine Complex.
Authors: Afanasiev Pavel 
Published: July 2016

AbstractDecomposition of AgNO3·hexamethylenetetramine (obtained from an aqueous mixture of AgNO3 and hexamethylenetetramine) under N2 above 200 °C leads to the formation of sponge‐like silver with pore sizes from 10 μm to 10 nm.
ChemInform Abstract: A Broensted Acid‐Amino Acid as a Synergistic Catalyst for Asymmetric List—Lerner—Barbas Aldol Reactions.
Authors: Ramachary Dhevalapally B. , Shruthi Kodambahalli S. 
Published: July 2016

AbstractThe combination of a thiazole‐based amino acid with TFA provides a synergistic catalyst for the asymmetric LLB aldol reaction of less reactive o‐azidobenzaldehydes with simple ketones.
ChemInform Abstract: Switching the Cleavage Sites in Palladium on Carbon‐Catalyzed Carbon—Carbon Bond Disconnection.
Authors: Hattori Tomohiro , Takakura Ryoya , Ichikawa Tomohiro , Sawama Yoshinari , Monguchi Yasunari , Sajiki Hironao 
Published: July 2016

AbstractThe regioselectivity of C—C bond cleavage in cinnamaldehyde derivatives can be altered by slight change of the reaction conditions.
ChemInform Abstract: N‐Rich Fused Heterocyclic Systems: Synthesis, Structure, Optical and Electrochemical Characterization.
Authors: Fusco Sandra , Maglione Cira , Velardo Amalia , Piccialli Vincenzo , Liguori Rosalba , Peluso Andrea , Rubino Alfredo , Centore Roberto 
Published: July 2016

AbstractAcid‐mediated condensation of diones (I) with diamino triazole (II) produces nitrogen‐rich fused heterocycles.
ChemInform Abstract: A New Approach for the Synthesis of Highly Substituted Aromatic Rings: The Alkyne‐Mediated Approach.
Authors: Parsons Philip J. , Jones Daniel R. , Padgham Alex C. , Allen Lewis A. T. , Penkett Clive S. , Green Robert A. , White Andrew J. P. 
Published: July 2016

AbstractPentasubstituted aromatic rings, useful templates for drug design, are prepared by thermolysis of suitably substituted alkynes under microwave conditions.
ChemInform Abstract: Synthesis of Nitriles from Amines Using Nanoscale Co3O4‐Based Catalysts via Sustainable Aerobic Oxidation.
Authors: Natte Kishore , Jagadeesh Rajenahally V. , Sharif Muhammad , Neumann Helfried , Beller Matthias 
Published: July 2016

AbstractThis green and selective oxidation process for the synthesis of nitriles from amines using molecular oxygen and aqueous ammonia is catalyzed by a nanostructured cobalt oxide‐based material, which is activated by nitrogen‐doped graphene layers.
ChemInform Abstract: CuSO4‐Mediated Decarboxylative Difluoroacetamidation of α,β‐Unsaturated Carboxylic Acids.
Authors: Chen Qiao , Wang Chao , Zhou Jiawei , Wang Yanan , Xu Zhaoqing , Wang Rui 
Published: July 2016

AbstractAn efficient protocol for preparation of difluorinated alkenes is presented.
ChemInform Abstract: Metal‐Free Allylation of Electron‐Rich Heteroaryl Boronic Acids with Allylic Alcohols.
Authors: Li Xue‐Dong , Xie Li‐Jun , Kong De‐Long , Liu Li , Cheng Liang 
Published: July 2016

AbstractThe regioselective cross‐coupling of heteroaryl boronic acids with allylic alcohols works under external oxidant‐ and metal‐free conditions, and proves to be very general with an unprecedented selectivity for ortho‐functionalization of the boronic acids.
ChemInform Abstract: General Method for Nucleophilic Aromatic Substitution of Aryl Fluorides and Chlorides with Dimethylamine Using Hydroxide‐Assisted Decomposition of N,N‐Dimethylforamide.
Authors: Garcia Juana , Sorrentino Jacob , Diller Emily J. , Chapman Daniel , Woydziak Zachary R. 
Published: July 2016

AbstractThe synthesis can be scaled up to gram quantities without significant change in yield.
ChemInform Abstract: Expanding the Scope of Primary Amine Catalysis: Stereoselective Synthesis of Indanedione‐Fused 2,6‐Disubstituted trans‐Spirocyclohexanones.
Authors: Madhusudhan Reddy G. , Ko Chi‐Ting , Hsieh Kai‐Hong , Lee Chia‐Jui , Das Utpal , Lin Wenwei 
Published: July 2016

AbstractMechanistic investigation of these organo‐catalytic spirocyclizations reveals two competing pathways: a concerted Diels—Alder reaction and a stepwise Michael addition.
ChemInform Abstract: Spirocyclopropanation Reaction of para‐Quinone Methides with Sulfonium Salts: The Synthesis of Spirocyclopropanyl para‐Dienones.
Authors: Zhang Xiang‐Zhi , Du Ji‐Yuan , Deng Yu‐Hua , Chu Wen‐Dao , Yan Xu , Yu Ke‐Yin , Fan Chun‐An 
Published: July 2016

AbstractA diastereoselective spirocyclopropanation is achieved using a chiral binaphthyl‐based sulfonium salt.
ChemInform Abstract: Substrate‐Dependent Mechanistic Divergence in Decarboxylative Heck Reaction at Room Temperature.
Authors: Hossian Asik , Bhunia Samir Kumar , Jana Ranjan 
Published: July 2016

AbstractHeck‐type reactions between arene carboxylic acids and alkenes proceed by two distinct pathways: electron‐rich compounds undergo Pd(II)‐catalyzed decarboxylation while silver(I)‐assisted decarboxylation works for electron‐deficient substrates.
ChemInform Abstract: Transition Metal‐Free Dimerization of Alkynes Using Hypervalent Iodine Reagents.
Authors: Schoergenhumer Johannes , Waser Mario 
Published: July 2016

AbstractThe use of acetoxybenziodoxole as activating agent facilitates the homo‐coupling of terminal alkynes under operationally simple conditions to give aryl‐ and alkyl‐substituted 1,3‐diynes.
ChemInform Abstract: Enantioselective Benzoin Condensation Catalyzed by Spirocyclic Terpene‐Based N‐Heterocyclic Carbenes.
Authors: Rafinski Zbigniew 
Published: July 2016

AbstractA series of new chiral spirocyclic triazolium salts, derived from (1S)‐fenchone and (IR)‐camphorquinone, act as N‐heterocyclic carbene precatalysts and are employed in the catalytic asymmetric benzoin condensation to afford acyloins.
ChemInform Abstract: Cobalt(II)‐Catalyzed C—H Amination of Arenes with Simple Alkylamines.
Authors: Zhang Lin‐Bao , Zhang Shou‐Kun , Wei Donghui , Zhu Xinju , Hao Xin‐Qi , Su Jian‐Hang , Niu Jun‐Long , Song Mao‐Ping 
Published: July 2016

AbstractA broad spectrum of arylamides can be readily ortho‐aminated with simple six‐membered secondary amines.
ChemInform Abstract: Catalytic Asymmetric Synthesis of Enantioenriched β‐Nitronitrile Bearing a C‐CF3 Stereogenic Center
Authors: Jakhar Ajay , Kumari Prathibha , Nazish Mohd , Khan Noor‐ul H. , Kureshy Rukhsana I. , Abdi Sayed H. R. , Suresh E. 
Published: July 2016

Abstractby hydrocyanation reaction using an in situ generated chiral Ti(IV) salen complex as catalyst
ChemInform Abstract: Synthesis of Vinyl Isocyanides and Development of a Convertible Isonitrile.
Authors: Spallarossa Martina , Wang Qian , Riva Renata , Zhu Jieping 
Published: July 2016

AbstractThe Wittig reaction of isocyanomethylenetriphenylphosphorane, in situ generated from the corresponding phosphonium salts, with various aldehydes affords vinyl isocyanides with good to high yields.
ChemInform Abstract: Aryl and Heteroaryl Nosylates as Stable and Cheap Partners for Suzuki—Miyaura Cross‐Coupling Reactions.
Authors: Dikova Anna , Cheval Nicolas P. , Blanc Aurelien , Weibel Jean‐Marc , Pale Patrick 
Published: July 2016

AbstractFirst time, (het)aryl para‐nitrophenylsulfonates (nosylates) are successfully used in Suzuki—Miyaura cross‐coupling reactions with various aryl or vinylboronic acids.
ChemInform Abstract: Design, Synthesis, and Validation of an Effective, Reusable Silicon‐Based Transfer Agent for Room‐Temperature Pd‐Catalyzed Cross‐Coupling Reactions of Aryl and Heteroaryl Chlorides with Readily Available Aryl Lithium Reagents.
Authors: Martinez‐Solorio Dionicio , Melillo Bruno , Sanchez Luis , Liang Yong , Lam Erwin , Houk K. N. , Smith Amos B. III 
Published: July 2016

AbstractIn continuation of previously published studies, an improved silicon‐based transfer agent allowing for cross‐coupling reactions using (hetero)aryl chlorides is designed.
ChemInform Abstract: Open‐Shell Phenalenyl in Transition Metal‐Free Catalytic C—H Functionalization.
Authors: Paira Rupankar , Singh Bhagat , Hota Pradip Kumar , Ahmed Jasimuddin , Sau Samaresh Chandra , Johnpeter Justin P. , Mandal Swadhin K. 
Published: July 2016

AbstractA phenalenyl ligand (MAP) promotes a chelation‐assisted single electron transfer process, facilitating the C—H functionalization of unactivated arenes to form the biaryl products.
ChemInform Abstract: On‐Water Synthesis of Biaryl Sulfonyl Fluorides.
Authors: Chinthakindi Praveen K. , Kruger Hendrik G. , Govender Thavendran , Naicker Tricia , Arvidsson Per I. 
Published: July 2016

AbstractThis ligand‐ and additive‐free Suzuki—Miyaura‐coupling protocol is compatible with the —SO2—F group, giving access to a wide range of bioorthogonal click reagents.
ChemInform Abstract: Highly Enantioselective Rhodium‐Catalyzed Addition of Arylboroxines to Simple Aryl Ketones: Efficient Synthesis of Escitalopram.
Authors: Huang Linwei , Zhu Jinbin , Jiao Guangjun , Wang Zheng , Yu Xingxin , Deng Wei‐Ping , Tang Wenjun 
Published: July 2016

AbstractA range of chiral diaryl alkyl carbinols is prepared with excellent yields and enantioselectivities as well as broad functional group tolerance utilizing a Rh/(R,R,R,R)‐WingPhos catalyst.
ChemInform Abstract: Copper‐ versus Palladium‐Catalyzed Aromatization of 2‐(Methoxycarbonyl) Tetralones: Synthesis of Methyl 1‐Hydroxy‐2‐naphthoates.
Authors: Civicos Jose F. , Ribeiro Carlos M. R. , Costa Paulo R. R. , Najera Carmen 
Published: July 2016

AbstractThe aromatization of α‐tetralones substituted at the β‐position by an ester group is reported catalyzed either by CuI or Pd2(dba)3.
ChemInform Abstract: Insertion of N‐Tosylacetimidates/Acetimidamides onto Arynes via [2 + 2] Cycloaddition.
Authors: Kranthikumar Ramagonolla , Chegondi Rambabu , Chandrasekhar Srivari 
Published: July 2016

AbstractThis novel insertion reaction proceeds via formation of a benzocyclobutene intermediate followed by ring cleavage.
ChemInform Abstract: Synthesis of Oxygenated 1‐Arylnaphthalenes.
Authors: Chang Meng‐Yang , Huang Yi‐Hsuan , Wang Heui‐Sin 
Published: July 2016

AbstractThe Lewis acid‐mediated one‐pot tandem benzannulation of alkynols with oxygenated benzenes provides arylnapthalenes in moderate to good yields.
ChemInform Abstract: Hydrogen‐Bonding Network Promoted [3 + 2] Cycloaddition: Asymmetric Catalytic Construction of Spiro‐Pseudoindoxyl Derivatives.
Authors: Zhang Liang‐Jie , Wang Yao , Hu Xiu‐Qin , Xu Peng‐Fei 
Published: July 2016

AbstractSpiro‐pseudoindoxyl derivatives with three stereocenters including one quaternary one are formed in high yields, with excellent diastereoselectivities and high enantioselectivities.