bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Thiophosphorylated 3(5)‐Amino‐4‐cyano(ethoxycarbonyl)pyrazoles.
Authors: RAZVODOVSKAYA L. V. , PUTSYKINA E. B. , ERIKOVA M. V. , KISELEVA N. A. , VASIL'EV A. F. , GRAPOV A. F. , MEL'NIKOV N. N. 
Published: May 2016

AbstractThiophosphorylation of the aminopyrazoles (I) with the thiophosphonic (thiophosphoric) chlorides (II) produces mainly the 3‐amino‐1‐thiophosphorylpyrazoles (III).
ChemInform Abstract: Synthesis and Chemical Behavior of 12‐Substituted Dibenz(c,f)(1,5)azastibocine and Dibenz(c,f)(1,5)azabismocine Derivatives: Evidence of 10‐Pn‐4 Type Hypervalent Interaction.
Authors: OHKATA K. , TAKEMOTO S. , OHNISHI M. , AKIBA K. 
Published: May 2016

AbstractMethyldi(o‐bromobenzyl)amine (I) is lithiated and then treated with the pnictogen trichlorides (II) to give the dibenzo‐fused heterocycles (III), which undergo substitution reactions, forming the derivatives (IV), (VI), or (VIII).
ChemInform Abstract: Synthesis, Redox Properties, and Reactivity of a Novel Family of Electron‐Rich Vinylidene and Vinylphosphonium Complexes of Rhodium(I).
Authors: BIANCHINI C. , MELI A. , PERUZZINI M. , ZANOBINI F. , ZANELLO P. 
Published: May 2016

AbstractThe vinylidene complexes (II) react with nucleophiles such as NEt3, MeLi, or PhLi via deprotonation to restore the parent σ‐acetylide compounds.
ChemInform Abstract: 4‐Hydroxybutyric Acid (and Analogues) Derivatives of D‐Glucosamine.
Authors: DARDOIZE F. , GOASDOUE C. , GOASDOUE N. , LABORIT H. M. , TOPALL G. 
Published: May 2016

Abstractγ‐Hydroxybutyric acid (GHB) is known to act as a neuromodulator or neurotransmitter in the CNS.
ChemInform Abstract: Facile Synthesis of 8‐Benzoylthio‐2,6‐methano‐3‐benzazocines and 3‐Benzoylthiomorphinans Having Small‐Ring Substitutents.
Authors: HORI M. , IWAMURA T. , MORITA T. , IMAI E. , OJI H. , KATAOKA T. , SHIMIZU H. , BAN M. , NOZAKI M. , NIWA M. , FUJIMURA H. 
Published: May 2016

AbstractRegioselective chlorosulfonation of the 2,6‐methano‐3‐benzazocines (I) leads to the formation of the sulfonyl chlorides (III) which are reduced with Zn/H2SO4 and subsequently acylated with benzoyl chloride (IV) to give the 8‐benzoylthio derivatives (V).
ChemInform Abstract: Intra‐ and Intermolecular Nucleophilic Phosphorus‐Sulfur Bond Cleavage. The Reaction of Fluoride Ion with O‐Aryl‐O,S‐dialkylphosphorothioates, and the Degradation of Phosphorothioate Linkage in di‐Ribonucleotides by the Vicinal 2′‐Hydroxyl Group.
Authors: SUND C. , CHATTOPADHYAYA J. 
Published: May 2016

AbstractOn treatment with Bu4NF the title dialkylphosphorothioates of type (I) and (III) undergo scission of the phosphorus‐sulfur bond to form phosphoromonofluoridates, e.g. (II) and (IV).
ChemInform Abstract: Preparation of Chiral, Highly Functionalized Cyclopentanes and Its Application to the Synthesis of Prostaglandin E1.
Authors: OKANO K. , SUEMUNE H. , SAKAI K. 
Published: May 2016

AbstractBase‐catalyzed cyclization of the 1,4‐diketone (I) and subsequent oxidation during chromatography on silica gel produce enantiomeric mixtures of the regioisomeric cyclopentenones (II) and (III).
ChemInform Abstract: The Superconductivity of the Series MxSnMo6S7.0 (M: Y, Ag, In, Pb, Bi).
Authors: WAKIHARA M. , SATOH K. , HINODE H. , TANIGUCHI M. 
Published: May 2016

AbstractThe relationships between doping element, doping level, lattice parameters, and Tc are studied.
ChemInform Abstract: Spectroscopic Studies of Molybdate Species Deposited on a Nb2O5 Support
Authors: JIN Y. S. , AUROUX A. , VEDRINE J. C. 
Published: May 2016

Abstract(XRD, Raman, FTIR, diffuse reflectance, ESCA, FABMS‐SIMS) show that the nature and structure of surface molybdate species mainly depend on the Mo loading and to a lesser extent on the preparation method (impregnation at pH 0.5 and 5.5, equilibrium adsorption methods).
ChemInform Abstract: Open‐Chain Polyamine Ligands with More Rigid Double Connecting Bridges. Study of Their Metal Ion Selectivities by Molecular Mechanics Calculation, Crystallography, and Thermodynamics.
Authors: HANCOCK R. D. , NGWENYA M. P. , EVERS A. , WADE P. W. , BOEYENS J. C. A. , DOBSON S. M. 
Published: May 2016

AbstractThe ligands (I)‐(III) are of interest in their potential resemblance to the corresponding tetraaza macrocycles.
ChemInform Abstract: Complete Control of the Rearrangement Modes of Enolates of α‐Allyloxy Ketones: Reversal from the (3,3)Claisen to the (2,3)Wittig Pathway by the Use of the Metalated N,N‐Dimethylhydrazones.
Authors: LUENGO J. I. , KOREEDA M. 
Published: May 2016

Abstract(2,3)Wittig rearrangement of the hydrazones (III) and (VII), obtained from the corresponding ketones (I) and (VI) with N,N‐dimethylhydrazine (II), is induced by treatment with potassium hydride to result in the formation of the α‐hydroxy hydrazones (IV) and (VIII) with predominance of the E‐stereoisomers.
ChemInform Abstract: Stereocontrolled Reduction of 2‐(p‐Tolylsulfinyl)cycloalkanones Under Basic Conditions: π‐Facial Selection in Cyclic Systems Directed by a Chiral Side Chain.
Authors: OGURA K. , ISHIDA M. , FUJITA M. 
Published: May 2016

AbstractReduction of diastereomeric mixtures of title compounds such as (I) and (II) with NaBH4 under basic conditions is accompanied by rapid epimerization at C‐2. Under the conditions employed, the π‐facial selectivity is directed by the side chain chirality and, among four possible isomers of the corresponding cycloalkanols (III)‐(VI), one isomer (III) is given with high selectivities up to 85%.
ChemInform Abstract: Reduction with Metal Borohydride‐Transition Metal Salt System. Part 1. Reduction of Aromatic Nitro Compounds with Potassium Borohydride‐Copper(I) Chloride.
Authors: HE Y. , ZHAO H. , PAN X. , WANG S. 
Published: May 2016

AbstractThe nitrobenzenes (I) are reduced with KBH4/Cu2Cl2 to yield the corresponding anilines (II).
ChemInform Abstract: Symmetrical and Unsymmetrical Coupling of Alkyl Halides Mediated by Grignard Reaction.
Authors: HERENDEEN B. L. , BHATIA S. K. , SINGH A. 
Published: May 2016

AbstractThe coupling of alkyl and aryl halides such as (I) or (V) to give symmetrical, e.g. (II), or asymmetrical products, e.g. (III) or (VI), is performed in the presence of magnesium and catalytic amounts of sodium peroxide.
ChemInform Abstract: Primary Polyfluoroallylic Alcohols. Preparation and Isomerization into 2‐Fluoroacrylic Acid Fluoride and 1‐Fluorovinyl Ketones.
Authors: NGUYEN T. , WAKSELMAN C. 
Published: May 2016

AbstractAddition of two equivalents of methyllithium (II) to the tetrafluoropropanol (I) gives the polyfluoroallylic alcohols (III) and (IV) after hydrolytic work‐up.
ChemInform Abstract: Synthesis of Ureidocarboxylic Acids and Hydantoins by Reaction of Aminocarboxylic Acids or Their Esters with Trichloroacetamides.
Authors: ATANASSOVA I. A. , PETROV J. S. , BALABANOVA A. N. , MOLLOV N. M. 
Published: May 2016

AbstractCoupling of the trichloroacetanilides (I) with the amino acids or ester (II) yields the ureidocarboxylic acids (IIIa) ‐ (IIIc) or the related carboxylate (IIId).
ChemInform Abstract: Organic Chemistry Without Solvent. Improvements to the One‐Step Preparation of Dibenzyl Sulfones.
Authors: LOUPY A. , SANSOULET J. , HARRIS A. R. 
Published: May 2016

AbstractThe reaction of benzyl bromide (I) with sodium dithionite (II) or sodium formaldehydesulfoxylate (VII) to give dibenzyl sulfone (III) is optimized.
ChemInform Abstract: Reaction of 1‐Lithio(phenylsulfinyl)cyclopropane with Electrophiles: An Alternative Synthesis of 1‐Alkyl‐ and 1‐(1‐Hydroxyalkyl)(phenylsulfinyl)cyclopropanes.
Authors: POHMAKOTR M. , SITHIKANCHANAKUL S. 
Published: May 2016

AbstractCyclopropyl phenyl sulfoxide (I) is lithiated to give the organolithium compound (III) mentioned in the title.
ChemInform Abstract: An Optically Active Terpenic Synthon for δ9‐Cannabinoids: Synthesis of (‐)‐11‐Hydroxy‐δ9‐tetrahydrocannabinol (THC) and Its 1′,1′‐Dimethylheptyl Analogue.
Authors: SIEGEL C. , GORDON P. M. , RAZDAN R. K. 
Published: May 2016

AbstractThe synthesis of (‐)‐11‐hydroxy‐Δ9‐tetrahydrocannabinol (VIIa) and its 1',1'‐dimethylheptyl analogue (VIIb) is performed as outlined in the reaction scheme.
ChemInform Abstract: Regio‐ and Stereoselectivity of Intramolecular Nitrile Oxide Cycloaddition to Furan.
Authors: ANNUNZIATA R. , CINQUINI M. , COZZI F. , RAIMONDI L. 
Published: May 2016

AbstractThe 2‐(nitroalkylsulfenyl)furans (VIII) and (XV), prepared via the lithium sulfide (III) as shown in the reaction scheme, undergo intramolecular cycloaddition reaction of the corresponding nitrile oxides to form the fused oxazolines (XI) or (XVI).
ChemInform Abstract: Pictet‐Spengler Reactions in Aprotic Media. Stereospecificity in the Pictet‐Spengler Reaction.
Authors: SANDRIN J. , HOLLINSHEAD S. P. , COOK J. M. 
Published: May 2016

AbstractPictet‐Spengler reaction of the racemic tryptophan methyl esters (±)‐(I) with the acetals (II) leads to the formation of cis/trans mixtures of the tetrahydropyrido(3,4‐b)indoles (III).
ChemInform Abstract: 1,3‐Dipolar Cycloaddition of Nitrile Oxides with 1,4‐Dihydropyridines and Conformational Analysis of Isoxazolo(5,4‐b)pyridines.
Authors: TAYLOR M. D. , HIMMELSBACH R. J. , KORNBERG B. E. , QUIN J. III , LUNNEY E. , MICHEL A. 
Published: May 2016

Abstract1,3‐Dipolar cycloaddition of the nitrile oxides (VI) with the 1,4‐dihydropyridines (V), obtained from o‐(trifluoromethyl)benzaldehyde (I) as shown in the reaction scheme, leads to the formation of the tetrahydroisoxazolo(5,4‐b)pyridines (VII).
ChemInform Abstract: Unsaturated Sulfinamides. Part 6. Substituted 4‐(1′,2′‐Alkadienesulfinyl)morpholines. Preparation and Hydrolytic Desulfinylation into the Corresponding Alkynes.
Authors: BAUDIN J.‐B. , JULIA S. A. , WANG Y. 
Published: May 2016

AbstractThe propargylic alcohol (I) reacts with morpholine‐4‐sulfenyl chloride (II) to give the allenesulfinylmorpholines (III) which are hydrolyzed to form alkynes, e.g. (IV).
ChemInform Abstract: 1‐(Acyloxy)alkyl Isocyanates. Part 3. Reactions with ortho‐Diphenols and Diols.
Authors: VOVK M. V. , DOROKHOV V. I. , SAMARAI L. I. 
Published: May 2016

AbstractThe reaction between the title compounds (I) and the catechols (II), which proceeds under very mild conditions, affords the hitherto unknown (novel‐type) 4‐oxo‐1,5,3‐benzodioxazepines (III) via an addition/elimination/intramolecular cyclization mechanism.
ChemInform Abstract: Trimethylsilyl Polyphosphate for Intramolecular Friedel‐Crafts Cyclizations.
Authors: BERMAN E. M. , SHOWALTER H. D. H. 
Published: May 2016

AbstractIntramolecular Friedel‐Crafts cyclization of the benzoic acid derivatives (I) and (III) is effected with trimethylsilyl polyphosphate (PPSE), prepared from P2O5 and hexamethyldisiloxane, yielding the (hetero)xanthenones (II) and (IV).
ChemInform Abstract: The First N‐Only‐Bonded Metal Derivatives of Cyclenphosphorane. Formation of cyclenPH·MCl2 and cyclenPH·HMCl3 (M: Zn, Cd).
Authors: KHASNIS D. V. , LATTMAN M. , SIRIWARDANE U. 
Published: May 2016

AbstractAccording to 31P NMR data the complexes (III) readily exchange MCl2 with the free ligand (I).
ChemInform Abstract: Synthesis and Transport Behavior of 1,1,6,6,11,11‐Hexamethyl‐1,6,11‐tristannacyclopentadecane.
Authors: JURKSCHAT K. , RUEHLEMANN A. + , TZSCHACH A. 
Published: May 2016

AbstractThe complexing ability of the title compound (III) for halide ions (Cl‐, Br‐) is studied, discussed and compared with that of the corresponding twelve‐membered compound.
ChemInform Abstract: Cr(CO)4(CNCF3)(CNCH3) and Cr(CO)4(CNCF3)(CNC6H5), Isocyanide Complexes with +I‐ and ‐I‐substituted Isocyanides.
Authors: LENTZ D. , POETTER B. + , MARSCHALL R. , BRUEDGAM I. + , FUCHS J. 
Published: May 2016

AbstractThe pentacarbonyl‐Cr complex (I) undergoes photolytic substitution of exclusively one CO ligand by THF giving a cis/trans mixture of the THF‐monosubstitution product.
ChemInform Abstract: Redox Chemistry, Dinuclear Complexes, and Ru3‐Cluster Derivatives of the “Ligand” (Cp(CO)2Mn‐CN)‐.
Authors: OSWALD B. , POWELL A. K. , RASHWAN F. , HEINZE J. , VAHRENKAMP H. 
Published: May 2016

AbstractBy means of the cyanomanganate complex (I) and its η5‐methylcyclopentadienyl analogue the abilities of the cyanide ion to link different organometallic units and to stabilize unusual electron counts in organometallic complexes are tested.
ChemInform Abstract: Phosphate Ester and Phosphinate Binding to the (μ‐Oxo)diiron(III) Core: Synthesis and Characterization of (Fe2O(O2P(OC6H5)2)2(HBpz3)2) and (Fe2O(O2P(C6H5)2)2(HBpz3)2).
Authors: TUROWSKI P. N. , ARMSTRONG W. H. , ROTH M. E. , LIPPARD S. J. 
Published: May 2016

AbstractTo model the interaction of phosphate ligands with oxo‐bridged diiron proteins the title complexes (III) are prepared.
ChemInform Abstract: Reactivity of Coordinated Phosphate Esters: Pentaamminecobalt(III) Complexes.
Authors: HENDRY P. , SARGESON A. M. 
Published: May 2016

AbstractThe reactivity of two phosphate ester complexes (I) and (III), designed to test the efficacy of different modes of activation of phosphate esters by metal ions, is studied by 31P NMR spectroscopy.
ChemInform Abstract: Synthesis and Spectra of Pyrazolo(4,5‐b)pyrido(2,3‐c)pyrazine Dimethine Cyanine Dyes.
Authors: KORAIEM A. I. M. , KHALAFALLA A. K. , SOLIMAN H. A. 
Published: May 2016

AbstractThe diaminonitrosopyridine (I) undergoes cyclocondensation with the methylpyrazolone derivatives (II) to form the pyrazolopyridopyrazines (IIIa) and (IIIb).
ChemInform Abstract: Preparation and Properties of Partially Protected 4‐Amino‐1‐methylimidazole‐2‐carboxylic Acids to be Used as Intermediates in the Synthesis of Analogues of Distamycin A.
Authors: GREHN L. , DING L. , RAGNARSSON U. 
Published: May 2016

AbstractThe title compounds and derivatives of them, e.g. (V), (VIII), (X), (XII) are prepared by convenient routes as shown from corresponding nitro pyrazoles (I) or (VII).
ChemInform Abstract: Preparation of Partially Protected 3‐Amino‐1‐methylpyrazole‐5‐carboxylic Acids to be Used as Intermediates in the Synthesis of Analogues of Distamycin A.
Authors: DING L. , GREHN L. , RAGNARSSON U. 
Published: May 2016

AbstractThe title compounds (IV), (V), (VI), (IX) are synthesized starting from the pyrazole (I); in addition, routes to further derivatives such as (X) and (XI) are described.
ChemInform Abstract: Total Synthesis of 7‐Deoxyaklavinone for Aklavin Anticancer Antibiotics.
Authors: CHO I. H. , CHUNG J. S. , HAN B. K. , YOO D. J. , LEE J. Y. , RHO Y. S. 
Published: May 2016

AbstractThe new ring anellation of (I) and (II) follows Michael addition using the sulfone anion.
ChemInform Abstract: Crystal Growth of Chromium Silicides by Chemical Vapor Transport with Halogens. Part 1. Growth of Chromium Disilicide Single Crystals.
Authors: KRAUSZE R. , KHRISTOV M. , PESHEV P. , KRABBES G. 
Published: May 2016

AbstractTransport experiments with Cl2, Br2, and I2, performed in the temp. range 1173‐1373 K at a total pressure of 105 Pa show the transport direction to be from hot to cold when Cl2 or Br2 are used as the transportation agent.
ChemInform Abstract: Preparation and Structures of Chlorostannates(II). Part 1. Some New Trichlorostannates(II) of Monovalent Cations.
Authors: VEITH M. , GOEDICKE B. + , HUCH V. 
Published: May 2016

AbstractKSnCl3, whose structure has hitherto been unknown, is recrystallized from MeCN to obtain single crystals suitable for X‐ray structure analysis.
ChemInform Abstract: Pyrolysis of α‐Acyl‐Substituted Ethyl Phenyl Sulfoxides.
Authors: TSUKURIMICHI E. , YOSHIMURA T. , YOSHIZAWA M. , ITAKURA H. , SHIMASAKI C. 
Published: May 2016

AbstractEthyl aryl sulfoxides such as (I) and (IV) are pyrolyzed, yielding the corresponding alkenes (II) and (V), together with the sulfenic acids (III).
ChemInform Abstract: Gas Phase Reactions. Part 71. PE Spectra and Pyrolyses of Nitrogen‐Rich Carbon Compounds: CN4, C2N4, C2H2N4, C4H6N4 and C5H4N4.
Authors: BOCK H. , DAMMEL R. , LORENCAK P. , WENTRUP C. 
Published: May 2016

AbstractThe PE spectra of the following compounds are presented and assigned by radical cation state comparison with related compounds or by Koopman's correlation with MNDO eigenvalues: cyanogen azide (I) (explosive liquid, the thermolysis of which is strongly dependent on pressure; at 10‐2 mbar the thermolysis ‐ beginning at 700 K ‐ produces nothing but carbon), azodicarbonitrile (II) (explosive crystals), tetrazolo(1,5‐a)pyridine (IV) (rearranging at 420 K/10‐4 mbar to 2‐pyridineazide), azidoacetonitrile (V) and trimethylenetetrazole (VII).
ChemInform Abstract: Ozonolysis of Olefins. Part 1. Ozonolysis of 1,4‐Cyclohexadiene and Acid‐Catalyzed Reaction of Primary Cleavage Products.
Authors: MITTELBACH M. , POKLUKAR N. , JUNEK H. 
Published: May 2016

AbstractComplete ozonolysis of (I) in CHCl3 leads to a highly explosive ozonide.
ChemInform Abstract: Direct Esterification of Carboxylic Acid with Bromothiophenol, Bromonaphthol, and Bromoanthrone via Triphenylphosphine‐Induced Debromination.
Authors: FURUKAWA I. , TAKENAKA N. , HASHIMOTO S. 
Published: May 2016

Abstractp‐Bromothiophenol (I) is debrominated upon heating with triphenylphosphine and then coupled with the carboxylic acid salts (II), producing the S‐phenyl thiolocarboxylates (III).
ChemInform Abstract: Synthesis of Alkyl Isocyanates by Pyrolysis of N‐Substituted 4‐Hydroxy‐5,5‐dimethyl‐2‐oxazolidinones.
Authors: SAITO N. , HATAKEDA K. , ITO S. , ASANO T. , TODA T. 
Published: May 2016

AbstractThe primary amines (I) react with the bromoisobutyrophenone (II) and carbon dioxide (III), forming the cyclic hydroxy carbamates (IV).
ChemInform Abstract: The Reactions of 1,4‐Dihalocubanes with Organolithiums. The Case for 1,4‐Cubadiyl.
Authors: EATON P. E. , TSANAKTSIDIS J. 
Published: May 2016

AbstractDropwise addition of Bu‐Li (II) to 1,4‐diiodocubane (Ia) followed by carbomethoxylation gives 30% of the bicubyl diester (V) and a little 4‐butylcarbomethoxycubane (VI).
ChemInform Abstract: Preparation of 1‐(tert‐Butoxycarbonyl)‐2,6‐dialkyl‐2,3‐dihydro‐4‐pyridones. A Stereocontrolled Synthesis of (.+‐.)‐Myrtine.
Authors: COMINS D. L. , LAMUNYON D. H. 
Published: May 2016

Abstract4‐Methoxypyridine (I) reacts with the Grignard compounds (II) and phenyl chloroformate (III), yielding the dihydropyridines (IV) which are transesterified with potassium tert‐butoxide (V) to produce the carbamates (VI).
ChemInform Abstract: Synthesis and Properties of Analogs of 5(4)‐Aminoimidazole‐4(5)‐carboxamide and Purines. Part 15. Ring Opening of Imidazo(4,5‐d)‐1,2,3‐triazine Derivatives.
Authors: USOVA V. K. , SELEZNEVA I. S. , POSPELOVA T. A. , MOKRUSHIN V. S. 
Published: May 2016

AbstractThe chloroimidazotriazine (I) reacts with N,N‐dimethylaniline (II) under ring opening to give the phenylazoimidazole (III).
ChemInform Abstract: Synthesis of 1,2,4‐Triazine‐3‐thione Derivatives from Biacetyl and 4‐Substituted Thiosemicarbazides.
Authors: ZELENIN K. N. , ALEKSEEV V. V. , PEKHK T. I. , KUZNETSOVA O. B. 
Published: May 2016

AbstractBiacetyl (II) reacts with the thiosemicarbazide (Ia) to produce the thiosemicarbazone (III) which is cyclized to give the methylenetriazinethione (IVa).
ChemInform Abstract: Biomimetic Studies Using Artificial Systems. Part 5. Design and Synthesis of Novel Water‐Soluble Biscyclophanes.
Authors: LAI C.‐F. , ODASHIMA K. , KOGA K. 
Published: May 2016

AbstractTrifluoroacetylation of the tetraazaparacyclophane (I) with trifluoroacetic anhydride (II) yields the tetrakis(trifluoroacetyl) derivative (III) which is hydrolyzed partially to form the trisamide (IV).
ChemInform Abstract: Chemistry of Halosilane Adducts. Part 19. Temperature‐Dependent Equilibrium Between Pentacoordinate and Ionic Tetracoordinate Structures of an Organochlorosilane‐Nitrogen Base Adduct. Synthesis and Structural Investigations of (N‐Si)‐Silicon‐Functional (1‐(2‐Pyridone(2′‐pyridyl)imine)methyl)silanes. The Crystal and Molecular Structure of (N‐Si)‐Chloro(1‐(2‐pyridone(2′‐pyridyl)imine)methyl)dimethylsilane, (N‐Si)‐(1‐(2‐Pyridone(2′‐pyridyl)imine)methyl)trichlorosilane and 1‐Methyl‐2‐(2′‐pyridyl)aminopyridiniu
Authors: KUMMER D. , CHAUDHRY S. C. , SEIFERT J. , DEPPISCH B. , MATTERN G. 
Published: May 2016

AbstractThe silanes (II) and (IV) are condensed onto solid (I) at liquid nitrogen temp., affording the compounds (III) or (V).
ChemInform Abstract: Diorganotin(IV) Dialkyl Dithiophosphates: Synthesis and Spectral Studies of Diorgano(hydroxo)tin(IV) Dialkyl Dithiophosphates.
Authors: PARULEKAR C. S. , JAIN V. K. , KESAVADAS T. 
Published: May 2016

AbstractReaction of the dialkyltin oxides (I) with the dialkyl dithiophosphates (II) produces the complexes (III) mentioned in the title.
ChemInform Abstract: Palladium(II) and Platinum(II) Complexes with Aryl Selenols and Diaryl Diselenides: A Comparative Approach with Tellurium and Sulfur Analogues.
Authors: KHANDELWAL B. L. , GUPTA S. K. 
Published: May 2016

AbstractThe reactivity of the polymeric Pd complexes (III) and (IV) is investigated.
ChemInform Abstract: Retention and Apparent Inversion During Azide Displacement of α‐Triflates of 1,5‐Lactones.
Authors: BRUCE I. , FLEET G. W. J. , GIRDHAR A. , HARALDSSON M. , PEACH J. M. , WATKIN D. J. 
Published: May 2016

AbstractReaction of azide ion with the 2‐O‐trifluoromethanesulfonate derived from the D‐glycero‐D‐talo‐heptano‐1,5‐lactone (I) yields the D‐glycero‐D‐galacto lactone (IV), which isomerizes to the more stable D‐glycero‐D‐talo lactone (V).
ChemInform Abstract: Analytical TEM Study of the Selective Photocatalytic Deposition of Platinum on Titania‐Silica Mixtures and Silica‐Supported Titania.
Authors: HERRMANN J.‐M. , MANSOT J.‐L. 
Published: May 2016

AbstractThe photodeposition of Pt onto mechanical TiO2/SiO2 mixtures and SiO2‐supported TiO2 is carried out in a static slurry photoreactor under UV irradiation.
ChemInform Abstract: On the Properties of Silica‐Supported Bimetallic Fe‐Cu Catalysts. Part 2. Reactivity in the Fischer‐Tropsch Synthesis.
Authors: WIELERS A. F. H. , KOEBRUGGE G. W. , GEUS J. W. 
Published: May 2016

AbstractIt is found that Fe‐Cu/SiO2 bimetallic catalysts are more active for the Fischer‐Tropsch reaction than the iron catalyst.
ChemInform Abstract: Steady‐State Kinetics of the CO‐N2O Reaction Over an Alumina‐Supported Rhodium Catalyst
Authors: MCCABE R. W. , WONG C. 
Published: May 2016

Abstractare studied in a plug‐flow reactor at temp. of 550‐700 K and CO and N2O partial pressures in the range 0.6‐7 torr.
ChemInform Abstract: Reduction of the Incomplete Cuboidal Molybdenum(IV) Aqua Ion (Mo3(μ3‐O)(μ‐O)3(OH2)9)4+ by Eu2+. Characterization of the Trinuclear Molybdenum(III) and Mixed‐Valence Molybdenum(III,III,IV) Aqua Ions by Oxygen‐17 NMR Spectroscopy.
Authors: RICHENS D. T. , GUILLE‐PHOTIN C. 
Published: May 2016

AbstractThe products of reduction of (I) by Eu2+ in p‐toluene sulfonic acid are characterized by 17O NMR.
ChemInform Abstract: A Stable Seven‐Membered Ring Ketenimine from a Thiocarbonyl Ylide and an Acceptor Olefin.
Authors: HUISGEN R. , LANGHALS E. , MLOSTON G. , OSHIMA T. 
Published: May 2016

AbstractThe thiocarbonyl ylide, generated from the 1,3,4‐thiadiazoline (I), and the trans‐dinitrile (II) undergo cyclization reaction to form a mixture of the spirocyclic tetrahydrothiophene (III) and the 7‐membered ketenimine (IV).
ChemInform Abstract: Metal Template Assisted Schiff Base Condensations: An Evaluation of Thermodynamic versus Kinetic Control.
Authors: SHEERAN D. J. , MERTES K. B. 
Published: May 2016

AbstractThe influence of kinetic and thermodynamic template effects is examined for a unique Pt(II) complex (I), resulting from the Schiff base condensation of o‐aminobenzaldehyde with (PtCl4)2‐.
ChemInform Abstract: Neophyl‐Like Rearrangement of Alkoxy Radicals: Direct Detection of a Bridged Intermediate by Time‐Resolved Absorption Spectroscopy.
Authors: FALVEY D. E. , KHAMBATTA B. S. , SCHUSTER G. B. 
Published: May 2016

AbstractBoth peroxides (I) are subjected to laser flash photolysis in different solvents (266 nm; 20 ns as well as 17 ps pulses).
ChemInform Abstract: Br2‐CO(NH2)2‐AcOH. A System for Highly Selective α‐Monobromination of Ketones.
Authors: ZAV'YALOV S. I. , EZHOVA G. I. , SITKAREVA I. V. , DOROFEEVA O. V. , ZAVOZIN A. G. , RUMYANTSEVA E. E. 
Published: May 2016

AbstractBromination of the ketones (I) with the title system produces the 1‐bromo ketones (II), together with 3‐isomers (III) as by‐products.