bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Zirconium Borohydride as a Zirconium Boride Precursor.
Authors: RICE G. W. , WOODIN R. L. 
Published: May 2016

AbstractThe applicability of Zr(BH4)4 (I) as starting material in ZrB2 synthesis is demonstrated by a variety of methods, including conventional CVD, laser CVD with both continuous wave and pulsed lasers.
ChemInform Abstract: Purity of Aluminum Hydroxide Derived from Triethylaluminum.
Authors: TEBBE F. N. , MORRIS P. A. , FRENCH R. H. , CHOWDHRY U. , COBLE R. L. 
Published: May 2016

AbstractIt is demonstrated that Al(OH)3 and Al2O3 prepared from commercial, productiongrade AlEt3 contain significantly lower amounts of metal ion impurities (Th and U below the detection limits of 1‐9 ppb, Fe: ∼ 1 ppm) Si: 1‐3 ppm) than Al oxides prepared from mineral sources.
ChemInform Abstract: High‐Temperature Behavior of Chemically Treated Silicon Nitride Powders.
Authors: HERMANSSON L. A. G. , BURSTROEM M. + , JOHANSSON T. , HATCHER M. E. 
Published: May 2016

AbstractSi3N4 powders are leached in different acids (HCl, HNO3, HF, and mixtures thereof), subsequently sintered by hot isostatic pressing with 2.5% yttria, and the high‐temp.
ChemInform Abstract: Anodic Oxidation of UO2. Part 5. Electrochemical and XPS Studies of Film‐Growth and Dissolution in Phosphate‐Containing Solutions.
Authors: SHOESMITH D. W. , SUNDER S. , BAILEY M. G. , WALLACE G. J. 
Published: May 2016

AbstractThe anodic oxidation of UO2 is studied in aqueous Na2HPO4 solutions over the pH range 4‐11. The early stages of oxidation resulting in the formation of an UO2.33 film are unaffected by the presence of phosphate, but phosphate concentrations of ≧ 0.1 M PO43‐ prevent the formation of higher oxide films which form in phosphate‐free solutions at higher oxidation potentials.
ChemInform Abstract: Characterization and Catalytic Studies of Y‐Zeolites Coexchanged with Iron and a Second Polyvalent Cation.
Authors: APARICIO L. M. , ULLA M. A. , MILLMAN W. S. , DUMESIC J. A. 
Published: May 2016

AbstractY‐zeolites exchanged with both Fe and either Ca, La, Eu, Cr, Mn, Co, Ni, or Cu are characterized by magnetic susceptibility measurements and Moessbauer spectroscopy and their catalytic activities for oxidation of CO with NO and for decomposition of N2O are determined.
ChemInform Abstract: Fe/Mn Oxide Catalysts for Fischer‐Tropsch Synthesis. Part 8. Surface Characterization of Fe/Mn‐Fischer‐Tropsch Catalysts by Auger‐Electron‐Spectroscopy.
Authors: HESS D. , PAPP H. , BAERNS M. 
Published: May 2016

AbstractA method for the quantification of Auger electron spectra is developed and it is demonstrated that AES can be used for the quantitative determination of the surface composition of Fe/Mn oxide catalysts.
ChemInform Abstract: Thermolysis and Mass Spectra of Polymeric Germanium Hydride Produced by γ‐Radiolysis.
Authors: BENZI P. , CASTIGLIONI M. , VOLPE P. , BATTEZZATI L. , VENTURI M. 
Published: May 2016

AbstractUpon heating solid polymeric Ge hydride, obtained by γ‐radiolysis of GeH4, undergoes two successive weight losses at 463 and 1173 K. At 948 K two crystal phases are formed, one of them being pure Ge.
ChemInform Abstract: Diastereo‐ and Enantioselective Aldol Reactions via α‐Silyl Ketones: Asymmetric Synthesis of the Aggregation Pheromone Sitophilure.
Authors: ENDERS D. , LOHRAY B. B. 
Published: May 2016

AbstractThe silyl ketone (I) is converted to its respective borenolate using the triflate (II); subsequent aldol reaction with aldehydes (III) and oxidative work‐up afford the syn‐aldol adducts (IV) which are desilylated to give the hydroxy ketones (V) of high diastereomeric and enantiomeric purity.
ChemInform Abstract: Synthesis of Some Thieno Analogues of the Protoberberine and Protopine Skeletons. X‐Ray Crystal Structure of 9,10‐Dimethoxy‐5‐methyl‐4,5,6,7,12,13‐hexahydrothieno(3,2‐e) (3)benzazecin‐12‐one.
Authors: BREMNER J. B. , BROWNE E. J. , ENGELHARDT L. M. , JAMES G. S. , WHITE A. H. 
Published: May 2016

AbstractWhereas the reaction of the tetracyclic compound (IV) (prepared starting from the compounds (I) and (II) via the intermediate (III)) with BrCN (XIII) in H2O, THF, and MgO as base gives rise to the product (V), the reaction of the tetracyclic compound (XI) (prepared starting from the readily available compound (VI) via the intermediate (VII)) under similar conditions effects the desired ring expansion giving the products (X) and (XI).
ChemInform Abstract: Electron‐Transfer Reactions in Cyanine Borate Ion Pairs: Photopolymerization Initiators Sensitive to Visible Light.
Authors: CHATTERJEE S. , GOTTSCHALK P. , DAVIS P. D. , SCHUSTER G. B. 
Published: May 2016

AbstractSolutions of the cyanine borate (I) in butyl acrylate are stable in the dark but a free‐radical polymerization is initiated by irradiation with visible light.
ChemInform Abstract: Carotenoid Cation Radicals: Electrochemical, Optical, and EPR Study.
Authors: GRANT J. L. , KRAMER V. J. , DING R. , KISPERT L. D. 
Published: May 2016

AbstractThe general aim of the investigation is to determine whether carotenoid cation radicals can be produced, and stabilized, electrochemically.
ChemInform Abstract: Stereoselective Reduction of 2‐Keto Acids to Hydroxy Acids.
Authors: NIKOLAEV V. A. , KORNEEV S. M. , ZHDANOVA O. V. 
Published: May 2016

AbstractTreatment of the 2‐keto acids (I) with NaBH4 affords the trans‐configurated 2‐hydroxy acids (II) in high stereoselectivity (ca.
ChemInform Abstract: Evidence for the Intermediacy of Chromium‐Ketene Complexes in the Synthesis of β‐Lactams by the Photolytic Reaction of Chromium‐Carbene Complexes with Imines. Use in Amino Acid Synthesis.
Authors: HEGEDUS L. S. , DE WECK G. , D'ANDREA S. 
Published: May 2016

AbstractBy a range of photolytic reactions it is evidenced that pentacarbonylchromium‐carbene complexes on irradiation (at wavelengths which include the metal‐to‐ligand CT absorption (350‐450 nm) of the specific carbene complex) rearrange to intermediate tetracarbonylchromium‐ketene complexes (without forming free ketenes) which may be trapped by nucleophiles with high stereoselectivity what has several important synthetic implications.
ChemInform Abstract: C5O2 (1,2,3,4‐Pentatetraene‐1,5‐dione) a Novel Oxide of Carbon.
Authors: MAIER G. , REISENAUER H. P. , SCHAEFER U. + , BALLI H. 
Published: May 2016

AbstractThe photochemically or thermally induced loss of H2O and CO from the diazoketone (I) reveals the formation of the diketone (II) which can be stored for several days even at room temp. and which releases CO under irradiation to give the butatrienone (III).
ChemInform Abstract: α,β‐Difluorocinnamic Aldehyde and Its Derivatives.
Authors: YAGUPOL'SKII L. M. , CHEREDNICHENKO P. G. , PAZENOK S. V. , KREMLEV M. M. 
Published: May 2016

AbstractThe difluoro‐β‐chlorostyryl derivatives (I) are lithiated and subsequently reacted in situ with N‐formylpiperidine (II) to give the title compound (IIIa) and its derivatives (IIIb)‐(IIId).
ChemInform Abstract: 2‐Alkenyl Aryl Sulfoxides in the Pummerer Reaction.
Authors: FEDOROV N. V. , ANISIMOV A. V. , VIKTOROVA E. A. 
Published: May 2016

AbstractThe Pummerer reaction between the title compounds (I) and the mixed anhydride (II) of trifluoric acid and acetic acid affords the α‐acetoxysubstituted sulfides (III) in fair to good yields.
ChemInform Abstract: Liquid Crystals Containing Fluorine. Part 11. Influence of Electronic Effects of the Terminal Groups on the Mesomorphism of 4′‐Substituted 4‐Perfluoroalkyldiphenyls.
Authors: SHELYAZHENKO S. V. , DRONKINA M. I. , FIALKOV YU. A. , YAGUPOL'SKII L. M. 
Published: May 2016

AbstractThe 4‐perfluorohexyl‐4'‐substituted diphenyls (I)‐(V) are prepared.
ChemInform Abstract: Simple Approach to Furo(3,4‐b)furans, a Novel Diheteropentalene System.
Authors: EBERBACH W. , FRITZ H. , LABER N. 
Published: May 2016

AbstractThe oxiranes (II), which can be obtained starting from the known compound (I), are converted to the novel furofurans (III), (IV) when heated under flash vacuum pyrolysis conditions or by short‐time thermolysis (350 °C, 10 s).
ChemInform Abstract: Improved Syntheses of Substituted Carbazoles and Benzocarbazoles via Lithiation of the (Dialkylamino)methyl (Aminal) Derivatives.
Authors: KATRITZKY A. R. , REWCASTLE G. W. , VAZQUEZ DE MIGUEL L. M. 
Published: May 2016

AbstractThe benzo‐fused N‐(pyrrolidinomethyl)pyrroles (I) and (VI) are selectively lithiated and then substituted with various electrophiles (II) to form the derivatives (III) or (VII) after deprotection.
ChemInform Abstract: Synthesis and Antifungal Activity of Some Allylamine Derivatives.
Authors: BANDIERA T. , ALBINI F. M. , ALBINI E. 
Published: May 2016

AbstractThe nitrile oxides (I) react with the allylamine (II) to form the intermediate aminomethylisoxazolines (III) and the N‐allylbenzamidoximes (IV) which are coupled with the hydroxamic acid chlorides (V), yielding the isoxazolines (VI).
ChemInform Abstract: 6‐ and 8‐Hydroxy‐3,4‐dihydro‐3‐(dipropylamino)‐2H‐1‐benzopyrans. Dopamine Agonists with Autoreceptor Selectivity.
Authors: WISE L. D. , DEWALD H. A. , HAWKINS E. S. , REYNOLDS D. M. , HEFFNER T. G. , MELTZER L. T. , PUGSLEY T. A. 
Published: May 2016

AbstractCyclization of the salicylaldehydes (I) with acrylonitrile (II) gives nitriles which are hydrolyzed to form the corresponding carboxylic acids (III).
ChemInform Abstract: N‐Alkylquinolinium and ‐isoquinolinium Salts with a Ketone Function in the Alkyl Chain. Synthesis and Reactivity Towards Secondary Amines.
Authors: SLIWA H. , OUATTARA L. 
Published: May 2016

AbstractQuinoline N‐oxide (I) is coupled with the bromo ketone (II) in the presence of silver perchlorate to give the quinolinium salt (III) which is treated with tetramethylpiperidine, forming the 2‐benzoylquinoline (IV).
ChemInform Abstract: Synthesis of Novel 1,2,3,4‐Tetrahydrobenzo(c)‐1,5‐naphthyridines from Pyrrolo(1,2‐b)isoquinolines.
Authors: MARTIN L. L. , SCOTT S. J. , SETESCAK L. L. , VAN ENGEN D. 
Published: May 2016

AbstractThe N‐benzylpyrrolidinonecarboxylic acids (I) are converted to the corresponding carboxylic chlorides which undergo intramolecular Friedel‐Crafts acylation, forming the pyrroloisoquinolinediones (II).
ChemInform Abstract: 3‐(Dialkylamino)‐Substituted‐2H‐1,4‐benzothiazines.
Authors: BALBI A. , FERRECCIO R. , DI BRACCIO M. , MAZZEI M. , ROMA G. 
Published: May 2016

Abstract2‐Aminothiophenol (I) is alkylated with the bromomalonamides (II) to yield the 2‐aminophenylthiomalonamides (III) which are converted to the benzothiazine derivatives (IV) by cyclization with POCl3, followed by hydrolysis.
ChemInform Abstract: Regio‐ and Site‐Selective Cycloadditions. Part 1. The Reaction of Aryl Azides and of Ethyl Diazoacetate with the Bis(trimethylsilyl)polyynes, Me3Si(CC)nSiMe3 (n = 2 or 3).
Authors: BETTISON R. M. , HITCHCOCK P. B. , WALTON D. R. M. 
Published: May 2016

Abstract1,3‐Dipolar cycloaddition of the aryl azides (I) or ethyl diazoacetate (IV) with the polyynes (II) produces the triazoles (III) or the pyrazole (V).
ChemInform Abstract: Reaction of Ethyl Dibutylphosphinite with O‐Alkyl Chlorothioformates.
Authors: BUVASHKINA N. I. , KOVALENKO L. V. , VIRIN L. I. , POPOVA I. YU. 
Published: May 2016

AbstractReaction of the chlorothioformates (I) with the phosphinite (II) gives the alkylthiocarbonylphosphine oxides (III) as the result of a thione‐thiol rearrangement.
ChemInform Abstract: Reaction of α‐Boryloxyalkyl(α‐hydroxyalkyl)phosphines and Their Derivatives with Bases.
Authors: NIKONOV G. I. , LITVINOV I. A. , IGNAT'EVA S. N. , ERASTOV O. A. , ARBUZOV B. A. 
Published: May 2016

AbstractBis(α‐hydroxyalkyl)phosphines, prepared in situ from phenylphosphine (I) and the benzaldehydes (II), or the phosphine oxide (VI) react with the borinate (III) and triethylamine (IV) to give the dioxaphosphaboratinanes (V) and (VII).
ChemInform Abstract: N,N‐Bis(trimethylstannyl)di‐tert‐butylfluorosilylamine. A Sterically Fixed Molecule.
Authors: STALKE D. , KLINGEBIEL U. , SHELDRICK G. M. 
Published: May 2016

AbstractThe aminofluorosilane (I) is lithiated and then treated with trimethylstannyl chloride (IV) to yield the stannyl‐substituted amine (V).
ChemInform Abstract: Catecholate LMCT Bands as Probes for the Active Sites of Nonheme Iron Oxygenases.
Authors: COX D. D. , BENKOVIC S. J. , BLOOM L. M. , BRADLEY F. C. , NELSON M. J. , QUE L. JUN. , WALLICK D. E. 
Published: May 2016

AbstractThe distorted octahedral high‐spin Fe(III) complexes (I) with the tetradentate tripodal ligands, derivatives of trimethylamine, are synthesized to correlate the energies of catecholate‐to‐Fe(III) CT‐transitions with the nature of the iron coordination environment.
ChemInform Abstract: Three‐Center Binding of a Nitroxyl Free Radical to Copper(II) Bromide.
Authors: CANESCHI A. , GRAND A. , LAUGIER J. , REY P. , SUBRA R. 
Published: May 2016

AbstractThe diamagnetic Cu complex (I) is prepared by mixing equimolar amounts of 2,2,6,6‐tetramethylpiperidinyl‐1‐oxy and Cu(II) bromide‐acetonitrile complex in Et2O. Its characterization occurs by X‐ray structure analysis (space group Pnma), variable‐temp.
ChemInform Abstract: Transformations of N‐Heteroarylformamidines into Derivatives of β‐Heteroarylamino‐α,β‐dehydro‐α‐amino Acids, β‐Heteroarylamino‐α‐amino Acids, and Dipeptides.
Authors: STANOVNIK B. , SVETE J. , TISLER M. 
Published: May 2016

AbstractThe formamidine (I) is coupled with the oxazolinone (II) to give the imine (III) which is methylated to form the aminomethylene derivative (V) or cleaved with the nucleophiles (VI) to give the amides (VII).
ChemInform Abstract: Xylitol Triphosphites.
Authors: MAKAROVA N. A. , MUKMENEV E. T. , ARBUZOV B. A. 
Published: May 2016

AbstractThe title compounds (III), which are of interest as intermediates in the synthesis of thermo‐ and photostabilizers for polymers, are prepared by transesterification of the phosphites (II) with xylitol (I).
ChemInform Abstract: Stereoselective Total Synthesis of (.+‐.)‐Atisine via Intramolecular Double Michael Reaction.
Authors: IHARA M. , SUZUKI M. , FUKUMOTO K. , KAMETANI T. , KABUTO C. 
Published: May 2016

AbstractIntramolecular double Michael reaction of the intermediate (XI) yields the pentacyclic ketone (XII) (space group P21/c; Z=4).
ChemInform Abstract: Studies on Rutaceae. Part 6. Reactions and Rearrangements of Coumarins.
Authors: BANERJI J. , DHARA K. P. , DAS B. , DAS A. K. , CHATTERJEE A. 
Published: May 2016

AbstractReactions and rearrangements of the naturally occurring coumarins micromelumin (I), phebalosin (III), osthol (VI) and auraptenol (VIII) are investigated leading to the natural compounds angelical (II), minumicrolin (IV)/murrangatin (V) and arnottinin (IX), respectively.
ChemInform Abstract: General Mechanism for Ruthenium(III)‐Titanium(III) Electron‐Transfer Reactions: Reductions Involving Sulfato Ligands.
Authors: BARONE P. , EARLEY J. E. 
Published: May 2016

AbstractThe reduction of (NH3)5RuX(3‐n)+ (X: SO42‐, S2O32‐, NH2SO3‐) by Ti(III) is studied at 1.0 M LiCl at 25 °C. It is shown that TiOH2+ reduces RuOSO3+.
ChemInform Abstract: Preparation and Chemical Properties of Single Crystals of YbAs4S7 and Yb3As4S9.
Authors: MAMEDOV A. I. , IL'YASOV T. M. , RUSTAMOV P. G. , AKPEROV F. G. 
Published: May 2016

AbstractThe title compounds are prepared from stoichiometric mixtures of the elements (1400 K, evacuated quartz ampoules).
ChemInform Abstract: NMR and Conformational Studies of Some 1,4‐Linked Disaccharides.
Authors: BACKMAN I. , ERBING B. , JANSSON P.‐E. , KENNE L. 
Published: May 2016

AbstractThe title compounds studied are the eight disaccharides (I)‐(III) in which the glycosidic linkages are in different stereochemical environments.
ChemInform Abstract: π‐Electron Transfer as Calculated at Various Levels of Basis Set. A Redefinition of the Theoretical Scale of σR° Values.
Authors: MARRIOTT S. , SILVESTRO A. , TOPSOM R. D. 
Published: May 2016

AbstractAb initio MO calculations are reported for the π‐electron transfer to or from the substituent for 20 monosubstituted benzenes, both at the minimal STO‐3G basis set and at the split‐valence 4‐31G basis set.
ChemInform Abstract: 1,3‐Dipolar Character of Six‐Membered Aromatic Rings. Part 56. The Cycloadditions of Acetylenes and 3‐Oxidopyridinium Betaines.
Authors: ISHAG C. Y. , FISHER K. J. , IBRAHIM B. E. , ISKANDER G. M. , KATRITZKY A. R. 
Published: May 2016

AbstractCycloaddition of dimethyl acetylenedicarboxylate (II) to the 3‐oxidopyridinium betaines (I) occurs across the oxygen and C‐2 with concomitant cleavage of the pyridine nucleus to yield the novel furans (III).
ChemInform Abstract: Radical‐Induced Cleavage of Keto Epoxides.
Authors: MURPHY J. A. , PATTERSON C. W. , WOOSTER N. F. 
Published: May 2016

AbstractThe acylvinyloxiranes (III), prepared from the bromo ketones (I) and acrolein or crotonaldehyde (II), are cleaved with butanethiol (IV) under radicalic conditions to produce the α,β‐unsaturated γ‐butylthioaldehydes (V).
ChemInform Abstract: Intramolecular ω‐Olefinic Ketone Ene‐Reaction for the Construction of Trifluoromethylated Five‐Membered Ring Compounds.
Authors: AUBERT C. , BEGUE J. P. 
Published: May 2016

AbstractThe unsaturated trifluoromethyl ketone (I) is cyclized in the presence of ethylaluminum dichloride to give the 1‐trifluoromethylcyclopentanol (II).
ChemInform Abstract: Photorearrangement of 4,4,5,5‐Tetramethoxycyclohepta‐2,6‐dienones to 6,6,7,7‐Tetramethoxybicyclo(3.2.0)hept‐3‐en‐2‐ones.
Authors: MORI A. , KUBOTA T. , TAKESHITA H. 
Published: May 2016

AbstractAnodic oxidation of the tropones (I) in methanol (II) gives the tetramethoxydihydrotropones (IIIa), (IIIb), and (IVb).
ChemInform Abstract: A New Class of Steoreoselective Reducing Agents, Potassium 9‐Alkyl‐9‐boratabicyclo(3.3.1)nonanes.
Authors: CHA J. S. , YOON M. S. , KIM Y. S. , LEE K. W. 
Published: May 2016

AbstractPotassium hydride (II) reacts with the 9‐alkyl‐9‐boracyclononanes (I) to give the potassium 9‐alkyl‐9‐boratabicyclononanes (III).
ChemInform Abstract: Alkylation of Silyl Ketene Acetals with Dienyliron Complexes: Application in the Formation of Quaternary Carbon Centers.
Authors: PEARSON A. J. , O'BRIEN M. K. 
Published: May 2016

AbstractThe silyl ketene acetals (II) react with the dienyliron carbonyl complex (Ia) to form mixtures of the isomeric adducts (III) and (IV).
ChemInform Abstract: Facile Routes to Boron Enolates. Et3B‐Mediated Reformatsky Type Reaction and Three Components Coupling Reaction of Alkyl Iodides, Methyl Vinyl Ketone, and Carbonyl Compounds.
Authors: NOZAKI K. , OSHIMA K. , UTIMOTO K. 
Published: May 2016

AbstractThe phenacyl halides (I) react with the oxo compounds (II) in the presence of triethylboron and triphenyltin hydride to give the ketols (III).
ChemInform Abstract: Nitrodiazomethane as a Source of Nitrocarbene.
Authors: O'BANNON P. E. , DAILEY W. P. 
Published: May 2016

AbstractRhodium diacetate induced release of nitrogen from nitrodiazomethane (II) produces nitrocarbene which is employed in the cyclopropanation of the olefins (I) and (IV).
ChemInform Abstract: The Stereoselective Michael Reaction of α,β‐Unsaturated Thioesters with Silyl Enol Ethers Promoted by Combined Use of Antimony(V) Chloride and Tin(II) Triflate.
Authors: KOBAYASHI S. , TAMURA M. , MUKAIYAMA T. 
Published: May 2016

AbstractThe silyl enol ether (Ia) or the O‐silyl ketene O,S‐acetals (Ib) are coupled with the α,β‐unsaturated S‐alkyl thioesters (II) in the presence of antimony pentachloride/tin triflate, yielding the Michael adducts (III) with predominance of the anti‐isomers.
ChemInform Abstract: Convenient Preparation of 11H‐Benzo(a)fluorenone and 11H‐Benzo(b)fluorenone.
Authors: STREITWIESER A. JUN. , BROWN S. M. 
Published: May 2016

AbstractCyclocondensation of 1‐indanone (I) with o‐phthalaldehyde (II) yields 11H‐benzo(b)fluorenone (III) which undergoes base‐induced cleavage to produce o‐(2‐naphthyl)benzoic acid (IV).
ChemInform Abstract: Structure of the Cycloaddition Products of α‐Ketonitrilimines to α,β‐Unsaturated Ketones.
Authors: EZMIRLY S. T. , SHAWALI A. S. , BUKHARI A. M. 
Published: May 2016

AbstractThe title reactions between the α‐ketonitrilimines, generated in situ from the chlorides (I) and (V), with the α,β‐unsaturated ketones (III) and (VI) afford regioselectively the pyrazolines (IV) and (VII), respectively.
ChemInform Abstract: Flash Vacuum Pyrolysis of 1‐Allylbenzotriazoles and Dihydrobenzoxazines: Formation of Quinolines.
Authors: BARKER S. J. , JONES G. B. , RANDLES K. R. , STORR R. C. 
Published: May 2016

AbstractPyrolysis of the 1‐allylbenzotriazoles (I) in vacuum yields the quinolines (II).
ChemInform Abstract: Photochemical Addition of Alkenes and Alcohols to Sodium Phthalimide.
Authors: SUAREZ R. S. , SEGURA R. G. 
Published: May 2016

AbstractPhotolysis of sodium phthalimide (I) in the presence of cyclohexene (II) and tert‐butanol gives only moderate yields of the dibenzodiazepine derivative (III) because of several side reactions, e.g. the formation of the isoindolones (V) ‐ (VII) by coupling of (I) with the solvent (IV).
ChemInform Abstract: Bis(2‐thione‐1,3‐dithiole‐4,5‐diselenolate)nickelate(II): A Precursor for Mixed Sulfur/Selenium Heterocycles.
Authors: NIGREY P. J. 
Published: May 2016

AbstractStarting with the dithiole derivative (I), the nickel complex (II) is synthesized.
ChemInform Abstract: Lewis‐Base Adducts of Main Group 1 Metal Compounds. Part 2. Syntheses and Structures of (Li4Cl4(pmdien)3) and (LiI(pmdien)).
Authors: RASTON C. L. , SKELTON B. W. , WHITAKER C. R. , WHITE A. H. 
Published: May 2016

AbstractLithium chloride, formed under unhydrous conditions from SiMe3Cl and BuLi, in the presence of the triamine (excess) in hexane yields the novel oligomer (I), crystallizing in P21/n with Z=4.
ChemInform Abstract: Lewis‐Base Adducts of Main Group 1 Metal Compounds. Part 3. Synthesis and Structural Systematics of (LiXL3) and (L′2LiX2LiL′2) Systems (X: Cl, Br, or I; L: 3,5‐Me2C5H3N, L′: 2‐MeC5H4N).
Authors: RASTON C. L. , WHITAKER C. R. , WHITE A. H. 
Published: May 2016

AbstractThe complexes (I) and (II) are prepared by recrystallization of the anhydrous lithium halide from the parent base and their stoichiometries and structures confirmed by X‐ray investigations at 295 K. (Ia) crystallizes in R3c with Z=2, (Ib) in Cc with Z=4 and (II) in P1 with Z=1.
ChemInform Abstract: Syntheses and Structural Studies of (2‐(6‐Methyl)pyridyl)‐ and (8‐Quinolyl)trimethylsilylamido Lithium Complexes.
Authors: ENGELHARDT L. M. , JACOBSEN G. E. , JUNK P. C. , RASTON C. L. , SKELTON B. W. , WHITE A. H. 
Published: May 2016

AbstractThe preparation of the title complexes is outlined in the scheme.
ChemInform Abstract: Reactivity of Rhenium(I) Pseudo‐Allyl Complexes with Heterocumulenes. Part 2. Insertion Reactions. Crystal Structures of the Thiazolyl‐thioureido and ‐dithiocarbamato Complexes (Re(CO)2(PPh3)2(SC(NPh)NMe(C3H2NS)))·CH2Cl2 and (Re(CO)2(PPh3)2(S2CNMe(C3H2NS)))·CH2Cl2(C3H2NS=thiazol‐2‐yl).
Authors: ROSSI R. , MARCHI A. , DUATTI A. , MAGON L. , CASELLATO U. , GRAZIANI R. 
Published: May 2016

AbstractThe title complexes (III) and (V) are prepared by insertion of PhNCS (II) or CS2 (IV) into the Re‐N(amino) bond of the starting chelate complex (I).
ChemInform Abstract: Synthesis, Characterization, and Electrochemistry of Dicyclopentadienylsiloxane‐Bridged Dicarbonyldiiron.
Authors: MORAN M. , CUADRADO I. , MASAGUER J. R. , LOSADA J. 
Published: May 2016

AbstractThe new metal‐metal bonded Fe complexes (III) are oxidized by (IV) to give, in the presence of PPh3, the dicationic compounds (VIIa)‐(VIIc).
ChemInform Abstract: Reactivity of Organoaminosilanes in the Reaction with Monofunctional Ferrocenyl Carbinols.
Authors: BUZIASHVILI V. I. , KABANOV B. K. , KHANANASHVILI L. M. , MOLCHANOV B. V. , TSOMAYA N. I. 
Published: May 2016

AbstractThe ferrocenyl carbinols (I) or (V) react with the aminosilane (II) to give the silyl ethers (III) and (VI) respectively.