bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Interactions of Isocyanides with Transition Metal Complexes. Part 29. Isocyanide Complexes with Pt2S and Pt2CS Cores. Crystal Structure of μ‐Sulphido‐bis[bis(2,4,6‐tri‐t‐butylphenyl isocyanide)platinum].
Authors: YAMAMOTO Y. , YAMAZAKI H. 
Published: May 2016

AbstractThe Pt3 compound (II) reacts with S8 or CS2 to give the Ptz Complexes (I) and (III).
ChemInform Abstract: Cobalt‐Catalyzed One‐Step Assembly of B‐Ring Aromatic Steroids from Acyclic Precursors.
Authors: LECKER S. H. , NGUYEN N. H. , VOLLHARDT K. P. C. 
Published: May 2016

AbstractAn approach is described in which all four rings of a steroid are assembled in one step to give B‐ring aromatic derivatives with complete control of the crucial stereochemistry of the C,D‐ring juncture.
ChemInform Abstract: Compatibility of β‐ and γ‐Turn Features with a Peptide Backbone Modification: Synthesis and Conformational Analysis of a Model Cyclic Pseudopentapeptide.
Authors: SPATOLA A. F. , ANWER M. K. , ROCKWELL A. L. , GIERASCH L. M. 
Published: May 2016

AbstractThe backbone‐modified cyclic peptide (III) has been synthesized by cyclization of the linear pseudopeptide (II) which, in turn, has been prepared starting from (I) by solid‐phase methods.
ChemInform Abstract: Influence of Additives on Suppression of Racemization in Peptide Syntheses.
Authors: PRZYBYLSKI J. 
Published: May 2016

AbstractThe effect of polymeric additives [polyacrylic acid (IVa) and its derivatives (IVb), (IVc)] on the suppression of racemization in peptide synthesis is investigated using the model reaction shown in the scheme.
ChemInform Abstract: ZrO2‐Transformation‐Toughened Glass‐Ceramics Prepared by the Sol‐Gel Process from Metal Alkoxides.
Authors: NOGAMI M. , TOMOZAWA M. 
Published: May 2016

AbstractGlass of 3 ZrO2 ‐ 2 SiO2 composition, prepared by the sol‐ ‐gel process, was crystallized to precipitate tetragonal ZrO2 crystals.
ChemInform Abstract: Kinetic Selection Criterion for Redox Couples Used to Decrease n‐Type Semiconductor Photocorrosion.
Authors: ARCE E. , IBANEZ J. , MEAS Y. 
Published: May 2016

AbstractThe photocorrosion behavior of n‐CdTe has been studied in aqueous solutions of hydroquinone, Fe", and Fe(CN)2′ . The anodic peak potential of each species does not depend on its thermodynamic potential but on its reaction kinetics.
ChemInform Abstract: Protonated Hydronium Dication, H4O2+. Hydrogen ‐ Deuterium Exchange of D2H17O+ in HF : SbF5 and DH217O+ in DF : SbF5 and Theoretical Calculations.
Authors: OLAH G. A. , PRAKASH G. K. S. , BARZAGHI M. , LAMMERTSMA K. , VON RAGUE SCHLEYER P. , POPLE J. A. 
Published: May 2016

AbstractThe H ‐ D exchange in D2H′7O+ and DH2′7O+/(D)HF‐ SbF5 ‐ SO2 solutions at ‐ 15°C has been monitored by "O NMR.
ChemInform Abstract: Novel Metastable Oxolanthanoides: BaCa2Y6O12 (I) and Ca0.33MgY2.67O5.33 (≡CaMg3Y8O16) (II).
Authors: SCHROEDER F. + , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractThe title compounds have been prepared from Ba(Ca)CO3 ‐ MgCO3 ‐ Y2O3 (1 22:3) mixtures by high temp. reactions (COz‐laser, T 2200°C).
ChemInform Abstract: Preparation and Vibrational Spectrum of Hexaiodoiridat(III), Cs3IrI6.
Authors: PREETZ W. , STEINEBACH H.‐J. 
Published: May 2016

AbstractThe title iridate is formed on annealing heterogeneous pellets of Cs3[IrBr6] and NaI at 160°C. Because of the slow diffusion rate of the halide ions within the NaI phase, the reaction must be repeated several times.
ChemInform Abstract: Structural Correlations Between the Tetraisopropylphosphonium Cation and Triisopropylphosphonium Isopropylide: An X‐Ray Diffraction Study
Authors: SCHMIDBAUR H. , SCHIER A. , FRAZAO C. M. F. , MUELLER G. + 
Published: May 2016

Abstract(space groups of (I)and (II) (both Z=2): PT and P2′2′2, respectively.
ChemInform Abstract: Synthesis, X‐Ray Crystal Structure, and Reactivity of Ternary Complexes of Crown Ethers, Organic n‐Acceptors, and Salts.
Authors: DE BOER J. A. A. , REINHOUDT D. N. , UITERWIJK J. W. H. M. , HARKEMA S. 
Published: May 2016

AbstractThe crown ethers (I) and (II) form blue charge‐transfcr complexes with tetracyanoethylene (TCNE) in Chloroform.
ChemInform Abstract: Substituent Effects in Fluoren‐9‐one Ketyls. Part 2. Electrolytic Reduction of Fluoren‐9‐ones Studied by Cyclic Voltammetry and Electron Spin Resonance Spectroscopy.
Authors: EMPIS J. M. A. , HEROLD B. J. 
Published: May 2016

AbstractFluorenone (Ia) and its derivatives (Ib) were reduced electrolytically in DMF in the presence of NBuI Cl04‐ . The resulting species were identified as the one‐electron reduction products, i.e. the paramagnetic radical anions.
ChemInform Abstract: Substitution of Acinitro Group by Arylazo Group in Dianions of 1,4‐Dinitrocyclooctatetraene and 1,5‐Dinitronaphthalene.
Authors: TODRES Z. V. , OVSENYAN G. TS. 
Published: May 2016

Abstract1,4‐Dinitro‐cyclooctatetraen (I) wird mit Hilfe des Cyclooctatetraendianions (II) in das Dinitronat (III) übergeführt, das mit den Diazonium‐ Salzen (IV) zu Gemischen der Mono‐ (V) bzw. Bis‐azoverbindungen (VI) reagiert.
ChemInform Abstract: Coal Swelling and Neutralization: Reactions within a Three‐Dimensional Organic Matrix.
Authors: MATTURRO M. G. , LIOTTA R. , ISAACS J. J. 
Published: May 2016

AbstractBituminöse Kohle wird mit Tetra‐alkyl‐ammonium‐Salzen getränkt, und die Diffusion und Neutralisierung dieser Komponenten werden in dieser dreidimensionalen Matrix untersucht.
ChemInform Abstract: Formation of Polycyanogen in the Solid Phase Reaction of Cyanogen Iodide and Potassium Cyanide.
Authors: TOTH Z. , GULYAS J. , BECK M. T. 
Published: May 2016

AbstractIt is shown that the product of the title reaction, contrary to a former assumption, is not paracyanogen, but a linear polycyanogen, with ‐ CN groups attached to the ‐(CN)" ‐ conjugated chain.
ChemInform Abstract: Heavy‐Atom Kinetic Isotope Effects and Mechanism of the Acid‐Catalyzed o‐Semidine and p‐Semidine Rearrangements and Disproportionation of 4,4′‐Dichlorohydrazobenzene.
Authors: RHEE E. S. , SHINE H. J. 
Published: May 2016

AbstractIn order to measure ′SN and "C or "Ckinetic isotope effects, quantitative product ratios are determined under kinetic conditions.
ChemInform Abstract: Alkylnaphthalenes. Part 9. Photolysis of 2‐Isopropylnaphthalene.
Authors: HONDA T. , KIYOZUMI M. , KOJIMA S. 
Published: May 2016

AbstractBei der Photolyse der im Titel genannten Verbindung (I) in dünner Schicht wird die Bildung der Photoprodukt‐e (III)‐(VIII) durch GC‐MS‐ Kopplung nachgewiesen.
ChemInform Abstract: Decomposition of Hexachloroacetone in Dimethyl Sulphoxide Solution: a Source of Trichloromethanide Anions.
Authors: GOLD V. , JOHNSTON G. J. , WASSEF W. N. 
Published: May 2016

AbstractIn undried DMSO the title compound forms the hydrate (I), which decomposes to give the anion (II) accompanied with trichloroacetic acid (TCAA).
ChemInform Abstract: Catalytic Reaction of Palladium π‐Allyl Complexes with Allylic O‐ and N‐Nucleophiles.
Authors: FAKHRETDINOV R. N. , TELIN A. G. , DZHEMILEV U. M. 
Published: May 2016

AbstractDie Octadienylamine (Ia) bzw. ‐ether (Ib) reagieren mit Butadien (II) unter Palladium‐Katalyse zu den Vinyl‐tetradecatrienyl‐Verbindungen (III).
ChemInform Abstract: Reactions of Perfluoro(2‐methyl‐2‐pentene) with Alkanediols.
Authors: SUGASAWA G. , NAKAYAMA N. , SHIMIZU H. , NEMOTO F. 
Published: May 2016

AbstractDie Umsetzung des Perfluor‐2‐methyl‐pentens (1) mit den Alkandiolen (II) und (V) wird untersucht.
ChemInform Abstract: [1,2]Anionic Rearrangements of Substituted N‐Hydroxy‐2‐azetidinones and Applications to the Synthesis of Bicyclic β‐Lactams.
Authors: LEE B. H. , BISWAS A. , MILLER M. J. 
Published: May 2016

AbstractBei der Alkylierung der gemäß dem Formelschema hergestellten N‐Hydroxyazetidinone (VIIb), (VIIc) und (XI) mit Brommalonsäurediethylester (VIII) erfolgt 1,2‐anionische (NOC ‐ NCO) Umlagerung zu den Hydroxydicarbonsäureestern (IXa), (IXb) und (XII).
ChemInform Abstract: General Method for the Preparation of α‐Methylene‐γ‐butyrolactones from (R)‐ and (S)‐1,2‐Isopropylideneglyceraldehydes.
Authors: SUZUKI T. , SATO E. , KAMADA S. , TADA H. , UNNO K. , KAMETANI T. 
Published: May 2016

AbstractWittiig olefination of′ (RJ‐(I) yiefdis; the E/ Zisomers (II), both 0‐f which can be transformed′ to the.
ChemInform Abstract: Synthesis and Transformations of Thiophene Sulfides. Part 40. Unusual Transformation of 2,5‐Bis(methylthio)‐3,4‐bis(o‐hydroxyphenyliminomethyl)‐thiophene.
Authors: GOL'DFARB YA. L. , KALIK M. A. , BOGDANOV V. S. , ZAV'YALOVA V. K. 
Published: May 2016

AbstractDer Bis‐methylthio‐thiophendialdehyd (I), dessen Herstellung früher beschrieben wur‐ 71 de, reagiert mit 2‐Amino‐phenol (II) in Benzol zu dem Bis‐ azomethin (III), das in polaren Lösungsmitteln zu Benzoxazolyl‐thiophen (IV) umlagert.
ChemInform Abstract: Synthesis via Sigmatropic Rearrangements. Part 10. Synthesis of 2,3‐Disubstituted Indoles via Claisen Ortho Ester Rearrangement: An Approach for the Synthesis of Vindorosine.
Authors: RAUCHER S. , KLEIN P. 
Published: May 2016

AbstractDie Claisen‐Orthoester‐Umlagerung der Indolylglykolamide (I) 72 führt zu den 2,3‐disubstituierten Indolen (III).
ChemInform Abstract: A Convenient Synthesis of 1,2,3,4,6,7,12,12b‐Octahydroindolo[2,3‐a]quinolizine Derivatives.
Authors: YAMANAKA E. , NARUSHIMA M. , INUKAI K. , SAKAI S. 
Published: May 2016

AbstractDie Pictet‐Spengler‐Reaktion von Tryptamin (VI) mit den Acetalen (IV) bzw. (X) und nachfolgende Einwirkung von Kaliumhydroxid in Ethanol licfern die Lactame (VII) bzw. (XI), die zu den Indolchinolizidinen (VIII) reduziert bzw. nach Oxidation zum Sulfoxid (XII) thermisch zu chromatographisch trennbaren Gemischen der Lactame (XIII)‐(XV) desulfuriert werden.
ChemInform Abstract: S‐Fluorouracil Derivatives. Part 10. Synthesis and Antitumor Activities of α‐Alkoxyalkyl‐5‐fluoro‐uracils.
Authors: OZAKI S. , WATANABE Y. , HOSHIKO T. , NAGASE T. , OGASAWARA T. , FURUKAWA H. , UEMURA A. , ISHIKAWA K. , MORI H. , HOSHI A. , IIGO M. , TOKUZEN R. 
Published: May 2016

AbstractDie N‐monosubstituierten (I) und (II) bzw. N,N′‐disubstituierten 5‐Fluoruracile (III) werden auf den im Formelschema angegebenen vier Wegen hergestellt.
ChemInform Abstract: Conversion of Fervenulin‐4‐oxide in Reactions with Some Nucleophiles.
Authors: AZEV YU. A. , MUDRETSOVA I. I. , PIDEMSKII E. L. , GOLENEVA A. F. , ALEKSANDROVA G. A. , KLYUEV N. A. 
Published: May 2016

AbstractWie im Formelschema angegeben wird bei der Einwirkung von Nucleophilen auf Fervenulin‐4‐oxid (I) der Triazinring geöffnet.
ChemInform Abstract: Synthesis of 1,2,3‐Triazine N‐Oxides.
Authors: OHSAWA A. , ARAI H. , OHNISHI H. , KAIHOH T. , YAMAGUCHI K. , IGETA H. , IITAKA Y. 
Published: May 2016

AbstractOxidation der 1,2,3‐Triazine (I) mit m‐ Chlorperbenzoesäure liefert vorwiegend die 2‐N‐Oxide (IV) neben geringeren Mengen der isomeren N‐Oxide (II) und (III).
ChemInform Abstract: Bi‐ and Tricyclic Twelve‐ring Azacrowns by Stepwise Annelation.
Authors: BUOEN S. , DALE J. 
Published: May 2016

AbstractDie Kronenether (II), (III), (V), (VII) und (VIII) lassen sich unter Einhaltung der aufgeführten Reaktionsbedingungen aus den einfachen Aza‐Kronenverbindungen (I) bzw. (VI) synthetisieren.
ChemInform Abstract: An Unusual Isomerization of Phosphonium Salts.
Authors: KHACHATRYAN R. A. , MKRTYHYAN G. A. , KINOYAN F. S. , INDZHIKYAN M. G. 
Published: May 2016

AbstractDas Phenylpropargylbromid (I) reagiert mit Triphenylphosphin (II) in Benzol zu dem Phenylpropadienylphosphoniumsalz (III), während in Chloroform das Phenylpropinylphosphoniumsalz (IV) gebildet wird.
ChemInform Abstract: Chemistry of Phosphorus. Part 159. On the Reaction of the Diphosphaborirane (tBuP)2BN(iPr)2 with Potassium or Potassium Naphthalenide.
Authors: BAUDLER M. , KUPPRAT G. 
Published: May 2016

AbstractReaction of (Ia) with potassium in THF leads to (IIa) via P‐P bond cleavage.
ChemInform Abstract: Mixed gem‐Dimetallic Organic Compounds. A New Class of Multicoupling Reagents.
Authors: KNOCHEL P. , NORMANT J. F. 
Published: May 2016

AbstractAllylzinkbromid (I) und Octenylmagnesiumbromid (II) ergeben die geminale Organo‐Dimetallverbindung (III), deren Hydrolyse und Iodierung zum Iod‐Derivat (IV) führt.
ChemInform Abstract: Titanacyclobutanes Derived from Strained Cyclic Olefins: The Living Polymerization of Norbornene.
Authors: GILLIOM L. R. , GRUBBS R. H. 
Published: May 2016

AbstractThe title compounds (II) are obtained from the reaction of norbornene (I) with either the Tebbe reagent (IV) or the titanacycle (V), whose synthesis has been described previously.
ChemInform Abstract: First Example of an Intermolecular Transfer of the Tetramethyldigermene Fragment to a Multiple Bond with Formation of a 1,1,2,2‐Tetramethyl‐ 1,2‐germacyclobutene Derivative.
Authors: NEFEDOV O. M. , KOLESNIKOV S. P. , EGOROV M. P. , GAL'MINAS A. M. , KREBS A. 
Published: May 2016

AbstractTetramethyl‐digermen (I) reagiert mit dem Thiacycloheptin (II) zu 121 dem Digermabicyclononen (III).
ChemInform Abstract: Reaction Between MgCl2(THF)2 and MoOCl3(THF)2. Crystal Structures of [Mg(THF)6][MoOCl4THF]2 and [Mg2(μ‐Cl)3(THF)6][MoOCl4THF].
Authors: SOBOTA P. , PLUZINSKI T. , LIS T. 
Published: May 2016

AbstractDepending on the molar ratio (1:2 or 2:1) the reaction between the title compounds (I) and (II) yields the title complex salts (IIIa) and (IIIb) with different cations.
ChemInform Abstract: Synthesis of Dioxomolybdenum(VI) Complexes of Heterocyclic‐N,O and ‐N,S Ligands.
Authors: SORRELL T. N. , ELLIS D. J. , CHEESMAN E. H. 
Published: May 2016

AbstractBenzimidazolylalcohols (III) react with the M0 compound (II) to give normal octahedral Complexes (I) whereas the mercapto analogues, which sterically and electronically mighthave forced skew‐trapezoidal coordination, instead caused reduction of the starting compound (II) to yield Mo(V) dimers (IV).
ChemInform Abstract: A Series of Edge‐Sharing Bioctahedral, M ‐ M Bonded Molecules: Non‐Monotonic Bond Length Variation and Its Interpretation.
Authors: CHAKRAVARTY A. R. , COTTON F. A. , DIEBOLD M. P. , LEWIS D. B. , ROTH W. J. 
Published: May 2016

AbstractPreparations of the three new stoichiometrically homologous compounds (I) starting from Ta2Cl6(TI‐IT)3, K4Mo2Cl8 or Ru2Cl(OAc)2L2 (THT: tetrahydrothiophene; L: 6‐methyl‐2‐hydroxypyridine) are described in detail.
ChemInform Abstract: New Sesquiterpene Esters from Euonymus verrucosus: The "Ever" Series.
Authors: BEGLEY M. J. , CROMBIE L. , FLEMING R. A. , WHITING D. A. , ROZSA Z. , KELENYI M. , HOHMANN J. , SZENDREI K. 
Published: May 2016

AbstractSeven new sesquiterpenoid esters [Ever‐l (I), ‐2 (IIa), ‐4 (IIIa), ‐6 (Ilc), ‐7 (IIb), ‐8 (IIIc), and ‐lO (IIIb)] have been isolated from the title species.
ChemInform Abstract: 1,3‐Dipolar Addition Reactions of 6‐Ethylideneolivanic Acid Derivatives with Diazomethane and Acetonitrile Oxide.
Authors: CORBETT D. F. 
Published: May 2016

AbstractThe 1,3‐dipolar addition of Z‐compounds (Ia)/(lb) with (IV) yields a mixture of the corresponding diastereomers (II) and (III), whose free thiols can be converted to the derivatives (IIc) (yield given in mg) and (IIIc) by treatment with the appropriate halides (V)/ (VI).
ChemInform Abstract: EXAF S Study of Chromium Ions in the Mixed‐Solvent System of Formamide and Ammonium Formate.
Authors: MIYAKE M. , NAKAGAWA N. , OHYANAGI H. , SUZUKI T. 
Published: May 2016

AbstractThe coordination structures of Cr(VI) and Cr(III) ions in the HCONHz‐HCOONH′, system have been investigated by EXAFS experiments.
ChemInform Abstract: Photoelectrochemical Generation of Hydrogen at Electrochemically Deposited p‐ CdTe Films: Effect of Heat‐Treatment, Surface Modification by Platinum and Surface Oxide Layer on Conversion Efficiency.
Authors: TAKAHASHI M. , UOSAKI K. , KITA H. 
Published: May 2016

AbstractHeat‐treatment of the p‐CdTe films causes an increase in the crystalline diameter and, thus, the number of grain boundaries at which effective electron‐hole recombination takes place, decreases.
ChemInform Abstract: Time‐Resolved Photocurrent of WSe2 Photoanode Studied with a Nanosecond Pulse Laser.
Authors: SAKATA T. , JANATA E. , JAEGERMANN W. , TRIBUTSCH H. 
Published: May 2016

AbstractThe dependence of the fast photocurrent transients, measured at single crystalline n‐WSe2 electrodes, on laser intensity shows that the photocurrent increases proportionally to the laser intensity below z 100 nJ/′pulse.
ChemInform Abstract: Deposition of Zinc Selenide Thin Films by Solution Growth Technique.
Authors: PRAMANIK P. , BISWAS S. 
Published: May 2016

AbstractA po1ycrystalline ZnSe film has been deposited on a glass slide by a solution growth technique at 100°C using a solution containing ZnCl2,triethanolamine, NaOH, hydrazi‐ ne hydrate and sodium selenosulfate.
ChemInform Abstract: Semiconductor Electrodes. Part 60. Photoelectrochemistry of p‐ReS2 and p‐ReSe2 in Aqueous Solutions.
Authors: WHEELER B. L. , LELAND J. K. , BARD A. J. 
Published: May 2016

Abstractp‐ReS2 and p‐ReSeZ are prepared in analogy to the preparation method for n‐ReSz and n‐ReSez, but using 12 instead of Br2 as the transport agent.
ChemInform Abstract: The High Aqueous Solubility of K2S and Its Effect on Bulk and Photoelectrochemical Characteristics of Cd(SeTe)/Sx2‐ Cells.
Authors: LICHT S. , MANASSEN J. , HODES G. 
Published: May 2016

AbstractThe measured high aqueous solubility of KZS, compared to NazS, results in the preparation of a novel series of polysulfide electrolytes for use in CdX/Sä′ PEC′s. An increase in K28 concentration in electrolytes containing a fixed ratio of dissolved sulfur to alkali sulfide is shown to: l. modify the distribution of polysulfide species in solution, 2. increase the solution absorbance of light, 3. negatively shift the redox potential, 4. increase the calculated disproportionation‐limited lifetime of the solution, and 5. decrease K+ activity.
ChemInform Abstract: Potentiodynamic Passivation of Zinc in Aqueous KOH Solutions.
Authors: CABOT P. L. , CORTES M. , CENTELLAS F. A. , GARRIDO J. A. , PEREZ E. 
Published: May 2016

AbstractThe anodic dissolution and passivation of Zn in KOH has been investigated by means of the potentiodynamic method in combination with SEM.
ChemInform Abstract: In Situ 119Sn Conversion Electron Mößbauer Study of the Surface of Tin Layers as Deposited by an Electroless Process.
Authors: VAN NOORT H. M. , MEENDERINK B. C. M. , MOLENAAR A. 
Published: May 2016

AbstractThe process of autocatalytic (electroless) Sn deposition has been investigated using a rotating disk.
ChemInform Abstract: Mechanism of Ni ‐ Zn Ferrite Formation in the Presence of Molten Li2SO4‐ Na2SO4.
Authors: HAYASHI Y. , KIMURA T. , YAMAGUCHI T. 
Published: May 2016

AbstractThe Ni ‐ Zn ferrite (NixZn1‐xFe2O4) formation from NiO, ZnO, and Fe2O3 in molten Li2SO4‐ Na2SO4 is studied by XRD and thermomagnetic analyses as well as SEM.
ChemInform Abstract: Reaction of Chlorine Trioxide with Potassium Nitrate, and with Absolute or Fuming Nitric Acid: New Ways to Synthesize Nitryl Perchlorate.
Authors: PASCAL J.‐L. , HASSAN A. , POTIER J. 
Published: May 2016

AbstractC1206 reacts slowly with KNO3 to give a complex mixture of KClO4, NO2ClO4, KNO2(ClO4)2 and traces of C1206.
ChemInform Abstract: Influence of External Negative Charges on the Absorption Maxima of Symmetrical Cyanines.
Authors: SHEVES M. , FRIEDMAN N. 
Published: May 2016

AbstractThe effect of a symmetrical distribution of negative charges along the polyene on the absorption maxima of symmetrical cyanines is examined, using the Compounds (1), (IIa), (IIb) (i.e.
ChemInform Abstract: Dispersive Triplet Excitation Transport in Organic Glasses.
Authors: RICHERT R. , BAESSLER H. + 
Published: May 2016

AbstractTime dependent transport of triplet excitations in amorphous benzophenone, anthraquinone, and phenanthrene has been investigated in the temp. range 4.2 K ä T ä 100 K by monitoring diffusion‐controlled decay of the inhomogeneously broadened 0‐0 phosphorescence band of bulk states.
ChemInform Abstract: Structure and Conformation of Heterocycles. Part 15. Solvent Polarity and the Anomeric Effect.
Authors: FUCHS B. , ELLENCWEIG A. , TARTAKOVSKY E. , APED P. 
Published: May 2016

AbstractWährend die Dioxane (Ia) und (IIa) nahezu ausschließlich die diaxiale Konformation bevorzugen, liegen die Dioxane (Ib) und (IIb) als Gemische aus diaxialer und diäquatorialer Form vor.
ChemInform Abstract: Heats of Hydrogenation. Part 6. Resonance Energy of Fused [4n]Annulenes.
Authors: ROTH W. R. , LENNARTZ H.‐W. , VOGEL E. , LEIENDECKER M. , ODA M. 
Published: May 2016

AbstractFrom heat of hydrogenation measurements a resonance energy of + 3.7 kcal/mol has been obtained for compound (I).
ChemInform Abstract: Diffusion Coefficients in Anisotropic Fluids by ESR Imaging of Concentration Profiles.
Authors: HORNAK J. P. , MOSCICKI J. K. , SCHNEIDER D. J. , FREED J. H. 
Published: May 2016

AbstractThe use of ESR imaging for determining the translational diffusion constants of typical ESR spin probes in ordered and isotropic solvents is reported.
ChemInform Abstract: Synthesis of 7‐Acy1‐10‐methyl‐octahydronaphthalene‐3‐ones and 7‐Acylsteroids.
Authors: ROUX‐SCHMITT M.‐C. , SEYDEN‐PENNE J. 
Published: May 2016

AbstractDie Reaktion des Naphthalins (I) und des Steroids (V) mit den Acetonitrilen (II) ergibt in 7‐Stellung substituierte Produkte, z.T. als Isomerengemische.
ChemInform Abstract: Hydroboration. Part 73. Relative Rates of Hydroboration of Representative Heterocyclic Olefins with 9‐Borabicyclo[3.3.1]nonane.
Authors: BROWN H. C. , RAMACHANDRAN P. V. , PRASAD J. V. N. V. 
Published: May 2016

AbstractDie Hydroborierung zahlreicher Olefine wie (I)‐(IV) mit 9‐Bora‐bicyclo[3.3.l]nonan (V) wird vergleichend untersucht.
ChemInform Abstract: Reaction of ω‐Azidoketones with Triphenylphosphine: General Approach to Cyclic Imines.
Authors: VAULTIER M. , LAMBERT P. H. , CARRIE R. 
Published: May 2016

AbstractThe haloketones (I), obtained in good to excellent yields by known literature methods, are transformed to the azides (II) which on reaction with triphenylphosphine slowly cyclize to Cyclic imines of type (III).
ChemInform Abstract: Bridgehead Hydrazines. Part 2. Preparation and Photolysis of 2‐Phenyl‐ s‐triazolo[1,2‐a]pyridazine‐1,3‐dione and of Pyridazino[1,2‐b]phthalazine‐6,11‐dione.
Authors: SHERADSKY T. , MOSHENBERG R. 
Published: May 2016

AbstractDas aus Butadien (I) und dem Triazolindion (II) erhaltene Addukt (III) wird nach Bromierung zu dem Dien (V) dehydrobromiert.
ChemInform Abstract: Aerosol Direct Fluorination: Direct Synthesis of Perfluorinated Glyme Ethers.
Authors: ADCOCK J. L. , CHERRY M. L. 
Published: May 2016

AbstractDie Aerosol‐Fluorierung der Glykolether(I) mit elementarem Fluor in einem bereits früher beschriebenen Reaktor liefert die perfluorierten Analoga (II) in isolierten Ausbeuten von 36%, 22%, 30% und 15%.
ChemInform Abstract: Synthesis of Aryl Methyl Ketones Mediated by Cobalt Tetracarbonyl Anion.
Authors: MIURA M. , AKASE F. , NOMURA M. 
Published: May 2016

AbstractDurch Umsetzung der Arylbromide (I) mit Methyliodid (II) und Kohlenmonoxid (III) erhält man unter Co‐Katalyse die Acetophenone (IV) und die Benzoesäuren (V).
ChemInform Abstract: The Effect of the Structure of Substrates and Reaction Conditions on the Preparation of Acetylene 1,4‐Diols.
Authors: OLEJNIK M. , JASIOBEDZKI W. , POGRANICZNA‐RAMZA M. 
Published: May 2016

AbstractThe asym. acetylene 1,4‐diols (IV) are prepared in a two‐step sequence by conversion of the ketones (I) to the carbinols (III) and subsequent reaction of a second ketone with the Grignard reagent derived from (III).
ChemInform Abstract: Reaction of 1‐Arylpropenyl‐lithium with tert‐Alkyl Bromides. The Influence of Substituent Electronic Effects and Additives on the Course of the Reaction.
Authors: TANAKA J. , NOJIMA M. , KUSABAYASHI S. 
Published: May 2016

AbstractUntersucht wird die Alkylierung der Lithiumverbindungen (I) mit tert.‐Butylbromid (II) oder dem Octenylbromid (X) in Abhängigkeit von Additiven wie HMPA und TMEDA; die Anteile an Alkylierung, Reduktion und Dimerisierung werden bestimmt.
ChemInform Abstract: Syntheses of Some Binaphthalenes.
Authors: BAJT O. , MEDJA Z. , POLANC S. , TISLER M. , KOLLER J. 
Published: May 2016

AbstractEine Reihe von Reaktionen werden in der Absicht durchgeführt, zwei Naphthalineinheiten unsymm. zu verknüpfen.