bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Lanthanoid and Uranium Nickel Arsenides with CaBe2Ge2‐ and ThCr2Si2‐Type Structures.
Authors: JEITSCHKO W. , HOFMANN W. K. , TERBUECHTE L. J. + 
Published: May 2016

AbstractNew ternary arsenides, LnNi2As2 (Ln: La, Ce, Pr, Nd, Sm, and U), are prepared by annealing stoichiometric mixtures of the elements in evacuated silica tubes at 660‐1000 °C for 1‐2 weeks.
ChemInform Abstract: Novel Compounds of the Type MBeLn2O5 (M: Ca; Ln: La, Y).
Authors: SCHROEDER F. + , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractThe title compounds are prepared for the first time by heating mixtures of CaCO3, BeO, and Ln2O3 up to ≈ 2000 °C (1:1:1, CO2 laser).
ChemInform Abstract: A Novel Lanthanoid Carbide Halide, Gd6Cl5C3,
Authors: SIMON A. , SCHWARZ C. , BAUHOFER W. 
Published: May 2016

Abstractobtained from GdCl3 and graphite in Ta ampoules at 900‐1100 °C, crystallizes in the space group C2/m with Z=2.
ChemInform Abstract: Centered Zirconium Chloride Cluster Compounds with the Ta6Cl15 Structure.
Authors: ZIEBARTH R. P. , CORBETT J. D. 
Published: May 2016

AbstractThe phase Zr6Cl15N (I) is prepared in nearly quantitative yield by the reaction of Zr powder, ZrCl4, and ZrNCl (stoichiometric quantities, sealed Ta tube, 700 °C, 2 weeks).
ChemInform Abstract: Growth of PtCl3 Crystals from the Vapor Phase.
Authors: SCHOENHERR E. + , WOJNOWSKI M. , RABENAU A. , LACHER S. 
Published: May 2016

AbstractWhen Pt is heated in closed fused silica ampoules at temp. near 785 K and a Cl2 pressure of about 26 atm, crystals of only one compound, namely PtCl3, are obtained.
ChemInform Abstract: Complexation of Neutral Molecules by Preorganized Macrocyclic Hosts.
Authors: GROOTENHUIS P. D. J. , VAN EERDEN J. , DIJKSTRA P. J. , HARKEMA S. , REINHOUDT D. N. 
Published: May 2016

AbstractThermodynamic parameters of the complexation of the hemispherands (I)‐(III) with malononitrile (NC‐CH2‐CN) in CDCl3 and benzene‐d6 are determined.
ChemInform Abstract: cyclo‐Trimerization of 1,4‐Naphthoquinone; Cooperation of Phenol/Quinone Additions and Redox Reactions.
Authors: BROCKMANN H. 
Published: May 2016

AbstractThe reaction course previously postulated for the cyclo‐trimerization of 1,4‐naphthoquinone (I) to cyclo‐tri‐1,4‐naphthoquinone (III) is confirmed and supplemented by: a) isolation of the red intermediate (V), b) synthesis of (III) starting from (V) or the compound (VI), a further intermediate, and c) reduction of (V) and (VI) by (II) to the bis‐hydroquinone (IV).
ChemInform Abstract: Electrophilic Aromatic Substitution. Part 34. Intramolecular Friedel‐Crafts Acylation of N‐Phthaloyl‐Substituted Arylalanyl and Homophenylalanyl Chlorides.
Authors: EFFENBERGER F. , STEEGMUELLER D. + , NULL V. , ZIEGLER T. 
Published: May 2016

AbstractThe acid chlorides derived from (I) undergo intramolecular cyclization to yield the indanones (IIa)‐(IIc) and the tetralone (IId) without racemization.
ChemInform Abstract: Regioselective Allylation of Ketones.
Authors: CORMIER R. A. , MORRIS T. E. 
Published: May 2016

AbstractThe ketones (I) are allylated by reaction with allyl alcohol (II) in the presence of acetone dimethyl acetal and catalytic amounts of p‐toluenesulfonic acid to give the homoallylic ketones (III) and (IV).
ChemInform Abstract: Ring Cleavage of Cyclic 2‐Nitro Ketones by KF Catalyst: A General Synthesis of ω‐Nitro Acids and ω‐Nitro Esters.
Authors: BALLINI R. , PETRINI M. 
Published: May 2016

AbstractThe α‐nitrocycloalkanones (I) are cleaved with potassium fluoride in aqueous THF, yielding the ω‐nitroalkanoic acids (II).
ChemInform Abstract: Polyethylene Glycols as Solvents for Anionic Activation: Synthesis of Thioacetates by Means of Potassium Thioacetate in Polyethylene Glycol 400.
Authors: FERRABOSCHI P. , FIECCHI A. , GRISENTI P. , SANTANIELLO E. , TRAVE S. 
Published: May 2016

AbstractThe allylic halides or sulfonates (I) react with potassium thioacetate (II) in polyethylene glycol 400 to produce the thioacetates (III) which yield the corresponding thiols (IV) upon hydrolysis.
ChemInform Abstract: 1‐Trimethylsiloxyallylic Iron Complexes as a β‐Acylcarbanion Equivalent.
Authors: ITO K. , NAKANISHI S. , OTSUJI Y. 
Published: May 2016

AbstractThe α,β‐unsaturated ketones (I) are coupled with trimethylsilyl iodide (II) to yield the trimethylsiloxypropenyl iodides (III).
ChemInform Abstract: Reaction of Silyl Enol Ethers with N‐Chlorosuccinimide: Trapping of the Siloxycarbinyl Cation by an Azide Anion.
Authors: OHKATA K. , MASE M. , AKIBA K. 
Published: May 2016

AbstractGeneration of chlorosiloxycarbinyl cations from the silyl enol ethers (I) with N‐chlorosuccinimide and subsequent reaction with sodium azide (II) or methanol (V) produce the chlorosiloxy azides (III) or the chloroacetal (VI).
ChemInform Abstract: Oxidative Coupling. Part 5. Carbon‐Carbon Bond Formation from β‐Ketosulfone Dianions.
Authors: BELLETIRE J. L. , SPLETZER E. G. 
Published: May 2016

AbstractThe α‐phenylsulfonyl ketones (III), prepared by known procedures, are converted to the dianion salts (V) by treatment with excess LDA (IV) in THF.
ChemInform Abstract: Synthesis of (3S)‐Pyrrolidinol from L‐Glutamic Acid.
Authors: HARRIS B. D. , BHAT K. L. , JOULLIE M. M. 
Published: May 2016

Abstract4‐Amino‐2‐hydroxybutyric acid (I), prepared from L‐glutamic acid by known methods, is cyclized in the presence of chlorotrimethylsilane (II) and hexamethyldisilazane, yielding the siloxypyrrolidinone (III).
ChemInform Abstract: Direct Chain Elongation of N‐Carbamoylpyroglutamate. An Efficient Synthesis of (‐)‐Pyrrolidine‐2,5‐dicarboxylic Acid.
Authors: OHTA T. , HOSOI A. , KIMURA T. , NOZOE S. 
Published: May 2016

AbstractReaction of the N‐carbamoylpyroglutamates (I) with the Grignard compounds (II) yields the acyclic esters (III).
ChemInform Abstract: Reaction of 2‐Diazopropane with an Arylsulfonyltrimethylsilyl Substituted Alkene. Steric Control of Regiochemistry by the Trimethylsilyl Group.
Authors: PADWA A. , WANNAMAKER M. W. 
Published: May 2016

AbstractPhotolysis of the tosyltrimethylsilylnorbornadiene (I) results in intramolecular (2 + 2)cycloaddition, yielding the quadricyclane (II).
ChemInform Abstract: Palladium‐Catalyzed Coupling of Organotin Reagents and Alkenes with 4‐Iodopyrimidines.
Authors: SOLBERG J. , UNDHEIM K. 
Published: May 2016

AbstractThe coupling reaction between the pyrimidine (I), whose C‐4 position is activated by iodine, and styrene (IIa) or methyl acrylate (IIb) is best catalyzed by Pd(OAc)2 and yields the trans‐configurated 4‐vinylpyrimidines (III).
ChemInform Abstract: Reaction of 3‐Formylchromones with 4‐Amino‐3‐mercapto‐5‐phenyl‐4H‐ 1,2,4‐triazole under Phase Transfer Catalysis Conditions. Synthesis of 7‐(2′‐Hydroxybenzoyl)‐3‐phenyl‐1,2,4‐triazolo(3,4‐b)(1,3,4)thiadiazepines.
Authors: REDDY G. J. , SABITHA G. , RAO A. V. S. 
Published: May 2016

AbstractThe triazolothiadiazepines (III) are prepared as described in the title and the reaction scheme.
ChemInform Abstract: Incipient Pentagonal‐Pyramidal Coordination of Tellurium in a Macrocyclic Tetra(secondary amine) Complex.
Authors: KING R. B. , SANGOKOYA S. A. , HOLT E. M. 
Published: May 2016

AbstractThe Te complex (IV), prepared as shown (no yield given), crystallizes as tetrakis‐chloroform‐bis‐methanol‐solvate in the space group P21/c with Z=2.
ChemInform Abstract: Coordination Complexes of Polyoxomolybdate Anions. Characterization of a Tetranuclear Core from Reactions in Methanol: Syntheses and Structures of Two Polyoxomolybdate Alcoholates, (MePPh3)2(Mo4O10(OCH3)6) and (n‐Bu4N)2(Mo4O10(OCH3)2(OC6H4O)2), and Their Relationship to a General Class of Tetranuclear Cluster Types (Mo4Ox(OMe)2(L)y(LL)z)2‐.
Authors: LIU S. , SHAIKH S. N. , ZUBIETA J. 
Published: May 2016

AbstractThe hexakis(methoxo) title complex (Ia) is obtained as a product from the reaction of α‐(MePPh3)4(Mo8O26) with two equiv. N‐methyl‐N‐phenylhydrazine in methanol.
ChemInform Abstract: A New Cyclam with an Appended Imidazole. The First Biomimetic Ligation of Imidazole for Axial π‐Interaction with Metal Ions.
Authors: KIMURA E. , SHIONOYA M. , MITA T. , IITAKA Y. 
Published: May 2016

AbstractCyclocondensation of the methyl imidazolylacrylate (I) with 1,9‐diamino‐3,7‐diazanonane (II) gives the macrocyclic carboxamide (IIIa) which is reduced with diborane, forming the cyclic polyamine (IIIb).
ChemInform Abstract: Structural Isomerism Involving an Ambidentate Ligand: The Synthesis and Characterization of Diselenocyanato(bis(diphenylphosphino)methane)palladium(II) and Cyano(selenocyanato)(diphenyl(diphenylphosphinomethyl)phosphineselenide)palladium(II).
Authors: GRYGON C. A. , FULTZ W. C. , RHEINGOLD A. L. , BURMEISTER J. L. 
Published: May 2016

AbstractThe reaction of the diphosphine (I) with (II) produces the complex (III), characterized by a crystal structure determination (space group P212121, Z=4), while reaction of (I) with Pd acetate and KSeCN yields (VI) which is converted into (III) on heating.
ChemInform Abstract: Ruthenium and Osmium Complexes of N,O Chelators: Syntheses, Oxidation Levels, and Distortion Parameters.
Authors: LAHIRI G. K. , BHATTACHARYA S. , GHOSH B. K. , CHAKRAVORTY A. 
Published: May 2016

AbstractThe meridional metal(III) tris(chelates) (III) and (VI) are prepared as shown in the scheme, their structure is investigated by EPR and IR spectroscopy.
ChemInform Abstract: Quinol Epoxides from p‐Cresol and Estrone by Photooxygenation and Titanium(IV)‐ or Vanadium(V)‐Catalyzed Oxygen Transfer.
Authors: ADAM W. , LUPON P. 
Published: May 2016

AbstractPhotooxidation of p‐cresol (I) or estrone (V) according to method A) yields the hydroperoxo derivatives (II) or (VI).
ChemInform Abstract: Synthesis and Structural Characterization of a Lithium Gallosilicate with the Zeolite ABW Framework.
Authors: NEWSAM J. M. 
Published: May 2016

AbstractThe syntheses and characterization of gallo‐ and galloaluminosilicates with the zeolite ABW framework and the preparation of condensed δ‐eucryptite phases by calcination of these materials are described.
ChemInform Abstract: Average Oxidation Number of Copper in High Temperature Superconductors of the Type Y1‐xAxBa2Cu3O7‐z (A: Rare Earth Metal).
Authors: SCHAEFER W. + , MAIER‐ROSENKRANZ J. , KIEMEL R. , KEMMLER‐SACK S. 
Published: May 2016

Abstract20 samples of the title compounds with varying z values (0 < z ≤ 0.5) (16 samples x = 0, 2 samples A: La, and 2 samples A: Lu, x = 0.05) have been prepared by different methods and the average valency number of Cu has been determined by a titration method which is described in detail (addition of (NH4)2Fe(SO4)2, back‐titration with K2Cr2O7).
ChemInform Abstract: Photocatalysis on Ti‐Al Binary Metal Oxides: Enhancement of the Photocatalytic Activity of TiO2 Species.
Authors: ANPO M. , KAWAMURA T. , KODAMA S. , MARUYA K. , ONISHI T. 
Published: May 2016

AbstractTi‐Al binary metal oxides prepared by coprecipitation are used as photocatalysts for the hydrogenation reaction of propene with water and isomerization of cis‐2‐butene in the gas‐solid system.
ChemInform Abstract: Spectroscopic Evidence for the Formation of Singlet Molecular Oxygen (1δ‐ gO2) Upon Irradiation of a Solvent‐Oxygen (3ε‐ gO2) Cooperative Absorption Band.
Authors: SCURLOCK R. D. , OGILBY P. R. 
Published: May 2016

AbstractIn a time‐resolved experiment, a near IR luminescence subsequent to laser excitation of the oxygen‐induced absorption bands of mesitylene, p‐xylene, o‐xylene, toluene, and benzene (excitation at 355 nm) and 1,4‐dioxane (266 nm) is observed that is shown to be due to 1ΔgO2 phosphorescence.
ChemInform Abstract: SO3 Adducts of Hexameric Oxoniobate Cluster in Nonintegral Subnormal Oxidation States: Formation, Properties and Formulation.
Authors: SAHA A. V. , BANDYOPADHYAY P. , SEN B. K. 
Published: May 2016

AbstractNb(V) in 9 M H2SO4 is reduced with metallic zinc to a red‐brown solution, from which eight different salts containing the cluster anion (Nb6O7(O·SO3)12)16‐ are isolated (e.g., K8H8(Nb6O7(O·SO3)12)·18 H2O, K4Zn4H4(Nb6O7(O·SO3)12)·ZnSO4·18 H2O; synthesis conditions are listed in a table, yields in gram).
ChemInform Abstract: Existence and Stability of the Laves Phase Ag2Na.
Authors: FESCHOTTE P. , SPITZ E.‐L. 
Published: May 2016

AbstractStoichiometric Ag2Na is formed by peritectic reaction below 322 °C after melting Ag‐Na alloys at temp. up to 750 °C (sealed Ni‐crucible).
ChemInform Abstract: Electron‐Transfer Photochemistry of Benzocyclobutenes: Stereospecific Electrocyclic Reactions of Their Cation Radicals.
Authors: TAKAHASHI Y. , KOCHI J. K. 
Published: May 2016

AbstractThe facile activation of the isomeric benzocyclobutenes (I) either by charge‐transfer irradiation of the electron donor‐acceptor complex with the compound (II) or by chloranil (IV) photosensitization leads to a series of rapid (4+2) cycloadditions providing the products (III) or (V).
ChemInform Abstract: Triaziridines. Part 9. Ring‐Openings of Triaziridines.
Authors: HILPERT H. , DREIDING A. S. 
Published: May 2016

AbstractThe triaziridines (Ia)‐(Ic), (IIa)‐(IIc), and (IIIa)‐(IIIc) are heated at 60 °C in CDCl3 to obtain information on the tendency towards, or the resistance to ring opening of the N3‐homocycle by thermolysis.
ChemInform Abstract: Photochemical Transformations. Part 6. Organic Iodides. Part 5. Template Effect of Transition Metal Ions on Photocyclization of Some Olefinic Acyclic Terpene Iodides.
Authors: SUBBARAO K. V. , DAMODARAN N. P. , DEV S. 
Published: May 2016

AbstractThe photocyclization of citronellyl iodide (I) in the presence of transition metal salts, especially CuCl, results in a significant increase in the yield of the cyclization products (IV)‐(VI).
ChemInform Abstract: A Convenient Synthesis of Tetrakis(2‐bromoethyl)methane.
Authors: NEWKOME G. R. , GUPTA V. K. , GRIFFIN R. W. , ARAI S. 
Published: May 2016

AbstractCyclocondensation of tetrahydro‐4H‐pyran‐4‐one (I) with ethyl cyanoacetate (II) and ammonia (III) yields the spirocyclic dicyanocycloimide (IVa) which is cleaved on treatment with acid, forming the diester (Va).
ChemInform Abstract: Stereoselective Synthesis of Vinylcyclopropanes via Palladium‐Catalyzed Reactions.
Authors: BAECKVALL J. E. + , VAGBERG J. O. , ZERCHER C. , GENET J. P. , DENIS A. 
Published: May 2016

AbstractThe 2‐acetoxy‐5‐chloro‐3‐hexenes (Ia) and (IIIa) are coupled with sodium dimethyl malonate (II) to give the acetoxyhexenylmalonates (Ib) and (IIIb).
ChemInform Abstract: The Adamantane Rearrangement of Tricyclo(4.2.2.01,5)decane to Tricyclo(5.3.0.04,8)decane.
Authors: GHATAK K. L. , GANTER C. 
Published: May 2016

AbstractThe epimeric alcohols (I) and (VI) are synthesized in order to study the rearrangements of adamantane isomers.
ChemInform Abstract: Facile Retro Diels‐Alder Reaction of a Vinyl Lithium Compound.
Authors: HART H. , SHAHLAI K. 
Published: May 2016

AbstractReaction of benzyne, generated from the diazocarboxylate (I), with chlorobenzene (II) yields the chlorobenzonorbornadiene (III) which is lithiated, forming the intermediate (V).
ChemInform Abstract: Studies on Hypolipidemic Agents. Part 5. Synthesis and Esterase‐Inhibitory Activity of 2‐(1,4‐ and 4,4‐Dialkylcyclohexyl)‐2‐oxoethyl Arenesulfonates.
Authors: OGAWA K. , TERADA T. , MURANAKA Y. , HAMAKAWA T. , FUJII S. 
Published: May 2016

AbstractAlkylation of the cyclohexanecarboxylic acids (I) with the alkyl iodides (II) produces the acids (III) which are treated with thionyl chloride and then with diazomethane (IV) to form the diazo ketones (V) and (VI).
ChemInform Abstract: Facile Desilylative Hydroxyalkylation and Acylation of 1‐Trimethylsilylmethyl‐2‐pyridone.
Authors: KATRITZKY A. R. , SENGUPTA S. 
Published: May 2016

AbstractThe N‐methylpyridone (I) is lithiated to form the intermediate (IIIa) which is trapped with diphenyl ketone (IV), yielding the carbinol (V), or dimerizes to give (VI).
ChemInform Abstract: Neighboring Group Participation by Pyridine Ring. Part 3. Synthesis and Solvolysis of 5,8‐Dihydro‐ and 5,6,7,8‐Tetrahydro‐5,8‐methanoquinoline Derivatives.
Authors: TANIDA H. , IRIE T. 
Published: May 2016

AbstractStarting with the norbornanone (I), the brigded quinoline (V) is prepared.
ChemInform Abstract: Synthesis of Dihydro‐1,4‐oxathiins by Action of Chlorine on 1,3‐Oxathiolanes.
Authors: LEE W. S. , PARK O. S. , CHOI J. K. , NAM K. D. 
Published: May 2016

AbstractTreatment of the 1,3‐oxathiolanes (I) with chlorine yields the dihydrooxathiines (II) as the main products.
ChemInform Abstract: A Facile Method for Synthesis of N‐Acyloxymethyl‐5‐fluorouracils as a Class of Antitumor Agents.
Authors: AHMAD S. , OZAKI S. , NAGASE T. , IIGO M. , TOKUZEN R. , HOSHI A. 
Published: May 2016

Abstract5‐Fluorouracil (I) is hydroxymethylated to give 1,3‐bis(hydroxymethyl)‐ 5‐fluorouracil (III) which is esterificated with the carboxylic acids (IV), producing the 1‐acyloxymethyl‐5‐fluorouracils (V) as the main products.
ChemInform Abstract: Studies on Diazepines. Part 28. Syntheses of 5H‐1,3‐Diazepines and 2H‐1,4‐Diazepines from 3‐Azidopyridines.
Authors: SAWANISHI H. , TAJIMA K. , TSUCHIYA T. 
Published: May 2016

AbstractThe azidopyridines (I), (V), and (VII) react with sodium methoxide (II) under photolytic conditions to give the diazepine derivatives (III), (IV), (VI), and (VIII).
ChemInform Abstract: Synthesis and Antihypertensive Activities of 1,4‐Dihydropyridine‐5‐ phosphonate Derivatives. Part 2.
Authors: MORITA I. , KUNIMOTO K. , TSUDA M. , TADA S. , KISE M. , KIMURA K. 
Published: May 2016

AbstractThe diols (I) react with trimethyl phosphite (II) to give the cyclic phosphites (III) which undergo Arbuzov reaction with bromoacetone (IV), producing the phosphonates (V).
ChemInform Abstract: Synthesis, Structure, and Characterization of the Tetranuclear Iron(III) Oxo Complex (Fe4O2(BICOH)2(BICO)2(O2CPh)4)Cl2.
Authors: GORUN S. M. , LIPPARD S. J. 
Published: May 2016

AbstractThe title complex (IV) is prepared as shown with addition of triethylamine to facilitate removal of the proton and formation of the alkoxide moiety of the anion of (III).
ChemInform Abstract: Oxygen Transfer from p‐Cyano‐N,N‐dimethylaniline N‐Oxide to the μ‐Oxo Dimer of (meso‐Tetraphenylporphinato)iron(III).
Authors: DICKEN C. M. , BALASUBRAMANIAN P. N. , BRUICE T. C. 
Published: May 2016

AbstractThe title reaction is studied in CH2Cl2 at 25 °C under N2.
ChemInform Abstract: Pentadienyl‐Metal‐Phosphine Chemistry. Part 13. Synthesis and Complexation of a New Chelating Bis(phosphite) Ligand, pinacop. Structural Characterization of (2,4‐Dimethylpentadienyl)M(pinacop) Complexes (M: Co, Rh).
Authors: BLEEKE J. R. , DONALDSON A. J. , PENG W.‐J. 
Published: May 2016

AbstractThe bis(phosphite) ligand (III) is prepared according to the scheme.
ChemInform Abstract: The PtCl2‐ 4/Thiamin System. Structures of a Complex, Pt(thiamin)Cl3·H2O, and Two Salts, (Hthiamin)(PtCl4) and (Hthiamin)2(PtCl4)Cl2·2 H2O.
Authors: CRAMER R. E. , KIRKUP R. E. , CARRIE M. J. J. 
Published: May 2016

AbstractThe interaction of thiamin with (PtCl4)2‐ in aqueous solution leads to the title compounds (I), (II), and (III), whose structures are determined by X‐ray analysis.
ChemInform Abstract: Metal Complexes with Biologically Important Ligands. Part 44. Platinum(II) and Palladium(II) as Amino Protecting Groups. Metal Complexes with Silyl Esters and Acid Chlorides as Ligands and Peptide Synthesis at the Complex.
Authors: STEINER N. , EHRENSTORFER E. , CHEN J. , BECK W. 
Published: May 2016

AbstractThe cleavage of the chelate ring of Pt(II) and Pd(II) glycinate (I) by trialkylchlorosilanes (II) results in the formation of the dichlorobis(glycinate ester) complexes (III).
ChemInform Abstract: Synthesis of Enantiomerically Pure, α‐Alkylated Lysine, Ornithine, and Tryptophan Derivatives.
Authors: GANDER‐COQUOZ M. , SEEBACH D. 
Published: May 2016

AbstractThe imidazolidones (V) (accessible from lysine (Ia) or ornithine by known methods) can be diastereoselectively alkylated with the electrophiles (III), (VIII), or (IX) to give the products (IV), (VI), or (VII) depending on the reaction conditions.
ChemInform Abstract: Regioselective Acetylation and Deacetylation of Glycals: Characterization by Mass Spectroscopy.
Authors: BOUHROUM S. , VOTTERO P. J. A. 
Published: May 2016

AbstractThe diacetylated glycal (I) reacts with hydrazine to give the deacetylated products (II) and (III).
ChemInform Abstract: n‐AgInSe2/Polyiodide and ‐Polysulfide Photoelectrochemical Cells.
Authors: DAGAN G. , CAHEN D. , NELSON A. J. 
Published: May 2016

AbstractThe n‐AgInSe2 photoanode is found to behave similar to the CuInSe2‐photoelectrode with respect to chemical and photoelectrochemical etching, photocorrosion and the differences between polyiodide and polysulfide electrolytes.
ChemInform Abstract: A Polymeric Electrolyte Rechargeable Lithium Battery.
Authors: BONINO F. , OTTAVIANI M. , SCROSATI B. , PISTOIA G. 
Published: May 2016

AbstractCharacteristics and performance of a complete solid‐state rechargeable battery based on the Li/Li1+xV3O8 couple is studied using poly(ethylene oxide) (PEO) based electrolytes.
ChemInform Abstract: Cathode Behavior and Cell Voltage in NaOH Solutions at Elevated Temperatures
Authors: OGATA Y. , HORI H. , YASUDA M. , HINE F. 
Published: May 2016

Abstractare investigated for Fe, Ni, and Raney‐Ni electrodes (50‐200 °C, 2‐20 M NaOH, 2.1 MPa) in order to study the applicability of these materials as cathodes for alkaline water electrolysis cells and chlor‐alkali cells.
ChemInform Abstract: Influence of Zinc Hydroxide Addition on the Electrochemical Behavior of Precipitated Thin Hydrous Nickel Hydroxide on Platinum Substrate.
Authors: UNATES M. E. , FOLQUER M. E. , VILCHE J. R. , ARVIA A. J. 
Published: May 2016

AbstractIt is shown that the coprecipitation of Zn(OH)2 and Ni(OH)2 on a Pt electrode has a beneficial effect on the Ni(II)/Ni(III) redox couple for a Zn/Ni ratio of about 0.2.
ChemInform Abstract: Photochemistry of Tetrasulfido Complexes of Molybdenum(VI), Tungsten(VI), Vanadium(V), and Rhenium(VII).
Authors: VOGLER A. , KUNKELY H. 
Published: May 2016

AbstractIn the presence of air, the irradiation of solutions of all four (MS4)n‐ complexes (I) with white light causes photolysis according to the stoichiometry given in the scheme.
ChemInform Abstract: The Torsional Spectra of Jet‐Cooled Methyl Substituted Indoles in the Ground and First Excited States.
Authors: BICKEL G. A. , LEACH G. W. , DEMMER D. R. , HAGER J. W. , WALLACE S. C. 
Published: May 2016

Abstract(BICKEL, G. A.; LEACH, G. W.; DEMMER, D. R.; HAG‐ ER, J. W.; WALLACE, S. C.; J. Chem.
ChemInform Abstract: Electron Affinities of Benzo‐, Naphtho‐, and Anthraquinones Determined from Gas‐Phase Equilibria Measurements.
Authors: HEINIS T. , CHOWDHURY S. , SCOTT S. L. , KEBARLE P. 
Published: May 2016

AbstractThe equilibrium constant Ket for gas‐phase electron transfer equilibria A‐ + B = A + B‐ between compounds A with known electron attachment energies such as (I) and some 21 benzo‐, naphtho‐, and anthraquinones B such as (II)‐(VI) are determined.
ChemInform Abstract: Cycloaddition and Copolymerization of Methyl Tricyanoethylenecarboxylate with Electron‐Rich Olefins.
Authors: HALL H. K. JUN. , PADIAS A. B. , WAY T.‐F. , BERGAMI B. 
Published: May 2016

AbstractMethyl tricyanoethylenecarboxylate (III), prepared from tetracyanoethylene (I) and the cyanoacetate (II), is subjected to cycloaddition reactions with the olefinic compounds (IV) and (VIII), yielding the diastereomeric cyclobutanes (V) and (VI) or (IX) and (X), together with the pyran derivatives (VII) or (XI).
ChemInform Abstract: Dipolar Cycloaddition Reactions of Diazoazoles with Electron‐Rich and with Strained Unsaturated Compounds.
Authors: MAGEE W. L. , RAO C. B. , GLINKA J. , HUI H. , AMICK T. J. , FISCUS D. , KAKODKAR S. , NAIR M. , SHECHTER H. 
Published: May 2016

AbstractVarious diazoazoles are prepared by diazotization of the corresponding aminoazoles and subsequent base‐induced elimination reaction.
ChemInform Abstract: Bistability in an Isothermal Photochemical System. The Triphenylimidazolyl Radical Dimer in a CSTR.
Authors: LAVABRE D. , LEVY G. , LAPLANTE J. P. , MICHEAU J. C. 
Published: May 2016

AbstractA sudden jump in absorbance (photochromism) of the title dimer solution in CHCl3 and the reverse transition are observed at different residence times in a continuous‐stirred tank reactor (CSTR).