bluuebunny/crossref_metadata_2025_split huggingface dataset:
Efficient X‐Ray Scintillators Based on Facile Solution Processed 0D Organic Manganese Bromide Hybrid Films
Authors: Manny Tarannuma Ferdous , Shonde Tunde Blessed , Liu He , Islam Md Sazedul , Olasupo Oluwadara Joshua , Viera Jarek , Moslemi Sahel , Khizr Mohammad , Chung Cianna , Winfred J.S. Raaj Vellore , Stand Luis M. , Hilinski Edwin F. , Schlenoff Joseph , Ma Biwu 
Published: September 2024

Abstract0D organic metal halide hybrids (OMHHs) have recently emerged as a new generation of scintillation materials, due to their high luminescence quantum efficiency, sensitivity, stability, and cost‐effectiveness. While numerous 0D OMHH scintillators have been developed to date, most of them are based on solution grown single crystals that require time‐consuming synthesis and are limited in size. Here, high‐performance X‐ray scintillators based on facile solution processed 0D OMHH amorphous films are reported for the first time. By reacting triphenyl(9‐phenyl‐9H‐carbazol‐3‐yl) phosphonium bromide (TPPcarzBr) with manganese bromide (MnBr2), 0D (TPPcarz)₂MnBr₄ amorphous films can be prepared via solution processing with mild thermal annealing, which exhibits green photoluminescence with an emission maximum ≈517 nm and a photoluminescence quantum efficiency of ≈87%. The X‐ray scintillation of 0D (TPPcarz)₂MnBr₄ amorphous films is characterized to exhibit a light yield of 44600 photon MeV−1 and an outstanding linearity with a low limit of detection of 32.42 nGyairs−1 over a wide range of X‐ray dose rates. The versatile processability of 0D (TPPcarz)₂MnBr₄ is illustrated with remarkable recyclability, high cost‐effectiveness, and scalability for large‐scale production. By taking advantage of the amorphous nature of newly designed OMHHs, the approach opens up new opportunities for developing high‐performance, solution‐processable scintillators.
Organic Heterophase Composites Induced Sulfur Vacancies and Internal Electric Field Enhancement for Advanced Magnesium Storage of Copper Sulfide Cathodes
Authors: He Xiaoqian , Cheng Ruiqi , Sun Xinyu , Sun Fengzhan , Fu Yang , Li Yitong , Li Peng , Li Zhao , Xu Hao , Laine Richard M. , Zou Jianxin 
Published: September 2024

AbstractRechargeable magnesium‐ion batteries (MIBs) hold significant promise for safe and efficient large‐scale energy storage, but the lack of high‐performance cathodes hinders their development for practical applications. In this work, a series of nanocomposites consisting of π‐conjugated perylene‐3,4,9,10‐tetracarboxylic dianhydride annealed at 450 °C and copper sulfide (CuSP) are synthesized solvothermally to explore their utility as a host for Mg2+ storage in MIBs. The carbonyl organics in the hybrid materials modify the predominant CuS phase, expanding interlayer spacing and enriching sulfur vacancies through modifications of the internal electric field. This synergistic interaction enhances magnesium storage performance and accelerates reaction kinetics. Using chlorine‐free Mg[B(hfip)4]2/DME electrolytes, the CuSP91 cathode containing an appropriate organic content displays a remarkably high reversible capacity of 285 mAh g−1 at 50 mA g−1, and demonstrates a stable capacity of 220 mAh g−1 at 100 mA g−1, surpassing pure CuS cathode in terms of shorter activation time. The CuSP91 cathode maintains a discharge capacity of 55 mAh g−1 over 1000 cycles at 500 mA g−1. A co‐redox mechanism is revealed through in/ex situ investigations and analyses. Overall, this research contributes valuable insights targeting the development of advanced organic–inorganic hybrid composite cathode materials in next‐generation energy storage systems.
Deciphering the Benefits of Coordinated Binders in Si‐Based Anodes by Combined Operando/In Situ and Ex Situ X‐Ray Micro‐ and Nano‐Tomographies
Authors: Vanpeene Victor , Huet Lucas , Villanova Julie , Olbinado Margie , Marone Federica , Maire Eric , Roué Lionel , Devic Thomas , Lestriez Bernard 
Published: September 2024

AbstractThe simple addition of a Zn(II) precursor to a preoptimized poly(carboxylic acid) binder solution enhances the electrochemical performance and cycle life of silicon‐based electrodes. The binder/cation couple forms a cross‐linked coordinated binder that plays a key role in enhancing the mechanical and chemical stability of the electrode microstructure. The impact of the addition of the Zn precursor on the microstructural evolution of the electrode during cycling is investigated at different scales (from cell/electrode to silicon particle scale) using complementary operando, in situ, and ex situ X‐ray tomography techniques. Comparative analyses conducted on the reference and with Zn electrode formulations using operando and in situ X‐ray micro‐tomography allow for monitoring of the electrode morphological deformations along with the crack pattern formation and evolution during cycling. The benefits of the precursor addition include enhancing the mechanical stability of the electrode through a strengthened microstructure more apt to maintaining its integrity, as well as a better anchoring to the current collector leading to decreased electrical disconnections and capacity fade. Moreover, complementary ex situ X‐ray nano‐tomography measurements highlight the benefits of the precursor addition in terms of chemical stability with mitigated solid electrolyte interface (SEI) formation over the electrode cycling.
Electrically conductive polyaniline: Graphite composite on porous polyurethane sponge with enhanced sensitivity of humidity
Authors: Das Dipankar , Das Jayanta , Dasgupta Debadrita , Saha Biswajit 
Published: September 2024

AbstractRecent advancements in organic materials based sensor technology created a prospective field in designing sensors that are both cost‐effective and environment friendly. In view of that an electronic material system has been prepared depositing a uniform layer of graphite‐infused Polyaniline (PANI) onto the sponge framework using a straightforward physical vapor deposition technique. The prepared active materials were studied for the composition, morphology, optical properties, and charge transport characteristics. In the current context of rapidly growing sensor technology, this works describes an innovative approach of improving the response of the prepared electronic system of PANI/Gr composites, integrated into porous PU sponge substrates. Incorporation of graphite in PANI improved the electrical conductivity of the composite and porous structure of PU increased the interaction surface area. The performance of the prepared materials in humidity detection was evaluated by studying their resistive response under varying humidity levels, which was measured through current‐voltage (I‐V) characteristics. The higher interaction sites of the reported active sensing system leads to inspiring humidity sensitivity of 0.522–26.22 kΩ/% RH with reasonable response and recovery time of 572 and 416 sec respectively. Additionally, the reported sensor system consisting of degradable materials will offer a useful way of reducing electronic garbage.
Effect of Different Ratios of Polyvinyl Alcohol‐Gum Odina for the Preparation and Characterization of Biodegradable Composite Films
Authors: Tudu Mousumi , Hazra Ahana , Paul Pankaj , Mohanta Abhishek , Chatterjee Sohini , Samanta Amalesh 
Published: September 2024

ABSTRACTThis research investigates the production of biodegradable films using a combination of gum odina (GO) and polyvinyl alcohol (PVA) with varied ratio. The study focuses on the chemical, physical, and mechanical properties of PVA‐GO composite films, emphasizing how versatile and biodegradable they may be for a range of packaging applications. Solvent‐cast PVA‐GO films with different ratios are subjected to a methodical analytical process to determine several parameters like mechanical qualities, thermal stability, biodegradability in soil, contact angle, transparency, water vapor permeability, moisture content, thickness, density, water solubility, microstructure, and FTIR analysis. The outcomes demonstrate that GO improves UV barrier qualities and water vapor permeability. Additionally, the films showed notable biodegradability, acceptable thermal stability, and mechanical qualities. In short, PVA‐GO films can provide an eco‐friendly packing substitute with adaptable qualities fit for a range of uses. Therefore, this research may further contribute promising information in the field of biodegradable packaging materials in the future.
Toward sustainable development: The triple nexus for enhanced supply chain performance through information technology, resilience, and sustainability integration
Authors: Sadia Umma Habiba , Liu Da , Irfan Muhammad 
Published: September 2024

AbstractThe dynamic interaction between supply chain resilience (SCR) and sustainability has become a crucial area of study in the evolving business landscape. While research has made strides in connecting information technology (IT) and SCR, a gap remains in understanding how sustainability dimensions integrate into these aspects, particularly in socio‐economically and environmentally challenged countries. This study aims to address this gap by investigating how IT and SCR contribute to enhancing overall supply chain performance, with a specific focus on the role of social (SS), environmental (ENS), and economic (ECS) sustainability dimensions. To achieve this, we formulated hypotheses that were tested using structural equation modeling, based on data from a sample of 321 apparel enterprises in Bangladesh. The findings reveal that IT significantly enhances resilience, while SCR does not directly improve supply chain performance when sustainability dimensions are considered. However, SCR positively influences all dimensions of sustainability, underscoring the importance of the combined strength of IT and SCR for achieving enduring sustainability in an uncertain world. Moreover, the results show that the triad of sustainability (SS, ENS, and ECS) fully mediates the relationship between resilience and supply chain performance, serving as the linchpin that binds and strengthens these elements. This research advances the understanding of the interplay between IT, resilience, and sustainability, providing valuable guidance for policymakers and sustainability professionals. Moreover, by integrating sustainability into IT and resilience strategies, organizations can enhance their supply chain performance and ensure long‐term success.
How do hybrid organisations use socio‐environmental impact information? An exploratory analysis in European B corps
Authors: Fuertes‐Fuertes Iluminada , Cabedo J. David , Tirado‐Beltrán José Miguel 
Published: September 2024

AbstractAchieving genuine sustainability progress depends on translating strategic goals into actionable steps. This is particularly crucial for hybrid organisations, where managers must integrate socio‐environmental impact information into daily practices. This study explores how managers use impact information for internal (company control and decision‐making) and external (dissemination) purposes. Furthermore, it examines whether there are differences in the usage patterns depending on corporate characteristics. Using sample data produced by an online questionnaire administered to European B Corps, the results show somewhat limited integration of this socio‐environmental information into management decision‐making. However, companies with better alignment between economic and social objectives, alongside highly innovative firms, showcase a more extensive use of this information. This research contributes to the literature by identifying specific organisational characteristics that are linked to the observed variations in the use of impact information. It points out which characteristics are associated with companies that exhibit a more comprehensive integration of this information into management practices.
Associations between language, telehealth, and clinical outcomes in patients with cancer during the COVID‐19 pandemic
Authors: Azizi Armon , Mahadevan Aditya , Arora Jagmeet S. , Chiao Elaine , Tanjasiri Sora , Dayyani Farshid 
Published: September 2024

AbstractBackgroundThe COVID‐19 pandemic prompted a surge in telehealth utilization. However, language barriers have emerged as a potential obstacle to effective telemedicine engagement, impacting millions of limited English proficient (LEP) individuals. Understanding the role of language spoken in telehealth outcomes is critical, particularly in cancer care, in which consistent follow‐up and communication are vital. The primary objective was to assess the impact of telehealth utilization and primary language spoken on clinical outcomes in cancer patients.MethodsThis study utilized a retrospective cohort design, encompassing cancer patients seen at the Chao Family Comprehensive Cancer Center between March 1, 2020, and December 31, 2022. The study incorporated both in‐person and telehealth visits, examining the association between encounter type and clinical outcomes.ResultsThe study included 7890 patients with more than one outpatient visit during the study period. There was decreased telehealth utilization in non‐English speaking cancer patients throughout the pandemic. Increased telehealth utilization was associated with higher rates of admission, irrespective of cancer type. Additionally, telehealth visits were associated with longer duration of subsequent admissions compared to in‐person visits. Spanish‐speaking patients utilizing telehealth had higher rates of re‐admission compared to English speakers utilizing telehealth. Patients who died had higher rates of telehealth utilization compared to patients who survived.Conclusions and RelevanceThis study demonstrates that primary language spoken is associated with differences in telehealth utilization and associated outcomes in cancer patients. These differences suggest that the interplay of telehealth and language could contribute to widening of disparities in clinical outcomes in these populations. The study underscores the need to optimize telehealth usage and minimize its limitations to enhance the quality of cancer care in a telehealth‐driven era.
Cross‐sectional investigation of the distribution characteristics and prognostic significance of lateral lymph nodes in patients with rectal cancer
Authors: Yang Xuyang , Zhang Yang , Zhuang Zixuan , Zeng Hanjiang , Zhang Tong , Deng Xiangbing , Meng Wenjian , Wang Ziqiang 
Published: September 2024

AbstractBackgroundInformation about the distribution characteristics and prognostic significance of lateral lymph nodes (LLNs) on primary computed tomography (CT) scan in rectal cancer patients is lacking.MethodsBetween January 2013 and December 2016, patients with pathologically proved rectal cancer and pretreatment abdominal enhanced CT in our department were screened. We firstly redivided LLNs into seven categories based on their locations. Then, the number and distribution of all measurable LLNs and the characteristics of the largest LLN in each lateral compartment were recorded. Furthermore, we investigated the long‐term outcomes in patients with different LLN characteristics and LLN risk scoring.ResultsA total of 572 patients were enrolled in this study. About 80% of patients had measurable LLNs, and most patients developed measurable LLNs in the obturator cranial compartment. Lateral local recurrence (LLR) was observed in 20 patients, which accounted for 83.3% of the local recurrence (LR). Patients with the largest LLN short‐axis diameter >10 mm had a poor prognosis, which was similar to that in patients with simultaneous distant metastasis (SDM). Patients with LLN risk scoring ≥2 had a worse prognosis than those with LLN risk scoring <2, while better than those with SDM.ConclusionThis study suggests that LLR is the main locoregional recurrence pattern. Most rectal cancer patients have measurable LLNs on primary CT scan. However, patients with enlarged LLNs <10 mm or LLN risk scoring <2 still have a significantly better prognosis than patients with SDM, which indicated the potential value of locoregional treatment for these LLNs.
Gibberellic Acid (GA3): A Versatile Chiral Building Block for Syntheses of Pharmaceutical Agents
Authors: Alabdeen Khdar Zein , Le Tam Minh , Szakonyi Zsolt 
Published: September 2024

AbstractGibberellic acid (GA3), an ent‐kaurene tetracyclic diterpene, has been considered to be a chiral pool for the chemical transformation of significant heterocyclic compounds. This chiral pool continues to influence modern synthetic chemistry as an inexpensive and versatile starting material since it is widely applied in agriculture. This review focuses on the stereoselective syntheses of bioactive agents with pharmaceutical potency prepared from Gibberellic acid.
Recent progress in the synthesis and electrocatalytic application of MXene‐based metal phosphide composites
Authors: Su Hengjun , Jin Chulong , Zhang Xiaofeng , Yu Zhixin , Zeng Xiaojun 
Published: September 2024

AbstractIn the domain of novel catalyst design and application, metal phosphides have attracted widespread interest due to their unique electronic structure and potential catalytic activity. Various types of supports that can effectively anchor metal phosphides have been reported, among which MXene have received significant attention due to their two‐dimensional (2D) structure, adjustable composition, and composite variability. This work mainly aims to elucidate the preparation of novel MXene carriers and their unique roles in loading metal phosphides and participating in catalytic reactions. We will clarify the preparation strategy of MXene, the interaction between metal phosphides and MXene carriers, to explain the stabilization of metal phosphide active sites and the rational adjustment of electronic structure. In addition, we will comprehensively summarize recent research progress of MXene‐based metal phosphide composites, with particular emphasis on advancements in the synergistic effect of heterostructures. Regarding applications, we review the utilization of MXene‐based metal phosphide composites in electrocatalysis, including hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). Finally, some fundamental challenges and prospects for the efficient electrocatalysis of MXene‐based metal phosphide composites are introduced.
Pharmacokinetics of Subcutaneous Itepekimab Injection With an Autoinjector Device and Prefilled Syringe in Healthy Participants
Authors: Xu Christine , Xin Kong , Kosloski Matthew P. , Butler Allison , Goulaouic Helene , Nivens Michael C. , Kanamaluru Vanaja 
Published: September 2024

AbstractItepekimab, a monoclonal antibody against interleukin‐33, has demonstrated clinical utility in previous studies in patients with asthma and chronic obstructive pulmonary disease. An autoinjector (AI) has been developed for administering itepekimab to facilitate further development. This study compared pharmacokinetics of single 300‐mg itepekimab subcutaneous administration via an AI versus a prefilled syringe (PFS). Of 90 healthy volunteers enrolled in this Phase 1, parallel‐design, randomized study and stratified by body weight (50 to <70 kg, ≥70 to <80 kg, ≥80 to 100 kg) and injection site (abdomen, thigh, or arm), 84 completed the study. Systemic exposure of itepekimab was similar for both groups. Point estimates for geometric mean ratios of pharmacokinetic parameters for AI versus PFS groups were 1.01 for maximum serum concentration, 1.06 for area under the serum concentration‐time curve to the last quantifiable concentration, and 1.04 for area under the serum concentration‐time curve extrapolated to infinity. The exposure was similar for both devices in each body weight and injection site subgroup. Overall, systemic exposure of 300‐mg single‐dose itepekimab in healthy participants was comparable when administered subcutaneously via an AI device and PFS, with an acceptable safety profile in both device groups.
Photoelectrocatalytic CO2 Reduction to Formate Using a BiVO4/ZIF‐8 Heterojunction
Authors: Yang Zhi , Yang Jiaqi , Yang Huimin , Gao Fanfan , Nan Cheng , Chen Rui , Zhang Yi , Gao Xuemei , Yuan Yue , Jia Yibo , Yang Yuanjing 
Published: September 2024

AbstractConverting CO2 into high‐value chemical fuels through green photoelectrocatalytic reaction path is considered as a potential strategy to solve energy and environmental problems. In this work, BiVO4/ZIF‐8 heterojunctions are prepared by in‐situ synthesis of ZIF‐8 nanocrystals with unique pore structure on the surface of BiVO4. The experimental results show that the silkworm pupa‐like BiVO4 is successfully combined with porous ZIF‐8, and the introduction of ZIF‐8 can provide more sites for CO2 capture. The optimal composite ratio of 4 : 1‐BiVO4/ZIF‐8 exhibits excellent CO2 reduction activity and the lowest electrochemical transport resistance. In the electrocatalytic system, the formate Faraday efficiency of 4 : 1‐BiVO4/ZIF‐8 at −1.0 V vs. RHE is 82.60 %. Furthermore, in the photoelectrocatalytic system, the Faraday efficiency increases to 91.24 % at −0.9 V vs. RHE, which is 10.8 times higher than the pristine BiVO4. The results show that photoelectric synergism can not only reduce energy consumption, but also improve the Faraday efficiency of formate. In addition, the current density did not decrease during 34 h electrolysis, showing long‐term stability. This work highlights the importance of the construction of heterojunction to improve the performance of photoelectrocatalytic CO2 reduction.
The Factors of the Psychotherapists' Attitude Towards Technology: Combining Attitudes Towards Technology and Technology Readiness Models
Authors: Koch Agnieszka , Graczykowska Agata , Szumiał Szymon , Rudnicka Patrycja , Marszał‐Wiśniewska Magdalena 
Published: September 2024

ABSTRACTObjectivesThe study aimed to explore psychotherapists' attitudes towards new technologies. Understanding the factors influencing their acceptance of technologies is essential to improving the accessibility, quality, and effectiveness of psychotherapeutic care in the digital age. Based on previous research from different fields (e.g., e‐government and mobile applications), we integrated the Unified Theory of Acceptance and Use of Technology (UTAUT‐T) with the Technology Readiness Index (TRI). UTAUT‐T focuses on one's perception of technology, while TRI emphasizes individual characteristics. Therefore, we regard psychotherapists' attitudes towards digital solutions by analysing factors related to technology and users (psychotherapists).MethodsWe conducted an online questionnaire study involving 391 psychotherapists aged 25–66 (M = 40.90; SD = 7.79). Participants completed self‐report questionnaires: UTAUT‐T, TRI 2.0, and a survey measuring technology usage at work.ResultsThe model explained 30.2% of the variance in actual technology usage and 57.6% in behavioural intention. Both technology‐related and therapist‐related factors affect technology use. Some factors directly influence use behaviour (optimism, ease of use, convenience), while others are mediated by behavioural intention (pressure from others, professional support, therapy quality expectations).ConclusionsTechnology‐related and therapist‐related factors influence psychotherapists' use of technology. The study revealed that optimism plays a crucial role in addition to behavioural intention. This insight is vital for implementing new technologies in mental health services.