bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Stereoselectivity in (2,3)Wittig Rearrangement of Isopropyl (2E‐1‐(ω‐Benzyloxyalkyl)‐2‐butenyl)oxyacetate. Preparation of Potent Building Blocks for the Synthesis of Polyoxo Compounds.
Authors: KURODA S. , SAKAGUCHI S. , IKEGAMI S. , HANAMOTO T. , KATSUKI T. , YAMAGUCHI M. 
Published: May 2016

AbstractThe Wittig rearrangement of the acetates (I) mentioned in the title is performed in the presence of lithium diisopropylamide and metallocenes to give the syn‐alcohols (II) and (III) as the main products.
ChemInform Abstract: Synthesis and Use of Benzyl tert.‐Butyl Iminodicarbonate (V), a Versatile Reagent for the Preparation of Amines.
Authors: GREHN L. , RAGNARSSON U. 
Published: May 2016

AbstractWith the iminodicarbonate (III) in hand, the title compound (V) is best prepared by a one‐pot procedure (see scheme).
ChemInform Abstract: Synthesis of Organo‐Sulfur Compounds from Trichloroallyl Alcohol.
Authors: SERGEEVA V. P. , PETUKHOVA N. P. , PRILEZHAEVA E. N. , NIKISHIN G. I. 
Published: May 2016

AbstractThe trichloroallyl alcohols (I) react with the thiolates (II) to give the ketene S,S‐acetals (III).
ChemInform Abstract: Chemistry of Enol Ethers. Part 86. Diene Condensation of 2‐Trimethylsilyloxy‐1,3‐dienes with α,β‐Unsaturated Aldehydes. 1‐Formyl‐4‐trimethylsilyloxy‐3‐cyclohexenes and 1‐Formyl‐4‐oxocyclohexanes.
Authors: MAKIN S. M. , SHAVRYGINA O. A. , NGUYEN PHUONG THUNG NGUYEN PHUONG THUNG 
Published: May 2016

AbstractThe regio‐ and the stereoselectivity of the reactions between the 2‐trimethylsilyl‐1,3‐dienes (I), (V) or the tautomeric couple (VIII)/(IX) and acrolein (IIa) or trans‐crotonic aldehyde (IIb) are investigated giving the products shown.
ChemInform Abstract: The Cyanamido Moiety as a Novel Leaving Group.
Authors: REITER J. 
Published: May 2016

AbstractCoupling of the N‐cyanocarbonimidodithiate (II) with the benzylic amines (I) yields the isothioureas (III) which react with 2‐ethanolamine (IV) to give the guanidine derivatives (V) as the main products, together with the isothiourea derivatives (VI) formed by elimination of the cyanamido group.
ChemInform Abstract: Aryl Radical‐Induced Cyclization Routes to Furo(2,3‐b)benzofurans. Abbreviated Formal Syntheses of Aflatoxins B1 and B2.
Authors: SLOAN C. P. , CUEVAS J. C. , QUESNELLE C. , SNIECKUS V. 
Published: May 2016

AbstractThe o‐halophenols (I) are coupled with the bromodihydrofuranone (II) to form the ethers (III) which undergo reductive cyclization to give the furobenzofurans (IV).
ChemInform Abstract: A Facile Synthesis of Arylazoselenazoles and of Aroylselenadiazoles.
Authors: HASSANEEN H. M. , FARAG A. M. , ALGHARIB M. S. , SHAWALI A. S. 
Published: May 2016

AbstractCyclocondensation of the hydrazonoyl bromides (I) with selenourea (II) gives the 5‐arylazoselenazoles (III).
ChemInform Abstract: Vanadium(III) Phenolate Complexes. Synthesis, Structure, and Properties of ((V(OC6H5)6)(Li(DME))3) and Two Species Containing the (V(DIPP)4)‐ Anion (DME: 1,2‐Dimethoxyethane, DIPP: 2,6‐Diisopropylphenolate).
Authors: WILISCH W. C. A. , SCOTT M. J. , ARMSTRONG W. H. 
Published: May 2016

AbstractThe title complexes are the first examples of structurally characterized homoleptic four‐ and six‐coordinate V(III) phenolate species.
ChemInform Abstract: Synthesis of Cyclometalated (8‐Methoxynaphthyl)‐ and (8‐(Dimethylamino)naphthyl)platinum Compounds and Their Reactivity Toward Electrophiles. X‐Ray Molecular Structures of Square‐Planar (8‐Methoxynaphthyl)platinum(II) Chloride Bis(diethyl sulfide) and Bis(8‐methoxynaphthyl)platinum(II) Diethyl Sulfide and Octahedral fac‐Bis(8‐methoxynaphthyl)methylplatinum(IV) Iodide.
Authors: WEHMAN E. , VAN KOTEN G. , KNAAP C. T. , OSSOR H. , PFEFFER M. , SPEK A. L. 
Published: May 2016

AbstractReaction of the lithiated compounds (I) or (VIII) with the Pt complexes (II) or (VI) in various stoichiometries affords a series of new cyclometalated compounds whose formulations are based on their 1H NMR and mass spectra.
ChemInform Abstract: Synthesis of Mono‐ and Sesquiterpenoids. Part 13. A New Synthesis of (‐)‐Khusimone.
Authors: SAKURAI K. , KITAHARA T. , MORI K. 
Published: May 2016

AbstractThe title compound (X), a minor constituent of vetiver oil, is prepared via Lewis acid catalyzed Diels‐Alder reaction of the ketone (I).
ChemInform Abstract: Terpenic Compounds. Part 22. A General Method for the Synthesis of Clerodane Diterpenoids. Stereospecific Total Syntheses of (.+‐.)‐15,16‐Epoxy‐cis‐cleroda‐3,13(16),14‐triene and (.+‐.)‐Maingayic Acid.
Authors: TOKOROYAMA T. , FUJIMORI K. , SHIMIZU T. , YAMAGIWA Y. , MONDEN M. , IIO H. 
Published: May 2016

AbstractThe key intermediates (VI) in the synthesis of the title compounds (XIV) and (XIX) are prepared starting from the ketone (I) via a stereospecific addition‐alkylation sequence followed by anellation.
ChemInform Abstract: Preparation of 1,6‐Anhydroglucose from (1 → 4)‐Glucans Using Microwave Technology.
Authors: STRAATHOF A. J. J. , VAN BEKKUM H. , KIEBOOM A. P. G. 
Published: May 2016

AbstractHeating of starch or other (1 → 4)‐glucans in a conventional microwave oven yields the title compound (I) within a few minutes.
ChemInform Abstract: Total Synthesis and Properties of Prostaglandins. Part 15. Synthesis of Heterocyclic Prostanoids.
Authors: KALNIN'SH A. P. , DIKOVSKAYA K. I. , FREIMANIS YA. F. , TUROVSKII I. V. , LIEPIN'SH E. E. 
Published: May 2016

AbstractStarting from γ‐keto esters, e.g. the compound (I), oximes are prepared which are formed as mixtures of the syn and anti isomers (III) and (IV).
ChemInform Abstract: Synthesis of Marasin and 9‐Methylmarasin, (Nona‐ and Deca‐6,8‐diyne‐3,4‐dienol).
Authors: DE GRAAF W. , SMITS A. , BOERSMA J. , VAN KOTEN G. , HOEKSTRA W. P. M. 
Published: May 2016

AbstractThe title compounds (IVa) and (IVb) are prepared starting from the iodide (I) and the protected dienol (II) and their antibiotic activities are tested against Staphylococcus aureus.
ChemInform Abstract: The Cathodic Reduction of SOCl2 in N,N‐Dimethyl Formamide. Part 1. Controlled Potential Coulometry and Rotating Ring‐Disk Electrode Voltammetry
Authors: SAKAI M. , OSTERYOUNG J. , OSTERYOUNG R. A. 
Published: May 2016

Abstractis performed at glassy carbon electrodes in DMF with Bu4N+PF6‐ as supporting electrolyte.
ChemInform Abstract: Arylation of Cyclic Ethers by Gaseous Phenylium Ions. Formation and Behavior of Phenoxenium Ions in the Gas Phase.
Authors: FORNARINI S. , SPERANZA M. 
Published: May 2016

AbstractFree, unsolvated phenylium ions formed by the spontaneous decay of 1,4‐ditritiobenzene are allowed to react with gaseous oxirane, methyloxirane, oxetane, and acetaldehyde in the pressure range 30‐250 torr and in the presence of O2 (4 torr) as thermal radical scavenger.
ChemInform Abstract: Preparation of Lactams via Oxidation of Cyclic, Tertiary, and Secondary Amines with Hg(II)‐EDTA Complex in Alkaline Medium.
Authors: WENKERT E. , ANGELL E. C. 
Published: May 2016

AbstractThe oxidation method mentioned in the title is employed to various pyrrolidine, piperidine, and morpholine derivatives as shown in the reaction scheme, yielding the corresponding lactams.
ChemInform Abstract: The Monoacetalization of Glyoxal: A Direct Synthesis of 2,2‐Dimethoxy and Diethoxy Ethanals.
Authors: SANGSARI F. H. , CHASTRETTE F. , CHASTRETTE M. 
Published: May 2016

AbstractWhen glyoxal (I) is treated with a seven‐ to tenfold excess of the alcohols (II) in the presence of zirconium disulfate, the monoacetals (III) are predominantly formed, together with only minor amounts of the diacetals (IV).
ChemInform Abstract: Ketimines from Ketones and Ammonia.
Authors: VERARDO G. , GIUMANINI A. G. , STRAZZOLINI P. , POIANA M. 
Published: May 2016

AbstractThe diaryl ketones (I) undergo pressure reaction with ammonia (III) and ammonium chloride (II), producing the ketimines (IV) which are isolated in the form of their hydrochlorides (V).
ChemInform Abstract: Synthesis of 2,5‐Bis(ethynyl)‐1,3,4‐trimethylpyrrole, (IIIb), the First Example of an Alkylpyrrole Bearing Two Terminal Acetylenic Groups in Conjugate Positions.
Authors: ORTAGGI G. , SCARSELLA M. , SCIALIS R. , SLEITER G. 
Published: May 2016

AbstractThe very unstable starting compound (I) is prepared according to Treibs and Kolm (yield 31%; no details given).
ChemInform Abstract: Claisen Rearrangement and Cyclization of N‐Alkenyl‐1,2,3,4‐tetrahydroquinolines.
Authors: ABDRAKHMANOV I. B. , MUSTAFIN A. G. , TOLSTIKOV G. A. 
Published: May 2016

AbstractTreatment of the N‐alkenyltetrahydroquinolines (I) with acidic catalysts gives the C‐alkenyl derivatives (II).
ChemInform Abstract: Synthesis of 2‐Substituted 1H‐Imidazo(4,5‐f)quinoxalines.
Authors: RAO S. K. , REDDY A. P. R. , VEERANAGAIAH V. 
Published: May 2016

AbstractThe quinoxaline (I) reacts with aliphatic carboxylic acids of type (II) under the conditions A) or B) to give title compounds of type (IV) together with lower amounts of amides (III), whereas the reaction of (I) with formic acid or treatment of (I)/(II) according to C) yields only type (IV).
ChemInform Abstract: Iron(III) Nitrate Complexes with Linear Pentacoordinate Ligands and Their Base Hydrolysis Products.
Authors: WANG X. , KOTUN M. E. , PENNINGTON W. T. , FANNING J. C. 
Published: May 2016

AbstractThe title complexes such as (I) are prepared from salicylaldehyde, the appropriate triamine and Fe(III) nitrate in EtOH in the presence of NEt3 and triethylorthoformate and characterized by Moessbauer spectra, magnetic moments and conductivity measurements.
ChemInform Abstract: Bis(imidazolidine‐2‐thione)(thiocyanato‐N)copper(I): Preparation, Thermal Analysis and Crystal Structure.
Authors: RAPER E. S. , CREIGHTON J. R. , WILSON J. D. , CLEGG W. , MILNE A. 
Published: May 2016

AbstractThe diamagnetic title complex (III) crystallizes in the space group P21/m with Z=2.
ChemInform Abstract: Selective Deprotection of the 2‐OH Group in Methyl‐2,3‐di‐O‐benzyl‐4,6‐O‐benzylidene‐α‐D‐glucopyranoside by Hydrogen Transfer.
Authors: DEAUPERE D. , BOUTBAIBA I. , DEMAILLY G. , UZAN R. 
Published: May 2016

AbstractThe selective deprotection of the O‐benzyl group in position 2 of the title compound (I) is possible when (I) is heated with cyclohexene in the presence of palladium on carbon and ammonium formate.
ChemInform Abstract: Structural Study of In6Sn8S19, a Mixed Valence Tin Phase in the Ternary System In‐Sn‐S.
Authors: ADENIS C. , OLIVIER‐FOURCADE J. , JUMAS J.‐C. , PHILIPPOT E. 
Published: May 2016

AbstractSingle crystals of the title compound are prepared by solid state reaction of a In2S3/SnS/SnS2 mixture (800 °C, 7 d).
ChemInform Abstract: High Resolution Powder Neutron Diffraction Study of the Tetragonal Anion‐Excess Fluorite‐Related LaF1.70O0.65 Phase.
Authors: LAVAL J.‐P. , ABAOUZ A. , FRIT B. , ROULT G. , HARRISON W. T. A. 
Published: May 2016

AbstractThe title oxyfluoride, prepared by heating an intimate mixture of commercial ultrapure La2O3 and LaF3 (2 · 2 d, 1200 °C, sealed Ni tube) crystallizes in the tetragonal space group P4/nmm, Z=2.
ChemInform Abstract: Membrel‐Water Electrolysis Cells with a Fluorinated Cation Exchange Membrane.
Authors: SCHERER G. G. , MOMOSE T. , TOMIIE K. 
Published: May 2016

AbstractStability tests demonstrate the possibility of using a low cost fluorinated cation exchange membrane for water electrolysis cells under conditions necessary to obtain cell voltages of economical interest (80 °C, 1 A/cm2).
ChemInform Abstract: Large Sn‐E‐Sn (E: Te, Se, S) Angles: Tri‐tert.‐butylstannyl Chalcogenides.
Authors: BATCHELOR R. J. , EINSTEIN F. W. B. , JONES C. H. W. , SHARMA R. D. 
Published: May 2016

AbstractThe X‐ray crystal structures of the isomorphous compounds (I) are determined (for all space group C2/c, Z=4) in order to probe the steric influence of bulkier ligands on the bond angle at the chalcogen.
ChemInform Abstract: Reactivities of Stable Rotamers. Part 24. Formation of Isomeric Ketones by Cyclization of Rotameric 3‐Methyl‐3‐(1,2,3,4‐tetrahalo‐9‐triptycyl)butanoyl Chloride and Barriers to Isomerization of the Ketones.
Authors: OKI M. , TANUMA T. , TANAKA Y. , YAMAMOTO G. 
Published: May 2016

AbstractThe rotameric alkenyltriptycenes (III) and (IV) isomerize in boiling 1‐chloronaphthalene and serve to prepare the ketones (VII) and (VIII) via carboxylic acids (V) (and their rotamers, from (III)).
ChemInform Abstract: Design and Synthesis of New Ferroelectric Liquid Crystals. Part 5. Properties of Some Chiral Fluorinated FLCs: A Direct Connection Between Macroscopic Properties and Absolute Configuration in a Fluid Phase.
Authors: WALBA D. M. , RAZAVI H. A. , CLARK N. A. , PARMAR D. S. 
Published: May 2016

AbstractThe basic correctness of the "bent cylinder binding site" model for packing in the smectic C* phase and its usefulness for stereochemical assignments are demonstrated.
ChemInform Abstract: Descriptive Photochemistry and Electronic Structure of the Cp2MoO and (MeCp)2MoO Complexes (Cp: η5‐C5H5; MeCp: η5‐CH3C5H4).
Authors: SILAVWE N. D. , BRUCE M. R. M. , PHILBIN C. E. , TYLER D. R. 
Published: May 2016

AbstractThe photochemistry of the title complexes is studied because these complexes are potential photochemically activated oxygenating agents.
ChemInform Abstract: Neighboring Hydroxyl Group Participation in Metal‐Ammonia Reduction of Spirocyclic Dienones.
Authors: IWATA C. , YAMADA M. , IDA Y. , IMAO T. , MIYAGAWA H. , MIYASHITA K. 
Published: May 2016

AbstractReduction of the spirodienone (I) yields the hydroxyspirodienone (II) which is reduced with alkali metals in liquid ammonia to form the hydroxyenones (III) and (IV).
ChemInform Abstract: The Reaction of Organoboranes with Trimethylsilyl Azide in a Neutral Medium: Synthesis of Primary Amines.
Authors: KABALKA G. W. , GOUDGAON N. M. , LIANG Y. 
Published: May 2016

AbstractThe terminal olefins (Ia) ‐ (Id) are hydroborated and then directly treated with trimethylsilyl azide (II), yielding the primary amines (IIIa) ‐ (IIId).
ChemInform Abstract: Competitive Dienone‐Phenol Type Rearrangements for the Regioselective Preparation of 2,4‐Disubstituted Naphth‐1‐ols.
Authors: DODGE J. A. , CHAMBERLIN A. R. 
Published: May 2016

AbstractNaphthoquinone (I) is converted to the diols (V) via consecutive twofold alkylation/arylation.
ChemInform Abstract: Synthesis of Pyrido(1,2‐b)pyrazol‐2‐ones and Study of Their Fluorescent Properties.
Authors: RANGNEKAR D. W. , PHADKE R. C. 
Published: May 2016

AbstractCyclocondensation of the N‐amino‐3‐cyanopyridone (I) with the acetates (II) produces the bicyclic compounds (III).
ChemInform Abstract: An Improved Preparation of Cyclopropylphosphonates and Their Application in Arylmethylenecyclopropane Formation.
Authors: LEWIS R. T. , MOTHERWELL W. B. 
Published: May 2016

AbstractCyclopentene (I) and the dihydropyran (Ib) are coupled with diethyl diazomethylphosphonate (II), yielding the fused cyclopropylphosphonates (III).
ChemInform Abstract: Platina(IV)cyclopentanes. Stereoselective Synthesis and Structural Characterization of Trisubstituted Platinacyclopentanes.
Authors: NEILSEN W. D. , LARSEN R. D. , JENNINGS P. W. 
Published: May 2016

AbstractOn the reaction of the epimeric hydrocarbons (IIa) + (IIb) with the Zeise's dimer (III), the Pt(II) readily oxidatively adds the 1,2,3‐trisubstituted cyclopropanes with kinetic preference for the syn isomer effecting an epimeric separation.
ChemInform Abstract: Synthesis of Ketofuranosides by Epoxidation‐Ring Closure of Enol Ethers.
Authors: BOSCHETTI A. , PANZA L. , RONCHETTI F. , RUSSO G. , TOMA L. 
Published: May 2016

AbstractThe Z‐ and E‐hydroxy enol ethers (I) and (IV), obtained from aldoses, react according to A)‐C) to afford the ketofuranosides (II), (III), (V) or (VI) in moderate to good yields with good stereoselectivities.
ChemInform Abstract: Synthesis of Thyroid Hormone Analogues. Part 2. Oxidative Coupling Approach to SK&F L‐94901.
Authors: HICKEY D. M. B. , LEESON P. D. , CARTER S. D. , GOODYEAR M. D. , JONES S. J. , LEWIS N. J. , MORGAN I. T. , MULLANE M. V. , TRICKER J. Y. 
Published: May 2016

AbstractA novel approach to the synthesis of the title compound (VII), a novel, selective and potent thyromimetic, is described the key step being the formation of the hindered diaryl ether moiety by oxidative coupling of the phenols (IV) and (V).
ChemInform Abstract: Bolaform and Classical Cationic Metallomicelles as Catalysts of the Cleavage of p‐Nitrophenyl Picolinate (II).
Authors: FORNASIER R. , SCRIMIN P. , TECILLA P. , TONELLATO U. 
Published: May 2016

AbstractBolaform micelles made of both ligand surfactants (Ib) and (Ic) in the presence of Cu(II) or Zn(II) are good catalysts for the hydrolysis of (II).
ChemInform Abstract: Co(III) Complex Promoted Hydrolysis of Phosphate Diesters: Comparison in Reactivity of Rigid cis‐Diaquotetraazacobalt(III) Complexes.
Authors: CHIN J. , BANASZCZYK M. , JUBIAN V. , ZOU X. 
Published: May 2016

AbstractThe complexes (I)‐(III) are ideal for evaluating a structure‐reactivity relationship since they are held rigidly in the cis form and cannot undergo isomerization processes.
ChemInform Abstract: Metal to Ligand Charge‐Transfer Photochemistry of Metal‐Metal‐Bonded Complexes. Part 7. Photochemistry of (CO)4CoM(CO)3(bpy) (M: Mn, Re; bpy: 2,2′‐Bipyridine): Photocatalytic Disproportionation of the Manganese Complex in the Presence of PR3.
Authors: VAN DIJK H. K. , VAN DER HAAR J. , STUFKENS D. J. , OSKAM A. 
Published: May 2016

AbstractAll photochemical reactions of the compounds (I) proceed via homolytic splitting of the metal‐metal bond.
ChemInform Abstract: Thermal Oxidative Deamination of Aliphatic Amines to Aldehydes with Bis(diphenylphosphinyl) Peroxide.
Authors: MASSE G. , STURTZ G. 
Published: May 2016

AbstractThe activated secondary amines (VI), prepared from the primary amines (II) via the N‐alkylphosphoric amides (V), react with bis(diphenylphosphinyl) peroxide to form the aldimines (VII).
ChemInform Abstract: Synthesis and Reactive Behavior of 3,3‐Diaminoacrylic Acid Derivatives.
Authors: AUGUSTIN M. , GUENTHER E. + 
Published: May 2016

AbstractTreatment of the 1,3‐dioxane‐4,6‐dione (I) with alkanols, e.g. with EtOH (II), in the presence of conc.
ChemInform Abstract: Keto Acids and Lactones. Part 2. Synthesis of γ‐Butyrolactones, Quinoxalines, and Azauracils from 4‐Aryl‐2‐oxobutanoic Acid Derivatives.
Authors: LABIB G. H. , ABDEL RAHMAN M. , EL‐KILANY Y. , EL‐MASSRY A. I. , EL‐ASHRY E. S. H. 
Published: May 2016

AbstractCondensation of the acids (I) with the aromatic aldehydes (II) affords the γ‐butyrolactones (III) which occur as equilibria of tautomers in solution.
ChemInform Abstract: Carbene Complex‐Promoted Ring Expansion of Aziridine: Formation of the 1‐Azabicyclo(4.3.0) Ring System by a Double Alkyne and a Single Carbon Monoxide Insertion Reaction.
Authors: DENISE B. , PARLIER A. , RUDLER H. , VAISSERMANN J. , DARAN J. C. 
Published: May 2016

AbstractThe chromium carbene complex (I) is coupled with the aziridine (II) to give the E‐ and Z‐isomers (III) and (IV) which react with diphenylacetylene (V), producing the heterocyclic chromium carbonyl complex (VI).
ChemInform Abstract: Synthesis of Tetrathiafulvalene (TTF) Derivatives Bearing Long Alkyl Chains.
Authors: DHINDSA A. S. , BRYCE M. R. , LLOYD J. P. , PETTY M. C. , KOBAYASHI K. , TUKADA H. 
Published: May 2016

AbstractThe dithiocarbonates (I), prepared from potassium O‐ethyl xanthate and the corresponding bromo ketones, cyclize upon treatment with phosphorus pentasulfide, forming the 1,3‐dithiole‐2‐thiones (II).
ChemInform Abstract: A New Route to 2,3‐Disubstituted Pyrazines. Regioselective Metalation of Chloropyrazine.
Authors: TURCK A. , MOJOVIC L. , QUEGUINER G. 
Published: May 2016

AbstractDirect lithiation of chloropyrazine (I) followed by reaction with various electrophiles, e.g. (II), (IV), and (VI), gives 2‐substituted 3‐chloropyrazines such as (III), (V), and (VII).
ChemInform Abstract: Synthesis of Trifluoromethylated Pyrazine‐Containing Nitrogen Heterocycles from Trifluoropyruvaldehyde and ortho‐Diamines: Scope and Regiochemistry.
Authors: CUSHMAN M. , PATEL H. , MCKENZIE A. 
Published: May 2016

AbstractHydrolysis of the trifluorodibromoacetone (II) and subsequent cyclocondensation with the primary diamines (I) or (IV) yield the quinoxaline derivatives (III) or a mixture of the isomeric trifluoromethylpteridinediones (V) and (VI).
ChemInform Abstract: Photochemistry of 2′‐Substituted 1,2,3,4‐Tetrahydronaphthalene‐1‐spiro‐3′‐oxaziridines. Variable‐Temperature 1H Nuclear Magnetic Resonance Spectroscopy of 1‐Substituted 1,3,4,5‐Tetrahydro‐2H‐1‐benzazepin‐2‐ones.
Authors: JOHNSON G. P. , MARPLES B. A. 
Published: May 2016

AbstractOn irradiation, the title oxaziridines (I) in which the N‐substituent is syn to the aromatic ring, rearrange less regioselectively than their anti isomers.
ChemInform Abstract: pπ‐pπ Bonding Between Phosphorus and Sulfur: Synthesis and Characterization of a Dithiaphospholium Cation.
Authors: BURFORD N. , ROYAN B. W. , LINDEN A. , CAMERON T. S. 
Published: May 2016

AbstractChloride ion abstraction reaction is employed to obtain the first isolated examples (III) of a dicoordinate phospholium cation.
ChemInform Abstract: An Equilibrium Involving Edge‐ and Face‐Shared Bioctahedral d3‐d3 Ditungsten Complexes: W2Cl6(PEt3)4 and W2Cl6(PEt3)3.
Authors: CHACON S. T. , CHISHOLM M. H. , STREIB W. E. , VAN DER SLUYS W. 
Published: May 2016

AbstractThe molecular structure determination of the product (III) (space group P21/n, Z=4) shows this to be a member of the family of edge‐shared bioctahedra.
ChemInform Abstract: Characterization of a Novel μ4‐Peroxide Tetrairon Unit of Possible Relevance to Intermediates in Metal‐Catalyzed Oxidations of Water to Dioxygen.
Authors: MICKLITZ W. , BOTT S. G. , BENTSEN J. G. , LIPPARD S. J. 
Published: May 2016

AbstractThe complex (II) is prepared by ligand substitution from (I) and can also be obtained from a MeCN solution of (NEt4)2‐(Fe2OCl6) and Zn benzoate and H2O2 with 84% yield.
ChemInform Abstract: Effects of Transition‐Metal Ions on the Reduction of Di‐2‐pyridyl Ketone with Sodium Borohydride.
Authors: SUH M. P. , KWAK C.‐H. , SUH J. 
Published: May 2016

AbstractThe Co(II) complexes (I), (IV), and (V) of the title ketone (III), its hydrated and its hydrogenated derivative are obtained according to the scheme and characterized by IR and UV/VIS spectral data as well as molar conductance measurements.
ChemInform Abstract: A Rhodium Complex That Combines Benzene Activation with Ethylene Insertion. Subsequent Carbonylation and Ketone Formation.
Authors: GHOSH C. K. , GRAHAM W. A. G. 
Published: May 2016

AbstractUV irradiation of a degassed benzene solution of the Rh(I) complex (I) results in complete conversion to the phenyl‐Rh(III) complexes (IIIa) and (IIIb) in approximately equal yield.
ChemInform Abstract: Electrochemical Investigation of Kinetic and Thermodynamic Aspects of Oxidation and Reduction of Mononuclear and Binuclear Rhodium Dithiocarbamate and Diselenocarbamate Complexes.
Authors: BOND A. M. , COLTON R. , MANN D. R. 
Published: May 2016

AbstractThe oxidation processes of the complexes (I) and (II) at a Pt electrode are similar to the previously reported oxidation of their Co analogues, although the Rh(IV) dithiocarbamates are less stable.
ChemInform Abstract: Stereospecificity in the Synthesis of C‐5 Modified Nucleosides Using Radical Chemistry: Furanosidic Chain‐Lengthening Through C‐4.
Authors: BARTON D. H. R. , GERO S. D. , QUICLET‐SIRE B. , SAMADI M. 
Published: May 2016

AbstractThe 2‐thiopyridone derivative (I) of glucuronic acid undergoes photochemical decarboxylation and insertion of the alkenes (II), producing the thioethers (III).
ChemInform Abstract: Syntheses of Pterocarpans. Part 2. Synthesis of Both the Enantiomers of Pisatin.
Authors: MORI K. , KISIDA H. 
Published: May 2016

AbstractNatural pisatin (+)‐(VIII), and antifungal phytoalexin, and its unnatural isomer (‐)‐(VIII) are prepared starting from the known isoflavone (I) via resolution of the racemate (IV).