bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis and Crystal Structure of New Polynuclear Rhodium Complexes Formed by Reaction of Bis(η‐ethylene)(η5‐indenyl)rhodium with tert.‐Butylphospha‐acetylene.
Authors: BINGER P. , BIEDENBACH B. , MYNOTT R. , BENN R. , RUFINSKA A. , BETZ P. , KRUEGER C. + 
Published: May 2016

AbstractThe study reveals that reactions of phosphaalkynes such as (II) with Rh(I) compounds are more complex than with the corresponding Co(I) compounds.
ChemInform Abstract: Metallaheteroborane Chemistry. Part 7. Synthesis, Crystal Structure, and Characterization of Two Dinuclear Rhodatelluraboranes, (((PPh3)2RhTeB10H10)2) and ((PPh3)(CO)Rh2Te2B20H20).
Authors: FERGUSON G. , LOUGH A. J. , FARIDOON FARIDOON , MCGRATH M. N. , SPALDING T. R. , KENNEDY J. D. , FONTAINE X. L. R. 
Published: May 2016

AbstractIn order to get hybrid metal cluster‐metallaheteroboranes the reaction of (I) with the osmium cluster (II) is carried out.
ChemInform Abstract: Iridium Thioether Chemistry: The Synthesis and Structures of (IrL2)(PF6)3 and (IrHL2)(PF6)2 (L: 1,4,7‐trithiacyclononane).
Authors: BLAKE A. J. , GOULD R. O. , HOLDER A. J. , HYDE T. I. , REID G. , SCHROEDER M. + 
Published: May 2016

AbstractThe hydrido complex (III) crystallizes as its hexafluorophosphate‐bis‐nitromethane solvate in the space group Cc with Z=4.
ChemInform Abstract: Synthesis of 1,2,4‐Triazolo(2,3‐c)pyrimidin‐5(6H)‐one Nucleosides and Their Antileishmanial Activity.
Authors: SINGH K. , HASAN A. , PRATAP R. , GURU P. Y. , BHAKUNI D. S. 
Published: May 2016

AbstractThe O‐silylated triazolo(2,3‐c)pyrimidinone (I) is coupled with the protected ribofuranose (II) to give the nucleoside (IIIa) which is converted to the deprotected derivative (IIIb).
ChemInform Abstract: Wet Chemical Passivation of YBa2Cu3O7‐x
Authors: VASQUEZ R. P. , HUNT B. D. , FOOTE M. C. 
Published: May 2016

Abstractis performed by immersion of the superconductor in dilute solutions of HI, H2SO4, Na2S, HF, or H2C2O4 and the resulting passive layers are studied by XPS.
ChemInform Abstract: The Influence of the Pretreatment of Powder on the Resulting Properties of LaNi5 Electrodes.
Authors: BOONSTRA A. H. , BERNARDS T. M. N. 
Published: May 2016

AbstractHydrogen absorption/desorption cycling of LaNi5 is found to result in an increase in the specific surface area and a decrease of the hydrogen absorption capacity.
ChemInform Abstract: On K(Mo4O6).
Authors: HOFFMANN R. , HOPPE R. , BAUER K. , RANGE K.‐J. 
Published: May 2016

AbstractThe normal pressure modification KMo4O6‐I is prepared by reaction of KO2 in a molybdenum cylinder at 1080 °C (heating rate of 100 °/h, 21 d at 1080 °C, quenching).
ChemInform Abstract: Competitive (4 + 2) and (3 + 2) Cycloadditions of Nitrosoalkenes to the Imino Bond of Bicyclic 1,2‐Oxazines.
Authors: LAI E. C. K. , MACKAY D. , TAYLOR N. J. , WATSON K. N. 
Published: May 2016

AbstractThe reaction of 2,5‐dimethylfuran with nitrosostyrene (IIa) is investigated with the hope to detect the adduct (X).
ChemInform Abstract: Formation of δ4‐Oxocenes from Lewis Acid Promoted Cyclizations of 5‐Hexenyl Acetals. Evidence for a Concerted Ene Cyclization Mechanism.
Authors: BLUMENKOPF T. A. , LOOK G. C. , OVERMAN L. E. 
Published: May 2016

AbstractBoth the intermolecular (kinetic) and intramolecular (product) hydrogen‐deuterium isotope effects are determined for the formation of the oxocenes (II) or (III), resp., from the SnCl4‐promoted cyclization of the acetals (Ia), (Ib), or (Ic).
ChemInform Abstract: Synthesis of Oxygenated Compounds from Carbon Monoxide and Hydrogen Through Addition of Substituted Acetylenes.
Authors: SLIVINSKY E. V. , RUMYANTSEV V. YU. , VOITSEKHOVSKY YU. P. , ZVEZDKINA L. I. , LOKTEV S. M. 
Published: May 2016

AbstractThe addition of phenylacetylene (I) to synthesis gas leads to an appreciable increase in the activity of the catalyst, i.e. modified Fe3O4, and to the formation of alcohols such as (III) and (IV), hydrocarbons such as (V), (VI), (VII) and its analogues up to octylbenzene, and aldehydes such as (VIII) and its analogues.
ChemInform Abstract: Investigations of the Metal Halide Catalyzed Alkylation Reactions of Pentaborane(9).
Authors: GAINES D. F. , LEE L. K. 
Published: May 2016

AbstractComparison studies of the effect of various catalysts (AlCl3, FeCl3, TbCl5, TaCl5, HfCl4) and reaction conditions on the catalyzed propylation reaction show that the use of the early‐transition‐metal halides HfCl4 and ZrCl4 allows a high‐yield route to (III).
ChemInform Abstract: Hydrogen Iodide Strategy for One‐Pot Preparation of Allylic Azides, Nitriles, and Phenyl Sulfones from Allylic Alcohols.
Authors: KANAI T. , KANAGAWA Y. , ISHII Y. 
Published: May 2016

AbstractAllylic alcohols such as (I) are converted by in situ generated hydrogen iodide to the corresponding iodides.
ChemInform Abstract: Acetylation of 2‐C‐Benzyl‐L‐lyxo‐3‐hexulosono‐1,4‐lactone.
Authors: KINOSHITA T. , YOSHIDA N. , MIWA T. 
Published: May 2016

AbstractAcetylation of the title compound (I) affords an unexpected product, the "open form" lactone diacetate (III) along with the expected "closed form" lactone triacetate (IV).
ChemInform Abstract: Electron Transfer Between Covalently Linked Porphyrin and Quinone Units: Synthesis, Magnetic Resonance, and Picosecond Fluorescence Spectroscopy.
Authors: VON GERSDORFF J. , HUBER M. , SCHUBERT H. , NIETHAMMER D. , KIRSTE B. , PLATO M. , MOEBIUS K. + , KURRECK H. , EICHBERGER R. , KIETZMANN R. , WILLIG F. 
Published: May 2016

AbstractQuinones, covalently linked with porphyrin, like (I) are suitable for investigating light‐induced charge separation in the primary process of photosynthesis.
ChemInform Abstract: Antifertility Agents. Synthesis of Yuehchukene Analogues: 6β‐(Indol‐3‐yl)‐9,12‐dimethyl‐6,7,10,11‐tetrahydro‐7,11‐methano‐5H‐(b)indo# le and 6β‐(Indol‐3‐yl)‐9,12‐dimethyl‐6,7,8,11‐tetrahydro‐7,11‐methano‐5H‐cyclo‐oc# t(b)indole.
Authors: CHENG K.‐F. , CHAN T.‐Y. , WONG T.‐T. , LAI T.‐F. 
Published: May 2016

AbstractThe title compounds (XI) and (XIII) are prepared, via the intermediates (IX) and (XII) (both space group P21/n with Z=4), in order to test their biological activity.
ChemInform Abstract: In situ Measurements of Tropospheric OH Radicals ‐ A Challenge for the Experimentalist.
Authors: ARMERDING W. , HERBERT A. , SCHINDLER T. , SPIEKERMANN M. , COMES F. J. 
Published: May 2016

AbstractThe method developed for quantitative measurements of tropospheric OH radicals is based on the differential optical absorption spectroscopy with fast scanning of a narrowband, frequency‐doubled and power‐stabilized dye laser.
ChemInform Abstract: Observation of a Remarkable Dependence of the Rate of Singlet‐Singlet Energy Transfer on the Configuration of the Hydrocarbon Bridge in Bichromophoric Systems.
Authors: KROON J. , OLIVER A. M. , PADDON‐ROW M. N. , VERHOEVEN J. W. 
Published: May 2016

AbstractIntramolecular singlet energy transfer is detected via time‐resolved emission spectroscopy (fluorescence lifetimes, quantum yields, energy transfer rates, solvent effects) in the series (I)‐(III) where the chromophore Z and the carbonyl chromophore are separated by extended all‐trans arrays of up to eight C‐C σ bonds (in (III)).
ChemInform Abstract: Reaction of Diphenacylphenylphosphine Oxide with o‐Phenylenediamine.
Authors: NASEDKIN A. V. , KALINOV S. M. , KAMINSKII V. A. , VYSOTSKII V. I. 
Published: May 2016

AbstractReaction of diphenacylphenylphosphine oxide (I) and o‐phenylenediamine (II) catalyzed by p‐toluenesulfonic acid produces predominantly 2‐phenylbenzimidazole (III), together with the phosphine oxide (IV) and, by dehydration of (I), the oxaphosphorin (V) as by‐products.
ChemInform Abstract: Gas‐Phase Oxygenation of Benzene Derivatives Around 300 K with O(3P) Atoms Produced by Microwave Discharge of N2O. Part 2. Kinetic H/D Isotope Effects.
Authors: SOL V. M. , LOUW R. , MULDER P. 
Published: May 2016

AbstractThe addition of a ground‐state atomic oxygen leads to the main phenol isomers (II)‐(IV); 69% of the p‐isotopomer is undeuterated (V).
ChemInform Abstract: Application of Elementoorganic Compounds of 15th and 16th Groups in Organic Synthesis. Part 82. An Efficient SbCl3‐Metal System for Allylation, Reduction and Acetalization of Aldehydes.
Authors: WANG W.‐B. , SHI L.‐L. , HUANG Y.‐Z. 
Published: May 2016

AbstractA novel and highly efficient method of allylation, reduction and acetalization of aldehydes is described, which works under very mild conditions.
ChemInform Abstract: Chiral Building Blocks for the Synthesis of N‐Containing Natural Products. Part 3. Enantiomerically Pure N‐Boc Protected β‐Keto γ‐Amino Acid Esters from Simple Keto Precursors. A Novel, Stereocontrolled Approach to Statine Derivatives with Any Desired Configuration.
Authors: BRINGMANN G. , KUENKEL G. + , GEUDER T. 
Published: May 2016

AbstractReaction of the isovalerophenone (I) with (S)‐1‐phenylethylamine (II) and subsequent hydrogenation result in the formation of the chiral secondary amine (III) which is deprotected, yielding the optically active primary amine (IV).
ChemInform Abstract: Palladium‐Catalyzed Coupling Reactions of (α‐Ethoxyvinyl)trimethylstannane with Vinyl and Aryl Triflates.
Authors: KWON H. B. , MCKEE B. H. , STILLE J. K. 
Published: May 2016

AbstractVinyl triflates such as (I) undergo Pd(0)‐catalyzed cross‐coupling reaction with the stannane (II) to yield dienes such as (III) which are hydrolyzed to give α,β‐unsaturated ketones such as (IV).
ChemInform Abstract: Preparation of E‐α,β‐Unsaturated Aromatic Aldehydes by High Stereoselective Olefinformylation.
Authors: GAUDEMAR M. , BELLASSOUED M. 
Published: May 2016

AbstractThe imine (I) is consecutively treated with two equivalents of each LDA and trimethylchlorosilane (II) to give the bissilylated compound (III) which reacts with the benzaldehyde (IVa), forming the azadienes (V).
ChemInform Abstract: cis‐2‐Lithiated Enol Ethers: Preparation and Reactions with Electrophiles.
Authors: BARLUENGA J. , RODRIGUEZ M. A. , CAMPOS P. J. 
Published: May 2016

AbstractTreatment of the iodo(isopropoxy)phenylalkenes (I) with organolithium compounds results in lithiation to form 1‐lithio‐1‐alkenes which are stereoselectively substituted with the electrophiles (II), producing the vinyl ethers (III).
ChemInform Abstract: Synthesis and Inhibitory Activity of Bromoquinone Derivatives.
Authors: GU L. , LIU C. , XU J. , KING T. E. 
Published: May 2016

AbstractAccording to an earlier report, 2,5‐dibromo‐3‐methyl‐6‐isopropyl‐1,4‐benzoquinone has inhibitory activity against b6‐f and b‐c1 complexes.
ChemInform Abstract: Highly Selective Oxidative Cross‐Coupling of Substituted 2‐Naphthols: A Convenient Approach to Unsymmetrical 1,1′‐Binaphthalene‐2,2′‐diols.
Authors: HOVORKA M. , GUENTEROVA J. + , ZAVADA J. 
Published: May 2016

AbstractOxidative coupling of the hydroxynaphthalenecarboxylate (I) with the β‐naphthols (II) is induced by copper(II) ‐ amine complexes to give predominantly the unsymmetrical products (III).
ChemInform Abstract: Novel 1‐Substituted 2,3‐Dihydro‐1H‐isoindoles: Synthesis via Meyers′ Methodology.
Authors: BEELEY L. J. , ROCKELL C. J. M. 
Published: May 2016

Abstract2,3‐Dihydro‐1H‐isoindoline (I) reacts with the formamidine (II) to give the 2‐iminomethyl derivative (III).
ChemInform Abstract: (1,4) and (5,5) Thermal Sigmatropic Rearrangements of 2‐Pentadienyloxypyridine N‐Oxides.
Authors: ALKER D. , OLLIS W. D. , SHAHRIARI‐ZAVAREH H. 
Published: May 2016

AbstractThe product ratio of (IIa)/(IIIa) is greatly influenced by the solvent (in Cl2C=CCl2 95:5, in water 2:98).
ChemInform Abstract: Synthesis, Structure and Reactivity of Bis(N‐aryl‐iminophosphoranyl)methanes. X‐Ray Crystal Structures of (4‐CH3‐C6H4‐N=PPh2)2CH2 and (4‐NO2‐C6H4‐N=PMe2)2CH2.
Authors: IMHOFF P. , VAN ASSELT R. , ELSEVIER C. J. , VRIEZE K. , GOUBITZ K. , VAN MALSSEN K. F. , STAM C. H. 
Published: May 2016

AbstractThe methylene group of (IIIa) can be metalated by BuLi or NaH.
ChemInform Abstract: Preparation of Pentahalogeno‐methyl‐ and ‐phenylantimonates(V), Trihalogenomethylantimonates(III), and Tetrahalogenophenylstiboranes.
Authors: WIEBER M. , WALZ J. 
Published: May 2016

AbstractThe title compounds of the type (III), (V), (VII), and (XI) are obtained from the corresponding methyl‐ and phenyl‐antimony dihalides (I), (VI), and (VIII) by reaction with halide salts such as (II) and subsequent with SO2Cl2 (IV) or Br2, or corresponding one‐pot reactions according to the scheme.
ChemInform Abstract: Unexpected Cleavage of Acetylacetone Induced by Yttrium Oxoisopropoxide: Synthesis and Molecular Structure of Y2(μ2‐OAc)2(acac)4(H2O)2.
Authors: PONCELET O. , HUBERT‐PFALZGRAF L. G. , DARAN J.‐C. 
Published: May 2016

AbstractThe reaction between the yttrium derivative (I) and acetylacetone (II) proceeds with complete substitution of the isopropoxo groups.
ChemInform Abstract: Reaction of Ethoxytitanium Chlorides with N,N,N′‐Tris(trimethylsilyl)phosphenimidous Amide.
Authors: BRUSILOVETS A. I. 
Published: May 2016

AbstractReaction of the phosphenimidous amide (I) with the ethoxytitanium chlorides (II) gives the titanium chelates (III).
ChemInform Abstract: Pseudo‐Sugars. Part 26. Synthesis of Some Anhydro Derivatives of DL‐1‐C‐Hydroxymethyl‐1,2,3,4,5,6‐cyclohexanehexol.
Authors: OGAWA S. , URAKAWA M. , TONEGAWA T. 
Published: May 2016

AbstractThe synthesis of the three stereoisomeric title compounds (VIII), (IX) and (XI) is described.
ChemInform Abstract: Perchlorate Compounds of Tungsten(VI).
Authors: BABAEVA V. P. , ROSOLOVSKII V. YA. 
Published: May 2016

AbstractThe reaction between WCl6 (I) and HClO4 (II), conducted at ‐5 °C, yields WO(ClO4)4 (III) instead of W(ClO4)6.
ChemInform Abstract: Synthetic Aspects of an Asymmetric Nitrogen‐Insertion Process: Preparation of Chiral, Non‐Racemic Caprolactams and Valerolactams. Total Synthesis of (‐)‐Alloyohimbane.
Authors: AUBE J. , WANG Y. , HAMMOND M. , TANOL M. , TAKUSAGAWA F. , VANDER VELDE D. 
Published: May 2016

AbstractA general route to the synthesis of optically active lactams with use of an asym.
ChemInform Abstract: Base Hydrolysis of αβ‐Nitro‐, Azido‐ and Isothiocyanato‐(1,9‐bis(2′‐pyridyl)‐2,5,8‐triazanonane)‐ and (1,11‐Bis(2′‐Pyridyl)‐2,6,10‐triazaundecane)‐cobalt(III) Cations. Departure from First‐Order Hydroxide Dependence.
Authors: AHMED E. , TOBE M. L. , HUMANES M. 
Published: May 2016

AbstractThe rate law for the displacement of NO2 in (I) and NCS in (IIa) by OH in aqueous solution is found to depart from the usual first‐order dependence on (OH‐) at (OH‐) > 0.01 mol dm‐3. Reasons for this anomaly are discussed.
ChemInform Abstract: Cobalt Carbonyl‐Mediated Michael Addition: Direct Synthesis of Esters Containing Other Functional Groups from Activated Olefins.
Authors: SISAK A. , UNGVARY F. , MARKO L. 
Published: May 2016

AbstractThe cobalt‐catalyzed alkoxycarbonylation of acrylonitrile (I) with carbon monoxide (III) and the alcohols (II) produces the dicyanobutanoic acid derivatives (VI) as the main products.
ChemInform Abstract: Synthesis of 2‐Methylene‐1,3‐dioxygenated Cyclopentanes and Cyclopentenes.
Authors: CHANTARASIRI N. , DINPRASERT P. , THEBTARANONTH C. , THEBTARANONTH Y. , YENJAI C. 
Published: May 2016

AbstractOxidation of the spirocyclopentenones (I) with a peracid such as MCPBA and subsequent treatment of the intermediate epoxides with triethylamine yield a mixture of the spiroketols (II) and (III) which is oxidized with pyridinium dichromate, forming the spirocyclopentenediones (IV).
ChemInform Abstract: Synthesis and Cytotoxic Activity of 5(6)‐Amino‐2‐(5′(6′)‐benzimidazolyl)benzimidazoles.
Authors: SOKOLOVA N. YU. , KUZNETSOV V. A. , GARABADZHIU A. V. , GINZBURG L. F. , DOBRYNIN YA. V. , NIKOLAEVA T. G. , FIN'KO V. E. , IVANOVA T. P. 
Published: May 2016

Abstract4‐Dialkylamino‐substituted o‐phenylenediamines, prepared in situ from the diaminonitrobenzenes (I), react with the imidic acid ester hydrochlorides (II) to give the benzimidazoles (III).
ChemInform Abstract: The Synthesis and Structure of Chiral Di‐N‐(p‐toluenesulfonyl) Diazacoronands Derived from L‐Tartaric Acid.
Authors: JURCZAK J. , OSTASZEWSKI R. , ANDREETTI G. D. , CALESTANI G. 
Published: May 2016

AbstractIn a modified Richmann‐Atkins procedure, the chiral bistosylate (I) and the bissulfonamides (II) undergo cyclization reaction in the presence of a base to produce the chiral di‐N‐sulfonyl diazacoronands (III).
ChemInform Abstract: Nucleotide Base Recognition: Synthesis of Artificial Receptors Containing Two Distinct Binding Regions for the Complexation of Bisthymine Derivatives.
Authors: HAMILTON A. D. , LITTLE D. 
Published: May 2016

AbstractThe diacid chloride (I) is coupled with 4‐propargyloxy‐2,6‐diaminopyridine (II) under high dilution conditions to give the macrocyclic dicarboxamide (III).
ChemInform Abstract: An Improved Preparation of Enamines of Acylsilanes, a New Synthesis of Acylsilanes.
Authors: PICARD J. P. , AIZPURUA J. M. , ELYUSUFI A. , KOWALSKI P. 
Published: May 2016

AbstractThe use of HMPA as a solvent instead of the previously used THF allows the high yield synthesis of enamines of acylsilanes such as (III) from the cyanohydrins (I) by reductive silylation.
ChemInform Abstract: Cyclic Compounds Made of Phosphorus, Carbon, and Sulfur.
Authors: BRAUN R. , FLUCK E. 
Published: May 2016

AbstractReactions of P4S10 (II) with an excess of tert. amines such as (I) or tribenzylamine lead to corresponding ammonium salts (III) and (IV) of dithiadiphosphorinan disulfide compounds.
ChemInform Abstract: X‐Ray Crystallographic and NOE Studies on the Conformation of Periplanones and Their Analogues.
Authors: MORI M. , OKADA K. , SHIMAZAKI K. , CHUMAN T. , KUWAHARA S. , KITAHARA T. , MORI K. 
Published: May 2016

AbstractThe 1H NMR data of the periplanone analogues (III)‐(V) are given.
ChemInform Abstract: XPS and EXAFS Studies of the Reactions of Co(III) Ammine Complexes with GaAs Surfaces.
Authors: TUFTS B. J. , ABRAHAMS I. L. , CALEY C. E. , LUNT S. R. , MISKELLY G. M. , SAILOR M. J. , SANTANGELO P. G. , LEWIS N. S. , ROE A. L. , HODGSON K. O. 
Published: May 2016

AbstractThe chemisorption of Co(II) and Co(III) complexes onto GaAs surfaces is investigated by a combination of XPS, X‐ray absorption spectroscopy, and radiotracer techniques.
ChemInform Abstract: Homolytic Reactions of Ligated Boranes. Part 14. ESR Studies of Ring Opening of Cycloalkylaminyl‐Borane Radicals and Reactions of Aminyl‐Borane Radicals with Silicon‐Containing Compounds.
Authors: JOHNSON K. M. , KIRWAN J. N. , ROBERTS B. P. 
Published: May 2016

AbstractAminyl‐borane radicals (II) are generated photochemically from amine‐boranes such as (I) either in cyclopropane/oxirane or in tBuOH/tert.‐pentyl alcohol.
ChemInform Abstract: Copper(II)‐Mediated Aromatic Hydroxylation by Trimethylamine N‐Oxide.
Authors: REINAUD O. , CAPDEVIELLE P. , MAUMY M. 
Published: May 2016

AbstractTreatment of N‐benzoyl‐2‐methylalanine (I) with trimethylamine N‐oxide, copper powder (II), and oxygen leads to the formation of the cyclic copper(II) salt (III) which is subjected to acidic hydrolysis, producing N‐(2‐hydroxybenzoyl)‐2‐methylalanine (IV).
ChemInform Abstract: Synthesis, Acid‐Base, and Complexing Properties of 2‐Hydroxy‐N,N,N′,N′‐tetrakis(2‐aminoethyl)‐1,3‐diaminopropaneoctaacetic Acid.
Authors: YASHUNSKII V. G. , TIKHONOVA L. I. , SAMOILOVA O. I. , FOMINOVA O. S. , KHRYASHCHEVA L. A. , SMIRNOVA S. V. 
Published: May 2016

AbstractThe dichloropropanol (II) is coupled with N,N''‐dibenzylidenediethylenetriamine (I) to give the tetrakis(2‐aminoethyl)diaminopropane (III) after acidic work‐up.
ChemInform Abstract: Vinyl Ethers Containing an Epoxy Group. Part 20. Reaction of Epichlorohydrin with Dithiocarbamates.
Authors: NEDOLYA N. A. , DYMCHENKO V. I. , YANILKINA R. L. 
Published: May 2016

AbstractThe reaction of the dithiocarbamates (I) with epichlorohydrin (II) in molar proportions yields the thiiranyl esters (III); former results regarding (Ia) are revised.
ChemInform Abstract: Synthesis and Antiviral Activity of N‐Alkyl‐3‐cyano‐2‐pyridones and 3‐Cyano‐2‐alkoxypyridines.
Authors: KUL'NEVICH V. G. , KAIGORODOVA E. A. , ARUSTAMOVA I. S. , KOROBCHENKO L. V. , VLADYKO G. V. , BOREKO E. I. 
Published: May 2016

AbstractAlkylation of the pyridone (I) with the halides (II) gives the N‐substituted pyridones (III) and, from (I) and allyl chloride (IId), the allyloxypyridine (IVd).
ChemInform Abstract: C‐Pivot Lariat Ethers Bearing an Electron‐Donating Side Arm as Li+‐Selective Extractants.
Authors: WAKITA R. , YONETANI M. , NAKATSUJI Y. , OKAHARA M. 
Published: May 2016

AbstractIntramolecular bromoalkoxylation of the 2‐methylallyl ethers (I) with NBS in the presence of lithium tetrafluoroborate produces the corresponding bromomethyl crown ethers (II) which are coupled with the alcohols (III) to prepare the corresponding alkoxymethyl derivatives (IV).
ChemInform Abstract: The Preparation of Amide Derivatives of the 3‐Azabicyclo(3.3.1)nonanes as New Potential Antiarrhythmic Agents.
Authors: ZISMAN S. A. , BERLIN K. D. , SCHERLAG B. J. 
Published: May 2016

AbstractThe heterocyclic ketones (I) are α,α'‐bishydroxymethylated and then directly cyclized with benzylamine (III) to form the bicyclic amines (IV).
ChemInform Abstract: The Reaction of 3‐Borolenes with Terminal Acetylenes: A New Route to 2‐Borolenes.
Authors: HERBERICH G. E. , WANG S. 
Published: May 2016

AbstractA variety of 3‐substituted 4‐vinyl‐2‐borolenes such as (III) (10 examples) are regiospecifically obtained from the title reaction.
ChemInform Abstract: Regiochemistry of the Rearrangement of Cyclohexenyl and Cyclohexadienyl Phosphates to β‐Keto Phosphonates.
Authors: GLOER K. B. , CALOGEROPOULOU T. , JACKSON J. A. , WIEMER D. F. 
Published: May 2016

AbstractAddition of the dimethylcuprate (II) to the cyclohexenone and subsequent coupling with the phosphorochloridate (III) produces the vinylic phosphate (IV).
ChemInform Abstract: The Synthesis of DL‐1‐(Hexadecanoyloxy)methyl‐ and 1‐O‐Hexadecanoyl‐inositols as Potential Inhibitors of Phospholipase C.
Authors: MASSY D. J. R. , WYSS P. 
Published: May 2016

Abstractmyo‐Inositol phosphates are key mediators of cellular metabolism.
ChemInform Abstract: A New Combined Purification/Phosphorylation Procedure for Oligodeoxynucleotides.
Authors: BANNWARTH W. , WIPPLER J. 
Published: May 2016

AbstractThe phosphoramidite (I) is synthesized, which allows the introduction of a purification handle into synthetic oligodeoxynucleotides during their synthesis on a solid support and proves to be useful in a simple purification procedure for oligodeoxynucleotides.
ChemInform Abstract: Incipient Hydrous Oxide Species as Inhibitors of Reduction Processes at Noble Metal Electrode.
Authors: BURKE L. D. , O'SULLIVAN J. F. , O'DWYER K. J. , SCANNELL R. A. , AHERN M. J. G. , MCCARTHY M. M. 
Published: May 2016

AbstractThe study of Au and Pt electrodes in acid and base solutions containing IO3‐, S2O82‐, or N2H4 demonstrates the important role of hydrous oxide species in noble metal electrocatalysis.
ChemInform Abstract: Palladium‐Catalyzed Heteroannulation of 1,3‐Dienes by Functionally Substituted Aryl Halides.
Authors: LAROCK R. C. , BERRIOS‐PENA N. , NARAYANAN K. 
Published: May 2016

AbstractThe ortho‐hetero‐substituted phenyl iodides (I) undergo Pd‐catalyzed heteroannulation reaction with 1,3‐dienes such as (II) to form benzo‐fused heterocycles such as (III).
ChemInform Abstract: The Use of Pearlman′s Catalyst for Selective N‐Debenzylation in the Presence of Benzyl Ethers.
Authors: BERNOTAS R. C. , CUBE R. V. 
Published: May 2016

AbstractVarious N‐benzylamines, e.g. (I), (III), or (V), also containing O‐benzyl are selectively N‐deprotected by hydrogenolysis in the presence of palladium(II) hydroxide on carbon.
ChemInform Abstract: Asymmetric Synthesis of Arylglycines.
Authors: WILLIAMS R. M. , HENDRIX J. A. 
Published: May 2016

AbstractThe coupling of the chiral diphenyloxazinone (I) with the cuprate reagent derived from lithiated benzenes such as (II) and copper bromide ‐dimethyl sulfide yields stereoselectively the arylated derivative (III) which after N‐deprotection and ring cleavage gives the desired D‐phenylglycine (V).