bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: The Synthesis and Characterization of Some New Thioether‐Imidazole Containing Ligands.
Authors: BOUWMAN E. , DRIESSEN W. L. 
Published: May 2016

AbstractThe hydroxymethylimidazole (I) is coupled with the thiols (II) or the dithiol (IV), producing the imidazolylmethyl thioethers (III) or (V).
ChemInform Abstract: Organic Syntheses via Transition Metal Complexes. Part 32. Ketenimine Manganese Complexes. ‐ 1,3‐Dipolaroid CCN Building Blocks for the Synthesis of Five‐Membered N‐Heterocycles C‐C‐N‐C‐X (X: O, S, NR).
Authors: AUMANN R. , HEINEN H. 
Published: May 2016

AbstractThe aminocarbene manganese complexes (IV) are obtained by three‐component reaction of the C1, C≡N and C=X building blocks (I), (II) and (III).
ChemInform Abstract: Thermal Dimerization of 2‐Hydroxychromanones to 1‐(2‐Hydroxybenzoyl)‐2‐(4‐oxo‐4H‐1‐benzopyran‐3‐yl)ethylene Derivatives. An Unusual Observation.
Authors: SONI R. R. , TRIVEDI K. N. 
Published: May 2016

AbstractThe hydroxychromanones (III), when heated above their melting points, undergo dimerization to give the products (IV).
ChemInform Abstract: Enolates of Diacetylresorcinols: Application to Synthesis of Benzodipyrans.
Authors: BANERJI A. , GOOMER N. C. , KALENA G. P. 
Published: May 2016

AbstractTreatment of the enolate of the resorcinol (I) with acetone (II) and benzoyl chloride (VII), resp., and subsequent work‐up of the condensation products leads to the benzodipyrans (IV) and (VIII).
ChemInform Abstract: Claisen Rearrangement of Some 7‐Cinnamyloxychromones.
Authors: JAIN A. C. , GUPTA R. K. , CHAWLA C. 
Published: May 2016

AbstractUnder the relatively mild conditions A) the chromones (I) and (III) undergo Claisen rearrangement to give the desired normal products (II) and (IV).
ChemInform Abstract: An N → N′‐Benzyl Migration During the Formation of Some (Trifluoromethyl)imidazo(4,5‐h)quinolines.
Authors: MOORES I. G. , SCRIVEN E. F. V. , SMALLEY R. K. 
Published: May 2016

AbstractThe 7‐amino‐8‐alkylaminoquinolines (VI) are synthesized via a Skraup reaction or photolysis of the azide (VII).
ChemInform Abstract: Condensed Heterocycles Containing the Pyrimidine Nucleus.
Authors: SANTAGATI A. , SANTAGATI M. , RUSSO F. , RONSISVALLE G. 
Published: May 2016

AbstractThe 2‐aminothiadiazoles (I) react with ethyl cyanoacetate (II) to give the new thiadiazolopyrimidinones (III).
ChemInform Abstract: Boron Compounds. Part 84. Nitrogen Base Adducts of Tetraorganodiboroxanes.
Authors: YALPANI M. , SERWATOWSKI J. , KOESTER R. + 
Published: May 2016

AbstractThe tetraorganodiboroxanes (I) and (II) react with N‐bases (substituted pyridines) to form 1:1 adducts as demonstrated for (IV).
ChemInform Abstract: Organometalloidal Derivatives of the Transition Metals. Part 18. Transition‐Metal‐Substituted Silanes. Hydrosilylation of Phenylacetylene Using ((η5‐C5H5)Fe(CO)2SiPh2H) and ((η5‐C5H4SiPh2H)Fe(CO)2R) (R: Me, SiMe3).
Authors: PANNELL K. H. , ROZELL J. M. , LII J. , TIEN‐MAYR S.‐Y. 
Published: May 2016

AbstractThe first title complex (III) is prepared and converted into the second ones (V) according to the scheme.
ChemInform Abstract: Cobalt(III) Complexes with N‐Methylethane‐1,2‐diamine(meen). Synthesis and Characterization of the Isomers of (Co(meen)3)3+, (Co(meen)2(en))3+ and (Co(meen)(en)2)3+.
Authors: SEARLE G. H. , KEENE F. R. 
Published: May 2016

AbstractThere are twelve geometric isomer‐diastereoisomer possibilities for the tris‐ligand complex.
ChemInform Abstract: Copper(II) Complexes with 2,2′‐Biimidazole. Preparation and Crystal Structure Determination of a Complex of Stoichiometry Cu1.5Cl3(H2bim)2 (H2bim: 2,2′‐biimidazole).
Authors: BENCINI A. , MANI F. 
Published: May 2016

AbstractThe 1:2 molar reaction of hydrated CuCl2 and 2,2'‐biimidazole in aqueous HCl gives in addition to the polymeric main product (I) a crystalline by‐product of the stoichiometry Cu1.5Cl3(H2bim)2.
ChemInform Abstract: Heterocyclic Compounds Series. Part 132. Metallocyclic Complexes of Palladium(II) and Platinum(II) Containing Six‐ and Seven‐Membered Chelate Rings.
Authors: NEWKOME G. R. , EVANS D. W. , KIEFER G. E. , THERIOT K. J. 
Published: May 2016

AbstractThe syntheses of the new cyclometalated Pd(II) and Pt(II) complexes (III) and (X) with ligands containing either bipyridine or the corresponding one or two C‐bridged species are described.
ChemInform Abstract: Polynuclear Platinum Complexes Deriving from Squaric Acid.
Authors: SOULES R. , MOSSET A. , LAURENT J.‐P. , CASTAN P. , BERNARDINELLI G. , DELAMAR M. 
Published: May 2016

AbstractThe squaric acid H2L reacts with the cis‐dichlorodiammine‐Pt(II) hydrolysis products to give two isolable complexes.
ChemInform Abstract: Intramolecular Alkylations of Aromatic Compounds. Part 22. Synthesis of cis‐1,6,10‐Trimethyl‐1,2,3,4,5,6,7,8,9,10‐decahydroindolo(4,3‐fg)quinoline, a New Approach to the Ergoline Framework.
Authors: REIMANN E. , HARGASSER E. 
Published: May 2016

AbstractThe synthesis of the ergoline derivative (IX) is shown in the reaction scheme.
ChemInform Abstract: A New Regiospecific Synthesis of “Branched” Tetraribonucleotide and Its Three Analogues to Delineate the Chemospecific Role of the “Branch‐Point” Adenine Nucleotide in Splicing.
Authors: BALGOBIN N. , FOELDESI A. + , REMAUD G. , CHATTOPADHYAYA J. 
Published: May 2016

AbstractThe title nucleotide (Va) and its three derivatives (Vb)‐(Vd) are prepared by analogous routes as shown in the scheme.
ChemInform Abstract: A Facile Synthesis of α‐Methyldeoxybenzoins Including Racemates of Natural Angolensin, 2‐O‐Methylangolensin and 4‐O‐Methylangolensin.
Authors: JAIN A. C. , PALIWAL P. 
Published: May 2016

AbstractReaction of the compound (I) under conditions A), which are found to be the best method for the α‐C‐methylation of deoxybenzoins, gives racemic 4‐O‐methylangolensin (II).
ChemInform Abstract: Halide Promotion of the Formation and Carbonylation of μ3‐Imido Ligands. Relevance to the Halide Promotion of Nitroaromatic Carbonylation Catalysis
Authors: HAN S. H. , GEOFFROY G. L. 
Published: May 2016

AbstractReview: (The Chemistry of Heteronuclear Clusters and Multimetallic Catalysts; Proceedings in the Seminar in Koenigstein, Sept.
ChemInform Abstract: Novel Catalytic Applications of Anionic Ruthenium Clusters in Isocyanate Chemistry
Authors: SUESS‐FINK G. + , HERRMANN G. , SCHMIDT G. F. 
Published: May 2016

AbstractReview: (The Chemistry of Heteronuclear Clusters and Multimetallic Catalysts; Proceedings of the Seminar in Koenigstein, Sept.
ChemInform Abstract: Synthesis, Vibrational Spectroscopy, and Crystal and Molecular Structure of (H3NCH2CH2NH3) (PdBr6).
Authors: CLARK R. J. H. , CROUD V. B. , DAWES H. M. , HURSTHOUSE M. B. 
Published: May 2016

AbstractThe crystals of the title complex belong to the space group Pnnm with Z=2.
ChemInform Abstract: Crystal Structure of the BiZr3F15 Phase.
Authors: CAIGNOL E. , METIN J. , CHEVALIER R. , COUSSEINS J. C. , AVIGNANT D. 
Published: May 2016

AbstractSingle crystals of the title compound are obtained by heating a stoichiometric BiF3/ZrF4 mixture at 500 °C in a sealed Pt‐tube.
ChemInform Abstract: Lithium Perchlorate Ammoniate Ionic Liquid, LiClO4·4 NH3. Densities, Viscosities, Electrical Conductivities, and Raman Spectra.
Authors: FAHYS B. , HERLEM M. , DAHER J. , ROBERT G. 
Published: May 2016

AbstractRaman spectra and NH3 vapor pressure measurements indicate that LiClO4·4 NH3 is stable for use as electrolyte in Li batteries below 80 °C. Density, viscosity, and conductivity data are reported for the temp. range 10‐80 °C. In this temp. range, the activation energy of ion transport remains mainly constant at 0.26 eV.
ChemInform Abstract: Electrochemistry of Osmium(III) and ‐(IV) Chloride Complexes in the Basic Aluminum Chloride‐1‐methyl‐3‐ethylimidazolium Chloride Ionic Liquid
Authors: SUN I‐W. , WARD E. H. , HUSSEY C. L. 
Published: May 2016

Abstract(AlCl3‐MeEtimCl).
ChemInform Abstract: Rechargeable Electrodes from Sodium Cobalt Bronzes.
Authors: SHACKLETTE L. W. , JOW T. R. , TOWNSEND L. 
Published: May 2016

AbstractFour different phases of the NaxCoO2 bronze are prepared by annealing mixtures of Co3O4 and Na2O2: O3, O'3, P3 (0.5 < x < 1; 400‐600 °C), and P2 (0.5 < x ≤ 0.7; > 650 °C); in this nomenclature, O and P represent octahedral or trigonal prismatic coordination of Na+ and 3 or 2 represents the number of distinguishable sodium layers.
ChemInform Abstract: Influence of the Mode of Preparation of LaCoO3 Doped with Altervalent Ions on Some of Its Physicochemical and Catalytic Properties.
Authors: WACHOWSKI L. 
Published: May 2016

AbstractSamples of the perovskite‐type oxides La0.85M0.15CoO3 with M: Ca, Sr, Ba, or Ce are prepared by ceramic, coprecipitation, freeze‐drying, and explosion methods.
ChemInform Abstract: Solution Chemistry of the Cuboidal Mixed‐Valence (3.25) Molybdenum/Sulfido Cluster (Mo4S4(H2O)12)5+.
Authors: OOI B.‐L. , SHARP C. , SYKES A. G. 
Published: May 2016

AbstractThe green aqua ion (I) (Mo4S45+) is remarkably stable over a wide (H+) range, 0.01‐4.0 M, when stored O2‐free.
ChemInform Abstract: The System CsF/CuF2: On Cs7Cu6F19.
Authors: KISSEL D. , HOPPE R. 
Published: May 2016

AbstractThe new moisture sensitive fluorocuprate(II), prepared as pale blue single crystals from CsF and CuF2 by annealing in a Au tube under argon (720 °C, 4 weeks; 760 °C, 12 weeks), crystallizes in the monoclinic space group P21/c with Z=2.
ChemInform Abstract: Sulfonic Acid Induced Fragmentation of Dialkyl Acylphosphonates. Formation of Alkyl Carboxylates and Alkyl Sulfonates.
Authors: BREUER E. , KARAMAN R. , GOLDBLUM A. , LEADER H. 
Published: May 2016

AbstractThe reaction of acylphosphonates (I) (and dibutyl acetylphosphonate) with TosOH (II) and some related reactions are studied under various reaction conditions to elucidate the mechanism.
ChemInform Abstract: Preparative Visible‐Laser Photochemistry: Qinghaosu‐Type 1,2,4‐Trioxanes by Molecular Oxygen Trapping of Paterno‐Buechi Triplet 1,4‐Diradicals Derived from 3,4‐Dihydro‐4,4‐dimethyl‐2H‐pyran‐2‐one and Quinones.
Authors: ADAM W. , KLIEM U. , MOSANDL T. , PETERS E.‐M. , PETERS K. , VON SCHNERING H. G. 
Published: May 2016

AbstractLaser irradiation of the dihydrodimethylpyranone (I) with p‐benzoquinone (II) gives the cycloadduct (III) as the main product.
ChemInform Abstract: Conversion of Methanol to Hydrocarbons. Part 3. Methylation, Ethylation, and Propylation of Benzene with Methanol.
Authors: KAEDING W. W. 
Published: May 2016

AbstractThe selectivity of the title reaction on HZSM‐5 (SiO2/Al2O3 = 70:1) is shown in the scheme for mild conditions.
ChemInform Abstract: Palladium(0)‐Catalyzed Carbonylation of Allyl Phosphates and Allyl Acetates. Selective Synthesis of β,γ‐Unsaturated Esters.
Authors: MURAHASHI S. , IMADA Y. , TANIGUCHI Y. , HIGASHIURA S. 
Published: May 2016

AbstractThe allylic phosphates (I), (V), (VII), and acetates (IX), (X), and (XII) are carbonylated in the presence of ethanol (III) and a Pd(0) catalyst, yielding the carboxylates (IV), (VI), (VIII), (XI), or (XIII).
ChemInform Abstract: Synthesis of Nitro Derivatives of (4)Peristylane Having High‐Density Characteristics.
Authors: WAYKOLE L. M. , SHEN C.‐C. , PAQUETTE L. A. 
Published: May 2016

AbstractTreatment of the peristylanedione dioxime (I) with m‐chloroperbenzoic acid results in ring closure and oxidation, producing the dinitro compound (II).
ChemInform Abstract: A Facile One‐Pot Synthesis of Vicinal Di‐ and Triketones from α‐Methylene Ketones by N‐Bromosuccinimide‐Dimethyl Sulfoxide Oxidation.
Authors: TATSUGI J. , IZAWA Y. 
Published: May 2016

AbstractThe title vicinal diketones, e.g. (II), (VII) and (IX) are useful synthons in heterocyclic chemistry.
ChemInform Abstract: 1,2‐Bis(organylideniminoxy)ethanes from Ketoximes and 1,2‐Dichloroethane.
Authors: KOROSTOVA S. E. , SOBENINA L. N. , MIKHALEVA A. I. , NESTERENKO R. N. , SHEVCHENKO S. G. , MODONOV V. B. , POLOVNIKOVA R. I. 
Published: May 2016

AbstractIn the presence of KOH‐DMSO the reaction between the ketoximes (I) and 1,2‐dichloroethane (II) affords the title compounds (III) in 17‐78% yields (15 examples).
ChemInform Abstract: Fluorinated Chalcones. Part 1. Synthesis of α,β‐Difluorochalcones.
Authors: YARMOLENKO S. N. , FIALKOV YU. A. , KREMLEV M. M. , YAGUPOL'SKII L. M. 
Published: May 2016

AbstractThe α,β‐difluoro‐β‐chlorostyrenes (I) are converted to lithium derivatives which react in situ with the N,N‐dimethylbenzamides (II) to yield the trans‐configurated title compounds (III) (11 examples).
ChemInform Abstract: The Stereospecific Cyclization of a threo‐α‐Benzamide Alcohol to a cis‐N‐Acylaziridine.
Authors: BOSCHELLI D. H. 
Published: May 2016

AbstractWhen the erythro‐α‐benzamido alcohol (IVa) is treated with triphenylphosphine and diethyl azodicarboxylate, a mixture of the oxazoline (V) and the aziridine (VI) is obtained.
ChemInform Abstract: Synthesis of Pyrrolo(1,2‐b)cinnolines.
Authors: HAMER R. R. L. , SEKERAK D. , EFFLAND R. C. , KLEIN J. T. 
Published: May 2016

AbstractThe N‐pyrrolyl carbamates (I) cyclize in an alkaline medium to give the pyrrolocinnolines (II).
ChemInform Abstract: Reaction of 5‐Allyl‐5‐isobutylbarbituric Acid with Electrophilic Reagents.
Authors: CURVELO A. A. S. , DE AMARAL L. 
Published: May 2016

AbstractThe barbituric acid (I) mentioned in the title is treated with the halogens (II) in aqueous sodium hydroxide solution or in chloroform, producing the halohydrins (III) and/or the dibromides (IV).
ChemInform Abstract: New Synthetic Methodology for the Preparation of Substituted 1‐Aryl‐1‐pyridylaminomethanephosphonic Acid Esters.
Authors: BURKHOUSE D. W. , ZIMMER H. 
Published: May 2016

AbstractThe title compounds, e.g. (V), (VIII), and (X), are prepared from the aminopyridines (I) and benzaldehydes such as (II) or (VI) by three different methods: the imines (III) are treated with diphenyl phosphite (IV) to give (V).
ChemInform Abstract: The Case Favoring Direct C‐Alkylation of Heteroatom Substituted Enolates.
Authors: SOLOMON M. , HOEKSTRA W. , ZIMA G. , LIOTTA D. 
Published: May 2016

AbstractLithium dimethylcuprate (II) reacts with the benzylselenenylcyclopentenone (I) to give an enolate which undergoes direct C‐alkylation with the halides (III), producing a mixture of the isomeric cyclopentanones (IV) and (V).
ChemInform Abstract: Vanadium Complexes of the Tridentate Schiff Base Ligand N‐Salicylidene‐N′‐(2‐hydroxyethyl)ethylenediamine: Acid‐Base and Redox Conversion Between Vanadium(IV) and Vanadium(V) Imino Phenolates.
Authors: LI X. , LAH M. S. , PECORARO V. L. 
Published: May 2016

AbstractThe reaction of vanadyl sulfate or vanadyl acetylacetonate with the title ligand affords a variety of V(IV) and V(V) complexes depending on the reaction conditions.
ChemInform Abstract: Spectroscopic and Electrical Properties of VO(dmit)2 and V(dmit)3 Anion Complexes and X‐Ray Crystal Structure of (NMP)2(V(dmit)3) (dmit: 2‐Thioxo‐1,3‐dithiole‐4,5‐dithiolate, NMP: N‐Methylphenazinium).
Authors: MATSUBAYASHI G. , AKIBA K. , TANAKA T. 
Published: May 2016

AbstractThe V(IV) dithiolate anion complexes (III) and (VI) are prepared as shown in the scheme.
ChemInform Abstract: Synthetic and Structural Studies on Organomolybdenum and Organotungsten Complexes Containing Bismuth. X‐Ray Crystal Structures of (BiCl(Mo(CO)3(η‐C5H5))2) and (BiCl(Mo(CO)2(CNtBu)(η‐C5H5))2).
Authors: CLEGG W. , COMPTON N. A. , ERRINGTON R. J. , NORMAN N. C. , TUCKER A. J. , WINTER M. J. 
Published: May 2016

AbstractThe reaction between BiCl3 (I) and Na((η5‐C5H5)Mo(CO)3) (II) results in the formation of the tri‐ and dimolybdenum‐bismuth complexes (III) and (IV) depending on the stoichiometry.
ChemInform Abstract: Dinuclear Allyl and μ‐Vinyl Complexes from the Reactions of a μ‐Hydrido Dimanganese and a μ‐Hydrido Manganese‐Molybdenum Complex with Alkynes Containing α‐Methyl or α‐Methylene Substituents.
Authors: HORTON A. D. , KEMBALL A. C. , MAYS M. J. 
Published: May 2016

AbstractThe photolytic reaction of the Mn complex (I) with 1‐propyne (II) gives an inseparable isomeric mixture of (IIIa) and (IIIb) together with the allyl complex (IVa).
ChemInform Abstract: Synthesis and Coordination Chemistry of Two Pentaazamacrocycles Containing a 1,4‐Piperazine Backbone. Crystal Structure Determinations of 6,12‐Dioxo‐1,5,13,17,22‐pentaazatricyclo(15.2.2.17,11)docosa‐7(22),8,10‐triene and 1,5,13,17,22‐Pentaazatricyclo(15.2.2.17,11)docosa‐7(22),8,10‐trienenickel(II) Perchlorate.
Authors: ALCOCK N. W. , MOORE P. , READER C. J. , ROE S. M. 
Published: May 2016

AbstractThe macrocycle (Ia) is prepared by a modification of a published method under high dilution conditions and crystallizes in P21/n with Z=4.
ChemInform Abstract: Dicopper(II) Complexes of a Binucleating N4 Macrocycle Containing Mono‐ and Diatomic Bridges; Magnetic Interactions Mediated by Alkoxo‐ and Diaza‐Bridging Ligands. Crystal Structures of (Cu2(L1)(pz)2) (ClO4)2, (Cu2(L1)(OEt)2(NCS)2), and (Cu2(L1)(OMe)2(MeCN)2) (BPh4)2.
Authors: DREW M. G. B. , YATES P. C. , ESHO F. S. , TROCHA‐GRIMSHAW J. , LAVERY A. , MCKILLOP K. P. , NELSON S. M. , NELSON J. 
Published: May 2016

Abstract(Ia), obtained by a known method via transmetalation of the Ba complex of the macrocyclic ligand, forms the pyrazolate‐bridged complex (III) (P21/c, Z=4) and reacts with 3,5‐dimethylpyrazole or 1,2,4‐triazole to give the same type of complexes (65‐70% yield).
ChemInform Abstract: Synthesis, Characterization, and Oxidation Catalysis by a Novel (μ3‐Oxo)triruthenium Carboxylate Complex.
Authors: DAVIS S. , DRAGO R. S. 
Published: May 2016

AbstractThe first (μ3‐oxo)triruthenium carboxylate complex (V) containing completely fluorinated carboxylate ligands is obtained according to the scheme and characterized spectroscopically (UV/VIS, FTIR, FAB‐MS, 19F NMR).
ChemInform Abstract: Organopalladium Approaches to Prostaglandins. Part 9. Synthesis of a Prostaglandin Endoperoxide Analogue by Allylpalladation‐Ozonolysis of Norbornene.
Authors: LAROCK R. C. , NARAYANAN K. 
Published: May 2016

AbstractThe title compound (VIII) with cis configuration of the 5,6‐double bond, characteristic of naturally occurring prostaglandins, is prepared.
ChemInform Abstract: X‐Ray Diffraction Study of Molten Eutectic LiF‐NaF‐KF Mixture.
Authors: IGARASHI K. , OKAMOTO Y. , MOCHINAGA J. , OHNO H. 
Published: May 2016

AbstractThe short‐range structures of molten eutectic LiF‐NaF‐KF (46.5, 11.5, and 42.0 mol%, resp.) at 520 °C are investigated using the radial‐distribution function based on X‐ray scattering data.
ChemInform Abstract: A New Form of the High‐Temperature Isopiestic Technique and Its Application to Mercury‐Bismuth, Mercury‐Cadmium, Mercury‐Gallium, Mercury‐Indium and Mercury‐Tin Binary Amalgams.
Authors: WANG Z.‐C. , ZHANG X.‐H. , HE Y.‐Z. , BAO Y.‐H. 
Published: May 2016

AbstractIt is demonstrated that the developed form of the high‐temp.
ChemInform Abstract: The Active Dissolution of Iron‐Metalloid Metallic Glasses.
Authors: MOFFAT T. P. , FLANAGAN W. F. , LICHTER B. D. 
Published: May 2016

AbstractThe corrosion rates of iron, rapidly quenched Fe80B20 (I), Fe80P20 (II), and Fe80P13C7 (III) are measured in HCl/NaCl and H2SO4/Na2SO4 solutions.
ChemInform Abstract: Preparation and Crystallographic Study of a Cyclotriphosphate Series: LnNa3(P3O9)2·9 H2O with Ln: Sm, Eu, Gd, Dy, Ho, Er, and Y.
Authors: BAGIEU‐BEUCHER M. 
Published: May 2016

AbstractThe double cyclotriphosphates, mentioned in the title, are obtained by crystallization from aqueous solutions of LnCl3·6 H2O and Na3P3O9 at 20 °C. All of the seven compounds are isotypic with the corresponding Bi salt (R3c, Z=18 in the hexagonal and Z = 6 in the rhombohedral description).
ChemInform Abstract: An Investigation of Halide Abstraction by Arsenic(III): Reactions of AsCl3 with MCl2 (M: Mg or Zn) and TiCl4 in Donor Solvents (MeCN or POCl3). Formation and Crystal Structure of the Dimeric Titanium(IV) Compound (Ti2Cl6(POCl3)2(PO2Cl2)2).
Authors: CLAIRE P. P. K. , WILLEY G. R. , DREW M. G. B. 
Published: May 2016

AbstractThe reactions of TiCl4, MgCl2, and ZnCl2 with AsCl3 in MeCN do not result in the expected halide abstraction but yields the simple adducts TiCl4L2 and MCl2L2 (M: Mg, Zn; L: MeCN).
ChemInform Abstract: Lattice‐Engineered Micromodulation of Intramolecular Electron‐Transfer Rates in Trinuclear Mixed‐Valence Iron Acetate Complexes.
Authors: JANG H. G. , GEIB S. J. , KANEKO Y. , NAKANO M. , SORAI M. , RHEINGOLD A. L. , MONTEZ B. , HENDRICKSON D. N. 
Published: May 2016

AbstractThe mixed‐valence complexes (Ib) and (Ic) are prepared by substitution of H2O in (Ia) with other neutral ligands and isolated as monosolvates of CHCl3, MeCCl3, MeCHCl2 and C6H6 (69% yield) in the case of (Ib) and of CHCl3 and Py in the case of (Ic) via recrystallizations (only one yield given).
ChemInform Abstract: 1,3‐Bis(2,5,8,11‐tetraazaundecyl)benzene (MXTRIEN): Synthesis, Binucleating Chelating Tendencies, and Formation and Thermal Degradation of Its Cobalt Dioxygen Complex.
Authors: MENIF R. , MARTELL A. E. 
Published: May 2016

AbstractThe title ligand (III) is prepared as shown in the scheme.
ChemInform Abstract: Ferric Ion Sequestering Agents. Part 20. 2,3‐Dihydroxyterephthalamides: Highly Efficient Iron(III)‐Chelating Agents.
Authors: GARRETT T. M. , MILLER P. W. , RAYMOND K. N. 
Published: May 2016

AbstractThe preparation of the new ligands (IV) and (VII) by two different routes is shown in the scheme.
ChemInform Abstract: Influence of Crown Ethers and Cryptands on the Kinetic Isotope Effects of Elimination Reactions of Some 1,1,1‐Trichloro‐2,2‐diarylethanes with Alkoxide Bases.
Authors: SCHROEDER G. 
Published: May 2016

AbstractThe addition of crown ethers and cryptands such as 18‐crown‐6 and (2.2.2)‐cryptand in equimolar amounts increases the rate of dehydrochlorination of (I) more than 2000 times due to the transformation of the base from the ion pair (tBuO‐, K+) into free tBuO‐ ions.
ChemInform Abstract: Dynamic Behavior of Photoexcited Solutions of 4‐Nitroveratrole Containing OH‐ or Amines.
Authors: VAN EIJK A. M. J. , HUIZER A. H. , VARMA C. A. G. O. , MARQUET J. 
Published: May 2016

AbstractThe nitroveratrole (II) is shown to react in its lowest triplet state with OH‐ ions to give exclusively the substitution product (I).
ChemInform Abstract: Regioselective Ring Opening Reactions of 1‐Aminocyclopropenes via Carbenium Ion and Carbene Intermediates.
Authors: YOSHIDA H. , SANO H. , OGATA T. , MATSUMOTO K. 
Published: May 2016

AbstractThe reaction of cyclopropenium salt (I) with PhMgBr (II) affords regioselectively the aminocyclopropane (IIIa).
ChemInform Abstract: Synthesis of (Z)‐Predominant α,β‐Unsaturated Nitriles from Enone Cyanohydrin Diethyl Phosphates: Application to the Synthesis of (.+‐.)‐Nuciferal, (.+‐.)‐(E)‐ and ‐(Z)‐Nuciferol, and (.+‐.)‐Manicone.
Authors: YONEDA R. , HARUSAWA S. , KURIHARA T. 
Published: May 2016

AbstractThe reaction of enone cyano phosphates, e.g. (I) and (IV), with a variety of organocopper reagents, e.g. (II) and (V), gives regio‐ and stereoselectively E/Z mixtures of the corresponding γ‐alkylation products, i.e. alk‐2‐enenitriles, with the Z isomer predominating in all cases.
ChemInform Abstract: Synthesis of Homoallylic Alcohols via Palladium‐Catalyzed Coupling of Organomercurials and Vinylic Oxetanes.
Authors: LAROCK R. C. , STOLZ‐DUNN S. K. 
Published: May 2016

AbstractThe arylmercuric chlorides (I) react with the 2‐vinyloxetanes (II) in the presence of a Pd(II) catalyst under cleavage, yielding the homoallylic alcohols (III).
ChemInform Abstract: Intramolecular Free Radical Cyclization of α‐Anilinoalkenenitriles.
Authors: FANG J.‐M. , CHANG H.‐T. , LIN C.‐C. 
Published: May 2016

AbstractCroton‐ and cinnamaldehyde (I) react with N‐methylaniline hydrochloride (II) and potassium cyanide (III) to give the α‐aminoalkenenitriles (IV) which are alkylated with the dihalides (V), producing the haloalkylalkenes (VI).
ChemInform Abstract: Convenient Synthesis of Chiral Pyranones from Carbohydrates.
Authors: DE FINA G. M. , VARELA O. , DE LEDERKREMER R. M. 
Published: May 2016

AbstractThe stereoisomeric acyloxyglycals (I) and (V) react with alcohols, e.g. isopropanol (II), in the presence of tin(IV) chloride to give the chiral pyranones (III), together with the furan derivatives (IV).