bluuebunny/crossref_metadata_2025_split huggingface dataset:
NMR Hyperpolarization Techniques of Gases
Authors: Barskiy Danila A. , Coffey Aaron M. , Nikolaou Panayiotis , Mikhaylov Dmitry M. , Goodson Boyd M. , Branca Rosa T. , Lu George J. , Shapiro Mikhail G. , Telkki Ville‐Veikko , Zhivonitko Vladimir V. , Koptyug Igor V. , Salnikov Oleg G. , Kovtunov Kirill V. , Bukhtiyarov Valerii I. , Rosen Matthew S. , Barlow Michael J. , Safavi Shahideh , Hall Ian P. , Schröder Leif , Chekmenev Eduard Y. 
Published: October 2016

AbstractNuclear spin polarization can be significantly increased through the process of hyperpolarization, leading to an increase in the sensitivity of nuclear magnetic resonance (NMR) experiments by 4–8 orders of magnitude. Hyperpolarized gases, unlike liquids and solids, can often be readily separated and purified from the compounds used to mediate the hyperpolarization processes. These pure hyperpolarized gases enabled many novel MRI applications including the visualization of void spaces, imaging of lung function, and remote detection. Additionally, hyperpolarized gases can be dissolved in liquids and can be used as sensitive molecular probes and reporters. This Minireview covers the fundamentals of the preparation of hyperpolarized gases and focuses on selected applications of interest to biomedicine and materials science.
Amine Catalysis for the Organocatalytic Diboration of Challenging Alkenes
Authors: Farre Albert , Soares Kaline , Briggs Rachel A. , Balanta Angelica , Benoit David M. , Bonet Amadeu 
Published: October 2016

AbstractThe generation of in situ sp2–sp3 diboron adducts has revolutionised the synthesis of organoboranes. Organocatalytic diboration reactions have represented a milestone in terms of unpredictable reactivity of these adducts. However, current methodologies have limitations in terms of substrate scope, selectivity and functional group tolerance. Here a new methodology based on the use of simple amines as catalyst is reported. This methodology provides a completely selective transformation overcoming current substrate scope and functional/protecting group limitations. Mechanistic studies have been included in this report.
Supra‐dendron Gelator Based on Azobenzene–Cyclodextrin Host–Guest Interactions: Photoswitched Optical and Chiroptical Reversibility
Authors: Xie Fan , Ouyang Guanghui , Qin Long , Liu Minghua 
Published: October 2016

AbstractA novel amphiphilic dendron (AZOC8GAc) with three l‐glutamic acid units and an azobenzene moiety covalently linked by an alkyl spacer has been designed. The compound formed hydrogels with water at very low concentration and self‐assembled into chiral‐twist structures. The gel showed a reversible macroscopic volume phase transition in response to pH variations and photo‐irradiation. During the photo‐triggered changes, although the gel showed complete reversibility in its optical absorptions, only an incomplete chiroptical property change was achieved. On the other hand, the dendron could form a 1:1 inclusion complex through a host–guest interaction with α‐cyclodextrin (α‐CD), designated as supra‐dendron gelator AZOC8GAc/α‐CD. The supra‐dendron showed similar gelation behavior to that of AZOC8GAc, but with enhanced photoisomerization‐transition efficiency and chiroptical switching capacity, which was completely reversible in terms of both optical and chiroptical performances. The self‐assembly of the supra‐dendron is a hierarchical or multi‐supramolecular self‐assembling process. This work has clearly illustrated that the hierarchical and multi‐supramolecular self‐assembling system endows the supramolecular nanostructures or materials with superior reversible optical and chiroptical switching.
Metal–Metal Single Bonds with the Magnetic Anisotropy of Quadruple Bonds: A Systematic Series of Heterobimetallic Bismuth(II)–Rhodium(II) Formamidinate Complexes
Authors: Sunderland Travis L. , Berry John F. 
Published: October 2016

AbstractThe first set of five heterobimetallic MM′(form)4 (form=formamidinate) complexes containing a BiRh core has been successfully synthesized. The Bi−Rh bond lengths lie between 2.5196(6) and 2.572(2) Å, consistent with Bi−Rh single bonds. All complexes have rich electrochemistry, with the [BiRh]4+/5+ redox couples spanning approximately 700 mV and showing a strong correlation to remote ligand substitution. Visible spectroscopy showed two features for complexes 1–5 at approximately 459 and 551 nm, unique to BiRh paddlewheel complexes that are attributed to LMCT bands into the Bi−Rh σ* orbital. The large spin–orbit coupling (SOC) of Bi creates a massive Bi−Rh magnetic anisotropy, Δχ, approximately −4800×10−36 m3molecule−1, which is the largest value reported for any single bond to date.
Structurally Divergent Lithium Catalyzed Friedel–Crafts Reactions on Oxetan‐3‐ols: Synthesis of 3,3‐Diaryloxetanes and 2,3‐Dihydrobenzofurans
Authors: Croft Rosemary A. , Mousseau James J. , Choi Chulho , Bull James A. 
Published: October 2016

AbstractThe first examples of 3,3‐diaryloxetanes are prepared in a lithium‐catalyzed and substrate dependent divergent Friedel–Crafts reaction. para‐Selective Friedel–Crafts reactions of phenols using oxetan‐3‐ols afford 3,3‐diaryloxetanes by displacement of the hydroxy group. These constitute new isosteres for benzophenones and diarylmethanes. Conversely, ortho‐selective Friedel–Crafts reactions of phenols afford 3‐aryl‐3‐hydroxymethyl‐dihydrobenzofurans by tandem alkylation–ring‐opening reactions; the outcome of the reaction diverging to structurally distinct products dependent on the substrate regioselectivity. Further reactivity of the oxetane products is demonstrated, suitable for incorporation into drug discovery efforts.
Synthesis of Potent and Selective HDAC6 Inhibitors Bearing a Cyclohexane‐ or Cycloheptane‐Annulated 1,5‐Benzothiazepine Scaffold
Authors: De Vreese Rob , Galle Lisa , Depetter Yves , Franceus Jorick , Desmet Tom , Van Hecke Kristof , Benoy Veronick , Van Den Bosch Ludo , D'hooghe Matthias 
Published: October 2016

AbstractSelective inhibitors of histone deacetylase 6 (HDAC6) are an emerging class of pharmaceuticals due to the involvement of HDAC6 in different pathways related to neurodegenerative diseases, cancer, and immunology. Herein, the synthesis of ten new benzohydroxamic acids, constructed by employing the tetrahydrobenzothiazepine core as a privileged pharmacophoric unit, is described. This is the first report on the synthesis and isolation of octahydrodibenzothiazepines and octahydro‐6H‐benzocycloheptathiazepines, which were then used to develop a new class of HDAC6 inhibitors. Evaluations of their HDAC‐inhibiting activity resulted in the identification of cis‐N‐(4‐hydroxycarbamoylbenzyl)‐1,2,3,4,4a,5,11,11a‐octahydrodibenzo[b,e][1,4]thiazepine‐10,10‐dioxide and cis‐N‐(4‐hydroxycarbamoylbenzyl)‐7‐trifluoromethyl‐1,2,3,4,4a,5,11,11a‐octahydrodibenzo[b,e][1,4]thiazepine‐10,10‐dioxide as highly potent and selective HDAC6 inhibitors with activity in the low nanomolar range, which also show excellent selectivity on the enzymatic and cellular levels. Furthermore, four promising inhibitors were subjected to an Ames fluctuation assay, which revealed no mutagenic effects associated with these structures.
Li+/Mg2+ Hybrid‐Ion Batteries with Long Cycle Life and High Rate Capability Employing MoS2 Nano Flowers as the Cathode Material
Authors: Ju Yanming , Meng Yuan , Wei Yingjin , Bian Xiaofei , Pang Qiang , Gao Yu , Du Fei , Liu Bingbing , Chen Gang 
Published: October 2016

AbstractThe demand for large‐scale and safe energy storage is increasing rapidly due to the strong push for smartphones and electric vehicles. As a result, Li+/Mg2+ hybrid‐ion batteries (LMIBs) combining a dendrite‐free deposition of Mg anode and Li+ intercalation cathode have attracted considerable attention. Here, a LMIB with hydrothermal‐prepared MoS2 nano flowers as cathode material was prepared. The battery showed remarkable electrochemical properties with a large discharge capacity (243 mAh g−1 at the 0.1 C rate), excellent rate capability (108 mAh g−1 at the 5 C rate), and long cycle life (87.2 % capacity retention after 2300 cycles). Electrochemical analysis showed that the reactions occurring in the battery cell involved Mg stripping/plating at the anode side and Li+ intercalation at the cathode side with a small contribution from Mg2+ adsorption. The excellent electrochemical performance and extremely safe cell system show promise for its use in practical applications.
Local A‐Site Layering in Rare‐Earth Orthochromite Perovskites by Solution Synthesis
Authors: Daniels Luke M. , Kashtiban Reza J. , Kepaptsoglou Demie , Ramasse Quentin M. , Sloan Jeremy , Walton Richard I. 
Published: October 2016

AbstractCation size effects were examined in the mixed A‐site perovskites La0.5Sm0.5CrO3 and La0.5Tb0.5CrO3 prepared through both hydrothermal and solid‐state methods. Atomically resolved electron energy loss spectroscopy (EELS) in the transmission electron microscope shows that while the La and Sm cations are randomly distributed, increased cation‐radius variance in La0.5Tb0.5CrO3 results in regions of localised La and Tb layers, an atomic arrangement exclusive to the hydrothermally prepared material. Solid‐state preparation gives lower homogeneity resulting in separate nanoscale regions rich in La3+ and Tb3+. The A‐site layering in hydrothermal La0.5Tb0.5CrO3 is randomised upon annealing at high temperature, resulting in magnetic behaviour that is dependent on synthesis route.
Time‐Gated Detection of Cystathionine γ‐Lyase Activity and Inhibition with a Selective, Luminogenic Hydrogen Sulfide Sensor
Authors: Yao Yao , Kong Chen , Yin Liang , Jain Atul D. , Ratia Kiira , Thatcher Gregory R. J. , Moore Terry W. , Driver Tom G. , Miller Lawrence W. 
Published: October 2016

AbstractHerein, we report the design, synthesis, and characterization of a lanthanideIII complex‐based probe for the time‐gated luminescence detection of hydrogen sulfide (H2S) in aqueous media. The probe's unique sensing mechanism relies on the selective reduction of azide to amine by sulfide, followed by intramolecular cyclization to form a quinolinone. The quinolinone is a sensitizer that absorbs near‐UV light and transfers excitation energy to coordinated TbIII or EuIII ions to trigger a strong “turn‐on” luminescence response with ms‐scale lifetimes characteristic of lanthanide complexes. Using this probe, we developed a robust, high throughput screening (HTS) assay for detecting H2S generated by cystathionine γ‐lyase (CSE), one of the main producers of H2S in mammalian cells. In a 240‐compound screen to identify potential CSE inhibitors, the EuIII analogue of the sensor showed a low false‐positive rate and high Z′‐factor (>0.7).
ChemInform Abstract: Low‐Temperature Cationic Rearrangement in a Bulk Metal Oxide.
Authors: Greenblatt Martha , et al.  
Published: October 2016

AbstractCationic rearrangement in bulk Mn2FeMoO6 at 150—300 °C leads to a transition from the Ni3TeO6‐type to an ordered ilmenite structure, and dramatic changes of the electrical and magnetic properties as evidenced by powder X‐ray and neutron diffraction, and second harmonic generation.
ChemInform Abstract: Crystal Structure of Strontium Dicobalt Iron(III) Tris(orthophosphate): SrCo2Fe(PO4)3.
Authors: Bouraima Adam , Makani Thomas , Assani Abderrazzak , Saadi Mohamed , El Ammari Lahcen 
Published: October 2016

AbstractSingle crystals of the title compound are prepared by solid state reaction of a 1:2:1:3 molar mixture of Sr, Co, and Fe nitrates along with NH4H2PO4 (Pt crucible, 1343 K; cooling to 273 K at a rate of 5 K/h).
ChemInform Abstract: Cu3V2O8 Nanoparticles as Intercalation‐Type Anode Material for Lithium‐Ion Batteries.
Authors: Li Malin , Gao Yu , Chen Nan , Meng Xing , Wang Chunzhong , Zhang Yaoqing , Zhang Dong , Wei Yingjin , Du Fei , Chen Gang 
Published: October 2016

AbstractCu3V2O8 nanoparticles (40‐50 nm) are prepared by addition of NH4VO3 to an aqueous 0.1 M Cu(NO3)2 solution followed by drying and sintering of the Cu3V2O7 (OH)2·2H2O precipitate in air (400 °C, 1 h).
ChemInform Abstract: New Clathrates of Rb7.50(1)Tl0.50(1)Ge46 and K7.62(1)Tl0.38(1)Ge45.34(3).
Authors: Zhang Hui , Mu Gang , Huang Fuqiang , Xie Xiaoming 
Published: October 2016

AbstractThe title type‐I clathrates are synthesized by solid state reactions of the elements (Ta tubes, 650 °C, 14 d) and characterized by powder XRD, SEM, and DFT calculations.
ChemInform Abstract: RbZnFe(PO4)2: Synthesis and Crystal Structure.
Authors: Badri Abdessalem , Ben Amara Mongi 
Published: October 2016

AbstractSingle crystals of the new title compound are grown in a flux of Rb2Mo2O7 starting with Rb2CO3, Zn(NO3)2, Fe(NO3)3, (NH4)2HPO4, and MoO3 dissolved in HNO3 (353 K, 24 h) followed by heating of the dried residue (Pt crucible, 1173 K, 1 h).
ChemInform Abstract: Ternary Arsenides RECo5As3 (RE: Y, Gd, Tb, Dy, Ho, Er).
Authors: Zhak O. , Senkiv I. , Babyzhetskyy V. , Dzevenko M. , Bigun I. , Havela L. , Maskova S. , Paukov M. 
Published: October 2016

AbstractLnCo5As3 (Ln: Y, Gd, Tb, Dy, Ho, Er) compounds are prepared by solid state reaction of stoichiometric amounts of the elements (evacuated silica tubes, 970 K, 10 d) followed by pelletizing, arc melting, and a final annealing (evacuated silica tubes, 970 K, 4 weeks).
ChemInform Abstract: Palladium Nanoparticles in Water: A Reusable Catalytic System for the Cycloetherification or Benzannulation of α‐Allenols.
Authors: Alcaide Benito , Almendros Pedro , Gonzalez Ana M. , Luna Amparo , Martinez‐Ramirez Sagrario 
Published: October 2016

AbstractPalladium nanoparticles freshly generated from PdCl2, K2CO3 and Bu4NBr, are described as highly efficient catalytic system for the chemoselective cyclization reaction of various allenyl substituted secondary alcohols.
ChemInform Abstract: Highly Efficient and Recyclable Magnetic Nanoparticles‐Supported Gold(III)‐bipy Catalyst for Oxidative α‐Cyanation of Tertiary Amines.
Authors: Yang Weisen , Wei Li , Yi Feiyan , Cai Mingzhong 
Published: October 2016

AbstractThe title reaction renders possible the direct synthesis of various α‐aminonitriles if the amine substrates bear at least one aromatic substituent.
ChemInform Abstract: Organocatalytic Regioselective Chlorosilylation of Oxirane Derivatives: Mild and Effective Insertion of Bulky Silyl Chloride by Using 4‐Methoxypyridine N‐Oxide.
Authors: Yoshida Keisuke , Suzuki Hina , Inoue Hiroki , Matsui Kohei , Fujino Yuta , Kanoko Yohei , Itatsu Yukihiro , Takao Ken‐ichi 
Published: October 2016

Abstract4‐Methoxypyridine N‐oxide is an efficient catalyst for the chlorosilylation of epoxides (I).
ChemInform Abstract: Copper Catalyzed Alkynylation of Tertiary Amines with CaC2 via sp3 C—H Activation.
Authors: Teong Siew Ping , Yu Dingyi , Sum Yin Ngai , Zhang Yugen 
Published: October 2016

AbstractThe copper‐catalyzed alkynylation of tertiary amines with CaC2 is described.
ChemInform Abstract: Highly Active Multidentate Ligand‐Based Alkyne Metathesis Catalysts.
Authors: Du Ya , Yang Haishen , Zhu Chengpu , Ortiz Michael , Okochi Kenji D. , Shoemaker Richard , Jin Yinghua , Zhang Wei 
Published: October 2016

AbstractThe catalyst combination MOC/BDMC can be successfully applied for homodimerization, ring closing alkyne metathesis and cyclooligomerization.
ChemInform Abstract: Efficient Synthesis of Unsymmetrical Sulfamides via a Lossen‐Like Rearrangement.
Authors: Pantaine Loic , Richard Francois , Marrot Jerome , Moreau Xavier , Coeffard Vincent , Greck Christine 
Published: October 2016

AbstractA direct synthesis of unsymmetrical sulfamides is achieved by Et3N‐promoted reaction of N,O‐bissulfonyl hydroxylamines with primary amines or diphenylamine.
ChemInform Abstract: The Multiple Facets of Iodine(III) Compounds in an Unprecedented Catalytic Auto‐Amination for Chiral Amine Synthesis.
Authors: Buendia Julien , Grelier Gwendal , Darses Benjamin , Jarvis Amanda G. , Taran Frederic , Dauban Philippe 
Published: October 2016

AbstractDiacetoxyiodoarene (III) is used both as an oxidant and a substrate for the C(sp3)—H amination reaction leading to chiral iodide (V).
ChemInform Abstract: Synthesis of Pyrrolidinone Derivatives from Aniline, an Aldehyde and Diethyl Acetylenedicarboxylate in an Ethanolic Citric Acid Solution under Ultrasound Irradiation.
Authors: Ahankar Hamideh , Ramazani Ali , Slepokura Katarzyna , Lis Tadeusz , Joo Sang Woo 
Published: October 2016

AbstractCompared to the conventional method, the utilization of ultrasound irradiation is shown to give slightly higher yields in significantly shorter reaction times.
ChemInform Abstract: Intramolecular Alkene Aminocarbonylation Using Concerted Cycloadditions of Amino‐Isocyanates.
Authors: Ivanovich Ryan A. , Clavette Christian , Vincent‐Rocan Jean‐Francois , Roveda Jean‐Gregoire , Gorelsky Serge I. , Beauchemin Andre M. 
Published: October 2016

AbstractThe title reaction proceeds via amino‐isocyanate intermediates to produce bi‐ or tricyclic N‐heterocycles which include an aminocarbonyl segment.
ChemInform Abstract: Efficient Synthesis of Dimeric Oxazoles, Piperidines and Tetrahydroisoquinolines from N‐Substituted 2‐Oxazolones.
Authors: Nicolaou K. C. , et al.  
Published: October 2016

AbstractDifferent types of N‐substituted 2‐oxazolone substrates are subjected to a boron trifluoride etherate promoted reaction under slightly modified conditions to produce the title heterocycles (investigation and discussion of the cascade mechanisms).
ChemInform Abstract: A Carboxylative Cyclization of Propargylic Amines with Carbon Dioxide Catalyzed by the N‐Heterocyclic Carbene 1,3‐Di‐tert‐butylimidazol‐2‐ylidene (ItBu).
Authors: Fujita Ken‐ichi , Sato Junichi , Fujii Akira , Onozawa Shun‐ya , Yasuda Hiroyuki 
Published: October 2016

AbstractDepending on the pressure of carbon dioxide employed, the carboxylative cyclization of propargylic amines gives selectively 2‐oxazolidiones (III) or 2‐oxazolones (IV).
ChemInform Abstract: Metal‐Free Autoxidative Nitrooxylation of Alkenyl Oximes with Molecular Oxygen.
Authors: Zhang Xiao‐Wei , Xiao Zu‐Feng , Zhuang Yan‐Jun , Wang Mei‐Mei , Kang Yan‐Biao 
Published: October 2016

AbstractA series of nitrooxyisoxazolines (II), (IV), and (VI) is prepared by nitrooxylation of alkenyl oximes under air atmosphere.
ChemInform Abstract: Ytterbium Triflate Promoted Coupling of Phenols and Propiolic Acids: Synthesis of Coumarins.
Authors: Fiorito Serena , Epifano Francesco , Taddeo Vito A. , Genovese Salvatore 
Published: October 2016

AbstractThe improved method using microwave irradiation under solvent‐free conditions allows the synthesis of coumarins from phenols or hydroxycoumarins and propiolic acid derivatives.
ChemInform Abstract: Synthesis of 6‐Aryl/Heteroaryl‐4‐oxo‐4H‐chromene‐2‐carboxylic Ethyl Ester Derivatives.
Authors: Fernandes Carlos , Soares Pedro , Gaspar Alexandra , Martins Daniel , Gomes Ligia R. , Low John N. , Borges Fernanda 
Published: October 2016

AbstractAn expeditious two‐step procedure to synthesize the title compounds is developed.
ChemInform Abstract: Broensted Acid Promoted One‐Pot Synthesis of 4‐Aryl‐3,4‐dihydrocoumarins.
Authors: Chen Cheng , Zhang Rui , Lin Long , Yang Guang‐Fu , Wu Qiong‐You 
Published: October 2016

AbstractA mild and facile approach to the title compounds, which are of interest in natural product and medicinal chemistry, becomes optimal in the presence of HClO4.
ChemInform Abstract: Metal‐Free C—H Arylation of Aminoheterocycles with Arylhydrazines.
Authors: Taniguchi Toshihide , Imoto Mitsutaka , Takeda Motonori , Matsumoto Fukashi , Nakai Takeo , Mihara Masatoshi , Mizuno Takumi , Nomoto Akihiro , Ogawa Akiya 
Published: October 2016

AbstractHeterocyclic amines and diamine (Ib) are successfully arylated under atmospheric conditions in the presence of an inexpensive base.
ChemInform Abstract: Rh(III)‐Catalyzed Double Molecular Alkyne Imine C—H Activation: A Facile and Efficient Synthesis of Functionalized Acridine Compounds.
Authors: Shan Yingying , Yan Weidong 
Published: October 2016

AbstractA facile protocol is developed for the synthesis of polyfunctionalized benzo‐ and thienoacridine derivatives from readily available imine substrates.
ChemInform Abstract: NBS Mediated One‐Pot Regioselective Synthesis of 2,3‐Disubstituted Imidazo[1,2‐a]pyridines and Their Unambiguous Characterization Through 2D NMR and X‐Ray Crystallography.
Authors: Aggarwal Ranjana , Singh Gulshan , Sanz Dionisia , Claramunt Rosa M. , Torralba M. Carmen , Torres M. Rosario 
Published: October 2016

AbstractThe access to the required heterocycles of type (III) proceeds via brominated 1,3‐diketones.
ChemInform Abstract: Synthesis of 3‐Substituted Indolizidines from Amino‐ynones Derivatives.
Authors: Vu Huy‐Dinh , Renault Jacques , Roisnel Thierry , Gouault Nicolas , Uriac Philippe 
Published: October 2016

AbstractThis study demonstrates access to indolizidines from racemic pipecolic acid with amino‐ynones as key intermediates.
ChemInform Abstract: One‐Pot Synthesis of Polyhydropyrido[1,2‐a]indoles and Tetracyclic Quinazolinones from 2‐Arylindoles Using Copper‐Mediated Oxidative Tandem Reactions.
Authors: Yamashita Mitsuaki , Nishizono Yukari , Himekawa Seiya , Iida Akira 
Published: October 2016

AbstractThe approach to the title heterocycles proceeds via C‐acylimine intermediates followed by aza‐Diels—Alder reactions or oxidative ring expansion and opens the way to important polycyclic systems.
ChemInform Abstract: A New Convenient Synthetic Approach to Diarylpyrimidines.
Authors: Guirado Antonio , Alarcon Enrique , Vicente Yesica , Andreu Raquel , Bautista Delia , Galvez Jesus 
Published: October 2016

AbstractTwo pathways to the desired compounds are presented: a stepwise and a one‐pot procedure which both are operationally simple.
ChemInform Abstract: A Facile, Regioselective Synthesis of Pyrazolo[1, 5‐a]pyrimidine Analogues in the Presence of KHSO4 in Aqueous Media Assisted by Ultrasound and Their Antiinflammatory and Anticancer Activities.
Authors: Kaping Shunan , Kalita Utpalparna , Sunn Melboureen , Singha Laishram Indira , Vishwakarma Jai Narain 
Published: October 2016

AbstractThe pyrimidine derivatives are screened for their anti‐inflammatory and anticancer activities.
ChemInform Abstract: Synthesis of Derivatives of Methoxydibenzo[b,f]oxepine in the Presence of Sodium Azide.
Authors: Krawczyk Hanna , Wrzesinski Michal , Mielecki Damian , Szczecinski Przemyslaw , Grzesiuk Elzbieta 
Published: October 2016

AbstractSodium azide promotes the formation of the pharmaceutically important ring system (mechanism and theoretical calculations).
ChemInform Abstract: Total Synthesis of (—)‐Stemoamide by Sequential Overman/Claisen Rearrangement.
Authors: Nakayama Yasuaki , Maeda Yuichiro , Hama Naoto , Sato Takaaki , Chida Noritaka 
Published: October 2016

AbstractThe enantioselective total synthesis of (—)‐stemoamide using Overman/Claisen rearrangement of an allylic 1,2‐diol is reported.
ChemInform Abstract: Application of Ionic Liquids in Pot‐in‐Pot Reactions
Authors: Cinar Simge , Schulz Michael D. , Oyola‐Reynoso Stephanie , Bwambok David K. , Gathiaka Symon M. , Thuo Martin 
Published: October 2016

AbstractReview: critical role of ionic liquids in site‐isolation of multiple catalyzed reactios in a standard pot‐in‐pot reaction; 71 refs.
ChemInform Abstract: Utilization of LDH‐Based Materials as Potential Adsorbents and Photocatalysts for the Decontamination of Dyes Wastewater: A Review
Authors: Yang Zhongzhu , Wang Fenghua , Zhang Chang , Zeng Guangming , Tan Xiaofei , Yu Zhigang , Zhong Yu , Wang Hou , Cui Fang 
Published: October 2016

AbstractReview: 166 refs.
ChemInform Abstract: Noble Gas Supported B3+ Cluster: Formation of Strong Covalent Noble Gas—Boron Bonds.
Authors: Saha Ranajit , Pan Sudip , Mandal Subhajit , Orozco Mesias , Merino Gabriel , Chattaraj Pratim K. 
Published: October 2016

AbstractB3Ng3+ (Ng: He—Rn) complexes are characterized by quantum chemical MP2 and CCSD(T) calculations.