bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: An Extremely Short‐Lived 1,4‐Biradical as Intermediate in the Photocycloaddition Reactions of Triplet State Aromatic Thiones with Allenes.
Authors: KAMPHUIS J. , BOS H. J. T. , VISSER R. J. , HUIZER B. H. , VARMA C. A. G. O. 
Published: May 2016

AbstractThe question is studied as to whether an exciplex or a 1,4‐biradical or both appear as intermediates in the photochemical reaction of aromatic thiones (I) and (II) with allenes such as (III)‐(V) and (IX), the butatriene (VII), or acetylenes (VI).
ChemInform Abstract: Stereoselective Oxygenation of 2,3‐Diaryloxiranes by Irradiation of Electron Donor‐Acceptor Complexes of Tetracyanoethylene.
Authors: MIYASHI T. , KAMATA M. , MUKAI T. 
Published: May 2016

AbstractPhotolysis of the epoxides (I) in the presence of tetracyanoethylene under various conditions yields the cis‐trioxolanes (II) and/or the adducts (III) and (IV).
ChemInform Abstract: Photodimerization of 2,6‐Diphenyl‐4‐(5‐bromofuryl‐2)pyrylium and Pyridinium Perchlorates.
Authors: FEIGEL'MAN V. M. , TYMYANSKII YA. R. , NOVIKOV V. N. , KNYAZHANSKII M. I. 
Published: May 2016

AbstractThe bromofurylpyrylium perchlorate (I) is photodimerized using acetonitrile as the solvent.
ChemInform Abstract: Dication Ethers. Part 11. Ambidoselective Reactions of β‐Ketoenolates with Dication Ethers.
Authors: FEITH B. , WEBER H.‐M. , MAAS G. 
Published: May 2016

AbstractTreatment of the salts (Ia), (Ib) with the β‐ketoenolate salts (II) or (IV) in MeCN effects electrophilic transfer of the tetramethyl or ethylene formamidinio group, resp., occurring exclusively at an oxygen atom of the ambident anion, thus yielding the uronium salts (III), (V), (VI).
ChemInform Abstract: A Convenient Synthesis of (11E,13E)‐11,13‐Hexadecadienal and (11Z,13E)‐ Hexadecadienal.
Authors: LO V. M. , SHIAO M.‐J. 
Published: May 2016

AbstractThe isomeric hexadecadienals (V) are prepared by Wittig reaction of the phosphonium bromide (II) and trans‐2‐pentenal (III), followed by oxidation of the alcohols generated (IV).
ChemInform Abstract: A Simplified Wittig Synthesis Using a Solid‐Liquid Transfer Process. Part 6. Synthesis of γ‐Unsaturated Alcohols from Aromatic and Heteroaromatic Aldehydes.
Authors: CHEIK‐ROUHOU F. , LE BIGOT Y. , EL GHARBI R. 
Published: May 2016

AbstractThe aldehydes (I) are coupled with the phosphonium salts (II) in the presence of potassium carbonate to yield predominantly the E‐isomers of the γ,δ‐unsaturated alcohols (III).
ChemInform Abstract: Activated Thiocarboxylic Esters. Part 8. Preparation of 2‐Oxodithiocarboxylic Esters from Diazoketones.
Authors: SAWLUK A. , VOSS J. 
Published: May 2016

AbstractThe alkyl 2‐oxodithiocarboxylates (IV) and (VI) are obtained by reaction of the diazoketones (I) or (V) with elemental sulfur and triethylamine and subsequent alkylation.
ChemInform Abstract: Free Radical Catalyzed Additions to the Double Bond of Diketene: A Synthesis of Novel Oxetan‐2‐ones.
Authors: DINGWALL J. G. , TUCK B. 
Published: May 2016

AbstractThe free radical catalyzed addition of the thiols (II) to diketene (I) yields the thiomethyloxetanones (III), which can be oxidized to the sulfones (IV) or the sulfoxide (V).
ChemInform Abstract: Synthesis of 4‐Ylidenebutenolides. A Practical Route to 2‐En‐4‐ynoic Acid Intermediates Based on Conjugate Addition of Alkynyl‐Lithium Reagents.
Authors: CLEMO N. G. , PATTENDEN G. 
Published: May 2016

AbstractThe alkynylalanes generated from (I) react with the malonate (II) to give the Michael adducts (III).
ChemInform Abstract: Synthesis of 2‐Penten‐4‐olides, 3‐Penten‐4‐olides, and 4,4‐Dialkyl‐1,3‐ cyclopentanediones by Acid‐ and Base‐Induced Isomerization of 4‐Penten‐ 4‐olides (γ‐Methylene‐γ‐butyrolactones).
Authors: GUNTRUM E. , KUHN W. , SPOENLEIN W. + , JAEGER V. + 
Published: May 2016

AbstractThe γ‐methylene‐γ‐butyrolactones (I) undergo acid or base‐induced rearrangements, producing pentenolides such as (II), (III), and (V) or the 3‐acetylpropanoic acids (IV).
ChemInform Abstract: Synthesis and Reactions of an Open‐Chain Bis‐Reissert Salt Analog.
Authors: IYER R. P. , RATNAM R. K. , KULKARNI S. P. , SONASETH M. S. 
Published: May 2016

AbstractPropionaldehyde (I), ethylenediamine (II), and KCN are coupled to yield the amino nitrile (III).
ChemInform Abstract: Indoles and Indole Alkaloids. Part 21. Preparation of 4‐(Acetylamino)‐1,2,3,9a‐tetrahydrocarbazole Derivatives by (4 + 2) Cycloadditions of 3‐Indolyl‐enimides and ‐enamides.
Authors: GOETZ P. H. + , BATS J. W. , FRITZ H. 
Published: May 2016

AbstractTreatment of the oximes (II) or (VI), derived from the corresponding 3‐acetylindoles (I) or (V), with Ac2O affords the enimides (III) or (VII).
ChemInform Abstract: Para‐Quinol Derivatives via Oxidative Cyclization of N‐Acyl‐4‐hydroxyphenethylamines.
Authors: SCHWARTZ M. A. , HUDEC T. T. 
Published: May 2016

AbstractOxidation experiments with the N‐acyl‐p‐hydroxyphenethylamines (I) and (III) are carried out in order to prepare derivatives of p‐quinols.
ChemInform Abstract: Thiono‐ and Dithioesters. Part 38. Condensation of 2‐Amino‐dithio‐O‐ oxalates with Cyanoacetic Esters.
Authors: HARTKE K. , FALLERT M. 
Published: May 2016

AbstractThe cyanoimidoates (II) react with H2S to produce the thioamides (I) or (III).
ChemInform Abstract: Preparations and Properties of Derivatives of 5‐Hydroxy‐1,3‐benzoxathiol 3,3‐Dioxide.
Authors: MEICHLE W. , OTTO H.‐H. 
Published: May 2016

AbstractThe derivatives (II) ‐ (XII) of the title compound (I) are prepared by simple synthetic methods as shown in the reaction scheme.
ChemInform Abstract: Synthesis and Spectroscopic Study of 2‐Thiazole and 2‐Benzothiazole Thiocarboxamides.
Authors: YAGODZIN'SKII T. , DZEMBOVSKA T. , YAGODZIN'SKA E. , YABLON'SKI Z. 
Published: May 2016

AbstractThe 2‐lithiothiazoles (I) react with the isothiocyanates (II) to give the thiocarboxamides (III).
ChemInform Abstract: Reaction of C‐(Triphenylphosphinimido)hydrazones with Isocyanates as a Route to 5‐Arylamino‐ and 5‐Alkylamino‐1H‐1,2,4‐triazoles.
Authors: BRUCHE L. , GARANTI L. , ZECCHI G. 
Published: May 2016

AbstractThe title reaction gives access to the triazoles (III); the triazolone (IV) is formed as a by‐product in the conversions of aromatic isocyanates (II).
ChemInform Abstract: Synthesis of Alkyloxybenzamide Derivatives as Potential Antimicrobial Agents.
Authors: HABIB N. S. , ISSA A. S. , RIDA S. M. , ASHOUR F. A. , TAWIL G. G. 
Published: May 2016

AbstractThe alkoxybenzamido derivatives (VI), (VIII), and (IX) are prepared from the key intermediates (III), obtained by reaction of ethyl p‐aminobenzoate (I) with the 4‐alkoxybenzoyl chlorides (II).
ChemInform Abstract: 1‐Azadienes in Heterocyclic Synthesis. Reaction of 1‐N‐Alkyl‐1‐azapenta‐1,3‐dienes with Mesoionic Oxazolones.
Authors: SAIN B. , SANDHU J. S. 
Published: May 2016

AbstractThe oxazolones (II), prepared by cyclization of the N‐acyl amino acids (I), react with the 1‐aza‐1,3‐pentadienes (III) to form the dihydropyridones (IV).
ChemInform Abstract: Synthesis and Acid‐Base Transformations of (4‐Styrylpyridinio)alkanesulphonates.
Authors: EIKHER‐LORKA O. S. , KUPYATIS G. K. K. 
Published: May 2016

AbstractThe styrylpyridinioalkanesulphonates (III) and (Va) are synthesized by condensation reaction of the pyridinioalkanesulphonates (I) or (IV) with the aromatic aldehydes (II).
ChemInform Abstract: Cardiotonic Agents. Part 1. Synthesis and Structure‐Activity Relationships in a New Class of 3‐, 4‐, and 5‐Pyridyl‐2(1H)‐quinolone Derivatives.
Authors: LECLERC G. , MARCINIAK G. , DECKER N. , SCHWARTZ J. 
Published: May 2016

AbstractA number of quinolone and dihydroquinolone derivatives is synthesized as shown in the reaction scheme.
ChemInform Abstract: Quinones. Part 11. The Reaction of o‐Aminothiophenol with o‐Benzo‐ and o‐Naphtho‐quinones: A New Route to 1H‐Phenothiazin‐1‐ones.
Authors: MACKENZIE N. E. , SURENDRAKUMAR S. , THOMSON R. H. , COWE H. J. , COX P. J. 
Published: May 2016

AbstractThe o‐benzoquinones (Ia) and (Ib), both containing two large blocking groups, can be converted to the title compounds (II) by condensation with the thiophenol (V).
ChemInform Abstract: Synthesis and Single Crystal X‐Ray Diffraction Characterization of (2‐Amino‐N‐(2,6‐dimethylphenyl)acetamidato‐N2)dichloroethylselenium, a Selenium Containing Lidocaine Mimic.
Authors: THOMPSON M. D. , BERLIN K. D. , SMITH G. S. , VAN DER HELM D. , MUCHMORE S. W. , FIDELIS K. A. 
Published: May 2016

AbstractThe title compound (X) is prepared from elemental selenium (I) via the selenenylacetic acid (VI).
ChemInform Abstract: Characterization of meso‐Rhodins and Their Fe(III) Complexes.
Authors: DIXON D. W. , CALLAHAN J. , GHOSH S. B. , HWANG Y. C. , SHIRAZI A. , TYLER A. W. 
Published: May 2016

AbstractThe meso‐rhodin ester and the corresponding acid were prepared from meso‐porphyrin IX dimethyl ester by an intramolecular Friedel‐Crafts reaction following a known procedure.
ChemInform Abstract: Dinuclear Complexes Derivatives of N,N′‐Ethylenebis(2‐hydroxyacetophenoneimine)(mesalen) and 1,3‐Bis‐(2‐hydroxyphenyl)‐1,3‐propanedione(bhppH3). The Crystal and Molecular Structure of Cu(mesalen)Zn(bhppH2)2.
Authors: TEIXIDOR F. , FLOR T. , CASABO J. , MIRAVITLLES C. , RIUS J. , MOLINS E. 
Published: May 2016

AbstractThe 1:1 molar reaction of the Schiff base complexes (I) with the bis(diketonato) complexes (II) leads to the formation of the heterobinuclear complexes (III) in which M1 is four‐coordinated and M2 six‐coordinated.
ChemInform Abstract: Tris(pentachlorophenyl) Gold(III) Complexes.
Authors: USON R. , LAGUNA A. , VILLACAMPA M. D. 
Published: May 2016

AbstractThe reaction of (III) with the gold(I) compounds (II) or (IV) yields the gold(III) complexes (I) or (V), which are the first tris(pentachlorophenyl)gold(III) complexes to be reported.
ChemInform Abstract: Cyclization of 3,3;20,20‐Bis(ethylenedioxy)‐C‐nor‐9,11‐seco‐5α‐pregnane‐9β,11‐diol Into 11‐Oxa‐5α,17α‐pregnane‐3,20‐dione.
Authors: NAGANO H. , IWADARE T. , SHIOTA M. 
Published: May 2016

AbstractThe diol (Ia) cyclizes in the presence of TosOH under reflux to the title compound (IIa), which is accompanied by the isomer (IIb).
ChemInform Abstract: Thiourea Derivatives of Carbohydrates. Part 8. A New Method for the Preparation of Acylated Glycosylamines and Their Transformations into Glycosyl Isothiocyanates and N,N′‐Diglycosylthioureas.
Authors: BABIANO CABALLERO R. , FUENTES MOTA J. , GALBIS PEREZ J. A. 
Published: May 2016

AbstractThe synthesis of the O‐acylated glycosylamines (II) is described.
ChemInform Abstract: Synthesis and Antiviral Evaluation of 1,4‐Dioxane Nucleoside Analogues Related to Nucleoside Dialdehydes.
Authors: PRISBE E. J. 
Published: May 2016

AbstractGuanosine (Ia) and the substituted adenosine (IV) are transformed into the hydroxymethyldioxanes (III) and (VII) or into the hydroxymethyldivinylether (VIII) as shown in the reaction scheme.
ChemInform Abstract: Photoelectrochemical Cells of the Electrolyte‐Metal‐Insulator‐Semiconductor (EMIS) Configuration. Part 2. Use of Non‐Native Oxides in Pt/Oxide/n‐Si Systems.
Authors: HOWE A. T. , FLEISCH T. H. 
Published: May 2016

AbstractPhotoelectrodes with 10 Å thick oxide layers of ZrO2, TiO2, Al2O3, and MgO have been prepared by using electron beam evaporation from pellets of the pure or doped oxides.
ChemInform Abstract: Exhaust‐Catalyst Development for Methanol‐Fueled Vehicles. Part 2. Synergism Between Palladium and Silver in Methanol and Carbon Monoxide Oxidation Over an Alumina‐Supported Palladium‐Silver Catalyst.
Authors: MCCABE R. W. , MITCHELL P. J. 
Published: May 2016

AbstractSelectivity and activity for MeOH and CO oxidation of a 0.01% Pd/5% Ag/Al2O3 bimetallic catalyst are compared to those of the corresponding single‐component catalysts.
ChemInform Abstract: A Direct Synthesis of Ammonium Monofluorophosphate Monohydrate, (NH4)2(PO3F)·H2O, and Potassium Monofluorophosphate, K2(PO3F)
Authors: BHATTACHARJEE M. , CHAUDHURI M. K. 
Published: May 2016

Abstractis based on the reaction between H3PO4 and AHF2 followed by precipitation with EtOH.
ChemInform Abstract: Structural Behavior of Vitamin B1 in Bonding to Hydrogen and Metal Ions.
Authors: MARZOTTO A. , BIAGINI CINGI M. , CLEMENTE D. A. 
Published: May 2016

AbstractAb initio LCAO‐SCF MO calculations are applied to the adducts obtained by binding H+ or ZnCl3‐ to vitamin B1 (I).
ChemInform Abstract: Effect of Anion Ordering on the H‐Anion Interactions and Band Electronic Structure of (TMTSF)2BF4 at 20 K.
Authors: EMGE T. J. , WANG H. H. , BENO M. A. , WILLIAMS J. M. , WHANGBO M.‐H. , EVAIN M. 
Published: May 2016

AbstractIn order to determine the precise H atom positions of the methyl groups of the bis(tetramethyltetraselenafulvalenium) ion single crystal neutron diffraction studies for the title compound at 20 K (space group F1, Z = 8) are carried out.
ChemInform Abstract: Mechanism of Chiral Recognition of Octahedral Metal Complexes Effected by Bis(μ‐d‐tartrato)diantimonate(III) Anion in Solution. Part 2. Cage Complexes of the Type (Co(N)6)3+.
Authors: MIYOSHI K. , IZUMOTO S. , NAKAI K. , YONEDA H. 
Published: May 2016

AbstractOn subjecting the hexaamine cage complexes (I) and (II) to ion‐exchange chromatography with the bis(μ‐d‐tartrato)diantimonate(III) anion as a chiral eluent, the Λ enantiomers are always eluted before the Δ enantiomers.
ChemInform Abstract: Research on Heterocyclic Compounds. Part 20. Synthesis of Trifluoromethyl Derivatives of Fused Imidazole Systems.
Authors: ABIGNENTE E. , DE CAPRARIIS P. , PATSCOT R. , SACCHI A. 
Published: May 2016

Abstract2‐Amino pyridine (I) is cyclized with bromo trifluoromethyl acetone (II) to yield the bicyclus (IV).
ChemInform Abstract: Allylic Oxidations by Peroxy Esters Catalyzed by Copper Salts. The Potential for Stereoselective Syntheses.
Authors: BECKWITH A. L. J. , ZAVITSAS A. A. 
Published: May 2016

Abstract1‐Butene (II), cis‐ and trans‐2‐butene with tert‐butyl peroxyacetate (I) and cuprous or cupric salts all give esters (IV) and (V) in the same distributions of about 90:10; cis‐ and trans‐2‐pentene give trans‐4‐acetoxypent‐2‐ene as the major product.
ChemInform Abstract: Copper‐Catalyzed Acetoxylation (Hydroacetoxylation) of Butadiene: A Comparison with the Hydrocyanation Reaction.
Authors: MAMALIS I. , NOELS A. F. , PUENTES E. , WARIN R. , TEYSSIE PH. , HUBERT A. J. , GRANDJEAN J. , HUBIN R. , WADDAN D. Y. 
Published: May 2016

AbstractCopper bromide catalyzes the monoaddition of acetic acid to butadiene yielding mixtures of acetoxybutenes.
ChemInform Abstract: Reaction of 1‐Nitroanthraquinone with Hexamethylenetetramine.
Authors: GALICH L. V. , PODREZOVA T. N. , TIKHONOV V. I. , YUGAI G. A. 
Published: May 2016

AbstractThe reaction between 1‐nitroanthraquinone (I) and hexamethylenetetramine (II) yields the anthraquinone derivatives (III)‐(V).
ChemInform Abstract: Synthesis of Thiophenedicarbonyldiazide and Di‐tert‐butyl Thiophenedicarbamates.
Authors: GALVEZ C. , GARCIA F. , GARCIA J. , SOLDEVILA J. 
Published: May 2016

AbstractThe isomeric dibromothiophenes (I) are converted to the dicarboxylic acids (III) via the dinitriles (II).
ChemInform Abstract: A Controlled‐Oxidation Synthesis of Substituted Aryl 1‐Methyl‐4‐nitro‐ 5‐imidazolyl Sulfones.
Authors: HEINDEL N. D. , LACEY C. J. , EGOLF R. , MEASE B. N. , SCHRAY K. J. 
Published: May 2016

AbstractThe chloronitroimidazole (I) reacts with the thiophenols (II) to yield the sulfides (III).
ChemInform Abstract: Local Anaesthetics. Part 4. Synthesis and Activity of 2‐(N‐Substituted or N,N‐Disubstituted Aminoacetamido)‐4‐ or ‐4,5‐Substituted Thiazoles.
Authors: LAKHAN R. , RAI B. J. 
Published: May 2016

AbstractThe chloroacetamidothiazoles (I) react with the amines (II) to give the aminoacetamidothiazoles (III).
ChemInform Abstract: Synthesis and Reactions of α‐Ketoaldehyde Adducts of Some Heterocyclic Ureas.
Authors: HOUGH T. L. , HOUGH I. R. , PANNELL R. W. 
Published: May 2016

AbstractThe ureas (I), prepared from aryl amines and methylisocyanate, are coupled with the α‐ketoaldehydes (II) to produce the dihydroxyimidazolidinones (III).
ChemInform Abstract: Vinyl Carbanions. Part 24. A Convenient Synthesis of δ‐Lactones.
Authors: BARUA N. C. , SCHMIDT R. R. 
Published: May 2016

Abstractα,β‐Unsaturated δ‐lactones (IV) are obtained by reacting the lithiated β‐ethylthio‐ and β‐phenylthioacrylic acids (I) with the oxiranes (III) in the presence of boron trifluoride etherate.
ChemInform Abstract: A Convenient Synthesis of Coumarins by Denitro‐Cyclization.
Authors: YOSHIDA Y. , NAGAI S. , ODA N. , SAKAKIBARA J. 
Published: May 2016

AbstractCondensation of the 2‐nitrobenzaldehydes (I) with malonic acid (II) yields the o‐nitrobenzylidenemalonic acids (III) which cyclize to form the coumarins (IV) on heating with copper in quinoline.
ChemInform Abstract: Reaction of N‐(4‐Pyridylmethyl)benzamide N‐Oxides with Ethyl Cyanoacetate in the Presence of Acetic Anhydride.
Authors: BRANA M. F. , LOPEZ RODRIGUEZ M. L. , RODRIGUEZ C. , GARRIDO‐PERTIERRA A. 
Published: May 2016

AbstractCoupling of the pyridine N‐oxides (II), obtained from the pyridines (I), with the cyanoacetates (III) yields the products (IV) and (V).
ChemInform Abstract: Lithio‐ketene‐S,N‐acetals: New Synthesis of Multifunctionalized 2‐Pyridones.
Authors: TAKAHATA H. , YAMABE K. , YAMAZAKI T. 
Published: May 2016

AbstractN,N‐Dimethylthioacetamide (I) is converted to the lithium derivative (II) which reacts with the isocyanates (III) to yield the monothiodiamides (IV).
ChemInform Abstract: Synthesis of 2‐Aryl‐6‐carbethoxythiazolo(4,5‐c)pyridine and 7‐Chloro‐2‐ phenylthiazolo(5,4‐c)pyridine.
Authors: SHAFIEE A. , GHAZAR H. 
Published: May 2016

AbstractThe thiazolecarbaldehydes (I) react with ethyl azidoacetate (II) to yield the olefins (III).
ChemInform Abstract: A Convenient Synthesis of 1‐Alkyl‐4‐oxo‐1,4‐dihydrocinnolines.
Authors: DEL BUTTERO P. , LICANDRO E. , MAIORANA S. , PAPAGNI A. 
Published: May 2016

AbstractThe title compounds (IV) are prepared by reaction of the 4‐oxo‐3‐triphenylphosphoranylidene‐3,4‐dihydrocinnolines (I) with an excess of the alkyl halides (II) and subsequent hydrolysis with sodium hydroxide.
ChemInform Abstract: Tellurium Tetrahalides in Rubber Chemistry: Some New Tellurium(IV) Complexes with an S2X4 (X = Halogen) Ligand Environment.
Authors: KARNIKA DE SILVA K. G. , MCWHINNIE W. R. , STUCKEY J. E. 
Published: May 2016

AbstractThe reaction of Te tetrahalides with natural rubber parallels closely reactions with model compounds such as cyclohexene and 2‐methylpent‐2‐ene carried out under similar conditions.
ChemInform Abstract: Structure and Properties of Tetrakis(tironato)cerate(IV), Na12(Ce(C6H2O2(SO3)2)4)·9 H2O·6 C3H7NO.
Authors: HADDAD S. F. , RAYMOND K. N. 
Published: May 2016

AbstractThe extremely hygroscopic title compound (I) is prepared by heating of (NH4)2(Ce(NO3)6) with four equiv. Tiron in 1 M NaOH and is crystallized from hot DMF/EtOH solutions.
ChemInform Abstract: Organo Transition Metal Compounds. Part 49. Reactions of Cerium(IV) Acetylacetonate with Organolithium and Organomagnesium Compounds.
Authors: JACOB K. , THIELE K.‐H. 
Published: May 2016

AbstractDepending on the molar ratio the Ce(IV) acetylacetonate (II) reacts with Li organyls with Ce(IV) reduction to give the Li cerate (I) or the Li trialkylcerates (III).
ChemInform Abstract: Electron Transfer. Part 82. Reduction of Carboxylato‐Bound Chromium(V) with Hypophosphorous Acid.
Authors: GHOSH S. K. , BOSE R. N. , LAALI K. , GOULD E. S. 
Published: May 2016

AbstractThe reduction of bis chelate (I) with H3PO2 passes through a mixture of strongly absorbing intermediates, the behavior of which corresponds to chromium(IV) species.
ChemInform Abstract: Reaction of Chromium(II) with Iodoacetamide and Properties of (H2O)5CrCH2CO(NH2)2+.
Authors: KITA P. , JORDAN R. B. 
Published: May 2016

AbstractAqueous Cr(II) perchlorate reacts with ICH2CONH2 in aqueous perchloric acid to give the expected products ((H2O)5CrI)2+ (50%), ((H2O)5CrOC(NH2)CH3)3+ (18%), and ((H2O)5CrCH2CONH2)2+ (30%).
ChemInform Abstract: Thorium and Uranium Porphyrins. Synthesis and Crystal Structure of Bis(acetylacetonato)(2,3,7,8,12,13,17,18‐octaethylporphyrinato)thorium(IV).
Authors: DORMOND A. , BELKALEM B. , CHARPIN P. , LANCE M. , VIGNER D. , FOLCHER G. , GUILARD R. 
Published: May 2016

AbstractThe reaction of the tetrachlorides (I) with the porphyrins (II) affords the dichloro complexes (III) which react with sodium acetylacetonate to give the derivatives (IV).
ChemInform Abstract: Sugar Complexation with Uranium Ion. Synthesis, Spectroscopic and Structural Analysis of UO2‐Fructose Adducts.
Authors: TAJMIR‐RIAHI H. A. 
Published: May 2016

Abstractβ‐D‐Fructose reacts with hydrated uranyl salts to give the 1:1 adducts (I) which are characterized by FT‐IR spectroscopy, molar conductivity, and X‐ray powder diffraction measurements.
ChemInform Abstract: Metal Boranates and Boranatometallates. Part 13. Preparation and Molecular Structure of Uranium(III) Tetrahydridoborate‐3‐tetrahydrofuran.
Authors: MAENNIG D. + , NOETH H. + 
Published: May 2016

AbstractThe title compound, U(BH4)3(THF)3, is formed from UH3 and diborane in the presence of THF as a solvent with 4% yield.
ChemInform Abstract: A General Method for the Selective Binding and Activation of One Aldehyde Enantioface: Synthesis and Reactivity of Rhenium Aldehyde Complexes ((η5‐C5H5)Re(NO)(PPh3)(η2‐RCH=O))+PF‐ 6.
Authors: FERNANDEZ J. M. , EMERSON K. , LARSEN R. H. , GLADYSZ J. A. 
Published: May 2016

AbstractThe reaction of (I) with HPF6 easily generates the chiral coordinatively unsaturated pyramidal cation (II), which on addition of aldehydes (III) binds one aldehyde enantioface to give (IV).
ChemInform Abstract: Hydrogen Bonding in Metalloporphyrins. Mechanistic Study of the Reactions of (Tetraphenylporphinato)iron(III) Azide with Imidazole and N‐Methylimidazole.
Authors: BYERS W. , COSSHAM J. A. , EDWARDS J. O. , GORDON A. T. , JONES J. G. , KENNY E. T. P. , MAHMOOD A. , MCKNIGHT J. , SWEIGART D. A. , TONDREAU G. A. , WRIGHT T. 
Published: May 2016

AbstractThe title reaction is studied in acetone and dichloromethane.
ChemInform Abstract: Dinuclear Complexes with a μ‐Cyano Ligand. Part 12. Synthesis and Characterization of cis‐((aa)2FCr‐NC‐Fe(CN)4NO) (aa: 1,3‐Propanediamine and 1,2‐Cyclohexanediamine) Kinetics of the Anation in the Solid State.
Authors: CORBELLA M. , MONFORT M. , RIBAS J. 
Published: May 2016

AbstractThe new mixed complex salts (I) are prepared from the analogous perchlorates by anion exchange in aqueous solution.
ChemInform Abstract: Octahedral Nickel(II) Dithiocarboxylates.
Authors: BORER L. L. , KONG J. , SINN E. 
Published: May 2016

AbstractThe heterocyclic zwitterionic 1,3‐dimethylimidazoliumdithiocarboxylate reacts with NiCl2 or (NEt4)2(NiCl4) and with Ni(II)‐nitrate in acetonitrile to give the paramagnetic octahedral Ni complexes (I).
ChemInform Abstract: Observations on the Structure and Magnetic Properties of Dinuclear Copper(II) Complexes Derived from Flexible Dinucleating Schiff Base Ligands.
Authors: ADAMS H. , BAILEY N. A. , FENTON D. E. , MOODY R. , LATOUR J. M. 
Published: May 2016

AbstractTreatment of appropriate Schiff bases with copper(II) ethanoate in the presence of a bridging ligand X results in the formation of complexes of type (I) and (II).
ChemInform Abstract: Ruthenium‐Modified Proteins. Reactions of cis‐(Ru(NH3)4(OH2)2)2+ and cis‐(Ru(en)2(OH2)2)2+ with Azurin, Myoglobin and Cytochrome c.
Authors: CHE C.‐M. , MARGALIT R. , CHIANG H.‐J. , GRAY H. B. 
Published: May 2016

AbstractReactions of the Ru title complexes generated by Zn(Hg) reduction of cis‐(RuL4Cl2)+ (L: NH3 or 2 L: en), with Pseudomonas aeruginosa azurin (Az), horse heart myoglobin (Mbh), and horse heart cytochrome c (cyt c) give Ru‐labelled proteins.
ChemInform Abstract: Reaction of Bromo Derivatives of 6β‐Bromocholest‐4‐en‐3‐one with NaBH4 and 13C‐NMR Spectroscopic Characterization of the Reduction Products.
Authors: ROEMER J. + , SCHELLER D. , GROSSMANN G. 
Published: May 2016

AbstractThe NaBH4 reduction of the title compound (Ia) was studied earlier and, unexpectedly, the formation of the corresponding derivative of type (III) ‐ i.e. the compound (III) (R1 to R3 = ‐H) ‐ was observed.