bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Oxidation of Alkynes Catalyzed by Mo(VI) and W(VI) Polyoxometalates.
Authors: BALLISTRERI F. P. , FAILLA S. , SPINA E. , TOMASELLI G. A. 
Published: May 2016

AbstractTerminal (I) and internal alkynes (V) are oxidized with hydrogen peroxide in the presence of Mo(VI) or W(VI) polyphosphates, yielding mainly the ketones or diketones (II) or (VI) and the carboxylic acids (III), (IV), and (VII) depending on the catalyst used.
ChemInform Abstract: 2,2′‐Bifurylidene‐5,5′‐diones, Coumarins, 3a,7a‐Dihydro‐1H‐inden‐1‐ones, and 5H‐Furo(3,2‐b)pyran‐5‐ones from Propyne and Carbon Monoxide.
Authors: RAUTENSTRAUCH V. , MEGARD P. , GAMPER B. , BOURDIN B. , WALTHER E. , BERNARDINELLI G. 
Published: May 2016

AbstractThe reaction of (I) with (II) is reinvestigated yielding a complex product mixture which contains five major components: the known product (III) as well as (IV) and (Va)‐(VIIa) (X‐ray analysis of (VIa): space group C2/c with Z = 8, and of (VIIa): P21/c with Z=4).
ChemInform Abstract: Phase‐Transfer‐Catalyzed Synthesis of Oligoethylene Glycols and Derivatives.
Authors: BARTSCH R. A. , CASON C. V. , CZECH B. P. 
Published: May 2016

AbstractThe α,ω‐diols (I) undergo base‐induced coupling with the chloroethyl tetrahydropyranyl ethers (II) in the presence of a phase‐transfer catalyst, yielding the oligoethylene glycols (III) after deprotection by acidic hydrolysis.
ChemInform Abstract: Hydrocarbon Analogue of the Squarate Dianion. Evidence for Its Possible Aromaticity and the Examination of Its Behavior with Two Quenching Agents.
Authors: THORSTAD W. T. , MILLS N. S. , BUCKELEW D. Q. , GOVEA L. S. 
Published: May 2016

AbstractThe dianion salt (III) mentioned in the title is generated by twofold deprotonation of 1,2‐dimethyl‐3,4‐dimethylenecyclobutane (I) with butyllithium (II) under two different conditions.
ChemInform Abstract: A Reexamination of the Acid‐Catalyzed Reaction of Ketals with 1,2‐Bis‐(trimethylsiloxy)cyclopentene.
Authors: WU Y.‐J. , BURNELL D. J. 
Published: May 2016

AbstractThe cyclohexanone acetals (I) react with 1,2‐bis(trimethylsiloxy)cyclopentene (II) in the presence of boron trifluoride etherate to give the spirocyclic dione (III).
ChemInform Abstract: Ligand‐Coupling Through σ‐Sulfurane Formed on Treatment of Sulfilimines with Hydride.
Authors: KIM K. S. , JUNG I. B. , KIM Y. H. , OAE S. 
Published: May 2016

AbstractThe sulfilimines (I) react with lithium alanate to give the sulfides (II) and tosylamide (III).
ChemInform Abstract: The Fixing Role of the tert.‐Butyl Group in the Conformational Properties of Acyclic Sulfur Compounds. Synthesis and Conformational Analysis of 2‐tert.‐Butylthioderivatives of 1‐Phenylethanol and Their O‐Methyl Analogues.
Authors: FERNANDEZ L. , LLERA J. M. , ZORRILLA F. , ALCUDIA F. 
Published: May 2016

AbstractThe title compounds (I) are synthesized starting from bromoacetophenone and their conformational equilibria are established by NMR.
ChemInform Abstract: Chalcogenolates. Part 192. S‐Bis(trimethylsilyl)amino Esters of Dithiocarbamic Acids. Part 1. Synthesis and Properties.
Authors: SCHUBERT G. , GATTOW G. 
Published: May 2016

AbstractThe title compounds (III) are prepared by the three methods outlined in the scheme and the yields are compared.
ChemInform Abstract: An Efficient Synthesis of the Highly Tumorigenic anti‐Diol Epoxide Derivative of Benzo(c)phenanthrene.
Authors: PATAKI J. , DI RADDO P. , HARVEY R. G. 
Published: May 2016

AbstractOne key step in the preparation of the epoxide (XII) mentioned in the title is the acid‐induced cyclization of 2‐(2‐naphthylethyl)‐1,4‐cyclohexanedione (III), producing a mixture of the benzophenanthrene derivative (IV) and its benzanthracene analogue (V) with predominance of the former.
ChemInform Abstract: 4,6‐Diphenylthieno(2,3‐c)furan.
Authors: SCHOENING A. + , DEBAERDEMAEKER T. , ZANDER M. , FRIEDRICHSEN W. 
Published: May 2016

AbstractThe title compound (III) is prepared as a heterosubstituted isobenzofuran analogue from the iodide (I).
ChemInform Abstract: Regiospecific Palladium‐Catalyzed Tandem Cyclization‐Anion Capture Processes. Carbon‐, Nitrogen‐, and Oxygen‐Centred Nucleophiles.
Authors: GRIGG R. , SRIDHARAN V. , SUKIRTHALINGAM S. , WORAKUN T. 
Published: May 2016

AbstractThe 1,3,8‐trienes (I) undergo Pd‐catalyzed tandem cyclization‐anion capture with the carbanion salts (II) to form the methylenecyclopentanes (III).
ChemInform Abstract: The Use of a Nicotinoyl Group as a Protective Group for Hydroxy and Amino Functions.
Authors: USHIDA S. 
Published: May 2016

AbstractProtection of the hydroxy and amino groups of the compounds (II), using nicotinic anhydride (I), and deprotection of the esters (IIIa) ‐ (IIIc) and amides (IIId), (IIIe) thus obtained, are performed as outlined in the reaction scheme.
ChemInform Abstract: Condensed Pyridazines. Part 7. Reaction of 7‐(Methylsulfonyl)‐1‐phenyl‐1H‐imidazo(4,5‐d)pyridazine with Nucleophiles.
Authors: OISHI E. , YAMADA A. , HAYASHI E. , TANJI K. , MIYASHITA A. , HIGASHINO T. 
Published: May 2016

AbstractCoupling of 7‐chloro‐1‐phenyl‐1H‐imidazo(4,5‐d)pyridazine (I) and the corresponding 7‐methylsulfonyl derivative (V), prepared from (I) as shown in the reaction scheme, with the active methylene compounds (VI) leads to the formation of the 7‐substituted imidazopyridazines (VII).
ChemInform Abstract: Synthesis and Antimicrobial Activity of Some New 2,3‐Dichloroquinoxaline‐6‐sulfonylamino Acid and Dipeptide Derivatives.
Authors: KORA F. A. , HUSSEIN M. E. , EL‐SAYED R. A. , EL‐NAGGAR A. M. 
Published: May 2016

AbstractTwenty‐two derivatives of type (III), (V), (VI) and (VIII) are synthesized.
ChemInform Abstract: Chromone Derivatives. Part 14. Reactions of 5(7)‐(2‐Hydroxyphenyl)‐2,3‐dihydro‐1,4‐diazepine with Methyl Iodide.
Authors: KOSTKA K. , OWCZAREK M. 
Published: May 2016

AbstractDifferent courses of the title reaction are observed with the diazepines (I), (IV) and (VI).
ChemInform Abstract: Synthesis and Crystal Structure of Bis(oxapropylenedithio)tetrathiafulvalene Hexafluorophosphate.
Authors: MEDNE R. S. , KHODORKOVSKII V. YU. , NEILAND O. YA. , ALDOSHINA M. Z. , GOL'DENBERG L. M. , LYUBOVSKAYA R. N. , TAKHIROV T. G. , D'YACHENKO O. A. , ATOVMYAN L. O. 
Published: May 2016

AbstractStarting with the complex (I), the salt (VI) mentioned in the title is synthesized as shown in the reaction scheme.
ChemInform Abstract: Synthesis, Structure and Electrochemical Behavior of a New Dinuclear Mo(0) Carbonyl Complex with Two μ2‐Thiolato Ligands, (Et4N)2(Mo2(CO)7(S,S‐C6H4‐1,2)).
Authors: ZHUANG B. , HUANG L. , HE L. , LU J. 
Published: May 2016

AbstractThe new dinuclear title Mo(0) complex (III) crystallizes in the space group Pnma with Z=4.
ChemInform Abstract: Monocyclopentadienyl Pentafluorothiophenolate Complexes of Molybdenum and Their Interactions with Thallium(I) Ions; Dynamic Nuclear Magnetic Resonance Studies and Crystal and Molecular Structures of (TlMo(SC6F5)2L2(cp)) (L: CO or SC6F5; cp: η5‐C5H5).
Authors: BAKAR W. A. W. A. , DAVIDSON J. L. , LINDSELL W. E. , MCCULLOUGH K. J. , MUIR K. W. 
Published: May 2016

AbstractThe reactions between the chloride (I) and the thiolate (II) afford the complexes (III) or (IV) depending on the reaction conditions.
ChemInform Abstract: Synthesis and Spectroscopic Studies of Cobalt(III) Complexes of the Chiral Pendant‐Arm Macrocycle N,N′,N′′‐Tris((2S)‐2‐hydroxypropyl)‐1,4,7‐triazacyclononane (H3L); Crystal Structure of the Hydrogen‐Bridged Dimer (CoLH3LCo) (PF6)3.
Authors: BELAL A. A. , FARRUGIA L. J. , PEACOCK R. D. , ROBB J. 
Published: May 2016

AbstractThe preparation of the macrocyclic ligand by reaction of (S)‐propylene oxide with 1,4,7‐triazacyclononane is described (yield 71%).
ChemInform Abstract: Photo‐Induced Hydroxylation of Copper Complexes of 2‐Hydroxyazobenzenes.
Authors: SHOSENJI H. , SHIMODA M. , KOIDE Y. , YAMADA K. 
Published: May 2016

AbstractThe reaction of the azo compounds (I) and (IV) with Cu(O‐Ac)2 (III) yields the corresponding copper complexes.
ChemInform Abstract: A Novel Glycosylation Reaction of 2‐Amino‐2‐deoxy‐D‐glucopyranose Using Dimethylphosphinothioate.
Authors: INAZU T. , YAMANOI T. 
Published: May 2016

AbstractReaction of the glucopyranosyl dimethylphosphinothioate (I) with cholestanol (IIa) or its silyl ether (IIb) yields the glucoside (III).
ChemInform Abstract: A Synthetic Approach to Discorhabdin Alkaloids: Hypervalent Iodine Oxidation of p‐Substituted Phenol Derivatives to Azacarbocyclic Spirodienones.
Authors: KITA Y. , YAKURA T. , TOHMA H. , KIKUCHI K. , TAMURA Y. 
Published: May 2016

AbstractThe 4‐(2‐aminoethyl)phenols (I) are coupled with the methoxynaphthoquinone (II) to give the products (III) which are silylated with the ketene silyl acetal (IV), yielding the phenol ethers (V).
ChemInform Abstract: A New Synthesis of (.+‐.)‐Sarkomycin from a β‐Ketophosphonate.
Authors: MIKOLAJCZYK M. , ZURAWINSKI R. , KIELBASINSKI P. 
Published: May 2016

AbstractThe acetonylphosphonate (I) reacts with the 4‐bromobutene (II) to give the unsaturated ketone (III).
ChemInform Abstract: Structure‐Activity Relationship of Odorants with a Bicyclo(2.2.2)octane System.
Authors: SPREITZER H. , BUCHBAUER G. , REISINGER S. 
Published: May 2016

AbstractIn the course of the synthesis of homonojigiku alcohol (VIIa) and its epimer (VIIb), the epimeric pairs of alcohols (V) and (VI) are obtained from the acetates (III) and (IV) by means of standard procedures.
ChemInform Abstract: Synthesis, Characterization, and EPR Studies of Heteropoly Compounds with Iron(III) in Tetrahedral and Octahedral Coordination.
Authors: WEINER H. , LUNK H.‐J. , STOESSER R. + , LUECK R. + 
Published: May 2016

AbstractThe heteropoly compounds (I)‐(IV), which are obtained for the first time by freeze‐drying, are investigated by EPR spectroscopy together with known Fe(III)‐heteropoly compounds, e.g. (V)‐(X).
ChemInform Abstract: High‐Resolution Solid‐State 119Sn NMR Spectroscopy of Ternary Tin Oxides.
Authors: CLAYDEN N. J. , DOBSON C. M. , FERN A. 
Published: May 2016

AbstractThe structurally well characterized ternary tin oxides (I)‐(III) are studied by high‐resolution solid‐state MAS 119Sn NMR spectroscopy and the ease with which the spectra can be obtained from ionic tin compounds without the need for cross‐polarization techniques is demonstrated.
ChemInform Abstract: Direct Evidence of Coordination on the Endocyclic Nitrogen Atom in the Adducts of 2‐Aminoazoles and 2‐Aminoazines with Copper(II) Acetate.
Authors: GARNOVSKY D. A. , SADIMENKO A. P. , OSIPOV O. A. , GARNOVSKY A. D. , ANTSISHKINA A. S. , PORAI‐KOSHITS M. A. 
Published: May 2016

AbstractX‐Ray investigations of the complexes (I) and (II) show the coordinative bond to the heterocyclic amines to be localized at the endocyclic N atom.
ChemInform Abstract: X‐Ray Crystallographic and Theoretical Studies of Factors Affecting the Ease of Reduction of Dioxathiadiazaheteropentalenes.
Authors: CAMILLERI P. , RZEPA H. S. , SLAWIN A. M. Z. , WILLIAMS D. J. 
Published: May 2016

AbstractThe title compounds (I) are assumed to interrupt the photosynthetic electron‐transport pathway in competition with the natural substance ferredoxin in a similar manner to the bipyridinium compounds.
ChemInform Abstract: Hydrolysis and First Ionization Constant of Monoperoxyphthalic Acid.
Authors: JONES P. , HAGGETT M. L. , HOLDEN D. , ROBINSON P. J. , EDWARDS J. O. , BACHOFER S. J. , HAYDEN Y. T. 
Published: May 2016

AbstractThe dissociation constant for the carboxy proton is evaluated by means of two independent methods: potentiometric titration (3.05) and ‐ more reliable ‐ distribution between octanol and H2O (2.96).
ChemInform Abstract: Dimerization Reaction of N‐(Arylmethylene)dehydroalanine Methyl Esters.
Authors: WULFF G. , LINDNER H. J. , BOEHNKE H. + , STEIGEL A. , KLINKEN H. T. 
Published: May 2016

AbstractHighly reactive esters (II) are prepared in situ from L‐serine esters (I).
ChemInform Abstract: Nucleophilic Cleavage of (2S,3S)‐3‐Phenylglycidol.
Authors: TAKANO S. , YANASE M. , OGASAWARA K. 
Published: May 2016

Abstract(2S,3S)‐3‐Phenylglycidol (I) reacts with the nucleophiles (II), (VI), (VII), and (X) to give predominantly the diols (IV), (VIII), and (XI) with inversion of the configuration at the benzylic position.
ChemInform Abstract: Reaction of Tetranitrodibenzo‐18‐crown‐6 with Sodium Alkoxides.
Authors: IVANOV E. I. , POLISHCHUK A. A. , AVRAAMOV S. M. , IVANOVA R. YU. 
Published: May 2016

AbstractThe tetranitrodibenzo‐18‐crown‐6 (I) is coupled with sodium methylate (II) in an aprotic polar solvent to give the dinitrodimethoxybenzene (III), the trimethoxy compound (IV), and the dinitrodimethoxy crowns (V).
ChemInform Abstract: Wavelength‐Dependent Photochemical Ligand Substitution in W(CO)5L (L: Pyridine, Piperidine).
Authors: MORALEJO C. , LANGFORD C. H. , SHARMA D. K. 
Published: May 2016

AbstractThe photochemical replacement of L by solvents in the title complex is studied in both alkane and alkene solvents using picosecond spectroscopy.
ChemInform Abstract: Potassium Chlorochromate on a Solid Support: A Convenient and Mild Reagent for the Oxidation of Alcohols.
Authors: CARLSEN P. H. J. , HUSBYN M. , BRAENDEN J. E. , ELIASON R. 
Published: May 2016

AbstractKCrO3Cl supported on alumina or silica gel is stable when kept dry; not carefully dried reagents and solvents lower the yields.
ChemInform Abstract: Electrochemical Reduction of Organic Compounds. Part 11. Synthesis of Dispirobicyclobutanes.
Authors: STRELOW T. , VOSS J. , ADIWIDJAJA G. 
Published: May 2016

AbstractThe electrochemical preparation of the dispirobicyclobutane (III) from the bispirocyclobutane (II) (space group P212121) is described.
ChemInform Abstract: N,7,7‐Tricyanoquinomethanimines: New Electron Acceptors for Organic Metals.
Authors: BRYCE M. R. , DAVIES S. R. 
Published: May 2016

AbstractConsecutive TiCl4‐mediated coupling reaction of the p‐quinones (I) with malononitrile (II) and bis(trimethylsilyl)carbodiimide (IV) yields the electron acceptors (V).
ChemInform Abstract: Reinvestigation of Cycloaddition of Nitrosobenzene Towards 1,3‐Diphenylisobenzofurans.
Authors: LIN C.‐T. , DIN L.‐W. , WANG S.‐L. 
Published: May 2016

AbstractReaction of the diphenylisobenzofuran (I) with nitrosobenzene (II) results in ring cleavage, producing the nitrone (III).
ChemInform Abstract: Reactions of ortho‐Manganated Aryl Ketones, Aldehydes, and Amides with Alkynes; A New Synthesis of Inden‐1‐ols and Indenones.
Authors: ROBINSON N. P. , MAIN L. , NICHOLSON B. K. 
Published: May 2016

AbstractThe ortho‐manganated acetophenone (I) reacts with the acetylenes (II) to produce the indenols (III), while the arylmanganese complexes (IV) are coupled with the acetylene (IIc), yielding the indenones (V).
ChemInform Abstract: Retention of the Optical Activity During the (3,3)Sigmatropic Rearrangement of a Vinyl Furfuryl Ether.
Authors: KUZNETSOVA S. V. , EGOROV A. M. , ANISIMOV A. V. , VIKTOROVA E. A. 
Published: May 2016

AbstractThe optically active furylethyl propenyl ether (‐)‐(IV), prepared from the allyl ether (+)‐(III), is rearranged upon thermal treatment, producing the optically active aldehyde (+)‐(V).
ChemInform Abstract: Novel Electron Acceptors Bearing a Heteroquinonoid System. Part 1. Synthesis and Conductive Complexes of 5,5′‐Bis(dicyanomethylene)‐5,5′‐dihydro‐δ2,2′‐bithiophene and Related Compounds.
Authors: YUI K. , ASO Y. , OTSUBO T. , OGURA F. 
Published: May 2016

AbstractNovel electron acceptors bearing a heteroquinoid system such as (III) and (IV), which can be potential components of organic electric conductors, are prepared.
ChemInform Abstract: Synthesis of Five‐Membered Lactams by α‐Carbamoyl Radical Cyclizations.
Authors: SATO T. , WADA Y. , NISHIMOTO M. , ISHIBASHI H. , IKEDA M. 
Published: May 2016

AbstractFree‐radical cyclization of N‐allyl‐α‐carbamoyl radicals generated from substrates such as (I), (IV), (VI) are studied in some detail.
ChemInform Abstract: Synthesis of Pyrrole‐3,4‐diacetic Acid and Its Derivatives.
Authors: CHIUSOLI G. P. , COSTA M. , REVERBERI S. 
Published: May 2016

AbstractPalladium‐catalyzed oxidative alkoxycarbonylation of the dipropargylamines (I) leads to the formation of the 3,4‐bis(alkoxycarbonylmethylene)pyrrolidines (IV) which are isomerized, forming the pyrrole‐3,4‐diacetic acid esters (V) or (VI).
ChemInform Abstract: Synthesis of 1‐Amino‐1H‐1,2,4‐triazoles.
Authors: LAUS G. , KLOETZER W. + 
Published: May 2016

AbstractAmination of the substituted 4‐amino‐1,2,4‐triazoles (I) yields the 1,4‐diamino‐1,2,4‐triazolium salts (III) which react with benzaldehyde (IV) to form the 1‐benzylidenamino‐1,2,4‐triazoles (V).
ChemInform Abstract: Asymmetric Reductive Amination of Cycloalkanones. Part 8. EPC‐Synthesis of Aryl‐Substituted cis‐(4aR,10bR)‐ and cis‐(4aS,10bS)‐Octahydrophenanthridines.
Authors: NACHTSHEIM C. M. , FRAHM A. W. 
Published: May 2016

AbstractPictet‐Spengler cyclocondensation of the cis‐2‐arylcyclohexanamines (I) with formaldehyde (II) leads to the formation of the title compounds (IV) via the postulated intermediates (III).
ChemInform Abstract: Mild Synthesis of N‐Alkyl‐ and N‐Acyl‐β‐carboline Anhydro‐Bases Using Trifluoromethanesulfonates.
Authors: DODD R. H. , POISSONNET G. , POTIER P. 
Published: May 2016

AbstractN‐Alkylation of the pyridoindoles (I) with alkyl trifluoromethanesulfonates yields the salts (V) which are converted into the β‐carboline anhydro‐bases (VI) on treatment with cesium carbonate.
ChemInform Abstract: (4 + 2)Cycloadducts of 5‐Benzyloxy‐2‐pyridone with Electron‐Deficient Dienophiles. Regio‐ and Stereochemistry.
Authors: HERDEIS C. , HARTKE C. 
Published: May 2016

AbstractCoupling of the pyridone (I) with the ene derivatives (II), (IV), (VII), and (IX) gives cycloadducts as outlined in the reaction scheme.
ChemInform Abstract: Heterocyclic Mesomeric Betaines. Part 5. Synthesis and Cycloaddition Reactions of Hetero Derivatives of the 2‐Methylene‐1,2‐dihydro‐1,3‐phenalenylene Dianion.
Authors: OLLIS W. D. , STANFORTH S. P. , RAMSDEN C. A. 
Published: May 2016

AbstractConjugated heterocyclic mesomeric betaines such as (IV), which are isoconjugate with the 2‐methylene‐1,2‐dihydro‐1,3‐phenalenylene dianion, are prepared by base treatment of the salt (III).
ChemInform Abstract: Pteridines. Part 109. Synthesis, Oxidations, and Reactions of 6‐ and 7‐Hydroxy‐2‐thiolumazines.
Authors: BARTKE M. , PFLEIDERER W. 
Published: May 2016

AbstractThe thiolumazines (III) are oxidized, yielding the sulfinates (V) or the sulfonates (VIII).
ChemInform Abstract: Gas Phase Ion Chemistry of Siloxide and Silamide Ions by Using the Flowing Afterglow. Unusual Rearrangements Involving SiO and SiS Bond Formation.
Authors: O'HAIR R. A. J. , SHELDON J. C. , BOWIE J. H. , DAMRAUER R. , DEPUY C. H. 
Published: May 2016

AbstractSiloxide ions undergo O/S exchange reactions with suitable sulfur‐containing neutrals such as CS2 and MeNCS.
ChemInform Abstract: Syntheses, Structures, Selected Physical Properties, and Band Electronic Structures of the Bis(ethylenediseleno)tetrathiafulvalene Salts (BEDSe‐TTF)2X, X‐ = I3‐, AuI2‐, and IBr2‐.
Authors: WANG H. H. , MONTGOMERY L. K. , GEISER U. , PORTER L. C. , CARLSON K. D. , FERRARO J. R. , WILLIAMS J. M. , CARISS C. S. , RUBINSTEIN R. L. , WHITWORTH J. R. , EVAIN M. , NOVOA J. J. , WHANGBO M.‐H. 
Published: May 2016

AbstractBis(ethylenediseleno)tetrathiafulvalene (VI), prepared from vinylene trithiocarbonate (I), is converted into its salts (VIII) by electrocrystallization.
ChemInform Abstract: Metal Complexes of Alkylating Agents. Part 5. Complexes of Phosphoramide Mustard Derivatives.
Authors: JOESTEN M. D. , NEIDERT J. B. 
Published: May 2016

AbstractThe title ligands (I) and (II) (preparation described) react with a variety of metal perchlorates (metal: Al, Ba, Co, Cu, La, Li, Mg, Mn, Ni) to give complexes of different stoichiometries (tables).
ChemInform Abstract: Synthesis and Molecular Structure of Two Members of a New Family of Zinc Organophosphates.
Authors: ORTIZ‐AVILA Y. , RUDOLF P. R. , CLEARFIELD A. 
Published: May 2016

AbstractBoth compounds (I) and (II) crystallize in the space group Pbca with Z = 8 and have layers formed by phosphate groups bridging the tetrahedral zinc atoms, which undulate perpendicularly to the layer direction.
ChemInform Abstract: Electron Transfer in the Mixed‐Valence Complexes (E)‐ and (Z)‐1,2‐Bis(1′‐ethyl‐1‐ferrocenyl)‐1,2‐dimethylethylene.
Authors: DONG T.‐Y. , KE T.‐J. , PENG S.‐M. , YEH S.‐K. 
Published: May 2016

AbstractThe coupling reaction of the acetylferrocene (I) by the TiCl4/LiAlH4 reagent yields the two isomers (II) and (III), which are separated by fractional recrystallization.
ChemInform Abstract: Preparation and Characterization of Four‐ and Five‐Coordinate Rhodium(I) Complexes. Crystal Structures of Chloro(2‐(phenylazo)pyridine)(norbornadiene)rhodium(I), (2,2′‐Bipyridyl)(norbornadiene)rhodium(I) Chloride Hydrate, and Chloro(2,2′‐bipyridyl)(norbornadiene)rhodium(I).
Authors: ROBERTSON J. J. , KADZIOLA A. , KRAUSE R. A. , LARSEN S. 
Published: May 2016

AbstractThe ability of 2‐(phenylazo)pyridine (II) to stabilize lower oxidation states is utilized in the preparation of the new five‐coordinate Rh(I) complex (III).
ChemInform Abstract: Preparation and Characterization of the trans‐Dioxoosmates, (OsO2(CN)2X2)2‐, X: NCO, NCS, SeCN, 1/2 (C2O4); (OsO2(CN)2X2), X: py, 1/2 bipy and (OsO2(CN)2X)2‐ 2, X: OH, OCH3.
Authors: SARTORI C. , PREETZ W. 
Published: May 2016

AbstractBy careful acidification of aqueous solutions of (I) KCN with acetic or oxalic acid the osmyl complexes (III) or (V) are prepared for the first time.
ChemInform Abstract: Stereoselective Dioxygenation of a Racemic Tryptophan Derivative Catalyzed by Chiral Manganese Porphyrins.
Authors: OHKUBO K. , SAGAWA T. , KUWATA M. , HATA T. , ISHIDA H. 
Published: May 2016

AbstractTreatment of the racemic N‐acetyltryptophan methyl ester (II) with oxygen in the presence of the chiral manganese porphyrin catalyst (I) results in ring cleavage, forming the optically active propionate (III), together with the aniline (IV), the isonitrile (V), and minor side‐products.
ChemInform Abstract: Use of a Recombinant Bacterial Fructose‐1,6‐diphosphate Aldolase in Aldol Reactions: Preparative Syntheses of 1‐Deoxynojirimycin, 1‐Deoxymannojirimycin, 1,4‐Dideoxy‐1,4‐imino‐D‐arabinitol, and Fagomine.
Authors: VON DER OSTEN C. H. , SINSKEY A. J. , BARBAS C. F. III , PEDERSON R. L. , WANG Y.‐F. , WONG C.‐H. 
Published: May 2016

AbstractA combined enzymatic aldol condensation and catalytic intramolecular reductive amination is used in the synthesis of the title alkaloids (I), (IV), (V) and (VIII).
ChemInform Abstract: Chemistry of Opium Alkaloids. Part 31. Face Selectivity of the Diels‐Alder Reaction of Thebaine‐Like Morphinandienes, a Computational Approach.
Authors: LINDERS J. T. M. , MAAT L. 
Published: May 2016

AbstractMolecular mechanics (MMP2(85)) are proven to be well‐suited to reproduce X‐ray structures of morphinans such as desoxycodeine‐A and can be considered to give reliable structural informations on compounds for which no X‐ray data are available.
ChemInform Abstract: Dependence of the Band Bending of the Oxide Semiconductors on pH
Authors: MATSUMOTO Y. , YOSHIKAWA T. , SATO E. 
Published: May 2016

Abstractis studied by measurements of the flatband potential, the photopotential, and rest dark potential for the n‐type semiconductors TiO2, SrTiO3, ZnO, and Zn2TiO4 in the absence of any redox species.
ChemInform Abstract: Effect of the Nature of the Precursor on the Electrocatalytic Properties of Thermally Prepared Ruthenium Oxide.
Authors: ARDIZZONE S. , FALCIOLA M. , TRASATTI S. 
Published: May 2016

AbstractRuOx is deposited on Ti‐substrates by thermal decomposition of either Ru(NO)(NO3)3 to prepare Cl‐free RuOx or RuCl3 resulting in RuOx containing residual chlorine and the surface and electrocatalytic properties of the resulting electrode materials are compared.