bluuebunny/crossref_metadata_2025_split huggingface dataset:
The PERMA model of well‐being and student engagement amid Covid‐19: A two‐wave study among a sample of Filipino university students
Authors: Miranda Jonee O. , Tulabut Olga Angelinetta P. , De Ala Cherry Lou , Gonzales Abigail , M. Embalsado Justin Vianey , Estacio Lee Vergel , Mandap Irish , Medina Aira Joy Keynn , Montoya Mary Anne Joseph , Balilu Beatriz , Leon June Rivera‐De , Mangalus Roger , Pare Ericka Lance , Cruz Reymond Neal C. 
Published: September 2024

AbstractPrevious research has underscored the negative effects on students of the abrupt shift to online delivery of education due to the COVID‐19 pandemic. Positive education applies the principles of positive psychology to education, which highlights the importance of students' well‐being and fosters holistic development. This study investigated whether students' well‐being at the start of the semester can predict their academic engagement mid‐way through the semester. We collected data on students' well‐being and academic engagement in two waves; first, at the beginning of the semester (Time 1) and then 3 months in the semester (Time 2). We tested the students' general well‐being and the positive emotion, engagement, relationships, meaning, accomplishment (PERMA) elements at Time 1 with their academic engagement in terms of behavioral, emotional, and cognitive facets at Time 2. Our results show that general well‐being at Time positively predicts their total academic engagement and all engagement facets. However, among the PERMA elements, the Meaning element is not correlated with students' engagement or any of its facets. We also tested whether there was a significant change in student well‐being and engagement from the start of the semester and midway through. We found that there is a significant small increase in well‐being and engagement. Our findings suggest the importance of well‐being as a potentially positive resource for students where students with better well‐being tend to be more academically engaged. Educational institutions may consider fostering student well‐being in their goals to improve the academic success of students.
The mediating effect of adolescents' emotional regulation strategies on their psychological resilience
Authors: Üstündağ Alev 
Published: September 2024

AbstractThe purpose of this study was to analyse emotional regulation and psychological resilience in adolescents, exploring various variables and their interrelationships. A descriptive and relational survey model was used in the study, which included a sample of 967 adolescents in Turkey. Data were collected using a “Personal Information Form,” the “Emotion Regulation Scale for Adolescents” and the “Adolescents Psychological Resilience Scale.” The results showed that adolescents' psychological resilience differed according to gender and maternal education level, while emotional regulation strategies differed according to gender, socioeconomic level and parental education level. There was a relationship between adolescents' psychological resilience and their internal functional emotional regulation strategies. Furthermore, factors such as peer support, school support, adjustment and empathy were found to be effective in improving adolescents' emotional regulation strategies.
Physical medicine and rehabilitation clinical experiences: A narrative review of curricula and educational interventions
Authors: Vernacchia Cara , Brown Elizabeth , Mhatre Priya , Rydberg Leslie 
Published: September 2024

AbstractPhysical medicine and rehabilitation (PM&R) is a specialty of medicine that focuses on function and the care of people with disabilities. Many medical schools offer PM&R content by means of PM&R clerkships for career development purposes with varying curricula and assessments; however, there is limited information regarding the optimal way to teach clinical skills relating to the field of PM&R. This narrative review study was performed to evaluate PM&R specific clinical curricular interventions. The review included a PubMed search that yielded 63 articles and a Cumulated Index to Nursing and Allied Health Literature (CINAHL) search of 175 articles. A total of 14 articles were selected for review. PM&R clerkships were found to have a variety of educational interventions, including inpatient and outpatient clinical experiences, lectures, Objective Structured Clinical Examinations (OSCEs), case discussions, written examinations, physical examination sessions, cadaver sessions, small group discussions, and virtual education. PM&R rotations can improve neurologic and musculoskeletal physical examination skills, PM&R specific knowledge, and confidence in PM&R skills. More research is needed to determine the optimal methods to teach and assess PM&R knowledge and skills in the clinical setting to drive future PM&R curriculum development and educational innovations.
The Impact of Depression on Adherence to Diabetes Self‐Management Behaviors in Breast Cancer Survivors
Authors: Vasa Devarshi , Guerra Lauren , Goel Mita S. , Harris Yael Tobi , Lin Jenny J. 
Published: September 2024

ABSTRACTObjectiveBreast cancer survivors (BCS) have higher rates of depression which is associated with lower adherence to medications, diet, and physical activity. Managing diabetes (DM) requires adherence to several of these self‐management behaviors (SMB), and BCS have an increased risk of DM. We investigated whether depressive symptoms were associated with adherence to DM SMB in a cohort of BCS.MethodsBCS with DM were surveyed semiannually for 2 years. Depression was assessed with the Hospital Anxiety and Depression Scale (HADS). Adherence to DM medication, diet, and physical activity was self‐reported using the Medication Adherence Report Scale (MARS), Summary of Diabetes Self‐Care Activities Assessment (SDSCA), and International Physical Activity Questionnaire (IPAQ), respectively. Using generalized linear equation modeling, the association of depressive symptoms with nonadherence to SMB was assessed, adjusting for age, race, marital status, education level, and beliefs about cancer and DM risk.ResultsAmong 244 BCS with DM, those who were nonadherent to medication, diet, and/or physical activity had higher depression scores (p < 0.01). In adjusted analyses, higher depression scores were independently associated with dietary (OR = 1.16, p < 0.001) and physical activity nonadherence (OR = 1.18, p < 0.001) but not with medication nonadherence. Concerns about medications was independently associated with medication nonadherence (OR = 1.17, p = 0.024).ConclusionsHigher depression scores are associated with nonadherence to DM SMB in this cohort of BCS. These findings highlight the importance of addressing depressive symptoms in BCS to help improve adherence to DM medications, diet, and physical activity.
Bronchopulmonary dysplasia and ventilation‐associated outcomes after pediatric tracheostomy
Authors: Chorney Stephen R. , Beams Dylan R. , Nadar Arushii , Afolabi Folashade , Gelfand Andrew , Brooks Rebecca , Kou Yann‐Fuu , Johnson Romaine F. 
Published: September 2024

AbstractObjectivesThe objective of this study is to determine the time to ventilator liberation and decannulation after tracheostomy placement in children with bronchopulmonary dysplasia (BPD) and pulmonary hypertension.MethodsA prospective cohort study included all children (<18 years old) who underwent tracheostomy between 2015 and 2021 with or without a diagnosis of BPD. The primary outcomes were time to ventilator liberation, tracheostomy decannulation, or death with tracheostomy in place.ResultsA total of 303 children met inclusion with a median (interquartile range [IQR]) age at tracheostomy of 6.9 (IQR: 4.0–49.5) months. A diagnosis of BPD was made for 42% (N = 127) and this group was younger (5.1 vs. 24.5 months, p < .001) and more often had pulmonary hypertension (68% vs. 24%, p < .001). Children with BPD spent a median of 2.9 years (IQR: 1.6–4.0) on ventilation compared to 1.9 years (IQR: 0.9–3.7) for children without BPD (p = .009). The time to decannulation was greater among children with BPD (3.4 vs. 1.8 years, p < .001). However, unadjusted estimates of ventilator liberation (hazard ratio [HR]: 1.05, 95% confidence interval [95% CI]: 0.77–1.44) and decannulation (HR: 1.11, 95% CI: 0.74–1.66) over time were not prolonged by BPD. Pulmonary hypertension was associated with shorter time to death (adjusted HR [aHR] = 1.99, 95% CI: 1.17–3.38, p = .01), while BPD was associated with longer time to death (aHR: 0.38, 95% CI: 0.22–0.67, p = .001).ConclusionBPD is associated with increased ventilation and duration of tracheostomy but over time many children with BPD will wean off the ventilator and be decannulated. Pulmonary hypertension and not BPD is associated with increased time to death after tracheostomy.
Implementation of Entanglement Witnesses with Quantum Circuits
Authors: Shen Shu‐Qian , Gao Xin‐Qi , Zhang Rui‐Qi , Li Ming , Fei Shao‐Ming 
Published: September 2024

AbstractEntanglement witnesses are economical tools for the experimental detection of quantum entanglement. Quantum algorithms for entanglement detection have recently attracted considerable attention. Based on block encoding techniques and state preparation methods, the implementation of several types of entanglement witnesses using quantum circuits without quantum state tomography is proposed. Further, explicit quantum circuits for the block encoding of some special matrices are presented.
Value Addition to α‐Position of Carbonyl: Synthesis of 2‐Arylidene and Halocycloalkanones
Authors: Bhatt Gaurang J. , Kahar Nidhi , Purohit Ashish C. , Deota Pradeep T. , Dhasmana Yogesh , Chopra Deepak 
Published: September 2024

AbstractBenzocyclotrimers (BCTs) like trindane and dodecahydrotriphenylene (DDHTP) have attracted attention as key components for the construction of higher polycyclic aromatic hydrocarbons due to their aesthetic architecture that is useful in developing beautiful carbocycles of higher order. However, there are limited reports on these ring systems since their functionalization is a formidable task. Our personal engagement with these scaffolds prompted us to explore the synthesis of their synthetically useful derivatives. Herein, we report syntheses of a new series of their derivatives by exploiting the α–position of these cycloalkanones using classical Claisen‐Schmidt condensation reaction as well as simple and practical α‐Csp3–H halogenation with suitable halogenating agents.
Green Synthesis of Bimetallic Cu−Cd Nanoparticles and its Catalytic Activity in Pyrido [2,3‐d;6,5‐d] Dipyrimidine Derivatives
Authors: Kopperundevi J. , Ashokkumar D. , Gopalakrishnan M. , Ramalingam G. 
Published: September 2024

AbstractGreen synthesis nanoparticles have gained interest in recent years due to their environmental friendliness and sustainability. The current study focuses on the green synthesis of BMNP using spearmint leaves as a reducing and stabilizing agent. Because of their excellent catalytic characteristics, the synthesized bimetallic nanoparticles function as an effective catalyst in pyrido[2,3‐d:6,5‐d] pyrimidine derivatives. The synthesized nanoparticles are characterized using a variety of techniques, including FT‐IR analysis, SEM & EDX, XRD, and TEM. The FT‐IR study shows a reduction in functional groups in the leaf extract, confirming the metal nanoparticles’ stretching. SEM and EDX studies confirm the shape and elemental composition of bimetallic nanoparticles. XRD investigation showed that the synthesized NPs are crystalline, and the Scherrer equation was used to calculate the average crystallite size. The calculated size was 49 nm. TEM analysis confirms the core‐shell nature of BMNPs. The synthesized nanoparticles acted as a superior catalyst in pyrido[2,3‐d:6,5‐d] dipyrimidines derivatives. in the synthetic procedure, BMNPs enhanced the catalytic activity and reduced the reaction time with more yield, Compared to the previous study. and the synthesized compound [1–5] has been confirmed by FT‐IR, 1H‐NMR, and 13C‐NMR analysis. and it has given better results in in‐vivo anti‐diabetic activity by Streptozotocin nicotinamide. This induced model adult male albino Wistar derivatives show significant fasting blood glucose levels when compared to metformin hydrochloride. and its evaluated molecular docking study, exhibit excellent CDDOCKER energy.
Lead‐Free Perovskite With Efficient Tellurium Ion Activation for Multifunctional Applications
Authors: Han Lulu , Zhang Shiwen , Yuan Junheng , Wang Tianchi , Yao Shuyi , Song Hao , Mu Dedan , Sun Jiabo , Yang Xiuxia , Xu Xuhui 
Published: September 2024

AbstractLead‐free perovskite materials have received extensive attention due to their non‐toxicity, super environmental stability and adjustable photoelectric properties. However, the inherent problems of low luminous efficiency and low photoluminescence quantum yields (PLQYs) limit its development in multifunctional applications. Here, Te4+ doped Cs2ZrCl6 with high luminous efficiency and stability for multifunctional applications are developed. Te4+ ions are used as emission centers to improve the optical properties of Cs2ZrCl6 to make efficient and stable single‐component white light‐emitting diodes (WLEDs), and can be used as scintillator materials to improve scintillation performance to achieve high‐resolution and low‐dose X‐ray imaging detection. In addition, it is found for the first time that Te4+ ions can be introduced into the trap center, so that the Cs2ZrCl6:Te4+ perovskite material exhibits excellent persistent luminescence (PersL) and mechanoluminescence (ML) after X‐ray radiation, which has potential applications in the fields of delayed imaging and stress sensing. This work provides a method for designing lead‐free perovskites with high optical performance and scintillating properties, as well as developing multifunctional applications.
Nanomotor‐Driven Targeting Chimeras as Accelerators for the Degradation of Extracellular Proteins
Authors: Ning Yujun , Li Bin , Liu Yixin , Lu Yanwei , Huang Xuedong , Liu Baohong 
Published: September 2024

AbstractTargeted protein degradation (TPD) is emerging as a therapeutic paradigm and a serviceable research tool in chemical biology and disease treatment. However, without driving sources, most targeting chimeras (TACs) lack the capability of self‐diffusion and active searching in biological environments, which significantly impedes degradation efficiency. Herein, nanomotor‐driven targeting chimeras (MotorTACs) are ingeniously designed to achieve effective internalization and degradation of extracellular platelet‐derived growth factor (PDGF), a driver to cancer invasion and metastasis. Catalyzed by endogenous H2O2, MotorTACs diffused rapidly and searched actively in living cells, as visualized at the single‐particle level under the dark‐field mode. Hydrolysis efficiency is significantly enhanced as target protein degradation is complete in only 4 h. Furthermore, MotorTACs‐mediated degradation of PDGF is found to be via the lysosome and ubiquitin‐proteasome dual‐degradation pathways. Taking advantage of the properties, it is anticipated that MotorTACs provide a unique strategy against extracellular undruggable proteins, thus advancing the development of therapeutic interventions in chemical biology and disease treatment.
Digital Light Processing of Thermoresponsive Hydrogels from Polyproline‐Based Star Polypeptides
Authors: Murphy Robert D. , Cosgrave Muireann , Judge Nicola , Tinajero‐Diaz Ernesto , Portale Giuseppe , Wu Bing , Heise Andreas 
Published: September 2024

AbstractThe first report of star poly(L‐proline) crosslinkers is disclosed for digital light processing 3D printing of thermoresponsive hydrogels. Through chain end functionalization of star poly(L‐proline)s with methacryloyl groups, access to high‐resolution defined 3D hydrogel structures via digital light processing is achieved through photoinitiated free radical polymerization. Changing the poly(L‐proline) molecular weight has a direct influence on both thermoresponsiveness and printability, while shape‐morphing behavior can be induced thermally.
Bimetallic Coupling Strategy Modulating Electronic Construction to Accelerate Sulfur Redox Reaction Kinetics for High‐Energy Flexible Li‐S Batteries
Authors: Dong Hanghang , Ji Ying , Wang Lei , Wang Haichao , Yang Chao , Xiao Yao , Chen Mingzhe , Wang Yong , Chou Shulei , Wang Renheng , Chen Shuangqiang 
Published: September 2024

AbstractLithium‐sulfur (Li‐S) batteries are considered the most promising energy storage battery due to their low cost and high theoretical energy density. However, the low utilization rate of sulfur and slow redox kinetics have seriously limited the development of Li‐S batteries. Herein, the electronic state modulation of metal selenides induced by the bi‐metallic coupling strategy is reported to enhance the redox reaction kinetics and sulfur utilization, thereby improving the electrochemical performance of Li‐S batteries. Theoretical calculations reveal that the electronic structure can be modulated by Ni‐Co coupling, thus lowering the conversion barrier of lithium polysulfides (LiPSs) and Li+, and the synergistic interaction between NiCoSe nanoparticles and nitrogen‐doped porous carbon (NPC) is facilitating to enhance electron transport and ion transfer kinetics of the NiCoSe@NPC‐S electrodes. As a result, the assembled Li‐S batteries based on NiCoSe@NPC‐S exhibit high capacities (1020 mAh g−1 at 1 C) and stable cycle performance (80.37% capacity retention after 500 cycles). The special structural design and bimetallic coupling strategy promote the batteries working even under lean electrolyte (7.2 µL mg−1) with a high sulfur loading (6.5 mg cm−2). The proposed bimetallic coupling strategy modulating electronic construction with N‐doping porous carbon has jointly contributed the good redox reaction kinetics and high sulfur utilization.
Species delimitation in Xanthium sect. Acanthoxanthium (Heliantheae, Asteraceae) and the neglected species Xanthium argenteum
Authors: Manzo Eleonora , Nillies Sebastian , Gutiérrez Diego G. , Panero José L. , Bräuchler Christian , Tomasello Salvatore 
Published: September 2024

AbstractXanthium is a genus of annual herbaceous plants that stands out within Asteraceae for being wind‐pollinated, diclinous monoecious, and bearing solitary pistillate flowers in peculiar spiny structures (burs). Xanthium sect. Acanthoxanthium is native to South America and characterized by the presence of trifurcate spines at the base of the leaves. Past taxonomic treatments of the section have been contradictory, some recognising up to six species, others reducing all to a single polymorphic species. Altogether, 42 samples of X. sect. Acanthoxanthium were analysed, the vast majority taken from herbarium specimens between 20 and 160 years old. We sampled multiple specimens of X. spinosum from throughout its broad range as well as those taxa with narrower distributions, covering the whole range of morphological variation in the section. When possible, we included types and original material. We used Hyb‐Seq techniques to obtain information from about 1000 single‐copy nuclear genes and complete plastomes. Phylogenomic data were submitted to coalescent‐based species delimitation approaches (SPEEDEMON). Additionally, we performed geometric morphometric analysis of leaf outlines. The results strongly support the identification of four lineages in the section favouring the acceptance of four of the hitherto described species, i.e., X. ambrosioides, X. argenteum, X. catharticum, and X. spinosum. These results were to some extent corroborated by morphometric analyses. While X. ambrosioides was well distinct from X. spinosum based on leaf morphology, such difference was not observed between X. spinosum and X. catharticum. However, X. catharticum differs from X. spinosum in its ecological requirements, being a species rather adapted to high‐mountain environments of the Neotropics. Intriguingly, X. argenteum – a taxon described from a single herbarium collection – was also inferred as a species.
String‐Like Self‐Capacitance‐Based Proximity and Tactile Sensor that Can be Wrapped Around Robotic Arms
Authors: Tsuji Satoshi 
Published: September 2024

AbstractCooperative robots that perform safety functions as part of cooperative work with humans have been recently drawing attention. Proximity and tactile sensors that can be retrofitted to a robot's surface are important safety measures for existing robots that are not manufactured as cooperative robots to be used as cooperative robots. In this paper, a string‐like self‐capacitance‐based proximity and tactile sensor that can be easily wrapped around various types of existing robots is proposed. The novel and useful point in this paper is that it can be easily mounted on various robots by a flexible string‐like proximity and tactile sensor. The sensor module can be adjusted to the required length by connecting different numbers of modules depending on the mounting surface. As a demonstration, six prototype sensor modules were connected by each connector and wrapped around a robotic arm. The sensor modules on the robot's surface could detect an object within its proximity range and detect the rough pressure after contact. In addition, the robotic arm with the sensor modules could be controlled in real time using the data obtained from the sensor that are object detection data at proximity range. These results confirm that the proposed sensor module can be used in the proximity and tactile sensors of existing robots. © 2024 Institute of Electrical Engineers of Japan and Wiley Periodicals LLC.
Clinicopathological findings in cats with haws syndrome
Authors: Fruchter Bar , Kuzi Sharon , Pe'er Oren , Ofri Ron , Sebbag Lionel 
Published: September 2024

AbstractBackgroundHaws syndrome is a relatively common yet poorly understood disorder in cats.MethodsTen cats with acute haws syndrome underwent ophthalmic and physical examinations, bloodwork, faecal analysis and pharmacological testing with 1% phenylephrine. The cats were discharged with broad‐spectrum deworming (with or without metronidazole) as well as topical tetrahydrozoline.ResultsCats were 17.6 ± 9.1 (2‒36) months old. All eyes had bilateral third eyelid protrusion and ptosis but no miosis or other ocular abnormalities. Diarrhoea was noted in four of 10 cats; otherwise, the cats were systemically healthy. A newly adopted kitten with haws syndrome and diarrhoea caused the condition to develop in the other three cats (from the same multicat household) within 4‒11 days. All cats tested negative for feline immunodeficiency virus and feline leukaemia virus. Serum amyloid A levels were elevated in two of eight tested cats. Tests for the presence of Giardia were positive in four of nine tested cats. Clinical signs transiently resolved within 20 minutes of the application of topical phenylephrine or tetrahydrozoline. Haws syndrome resolved in nine of the 10 cats within 37.7 ± 23 (12‒95) days but recurred in three of the nine cats 156‒182 days later.LimitationsThe small sample size limits the conclusions that can be drawn.ConclusionsHaws syndrome occurs in generally healthy cats, with or without diarrhoea, and is characterised by a sympathetic neuropathy causing bilateral third eyelid protrusion and ptosis. Clinical signs are possibly triggered by contagious gastrointestinal pathogen(s) that presumably affect(s) the gut microbiota and influence(s) the gut‒brain axis.