bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Indole‐ and Pyrrole‐Sulfonium Ylides.
Authors: HARTKE K. , TEUBER D. , GERBER H.‐D. 
Published: May 2016

AbstractReaction of pyrrole (I) with sulfoxides such as (II) yields predominantly the 2‐sulfonium salts (IV), which are deprotonated to give the pyrrole‐2‐sulfonium ylides (VI) (yields of (VI) not given).
ChemInform Abstract: Condensed as‐Triazines. Part 10. Regioselectivity in Methylation and Phenylation of the Zwitterionic Pyrido(2,1‐f)‐as‐triazinium‐1(3)‐olates and Thiolates.
Authors: BATORI S. , MESSMER A. 
Published: May 2016

AbstractThe betaines (IV), obtained from the 1‐amino‐2‐(amino(ethoxy)carbonyl)pyridinium salts (I) or (V), are N‐methylated with methyl iodide (VII) to give the salts (VIII).
ChemInform Abstract: A Facile Synthesis of 2,4,8,10‐Tetrahalo‐6,12‐diaryldibenzo(b,f)(1,5)diazocines.
Authors: BORUAH R. C. , SANDHU J. S. 
Published: May 2016

AbstractThe benzisoxazoles (I) are cleaved with thionyl chloride to produce the 2‐amino‐3‐chlorobenzophenones (II) which form the title compounds (III) upon refluxing in pyridine.
ChemInform Abstract: Synthesis of Cyclodisilathianes and Their Degradation by Iron Carbonyls.
Authors: KUZ'MIN O. V. , BYKOVA A. L. , LEBEDEV A. V. , BASHKIROVA S. A. , RAISIN I. I. 
Published: May 2016

AbstractThe polysilens (I) react with elemental sulfur (II) in the presence of diphenylacetylene to give the cyclodisilathianes (III).
ChemInform Abstract: Reaction of Dialkyl 1,2,4‐Trichloro‐2‐buten‐3‐ylphosphonates with Potassium Iodide.
Authors: BELYKH O. A. , SOKOLOV V. V. , DOGADINA A. V. , IONIN B. I. , PETROV A. A. 
Published: May 2016

AbstractThe phosphonates (I) mentioned in the title react with KI to give the butadienylphosphonates (III) via the intermediate diiodobutenylphosphonates (II).
ChemInform Abstract: Synthesis and Structural Determination of the First Representative of cis‐Phosphenimidous Amides.
Authors: ROMANENKO V. D. , RUBAN A. V. , CHERNEGA A. N. , POVOLOTSKII M. I. , ANTIPIN M. YU. , STRUCHKOV YU. T. , MARKOVSKII L. N. 
Published: May 2016

AbstractReaction of the lithium amide (II) with the phosphoramidous dichloride (Ia) yields the cis‐phosphenimidous amide (III) which does not isomerize on UV‐irradiation or heating to give the corresponding trans‐form.
ChemInform Abstract: Oxidative Addition of Hexafluoroacetone at 1‐Chloro‐, 1‐(2,2,2‐Trifluoroethoxy)‐ and 1‐(2,2,2‐Trifluoro‐1‐(trifluoromethyl)ethoxy)phosphorinane.
Authors: HACKLIN H. , ROESCHENTHALER G.‐V. + 
Published: May 2016

AbstractThe products are characterized by 1H, 19F and 31P NMR spectroscopy and a formation mechanism is proposed.
ChemInform Abstract: A Novel Oxygen‐Induced Reduction of α,β‐Unsaturated Carbonyl Compounds by Benzeneselenol.
Authors: MASAWAKI T. , UCHIDA Y. , OGAWA A. , KAMBE N. , MIYOSHI N. , SONODA N. 
Published: May 2016

AbstractReaction of the α,β‐unsaturated carbonyl compounds (I) with benzeneselenol (II) in the presence of small amounts of oxygen yields the saturated aldehydes and ketones (III), together with the Michael adducts (IV).
ChemInform Abstract: Dichalcogen‐Bridged Acenaphthenes (I) as New Electron Donors.
Authors: ASO Y. , YUI K. , MIYOSHI T. , OTSUBO T. , OGURA F. , TANAKA J. 
Published: May 2016

AbstractThe title compounds (I) form 1:1 complexes with tetracyanoquinodimethane (TCNQ) ((Ia) and (Ib) readily in THF; (Ic) only in hot Ph‐Cl).
ChemInform Abstract: Rhodium(III) cis‐Dihydrido Complexes with 3,6‐Bis(2′‐pyridyl)pyridazine (dppn) and Bidiazines. Crystal and Molecular Structure of (Rh(H)2(dppn)(PPh3)2)PF6·CH2Cl2.
Authors: GHEDINI M. , NEVE F. , MANOTTI LANFREDI A. M. , UGOZZOLI F. 
Published: May 2016

Abstract(I) reacts with the pyridazine derivative (II) to give the air‐stable complex (III), which crystallizes as dichloromethane solvate in P21/a with Z=4.
ChemInform Abstract: Complexes with Functional Phosphines. Part 12. Carbon‐Carbon Coupling Reactions by Isocyanate Insertion into Nickel‐, Palladium‐, and Platinum‐Coordinated β‐Phosphino Enolates. Molecular Structures of Cyclic ((C10H8N)Pd(Ph2PC(C(O)OEt)(=C(O)NHPh))) and Cyclic cis‐(Ni(Ph2PC(C(O)Ph)(=C(O)NH(p‐MeC6H4)))2)·CH2Cl2.
Authors: BOUAOUD S.‐E. , BRAUNSTEIN P. , GRANDJEAN D. , MATT D. , NOBEL D. 
Published: May 2016

AbstractThe reaction of phenyl isocyanate with the Pd complexes (Ia), (Ib) and (Va) affords the corresponding complexes (III) and (VI), whereas starting with (Ic) or (Vb) two coupling products, (IIIc) and (IVc) or (VIb) and (VIIb), are obtained which are in equilibrium.
ChemInform Abstract: Reactions of Acetylenes with Noble Metal Carbonyl Halides. Part 11. Synthesis of Cyclic (Pt(CMe=C(H)COOMe)(CO)Cl) via Polynuclear Platinum Carbonyls. X‐Ray Crystal Structure Determination of the σ‐Alkenyl Platinum Complex (N(PPh3)2) (Pt(CMe=C(H)CO2Me)(CO)Cl2).
Authors: ALLEVI C. , GARLASCHELLI L. , MALATESTA M. C. , GANAZZOLI F. 
Published: May 2016

AbstractIn the reaction of (I) with H2O (II) the polynuclear derivative (Pt(CO)2)n is generated together with H(Pt(CO)Cl3) which on addition of (III) react to give the complexes (IV) and (V).
ChemInform Abstract: An Aromatization Reaction of a 13α‐Methyl Steroid.
Authors: HANSON J. R. , TRUNEH A. 
Published: May 2016

AbstractWhereas treatment of the androstane (I) with HBr/glacial AcOH affords the 13β,14β‐cis‐fused anthrasteroid (II), the reaction of the 13α‐methyl analogue (IV) proceeds without isomerization at C‐14 to give the anthrasteroid (V).
ChemInform Abstract: One‐Step Synthesis of Steroidal Lactams from Ketones of Spirostane Series.
Authors: SIDDIQUI A. H. , RAO N. S. , RAMESH D. , RAO K. V. , LAKSHMI C. A. V. 
Published: May 2016

AbstractTreatment of the steroidal ketones (I) with hydroxylamine‐O‐sulfonic acid (II) gives the lactams (III).
ChemInform Abstract: A Directed Metalation Route to the Zwitterionic Indole Alkaloids. Synthesis of Sempervirine.
Authors: GRIBBLE G. W. , BARDEN T. C. , JOHNSON D. A. 
Published: May 2016

AbstractThe key intermediate (VII) is synthesized starting from the indole (I) via Taylor‐Boger triazine Diels‐Alder anellation chemistry.
ChemInform Abstract: Synthesis of 2′‐Deoxyribofuranosyl Indole Nucleosides Related to the Antibiotics SF‐2140 and Neosidomycin.
Authors: GIRGIS N. S. , COTTAM H. B. , ROBINS R. K. 
Published: May 2016

AbstractThe indoles (I) are coupled with the chlorofuranose (II) to form the nucleosides (III) which are O‐deprotected, yielding (IV).
ChemInform Abstract: The Surface Properties of Microcrystalline Hydrous Titanium Oxide as Obtained by Thermal Hydrolysis from a TiCl4 Solution
Authors: OOI K. , MIYAI Y. , KATOH S. , SUGASAKA K. 
Published: May 2016

Abstractare studied by means of nitrogen adsorption/desorption at 77 K, and fluoride ion adsorption, XRD, and electron microscopy.
ChemInform Abstract: An EXAFS Study of Co‐Mn/SiO2 Bimetallic Solvated Metal Atom Dispersed (SMAD) Catalysts.
Authors: TAN B. J. , KLABUNDE K. J. , TANAKA T. , KANAI H. , YOSHIDA S. 
Published: May 2016

AbstractIn the title catalysts, manganese is present in the oxidized state and Co is in both the metallic and oxidized state.
ChemInform Abstract: Laser Raman Studies of the Preparation of Platinum and Iridium Catalyst Systems.
Authors: CHAN S. C. , FUNG S. C. , SINFELT J. H. 
Published: May 2016

AbstractPt/Al2O3, Ir/Al2O3, and Pt‐Ir mixed catalysts are prepared by the impregnation method using chloroplatinic acid and chloroiridic acid solutions and subsequently heated in air at various temperatures.
ChemInform Abstract: Properties and Structure of Novel Ternary Stannides of Rare Earth Metals with a High Content of Tin.
Authors: KORETSKAYA O. E. , KOMAROVSKAYA L. P. , SKOLOZDRA R. V. 
Published: May 2016

AbstractThe novel binary stannides MSn3 (M: Tb, Dy, Ho) and the novel ternary stannides M2NiSn6 (M: Ho, Er, Tm) are prepared from the elements by solid‐phase reactions (670 K, 720 h).
ChemInform Abstract: Rapid Inversion versus Stable Chiral Center Formation. Different Behavior of Coordinated Nitrogens in Four‐ and Five‐Coordinate Platinum(II) Complexes with N,N′‐Disubstituted Ethylenediamines.
Authors: FANIZZI F. P. , MARESCA L. , NATILE G. , LANFRANCHI M. , MANOTTI LANFREDI A. M. , TIRIPICCHIO A. 
Published: May 2016

AbstractThe five‐coordinate complexes (II) are prepared by a known procedure.
ChemInform Abstract: Interaction of Organoaluminum Compounds and Crown Ethers. Formation in Solution of R2Al(crown)+ and RAl(halide)(crown)+ Ions.
Authors: RICHEY H. G. JUN. , BERGSTRESSER G. L. 
Published: May 2016

Abstract1H NMR studies indicate that solutions prepared from R2AlX (R: ‐Et, ‐Me and ‐Pr; X: ‐Br, ‐I) and 15‐crown‐5 contain significant amounts of R2Al(crown)+ and RAlX(crown)+ ions.
ChemInform Abstract: Stereoselective Synthesis of Alcohols. Part 27. Addition of (α‐Chlorocrotyl)boronates to Aldehydes.
Authors: HOFFMANN R. W. , DRESELY S. , LANZ J. W. 
Published: May 2016

AbstractThe racemic boronate (I) adds to nonchiral aldehydes of type (II) to give the homoallyl alcohols (III) as main products.
ChemInform Abstract: Formal Addition of Methanesulfenyl Fluoride to Unsaturated Substrates.
Authors: HAUFE G. , ALVERNHE G. , ANKER D. , LAURENT A. , SALUZZO C. 
Published: May 2016

AbstractDimethyl(methylthio)sulfonium tetrafluoroborate (II) reacts with the olefines (I) to give the products (III) by formal addition of methanesulfenyl fluoride.
ChemInform Abstract: A Convenient Synthesis of Amino‐Substituted 2‐Oxo‐1,3,5‐triazinium and 1,3,5‐Oxadiazinium Salts.
Authors: AL‐TALIB M. 
Published: May 2016

AbstractIn connection with investigations of new classes of heterocumulenes, the behavior of the salts (I) toward the carbodiimide (II) and the cyanamides (IV) is studied.
ChemInform Abstract: Oxidative Cleavage of Carbon‐Silicon Bonds by Dioxygen: Catalysis by a Flavin‐Dihydronicotinamide Redox System.
Authors: TAMAO K. , HAYASHI T. , ITO Y. 
Published: May 2016

AbstractTreatment of the organo‐silicon compounds (I) with oxygen in the presence of tetraacetylriboflavin/N‐benzyl‐1,4‐dihydronicotinamide and cesium fluoride gives the alcohols (IIa) ‐ (IId) or phenol (IIe) via fluoride‐promoted cleavage of the intermediate silyl ethers.
ChemInform Abstract: Alkylmetal Asymmetric Reduction. Part 19. Grignard Reagents Derived from Naturally Occurring Products as Reducing Agents of Ketones.
Authors: FALORNI M. , LARDICCI L. , UCCELLO‐BARRETTA G. , GIACOMELLI G. 
Published: May 2016

AbstractThe optically active Grignard reagent (II), which is available by a conventional straightforward elaboration starting from (‐)‐menthone (I), reacts with prochiral ketones such as (III) to give exclusively reduction products, e.g. (IV); contrary to what is generally observed with aliphatic alkyl butyl Grignards, no addition products are additionally formed.
ChemInform Abstract: Synthesis of (1.1.1.1)(1,3)‐2‐Methoxyazulenophane: Azulene Analogue of Calixarenes.
Authors: ASAO T. , ITO S. , MORITA N. 
Published: May 2016

AbstractThe bis(azulene)diol (VIII) is prepared from 2‐methoxyazulene (I) or from ethyl 2‐methoxyazulene‐1‐carboxylate (VI) as shown in the reaction scheme.
ChemInform Abstract: Asymmetric Synthesis of Phenyl Alkyl Sulfoxides via the Nondestructive Mediation of the Chiral Iron Acyl ((η5‐C5H5)Fe(CO)(PPh3)COCH2Me).
Authors: DAVIES S. G. , GRAVATT G. L. 
Published: May 2016

AbstractThe lithium enolate of the acetyliron complex (I) is methylated to give the ethyl ketone (III).
ChemInform Abstract: Highly Diastereoselective Intramolecular Nitrone Cycloadditions to α,β‐Unsaturated Esters.
Authors: ANNUNZIATA R. , CINQUINI M. , COZZI F. , RAIMONDI L. 
Published: May 2016

AbstractThe allylic β‐sulfonylcarboxylates (III), prepared from the alcohols (I) and the acyl chlorides (II), are subjected to ozonolysis and then directly treated with N‐benzylhydroxylamine (IV) to give the nitrones (V).
ChemInform Abstract: Rearrangement of 5‐Amino‐1,2,3‐thiadiazole‐4‐carbothioamides.
Authors: DANKOVA E. F. , BAKULEV V. A. , GRISHAKOV A. N. , MOKRUSHIN V. S. 
Published: May 2016

AbstractConsecutive reaction of the cyanoacetamides (I) with phosphorus pentasulfide (II) and benzenesulfonyl azide (III) gives the aminothiadiazolecarbonitriles (IV).
ChemInform Abstract: Studies of (3,3)Sigmatropic Rearrangements: Rearrangement of 3‐(4‐p‐Tolyloxybut‐2‐ynyloxy)(1)benzopyran‐2‐one.
Authors: MAJUMDAR K. C. , DE R. N. , KHAN A. T. , CHATTOPADHYAY S. K. , DEY K. , PATRA A. 
Published: May 2016

AbstractThe hydroxybenzopyranone (I) is coupled with the chlorobutyne (II) to yield the butynyloxybenzopyranone (III) which undergoes intramolecular ring closure upon thermolysis, producing the pyranobenzopyranone (IV) or the furobenzopyranone (V).
ChemInform Abstract: Synthesis, Properties, and Cardiovascular Activity of Substituted 4‐Dihydropyridine‐2(3H)‐thiones.
Authors: KRAUZE A. A. , VITOLIN'A R. O. , ROMANOVA M. R. , DUBUR G. YA. 
Published: May 2016

AbstractThe dihydropyridinethiolates (V), prepared by common cyclization reactions, are converted to the thiones (VIII), the betaines (IX), and the sodium salts (X).
ChemInform Abstract: Iminophosphorane‐Mediated Synthesis of Mesoionic 1,3,4‐Oxadiazolo(3,2‐a)pyridinylium‐2‐aminides.
Authors: MOLINA P. , ALAJARIN M. , PEREZ DE VEGA M. J. , FOCES‐FOCES C. , HERNANDEZ CANO F. 
Published: May 2016

AbstractMesoionic compounds such as (III) are of interest because of their unique structure, reaction behavior and pharmaceutical activity.
ChemInform Abstract: A New Cinnoline Ring Construction by the Reaction of 2‐Diazo‐3‐(2‐fluorophenyl)‐3‐oxopropionates with Tri‐n‐butylphosphine.
Authors: MIYAMOTO T. , MATSUMOTO J. 
Published: May 2016

AbstractThe polyhalobenzoylacetates (I) react with tosyl azide (II) to give the α‐diazoesters (III) which, when treated with triphenylphosphine (IV), produce the triphenylphosphazines (Va) and (Vb) or the hydrazone (VIc).
ChemInform Abstract: Chlorination of Diethylaminodifluorophosphine with Phosphorus Pentachloride and Its Organic Derivatives.
Authors: TIMOKHIN B. V. , KAZANTSEVA M. V. , DMITRIEV V. K. , DONSKIKH V. I. 
Published: May 2016

AbstractReaction of the difluorophosphine (I) with 1 equivalent phosphorus pentachloride or the organyltrichlorophosphonium hexachlorophosphates (III) gives the dichlorodifluorophosphorane (II).
ChemInform Abstract: Generation of a 1‐Ferracyclobutene from Thermal and Photolytic Induced Rearrangement of α‐Ethoxycyclopropyl σ Complexes of Iron.
Authors: CONTI N. J. , JONES W. M. 
Published: May 2016

AbstractThe formation of the ferracyclobutene (II) in the title reactions is monitored by 13C NMR spectroscopy.
ChemInform Abstract: Synthesis and Characterization of Metal Complexes of Nickel, Cobalt, and Iron Having Monomeric 15‐Membered Lacunar Cyclidene Ligands, with a Representative Crystal Structure. Dioxygen Binding by the Cobalt Complexes.
Authors: THOMAS R. , FENDRICK C. M. , LIN W.‐K. , GLOGOWSKI M. W. , CHAVAN M. Y. , ALCOCK N. W. , BUSCH D. H. 
Published: May 2016

AbstractLacunar Ni(II) complexes (IIIa)‐(IIId) are synthesized by a template process.
ChemInform Abstract: Photolytic Cluster Synthesis: Synthesis and Structure of (((Ph3P)Au)7Mo(CO)3)OH.
Authors: BEUTER G. , STRAEHLE J. + 
Published: May 2016

AbstractThe photolysis of a mixture of the gold azide (I) and the Mo carbonyl (II) results in elimination of N2 and formation of the title cluster (IV).
ChemInform Abstract: Synthesis and Crystal Structure of (Et4N)2(Re7C(CO)21Pd(C9H9)) (C9H9 = η3‐1‐Phenylallyl). An Example of a Non‐“Slipped” Palladium(II) Capping Moiety.
Authors: HENLY T. J. , WILSON S. R. , SHAPLEY J. R. 
Published: May 2016

AbstractThe title compound (III) crystallizes in the space group P21 with Z=2.
ChemInform Abstract: Activation of an Aliphatic C‐H Bond at Room Temperature. Part 4. Conversion on a Cluster of a Stable σ‐Bonded Alkyl Group to a μ2‐Alkylidene Ligand. Synthesis and Crystal Structure Determination of HOs3(6‐CH2C5H3N‐2‐C(H)=N‐i‐Pr)(CO)9 and H2Os3(6‐CHC5H3N‐2‐C(H)=N‐i‐Pr)(CO)8.
Authors: ZOET R. , VAN KOTEN G. , VRIEZE K. , JANSEN J. , GOUBITZ K. , STAM C. H. 
Published: May 2016

AbstractAs demonstrated by the reaction of the complex (I) with (II) under mild conditions, an aliphatic C‐H bond may be activated on a transition‐metal cluster yielding the complex (III) which is one of the few examples of a transition‐metal cluster containing a σ‐bonded alkyl moiety.
ChemInform Abstract: Bis(platinum) Complexes Containing Two Platinum cis‐Diammine Units. Synthesis and Initial DNA‐Binding Studies.
Authors: FARRELL N. P. , DE ALMEIDA S. G. , SKOV K. A. 
Published: May 2016

AbstractThe title complexes (III) with two units of the cis‐diammine complex linked by variable‐length hydrocarbon chains are prepared as shown (no yields given) and their configuration confirmed by IR spectroscopy.
ChemInform Abstract: Tobacco Chemistry. Part 68. Structure Determination and Biomimetic Syntheses of Two New Tobacco Cembranoids.
Authors: ARNDT R. , WAHLBERG I. , ENZELL C. R. , BERG J.‐E. 
Published: May 2016

AbstractThe structure of the title compounds (IIa) and (IIb) is established by spectroscopic methods, chemical correlation and a biomimetic synthesis via the intermediate (I) (yields given in g).
ChemInform Abstract: A Biomimetic Synthesis of (.+‐.)‐Petiodial. A Novel Palladium‐Catalyzed Enallene Cyclization.
Authors: TROST B. M. , MATSUDA K. 
Published: May 2016

AbstractThe palladium‐catalyzed cyclization of the enyne (V) is sluggish and gives the desired cyclopentene (VIa) as minor product together with its trimethylsilyl derivative (VIb).
ChemInform Abstract: Electronic States and Nature of Bonding of the Molecule NiGe by all Electron ab initio Hartree‐Fock (HF) and Configuration Interaction (CI) Calculations and Mass Spectrometric Equilibrium Experiments.
Authors: SHIM I. , KINGCADE J. E. JUN. , GINGERICH K. A. 
Published: May 2016

AbstractBased on the theoretical calculations a detailed description of the electronic structure and bonding of NiGe is presented.
ChemInform Abstract: A Single‐Crystal and Synchrotron Powder X‐Ray Refinement of the Structure of SrNb8O14, a New Oxoniobate Containing Nb6 Octahedra.
Authors: KOEHLER J. + , SIMON A. , HIBBLE S. J. , CHEETHAM A. K. 
Published: May 2016

AbstractSingle crystals of the title compound are prepared by heating a pellet of SrNb2O6, NbO, Nb, and B2O3 as mineralizer (2:2:2:1, 950 °C, 7 d).
ChemInform Abstract: Synthesis, Spectral Analyses and X‐Ray Diffraction Studies of 1:1 (Sc,In)(OH)3.
Authors: MULLICA D. F. , SAPPENFIELD E. L. , GABLE D. R. 
Published: May 2016

AbstractSingle‐crystals of Sc0.5In0.5(OH)3 (I) are prepared by hydrothermal aging of a mixture of Sc2O3 and In2O3 in 30 N NaOH (503 K, 6 d).
ChemInform Abstract: Analysis of the 5f1 → 6d1 Transitions in PaX2‐ 6 (X: Cl, Br) and Pa4+/ThBr4.
Authors: EDELSTEIN N. , KRUPA J. C. , NAIK R. C. , RAJNAK K. , WHITTAKER B. , BROWN D. 
Published: May 2016

AbstractThe UV/VIS spectra of M2PaX6 (M: Cs, X: Cl; M: NEt4, X: Cl, Br) and Pa4+ incorporated into a ThBr4 single crystal are analyzed in terms of a Hamiltonian including the crystal field and spin‐orbit interactions for the 6d configuration.
ChemInform Abstract: Diamagnetic ⇄ Paramagnetic Equilibria in Solutions of Bis(dialkylphosphino)ethane Complexes of Iron.
Authors: BAKER M. V. , FIELD L. D. , HAMBLEY T. W. 
Published: May 2016

AbstractThe Fe(II) complexes (I) are prepared from corresponding Fe(II) halides and diphosphines in Et2O or THF.
ChemInform Abstract: Methoxy‐ and Dichloro‐Substituted Oxyallyl Intermediates.
Authors: FOEHLISCH B. + , KRIMMER D. , GEHRLACH E. , KAESHAMMER D. + 
Published: May 2016

AbstractSolvolysis of both the chloride (I) or the mesylate (III) in basic 2,2,2‐trifluoroethanol affords the same product (II) by an enolization‐ionization mechanism; the oxyallyl intermediate (V) can be trapped by furan to give the cycloadduct (VI) as 95:5 mixture of endo‐ and exo‐isomers.
ChemInform Abstract: Ketonization of Secondary Hydroxy Groups of Alcohols and Diols with Hydrogen Peroxide Under the Influence of Tris(cetylpyridinium) 12‐Tungstophosphate.
Authors: YAMAWAKI K. , NISHIHARA H. , YOSHIDA T. , URA T. , YAMADA H. , ISHII Y. , OGAWA M. 
Published: May 2016

Abstract1‐Octanol (Ia) and the secondary alcohols (Ib) ‐ (Id) are treated with hydrogen peroxide in the presence of tris(cetylpyridinium) 12‐tungstophosphate to yield the aldehyde (IIa) and the ketones (IIb) ‐ (IId).
ChemInform Abstract: The Reaction of α‐Methylstyrene Analogues and Related Compounds with Sodium Perborate in Acetic Acid.
Authors: GUPTON J. T. , DURANCEAU S. J. , MILLER J. F. , KOSIBA M. L. 
Published: May 2016

AbstractThe methylstyrenes (I) are treated with sodium perborate in glacial acetic acid (II), producing the 1‐acetoxy‐2‐phenyl‐2‐propanols (III).
ChemInform Abstract: Synthesis of 2‐Functionalized 1,1‐Diiodo‐1‐alkenes. Generation and Reactions of 1‐Iodo‐1‐lithio‐1‐alkenes and 1,1‐Dilithio‐1‐alkenes.
Authors: BARLUENGA J. , RODRIGUEZ M. A. , CAMPOS P. J. , ASENSIO G. 
Published: May 2016

AbstractIodination of (I) in the presence of a nucleophile such as (II) yields the title compounds (III).
ChemInform Abstract: Use of Moist Silica Gel for Obtaining α‐Ethylenic Carbonyl Compounds from β‐Alkylthio or β‐Phenylthio Allylic Alcohols.
Authors: PELLET M. , HUET F. 
Published: May 2016

AbstractThe β‐alkylthio α‐ethylenic aldehydes (III), (VII) (one stereoisomer), (IX), or (XI) are prepared from the corresponding β‐chloro aldehydes, e.g. (I); the ketones (XIV) are available from the cyclohexanone (XII) by Peterson reaction followed by deacetalization.
ChemInform Abstract: Competitive (4 + 2)Cycloaddition versus (1,5)‐Hydrogen Sigmatropy in a Cycloheptatriene. An Efficient Route to 3‐Azatricyclo(5.3.1.04,10)undeca‐5,8‐diene.
Authors: KROW G. R. , CANNON K. C. , CAREY J. T. , MA H. , RAGHAVACHARI R. , SZCZEPANSKI S. W. 
Published: May 2016

AbstractThe cycloheptatrienes (V) are prepared from tropylium tetrafluoroborate (I) by reaction with allylamine (II) and subsequent acylation of the product (III).
ChemInform Abstract: Palladium‐Catalyzed Cross‐Coupling of Perfluoroalkenylzinc Reagents with Aryl Iodides. A New, Simple Synthesis of α,β,β‐Trifluorostyrenes and the Stereoselective Preparation of 1‐Arylperfluoropropenes.
Authors: HEINZE P. L. , BURTON D. J. 
Published: May 2016

AbstractPalladium‐catalyzed cross‐coupling reaction of the trifluoroethylenylzinc reagents (I) with the aryl iodides (II) gives the trifluorostyrenes (III).
ChemInform Abstract: Transmetalation and Reverse Transmetalation on Ortho‐Activated Aromatic Compounds: A Direct Route to o,o′‐Disubstituted Benzenes.
Authors: EATON P. E. , MARTIN R. M. 
Published: May 2016

AbstractTreatment of the activated benzenes (I) with lithium tetramethylpiperidide (II)/mercuric chloride (III) produces the corresponding mono‐ and dimercury ortho‐substituted derivatives.
ChemInform Abstract: Products Active on Mosquitoes. Part 2. Synthesis of Biologically Active Diethers of 3,7‐Dimethyl‐1,8‐octanediol.
Authors: PHADNIS A. P. , PATWARDHAN S. A. , POWAR P. V. , SHARMA R. N. 
Published: May 2016

AbstractThe title compounds (I) are prepared starting from the corresponding geranyl monoethers and tested for their biological properties.
ChemInform Abstract: Rhodium(II) Acetate‐Catalyzed Reactions of 2‐Diazo‐1,3‐indandione and 2‐Diazo‐1‐indanone with Various Substrates.
Authors: ROSENFELD M. J. , SHANKAR B. K. R. , SHECHTER H. 
Published: May 2016

AbstractDecomposition of 2‐diazo‐1,3‐indandione (I) by rhodium(II)‐acetate in cyclohexane (II) or in the benzenes (IV) results in carbon‐hydrogen insertion to give the 2‐substituted indandiones (III) or (V) and (VI).
ChemInform Abstract: Condensation Products of 2‐Aminobenzothiazoles and 3‐Aryl‐5‐bromorhodanines.
Authors: GAKHAR H. K. , GUPTA S. B. 
Published: May 2016

AbstractThe reaction of benzothiazoles of type (I) with 3‐aryl‐5‐bromorhodanines such as (II) yields the corresponding dimeric benzothiazoles (cf.
ChemInform Abstract: Synthesis of 4,8‐Dimethyl‐8,9‐dihydro‐7H‐pyrano(2,3‐e)indol‐2‐ones.
Authors: PRASAD D. V. , DARBARWAR M. 
Published: May 2016

AbstractThe aminocoumarins (I) are consecutively N‐tosylated and N‐allylated to produce the key intermediates (V) which undergo rearrangement and ring closure upon thermolysis, forming the fused N‐tosylmethylpyrrolines (VI).