bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: The Structure and Function of Estrogens. Part 10. Synthesis of 5,5‐Dimethyl‐cis‐4b,5,6,10b,11,12‐hexahydrochrysene‐2,8‐diol: The Estrogenic Activity of This and of Related C‐Methylated Hydrochrysenediols.
Authors: COLLINS D. J. , CULLEN J. D. , STONE G. M. 
Published: May 2016

AbstractThe title compound (VIII) is prepared in order to gain further insight into the action of estrogen.
ChemInform Abstract: Biomimetic Syntheses of Pretetramides. Part 3. Synthesis of 6‐Methylpretetramides Using a Preassembled D Ring Template.
Authors: HARRIS T. M. , HARRIS C. M. , KUZMA P. C. , LEE J. Y.‐C. , MAHALINGAM S. , GILBREATH S. G. 
Published: May 2016

AbstractThe synthesis of the methylpretetramide (IXa) is accomplished by a modification of the biomimetically engineered (5 + (2 · 2 ) + 1) route previously described for pretetramide starting from the phthalide (I).
ChemInform Abstract: Chemisorption on the Microsurface of Metal Clusters: Activation Barriers and Chemical Reactions for CO, N2, O2, and CH4 on Al+ 25.
Authors: JARROLD M. F. , BOWER J. E. 
Published: May 2016

AbstractChemisorption and subsequent chemical reaction of the neutral title reactants with size selected Al2+5 clusters are investigated over a wide range of collision energies.
ChemInform Abstract: Spectral Properties and Isomerism of Nitroenamines. Part 1. 3‐Amino‐2‐nitroacrylic Esters (I).
Authors: CHIARA J.‐L. , GOMEZ‐SANCHEZ A. , HIDALGO F.‐J. , BELLANATO J. 
Published: May 2016

AbstractThe IR, Raman, 1H, and 13C NMR spectra of esters (I) are reported.
ChemInform Abstract: Polar Effects. Part 15. Twin γ‐Substituent Effects in the Formation of Adamantyl‐1‐cations.
Authors: GROB C. A. , GRUENDEL M. + , SAWLEWICZ P. 
Published: May 2016

AbstractThe relative rates of the hydrolysis of (I) and (II) in 70% dioxane show that the rate factors for the twin substitution in (II) are less than the square of the rate factors for single substitution due to electron repulsion.
ChemInform Abstract: Alkylation Studies of 5‐exo‐Methylene Substituted Isoxazolidines.
Authors: PADWA A. , CARTER S. P. , CHIACCHIO U. , KLINE D. N. , PERUMATTAM J. 
Published: May 2016

AbstractTreatment of 5‐methyleneisoxazolidine (I), obtained by 1,3‐dipolar cycloaddition of the respective nitrone to phenylsulfonylallene, with base and subsequent reaction with electrophiles such as (II) or (IV) affords α‐substituted (e.g.
ChemInform Abstract: Syntheses of 1,5‐Benzothiazepines. Part 4. Synthesis of 2,4‐Diaryl‐2,3‐dihydro‐1,5‐benzothiazepines.
Authors: PANT U. C. , GAUR B. S. , CHUGH M. 
Published: May 2016

AbstractThe synthesis of the title compounds is envisaged in order to obtain analogues of the drug diltiazem.
ChemInform Abstract: First Example of a Trimeric Metalloporphyrin. Synthesis, Electrochemical, and Spectroelectrochemical Studies of ((P)Th(OH)2)3 Where P is the Dianion of Octaethyl‐ or Tetraphenylporphyrin. Crystal Structure of a Dihydrated Trinuclear Complex of Dihydroxy(5,10,15,20‐tetraphenylporphinato)thorium(IV) Heptane Solvate.
Authors: KADISH K. M. , LIU Y. H. , ANDERSON J. E. , CHARPIN P. , CHEVRIER G. , LANCE M. , NIERLICH M. , VIGNER D. , DORMOND A. , BELKALEM B. , GUILARD R. 
Published: May 2016

AbstractThe reaction of dichlorothorium complexes of octaethyl‐ or tetraphenylporphyrin with sodium carbonate in oxygen‐free THF gives the corresponding dihydroxo‐porphyrinatothorium compounds as trimers (80 and 82% yield).
ChemInform Abstract: Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 77. Reactions of Iron‐Molybdenum Compounds with Alkynes; Crystal Structures of (MoFe(μ‐C(C6H4Me‐4)C(CHMe)CH2C(Me)C(Me))(CO)4(η‐C5H5)), (MoFe(μ‐C(C6H4Me‐4)C(CHMe)CH2)(CO)5(η‐C5H5)), and (MoFe(μ‐C(C6H4Me‐4)C(CH2PMe3)CHMe)(CO)5(η‐C5H5)).
Authors: GARCIA M. E. , JEFFERY J. C. , SHERWOOD P. , STONE F. G. A. 
Published: May 2016

AbstractThe title reactions are outlined in the scheme.
ChemInform Abstract: Reactions of Cyclopentadienylhydridotricarbonylmolybdenum and ‐tungsten with Diorganomagnesium Reagents.
Authors: MACKEY O. N. D. , MORLEY C. P. 
Published: May 2016

AbstractEquimolar reaction of dicyclopentadienyl‐Mg (III) with the title metalates (II) results in formation of the trinuclear products (I).
ChemInform Abstract: Kinetics of the Decomposition of Coprohaem Compound I in Aqueous Solution.
Authors: BRETSCHER K. R. , JONES P. 
Published: May 2016

AbstractThe title compound, formed by oxidation of coproferrihaem (I) with MCPBA in a 1:1 stoichiometric reaction, decomposes in aqueous solution in the absence of added reductants.
ChemInform Abstract: Synthesis and Characterization of N(8)‐Coordinated Metal Complexes of the Anti‐Hyperuricemia Drug Allopurinol: Bis(allopurinol)triaquo(sulfato)metal(II) Hydrates (Metal: Co, Ni, Zn, Cd).
Authors: HAENGGI G. + , SCHMALLE H. , DUBLER E. 
Published: May 2016

AbstractThe title complexes (I) are prepared from the metal sulfates and the ligand in hot aqueous solution (no yields given).
ChemInform Abstract: Exchange Interaction on Multinuclear Transition‐Metal Complexes. Part 11. Synthesis and X‐Ray Structure of Cu2L2(CH3COO)2·Cu2(CH3COO)4·2 C2H5OH (LH: N‐Methyl‐N′‐(4,6‐dimethoxysalicylidene)‐1,3‐propanediamine), a Novel Alternating‐Chain Compound of Copper(II).
Authors: CHIARI B. , PIOVESANA O. , TARANTELLI T. , ZANAZZI P. F. 
Published: May 2016

AbstractThe title complex (I) is obtained from the Schiff base and Cu acetate in abs.
ChemInform Abstract: Synthesis and Crystal and Molecular Structure of New (N,N‐Di‐n‐propylthiocarbamato)palladium(II) Compounds.
Authors: BESENYEI G. , HERDTWECK E. , HOLLY S. , MAENNIG D. + , NOETH H. + , SIMANDI L. I. , VISKI P. 
Published: May 2016

AbstractDepending on the conditions, the reaction of sodium tetrachloropalladate with the thiocarbamate (II) yields (III) or (VIII).
ChemInform Abstract: Dinuclear Complexes of Rhodium and Iridium with Cyanide or Thiocyanate Bridges: Molecular Structure of ((PMe2Ph)3Cl2Ir(μ‐CN)IrCl2(PMe2Ph)3) (ClO4).
Authors: DEEMING A. J. , PROUD G. P. , DAWES H. M. , HURSTHOUSE M. B. 
Published: May 2016

AbstractReactions between the Rh and Ir complexes (I) and (II) give the homometallic and heterometallic cyano‐bridged compounds (IIIa) and (IIIb); the last do not interconvert.
ChemInform Abstract: The Nodule Formation in Electroless Copper Baths
Authors: JUNGINGER R. 
Published: May 2016

Abstractcontaining copper sulfate, EDTA, formaldehyde, and NaOH as major components is studied as a function of the presence of complexing agents for Cu(I) ions (e.g., quinoline, pyridine, ethylenediamine, diphosphate, cyanide) and of dissolved oxygen both in the presence and absence of a surfactant.
ChemInform Abstract: 29Si Cross‐Polarization/Magic Angle Spinning NMR Evidence for Geminal Silanols on Vacuum‐Activated Aerosil Silica.
Authors: MORROW B. A. , GAY I. D. 
Published: May 2016

AbstractSamples of aerosil silica are activated under vacuum at temp. up to 1000 °C. The 29Si CPMAS NMR spectra of samples activated at 450, 600, or 800 °C exhibit a signal due to geminal (Si(OH)2) silanol groups demonstrating for the first time that these species exist on aerosil silicas.
ChemInform Abstract: A Kinetics Study of the Reaction of Cl with NO2.
Authors: RAVISHANKARA A. R. , SMITH G. J. , DAVIS D. D. 
Published: May 2016

AbstractThe third order rate coefficients of the title reaction (see scheme) are measured to be k(He): 7.5·10‐31 cm6 molecule‐2 s‐1and k(N2): 16.6·10‐31 cm6 molecule‐2 s‐1at 298 K (flash photolysis‐resonance fluorescence method).
ChemInform Abstract: Photochemistry of 5‐Methylpyrimidin‐4‐ones in Acetic Acid Solution: Thermal Rearrangements of Dewar Pyrimidinones and 4‐Actoxyazetidin‐2‐ones.
Authors: TAKAHASHI T. , HIROKAMI S. , NAGATA M. , YAMAZAKI T. 
Published: May 2016

AbstractPhotolysis of the title compounds (I) yields the Dewar pyrimidinones (III), which under the influence of H+ are converted into a variety of products (IV)‐(VII).
ChemInform Abstract: Ruthenium(IV)‐Oxo Complexes: A Novel Hydrophobic Effect of Tertiary Phosphine Ligands on the Selective Oxidation of Alcohols.
Authors: MARMION M. E. , TAKEUCHI K. J. 
Published: May 2016

AbstractKinetic and mechanistic studies on the oxidation of a series of alcohols by complexes of type (I) are conducted in both aqueous and acetonitrile solutions.
ChemInform Abstract: Tin(IV) Chloride Promoted vs. Metal β‐Carbonylenolate Catalyzed Reactions of β‐Dicarbonyls with Nitriles.
Authors: VERONESE A. C. , GANDOLFI V. , BASATO M. , CORAIN B. 
Published: May 2016

AbstractThe diketo compounds (Ia) and (Ib) undergo SnCl4‐promoted reaction with activated nitriles (II) (R3: COPh, COOEt, CCl3) to give mixtures of the enamino diketo compounds (III) and their deacetylated derivatives (IV).
ChemInform Abstract: 1‐Functionalized 5,6‐Dimethyl‐6H‐pyrido(4,3‐b)carbazoles (Ellipticines) and Analogues: A New Rapid Synthesis.
Authors: BISAGNI E. , RAUTUREAU M. , HUEL C. 
Published: May 2016

AbstractFormylation of the fused pyrroles (I) gives the 3‐formyl derivatives (III) which react with the 3‐lithio derivative of compound (V), yielding the alcohols (VI).
ChemInform Abstract: Reactions of Thianthrene Cation Radical Perchlorate with 1‐Alkyl‐4‐arenesulfonylaminobenzenes.
Authors: NOH J. S. , LEE S. H. , KIM K. 
Published: May 2016

AbstractThe reaction of the title cation radical (II) with the sulfonylaminobenzenes (I) and (VII) yields thianthrene (III) as major product.
ChemInform Abstract: Heteroaromatic Aza Compounds: A Novel Synthesis of Phthalazines.
Authors: ELNAGDI M. H. , IBRAHIM N. S. , SADEK K. U. , MOHAMED M. H. 
Published: May 2016

AbstractThe phthalazines (V) are prepared starting from the reaction between the hydrazines (I) and the nitrile (II) as shown.
ChemInform Abstract: Preparation and Thermal Stability Study of L‐(‐)‐Menthyl 1,2‐Phenylene Phosphite Ozonide.
Authors: SHERESHOVETS V. V. , KOROTAEVA N. M. , SPIRIKHIN L. V. , KOMISSAROV V. D. , TOLSTIKOV G. A. 
Published: May 2016

AbstractOzonization of the phosphite (I) gives the optically active, relatively stable ozonide (III).
ChemInform Abstract: Observation of Secondary Bonding in Solution: Synthesis, NMR Studies, and the Crystal Structure of Te(VI)(OTe(IV)(C8H8)(S2P(OEt)2))6.
Authors: DAKTERNIEKS D. , DI GIACOMO R. , GABLE R. W. , HOSKINS B. F. 
Published: May 2016

AbstractThe title compound (IV), an unexpected hydrolysis product of (V), could be prepared under very mild conditions by the one‐pot synthesis shown in the scheme.
ChemInform Abstract: Photolysis of Cyclotrigermane. Synthesis and Chemistry of Digermiranes and Digermetanes Containing Sulfur and Selenium.
Authors: TSUMURAYA T. , SATO S. , ANDO W. 
Published: May 2016

AbstractPhotolysis of the cyclotrigermane (I) produces tetramesityldigermene and dimesitylgermylene which react with elemental sulfur (II) to give the thiadigermirane (III) and the dithiadigermetane (IV).
ChemInform Abstract: Construction of 8‐Oxabicyclo(5.3.0)deca‐2,9‐diones: An Approach to the Pseudoguaianolides.
Authors: CUMMINS W. J. , DREW M. G. B. , MANN J. , MARKSON A. J. 
Published: May 2016

AbstractThe oxabicycle (I) is converted to the desired dione (VIII) via the intermediates (III), (IV) and (VI).
ChemInform Abstract: Conditions of Preparation and Physico‐Chemical Characteristics of the Double Dihydrophosphates of Magnesium and Cobalt.
Authors: ANTRAPTSEVA N. M. , PONOMAREVA I. G. , SHCHEGROV L. N. , SEGEDA M. N. 
Published: May 2016

AbstractReactions between mixtures of magnesium and cobalt hydroxocarbonates and monophosphoric acid at 25 °C afford the novel title compounds Mg1‐xCox(H2PO4)2·2 H2O; 0 < x < 1. They are shown to be members of a continuous series of solid solutions crystallizing in the monoclinic space group P21/n. A correlation is found between the parameters of the unit cell, the density, the refraction indices and the compositions of the polycrystalline title compounds.
ChemInform Abstract: Photochemistry of Matrix‐Isolated Di‐tert.‐butyldiazidosilane. Observation of Di‐tert.‐butylsilylene and N,N′‐Di‐tert.‐butylsilanediimine.
Authors: WELSH K. M. , MICHL J. , WEST R. 
Published: May 2016

AbstractThe major product from 254 nm irradiation of the matrix‐isolated title compound (I) is di‐tert.‐butylsilylene (III), a highly ground‐state singlet species with λmax 480 nm, which undergoes a subsequent photochemical C‐H insertion to give the stable silacyclopropane (IV).
ChemInform Abstract: Tricyclo(3.1.0.02,6)hexanedione (VI) (the Valene of o‐Benzoquinone), Bicyclo(2.1.1)hexane‐2,3‐dione (Va), and Valenes (VIII) of a Quinoxaline, of Phenazine, and of a Benzophenazine.
Authors: CHRISTL M. , KRAFT A. 
Published: May 2016

AbstractFrom cyclopentadiene the cis diol (IV) is now obtained in 4 steps (total yield 10%) and accordingly (Va) in 5 steps (total yield 5%).
ChemInform Abstract: Acylamidation of Acetylenes.
Authors: GRIDNEV I. D. , BALENKOVA E. S. 
Published: May 2016

AbstractThe reaction between the alkynes (I), the nitriles (II) and acetyl tetrafluoroborate (III) proceeds regio‐ and stereospecifically by way of a syn‐addition according to Markovnikov to afford the hitherto unknown Z‐configurated N‐acyl‐β‐amino‐α,β‐unsaturated ketones (III).
ChemInform Abstract: Acylation of 5‐Amino‐2‐aryl‐3‐phenyl‐1,2,4‐thiadiazolium Chlorides.
Authors: ZYABREV V. S. , KHARCHENKO A. V. , PIROZHENKO V. V. , DRACH B. S. 
Published: May 2016

AbstractOn chlorination under mild conditions the thioureas (IV) undergo cyclization to afford the title compounds (V).
ChemInform Abstract: Studies on the Synthesis and Antimicrobial Properties of Aryl Barbituryl Sulfones.
Authors: SHRIMALI S. S. , JOSHI B. C. , KISHORE D. 
Published: May 2016

AbstractThe sulfonamides (III) are coupled with the ureas (IV) to give the barbituric acid derivatives (V) which rearrange in concentrated sulfuric acid, producing the corresponding sulfones (VI).
ChemInform Abstract: Synthesis and Pharmacological Effect of Substituted Phenyl‐4‐(2‐chloroethyl)tetrahydro‐1,4‐oxazine Hydrochlorides.
Authors: DAOUD S. S. , OSMAN S. A. , KARRAR M. A. 
Published: May 2016

AbstractReduction of the bromoacetophenones (I) produces the bromohydrins (II) which react with diethanolamine (III) to yield the aminocarbinols (IV).
ChemInform Abstract: Convenient Routes to Di‐tert.‐butylsilanediyl (II): Chemical, Thermal, and Photochemical Generation.
Authors: BOUDJOUK P. , SAMARAWEERA U. , SOORIYAKUMARAN R. , CHRISCIEL J. , ANDERSON K. R. 
Published: May 2016

AbstractThree routes are described to generate the diyl (II): a) α‐elimination of halogen from (I), b) thermolysis or c) photolysis of either isomer (VI).
ChemInform Abstract: Synthesis, NMR Study, and Crystal Structures of Bis(diethyldithiocarbamato)(O,O′‐diethyl dithiophosphato)phenyltellurium(IV), PhTe(S2CNEt2)2(S2P(OEt)2), and Bis(diethyldithiocarbamato)iodomethyltellurium(IV), MeTe(I)(S2CNEt2)2.
Authors: DAKTERNIEKS D. , DI GIACOMO R. , GABLE R. W. , HOSKINS B. F. 
Published: May 2016

AbstractReactions of PhTeCl3 (I) with the dithiolate ligands (II), (IV), and SSCOEt‐ in solution are studied by variable‐temp.
ChemInform Abstract: The Kinetics of Photochemical Deconjugation Reactions of Methyl Geranate.
Authors: FREEMAN P. K. , SIGGEL L. 
Published: May 2016

AbstractThe photochemical deconjugation of the title compound (I) which leads to the products (II)‐(IV) is compared with the triplet state ring closure yielding the cyclopentane derivative (V).
ChemInform Abstract: Investigations of Solid State Reactions of Binary Polyphosphate‐Fluoride Systems by Means of Thermal Analysis, X‐Ray Diffraction and NMR Spectroscopy. Part 2. Systems Sr(PO3)2 + SrF2 and Ca(PO3)2 + CaF2.
Authors: EHRT D. , JAEGER C. + 
Published: May 2016

AbstractBoth solid state systems are characterized by the reactions outlined in the scheme.
ChemInform Abstract: IR and Gravimetric Studies of the Adsorption of Water on Barium Sulfate.
Authors: NEAGLE W. , ROCHESTER C. H. 
Published: May 2016

AbstractA self‐supporting disc of BaSO4 is freed from adsorbed and bulky water by heat treatment at 773 K. Subsequent adsorption of water vapor gives spectra containing IR bands due to isolated hydroxyl groups and to vibrations of water molecules.
ChemInform Abstract: 95Mo NMR Studies of (Aryldiazenido)‐ and (Organohydrazido)molybdates. Crystal and Molecular Structure of (n‐Bu4N)3(Mo6O18(NNC6F5)).
Authors: BANK S. , LIU S. , SHAIKH S. N. , SUN X. , ZUBIETA J. , ELLIS P. D. 
Published: May 2016

AbstractThe 95Mo NMR spectroscopy of a select series of (aryldiazenido)‐ and (organohydrazido)molybdates of known structure is studied.
ChemInform Abstract: Time‐Resolved Resonance Raman Spectroscopy Applied to the Photochemistry of the Sulfonated Derivatives of 9,10‐Anthraquinone.
Authors: MOORE J. N. , PHILLIPS D. , HESTER R. E. 
Published: May 2016

AbstractVariation of the chemical conditions (pH 6, with and without addition of NaNO2), probe laser wavelength (370‐580 nm) and time delays allows the observation of five species in the photolysis of the "strong" sensitizer (I): its triplet, radical anion and neutral radical, and two water‐triplet complexes.
ChemInform Abstract: Thermal and Photochemical Reactions of d9 Metal Complexes: The Silver(II) Macrocycles.
Authors: RONCO S. , VAN VLIERBERGE B. , FERRAUDI G. 
Published: May 2016

AbstractRate constants for electron transfer reactions of Cu(II), Ni(I), and Ag(II) complexes of the ligands (I)‐(VI) are determined by pulse radiolysis.
ChemInform Abstract: Thermal Interconversion and Cyclization Reactions of 2‐(Arylthio)benzyl Radicals and 2‐(Benzyl)thiophenoxyl Radicals.
Authors: CADOGAN J. I. G. , HUTCHISON H. S. , MCNAB H. 
Published: May 2016

AbstractThe title radicals are generated either from oxalates (VI) or from allyl compounds (IV), respectively.
ChemInform Abstract: Kinetics and Stereochemistry in the Catalytic Hydrogenation of Acridine.
Authors: SAKANISHI K. , OHIRA M. , MOCHIDA I. , OKAZAKI H. , SOEDA M. 
Published: May 2016

AbstractAt 150 °C the hydrogenation of acridine (I) follows the consecutive pathway to predominantly give the stereoisomer (IV).
ChemInform Abstract: A Novel Approach to the Synthesis of Two Versatile Synthetic Intermediates, 2,3‐Bis(bromomethyl)‐1,3‐butadiene and Tetrakis(bromomethyl)ethylene.
Authors: ALI S. M. , TANIMOTO S. , OKAMOTO T. 
Published: May 2016

AbstractThe (π‐allyl)palladium complex (III), generated from allene (I) and bis(benzonitrile)palladium(II) bromide (II), reacts with two equivalents of bromine to give 2,3‐bis(bromomethyl)‐1,3‐butadiene (IV).
ChemInform Abstract: Direct Regio‐ and Stereoselective Lithiation of Secondary Allyl and Methylallylamines: Reaction with Electrophiles.
Authors: BARLUENGA J. , FANANAS F. J. , FOUBELO F. , YUS M. 
Published: May 2016

AbstractThe allylic amines (Ia) ‐ (Ie) are transformed into the vinyl substituted allylamines (III) in a one‐pot procedure via lithiation, reaction with the electrophiles (II), and subsequent hydrolysis.
ChemInform Abstract: Studies on Antirheumatic Agents: 3‐Benzoylpropionic Acid Derivatives.
Authors: KAMEO K. , OGAWA K. , TAKESHITA K. , NAKAIKE S. , TOMISAWA K. , SOTA K. 
Published: May 2016

AbstractThe acetophenones (I) and glyoxylic acid (II) are combined to give the α,β‐unsaturated acids (III) which react with thioacetic acid (IV), producing the adducts (V).
ChemInform Abstract: Preparation of Fused Aziridines by Intramolecular Cycloaddition.
Authors: JONES G. B. , MOODY C. J. 
Published: May 2016

AbstractThe dialdehyde monoxime ethers (III) and (IX), synthesized from biphenyl‐2,2'‐dicarbaldehyde (I) or the 2‐formylindoles (VII), react with tosyl hydrazide (IV) to give the hydrazones (V) and (X).
ChemInform Abstract: Studies Related to Penicillins. Part 26. Conversion of Potassium Benzylpenicillinate into 1‐Substituted Derivatives of 3‐Phenylacetamidoazetidine‐2,4‐dione.
Authors: KAURA A. C. , STOODLEY R. J. 
Published: May 2016

AbstractThe (2R,3S)‐azetidinesulfinic acids (I), derived from benzylpenicillinates, are converted into the title compounds (Va) and (Vb) the key step being the Norrish type II photoreaction of (IV).
ChemInform Abstract: Reactivity of (R)‐2‐tert.‐Butyldihydrooxazole Derivatives Prepared from Serine and Threonine: Novel, Versatile Chiral Building Blocks.
Authors: SEEBACH D. , STUCKY G. 
Published: May 2016

AbstractThe known title compounds (II) and (XI) are promising starting materials for regio‐ and stereoselective syntheses of derivatives such as (I), (III), (VII), (X) or (XII) which are obtained from (II), (XI) by simple, conventional reactions.
ChemInform Abstract: Formation of Mutagens by Photochemical Reaction of 2‐Naphthol in Aqueous Nitrite Solution.
Authors: SUZUKI J. , WATANABE T. , SUZUKI S. 
Published: May 2016

AbstractIrradiation of 2‐naphthol (I) in the presence of sodium nitrite (II) yields a mixture of the compounds (III) ‐ (IX).
ChemInform Abstract: Synthesis and Reactions of Isoquinoline Derivatives. Part 3. Synthesis and Reactions of 3,4‐Dihalo‐1‐phenylisoquinolines.
Authors: RENGER B. , KONZ E. , RUEGER W. + 
Published: May 2016

AbstractThe title compounds (II) are prepared from 1‐phenyl‐1,4‐dihydroisoquinolinone (I) by treatment with phosphorus pentahalides or by consecutive Vilsmeier‐Haack acylation and oxidative cleavage with sodium hypohalites.
ChemInform Abstract: Nickel‐Catalyzed Coupling of Dithioacetals with Silylmethylmagnesium Chloride. A Simple Synthesis of Allylsilanes.
Authors: NI Z.‐J. , LUH T.‐Y. 
Published: May 2016

AbstractCoupling reaction of the 1,3‐dithiols (I) and (IV) with trimethylsilylmethylmagnesium chloride (II) in the presence of a Ni‐catalyst yields the alkylsilanes (III) or (V), together with the vinylsilanes (VI).
ChemInform Abstract: The First Octasilacubane System: Synthesis of Octakis(tert‐butyldimethylsilyl)pentacyclo(4.2.0.02,5.03,8.04,7)octasilane.
Authors: MATSUMOTO H. , HIGUCHI K. , HOSHINO Y. , KOIKE H. , NAOI Y. , NAGAI Y. 
Published: May 2016

AbstractThe tetraphenyltetrasilane (I) or the triphenyldisilane (IV) are brominated with hydrogen bromide in the presence of aluminum tribromide to give the tetrabromotetrasilane (II) or the tribromodisilane (V).
ChemInform Abstract: Synthesis of Selenocyanates via Cyanoselenation of Organocopper Reagents.
Authors: MEINKE P. T. , KRAFFT G. A. , GURAM A. 
Published: May 2016

AbstractThe methylene compounds (I) react with butyllithium and cuprous cyanide to give the intermediate compounds (III) which subsequently undergo exchange selenation with selenocyanogen (IV) to yield the selenocyanates (V).
ChemInform Abstract: closo‐(B11H11AlCH3)2‐, an Aluminaborane Analogue of the closo‐(B12H12)2‐ Dianion: Synthesis, Characterization, and Molecular Structure.
Authors: GETMAN T. D. , SHORE S. G. 
Published: May 2016

AbstractThe air‐sensitive compound (IVa) is prepared according to the scheme.
ChemInform Abstract: The Direct Electrochemical Synthesis of Tin(II) Derivatives of Aromatic 1,2‐Diols, and a Study of Their Oxidative Addition Reactions.
Authors: MABROUK H. E. , TUCK D. G. 
Published: May 2016

AbstractThe title compounds (I) are obtained by electrochemical oxidation of anodic tin in non‐aqueous solutions of the aromatic diols.
ChemInform Abstract: Tertiary Phosphine Complexes of Iron Porphyrins: Synthesis, Molecular Stereochemistry, and Crystal Structure of Bis(dimethylphenylphosphine)(meso‐5,10,15,20‐tetraphenylporphyrinato)iron(II).
Authors: SODANO P. , SIMONNEAUX G. , TOUPET L. 
Published: May 2016

AbstractThe low‐spin Fe(II) complex (Ia) (P1, Z=1) is the first structurally characterized model compound for protein phosphine complexes.
ChemInform Abstract: Ruthenium(II) Cluster Complexes: A Series of Homooligonuclear Complexes Based on Bidentate Bridging Ligands.
Authors: SAHAI R. , MORGAN L. , RILLEMA D. P. 
Published: May 2016

AbstractBy addition of bis(bipyridine)ruthenium fragments to bipyridine/bipyrimidine ruthenium cores the trimetallic (I) and tetrametallic cluster complexes (II) are prepared.