bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Novel C14‐ and C15‐Bicyclo(2.2.1)heptane‐Based Dicarboxylic Acids from Longibornane‐4‐one via Riley Oxidation.
Authors: DALAVOY V. S. , DEODHAR V. B. , NAYAK U. R. 
Published: May 2016

AbstractRiley oxidation of the title compound (I) is studied under two conditions leading to the diketones (II) or (III) (discussion of the formation mechanisms).
ChemInform Abstract: Alloisolongifolene. Part 3. Prins Reaction on Alloisolongifolene: Formation of a Unique 4‐Substituted 3,6‐Dihydro‐2H‐pyran.
Authors: DALAVOY V. S. , DEODHAR V. B. , NAYAK U. R. 
Published: May 2016

AbstractThe title compound (I) reacts with 1 mol of paraformaldehyde (II) to give the acetate (IIIa) which, on base hydrolysis, affords the carbinol (IIIb) (yield given in g).
ChemInform Abstract: Mn3Nb6O11 (I) and Mg3Nb8O11 (II) ‐ Preparation of Single Crystals and Structure Refinement.
Authors: BURNUS R. , KOEHLER J. + , SIMON A. 
Published: May 2016

AbstractSingle crystals of (II) are obtained by annealing a mixture of MgO, Nb, and Nb2O5 (15:14:8, 1550 °C, 7 h) and single crystals of the isotypic (I) are prepared from LiF, MnF2, Mn, NbO, NbO2 (1:1:1:1:2, 750 °C, 7 d).
ChemInform Abstract: Double Oxides of Rhodium and Rhenium.
Authors: SHAPLYGIN I. S. , APARNIKOV G. L. 
Published: May 2016

AbstractHeating a mixture of Rh2O3 and ReO3 to 1200 °C under high pressure (65 kbar) affords the binary oxide Rh2ReO6 with trirutile structure; space group P4/mmm with Z=2.
ChemInform Abstract: Anion‐Induced Quenching of *Cu(dmp)+ 2.
Authors: GOODWIN K. V. , MCMILLIN D. R. 
Published: May 2016

AbstractAs the couteranion (BPh4‐, BF4‐, ClO4‐, NO3‐) is varied, the emission quantum yield of the title compound (dmp: 2,9‐dimethyl‐1,10‐phenanthroline) varies by as much as 30% in fluid CH2Cl2 while the lifetime is unchanged.
ChemInform Abstract: Chemistry of Enol Ethers. Part 76. Synthesis of Unsaturated Aldehydic Acids and Their Derivatives ‐ Synthons for Retinoids.
Authors: MAKIN S. M. , DOBRETSOVA E. K. , SHAVRYGINA O. A. , ARSHAVA B. M. 
Published: May 2016

AbstractEthyl glyoxylate (I) and the dienes (II) are cyclized to give the dihydropyrans (III).
ChemInform Abstract: Syntheses Starting from Cyclopropylmethyl Cyclopropyl Ketone.
Authors: TARAKANOVA A. V. , BARANOVA S. V. , PEKHK T. I. , DOGADIN O. B. , ZEFIROV N. S. 
Published: May 2016

AbstractThe known title compound (III) is prepared by a novel method in much higher yield as compared to earlier procedures.
ChemInform Abstract: Benzoannellated Centropolyquinanes. Part 3. Synthesis of Multiply Substituted Triptindans (9H,10H‐4b,9a‐((1,2)Benzenomethano)indeno(1,2‐a)indenes) with Substituents in Their Molecular Cavity.
Authors: KUCK D. , PAISDOR B. , GRUETZMACHER H.‐F. + 
Published: May 2016

AbstractThe dibenzylindanones (V), which are prepared in three steps from (I) and (II), undergo acid‐catalyzed cyclodehydration to give the triptindans (VIa)‐(VIc).
ChemInform Abstract: Reactions of Lithium, Sodium, and Potassium tert‐Butylhydroperoxide with Crotonaldehyde.
Authors: SHEKUNOVA V. M. , MOROZOV O. S. , SOKOLOV N. A. , ALEKSANDROV YU. A. 
Published: May 2016

AbstractCrotonaldehyde (I) reacts with the tert‐butylhydroperoxides (II) in MeOH, producing the epoxyaldehyde (III).
ChemInform Abstract: Preparation and Evaluation of Electrophilic Derivatives of Phenylbutazone as Inhibitors of Prostaglandin‐H Synthase.
Authors: VENNERSTROM J. L. , HOLMES T. J. JUN. 
Published: May 2016

AbstractThe N,N'‐diphenylpyrazolidinedione (Ia) is converted into the derivatives (Ib) and (II) which are evaluated as prostaglandin synthase inhibitors.
ChemInform Abstract: Derivatives of 5(6)‐Aminobenzimidazole
Authors: KUZNETSOV V. A. , GARABADZHIU A. V. , GINZBURG O. F. 
Published: May 2016

AbstractThe 2‐nitro‐5‐aminoanilines (IIa)‐(IIf), which are prepared starting from 2‐nitro‐5‐chloroaniline (I), are converted to the corresponding triamines by hydrogenation in the presence of Raney‐Ni.
ChemInform Abstract: Direct Access to 4‐Substituted 3‐Isochromanones by the pH Controlled Addition of Aldehydes.
Authors: BARBIER M. 
Published: May 2016

Abstract3‐Isochromanone (I) is coupled with the aldehydes (II) to give the 4‐alkylidene‐3‐isochromanones (III).
ChemInform Abstract: Synthesis of the Thio Analogue of Cinnabarinic Acid and of Its Dimethyl Ester.
Authors: NEKHOROSHEV A. A. , SEVBO D. P. , GINZBURG O. F. 
Published: May 2016

AbstractThe syntheses of the title compound (VI) and of its dimethyl ester (VII) are described for the first time.
ChemInform Abstract: Unsaturated Silicon Compounds. Part 20. Compounds of Silicon and Its Group Homologues. Part 72. Fluxional Behaviour of Silaethene Me2Si=C(SiMe3)2.
Authors: WIBERG N. , KOEPF H. + 
Published: May 2016

AbstractThe Me groups of the title compound, which is not isolable, migrate with a rapid shift of the Si=C double bond from Si to Si atom.
ChemInform Abstract: Transsilylation Reactions of Phosphazene Precursors.
Authors: WETTERMARK U. G. , NEILSON R. H. 
Published: May 2016

AbstractThe transsilylation reactions of the phosphazene precursor (I) with the chlorosilane (II), the dichlorosilanes (IV) and (VI), and the dichlorodisiloxanes (X) lead to the products (III), and depending on the stoichiometry to (Va) or (Vb), (VIIa) or (VIIb), and (XIa) or (XIb‐d), respectively.
ChemInform Abstract: Menthyl‐Substituted Organophosphorus Compounds. Part 6. Preparation of P(L‐men)RCl and P(L‐men)R(S)Cl (R: Me, Et, iPr, tBu, or Ph; men: cyclo‐C6H9‐2‐iPr‐5‐Me) and NMR Studies of Configuration and Halogen Exchange.
Authors: HAEGELE G. + , KUECKELHAUS W. + , TOSSING G. , SEEGA J. , HARRIS R. K. , CRESWELL C. J. , JAGELAND P. T. 
Published: May 2016

AbstractThe menthyl‐substituted chlorophosphines (I) are prepared by reaction of PRCl2 (R: Ph, Me, Et) with Mg(L‐men)Cl or P(L‐men)Cl2 with MgRCl (R: iPr, tBu) and are converted into the epimeric thiophosphoryl chlorides (II) and (III).
ChemInform Abstract: Stability of d3 Diimine Complexes: Molybdenum(III) vs. Chromium(III).
Authors: CORNIOLEY‐DEUSCHEL C. , VON ZELEWSKY A. 
Published: May 2016

AbstractThe octahedral tris(bipyridine)‐Mo(III) complex (I) is obtained by reaction of (NH4)2(MoCl5(OH2)) with three equiv. of 2,2'‐bipyridine in MeOH at room temp. followed by addition of NH4PF6 (yield given in mg).
ChemInform Abstract: New Mechanistic Probes of Hydride Abstraction from Rhenium‐Alkyl Complexes (η5‐C5H5)Re(NO)(PPh3)(R) by Ph3C+PF‐ 6; Evidence for Initial Electron Transfer.
Authors: BODNER G. S. , GLADYSZ J. A. , NIELSEN M. F. , PARKER V. D. 
Published: May 2016

AbstractThe mechanism of hydride abstraction from the title complexes (I) by trityl cations is probed by study of the equilibrium shown and the effect of oxygen on the rate and deuterium kinetic isotope effect.
ChemInform Abstract: Preparation and Characterization of an (Acylperoxo)iron(III) Porphyrin.
Authors: GROVES J. T. , WATANABE Y. 
Published: May 2016

AbstractThe sterically hindered complex (I) reacts slowly with (IIa) to give a stable new species (IIIa), which decomposes slowly to the corresponding m‐chlorobenzoato complex.
ChemInform Abstract: Characterization of Tetra‐, Penta‐, and Hexacoordinated High‐Spin Iron(II) Complexes with Neutral Monodentate Sulfur Donor Ligands. Crystal and Molecular Structure of Fe(DMTU)7(BF4)2 (DMTU: N,N′‐Dimethylthiourea).
Authors: FACKLER J. P. , MOYER T. , COSTAMAGNA J. A. , LATORRE R. , GRANIFO J. 
Published: May 2016

AbstractNew cationic complexes (I)‐(IV) are obtained by reaction of Fe(II) perchlorate or tetrafluoroborate with the appropriate thioureas in stoichiometric amounts in 1‐butanol.
ChemInform Abstract: Synthesis, Aggregation, Electrocatalytic Activity, and Redox Properties of a Tetranuclear Cobalt Phthalocyanine.
Authors: NEVIN W. A. , LIU W. , GREENBERG S. , HEMPSTEAD M. R. , MARCUCCIO S. M. , MELNIK M. , LEZNOFF C. C. , LEVER A. B. P. 
Published: May 2016

AbstractWith use of procedures described earlier, four phthalonitrile units are attached to a pentaerythritol residue and converted to (I) which is then condensed with excess of the isoindoline derivative (II) to give the metal‐free compound (IIIa) together with 2,9,16,23‐tetraneopentoxyphthalocyanine (61% yield).
ChemInform Abstract: Bimetallic Systems. Part 18. Nickel(II)‐Mercury(II) Acetylide Complexes Containing Bridging Ph2PCH2PPh2 Ligands.
Authors: FONTAINE X. L. R. , HIGGINS S. J. , LANGRICK C. R. , SHAW B. L. 
Published: May 2016

AbstractTreatment of the Ni complex (I), containing monodentate diphosphines, with Hg(II) acetylides (II) gives the complexes (III).
ChemInform Abstract: Synthetic and Spectroscopic Studies on the Hexakis(aryl isocyanide) Complexes of Ruthenium(II) (Ru(CNAr)6)(PF6)2.
Authors: LAROWE J. E. , MCMILLIN D. R. , STACY N. E. , TETRICK S. M. , WALTON R. A. 
Published: May 2016

AbstractThe title complexes (I) are obtained by reaction of Ru2(OAc)4Cl with an excess of aryl isocyanides and KPF6 in the presence of Pb(II) nitrate in refluxing methanol.
ChemInform Abstract: Mechanism for the Oxidative Addition of Iodomethane to Carbonyl(N‐hydroxy‐N‐nitrosobenzenaminato‐O,O′)triarylphosphinerhodium(I) Complexes and Crystal Structure of (Rh(cupf)(CO)(CH3)(I)(PPh3)).
Authors: BASSON S. S. , LEIPOLDT J. G. , ROODT A. , VENTER J. A. 
Published: May 2016

AbstractThe reaction of the Rh(I) complexes (II) with iodomethane to form Rh(III) alkyl compounds is studied in several solvents (benzene, EtOAc, acetone, MeOH, CH3CN and DMSO) having different polarities and donocities.
ChemInform Abstract: Bis(bis(diphenylphosphino)methane)platinum(II) Salts: Evidence for the Formation of a Five‐Coordinate Bis(bis(diphenylphosphino)methane)halogenoplatinum(II) Cation.
Authors: GROSSEL M. C. , MOULDING R. P. , SEDDON K. R. , WALKER F. J. 
Published: May 2016

AbstractThe title complex salts (I), prepared as shown in the scheme (no yields given), are studied in solution by 1H, 13P, and 195Pt NMR spectroscopy and by conductivity measurements.
ChemInform Abstract: Steroids. Part 329. New Approach to Steroidal Hemisuccinates and Glycosides.
Authors: POUZAR V. , CERNY I. , DRASAR P. , HAVEL M. 
Published: May 2016

AbstractIn order to verify the potentialities of monosuccinate or peracetylglucose units as protecting groups and masked polar moieties in position 3 of steroids, the compounds (III) and (VIII) are synthesized.
ChemInform Abstract: Selective Cytotoxicity of a System L Specific Amino Acid Nitrogen Mustard.
Authors: HAINES D. R. , FULLER R. W. , AHMAD S. , VISTICA D. T. , MARQUEZ V. E. 
Published: May 2016

AbstractThe isomeric amines (II) and (III), derived from the spirohydantoin (I) by nitration and subsequent reduction, are transformed into the aminotetrahydronaphthoic acids (VII) and (VIII).
ChemInform Abstract: Stereoselective Allylation for Preparation of L‐Hexose Derivatives.
Authors: WILLIAMS D. R. , KLINGLER F. D. 
Published: May 2016

AbstractThe isomeric aldehydes (III), prepared as described in the reaction scheme, are coupled with the allylic organometallic compounds (V) to give mixtures of the isomeric adducts (VI).
ChemInform Abstract: Synthesis of Certain 3‐Alkoxy‐1‐β‐D‐ribofuranosylpyrazolo(3,4‐d)pyrimidines Structurally Related to Adenosine, Inosine, and Guanosine.
Authors: ANDERSON J. D. , DALLEY N. K. , REVANKAR G. R. , ROBINS R. K. 
Published: May 2016

AbstractThe pyrazolo(3,4‐d)pyrimidine (II), prepared from the pyrazinenitrile (Ia), is converted to the nucleosides (IV).
ChemInform Abstract: Dimeric Naphthoquinones. Part 20. Partial Synthesis of Actinorhodine (I).
Authors: LAATSCH H. 
Published: May 2016

AbstractThe (1S, 1'S, 3R, 3'R)‐enantiomer of the title compound (I) is prepared from α‐naphthocyclinone which in turn is obtained by fermentation of Streptomyces arenae.
ChemInform Abstract: Rechargeable Manganese Oxide Electrodes. Part 1. Chemically Modified Materials.
Authors: YAO Y. F. , GUPTA N. , WROBLOWA H. S. 
Published: May 2016

Abstract"Chemically modified" manganese oxide materials as Bi and Pb birnessites, prepared by ion exchange and coprecipitation methods, are shown to have no inherent limitations to their cycle life even under the condition of deep discharge reaching 80‐95% of their theoretical two‐electron capacity in each cycle.
ChemInform Abstract: Photoenhancement of the Nitrous Acid Formation in the Surface Reaction of Nitrogen Dioxide and Water Vapor: Extra Radical Source in Smog Chamber Experiments.
Authors: AKIMOTO H. , TAKAGI H. , SAKAMAKI F. 
Published: May 2016

AbstractThe heterogenous reaction of NO2 and H2O to emit HONO into the gas phase is studied in a evacuable photochemical smog chamber in both dark and irradiated (> 290 nm) conditions and is found to be photoenhanced by a factor 2‐6 depending on light intensity.
ChemInform Abstract: Complexation of Osmium Tetroxide with Tertiary Amines.
Authors: KOBS S. F. , BEHRMAN E. J. 
Published: May 2016

AbstractThe rate of formation of OsO4 complexes with tetramethylethylenediamine, phenanthroline and 4,7‐diphenyl‐1,10‐phenanthroline disulfonate is investigated.
ChemInform Abstract: Substitution Reactions which Proceed via Radical Anion Intermediates. Part 29. Electron‐Transfer Substitution Reactions: The p‐Nitrocumyl System.
Authors: KORNBLUM N. , CHENG L. , DAVIES T. M. , EARL G. W. , HOLY N. L. , KERBER R. C. , KESTNER M. M. , MANTHEY J. W. , MUSSER M. T. , PINNICK H. W. , SNOW D. H. , STUCHAL F. W. , SWIGER R. T. 
Published: May 2016

AbstractThe p‐nitrocumyl compounds (I) react with organic and inorganic nucleophiles (II) at the tertiary carbon to give the substitution products (III).
ChemInform Abstract: Reaction of Carbanions Derived from α,β‐Unsaturated Nitro Compounds with Electrophiles to Give α‐Substituted Products.
Authors: ONO N. , HAMAMOTO I. , KAMIMURA A. , KAJI A. , TAMURA R. 
Published: May 2016

AbstractThe α,β‐unsaturated nitro compounds (I) react regioselectively with the aldehydes (II) or with the electron‐deficient olefins (IV) in the presence of bases to yield the adducts (III) and (V) respectively.
ChemInform Abstract: Photoinduced Molecular Transformations. Part 84. Transformation of Cyclic Alcohols Into Cyclic Acetals Through a New Oxygen Atom Insertion by Photolysis in the Presence of Lead Tetraacetate and Iodine.
Authors: SUGINOME H. , WASHIYAMA H. , YAMADA S. 
Published: May 2016

AbstractThe reaction of a series of steroidal cyclic homoallyl alcohols such as (I), (III), (V), (VII) and (X) and of 2‐indanol (XII) according to A) is investigated.
ChemInform Abstract: Observation of “Intramolecular” Ion‐Molecule Reactions Within Ionized Clusters: Hetero Systems Involving Methyl Halides and Oxygen‐Containing Compounds.
Authors: GARVEY J. F. , BERNSTEIN R. B. 
Published: May 2016

AbstractWithin ionized heteroclusters (oxy compound: acetone, MeOH, H2O, and dimethyl ether; methyl halide: X: ‐Cl, ‐I) the rates of protonation increase with increasing cluster size in contrast to the protonation within the homoclusters.
ChemInform Abstract: A Convenient One‐Flask Preparation of Di‐tert‐butyl Iminodicarbonate: A Versatile Gabriel Reagent.
Authors: GREHN L. , RAGNARSSON U. 
Published: May 2016

AbstractThe synthesis of the title compound (IV) from formamide (I) and di‐ tert‐butyl dicarbonate (II) is improved.
ChemInform Abstract: Carbanions Derived from 2‐Alkylthiobenzothiazoles. A Novel α‐Lithiomethyl Mercaptan Synthon for Mercaptomethylation.
Authors: KATRITZKY A. R. , AURRECOECHEA J. M. , VAZQUEZ DE MIGUEL L. M. 
Published: May 2016

AbstractThe methylthiobenzothiazole (I) readily gives a methyl group lithio derivative which reacts cleanly with electrophiles such as (II), (IV) or (V) to give (III).
ChemInform Abstract: The Chemistry of N‐Substituted Benzotriazoles. Part 4. A Novel and Versatile Method for the Mono‐N‐alkylation of Aromatic and Heteroaromatic Amines.
Authors: KATRITZKY A. R. , RACHWAL S. , RACHWAL B. 
Published: May 2016

AbstractReduction of the adducts (I) derived from benzotriazole, an aliphatic aldehyde and the corresponding aromatic amine gives the N‐alkylated aromatic amines (II).
ChemInform Abstract: Stereochemistry in the Knoevenagel Reaction of Methyl Arylsulfinylacetate and Aldehydes.
Authors: TANIKAGA R. , KONYA N. , TAMURA T. , KAJI A. 
Published: May 2016

AbstractKnoevenagel reaction between the sulfinylacetate (I) and the aldehydes (II) affords the thermodynamically stable (E)‐alkenes (III) with only minor amounts of the (Z)‐isomers (IV).
ChemInform Abstract: A Novel Reaction of Some Enolizable Ketones not Involving the Rate‐Determining Enolization Step. Kinetics of the Reaction of Ketones with Trichloroisocyanuric Acid in the Presence of Added Chloride Ion in Acid Medium.
Authors: RADHAKRISHNAMURTI P. S. , RATH N. K. , PANDA R. K. 
Published: May 2016

AbstractThe kinetics of the reaction between some enolizable ketones and trichloroisocyanuric acid (Z) in aqueous acid‐acetic acid medium at 35 °C show pseudo‐zero‐order and pseudo‐first‐order disappearance of (Z) in the absence and the presence of added Cl‐, respectively.
ChemInform Abstract: A Facile Access to (R)‐Malic Acid.
Authors: ALPEGIANI M. , HANESSIAN S. 
Published: May 2016

Abstract(R,R)‐Dimethyl tartrate (I) is transformed into the corresponding thionocarbonate (II) which gives (R)‐dimethyl malate (III) on reduction with tributyltin hydride.
ChemInform Abstract: Synthesis of Geminal Vinylcyclane Derivatives via New Allylboranes with an Exocyclic Double Bond.
Authors: BUBNOV YU. N. , ZHELUDEVA V. I. 
Published: May 2016

AbstractHydroboration of the allenes (I) with the boranes (II) gives the alkenylboranes (III) with an exocyclic double bond.
ChemInform Abstract: Synthesis of Bridgehead Derivatives. Part 1. Preparation of Substituted Bicyclo(2.2.1)heptan‐1‐ols and the Corresponding Trifluoromethanesulfonates.
Authors: GARCIA MARTINEZ A. , TESO VILAR E. , GARCIA FRAILE A. , RUANO FRANCO C. , SOTO SALVADOR J. , SUBRAMANIAN L. R. , HANACK M. 
Published: May 2016

AbstractSubstituted bicyclo(2.2.1)heptan‐2‐ones such as (I) and (V) react with trifluoromethanesulfonic anhydride (II) to perform a rearrangement reaction, yielding bridgehead triflates.
ChemInform Abstract: A Simple Preparative Route to New Fluoroisopropenyl Carbamates and Ethers.
Authors: SHIMIZU M. , TANAKA E. , YOSHIOKA H. 
Published: May 2016

AbstractThe dihaloisopropyl carbamates (III) and acetals (VII), derived from the chloroformates (II) and the trichloroether (V), are converted to the fluoroisopropenyl derivatives (IV) and (VIII) by fluoroolefination with tetrabutylammonium fluoride.
ChemInform Abstract: Synthesis of 1,2‐Diazetidinones (Aza‐β‐lactams) by Photochemical Ring Contraction.
Authors: LAWTON G. , MOODY C. J. , PEARSON C. J. 
Published: May 2016

AbstractPhotolysis of the diazopyrazolidinediones (I) in the presence of a nucleophile (II) affords the title compounds (III) via Wolff rearrangement with ring contraction followed by reaction of the resulting ketene with the nucleophile.
ChemInform Abstract: The Chemistry of N‐Substituted Benzotriazoles. Part 1. 1‐(Chloromethyl)benzotriazole.
Authors: KATRITZKY A. R. , RACHWAL S. , CASTER K. C. , MAHNI F. , LAW K. W. , RUBIO O. 
Published: May 2016

AbstractThe N‐chloromethyl group of (I) undergoes substitution by various nucleophiles such as (II) to give (III).
ChemInform Abstract: Nitrogen‐Bridged Heterocycles. Part 4. Synthesis and Properties of Cyclohepta(hi)pyrrolo(2,1,5‐cd)indolizines.
Authors: NOGUCHI M. , TAMAI R. , TANIGAWA N. , OKUMURA H. , KAJIGAESHI S. 
Published: May 2016

AbstractOxidation of the methylene moiety in compounds (I) with NBS yields the products (II) and (III).
ChemInform Abstract: Reaction of Dialkyl Phosphites with 1,1‐Dichloronitrosoalkanes.
Authors: IVANOV A. N. , EPISHINA T. A. , GOREVA T. V. , SOKOLOV V. B. , MARTYNOV I. V. 
Published: May 2016

AbstractThe dialkyl phosphites (I) react with the dichloronitrosoalkanes (II) to give the phosphates (III).
ChemInform Abstract: Telomerization of 1‐Hexene with Diethyl Phosphite in the Presence of Dimanganese Decacarbonyl and Peroxides.
Authors: TERENT'EV A. B. , MOSKALENKO M. A. , KARDANOV N. A. , ORLOVA S. A. , GODOVIKOV N. N. 
Published: May 2016

AbstractThe title reaction gives the phosphonates (III) and (IV).
ChemInform Abstract: Synthesis and Choline Esterase‐Inhibiting Activity of S‐Ethynyl O,O‐Dialkyl Thiophosphates Containing Cyclic Substituents at the Acetylenic Bond.
Authors: GODOVIKOV N. N. , VIKHREVA L. A. , DARISHEVA A. M. , BALASHOVA E. K. , MORALEV S. N. , BRESKIN A. P. , ROZENGART V. I. , SHERSTOBITOV O. E. , KABACHNIK M. I. 
Published: May 2016

AbstractThe phosphoric acid esters (III) are synthesized from the salts (I) and the bromides (II).
ChemInform Abstract: The Electrochemistry of Amavadine, a Vanadium Natural Product.
Authors: NAWI M. A. , RIECHEL T. L. 
Published: May 2016

AbstractThe title compound (I), a product of the mushroom Amanita muscaria, is synthesized by the reaction of vanadyl acetate in methanol with the N‐hydroxy‐α,α‐iminodipropionic acid at the pH approximately 2. The overall yield including the known synthesis of the ligand is about 10%.
ChemInform Abstract: Metal Complexes of Phytohormones. Part 1. Copper(II) Complexes of 6‐Furfurylaminopurine (Kinetin).
Authors: CABRAS M. A. , ZORODDU M. A. 
Published: May 2016

AbstractThe Cu(II) complexes (I) and (II) are prepared by reaction of Cu(II) perchlorate with the title ligand HL or of Cu(II) chloride and HL in the presence of NaOH and are characterized by magnetic susceptibility measurements, ESR, electronic, and IR spectroscopy.
ChemInform Abstract: Complexes of the Platinum Metals. Part 32. Synthesis and Chemistry of Some Iridium Sulfonate Derivatives.
Authors: HARDING P. A. , ROBINSON S. D. 
Published: May 2016

AbstractSulfonic acids (II) react with some Ir complexes to afford the products (III), (V), and (VI) or (VIII) depending on the reaction conditions.
ChemInform Abstract: Metallacyclic Complexes. Synthesis of Metallathietane‐3,3‐dioxide (Metallacyclosulphone) Complexes of Platinum(II), Palladium(II), and Nickel(II); Crystal Structure of trans‐2,4‐Diphenyl‐1,1‐bis(triphenylarsine)platinathietane‐3,3‐dioxide.
Authors: CHIU K. W. , FAWCETT J. , HENDERSON W. , KEMMITT R. D. W. , RUSSELL D. R. 
Published: May 2016

AbstractThe reaction of cis‐ or trans‐(I) with the dianion (II) affords the title complexes (IIIa)‐(IIIf).
ChemInform Abstract: The Kinetics and Mechanism of the Reaction of 2′‐Deoxy‐5′‐guanosinemonophosphoric Acid and the Diaquo Form of cis‐Platin.
Authors: EVANS D. J. , GREEN M. , VAN ELDIK R. 
Published: May 2016

AbstractThe title acid reacts with cis‐(Pt(NH3)2(H2O)2)2+ in two steps to form finally a platinum ligand 1:2 complex in cis arrangement.
ChemInform Abstract: Ring‐Closure of Halogenonaphthoquinones with Potassium 2‐Aminobenzenethiolate: Tautomerism and Substituent Effects.
Authors: TAKAGI K. , KANAMOTO S. , ITOH K. , MATSUOKA M. , KIM S. H. , KITAO T. 
Published: May 2016

AbstractRing‐closure of the halogenonaphthoquinones (I) and (VII) is performed by reaction with potassium 2‐aminobenzenethiolate (II) as outlined in the reaction scheme, giving a series of infrared conductor lasers.
ChemInform Abstract: Stereocontrolled Total Synthesis of (.+‐.)‐Norpatchoulenol (XIII) and Two Metabolites of Patchouli Alcohol, (.+‐.)‐Hydroxy Patchouli Alcohol (XIIa) and the Corresponding (.+‐.)‐Carboxylic Acid (XIIb).
Authors: NIWA H. , HASEGAWA T. , BAN N. , YAMADA K. 
Published: May 2016

AbstractThe racemates of the biooxidation products (XIIa) and (XIIb) of patchouli alcohol are synthesized in a highly stereocontrolled manner starting from the bicyclic enone (I).
ChemInform Abstract: Amino Acids and Peptides. Part 59. Synthesis of Biologically Active Cyclopeptides. Part 9. Synthesis of 16 Isomers of Delastatin 3. Part 1. Synthesis of the 2‐(1‐Aminoalkyl)thiazole‐4‐carboxylic Acids.
Authors: SCHMIDT U. , UTZ R. , LIEBERKNECHT A. , GRIESSER H. , POTZOLLI B. , BAHR J. , WAGNER K. , FISCHER P. 
Published: May 2016

AbstractStarting with (S)‐γ‐butyrolactone‐γ‐carboxylic acid chloride (I), the (R)‐2‐(1‐amino‐3‐cyanopropyl)thiazole‐4‐carboxylic ester (VI), which is a building block for dolastatin 3, is prepared in 7 steps.