bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Intramolecular Radical Trapping in “Set” Ring Opening of N‐Enoyl Aziridines. A New Mechanistic Probe and a New Synthesis of Pyrrolidones.
Authors: BENTZ G. , BESBES N. , LAURENT A. , STAMM H. 
Published: May 2016

AbstractRadical‐induced rearrangement of the N‐enoylaziridines (I) yields the pyrrolidones (II).
ChemInform Abstract: A New and Easy Synthesis of 2‐Carboxy‐6‐oxo‐cis‐octahydroindole.
Authors: SOUCHET M. , GUILHEM J. , LE GOFFIC F. 
Published: May 2016

AbstractThe adduct (III), prepared by Diels‐Alder reaction of the cyclohexadiene (II) with the acetamidoacrylate (I), is cleaved and rearranged with perchloric acid to give the octahydroindolones (IV).
ChemInform Abstract: Syntheses of 4‐Substituted 2‐Phenyl‐5‐methyl‐imidazoles.
Authors: YOUSIF M. Y. , ISMAIL A. M. , METWALLY M. A. , EL‐KERDAWY M. M. 
Published: May 2016

AbstractThe reaction of the ketone (I) with the nucleophiles (II) and (IV) yields the title compounds (III).
ChemInform Abstract: Thromboxane Synthetase Inhibitors and Antihypertensive Agents. Part 3. N‐((1H‐Imidazol‐1‐yl)alkyl)heteroaryl Amides as Potent Enzyme Inhibitors.
Authors: PRESS J. B. , WRIGHT W. B. JUN. , CHAN P. S. , HAUG M. F. , MARSICO J. W. , TOMCUFCIK A. S. 
Published: May 2016

AbstractAcylation of the primary amines (I) with the acid chlorides (II) or the acids (III) yields the carboxamides (IV).
ChemInform Abstract: Synthesis of 3‐Styrylcoumarins from Coumarin‐3‐acetic Acids and 3‐Phenacylcoumarins.
Authors: CHODANKAR N. K. , JOSHI S. D. , SEQUERIA S. , SESHADRI S. 
Published: May 2016

AbstractIn order to obtain optical whiteners, title compounds of type (III) and (V) are synthesized starting from the acetic acids (I) and the butenolides (IV), respectively.
ChemInform Abstract: Flavones. Part 1. Synthesis and Antihypertensive Activity of (3‐Phenylflavonoxy)propanolamines without β‐Adrenoceptor Antagonism.
Authors: WU E. S. C. , COLE T. E. , DAVIDSON T. A. , BLOSSER J. C. , BORRELLI A. R. , KINSOLVING C. R. , MILGATE T. E. , PARKER R. B. 
Published: May 2016

AbstractReaction of epichlorohydrin (I) with the hydroxychromone (II) yields a mixture of the products (III) ‐ (V).
ChemInform Abstract: Intramolecular Acid‐Catalyzed Reactions of o‐Carbomethoxy‐ω‐diazoacetophenones.
Authors: CHAPYSHEV S. V. , KIRKOVSKII L. I. , KARTSEV V. G. 
Published: May 2016

AbstractThe title compounds (III), prepared from the carboxylic acids (I) via their chlorides and diazomethane (II), yield the isochromanediones (IV) on decomposition with sulfuric acid in methanol.
ChemInform Abstract: Cardiotonic Agents. Part 5. 1,2‐Dihydro‐5‐(4‐(1H‐imidazol‐1‐yl)phenyl)‐ 6‐methyl‐2‐oxo‐3‐pyridinecarbonitriles and Related Compounds. Synthesis and Inotropic Activity.
Authors: SIRCAR I. , DUELL B. L. , BRISTOL J. A. , WEISHAAR R. E. , EVANS D. B. 
Published: May 2016

AbstractCondensation reaction of the benzaldehydes (I) with nitroethane (II) and subsequent reduction produce the phenylpropanones (IV) which are transformed into the enamines (VI) by treatment with the amide acetal (V).
ChemInform Abstract: Photostimulated and Dark Reactions of Aryl Halides with 2‐ and 4‐Pyridinethiolates.
Authors: RYBAKOVA I. A. , SHEKHTMAN R. I. , PRILEZHAEVA E. N. 
Published: May 2016

AbstractThe thioethers (III) are prepared from the aryl halides (I) and the pyridinethiolates (II) either by a photostimulated reaction in liquid ammonia, using tetrabutylammonium hydroxide as a catalyst, or in aprotic solvents without irradiation.
ChemInform Abstract: Reactions of 2‐Chloro‐3‐formylquinolines.
Authors: SRIVASTAVA R. P. , NEELIMA NEELIMA , BHADURI A. P. 
Published: May 2016

AbstractIn order to obtain biologically interesting 3‐substituted quinolines, the compounds (IV), (V), (VIII)‐(X) and (XIV) are synthesized.
ChemInform Abstract: Antimalarial Drugs. Part 61. Synthesis and Antimalarial Effects of 4‐((7‐Chloro‐4‐quinolinyl)amino)‐2‐((diethylamino)methyl)‐6‐alkylphenols and Their Nω‐Oxides.
Authors: KESTEN S. J. , JOHNSON J. , WERBEL L. M. 
Published: May 2016

AbstractThe ammonium chlorides (VII) are prepared from the 2‐alkylphenols (I) in a six‐step synthesis.
ChemInform Abstract: Synthesis, Absolute Configuration, and Antibacterial Activity of 6,7‐Dihydro‐5,8‐dimethyl‐9‐fluoro‐1‐oxo‐1H,5H‐benzo(ij)quinolizine‐2‐ carboxylic Acid.
Authors: GERSTER J. F. , ROHLFING S. R. , PECORE S. E. , WINANDY R. M. , STERN R. M. , LANDMESSER J. E. , OLSEN R. A. , GLEASON W. B. 
Published: May 2016

AbstractResolution of the (R)‐ and (S)‐isomers of the tetrahydroquinoline (I) is achieved by flash chromatography of the diastereomeric amides (III) and (IV).
ChemInform Abstract: 2,4‐Diamino‐6,7‐dimethoxyquinazolines. Part 2. 2‐(4‐Carbamoylpiperidino) Derivatives as α1‐Adrenoceptor Antagonists and Antihypertensive Agents.
Authors: ALABASTER V. A. , CAMPBELL S. F. , DANILEWICZ J. C. , GREENGRASS C. W. , PLEWS R. M. 
Published: May 2016

AbstractThe aminochlorodimethoxyquinazoline (I) is coupled with the piperidinocarboxylic amides (II) to form the carbamoyl derivatives (IIIa) ‐ (IIIe).
ChemInform Abstract: 1,3‐Oxazines and Related Compounds. Part 13. Reaction of Acyl Meldrum′s Acids with Schiff Bases Giving 2,3‐Disubstituted 5‐Acyl‐3,4,5,6‐tetrahydro‐2H‐1,3‐oxazine‐4,6‐diones and 2,3,6‐Trisubstituted 2,3‐Dihydro‐ 1,3‐oxazin‐4‐ones.
Authors: YAMAMOTO Y. , WATANABE Y. , OHNISHI S. 
Published: May 2016

AbstractReaction of the acylated Meldrum's acids (I) with the benzaldimines (II) produces mixtures of the oxazines (III) ‐ (V).
ChemInform Abstract: Unexpected Products from the Reactions of 6‐Cyano‐ and 6‐Nitro‐3,4‐epoxy‐3,4‐dihydro‐2,2‐dimethyl‐2H‐1‐benzopyran with Azacyclotridecanone.
Authors: CASSIDY F. , EVANS J. M. , SMITH D. M. , STEMP G. 
Published: May 2016

AbstractThe epoxybenzopyrans (I) are coupled with the lactam (II): (Ia) and the chloro derivative (Id) produce the amidohydroxybenzopyrans (VI) while the nitrile (Ib) and (II) form the bridged isoquinolone (III) and the enamide (IV).
ChemInform Abstract: Synthesis and Structure of Dialkyl Fluoroformiminophosphates.
Authors: MARTYNOV I. V. , BREL' V. K. , UVAROV V. I. , YARKOV A. V. , NOVIKOV V. P. , CHEPAKOVA L. A. , RAEVSKII O. A. 
Published: May 2016

AbstractThe title compounds (III) are prepared by reaction of the phosphites (I) with fluorochloronitromethane (II).
ChemInform Abstract: Iminobis(methylenediphosphonic) Acid.
Authors: ALFER'EV I. S. , BOBKOV S. YU. , KOTLYAREVSKII I. L. 
Published: May 2016

AbstractReaction of formamide (I) with phosphorous acid and phosphorus trichloride, followed by acidic hydrolysis, yields the title compound (III), together with aminomethylenediphosphonic acid (II).
ChemInform Abstract: Synthesis and Antiarrhythmic Properties of Novel 3‐Selena‐7‐azabicyclo(3.3.1)nonanes and Derivatives. Single‐Crystal X‐Ray Diffraction Analysis of 7‐Benzyl‐3‐selena‐7‐azabicyclo(3.3.1)nonan‐9‐one and 7‐Benzyl‐3‐selena‐7‐azabicyclo(3.3.1)nonane Hydroperchlorate.
Authors: THOMPSON M. D. , SMITH G. S. , BERLIN K. D. , HOLT E. M. , SCHERLAG B. J. , VAN DER HELM D. , MUCHMORE S. W. , FIDELIS K. A. 
Published: May 2016

AbstractThe 3‐selena‐7‐azabicyclo(3.3.1)nonanes (IV) ‐ (VI) and (VIII) ‐ (X) are synthesized as outlined in the reaction scheme.
ChemInform Abstract: Metalloporphyrins with Metal‐Metal Bonds. Synthesis and Characterization of (P)InMn(CO)5, (P)InCo(CO)4, and (P)InM(CO)3Cp Where M: Cr, Mo, and W. Molecular Stereochemistry of ((2,3,7,8,12,13,17,18‐Octaethylporphyrinato)indium(III))pentacarbonylmanganese.
Authors: GUILARD R. , MITAINE P. , MOISE C. , LECOMTE C. , BOUKHRIS A. , SWISTAK C. , TABARD A. , LACOMBE D. , CORNILLON J.‐L. , KADISH K. M. 
Published: May 2016

AbstractThe title complexes (III) can be prepared using slightly different methods.
ChemInform Abstract: Synthesis, Electrochemistry, and Spectroelectrochemistry of Thallium(III) Porphyrins. Redox Properties of Five‐Coordinate Ionic and σ‐Bonded Complexes.
Authors: KADISH K. M. , TABARD A. , ZRINEH A. , FERHAT M. , GUILARD R. 
Published: May 2016

AbstractThe Tl porphyrin derivatives show the most unusual behavior of all group 13 metalloporphyrins.
ChemInform Abstract: Mechanism of Titanocene Metallacyclobutane Cleavage and the Nature of the Reactive Intermediate.
Authors: ANSLYN E. V. , GRUBBS R. H. 
Published: May 2016

AbstractThe reaction of titanocene metallacyclobutanes (I)‐(V) and phosphine adducts (VI) via titanocene methylidene Cp2Ti=CH2 trapped by acetylenes (VII) or olefin (VIII) displays either first‐ or second‐order kinetics depending upon the metallacycle, its reaction temp., and the trapping agent.
ChemInform Abstract: Synthesis, Characterization, Low‐Temperature (50 K) Neutron Diffraction Structure, and Reactivity of Chlorodihydridotetrakis(trimethylphosphine)tantalum(III).
Authors: LUETKENS M. L. JUN. , HOPKINS M. D. , SCHULTZ A. J. , WILLIAMS J. M. , FAIR C. K. , ROSS F. K. , HUFFMAN J. C. , SATTELBERGER A. P. 
Published: May 2016

AbstractThe preparation of the title compound (II) and its reactivity toward potential ligands is outlined in the scheme.
ChemInform Abstract: Synthesis, X‐Ray Crystal Structures, and Ligand Substitution Kinetics of the Carbon‐Bonded Chromium(III) Complexes trans‐(CrR(acac)2(L)) (R: CH2Cl, CHCl2; L: H2O, CH3OH, Pyridine).
Authors: OGINO H. , SHOJI M. , ABE Y. , SHIMURA M. , SHIMOI M. 
Published: May 2016

AbstractThe starting compounds (I) are prepared in solution by improved methods to give approximately quantitative yields.
ChemInform Abstract: Two‐Electron Transfer Accompanied by Metal‐Metal Bond Formation. Synthesis and Electrochemistry of Dinuclear Molybdenum and Tungsten Carbonyl Thiolates.
Authors: SMITH D. A. , ZHUANG B. , NEWTON W. E. , MCDONALD J. W. , SCHULTZ F. A. 
Published: May 2016

AbstractThe thiolate‐bridged dianionic complexes (III) are prepared as shown and characterized as 2:1 electrolytes consisting of two thiolate‐bridged M(0) tetracarbonyl fragments by analytical, spectroscopic and conductometric data.
ChemInform Abstract: Intramolecular Cyclopropanation and Olefin Metathesis Reactions of (CO)5W=C(OCH2CH2CH=CHOCH3)C6H4‐p‐CH3.
Authors: CASEY C. P. , HORNUNG N. L. , KOSAR W. P. 
Published: May 2016

AbstractIn coordinating solvents such as MeCN or THF the title complexes trans‐(I) and cis‐(II) are stereospecifically converted to the cyclopropane derivatives exo‐(III) and endo‐(IV).
ChemInform Abstract: Mononuclear Manganese(IV) Complexes of Hydroxyl‐Rich Schiff Base Ligands.
Authors: KESSISSOGLOU D. P. , LI X. , BUTLER W. M. , PECORARO V. L. 
Published: May 2016

AbstractHydroxyl‐rich Schiff base ligands prepared from salicylaldehyde (II) and appropriate hydroxyl‐rich prim. amines such as (II) react with Mn(III) acetate (III) or Mn(II) chloride in basic solution of DMF or MeOH with air oxidation generating the monomeric stable Mn(IV) complexes (IV) and (V).
ChemInform Abstract: Electrochemistry of Nitrite Reductase Model Compounds. Part 3. Formation and Characterization of a Bis(hydroxylamine)(tetraphenylporphyrinato)iron(II) Complex.
Authors: FENG D. , RYAN M. D. 
Published: May 2016

AbstractThe reaction of a Fe(III) or Fe(II) porphyrin complex with hydroxylamine at room temp. yields a nitrosyl complex (III) whereas at lower temp. (< ‐20 °C) the title compound is obtained.
ChemInform Abstract: Synthesis and Spectroscopic and Structural Characterization of Derivatives of the Quasi‐Alkoxide Ligand (OBMes2)‐ (Mes: 2,4,6‐Me3C6H2).
Authors: WEESE K. J. , BARTLETT R. A. , MURRAY B. D. , OLMSTEAD M. M. , POWER P. P. 
Published: May 2016

AbstractTreatment of the hydrogen‐bonded tetramer (I) with BuLi (II) affords a suspension of LiOBAr2 which can be crystallized from THF (III) as the dimer (IV).
ChemInform Abstract: Synthesis and X‐Ray Structural Characterization of the Metal Borylamide Complexes Li(Et2O)2NPhBMes2, (THF)(Et2O)2LiClCo(NPhBMes2)2, and Mn(NMesBMes2)2·3 PhMe (Mes: 2,4,6‐Me3C6H2): Modified Amide Ligands with Poor Bridging and π‐Donor Characteristics.
Authors: BARTLETT R. A. , FENG X. , OLMSTEAD M. M. , POWER P. P. , WEESE K. J. 
Published: May 2016

AbstractThe aminoboranes (III) are prepared by reaction between the Li amides of (I), generated in situ, and the boron fluoride (II).
ChemInform Abstract: An Unusual Six‐Membered Chelate Ring Involving Carboxylic Function to Copper(II) Coordination: Synthesis, Crystal Structure, and Properties of Aquo(((2‐carboxyethyl)imino)diacetato)copper(II).
Authors: NGUYEN‐HUY‐DUNG NGUYEN‐HUY‐DUNG , VIOSSAT B. , BUSNOT A. , GONZALEZ PEREZ J. M. , GONZALEZ GARCIA S. , NICLOS GUTIERREZ J. 
Published: May 2016

AbstractThe title complex (I) is obtained by 2:1 molar reaction of (2‐carboxyethyl)iminodiacetic acid and Cu2(CO3)(OH)2 in aqueous solution at 60 °C. It is characterized by X‐ray structure analysis (space group P21/c, Z=4), potentiometric and conductometric titrations, thermal, spectral (IR, UV, ESR), and magnetic data.
ChemInform Abstract: Spontaneous Reduction of Copper(II) Complexes of the Ligand 3,6‐Bis(2‐pyridylthio)pyridazine. Crystal Structures of Bis(3,6‐bis(2‐pyridylthio)pyridazine‐N1,N2)aquocopper(II) Diperchlorate Trihydrate and Bis(μ‐3,6‐bis(2‐pyridylthio)pyridazine‐N4,μ‐N1,μ‐N2,N3)dicopper(I) Diperchlorate.
Authors: MANDAL S. K. , THOMPSON L. K. , GABE E. J. , LEE F. L. , CHARLAND J.‐P. 
Published: May 2016

AbstractThe ligand (IV) forms both mono‐ and binuclear Cu(II) and binuclear Cu(I) derivatives.
ChemInform Abstract: Mixed‐Metal Gold Phosphine Cluster Complexes and Their Reactivity Toward Triphenylphosphine.
Authors: ALEXANDER B. D. , BOYLE P. D. , JOHNSON B. J. , CASALNUOVO J. A. , JOHNSON S. M. , MUETING A. M. , PIGNOLET L. H. 
Published: May 2016

AbstractThe reactivity of several mixed‐metal gold clusters toward PPh3 (II) is investigated.
ChemInform Abstract: Polyaza Cavity‐Shaped Molecules. Part 12. Ruthenium(II) Complexes of 3,3′‐Anellated 2,2′‐Bipyridine: Synthesis, Properties, and Structure.
Authors: THUMMEL R. P. , LEFOULON F. , KORP J. D. 
Published: May 2016

AbstractThe preparation of the complexes (IV) and (VI) is described.
ChemInform Abstract: An Unusual Example of Intramolecular Hydrogen Bonding in a Metal Carbonyl Cluster Compound. Synthesis and Crystal and Molecular Structure of Ru6(CO)16(μ‐CO)2(μ‐OH)2(μ4‐S).
Authors: ADAMS R. D. , BABIN J. E. , TASI M. 
Published: May 2016

AbstractThe title complex (I) is obtained as a minor product in the reaction of a mixture of the compounds Ru3(CO)9(μ3‐CO)(μ3‐S) and Ru3(CO)12 with H2O upon UV irradiation.
ChemInform Abstract: Synthesis of Trifluorosilyl Organometallic Complexes from Trifluorosilyl Radicals and Metal Atoms.
Authors: BIERSCHENK T. R. , GUERRA M. A. , JUHLKE T. J. , LARSON S. B. , LAGOW R. J. 
Published: May 2016

AbstractTrifluorosilyl radicals generated in a radio frequence glow discharge of Si2F6 are reacted with metal atoms to give the first homoleptic trifluorosilyl metal compounds.
ChemInform Abstract: Synthesis and Fluorescence Analysis of 3‐Substituted 7‐Dialkylamino‐2H‐1,4‐benzoxazin‐2‐ones.
Authors: TREBAUL C. , RONCALI J. , GARNIER F. , GUGLIELMETTI R. 
Published: May 2016

AbstractThe title compounds (III), (IV), (VI) and (VIII) show a strong fluorescence and may be used as laser dyes.
ChemInform Abstract: Synthesis and Structure‐Activity Studies of Corticosteroid 17‐Heterocyclic Aromatic Esters. Part 1. 9α,11β‐Dichloro Series.
Authors: SHAPIRO E. L. , GENTLES M. J. , TIBERI R. L. , POPPER T. L. , BERKENKOPF J. , LUTSKY B. , WATNICK A. S. 
Published: May 2016

AbstractEsterification of the hydroxypregnadienedione (I) with the heterocyclic acid chlorides (II) yields the carboxylates (III).
ChemInform Abstract: Peptide Synthesis in Aqueous Solution. Part 1. Application of p‐Dialkylsulfoniophenols as a Water‐Soluble Coupling Reagent.
Authors: KOUGE K. , KOIZUMI T. , OKAI H. , KATO T. 
Published: May 2016

AbstractEsters of the title reagent (VII), e.g. the compounds (II) or (VIII) and (XI) selectively react at controlled pH with the bifunctional amino acids (I) and (IV) to afford the α‐acylated amino acids (III) and (V) or the peptides (IX) and (XII).
ChemInform Abstract: Synthesis of Peptides Containing α,α′‐Iminodicarboxylic Acids.
Authors: YAMADA T. , MOTOYAMA N. , TANIGUCHI T. , KAZUTA Y. , MIYAZAWA T. , KUWATA S. , MATSUMOTO K. , SUGIURA M. 
Published: May 2016

AbstractThe peptides (V) containing an α,α'‐iminodicarboxylic acid unit are obtained by the four‐component Ugi condensation reaction of the N‐protected amino acids (I), the amino esters (II), isobutyraldehyde (III), and tosylmethyl isocyanide (IV).
ChemInform Abstract: One‐Step Stereoselective Syntheses of Cyclopentanol Derivatives from 1,5‐Anhydro‐2,3‐O‐benzylidene‐β‐D‐ribofuranose.
Authors: KLEMER A. , KOHLA M. 
Published: May 2016

AbstractThe anhydroribofuranose (I) reacts with butyl‐ (IIa) or methyllithium (IIb) to give the hexuloses (IVa) or (IVb).
ChemInform Abstract: 6‐Methyl‐6‐azabicyclo(3.2.1)octan‐3α‐ol 2,2‐Diphenylpropionate (Azaprophen), a Highly Potent Antimuscarinic Agent.
Authors: CARROLL F. I. , ABRAHAM P. , PARHAM K. , GRIFFITH R. C. , AHMAD A. , RICHARD M. M. , PADILLA F. N. , WITKIN J. M. , CHIANG P. K. 
Published: May 2016

AbstractAzaprophen (IV) is synthesized by reduction of the ketone (I) and subsequent esterification of the isomeric alcohols (II).
ChemInform Abstract: Nucleotides. Part 27. Bis(2‐(p‐nitrophenyl)ethyl) Phosphorochloridate, a New Versatile Phosphorylating Agent in Nucleotide Chemistry.
Authors: HIMMELSBACH F. , CHARUBALA R. , PFLEIDERER W. 
Published: May 2016

AbstractThe title reagent (IV), which is readily accessible from the components (I) and (II), is efficiently used for 3'‐ and 5'‐phosphorylations of nucleosides.
ChemInform Abstract: Synthesis and Antiviral Evaluation of Carbocyclic Analogues of 2‐Amino‐ 6‐Substituted Purine 3′‐Deoxyribofuranosides.
Authors: SHEALY Y. F. , O'DELL C. A. , ARNETT G. 
Published: May 2016

Abstract2‐Amino‐4,6‐dichloropyrimidine (I) reacts with the aminohydroxy(hydroxymethyl)cyclopentane (II) to form the pyrimidine derivative (III) which is converted into the triaminopyrimidine (VI).
ChemInform Abstract: Structure‐Activity Relationship in PAF‐Acether. Part 3. Hydrophobic Contribution to Agonistic Activity.
Authors: GODFROID J.‐J. , BROQUET C. , JOUQUEY S. , LEBBAR M. , HEYMANS F. , REDEUILH C. , STEINER E. , MICHEL E. , COEFFIER E. , FICHELLE J. , WORCEL M. 
Published: May 2016

AbstractThe platelet‐activating factor (PAF‐acether) homologues (VI) are synthesized from the glyceryl ethers (I) using modified versions of previously published procedures.
ChemInform Abstract: Synthesis of a Bipolar Phosphatidylethanolamine: A Model Compound for a Membrane‐Spanning Probe.
Authors: DELFINO J. M. , STANKOVIC C. J. , SCHREIBER S. L. , RICHARDS F. M. 
Published: May 2016

AbstractThe mercaptododecanoic acid (Ib), obtained from the bromide (Ia) via the xanthogenate, reacts with benzaldehyde (II) to form the dithioacetal (III).
ChemInform Abstract: Semisynthetic β‐Lactam Antibiotics. Part 4. Synthesis and Antibacterial Activity of New Ureidocephalosporin and Ureidocephamycin Derivatives Containing a Catechol Moiety or Its Acetate.
Authors: OHI N. , AOKI B. , SHINOZAKI T. , MORO K. , KUROKI T. , NOTO T. , NEHASHI T. , MATSUMOTO M. , OKAZAKI H. , MATSUNAGA I. 
Published: May 2016

AbstractThe cephalosporins (III) mentioned in the title are prepared either by coupling the ureidocarboxylic acids (I) with 7‐aminocephalosporanic acid (II) or by reaction of the carbamic acid chlorides (VII) with the aminocephem (VIII).
ChemInform Abstract: Enzymatic Cyclization of 2‐Carbamoyloxy Benzoates: Formation of 2H‐1,3‐ Benzoxazine‐2,4(3H)‐diones.
Authors: KAMAL A. , RAO A. B. , SATTUR P. B. 
Published: May 2016

AbstractThe salicylic acid esters (I) react with chlorosulfonyl isocyanate (II), yielding the carbaminates (III).
ChemInform Abstract: Observation of the Gas‐Phase Infrared Spectrum of BH3.
Authors: KAWAGUCHI K. , BUTLER J. E. , YAMADA C. , BAUER S. H. , MINOWA T. , KANAMORI H. , HIROTA E. 
Published: May 2016

AbstractThe gas‐phase spectrum of BH3, produced by photolysis of B2H6 or BH3CO with an ArF excimer laser, is detected for the first time by diode laser spectroscopy through the observation of the ν2 band.
ChemInform Abstract: Evidence for a New Family of Perovskite‐Related Compounds.
Authors: SAINE M.‐C. 
Published: May 2016

AbstractCa(K6Ba2)U6O24 has been prepared by a flux method from a stoichiometric mixture of U3O8, Nb2O5, and BaCO3(K2CO3, 1200 °C, 15 h, no yield given).
ChemInform Abstract: Moessbauer and DTA Studies on the Structure of Semiconducting Sodium Vanadate Glasses.
Authors: NISHIDA T. , OGATA M. , TAKASHIMA Y. 
Published: May 2016

AbstractVanadate glasses having the following compositional ranges have been studied: 0‐40 mol% Na2O, 50‐90 mol% V2O5, and 0‐30 mol% Fe2O3.
ChemInform Abstract: Effects of Hydrogen Absorption on the Electrical Resistivity of LaCo5 Films and the Determination of the Hydrogen Content in the Films.
Authors: SAKAGUCHI H. , YAGI Y. , TANIGUCHI N. , ADACHI G. , SHIOKAWA J. 
Published: May 2016

AbstractThe electrical resistivity of amorphous LaCo5 films is found to increase during absorption of hydrogen.
ChemInform Abstract: Kinetics and Mechanism of Oxidation Reaction of the Oxo‐Bridged Trinuclear ((NH3)5RuORu(NH3)4ORu(NH3)5)6+ by Hydrogen Peroxide in Acid Medium.
Authors: BANAS B. 
Published: May 2016

AbstractThe kinetics of the title reaction (see scheme) have been investigated spectrophotometrically at 14.6‐35.2 °C using different acidities and ionic strengths (NaClO4, HClO4).
ChemInform Abstract: “Pseudoliquid” Behavior of Heteropoly Compound Catalysts. Unusual Pressure Dependencies of the Rate and Selectivity for Ethanol Dehydration.
Authors: MISONO M. , OKUHARA T. , ICHIKI T. , ARAI T. , KANDA Y. 
Published: May 2016

AbstractEtOH dehydration has been carried out over H3PW12O40 and Cs2.5H0.5PW12O44, resp., by a conventional flow method using 0.4‐60 kPa EtOH in He.
ChemInform Abstract: The Role of Bismuth in Molybdenum‐Praseodymium‐Based Catalysts.
Authors: KREMENIC G. , LOPEZ NIETO J. M. , FIERRO J. L. G. , TEJUCA L. G. 
Published: May 2016

AbstractThe effect of the Bi2O3 content in Mo‐Pr‐Bi‐O catalysts (constant atomic ratio Mo/(Mo + Pr) = 0.88) used for propene oxdiation has been studied.
ChemInform Abstract: Soluble Metal Selenides. Synthesis and Structure of the Tridecaselenidovanadate Anion, V2Se2‐ 13.
Authors: CHAU C.‐N. , WARDLE R. W. M. , IBERS J. A. 
Published: May 2016

Abstract(Et4N)2(V2Se13) (I) has been prepared by addition of a toluene solution of bis(dimethyloctylsilyl)selenide to a mixture of NH4VO3, (Et4N)Cl, and Et3N in MeCN (20% yield).
ChemInform Abstract: Preparation of 3s‐Type Mo0.5Ta0.5S2.
Authors: SAEKI M. , ONODA M. 
Published: May 2016

AbstractAn equimolar mixture of TaS2 and MoS2 (both prepared at 1000 °C, resulting in 1s‐TaS2 and 2s‐MoS2 with many stacking faults) is sealed in an evacuated silica tube with a small amount of NH4Cl as mineralizing agent (1000 °C, 1 week).
ChemInform Abstract: Synthesis and Crystal Structure of a New Ternary Phosphide, U4Cu4P7.
Authors: NOEL H. , ZOLNIEREK Z. , KACZOROWSKI D. , TROC R. , STEPIEN‐DAMM J. 
Published: May 2016

AbstractSingle crystals of the title compound have been prepared by the chemical transport method from U3P4, Cu, and P (1:3:1) using iodine as transporting agent (1000 → 1050 °C).
ChemInform Abstract: Metal Ion‐Bridged Intramolecular Stacking Interaction Between the Tryptophyl Residue and the Aromatic Heterocyclic Amine Within the Ternary Complex (1,10‐Phenanthroline)(L‐tryptophanato‐O,N)copper(II) Percholate‐Water (1/2.5): An X‐Ray Study.
Authors: AOKI K. , YAMAZAKI H. 
Published: May 2016

AbstractThe title complex crystallizes in the space group P212121 with Z=4.
ChemInform Abstract: The Influence of the Alkyl Substituents on Copper(II) Extraction by 1‐Alkyl‐2(2‐hydroxyphenyl)‐δ2‐imidazolines.
Authors: UHLIG E. , UNDEUTSCH B. 
Published: May 2016

AbstractIn acid solution title compounds normally form monocations and Cu(II) chelates such as (II).
ChemInform Abstract: Specific Ag+ Ion Binding and Transport Properties of “Tripod” Type Open‐Chain Cryptands.
Authors: TSUKUBE H. , TAKAGI K. , HIGASHIYAMA T. , IWACHIDO T. , HAYAMA N. 
Published: May 2016

AbstractThe cation binding and transport properties of the tripod host molecules (I) are compared with those of the macrocycles (II).