bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Menke Reaction of Disulfonyl Derivatives of Phenylenediamines.
Authors: ZAKATOV V. V. , DUBINA V. L. , BEZVERKHII N. P. , CHEREMISINOV I. V. , NEVIDOMSKAYA G. S. 
Published: May 2016

AbstractThe nitration reactions of the o‐ (Ia) and the m‐phenylenediamine ditosylates (Ib) according to method A) afford the nitro derivatives (IIa) or (IIb), whereas p‐methylenediamine ditosylate (III) gives the p‐benzoquinone derivative (IV).
ChemInform Abstract: Monosulfonylcyclopentadienes.
Authors: HARTKE K. , JUNG M. H. , ZERBE H. , KAEMPCHEN T. + 
Published: May 2016

AbstractAddition of the sulfonylbromides (II) to cyclopentadiene (I) yields a cis/trans mixture of the bromosulfones (IIIa) ‐ (IIId).
ChemInform Abstract: Coupling of Aryl Chlorides by Nickel and Reducing Metals.
Authors: COLON I. , KELSEY D. R. 
Published: May 2016

AbstractThe coupling of the aryl chlorides (I) producing the biaryls (V) is accomplished by reacting (I) with zinc (III) and nickel chloride (II) in the presence of a phosphine such as (IV).
ChemInform Abstract: Synthesis and Cytostatic Activity of N‐(Chloroethylaminoethyl)‐4‐chloro‐L‐proline Ethyl Ester.
Authors: KHVOROVA N. M. , KLYUEV N. A. , NIFONTOV V. I. , PUSHKAREVA Z. V. , BOBARYKINA K. YU. , SMAL'KO M. A. , ANOSHINA G. M. 
Published: May 2016

AbstractStarting with the chloroproline ester (I) or the tosylate (VIII), the title compound (VII) is obtained by three synthetic routes.
ChemInform Abstract: Synthesis and Decomposition of 1,3‐Dioxolanehydrotrioxides.
Authors: KURAMSHIN E. M. , KULAK L. G. , ZLOTSKII S. S. , RAKHMANKULOV D. L. 
Published: May 2016

AbstractTreatment of the dioxolanes (I) with ozone affords the title compounds (II), which are stable at low temperatures (up to ‐40 °C).
ChemInform Abstract: Reaction of 1,2‐Dihydro‐3‐indazolone with v‐Dialkylaminoalkyl Halides and α,ω‐Dihalogenalkanes.
Authors: OELSCHLAEGER H. + , MATTHIESEN U. , SHAIK M. A. 
Published: May 2016

AbstractThe reaction of 1,2‐dihydro‐3‐indazolone (I) with 1‐bromo‐3‐chloropropane (II) yields the isomeric tricyclic compounds (III) and (IV).
ChemInform Abstract: Products from Furans. Part 4. Selective Oxidation of 2‐Furfuryl Alcohol Derivatives, in the Presence of Aryl Thioethers, with N‐Bromosuccinimide (NBS). A New Procedure for the Preparation of 2H‐Pyran‐3(6H)‐ones.
Authors: GEORGIADIS M. P. , COULADOUROS E. A. 
Published: May 2016

AbstractThe furfuryl alcohols (I) react with NBS (II), yielding the hydroxypyranones (III).
ChemInform Abstract: A Novel Synthesis of 1‐(2,2‐Dichlorovinyl)uracils by the Reactions of 3‐tert.‐Butyl‐6‐methyluracil and 3‐tert.‐Butyl‐5‐chloro‐6‐methyluracil with Trichloroacryloyl Chloride.
Authors: AKHMETOV L. I. , IVANOV A. V. , SAVIN V. P. , TALZI V. P. 
Published: May 2016

AbstractThe uracils (I) are converted to their sodium salts, which react with perchloroacryloyl chloride (II) to give the title compounds (III) instead of the expected N‐acyl derivatives.
ChemInform Abstract: Polyfluoroalkyl Dibasic Acid Phosphates, Bis(polyfluoroalkyl) Monobasic Acid Phosphates, and Their Precursors.
Authors: MAHMOOD T. , SHREEVE J. M. 
Published: May 2016

AbstractReaction of the lithium salts of the alcohols (I) with PCl3 yields ‐ in dependence on the stoichiometry of the reactants ‐ either the dichlorophosphinites (II) or the chlorophosphonites (IV); both undergo N2O4 oxidation to the dichlorophosphinates (III) or to the chlorophosphonates (Va).
ChemInform Abstract: Low Coordinated Phosphorus Compounds. Part 51. Isophosphindoles from 1,2‐Dicarbonyl Dichlorides and Tris(trimethylsilyl)phosphane.
Authors: APPEL R. , CASSER C. , KNOCH F. , NIEMANN B. 
Published: May 2016

AbstractThe 1:1 molar reaction of trisilylphosphane (I) with cyclic 1,2‐dicarbonyl dichlorides (IIa)‐(IIc) leads to the title compounds (III).
ChemInform Abstract: Complexes of IIB Metal Halides with N,N‐Diethylbenzenecarbothioamide Crystal Structure of (Hg(C6H5C(S)N(C2H5)2)I2)2.
Authors: CASTINEIRAS A. , ARQUERO A. , MASAGUER J. R. , MARTINEZ‐CARRERA S. , GARCIA‐BLANCO S. 
Published: May 2016

AbstractThe complexes (I)‐(IV) are prepared by reaction of a solution of the metal halide in EtOH or 1,2‐dichloroethane with the ligand at room temp. for two or more days.
ChemInform Abstract: Spectrophotometric and X‐Ray Absorption Edge Study of Complexation of Carbon Monoxide with Ferric Tetrasulfophthalocyanine in Alkaline Solution.
Authors: LINKOUS C. A. , O'GRADY W. E. , SAYERS D. , YANG C. Y. 
Published: May 2016

AbstractThe square‐planar title complex is found to complex OH‐ and CO and is believed to produce a reduced state of the metal and a ligand radical of the macrocycle.
ChemInform Abstract: Facile Synthesis of (Z)‐12‐Nonadecen‐9‐one and (Z)‐13‐Eicosen‐10‐one ‐ Components of the Sex Pheromone of Carposina Niponensis Walsingham.
Authors: KULINKOVICH O. G. , TISHCHENKO I. G. , SOROKIN V. L. 
Published: May 2016

AbstractThe title compounds (IVa) and (IVb) are obtained by an improved method.
ChemInform Abstract: Transition‐Metal Complexes of Inorganic Sulphur‐Nitrogen Ligands
Authors: CHIVERS T. , EDELMANN F. 
Published: May 2016

AbstractReview: (preparation, spectroscopic and structural studies, reactions of complexes of sulphur nitrides, thiazyl halides, sulphur‐nitrogen oxides, sulphur imides, and cyclometallathiazenes and related complexes.
ChemInform Abstract: Vapor‐Phase Composition Above the CdI2‐NaI and the ThI4‐NaI Systems.
Authors: RUSSELL T. D. 
Published: May 2016

AbstractThe UV adsorption spectra of the vapor phases in equilibrium with ThI4, CdI2, and NaI single components and NaI‐CdI2 and NaI‐ThI4 molten salt mixtures are reported and briefly discussed.
ChemInform Abstract: Steady‐State Decomposition of Ammonia on the Pt(110)‐(1 · 2) Surface.
Authors: VAJO J. J. , TSAI W. , WEINBERG W. H. 
Published: May 2016

AbstractAbsolute reaction rates have been measured for the steady‐state decomposition of NH3 on the Pt(110)‐(1 · 2) surface at pressures in the range 1·10‐6 ‐2.6·10‐6 Torr and temp. of 350‐900 K. Thermal desorption measurements, conducted during the steady‐state decomposition, have been used to determine composition, coverage, and kinetics of desorption of the adsorbed species that are present during NH3 decomposition.
ChemInform Abstract: Dependence of the Catalytic Properties of Phosphates with Zeolite Structure on the State of Their Al and P Atoms.
Authors: KIKHTYANIN O. V. , IONE K. G. , MASTIKHIN V. M. 
Published: May 2016

AbstractAluminophosphate catalysts M‐AlPO4‐5 (M: Be2+, B3+, Ga3+, Fe3+, Si4+, Ti4+) are synthesized and studied by XRD, high‐resolution MAS NMR and selectivity measurements (methanol conversion).
ChemInform Abstract: Reactions of Hydrocarbons on Alumina‐Supported Pt‐Ir Bimetallic Catalysts. Part 1. Exchange of Methane and Cyclopentane with Deuterium, and Hydrogenolysis of Butane, Pentane and Cyclopentane.
Authors: GARDEN D. , KEMBALL C. , WHAN D. A. 
Published: May 2016

AbstractExchange reactions with deuterium of cyclopentane (303 K) and of methane (473 K) and the hydrogenolysis of n‐butane, n‐pentane and cyclopentane have been studied on a series of alumina‐supported Pt‐Ir catalysts.
ChemInform Abstract: Butanolides and Butenolides by Intramolecular Ene‐Reaction During Thermolysis of Propargyl Propiolates.
Authors: BILINSKI V. , KARPF M. , DREIDING A. S. 
Published: May 2016

AbstractGas‐phase flow thermolysis of the alkynyl alkynoates (Ia)‐(Ic) at 550 °C yields the products (III), (V), or (X)‐(XIII) via the intermediates shown in the scheme.
ChemInform Abstract: 3,3‐Bis(alkylthio)‐2‐phenylacrylaldehydes as Building Sets for Thiophenes and Pyrazoles.
Authors: RUDORF W.‐D. 
Published: May 2016

AbstractOn the basis of the known synthesis of (VIf) from (I), the title compounds (VI) are prepared in a one‐pot sequence via alkylation of the dithiolates (III).
ChemInform Abstract: Tosyloxylactonization of Alkenoic Acids with (Hydroxy(tosyloxy)iodol) Benzene.
Authors: SHAH M. , TASCHNER M. J. , KOSER G. F. , RACH N. L. 
Published: May 2016

AbstractThe alkenoic acids (I) or (V) are converted to the tosyl lactones (III), (IVb), and (IVc), or (VI) by treatment with the hypervalent iodine reagent mentioned in the title.
ChemInform Abstract: Palladium‐Mediated Diazo Insertions: Preparation of 3‐Alkyl‐2‐carbomethoxycyclopentenones.
Authors: TABER D. F. , AMEDIO J. C. JUN. , SHERRILL R. G. 
Published: May 2016

AbstractThe diazoketo esters (I) or (V) undergo a palladium‐mediated cyclization reaction with compound (II) to form cyclopentenones (III) or (VI).
ChemInform Abstract: Stereoselective Acid‐Catalyzed Claisen Rearrangements.
Authors: DAUB G. W. , SHANKLIN P. L. , TATA C. 
Published: May 2016

AbstractThermal ortho ester Claisen rearrangement during the reaction of allylic alcohols (I) with ortho esters (II) produces mixtures of the esters (III) and (IV) with high diastereoselectivity for the syn‐products (III).
ChemInform Abstract: Dye Sensitized Photooxygenation of Substitute Oxime Carbamates.
Authors: CHAWLA H. M. , HASSNER A. 
Published: May 2016

AbstractCyclohexanone oxime (Ia) or the corresponding oxime ether (Ib) are photooxygenated to produce cyclohexanone (III) via the intermediate (II).
ChemInform Abstract: 3‐Oxo‐indazoline and 4‐Oxo‐dihydroquinazoline Derivatives from Isatic Acids.
Authors: ALEMAGNA A. , BALDOLI C. , LICANDRO E. , MAIORANA S. , PAPAGNI A. 
Published: May 2016

AbstractIn an attempt to obtain the phosphoranes (III), which are the proposed intermediates in the reaction of the isatins (I) to give the indazolines (IV), the hydrazonoyl chlorides (VIIIa) and (VIIIb) are synthesized from (I).
ChemInform Abstract: Base‐Induced α‐Alkenylation of Ethyl Bromoacetate, Phenacyl Bromide, and Chloroacetonitrile via B‐trans‐1‐Alkenyl‐9‐borabicyclo(3.3.1)nonanes.
Authors: BROWN H. C. , BHAT N. G. , CAMPBELL J. B. JUN. 
Published: May 2016

AbstractB‐trans‐1‐alkenyl‐9‐borabicyclo(3.3.1)nonane derivatives (I) react with halides (III) in the presence of the base (II) to form E‐olefins (IV) with an isomeric purity of 95 ‐ 98%.
ChemInform Abstract: Peptide Synthesis by Prior Thiol Capture. Part 4. Amide Bond Formation: The Effect of a Side‐Chain Substituent on the Rates of Intramolecular O,N‐Acyl Transfer.
Authors: KEMP D. S. , GALAKATOS N. G. , DRANGINIS S. , ASHTON C. , FOTOUHI N. , CURRAN T. P. 
Published: May 2016

AbstractThe rates of O,N‐acyl transfer from (I) to give (II) are studied to determine the effect of the side chains in the amino acids (A).
ChemInform Abstract: A (2+ + 4) Polar Cycloaddition of α‐Thiocarbocations with 1,3‐Dienes: Synthesis and Thermal Reaction of 1‐Acyl‐1‐methylthio‐2‐vinylcyclopropanes.
Authors: ISHIBASHI H. , OKADA M. , NAKATANI H. , IKEDA M. , TAMURA Y. 
Published: May 2016

AbstractTreatment of the dienes (II) or (IV) with the chloromethyl methyl sulfides (I) in the presence of SnCl4 gives the vinylcyclopropanes (III) or (V).
ChemInform Abstract: Generation and Reactions of Lithiated tert. Butyl and 2,6‐Di(tert‐butyl)‐4‐methylphenyl Cyclopropane Carboxylates.
Authors: HAENER R. + , MAETZKE T. , SEEBACH D. 
Published: May 2016

AbstractLithiation of the cyclopropane carboxylates (I), (XIIIa), or (XIIIb) and subsequent reaction with electrophiles (III)‐(XII) yields the derivatives (II), (XIV), or (XVII).
ChemInform Abstract: Improved Route to 3‐Vinyl Substituted Cyclopentanones. Synthesis of (.+‐.)‐Mitsugashiwalactone.
Authors: NUGENT W. A. , HOBBS F. W. JUN. 
Published: May 2016

AbstractThe unsaturated diester (I) gives the cyclopentanones (III) in a tandem addition/cyclization reaction with lithium cuprates (II).
ChemInform Abstract: Enantioface Differentiating Michael Reaction of Ethyl Acetoacetate with Alkylidenemalonates via Chiral Enamine.
Authors: TOMIOKA K. , YASUDA K. , KOGA K. 
Published: May 2016

AbstractThe salt (Ib), prepared from the optically active enamine (Ia), reacts with the alkylidenemalonates (II), yielding the adducts (III).
ChemInform Abstract: Alkoxyoxaziridines. Stereochemical Aspects of Imidate Oxidation, an Asymmetric Synthesis, and Unusually Facile E‐Z Isomerizations.
Authors: GONZALEZ C. O. , GALLIS D. E. , CRIST D. R. 
Published: May 2016

AbstractPeracid oxidation of the imidates (Ia) ‐ (Ic) yields the oxaziridines (II) and (III).
ChemInform Abstract: A New Synthesis of Optically Active 2‐Methoxycarbonyl‐4‐azetidinone from L‐Azetidine‐2‐carboxylic Acid: Utility of Ruthenium Tetroxide Oxidation.
Authors: TANAKA K. , YOSHIFUJI S. , NITTA Y. 
Published: May 2016

AbstractThe azetidinone (L)‐(V) mentioned in the title is a versatile chiral building block in the synthesis of β‐lactam antibiotics.
ChemInform Abstract: Synthesis of 4‐(Cyanomethylidene)‐ and 4‐(Ethoxycarbonylmethylidene)4,5,6,7‐tetrahydroindoles and Their Dehydrogenation to 4‐(Cyanomethyl)‐ and 4‐(Ethoxycarbonylmethyl)indoles.
Authors: MATSUMOTO M. , WATANABE N. 
Published: May 2016

AbstractReaction of the oxotetrahydroindoles (I) with the phosphonates (II) produces a mixture of the methylidene derivatives (III) and (IV).
ChemInform Abstract: The Reaction of β‐Aminoalcohols with 1,2‐Benzenedicarboxaldehyde. A Correction.
Authors: METZ W. A. , WEPPLO P. J. 
Published: May 2016

AbstractThe condensation product of (II) and (III) is the dihydrooxoisoindole (IVa) and not the oxazoline (Ic) as reported previously in the literature.
ChemInform Abstract: Addition of 2(1H)‐Pyridinethione to 3,4‐Dihydro(2H)‐pyran.
Authors: MEREYALA H. B. 
Published: May 2016

AbstractThe dihydropyran (I) reacts with the pyridinethione (II) to give the tetrahydropyranylthiopyridine (III) rather than the adduct (IV) reported in the literature.
ChemInform Abstract: The Reaction of Quinazolin‐4‐ones with Organo‐Metallic Agents. A Persistent Preference for Ring Rupture over Cyclization.
Authors: RANGANATHAN D. , FAROOQUI F. , MEHROTRA S. , KESAVAN K. 
Published: May 2016

AbstractStarting with (Ia), the 3‐substituted quinazolinones (Ib), (III), and (IV) are prepared.
ChemInform Abstract: Formation of Pyrimido(1,2‐a)benzimidazoles from 1,2‐Diaminobenzimidazole and Chalcones.
Authors: ORLOV V. D. , DESENKO S. M. , KRUGLENKO V. P. , GNIDETS V. P. , KLYUEV N. A. , POVSTYANOI M. V. 
Published: May 2016

AbstractThe pyrimido(1,2‐a)benzimidazoles (III) are formed by condensation of 1,2‐diaminobenzimidazoles (I) with the chalcones (II).
ChemInform Abstract: Synthesis and Reactions of the First Examples of the 1,5,2,4‐Dioxadiazine Ring System: 2,4‐Dialkyl‐2H‐1,5,2,4‐dioxadiazine‐3,6(4H)‐diones.
Authors: STOWELL J. C. , LAU C. M. 
Published: May 2016

AbstractThe hydroxylamines (I) react with phosgene (II) in the presence of a base like K2CO3 or NaOH to form the carbonates (III) which yield the dioxadiazindiones (IV) upon further treatment with (II).
ChemInform Abstract: Addition Compounds of Alkali Metal Hydrides. Part 29. Preparation and Properties of Chiral Dialkylmonoalkoxyborohydrides. A New Class of Asymmetric Reducing Agents.
Authors: BROWN H. C. , PARK W. S. , CHO B. T. 
Published: May 2016

Abstract9‐Borabicyclononane (II) (9‐BBN) reacts with the optically active alcohols (I) to form the alkoxy derivatives (III) which are converted to the potassium boranate derivatives (IV).
ChemInform Abstract: Preparation of Enantiomerically Pure β‐Silylcarboxyl Derivatives by Asymmetric 1,4‐Addition to N‐Enoyl‐sultams.
Authors: OPPOLZER W. , MILLS R. J. , PACHINGER W. , STEVENSON T. 
Published: May 2016

AbstractThe sultam (IV) is readily prepared from the acid chloride of (II) with the component (I).
ChemInform Abstract: Synthesis of Phosphinamides in the 5,6‐Oxaphosphabicyclo(2.2.2)octene Series as Possible Precursors of Metaphosphoramidates.
Authors: QUIN L. D. , SZEWCZYK J. , SZEWCZYK K. M. , MCPHAIL A. T. 
Published: May 2016

AbstractThe phospholene oxides (I) and (II) undergo a bromination‐dehydrobromination sequence to give phosphole oxides, which dimerize to yield the phosphanorbornenes (III) or can be trapped with dienophiles like (IV) to yield the adducts (V).
ChemInform Abstract: 1,2,3‐Selenadiazolo(4,5‐d)pyrimidine‐5,7(4H,6H)dione. A Novel Anellated Heterocyclic System.
Authors: IVANOV E. I. , YAVOLOVSKII A. A. , DANILIN V. V. , TKACH A. E. , IVANOVA R. YU. 
Published: May 2016

Abstract6‐Hydrazinouracil (I) cyclizes with selenous acid to give the selenadiazolopyrimidinedione (II).
ChemInform Abstract: A Facile High‐Yield Synthesis of Di‐η5‐cyclopentadienylhafnacyclopentadiene Compounds.
Authors: SABADE M. B. , FARONA M. F. 
Published: May 2016

AbstractHafnocene dichloride (I) is reductively coupled with the alkynes (II), yielding the hafnacyclopentadienes (III).
ChemInform Abstract: Gold(I) Complexes with Bidentate Tertiary Phosphine Ligands: Formation of Annular vs. Tetrahedral Chelated Complexes.
Authors: BERNERS‐PRICE S. J. , SADLER P. J. 
Published: May 2016

AbstractReactions of the Au(I) complexes (Ia)‐(Ie), prepared from NaAuCl4 by thioglycol reduction followed by 2:1 molar reaction with diphosphines, with further diphosphines are studied by 31P NMR spectroscopy.
ChemInform Abstract: Metabolites from the Marine Sponge Spongionella Gracilis. Three Further Nor‐Diterpenes, One of Them Based on a Novel Carbocyclic Skeleton.
Authors: MAYOL L. , PICCIALLI V. , SICA D. 
Published: May 2016

AbstractThe title compounds (I) and (II), the latter with a novel carbocyclic skeleton, are very rare metabolites from a marine environment.
ChemInform Abstract: Rearrangements of Pinane Derivatives. Part 9. 8,8‐Dimethyltricyclo(5.1.1.02,5)nonan‐2β‐ol, a Tricyclic Pinane Derivative.
Authors: GIDDINGS R. M. , JONES‐PARRY R. , OWEN R. , WHITTAKER D. 
Published: May 2016

AbstractThe acetate of the previously unknown title compound (II) is prepared by acetolysis of the bicyclic tosylate (I) as main product.
ChemInform Abstract: Deoxy‐nitrosugars. Part 16. Synthesis of N‐Acetyl‐4‐deoxyneuraminic Acid.
Authors: BAUMBERGER F. , VASELLA A. 
Published: May 2016

AbstractThe synthesis of the title compound (III) starts with the γ‐keto ester corresponding to (Ia), the NaBH4 reduction of which yields the epimeric triols (Ia).
ChemInform Abstract: Synthesis of Reducing Disaccharides Bearing a Lipophilic Chain for the Conjugation of Proteins.
Authors: CABARET D. , KAZANDJAN R. , WAKSELMAN M. 
Published: May 2016

AbstractThe disaccharides (V) and (VIIIb) bearing a lipophilic chain at C‐2 and C‐6 respectively are synthesized as outlined in the reaction scheme.
ChemInform Abstract: Synthesis of a Versatile Prostaglandin Intermediate by Ozonization of endo‐cis‐Bicyclo(3.3.0)oct‐6‐en‐2‐ol.
Authors: THEIL F. , MAHRWALD R. , SCHICK H. , MEL'NIKOVA V. I. , VASIL'EVA L. L. , PIVNITSKY K. K. 
Published: May 2016

AbstractWith a view to the applicability in various prostaglandin (PG2‐type) syntheses the racemic aldehydes (IIIa) and (IIIb) are synthesized from the racemic alcohol (I) by ozonolysis, reduction with Me2S in the presence of traces of HCl (→ (II)) and subsequent base catalyzed epimerization.
ChemInform Abstract: Enzymes in Asymmetric Synthesis: Effect of Reaction Media on the PLE Catalysed Hydrolysis of Diesters.
Authors: GUANTI G. , BANFI L. , NARISANO E. , RIVA R. , THEA S. 
Published: May 2016

AbstractPig liver esterase selectively hydrolyzes the diacetate (I) to produce the optically active hydroxy ester (III).
ChemInform Abstract: A Paramagnetic Cl‐O Defect Produced by X Irradiation of KBr:ClO‐ 4.
Authors: SEKHAR Y. R. , BILL H. 
Published: May 2016

AbstractFrom IR, Raman, and EPR measurements on KBr:ClO4‐ single crystals before and after X‐ray irradiation at 77 K it is concluded that irradiation causes the formation of ClO42‐ (from a parent ClO4‐ ion in Td symmetry) in trigonal symmetry.
ChemInform Abstract: Crystal Structure of ((C2H5)4N)4Cu4Cl12, a New Structural Type for a Tetranuclear Copper(II) Halide Complex.
Authors: WILLETT R. D. , GEISER U. 
Published: May 2016

AbstractThe title compound (prepared by boiling a solution of Et4NCl and CuCl2 in a 1‐propanol‐12 M HCl solution) crystallizes in the monoclinic system, space group P21/c with Z=2.
ChemInform Abstract: The Effects of Anions on Hydrogen Electrosorption on Platinum Single‐Crystal Electrodes.
Authors: MARKOVIC N. , HANSON M. , MCDOUGALL G. , YEAGER E. 
Published: May 2016

AbstractThe hydrogen adsorption on the low index planes of single crystal Pt has been investigated using a technique which involves annealing in a H2 flame and transfer through the air into the electrolyte.
ChemInform Abstract: Systematic Design of Chemical Oscillators. Part 35. Kinetics and Mechanism of the Reaction Between Chlorine(III) and Bromide Ion.
Authors: VALDES‐AGUILERA O. , BOYD D. W. , EPSTEIN I. R. , KUSTIN K. 
Published: May 2016

AbstractThe main products of the title reaction are found to be Br3‐ and Clwhen Br‐ is in excess, and ClO2 and Br2 when chlorine(III) is in excess.
ChemInform Abstract: Derivatives of Tetrathiotungstate(VI). Synthesis and Structure of (W2(S)2(SH)(μη3‐S2)(η2‐S2)3)‐.
Authors: SECHERESSE F. , MANOLI J. M. , POTVIN C. 
Published: May 2016

AbstractThe title anion has been obtained by simple acidification of a solution of (I) in MeCN.
ChemInform Abstract: Multiply Bonded Octahalodiosmate(III) Anions. Part 3. Synthesis and Characterization of the Octahalodiosmate(III) Anions (Os2X8)2‐ (X: Cl, Br). Crystal Structure Determinations of Two Forms of (PPN)2Os2Cl8 (PPN = Bis(triphenylphosphine)nitrogen(1+)).
Authors: FANWICK P. E. , TETRICK S. M. , WALTON R. A. 
Published: May 2016

AbstractThe complexes (III), (V), (VIIIa) and (VIIIb) have been prepared as shown in the scheme.
ChemInform Abstract: Crystal Structure and Magnetic Properties of Dimeric (2‐Hydroxypropane‐1,3‐diylbis(3′‐t‐butyl‐5′‐methylsalicylideneaminato))copper(II).
Authors: HILMS E. , ELIAS H. , PAULUS H. , WALZ L. 
Published: May 2016

AbstractThe title compound (I) crystallizes in the space group I41/a with Z=16.
ChemInform Abstract: Fe7S6(PEt3)4Cl3: A Topological Link Between the Prismatic and Cuboctahedral Structures of Iron‐Sulfur Clusters.
Authors: NODA I. , SNYDER B. S. , HOLM R. H. 
Published: May 2016

AbstractOn topological grounds, the stability of Fe6S6 and Fe8S6 cores suggests the existence of a heptanuclear cluster containing the Fe7(μ4‐S)3(μ3‐S)3 core of idealized C3v symmetry.
ChemInform Abstract: Kinetic and Equilibrium Studies of the Copper(II) Promoted Hydrolysis of Salicyl Phosphate. A Rate Acceleration of 108 for the Hydrolysis of a Phosphate Monoester Dianion.
Authors: HAY R. W. , BASAK A. K. , PUJARI M. P. , PEROTTI A. 
Published: May 2016

AbstractThe dissociation of salicyl phosphate (I) is investigated in the absence and presence of Cu2+ ions.
ChemInform Abstract: Condensation of Pentafluorobenzaldehyde with Ketones.
Authors: MIKHALINA T. V. , FOKIN E. P. 
Published: May 2016

AbstractThe acid catalyzed condensation of the title compound (I) with the aliphatic ketones (II), (IV) or (VI) yields the products (III), (V) and (VIII) of bis‐condensation and the product (VII) of monocondensation.
ChemInform Abstract: (3,3)Claisen vs. (2,3)Wittig Shift in Thermal and Fluoride Ion‐Promoted Rearrangements of the O‐ and C‐Silylated Forms of α‐Allyloxy Esters.
Authors: TAKAHASHI O. , MAEDA T. , MIKAMI K. , NAKAI T. 
Published: May 2016

AbstractThe allyloxycarboxylates (I) are converted to the ester enolates (III) or the α‐trimethylsilylcarboxylates (V).
ChemInform Abstract: Bromination of 4‐(Adamantyl‐1)toluene Initiated with the Di‐tert‐butylperoxyester of 1,6‐Hexanedicarbamic Acid.
Authors: RAKHIMOVA T. F. , OZEROV A. A. , KAL'DERON A. KH. 
Published: May 2016

AbstractThe adamantyltoluene (I) reacts with bromine in the presence of the peroxyurethane (II) at 50°C to give exclusively 2‐bromo‐4‐adamantyltoluene (III).
ChemInform Abstract: Reactions of Enamines of Cyclodecanone and Cyclododecanone with Dimethyl Acetylenedicarboxylate in Apolar and in Polar Solvents.
Authors: VOS G. J. M. , BENDERS P. H. , EGBERINK R. J. M. , REINHOUDT D. N. , HARKEMA S. , VAN HUMMEL G. J. , VAN DER WEERDT A. J. A. 
Published: May 2016

AbstractThe title enamines (I) react with the diester (II) in Et2O as apolar solvent via the (2 + 2) cycloaddition intermediate (III) to afford the dienes (IV), which are stable towards thermal or photochemical treatment.