bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Diastereofacial Selectivity Studies on 3‐Alkenyl‐4,5‐diphenyl‐4,5‐dihydroisoxazoles.
Authors: WADE P. A. , BEREZNAK J. F. , PALFEY B. A. , CARROLL P. J. , DAILEY W. P. , SIVASUBRAMANIAN S. 
Published: May 2016

AbstractThe epoxidation of the 3‐ethenyl‐4,5‐diphenyldihydroisoxazoles (I) yields the epoxides (II) and (III).
ChemInform Abstract: Synthesis and Antimicrobial Activities of 5‐Amidobenzotriazole Derivatives.
Authors: CALIENDO G. , NOVELLINO E. , SAGLIOCCO G. , SANTAGADA V. , SILIPO C. , VITTORIA A. 
Published: May 2016

AbstractThe title compounds of type (I) are synthesized by conventional methods and their antimicrobial activity against Gram‐positive and Gram‐negative bacteria and Candida albicans is evaluated.
ChemInform Abstract: Synthetic Methods. Part 33. Utility of a Polymeric Azide Reagent in the Formation of Di‐ and Triazidomethane. Their NMR Spectra and the X‐Ray Structure of Derived Triazoles.
Authors: HASSNER A. , STERN M. , GOTTLIEB H. E. , FROLOW F. 
Published: May 2016

AbstractThe halomethanes (I), (VI), and (IX) are treated with the polymeric azide reagent (II) to produce the corresponding explosive azidomethanes (III), (VII), and (X).
ChemInform Abstract: A Convenient Synthetic Route to Functionalized 5‐Trifluoroacetyl‐6‐trifluoromethyl‐3,4‐dihydro‐2H‐pyrans: Hetero‐Diels‐Alder Reaction of β,β‐Bis(trifluoroacetyl)vinyl Ethers with Electron‐Rich Alkenes.
Authors: HOJO M. , MASUDA R. , OKADA E. 
Published: May 2016

AbstractThe vinyl ethers (I) and (VI) are acylated with trifluoroacetic anhydride (II) to produce the bis(trifluoroacetyl) derivatives (III) and (VII).
ChemInform Abstract: Periselectivity Between the (1,4) and (3,3) Thermal Sigmatropic Rearrangements of 2‐Allyloxypyridine N‐Oxides.
Authors: ALKER D. , OLLIS W. D. , SHAHRIARI‐ZAVAREH H. 
Published: May 2016

AbstractThe rearrangement of the N‐oxides (I), (IV) is investigated under various conditions (for (I) 19 sets of solvent, temperature and reaction time).
ChemInform Abstract: Synthesis of Novel 2‐Substituted Quinoline Derivatives: Antimicrobial, Inotropic, and Chronotropic Activities.
Authors: FARGHALY A. M. , HABIB N. S. , KHALIL M. A. , EL‐SAYED O. A. , BISTAWROOS A. E. 
Published: May 2016

AbstractThe thiocarbamoylhydrazines (VI) are prepared as outlined.
ChemInform Abstract: Elaboration of 1,2,3,4‐Tetrahydroquinoline via η2‐Imine Complexes of Zirconocene.
Authors: COLES N. , WHITBY R. J. , BLAGG J. 
Published: May 2016

AbstractThe anion of 1,2,3,4‐tetrahydroquinoline (I) reacts with methylzirconocene chloride (II) to produce the complex (III) which forms the unstable THF complex (V) upon thermolysis in tetrahydrofuran (IV).
ChemInform Abstract: Studies on Uracil Derivatives and Analogues. Part 14. A Highly Convenient Procedure for the Synthesis of 5‐(2‐Acylvinyl)uracils, a Group of Novel 5‐Substituted Uracils.
Authors: KUNDU N. G. , CHAUDHURI L. N. , DASGUPTA S. K. 
Published: May 2016

AbstractTreatment of the 2,4‐dimethoxypyrimidines (III) with Me3SiCl/NaI in acetonitrile results in smooth demethylation without concurrent addition to the double bond.
ChemInform Abstract: Reaction of the Cage‐Like Vinylsilylated Double Four‐Ring Silicic Acid ((CH2=CH)(CH3)2Si)8Si8O20 with HSi Containing Compounds and the Preparation of a New Polymer.
Authors: HOEBBEL D. , PITSCH I. , HEIDEMANN D. , JANCKE H. , HILLER W. 
Published: May 2016

AbstractBy means of NMR studies it is shown that the compounds (II) react completely with the eight vinyl groups of the cage‐like silicic acid derivative (I) to give the derivatives (III).
ChemInform Abstract: 1‐Phosphinodiazaphosphene: Synthesis, Crystal Structure, and Bonding Properties.
Authors: ALTMEYER O. , NIECKE E. , NIEGER M. , BUSCH T. , SCHOELLER W. W. , STALKE D. 
Published: May 2016

AbstractReaction of the phosphorodichloridous hydrazide (I) with the lithium phosphide (II) gives the diphosphine (III) which is treated with DBU to produce the title compounds (IV) via elimination of trimethylsilyl chloride.
ChemInform Abstract: Nucleophilic Additions of Phosphorus Compounds to Aromatic Methyleneamines.
Authors: BARLUENGA J. , CAMPOS P. J. , CANAL G. , ASENSIO G. 
Published: May 2016

AbstractThe arylaminomethyl methyl ethers (Ia) and (Ib) react with diphenylphosphine (II) to produce the N‐(phosphinomethyl)arylamines (IIIa) and (IIIb).
ChemInform Abstract: Reaction of Bis(trimethylsilyl) Phosphonite with 1‐Nitro‐1‐alkenes.
Authors: GAREEV R. D. , NAZMUTDINOV R. YA. , BURANGULOVA R. N. , KHAYAROV A. I. 
Published: May 2016

AbstractReaction of the title compounds (I) and (II) produces the aci‐nitroalkylphosphinates (III) which are unstable at room temperature but are further transformed into the phosphinates (IV) and the phosphonites (V) and (VI).
ChemInform Abstract: Bis(trialkoxysilylmethyl) Chalcogenides and 2,2,6,6‐Tetramethoxy‐1‐oxa‐4‐chalcogena‐2,6‐disilacyclohexanes.
Authors: VORONKOV M. G. , SOROKIN M. S. , POTAPOV V. A. 
Published: May 2016

AbstractReaction of the (chloromethyl)trialkoxysilanes (I) with the sodium chalcogenides (II) gives the bis(silylmethyl) chalcogenides (III), together with the oxachalcogenadisilacyclohexanes (IVa) and (IVb).
ChemInform Abstract: Reactions of 1‐Isopropoxy‐2‐bis(trimethylsilyl)amino‐3‐trimethylsilyl‐4,4,4‐tris(isopropoxy)‐1,3,2,4‐oxazaphosphatitanetidine with Sulfur and Selenium.
Authors: BRUSILOVETS A. I. 
Published: May 2016

AbstractReaction of the titanium chelate (I) with the chalcogenes (II) gives the heterocycles (III).
ChemInform Abstract: Synthesis and Characterization of the Mixed‐Valent Complex Ion Di‐μ‐oxobis(1,4,8,11‐tetraazacyclotetradecane)dimanganese(III,IV), ((cyclam)MnO)3+ 2.
Authors: GOODSON P. A. , HODGSON D. J. , MICHELSEN K. 
Published: May 2016

AbstractThe use of an external oxidant is not necessary for the formation of the title III/IV dimer cation as demonstrated in the synthesis of the bromide salt (V) ( P21/n, Z=2).
ChemInform Abstract: Synthesis and Structural Studies of Some New Rhenium Phosphine Heptahydride Complexes. Evidence for Classical Structures in Solution.
Authors: LUO X.‐L. , CRABTREE R. H. 
Published: May 2016

AbstractA series of new complexes (IV) are synthesized and characterized by IR and 1H, 31P and 13C NMR spectroscopy.
ChemInform Abstract: Synthesis and Crystal Structure of a Stable Hexacobalt Complex of Cyclo(18)carbon.
Authors: RUBIN Y. , KNOBLER C. B. , DIEDERICH F. 
Published: May 2016

AbstractStarting with the pyrolysis product (II) from (I) the diphosphine‐bridged dicobalt complex (V) (space group P21, Z=2) is synthesized as shown.
ChemInform Abstract: Tetranuclear Complexes of 1,3,5,9,11,13‐Hexaketonates. Part 1. Synthesis and Structure of Bis(1,3‐bis(2‐methyl‐4,6,8‐octanetrion‐8‐yl)benzenato(4‐))tetrakis(pyridine)tetracopper(II), Cu4(MOB)2(py)4. Observation of Four‐Electron‐Transfer Electrochemistry.
Authors: LINTVEDT R. L. , ZEHETMAIR J. K. 
Published: May 2016

AbstractA new hexaketone ligand (I), prepared by condensation of 2‐methyl‐4‐pentanone and dimethyl isophthalate in dry THF with NaH, is capable of binding four metal ions.
ChemInform Abstract: Heterocyclic Tellurium Compounds as Ligands; Some Complexes of Rhodium(III) and Rhodium(I).
Authors: AL‐RUBAIE A. Z. , AL‐OBAIDI Y. N. , YOUSIF L. Z. 
Published: May 2016

AbstractEight examples of new Rh(III) complexes such as (I) are prepared by the reaction of RhCl3 with the corresponding heterocyclic tellurium compounds in ethanol.
ChemInform Abstract: Synthesis and Structural Characterization of Metallacarborane Poly(pyrazolyl)borate Complexes.
Authors: SCHUBERT D. M. , KNOBLER C. B. , TROFIMENKO S. , HAWTHORNE M. F. 
Published: May 2016

AbstractThe first examples of mixed‐ligand sandwich complexes containing poly(pyrazolyl)borate and dicarbollide ligands are prepared according to the scheme.
ChemInform Abstract: Thiophene Ring Cyclopalladation of N,N‐Dimethyl‐2(or 3)‐thiophenecarbothioamide.
Authors: MIZUNO H. , NONOYAMA M. 
Published: May 2016

AbstractN,N‐Dimethyl‐2‐thiophenecarbothioamide (I) and its 3‐isomer react with lithium tetrachloropalladate(II) to give the cyclopalladated dimers (III) and (VIII), respectively.
ChemInform Abstract: Efficient Synthetic Routes to Fluorinated Isosteres of Inositol and Their Effects on Cellular Growth.
Authors: KOZIKOWSKI A. P. , FAUQ A. H. , POWIS G. , MELDER D. C. 
Published: May 2016

AbstractAs reported in a previous work, quebrachitol can be transformed in a two‐step sequence to the monofluoro product (I).
ChemInform Abstract: Glycoside and Saccharide Synthesis Using N‐Glycosyltriazoles as Hydrolytically Stable Glycosyl Donors.
Authors: BROEDER W. + , KUNZ H. 
Published: May 2016

AbstractDiels‐Alder reaction of the tetra‐O‐pivaloyl‐β‐D‐glucopyranosyl azide (I) with the dialkyl acetylenedicarboxylates (II) in toluene yields the hydrolytically stable N‐glycosyltriazoles (III) which serve as glycosyl donors.
ChemInform Abstract: The Chemistry of 2′,3′‐Seconucleosides. Part 4. Synthesis and Reactions of 3′‐Azido‐2′,3′‐dideoxy‐2,′,3′‐secothymidine and Related Analogues.
Authors: KUMAR A. , WALKER R. T. 
Published: May 2016

AbstractThe title nucleosides, e.g. (VI), (VIII) and (X), and the corresponding uridines which are synthesized by analogous routes are tested for their ability to prevent infection of cells by HIV.
ChemInform Abstract: Pigments of Fungi. Part 12. Structure and Absolute Stereochemistry of Antibiotic Tetrahydroanthraquinones from the Fungus Dermocybe splendida Horak. X‐Ray Structure Determination of Austrocortirubin Phenylboronate and Austrocortilutein Acetonide.
Authors: GILL M. , SMRDEL A. F. , STRAUCH R. J. , BEGLEY M. J. 
Published: May 2016

AbstractThe principal dark red pigment austrocortirubin (I), the principal yellow pigment (1S,3S)‐austrocortilutein (II) and a minor yellow pigment (1S,3R)‐austrocortilutein (III) represent new components found in the title species and are the first tetrahydroanthraquinones to be found in Basidiomycetes.
ChemInform Abstract: B‐2′‐Isoprenyldiisopinocampheylborane: An Efficient Reagent for the Chiral Isoprenylation of Aldehydes. A Convenient Route to Both Enantiomers of Ipsenol and Ipsdienol.
Authors: BROWN H. C. , RANDAD R. S. 
Published: May 2016

AbstractThe isoprenyl potassium (I) reacts with the chiral borinate (+)‐(II) to give the salt (III) which is demethoxylated, forming the dienylborane (IV).
ChemInform Abstract: 31P, 27Al, and 129Xe NMR Study of Phosphorus‐Impregnated HZSM‐5 Zeolite Catalysts.
Authors: SEO G. , RYOO R. 
Published: May 2016

AbstractHZSM‐5 zeolites with phosphorus contents of 0.4‐7.1% are prepared by the incipient wetness method using aqueous (NH4)2HPO4.
ChemInform Abstract: Sodium Dinitridoborate with the Linear Symmetric Anion BN3‐ 2.
Authors: EVERS J. , MUENSTERKOETTER M. + , OEHLINGER G. , POLBORN K. , SENDLINGER B. 
Published: May 2016

AbstractNa2BN2 is prepared by reaction of Na, NaN3, and BN (2:1:1) in a BN‐crucible at 1000 °C and 4 GPa (Belt‐type apparatus, 15 min).
ChemInform Abstract: The First Barium Oxomercurate: BaHgO2 ‐ Synthesis and Crystal Structure.
Authors: SOLL M. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractSingle crystals of BaHgO2 are prepared by reaction of BaO and HgO in pure, dry O2 at 6000 bar and 700 °C (5 d).
ChemInform Abstract: Study on the Formation of Fe1‐xMnxSi2 from the Sintered FeSi‐Fe2Si5 Eutectic Alloy Doped with Manganese.
Authors: KOJIMA T. , SAKATA M. , NISHIDA I. 
Published: May 2016

AbstractThe sintered eutectic alloy composed of ε‐FeSi and α‐Fe2Si5 and Mn as dopant corresponding to the composition Fe1‐xMnxSi2 with 0 ≤ x ≤ 0.13 is annealed in the range 1073‐1173 K to determine the most effective annealing conditions for the formation of the β‐phase.
ChemInform Abstract: Stabilization of the Open‐Chain Structure of D‐Galacturonic Acid in a Dimeric Complex with Oxovanadium(IV).
Authors: BRANCA M. , MICERA G. , SANNA D. , DESSI A. , KOZLOWSKI H. 
Published: May 2016

AbstractElectronic absorption and ESR spectroscopic investigations establish that the properties of a dimeric oxovanadium complex of D‐galacturonic acid, formed in aqueous solutions, are consistent with a metal‐metal distance of about 5 Å.
ChemInform Abstract: New Catalytic Activity of Polymer‐Supported Quaternary Onium Salts. Regioselective Addition Reaction of Oxiranes with Active Esters Catalyzed by Insoluble Polystyrene‐Bound Quaternary Ammonium and Phosphonium Salts.
Authors: NISHIKUBO T. , IIZAWA T. , SHIMOJO M. , KATO T. , SHIINA A. 
Published: May 2016

AbstractThe chloromethyl‐substituted polystyrene (I) is coupled with trialkylamines and phosphines such as (II) to produce the corresponding polymer‐supported onium salts (III) mentioned in the title.
ChemInform Abstract: Optically Active (Z)‐(R)‐(+)‐Methyl 2‐Phenyl‐2‐(pyrid‐4‐yl)vinyl Sulfoxide: Synthesis and Structure.
Authors: MADESCLAIRE M. , FAUVE A. , METIN J. , CARPY A. 
Published: May 2016

AbstractThe title compound (II) is obtained in high enantiomeric purity by microbiological sulfoxidation of the sulfide (I).
ChemInform Abstract: Manganese(III)‐Based Oxidative Free‐Radical Cyclization of Unsaturated β‐Keto Esters, 1,3‐Diketones, and Malonate Diesters.
Authors: KATES S. A. , DOMBROSKI M. A. , SNIDER B. B. 
Published: May 2016

AbstractThe unsaturated β‐keto ester (I) undergoes oxidatively induced ring closure by reaction with Mn(OAc)3 (II) to give the radical (IV) via the enolate (III).
ChemInform Abstract: Sulfuric Acid‐Acetic Anhydride Promoted Rearrangement of α,β‐Unsaturated Ketones.
Authors: BANERJEE A. K. , CARRASCO M. C. , PENA M. C. A. 
Published: May 2016

AbstractOn treatment with sulfuric acid in acetic anhydride (II) the α,β‐unsaturated ketones (I), (IV), and (VI) undergo different molecular transformations yielding the products (III), (V), and (VII), respectively.
ChemInform Abstract: Pyridinium Chlorochromate: an Improved Method for Its Synthesis and Use of Anhydrous Acetic Acid as Catalyst for Oxidation Reactions.
Authors: AGARWAL S. , TIWARI H. P. , SHARMA J. P. 
Published: May 2016

AbstractAn improved procedure for the preparation of the title compound (IV) is carried out as shown.
ChemInform Abstract: Kinetics of Silver(I)‐Catalyzed Oxidation of Hydrazinium Ion by the (Ethylenebis(biguanide))silver(III) Cation.
Authors: BANERJEE R. , DAS A. , DASGUPTA S. 
Published: May 2016

AbstractThe title complex (I) is a rare example of a cationic complex of Ag(III) extensively stabilized by an acyclic ligand environment and in acid solution reasonably resistant to autodecomposition.
ChemInform Abstract: Application of the Isoamyl Nitrite‐Diiodomethane Route to Aryl Iodides.
Authors: SMITH W. B. , HO O. C. 
Published: May 2016

AbstractThe anilines (I) and the diaminobiphenyl (III) are converted into the corresponding iodides (II) and (IV) by reaction with diiodomethane in the presence of isoamyl nitrite.
ChemInform Abstract: Diastereoselective Addition of Methylcopper‐ and Dimethylcuprate‐Boron Trifluoride Reagents to (S)‐(N‐Alkylidene)‐1‐phenylethylamines.
Authors: BOGA C. , SAVOIA D. , UMANI‐RONCHI A. 
Published: May 2016

AbstractThe reactions of methylcopper‐ and dimethylcuprate‐boron trifluoride reagents with aldimines such as (I), derived from (S)‐1‐phenylethylamine, yield with good diastereoselectivity the (1S,1'S)‐amines (IIIa) and (IIIb) from aromatic imines.
ChemInform Abstract: Organometallics in Organic Synthesis. Part 32. Selective Carbon‐Carbon Coupling Reactions with Nucleophilic Thermolabile Methylcobalt Reagents.
Authors: KAUFFMANN T. , HOPP G. , LAARMANN B. , STEGEMANN D. , WINGBERMUEHLE D. + 
Published: May 2016

AbstractThe methylcobalt compounds (III) are tested in the methylation of the bromostyrene (I) and various carbonyl compounds such as (II), (VII), or (IX).
ChemInform Abstract: Organometallics in Organic Synthesis. Part 30. Chlorinating Methylation of Aldehyde and Keto Groups with Niobium Reagents and Investigation of the Mechanism.
Authors: KAUFFMANN T. , ABEL T. , NEITELER G. , SCHREER M. 
Published: May 2016

AbstractThe aldehydes and ketones (I) are simultaneously chlorinated and methylated with methylniobium tetrachloride (II) to produce the branched chlorides (III).
ChemInform Abstract: Organometallics in Organic Synthesis. Part 31. Application of Non‐Stabilized Iron(II) Alkyls as Highly Selective Nucleophilic Alkylation Reagents.
Authors: KAUFFMANN T. , LAARMANN B. , MENGES D. , VOSS K.‐U. , WINGBERMUEHLE D. + 
Published: May 2016

AbstractThe methyliron reagents (III) are added to mixtures of the bromostyrene (I) and the ketone (II) to yield predominantly the methylation product (IV) of (I).
ChemInform Abstract: Asymmetric Synthesis of Chiral Amines via Nucleophilic Addition to Ferrocenylalkyl Substituted Imines.
Authors: DAVID D. M. , KANE‐MAGUIRE L. A. P. , PYNE S. G. 
Published: May 2016

AbstractThe isomerically pure imine (III) undergoes nucleophilic attack to give the diastereomeric compounds (V) and (VI) from which the amine (VIII) (yield not given) is released and the chiral ferrocenyl auxiliary is regenerated as the acetate (IX).
ChemInform Abstract: Palladium(0)‐Catalyzed Azidation of Allyl Esters with Trimethylsilyl Azide.
Authors: SAFI M. , FAHRANG R. , SINOU D. 
Published: May 2016

AbstractAllylic esters and chlorides react with trimethylsilyl azide (II) in the presence of palladium catalysts to produce the corresponding allyl azides.
ChemInform Abstract: Reductive Cyclizations of Ketyls of Bicyclo(2.2.2)octanones.
Authors: SPREITZER H. , KALCHHAUSER H. 
Published: May 2016

AbstractGeneration of ketyls from ketones (I) using Li/THF leads to cyclization by C‐C bond formation with the terminal methylene group to give (III) as already reported.
ChemInform Abstract: Synthesis and Biological Activity of Some 1‐Hydroxy‐3‐aminoalkyladamantanes and Their Derivatives.
Authors: LAVROVA L. N. , INDULEN M. K. , RYAZANTSEVA G. M. , KORYTNYI V. S. , YASHUNSKII V. G. 
Published: May 2016

AbstractThe adamantylalkylamine hydrochlorides (I) are oxidized to give the hydroxyadamantyl derivatives (II) which are converted to the thiosulfates (VI) via the chloroacetamidines (IV).
ChemInform Abstract: A Method for Easy Preparation of Optically Pure (S)‐5‐Hydroxy‐2‐penten‐4‐olide and (S)‐5‐Hydroxypentan‐4‐olide.
Authors: KOSEKI K. , EBATA T. , KAWAKAMI H. , MATSUSHITA H. , NAOI Y. , ITOH K. 
Published: May 2016

AbstractOxidation of levoglucosenone (I) with m‐chloroperbenzoic acid in dichloromethane yields a mixture of the formyloxymethylbutenolide (II) and the carbonate (III).
ChemInform Abstract: Studies in Spiroheterocycles. Part 28. Investigation of the Reaction of 3‐Aroylmethyleneindolin‐2‐ones with Thiosemicarbazide and Synthesis of Spiro(3H‐indole‐3,4′‐(3′H)‐pyrimidin)‐2(1H)‐ones.
Authors: JOSHI K. C. , JAIN R. , SHARMA K. 
Published: May 2016

AbstractN‐Methylindoline‐2,3‐dione (I) and the acetophenone (II) undergo addition reaction in the presence of a base to produce the 3‐hydroxyindolin‐2‐one (III) which is dehydrated upon treatment with conc.
ChemInform Abstract: 2H‐Benzimidazoles. Part 5. Convenient Synthons for Tricyclic Heterocycles.
Authors: CADA A. , KRAMER W. , NEIDLEIN R. , SUSCHITZKY H. 
Published: May 2016

AbstractThe readily available spiro compound (I) or its phenylthio derivative (IX) are converted to the heterocycles (VI), (VIII), (XII), (XIII) and (XVI).
ChemInform Abstract: One‐Pot Preparation of γ‐Butyrolactone Derivatives from Olefinic Alcohols via Intramolecular Radical Cyclization Reaction.
Authors: TOGO H. , YOKOYAMA M. 
Published: May 2016

AbstractSubsequent reaction of 1‐octanol (I) with oxalyl chloride (II) and N‐hydroxy‐2‐thiopyridone (III) yields the thiocarbonate (IV) as the main product.
ChemInform Abstract: Reaction of 3‐Amino‐2H‐azirines with 2‐Amino‐4,6‐dinitrophenol (Picramic Acid): Synthesis of Quinazoline‐ and 1,3‐Benzoxazole Derivatives.
Authors: VILLALGORDO J. M. , VINCENT B. R. , HEIMGARTNER H. 
Published: May 2016

AbstractThe title reaction of the compounds (I) and (II) gives the products (III)‐(VI).
ChemInform Abstract: A New Synthesis of Thiophosphoric Acid Esters with a C‐S‐P Bond.
Authors: MUELLER C. E. + , ROTH H. J. 
Published: May 2016

AbstractThe N‐sulfenylsuccinimides (II) or the corresponding phthalimides (V) react with the phosphites (I) or (VII) to form the thiolophosphates (III) or (VIII).
ChemInform Abstract: 1,1,2,2,9,9,10,10‐Octamethyl‐1,2,9,10‐tetragerma(2.2)paracyclophane: The First (2.2)Paracyclophane Bridged by Two Ge‐Ge Bonds.
Authors: SEKIGUCHI A. , YATABE T. , KABUTO C. , SAKURAI H. 
Published: May 2016

AbstractThe title compound (II) is obtained by reductive coupling of (I) with molten sodium.
ChemInform Abstract: Synthesis of New Ferrocenyl Amine Sulfide and Selenide Complexes of Group 10 Metals and Their Catalytic Activities Toward Selective Hydrogenation, Isomerization, and Asymmetric Grignard Cross‐Coupling Reactions.
Authors: NAIINI A. A. , LAI C.‐K. , WARD D. L. , BRUBAKER C. H. JUN. 
Published: May 2016

AbstractTwo series of previously unknown ferrocenyl amine sulfide and selenide ligands such as the (S,R)‐amines (III) and the rac. compounds (V) are described.
ChemInform Abstract: Reactions of the Coordinatively Unsaturated μ3‐Alkylidyne Cluster (WFe2(μ3‐CC6H4Me‐4)(μ‐H)(μ‐PPh2)(CO)6(η‐C5H5)) with PMe2Ph.
Authors: JEFFERY J. C. , LAWRENCE‐SMITH J. G. 
Published: May 2016

AbstractTreatment of the coordinatively unsaturated complex (I) with one equiv. of the phosphine (II) affords a mixture of the thermally unstable kinetic derivatives (III) and (IV).
ChemInform Abstract: Conversion of (Vinylketene)tricarbonyliron(0) Complexes to (Vinylketenimine)tricarbonyliron(0) Complexes.
Authors: RICHARDS C. J. , THOMAS S. E. 
Published: May 2016

AbstractThe vinylketeneiron(0) complexes (I) react with the isonitriles (II) in toluene to produce the vinylketenimineiron(0) complexes (III).
ChemInform Abstract: Synthesis, Crystal Structure, Magnetic Properties, and Solution Study of the Complex μ‐Oxalato‐bis(aquo(1,4,7‐triazacyclononane)nickel(II)) Nitrate Dihydrate.
Authors: BENCINI A. , BIANCHI A. , PAOLI P. , GARCIA‐ESPANA E. , JULVE M. , MARCELINO V. 
Published: May 2016

AbstractThe title complex (IV) crystallizes in P21/c with Z=2.
ChemInform Abstract: Synthesis, Structure, and Dynamic Behavior of (p‐Quinone)copper(I) Complexes. Crystal Structure Determination of a Copper p‐Benzoquinone Complex Stabilized by a Tridentate Oxygen Ligand.
Authors: LENDERS B. , KLAEUI W. + , IRMLER M. , MEYER G. 
Published: May 2016

AbstractThe quinone‐Cu(I) complexes (IV) synthesized according to the scheme can also be obtained from the CO analogue by CO substitution by the quinones.
ChemInform Abstract: Copper(II)‐Promoted Oxidation of Mercaptocarboxylic Acids. The Characterization of Disulfide‐ and Oxalate‐Containing Products. Crystal Structures of ((Cu(bipy)(2,2′‐dtdp))n)·3nH2O and ((Cu(bipy)(3,3′‐dtdp))n)·2nH2O (bipy: 2,2′‐Bipyridine, dtdp: Dithiodipropanoate).
Authors: BRADER M. L. , AINSCOUGH E. W. , BAKER E. N. , BRODIE A. M. , LEWANDOSKI D. A. 
Published: May 2016

AbstractThe infinite chain polymer (IV) crystallizes in P1 with Z=2.
ChemInform Abstract: Formation in Solution, Synthesis, Crystal Structure, and Magnetic Properties of μ‐Hydroxo‐μ‐perchlorato‐bis((diethylenetriamine)perchloratocopper(II)).
Authors: CASTRO I. , FAUS J. , JULVE M. , LLORET F. , VERDAGUER M. , KAHN O. , JEANNIN S. , JEANNIN Y. , VAISSERMANN J. 
Published: May 2016

AbstractThe title complex (III) crystallizes in P21 with Z=2.
ChemInform Abstract: Synthesis, X‐Ray Crystal Structure, and Reactivity of the Binuclear Copper(I) Complex ((Cu(3,5Me2‐pz)(CNR))2) (R: cyclohexyl, 3,5Me2‐pz: 3,5‐dimethylpyrazolate) Toward RNCO (R: cyclohexyl), PhNCS, COS, and CS2. N,S Coordination of the 3,5‐Dimethylpyrazolecarbodithioate Anion in Cyclic (Cu(3,5Me2‐pz‐C(S)‐S)(CNR)2).
Authors: ARDIZZOIA G. A. , ANGARONI M. A. , LA MONICA G. , MASCIOCCHI N. , MORET M. 
Published: May 2016

AbstractThe structure of the title complex (I) (space group C2/m, Z=2) which is prepared by reaction of polymeric 3,5‐dimethylpyrazolato‐Cu(I) with cyclohexyl isocyanide in 94% yield is determined by X‐ray analysis.