bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: New Entry to γ,δ‐Unsaturated Seven‐Membered Lactones.
Authors: KIDO F. , KAZI A. B. , YOSHIKOSHI A. 
Published: May 2016

Abstractγ,δ‐Unsaturated 7‐membered lactones such as (VI) or (IX) are obtained via (2,3)sigmatropic rearrangement of cyclic allylsulfonium ylides which are formed in situ from the corresponding diazomalonates, e.g. (V), in the presence of rhodium(II) acetate as the catalyst.
ChemInform Abstract: Synthesis and Structural Characterization of New Boron‐Substituted Monocarbon Carborane Adducts: nido‐8‐L‐7‐CB10H12 (L: SMe2, PPh3).
Authors: QUINTANA W. , SNEDDON L. G. 
Published: May 2016

AbstractA formation mechanism for the nido‐carborane compound (III) is suggested.
ChemInform Abstract: Synthesis of 1,1,3,3‐Tetramethyl‐1,3‐disilacyclobutanes Using Lithium Metal or Organolithium Reagents.
Authors: CHMIELECKA J. , STANCZYK W. 
Published: May 2016

AbstractTreatment of (bromomethyl)chlorodimethylsilane (I) with butyllithium, methyllithium, or lithium metal results in cyclization to yield the tetramethyldisilacyclobutane (II).
ChemInform Abstract: Insertion of RPS2 into the PN‐Bond of Aminophosphines.
Authors: DIEMERT K. , HEIN G. , JANSSEN A. , KUCHEN W. 
Published: May 2016

AbstractDepending on the molar ratio, the diamines (I) form with dithiodiphosphetanes, e.g. (II), monoinsertion products (III) or diinsertion products (IV).
ChemInform Abstract: O,O‐Dialkyl (N,N′‐Diphenylformamidinyl)‐ and O‐Alkyl (N,N′‐Diphenylformamidinio)phosphonates.
Authors: KAMALOV P. M. , MAKAROV G. M. , ISLAMOV R. G. , PUDOVIK M. A. , CHERKASOV R. A. , PUDOVIK A. N. 
Published: May 2016

AbstractDiphenylcarbodiimide (I) reacts with the trimethylsilyl dialkyl phosphites (II) to form the adducts (III) which are desilylated in the presence of the corresponding alkanols (IV) to give the phosphonates (V).
ChemInform Abstract: Reaction of Diaza‐18‐crown‐6 with Dialkyl Chloro(thio)phosphates and Dithio Phosphorus Acids.
Authors: ZABIROV N. G. , SHCHERBAKOVA V. A. , CHERKASOV R. A. 
Published: May 2016

AbstractThe diaza crown ether (I) is coupled with the chloro(thio)phosphates (II) to give the N,N'‐diphosphorylated derivatives (III).
ChemInform Abstract: Synthesis of 1,2‐Oxaphospholane Oxides by Oxygen Insertion into the C‐P Bond of Phosphetane Oxides.
Authors: SZEWCZYK J. , YAO E.‐Y. , QUIN L. D. 
Published: May 2016

AbstractFor the pentamethyl‐substituted oxides only one site of attack is possible and the reaction is assumed to proceed with retention, whereas in the case of the trimethyl derivatives (Ia), (Ib) and (Ic) the regioisomers (II) and (III) are formed.
ChemInform Abstract: Tertiary Arsines: A New Synthesis Route and an NMR Study.
Authors: SRIVASTAVA D. K. , KRANNICH L. K. , WATKINS C. L. 
Published: May 2016

AbstractA series of highly pure tert. arsines are conveniently prepared in high yield from the reactions of the chlorodioxarsolane (I) with organo‐Mg, ‐Zn, ‐Al, or ‐Li reagents as demonstrated for the examples (III), (V), and (VII).
ChemInform Abstract: Synthesis and Reactions of 10‐Chloro‐10,9‐(epoxyalkano)selenoxanthenes and 1‐Chloro‐1‐phenyl‐3H‐2,1‐benzoxaselenoles.
Authors: KATAOKA T. , SHIMIZU H. , TOMIMATSU K. , TANAKA K. , HORI M. , KIDO M. 
Published: May 2016

AbstractThe bridged Se‐chloroselenoxanthenes (II) or the benzoxaselenoles (IV) are obtained by NCS‐mediated ring closure of the hydroxyalkyl precursors (I) and (III) respectively.
ChemInform Abstract: Cleavage of a Phosphorus‐Carbon Double Bond and Formation of a Linear Terminal Phosphinidene Complex.
Authors: COWLEY A. H. , PELLERIN B. , ATWOOD J. L. , BOTT S. G. 
Published: May 2016

AbstractTreating the phosphaketene (II) with the W complex (I) leads to the cleavage of the P=C bond in (II) and to the formation of the diamagnetic (phosphinidene)carbonyl complex (III) (space group P21/n, Z=4).
ChemInform Abstract: Synthesis, Characterisation, and Some Properties of Molecular Mixed‐Ligand Peroxo Complexes of Uranium(VI) Containing Amines or Aminocarboxylic Acids as Coligands.
Authors: BHATTACHARJEE M. , CHAUDHURI M. K. , PURKAYASTHA R. N. D. 
Published: May 2016

AbstractIn order to get the diamagnetic complexes (III), it is necessary that the addition of H2O2 follows that of the co‐ligand because otherwise unsoluble UO2(O2) is obtained.
ChemInform Abstract: A Novel Oxygen‐Carrying and Activating System of Rhodium(III). Oxidation and Oxygenation Reactions of 3,5‐Di‐tert.‐butylcatechol Catalyzed by a Rhodium(III) Catecholate Through Its (η1‐Superoxo) (η2‐semiquinonato)rhodium(III) Complex.
Authors: BIANCHINI C. , FREDIANI P. , LASCHI F. , MELI A. , VIZZA F. , ZANELLO P. 
Published: May 2016

AbstractThe coordinatively unsaturated Rh(III) catecholate complex (III) undergoes electron‐transfer reactions involving the oxidation states (I)‐(III) for the metal and the catecholate, semiquinone and quinone oxidation levels of the quinoid ligands.
ChemInform Abstract: The Oxidative Dimerization of Arylamido Complexes of Platinum Revisited: Protonation/Deprotonation or Oxidation/Reduction?
Authors: ESPINET P. , GARCIA‐HERBOSA G. , RAMOS J. M. 
Published: May 2016

AbstractA study of the products of oxidative dimerization of complexes such as (I) using cyclic voltammetry and rotating‐electrode techniques demonstrates that the first compound isolated is (II) rather than a product with an additional unlocalized hydrogen atom.
ChemInform Abstract: O‐1‐(1,3‐Butadienyl) Carbamates as Diels‐Alder Dienes: Stereospecific Synthesis of (.+‐.)‐Hernandulcin and Congeners.
Authors: DE CUSATI P. F. , OLOFSON R. A. 
Published: May 2016

AbstractThe butadienyl carbonate (Ia) and the corresponding carbamate (Ib) are submitted to Diels‐Alder reaction to give the cyclohexene derivatives (IIIa) and (IIIb) respectively, together with small amounts of the Michael elimination products (IV).
ChemInform Abstract: Preparation of Steroid Hydroxy Sulfates.
Authors: ARNOSTOVA L. M. , POUZAR V. , DRASAR P. 
Published: May 2016

AbstractThe steroidal diol monoacetates (I) and (VI) are sulfated with the sulfur trioxide pyridine complex (II) and then deprotected with sodium hydroxide (IV) to yield the sodium hydroxy sulfates (V) and (VII) respectively via the corresponding pyridinium salts, e.g. (III).
ChemInform Abstract: Syntheses and Antifungal Activities of dl‐Griseofulvin and Its Congeners. Part 1.
Authors: TOMOZANE H. , TAKEUCHI Y. , CHOSHI T. , KISHIDA S. , YAMATO M. 
Published: May 2016

AbstractAldol condensation of the benzofuranone (I) with the acetals (II) yields the Z‐alkylidenebenzofuranones (III).
ChemInform Abstract: Stabilization of Orthorhombic Ba2YCu3O7‐δ Phase by the 5a Group Transition Metal Elements.
Authors: BRNICEVIC N. , TUSEK‐BOZIC LJ. , PLANINIC P. , POPOVIC S. , RAKVIN B. , POZEK M. , DULCIC A. , LEISING G. , AICHHOLZER K. D. , SCHWEIGER E. , WIPPEL V. 
Published: May 2016

AbstractThe effects of the partial substitution of Cu by V, Nb, and Ta on the structural, superconducting, magnetic, and mechanical properties of the orthorhombic phase YBa2Cu3O7‐δ are studied.
ChemInform Abstract: The Co‐Sb Phase Diagram and Some Properties of NiAs‐Type Co1.+‐.xSb.
Authors: HANNINGER G. , IPSER H. , TERZIEFF P. , KOMAREK K. L. 
Published: May 2016

AbstractThe Co‐Sb phase diagram is presented for the composition range 20‐85 at.% Sb.
ChemInform Abstract: The Effect of the Partial Replacement of Lanthanum in LaNi5‐H with Cerium, Praseodymium, and Neodymium on Absorption and Desorption Kinetics.
Authors: CLAY K. R. , GOUDY A. J. , SCHWEIBENZ R. G. , ZARYNOW A. 
Published: May 2016

AbstractA series of La0.8Ln0.2Ni5 hydrides (Ln: Ce, Pr, Nd) are prepared and their H2 absorption and desorption kinetics are studied.
ChemInform Abstract: Synthesis, Crystal Structure and Magnetic Properties of Tm8S11.
Authors: ZHANG Y. , FRANZEN H. F. , HARBRECHT B. 
Published: May 2016

AbstractThe title compound is prepared by annealing a stoichiometric mixture of the elements (700 °C, 14 d; 1320 °C, 2 d; 750 °C, 7 d).
ChemInform Abstract: The Electrochemical Fluorination of Nitrogen‐Containing Carboxylic Acids. Fluorination of Dimethylamino‐ or Diethylamino‐Substituted Carboxylic Acid Derivatives.
Authors: ABE T. , HAYASHI E. , BABA H. , FUKAYA H. 
Published: May 2016

AbstractThe electrochemical fluorination (aniodic current density 3.5 A/dm2, cell voltage 5.8 V) of the title compounds such as (I), (V), or (X) gives a variety of highly fluorinated products as shown in the reaction scheme.
ChemInform Abstract: A Convenient Chemoenzymatic Synthesis of (R)‐ and (S)‐(Chloromethyl)oxirane.
Authors: CHEN C.‐S. , LIU Y.‐C. , MARSELLA M. 
Published: May 2016

AbstractThree methods of enzymatic preparation of (R)‐ and (S)‐1‐chloro‐3‐tosyloxypropan‐2‐ol (II), the precursor of the title compound, are described.
ChemInform Abstract: Highly Stereoselective Radical Addition to a Trisubstituted Alkene by Low Temperature Photolysis of Thiohydroxamic Esters.
Authors: SCOTT D. M. , MCPHAIL A. T. , PORTER N. A. 
Published: May 2016

AbstractThe α,β‐unsaturated chiral amide (VIII), prepared as shown in the reaction scheme, is alkylated with the organomercury halides (IX) to give predominantly the (S,S,S)‐diastereomers (X).
ChemInform Abstract: Kinetic Resolution of Racemic β‐Hydroxy Amines by Enantioselective N‐Oxide Formation.
Authors: HAYASHI M. , OKAMURA F. , TOBA T. , OGUNI N. , SHARPLESS K. B. 
Published: May 2016

AbstractThe racemic β‐hydroxy amines (I) are separated via kinetically controlled asymmetric oxidation to form the N‐oxides (III).
ChemInform Abstract: Stereospecific Insertion of a Carbene Ligand of a Fischer‐Carbene Complex in the Olefinic C‐H Bonds.
Authors: WIENAND A. , REISSIG H.‐U. 
Published: May 2016

AbstractThe product distribution shows that the insertion reaction is stereospecific with >90% inversion of the olefin configuration, whereas the cyclopropane formation is not stereospecific.
ChemInform Abstract: X=Y‐ZH Compounds as Potential 1,3‐Dipoles. Part 29. The Iminium Ion Route to Azomethine Ylides. Reaction of Cyclic Secondary Amines with Mono‐ and Bifunctional Aldehydes.
Authors: ARDILL H. , FONTAINE X. L. R. , GRIGG R. , HENDERSON D. , MONTGOMERY J. , SRIDHARAN V. , SURENDRAKUMAR S. 
Published: May 2016

AbstractThe tetrahydro‐β‐carboline (I) and the tetrahydroquinoline (VI) react with a range of aldehydes such as (II), (VII), (IX) and (XI) to form azomethine ylides.
ChemInform Abstract: Synthesis of Useful Intermediates from the Claisen Rearrangement of α‐Hydroxy Alkyl Acrylate Precursors.
Authors: DREWES S. E. , EMSLIE N. D. , KARODIA N. , LOIZOU G. 
Published: May 2016

AbstractThe phenyloxymethylbutenoate (III) undergoes acid‐induced rearrangement, forming the methylenebenzopyranone (IV).
ChemInform Abstract: Synthesis of the Carbapenam Ring System via Carbene‐Mediated Rearrangement of an N‐Benzyloxy‐β‐lactam.
Authors: WILLIAMS M. A. , MILLER M. J. 
Published: May 2016

AbstractThe α‐diazocarboxylic acid ester (I) undergoes rearrangement and ring closure to form the carbapenam (III) on treatment with a rhodium acetate catalyst.
ChemInform Abstract: Heterocyclic o‐Xylylenes: Thiazole, Oxazole, and Imidazole Analogues.
Authors: CHAUHAN P. M. S. , CREW A. P. A. , JENKINS G. , STORR R. C. , WALKER S. M. , YELLAND M. 
Published: May 2016

AbstractThe azolylmethyl p‐chlorobenzoates (V), synthesized from the (thio)amides (I) as outlined in the reaction scheme, are submitted to flash vacuum pyrolysis, forming the heterocyclic o‐xylylene‐like intermediates (VI) which are trapped in situ by co‐condensation with thiophenol (VII) or sulfur dioxide (XII) to yield the regioisomeric thiazoles (VIII) and (IX), the oxazoles (X) and (XI), or the sulfolene‐fused oxazole (XIII).
ChemInform Abstract: Hydroxylation of Saturated Hydrocarbons by Magnesium Monoperoxyphthalate Catalyzed by Manganese Porphyrins.
Authors: QUERCI C. , RICCI M. 
Published: May 2016

AbstractThe title reaction is applied to adamantane (I) under various conditions all leading to the predominant formation of 1‐adamantanol (II), together with 2‐adamantanol (III) and the ketone (IV).
ChemInform Abstract: Connections to the Directed ortho‐Metalation Strategy. Pd(0)‐Catalyzed Cross Coupling of Aryl Boronic Acids with Aryl Triflates.
Authors: FU J.‐M. , SNIECKUS V. 
Published: May 2016

AbstractThe haloaryl triflates (I) and (VI) are treated with phenylboronic acid (II) in the presence of a palladium catalyst to yield the phenylation products (III) ‐ (V) or (VII) and (VIII).
ChemInform Abstract: Synthesis and Mesomorphic Properties of p‐(p′‐n‐Alkoxycinnamoyloxy)benzylidene‐p′′‐halogen‐Substituted Aniline.
Authors: RAJPUT S. , AGRAWAL Y. K. 
Published: May 2016

AbstractThe title compounds, e.g. (V), are synthesized from the corresponding benzaldehydes (I) via the acid chlorides (II) and reaction with 4‐fluoroaniline (IV) as shown in the reaction scheme.
ChemInform Abstract: Synthetic Studies on Optically Active β‐Lactams. Part 2. Asymmetric Synthesis of β‐Lactams by (2 + 2)Cyclocondensation Using Heterocyclic Compounds Derived from L‐(+)‐Tartaric Acid, (S)‐ or (R)‐Glutamic Acid, and (S)‐Serine as Chiral Auxiliaries.
Authors: IKOTA N. 
Published: May 2016

AbstractThe key step in the synthesis of various optically active β‐lactams is the stereoselective (2 + 2)cycloaddition reaction between the ketenes, derived from the chiral pyrrolidineacetic acids (I), and benzalaniline (II), yielding the azetidinones (III).
ChemInform Abstract: A New Synthesis of 4,5,6,7‐Tetrahydrofuro(2,3‐c)pyridines and Furo(2,3‐c)pyrrolidines
Authors: ARNOLDI A. , BREGANTE G. , CALDIROLA P. , MERLINI L. , TAMBURINI B. 
Published: May 2016

Abstract(i.e.
ChemInform Abstract: Oxidation of α‐Benzoyl‐o‐hydroxyacetophenones Using Iodobenzene Diacetate in Methanolic Potassium Hydroxide: A New Synthesis of 2‐Benzoylcoumaran‐3‐ones.
Authors: PRAKASH O. , GOYAL S. , PAHUJA S. , SINGH S. P. 
Published: May 2016

AbstractThe 1‐(o‐hydroxyphenyl)‐1,3‐propanediones (I) undergo oxidative cyclization upon treatment with iodosylbenzene diacetate to form the hydroxybenzofurans (II).
ChemInform Abstract: N‐Hydroxypyridine‐2‐thione Carbamates. Part 7. Intermolecular Addition and Addition‐Cyclization Reactions of Aminium Cation Radicals.
Authors: NEWCOMB M. , KUMAR M. U. 
Published: May 2016

AbstractThe secondary amines (I) react with the fused pyridinium salt (II) to give the N‐hydroxypyridinethione carbamates (III).
ChemInform Abstract: A Facile Synthesis of 4‐Arylidene‐2‐oxazolin‐5‐ones by Using N,N‐Dimethylchlorosulfite Methaniminium Chloride as a Cyclodehydrating Agent.
Authors: SAIN B. , SINGH S. P. , SANDHU J. S. 
Published: May 2016

AbstractThe iminium salt (II), prepared by reaction of DMF with thionyl chloride, is coupled with N‐acylamino acids such as (I) to give the oxazolines (IV) via the intermediates (III).
ChemInform Abstract: Synthesis of 5‐(5‐R‐2‐Furyl)thiazole Derivatives by Reaction of 2‐(5‐R‐Furfuryl)thiuronium Salts with Acetic Anhydride.
Authors: USOVA E. B. , KRAPIVIN G. D. , KUL'NEVICH V. G. 
Published: May 2016

AbstractThe halomethylfurans (I) react with thiourea (II) to give the thiuronium salts (III).
ChemInform Abstract: Optically Active Dihydropyrans and 3‐Methylenetetrahydrofurans from Cyclopropenylethanol Derivatives.
Authors: AL‐DULAYYMI J. R. , BAIRD M. S. 
Published: May 2016

AbstractThe reaction of a number of cyclopropenylethanol derivatives such as (I) or (IV) with bromine, silver ion or acid leads to ring expansion to give either methylenetetrahydrofurans such as (II) and (III) or dihydropyrans such as (V).
ChemInform Abstract: Rhodium Carbenoid Mediated Cyclizations. Part 6. Synthesis of Cyclic Sulfoxonium Ylides.
Authors: MOODY C. J. , TAYLOR R. J. 
Published: May 2016

AbstractThe title ylides (III) are high‐melting, polar, and crystalline solids which, with the exception of (IIIa), decompose slowly in refluxing mesitylene.
ChemInform Abstract: Vinylogous and Coupled Hexahydroquinolinones and Dihydropyridines with Calcium‐Modulating Effects.
Authors: ROSE U. 
Published: May 2016

AbstractThe cyclohexanediones (I) react with the cinnamic aldehydes (II) and methyl aminocrotonate (III) to give the hexahydroquinolinones (IV).
ChemInform Abstract: Synthesis of 4′‐Nitrophenyl 2‐Aminobenzothiazol‐6‐yl Sulfides and 4′‐Nitrophenyl 2‐Aminobenzothiazol‐6‐yl Sulfones Containing Dithiocarbamate.
Authors: KANDEEL M. M. 
Published: May 2016

AbstractConsecutive treatment of 2‐amino‐6‐((p‐nitrophenyl)thio)benzothiazole (I) with carbon disulfide (II) and one equivalent of methyl iodide (III) produces the methyl dithiocarbamate (IV) which gives the benzothiazolyldihydrothioxoquinoxalinone (VI) upon cyclocondensation with anthranilic acid (V).
ChemInform Abstract: Synthetic Reactions and Structural Studies of Heterocycles Containing Nitrogen. Part 6. Heterocycles from Carbohydrate Precursors. Structure of the Reaction Products from Dehydroascorbic Acid Analogues, o‐Phenylenediamine, and Arylhydrazines. X‐Ray Molecular Structure of 3‐(L‐threo‐2,3,4‐Triacetoxy‐1‐(phenylhydrazono)butyl)quinoxalin‐2(1H)‐one Hemihydrate.
Authors: AMER A. , EL MASSRY A. M. , AWAD L. , RASHED N. , EL ASHRY E. S. H. , HO D. M. 
Published: May 2016

AbstractAcetylation of (I) gives (III) (space group P21 with Z=4).
ChemInform Abstract: New Symmetrical and Unsymmetrical Tetrathiafulvalene π‐Donors Containing the Dithiinoquinoxaline Ring System.
Authors: VARMA K. S. , EDGE S. , UNDERHILL A. E. , BECHER J. , BOJESEN G. 
Published: May 2016

AbstractThe formation of the unsym. title compounds (VI) and (VIII) is accompanied by the formation of symmetric condensation products, viz.
ChemInform Abstract: Reissert‐Type Reaction of N‐Sulfonyl‐ or N‐Acylphthalazinium Salts with Trimethyl Phosphite and Crystal Structure of Dimethyl 2‐Mesyl‐1,2‐dihydro‐1‐phthalazinylphosphonate.
Authors: TAKEUCHI I. , HAMADA Y. , HATANO K. , KURONO Y. , YASHIRO T. 
Published: May 2016

AbstractThe phthalazinium salts mentioned in the title are obtained as intermediates by treatment of phthalazine (I) with the acyl (II) or sulfonyl chlorides (V) and trimethyl phosphite (III).
ChemInform Abstract: tert‐Butylarsolane and ‐arsenane: Synthesis and Mass Spectrometry.
Authors: PASTERCZYK J. W. , BARRON A. R. 
Published: May 2016

AbstractReaction of the bis‐Grignard compounds (I) with tert‐butylarsonous dichloride (II) produces the tert‐butylarsolanes and ‐arsenanes (III), together with the halides (IV) and (V) as by‐products.
ChemInform Abstract: Synthesis of Mixed Oligomeric Heteroarylenes Containing Unsubstituted Furan, Thiophene, and Selenophene Rings. Their UV Spectra and Oxidation Potentials.
Authors: SHABANA R. , GALAL A. , MARK H. B. JUN. , ZIMMER H. , GRONOWITZ S. , HOERNFELDT A.‐B. + 
Published: May 2016

AbstractThe Grignard compound (III), obtained from furan (I) with BuLi and MgBr2 etherate (II), is coupled with 2‐bromoselenophene (IV) in the presence of a nickel(II) complex.
ChemInform Abstract: Aldol Condensation of Ketones Promoted by Sterically Crowded Aryloxide Compounds of Aluminum.
Authors: POWER M. B. , APBLETT A. W. , BOTT S. G. , ATWOOD J. L. , BARRON A. R. 
Published: May 2016

AbstractThe mixture (III)/(IV) crystallizes in P21 with Z=2.
ChemInform Abstract: A Stepwise Formation of η4‐Coordinated (s‐cis)‐1‐Molybda‐2‐phospha‐1,3‐diene Complexes.
Authors: LANG H. , LEISE M. , ZSOLNAI L. , FRITZ M. 
Published: May 2016

AbstractThe stepwise formation of the η4‐coordinated Fe complexes (IV) ((IVa): space group P1, Z=2) from (I) and its analogue (V) and Fe2(CO)9 (II) is confirmed by the isolation of the intermediate (III).
ChemInform Abstract: Synthesis, Structure and Catalase‐Like Action of a Novel Oxo‐Bridged Tetranuclear Manganese Complex with Short Oxygen‐Oxygen Distance.
Authors: STIBRANY R. T. , GORUN S. M. 
Published: May 2016

AbstractAs a model compound for the release of O2 in the photosystem II, the mixed‐valent Mn(II)/3 Mn(III) complex (I) with the until now unknown core (Mn4O2H)8+ is prepared by the reaction of the ligand with Mn(OAc)2 in water in the presence of Ba(OH)2 and Ca(OH)2 followed by the addition of H2O2.
ChemInform Abstract: ((Ph3P)2N)2(Os18Hg2C2(CO)42), a Photochemically Generated Multinuclear Cluster, Which Reversibly Inserts Mercury in Its Metal Core.
Authors: CHARALAMBOUS E. , GADE L. H. , JOHNSON B. F. G. , KOTCH T. , LEES A. J. , LEWIS J. , MCPARTLIN M. 
Published: May 2016

AbstractThe formation of the title compound (yield 92%; space group P1, Z=1) by photolysis of the corresponding Hg3‐containing cluster dianion is confirmed by IR, 13C NMR and mass spectroscopy.
ChemInform Abstract: Theoretical and Synthetic Study on the Existence, Structures, and Bonding of the Halide‐Bridged [B2X7]‐ (X: = F, Cl, Br, I) Anions.
Authors: Bertocco Philipp , Bolli Christoph , Correia Bicho Bruno A. , Jenne Carsten , Erken Berrin , Laitinen Risto S. , Seeger Helene A. , Takaluoma Teemu T. 
Published: May 2016

AbstractThe structures of the title anions are calculated at the MP2 level of theory.
ChemInform Abstract: Centrosymmetry vs Noncentrosymmetry in La2Ga0.33SbS5 and Ce4GaSbS9 Based on the Interesting Size Effects of Lanthanides: Syntheses, Crystal Structures, and Optical Properties.
Authors: Zhao Hua‐Jun 
Published: May 2016

AbstractLa2Ga0.33SbS5 (I) and Ce4GaSbS9 (II) are prepared from stoichiometric mixtures of the elements (evacuated silica tubes, 950 °C, 96 h; cooling to 200 °C at a rate of 2.5 °C/h).
ChemInform Abstract: Evidences of the Existence of SiTe2 Crystalline Phase and a Proposed New Si—Te Phase Diagram.
Authors: Mishra R. , Mishra P. K. , Phapale S. , Babu P. D. , Sastry P. U. , Ravikumar G. , Yadav A. K. 
Published: May 2016

AbstractSi—Te alloys with compositions of 50—95 mol% Te are prepared by reaction of the elements in evacuated quartz ampoules (950 °C, 48 h; cooling to 25 °C at a rate of 3 °C/h).
ChemInform Abstract: Crystal Structure, Electronic Structure, and Photocatalytic Activity of Oxysulfides: La2Ta2ZrS2O8, La2Ta2TiS2O8, and La2Nb2TiS2O8.
Authors: Goto Yosuke , Seo Jeongsuk , Kumamoto Kazunori , Hisatomi Takashi , Mizuguchi Yoshikazu , Kamihara Yoichi , Katayama Masao , Minegishi Tsutomu , Domen Kazunari 
Published: May 2016

AbstractThe title compounds are synthesized by solid state reactions using La2O3, La2S3, Ta2O5, ZrO2, Nb2O5, TiS2, and S as starting materials (sealed quartz tubes, 1100 °C, 48 h).
ChemInform Abstract: From Minor Side Phases to Bulk Samples of Lanthanum Oxonitridosilicates: An Investigation with Microfocused Synchrotron Radiation.
Authors: Durach Dajana , Schultz Peter , Oeckler Oliver , Schnick Wolfgang 
Published: May 2016

AbstractMicrometer‐sized crystals of La11Si13N27.636O1.046:Ce 3+ are obtained as a side product from a mixture of La, La(NH2)3, Si(NH)2, BaH2, and CeF3 (tungsten crucible, N2 atmosphere, 1650 °C, 5 h).
ChemInform Abstract: [AgPb2I3(OH)2]: An Unprecedented Quaternary Heterometallic Semiconducting Framework Synthesized under Ionothermal Condition.
Authors: Zhang Li‐Xia , Zhai Quan‐Guo , Li Shu‐Ni , Jiang Yu‐Cheng , Hu Man‐Cheng 
Published: May 2016

AbstractThe title compound is synthesized from a mixture of PbI2, AgCN, KI, H2O, and [emim]I (autoclave, 180 °C, 5 d, 89% yield).
ChemInform Abstract: The Rare Transformation of 2,7‐Diazaspiro[4.4]nonanes in Furo[3,4‐c]pyridines.
Authors: Fedoseev Sergey V. , Ershov Oleg V. , Lipin Konstantin V. , Belikov Mikhail Yu. 
Published: May 2016

AbstractRefluxing spiro compounds (I) in hydrohalic acids in the presence of the appropriate phosphorous halide yields a mixture of two compounds (II) and (III).
ChemInform Abstract: Photoorganocatalyzed and Visible Light Photoredox Catalyzed Trifluoromethylation of Olefins and (Hetero)aromatics in Batch and Continuous Flow.
Authors: Lefebvre Quentin , Hoffmann Norbert , Rueping Magnus 
Published: May 2016

AbstractThis reaction can be also conducted by using a photo‐flow setup which leads to significantly decreased reaction times.
ChemInform Abstract: A Direct Approach to Amines with Remote Stereocentres by Enantioselective CuH‐Catalyzed Reductive Relay Hydroamination.
Authors: Zhu Shaolin , Niljianskul Nootaree , Buchwald Stephen L. 
Published: May 2016

Abstractγ‐Or δ‐chiral amines are synthesized from readily available allylic alcohols, esters, and ethers with high regio‐, chemo‐ and enantioselectivities and excellent functional group tolerance.