bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Reactions of 1,1‐Dimethyl‐4‐Substituted Semicarbazides with Phosgene.
Authors: COOLEY J. H. , EVAIN E. J. , WILLETT R. D. , BLANCHETTE J. T. 
Published: May 2016

AbstractReaction of the semicarbazide (I) with two equivalents of phosgene (II) yields the triazolinone (III).
ChemInform Abstract: A Novel Synthesis of 3‐Bromo‐1,2,4‐oxadiazoles.
Authors: HUMPHREY G. R. , WRIGHT S. H. B. 
Published: May 2016

AbstractThe title compounds (III) and (V) are obtained together with 5‐10% of 3,4‐dibromo‐1,2,5‐oxadiazole 2‐oxide.
ChemInform Abstract: Reaction of Hydrazidoyl Halides with Thiocyanate Anion: Synthesis of Thiadiazolines and Thiadiazolo(4,5‐a)quinazoline.
Authors: IBRAHIM M. K. A. 
Published: May 2016

AbstractThe reaction between the chlorides (I) or (IV) and KSCN (II) gives the title compounds (III) and (V), respectively (yields not given).
ChemInform Abstract: A Very Efficient, Short Synthesis of 6,7,8,8a‐Tetrahydropyrrolo(1,2‐a)pyrimidines from Imines via 4‐Amino‐1‐azabutadienes.
Authors: BARLUENGA J. , TOMAS M. , JARDON J. , RUBIO E. , GOTOR V. 
Published: May 2016

AbstractThe ketimines (III), derived from 4‐aminobutyraldehyde acetal (II), are converted to the title compounds (V) by consecutive metalation, coupling with the nitriles (IV), and acid‐catalyzed cyclization.
ChemInform Abstract: Synthesis of 2‐Substituted 2‐Azapyracridone Derivatives.
Authors: HUBER I. , FUELOEP F. + , BERNATH G. , HERMECZ J. 
Published: May 2016

AbstractCyclocondensation of the piperidiniumcarboxylate (I) with the aminopyridine (II) in polyphosphoric acid yields the 2‐azapyracridone (III).
ChemInform Abstract: Spirocyclization of 1‐(o‐Aminophenyl)cycloalkanols and 1‐(2′‐Amino‐3′‐pyridinyl)cycloalkanols.
Authors: CANONNE P. , BOULANGER R. , CHANTEGREL B. 
Published: May 2016

AbstractThe one‐step spirocyclization of the title compounds (I) opens a route to the benzoxazinones and pyridooxazinones (III), which is more efficient than previously reported routes.
ChemInform Abstract: Chemistry of 1,4‐Oxazines. Part 18. Synthesis of Tricyclic 1,4‐Benzoxazines via Nucleophilic Substitution of Activated Precursors.
Authors: BARTSCH H. , ERKER T. , NEUBAUER G. 
Published: May 2016

AbstractThe activated benzoxazines (I) and (XIII) serve as educts for a series of title compounds.
ChemInform Abstract: Synthesis of 5‐Oxa‐13‐thiaprotoberberine Derivatives.
Authors: SZABO J. , BERNATH G. , SOHAR P. 
Published: May 2016

AbstractThe hydrochloride (I) of 2‐(aminomethyl)‐4,5‐dimethoxythiophenol undergoes ring closure with salicylaldehyde (II) to form the benzothiazine derivative (III).
ChemInform Abstract: Reactions of Protonated 1,3‐Diaza‐4,4‐diphenyl‐2‐(methylthio)butadienes with Isocyanides: Preparation of Imidazole and Triazine Derivatives.
Authors: MOREL G. , MARCHAND E. , FOUCAUD A. , TOUPET L. 
Published: May 2016

AbstractCoupling of diphenylmethylenimine (II) with isothiocyanates such as (I) yields thiourea derivatives such as (III) which is converted to the salt (V) by S‐alkylation.
ChemInform Abstract: Reaction of Chloro(chloromethyl)dimethylsilane and ‐germane with Group 14 Element Nucleophiles.
Authors: INOUE S. , SATO Y. 
Published: May 2016

AbstractIn order to prepare periodic group 14 element‐element bonded compounds such as (I) containing a chloromethyl substituent the reactions of the title compounds with the nucleophiles LiM2RMe2 are investigated under various conditions (table).
ChemInform Abstract: Formation of Thiocarbonyl Compounds in the Reaction of Ebselen Oxide with Thiols.
Authors: GLASS R. S. , FAROOQUI F. , SABAHI M. , EHLER K. W. 
Published: May 2016

AbstractDuring the reaction of ebselen oxide (I) with benzyl sulfide (II), yielding the seleno sulfide (III) and dibenzyl disulfide (IV), a transient blue color of the intermediately formed thiobenzaldehyde is observed.
ChemInform Abstract: A New Barium Tantalum Oxide Fluoride (III).
Authors: AVERDUNK F. , HOPPE R. 
Published: May 2016

AbstractThe title compound (III) crystallizes in the orthorhombic space group CmCm in which Ta has both coordination number eight in the anion (TaF8)3‐ and seven in the anion (TaF6O)3‐.
ChemInform Abstract: Preparation, Solution Dynamics, and X‐Ray Structure of Bis(pentamethylcyclopentadienyl)actinoid Complexes of Chelating Phosphorus Ylides.
Authors: CRAMER R. E. , ROTH S. , EDELMANN F. , BRUCK M. A. , COHN K. C. , GILJE J. W. 
Published: May 2016

AbstractThe reaction of actinoid compounds (I) with (II) produces the thermally stable complexes (III), which contain chelating ylide ligands.
ChemInform Abstract: Synthesis of η6‐Octafluorocyclooctatetraene and η6‐Cyclooctatetraene Complexes of Manganese(I). Molecular Structures of (Mn(η5‐C5R5)(η6‐C8X8)) (R: H, Me, X: F; R: Me, X: H).
Authors: HEMOND R. C. , HUGHES R. P. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe title complexes (III) are prepared as exemplified for (IIIa).
ChemInform Abstract: Ring‐Opening Hydroformylation of α‐Cyclopropylstyrene by HMn(CO)5, and Structure of a Novel Mn2(CO)9(η1‐Aldehyde) Complex.
Authors: BULLOCK R. M. , RAPPOLI B. J. , SAMSEL E. G. , RHEINGOLD A. L. 
Published: May 2016

AbstractReaction of the alkene (I) with HMn(CO)5 (II) produces the η1‐aldehyde complex (III) via ring opening and hydroformylation.
ChemInform Abstract: Synthesis of Hybrid “Metalloporphyrin‐Ellipticine” Molecules.
Authors: ETEMAD‐MOGHADAM G. , DING L. , TADJ F. , MEUNIER B. 
Published: May 2016

AbstractThe porphyrin ligand (Ia) is obtained by coupling of the mixed anhydride formed from an ellipticine derivative (preparation described) and ethyl chloroformate with a metal‐free porphyrin bearing an amino function attached by a methylene chain to the p‐phenoxy ring of a meso‐tetraarylporphyrin.
ChemInform Abstract: Highly Reduced Organometallics. Part 26. Tricarbonyl(phosphine)ferrates(2‐), Fe(CO)3(PR3)2‐, and Their Derivatives.
Authors: ELLIS J. E. , CHEN Y.‐S. 
Published: May 2016

AbstractA two‐step synthesis of (IV) (thermally stable, but air‐sensitive) from the corresponding compounds (I) via the monohydride (IIIa) is developed which may be of general importance for the conversion of other substituted mononuclear carbonyls to the corresponding dinegative anions.
ChemInform Abstract: X‐Ray Structure, Reactivity, and Catalytic Properties of a (Cyclopentadienone)ruthenium Dimer, ((C4Ph4CO)(CO)2Ru)2.
Authors: MAYS M. J. , MORRIS M. J. , RAITHBY P. R. , SHVO Y. , CZARKIE D. 
Published: May 2016

AbstractThe title complex (II) (as well as two isostructural complexes with Me and Ph or p‐chlorophenyl and Ph substituents) is prepared in high yields provided moisture and protic compounds are excluded.
ChemInform Abstract: Stereoselective Intramolecular C‐H Bond Activation in a Dinuclear Iridium Complex.
Authors: HEINEKEY D. M. , MICHEL S. T. , SCHULTE G. K. 
Published: May 2016

AbstractReaction of the complex (I) with diazomethane (II) affords the methylene‐bridged dimer (III) without fragmentation of (I), shown by isotopic double‐labeling experiments.
ChemInform Abstract: Tetra(pentafluorophenyl)porpholactone.
Authors: GOUTERMAN M. , HALL R. J. , KHALIL G.‐E. , MARTIN P. C. , SHANKLAND E. G. , CERNY R. L. 
Published: May 2016

AbstractThe porphyrin (I), under the conditions outlined in the scheme, converts to a new type of porphyrinic species, the porpholactone (II), in which one exo C2H2 unit is tranformed to a CO2 unit.
ChemInform Abstract: A New Route to 1,3‐Dienes Using 3‐Methylene‐2,3‐dihydrothiophene S,S‐Dioxide as an Allyl Sulfone and Michael Acceptor: Synthesis of (.+‐.)‐Ipsenol.
Authors: NOMOTO T. , TAKAYAMA H. 
Published: May 2016

AbstractThe diene (I) reacts with nucleophiles such as (II) to give the adducts (III).
ChemInform Abstract: Syntheses of (1S,2S,3S,4R)‐ and (1R,2R,3S,4R)‐2,3,4‐Trihydroxycyclopentane‐1‐methanol, Carbocyclic Analogues of α‐L‐Arabinofuranose and β‐D‐Ribofuranose.
Authors: TADANO K. , HAKUBA K. , KIMURA H. , OGAWA S. 
Published: May 2016

AbstractStarting with the protected glucofuranose (I), the title compounds pseudo‐α‐L‐arabinofuranose (VIIIb) and pseudo‐β‐D‐ribofuranose (IXb) are synthesized as outlined in the reaction scheme.
ChemInform Abstract: α‐Acylamino Radical Cyclizations: Application to the Synthesis of a Tetracyclic Substructure of Gelsemine.
Authors: CHOI J.‐K. , HA D.‐C. , HART D. J. , LEE C.‐S. , RAMESH S. , WU S. 
Published: May 2016

AbstractTreatment of the radical precursors (I) and (IV) with tributyltin hydride and AIBN results in cyclization, forming the products (II) and (V).
ChemInform Abstract: General Methods for Alkaloid Synthesis via Intramolecular Diels‐Alder Reactions. A Concise Formal Total Synthesis of (.+‐.)‐Dendrobine.
Authors: MARTIN S. F. , LI W. 
Published: May 2016

AbstractIntramolecular Diels‐Alder reaction of the olefinic dienamides (I) forms the cycloadducts (II).
ChemInform Abstract: Gas Phase Water and Hydroxyl Binding Energies for Monopositive First‐Row Transition‐Metal Ions.
Authors: MAGNERA T. F. , DAVID D. E. , MICHL J. 
Published: May 2016

AbstractM+‐OH2 and M+‐OH binding energies of first‐row transition metals are determined by means of collision‐induced dissociation in a triple‐quadrupole mass spectrometer.
ChemInform Abstract: Sequential Solvation of Atomic Transition‐Metal Ions. The Second Solvent Molecule Can Bind More Strongly Than the First.
Authors: MARINELLI P. J. , SQUIRES R. R. 
Published: May 2016

AbstractSequential water and ammonia solvation energies are determined for V+, Cr+, Mn+, Fe+, Co+, and Ni+ by means of collision‐induced dissociation in a triple quadrupole mass spectrometer.
ChemInform Abstract: Disordering and Heat Capacity of Sodium Hexabromouranate(IV).
Authors: GAMBINO M. , GAUNE P. , SZCZEPANIAK W. 
Published: May 2016

AbstractFrom the electrical conductivity, heat capacity, and structural data of Na2UBr6 it is suggested that the disordering processes in the cationic and anionic sublattices are to some degree separated.
ChemInform Abstract: Phase Diagrams of Mixtures of CuI with ZnI2, CdI2 and HgI2.
Authors: BLACHNIK R. , STOETER U. + 
Published: May 2016

AbstractThe systems CuI‐ZnI2, CuI‐CdI2 and CuI‐HgI2, investigated by DTA, DSC, dilatometric and X‐ray measurements, resemble each other very closely.
ChemInform Abstract: Preparation of Large Semiconductor Clusters via the Pyrolysis of a Molecular Precursor.
Authors: BRENNAN J. G. , SIEGRIST T. , CARROLL P. J. , STUCZYNSKI S. M. , BRUS L. E. , STEIGERWALD M. L. 
Published: May 2016

AbstractNanometer‐sized clusters of CdSe (zinc‐blende structure) are prepared by mild pyrolysis of the precursors (III) or (VI).
ChemInform Abstract: Stereochemical Control in Microbial Reduction. Part 9. Diastereoselective Reduction of 2‐Alkyl‐3‐oxobutanoate with Bakers′ Yeast.
Authors: NAKAMURA K. , MIYAI T. , NAGAR A. , OKA S. , OHNO A. 
Published: May 2016

AbstractBakers' yeast reduces esters of 2‐alkyl‐3‐oxobutanoic acid such as (I) to the corresponding hydroxy esters with exclusive (3S)‐stereochemistry.
ChemInform Abstract: Diels‐Alder Reaction of Unactivated 2‐Aza‐1,3‐dienes with Azodienophiles and Tetracyanoethylene. Crystal Structure of 1,2‐Bis(ethoxycarbonyl)‐3‐ethyl‐6‐methyl‐3,5‐diphenyl‐1,2,3,6‐tetrahydro‐1,2,4‐triazine.
Authors: BARLUENGA J. , GONZALEZ F. J. , FUSTERO S. , FOCES‐FOCES C. , HERNANDEZ CANO F. , SAN FELICIANO A. 
Published: May 2016

AbstractWhile azo compounds have been widely used as azodienophiles and azo dienes, their reactivity as dienophiles toward 2‐azadienes is almost unknown.
ChemInform Abstract: Intramolecular Reactions of Compounds Derived from Sugars. Part 2. Stereocontrolled Intramolecular Diels‐Alder Cyclizations of 1,6(E,Z),8‐Nonatrienes and 1‐Aza‐6(E,Z),8‐nonatrienes.
Authors: HERCZEGH P. , ZSELY M. , SZILAGYI L. , BATTA G. , BAJZA I. , BOGNAR R. 
Published: May 2016

AbstractThe Diels‐Alder reaction of the E,Z mixtures of the trienes (VI) and (IX) (yield given in g) leads to the exclusive formation of the bicyclic compounds (VII) and (X), respectively.
ChemInform Abstract: Radical Ions in Photochemistry. Part 21. The Photosensitized (Electron Transfer) Tautomerization of Alkenes; the Phenyl Alkene System.
Authors: ARNOLD D. R. , MINES S. A. 
Published: May 2016

AbstractAlkenes such as (I), (III), or (V), conjugated with a phenyl group, can be converted to nonconjugated tautomers by sensitized (electron transfer) irradiation.
ChemInform Abstract: Sulfonation Reactions of β‐Carbolines.
Authors: CARMONA GUZMAN M. C. , BALON ALMEIDA M. , HIDALGO TOLEDO J. , MUNOZ PEREZ M. A. , LOPEZ POVEDA M. 
Published: May 2016

AbstractKinetics and the different mechanisms of the homogeneous sulfonations of β‐carboline derivatives (I)‐(III) are studied.
ChemInform Abstract: Chemical Differentiation of Bilayer Surfaces in Functional Dialkylammonium Ion Vesicles: Observation of Surfactant Flip‐Flop.
Authors: MOSS R. A. , BHATTACHARYA S. , CHATTERJEE S. 
Published: May 2016

AbstractIn contrast to (Ib) the cleavage of p‐nitrophenylate from (Ia) at pH 7.94 is kinetically biphasic.
ChemInform Abstract: Synthesis of Fluorocodlemones.
Authors: TELLIER F. , SAUVETRE R. , NORMANT J.‐F. 
Published: May 2016

AbstractThe difluoroalkenes (III), prepared by alkylation of the trifluoroalkene (I) with the lithium agents (II) and subsequent desilylation, are metalated to give the zinc organyls (V).
ChemInform Abstract: Synthesis, Redox Behavior, and Spin‐Trap Properties of 2,6‐Di‐tert‐butylnitrosobenzene (DTBN).
Authors: CERRI V. , FREJAVILLE C. , VILA F. , ALLOUCHE A. , GRONCHI G. , TORDO P. 
Published: May 2016

AbstractThe nitrosoarene (II) is obtained by smooth oxidation of the corresponding aniline (I) with peroxybenzoic acid.
ChemInform Abstract: Formation of N‐Acetyl‐p‐benzoquinonimine, the Well‐Known Toxic Metabolite of Acetaminophen, by the Reaction of Acetaminophen with Nitrile Under Model Stomach Conditions.
Authors: OHTA T. , ORIBE H. , IDE M. , TAKITANI S. 
Published: May 2016

AbstractTreatment of acetaminophen (I) with acidic nitrite solution yields a complex reaction mixture.
ChemInform Abstract: An Improved Synthesis of 2‐Carbamoyloxymethyl‐1,4‐dihydropyridine.
Authors: SUZUKI K. , USHIJIMA R. , MIYANO T. , NAKAGAWA S. 
Published: May 2016

AbstractThe O‐butynyl carbamates (IV), prepared by consecutive reaction of the alcohols (I) with phosgene (II) and the amines (III), react with ammonium salts, e.g. (V), or ammonia (VI) to give the amino compounds (VII).
ChemInform Abstract: An Efficient Synthesis of the 4a‐Aryl‐6‐oxodecahydroisoquinolines.
Authors: CANTRELL B. E. , PASCHAL J. W. , ZIMMERMAN D. M. 
Published: May 2016

AbstractThe enamine (I) is lithiated with BuLi and then coupled with the oxirane (II) to give the stereoisomeric oxazabicyclononanes (III).
ChemInform Abstract: Compounds with Bridgehead Nitrogen. Part 58. Configurational Assignments to 1‐Methyl‐1‐isopropylperhydro‐oxazolo(3,4‐a)pyridines.
Authors: CRABB T. A. , TRETHEWEY A. N. 
Published: May 2016

AbstractProtonation of the diastereomeric perhydro‐oxazolopyridines (I) or (IV) gives different proportions of the trans‐fused hydrochlorides (II) or (V) and the O‐outside cis‐fused products (III) or (VI), as shown by NMR.
ChemInform Abstract: Quinolinone Derivatives as Neuroleptic Agents. Part 1. Synthesis and Biological Activities of (4‐Phenyl‐1‐piperazinyl)propoxy‐2(1H)‐quinolinone Derivatives.
Authors: BANNO K. , FUJIOKA T. , KIKUCHI T. , OSHIRO Y. , HIYAMA T. , NAKAGAWA K. 
Published: May 2016

AbstractThe title compounds, e.g. (V), are prepared by etherification of hydroxydihydroquinolones such as (II) with the α,ω‐dihaloalkanes (I) and subsequent coupling with the 4‐substituted piperazines (IV).
ChemInform Abstract: Cyclofunctionalization of Olefinic Urethanes and Ureas with Halogens. Synthesis of 1‐Substituted Spiro(piperidine‐4,4′(3′H)‐quinazoline)‐2′(1′H)‐one Derivatives.
Authors: TAKAI H. , OBASE H. , TERANISHI M. 
Published: May 2016

AbstractThe urethane (I) is treated with bromine in aqueous acetic acid at room temperature to form the cyclization products (II) and (III).
ChemInform Abstract: Formation of Regioisomeric Tetrahydroisoxazolo(2,3‐d)(1,4)benzodiazepines by Kinetic and Thermodynamic Controls.
Authors: MERENDA I. , OTTANA R. , ROMEO G. , ROTONDO E. 
Published: May 2016

Abstract1,3‐Dipolar cycloaddition of the benzodiazepine N‐oxide (I) with the acrylic acid derivatives (II) gives the regioisomeric isoxazolidines (III) and (IV).
ChemInform Abstract: Synthesis of Macrocyclic Esters: Solid‐Liquid Phase‐Transfer‐Catalyzed Condensations of Diacid Halides and Diols.
Authors: SINGH H. , KUMAR M. , SINGH P. 
Published: May 2016

AbstractThe synthesis of tetraester macrocycles such as (III) or (IV) is described using solid‐liquid phase‐transfer systems with non‐hydroxylic bases such as KF or K2CO3.
ChemInform Abstract: Synthesis of 2,4(5)‐Bis(hydroxymethyl)imidazoles and 2,4(5)‐Bis((2‐hydroxyethoxy)methyl)imidazoles: Precursors of 2,4(5)‐Connected Imidazole Crown Ethers.
Authors: ZIMMERMAN S. C. , CRAMER K. D. , GALAN A. A. 
Published: May 2016

AbstractThe bis(hydroxymethyl)imidazole (I) is transformed into the bis(hydroxyethoxymethyl) derivative (IV) which is debenzylated by catalytic hydrogenation to give the key intermediate (V).
ChemInform Abstract: Selective Carriers of Ammonium Ions. Part 1. Synthesis and Template Effect of CsCl and X‐Ray Structure and Ionophoric Properties of Polyether Crowns Containing 1‐Methyl‐3,5‐bis(methylene)‐1H‐pyrazole Units.
Authors: NAVARRO P. , RODRIGUEZ‐FRANCO M. I. , FOCES‐FOCES C. , CANO F. , SAMAT A. 
Published: May 2016

AbstractThe bis(chloromethyl)pyrazole is coupled with tetraethylene glycol (II) in the presence of two equivalents of sodium hydride to give the crown ethers (III) and (IV) with 18 or 36 ring atoms.
ChemInform Abstract: First Asymmetric Synthesis of Enantiomerically Pure (1R,2S)‐(‐)‐(1,2‐Epoxypropyl)phosphonic Acid (Fosfomycin).
Authors: GIORDANO C. , CASTALDI G. 
Published: May 2016

AbstractSynthesis of the chiral phosphonic acid mentioned in the title starts with coupling of cis‐1‐propenylphosphonic acid dichloride (I) with the (S,S)‐tartaric acid diamide (II) followed by bromohydroxylation of (III).
ChemInform Abstract: Acyclic Enol‐ and Ketophosphonates and Cyclic Hydroxyphosphonates from Dialkyl Phosphites and Z‐1,1,1,5,5,5‐Hexafluoro‐4‐hydroxy‐3‐penten‐2‐one.
Authors: FRANCKE R. , ROESCHENTHALER G.‐V. + 
Published: May 2016

AbstractReaction of the hydroxypentenone (I) with the dialkyl phosphites (II) gives the γ‐ketophosphonates (III).
ChemInform Abstract: Functionalized Transition Metal Alkyls. Part 2. Synthesis, Crystal Structure, and Reactivity of (η5‐C5H5)W(CO)3‐CH2‐S(O)‐C6H5, an α‐Metallated Sulfoxide.
Authors: KNEUPER H.‐J. , ZIMMERMANN C. , HARMS K. , BOCHE G. 
Published: May 2016

AbstractThe title compounds (II) are obtained according to the scheme.
ChemInform Abstract: Highly Efficient Hydrolytic Cleavage of Adenosine Monophosphate Resulting in a Binuclear Co(III) Complex with a Novel Doubly Bidentate μ4‐Phosphato Bridge.
Authors: CHIN J. , BANASZCZYK M. 
Published: May 2016

AbstractThe Co(III) complex (I) hydrolyzes unactivated phosphate monoesters such as (II) with unprecedented efficiency.
ChemInform Abstract: Thiophenophane Metal Complexes. Part 2. Preparation, Structure, and Properties of Binuclear Copper(II) Complexes and of 2,5,9,12‐Tetrathia(13)(2,5)thiophenophane. Evidence for S‐Coordinated Thiophene.
Authors: LUCAS C. R. , LIU S. , NEWLANDS M. J. , CHARLAND J.‐P. , GABE E. J. 
Published: May 2016

AbstractThe thiophenophane (III) prepared as shown reacts with Cu(II) chloride (IV) to give the binuclear chloride‐bridged Cu(II) complex (V) with only bidentate coordination of the ligand and distorted square planar coordination geometry about each Cu atom.
ChemInform Abstract: Metal Complexes of Biologically Important Ligands. Part 51. Reactions of α‐Amino Acids with Hexachloropalladate(IV). Stabilization of 1‐Pyrroline at Palladium(II).
Authors: WAGNER B. , TAUBALD U. , BECK W. 
Published: May 2016

AbstractHexachloropalladate(IV) reacts with an excess of α‐amino acids with reduction of the metal to give Pd(II) complexes of the different type (I)‐(VI) depending on the used amino acid.
ChemInform Abstract: Metallabenzene: Synthesis, Structure, and Spectroscopy of a 1‐Irida‐3,5‐dimethylbenzene Complex.
Authors: BLEEKE J. R. , XIE Y.‐F. , PENG W.‐J. , CHIANG M. 
Published: May 2016

AbstractFrom the starting compound (I) (two‐step preparation described earlier) a proton is abstracted to give the title complex (II), which crystallizes in the P21/n with Z=4.
ChemInform Abstract: New PtS4 Chromophores of Dithiocarbamates Derived from α‐Amino Acids: Synthesis, Characterization and Thermal Behavior.
Authors: CRIADO J. J. , CARRASCO A. , MACIAS B. , SALAS J. M. , MEDARDE M. , CASTILLO M. 
Published: May 2016

AbstractThe Pt(II) dithiocarbamate complexes (III) derived from glycine, DL‐alanine, DL‐valine, and DL‐leucine are prepared as shown and characterized by elemental analysis, IR, electronic, 1H and 13C NMR, and X‐ray photoelectron spectroscopies, magnetic susceptibility measurements, TG and DSC analysis.
ChemInform Abstract: The Autoxidation of 3‐Hydroxyanthranilic Acid in the Presence of Amino Acids.
Authors: MANTHEY M. K. , PYNE S. G. , TRUSCOTT R. J. W. 
Published: May 2016

AbstractTo address the problem of protein modification by the oxidized title compound, the title reaction which leads to the p‐quinone derivatives (III), (VI), (VIII) and (IX) is carried out.
ChemInform Abstract: Stereochemical Aspects of Photo‐SET Induced Diradical Cyclization Reactions as Part of Isoquinoline Alkaloid Synthetic Strategies.
Authors: CHO I.‐S. , LEE C.‐P. , MARIANO P. S. 
Published: May 2016

AbstractPhotolytic C‐desilylation of the dihydroisoquinolinium perchlorate (II) produces the diradical (III) which undergoes intramolecular cyclization, forming the berbine isomers (IV) and (V).
ChemInform Abstract: Structure Determination of New Isomeric Naphtho(2,3‐b)furan‐4,9‐diones from Tabebuia avellanedae by the Selective‐INEPT Technique.
Authors: WAGNER H. , KREHER B. , LOTTER H. , HAMBURGER M. O. , CORDELL G. A. 
Published: May 2016

AbstractBesides the known naphthoquinones, dehydro‐α‐lapachone and lapachol, the new title compounds (I), the benzofuranaldehyde (II), and (III) are isolated from a CHCl3 extract of the inner stem bark of T. avellanedae Lorentz ex Griseb., together with a variety of known compounds, which have not been reported previously from this plant.
ChemInform Abstract: Synthesis of Potential Oxa and Dioxa Juvenoids with Camphene and Bornane Systems in the Terminal Position.
Authors: BOROWIECKI L. , WELNIAK M. , WODZKI W. 
Published: May 2016

AbstractThe (camphenyl)‐6‐oxaesters (VI) and (VIII) are synthesized starting with the acids (II) and the ketone (VII), respectively, as demonstrated for (VI).
ChemInform Abstract: Fabrication of Titanium Carbide Ceramics by High‐Pressure Self‐Combustion Sintering of Titanium Powder and Carbon Fiber.
Authors: ADACHI S. , WADA T. , MIHARA T. , MIYAMOTO Y. , KOIZUMI M. , YAMADA O. 
Published: May 2016

AbstractPorous TiC with a density of ∼50% of the theoretical density is obtained by means of the title method using a pressure of 65 MPa, while a pressure of 3 GPa yields a dense TiC compact (>95% of theoretical).
ChemInform Abstract: Chemistry of Silicon‐Nitrogen Compounds. Part 165. Crystalline Products from the Reaction of Silicon Tetrachloride with Nitrogen in a Glow Discharge. Single Crystal X‐Ray Structure Determination of N(SiCl3)3 and Cl3SiN(SiCl2)2NSiCl3.
Authors: WANNAGAT U. , FLINDT R. , BRAUER D. J. , BUERGER H. + , DOERRENBACH F. + 
Published: May 2016

AbstractUsing mass and vibrational spectroscopy as well as single crystal XRD the two crystalline compounds obtained by reacting a SiF4/N2 mixture in a glow discharge tube are identified to be (I) and (II), respectively.
ChemInform Abstract: BaNi2In4Sc4O15 with BaV10O15 Structure, but Ordered Metal Distribution.
Authors: MUELLER‐BUSCHBAUM HK. + , RUETER I. + 
Published: May 2016

AbstractThe title compound, obtained by heating a pressed pellet containing BaCO3, basic nickel carbonate, Sc2O3, and In2O3 (1:2:2:2.5; 1. 1000 °C, 48 h; 2. 2000 °C (CO2 laser); 3. 1600 °C, 15 min), crystallizes in the space group Cmca, Z=4.