bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Tetraamminebis(tetraiodothallate(III))copper(II).
Authors: TEBBE K.‐F. 
Published: May 2016

AbstractThe title compound (I), which can be precipitated from a solution of NH4TlI4 and (Cu(NH3)4)SO4, is monoclinic and belongs to the space group P21/n with Z=2.
ChemInform Abstract: Structure of Tetrapotassium Trisilver Heptanitrite and Potassium Silver Dinitrite Hemihydrate.
Authors: OKAMURA Y. , ISHIHARA M. , OHBA S. , SAITO Y. 
Published: May 2016

AbstractThe structures of the title double salts (obtained from aqueous solutions in different concentrations) are determined to study the interactions between NO2‐ and Ag+ ions.
ChemInform Abstract: Structural and Electronic Origin of the Three‐Dimensional Electrical Properties of P8W12O52 and Its Inserted and Substituted Analogues AxP8W12O52 (A: Li, Na) and P8W12‐xMoxO52
Authors: CANADELL E. , EL‐IDRISSI RACHIDI I. , WANG E. , GREENBLATT M. , WHANGBO M.‐H. 
Published: May 2016

Abstract(x: 0.28, 0.40, 0.68).
ChemInform Abstract: Phosphate Complexation of Gadolinium(III) in Aqueous Solution
Authors: BINGLER L. S. , BYRNE R. H. 
Published: May 2016

Abstractis studied by determination of the distribution of high specific activity 153Gd between tributyl phosphate and a 0.68 M aqueous phase at 25 °C. The formation constants of GdH2PO42+, GdHPO4+, and Gd(HPO4)2‐ are given.
ChemInform Abstract: Impedance of Hydrated Iridium Oxide Electrodes.
Authors: AURIAN‐BLAJENI B. , BEEBE X. , RAUH R. D. , ROSE T. L. 
Published: May 2016

AbstractThe results of ac impedance measurements on anodically formed iridium oxide films, measured as a function of potential and film thickness over a frequency range of 8 orders of magnitude in solutions of different pH are analyzed in terms of an equivalent circuit in which the components are related to the electric and morphological properties of the film and to contributions from the solution.
ChemInform Abstract: The Pt Electrodeposition on PAN‐Based Carbon Fibers
Authors: GEORGOLIOS N. , JANNAKOUDAKIS D. , KARABINAS P. 
Published: May 2016

Abstractfrom 0.5 M H2SO4 solution is studied using cyclic voltammetry, chronoamperometry, and chronopotentiometry combined with SEM observation.
ChemInform Abstract: Kinetics and Mechanism of the Iron(III)‐Catalyzed Autoxidation of Sulfur(IV) Oxides in Aqueous Solution. Part 2. Decomposition of Transient Iron(III)‐Sulfur(IV) Complexes.
Authors: KRAFT J. , VAN ELDIK R. 
Published: May 2016

AbstractThe 1:1, 1:2, and 1:3 sulfito complexes of Fe(III) produced by reaction of aquated Fe(III) with S(IV) oxides (see preceding abstract) are found to produce Fe(II), SO42‐, and S2O62‐ in two successive redox reactions.
ChemInform Abstract: Reactivity of Coordinated Peroxide at a Highly Peroxygenated Vanadium(V) Center in an Aqueous Medium.
Authors: BHATTACHARJEE M. N. , CHAUDHURI M. K. , ISLAM N. S. 
Published: May 2016

AbstractA deep blue aqueous solution of the peroxo complex (I) readily reacts with gaseous SO2 to produce a yellow, ESR‐inactive solution that on further reaction with SO2(g) affords a green‐blue, ESR‐active solution.
ChemInform Abstract: Chiral Recognition of Aromatic Carboxylate Anions by an Optically Active Abiotic Receptor Containing a Rigid Guanidinium Binding Subunit.
Authors: ECHAVARREN A. , GALAN A. , LEHN J.‐M. , DE MENDOZA J. 
Published: May 2016

AbstractThe (S,S)‐ and (R,R)‐enantiomers of the title compound (I) are prepared in 58% yield from both enantiomers of the bicyclic guanidine subunit recently described and 2‐naphthoyl chloride (Et3N, DMF).
ChemInform Abstract: Effect of Catalyst on Zwitterionic Intermediacy in Additions of Dimethyl Diazomalonate to Vinyl Ethers.
Authors: ALONSO M. E. , FERNANDEZ R. 
Published: May 2016

AbstractThe reaction of the diazomalonate (II) with the pyran derivative (I) in hot fluorobenzene leading to the pyran (III) and to the rearrangement products (IV) and (V) is strongly influenced by the nature of the transition metal catalyst used, as it is exemplified in the scheme.
ChemInform Abstract: The Walk Rearrangement in Bicyclo(2.1.0)pent‐2‐ene. An MCSCF Study.
Authors: JENSEN F. 
Published: May 2016

AbstractThe Woodward‐Hoffmann allowed reaction in the title compound, occurring with inversion at the migrating carbon, is found to be a concerted process whereas the rearrangement, which occurs with retention, proceeds via a biradical intermediate.
ChemInform Abstract: Charge Transfer Ion Pairs. Structure and Photoinduced Electron Transfer of Carbonylmetalate Salts.
Authors: BOCKMAN T. M. , KOCHI J. K. 
Published: May 2016

AbstractBrightly colored crystals, readily isolated from such colorless carbonylmetalates such as Co(CO)‐ 4, Mn(CO)‐ 5 and V(CO)‐ 6 in conjunction with various metallocenium and pyridinium cations are identified as CT salts by their absorption and diffuse reflectance spectra.
ChemInform Abstract: Lifetimes of α‐Dialkoxy Carbocations Produced via Radical Cations Generated by Electron Transfer and Photoionization in Aqueous Solution.
Authors: STEENKEN S. , MCCLELLAND R. A. 
Published: May 2016

AbstractTwenty‐four carbocations such as (IV)‐(VI) are generated by electron transfer or by biphotonic ionization (λ = 248 nm).
ChemInform Abstract: Photoreactivity of σ‐Bonded Metalloporphyrins. Part 1. Formation of Zwitterionic Indium and Gallium Porphyrin Complexes in Tetrahydrofuran.
Authors: KADISH K. M. , MAIYA G. B. , XU Q. Y. 
Published: May 2016

AbstractThe laser‐flash and steady‐light photolysis of complexes such as (I) (19 examples) is investigated in THF.
ChemInform Abstract: Inorganic Solids in ′Dry Media′: An Efficient Way for Developing Microwave Irradiation‐Activated Organic Reactions.
Authors: GUTIERREZ E. , LOUPY A. , BRAM G. , RUIZ‐HITZKY E. 
Published: May 2016

AbstractThe metal montmorillonite‐mediated rearrangement of pinacol (I) to give pinacolone (II) is performed under heating or microwave irradiation.
ChemInform Abstract: Benzylbromocarbene: Absolute Rate Constant for 1,2‐Hydrogen Migration and Ambiphilicity.
Authors: BONNEAU R. , LIU M. T. H. , SURESH R. V. 
Published: May 2016

AbstractThe carbene (I), which is generated photochemically from the corresponding diazirine, shows 1,2‐hydrogen migration (k = 5.6·107/s at 25 °C) in the presence of pyridine to give a mixture of (III) and the ylide (IV).
ChemInform Abstract: Substrate Selectivity in Epoxidation by Metalloporphyrin and Metallosalen Catalysts Carrying Binding Groups.
Authors: BRESLOW R. , BROWN A. B. , MCCULLOUGH R. D. , WHITE P. W. 
Published: May 2016

AbstractEpoxidations of the double binding, single binding and nonbinding substrates (I) are carried out using PhIO in the presence of metalloporphyrin and metallosalen catalysts; they are compared with the epoxidations of the nonbinding standard substrate (II).
ChemInform Abstract: Oxygenation of Substituted Vinylcyclopropanes: Preparative and Mechanistic Studies.
Authors: FELDMAN K. S. , SIMPSON R. E. 
Published: May 2016

AbstractVarious vinylcyclopropanes such as (I), (IV), (VI), (VIII) are subjected to phenylseleno or phenylthio radical catalyzed oxygenation to furnish dioxolane products.
ChemInform Abstract: Hydroboration of Silylacetylenes. The “Silyl‐Markovnikov” Hydroboration Route to Pure (Z)‐1‐(2‐Borylvinyl)silanes and β‐Keto Silanes.
Authors: SODERQUIST J. A. , COLBERG J. C. , DEL VALLE L. 
Published: May 2016

AbstractThe regiochemistry and stoichiometry of the hydroborylation of simple 1‐silylacetylenes with 9‐borabicyclo(3.3.1)nonane (II) is examined in detail.
ChemInform Abstract: Electron‐Transfer Processes. Part 46. Allylic and Propargylic Substitution Reactions Involving Radicals Generated from Alkylmercury Halides.
Authors: RUSSELL G. A. , NGOVIWATCHAI P. , WU Y. W. 
Published: May 2016

AbstractThe photostimulated reactions between allylic systems such as (I) or (V) and alkylmercury halides such as (II) are reported.
ChemInform Abstract: Zirconocene Complexes of Imines: General Synthesis, Structure, Reactivity, and in situ Generation to Prepare Geometrically Pure Allylic Amines.
Authors: BUCHWALD S. L. , WATSON B. T. , WANNAMAKER M. W. , DEWAN J. C. 
Published: May 2016

AbstractA general method for the preparation of zirconocene complexes of imines such as (V) is developed; the X‐ray structure of (Va) is given.
ChemInform Abstract: Aldol Reactions of Methyl Ketones Using Chiral Boron Reagents: A Reversal in Aldehyde Enantioface Selectivity.
Authors: PATERSON I. , GOODMAN J. M. 
Published: May 2016

AbstractAcetone (I) and its substituted derivatives (IV) are subjected to selective enolization with a chiral borinate in the presence of di(isopropyl)ethylamine and subsequent coupling with the aldehydes (II), yielding the hydroxy ketones (+)‐(III) or (+)‐(V) as the main products.
ChemInform Abstract: Synthesis of γ‐Lactone of (1R)‐cis‐2,2‐Dimethyl‐3‐(2,2,2‐tribromo‐1‐hydroxyethyl)cyclopropanecarboxylic Acid, a Key Intermediate for Deltamethrin, from (+)‐3‐Carene.
Authors: KULKARNI G. H. , TOKE S. M. 
Published: May 2016

AbstractThe cis‐isobutenyl(hydroxymethyl)cyclopropane (II), prepared from (+)‐3‐carene (I) by a known procedure, is oxidized to give the aldehyde (III).
ChemInform Abstract: Synthesis and Antiviral Activity of Nitrogen‐Containing Derivatives in the Adamantane Series.
Authors: KLIMOCHKIN YU. N. , MOISEEV I. K. , BOREKO E. I. , VLADYKO G. V. , KOROBCHENKO L. V. 
Published: May 2016

AbstractThe adamantanes (I) and (VI) are treated with nitric acid and then coupled with the carbamate (II), the nitriles (IV), or urea (VII) to give the derivatives (III), (V), and (VIII).
ChemInform Abstract: Electrophilic Trichloromethylation of Xylenes and Pseudocumene. Steric Effects and Some Transformations of Reaction Products.
Authors: BELEN'KII L. I. , BROKHOVETSKII D. B. , KRAYUSHKIN M. M. 
Published: May 2016

AbstractThe reaction of (I), (VI) and (IX) with CCl4 (V) in the presence of AlCl3 is studied.
ChemInform Abstract: Palladium‐Catalyzed Asymmetric Allylations of Aldehydes via (S)‐Proline Allyl Ester Enamines.
Authors: HIROI K. , ABE J. , SUYA K. , SATO S. 
Published: May 2016

AbstractThe phenylpropionaldehyde (II) is coupled with (S)‐proline allyl ester (I) to form the enamine (III) which undergoes hydrolysis and intramolecular allylation in the presence of Pd complexes, yielding the optically active aldehyde (R)‐(IV).
ChemInform Abstract: N‐Arenesulfonyl‐N‐phenylhydrazones.
Authors: SCHANTL J. G. , HEBEISEN P. , KARPELLUS P. 
Published: May 2016

AbstractThe aldehyde hydrazones (III) are treated with the sulfonyl chlorides (IV) or (VI) in the presence of bases, yielding the N‐sulfonyl‐N‐phenylhydrazones (V) or (VII).
ChemInform Abstract: Reaction of N‐Sulfinylarylamines with 1,1,1‐Trimethyl‐N‐(trimethylsilyl)‐N‐(trimethylstannyl)silanamine.
Authors: MILLER A. O. , ZIBAREV A. V. , FEDOTOV M. A. , FURIN G. G. 
Published: May 2016

AbstractThe sulfinylanilines (I) react with the amine (II) to give the sulfur diimides (III) or (IV) depending on the nature of Ar.
ChemInform Abstract: 1,4‐Naphthoquinones. Part 17. Studies on the Synthesis of 3‐Hydroxyjuglone Derivatives.
Authors: WURM G. , GERES U. 
Published: May 2016

AbstractReaction of the 3‐halojuglones (I) with sodium methoxide (II) produces 3‐methoxyjuglone (IIIa) in a moderate yield.
ChemInform Abstract: Model Studies for the Synthesis of Ribbon‐Shaped Structures by Repetitive Diels‐Alder Reaction.
Authors: BLATTER K. , SCHLUETER A.‐D. + 
Published: May 2016

AbstractMulticyclic, quinoid aromatic compounds such as (VII), (X), and (XII) are synthesized as shown in the scheme for the examples (VII) and (X).
ChemInform Abstract: 2‐Azoniaallene Salts from the Reaction of Chlorocarbenium Salts with N‐Silylimines.
Authors: HAMED A. , JOCHIMS J. C. , PRZYBYLSKI M. 
Published: May 2016

AbstractThe N‐silylimines (II) react with the chlorocarbenium salts (I) to form the 2‐azoniaallene salts (III).
ChemInform Abstract: Chiral Lactols. Part 9. Comparing the Reactivity of Lactols and α‐Hydroxy Lactols.
Authors: NOE C. R. , KNOLLMUELLER M. + , JANGG E. , STEINBAUER G. 
Published: May 2016

AbstractThe synthesis of the enantiomerically pure α‐hydroxy lactols (III), (V), (VI) and (VIII) is achieved starting from the acid (I).
ChemInform Abstract: The Synthesis of Spirocyclic Compounds by Regiospecific Palladium Catalyzed Cyclization Reactions.
Authors: GRIGG R. , SRIDHARAN V. , STEVENSON P. , SUKIRTHALINGAM S. 
Published: May 2016

AbstractEnamides such as (III) derived from the imines (I) and the iodide (II) undergo regiospecific exo‐trig cyclization to give the spirocycles (IV).
ChemInform Abstract: 4,5‐Bis(methylthio)‐4′,5′‐bis(alkylthio)tetrathiafulvalenes (Vb).
Authors: PAPAVASSILIOU G. C. , KAKOUSSIS V. C. , MOUSDIS G. A. , ZAMBOUNIS J. S. , MAYER C. W. 
Published: May 2016

AbstractStarting from (I), the dithiol‐2‐ones (III) are prepared and, on the other hand, derivatives such as (IV) as well (according to literature procedures).
ChemInform Abstract: Clay Catalysis: Synthesis of Organosulfur Synthons.
Authors: LABIAD B. , VILLEMIN D. 
Published: May 2016

AbstractThe reaction of ketones, aldehydes, and O‐acetals with mercaptans or α,ω‐dithiols is mediated by the clay catalyst montmorillonite KSF to give (cyclic) dithioacetals.
ChemInform Abstract: Exchange Reactions Starting with Germanium‐Containing Dioxolanes, Oxazolidines, and Imidazolidines.
Authors: DOUSSE G. , LAVAYSSIERE H. , SATGE J. 
Published: May 2016

AbstractGermylated heterocyclic compounds such as (I), (IV), and (VII) react with dihalides such as phenyldichlorophosphine (II), thiophosgene (V), and phenyldichloroarsine (VIII) with exchange of the germanium atom to yield the corresponding heterocyclic derivatives as outlined in the reaction scheme.
ChemInform Abstract: Syntheses with Nitriles. Part 82. On Spiro(indan‐pyrans) and Indene‐propellanes ‐ Adducts of 2‐(Dicyanomethylene)‐1,3‐indandione with 1,3‐Dicarbonyl Compounds.
Authors: DWORCZAK R. , STERK H. , KRATKY C. , JUNEK H. 
Published: May 2016

AbstractThe reaction of the title indandione (I) with 1,3‐dicarbonyl compounds depends on the nature of the latter and leads to products of type (III), (V) and (VII).
ChemInform Abstract: Synthesis of Primary ω‐Phenyl‐ω‐pyridylalkylamines.
Authors: BUSCHAUER A. 
Published: May 2016

AbstractReaction of 2‐chloropyridine (I) with the arylacetonitriles (II) forms the arylpyridylacetonitriles (III) which are treated with phthalimidoethyl bromide (IV) to give the coupling products (V).
ChemInform Abstract: Intramolecular Alkylations of Aromatic Compounds. Part 23. Synthesis of cis‐9,11a‐Dimethyl‐4,5,6,6a,7a,8,9,10,11,11a‐decahydro‐7H‐naphtho‐(1,8‐fg)isoquinolines.
Authors: REIMANN E. , HARGASSER E. 
Published: May 2016

AbstractTreatment of the tetralols (I) with triphenylphosphonium bromide (II) yields the Wittig reagents (III) which react with nicotinealdehyde (IV) to form the alkenes (V).
ChemInform Abstract: A Bridgehead α‐Amino Carbanion: Facile Preparation of C5(Bridgehead)‐Substituted Analogues of (.+‐.)‐5H‐Dibenzo(a,d)cyclohepten‐5,10‐imine Including a Stable α‐Iodo Secondary Amine.
Authors: MONN J. A. , RICE K. C. 
Published: May 2016

AbstractThe polycyclic imine (I) is converted to the amidine (III) which reacts with the halides (IV) to produce the bridgehead‐substituted derivatives (V).
ChemInform Abstract: Photochemical Reaction of 1‐Alkyl‐4,6‐diaryl‐2(1H)‐pyrimidinones in the Presence of Amines.
Authors: NISHIO T. , KATO M. , KASHIMA C. 
Published: May 2016

AbstractIrradiation of the pyrimidinones (I) in the presence of aliphatic amines, e.g. (II), give C‐C adducts such as (III) and small amounts of the reduced dihydropyrimidinones (IV), while irradiation of (I) in the presence of aromatic amines such as (V) yields the 1:1 adducts, e.g. (VI), exclusively.
ChemInform Abstract: 2‐(5‐Pyrimidinyl)propionic Acids as Potential Antiphlogistics and Peripheral Analgesics.
Authors: KVITA V. , SCHWEIZER A. 
Published: May 2016

AbstractTreatment of the 5‐vinylpyrimidines (I) with carbon monoxide (II) in ethanol (III) yields the esters (IV) which are hydrolyzed, forming the compounds (V) mentioned in the title.
ChemInform Abstract: The Synthesis and Structures of Cyclic Oligoether Esters. Part 4. The Formation and Conformation of Macrocyclic Ether Rings of α,β‐Dioxocyclopolyoxa Oligo(Ether‐Esters).
Authors: ERK C. 
Published: May 2016

AbstractThe reaction of oxalyl chloride (I) with polyethylene glycols, e.g. tetraethylene glycol (II), is investigated in order to prepare macrocyclic di‐ and tetraoxo polyethers.
ChemInform Abstract: Boron‐Nitrogen Compounds. Part 119. Reactions of Boron Heterocycles with Pyrazole.
Authors: HABBEN C. , KOMOROWSKI L. , MARINGGELE W. , MELLER A. , NIEDENZU K. 
Published: May 2016

AbstractThe interaction of pyrazole (II) with heterocycles containing two annular B atoms generally seem to proceed by initial attack of the pyrazole NH moiety at the most basic site of the heterocycle.
ChemInform Abstract: Electrochemical Synthesis of Esters of Phosphorus(III) and Phosphorus(V) Acids on the Basis of Elemental Phosphorus.
Authors: ROMAKHIN A. S. , ZARIPOV I. M. , BUDNIKOVA YU. G. , IGNAT'EV YU. A. , NIKITIN E. V. , TOMILOV A. P. , KARGIN YU. M. 
Published: May 2016

AbstractIn the presence of tetraethylammonium iodide, which generates iodine, electrolysis of solutions of the alkanols (I) in acetonitrile containing suspended white phosphorus (II) affords the trialkyl phosphates (III) in high yields along with minor amounts of the alkyl phosphonates (IV).
ChemInform Abstract: Reaction of Phosphinic Acid and Its Salts with Diphenylacylphosphinic Acid and Its Methyl Ester.
Authors: FEDOROVA G. K. , ANAN'EVA L. G. , FESHCHENKO N. G. 
Published: May 2016

AbstractDiphenylacylphosphinic acid (Ia) and its methyl ester (Ib) react with ammonium phosphinate (II) to give the azaphosphorinanes (III).
ChemInform Abstract: Radical C‐Se Bond Cleavage of Selenonium Salts with Grignard Reagents or Magnesium Metal.
Authors: HORI M. , KATAOKA T. , SHIMIZU H. , TSUTSUMI K. 
Published: May 2016

Abstract2‐Methylisoselenochromanium tetrafluoroborate (I) is cleaved upon reaction with organomagnesium iodides or magnesium to give the methylselenoethyltoluene (II).
ChemInform Abstract: 2‐Methyl‐2‐R‐6‐trialkylstannyl‐1,3‐dioxa‐6‐aza‐2‐silacyclooctanes. Synthesis and Unusual Thermal Decomposition.
Authors: KUZNETSOV A. L. , RAKHLIN V. I. , MIRSKOV R. G. , VORONKOV M. G. 
Published: May 2016

AbstractReaction of the dioxaazasilacyclooctanes (I) with the aminostannane (II) gives the triethylstannyl derivatives (III).
ChemInform Abstract: Reactions of the Acetylene Complex (C6H3Me3)(CO)2Cr(C2H2) with PMe3 and HNMe2. Crystal Structures of (C6H3Me3)(CO)2Cr(PMe3) and (C6H3Me3)(CO)2Cr(C(Me)NMe2).
Authors: ROGERS R. D. , ALT H. G. , ENGELHARDT H. E. 
Published: May 2016

AbstractReactions of the acetylene complex (I) with the phosphine (II) and the amine (V) have already been published.
ChemInform Abstract: Chemistry of High‐Valent Transition‐Metal Polytellurides: Preparation and Structure of Oxy Tellurides and Ditellurolenes of Molybdenum and Tungsten.
Authors: FLOMER W. A. , KOLIS J. W. 
Published: May 2016

AbstractThe high‐valent chlorides (I) react readily with a solution of polytelluride anions (Te32‐, Te42‐, Te52‐) in DMF to form oxy telluride complexes isolated as their phosphonium salts (III) (for both space group C2/c, Z=4).
ChemInform Abstract: Synthesis and Structural Characterization of Three New Trinuclear Group VI Clusters.
Authors: COTTON F. A. , KIBALA P. A. , MATUSZ M. , MCCALEB C. S. , SANDOR R. B. W. 
Published: May 2016

AbstractThe Mo clusters (III) (space group P21/c, Z=4) and (IV) (Pc, Z=4) are prepared by reacting Mo3S7Cl4 (I) with the corresponding phosphine ligands as shown for the example (III).
ChemInform Abstract: Reactions of the Asymmetric Dinuclear Dioxo Complex C5Me5(CO)3W‐W(O)2C5Me5 with Cl2, Br2, I2, HCl, CF3COOH, NOCl, NO, and Air. Molecular Structure of C5Me5W(CO)2Br3.
Authors: ALT H. G. , ENGELHARDT H. E. , HAYEN H. I. , ROGERS R. D. 
Published: May 2016

AbstractThe W‐W bond in the dinuclear complex (I) is oxidized by halogens to produce the mononuclear complexes (II) and (III), while hydrochloric acid reacts with (I), yielding the four‐membered ring (IV).
ChemInform Abstract: Lipophilic Technetium Complexes. Part 5. Synthesis and Characterization of (3‐Thiapentane‐1,5‐dithiolato)(thiophenolato)oxotechnetium(V).
Authors: PIETZSCH H.‐J. , SPIES H. , HOFFMANN S. , STACH J. 
Published: May 2016

AbstractThe reaction of a 1:1 molar mixture of the ligands with Tc gluconate in aqueous acetone yields the mononuclear title complex (I).
ChemInform Abstract: Organotransition‐Metal Metallacarboranes. Part 13. Fulvalene‐ and Polyarene‐Transition Metal‐Carborane Complexes as Building Blocks for Multilevel Arrays. Stepwise Synthesis and Structural Characterization of Polymetallic Linked Sandwiches.
Authors: DAVIS J. H. JUN. , SINN E. , GRIMES R. N. 
Published: May 2016

AbstractThe reaction of the carborane anion of (I) with the fulvalenide dianion (II) and CoCl2 (III) yields besides other products the linked double‐decker products (IV).
ChemInform Abstract: Synthesis, Structure, and Reactivity of Cp3Co3(CO)2.
Authors: BARNES C. E. , ORVIS J. A. , STALEY D. L. , RHEINGOLD A. L. , JOHNSON D. C. 
Published: May 2016

AbstractThe oxygen‐sensitive title compound (IV) is synthesized by the reaction of (I) and (II).
ChemInform Abstract: Homo‐ and Heterobimetallic Trihydride Complexes Stabilized by the Tripodal Phosphine Ligand MeC(CH2PPh2)3: Experimental and Theoretical Studies.
Authors: BIANCHINI C. , LASCHI F. , MASI D. , MEALLI C. , MELI A. , OTTAVIANI F. M. , PROSERPIO D. M. , SABAT M. , ZANELLO P. 
Published: May 2016

AbstractThe Rh trihydride (I) reacts with coordinatively unsaturated metal fragments such as the dimer (II), Ni(II) and Co(II) perchlorate, and Fe(BF4)2, and the corresponding tripodal triphosphine to give the stable bimetallic polyhydride complexes (IVa), (IVc), and (V).
ChemInform Abstract: Syntheses, Reactions, and Molecular Structures of trans‐Hydrido(phenylamido)bis(triethylphosphine)platinum(II) and trans‐Hydridophenoxobis(triethylphosphine)platinum(II).
Authors: COWAN R. L. , TROGLER W. C. 
Published: May 2016

AbstractThe title complexes, the phenylamido complex (I) (space group P21/n, Z=4) and the phenoxo complex (V) (P1, Z=2) are synthesized according to the scheme and characterized by X‐ray structure analysis.
ChemInform Abstract: Spectroscopic and Electrochemical Studies of Some α‐Diimine Complexes of Platinum(II) and Palladium(II) with Azide and Chloride.
Authors: KAMATH S. S. , UMA V. , SRIVASTAVA T. S. 
Published: May 2016

AbstractIn view of the importance of Pt(II) and Pd(II) complexes in photochemistry, the six new complexes (I) and (II) are prepared.
ChemInform Abstract: Synthetic Studies Towards Complex Diterpenoids. Part 17. Synthesis and Oxidative Cleavage of (+)‐19,20‐Cycloabieta‐19‐oxo‐8,11,13‐triene.
Authors: BANIK B. K. , GHATAK U. R. 
Published: May 2016

AbstractThe title compound (IVa) is prepared on two routes developed earlier for the analogue (IVb); one of these routes is outlined in the scheme.
ChemInform Abstract: 1,1′Carbonylbis(3‐methylimidazolium) Triflate: An Efficient Reagent for Aminoacylations.
Authors: SAHA A. K. , SCHULTZ P. , RAPOPORT H. 
Published: May 2016

AbstractThe title reagent ‐ readily obtainable by bis‐alkylation of carbonyldiimidazole with methyl triflate ‐ couples amino acids with alcohols or amino acid components to give esters and di‐ or tripeptides such as (III) or (V).
ChemInform Abstract: N‐Phenylation of Amino Acid Derivatives.
Authors: BARTON D. H. R. , FINET J.‐P. , KHAMSI J. 
Published: May 2016

AbstractThe salts (I) of amino acid esters or the corresponding free α‐aminocarboxylates (IV) are N‐phenylated with triphenylbismuth diacetate (II) in the presence of metallic copper to produce the N‐phenylamino acid esters (III).
ChemInform Abstract: 1,4‐Addition of (Diphenylmethylene)amine to Acceptor‐Substituted Olefins. A Versatile Synthesis of Protected β‐Amino Acids, Nitriles, and Ketones.
Authors: WESSJOHANN L. , MCGAFFIN G. , DE MEIJERE A. 
Published: May 2016

AbstractMichael addition of benzophenonimine (I) to the electrophilic alkenes (II) yields the adducts (III).