bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthetic and Mechanistic Aspects of Palladium‐Catalyzed Asymmetric Hydrocyanation of Alkenes: Crystal Structure and Reactions of (η2‐Ethene)(diop)palladium.
Authors: HODGSON M. , PARKER D. , TAYLOR R. J. , FERGUSON G. 
Published: May 2016

AbstractThe asymmetric hydrocyanation of norbornene (I), catalyzed by chiral palladium diphosphine complexes, gives the exo nitrile (III) with up to 40% e.e.
ChemInform Abstract: Synthesis of N‐Heterocyclic Complexes of Osmium, Ruthenium, Cobalt, and Rhodium Pentaammines.
Authors: LAY P. A. , MAGNUSON R. H. , TAUBE H. 
Published: May 2016

AbstractExamples are given of the improved syntheses of a variety of N‐heterocyclic complexes of the type (M(NH3)5L)n+ (M: Os, Ru, Rh, Co; L: N‐heterocycle e.g. pyrazine, pyridine, 2,2'‐bipyridine; n = 3, 2) which are prepared by the reaction of (M(NH3)5(OSO2CF3))(CF3SO3)2 either with neat ligand or with an excess of the ligand in a poorly coordinating solvent.
ChemInform Abstract: New Entry to syn‐β‐Hydroxy‐α‐amino Acids.
Authors: HIRAMA M. , HIOKI H. , ITO S. 
Published: May 2016

AbstractThe α‐siloxy aldehyde (I) is coupled with the methylthiomethyl sulfone (II) and then dehydrated to form the ketene dithioacetal dioxide (III) which is converted to the N‐trichloroacetyl carbamate (V).
ChemInform Abstract: Pheromone Synthesis. Part 111. An Enzyme‐Mediated Synthesis of Both Enantiomers of Seudenol and 1‐Methyl‐2‐cyclohexen‐1‐ol, the Aggregation Pheromones of Dendroctonus pseudotsugae.
Authors: MORI K. , OGOCHE J. I. J. 
Published: May 2016

AbstractThe (S)‐(‐)‐isomer of seudenol (I) is converted to the cyclohexenol (R)‐(+)‐(III) as shown.
ChemInform Abstract: Polarized Ketene Dithioacetals. Part 65. Additions of 2‐Aroyl‐3‐cyano‐1,1‐bis(methylthio)propenide Anions to Hetero‐Multiple Bonds.
Authors: SINGH L. W. , ILA H. , JUNJAPPA H. 
Published: May 2016

AbstractWith a view to synthesizing five‐membered heterocycles, the anions generated from title compounds of type (III) are treated with (II) and (IV) to give the expected (3 + 2) cycloadducts (I) and (V).
ChemInform Abstract: A Stereoselective Synthesis of Functionalized Cyclopentenes via Base‐Induced Ring Contraction of Thiocarbonyl Diels‐Alder Adducts.
Authors: LARSEN S. D. 
Published: May 2016

AbstractA two‐step procedure is developed for the preparation of usefully functionalized cyclopentenes such as (IV) or (VII).
ChemInform Abstract: Chiral Allenes from D‐(+)‐Camphor and Camphene.
Authors: MATTAY J. , CONRADS M. , RUNSINK J. 
Published: May 2016

AbstractCyclopropanation of the methylenebicycloheptane (I), obtained by Wittig reaction of D‐(+)‐camphor (VII), with dibromocarbene yields a mixture of the isomeric cyclopropanes (III) and (IV).
ChemInform Abstract: Synthesis and Spectroscopic Characterization of Cobalt(III) and Copper(II) Complexes of Hexadentate and Tetradentate Ligands Containing Pyridyl Arms.
Authors: MANDEL J. B. , MARICONDI C. , DOUGLAS B. E. 
Published: May 2016

AbstractThe preparation of (IV) is shown in the scheme.
ChemInform Abstract: Strength and Toughness of Continuous‐Alumina‐Fiber‐Reinforced Glass‐Matrix Composites.
Authors: MICHALSKE T. A. , HELLMANN J. R. 
Published: May 2016

AbstractUnidirectional, continuous‐fiber composites, fabricated using polycrystalline alumina fibers and four different silicate glass matrices having thermal expansions above and below alumina, are investigated by fracture toughness measurements, strength measurements, and fractographic analysis.
ChemInform Abstract: Effect of Various Chemical Substitutions on the Physical Properties of Cathodochromic Sodalite.
Authors: TRANJAN F. M. , TODD L. T. JUN. 
Published: May 2016

AbstractThe F‐band absorption energy EF and the thermal activation energy ET of the electron in the F‐center are measured as a function of the lattice parameter a0 of various substituted cathodochromic sodalites of general formula (I).
ChemInform Abstract: Luminescent Properties of Cadmium Sulfoselenide Electrodes Prepared by Ion Implantation.
Authors: SHARPE L. R. , ELLIS A. B. , KALWEIT H. 
Published: May 2016

AbstractInhomogeneous samples of n‐type CdSxSe1‐x are prepared by implantation of Se+ ions into single‐crystal n‐CdS substrates.
ChemInform Abstract: Oxygen Reduction at Nafion Film‐Coated Platinum Electrodes: Transport and Kinetics.
Authors: LAWSON D. R. , WHITELEY L. D. , MARTIN C. R. , SZENTIRMAY M. N. , SONG J. I. 
Published: May 2016

AbstractA high temp. film casting procedure which yields high quality solution‐cast Nafion films is used to prepare the Nafion‐coated electrodes.
ChemInform Abstract: Experimental Approach to the Process of the Reaction Between Silicon and Copper Chloride Powders.
Authors: WEBER G. , VIALE D. , SOUHA H. , GILLOT B. 
Published: May 2016

AbstractThe progress of the reaction between Si and CuCl is studied both in closed and open systems using TG, HCl titration with NaOH after hydrolysis of SiCl4, and XRD.
ChemInform Abstract: Ionic Probes of Aromaticity in Anellated Rings.
Authors: MEOT‐NER M. , LIEBMAN J. F. , KAFAFI S. A. 
Published: May 2016

AbstractThe effects of anellation (benzene → naphthalene → anthracene or pyrrole → indole, e.g.) on proton affinities are studied by measurements of gas‐phase acidities and theoretical (AM1) calculations for a wide range of parent compounds such as benzene, pyridine, cyclopentadiene, cycloheptatriene, and their anellated derivatives.
ChemInform Abstract: Thermodynamic Studies of Competitive Adduct Formation: Single‐ and Double‐Insertion Reactions of Carbon Monoxide with Rhodium Octaethylporphyrin Dimer.
Authors: COFFIN V. L. , BRENNEN W. , WAYLAND B. B. 
Published: May 2016

AbstractThe enthalpy and entropy changes for the title reactions are determined.
ChemInform Abstract: A New, One‐Pot Synthesis of Primary 2‐Alkynamides.
Authors: PAGE P. C. B. , ROSENTHAL S. , WILLIAMS R. V. 
Published: May 2016

AbstractThe silylalkynes (I) react with chlorosulfonyl isocyanate (II) to produce the alkynamides (III) after hydrolytic work‐up.
ChemInform Abstract: Sulfinic Acids and Related Compounds. Part 20. Synthesis and Properties of Some α,ω‐Alkylenebis(dithiaalkanesulfinates).
Authors: MACKE J. D. , FIELD L. 
Published: May 2016

AbstractThe cyclic disulfide 1,1‐dioxides (I) react with the butanedithiols (II) or (V) in the presence of sodium methoxide to produce the butane‐1,4‐bis(dithiaalkanesulfinates) (IV) or (VI).
ChemInform Abstract: A Prosthetic Group for the Rapid Introduction of Fluorine into Peptides and Functionalized Drugs.
Authors: JACOBSON K. A. , FURLANO D. C. , KIRK K. L. 
Published: May 2016

AbstractReaction of the succinimidyl p‐(bromomethyl)benzoates (III) with several amino compounds (IV) yields the amides (V) which are fluorinated with tetrabutylammonium fluoride to give the fluoromethyl derivatives (VI).
ChemInform Abstract: Friedel‐Crafts Cycloalkylations of Some Epoxides. Part 3. Cyclizations of Tertiary and Meta‐Substituted Arylalkyl Epoxides.
Authors: TAYLOR S. K. , BLANKESPOOR C. L. , HARVEY S. M. , RICHARDSON L. J. 
Published: May 2016

AbstractTreatment of the epoxides (I), (V), and (VIII) with Lewis acids results in the formation of the ring closure products (II), (VI), or (IX) and (X), together with the uncyclized products (III) and (IV) or (VII) or (XI) ‐ (XIII).
ChemInform Abstract: Tetrazoles. Part 25. Preparation and Properties of N‐Benzoyltetrazoles.
Authors: MYZNIKOV YU. E. , KOLDOBSKII G. I. , VASIL'EVA I. N. , OSTROVSKII V. A. 
Published: May 2016

AbstractAcylation of 5‐phenyltetrazole (I) by benzoyl chloride (IIa) or by the substituted benzoyl chlorides (IIb) and (IIc) affords the title compounds as mixtures of the 5‐phenyl‐1‐acyl‐ (III) and 5‐phenyl‐2‐acyltetrazoles (IV).
ChemInform Abstract: Chemistry of Ketene Acetals. Part 9. A Simple ′One‐Pot′ Synthesis of 4‐Hydroxy‐δ‐lactones and 5,6‐Dihydro‐2‐pyrones from 1,1‐Dimethoxypropene and β‐Oxy Aldehydes.
Authors: HOFSTRAAT R. G. , LANGE J. , SCHEEREN H. W. , NIVARD R. J. F. 
Published: May 2016

AbstractThe protected β‐oxy aldehyde (I) reacts with the ketene acetal (II) in the presence of a catalyst to give the acyclic compound (III), which undergoes saponification and deprotection to give the hydroxylactone (IV).
ChemInform Abstract: Addition of 4‐Ethoxyimidazoles to Dimethyl Acetylenedicarboxylate and Transformation of the Adducts to Pyrimidin‐5‐ylacetates.
Authors: FURUYA S. , OMURA K. , FURUKAWA Y. 
Published: May 2016

AbstractRing closure reaction of the N‐acylated glycine amides (I) with the triethyl oxonium salt (II) gives the ethoxyimidazoles (III) which are coupled with the acetylenedicarboxylate (IV), yielding mixtures of the maleates (V) and the fumarates (VI).
ChemInform Abstract: Synthesis of α‐Halogenated Methanediphosphonates.
Authors: MCKENNA C. E. , KHAWLI L. A. , AHMAD W.‐Y. , PHAM P. , BONGARTZ J.‐P. 
Published: May 2016

AbstractThe tetraalkyl methanediphosphonates (I) are chlorinated with sodium hypochlorite to form the dichloro derivatives (II).
ChemInform Abstract: Formation of Bridging Acylium and Nitrilium Complexes by Reaction of CO and CNC(CH3)3 with a Bridging Diiron Methylidyne Complex. Evidence for Strong Electron Donation from the Fe2C Core onto the μ‐CHCO and μ‐CHCNR Ligands.
Authors: CASEY C. P. , CROCKER M. , NICCOLAI G. P. , FAGAN P. J. , KONINGS M. S. 
Published: May 2016

AbstractThe reaction of the μ‐methylidyne complex (I) with CO (II) gives the cationic 1:1 adduct (III).
ChemInform Abstract: Preparation, Electrochemical Oxidation, and XPS Studies of Unsymmetrical Ruthenocenes Bearing the Pentamethylcyclopentadienyl Ligand.
Authors: GASSMAN P. G. , WINTER C. H. 
Published: May 2016

AbstractThe reaction of dichloro(pentamethylcyclopentadienyl)‐Ru(III) oligomer (I) with alkali metal salts of a variety of cyclopentadienyl derivatives provides a convenient synthetic approach to unsym. ruthenocenes.
ChemInform Abstract: Synthesis of 17α‐Amino‐5α‐androstan‐3α‐ol.
Authors: NADARAIA N. SH. , SLADKOV V. I. , SUVOROV N. N. 
Published: May 2016

AbstractThe hitherto unknown title compound (IV) is prepared starting from the 17α‐amino‐5α‐androstane‐3β‐ol (I).
ChemInform Abstract: 2‐Pyridyl‐ and Quinolin‐2‐yl‐functionalized Organyltellurium Ligands. The Stabilization of Diorganyl Tritellurides. The Crystal and Molecular Structures of 2‐(2‐Pyridyl)phenyltellurium(IV) Tribromide, Dimethyldithiocarbamato(2‐(2‐pyridyl)phenyl)tellurium(II), and p‐Ethoxyphenyl 2‐(2‐Pyridyl)phenyl Telluride.
Authors: AL‐SALIM N. , WEST A. A. , MCWHINNIE W. R. , HAMOR T. A. 
Published: May 2016

AbstractSyntheses and spectroscopic (13C NMR) data for some new organyl‐Te ligands are described.
ChemInform Abstract: Cationic Technetium Complex with 1,4‐Dithia‐8,11‐diazacyclotetradecane.
Authors: TRUFFER S. , IANOZ E. , LERCH P. , KOSINSKI M. 
Published: May 2016

AbstractThe complex of 99Tc with the ligand (Ib) is prepared via a ligand exchange reaction and is compared to the complex of 99Tc with the ligand (Ia).
ChemInform Abstract: Metabolites of Microorganisms. Part 250. Maduraferrin, a Novel Siderophore from Actinomadura madurae.
Authors: KELLER‐SCHIERLEIN W. , HAGMANN L. , ZAEHNER H. + , HUHN W. 
Published: May 2016

AbstractThe red‐brown title compound is found to be an Fe(III) complex of the compound (I).
ChemInform Abstract: Thermal Cycloaddition Reactions of π‐Delocalized Singlet Vinylcarbenes: Three‐Carbon 1,1‐/1,3‐Dipoles. The Thermal Three‐Carbon + Two‐Carbon Cycloaddition.
Authors: BOGER D. L. , WYSOCKI R. J. JUN. 
Published: May 2016

AbstractThe Z‐ and E‐isomeric methylenemalonates (I) and (V), whose syntheses and separation are described, react with the cyclopropenone acetal (II) in a (3 + 2)cycloaddition reaction to yield the inseparable mixtures of the adducts (III) and (IV).
ChemInform Abstract: Propyniminium Salts ‐ Synthesis, (2 + 2), and (2 + 4) Cycloadditions.
Authors: MAAS G. , SINGER B. , WALD P. , GIMMY M. 
Published: May 2016

AbstractElimination of triflic acid from (I) yields the title compounds (II), which undergo (2 + 4) cycloaddition with dienes such as (III) to give the adducts (IV).
ChemInform Abstract: Polarity Reversal Catalysis of Radical Reactions: Hydrogen‐Atom Abstraction from Cyclopentadiene and from Cycloheptatriene.
Authors: PAUL V. , ROBERTS B. P. , ROBINSON C. A. S. 
Published: May 2016

AbstractIn the absence of catalyst (cat.) both radicals (III) and (IV) are observed (ESR) from tBuO· attack on cyclopentadiene (I) while in the presence of cat.
ChemInform Abstract: Dimerization of Vinylcyclopropane and Its Codimerization with 1,3‐Dienes Catalyzed by Cobalt Complexes.
Authors: DZHEMILEV U. M. , KHUSNUTDINOV R. I. , SHCHADNEVA N. A. 
Published: May 2016

AbstractDimerization of vinylcyclopropane (I) in the presence of a catalytic system, containing Co(acac)3, gives the dimer (II).
ChemInform Abstract: Nickel‐Induced Conversion of Carbon‐Nitrogen into Carbon‐Carbon Bonds. One‐Step Transformations of Quaternary Arylammonium Salts into Alkylarenes, and Biaryls.
Authors: WENKERT E. , HAN A.‐L. , JENNY C.‐J. 
Published: May 2016

AbstractNi(II)‐catalyzed substitution of the aryltrimethylammonium iodides (I) with the Grignard reagents (II) yields the arenes (III).
ChemInform Abstract: Macroheterocycles. Part 34. Synthesis and Enantioselectivity of Chiral Aza‐Crown Ethers.
Authors: LUK'YANENKO N. G. , LOBACH A. V. , NAZAROVA N. YU. , KARPENKO L. P. , LYAMTSEVA L. N. 
Published: May 2016

AbstractThe ditosylate (I) is coupled with the diol (II) to give the chiral aza‐crown ethers (III) ‐ (V).
ChemInform Abstract: nido‐Carborane Building‐Block Reagents. Part 2. Bulky‐Substituent (alkyl)2C2B4H6 Derivatives and (C6H5)2C2B4H6: Synthesis and Properties.
Authors: BOYTER H. A. JUN. , GRIMES R. N. 
Published: May 2016

AbstractIn order to further assess the steric and electronic influence of the R groups on the properties of the nido‐C2B4 cage, especially with respect to metal complexation at the C2B3 face and metal‐promoted oxidative fusion the three dialkyl derivatives (IIIa)‐(IIIc) are prepared as demonstrated for (IIIa).
ChemInform Abstract: Discrete Trinuclear Complexes of Niobium and Tantalum Related to the Local Structure in Nb3Cl8.
Authors: COTTON F. A. , DIEBOLD M. P. , FENG X. , ROTH W. J. 
Published: May 2016

AbstractThe reaction of a mixture of PMe2Ph or PEt3 and NbCl4(THF)2 in toluene gives the clusters (I) or (IIa).
ChemInform Abstract: Enantioselective Synthesis of (‐)‐Kainic Acid.
Authors: TAKANO S. , SUGIHARA T. , SATOH S. , OGASAWARA K. 
Published: May 2016

AbstractThe title compound (XIV), which is known to possess anthelmintic, insecticidal and neuroexcitatory activity, and its lactone (XV) are prepared via the common intermediate (IX) as shown.
ChemInform Abstract: Properties of High‐Temperature Superconducting Materials Prepared by Impuls Compaction.
Authors: DERIBAS A. A. , MATIZEN E. V. , NESTERENKO V. F. , PERSHIN S. A. , STARIKOV M. A. , VORONIN A. N. , BLINOV A. G. 
Published: May 2016

AbstractHigh‐temp. superconductive ceramics of the system Y‐Ba‐Cu‐O are synthesized by shock‐wave treatment of powders, which contain the high‐temp.
ChemInform Abstract: Asymmetric Synthesis via Heterocyclic Intermediates. Part 39. Asymmetric Synthesis of (Enantiomerically and Diastereomerically Virtually Pure) Methyl 2‐Amino‐4,5‐epoxy‐3‐hydroxy‐alkanoates and Methyl 2‐Amino‐3‐hydroxy‐4,5‐methylene‐alkanoates by the Bislactim Ether Method.
Authors: SCHOELLKOPF U. + , TILLER T. , BARDENHAGEN J. 
Published: May 2016

AbstractThe titanated bislactim ether (I) of cyclo‐(L‐Val‐Gly) reacts with various unsaturated aldehydes (III) to give the adducts (IV).
ChemInform Abstract: Gas‐Phase Chemistry of Transition Metal‐Imido and ‐Nitrene Ion Complexes. Oxidative Addition of N‐H Bonds in NH3 and Transfer of NH from a Metal Center to an Alkene.
Authors: BUCKNER S. W. , GORD J. R. , FREISER B. S. 
Published: May 2016

AbstractEarly transition metal ions (group 3‐5) react with NH3 at thermal energies to form MNH+ via dehydrogenation.
ChemInform Abstract: Reduction of Aldehydes and Ketones to Methylene Derivatives Using Ammonium Formate as a Catalytic Hydrogen Transfer Agent.
Authors: RAM S. , SPICER L. D. 
Published: May 2016

AbstractThe aldehydes or ketones (I) are reduced with ammonium formiate in the presence of Pd on carbon to give the methylene compounds (II).
ChemInform Abstract: A General Synthesis of Substituted Fluorenones and Azafluorenones.
Authors: KYBA E. P. , LIU S.‐T. , CHOCKALINGAM K. , REDDY B. R. 
Published: May 2016

AbstractPhotochemically induced cyclization of 2‐diazoniodiaryl ketones, prepared in situ from the corresponding amino compounds (V) or (VII), gives the (aza)fluorenones (VI) or (VIII) and (IX).
ChemInform Abstract: Metal Complexes of Functional Isocyanides. Part 17. Reactions of Pentacarbonyl(trichloromethyl isocyanide)chromium.
Authors: BECK G. , FEHLHAMMER W. P. 
Published: May 2016

AbstractA wide variety of organometallic products can be synthesized from the title compound (I), which exhibits two mutually reinforcing electrophilic centers, the isocyano unit and the halogenated α‐C atom.
ChemInform Abstract: Kinetic and Thermodynamic Studies on the Reaction of O2 with Two Dinuclear Copper(I) Complexes.
Authors: CRUSE R. W. , KADERLI S. , KARLIN K. D. , ZUBERBUEHLER A. D. + 
Published: May 2016

AbstractIn order to elucidate the factors which are important in practical dioxygen carriers and biological dioxygen utilization the first thermodynamic and kinetic data for two synthetic systems are reported.
ChemInform Abstract: Synthesis of Ketomethylene Dipeptides Containing Basic Amino Acid Analogues at C‐Terminus.
Authors: GARCIA‐LOPEZ M. T. , GONZALEZ‐MUNIZ R. , HARTO J. R. 
Published: May 2016

AbstractThe title compounds (V), (VII), and (IX) are prepared as shown in the scheme starting from the diesters (Ia), (Ib).
ChemInform Abstract: A High Tc Superconducting Orthorhombic Form of LaBa2Cu3O6.8.
Authors: HERVIEU M. , DOMENGES B. , DESLANDES F. , MICHEL C. , RAVEAU B. 
Published: May 2016

AbstractAnnealing of the tetragonal title superconductor at 450 °C causes a tetragonal → orthorhombic transition.
ChemInform Abstract: Some Thermal and Photochemical Reactions of (4.4.4.5)Fenestranes.
Authors: WOLFF S. , RAO V. B. , GEORGE C. F. , AGOSTA W. C. 
Published: May 2016

AbstractThermolysis of the ester (IIa) (obtained together with its isomer (IIb) by a reaction sequence starting from the fenestrane derivative (I)) leads to isomerization to give the compounds (III) and (IV).
ChemInform Abstract: Diels‐Alder Addition of Cyclopentadiene to Allenic Esters: Catalysis by Lanthanide Complexes.
Authors: GANDHI R. P. , ISHAR M. P. S. , WALI A. 
Published: May 2016

AbstractCycloaddition reaction of cyclopentadiene (I) with the allenic esters (II) in the absence of a catalyst gives moderate yields of a mixture of the isomeric methylenenorbornenes (III) ‐ (V).
ChemInform Abstract: Novel (3 + 2)Photocycloadditions with 3‐(1‐Alkynyl)cyclohexenones and Tetramethylethylene.
Authors: MARGARETHA P. , RATHJEN H. J. , WOLFF S. , AGOSTA W. C. 
Published: May 2016

AbstractIrradiation of the propynylcyclohexenone (I) and tetramethylethene (II) in tert‐butanol (III) produces a mixture of the bicyclic ketones (IV) ‐(VI) which is separated by preparative glc.
ChemInform Abstract: Synthesis and Reactions of Isoquinoline Derivatives. Part 2. Synthesis of 3‐Chloroisoquinoline‐4‐aldehydes.
Authors: BARTMANN W. , KONZ E. , RUEGER W. + 
Published: May 2016

AbstractThe title compounds (IV) are prepared from the 1,4‐dihydroisoquinolinones (I) by a Vilsmeier‐Haack reaction, followed by oxidation with potassium permanganate in the presence of an acid.
ChemInform Abstract: A Novel Entry to the PC Double Bond: The “Phospha‐Wittig” Reaction.
Authors: MARINETTI A. , MATHEY F. 
Published: May 2016

AbstractBase treatment of the phosphorylphosphane complexes (II) (no yields given) yields the corresponding phospha‐Wittig reagents which react with ketones to give phosphaalkene complexes, e.g. (IV).
ChemInform Abstract: Organohydrazido(2‐) Complexes of Molybdenum and Tungsten from α,ω‐Dibromides; Crystal and Molecular Structures of (Azetidinylimido)bis(1,2‐bis(di‐p‐tolylphosphino)ethane)bromotungsten Bromide‐Dichloromethane (1/3).
Authors: ABU BAKAR M. , HUGHES D. L. , LEIGH G. J. 
Published: May 2016

AbstractThe photochemical reactions of α,ω‐dibromoalkanes with a range of trans‐bis(dinitrogen)bis(diphosphine)‐Mo complexes generally results in the formation of cationic trans‐bromo(cyclic hydrazido(2‐)) complexes of the type (III) as demonstrated for the examples (IIIa)‐(IIIc).
ChemInform Abstract: Addition of Halogens to ((Au(CH2)2PPh2)2RX) Complexes. The Structures of cis,trans‐((Au(CH2)2PPh2)2(CH2CF3)Br3) and trans,trans‐((Au(CH2)2PPh2)2(CHCl2)Br2Cl).
Authors: MURRAY H. H. III , PORTER L. C. , FACKLER J. P. JUN. , RAPTIS R. G. 
Published: May 2016

AbstractBoth title complexes (II) and (V) are obtained as shown in the scheme and characterized by X‐ray structure analysis (for both space group P1, Z=2).
ChemInform Abstract: Organometallic Complexes with Chiral Cyclometalated Ligands. The Synthesis of Cycloplatinated Complexes Containing the (S)‐ or (R)‐2‐NMe2C6H4CH(SiR3) (R: Me, Ph) Monoanion. X‐Ray Crystal and Molecular Structure of (PtCl(CH(SiMe3)C6H4‐2‐NMe2)(Et2S)).
Authors: WEHMAN E. , VAN KOTEN G. , HARDEMAN G. , STAM C. H. , PFEFFER M. 
Published: May 2016

AbstractThe equimolar reaction of the Li compounds (I) of α‐silylated 2‐(dimethylamino)toluene with the Pt(II) complex (II) results in the formation of the monoalkylated Pt complexes (III).
ChemInform Abstract: Glycosylimidates. Part 38. A Convenient Synthesis of 2‐Deoxy‐β‐D‐glucopyranosides.
Authors: PREUSS R. , SCHMIDT R. R. 
Published: May 2016

Abstract3,4,6‐Tri‐O‐benzyl‐D‐glucal (I) is converted to the α‐trichloroacetimidate (V) in a two‐step sequence.
ChemInform Abstract: Preparation and Structure of M1‐LnTa3O9 (Ln: Pr, Nd), X‐Ray and Electronmicroscopical Investigations.
Authors: SCHAFFRATH U. , STEINMANN G. , GRUEHN R. 
Published: May 2016

AbstractThe new title compounds are prepared from Ln2O3/Ta2O5 (Ln: Pr, Nd) mixtures by chemical transport reactions (1100 → 1000 °C, Cl2 as transportation agent).
ChemInform Abstract: Oxygen Reduction Electrocatalysis by Chevrel Phase Sulfides Supported on Carbon Paste Electrodes.
Authors: SCHUBERT B. , ALONSO VANTE N. , GOCKE E. , TRIBUTSCH H. 
Published: May 2016

AbstractThe electrocatalytic behavior of the following Chevrel phases is studied: Mo6S8, MxMo6S8 (M(x): Ag(1), Pd(1), In(1), Cu(2), Cd(1), Zn(1), Ba(1), Sn(1), Pb(1)) and Mo2Re4S8.
ChemInform Abstract: Metal‐Promoted Cyclization. Part 20. Palladium‐Catalyzed Cyclization of Alkenyl and Aryl Halides Containing α,β‐Unsaturated Carbonyl Groups via Intramolecular Carbopalladation.
Authors: O'CONNOR B. , ZHANG Y. , NEGISHI E. , LUO F.‐T. , CHENG J.‐W. 
Published: May 2016

Abstract2‐Iodobenzyl bromide (I) reacts with the deprotonated esters (II) to give the α,β‐unsaturated carboxylates (III) which are cyclized in the presence of a Pd(0) catalyst to form the indenes (IV).
ChemInform Abstract: A New Synthesis of Polycyclic Aromatic Hydrocarbons via Titanium(IV)‐Catalyzed Aldol‐Type Condensation of Silyl Enol Ethers with 2‐Arylacetaldehydes.
Authors: DI RADDO P. , HARVEY R. G. 
Published: May 2016

AbstractThe naphthylacetaldehydes (I) react with the cyclohexenyl silyl ether (II) in the presence of TiCl4 to give the intermediate adducts (III) which undergo ring closure, forming the tetrahydrochrysenes (IV).
ChemInform Abstract: Reductive Coupling of Nitriles via Formal (2 + 2) Cycloadditions to the Titanium‐Carbon Double Bond.
Authors: DOXSEE K. M. , FARAHI J. B. 
Published: May 2016

AbstractElectron deficient or sterically hindered nitriles, e.g. (II), react with the titanacyclobutane (III) to give the 1:1 complexes (I) with slower transformation to the 2:1 complexes (IV).
ChemInform Abstract: Kinetic and Equilibrium Study of the Reaction of (meso‐Tetrakis(p‐sulfonatophenyl)porphinato)diaquochromate(III) with Imidazole in Aqueous Solution.
Authors: ASHLEY K. R. , KUO J. 
Published: May 2016

AbstractThe ligation reaction of the title complex with imidazole is studied at pH 6.0 and 10.0.