bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Transformation of the Hydroxymethyl into the Aldehyde Group in the Series of Organo‐Tellurium Compounds.
Authors: MAKSIMENKO A. A. , SADEKOV I. D. , MINKIN V. I. 
Published: May 2016

AbstractThe 2‐hydroxymethylphenyl telluride (IV), prepared from the benzyl alcohol (I), is consecutively treated with bromine and triethylamine to give the 2,1‐benzoxatellurole (VI), the first representation of this ring system.
ChemInform Abstract: Disulfur and Diselenium Titanium(IV) Porphyrins: Synthesis and Characterization of (P)Ti(η2‐S2) and (P)Ti(η2‐Se2), Where P is One of Several Different Porphyrin Rings. Crystal Structure of (5,10,15,20‐Tetra‐p‐tolylporphinato)perthiotitanium(IV).
Authors: GUILARD R. , RATTI C. , TABARD A. , RICHARD P. , DUBOIS D. , KADISH K. M. 
Published: May 2016

AbstractAs shown for (III) in an analogous manner complexes with octaethylporphyrin and four phenyl‐substituted tetraphenylporphyrins (substituents: mesityl, m‐tolyl, p‐tolyl, CF3) are prepared in yields between 61 and 88%.
ChemInform Abstract: Preparation and Electronic Characterization of M2(CCR)4(PMe3)4: A Class of Conjugated Transition‐Metal Complexes.
Authors: STONER T. C. , DALLINGER R. F. , HOPKINS M. D. 
Published: May 2016

AbstractThe synthesized title complexes (III) are characterized by X‐ray crystallographic studies (data not given), NMR, electronic and resonance Raman spectra.
ChemInform Abstract: Single and Double C‐C Bond Formation via Iron‐Carbene Species: Access to New π‐ and σ,π‐Vinylarene Complexes.
Authors: GUERCHAIS V. 
Published: May 2016

AbstractThe methoxycarbeneiron complex (I) is coupled with the iron complex (II) in tetrahydrofuran to give the cationic biiron complex (III) which is cleaved upon treatment with trimethylsilyl trifluoromethanesulfonate (IV), yielding a mixture of the η6‐vinylpentamethylbenzene iron complex (V) and the trifluoromethanesulfonate (VI).
ChemInform Abstract: Synthesis and Characterization of New Cobalt Dioxygen Carriers Based on a Familiar Macrocyclic Ligand.
Authors: DZUGAN S. J. , BUSCH D. H. 
Published: May 2016

AbstractA new class of macrocyclic Co(II) dioxygen carriers, the bisacylated complexes (Ib)‐(Id) are prepared by reaction of Co(II) acetate tetrahydrate with the corresponding free macrocycles in MeOH/MeCN in the case of (Ib) and (Id) or by acylation of (Ia) with trifluoroacetic anhydride in benzene in the case of (Ic).
ChemInform Abstract: Transition‐Metal Complexes with Sulfur Ligands. Part 49. Unusual Acid Base Reactions of Low Valence Ruthenium Nitrosyl Complexes with the Thiolate‐amine Ligands “S2N2H”2‐ x (x = 1, 2) and Molybdenum Complexes with the Ligands “S2N2H”2‐ 2 and “tBuS2N2H”2‐ 2 ‐ Syntheses, Structure and Reactions.
Authors: SELLMANN D. , KAEPPLER O. + , KNOCH F. , MOLL M. 
Published: May 2016

AbstractIn order to find complexes suitable as model compounds for oxidoreductases catalyzing reactions of the biological nitrogen cycle, Ru‐ and Mo‐nitrosyl complexes with the title ligands are prepared.
ChemInform Abstract: Metal‐Promoted Binuclear C‐H Activation of Ethylene and Formation of a Novel Heterobimetallic Ir‐Pt Complex. X‐Ray Crystal Structure of ((Ph3P)2(CO)Ir(μ‐H)(.mu±eta.2:η1‐CH=CH2)Pt(PPh3)2)+CF3SO‐ 3.
Authors: HUANG Y.‐H. , STANG P. J. , ARIF A. M. 
Published: May 2016

AbstractThe interaction of the Ir(I) triflate complex (I) with the π‐ethylene‐Pt(0) complex (II) results in C‐H activation and ready formation of the novel heterobimetallic title complex (III) which is characterized by IR and NMR spectroscopy.
ChemInform Abstract: A New Method for the Stereochemical Analysis of Acyclic Terpenoid Carbonyl Compounds.
Authors: KNIERZINGER A. , WALTHER W. , WEBER B. , MUELLER R. K. + , NETSCHER T. 
Published: May 2016

AbstractA new method is given for the determination of the enantiomeric and diastereomeric composition of terpenoid carbonyl compounds.
ChemInform Abstract: Steroidal Cyclobutanones. Part 1. Synthesis and Stereochemistry of Steroidal Spirocyclobutanones.
Authors: PARYZEK Z. , BLASZCZYK K. 
Published: May 2016

AbstractCycloaddition of dichloroketene derived from (II) to the 3‐methylene‐cholestane (I) affords the spirodichlorobutanones (III) and (IV).
ChemInform Abstract: Asymmetrically Substituted myo‐Inositol Derivatives. Part 34. Synthesis of Diastereomeric Acetates of β‐D‐Glucosyl‐myo‐inositol and Chiral Pentaacetates of myo‐Inositol.
Authors: SIBRIKOV YU. I. , STEPANOV A. E. , SHVETS V. I. 
Published: May 2016

AbstractThe diastereomeric glucosylinositols (III) and (IV) can be separated by chromatography.
ChemInform Abstract: Synthesis of 5′‐Chloro‐5′‐deoxythioinosine, Its Acyclic Analogue, and 9‐(2‐Tosyloxyethoxymethyl)guanine.
Authors: BELOZEROVA E. V. , RUDAKOVA I. P. , FILIPPOVA T. M. , YURKEVICH A. M. 
Published: May 2016

AbstractThioinosine (I) is coupled with thionyl chloride (II) to give the cyclic sulfite (III) which is converted to 5'‐chloro‐5'‐deoxythioinosine (IV) upon hydrolysis.
ChemInform Abstract: Synthesis and Properties of 5‐Hetera‐6‐oxoprostaglandins E1. Part 3. Synthesis of 5‐Aza‐6‐oxoprostaglandin E1 Derivatives.
Authors: LOZHA E. V. , LOLYA D. O. , FREIMANIS YA. F. , TUROVSKII I. V. , LIEPIN'SH E. E. , ROZITE S. KH. , SAKHARTOVA O. V. 
Published: May 2016

Abstract1,4‐Addition of the octenyllithium (I) to the amide (II) can be performed via cuprate complexes.
ChemInform Abstract: Mechanism of Material Removal from Silicon Carbide by Carbon Dioxide Laser Heating.
Authors: DEBASTIANI D. L. , MODEST M. F. , STUBICAN V. S. 
Published: May 2016

AbstractMaterial removal rates are measured as a function of laser power, scanning rate and gas assists (argon, air), and the chemical composition, microstructure and morphology of the phases present in and near the groove are studied (SEM, XRD, Raman spectroscopy, Auger analysis).
ChemInform Abstract: 1000 °C Phase Relations and Superconductivity in the (Nd‐Ce‐Cu)‐O Ternary System.
Authors: PIECZULEWSKI C. N. , KIRKPATRICK K. S. , MASON T. O. 
Published: May 2016

AbstractThe 1000 °C isothermal section of the NdO1.5‐CeO2‐CuO phase diagram contains only one ternary phase, Nd2‐xCexCuO4.
ChemInform Abstract: Chemical and Electrochemical Properties of Li+‐ and K+‐Implanted Glassy Carbons
Authors: TAKAHASHI K. , YOSHIDA K. , IWAKI M. 
Published: May 2016

Abstractare investigated in order to elucidate the reactivity of a chemically‐active element implanted in a chemically‐stable substrate and some characteristics of the modified GC.
ChemInform Abstract: Li/Li1+xV3O8 Secondary Batteries. Synthesis and Characterization of an Amorphous Form of the Cathode.
Authors: PISTOIA G. , PASQUALI M. , WANG G. , LI L. 
Published: May 2016

AbstractX‐ray amorphous Li1+xV3O8 powder is obtained from a solution of LiOH and V2O5 (∼50 °C, 24‐30 h).
ChemInform Abstract: Electrocatalysis of Anodic Oxygen‐Transfer Reactions. Activation of PbO2‐Film Electrodes in 1.0 M HClO4 by Addition of Bismuth(III) and Arsenic(III,V).
Authors: CHANG H. , JOHNSON D. C. 
Published: May 2016

AbstractThe electrocatalytic effect of the addition of Bi3+ to PbO2‐film electrodes is studied using the oxidation of DMSO in 1 M HClO4 as test reaction.
ChemInform Abstract: Synthesis of Monodispersed Spherical β‐Silicon Carbide Powder by a Sol‐Gel Process.
Authors: HATAKEYAMA F. , KANZAKI S. 
Published: May 2016

AbstractMonodispersed spherical β‐SiC powder is prepared by a sol‐gel process starting with a methanolic solution of PhSi(OEt)3 (I) and Si(OEt)4 (II) (67 mol% and 33 mol%, resp.) which is hydrolyzed by a 25% NH4OH aqueous solution.
ChemInform Abstract: Synthesis and Crystal Structure of Trichlorosulfonium Nonachlorodititanate(IV), (SCl3)(Ti2Cl9).
Authors: TROYANOV S. I. , RYBAKOV V. B. , TIMOSHCHENKO N. I. , FOKINA Z. A. 
Published: May 2016

AbstractProlonged treatment of TiCl4 (II) with a large excess of SCl2 (I) yields the novel ionic title compound (III).
ChemInform Abstract: A New Ambient‐Pressure Organic Superconductor, ϰ‐(ET)2Cu(N(CN)2)Br, with the Highest Transition Temperature Yet Observed (Inductive Onset Tc = 11.6 K, Resistive Onset = 12.5 K).
Authors: KINI A. M. , GEISER U. , WANG H. H. , CARLSON K. D. , WILLIAMS J. M. , KWOK W. K. , VANDERVOORT K. G. , THOMPSON J. E. , STUPKA D. L. , JUNG D. , WHANGBO M.‐H. 
Published: May 2016

AbstractThe title compound is obtained by in situ electrocrystallization of bis(ethylenedithio)tetrathiafulvalene (ET) by use of a 1:1 mixture of CuBr and tetraphenylphosphoniumdicyanamide.
ChemInform Abstract: Asymmetric Catalysis. Part 56. Enantioselective Hydrosilylation of Acetophenone with a Rhodium/Picolineoxazoline Catalyst 1:1.
Authors: BRUNNER H. , BRANDL P. 
Published: May 2016

AbstractThe direction of optical induction in the hydrosilylation of acetophenone (I) is inverted in going from an optically active pyridineoxazoline to a picolineoxazoline co‐catalyst.
ChemInform Abstract: Novel Cage Compounds from Inter‐ and Intramolecular Diels‐Alder Reactions of Heteroaromatic Azadienes and Methyl Coumalate with Cycloocta‐1,5‐diene.
Authors: LANTOS I. , SHELDRAKE P. W. , WELLS A. S. 
Published: May 2016

AbstractThe title reaction proceeds with extrusion of N2 or CO2, respectively, followed by a second Diels‐Alder reaction.
ChemInform Abstract: Unexpected cis Opening of Cyclopentadiene Monoepoxide with Lithium Acetylides and Dialkylalkynylalanes.
Authors: BRIGGS A. J. , WALKER K. A. M. 
Published: May 2016

AbstractThe epoxide (I) reacts with the lithium acetylides (II) to give the adducts (III) and (IV).
ChemInform Abstract: Utilization of PPh3‐Ti(IV) Reagents. An Efficient α′‐Alkylidenation of Cyclic Enones.
Authors: TAKANAMI T. , SUDA K. , OHMORI H. 
Published: May 2016

AbstractThe cycloalkenones (I) react with the aldehydes (II) in the presence of a triphenylphosphine/titanium(IV) catalyst system to yield regioselectively the condensation products (III).
ChemInform Abstract: Regioselective Formation of Fluorohydrins and Their Stereoselective Conversion to Fluoroolefins.
Authors: SUGA H. , HAMATANI T. , SCHLOSSER M. 
Published: May 2016

AbstractTosylated fluorohydrins such as (III) are obtained by HF addition to oxiranes such as (I) using the pyridine‐HF complex followed by tosylation.
ChemInform Abstract: Aromatic Tertiary Amines and n‐Butyl Nitrite.
Authors: VERARDO G. , GIUMANINI A. G. , STRAZZOLINI P. 
Published: May 2016

AbstractThe reaction between alkyl nitrites, particularly n‐butyl nitrite, and tertiary aromatic amines under a variety of experimental conditions yields products of N‐dealkylation‐N‐nitrosation, ring nitration, ipso‐substitution and, occasionally, combinations of these products.
ChemInform Abstract: (+)‐ and (‐)‐(2‐(1,3‐Dithianyl))myrtanylborane. Solid and Stable Monoalkylboranes for Asymmetric Hydroboration.
Authors: KIESGEN DE RICHTER R. , BONATO M. , FOLLET M. , KAMENKA J.‐M. 
Published: May 2016

AbstractOxidation of (+)‐pinene, followed by NaBH4 reduction, produces (+)‐myrtenol (II) which is converted into (+)‐myrtenyl bromide (III) by reaction with bromine in the presence of triphenylphosphine.
ChemInform Abstract: Chemistry of Sulfur‐Halogen Compounds. Part 37. Synthesis of CF3SSI, Vibrational Analyses for CF3SSX (X: F, Cl, Br, I, and H), and Gas‐Phase Structures of CF3SSF and CF3SSH.
Authors: MINKWITZ R. , LEKIES R. , LENNHOFF D. , SAWATZKI J. , KADEL J. , OBERHAMMER H. 
Published: May 2016

AbstractThe title iododisulfane is synthesized by reacting CF3SSH with N‐iodosuccinimide at ‐120 °C. Vibrational spectra are recorded to characterize its physical properties.
ChemInform Abstract: Preparation of the First Thione S‐Imides with Perfluoromethyl Groups by the Use of Sodium Hexamethyldisilazanide as a Mild Dehydrohalogenation Reagent.
Authors: MAY A. , ROESKY H. W. , STALKE D. , PAUER F. , SHELDRICK G. M. 
Published: May 2016

AbstractFrom the reaction of the sulfenyl chloride (I) with the monosilylated amines (II) the sulfenamides (III) are obtained.
ChemInform Abstract: Syntheses of Bicyclo(3.3.0)octanes via Bifurcating Radical Cyclization Pathways.
Authors: NAGAI M. , LAZOR J. , WILCOX C. S. 
Published: May 2016

AbstractThe radical cyclization pathway mentioned in the title converts the geminal dibromo dienes (I) or (IV) to the bicyclo(3.3.0)octanes (II) and (III) or (V) ‐ (VII).
ChemInform Abstract: Diastereoselectivity of Organometallic Additions to Nitrones Bearing Stereogenic N‐Substituents.
Authors: CHANG Z.‐Y. , COATES R. M. 
Published: May 2016

AbstractReaction of nitrones such as (III), prepared by coupling the hydroxylamine (II) with the aldehydes (I), with the Grignard compounds (IV) yields the disubstituted hydroxylamines (V) and (VI) with predominance of (V).
ChemInform Abstract: Epoxide Formation from Aldehydes and Ketones. A Modified Method for Preparing the Corey‐Chaykovsky Reagents.
Authors: NG J. S. 
Published: May 2016

AbstractThe aldehydes and ketones (I) are treated with trimethylsulfoxonium iodide (II) in the presence of potassium tert‐butoxide to form the oxiranes (III).
ChemInform Abstract: Stereoselective Hydroxyalkylations of (S)‐2‐Azetidinecarboxylic Acid.
Authors: SEEBACH D. , VETTIGER T. , MUELLER H.‐M. + , PLATTNER D. A. , PETTER W. 
Published: May 2016

AbstractThe stereoselective hydroxyalkylation of (S)‐2‐azetidinecarboxylic acid (I) is achieved via the bicyclic acetal (V).
ChemInform Abstract: The Conversion of an Aziridine to a β‐Lactam.
Authors: CHAMCHAANG W. , PINHAS A. R. 
Published: May 2016

AbstractThe aziridines (I) are cleaved with lithium iodide (II) to give the intermediate lithium amides (III) which are treated with nickel tetracarbonyl (IV) to produce the β‐lactams (V) after work‐up with iodine.
ChemInform Abstract: Menthol Mediated Optical Resolution of 10‐Oxatricyclodecadienones. Application in the Enantioselective Synthesis of Cyclopentenoids.
Authors: HOUWEN‐CLAASSEN A. A. M. , KLUNDER A. J. H. , ZWANENBURG B. , BEURSKENS P. T. , MOERS F. G. , BEURSKENS G. 
Published: May 2016

AbstractThe enantiomerically pure tricyclodecadienones (+)‐(VIII) and (‐)‐(IX) (yield not given) are synthesized starting from the known sulfone (I).
ChemInform Abstract: Reaction of Methyl 2,3‐Pentadienoate with Bromine. Preparation of 4‐Bromo‐5‐methyl‐5H‐furan‐2‐one.
Authors: FONT J. , GRACIA A. , DE MARCH P. 
Published: May 2016

AbstractTreatment of the dienoate (I) with bromine gives a mixture of the compounds (II)‐(V).
ChemInform Abstract: A Short, Efficient, Multigram Synthetic Route to 2,3‐Dimethylfuran and Some of Its 2‐Substituted Derivatives.
Authors: VEGH D. , ZALUPSKY P. , KOVAC J. 
Published: May 2016

AbstractCopper(II)‐mediated thermal cyclization of 3‐methyl‐2‐penten‐4‐yn‐1‐ol (I) produces optimum yields of 2,3‐dimethylfuran (II).
ChemInform Abstract: Potentially CNS‐Active Tricyclic Compounds with Bridged Central Ring. Part 3. Synthesis of Partially Hydrogenated 9,10‐Epithioanthracenes.
Authors: LINDE H. F. G. , KRAEMER N. H. + 
Published: May 2016

AbstractIsobenzothiophene (I) undergoes cycloaddition reaction with p‐benzoquinone (II) to give the epithioanthracene (III) and the diepithiodecahydropentacene (IV).
ChemInform Abstract: Acylation of Pyrrolidine‐2,4‐diones: A Synthesis of 3‐Acyltetramic Acids. X‐Ray Molecular Structure of 3‐(1‐(Difluoroboryloxy)ethylidene)‐5‐isopropyl‐1‐methylpyrrolidine‐2,4‐dione.
Authors: JONES R. C. F. , BEGLEY M. J. , PETERSON G. E. , SUMARIA S. 
Published: May 2016

AbstractA series of tetramic acids, e.g. (I), is prepared, mostly by conventional methods.
ChemInform Abstract: Stereospecificity in Fe(CO)5‐Induced Reactions of Divinylpyrrolidines.
Authors: LASSALLE G. , GREE R. 
Published: May 2016

AbstractThe 1,2,5‐triphenyl‐3,4‐cis‐divinylpyrrolidine (I) reacts with iron pentacarbonyl (II) to give the triphenyldiethylpyrrole (III) and the vinylpyrroline (IV).
ChemInform Abstract: Electrophilic Olefin Heterocyclization in Organic Synthesis. Highly Stereoselective Synthesis of trans‐3,5‐Disubstituted Pyrrolidin‐2‐ones by Iodolactamization via Homoallylic Asymmetric Induction.
Authors: TAKAHATA H. , TAKAMATSU T. , CHEN Y.‐S. , OHKUBO N. , YAMAZAKI T. , MOMOSE T. , DATE T. 
Published: May 2016

AbstractThe base‐catalyzed reaction of the thioamides (I) with allyl bromide (II) yields the derivatives (III) which are converted to the γ,δ‐unsaturated thioimidates (V).
ChemInform Abstract: Zeolites as Catalysts in the Fischer Indole Synthesis. Enhanced Regioselectivity for Unsymmetrical Ketone Substrates.
Authors: PROCHAZKA M. P. , EKLUND L. , CARLSON R. 
Published: May 2016

AbstractThe indole synthesis is studied for five ketone substrates (2‐hexanone and (II)) with 14 different zeolites (a total of 112 different systems).
ChemInform Abstract: Intramolecular Alkylations of Aromatic Compounds. Part 29. Synthesis and Assignment of Absolute Configuration of 1‐Acetylindoline‐3‐carboxylic Acid.
Authors: REIMANN E. , HASSLER T. , LOTTER H. 
Published: May 2016

AbstractThe carboxylation of indole (I) with ethyl chloroformate (II) yields a mixture of the regioisomeric indolecarboxylates (III) and (IV).
ChemInform Abstract: An Improved Synthesis of 2‐(β‐Bromoethyl)‐2‐methyl‐1,3‐dioxolane, a Useful Methyl Vinyl Ketone Equivalent.
Authors: HSUNG R. P. 
Published: May 2016

AbstractThe enones (I) are consecutively treated with bromotrimethylsilane and ethylene glycol (II) in the presence of p‐toluenesulfonic acid to yield the 2‐(β‐bromoethyl)‐1,3‐dioxolanes (III).
ChemInform Abstract: Cyclocondensation of 2‐Lithiomethylthiazoles and 2‐Lithiomethylthiazoline with α‐Oxoketene Dithioacetals: Synthesis of Substituted and Anellated Thiazolo‐ and Dihydrothiazolo(3,2‐a)pyridinium Compounds.
Authors: THOMAS A. , ILA H. , JUNJAPPA H. 
Published: May 2016

AbstractRegioselective 1,2‐addition of the in situ prepared Li species (II) with the dithioacetals (Ia), (Ib) or (VII) and (IX) gives carbinol acetals (cf.
ChemInform Abstract: Synthesis of 2,4‐Dialkoxy‐6‐(trifluoromethyl)‐3,5‐pyridinedicarboxylates via a Novel Cyclocondensation of Dialkyl 3‐Oxopentanedioates with Trifluoroacetonitrile.
Authors: LEE L. F. , NORMANSELL J. E. 
Published: May 2016

AbstractReaction of the acetonedicarboxylates (I) with the trifluoroacetonitrile (II) in the presence of potassium butoxide gives the dihydroxypyridines (III) which are O‐alkylated with the alkyl iodides (IV) to produce the pyridones (V), together with the dialkoxypyridines (VI).
ChemInform Abstract: Efficient Preparative Routes to 6,6′‐Dibromo‐2,2′‐bipyridine and 6‐Bromo‐2,2′‐bipyridine.
Authors: GARBER T. , RILLEMA D. P. 
Published: May 2016

AbstractThe key step in the preparation of the title compounds (VI) and (VII) is the oxidative coupling reaction of the pyridyl cuprate (V).
ChemInform Abstract: Synthesis and Biological Activity of Some New 1‐Aryl‐3‐benzoxazinyldihydropyrimidinediones.
Authors: RAM B. , SINGH A. N. , CHATURVEDI S. C. , SASTRY C. V. R. 
Published: May 2016

AbstractEleven title compounds are prepared according to the reaction sequence shown in the scheme.
ChemInform Abstract: A New and Expeditious Synthesis of 5H‐Pyrrolo(1,2‐b)(2)benzazepine Derivatives.
Authors: CORELLI F. , GAROFALO A. , MASSA S. , ARTICO M. 
Published: May 2016

AbstractThe 2‐acylpyrroles (II) are treated with excess α,α'‐dichloro‐o‐xylene (I) to form predominantly the monosubstituted products (III).
ChemInform Abstract: Introduction of Some Pharmaceutically Active Heterocycles into the Benzylic Moiety of 2‐Benzyl‐1,3‐indandione.
Authors: AFSAH E. M. , HAMMOUDA M. , ZOOROB H. , KHALIFA M. M. , ZIMAITY M. 
Published: May 2016

AbstractMichael addition of the active methylene compounds (II) or thiophenol (X) to the benzylideneindandione (I) gives the corresponding adducts (III) and (XI).
ChemInform Abstract: Abiotic Anion Receptor Functions. A Facile and Dependable Access to Chiral Guanidinium Anchor Groups.
Authors: KURZMEIER H. , SCHMIDTCHEN F. P. 
Published: May 2016

AbstractThe double cyclization reaction of the thiourea (I), obtained by a multi‐step procedure from the chiral amino acids asparagine and methionine, yields the guanidine (II) as a diastereomeric mixture.
ChemInform Abstract: Phenylselenofluorination of Acid‐Sensitive Alkenes.
Authors: SALUZZO C. , ALVERNHE G. , ANKER D. , HAUFE G. 
Published: May 2016

AbstractStable alkenes such as (I), (IV), and (VI) as well as the alkenes (VIII) and (X), which are sensitive to acids, undergo phenylselenofluorination to yield regioselectively the products outlined in the reaction scheme.
ChemInform Abstract: Synthesis of Group 13 Element Metallacarboranes and Related Structure‐Reactivity Correlations.
Authors: SCHUBERT D. M. , BANDMAN M. A. , REES W. S. JUN. , KNOBLER C. B. , LU P. , NAM W. , HAWTHORNE M. F. 
Published: May 2016

AbstractThe known icosahedral aluminacarborane (I), obtained from nido‐7,8‐C2B9H13, reacts with Lewis bases to form bis adducts with a bonding formalism considered to utilize a single hybrid orbital for endo bonding with the η1‐dicarbollide cage.
ChemInform Abstract: Metal Trifluorophosphine Complexes. Part 51. Hexakis(trifluorophosphine)vanadium(0) ‐ Synthesis, Chemical Properties, and Reactions.
Authors: COLLONG W. , KRUCK T. 
Published: May 2016

AbstractTreating the vanadate(‐I) (I) with (PhN2)+ leads via the expected redox reaction to formation and isolation of the highly volatile, paramagnetic title compound (II), while on reaction of (I) with cycloheptatrienylium tetrafluoroborate only the cation is exchanged.
ChemInform Abstract: Tungsten(VI) Complexes as New Products in the High‐Intensity Photolysis of Octacyanotungstate(V) Ion in Hydroxylic Solvents; Crystal Structure of (PPh4)2(W(CN)6O)·H2O and (PPh4)2(W(CN)5O(OMe)).
Authors: SIEKLUCKA B. , ALCOCK N. W. , KEMP T. J. , STUFKENS D. J. 
Published: May 2016

AbstractIrradiation of K3(W(CN)8) under high light intensities leads in water to the oxo‐W(VI) complexation of (Ia), while in water‐methanol (1:1) the oxo(methoxo)‐Mo(VI) complexation of (Ib) is formed on standing after photolysis.
ChemInform Abstract: Synthesis and Redox Reactivity of the Thermally Unstable Mixed‐Metal Arachno Cluster Fe2(CO)6(μ3‐S)2Cu(η5‐Cp*).
Authors: DON M.‐J. , RICHMOND M. G. 
Published: May 2016

AbstractThe solvated Cu complex (II) is an excellent low‐temp.
ChemInform Abstract: Synthesis, Molecular Structure and Magnetic Properties of (Cu2L(μ‐OH)CH3CN)2(Cu6I10) and (Cu2L(μ‐Br))Br2, Where L: 2,6‐Bis(N‐(2‐dimethylaminoethyl)formimidoyl)‐4‐methylphenolato.
Authors: FIRMIN D. A. , QUILANO E. R. , CAMERON R. , PANT A. K. , STEVENS E. D. , O'CONNOR C. J. , KAHN O. , MALLAH T. 
Published: May 2016

AbstractBoth the title complexes (I) (space group P1, Z=2) and (II) (Pbca, Z = 8) are synthesized by template reactions and characterized by X‐ray structure analysis.
ChemInform Abstract: Syntheses and Reactivity of Acetylide‐Containing Clusters of Group 1B Metals. Part 8. Preparation, Characterization and Possible Structure of a Novel Pentanuclear Trimetallic Cluster (Au3AgCu(C2Ph)6)‐. Reactions of Pentanuclear and Trinuclear Acetylide Complexes.
Authors: ABU‐SALAH O. M. , AL‐OHALY A. R. A. , MUTTER Z. F. 
Published: May 2016

AbstractDuring the studies on the possible formation of high polynuclearity clusters when starting with the pentanuclear Au3Cu2 phenylacetylide complex, its reaction with a mixture of polymeric gold and silver acetylide affords the trimetallic title cluster in 56% yield, whose possible structure is discussed.
ChemInform Abstract: Fixation of Hydrazines and Hydrazones to Trinuclear Ruthenium Clusters: Synthesis and Molecular Structure of (μ2‐H)Ru3(CO)9(μ3‐NH‐NH2).
Authors: JENKE T. , STOECKLI‐EVANS H. , SUESS‐FINK G. + 
Published: May 2016

AbstractHydrazines and hydrazones such as (II) and (IV) react thermally with Ru3(CO)12 (I) with fixation of the intact N‐N unit as a μ3‐bridging ligand to give products of the type (III) and (V).
ChemInform Abstract: Dimethylselenide Substituted Mixed Metal Clusters: Synthesis and Crystal Structures of (HRuCo3(CO)11(SeMe2)), (HRuCo3(CO)10(SeMe2)2) and (HRuRh3(CO)9)2(SeMe2)3.
Authors: ROSSI S. , PURSIAINEN J. , AHLGREN M. , PAKKANEN T. A. 
Published: May 2016

AbstractThe dimethyl selenide ligands coordinate terminally as two‐electron donors on basal cobalt atoms in the case of (III) (space group P21/n, Z=4) and (IV) (P1, Z=2), and as a bridging four‐electron donor in (VI) (R3c, Z=2).