bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: 3‐Amino‐1H‐pyrazolo(5,4‐d)pyrimidines and 3‐Amino‐isothiazolo(5.4‐d)pyrimidines as Precursors of Tricyclic Heteroaromatic Systems Containing a Bridgehead Nitrogen Atom.
Authors: GOLEC J. M. C. , SCROWSTON R. M. 
Published: May 2016

AbstractThe reaction of the compounds (I) and (VI) with the ketones (II), (IV) and (VIII) yields the title heteroaromatic systems (III), (V), (VII) and (IX).
ChemInform Abstract: Characterization and Toxicity of Lanthanoid Complexes with Nitrogen‐ and Sulfur‐Containing Schiff Bases.
Authors: SIDDIQI K. S. , KURESHY R. I. , KHAN N. H. , TABASSUM S. , ZAIDI S. A. A. 
Published: May 2016

AbstractThe eight‐coordinate lanthanoid complexes (I) are prepared by 1:3 molar reaction of corresponding lanthanoid chlorides with the Schiff bases from sulfamethoxazole and salicylaldehyde or thiophene‐2‐aldehyde in ethanol.
ChemInform Abstract: Dramatic Acceleration of the Diels‐Alder Reaction by Adsorption on Chromatography Adsorbents.
Authors: VESELOVSKY V. V. , GYBIN A. S. , LOZANOVA A. V. , MOISEENKOV A. M. , SMIT W. A. , CAPLE R. 
Published: May 2016

AbstractThe cycloadducts (III) and (V) are prepared by Diels‐Alder reaction of the α,β‐unsaturated carbonyl compounds (I) with cyclopentadiene (II) or from (Ia) or (Ic) and ethyl vinyl ether (IV), using dry state adsorption conditions.
ChemInform Abstract: Low Coordinated Phosphorus Compounds. Part 62. Valence Isomerization of λ3‐Monophosphahexadienes and λ3‐Monophosphahexenynes.
Authors: APPEL R. , KOCHTA J. , WINKHAUS V. 
Published: May 2016

Abstract(3,3')‐Phospha‐carbon Cope rearrangements, hitherto known from tetraand diphosphahexadienes, are observed for the first time with monophosphahexadienes (III) and a monophosphahexenyne (VII).
ChemInform Abstract: Photochemical Studies. Part 30. Unusual Photorearrangements of Homoconjugated Diacylcyclohexa‐2,4‐dienes.
Authors: OREN J. , SCHLEIFER L. , WEINMAN S. , FUCHS B. 
Published: May 2016

AbstractPhotolysis of the substituted dihydroindans (II), synthesized from the carboxylic anhydride (I), results in rearrangement processes, yielding the tricyclononene (III), or the all‐cis‐cyclononatrienes (IV) and (V).
ChemInform Abstract: Reactions of Imidazole‐2‐thiones with Molecular Iodine and the Structures of Two Crystalline Modifications of the 1:1 1,3‐Dimethylimidazole‐2‐thione‐Diiodine Charge‐Transfer Complex (C5H8I2N2S).
Authors: FREEMAN F. , ZILLER J. W. , PO H. N. , KEINDL M. C. 
Published: May 2016

AbstractImidazole‐2‐thione, 1‐methyl‐, and 1,3‐dimethylimidazole‐2‐thione (I) react with I2 to give 1:1 CT complexes (UV/VIS).
ChemInform Abstract: Pentacoordinated Molecules. Part 73. Square‐Pyramidal and Trigonal‐Bipyramidal Anionic (Ethanedithiolato)stannates. Binuclear Centers with Tin‐Sulfur Bonding.
Authors: HOLMES R. R. , SHAFIEEZAD S. , HOLMES J. M. , DAY R. O. 
Published: May 2016

AbstractThe first anionic five‐coordinate Sn compounds (I), (II), and (V) are formed from the reaction of alkyl‐ or aryltin trichlorides and tetraethylammonium chloride in acetone with sodium ethane‐1,2‐dithiolate (generated in methanol) and from partial hydrolysis of bis(ethane‐1,2‐dithiolato)‐Sn (III) in the presence of the amine bases L (IV).
ChemInform Abstract: Structure and Reactivity of Stannylated Propylamines and Propyl Sulfides. Crystal and Molecular Structure of Bis(3‐chlorodimethylstannylpropyl)sulfide S(CH2CH2CH2SnMe2Cl)2.
Authors: JURKSCHAT K. , SCHMID B. , DYBIONA M. , BAUMEISTER U. , HARTUNG H. , TZSCHACH A. 
Published: May 2016

AbstractThe reactions of the stannylated propylamines (IIIa), (IIIb) and the propyl sulfide (IIIc) with 2 equiv. dichlorodimethylstannane (V) lead to the azastannacycloalkanes (IV), (VI) and to the binuclear product (VII) (space group Pna21, Z=4), respectively.
ChemInform Abstract: Formation and the Magnetic Properties of the Compound Nd2Fe14C.
Authors: BUSCHOW K. H. J. , DE MOOIJ D. B. , DENISSEN C. J. M. 
Published: May 2016

AbstractThe title compound is prepared by arc melting of the elements and subsequent annealing of the as‐cast alloy in a narrow temp. range below 890 °C (∼ 830‐880 °C).
ChemInform Abstract: Reactivity of Monothio‐ and Monoselenoacetals Towards Oxidation in the Synthesis of Substituted 2,3‐Dihydrofurans.
Authors: BRUNETIERE A. P. , LALLEMAND J.‐Y. 
Published: May 2016

AbstractThe butyrolactone (I) is reduced with diisobutylaluminum hydride and then treated with thio‐ or selenophenol (II) to give the substitution products (III).
ChemInform Abstract: 9,10‐Dicyanoanthracene‐Sensitized NO Insertion into the Cyclopropane Ring via Photoinduced Electron Transfer.
Authors: ICHINOSE N. , MIZUNO K. , YOSHIDA K. , OTSUJI Y. 
Published: May 2016

Abstract1,2‐Diarylcyclopropanes such as (Ia), (Ib), (Id), and (Ie) with electron donating aryl substituents undergo sensitized photoreaction with NO (II) in the presence of 9,10‐dicyanoanthracene to form the 2‐isoxazolines (III).
ChemInform Abstract: Studies in Medicinal Plants. Part 16. New Xanthone from Hypericum mysorense Heyne.
Authors: BALACHANDRAN S. , VISHWAKARMA R. A. , POPLI S. P. , KAPIL R. S. 
Published: May 2016

AbstractThe xanthone (III) is isolated together with seven known xanthones from the antifungal fraction of the title species.
ChemInform Abstract: Removal of N‐Arylsulfonyl Groups from Hydroxy α‐Amino Acids.
Authors: ROEMMELE R. C. , RAPOPORT H. 
Published: May 2016

AbstractIn order to convert the N‐(arylsulfonyl)threonines (I) into threonine (II), three specific reductive methods are compared, namely, sodium in liquid ammonia, HBr in acetic acid, and electrolysis.
ChemInform Abstract: Synthesis of (S)‐(+)‐Cryptone.
Authors: MANCINI I. , GUELLA G. , PIETRA F. 
Published: May 2016

AbstractThe title compound (VII) can be prepared from commercially available (R)‐(+)‐p‐menthene (I) with 27% overall yield and ca. 70% e.e.
ChemInform Abstract: Spectroscopic (IR, UV‐VIS, 1H and 119Sn NMR, Resonance Raman) Properties of ((C6H5)3EM(CO)3(α‐diimine)) (M: Mn, E: Ge, Sn, Pb; M: Re, E: Sn) Complexes and X‐Ray Structure of ((C6H5)3SnMn(CO)3(tBu‐DAB)).
Authors: ANDREA R. R. , DE LANGE W. G. J. , STUFKENS D. J. , OSKAM A. 
Published: May 2016

AbstractIn order to get more insight into the electronic structures of the complexes (I) their spectroscopic properties are discussed and a comparison is made with the parent compounds Ph3EM(CO)5 for which a qualitative MO diagram is given.
ChemInform Abstract: First Experimental Evaluation of Hypervalent N‐S‐N Bond Energy from the Restricted Rotation of Pyrimidine Ring in 10‐S‐3 Sulfuranes (I).
Authors: AKIBA K. , OHSUGI M. , IWASAKI H. , OHKATA K. 
Published: May 2016

Abstract1H NMR line‐shape analysis of the methyl signals in (Ia) (coalesces at 45 °C; heteroaromatic peaks remain unchanged between 28‐58 °C) affords k = 8.6 s‐1and ΔG‡ = 16.6.
ChemInform Abstract: Synthesis and Biological Activity of 5(6)‐Amido‐ and 5(6)‐Amino‐2‐arylbenzimidazole Derivatives.
Authors: SKLYAROVA I. V. , KUZNETSOV V. A. , SOKOLOVA N. YU. , GARABADZHIU A. V. , GINZBURG O. F. , DOBRYNIN YA. V. , NIKOLAEVA T. G. , FIN'KO V. E. 
Published: May 2016

Abstracto‐Diaminobenzenes, prepared in situ from the corresponding nitroalinines (I), are coupled with the carboximidate (II) to give the benzimidazoles (III).
ChemInform Abstract: Simple Phenylnitrones and Their Transformation into Substituted Isoxazolidines.
Authors: ZELENIN K. N. , BEZHAN I. P. , ERSHOV A. YU. 
Published: May 2016

AbstractThe carbonyl compounds (I) react with phenylhydroxylamine (II) to give the nitrones (III) which dimerize upon standing, producing the isoxazolidines (IV).
ChemInform Abstract: Di‐ and Trinuclear Complexes of Palladium(II) Containing Doubly‐ and Triply‐Bridging Pyridine‐2‐thionato (pyS) Ligands: Crystal Structure of (Pd3(C6H4CH2NMe2)3(pyS)2) (BF4).
Authors: DEEMING A. J. , MEAH M. N. , BATES P. A. , HURSTHOUSE M. B. 
Published: May 2016

AbstractThe chloride‐bridged Pd dimer (I) reacts with the 1H‐pyridine‐2‐thiones (II) as shown to generate the dinuclear complexes (III).
ChemInform Abstract: Enantioselective Ring Cleavage of meso‐Epoxides with B‐Halodiisopinocampheylboranes.
Authors: JOSHI N. N. , SREBNIK M. , BROWN H. C. 
Published: May 2016

AbstractThe enantioselective ring opening reaction of the meso‐epoxides (I), (III), (VI), (VIII) using the B‐iododiisopinocampheylborane (V) leads to the optically active 1,2‐halohydrins (II), (IV), (VII), (IX).
ChemInform Abstract: Dicobalt Octacarbonyl Catalyzed Conversion of Benzylic Alcohols to Thiols, Hydrocarbons, and Esters Using Hydrogen Sulfide and Carbon Monoxide.
Authors: ALPER H. , SIBTAIN F. 
Published: May 2016

AbstractThe benzylic alcohols (I) react with hydrogen sulfide and carbon monoxide in the presence of dicobalt octacarbonyl to form the thiols (II) and the hydrocarbons (III) as the main products.
ChemInform Abstract: Regio‐ and Stereoselective C‐Alkylation of Enamines Derived from 2‐Methyl‐1,3‐cyclopentanedione in the Presence of Strong Bases.
Authors: LAKHVICH F. A. , LIS L. G. , PAP A. A. 
Published: May 2016

AbstractThe stereo‐ and regioselectivity of the alkylation of the enamine (III) derived from the cyclopentane dione (II) is investigated.
ChemInform Abstract: Conversion of 2‐Arylmethylene‐3‐indolinones to 4‐(2‐Acetylaminobenzoyl)‐5‐aryl‐1,2,3‐triazoles.
Authors: VELEZHEVA V. S. , MARSHAKOV V. YU. , MEL'MAN A. I. , KURKOVSKAYA L. N. , SUVOROV N. N. 
Published: May 2016

AbstractCondensation of the indolinone (I) with the aromatic aldehydes (II) affords the 2‐arylidene derivatives (III).
ChemInform Abstract: The 5‐Hydroxy‐1,2,3‐oxadiazolinium Ion: Neighboring Group Interaction Between N‐Nitroso and Aldehyde Carbonyl.
Authors: LOEPPKY R. N. , FLEISCHMANN E. D. , ADAMS J. E. , TOMASIK W. , SCHLEMPER E. O. , WONG T. C. 
Published: May 2016

AbstractA set of MNDO calculations performed on (I) and (II) to explore possible neighboring group interactions demonstrates the formation of the stable cation (III) from the protonated aldehyde (IIa).
ChemInform Abstract: Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 79. Synthesis and Reactions of the Alkylidynemetal Complexes (M(CR)(CO)2(η‐C5H5)) (R: C6H3Me2‐2,6, M: Cr, Mo, or W; R: C6H4Me‐2, C6H4OMe‐2, or C6H4NMe2‐4, M: Mo); Crystal Structure of the Compound (MoFe(μ‐CC6H3Me2‐2,6)(CO)5(η‐C5H5)).
Authors: DOSSETT S. J. , HILL A. F. , JEFFERY J. C. , MARKEN F. , SHERWOOD P. , STONE F. G. A. 
Published: May 2016

AbstractIn order to define more precisely the effect of the aryl group in substituted methylidyne metal complexes of type (I), the compounds (Ia)‐(If) (where the predominantly used p‐tolyl substituent is replaced by electronically and sterically different aryl groups) are prepared in yields of 60‐80% by the extension of known procedures.
ChemInform Abstract: Preparation of an Oxoperoxocyanomolybdate(VI) Complex by Dioxygen Oxidation of an Oxocyanomolybdate(IV) Anion. Structure and Reactivity Toward Phosphines and Olefins.
Authors: ARZOUMANIAN H. , PETRIGNANI J.‐F. , PIERROT M. , RIDOUANE F. , SANCHEZ J. 
Published: May 2016

AbstractThe oxopentacyanomolybdate(IV) (III) is prepared by controlled hydrolysis of the octacyanomolybdate (I).
ChemInform Abstract: Bis((pentamethylcyclopentadienyl)metal)pentalenes. A New Class of Highly Delocalized, Fused Metallocenes.
Authors: BUNEL E. E. , VALLE L. , JONES N. L. , CARROLL P. J. , BARRA C. , GONZALEZ M. , MUNOZ N. , VISCONTI G. , AIZMAN A. , MANRIQUEZ J. M. 
Published: May 2016

AbstractThe air‐sensitive title compounds (IV) are prepared in a one‐pot procedure as outlined in the scheme.
ChemInform Abstract: Stereoselective Formation of a Steroidal 20‐Hydroxy‐24‐oic Lactone by a Novel Reaction of Dichloro Ketene with an Epoxy Olefin.
Authors: RAMESH U. , WARD D. , REUSCH W. 
Published: May 2016

AbstractReaction of the pregnene derivative (I) with dichloro ketene (II), generated in situ from the trichloroacetyl chloride and zinc dust, leads unexpectedly to the formation of the dichloro lactone (III) which is reduced to the monochloro derivative (IV).
ChemInform Abstract: 2‐Benzoyl‐4‐substituted‐phenyl‐5‐phenylthiazoles.
Authors: KULKARNI R. A. , THAKER S. R. 
Published: May 2016

AbstractThe α‐bromodeoxybenzoins (I) are cyclized with the thioamide (II) to give the thiazoles (III).
ChemInform Abstract: Reaction of Tosylamide Monosodium Salt with Bis(halomethyl) Compounds: An Easy Entry to Symmetrical N‐Tosyl Aza Macrocycles.
Authors: BOTTINO F. , DI GRAZIA M. , FINOCCHIARO P. , FRONCZEK F. R. , MAMO A. , PAPPALARDO S. 
Published: May 2016

AbstractThe 1,ω‐dihalooxaalkanes (I) react with the tosylamide monosodium salt (II) in DMF to give the cyclic products (III).
ChemInform Abstract: Nitrogen Atom Activation: The Influence of Porphyrin Ring Structure on the Kinetics of the Reaction of Trifluoroacetic Anhydride with Nitrido Manganese(V) Porphyrins.
Authors: BOTTOMLEY L. A. , NEELY F. L. 
Published: May 2016

AbstractThe kinetics of the reactions of (I) (and 6 other phenyl‐substituted analogues), (II) and (III) with trifluoroacetic anhydride and of (II) with trifluoro‐, trichloro‐, dichloro‐, monochloro‐ and unsubstituted acetic anhyride to form the corresponding nitrenoid Mn porphyrin complex are determined under pseudo‐first‐order conditions.
ChemInform Abstract: 3‐ and 3,6‐Silylated 2‐Pyridinethiols: New Bulky Bidentate Ligands and Their Silver and Copper Clusters.
Authors: BLOCK E. , GERNON M. , KANG H. , ZUBIETA J. 
Published: May 2016

AbstractThe mono‐ and disilylated pyridinethiols (I) and (V) are prepared by the one‐pot reaction of pyridinethiol (III) with LDA and addition of the corresponding chlorosilanes (II) or (IV) depending on the silane substituents.
ChemInform Abstract: Friedel‐Crafts Alkylation of Pyrene in Carbon Disulfide; 1H NMR Spectroscopy of Pyrene Derivatives.
Authors: RODENBURG L. , DE BLOCK R. , ERKELENS C. , LUGTENBURG J. , CORNELISSE J. 
Published: May 2016

AbstractWhereas 2,5‐dichloro‐ and 2,5‐diiodohexane lead to products not identified to be pyrene derivatives, compounds (I) yield cleanly (III).
ChemInform Abstract: Alkyl 2‐Methyldithiocarbazates in Heterocyclic Synthesis: Preparation of 2‐Alkylthio‐1,3,4‐thiadiazolium Cations and 2‐Thioxo‐2,3‐dihydro‐1,3,4‐oxadiazole Derivatives.
Authors: MOLINA P. , TARRAGA A. , ESPINOSA A. 
Published: May 2016

AbstractAcylation of the 2‐methyldithiocarbazates (I) gives the 3‐acyl derivatives (III) which cyclize upon treatment with perchloric acid and acetic anhydride, forming the 1,3,4‐thiadiazolium salts (IV).
ChemInform Abstract: Preparation and Properties of Novel Sulfur Heterocycles from the Reaction of 4,5‐Disubstituted 2‐Lithio‐1,3‐dithioles with Carbon Disulfide and X‐Ray Crystallographic Structure of 2‐(4,5‐Dimethyl‐1,3‐dithiolylidene)‐5,6‐dimethyl‐2,3‐dihydro‐1,4‐dithiine‐3‐thione.
Authors: MORADPOUR A. , BITTNER S. , BERNSTEIN J. , SARMA J. A. R. P. 
Published: May 2016

AbstractThe reaction of the respective 2‐lithio derivatives from the dithioles (I) with CS2 (II) followed by treatment with ethyl chloroformate (or MeI) produces a new type (III) of heterocyclic system.
ChemInform Abstract: 2‐(2‐Aryl‐2‐oxoethylidene)‐1,2,3,4‐tetrahydropyridines. Novel Isomers of 1,4‐Dihydropyridine Calcium Channel Blockers.
Authors: TAYLOR M. D. , BADGER E. W. , STEFFEN R. P. , HALEEN S. J. , PUGSLEY T. A. , SHIH Y. H. , WEISHAAR R. E. 
Published: May 2016

AbstractTetrahydropyridine derivatives such as (IV), (VI), and (IX) are prepared using the Hantzsch dihydropyridine synthesis.
ChemInform Abstract: Synthesis and Characterization of New Adducts of Cobalt Bis(2,4‐pentanedionate). Molecular Structure of a Cis Complex: Cobalt Bis(2,4‐pentanedionate) N,N,N′,N′‐Tetraethyl‐1,2‐diaminoethane.
Authors: COLBORN R. E. , GARBAUSKAS M. F. , HEJNA C. I. 
Published: May 2016

AbstractBis(acetylacetonato)‐Co (I) reacts with a variety of bidentate ligands such as (II) to give nearly octahedral 1:1 adducts which are characterized spectroscopically.
ChemInform Abstract: Trimethylamine Oxide Induced Decarbonylation of M(CO)2Cl2(PPh3)2 (M: Ru, Os) Complexes.
Authors: FOLEY B. L. , SMITH C. A. , THOMAS N. C. 
Published: May 2016

AbstractThe title dicarbonyl complexes (I) are monodecarbonylated by 0.5 equiv. trimethylamine oxide in the presence of phenanthroline (II) to give the cationic complexes (III) isolated as their hexafluorophosphates.
ChemInform Abstract: Electron Spin Resonance and Electron Spin Echo Spectroscopic Studies of Cu2+ Sites in Synthetic Cancrinite Zeolites.
Authors: RAGHUNATHAN P. , KEVAN L. 
Published: May 2016

AbstractCu2+ is introduced (ion exchange) into the synthetic cancrinite zeolites Na6Al6Si6O24·8 H2O (I) and Na6Al6Si6O24·CaCO3·8 H2O (II).
ChemInform Abstract: Photochemistry of Cyclopropene Derivatives. Intramolecular Hydrogen Transfer Reaction of Some 1‐(Alkyl‐Substituted) Cyclopropenes.
Authors: PADWA A. , CHOU C. S. , ROSENTHAL R. J. , TERRY L. W. 
Published: May 2016

AbstractThe thioxanthone triplet‐sensitized photoirradiation of the cyclopropenes (I) or (III) gives either spirocyclopropanes such as (II) or cyclopropanes such as (IV) due to intramolecular hydrogen transfer.
ChemInform Abstract: Stereochemical Behavior of Intermediary Compounds in the Amine‐Catalyzed Knoevenagel Reaction.
Authors: TANIKAGA R. , KONYA N. , HAMAMURA K. , KAJI A. 
Published: May 2016

AbstractKnoevenagel reaction of the methylene compounds (I) and the aldehydes (II) in the presence of a secondary amine produces the thermodynamically stable alkenes (III).
ChemInform Abstract: Synthesis of Diperoxy Ketals from 5,5,6‐Trimethylbicyclo(2.2.1)heptan‐2‐one.
Authors: YUVCHENKO A. P. , BERESNEVICH L. B. , ZHUKOVSKAYA N. A. , KOZLOV N. G. , MOISEICHUK K. L. , OL'DEKOP YU. A. 
Published: May 2016

AbstractThe novel title compounds (III), (V), (VI) and (VII) are prepared starting from the bicyclic ketone (I) specified in title and the corresponding peroxides.
ChemInform Abstract: New Synthetic Approaches to Cyclopenta(a)phenanthrenes and Their Carcinogenic Derivatives.
Authors: LEE H. , HARVEY R. G. 
Published: May 2016

AbstractThe naphthylalkyl iodides (I) are coupled with the bromomagnesium enamide (II), obtained from cyclopentenylcyclohexylamine and ethylmagnesium bromide, yielding the adducts (III).
ChemInform Abstract: Phosphonylation of Biomolecules with Inorganic Diphosphonate. Part 2. Phosphonylation of Phosphate Groups on Nucleoside 5′‐Monophosphates, Deoxynucleoside 5′‐Monophosphates, and Sugar Phosphates.
Authors: YAMAMOTO Y. , BABA Y. , MIZOKUCHI M. , ONOE M. , SUMIYAMA T. , TSUHAKO M. , YOZA N. , OHASHI S. 
Published: May 2016

AbstractNa2P2H2O5 is used to phosphonylate a variety of nucleoside 5'‐monophosphates such as AMP, GMP, IMP, CMP and UMP as well as deoxynucleoside 5'‐monophosphates (dAMP, dTMP) and sugar phosphates (Glc1P, Glc6P, Rib5P) in aqueous solutions under mild conditions (50‐70 °C, pH 6).
ChemInform Abstract: Intramolecular Cyclization of Allyl‐ and Propargylsilanes. The Regio‐and Stereochemical Outcome of the Cyclization.
Authors: SCHINZER D. , DETTMER G. , RUPPELT M. , SOLYOM S. , STEFFEN J. 
Published: May 2016

AbstractSilylalkynylcyclohexanones such as (III) and (V) are prepared from cyclohexenones and organometallic compounds.
ChemInform Abstract: Variable Coordination Numbers in Crystalline Bis(pentamethylcyclopentadienyl)samarium Oxide, Iodide and Alkoxide Complexes.
Authors: EVANS W. J. , DRUMMOND D. K. , HUGHES L. A. , ZHANG H. , ATWOOD J. L. 
Published: May 2016

AbstractThe three crystallographically characterized complexes (I), (IV), and (VII) on recrystallization under appropriate conditions give the complexes (III), (VI), and (IX), respectively, which have a coordination number one higher than the precursors.
ChemInform Abstract: Reaction of Oxygen with a Binuclear Cobalt(II) Hexaphosphine Complex. Single‐Crystal X‐Ray Structure of an Extended Chain Cobalt(II) Hexaphosphine Oxide System.
Authors: SAUM S. E. , ASKHAM F. R. , FRONCZEK F. R. , STANLEY G. G. 
Published: May 2016

AbstractThe five‐coordinate complex (Ia) or the tetrahedral (Ib) react with O2 to yield the fully oxygenated phosphine oxide complex (II).
ChemInform Abstract: Lewis Acidity of Nickel(0). Part 10. Diorganylmagnesium Complexes of Nickel(0): (TMEDA)MgCH3(μ‐CH3)Ni(C2H4)2.
Authors: KASCHUBE W. , POERSCHKE K.‐R. + , ANGERMUND K. , KRUEGER C. + , WILKE G. 
Published: May 2016

AbstractThe Ni(0) complex (I) reacts with Grignard reagents such as (II), (VII) or (VIII) to give crystalline thermolabile compounds (IV), (VI), (IX) or (X).
ChemInform Abstract: Copper(II) Carboxylates and Their 3‐Pyridylcarbinol Adducts.
Authors: MELNIK M. , MACASKOVA L. , MROZINSKI J. 
Published: May 2016

AbstractThe title complexes (I) are prepared by reaction of the pyridine alcohol with the copper(II) salts of the appropriate acid (ratio 2:1) in hot MeOH in a yield of 50%.
ChemInform Abstract: Molecular Structures and Magnetic Properties of μ‐Phenolato Binuclear Copper(II) Complexes Incorporating Chloro, Hydroxo, and Azido Exogenous Bridging Ligands.
Authors: BENZEKRI A. , DUBOURDEAUX P. , LATOUR J.‐M. , LAUGIER J. , REY P. 
Published: May 2016

AbstractThe new binucleating ligand (IV) is prepared in two steps with an overall yield of 15%.
ChemInform Abstract: Permeability Characteristics of Lipid Bilayers from Lipoic Acid Derived Phosphatidylcholines: Comparison of Monomeric, Cross‐Linked and Non‐Cross‐Linked Polymerized Membranes.
Authors: STEFELY J. , MARKOWITZ M. A. , REGEN S. L. 
Published: May 2016

AbstractPolymerized and monomeric forms of large unilamellar liposomes (ca.
ChemInform Abstract: The Dynamics of Reaction of a Water‐Soluble and Non‐μ‐Oxo Dimer Forming Iron(III) Porphyrin with tert.‐Butyl Hydroperoxide in Aqueous Solution. Part 1. Studies Using a Trap for Immediate Oxidation Products.
Authors: SMITH J. R. L. , BALASUBRAMANIAN P. N. , BRUICE T. C. 
Published: May 2016

AbstractA kinetic and product study is carried out in aqueous solution for the title reaction of (I) at 30 °C between pH 2.22 and 12.96.
ChemInform Abstract: Neutron Diffraction Studies of SrBr2·H2O and SrI2·H2O, Symmetrically and Asymmetrically Bonded Water Molecules.
Authors: ENGELEN B. , KELLERSOHN TH. , KUSKE P. , LUTZ H. D. 
Published: May 2016

AbstractIt is found that the hydrogen atoms in the isostructural title compounds (space group Pnma) are crystallographically not equivalent.
ChemInform Abstract: Effect of Oxygen Atom Disordering on Tc of YBa2Cu3O7‐x.
Authors: BUKOWSKI Z. , HORYN R. , ROGACKI K. , FILATOW I. , SULKOWSKI C. , WOLCYRZ M. , KLAMUT J. 
Published: May 2016

AbstractTwo structural changes due to oxygen deficiency or temp.‐induced oxygen atom disordering are observed and used to explain the extraordinary behavior of Tc in the oxygen deficient region.
ChemInform Abstract: Free Radical Reactions of N‐Heterocyclic Compounds. Part 8. ESR Investigations on the N,N‐Bond Cleavage Reaction of Cyclic 2,2‐Diacylhydrazinoxyls (II).
Authors: OMELKA L. , KLUGE R. , REINHARDT M. , SCHULZ M. 
Published: May 2016

AbstractOxidation of the N‐anilinophthalimides (I) under the conditions shown leads to the known hydrazinoxyls (II) which in solution are stable for hours, but by addition of an alcohol undergo decomposition to the new nitroxides (III).
ChemInform Abstract: Cesium Carbonate in Weakly Hydrated Solid/Liquid Heterogeneous Medium: A New Reagent for Anionic Activation Synthesis.
Authors: MOULOUNGUI Z. , MURENGEZI I. , DELMAS M. , GASET A. 
Published: May 2016

AbstractThe (het)aromatic aldehydes (I) are subjected to Wittig‐Horner olefination with the phosphonate (II) in the presence of cesium carbonate, yielding the 3‐arylacrylates (III) with predominance of the E‐isomers.
ChemInform Abstract: Copper(II) Ion Promoted Direct Hydrolysis of 2‐Cyanopyridine to Picolinic Acid. Intramolecular Catalysis by the Coordinated N‐β‐Hydroxyethyl Group.
Authors: BELOKON' YU. N. , TARAROV V. I. , SAVEL'EVA T. F. , VITT S. V. , PASKONOVA E. A. , DOTDAYEV S. CH. , BORISOV Y. A. , STRUCHKOV Y. T. , BATASANOV A. S. , BELIKOV V. M. 
Published: May 2016

AbstractThe kinetics and mechanisms of the hydrolysis of 2‐cyanopyridine in water catalyzed by Cu(II) complexes of the bidentate and tridentate ligands (I) are investigated.