bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Unusual Route to an Acyl Complex in Cluster Chemistry: Synthesis, Structure, and Reactivity of Ru3(μ‐η2‐C(O)(C6H5))(μ3‐η2‐P(C6H5)(C5H4N))(CO)9.
Authors: LUGAN N. , LAVIGNE G. , BONNET J.‐J. 
Published: May 2016

AbstractThermal reaction of diphenylpyridylphosphine with Ru3(CO)12 in the presence of either sodium benzophenone ketyl or [N(PPh3)2]CN leads selectively and quantitatively to (I) which is metastable at ambient temperature yielding the new cluster Complex (II) (space group P2,2,2" Z=4) in contrast to the stability of the phosphine ligand toward Ru3(CO)12 in thermally induced Substitution reactions.
ChemInform Abstract: Insertions of Small Molecules CO, CH3NC, SO2, and CS2 into the Pd ‐ Pd σ‐Bond of Pd2Cl2(PMe2CH2PMe2)2. Crystal and Molecular Structure of Pd2(μ‐CO)Cl2(PMe2CH2PMe2)2.
Authors: KULLBERG M. L. , KUBIAK C. P. 
Published: May 2016

AbstractThe reaction of (I) with small molecules leads to formation of (II) and (III).
ChemInform Abstract: Complexes of Binucleating Ligands. Part 19. Facile Hydration of Nitriles at a Di‐palladium(II) Site Under Mild Conditions.
Authors: LOUEY M. , MCKENZIE C. J. , ROBSON R. 
Published: May 2016

AbstractAusgehend von (Ia) bzw. der besseren Löslichkeit wegen von (Ib) (dargestellt aus (Ia) durch 5 min Erhitzen mit Isobuttersäure bei 100 °C) wurde durch Reaktion mit NaOH (Dioxan, 25°C, 8h) oder in einer Zwei‐Phasen‐Reaktionsmischung ‐ (I) in organischem Medium ‐ und Hydroxid, Carbonat oder Bicarbonat in wäßriger Lösung in Gegenwart oder Abwesenheit von NBuI als Phasenübertragungsreagens ein Komplex mit Hydroxobrükke erhalten, für den mehrere Strukturen möglich erscheinen (Hydroxo‐aquo‐Brükke oder cyclische Struktur mit OH‐Brücken zwischen 3‐4 getrennten Pd2(ligand)+‐Einheiten).
ChemInform Abstract: Synthesis and X‐Ray structure of (C5Me5)2Th(μ‐PPh2)2Pt(PMe3): a Complex with a Thorium ‐ Platinum Bond.
Authors: HAY P. J. , RYAN R. R. , SALAZAR K. V. , WROBLESKI D. A. , SATTELBERGER A. P. 
Published: May 2016

AbstractThe Th(IV) complex (I) reacts smoothly with 1 equiv. Pt(COD)2 in the presence of PMe3 to provide the air‐sensitive title compound (II).
ChemInform Abstract: Synthesis of Azoic Dyes from 7‐Hydroxy‐3‐phenyl Quinoline Derivatives.
Authors: KRISHNAN R. , SESHADRI S. 
Published: May 2016

AbstractDie Kondensation des Phenylacetaldehyds (I) mit Aminophenol (II) ergibt das Chinol‐inderivat (IIIa), aus dem durch Reduktion das Amin (IIIb) gewonnen wird.
ChemInform Abstract: The Formation of 8,14‐seco‐Steroid Systems: 3β,5,17β‐Trihydroxy‐8,14‐seco‐5α‐androstan‐8‐one (IIIb) and Its 3,17‐Diacetate Ester (IIIa).
Authors: MIHAILOVIC M. LJ. , LORENC L. , BONDARENKO L. , TINANT B. , DECLERQ J.‐P. , VAN MEERSSCHE M. 
Published: May 2016

AbstractThe thermolysis of the peroxide (I) gives the dienedione (II) and the title compound (IIIa).
ChemInform Abstract: Synthesis and Antiviral Activity of the Carbocyclic Analogues of S‐Ethyl‐T‐deoxyuridine and of 5‐Ethynyl‐2′‐deoxyuridine.
Authors: SHEALY Y. F. , O'DELL C. A. , ARNETT G. , SHANNON W. M. 
Published: May 2016

AbstractDie über das Si‐acetylen (III) zugänglichen carbocyclischen Analoga (IV) und (V) werden auf Wirkung gegen Herpes simplex‐Viren, Typ HSV‐1 und HSV‐2, untersucht.
ChemInform Abstract: Nucleosides. Part 136. Synthesis and Antiviral Effects of Several 1‐(2‐Deoxy‐2‐fluoro‐β‐D‐arabinofuranosyl)‐5‐alkyluracils.
Authors: SU T.‐L. , WATANABE K. A. , SCHINAZI R. F. , FOX J. J. 
Published: May 2016

AbstractNucleoside vom Typ (III) werden synthetisiert und auf ihre Wirkung gegen Herpes simplex‐Viren (HSV‐1 und HSV‐2) getestet.
ChemInform Abstract: Synthesis of C‐Terminal Fragments of Thymopoietin II (TP II).
Authors: KONOPINSKA D. , PIETRZYNSKI G. , CZARNECKI J. 
Published: May 2016

AbstractThe title peptides (I), (II), and (III) are synthesized: The building units (IV) and (V), each prepared by used procedures, are coupled to give the fully protected peptides (VI) or (IX).
ChemInform Abstract: Solvated Electrons and Electron‐Cation Aggregates in Solutions of the Alkali Metals in 12‐Crown‐4.
Authors: EDMONDS R. N. , HOLTON D. M. , EDWARDS P. P. 
Published: May 2016

AbstractNa, K, Rb, and Cs metals dissolve in 1,4,7,10‐tetraoxacyclododecane to give blue solutions containing metal cations, metal anions, electrons, and cation‐electron pairs.
ChemInform Abstract: Pressure Dependence of the Rate Constant for the Reaction HO2 + NO2 + M ‐→ HO2NO2 + M (M: N2, O2) at 298 K.
Authors: KURYLO M. J. , OUELLETTE P. A. 
Published: May 2016

AbstractThe pressure dependence at 298 K of the title reaction has been investigated by flash photolysis kinetic absorption spectroscopy at N2 and O2 pressures ranging from 25 to 600 torr.
ChemInform Abstract: Kinetics of the Reaction OH + NH3.
Authors: JEFFRIES J. B. , SMITH G. P. 
Published: May 2016

AbstractThe rate constants for the OH + NH3 reaction which is an important reaction in the combustion mechanism for fossil fuels have been measured by laser pyrolysis/laser fluorescence over the temp. range 840‐1425 K. These direct high‐temp.
ChemInform Abstract: Electroreduction of Bicyclic Heteroaromatics. Selective Product Formation.
Authors: KARIV‐MILLER E. , DEDOLPH D. F. , RYAN C. M. , MAHACHI T. J. 
Published: May 2016

AbstractBei der elektrolytischen Reduktion der Benzofurane (I) werden die Reduktionsprodukte (II)‐(IV) in Abhängigkeit von den Bedingungen in unterschiedlichen Anteilen erhalten.
ChemInform Abstract: Kinetic Resolution of Racemic β‐Hydroxy Amines by Enantioselective N‐Oxide Formation.
Authors: MIYANO S. , LU L. D.‐L. , VITI S. M. , SHARPLESS K. B. 
Published: May 2016

AbstractEs wird eine zweckmäßige und allgemeine Methode für die kinetisch kontrollierte Trennung von β‐Hydroxy‐tert‐Butylamin‐Racematen beschrieben.
ChemInform Abstract: The Flow Thermolyses of 1‐Isobutenyl Alkynyl‐ and 2‐Methylphenyl Alkynyl Ketones. Synthesis of Methylenomycin B.
Authors: KOLLER M. , KARPF M. , DREIDING A. S. 
Published: May 2016

AbstractDie Thermolyse von Acetylenketonen wie (I), (IV), (IX) und (XIII) wird bei verschiedenen Temperaturen untersucht, und es werden unterschiedliche im Formelschema aufgeführte Anteile an Phenolen, Cy‐ clopentenonen wie Methylenomycin B (VIII) und Indanonen erhalten.
ChemInform Abstract: Synthesis and Reactivity of N‐Mesitylcyclopropylideneazomethine.
Authors: BATTAGLIA A. , BARBARO G. , GIORGIANNI P. , FORESTI E. , SABATINO P. , DONDONI A. 
Published: May 2016

AbstractDas aus dem Imidchlorid (I) durch Dehydrohalogenierung erzeugte Ketenimin (II) reagiert in situ mit dem Thioketon (III) bzw. dem Azomethin (VI) zu den [2 + 2]‐Cycloaddukten (IV) bzw. (V).
ChemInform Abstract: Products and Reaction Routes in the Diozonolysis of 2,3‐Dimethyl‐1,3‐ butadiene in Methanol.
Authors: GRIESBAUM K. , ZWICK G. , AGARWAL S. , KEUL H. , PFEFFER B. , MURRAY R. W. 
Published: May 2016

Abstract2,3‐Dimethylbutadien wird der Ozonolyse unterworfen, und die in ei‐ ner ggf. explosionsartigen Reaktion gebildeten anomalen Oxidationsprodukte werden isoliert und identifiziert.
ChemInform Abstract: A New Synthesis of Phenyl Ketones by Intramolecular ′Deoxybenzoylation′ of Enols and Phenols.
Authors: KAY I. T. , GLUE S. E. J. 
Published: May 2016

AbstractDas Phenylcyanmethyl‐carbamoylchlorid (I) reagiert über das Ylid (II) mit den Enolaten (III) mit einer Elektronen‐anziehenden Gruppierung über die Zwischenstufen (IV)‐(VII) zu den Benzoyl‐ole?nen (VIII), wobei als Edukte (III) auch Derivate wie (IX), (XIIIa) oder (XIVa) eingesetzt werden können.
ChemInform Abstract: Bromomethyl Ketones and Enolates: Alternative Products from Ester Homologation Reactions.
Authors: KOWALSKI C. J. , HAQUE M. S. 
Published: May 2016

AbstractDie Ester (I) werden unter den im Schema angegebenen Reaktionsbedingungen in die Brommethylketone (II), das Bromenolacetat (III) und den Silylenolether (IV) übergeführt.
ChemInform Abstract: Potential Antimalarials. Part 5. 4‐(7′‐Trifluoromethylquinolin‐4′‐ylamino)phenols, 4‐[2′,7′‐ and 2′,8′‐Bis(trifluoromethyl)quinolin‐4′‐ylaminolphenols and N4‐Substituted 2,7‐(and 2,8‐)Bis(trifluoromethyl)quinolin‐4‐amines.
Authors: BARLIN G. B. , TAN W.‐L. 
Published: May 2016

AbstractReaction of the quinoline (I) with the aminophenol (II) gives (IIIa) or (IIIb).
ChemInform Abstract: About the Synthesis of [1,2]Diazepinoindole Derivatives from Ethyl 2‐(1‐Methylindole)acetate, 2‐Indole and 3‐Indoleacetohydrazones.
Authors: MONGE A. , PALOP J. A. , GONI T. , MARTINEZ A. , FERNANDEZ‐ALVAREZ E. 
Published: May 2016

AbstractAus dem Indolyl‐essigsäureester (I) erhält man mit den Carbonsäureamiden (II) in Gegenwart von Phosphoroxychlorid die Acylierungsprodukte (III), die mit Hydrazin zu Diazepino‐indolen (IV) cyclisiert und weiter zu (V) acyliert werden können.
ChemInform Abstract: 6‐Substituted and 2‐Chloro‐6‐substituted 10‐Piperazino‐10,11‐dihydrodibenzo[b,f]thiepins as Potential Antidepressants.
Authors: CERVENA I. , HOLUBEK J. , SVATEK E. , METYSOVA J. , VALCHAR M. , DLABAC A. , WILDT S. , PROTIVA M. 
Published: May 2016

AbstractThe Starting compound (VIIIb) is obtained from (I) and (II) via (III), whereas starting compounds (VIIIa), (VIIIc) and (VIIId) are prepared from the phenyl acetic acid (VI) and the thiophenol (VII) in the presence of copper.
ChemInform Abstract: Potential Noncataleptic Neuroleptic Agents; 2,6‐Dichloro‐, 2,7‐Dichloro‐ and 2,8‐Dichloro‐10‐piperazino‐10,11‐dihydrodibenzo[b,f]thiepins.
Authors: PROTIVA M. , DLABAC A. , VALCHAR M. , WILDT S. , CERVENA I. , SEDIVY Z. 
Published: May 2016

AbstractThe acetophenone (I) reacts with the thiophenols (II) to give (III), which are converted to the thiomorpholides (VI).
ChemInform Abstract: Tris(o‐phenylenedioxy)cyclotriphosphazene: The Clathration‐Induced Monoclinic to Hexagonal Solid‐State Transition.
Authors: ALLCOCK H. R. , LEVIN M. L. , WHITTLE R. R. 
Published: May 2016

AbstractThe title compound (I) prepared from hexachlorocyclotriphosphazene with catechol in the presence of sodium carbonate is known to clathrate a variety of small molecules.
ChemInform Abstract: Synthesis and Characterization of Some Lanthanide(III) Chelates with O‐Hydroxyacetophenone Oxime.
Authors: MOHAN M. , TANDON J. P. , GUPTA N. S. 
Published: May 2016

AbstractDie 1:3‐molare Umsetzung von Lanthanoid(III)‐chlorid oder ‐nitrat mit dem Titeloxim in 2,2‐Dimethoxypropan/Ethanol unter Rückfluß ergibt die achtfach‐koordinierten, monokationischen Komplexe (I).
ChemInform Abstract: Electrochemistry of Porphyrins Containing a Metal ‐ Metal Bond. Reactions of "Carbenoid" (TpTP)GeFe(CO)4 and (TpTP)SnFe(CO)4.
Authors: KADISH K. M. , BOISSELIER‐COCOLIOS B. , SWISTAK C. , BARBE J. M. , GUILARD R. 
Published: May 2016

AbstractBoth the complexes (TpTP)MFe(CO)4 (M: Ge, Sn, TpTP is the meso‐tetra‐p‐tolylporphyrin dianion) are reversibly and diffusion‐controlled reduced in two single‐electron‐transfer steps (at ‐ l.O5/ ‐ 1.45 Vand ‐ l.OO/ ‐ 1.39 V, resp., versus SCE).
ChemInform Abstract: Monodentate‐N Coordination of 1‐Aza‐4‐oxo‐1,3‐butadienes
Authors: VAN VLIET M. R. P. , VAN KOTEN G. , VAN BEEK J. A. M. , VRIEZE K. , MULLER F. , STAM C. H. 
Published: May 2016

AbstractReaction of dimeric (I) with l‐aza‐4‐oxo‐1,3‐butadienes (II) results in formation of mononuclear complexes (II).
ChemInform Abstract: New Approach to Polyisoprenepolyols Possessing Glycerol Termini by Using a Highly Oxygenated C5‐Unit.
Authors: SUZUKI S. , FUJITA Y. , KOBAYASHI Y. , SATO F. 
Published: May 2016

AbstractDas Allylacetat (I) liefert über (II) das Epoxid (III), das in Gegenwart eines Pd‐Katalysators mit Benzaldehyd (IV) zum Dioxolan (V) reagiert.
ChemInform Abstract: Exaggerated Grain Growth in ZrO2‐Toughened Al2O3.
Authors: KIBBEL B. , HEUER A. H. 
Published: May 2016

AbstractAnnealing of ZrOZ‐toug hened Al2O3 (ZTA) at elevated temp. causes growth of both the intergranular ZrO;, particles and the Al2O3 "matrix" grains.
ChemInform Abstract: Strength‐Toughness Relations in Sintered and Isostatically Hot‐Pressed ZrO2‐Toughened Al2O3.
Authors: HORI S. , YOSHIMURA M. , SOMIYA S. 
Published: May 2016

AbstractPostsintering pressing of fine‐grained undoped lrOz‐thoughened Al2O3 (ZTA) was conducted to investigate the mechanical property changes caused by removal of pores and probable reduction of microcracks.
ChemInform Abstract: Characterization of Synthetic and Naturally Occurring Clays by 27Al and 29Si Magic‐Angle Spinning NMR Spectroscopy.
Authors: KOMARNENI S. , FYFE C. A. , KENNEDY G. J. , STROBL H. 
Published: May 2016

AbstractThree Synthetic clays (fluorphlogopite, mica‐montmorillonite, laponite) and five naturally occurring clay minerals (mqntmorillonite, hectorite, saponite, chlorite, muscovite) have been investigated by the title method.
ChemInform Abstract: Solid‐State 27Al and 29Si Magic‐Angle Spinning NMR of Aluminosilicate Gels.
Authors: KOMARNENI S. , ROY R. , FYFE C. A. , KENNEDY G. J. , STROBL H. 
Published: May 2016

AbstractThe environment of the Al and Si atoms of diphasic and single‐phase aluminosil:icate gels has been determined by the title methods.
ChemInform Abstract: N‐Phenyl N‐Pyridyl and N‐(2,3‐Dioxocyclobutenyl)‐Substituted S,S‐Dialkylsulfur Diimides.
Authors: RIED W. , PAULI R. 
Published: May 2016

AbstractSchwefeldiimide des Typs (I) lassen sich mit einer Reihe von Verbindungen zu den im Formelschema aufgeführten Produkten umsetzen.
ChemInform Abstract: Photo‐Induced Carbon‐Carbon Bond Formation: Reactions of 2‐Thiopyridones and ‐Quinolinethiones with Alkenes.
Authors: NISHIO T. , OMOTE Y. 
Published: May 2016

AbstractDie photochemische Addition der 2‐Thiopyridone (I) an Alkene (II) führt über eine [2 + 2]‐Cycloaddition zu Mercaptanen (III).
ChemInform Abstract: Chelation‐ and Non‐Chelation‐Controlled Additions to 2‐O‐Benzyl‐3‐O‐ (tert‐butyldimethylsilyl)glyceraldehyde.
Authors: REETZ M. T. , KESSELER K. 
Published: May 2016

AbstractGrignard‐Reaktionen und Aldol‐Additionen mit dem aus dem Mannitol‐Derivat (I) gemäß Reaktionsschema hergestellten zweifach O‐blockierten Glycerinaldehyd (V) verlaufen je nach Art des eingesetzten metallorganischen Reagenses chelat‐ oder nicht‐chelat‐kontrolliert stereoselektiv zu den syn‐ (VIII) bzw. (XI) oder anti‐Addukten (IX) bzw. (XII).
ChemInform Abstract: Palladium‐Catalyzed Carbonylation of Alkynes. Part 2. Aspects of Additive, Oxidative, and Reductive Carbonylation.
Authors: CHIUSOLI G. P. , COSTA M. , PERGREFFI P. , REVERBERI S. , SALERNO G. 
Published: May 2016

AbstractDie Reaktionen der Alkine (I), (VIII), (XIV), (XIX) und (XXI II) mit CO (VII) in Methanol unter Pd‐Katalyse ergeben die aufgeführten Produkte.
ChemInform Abstract: 3,3,3‐Trifluoropropan‐1‐ol and 3,3,3‐Trifluoropropanal.
Authors: GOLDING B. T. , SELLARS P. J. , WATSON W. P. 
Published: May 2016

AbstractAuf dem skizzierten Weg werden die beiden im Titel genannten Verbindungen (IV) und (V) synthetisiert.
ChemInform Abstract: Synthesis of 2‐(o‐Chlorophenyl)‐2‐methylaminocyclohexanone Hydrochloride.
Authors: POSLINSKA H. , PALANOWSKI R. 
Published: May 2016

AbstractThe synthesis of the title compound (V) has been carried out starting from the compounds (Ic) [from (Ia) via (Ib)] and (IIb) [from (IIa)] via the intermediates shown in the scheme.
ChemInform Abstract: 1,3‐Dipolar Cycloaddition of 2‐Diazopropane to 1‐Phenyl‐bis‐s‐triazolo[4,3‐b:3′,4′‐f]pyridazine. The Synthesis of 11,11‐Dimethyl‐11H‐pyrazolo[3,4‐d]bis‐s‐triazolo[4,3‐b:3′4′‐f]pyridazines, Derivatives of a Novel Heterocyclic System.
Authors: FURLAN B. , STANOVNIK B. , TISLER M. 
Published: May 2016

AbstractDie Cycloaddition von 2‐Diazopropan (II) an den Heterocyclus (I) führt zum Isomerengemisch der Cycloaddukte (IIIa) und (IIIb), deren Strukturen durch unabhängige Synthesen bewiesen werden.
ChemInform Abstract: Heterocyclic Amplifiers of Phleomycin. Part 10. Derivatives of Diazine Mono‐ and Di‐thiols.
Authors: BARLIN G. B. , BROWN D. J. , CRONIN B. J. , NGU M. 
Published: May 2016

AbstractThe pyrazinethiols (IVa)‐(IVc) are prepared either by reaction of the corresponding chlorides (I) with thiourea (II) or by treatment of the corresponding hydroxy compounds (III) with P285.
ChemInform Abstract: 2,3‐Bis[triphenylphosphoniomethyl]piperazine. Precursor of a New Heterocyclic Bis‐ Wittig Reagent.
Authors: CRISTAU H.‐J. , CHICHE L. , PLENAT F. 
Published: May 2016

AbstractDurch Addition von Ethylendiamin (II) an 1,4‐Butadienylenbis‐phosphoniumsalz (I) entsteht ein Piperazin‐bis‐phosphoniumsalz (III), das durch Olefinierungsreaktionen zu neuen Piperazin‐Derivaten (IV) umgesetzt wird; diese können zu den Derivaten (V) hydriert werden.
ChemInform Abstract: Reactions of 2,3‐Diamino‐4(3H)‐pyrimidinones. Part 2.
Authors: HLAVKA J. J. , BITHA P. , LIN Y. , STROHMEYER T. 
Published: May 2016

AbstractAus den Diamino‐pyrimidinonen (III) erhält man mit zahlreichen Dioxo‐ Verbindungen (II), (IV), (VII), (VIII) oder (X) die entsprechenden Cyclisierungsprodukte (I), (V), (VI), (IX) oder (XI), aus (XIII) und (II) ist analog Verbindung (XII) zugänglich.
ChemInform Abstract: A Detailed, Convenient Preparation of Dimethyl l,2,4,5‐Tetrazine‐3,6‐ dicarboxylate.
Authors: BOGER D. L. , COLEMAN R. S. , PANEK J. S. , HUBER F. X. , SAUER J. 
Published: May 2016

AbstractDie im Titel genannte Verbindung (IV) wird in einer vierstufigen Synthese aus Diazoessigsäureester (I) hergestellt.
ChemInform Abstract: Dioxopyrrolines. Part 35. Synthesis of 2H‐Azepin‐2‐ones (2‐Azatropones).
Authors: SANO T. , HORIGUCHI Y. , TANAKA K. , TSUDA Y. 
Published: May 2016

AbstractDie Azabicycloheptanone (I) werden durch Behandlung mit DBU zu (II) und durch anschließende Dehydrierung zu den Azepinonen (III) umgesetzt.
ChemInform Abstract: Chemistry of Boron. Part 168. Synthesis and Structure of Azadiboriridines.
Authors: DIRSCHL F. , HANECKER E. , NOETH H. + , RATTAY W. , WAGNER W. 
Published: May 2016

AbstractDie Titelverbindungen (IV) werden durch Enthalogenierung der Haloborierungsprodukte (III) von Aminoiminoboran (I) und den Aminobordihalogeniden (II) mittels einer Na/K‐Legierung synthetisiert.
ChemInform Abstract: Optically Active α‐Chloro‐(E)‐crotylboronic Acid Esters via Allylic Rearrangement.
Authors: HOFFMANN R. W. , DRESELY S. 
Published: May 2016

AbstractSilylation and hydroboration of the butinol (I), followed by oxidation and esteri‐ fication with pinacol (II), gives (III), which is converted to its Chloride (IV).
ChemInform Abstract: Novel Basic Ligands for the Homogeneous Catalytic Homologation of Methanol to Ethanol.
Authors: LINDNER E. , SCHEYTT C. 
Published: May 2016

AbstractDie wie aufgezeichnet aus den Silylphosphinen (I) und Furfurylbromid (II) gebildeten Furfurylphosphoniumsalze (III) werden durch LiAlH4 zu den gewünschten Titelverbindungen (IV) abgebaut.
ChemInform Abstract: Synthesis and Characterisation of Tungsten and Rhenium Aluminopolyhydrides: X‐Ray Crystal Structures of (Me3P)3H3W(μ‐H)2Al(H)(μ‐OBu)2Al(H)(μ‐H)2WH3(PMe3)3 and (Me3P)3H3W(μ‐H)2Al(H)(μ‐H)2WH3(PMe3)3.
Authors: BARRON A. R. , LYONS D. , WILKINSON G. , MOTEVALLI M. , HOWES A. J. , HURSTHOUSE M. B. 
Published: May 2016

AbstractThe reaction of WCl4(PMe3)3 with LiAlH4 in refluxing THF (48 h) leads to one of the title compounds, (Ia) (with bridging butoxide groups arising from the cleavage of THF by aluminium hydride), whereas in Et2O (20°C, 2h) the product (Ib) is formed.
ChemInform Abstract: Chemistry of Transition Metal Alkyl Compounds. Part 44. Formation of Tetraorganylzirconates(II).
Authors: KRUEGER A. + , THIELE K.‐H. 
Published: May 2016

AbstractZirconiumtetraorganyls such as (I) are reduced by n‐butyl Li with formation of dilithium tetraorganyl zirconates(II).
ChemInform Abstract: Novel Octahedral Silicium and Germanium Complexes with Hexadentate Diphenol Ligand.
Authors: WOLFF B. , WEISS A. 
Published: May 2016

AbstractThe 1:1 molar reaction of Si(OEt)4 or GeCl4 with tris[(2,3‐dihydroxyphenoxy)propyl]ammonium Chloride in the presence of NEt3 in refluxing MeOH under N2 atmosphere yields the crystalline cationic Complexes (Ia) and (Ib), respectively.
ChemInform Abstract: Triple‐Decker Complexes. Part 4. Synthesis of Anionic Triple‐Decker Complexes Having Closed 30c Valence Shells by Stacking of Sandwich Anions with Cr(CO)3 Fragments.
Authors: HERBERICH G. E. , HESSNER B. , HOWARD J. A. K. , KOEFFER D. P. J. + , SAIVE R. 
Published: May 2016

Abstract(Borol)metall‐Sandwich‐Anionen (I) lassen sich durch Reaktion mit dem 12e‐Baustein Cr(CO)3 zu Tripeldecker‐Anionen (II) aufstocken.
ChemInform Abstract: The Ferrocenylmethyl (Fem) Group as a Highly Lipophilic and Chromophoric Group for Masking Peptide Bonds.
Authors: ECKERT H. , SEIDEL C. 
Published: May 2016

AbstractWhile the reduction of the aldehyde (I) is a slow reaction, the hydrogenation of the azomethines (III), formed with the amino acid esters or salts (II), in the presence of a Pd(II) catalyst proceeds quickly and without racemization to give the (yellow) Fem‐amino acid derivatives (IV).
ChemInform Abstract: Chiral α‐Ferrocenylalkylamines.
Authors: HERRMANN R. , HUEBENER G. + , SIGLMUELLER F. + , UGI I. 
Published: May 2016

AbstractDie Ferrocenylalkylamine (IVa) und (IVb) mit zwei Chiralitätszentren wurden ‐ wie im Schema aufgezeigt ‐ dargestellt.
ChemInform Abstract: Heteronuclear "Star Clusters"; [Ni2Pt2W4(μ3‐CPh)4(CO)8(η‐C5H5)4] and [Ni2Pt2W4(μ2‐CR)(μ3‐CR)3(CO)8(η‐C5H5)4] (R = Ph or p‐C6H4CH3).
Authors: ELLIOTT G. P. , HOWARD J. A. K. , MISE T. , NUNN C. M. , STONE F. G. A. 
Published: May 2016

AbstractAus der Reaktion der Dreikernkomplexe (Ia) bzw. (Ib) mit (II) werden in Gesamtausb.
ChemInform Abstract: Methods for the Preparation of Alkyl 1,2‐Orthoacetates of D‐Glucopyranose and D‐ Galactopyranose in High Yield.
Authors: TSUI D. S. K. , GORIN P. A. J. 
Published: May 2016

AbstractIn Gegenwart einiger Silbersalze entstehen aus den Glykosylhalogeniden (I) die im Titel genannten Orthoester (II) mit guten Ausbeuten.
ChemInform Abstract: Synthesis of Pseudo‐Oligosaccharide Glycosidase Inhibitors. Part 4.
Authors: OGAWA S. , IWASAWA Y. , TOYOKUNI T. , SUAMI T. 
Published: May 2016

AbstractDie Kondensation der aus dem Azid (II) dargestellten Aminozucker (I) und (IV) mit dem Cyclohexan‐Derivat (V) führt zu den isomeren Pseudodisacchariden (VI), (VIII), (X) und (XII).
ChemInform Abstract: Semisynthetic β‐Lactam Antibiotics. Part 6. Synthesis and Antimicrobial Activity of α‐Hydrazonobenzylcephalosporins.
Authors: MONGUZZI R. , PINZA M. , PIFFERI G. , VISCONTI M. , BROCCALI G. 
Published: May 2016

AbstractDie Hydrazone (Ia) und (Ib) reagieren mit den Aminocephalosporansäureestern (IIa) und (IIb) bei nachfolgender saurer Ver‐ 185 seifung zu den E‐isomeren Cephalosporinen (IIIa) und (I IIb), von denen (IIIa) mit Mercaptanen (IV) in die Thiomethyl‐cephalosporine (IIIc) und (IIId) umgewandelt werden.
ChemInform Abstract: Far‐lnfrared Spectrum of Solvated Lithium Cations in Dimethyl Sulfoxide.
Authors: CHANG S. , SCHMIDT P. P. , SEVERSON M. W. 
Published: May 2016

AbstractThe far‐IR spectra of solutions of LiCl, Lißr, Lil, LiBF4, and LiClO4 in DMSO at 298 and 1 10 K are obtained and the spectral maxima are calculated.
ChemInform Abstract: Electron‐microscopic Observation of Photodeposited Pt on TiO2 Particles in Relation to Photocatalytic Activity.
Authors: NAKAMATSU H. , KAWAI T. , KOREEDA A. , KAWAI S. 
Published: May 2016

AbstractThe factors determining the spatial distribution of Pt deposits on TiO2 particles are identified and the photocatalytic activity is discussed for TiO2 powders with different degrees of Pt dispersion.
ChemInform Abstract: Generation of Cyclopropanone‐Oxyallyl Intermediates from α‐Mesyloxyketones: [4+3]Cycloadditions to Furan and Cyclopentadiene.
Authors: FOEHLISCH B. + , HERRSCHER I. 
Published: May 2016

AbstractThe hydroxyketones (I) are converted to their methane sulfonates (II).
ChemInform Abstract: Photochemical Transformations. Part 65. The 3σ → 3π Route to 1H‐Azepines/Benzene Imines.
Authors: PRINZBACH H. , BINGMANN H. , FRITZ H. , MARKERT J. , KNOTHE L. , EBERBACH W. , BROKATZKY‐GEIGER J. , SEKUTOWSKI J. C. , KRUEGER C. + 
Published: May 2016

AbstractThe azanorbornadienes (IIIc), (IIId) and (IIIf) are obtained by reaction of the pyrroles (I) with (II).