bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Sublimation and Desublimation in the System AlCl3‐FeCl3.
Authors: EGGERS H.‐H. , OLLMANN D. , HEINZ D. , DROBOT D. V. , NIKOLAEV A. V. 
Published: May 2016

AbstractThe solid‐gas equilibrium in the title system is characterized in the composition range 0‐5 mol°/o FeCl3 using vapour pressure measurements.
ChemInform Abstract: Effect of Cerium ‐ Lead Substitution on the Crystallographic and Dielectric Properties of the Niobates Pb2.5Nb5O15 and Pb2KNb5O15 with Tetragonal Tungsten Bronze‐Type Structure.
Authors: LAUNAY S. 
Published: May 2016

AbstractNovel phases (III) and (VI) with tetragonal tungsten bronze‐type structure are obtained by solid‐state reactions at 1200°C. The Starting materials (I), (II), (IV), and (V) are prepared outgoing from the oxides of Pb, Nb, and Ce, and K2CO3.
ChemInform Abstract: The Crystal Structure of R,S,R,S‐(1,4,8,11‐Tetramethyl‐1,4,8,11‐tetraazacyclotetradecane)nickel(II) Bis(trifluoromethanesulphonate)‐Acetone Hydrate, [Ni(tmtactd)] (CF3SO3)2·Me2CO·H2O, and a Strain‐energy Minimization Analysis of Four‐, Five‐, and Six‐co‐ordinate Nickel(II)‐tmtactd Solvento Complexes.
Authors: HAMBLEY T. W. 
Published: May 2016

AbstractThe title Crystal has the space group PT, with Z=2.
ChemInform Abstract: Radical Addition to Vinyl Sulphones and Vinyl Phosphonium Salts.
Authors: BARTON D. H. R. , TOGO H. , ZARD S. Z. 
Published: May 2016

AbstractN‐Hydroxythiopyridon (I) liefert mit den Carbonsäuren (II) die Ester (III), die thermisch oder photochemisch zu den Thioethern (IV), Kohlendioxid und freien Radikalen (V) gespalten werden.
ChemInform Abstract: Diels‐Alder Reactions of Bridgehead Enones.
Authors: KRAUS G. A. , HON Y.‐S. 
Published: May 2016

AbstractDie Diels‐Alder‐Reaktion der aus den Bromketonen (I) in situ hergestellten Enone (II) mit den Dienen (III) liefert ausschließlich die exo‐Addukte (IV).
ChemInform Abstract: Novel Rigid Calcium‐Entry Blockers: Intramolecular Reactions of 1,4‐Dihydropyridine Derivatives.
Authors: CLAREMON D. A. , HIRSHFIELD J. , LUMMA P. K. , MCCLURE D. E. , SPRINGER J. P. 
Published: May 2016

AbstractAus dem 1,4‐Dihydropyridin‐Derivat (I) erhält man durch Etherspaltung das tricyclische Pyranon (II), das nach Ringöffnung zum Diester (III) sauer zum Diastereomerengemisch der tricyclischen Ether (IV) und (V) cyclisiert.
ChemInform Abstract: Selectivity and Charge Transfer in Photoreactions of Donor‐Acceptor Systems.
Authors: MATTAY J. , RUNSINK J. , GERSDORF J. , RUMBACH T. , LY C. 
Published: May 2016

AbstractExergonic photoreaction of (III) with the diole (II) results in substitution, while the vinylene carbonate (IV) prefers cycloaddition, according to an endergonic electron‐transfer process.
ChemInform Abstract: Unimolecular Reactions of [CH3‐(CH2)n‐1‐NH2]+′ Radical Cations in the Gas Phase.
Authors: AUDIER H. E. , SOZZI G. , DENHEZ J. P. 
Published: May 2016

AbstractThe metastable fragmentations of the amines (I) have been studied by the MIKE technique.
ChemInform Abstract: Halogenative Deoxygenation of Ketones. Vinyl Bromides and/or gem‐Dibromides by Cleavage of lß‐Benzodioxoles (Ketone Phenylene Acetals) with Boron Tribromide.
Authors: NAPOLITANO E. , FIASCHE R. , MASTRORILLI E. 
Published: May 2016

AbstractDie Ketone (I) werden in Form ihrer Dimethylacetale (II) mit Brenzcatechin in Benzodioxole (III) übergeführt, die durch Bortribromid in gem‐ Dibromide (IV) und Vinylbromide gespalten werden, wie am Beispiel von (III) (R′ = Et, R2 = Ph) gezeigt ist.
ChemInform Abstract: Chelation Assisted Transmetallation of Tetraalkyl Tin Derivatives: C‐Metallated Lithiocarbamates as d3 Reagents for the Synthesis of δ‐Hydroxycarbamates.
Authors: ZIDANI A. , VAULTIER M. 
Published: May 2016

AbstractDie Nitrile (I) werden in die Urethane (II) übergeführt, die über die Bis‐lithium‐Derivate (III) mit den Carbonylverbindungen (IV) zu den Addukten (V) umgesetzt werden.
ChemInform Abstract: Improved Synthesis of C‐(p‐Nitrophenyl)‐N‐(p‐formylphenyl)nitrone: A Key Intermediate for Organic Synthesis.
Authors: NOUR T. A. , EBAID W. S. 
Published: May 2016

AbstractDie Reaktion von p‐Nitrosobenzaldehyd (I) mit dem Nitrobenzylpyridiniumtosylat (II) liefert das Diarylnitron (III) in sehr guten Ausbeuten.
ChemInform Abstract: Synthesis of Furo[3,4‐d]pyrimidine Derivatives via Reaction of 4‐Methylpyrimidine‐ 5‐carboxylic Acids with Thionyl Chloride.
Authors: MACHON Z. , CIEPLIK J. 
Published: May 2016

AbstractDie 5‐Carboxy‐4‐methylpyrimidine (I) reagieren mit Thionylchlorid unter Oxidation zu Thioxo‐anhydriden (II), die mit primären Aminen (III) Diimine (IV) bilden.
ChemInform Abstract: Conversion of Shikimic Acid to 5‐Enolpyruvylshikimate 3‐Phosphate.
Authors: CHOUINARD P. M. , BARTLETT P. A. 
Published: May 2016

AbstractDie im Titel genannte Zielverbindung (XI) wird in einer siebenstufigen Synthesefolge aus dem bekannten Acetonid (I) in einer Gesamtausbeute von 22% hergestellt.
ChemInform Abstract: Reaction of Acetals with Some PH‐Acids.
Authors: LIVANTSOV M. V. , PRISHCHENKO A. A. , LUTSENKO I. F. 
Published: May 2016

AbstractDie Acetale (I) bzw. (IV) reagieren in Gegenwart von Bortrifluorid‐ Etherat mit den Phosphiten (II) bzw. den Phosphinen (V) unter Abspaltung von Alkoholen, wobei die P‐Derivate (III) und (VI) entstehen.
ChemInform Abstract: An Effective Method for the Synthesis of Unsymmetrical Difurylmethane Derivatives and 1,1‐Difuryl Olefins.
Authors: CASTAGNINO E. 
Published: May 2016

AbstractFuran (II) reagiert mit dem Methylfuryl‐hydroxy‐methanphosphonsäureester (III) je nach Temperatur zu den isomeren Kondensationsprodukten (I) bzw. (IV).
ChemInform Abstract: Synthesis of Some (11‐Arene)dihydridorhenium Cations and Their Reactions with Li‐ AlH4 and LiAlD4.
Authors: BAUDRY D. , BOYDELL P. , EPHRITIKHINE M. 
Published: May 2016

AbstractThe title complexes (II) were prepared from the corresponding neutral dihydridocyclohexadienyl complexes (I) by treatment with [Ph3C]BF4.
ChemInform Abstract: New Synthetic Route to Monophosphaferrocenes.
Authors: ROBERTS R. M. G. , WELLS A. S. 
Published: May 2016

AbstractPhosphacyclopentadienyl anions derived from the 1‐phenylphospholes (I) cleave the nÖ‐bonded arene from 116‐mesitylene‐nS‐cyclopentadienyl‐Fe(II) cations via nucleophilic attack at Fe to yield the n5‐cyclopentadienyl‐n5‐phosphacyclopentadienyl‐Fe(II) sandwich compounds (II).
ChemInform Abstract: Redox Reactions of Some Iron(II), Iron(III), and Cobalt(III) Picolinate Complexes.
Authors: LANNON A. M. , LAPPIN A. G. , SEGAL M. G. 
Published: May 2016

AbstractThe kinetics of reduction of iron(III) in pyridine‐2‐carboxylate, picolinate (pic′), solutions by ascorbate ion show a complex dependence upon pH, ligand concentration, and reductant concentration.
ChemInform Abstract: Reaction of Bis(glycinato)copper(II) with Formaldehyde and Benzaldehyde Phenylhydrazone: X‐Ray Crystal Structure of Aquobis[(2,3,4,5‐tetrahydro‐2,6‐diphenyl‐1,2,4‐triazin‐4‐yl)acetato‐O,N4[copper(II) Dihydrate.
Authors: TEO S.‐B. , TEOH S.‐G. , HAMBLEY T. W. , SNOW M. R. 
Published: May 2016

AbstractThe title reaction results in the formation of (I), which crystallizes in the space group Cc with Z=4.
ChemInform Abstract: Formation and Decomposition of an α‐Alkoxyalkyl Complex of Palladium(II).
Authors: MCCRINDLE R. , STEPHENSON D. K. , MCALEES A. J. , WILLSON J. M. 
Published: May 2016

AbstractThe title Complex (III) decomposes in solution to give complexes containing the acetal (Ic) or the corresponding aldehyde (Ib).
ChemInform Abstract: Asymmetric Syntheses of α‐Amino Acids from α‐Halogenated 10‐Sulfonamido‐Isobornyl Esters.
Authors: OPPOLZER W. , PEDROSA R. , MORETTI R. 
Published: May 2016

AbstractDie Isobornylsulfonamidalkohole (I) bzw. (II) werden zur optischen Induktion bei der Synthese der Aminosäuren (VI) oder (VII) aus den Carbonsäure‐Derivaten (III) oder (IV) eingesetzt.
ChemInform Abstract: Synthesis of N′‐Mono and Dialkyl‐2′‐deoxycytidines and Their Insertion into an Oligonucleotide.
Authors: KRASZEWSKI A. , DELORT A. M. , TEOULE R. 
Published: May 2016

AbstractDie aus dem Desoxyuridin (I) erhaltene Thioverbindung (II) reagiert mit den Aminen (III) zu den Desoxycytidinen (IV).
ChemInform Abstract: New Potential Immunoenhancing Compounds. Part 2. Syntheses of 1‐Deoxy‐1‐thiophosphatidylcholine Derivatives.
Authors: NALI M. , RINDONE B. , BOSONE E. , FARINA P. , INNOCENTI S. , VALCAVI U. 
Published: May 2016

AbstractTreatment of (I) with hexadecyl bromide (IIa) or benzyl Chloride (IIb) gives the ethers (III), which are hydrolyzed to (IV).
ChemInform Abstract: Stereoselective Synthesis of Both Enantiomers of Disparlure, the Sex Pheromone of the Gypsy Moth, from D‐Glucose.
Authors: ACHMATOWICZ O. JUN. , SADOWNIK A. , BIELSKI R. 
Published: May 2016

AbstractThe dialdose (I) which is obtained from glucose by a well‐known procedure in three steps is converted via the intermediates shown in the scheme to both enantiomers of the title compound, (+)‐disparlure (IX) and (‐ )‐disparlure (XI).
ChemInform Abstract: High Resolution Neutron Diffraction Study of the Perovskite LaTiO3.
Authors: EITEL M. , GREEDAN J. E. 
Published: May 2016

AbstractLaTiO3 shows a transition from temp.‐independent paramagnetism to antiferromagnetism at 125 K. The temp. coefficient of the electrical resistivity changes at 125 Kfrom positive to negative.
ChemInform Abstract: UV Laser Photochemistry: Triplet Biradical Trapping Efficiencies and Lifetimes.
Authors: ADAM W. , HANNEMANN K. , WILSON R. M. 
Published: May 2016

AbstractIn the search for methods applicable to the quantitative study of localized simple biradicals in solution, the triplet radical (II) (lifetime (T) = 720‐900 ns) is trapped with O2 leading to nearly quantitative formation of the peroxide (III) (trapping factor 0.98‐0.99).
ChemInform Abstract: Crossed Coupling of Functionalised Ketones by Low Valent Titanium (The McMurry Reaction): A New Stereoselective Synthesis of Tamoxifen (IId).
Authors: COE P. L. , SCRIVEN C. E. 
Published: May 2016

AbstractDie Tamoxifenanalogen (IIa)‐(IIc) lassen sich sowohl nach Methode A) als auch nach Methode B) durch Reaktion der Benzophenone (Ia)‐(Ic) mit Propiophenon (III) darstellen.
ChemInform Abstract: A Simple Synthesis of 3‐Nitrocycloalkenones and Their Acetals.
Authors: VANKAR Y. D. , BAWA A. 
Published: May 2016

AbstractDie im Titel genannten Verbindungen (III) werden durch Nitromercurierung der Acetale (I) und anschließende alkalische Behandlung der so erhaltenen Addukte (II) hergestellt.
ChemInform Abstract: Enhancement of Catalytic Activity Through Orthometalation. Synthesis, Structure, and Catalytic Activity of a New Orthometalated Ruthenium Complex.
Authors: LEWIS L. N. 
Published: May 2016

AbstractIn contrast to their nonorthometalated analogues (II), the known complexes (I) are active Catalysts for the hydrogenation of olefins such as (VIa)/(VIb).
ChemInform Abstract: Selective α‐D‐Glucosylation of Methyl 4,6‐O‐Benzylidene‐α‐ and ‐β‐D‐ glucopyranosides with 2,3,4,6‐Tetra‐O‐benzyl‐α‐D‐glucopyranosyl Bromide Under Catalysis by Halide Ion.
Authors: TAKEO K. , TEI S. 
Published: May 2016

AbstractUnter den angegebenen Bedingungen verläuft die Glykosylierung der Benzyliden‐geschützten Glucoside (I) mit dem Bromid (II) selektiv zu den α‐Verknüpften Disacchariden (III) und (IV).
ChemInform Abstract: Affinity Labels for anti‐(1 → 6)‐β‐D‐Galactopyranan Antibodies. Part 2. Synthesis of 2,3‐Epoxypropyl O‐β‐D‐Galactopyranosyl‐(1 → 6)‐β‐D‐galactopyranoside.
Authors: FALENT‐KWAST E. , KOVAC P. , BAX A. , GLAUDEMANS C. P. J. 
Published: May 2016

AbstractDie Synthese des im Titel genannten Galaktosids (VIb) gelingt entsprechend der im Formelschema skizzierten Umsetzungen.
ChemInform Abstract: Neutron Powder Diffraction Investigation of Deuterated Pd15P2.
Authors: ANDERSSON Y. , RUNDQVIST S. , TELLGREN R. , FLANAGAN T. B. 
Published: May 2016

AbstractWith the aid of crystal structure refinements of pure and deuterated Pd,5P2 (Rietveld‐type profile analysis of neutron powder diffraction intensities) the positions and the degree of occupancy for the dissolved Datoms are determined at 296 Kand 500kPa deuterium pressure.
ChemInform Abstract: Mechanical Properties of ZrC ‐ ZrB2 and ZrC ‐ TiB2 Directionally Solidified Eutectics.
Authors: SORRELL C. C. , STUBICAN V. S. , BRADT R. C. 
Published: May 2016

AbstractThe mechanical properties (Knoop microhardness, fracture toughness, and wear resistance) of directionally solidified (floating‐zone method) lamellar ZrC ‐ ZrB2 and Chinese‐Script ZrC ‐ TiB2 are shown to be superior when compared with the individual constituents.
ChemInform Abstract: Mixed‐Valence l′,6′‐Dihalobiferrocenium Salts: The Effect of the Solid‐State Environment on Electron‐Transfer Rates.
Authors: DONG T.‐Y. , HENDRICKSON D. N. , PIERPONT C. G. , MOORE M. F. 
Published: May 2016

AbstractThe mixed‐valence cation of (Ia) contains two crystallographically equivalent iron ions, whereas the dichloro derivative is composed of two (Ic) cations, valence localized with Fe(II) and Fe(III) ions.
ChemInform Abstract: The Fluorination of Organic Substrates with Tetraphenylphosphonium Hydrogendifluoride.
Authors: BROWN S. J. , CLARK J. H. 
Published: May 2016

AbstractDie Eigenschaften des aus (I) und (II) hergestellten Phosphonium‐Salzes (III) als Fluorierungsagens werden untersucht und umfassend diskutiert.
ChemInform Abstract: Photoenolization with α‐Chloro Substituents.
Authors: BERGMARK W. R. , BARNES C. , CLARK J. , PAPARIAN S. , MARYNOWSKI S. 
Published: May 2016

AbstractAus den aromatischen Chlorketonen (I) erhält man bei der Photolyse in Gegenwart von Methanol ein Gemisch der Produkte (II)‐(V).
ChemInform Abstract: Reduction of Vinyl Mercurials with Hydrazine Hydrate. A New Pathway.
Authors: AWAD W. I. , EL‐BIEH A. , AHMED M. A. 
Published: May 2016

AbstractDie Vinylquecksilberverbindungen (I) reagieren mit Hydrazinhydrat über diskutierte Zwischenstufen zu Acetophenonazin (II), wobei die Methylgruppen letztlich durch Reduktion aus den mercurierten vinylischen C‐Atomen entstehen.
ChemInform Abstract: Reaction of Fluoroxytrifluoromethane with Ring‐Substituted Styrenes: A Structure‐ Reactivity Study.
Authors: LEVY J. B. , STERLING D. M. 
Published: May 2016

AbstractDie Styrole (II) werden mit Fluoroxy‐trifluormethan (I) zu den Fluorierungsprodukten (III)‐(V) umgesetzt.
ChemInform Abstract: Chlorosulfination of Aromatic Methyl Ethers with Thionyl Chloride
Authors: BELL K. H. 
Published: May 2016

AbstractDas Sulfinyl‐ Chlorid (II) ist auf einfache Weise durch direkte Umsetzung des aromatischen Methylethers (I) mit Thionylchlorid zugänglich.
ChemInform Abstract: Synthesis of 12(R),13(S)‐Oxido‐9Z‐octadecenoic (Vernolic) and 13(S)‐ Hydroxy‐ 9Z,11E‐octadecadienoic (Coriolic) Acids.
Authors: MOUSTAKIS C. A. , WEERASINGHE D. K. , MOSSET P. , FALCK J. R. , MIOSKOWSKI C. 
Published: May 2016

AbstractAusgehend von dem literaturbekannten Aldehyd (I) erhält man in einer enantiospezi?schen Totalsynthese über zahlreiche diskutierte Zwischenstufen, z.B. (II) und (III), (‐)‐Vernolsäure (IV) und schließ‐ lich (+)‐Coriolsäure (V).
ChemInform Abstract: Model Studies for the Synthesis of Trichothecenes. Synthesis of rac‐ Trichodiene and rac‐Bazzanene.
Authors: GILBERT J. C. , WIECHMAN B. E. 
Published: May 2016

AbstractDie aus dem Cyclohexenon (I) und dem Cyclopentenyl‐methanol (II) erhaltenen Enolether (IV) werden zu (V) als Modellverbindungin der Synthese verschiedener Naturstoffe umgelagert.
ChemInform Abstract: Additions of Benzvalene to Nitrile Oxides: A Synthesis for Benzvalene‐3‐carbonitrile.
Authors: CHRISTL M. , MATTAUCH B. , IRNGARTINGER H. , GOLDMANN A. 
Published: May 2016

AbstractAddition der z.T. in situ erzeugten Nitriloxide (II) an Benzvalen (I) ergibt die Isoxazoline (III), deren Struktur anhand einer Röntgenstrukturanalyse von (IIIa) (RG: P2,2,2,; Z=4) untersucht wird.
ChemInform Abstract: Reactions of Perfluoronitriles. Part l. Interactions with Aniline.
Authors: PACIOREK K. J. L. , NAKAHARA J. H. , KRATZER R. H. 
Published: May 2016

AbstractDie Umsetzung des Per?uornitrils (I) mit Anilin (II) ergibt ein Produktgemisch, in dem die Verbindungen (III)‐(VII) nachgewiesen werden können.
ChemInform Abstract: The Reactions of α‐Arylsulfonoxy Ketones with Nucleophiles.
Authors: HOFFMAN R. V. , JANKOWSKI B. C. , CARR C. S. , DUESLER E. N. 
Published: May 2016

AbstractBei der Behandlung mit Alkali in Methanol erhält man aus den ot‐Nitrophenylsulfonoxyketonen (I) die Acetale (II), die sauer zu den α‐Hydroxy‐ketonen (III) gespalten werden.
ChemInform Abstract: Palladium‐Catalysed Decarbonylative Cross Condensation of Acyl Halides.
Authors: KADOKURA M. , MITSUDO T. , WATANABE Y. 
Published: May 2016

AbstractDie substituierten Acetylchloride (I) reagieren mit den Aroylchloriden (II) unter Decarbonylierung zu den Enonen (III).
ChemInform Abstract: Synthesis of Polyfluoroaryl[2.2]cyclophanes.
Authors: FILLER R. , CANTRELL G. L. , WOLANIN D. , NAQVI S. M. 
Published: May 2016

AbstractGemäß Formelschema wird aus dem Dibromid (I) und dem Dithiol (II) über das Dithiametaparacyclophan (III) das neue Tetra?uor[2.2]metaparacyclophan (IV) hergestellt.
ChemInform Abstract: Anionic Aromatic Ring Annelation of o‐Allylbenzamides. Regiospecific Synthesis of Naphthols and Naphthoquinones.
Authors: SIBI M. P. , DANKWARDT J. W. , SNIECKUS V. 
Published: May 2016

AbstractAus den Alkoxy‐benzamiden (I) erhält man nach Metallierung und Umsetzung mit Allylbromid (II) die Allylverbindungen (III), die mit Methyllithium zu den 1‐Naphtholen (IV) cyclisiert werden.
ChemInform Abstract: Preparation of Cyclic Carbonates from Oxiranes and Carbon Dioxide in the Presence of Bifunctional Catalysts.
Authors: KISCH H. , MILLINI R. , WANG I.‐J. 
Published: May 2016

AbstractThe chemoselective formation of Cyclic carbonates is best catalyzed by 1:2 to 1:4 mixtures ofZnC12 with an onium salt such as tetrabutylammonium iodide under mild conditions.
ChemInform Abstract: Search for Structural Parameters Influencing the Anthelminthic Activity of Thiazole Derivatives.
Authors: WALCHSHOFER N. , MINJAT M. , TINLAND B. , JAUSSAUD P. , PETAVY A.‐F. , PARIS J. 
Published: May 2016

AbstractOn reaction of the corresponding Z‐aminothiazoles with the phenylisocyanates, the compounds (I)‐(IV) are produced in 46‐90% yield.
ChemInform Abstract: Unfused Heterobicycles as Amplifiers of Phleomycin. Part 8. Some Bithiazoles.
Authors: COWDEN W. B. , SULLIVAN S. J. , BROWN D. J. 
Published: May 2016

AbstractDie Verbindungsklassen (I)‐(VI) werden durch Anwendung gängiger Methoden in meist mittlerer Ausb. synthetisiert und auf ihre Eigenschaft als Phleomycin‐Verstärker getestet.
ChemInform Abstract: 2‐Oxaadamantane‐1‐N,N,N‐trimethylmethanaminium Iodide: Synthesis and Potential for Muscarinic Activity.
Authors: PARTCH R. , BREWSTER W. , STOKES B. 
Published: May 2016

AbstractAdamantanone (I) undergoes Baeyer‐Villiger oxidation to give the lactone (II).
ChemInform Abstract: Synthesis and Reaction of Biheterocyclic Thiazolo[3,2‐a]pyrimidinium‐betaines.
Authors: YOO K. H. , PARK S. W. 
Published: May 2016

AbstractThe thiazolopyrimidines (I) react with isothio‐ and isocyanates (II) to yield the betaines (III) (only one resonance structure given in the scheme).
ChemInform Abstract: Anti‐Cyclisation Reactions of Enantiomeric 1‐(2,3‐Dihydroxypropyl)uracil Derivatives.
Authors: SKARIC V. , KASNAR B. 
Published: May 2016

AbstractThe (R)‐dihydroxypropyl uracil (Ia) is brominated to give (R)‐(Ib), which is treated with KCN/DMF to give the oxazolopyrimidinediketone (R)‐(IIa).
ChemInform Abstract: A Regioselective Entry to Vinyllithiums from Unsymmetrical Ketones via Enol Triflates.
Authors: WULFF W. D. , PETERSON G. A. , BAUTA W. E. , CHAN K.‐S. , FARON K. L. , GILBERTSON S. R. , KAESLER R. W. , YANG D. C. , MURRAY C. K. 
Published: May 2016

AbstractDie Enoltri?ate (I) reagieren mit Hexamethyldistannan (II) in Gegenwart von Pd(O)‐Katalysatoren zu den Vinylstannanen (III), die nach literaturbekannten Methoden in die entsprechenden Vinyllithiumverbindungen (IV) übergeführt werden können.
ChemInform Abstract: Structure and Reactivity Towards Oxygen Transfer of Pyrazinedicarboxylato Peroxo Titanium Derivatives.
Authors: POSTEL M. , CASABIANCA F. , GAUFFRETEAU Y. , FISCHER J. 
Published: May 2016

AbstractThe 1:1 molar reaction of the titanyl acetylacetonate (II) with 2,3‐pyrazinedicarboxylic acid in the presence of two equiv. of HMPA followed by H2O2 oxidation leads to the monomeric title compound (I).
ChemInform Abstract: Reactive π‐Complexes of the Group VIII Transition Metals. Part 1. (η6‐Arene)‐(η5‐2,5‐dihydro‐1,2,5‐thiadiborol)iron: Syntheses from Bis(arene)iron and Arene‐bis(ethene)iron.
Authors: ZENNECK U. , SUBER L. , PRITZKOW H. , SIEBERT W. 
Published: May 2016

AbstractBis(arene)iron (I), co‐condensation products of Fe and arene, react in the temp. range ‐ 100 to‐60°C with the thiadiborolene (II) to form reactive intermediates which decompose at ‐ 30°C ; the title compounds (III) are obtained.
ChemInform Abstract: Halogenolysis of para‐Substituted Benzyl Cobaloximes. Part 2.
Authors: GUPTA B. D. , KUMAR M. 
Published: May 2016

AbstractThe reaction of benzyl cobaloximes (I) with halogens in the dark forms benzyl halides (II) and benzyl ethers (III) of dimethylglyoxime by an oxidative dealkylation mechanism.
ChemInform Abstract: Reversible Interconversion of C ‐ C and C ‐ N Multiple Bond Systems on Clusters.
Authors: BERNHARDT W. , VON SCHNERING C. , VAHRENKAMP H. 
Published: May 2016

AbstractCluster moieties can be so conditioned by metal exchange that they support one and the same reaction in the region of the organic ligands both in the forward and reverse direction.
ChemInform Abstract: Structure of 2‐Carboxyquinolinatobis(triphenylphosphite)rhodium(I).
Authors: LAMPRECHT G. J. , BEETGE J. H. , LEIPOLDT J. G. , DE WAAL D. R. 
Published: May 2016

AbstractThe title compound (II) is prepared by the Substitution reaction of its dicarbonyl analogue (I) as shown and characterized by X‐ray structure analysis (space group PT, Z=2).
ChemInform Abstract: Porphycene, a Novel Porphin Isomer.
Authors: VOGEL E. , KOECHER M. + , SCHMICKLER H. , LEX J. 
Published: May 2016

AbstractReductive coupling of the dialdehyde (I) with low‐valent titanium yields the desired violet title compound (II) as the only nonpolymeric product (X‐ray analysis: space group = P21/c; Z=2).
ChemInform Abstract: Steroids. Part 236. Synthesis of 19‐Hydroxyaldosterone.
Authors: BIOLLAZ M. , FUHRER H. , KALVODA J. 
Published: May 2016

AbstractThe hydroxycorticosterone (Ia) is derivatized via the acetate (Ib) to give the nitrite (Ic), the photolysis of which yields the nitrone (II) together with the pregnene derivative (III) and the hydrolysis product (Ib).
ChemInform Abstract: Reactions of p‐Toluenesulfonates with Lithium Triethylborohydride.
Authors: BINKLEY R. W. 
Published: May 2016

AbstractDas aus (Ia) erhaltene Tosylat (Ib) reagiert mit Lithiumtriethylborhydrid (II) über (III) zu den Reduktionsprodukten (IV)‐(VI).
ChemInform Abstract: Ring‐Extended Products from the Reaction of Epoxy Carbonyl Compounds and Nucleic Acid Bases.
Authors: NAIR V. , OFFERMAN R. J. 
Published: May 2016

AbstractAus den Epoxy‐aldehyden (I) erhält man mit den Cytosinen (II) die Bicyclen (III), aus (IV) erhält man mit (IIb) die beiden Kondensate (V) und (VI).
ChemInform Abstract: Synthesis and Neuroleptic Activity of Substituted Benzamides Related to Metoclopramide.
Authors: KUMAR Y. , DE PAULIS T. , BENGTSSON S. , HALL H. , SAELLEMARK M. + , AENGEBY K. + , OEGREN S.‐O. + 
Published: May 2016

AbstractThe benzamides (I)‐(V) are synthesized by treatment of the appropiate amines with the corresponding benzoic acid chlorides (35‐82% yield) followed by demethylation with BBr3 (45‐92%), as shown in the scheme for (IIIa) and (IIIb).
ChemInform Abstract: Electrodeposition and Analysis of Tin Selenide Films.
Authors: ENGELKEN R. D. , BERRY A. K. , VAN DOREN T. P. , BOONE J. L. , SHAHNAZARY A. 
Published: May 2016

AbstractSn1±xSe films have been electrodeposited from acidic aqueous solutions of SnCl2 and SeO2 or H2SeO3 and from DMF solutions of SnCl2 and dissolved gray Se.