bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Asymmetric Synthesis of (R)‐α‐Methyl‐o‐methoxybenzyl Methyl Ether via the Diastereoselective Functionalization of (+)‐(o‐Methoxybenzyl Methyl Ether)chromium Tricarbonyl.
Authors: DAVIES S. G. , GOODFELLOW C. L. 
Published: May 2016

AbstractThe benzyl ether chromium tricarbonyl complex (V) is selectively alkylated with methyl iodide (II) or the methyleneammonium iodides (X), yielding branched benzylic ethers, e.g. (±)‐(VIII), after decomplexation.
ChemInform Abstract: Synthesis of Complexes of Transition Metals with Bis(4‐hydroxy‐3,5‐ditert‐butylphenyl)dithiophosphinic Acid.
Authors: RAFIEVA S. R. , MAMEDOV M. KH. , MARKOVA E. I. , DZHANIBEKOV N. F. 
Published: May 2016

AbstractThe acid (III) mentioned in the title is prepared either by reaction of the phenol (I) with phosphorus pentasulfide (II) or from (I) and the dithiadiphosphetane (IV).
ChemInform Abstract: Intramolecular Reactions Between P(III)‐N and C=O Groups, e.g. in O‐Phosphor(III)ylated 2‐Acetylphenol Derivatives.
Authors: MUKHAMETOV F. S. , KORSHIN E. E. , NEKHOROSHKOV V. M. , EFREMOV YU. YA. 
Published: May 2016

Abstract2‐Hydroxyacetophenone (I) is coupled with the phosphonous diamides (Ia), (Ib), or the phosphorodiamidite (Ic) to give the acetylphenyl phosphonamidites (IIIa) and (IIIb) or the phosphoramidite (IIIc).
ChemInform Abstract: Iron‐Hydroperoxide‐Induced Phenylselenization of Hydrocarbons (Fenton Chemisty).
Authors: SHEU C. , SOBKOWIAK A. , ZHANG L. , OZBALIK N. , BARTON D. H. R. , SAWYER D. T. 
Published: May 2016

AbstractThe title reaction is demonstrated in the scheme for the example of cyclohexane (I).
ChemInform Abstract: Preparation and Properties of Tantalum Imido Complexes and Their Reactions with Alkynes. Coordination Control Through Multiple Metal‐Ligand Bonding.
Authors: CHAO Y.‐W. , WEXLER P. A. , WIGLEY D. E. 
Published: May 2016

AbstractThe simple entry into Ta complexes such as (IV) with use of the trimethylsilyl reagent (I) in donor solvents provides a high‐yield route to potential precursors for a variety of mid‐valent tantalum imides.
ChemInform Abstract: Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphin‐Transition Metal Complexes. Part 7. New Chiral Ferrocenylphosphines with C2 Symmetry.
Authors: HAYASHI T. , YAMAMOTO A. , HOJO M. , KISHI K. , ITO Y. , NISHIOKA E. , MIURA H. , YANAGI K. 
Published: May 2016

AbstractThe bis(aminoethyl)ferrocene (I) is lithiated and then coupled with chlorodiphenylphosphine (II), producing a mixture of the racemic bis‐(diphenylphosphino)ferrocene (±)‐(III) and its meso form.
ChemInform Abstract: Synthesis and Characterization of Ir(η4‐C4H6)(N(SiMe2CH2PPh2)2). A Non‐Fluxional Five‐Coordinate Iridium(I) Complex Containing an η4‐Butadiene Ligand.
Authors: FRYZUK M. D. , JOSHI K. , RETTIG S. J. 
Published: May 2016

AbstractBoth the NMR spectral data and the single crystal X‐ray structure of (III) (space group P1 with Z=2) reveal that the tridentate amido‐diphosphine ligand is coordinated in a quasi facial manner.
ChemInform Abstract: First Stereoselective Synthesis of D‐Amino Acid N‐Alkyl Amide Catalyzed by D‐Aminopeptidase.
Authors: KATO Y. , ASANO Y. , NAKAZAWA A. , KONDO K. 
Published: May 2016

AbstractThe first stereoselective synthesis of D‐amino acid N‐alkyl amides such as (III) is achieved by the use of D‐aminopeptidase from Ochrobactrum anthropi in water‐saturated organic solvents.
ChemInform Abstract: Effects of Various Atmospheres on the Reduced‐Pressure CVD of Al2O3 Thin Films at Low Temperatures.
Authors: SARAIE J. , ONO K. , TAKEUCHI S. 
Published: May 2016

AbstractAl2O3 thin films are grown by CVD using Al(OiPr)3 in N2, N2/H2, N2/O2, and N2/H2O, atmospheres.
ChemInform Abstract: Characterization of the ESR Spectrum of the Superoxide Anion in the Liquid Phase.
Authors: BAGCHI R. N. , BOND A. M. , SCHOLZ F. , STOESSER R. + 
Published: May 2016

AbstractESR spectra of the O2‐ radical can be obtained in solution at temp. well above the melting point of aprotic solvents, e.g. propionitrile; hence, frozen or solid‐state media are not required.
ChemInform Abstract: Magnetic Anisotropy of the Y2(Co1‐xFex)14B Intermetallic Compounds
Authors: NGUYEN MINH HONG NGUYEN MINH HONG , FRANSE J. J. M. , NGUYEN PHU THUY NGUYEN PHU THUY 
Published: May 2016

Abstractis determined in the temp. range 4.2‐250 K. The non‐linear concentration dependence of the anisotropy of the Y2(Co,Fe)14B compounds is explained by a simple model of individual site anisotropy in combination with the preferential occupation of different 3d sites by Fe.
ChemInform Abstract: Hydrogen Absorption‐Desorption Kinetics of MmNi5 and Related Compounds
Authors: HUANG P. , GOUDY A. J. , KOH J. T. 
Published: May 2016

Abstract(MmNi4.5Al0.5 and MmNi4.85Fe0.15; Mm: mischmetal) are studied under nearly isothermal conditions at 0, 10, 25, 30, 40, and 50 °C. It is found that aluminum and iron substitution have a deleterious effect on the reaction kinetics of the MmNi5 hydride.
ChemInform Abstract: The Heteronuclear Cluster Chemistry of the Group 1B Metals. Part 12. Variable Temperature NMR Spectroscopic Studies of the Dynamic Behavior of the Mixed‐Metal Cluster Compounds (M2Ru4(μ3‐H)2(μ‐L)(CO)12) (M: Cu or Ag, L: Ph2P(CH2)nPPh2 (n = 1‐6) or cis‐Ph2PCH=CHPPh2; M: Cu, L: Ph2As(CH2)nPPh2 (n = 1 or 2)) in Solution.
Authors: BLAXILL C. P. , BROWN S. S. D. , FRANKLAND J. C. , SALTER I. D. , SIK V. 
Published: May 2016

AbstractThe free energies of activation for the intramolecular metal core rearrangements, which the clusters (I) undergo in solution, are calculated by band‐shape analysis of variable temp. 31P(1H) or 1H NMR spectra or estimated from the coalescence temp. in the spectra.
ChemInform Abstract: Chemistry of Novel Compounds with Multifunctional Carbon Structure. Part 4. Steric and Electronic Influences on the Diastereoisomeric Chemical Shift Differences in 19F NMR Spectra by Introduction of Fluorine, Phenyl, and Heteroatom Groups into Acetates.
Authors: TAKEUCHI Y. , OGURA H. , ISHII Y. , KOIZUMI T. 
Published: May 2016

AbstractIn order to develop reagents which are more efficient than MTPA (α‐methoxy‐α‐trifluoromethylphenylacetic acid) for the determination of enantiomeric excess, several fluoroacetic esters such as (I) are prepared and the 1H and 19F chemical shift differences of their s‐butyl ester, α‐phenylethyl ester and α‐phenylethylamide diastereomeric pairs measured.
ChemInform Abstract: Rearrangement of Isoxazoline‐5‐spiro Derivatives. Part 4. Synthesis of Medium‐Sized Benzofused Azaheterocycles.
Authors: CORDERO F. M. , GOTI A. , DE SARLO F. , GUARNA A. , BRANDI A. 
Published: May 2016

AbstractIn addition to the reaction of C,N‐diphenylnitrone (I) with methylenecyclopropane (II), the analogous reaction of (I) with methylenecyclobutane (VIII) is investigated.
ChemInform Abstract: Asymmetric Synthesis of N‐Acetyl‐1‐phenylethylamine.
Authors: DAVIES S. G. , NEWTON R. F. , WILLIAMS J. M. J. 
Published: May 2016

AbstractThe chromium tricarbonyl complexes (I) and (IV) of benzaldehyde acetals are consecutively treated with titanium tetrachloride and trimethylaluminum (II) to yield the derivatives (III) or (V) due to cleavage and reductive methylation.
ChemInform Abstract: Synthesis and J.H. Activity of N‐Substituted (2‐Alkyl)‐3‐(Substituted‐phenyl)acrylamides.
Authors: BHATIA M. S. , KAUR A. , KAUR B. , CHERIAN X. M. 
Published: May 2016

AbstractThe acrylamides (III) are prepared from the esters (I) by hydrolysis and subsequent coupling with the amines (II).
ChemInform Abstract: Some Studies Towards Preparation of N‐Acyl‐O‐alkylhydroxylamines and O‐Acylhydroxamic Acids.
Authors: SINGHA A. S. , MISRA B. N. 
Published: May 2016

AbstractThe hydroxamic acids (I) are converted into the O‐alkyl (III) and O‐acyl derivatives (V) by reaction with the halides (II) or (IV).
ChemInform Abstract: Synthesis of Condensed Heterocyclic Systems Using 2‐Vinylbenzo(b)thiophene in Diels‐Alder Reaction.
Authors: GHOSH A. , MAITI S. B. , CHATTERJEE A. , RAYCHAUDHURI S. R. 
Published: May 2016

AbstractDiels‐Alder reactions of the title compounds (I) are studied for the first time.
ChemInform Abstract: Synthesis and Fungicidal Activity of Some 3,7‐Diaryl‐6‐cyanorhodanino(4,5‐b)pyridin‐5(4H)‐ones and 3‐Arylrhodanino(4,5‐b)furan‐6(5H)‐ones.
Authors: TIWARI N. , CHATURVEDI B. , NIZAMUDDIN NIZAMUDDIN 
Published: May 2016

AbstractCompounds (V) possess a higher fungicidal activity than compounds (VII).
ChemInform Abstract: Novel Method in Synthesis of 3‐Phenyl‐4‐styryl‐ and 3‐Phenyl‐4‐hydroxycoumarins. Formation of Benzisoxazole‐3‐phenylacetic Acid from 3‐Phenyl‐4‐hydroxycoumarin and NH2OH·HCl.
Authors: LOKHANDE P. D. , GHIYA B. J. 
Published: May 2016

AbstractThe coumarins (IV) and (VII) mentioned in the title are prepared by the esterification of phenylacetic acid (II) with the hydroxybenzenes (I) or (V) and subsequent cyclization of the esters (III) and (VI) respectively.
ChemInform Abstract: Enantiomerically Pure α′,β′‐Difunctionalized α,β‐Enones by Highly Diastereoselective Nucleophilic Alkenoylation of Chiral Aldehydes.
Authors: TEBBEN P. , REGGELIN M. , HOPPE D. 
Published: May 2016

AbstractThe O‐(1‐tosyl‐2‐alkenyl) carbamates (I) are consecutively treated with butyllithium and the aldehydes (II) in the presence of tetra(isopropoxy)titanium to give selectively the enones (III).
ChemInform Abstract: A Novel Synthesis of 2‐Amino‐4,5‐Disubstituted‐thiazole and 6‐Amino‐3‐hydro‐2‐aryl‐4‐arylazothiazolo(5,4‐c)pyridazin‐3‐ones and Their Biological Properties.
Authors: PATEL H. V. , FERNANDES P. S. 
Published: May 2016

AbstractThe bromoacetylhydrazones (I) react with thiourea (II) to give the aminothiazoles (III) which undergo coupling with the aryldiazonium salts (IV) to yield the azo compounds (V).
ChemInform Abstract: Studies on 3‐Aminocoumarin Derivatives as Potent Antifungal and Antibacterial Agents.
Authors: SEN S. , SRIVASTAVA V. 
Published: May 2016

AbstractCoupling of the aminocoumarin (I) with the isothiocyanates (II) yields the thioureas (III) which are cyclized with malonic acid (IV) to give the thiobarbituric acids (V).
ChemInform Abstract: Ring Interconversion Between a 7‐Membered Ring (2,3‐Dihydro‐1,4‐benzodiazepine) and a 14‐Membered Ring (2,3,9,10‐Dibenzo‐1,5,8,12‐tetraazacyclotetradeca‐4,11‐diene).
Authors: BERGMAN J. , BRYNOLF A. 
Published: May 2016

AbstractIn contrast to previous investigations, lithium alanate reduction of the benzodiazepinedione (I) forms the dimer (II) which is further reduced to produce the cyclic tetramine (III).
ChemInform Abstract: Intramolecular Cycloadditions with Nitrile Oxides: Investigations Towards the Synthesis of Heterophanes.
Authors: HEINZE I. , KNOLL K. , MUELLER R. + , EBERBACH W. 
Published: May 2016

AbstractIntramolecular cycloaddition of the nitrile oxide (II) yields the expected isoxazolofuranophane (III) in acceptable yield.
ChemInform Abstract: Arenechromium Tricarbonyl Complexes: Stereoselective Reactions with Isocyanide.
Authors: SOLLADIE‐CAVALLO A. , QUAZZOTTI S. , COLONNA S. , MANFREDI A. 
Published: May 2016

AbstractReaction of the racemic benzaldehydechromium tricarbonyl complexes (±)‐(I) with tosylmethyl isocyanide (II) and a base at 0°C gives almost exclusively the trans‐isomers of the complexed phenyltosyloxazolines (III).
ChemInform Abstract: Alkoxide and Thiolate Rhenium(VII) Oxo‐Alkyl Complexes and Re2O5(CH2CMe3)4, a Compound with a (O2Re‐O‐ReO2)4+ Core.
Authors: CAI S. , HOFFMAN D. M. , WIERDA D. A. 
Published: May 2016

AbstractRe(VII) compounds supported by only two oxo groups are rare.
ChemInform Abstract: Metalladiboranes of the Iron Subgroup: K(M(CO)4(η2‐B2H5)) (M: Fe, Ru, Os) and M′(η5‐C5H5)(CO)2(η2‐B2H5) (M′: Fe, Ru). Analogues of Metal‐Olefin Complexes.
Authors: COFFY T. J. , MEDFORD G. , PLOTKIN J. , LONG G. J. , HUFFMAN J. C. , SHORE S. G. 
Published: May 2016

AbstractThe metalladiboranes (III) and (VI) are prepared according to the scheme and their properties including their NMR spectra, X‐ray structure of (VIa) (space group Pnam, Z=4), and Moessbauer spectra are described.
ChemInform Abstract: Ruthenium Oxo Complexes of Macrocyclic Tertiary Amines. Synthesis, Electrochemistry, and Reactivities of Ruthenium Oxo Complexes of meso‐2,3,7,11,12‐Pentamethyl‐3,7,11,17‐tetraazabicyclo(11.3.1)heptadeca‐1(17),13,15‐triene (L1), and X‐Ray Crystal Structure of trans‐(RuIVL1(O)(NCO))ClO4.
Authors: CHE C.‐M. , TANG W.‐T. , LEE W.‐O. , WONG W.‐T. , LAI T.‐F. 
Published: May 2016

AbstractThe new complexes (III), (IV) (space group P1, Z=2), and (VI) of the title ligand are synthesized according to the scheme.
ChemInform Abstract: Activation of a Vinyl Carbon‐Hydrogen Bond in a Tris(pyrazolyl)boratoiridium Complex. The X‐Ray Crystal Structure of (IrH(HB(pz)3)(σ‐C8H13)(η2‐C8H14)).
Authors: FERNANDEZ M. J. , RODRIGUEZ M. J. , ORO L. A. , LAHOZ F. J. 
Published: May 2016

AbstractThe only product formed in the reaction of (I) and (II) is the vinyl hydrido complex (III).
ChemInform Abstract: Peracid Oxidation of Steroidal Oximes.
Authors: SHAFIULLAH SHAFIULLAH , SIDDIQUI I. H. 
Published: May 2016

AbstractOxidation of the cholestenone oxime (I) with perbenzoic acid yields the nitrooxirane (II), the oxetane (III), and the nitrocarboxylic acid (IV).
ChemInform Abstract: IR Spectra of As4‐Ozone Reaction and Photolysis Products in Solid Argon.
Authors: ANDREWS L. , MIELKE Z. 
Published: May 2016

AbstractThe codeposition of As4 and O3 with excess argon at 14‐17 K produces new IR bands at 921.7, 590.3 and 565.4 cm‐1, whose intensities are increased by red‐light photolysis.
ChemInform Abstract: IR Spectroscopic Studies of Amination of ZSM‐5 Zeolites.
Authors: FINK P. , DATKA J. 
Published: May 2016

AbstractThe reaction between dry NH3 and NaZSM‐5 (only 3743 cm‐1 Si‐OH groups) or NaHZSM‐5 (3743 cm‐1 Si‐OH groups and 3609 cm‐1 Si‐OH···Al groups) at temp. in the range 673‐1073 K is found to produce Si‐NH2 and Si‐NH2···Al groups, the amination of bridged Si‐OH···Al groups occurring at lower temp. than that of Si‐OH groups.
ChemInform Abstract: Anodic Oxidation of Alkylated Biphenyls. Synthetic Routes to Certain Cyclohexa‐1,4‐dienes.
Authors: BARBA I. , CHINCHILLA R. , GOMEZ C. 
Published: May 2016

Abstract3‐Methylbiphenyl (I) is subjected to anodic oxidation in the presence of sodium methoxide (II) to give the trimethoxycyclohexadienes (III) and (IV) which are hydrolyzed with acids, forming the cyclohexadienones (V) and (VI).
ChemInform Abstract: New Photoproducts in the High‐Intensity Solution Photolysis of Octacyanotungstate(V) Ion: Definition of a High‐Energy Photochemical Channel.
Authors: SIEKLUCKA B. , ALCOCK N. W. , KEMP T. J. , VINCZE L. , STUFKENS D. J. 
Published: May 2016

AbstractFrom the aqueous photolysate containing the mixture of photoproducts after high‐intensity photolysis of K3(W(CN)8) the product (I) and, from methanol‐water, the product (II) are isolated following precipitation with PPh4+Cl‐.
ChemInform Abstract: Chiral Ligands Containing Heteroatoms. Part 4. Temperature Dependence of Enantioselectivity in a Tin(II) Hydride Reduction of Ketones.
Authors: FALORNI M. , LARDICCI L. , PIRODDI A. M. , GIACOMELLI G. 
Published: May 2016

AbstractChiral reducing agents are prepared from SnCl2, (iBu)2AlH and optically active diamines.
ChemInform Abstract: Aromatics Formation from Alumina‐Catalyzed Reactions of Methanol with Aliphatic and Alicyclic Carbonyl Compounds.
Authors: GANESAN K. , PILLAI C. N. 
Published: May 2016

AbstractAt 250‐260 °C the series of reactions (alkylation, dealkylation, condensation, and cleavage) of acetone (I) with MeOH (II) over Al2O3 leads to a mixture of simple ketones such as (III) and (IV) and the aromatics (V) and (VI).
ChemInform Abstract: Triethylborane‐Induced Stereoselective Radical Addition of Perfluoroalkyl Iodides to Acetylenes.
Authors: TAKEYAMA Y. , ICHINOSE Y. , OSHIMA K. , UTIMOTO K. 
Published: May 2016

AbstractThe alkynes (I) react with the perfluoroalkyl iodides (II) in the presence of triethylboron to form exclusively the iodo olefines (III) bearing the iodide and the perfluoroalkyl substituent in trans‐position.
ChemInform Abstract: Unsolvated Magnesium Diisopropylamide in Organic Synthesis. Part 2. Reduction of Nitro, Nitroso, and Azoxy Compounds.
Authors: SANCHEZ R. , VEST G. , SCOTT W. , ENGEL P. S. 
Published: May 2016

AbstractReaction of the title agent with equimolar amounts of nitro‐ (I) or nitrosoarenes (III) yields the azoxyarenes (II) and the azoarene (IV).
ChemInform Abstract: Bromofluorination of Allylic Alcohols and NBS/Et3N, 3HF: A Simple Access to Epifluorohydrines.
Authors: CHEHIDI I. , CHAABOUNI M. M. , BAKLOUTI A. 
Published: May 2016

AbstractTreatment of the allylic alcohols (I) with NBS and triethylamine tris‐(hydrofluoride) yields the 3‐bromo 2‐fluoro alcohols (II), and/or the 2‐bromo 3‐fluoro regioisomers (III).
ChemInform Abstract: Synthesis and Immunotropic Properties of Novel 2‐Methoxy‐2,3‐dihydrofurans.
Authors: TOLSTIKOV G. A. , RATNIKOV V. I. , MIFTAKHOV M. S. , VAISPAPIR M. R. , VALEEV F. A. , AKHMETVALEEV R. R. , KHALIKOV R. M. 
Published: May 2016

AbstractStarting with ethyl acetoacetate (I), the dihydrofurans (VI) and (VII) are prepared via the acetylbutenoate (III).
ChemInform Abstract: Aromatization of Aliphatic Compounds. Part 9. Benzofuranones from (4‐Substituted 2‐Oxo‐3‐cyclohexen‐1‐yl)Acetic Acids.
Authors: BAIOCCHI L. , BONANOMI M. 
Published: May 2016

AbstractThe title compounds (II) (17 examples) are prepared by the new synthetic procedure shown.
ChemInform Abstract: Hypervalent Iodine Oxidation: Synthesis of 5‐Substituted‐2(5H)‐Furanones Using Iodosobenzene.
Authors: MORIARTY R. M. , VAID R. K. , HOPKINS T. E. , VAID B. K. , TUNCAY A. 
Published: May 2016

AbstractThe 2‐(trimethylsiloxy)furans (I) react with iodosobenzene in the presence of the nucleophiles (II) to form the 5‐substituted 2‐furanones (III).
ChemInform Abstract: Lewis Acid‐Catalyzed Cycloaddition of 1,3‐Bistrimethylsilyloxycyclohexadienes to 2‐Chloroacrylonitrile. Novel Rearrangement of the Resulting Adducts to Cyclohexenones.
Authors: CLARK R. S. J. , HOLMES A. B. , MATASSA V. G. 
Published: May 2016

AbstractThe disiloxycyclohexadienes (I) are subjected to cycloaddition reaction with 2‐chloroacrylonitrile (II), to form the cycloadducts (III), together with the anti‐isomer (IVb).
ChemInform Abstract: Radical Addition to Amide‐Substituted Alkenes: Stereoselective Intermolecular Radical Additions.
Authors: PORTER N. A. , SCOTT D. M. , LACHER B. , GIESE B. , ZEITZ H. G. , LINDNER H. J. 
Published: May 2016

AbstractThe addition of alkyl radicals such as (II), generated by the tin or mercury method, to fumaric amides or diamides such as (I) is shown to be stereoselective in many cases.
ChemInform Abstract: Reaction of Trimethylsilyl Derivatives with Meldrum′s Acid: A New and Easy Monofunctionalization of Malonic Acid.
Authors: RIGO B. , FASSEUR D. , CAULIEZ P. , COUTURIER D. 
Published: May 2016

AbstractMeldrum's acid (I) reacts with the trimethylsilylated nucleophiles (II) to give the trimethylsilyl acetoacetates (III) and acetone (IV).
ChemInform Abstract: A New Building Block Method to Synthesize Symmetrical and Asymmetrical Per‐N‐alkyl‐Substituted Polyaza‐Crown Compounds.
Authors: KRAKOWIAK K. E. , BRADSHAW J. S. , IZATT R. M. , ZAMECKA‐KRAKOWIAK D. J. 
Published: May 2016

AbstractN‐Acetylation of 2‐(2‐aminoethoxy)ethanol (I) gives the acetamide (III) which is chlorinated to yield the key intermediate (IV).
ChemInform Abstract: Complexes of 2‐(2′‐Pyridyl)quinoline and 3,6‐Di(4′‐pyridyl)‐s‐tetrazine.
Authors: ZAGHAL M. H. , QASEER H. A. 
Published: May 2016

AbstractThe reaction of the pyridylquinoline with RhCl3, K3(RhBr6) (prepared in situ) and MY2(PhCN)2 (M: Pd, Pt; Y: Cl, Br, I) in CHCl3 or acetone gives the complexes (I) and (II) in yields from 40‐85%.
ChemInform Abstract: A Novel Type of Tetranuclear Cluster with the Trinucleating Ligand 1,2‐Bis(benzimidazol‐2‐yl)‐1‐hydroxyethane. Crystal and Molecular Structure of Ni(HRSL)2(CF3SO3)2 and (Cu4(SL)4(NO3)2(EtOH))(NO3)2(EtOH)3(H2O)2; Spectroscopy and Magnetism of These and Related Transition Metal Compounds.
Authors: VAN ALBADA G. A. , REEDIJK J. , HAEMAELAEINEN R. + , TURPEINEN U. , SPEK A. L. 
Published: May 2016

AbstractThe title ligand forms the mononuclear complexes of the general formula (I) for all metal ions for the racemic mixture and in the case of Cu also for the chiral (S) ligand.
ChemInform Abstract: Ruthenium Complexes of Some Selected N‐S Donors. Part 2. Ligational Behavior of 2‐Formylpyridine(4‐phenyl) Thiosemicarbazone Toward Ruthenium.
Authors: CHATTOPADHYAY S. K. , GHOSH S. 
Published: May 2016

AbstractRu(II) and Ru(III) complexes of the biologically active tridentate NNS donor title ligand HL1 (II) are synthesized and characterized by elemental analysis, conductance and magnetic susceptibility measurements as well as by spectroscopic (UV/VIS, IR, NMR) techniques.
ChemInform Abstract: Novel Rhodium Porphyrin Derivatives. Part 4. A Study of the Interaction Between Rhodium Porphyrinates and Amides.
Authors: BOSCHI T. , LICOCCIA S. , PAOLESSE R. , TAGLIATESTA P. , MARCONI W. 
Published: May 2016

AbstractThe mechanisms of the reactions shown in the scheme, employing amides with different lengths of the alkyl chains bound to N or C, are discussed.
ChemInform Abstract: Bicyclic β‐Enamino Esters: Synthesis and Stereospecific Reduction. Access to Isoretronecanol, Trachelanthamidine, Lupinine and Epilupinine.
Authors: CELERIER J. P. , HADDAD M. , SALIOU C. , LHOMMET G. , DHIMANE H. , POMMELET J. C. , CHUCHE J. 
Published: May 2016

AbstractCatalytic hydrogenation of the title esters (VII) and (XIII) at 100 °C leads to the products (VIII) and (XIV), resp., while at 200 °C the epimeric esters are formed.
ChemInform Abstract: Synthesis of 9‐(3‐Deoxy‐ and 2,3‐Dideoxy‐3‐fluoro‐β‐D‐xylofuranosyl) Guanines as Potential Antiviral Agents.
Authors: PUECH F. , GOSSELIN G. , IMBACH J.‐L. 
Published: May 2016

AbstractThe nucleosides (XI) mentioned in the title are prepared as shown in the reaction scheme.
ChemInform Abstract: New Aromatic Musk Odorants: Design and Synthesis.
Authors: FEHR C. , GALINDO J. , HAUBRICHS R. , PERRET R. 
Published: May 2016

AbstractBy appropriate structural modification of known musk odorants, new strong analogues such as (IV), (VIII) or (XIII) possessing supplementary CH3 or CH2 groups in the basic musk skeleton are prepared.
ChemInform Abstract: Complexes of Silicon Tetrafluoroborate with Ammonia.
Authors: GEL'MBOL'DT V. O. , ENNAN A. A. , SAKHAROV A. V. , SUKHOVERKHOV V. F. 
Published: May 2016

AbstractReview: A literature survey is given of the experimental and calculated details on the stereochemistry, the electronic structure and the energetic characteristics of the complexes specified in the title (53 refs.
ChemInform Abstract: Kinetics of Ferrate(V) Decay in Aqueous Solution. A Pulse‐Radiolysis Study.
Authors: RUSH J. D. , BIELSKI B. H. J. 
Published: May 2016

AbstractWith the goal to obtain closer comparison with the parent ferrate(VI) ion and to obtain additional information on the factors contributing to the reactivity of the oxo‐iron bond, the spectral and kinetic properties of ferrate(V) derived from pulse‐radiolytic reduction of aqueous ferrate(VI) by 2‐propanol radicals are characterized between pH 6 and 13. In this pH range three forms of Fe(V) occur, which are represented by the equilibria shown in the scheme.
ChemInform Abstract: Systematic Design of Chemical Oscillators. Part 61. Oxidation of Hydroxylamine by Periodate in a Continuous‐Flow Stirred Tank Reactor: A New pH Oscillator.
Authors: RABAI G. , EPSTEIN I. R. 
Published: May 2016

AbstractThe periodate oxidation of hydroxylamine shows different features depending on the starting NH2OH/IO4 ratio (r).
ChemInform Abstract: Structure of the Lanthanum Chlorosilicate La3(SiO4)Cl5.
Authors: GRAVEREAU P. , ES‐SAKHI B. , FOUASSIER C. 
Published: May 2016

AbstractSingle crystals of the title compound, synthesized by the solid‐state reaction shown in the scheme, belong to the orthorhombic space group Pnma, Z=4.