bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Heterocyclic β‐Enamino Esters. Part 49. Syntheses of Heterocycles wit Dihalotriphenylphosphoranes. Part 17. Furo(3,2‐e)quinazolines, Furo(2,3‐f)phthalazine, and (4 + 2) Adducts with 4‐Phenyl‐1,2,4‐triazoline‐3,5‐dione to Benzofurans, Indoles, and Benzo(b)thiophenes.
Authors: WAMHOFF H. , FASSBENDER F.‐J. , NIEGER M. 
Published: May 2016

AbstractThe compounds (I) and (IV) undergo (4 + 2)cycloaddition with the title triazoline (II).
ChemInform Abstract: The Reaction of Cysteine with 1,4‐Benzoquinone: A Revision.
Authors: CRESCENZI O. , PROTA G. , SCHULTZ T. , WOLFRAM L. J. 
Published: May 2016

AbstractThe title reaction yields the benzothiazine oligomer (IV) as major product, which is most likely formed via trimerization of the intermediate (III).
ChemInform Abstract: Heterocyclic Seven‐Membered Ring Compounds. Part 33. Synthesis and Properties of 5‐Methoxy‐1,4‐benzothiazepine and of 5‐Methoxy‐1‐methyl‐1,4‐benzothiazepinium Tetrafluoroborate.
Authors: HOFMANN H. , FISCHER H. 
Published: May 2016

AbstractLoss of sulfur has been observed on thermal treatment of 4‐methoxy‐1,5‐benzothiazepine.
ChemInform Abstract: Preparations, X‐Ray Crystal Structures, and Spectral Studies of Seleninyl Bis(trifluoromethanesulfonate) and Seleninyl Bis(acetate).
Authors: KAPOOR R. , WADHAWAN P. , KAPOOR P. , SAWYER J. F. 
Published: May 2016

AbstractBoth of the title compounds (I) and (II) are prepared from SeOCl2 and trifluoromethane sulfonic acid anhydride or acetate, resp. (no yields given).
ChemInform Abstract: Transition Metal Heterocyclic Chemistry. Part 9. An α‐Seleno Ketoketene. Trapping Subsequent to Oxidative Release from Tricarbonyliron Complexes to Form Vinyl Selenides.
Authors: PANNEL K. H. , MAYR A. J. , CARRASCO‐FLORES B. 
Published: May 2016

AbstractCleavage of the selenoiron carbonyl complex (I) with trimethylamine oxide in the presence of the alcohols (II) results in the formation of the diselenides (III).
ChemInform Abstract: Preparation and Structural Characterization of Methylmercury(II) Complexes of the Minor tRNA‐Base 7‐Methylguanine.
Authors: SHELDRICK W. S. , GROSS P. 
Published: May 2016

AbstractThe methyl‐Hg(II) complexes (I)‐(V) of 7‐methylguanine are isolated from aqueous solution depending on the pH value and molar ratio and characterized by 1H NMR spectroscopy.
ChemInform Abstract: Coordinatively Unsaturated Alkyne Complexes of Tungsten: Synthesis and Dynamic NMR Studies of Some But‐2‐yne Derivatives.
Authors: DAVIDSON J. L. , VASAPOLLO G. 
Published: May 2016

AbstractAs demonstrated for (IIIa) the reactions of bidentate anions with the dimer (I) proceed via sequential displacement of bromide, giving the monomeric bis‐alkyne complexes (III) as the initial products.
ChemInform Abstract: (Fp‐η1‐(1‐polycycloalkyl)methylidene)+ to (Fp‐η2‐(1‐homopolycycloalkene))+ Rearrangement. Carbon Migration in Iron(II) Alkylidenes. A New Route to Stabilized Bridgehead Olefins.
Authors: BLY R. S. , BLY R. K. , HOSSAIN M. M. , LEBIODA L. , RAJA M. 
Published: May 2016

AbstractThe acyl (I) is converted into a diastereomeric mixture of the methoxyalkyls (III).
ChemInform Abstract: Conversion of Chelated Hydroxy‐L‐proline into Pyrrole‐2‐carboxylate.
Authors: HAMMERSHOI A. , HARTSHORN R. M. , SARGESON A. M. 
Published: May 2016

AbstractThe hydroxy‐L‐prolinatocobalt complex (I) is oxidized on treatment with thionyl chloride, producing the dihydropyrrole complexes (II) or (III).
ChemInform Abstract: Reaction of Primary Silanes with a Binuclear Rhodium Complex. Formation of μ‐Silylene Complexes and Rapid Si‐H/Rh‐H Exchange.
Authors: WANG W.‐D. , HOMMELTOFT S. I. , EISENBERG R. 
Published: May 2016

AbstractThe prim. silanes (II) react with the binuclear complex (I) to produce in sequence the μ‐silylene dihydride species (III) and the bis(silylene) complexes (IV).
ChemInform Abstract: Synthesis and Antitumor Activity of a Series of 1,2‐Diaminocyclohexanepalladium(II) Dicarboxylate Complexes.
Authors: KHOKHAR A. R. , LUMETTA G. J. 
Published: May 2016

AbstractThe title complexes (I) are prepared from sulfato(1,2‐cyclohexanediamine)‐Pd(II) and corresponding disodium or barium dicarboxylates or from diaquo(1,2‐cyclohexanediamine)‐Pd dinitrate and disodium dicarboxylates.
ChemInform Abstract: Diborylethene Compounds as Ligands in Metal Complexes. Part 19. New Coordination Patterns of 2,3‐Dihydro‐1H‐1,3‐diboroles and 2,3‐Dihydro‐1H‐1,3‐diborolyls in Platinum Complexes.
Authors: WADEPOHL H. , ROEMICH H. + , PRITZKOW H. , SIEBERT W. 
Published: May 2016

AbstractBis(cyclooctadiene)‐Pt (I) reacts with the dihydro‐1H‐diborole (II) to yield the isomeric 16‐VE complexes (III) and (IV).
ChemInform Abstract: Preparation of Phenylplatinum‐Zirconium Complexes with Ph2PC5H4 or PhP(C5H4)2 Bridging Ligands and Their Reactions with Carbon Monoxide.
Authors: ANDERSON G. K. , LIN M. 
Published: May 2016

AbstractThe reaction of (I) with (II) produces (III) with cis geometry at Pt.
ChemInform Abstract: Extraction‐Photometric Determination of Indium with 8‐Quinolinol in Layered Crystals of the Type AV 2BVI 3.
Authors: SRAMKOVA J. , KOTRLY S. , KALISCHOVA Y. 
Published: May 2016

AbstractA method for the quantitative analysis of indium in samples of In‐doped Bi2Te3 is described.
ChemInform Abstract: Na2SiF6 and Ordered Trirutile Types: Crystal and Magnetic Structure of α‐ and β‐LiMnVF6.
Authors: COURBION G. , JACOBONI C. , WOLFERS P. 
Published: May 2016

Abstractα‐LiMnVF6 (I) crystallizes in the Na2SiF6‐type structure, space group P321, Z=3.
ChemInform Abstract: Transformation of Allylsilanes into Allylamines via Phenyltellurinylation.
Authors: HU N. X. , ASO Y. , OTSUBO T. , OGURA F. 
Published: May 2016

AbstractThe allylsilane (I) is coupled with the tellurinyl triflate (II) in the presence of a Lewis acid to give the intermediate telluroxide (III) which reacts with the primary (IV) or secondary amines (VII), producing the allylic amines (V), (VI), or (VIII).
ChemInform Abstract: Properties of Indium Oxide Films Doped by Cerium.
Authors: SUKHAREV YU. G. , TROSTYANSKAYA N. I. , BOIKO V. A. 
Published: May 2016

AbstractTransparent films of In2O3 have an electric resistivity of ρ = 22·10‐4 Ω·cm and a mobility of the free charge carriers of μ = 49.5 cm·V‐1·s‐1.
ChemInform Abstract: Thermolysis of 7‐(Acylamino)‐7‐azabenzonorbornadienes and 1‐(Acylamino)aziridines. Generation and Trapping of Monosubstituted Azamines.
Authors: CARPINO L. A. , PADYKULA R. E. , LEE S.‐N. , HAN G. Y. , KIRKLEY R. K. 
Published: May 2016

AbstractThermolysis of the 7‐amino‐7‐azanorbornadiene (I) in inert solvents yields only naphthalene (II) and the hydrazine (III).
ChemInform Abstract: Electrochemical Study of Halides and Oxyhalides in LiAlCl4, 3 SO2 Electrolyte. Part 2. Comparison Between SO2Cl2, SOCl2, and Cl2.
Authors: LOJOU E. , MESSINA R. , PERICHON J. , DESCROIX J. P. , SARRE G. 
Published: May 2016

AbstractThe electrochemical study of the systems Li/Cl2, Li/SO2Cl2, and Li/SOCl2 at microelectrodes shows that the corresponding reduction processes in the LiAlCl4·3 SO2 electrolyte are all diffusion controlled.
ChemInform Abstract: Surface Chemistry of Sputter‐Deposited Al‐Mo and Al‐Cr Alloys Polarized in 0.1 N KCl.
Authors: MOSHIER W. C. , DAVIS G. D. , COTE G. O. 
Published: May 2016

AbstractThe influence of alloying elements such as Mo and Cr on the behavior of the passive films on Al alloys in Cl‐‐containing environments is studied as a function of solute concentration and applied potential in 0.1 N KCl.
ChemInform Abstract: Enantioselective Catalysis. Part 47. Rhodium(II)‐Carboxylate Complexes and Their Use in the Enantioselective Cyclopropanation.
Authors: BRUNNER H. , KLUSCHANZOFF H. , WUTZ K. 
Published: May 2016

AbstractThirteen optically active complexes of type (I) are synthesized and used as catalysts in the cyclopropanation of styrene with ethyl diazoacetate.
ChemInform Abstract: Enzymatically Cleavable (Alkoxycarbonyl)ethoxymethyl Esters for Reversible Blocking of Carboxyl Groups.
Authors: KLEMM D. , GESCHWEND G. 
Published: May 2016

AbstractThe carboxylic (I) and dicarboxylic acids (IV) are converted to the (alkoxycarbonyl)ethoxymethyl carboxylates (III) or (V) upon reaction with the bromoethoxyacetate (II) in the presence of a base.
ChemInform Abstract: A Novel Synthesis of Ketoprofen, Important Non‐Steroidal Antiinflammatory Agent.
Authors: MITRA R. B. , JOSHI V. S. 
Published: May 2016

AbstractThe benzylcyclohexanone (III) obtained by Grignard reaction is subjected to Wittig‐Horner olefination with the 2‐phosphorylpropionate (IV), yielding the 2‐cyclohexenylpropionate (V).
ChemInform Abstract: Reaction of 4‐Nitrophthalodinitrile with Pyrrolidine.
Authors: BERZIN'SH E. L. , ROZE M. P. , NEILAND O. YA. , GAVAR M. P. 
Published: May 2016

AbstractThe reaction specified in the title affords the 1‐pyrrolidino derivative (III) as the main product by substitution of a cyano group.
ChemInform Abstract: Pyridazine Compounds. Part 19. Mesylation of 5‐Aminopyrazoles and Related Compounds.
Authors: SZILAGYI G. , DVORTSAK P. 
Published: May 2016

AbstractThe mesylation of the methylated aminopyrazoles (Ia), (Ic) gives mixtures of the di‐ (III) and so‐called trimesylated compounds (IV) whereas no products analogous to (IV) are formed from the mesylation of the phenylated aminopyrazoles (Ib), (Id) due to steric hindrance.
ChemInform Abstract: Synthesis of 2‐Aminomethylpyridines from Aminonitriles and Acetylene.
Authors: IVANOV A. P. , LEVIN D. Z. , MORTIKOV E. S. , PROMONENKOV V. K. 
Published: May 2016

AbstractIn the presence of cobaltocene, the reaction between the α‐aminonitriles (I) and acetylene (II) affords the title compounds (III) in fair to good yields.
ChemInform Abstract: Optically Active Phosphine Oxides. Part 6. Conjugate Addition of Thiols and Alcohols to (S)‐(‐)‐Methylphenylvinylphosphine Oxide.
Authors: PIETRUSIEWICZ K. M. , ZABLOCKA M. 
Published: May 2016

AbstractThe optically active vinylphosphine oxide (I) undergoes addition reaction with the thiols and alcohols (II), forming the corresponding ether derivatives (IIIa) ‐ (IIIe).
ChemInform Abstract: Carbonyliron Complexes of a 1,3‐Dihydro‐1,3‐diborapentafulvene Derivative.
Authors: BRODT G. , SIEBERT W. 
Published: May 2016

AbstractThe tricarbonyl‐Fe complex (III) and the heptacarbonyldiiron complex (IV) are prepared as shown in the scheme depending on the stoichiometric ratio.
ChemInform Abstract: Limits of Direct Transmetalation of Polynuclear Copper(II) Complexes with M(NS)n Reagents. Scissor Transmetalators. Synthesis and Properties of the Trimers (μ3‐O)(N,py)3Cu3X4 (N: N,N‐Diethylnicotinamide; py: Pyridine, X: Cl, Br).
Authors: ABU‐RAQABAH A. , DAVIES G. , EL‐SAYED M. A. , EL‐TOUKHY A. , HENARY M. 
Published: May 2016

AbstractThe practical limit of direct, stoichiometric transmetalation of the tetranuclear Cu(II) complex (I), its hexabromo and tetrakis(pyridine) analogues with the Co(III), Ni(II), Zn(II), Cd(II), Hg(II), and Sn(II) reagents (II) and (IV) is reagent‐dependent.
ChemInform Abstract: Sulfidation Behavior of an Iron‐Nickel Alloy
Authors: ORCHARD J. P. , YOUNG D. J. 
Published: May 2016

Abstractcontaining 41 wt% Ni is studied as a function of the H2S partial pressure of H2/H2S/N2 gas mixtures at temp. in the range 793‐938 K. At 793 K, the sulfidation product consists of an inner compact layer of (Fe, Ni)1‐xS and pentlandite overgrown by layers of pentlandite and Ni‐rich sulfide whiskers.
ChemInform Abstract: Diastereoselective Crossed Aldol Reactions with Chiral Fluorinated Aldehydes.
Authors: YAMAZAKI T. , YAMAMOTO T. , KITAZUME T. 
Published: May 2016

AbstractThe optically active malonate (S)‐(I) is converted to the chiral aldehydes (II) and the enantiomer of (IIa).
ChemInform Abstract: Molecular Recognition in Cytochrome P‐450: Alteration of Regioselective Alkane Hydroxylation via Protein Engineering.
Authors: ATKINS W. M. , SLIGAR S. G. 
Published: May 2016

AbstractThe variation of three active sites in cytochrome P‐450 affords changes in the regioselectivity of hydroxylation of camphor (II) and its demethylated derivatives such as (IV).
ChemInform Abstract: Dianion of N‐Phenyl‐2‐((phenylsulfonyl)methyl)propenamide as a Versatile Reagent for the Preparation of α‐Methylene Carbonyl Compounds.
Authors: TANAKA K. , HORIUCHI H. , YODA H. 
Published: May 2016

AbstractThe dianion (III) mentioned in the title is coupled with the aldehydes (IV) to produce the anilides (V), together with minor amounts of the sulfonylmethylene derivatives (VI).
ChemInform Abstract: Recyclization of 6(8)‐Nitro‐3‐trifluoroacetyl‐2‐phenylindolizine with Formation of 5(7)‐Nitro‐3‐phenyl‐2‐indolecarboxylic Acid.
Authors: BABAEV E. V. , BOBROVSKII S. I. , BUNDEL' YU. G. 
Published: May 2016

AbstractThe indolizines (I) are coupled with trifluoroacetic anhydride (II) to give the 3‐acyl derivatives (III).
ChemInform Abstract: Reactions of Pyridinium or Isoquinolinium Ketene Dithioacetals with Aromatic N‐Imines and S‐Imines.
Authors: TOMINAGA Y. , HOSOMI A. 
Published: May 2016

AbstractThe pyridinium ketene dithioacetal (I) reacts with the 1‐aminopyridinium salts (II) in the presence of triethylamine to produce the imidazopyridines (III) and/or the pyrazolopyridines (IV).
ChemInform Abstract: The Reactions of Thiosemicarbazides and 5‐Halovalerophenones.
Authors: KANE J. M. , STEWART K. T. 
Published: May 2016

AbstractThe 5‐chlorovalerophenones (I) undergo cyclization with the 4‐substituted thiosemicarbazides (II) in a basic methanolic solution, forming the tetrahydrodiazepinethiocarboxylic amides (III).
ChemInform Abstract: Polyfunctional Macroheterocycles. Part 2. Synthesis of Crown Compounds Containing Dimethyl Aspartate Fragments.
Authors: VORONKOV M. G. , KNUTOV V. I. , BUTIN M. K. 
Published: May 2016

AbstractThe aziridinylsuccinic acid ester (I) reacts with thioglycol (II) to give the diamine (III) which is coupled with the dicarboxylic dichlorides (IV) or formaldehyde (VII), producing the crown compounds (V) and (VIII).
ChemInform Abstract: Preparation and Characterization of n‐ and i‐Butylindium Thiolate.
Authors: NOMURA R. , INAZAWA S. , KANAYA K. , MATSUDA H. 
Published: May 2016

AbstractThe title thiolates (I) and (II) are prepared in the reactions of the corresponding thiols with Bu3In and iBu3In, resp., in ether.
ChemInform Abstract: The Synthesis of Some Tris‐(3,5‐dimethylpyrazol‐1‐yl)‐boratotrisaryloxozirconium(IV) Complexes. The Molecular Structure of (Zr(HB(3,5‐Me2C3N2H)3) (OC6H4(NO2))3).
Authors: KRESINSKI R. A. , HAMOR T. A. , ISAM L. , JONES C. J. , MCCLEVERTY J. A. 
Published: May 2016

AbstractIn order to get insight into the ability of sterically demanding tripodal ligands to regulate the chemistry at metal centers the complexes (III) are prepared ((IIIa): space group R3, Z=2).
ChemInform Abstract: Metal Complexes of Antiinflammatory Drugs. Part 6. 2‐Aminomethyl‐5(1,1‐dimethylethyl)‐3‐iodophenol (MK‐447) Complex of Copper(II).
Authors: BURY A. , UNDERHILL A. E. , FLEET M. B. , KEYMER P. J. , STEVENS A. , GOMM P. S. 
Published: May 2016

AbstractThe octahedral title complex, containing the water axially coordinated, is prepared by reaction of the ligand with CuCl2 in water at pH 12 and characterized by IR and electronic spectral data.
ChemInform Abstract: Synthesis of Diphenylphosphido‐Bridged Manganese‐Gold Complexes. Crystal Structures of (N(PPh3)2) (Au2Mn(μ‐PPh2)2(CO)4(C6F5)2) and (Au2Mn2(μ‐PPh2)4(CO)8).
Authors: CARRIEDO G. A. , RIERA V. , RODRIGUEZ M. L. , JONES P. G. , LAUTNER J. 
Published: May 2016

AbstractThe MnAu complexes (III), (V), (VIII)‐(X) are prepared from the corresponding Mn(I) salts (I) and (VI) by reaction with the Au(I) complexes (II), (IV), and (VII) in the presence of K(acac), Tl(acac), or (N(PPh3)2) (acac) or mixtures of these reagents in appropriate molar rations.
ChemInform Abstract: Syntheses, Electrochemistry, and Spectroscopy of Dirhodium(II) Tetraacetamidate and Tetrakis(trifluoroacetamidate) Complexes with Axial Group 15 Substituents. The X‐Ray Crystal Structures of (Rh2(CH3CONH)4(AsPh3)2) and (Rh2(CH3CONH)4‐n(CH3CO2)n (MPh3)2), M: As or Sb, n ≈ 1.
Authors: BEST S. P. , CHANDLEY P. , CLARK R. J. H. , MCCARTHY S. , HURSTHOUSE M. B. , BATES P. A. 
Published: May 2016

AbstractThe title complexes (I) are obtained from tetrakis(acetato)dirhodium by reaction with appropriate amounts of acetamide or trifluoroacetamide at 120 and 160 °C in vacuo and subsequent treatment of the prepared tetrakis(acetamidato)dirhodium products with MPh3 in MeOH (no yields given).
ChemInform Abstract: Chemical and Electrochemical One‐Electron Oxidation of Diamidonaphthalene‐Bridged Complexes; Paramagnetic (Rh2)3+‐Containing A Frames.
Authors: CONNELLY N. G. , LOYNS A. C. , FERNANDEZ M. J. , MODREGO J. , ORO L. A. 
Published: May 2016

AbstractThe Rh2 complexes (I) undergo two sequential one‐electron oxidations at a Pt bead electrode.
ChemInform Abstract: Trinuclear Mixed‐Valence Complexes with the Linear (Rh3)4+ Core.
Authors: CONNELLY N. G. , LOYNS A. C. , CIRIANO M. A. , FERNANDEZ M. J. , ORO L. A. , VILLARROYA B. E. 
Published: May 2016

AbstractThe monocationic Rh3 complexes (Ia) and (Ib) undergo two reversible one electron oxidations at a Pt bead electrode in CH2Cl2.
ChemInform Abstract: Binuclear Pentamethylcyclopentadienylrhodium(III) Phosphido‐Pyrazolate Complexes. X‐Ray Structure of (((C5Me5)Rh)2(μ‐pz)2(μ‐PPh2))BF4 (pz = pyrazolate).
Authors: LAMATA M. P. , CARMONA D. , ORO L. A. , APREDA M. C. , FOCES‐FOCES C. , CANO F. H. 
Published: May 2016

AbstractThe phosphido‐ and pyrazolato‐bridged dirhodium complexes (III) are prepared according to the scheme and characterized by 31P and 1H NMR spectra.
ChemInform Abstract: Crystal Structure and X‐Ray Photoelectron Spectroscopy of Bis(o‐aminothiophenolato)platinate(II).
Authors: MATSUMOTO K. , FUKUTOMI I. , KINOSHITA I. , OOI S. 
Published: May 2016

AbstractThe trans‐planar title complex is prepared by 1:2 molar reaction of K2PtCl4 with o‐aminothiophenol in MeOH/H2O. Its structure is determined by X‐ray analysis (space group P21/c, Z=2).
ChemInform Abstract: Synthesis of (.+‐.)‐erythro‐ and (.+‐.)‐threo‐1,2‐Diphenyltaurines by Diastereoselective Hydrolysis of Thiazetidine 1,1‐Dioxides.
Authors: GRUNDER E. , LECLERC G. 
Published: May 2016

AbstractCycloaddition reaction of phenylsulfene, generated from benzylsulfonyl chloride (I) and N‐benzylidenebenzylamine (II), with a second equivalent of (II) yields a mixture of cis‐ (IIIa) and trans‐diphenyl‐1,2‐thiazetidine 1,1‐dioxide (IIIb) which is separated by chromatography.
ChemInform Abstract: New Depsides from Dimelaena Lichens.
Authors: ELIX J. A. , EVANS J. E. , NASH T. H. III 
Published: May 2016

AbstractThe novel title compounds (VI), (VIII) and (X) are isolated from Dimelaena californica, from Erioderma wrightii and from Dimelaena thysanota, respectively.
ChemInform Abstract: On the Question of Hypoiodite Ion Formation in the Aqueous Solution of Iodine: Theoretical and Experimental Study of H2OI2 Complex.
Authors: FONSLICK J. , KHAN A. , WEINER B. 
Published: May 2016

AbstractAqueous solutions of iodine exhibit three absorption maxima at 205, 285, and 355 nm with an intensity ratio of 8:2:1.
ChemInform Abstract: Role of Inclusions on Initiation of Crevice Corrosion of Stainless Steel. Part 1. Experimental Studies.
Authors: LOTT S. E. , ALKIRE R. C. 
Published: May 2016

AbstractThe initiation of crevice corrosion on 304 stainless steel in neutral NaCl solution is suggested to be caused by a concerted depassivation effect of Cl‐ and S2O32‐ ions, the latter being produced by electrochemical dissolution of MnS inclusions.
ChemInform Abstract: Infrared Spectroscopic Studies of the Reactions of Copper and Ammonia in Cryogenic Argon Matrices.
Authors: BALL D. W. , HAUGE R. H. , MARGRAVE J. L. 
Published: May 2016

AbstractProlonged photolysis of cocondensed Cu and NH3 in a cryogenic Ar matrix leads to two new sets of absorptions in addition to that of the Cu‐NH3 adduct.
ChemInform Abstract: Synthesis and Thermal Decomposition of Magnesium Hydroxide Nitrates.
Authors: PETROV K. , LYUBCHOVA A. , MARKOV L. 
Published: May 2016

AbstractMg2(OH)3NO3 (hexagonal, space group P3m1) is precipitated by addition of 0.5 M NaOH to a 3 M Mg(NO3)2 solution.
ChemInform Abstract: Neutron Diffraction Structure Analysis of a Hexanuclear Copper Hydrido Complex, H6Cu6(P(p‐tolyl)3)6: An Unexpected Finding.
Authors: STEVENS R. C. , MCLEAN M. R. , BAU R. , KOETZLE T. F. 
Published: May 2016

AbstractThe title complex crystallizes in the space group P1 with Z=2.
ChemInform Abstract: Nonplanar Rh(I) in Rh(PMe2Ph)+ 4: Magnitude and Origin of the Distortion.
Authors: LUNDQUIST E. G. , STREIB W. E. , CAULTON K. G. 
Published: May 2016

AbstractThe spectroscopic (1H, 31P NMR) identification of the title complex as its BF4 salt is confirmed by an X‐ray diffraction study (P1, Z=2).
ChemInform Abstract: Correlation Between Geometric Changes of the Ligands and Extinction Coefficient of the MLCT Absorption Band in Ru(II)‐Diimine Complexes.
Authors: DE COLA L. , BARIGELLETTI F. 
Published: May 2016

AbstractThe spectroscopic and electrochemical properties of the complexes (I) are correlated with the LUMO properties of the ligands.
ChemInform Abstract: Solvent Effects on the Thermochemistry of Free‐Radical Reactions.
Authors: KANABUS‐KAMINSKA J. M. , GILBERT B. C. , GRILLER D. 
Published: May 2016

AbstractHeats of the reaction HO· + H‐R → H2O + R· are measured in H2O for MeOH, EtOH, iPrOH, tBuOH, (CH2OH)2, MeCN, and AcO‐ by using photoacoustic calorimetry; HO· radicals are generated by laser excitation of H2O2.
ChemInform Abstract: Ternary Complexes in Solution. Part 51. Intramolecular Hydrophobic and Stacking Interactions in Mixed Ligand Complexes Containing Cu(II), 2,2′‐Bipyridyl or 1,10‐Phenanthroline, and a Simple Phosphate Monoester, D‐Ribose 5′‐Monophosphate or a Nucleoside 5′‐Monophosphate (CMP, UMP, TMP, TuMP) with a Non‐Coordinating Base Residue.
Authors: MASSOUD S. S. , SIGEL H. 
Published: May 2016

AbstractStability constants of mixed ligand complexes are determined by potentiometric pH titrations.
ChemInform Abstract: Selective Substitution of the Dimethyl Sulfide Group in Sulfobetaines.
Authors: SHASTIN A. V. , POPKOVA T. V. , BALENKOVA E. S. 
Published: May 2016

AbstractThe title compounds (I), (IV) and (VI) are prepared according to known procedures by the reactions between the complex compound Me2S·SO3 and alkenes or alkynes.
ChemInform Abstract: The Behaviour of Unsaturated 1,2‐Hydroxyimino Ketones with Trifluoroacetic Acid.
Authors: BISHOP R. , HAWKINS S. C. , QUIBUYEN T. A. O. , BROOKS P. R. 
Published: May 2016

AbstractThe unsaturated oximes (I), (III), (IV), and (VI) cyclize in the presence of trifluoroacetic acid to form heterocyclic systems as outlined in the reaction scheme.
ChemInform Abstract: ESR Studies on Carboxylic Acid Esters. Part 12. Formation of 9‐Fluorenone Radical Anions During Electroreduction of Sterically Hindered Methyl Biphenyl‐2‐dithiocarboxylates.
Authors: EDLER R. , VOSS J. 
Published: May 2016

AbstractESR signals due to (II)·‐ are observed besides those of (I)·‐ if (I) is electroreduced in DMF or MeCN.
ChemInform Abstract: Photodechlorination of Chloroaromatics by Electron Transfer from an Anionic Sensitizer.
Authors: SOUMILLION J. P. , VANDEREECKEN P. , DE SCHRYVER F. C. 
Published: May 2016

AbstractThe dechlorination of the chloroarenes (I) to give the hydrocarbons (II) is achieved by irradiation in the presence of β‐naphthoxide anions.
ChemInform Abstract: Trityl Thionitrite: A Potential Transfer Nitrosating Agent for Metal Nitrosylation.
Authors: PANDEY D. S. , AGARWALA U. C. 
Published: May 2016

AbstractSeveral known nitrosyl complexes of Ru, Rh, Ir, Co, Mo, and W have been synthesized using trityl thionitrite as a nitrosylating agent at elevated temperatures.
ChemInform Abstract: Reactions of Polyhalogenofunctionalized Compounds with Metals and Electrophilic Reagents. Part 11. Reactions of 2,2‐Dichloroalkylidene Derivatives of β‐Dicarbonyl Compounds and Their Analogues with Zinc and Electrophilic Reagents.
Authors: SHCHEPIN V. V. , RODYGIN A. S. , FASTOVA V. V. 
Published: May 2016

AbstractCondensation of 2,2‐dichloropropionaldehyde (I) with (II) affords the hitherto unknown title compounds (III).