bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis, Stereochemistry, and Isomerization of 4‐Aryl‐5‐aroyl‐2‐methyl‐2‐imidazolines.
Authors: KONOVALOV V. A. , BUBEL' O. N. , TISHCHENKO I. G. 
Published: May 2016

AbstractTreatment of the trans‐ (I) or cis‐arylaroylaziridine boron trifluoride complexes (V) with methyl thiocyanate (II) gives regio‐ and stereoselectively the cis‐ (III) or trans‐imidazolines (VI) which are converted to the free bases (IV) or (VII) upon treatment with triethylamine.
ChemInform Abstract: Synthesis of 2,3‐Diaryl‐1,4‐diazolyl‐2,3‐epoxybutanes.
Authors: MORENO‐MANAS M. , TEIXIDO M. 
Published: May 2016

AbstractThe hydrazones (III), prepared from the acetophenones (I), are treated with lead dioxide and sulfur dioxide, yielding Z/E‐mixtures of the stilbenes (IV).
ChemInform Abstract: Indolizinium Salts and Heteroanalogues via Anellation of Heterocyclic α‐Methylimines with 3‐Alkoxyacroleins.
Authors: BOEHME R. + , ROTSCHEIDT K. , BREITMAIER E. 
Published: May 2016

AbstractThe 2‐methyldihydroazoles (I) are lithiated and then coupled with the ethoxyacroleins (II) to give the allylic alcohols (III) which are cyclized and dehydrated upon treatment with hydroiodic acid, forming the fused pyridinium iodides (IV).
ChemInform Abstract: Some Aspects of the Chemistry of Pyrimido(1,2‐b)pyridazinones.
Authors: MATYUS P. , SZILAGYI G. , KASZTREINER E. , RABLOCZKY G. , SOHAR P. 
Published: May 2016

AbstractCyclocondensation of the 3‐aminopyridazines (I) or (X) with dimethyl acetylenedicarboxylate forms the regioisomeric pyrimidopyridazine derivatives (IV) or (XI).
ChemInform Abstract: Synthesis and Polymerization of Isopropenyl‐1,3,5‐triazines Obtained from 1‐Aryl‐1‐ethylbiguanide.
Authors: KUNISADA H. , YUKI Y. , ARAI H. 
Published: May 2016

AbstractThe biguanidines (I) are alkylated with ethyl iodide (II) to produce the corresponding ethyl biguanidines (III) which are cyclized with methacryloyl chloride (IV), forming the sym‐triazines (V).
ChemInform Abstract: Synthesis and Structure of 1,5,6,7,8‐Pentachloro‐3‐phenyl‐1,2,4‐benzothiadiazine.
Authors: SHERMOLOVICH YU. G. , SIMONOV YU. A. , DVORKIN A. A. , POLUMBRIK O. M. , BOROVIKOVA G. S. , KAMINSKAYA E. I. , LEVCHENKO E. S. , MARKOVSKII L. N. 
Published: May 2016

AbstractIt is known that the reaction between N‐chloro‐N'‐phenylbenzamidine (I) and SCl2 (II) yields 1‐chloro‐1,2,4‐benzothiadiazine (III).
ChemInform Abstract: Perfluorohexylsubstituted Benzocrown Ethers.
Authors: MIRONOVA A. A. , ORDA V. V. , MALETINA I. I. , YAGUPOL'SKII L. M. 
Published: May 2016

AbstractStarting from dibenzo‐18‐crown‐6 ether (I) the perfluorohexyl derivatives (III) and (IV) are prepared.
ChemInform Abstract: Synthesis of the Furanoheliangolide Ring Skeleton.
Authors: MCDOUGAL P. G. , OH Y.‐I. , VANDERVEER D. 
Published: May 2016

AbstractThe key step in the synthesis of the bis(oxo‐bridged) macrocycle (X) from the protected (phenylthio)acrolein (I) is the ozonolytic cleavage of the double bond in the cycloadduct (VIII).
ChemInform Abstract: Reactions of Chalcogens with Acetylenes. Part 5. Reaction of Metallic Selenium with Phenylacetylene.
Authors: AMOSOVA S. V. , POTAPOV V. A. , KASHIK A. S. , GUSAROVA N. K. , SINEGOVSKAYA L. M. , TROFIMOV B. A. 
Published: May 2016

AbstractThe reaction between phenylacetylene (I) and Se (II) is investigated in order to find out the optimum conditions necessary for the preparation of Z‐2‐benzylidene‐4‐phenyl‐1,3‐diselenol (III).
ChemInform Abstract: Selenophene, Oxazole, and N‐Methylpyrazole as Dienophiles in the “Inverse” (4 + 2)Cycloaddition.
Authors: SEITZ G. , MOHR R. , HOFERICHTER R. 
Published: May 2016

AbstractThe heterocyclic 5‐ring derivatives (II) react with the tetrazinedicarboxylate (I) to give the fused pyridazines (III).
ChemInform Abstract: Synthesis, Characterization, and Crystal Structures of Bismuth Complexes with 2,6‐Diacetylpyridine Bis(2‐thenoylhydrazone) (H2dapt): (Bi(Hdapt)Cl2)·dmso·H2O and (Bi(dapt)Cl)·dmso, Containing a Quinquedentate Ligand.
Authors: BATTAGLIA L. P. , BONAMARTINI CORRADI A. , PELOSI G. , TARASCONI P. , PELIZZI C. 
Published: May 2016

AbstractThe title ligand (I) reacts with BiCl3 (II) to give the pentagonal bipyramidal trans‐dichloro complex (IIIa).
ChemInform Abstract: η2‐Coordination of a Sn‐H Bond to a Transition Metal. Molecular Structure of (η5‐MeC5H4)(CO)2Mn(H)SnPh3.
Authors: SCHUBERT U. , KUNZ E. , HARKERS B. , WILLNECKER J. , MEYER J. 
Published: May 2016

AbstractThe photochemically generated complex (III) crystallizes in the space group P1 with Z=2.
ChemInform Abstract: Formation in Solution, Synthesis, and Electrochemical Study of Oxalato Complexes of N,N′‐Ethylenebis(salicylideneaminato)‐chromium(III) and ‐iron(III): Crystal Structures of Piperidinium (N,N′‐Ethylenebis(salicylideneaminato))(oxalato‐O1O2)‐chromate(III) and ferrate(III).
Authors: LLORET F. , JULVE M. , MOLLAR M. , CASTRO I. , LATORRE J. , FAUS J. , SOLANS X. , MORGENSTERN‐BADARAU I. 
Published: May 2016

AbstractThe two mononuclear title complexes (III) and the oxalate‐bridged dinuclear Fe(III) complex (V) are synthesized according to the scheme.
ChemInform Abstract: Reactions of Hydride Complexes of Ruthenium(II) with Alkynes.
Authors: BRAY J. M. , MAWBY R. J. 
Published: May 2016

AbstractThe hydrido‐Ru complex (I) reacts with the alkynes (II) and dimethyl acetylenedicarboxylate to yield the vinyl complexes (III) and (IV), respectively.
ChemInform Abstract: Chemistry of Multi‐Site Bound Unsaturated Ligands on Metal Carbonyl Clusters. Intramolecular Reductive Coupling in the Conversion of (Ru3(μ‐H)(CO)9(μ3,η2‐CCtBu)) to the Butadienyl Cluster (Ru3(CO)8(μ3,η4‐C(tBu)CC(H)C(Ph)(PPh2))), and Its Crystal Structure. An Example of Ligand Isomerism on Metal Clusters.
Authors: SAPPA E. , PASQUINELLI G. , TIRIPICCHIO A. , TIRIPICCHIO‐CAMELLINI M. 
Published: May 2016

AbstractThe substitution product (III) from the cluster (I) and the phosphinoacetylene (II) undergoes thermal intramolecular coupling of both alkyne ligands to give the isomeric derivative (IV).
ChemInform Abstract: Synthesis, Structure, and Reactivity of a Monomeric Pentamethylcyclopentadienyliridium(III)‐Imido Complex.
Authors: GLUECK D. S. , HOLLANDER F. J. , BERGMAN R. G. 
Published: May 2016

AbstractThe imido complex (III) is obtained according to the scheme and characterized by spectral data (1H NMR, MS) and X‐ray structure analysis (at ‐60 °C space group Pbcm, Z=4).
ChemInform Abstract: Synthesis of 21‐Thioalkanoic Acids of Corticosteroids.
Authors: PSHENICHNYI V. N. , MIKHAL'CHUK A. L. , KHRIPACH V. A. 
Published: May 2016

AbstractIn the presence of NaOMe the reactions between the 21‐tosylsubstituted corticosteroids (I) and mercaptoacetic or 3‐mercaptopropionic acids (II) afford the title compounds (III) in high yields.
ChemInform Abstract: Partial Synthesis of Some Physiologically Relevant Gibberellin Glucosyl Conjugates.
Authors: SCHNEIDER G. , SEMBDNER G. , SCHREIBER K. , PHINNEY B. O. 
Published: May 2016

AbstractThe glucoside (VI), which is prepared via glucosylation of the ester (I), is identical with the natural product which has been isolated from the pods of Phaseolus coccineus.
ChemInform Abstract: A New Fluorescence Sensor for Quantification of Atmospheric Humidity.
Authors: ZHU C. , BRIGHT F. V. , WYATT W. A. , HIEFTJE G. M. 
Published: May 2016

AbstractThe new fiber‐optic sensor for humidity utilizes a fluorescent dye (rhodamine 6 G) incorporated into a perfluorinated polymer matrix (nafion).
ChemInform Abstract: Preparation and Properties of Aluminum Nitride Films Using an Organometallic Precursor.
Authors: INTERRANTE L. V. , LEE W. , MCCONNELL M. , LEWIS N. , HALL E. 
Published: May 2016

AbstractTransparent, smooth, and highly adherent polycrystalline AlN films are deposited on Si and SiO2 substrates by low pressure CVD using (Me2AlNH2)3 (I) as precursor.
ChemInform Abstract: Efficiency of Activated Carbon for the Removal of Diethyltellurium from a Carrier Gas Stream.
Authors: KRAJEWSKI J. J. , KISKER D. W. 
Published: May 2016

AbstractBecause of its toxicity, which is comparable to elemental Te, the efficient removal of diethyltellurium from the effluent of an organometallic vapor phase epitaxy reactor is very desirable.
ChemInform Abstract: Di‐ and Trinuclear Fluorooxoanions of Molybdenum and Tungsten. Crystal Structures of K2(NMe4)(MoV2O2F9)·H2O (I) and (NMe4)2(MoVI2O4F6(H2O)) (II).
Authors: LEIMKUEHLER M. + , BUCHHOLZ N. , MATTES R. 
Published: May 2016

AbstractIn addition to the title compounds (I) and (II), the fluorooxo complexes (NMe4)2(W2O4F6(H2O)), K(NMe4)2(Mo3O6F9), and (NEt4)2(Mo2O4F6) are prepared by reaction of MoCl5 (for (I)), MoO3, and WO3, resp., with 40% HF and the chlorides of the corresponding cations.
ChemInform Abstract: X‐Ray and Spectroscopic Investigation of Some Strontium and Zinc Substituted Calcium Fluoroapatites.
Authors: APELLA M. C. , TUTTOLOMONDO M. E. , BARAN E. J. 
Published: May 2016

AbstractXRD data are reported for 12 members of the series Ca10‐x‐ySrxZny(PO4)6F2 (x = 0‐10, y = 0‐3).
ChemInform Abstract: Preparation of Proton‐Conducting Amorphous Films Containing Dodecamolybdophosphoric Acid by the Sol‐Gel Method.
Authors: TATSUMISAGO M. , MINAMI T. 
Published: May 2016

AbstractSilica gel films containing up to 42 wt.% H3PMo12O40·29 H2O (I) are shown to have considerably high proton conductivity in a highly humid atmosphere, that increases with increasing content of (I).
ChemInform Abstract: Photoelectrochemical Properties of Double Layer Photoelectrode of Cadmium Chalcogenides Prepared by Vacuum Evaporation.
Authors: FUJII M. , KAWAI T. , KAWAI S. 
Published: May 2016

AbstractDouble layer CdSe/CdS and CdTe/CdSe electrodes are investigated and compared with single layer electrodes.
ChemInform Abstract: Phase Equilibria and Crystal Chemistry in the Quaternary System Ba‐Sr‐Y‐Cu‐O in Air.
Authors: ROTH R. S. , RAWN C. J. , WHITLER J. D. , CHIANG C. K. , WONG‐NG W. K. 
Published: May 2016

AbstractIt is found that Sr can substitute for up to about 60% Ba in (Ba,Sr)2YCu3O6+x. In the Sr‐Y‐Cu‐O system no ternary compounds are observed.
ChemInform Abstract: The Hexacyanoferrate Redox Couple at Porous BaSn0.9Sb0.1O3 Perovskite Electrodes.
Authors: DA SILVA PEREIRA M. I. , MELO M. J. B. V. , DA COSTA F. M. A. , ROSA NUNES M. , PETER L. M. 
Published: May 2016

AbstractThe title perovskite is synthesized by heating stoichiometric amounts of BaCO3, SnO2, and Sb2O3 at 900 °C (12 h) and subsequently at 1200‐1300 °C (14 h) under an oxygen atmosphere.
ChemInform Abstract: Influence of Nitrogen and Molybdenum on the Sensitization Properties of Low‐Carbon Austenitic Stainless Steels.
Authors: BENEKE R. , SANDENBERGH R. F. 
Published: May 2016

AbstractIt is reported that for conventional low carbon steel (0.03%), as well as steels with higher carbon contents (0.05%), the addition of nitrogen (up to 0.123%) improves significantly the resistance to sensitization.
ChemInform Abstract: Synthesis and Multinuclear NMR Characterizations of Some (3.3)Diselena‐ and (4.4)Tetraselenacyclophanes.
Authors: HOJJATIE M. , MURALIDHARAN S. , FREISER H. 
Published: May 2016

AbstractSeveral (18 examples) symmetrical and unsymmetrical bis‐selenacyclophanes of phenyl, furyl, pyridyl and thiophenyl are investigated.
ChemInform Abstract: Novel Hydrogen/Methyl Exchange Between SiHx(CH3)+ 3‐x (x = 1‐3) and Propene in the Gas Phase.
Authors: REUTER K. A. , JACOBSON D. B. 
Published: May 2016

AbstractA novel H/CH3 exchange reaction involving (SiHx(CH3)3‐x)+ (x = 1‐3) with propene and 2‐methylpropene in the gas phase using Fourier transform mass spectrometry is described.
ChemInform Abstract: Organometallic Ring‐Opening Reactions of N‐Acyl and N‐Alkoxycarbonyl Lactams. Synthesis of Cyclic Imines.
Authors: GIOVANNINI A. , SAVOIA D. , UMANI‐RONCHI A. 
Published: May 2016

AbstractThe N‐acylated lactams (III) are cleaved upon reaction with organometallic agents such as the Grignard compounds (IV), yielding the N‐acylamino carbonyl compounds (V) which are sometimes accompanied by the esters (VId) ‐ (VIf).
ChemInform Abstract: Stereochemical Effects in the Ozonolysis of E‐ and Z‐1‐Ethoxypropene.
Authors: WOJCIECHOWSKI B. J. , PEARSON W. H. , KUCZKOWSKI R. L. 
Published: May 2016

AbstractThe stereoisomeric 1‐ethoxypropenes (I) and (VII) are subjected to ozonolysis under various conditions, yielding mixtures of the dioxolanes (II) and (III) or (VIII) and (IX), together with the trioxolanes (IV) and (V) and the tetroxane (VI).
ChemInform Abstract: Silicon‐Phosphorus Analogies. Nucleophilic Catalysts in the Alcoholysis of Chlorophosphorus Derivatives.
Authors: CORRIU R. J. P. , LANNEAU G. F. , LECLERCQ D. 
Published: May 2016

AbstractThe mechanism of the alcoholysis of chlorophosphonates and chlorophosphates in the presence of nucleophilic catalysts like HMPA, pyridine, and N‐methylimidazole is discussed on the basis of kinetic and stereochemical results.
ChemInform Abstract: N‐Methyl‐2‐dimethylaminoacetohydroxamic Acid as a New Reagent for the Selective Cleavage of Active Esters Under Neutral Conditions.
Authors: ONO M. , ITOH I. 
Published: May 2016

AbstractThe hydroxamic acid (III) mentioned in the title is employed in the cleavage of aromatic or otherwise activated ester groups.
ChemInform Abstract: (3,3‐Diisopropoxypropyl)triphenylarsonium Ylide: A New Synthetic Equivalent of β‐Formylvinyl Anion.
Authors: CHABERT P. , OUSSET J. B. , MIOSKOWSKI C. 
Published: May 2016

AbstractThe arsonium ylide (I) is coupled with the iodo acetal (II) to give the arsonium salt (III) which is dehydroiodinated, forming the ylide (IV) mentioned in the title.
ChemInform Abstract: A Novel Paired Electrosynthesis of p‐Benzoquinone and Hydroquinone from Benzene.
Authors: ITO S. , KATAYAMA R. , KUNAI A. , SASAKI K. 
Published: May 2016

AbstractElectrooxidation of benzene (I) produces p‐benzoquinone (II) and hydroquinone (III), together with minor amounts of phenol (IV).
ChemInform Abstract: Selective Reductions of Conjugated Acetylenes with Magnesium in Methanol and Methanol‐d.
Authors: HUTCHINS R. O. , SUCHISMITA SUCHISMITA , ZIPKIN R. E. , TAFFER I. M. , SIVAKUMAR R. , MONAGHAN A. , ELISSEOU E. M. 
Published: May 2016

AbstractThe acetylenecarboxylates (I) are reduced with magnesium in methanol to form the saturated esters (II).
ChemInform Abstract: Molecules with Twist Bent Bonds. The Synthesis, Properties, and Reactions of trans‐Bicyclo(4.1.0)hept‐3‐ene and Certain Methylated Derivatives.
Authors: GASSMAN P. G. , BONSER S. M. , MLINARIC‐MAJERSKI K. 
Published: May 2016

AbstractThe synthesis of the title compounds (X) and (XIII) is described as shown for (X).
ChemInform Abstract: Bistrifluoromethylation of Acrylamide for Trifluoromethylated Synthetic Blocks.
Authors: UNEYAMA K. , MORIMOTO O. , NANBU H. 
Published: May 2016

AbstractElectrolysis of acrylamide (I) in trifluoroacetic acid (II) in the presence of bases gives the bistrifluoromethylated propionamide (III).
ChemInform Abstract: Regioselective Metalation of Thiazolo(5,4‐b)pyridines.
Authors: COUTURE A. , HUGUERRE E. , GRANDCLAUDON P. 
Published: May 2016

AbstractThe thiazolopyridines (Ia) and (Ib) are lithiated stereoselectively and then treated with the electrophiles (IV) to form the 4‐substituted products (V).
ChemInform Abstract: Chemistry of the Pyrrolo(3,4‐c)pyrido(2,3‐d)pyrimidine System. Synthesis of 6,7‐Dihydropyrrolo(3,4‐c)pyrido(2,3‐d)pyrimidines, a Novel Ring System with Potential Biological Interest.
Authors: SU T.‐L. , WATANABE K. A. 
Published: May 2016

AbstractThe key step in the synthesis of the pyrrolopyridopyrimidine (V) is the thermally induced cyclization of the 5‐aminomethyl‐6‐acetoxymethylpyridopyrimidine derivative (IV).
ChemInform Abstract: Reaction of Aldoses with Amino Acids and Proteins. Part 3. Reaction of 2‐Amino‐2‐deoxy‐D‐glucose and Lysine: Isolation and Characterization of 2,5‐Bis(tetrahydroxybutyl)pyrazine.
Authors: CANDIANO G. , GHIGGERI G. M. , GUSMANO R. , ZETTA L. , BENFENATI E. , ICARDI G. 
Published: May 2016

AbstractReaction between 2‐amino‐2‐deoxy‐D‐glucose (I) and lysine (II) in water at 37°C gives a mixture of several products.
ChemInform Abstract: Amino Acid Derivatives That Stabilize Secondary Structures of Polypeptides. Part 4. Practical Synthesis of 4‐(Alkylamino)‐3‐cyano‐6‐azabicyclo(3.2.1)oct‐3‐enes (Ben Derivatives) as γ‐Turn Templates.
Authors: KEMP D. S. , CARTER J. S. 
Published: May 2016

AbstractStarting with the hydroxyproline derivative (I), the stereoisomeric azabicyclooctanes (VI) are prepared via base‐induced cyclization of the cyanoethylprolines (V).
ChemInform Abstract: Synthesis of 1,2‐Dihydro‐1‐oxo‐3H‐3‐benzazepine and 3‐Acyl Derivatives.
Authors: SCHNUR R. C. , GALLASCHUN R. J. 
Published: May 2016

AbstractThe N‐sulfonyltetrahydrobenzazepinones (II) undergo base‐induced desulfonation, generating the dihydrobenzazepinone (III) mentioned in the title.
ChemInform Abstract: Regioselection in the Hydroformylation of tert‐Butyldiphenylsilylalkenes: A New Approach to Aldol Synthesis.
Authors: DOYLE M. M. , JACKSON W. R. , PERLMUTTER P. 
Published: May 2016

AbstractThe cis‐silylalkenes (I) are hydroformylated in the presence of a rhodium hydrido carbonyl/triphenylphosphine catalyst to give mainly the β‐silylaldehydes (III), together with low amounts of the regioisomers (IV).
ChemInform Abstract: Alkyl‐ and Aryl‐Metal Compounds. Part 38. Synthesis and Structure of a Phenylsodium Solvate, Bis(μ‐phenyl(pentamethyldiethylenetriamine)sodium).
Authors: SCHUEMANN U. + , BEHRENS U. , WEISS E. 
Published: May 2016

AbstractThe title compound (III) crystallizes in P21/n with Z=2.
ChemInform Abstract: Reactions of η2‐Acyl Ligands in Tp′(CO)2Mo(η2‐C(O)R) Complexes to Form Complexed Enolates and Enones, Allyls, and Alkyne Insertion Products.
Authors: RUSIK C. A. , COLLINS M. A. , GAMBLE A. S. , TONKER T. L. , TEMPLETON J. L. 
Published: May 2016

AbstractThe preparation of phosphite‐containing η2‐acyl complexes (III) involves photolytic generation of a MeCN adduct which reacts with phosphite in a non‐donor solvent to form the substitution product.
ChemInform Abstract: Transition Metal Complexes with the Thiosemicarbazide‐Based Ligands. Part 7. Complexes of Some 3d Elements with Pyruvic Acid S‐Methylisothiosemicarbazone.
Authors: LEOVAC V. M. , CESLJEVIC V. I. , OBADOVIC D. Z. , PETROVIC D. M. , CHUNDAK S. YU. 
Published: May 2016

AbstractIn the neutral octahedral title complexes (IV) the ligand is coordinated by a NNO donor set involving the deprotonated oxygen of the carboxyl group and the nitrogen of the thioamido group.
ChemInform Abstract: Stepwise Interaction of ((phen)(Ph3P)Cu(O2COH)) with Pyrazoles and CO2: Synthesis and Reactivity of Copper(I) Pyrazolecarboxylates.
Authors: ARDIZZOIA G. A. , LA MONICA G. , ANGARONI M. A. , CARIATI F. 
Published: May 2016

AbstractReactions of the title complex (I) with the pyrazoles (II) afford the insoluble Cu(I) pyrazolates (III) in solutions.
ChemInform Abstract: Reaction of 4,6‐O‐Benzylidene‐2‐deoxypyranosides with Sodium Cyanoborohydride: Formation of 1,5‐Anhydroalditols.
Authors: CHAPLEUR Y. , BOQUEL P. , CHRETIEN F. 
Published: May 2016

AbstractThe pyranosides (I), (IV) and (VII) specified in the title are treated with sodium cyanoborohydride.
ChemInform Abstract: Stereoselective Syntheses of C‐(D‐Glucopyranosyl)alkenes.
Authors: HORTON D. , MIYAKE T. 
Published: May 2016

Abstractα‐D‐Glucopyranose pentaacetate (I) is treated with allyltrimethylsilane (II) and boron trifluoride etherate to give a mixture of the acetylated 3‐(α‐ and β‐D‐glucopyranosyl)‐1‐propenes (III) and (IV).
ChemInform Abstract: Regiospecific C‐9 Substitution of Ellipticine Derivatives.
Authors: LANGENDOEN A. , PLUG J. P. M. , KOOMEN G.‐J. , PANDIT U. K. 
Published: May 2016

AbstractPrevious papers report, in the most cases the preparation of 9‐substituted ellipticine derivatives via construction of the ellipticine nucleus starting from the appropriately substituted precursors.
ChemInform Abstract: Remote Diastereoselection in the Asymmetric Total Synthesis of Mevinolin.
Authors: WOVKULICH P. M. , TANG P. C. , CHADHA N. K. , BATCHO A. D. , BARRISH J. C. , USKOKOVIC M. R. 
Published: May 2016

AbstractThe total synthesis of the HMG‐CoA reductase inhibitor mevinolin (XIII) is described.
ChemInform Abstract: Low‐Temperature Sintering of Lead‐Based Piezoelectric Ceramics.
Authors: GUI Z. , LI L. , GAO S. , ZHANG X. 
Published: May 2016

AbstractIt is demonstrated that the sintering temp. of a lead zirconate titanate (PZT) is reduced from ∼1250 °C to ∼960 °C in the presence of a small amount of an additive consisting of B2O3‐Bi2O3‐CdO.
ChemInform Abstract: Intrazeolite Site‐Selective Far‐IR Cation Probe.
Authors: OZIN G. A. , BAKER M. D. , GODBER J. , GIL C. J. 
Published: May 2016

AbstractThe investigations are mainly focused on the use of cation site selective far‐IR spectroscopy to obtain information pertaining to extraframework intrazeolitic cations.
ChemInform Abstract: A Coordinated Study of the Passivation of Alloy Steels by Plasma Source Mass Spectrometry and X‐Ray Photoelectron Spectroscopy. Part 1. Characterization of the Passive Film.
Authors: CASTLE J. E. , QIU J. H. 
Published: May 2016

AbstractThe passivation of chromium steels, i.g .Fe17Cr and Fe15Cr4Mo, is studied in 0.1 M H2SO4 solution at different potentials.
ChemInform Abstract: Reutilization of the Unwanted (S)‐Isomer of (R)‐(‐)‐1‐(4‐Hydroxyphenyl)‐2‐((3,4‐dimethoxyphenethyl)amino)ethanol (Denopamine).
Authors: SENUMA M. , YAMATO E. , KOUMOTO T. , GAINO M. , KAWAGUCHI T. , IWAKUMA T. 
Published: May 2016

AbstractDenopamine, an effective cardiotonic agent, is obtained via optical resolution of the racemic O‐benzyl derivative (±)‐(II) followed by hydrogenolysis.
ChemInform Abstract: Gas‐Phase Ion Chemistry of the Acetic Acid Enolate Anion (CH2CO2H)‐.
Authors: O'HAIR R. A. J. , GRONERT S. , DEPUY C. H. , BOWIE J. H. 
Published: May 2016

AbstractIn contrast to the behavior of the acetate anion, the title anion (I) incorporates deuterium to give (II).
ChemInform Abstract: Transition‐Metal Phthalocyanins as Catalysts for Alkene Epoxidation.
Authors: Larsen E. , Joergensen K. A. 
Published: May 2016

AbstractThe phthalocyanin (I) is most effective in the epoxidation of alkenes such as styrene, (E)‐stilbene, and norbornene when iodosylbenzene is used as oxygen donor.
ChemInform Abstract: A Highly Selective Montmorillonite Catalyst for the Hydrogenation of Alkynes, Alkenynes and Alkadienes.
Authors: CHOUDARY B. M. , SHARMA G. V. M. , BHARATHI P. 
Published: May 2016

AbstractThe title catalyst allows the transformation of alkynes and alkenynes such as (Ia) or (Ib) to the cis‐alkenes (II) and the regioselective hydrogenation of alkadienes such as (III).
ChemInform Abstract: Migratory Insertion Reactions of Organometallics. Part 3. Carbon‐Carbon Bond‐Forming Reactions of Organotransition Metals with α‐ or γ‐Haloorganolithium Reagents.
Authors: NEGISHI E. , AKIYOSHI K. , O'CONNOR B. , TAKAGI K. , WU G. 
Published: May 2016

AbstractA variety of examples shows that all eight metals of the first transition series as well as some others, such as Zr and Hf, can promote C‐C bond formation between organometals containing these metals and α‐ and γ‐haloorgano‐Li compounds.
ChemInform Abstract: Silver‐Assisted Reactions of Organotin Oxides. A Mild, Neutral, and Anhydrous One‐Step Conversion of Primary Organic Halides to Alcohols.
Authors: GINGRAS M. , CHAN T. H. 
Published: May 2016

AbstractAlkylhalides such as (I) are treated with bis(tributyltin) oxide (II) in the presence of silver tosylate or nitrate to form the corresponding alcohols such as (IV) after work‐up.
ChemInform Abstract: Novel Regioselective Generation of Nitroalkane Dianions.
Authors: YAMADA K. , TANAKA S. , KOHMOTO S. , YAMAMOTO M. 
Published: May 2016

AbstractThe dianions, generated from nitroethane (I), are coupled with benzaldehyde (II) to give mixtures of the regioisomeric nitro alcohols (III) and (IV).
ChemInform Abstract: Iron‐Catalyzed Oxidation of N,N‐Dimethylaniline with Molecular Oxygen.
Authors: MURATA S. , MIURA M. , NOMURA M. 
Published: May 2016

AbstractTreatment of N,N‐dimethylaniline (I) with oxygen in the presence of iron catalysts yields mixtures of the amines (II), (IV), (V), and the formanilide (III).