bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: High‐Valent Ruthenium Oxo Complexes of NNN′N′‐Tetramethyl‐3,6‐dimethyl‐3,6‐diazaoctane‐1,8‐diamine (L1). X‐Ray Crystal Structure Determination of cis‐(Ru(III)(L1)Cl2)ClO4.
Authors: CHE C.‐M. , TANG W.‐T. , LAM M. H.‐W. , MAK T. C. W. 
Published: May 2016

AbstractThe title ligand (I) reacts with the aqua complex (II) to yield the cis complex (III) which is characterized by X‐ray crystallography (space group P21/c, Z=4).
ChemInform Abstract: Potential Multifunctional Anticancer Metal Complexes. Part 1. Synthesis and X‐Ray Structural Studies of Some Dinuclear Rhodium(II) Carboxylate Complexes with Diamine‐Substituted Acridine Ligands in Terminal Coordination Positions.
Authors: GOODGAME D. M. L. , PAGE C. J. , WILLIAMS D. J. 
Published: May 2016

AbstractThe dinuclear Rh(II) complexes (I) are prepared by 1:2 molar reaction of corresponding anhydrous Rh(II) carboxylates with the acridine ligands L in methanol.
ChemInform Abstract: Synthesis, X‐Ray Structure, and Reactivity of (NBu4)2(Pt2(μ‐C6F5)2(C6F5)4)·H2O and (NBu4)(Pt2Ag(μ‐C6F5)2(C6F5)4O(C2H5)2). The First Complexes Containing Bridging Pentafluorophenyl Groups.
Authors: USON R. , FORNIES J. , TOMAS M. , CASAS J. M. , COTTON F. A. , FALVELLO L. R. , LLUSAR R. 
Published: May 2016

AbstractThe syntheses of the title complexes (II) and (V) are outlined in the scheme.
ChemInform Abstract: Stereoselective Glycosidation Reactions of Activated Glycals with a C1‐Oxygenated Allylsilane: Synthesis of a cis‐Pyrano(2,3‐b)pyran.
Authors: PANEK J. S. , SPARKS M. A. 
Published: May 2016

AbstractThe dihydropyrans (II) and (IV) react with the 1‐silylallyl alcohol (I) in the presence of boron trifluoride etherate to give the dihydropyranyl ethers (III) or (V).
ChemInform Abstract: Synthesis of the C‐Glycoside Fragment of Nogalamycin and Some Nogalamycin Precursors.
Authors: BATES M. A. , SAMMES P. G. , THOMSON G. A. 
Published: May 2016

AbstractThe title glycoside fragment (VII) represents the D,E,F ring system of the anticancer antibiotic nogalamycin (XII).
ChemInform Abstract: Fungal Biotransformation of 1,3‐Oxathiolanes.
Authors: HOLLAND H. L. , MUNOZ B. 
Published: May 2016

AbstractIncubation of the oxathiolanes (I) with the fungus Mortierella isabellina leads to sulfoxidation yielding the products (II) as single diastereomers, whose relative stereochemistry is assigned by 1H NMR analysis.
ChemInform Abstract: Electrocatalytic Reduction of Nitrate and Nitrite at NafionR‐Coated Electrodes in Concentrated Sodium Hydroxide Solution.
Authors: LI H.‐L. , CHAMBERS J. Q. , HOBBS D. T. 
Published: May 2016

AbstractNafion film electrodes containing the Co(III)‐cyclam complex (cyclam: 1,4,8,11‐tetraazacyclotetradecane) as electrocatalyst are prepared either by codeposition of Nafion and the Co‐cyclam complex onto a gold substrate or by electrochemical cycling of a Nafion film electrode in a solution of the Co(III)/Co(II)‐cyclam couple in 1 M NaOH.
ChemInform Abstract: Supported Metal Catalysts Prepared from Bimetallic Clusters: ReOs3 Clusters on γ‐Al2O3.
Authors: FUNG A. S. , TOOLEY P. A. , MCDEVITT M. R. , GATES B. C. , KELLEY M. J. 
Published: May 2016

AbstractSupported ReOs3 clusters are prepared by deposition of H3ReOs3(CO)13 on partially dehydroxylated γ‐Al2O3 in dry hexane, followed by a thermal pretreatment in either He or H2 and subsequent H2 reduction (400 °C, 4 h).
ChemInform Abstract: Syntheses of Sulfinylmethyl Ethers and Conversion of These into Halomethyl and Acyloxymethyl Ethers.
Authors: ANTONSEN OE. , BENNECHE T. , UNDHEIM K. 
Published: May 2016

AbstractThe sulfinylmethyl ethers (III) are prepared from the alcohols (I) and used as starting materials for a series of functionalized ethers.
ChemInform Abstract: The Stereochemistry of Organometallic Compounds. Part 31. Hydrocyanation of Alkynols.
Authors: JACKSON W. R. , LOVEL C. G. , PERLMUTTER P. , SMALLRIDGE A. J. 
Published: May 2016

AbstractThe phosphite‐catalyzed title reaction of the alkynes (I) is regioselective only in the case of (Ib) and (Id).
ChemInform Abstract: Photochemical Ring Slippage of Bis(pentafluorophenyl)titanocene: Reaction Kinetics and Matrix Isolation of the Primary Photoproduct.
Authors: KLINGERT B. , ROLOFF A. , URWYLER B. , WIRZ J. 
Published: May 2016

AbstractThe primary photochemical reaction of (I), which is used as a polymerization photo‐initiator, yields a reactive isomer.
ChemInform Abstract: E‐4‐Lithio‐4‐tosylbutenone Dimethyl Acetal: A New and Versatile β‐Acylvinyl Anion Equivalent in Organic Synthesis.
Authors: NAJERA C. , YUS M. 
Published: May 2016

AbstractLithiation of the tosylated acetal (I) with MeLi (II) yields the lithiotosylbutenone acetal (III) mentioned in the title.
ChemInform Abstract: Imidazo(1,2‐b)pyridazines. Part 3. Syntheses and Central Nervous System Activities of Some 6‐Chloro‐3‐methoxy(and ethoxy)‐2‐aryl(and heteroaryl)imidazo(1,2‐b)pyridazines.
Authors: BARLIN G. B. , DAVIES L. P. , NGU M. M. L. 
Published: May 2016

AbstractCompounds of type (IV) are tested for their ability to displace diazepam‐3H bound to rat brain membranes.
ChemInform Abstract: Syntheses and Structures of Diastereomerically Pure 2,6‐Disubstituted 3‐Morpholinones.
Authors: DANKLMAIER J. , HOENIG H. + 
Published: May 2016

AbstractThe syntheses of the hitherto unknown diastereomerically pure morpholinones (IV), (VI), (VII) start from the compounds (I) or, analogously, from the compounds (V) as shown in the scheme.
ChemInform Abstract: Functional Trimethylphosphine Derivatives. Part 26. Silyl‐Substituted Phosphinomethanes and Lithiumphosphinomethanides.
Authors: KARSCH H. H. , APPELT A. , DEUBELLY B. , ZELLNER K. , RIEDE J. , MUELLER G. + 
Published: May 2016

AbstractThe Li phosphinomethanides (I) react with Me3SiCl (II) to give the silyl‐substituted phosphinomethanes (III).
ChemInform Abstract: Dimolybdenum(II) Complexes that Contain the Ligand cis‐Ph2PCH=CHPPh2 (dppee). Synthesis and Characterization of the α‐ and β‐Isomers of Mo2X4(dppee)2 (X: Cl, Br).
Authors: BAKIR M. , COTTON F. A. , FALVELLO L. R. , SIMPSON C. Q. , WALTON R. A. 
Published: May 2016

AbstractThe α‐ and β‐isomers (I) and (II) of the title complexes are prepared by different routes.
ChemInform Abstract: Linkage of Alkylidyne, Carbonyl, and Alkyne Ligands at a Tungsten Center: Formation of a Metallacyclopentadienone and of an η3‐Oxocyclobutenyl Complex.
Authors: MAYR A. , LEE K. S. , KAHR B. 
Published: May 2016

AbstractThe conversion of alkylidyne into alkylidene complexes, which is of interest in connection with the catalysis of acetylene polymerization, is demonstrated by the reaction of (I) with phenylacetylene (II).
ChemInform Abstract: Synthesis and Characterization of Stable Rhenium(V) Dioxo Complexes with Acyclic Tetraamine Ligands, (LReO2)+.
Authors: PARKER D. , ROY P. S. 
Published: May 2016

AbstractThe title complexes (I) are prepared in a single‐step synthesis from trans‐ReOCl3(PPh3)2 and the corresponding acyclic tetraamines in dry CHCl3.
ChemInform Abstract: Electron‐Transfer Activation in the Thermal and Photochemical Osmylations of Aromatic EDA Complexes with Osmium(VIII) Tetroxide.
Authors: WALLIS J. M. , KOCHI J. K. 
Published: May 2016

AbstractVarious types of arenes spontaneously form with OsO4 a series of highly colored solutions of electron donor‐acceptor complexes in nonpolar solvents.
ChemInform Abstract: Reaction of Dianions Derived from β‐Ketoesters with Epoxides‐Utility in the Preparation of Synthetically Useful Tetrahydrofurans.
Authors: LYGO B. , O'CONNOR N. , WILSON P. R. 
Published: May 2016

AbstractSeveral examples are presented for the preparation of tetrahydrofurans such as (III), (VI) or (IX).
ChemInform Abstract: 4(5)‐Vinylimidazole by Dehydrobromination of 1‐Triphenylmethyl‐4‐(2‐bromoethyl)imidazole.
Authors: ALTMAN J. , WILCHEK M. 
Published: May 2016

AbstractThe bromoethylimidazole hydrobromide (I) is tritylated and then treated with ethoxide to form the N‐trityl‐4‐vinylimidazole (IV) which is detritylated to give 4‐vinylimidazole (V).
ChemInform Abstract: Rearrangement of o‐Nitrosubstituted Benzenes to o‐Nitrosoketones and Synthesis of 2,1‐Benzoxazine Derivatives.
Authors: FEDOTOV A. N. , TROFIMOVA E. V. , MOCHALOV S. S. , SHABAROV YU. S. 
Published: May 2016

AbstractThe reaction between o‐nitrobenzylcyclopropane (I) or o‐nitrophenylbut‐2‐ene (VII) and conc.
ChemInform Abstract: Synthetic Molecular Receptors for Urea. Macrocyclic Ligands with Intraannular Acidic Groups and the Complexes with Urea.
Authors: VAN STAVEREN C. J. , AARTS V. M. L. J. , GROOTENHUIS P. D. J. , DROPPERS W. J. H. , VAN EERDEN J. , HARKEMA S. , REINHOUDT D. N. 
Published: May 2016

AbstractA systematic study is carried out on the effect of intraannular acidic groups present in the cavities of the macrocycles (III), (IV), (VIII), (X) on the complexation of urea.
ChemInform Abstract: Oxidations of Some α‐Amino Acids Under Mitsunobu Reaction Conditions.
Authors: KOLASA T. , MILLER M. J. 
Published: May 2016

AbstractTreatment of the N‐acylamino acid esters (I) with diisopropyl azodicarboxylate (II) in the presence of triphenylphosphine (Mitsunobu conditions) results in the formation of the cyclocondensation products (III) ‐ (V) depending on the substitution patterns.
ChemInform Abstract: Regiospecific Formation of Alkylidene‐1,2‐oxasiletane.
Authors: SASO H. , YOSHIDA H. , ANDO W. 
Published: May 2016

AbstractThe alkylidenesilirane (I) reacts with cyclohexyldimethylamine N‐oxide to give the alkylideneoxasiletane (II) which is hydrolyzed to yield the silanol (IV).
ChemInform Abstract: Synthesis of Phosphonic Acid Derivatives by Oxidative Activation of Phosphinate Esters.
Authors: SAMPSON N. S. , BARTLETT P. A. 
Published: May 2016

AbstractSilylation of the ethyl phosphinate (Ia) with bis(trimethylsilyl)acetamide (II) and subsequent oxidation with tetrachloromethane in the presence of the alcohols (IV) give the phosphonates (V) via the corresponding phosphonochloridate.
ChemInform Abstract: C‐H Oxidative Addition and Reductive Elimination Reactions in a Dinuclear Iridium Complex.
Authors: MCGHEE W. D. , HOLLANDER F. J. , BERGMAN R. G. 
Published: May 2016

AbstractThermolysis of the hydrido‐allyl complex (I) at relatively high concentrations of starting material in benzene (II) leads to the benzene C‐H oxidative addition product (III).
ChemInform Abstract: Synthesis of 2,7,10,15,18,23‐Hexamethyltetracosane, a Squalane Isomer from the Telomer of Isoprene and Acetoacetic Ester.
Authors: ZAKHARKIN L. I. , ANIKINA E. V. , PETROVSKII P. V. 
Published: May 2016

AbstractTelomerization of isoprene (I) with ethyl acetoacetate (II) affords a mixture of at least six isomeric telomers differing in the structure of the dimethyloctadienyl moiety.
ChemInform Abstract: Amino Acids and Peptides. Part 205. An Alternative Route to Nα‐Methylamino Acid Derivatives: Synthesis and Conformation of Some Nα‐Acetyl‐Nα‐Methylamino Acid Methylamides.
Authors: HLAVACEK J. , FRIC I. , BUDESINSKY M. , BLAHA K. 
Published: May 2016

AbstractThe methylation of Nα‐4‐toluenesulfonylamino acid esters such as (I) by dimethyl sulfate (II) in the presence of a detergent leads to the Nα‐methyl derivatives (III) which are converted to the title compounds (VIII).
ChemInform Abstract: Electrochemical Stability of LiMF6 (M: P, As, Sb) in Tetrahydrofuran and Sulfolane.
Authors: NANJUNDIAH C. , GOLDMAN J. L. , DOMINEY L. A. , KOCH V. R. 
Published: May 2016

AbstractBecause of the instability and potential toxicity of LiAsF6, which is one of the most popular supporting electrolytes in rechargeable Li batteries, the electrochemical stability of LiSbF6 and LiPF6 in aprotic solvents is studied.
ChemInform Abstract: Correlation Between Environmental and Electrochemical Corrosion of Thin Film Magnetic Recording Media.
Authors: NOVOTNY V. , STAUD N. 
Published: May 2016

AbstractCobalt alloys with and without thin overcoats are studied by XPS, AES, SIMS, SEM after exposure to different environments (varying temp., humidity, addition of corrosive gases such as Cl2, SO2, H2S, NO2).
ChemInform Abstract: Synthesis and Some Reactions of β‐Keto Anilides.
Authors: EL‐HOSSINI M. S. , KHALIL A. M. , OSMAN A. I. , EL‐ABLAC F. Z. 
Published: May 2016

AbstractVarious substitution and cyclocondensation reactions of the keto anilides (III), prepared by Michael reaction of the dibenzylidenecyclohexanones (I) with the acetoacetanilides (II), are performed as described in the reaction scheme.
ChemInform Abstract: Asymmetric Induction in the (2,3) Wittig Rearrangement. The Stereoselective Synthesis of Unsaturated Alcohols with Three Contiguous Stereogenic Centers.
Authors: BRUECKNER R. + 
Published: May 2016

AbstractThe (2,3) Wittig rearrangement of the lithio anions derived from the cis‐ or trans‐configurated allyl propargyl ethers (I) possessing a chiral dioxolane moiety results in the diastereoselective formation of two new stereogenic centers to give the anti‐ and syn‐dioxygenated systems (II) or (III).
ChemInform Abstract: α‐Hydroxylation of Thiazolyl and Benzothiazolyl Ketones Using Iodobenzene Diacetate Under Basic Conditions.
Authors: PRAKASH O. , GOYAL S. , SEHGAL S. , SINGH S. P. , MORIARTY R. M. 
Published: May 2016

AbstractOxidation of the ketones (I) according to A) yields the dimethyl acetals (II).
ChemInform Abstract: Synthetic Utility of 3‐(Perfluoro‐1,1‐dimethylbutyl)‐1‐propene. Part 1. Conversion to the Epoxide and to Alcohols.
Authors: DMOWSKI W. , PLENKIEWICZ H. , PORWISIAK J. 
Published: May 2016

AbstractThe conversion of the alkene (I) mentioned in the title to its epoxide (II) is accomplished by direct epoxidation or, more effective, via the bromo acetates (IV) and (V).
ChemInform Abstract: Studies on 4‐Thiazolidinones. Part 5. Synthesis and Antimicrobial Activity of 2‐Aryl‐3‐(2′,4′‐diphenylamino‐s‐triazin‐6′‐yl)‐5H/methyl/carboxymethyl‐4‐thiazolidinones.
Authors: MEHTA L. , PAREKH H. 
Published: May 2016

AbstractStarting with the bis(anilino)chlorotriazine (I), the Schiff bases (V) are prepared by ammonolysis and subsequent condensation reaction with the aldehydes (IV).
ChemInform Abstract: Inhibition of Monoamine Oxidase Types A and B by 2‐Aryl‐4H‐1,3,4‐oxadiazin‐5(6H)‐one Derivatives.
Authors: MAZOUZ F. , LEBRETON L. , MILCENT R. , BURSTEIN C. 
Published: May 2016

AbstractMonoamine oxidase (MAO) is responsible for the metabolic inactivation of amine neurotransmitters such as serotonin and dopamine.
ChemInform Abstract: Al‐C Bond Reactivity in a Bidentate Ligand System: Structure and Reactivity Studies of (Al(8‐quinolinol)(C2H5)2)2.
Authors: DZUGAN S. T. , GOEDKEN V. L. 
Published: May 2016

AbstractThe title compound (I) is prepared from Al2Et6 and 8‐quinolinol and characterized by X‐ray structure analysis (space group P21/c, Z=4) and 1H NMR spectroscopy.
ChemInform Abstract: Transition Metal Complexes with Sulfur Ligands. Part 38. 18 and 19 Electron Iron(II) Nitrosyl Complexes with Thiolato Thioether Ligands Including Nitrogen and Oxygen Donators in S5, OS4, NS4, S4 and S3 Donator Sets: Synthesis and Reactions of (Fe(NO)(′S5′))n+, (Fe(NO)(′NHS4′))n+ (n = 0, 1) and (Fe(NO)2(L)) and X‐Ray Structure Analysis of (Fe(NO)(′NHS4′)).
Authors: SELLMAN D. , KUNSTMANN H. , MOLL M. , KNOCH F. 
Published: May 2016

AbstractThe mononitrosyl‐Fe(II) complexes (III) and (IV) are obtained from the CO analogues e.g. (I) and NOBF4 (II).
ChemInform Abstract: Metal Ion Promoted Reactions in Organic Synthesis. Intramolecular Condensations Between Ligands Containing Amine and Carbonyl Groups.
Authors: ENGELHARDT L. M. , GAINSFORD A. R. , GAINSFORD G. J. , GOLDING B. T. , HARROWFIELD J. MACB. , HERLT A. J. , SARGESON A. M. , WHITE A. H. 
Published: May 2016

AbstractThe intramolecular condensation of monodentate ligands NH2‐CH2‐CO‐R (R: H, Me, Ph) with quadridentate amines such as tris(2‐aminoethyl)amine and 1,8‐diamino‐3,6‐diazaoctane bound to Co(III) ions is explored in terms of controlling the regiospecificity and stereospecificity of such reactions.
ChemInform Abstract: Sequential Synthesis of “FePt”, “FePt2”, and “FePt3” Complexes from the Reaction of Fe(CO)4(PR2H) with Pt(C2H4)2(PCy3). A Detailed Look at a Cluster Assembly Process.
Authors: POWELL J. , GREGG M. R. , SAWYER J. F. 
Published: May 2016

AbstractOxidative addition of the P‐H bond of the Fe complexes (I) to the Pt(0) complex (II) in CD2Cl2 gives rise to a range of "FePt", "FePt2", and "FePt3" clusters such as the isolable (III), (IV), and (V) depending of the initial Fe:Pt stoichiometry.
ChemInform Abstract: Synthesis, X‐Ray Crystal Structure, and Antimitotic Properties of 6‐Chloro‐2‐methoxy‐5‐(2′,3′,4′‐trimethoxyphenyl)cyclohepta‐2,4,6‐trien‐1‐one, a Bicyclic Analogue of Colchicine.
Authors: BANWELL M. G. , HERBERT K. A. , BUCKLETON J. R. , CLARK G. R. , RICKARD C. E. F. , LIN C. M. , HAMEL E. 
Published: May 2016

AbstractStarting with the isopropoxycyclohexenone (I), the dichlorobicycloheptenone (XVI) is prepared via addition of dichlorocarbene to the diacetoxycyclohexene (VIII).
ChemInform Abstract: Highly syn‐Selective Reduction of α‐Phenylthio‐β‐methoxy Ketones with Superhydride.
Authors: SHIMAGAKI M. , SUZUKI A. , NAKATA T. , OISHI T. 
Published: May 2016

AbstractReduction of the title compounds (I) with LiBHEt3 (superhydride) leads to the selective formation of the syn‐alcohols (III), together with minor amounts of the antialcohols (IV).
ChemInform Abstract: A 5C + 5C Bicycloaromatization Reaction via an Aldol Condensation Cascade: A Regioselective Synthesis of Functionalized Naphthalenes from Acyclic Precursors.
Authors: STOSSEL D. , CHAN T. H. 
Published: May 2016

AbstractThe tris(trimethylsiloxy)methoxyhexatriene (II) undergoes cyclocondensation reaction with the acetals (I), (IV), or (VI) in the presence of Lewis acids, producing the phenols (III), (V), or (VII).
ChemInform Abstract: The Reaction of Alkyl‐Substituted Thioanisoles with PCl3 and AlCl3: A Route to (1,2,3)Benzothiadiphospholo(2,3‐b) (1,2,3)benzothiadiphosphole Derivatives.
Authors: BACCOLINI G. , MEZZINA E. , TODESCO P. E. 
Published: May 2016

AbstractWhen analogues of the title thioanisoles (I) with R1: ‐Br, ‐Cl, ‐NH‐Ac, ‐O‐Me are used for the reaction with PCl3 (II) no products of type (III) are formed.
ChemInform Abstract: Synthesis of Isoselenazolo‐ and Isothiazolo(4,3‐e)(1,4)diazepines.
Authors: UEDA T. , KATO Y. , SAKAKIBARA J. , MURATA M. 
Published: May 2016

AbstractThe isoselenazolo‐ and isothiazolopyrimidines (I) react with with malononitrile (II) to form the dicyanovinylamino compounds (III) which are hydrolyzed to yield the amino derivatives (IV).
ChemInform Abstract: Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 81. Reactions of the Compound (Fe2(μ‐CH2)(CO)8) with Alkylidyne‐Molybdenum and ‐Tungsten Complexes. Reactivity of the Product (WFe(.mu±sigma.:η‐CH=CH(C6H4Me‐4))(CO)6(η‐C5H5)), and Crystal Structures of the Species (W2Fe(μ3‐CC6H4Me‐4)(.mu±sigma.:η‐C(C6H4Me‐4)=CH2)(CO)6(η‐C5H5)2) and (WFe(μ‐C(Et)C(Et)C(H)CH(C6H4Me‐4))(μ‐CO)(CO)4(η‐C5H5)).
Authors: JEFFERY J. C. , PARROTT M. J. , STONE F. G. A. 
Published: May 2016

AbstractTreatment of the dinuclear title Fe compound (I) with the alkylidyne complexes (II) affords the complexes (III) as the main products.
ChemInform Abstract: Fragmentation and Wittig Olefination of Glucosamine Derivatives ‐ A Simple Route to Open Chain Amino Sugars and Chiral Glycerols.
Authors: GIANNIS A. , MUENSTER P. + , SANDHOFF K. , STEGLICH W. 
Published: May 2016

AbstractThe Wittig reaction between the N‐protected amino sugar (I) and the non‐stabilized ylides (II) affords the chiral glycerol derivatives (III) instead of the expected chain‐elongated sugars.
ChemInform Abstract: Synthesis of Thyroid Hormone Analogues. Part 3. Iodonium Salt Approaches to SK&F L‐94901.
Authors: HICKEY D. M. B. , LEESON P. D. , NOVELLI R. , SHAH V. P. , BURPITT B. E. , CRAWFORD L. P. , DAVIES B. J. , MITCHELL M. B. , PANCHOLI K. D. , TUDDENHAM D. , LEWIS N. J. , O'FARRELL C. 
Published: May 2016

AbstractThe key step in the synthesis of SK&F L‐94901 (VI) is the formation of the diaryl ether (V) by copper‐catalyzed coupling of the sym. bisaryliodonium salt (III) with the protected dibromotyrosine (IV).
ChemInform Abstract: The Discharge Behavior of Active Metal Anodes in Bromine Trifluoride
Authors: PARK K. H. , MILES M. H. , BLISS D. E. , STILWELL D. , HOLLINS R. A. , RHEIN R. A. 
Published: May 2016

Abstractis studied because the use of BrF3 and BrF5 with Li and other active metal anodes (Ca and Mg are also studied) offers the possibility of new battery systems with high cell voltages and energy densities.
ChemInform Abstract: Chiral Lithium: Conformation and Dynamic Behavior of Monomeric Neopentyllithium‐N,N,N′,N′,N′′‐Pentamethyldiethylenetriamine Complex.
Authors: FRAENKEL G. , WINCHESTER W. R. 
Published: May 2016

AbstractThe structure of the chiral monomeric complex (I) can be described by NMR studies because at 160 K the species is conformationally locked into one rotamer, due to steric interactions, and all bond exchange processes are slow relative to the NMR time scale.
ChemInform Abstract: Control of Reaction Rates in Vesicular Systems.
Authors: CUCCOVIA I. M. , KAWAMURO M. K. , KRUTMAN M. A. K. , CHAIMOVICH H. 
Published: May 2016

AbstractVesicles are prepared by injecting the amphiphile (I) in CHCl3 into an aqueous solution of the substrate (II) (pH 5.3).
ChemInform Abstract: Formation of Benzoxathiete Under Mild Conditions and Its Valence Tautomerism in Solution to Monothio‐o‐benzoquinone: An Experimental and Quantum Chemical Study.
Authors: NAGHIPUR A. , RESZKA K. , SAPSE A.‐M. , LOWN J. W. 
Published: May 2016

AbstractAprotic diazotization of the sulfinyl anilines (I) in the presence of the trapping agents (IV) or (VIII) affords products that include biphenylene (V) and dibenzooxathiane (VI) and the compounds of trapping (VII) or (IX), respectively.
ChemInform Abstract: Thermal Fragmentation of 2‐Azidobenzo(b)thiophene in the Presence of Alkenes: A New Synthetic Route to 1‐(2‐Benzo(b)thienyl)aziridines and/or Thiochroman‐4‐carbonitriles.
Authors: SPAGNOLO P. , ZANIRATO P. 
Published: May 2016

AbstractThermal fragmentation of the azidobenzothiophene (I) in the presence of olefins such as (II) results in formation of the aziridines (III) and the cyanothiochromans (IV) and (V), the ratio being dependent on the nature of the substituent R1 and on the temperature.
ChemInform Abstract: Reactions of Uracils. Part 15. 7‐Ethoxypyrimido(4,5‐d)pyrimidines via a Uracil‐Carbodiimide Derivative and Their Products of Aminolysis and Pyrolysis.
Authors: WAMHOFF H. , MUHR J. 
Published: May 2016

AbstractReaction of the 6‐(phosphoranylideneamino)uracil‐5‐carboxylate (I) with the isocyanates (II) yields the title compounds (III) which are converted into the 7‐amino derivatives (V) by displacement of the ethoxy group with the amines (IV).
ChemInform Abstract: (1,2,4)Triazino(6,5‐e)‐1,2,4‐triazines. Part 2.
Authors: NEUNHOEFFER H. , REICHEL D. 
Published: May 2016

AbstractThe title compounds (XI) are prepared from the 6‐aminodihydro‐1,2,4‐triazin‐5‐ones (I) via the 2‐methyl (IV), 5‐thioxo (V), and the phenylhydrazono derivative (VII).
ChemInform Abstract: Generation of Spirocyclic Quaternary Centres via a Tandem Free Radical Cyclopropylcarbinyl Rearrangement‐Cyclization Strategy.
Authors: HARLING J. D. , MOTHERWELL W. B. 
Published: May 2016

AbstractCoupling of the silylbutynyllithium compound (II) with the enol ether (I) of dimedone yields the cyclohexenone (III) which is converted into the bicyclo(4.1.0)heptane (VIII) via reduction, cyclopropanation, and reaction with thiocarbonyldiimidazole (VII).
ChemInform Abstract: An Improved Access to Phosphonic Acids and Their Mono‐ and Diesters.
Authors: PLENAT F. , IBRAHIM S. , CRISTAU H.‐J. 
Published: May 2016

AbstractReaction of the phosphonic dichlorides (I) with benzyl alcohol (III) and the aliphatic alcohols (II) yields mixtures of the dibenzyl phosphonates (V), the dialkyl phosphonates (IV), and the mixed diesters (VI).
ChemInform Abstract: Anthelmintic Activity of Organo‐Tellurium Compounds.
Authors: ORDYNTSEVA A. P. , SIVOVOLOVA I. D. , ABAKAROV G. M. , SABEKOVA E. I. 
Published: May 2016

AbstractCyclization of o‐methyltelluryl‐N‐benzoylanilin (I) yields 2‐phenylbenzotellurazole (III) which is brominated to give the dibromotellurazole (IV).