bluuebunny/crossref_metadata_2025_split huggingface dataset:
Effect of the exposure time on the structure and performance of hydrophobic polydimethylsiloxane–poly(vinylidene fluoride) membranes via a non‐solvent‐induced phase separation process in a clean room
Authors: Zhang Heiyan , Li Bingbing , Sun De , Li Dayong , Li Jing , Shao Xiaofeng 
Published: May 2016

ABSTRACTThe objective of this study was to investigate the effects of the exposure time on the properties and permeability of polydimethylsiloxane (PDMS)–poly(vinylidene fluoride) (PVDF) blend hydrophobic microporous membranes, which were fabricated via a non‐solvent‐induced phase separation process at 25 °C and 60% relative humidity in a clean‐room circumstance. For the prepared PDMS–PVDF membranes, the membrane morphologies were observed by scanning electron microscopy. Crystalline structures were observed by X‐ray diffraction. Pore structures were analyzed by membrane porosity and mean pore size. Hydrophobicity was measured by contact angle measurement, and the mechanical properties were characterized by tensile strength testing. Our study results show that with increasing exposure time from 10 to 110 s, all of the membranes showed a similar pore structure: a spongelike substrate layer with a thin realm of fingerlike structures under the top surface. Phase separation between PDMS and PVDF occurred. The membrane porosity and mean pore radius decreased, and the membrane thickness increased. The membrane hydrophobicity decreased, and the mechanical properties first increased and then decreased. In addition, vacuum membrane distillation experiments were conducted. With the increase in the exposure time from 10 to 110 s, the membrane permeate flux decreased from 16.54 to 6.65 kg m−2·h−1, and the salt rejection was higher than 99.9%. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43842.
Poly1‐hexene: New impact modifier in HIPS technology
Authors: Hanifpour Ahad , Bahri‐Laleh Naeimeh , Nekoomanesh‐Haghighi Mehdi , Mirmohammadi Seyed Amin 
Published: May 2016

ABSTRACTPoly1‐hexene was prepared using a conventional heterogeneous Ziegler–Natta catalyst and its stereoregularity was characterized using 13C‐NMR analysis. New kind of high impact polystyrene (HIPS) was prepared by radical polymerization of styrene in the presence of different amounts of synthesized poly1‐hexene (PH) as impact modifier (HIPS/PH) and compared with conventional high impact polystyrene with polybutadiene (HIPS/PB) as rubber phase. Scanning electron microscopy (SEM) revealed that the dispersion of poly1‐hexene in polystyrene matrix was more uniform compared with it in HIPS/PB. The impact strength of HIPS/PH was 29–79% and 80–289% higher than that in HIPS/PB and neat polystyrene, respectively. FTIR was used to confirm more durability of HIPS/PH samples toward ozonation. To study the effect of rubber type and amount on the Tgs of polystyrene, differential scanning calorimetry was employed. Results obtained from TGA demonstrated higher thermal stability of HIPS/PH sample in comparison with conventional HIPS/PB one. Our obtained results suggest new high impact polystyrene that in all studied aspects has better performance than the conventional HIPS. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43882.
On the treatment of binary data by means of ranks
Authors: Bennett B. M. 
Published: May 2016

AbstractThe justification of the use of mid‐ranks in proposing test statistics for hypotheses involving binary data is discussed and illustrated for several situations, including the ‘index of dispersion’ in 2 × k contingency tables (e.g. Fisher, 1954), the Mantel‐Haenszel (1959) hypothesis of equality of relative risk in a series of 2 × 2 contingency tables, and finally the problem of quantal assays (e.g. Finney, 1964).
Some aspects of distribution theories in quantitative genetics I. Some general results
Authors: Tan W. Y. 
Published: May 2016

AbstractThis paper derives the probability distributions of quantitative genetics for more general quantitative genetic models. Under the assumption of normal environmental disturbances, it is shown that the probability distributions of phenotypic values in segregating populations are in general mixtures of normals. The mixing proportion in the population is then derived for various mating systems. As an extension of the results, the joint distribution of two linked quantitative characters is also derived as mixtures of bivariate normals.
Combined metabolomics and proteomics reveals hypoxia as a cause of lower productivity on scale‐up to a 5000‐liter CHO bioprocess
Authors: Gao Yuanwei , Ray Somak , Dai Shujia , Ivanov Alexander R. , Abu‐Absi Nicholas R. , Lewis Amanda M. , Huang Zhuangrong , Xing Zizhuo , Borys Michael C. , Li Zheng Jian , Karger Barry L. 
Published: May 2016

AbstractLarge‐scale bioprocessing is key to the successful manufacturing of a biopharmaceutical. However, cell viability and productivity are often lower in the scale‐up from laboratory to production. In this study, we analyzed CHO cells, which showed lower percent viabilities and productivity in a 5‐KL production scale bioreactor compared to a 20‐L bench‐top scale under seemingly identical process parameters. An increase in copper concentration in the media from 0.02 µM to 0.4 µM led to a doubling of percent viability in the production scale albeit still at a lower level than the bench‐top scale. Combined metabolomics and proteomics revealed the increased copper reduced the presence of reactive oxygen species (ROS) in the 5‐KL scale process. The reduction in oxidative stress was supported by the increased level of glutathione peroxidase in the lower copper level condition. The excess ROS was shown to be due to hypoxia (intermittent), as evidenced by the reduction in fibronectin with increased copper. The 20‐L scale showed much less hypoxia and thus less excess ROS generation, resulting in little to no impact to productivity with the increased copper in the media. The study illustrates the power of 'Omics in aiding in the understanding of biological processes in biopharmaceutical production.
Outcome of paravalvular leak repair after transcatheter aortic valve replacement with a balloon‐expandable prosthesis
Authors: Dhoble Abhijeet , Chakravarty Tarun , Nakamura Mamoo , Abramowitz Yigal , Tank Rikin , Mihara Hirotsugu , Mangat Geeteshwar , Jilaihawi Hasan , Shiota Takahiro , Makkar Raj 
Published: May 2016

BackgroundSignificant paravalvular leak (PVL) occurs in up to 13% of patients after transcatheter aortic valve replacement (TAVR) with a balloon‐expandable bioprosthesis. Transcatheter PVL repair has emerged as a less invasive alternative for this problem.ObjectivesThe aim of this study was to evaluate the safety, feasibility, and clinical outcomes of transcatheter PVL repair after TAVR with balloon‐expandable valve.MethodsWe retrospectively identified 15 patients who underwent 16 PVL repair procedures after the TAVR at our center. Procedural characteristics, results, and clinical outcomes were analyzed. The association of PVL repairs with subsequent hospitalizations and mortality was assessed and compared to 57 patients who did not undergo repair for at least moderate PVL after TAVR.ResultsThe PVL repair was successful in 13 (87%) patients, without significant procedure or device related complications. In patients with successful PVL repair, there was an improvement in symptom status, subsequent hospitalizations, and B‐type natriuretic peptide levels. There was 1 (out of 13, 8%) death in the group of patients who successfully underwent PVL repair whereas 24 (out of 57, 42%) patients died during follow up in the group that did not undergo repair of their PVL. Similarly, there was significant reduction in the subsequent heart failure related hospitalization after the PVL repair, compared with the patients who did not undergo PVL repair (P = 0.03).ConclusionTranscatheter repair of PVL after TAVR can be safely and effectively accomplished in carefully selected patients, and may lead to reduction in hospitalizations, improvement in symptoms, and long‐term survival. © 2016 Wiley Periodicals, Inc.
Relationship of mitral valve annulus plane and circumflex‐right coronary artery plane: Implications for transcatheter mitral valve implantation
Authors: Kapadia Samir R. , Mentias Amgad , Barakat Amr F. , Raza Mohammad Q. , Lal Poddar Kanhaiya , Baeza Cristian , Maluenda Gabriel , Navia Jose , Schoenhagen Paul , Murat Tuzcu E. 
Published: May 2016

AimTranscatheter mitral valve implantation (TMVI) is a novel technology for patients with severe mitral valve disease but at high surgical risk. Imaging guidance during the procedure is critical for successful device deployment. Identification of the mitral annular plane (MAP) with fluoroscopy during the procedure is limited by lack of clearly defined landmarks. We hypothesized that a plane defined by left circumflex‐right coronary arteries (LCX‐RCA) would have a consistent relationship to MAP.Methods and resultsWe studied 25 patients with gated cardiac computed tomography. We identified the MAP and the LCX‐RCA plane in mid systole and diastole. The distance between the two planes in prespecified four points (anterior, posterior, medial, and lateral) in the apical 2 and 3‐chamber views. Alignment of the planes was described by cranial/caudal angulation for both planes in RAO 30° and LAO 90° (lateral) angulation. Mean age was 81 ± 9 years, 56% of patients had ≥2+ mitral regurgitation. In mid systole, the distances between the LCX‐RCA plane and the MAP in the four points were < 5 mm in 92% of patients. In mid diastole, distances were < 5 mm in 100% of patients. In mid systole, the correlation between the caudal/cranial orientations of the 2 planes was 0.85 and 0.80 in the LAO 90° and RAO 30°, respectively (P = <0.001). In mid diastole, this was 0.92 and 0.92 in the LAO 90° and RAO 30°, respectively (P = <0.001).ConclusionLCX‐RCA plane has a close and consistent relationship to the MAP and can be useful to guide TMVI.Accurate imaging of mitral valve annular plane during TMVI procedure is challenging. MAP guided by fluoroscopy might be crucial to guide successful prosthesis deployment. A plane defined by the left circumflex‐ right coronary arteries in the atrioventricular grove has a consistent relationship with MAP; this can be used aided by pre‐procedural MDCT to guide TMVI procedure. © 2016 Wiley Periodicals, Inc.
Novel, Highly Conductive Pt/TiO2 Thin‐Film Model Catalyst Electrodes: The Role of Metal–Support Interactions
Authors: Gebauer Christian , Hoffmann Doris , Jusys Zenonas , Behm R. Jürgen 
Published: May 2016

AbstractToward the aim of better understanding of metal–support interactions in oxide‐supported Pt electrocatalysts, planar Pt/TiO2 model catalyst electrodes that combine high conductivity and direct Pt–TiO2 interactions are prepared and characterized. These consist of thin TiO2 films decorated with Pt nanoparticles on a glassy carbon substrate. TiO2 films are deposited by using a potential‐induced sol–gel process and subsequently functionalized with Pt nanoparticles, by electrochemical Pt deposition, deposition of pre‐formed Pt nanoparticles or by photo‐assisted local reduction of Pt ions. Scanning electron microscopy, transmission electron microscopy and X‐ray photoelectron spectroscopy are used for structural and electronic characterization of the model catalyst electrodes, as are cyclic voltammetry, electrooxidation of pre‐adsorbed CO and O2 reduction for evaluating their electrochemical/electrocatalytic properties. The impact of the Pt deposition method, of particle size effects and of metal–support interactions on the electrochemical properties and the catalytic activity/selectivity of these systems is discussed.
ChemInform Abstract: Optical Spectra, X‐Ray Photoelectron Spectra and XANES of Divalent Nickel in Mixed Spinels NiFe2‐xCrxO4
Authors: LENGLET M. , D'HUYSSER A. , JOERGENSEN C. K. 
Published: May 2016

Abstract(0 ≤ x ≤ 2) have been measured at room temperature.
ChemInform Abstract: Anionic Rearrangements of syn‐ and anti‐7‐Cyclopentenyl‐7‐hydroxynorbornenes. The Case for Sequential Ring Cleavage and Intramolecular Michael Addition.
Authors: PAQUETTE L. A. , PIERRE F. , COTTRELL C. E. 
Published: May 2016

AbstractThe mechanistic processes which act in the reactions of several syn‐ and anti‐norbornenols such as (III)‐(VI) with iodine‐pretreated KH in THF are investigated and discussed in detail.
ChemInform Abstract: Wittig‐Horner Reaction and Transformations of Aldehydes and Ketones into Higher Amines. Part 1. A New Rearrangement: Iminophosphonates‐ Phosphoramidates. Evidence and Investigation.
Authors: HEYMES A. , CHEKROUN I. 
Published: May 2016

AbstractThe iminophosphonate (Ia), prepared from the corresponding aminomethylphosphonate and o‐chlorobenzaldehyde, undergoes Wittig‐Horner reaction with the thiophenecarbaldehyde (II).
ChemInform Abstract: Photochemistry of (η5‐idenyl)2Fe2(CO)4 in the Presence of 2e‐ Donor Ligands: Reversible Formation of the Radicals (indenyl)Fe(CO)2L.
Authors: WUU Y.‐M. , ZOU C. , WRIGHTON M. S. 
Published: May 2016

AbstractIrradiation of the dimeric title complex (I) in the presence of CCl4 or Mn2(CO)10 gives the mononuclear compounds (II) or (IV).
ChemInform Abstract: Selective Oxidations with Activated Carbon: Application to Substrates Containing Acidic Methine and Methylene Groups.
Authors: ANANDA G. D. S. , CREMINS P. J. , STOODLEY R. J. 
Published: May 2016

AbstractActivated charcoal is employed as a mediator in the oxidation of several unsaturated compounds: the cephem dioxide (I) and the enone (IIIa) are converted to the allylic alcohols (II) and (IIIb) respectively.
ChemInform Abstract: A New Synthesis and the Crystal Structure Analysis of “Croconate Blue”, 1,2,4‐Tris(dicyanomethylene)croconate.
Authors: AUCH J. , BAUM G. , MASSA W. , SEITZ G. 
Published: May 2016

AbstractIn the condensation product (III) the two dimethylamino groups can be replaced by the anion of (II).
ChemInform Abstract: Amberlyst‐A21 as a New and Efficient Surface Catalyst for the Conjugate Addition of Nitroalkanes to Methyl Acrylate: An Improved Synthesis of Methyl 4‐Nitro‐ and 4‐Oxoalkanoates.
Authors: BALLINI R. , PETRINI M. , ROSINI G. 
Published: May 2016

AbstractMichael addition of the nitroalkanes (I) to methyl acrylate (II) gives the 4‐nitroalkanoic esters (III) which are converted to the 4‐oxoalkanoic esters (IV) by a Nef reaction using potassium permanganate as the oxidant.
ChemInform Abstract: Reactions on Heterocycles Containing the 2‐Acyl‐2‐propenone Structure. Part 5. (1)Benzopyrano(4,3‐b)pyridine‐2,5(2H,5H)‐diones by Cyclization of 3‐Substituted 4‐Aminocoumarins.
Authors: HEBER D. 
Published: May 2016

AbstractThe 4‐chlorocoumarin‐3‐carbaldehyde (I) undergoes Wittig reaction with the methoxycarbonylmethylidenephosphorane (II), producing the benzopyranylacrylates (III).
ChemInform Abstract: Reactivity of 5‐Hydroxymethylpyridazin‐3(2H)‐ones Toward Organomagnesium Halides.
Authors: SHAMS N. A. , SOLIMAN E. A. , HAMED A. A. , DONIA S. A. 
Published: May 2016

AbstractThe arylhydroxymethylpyridazinones (I) react with the Grignard compounds (II) to produce a mixture of the pyridazine (III) and (IV).
ChemInform Abstract: Reactions with 2‐Aminobenzimidazole: Synthesis of Several New Pyrimido‐(1,2‐a)benzimidazole Derivatives.
Authors: ABDELHAMID A. O. , RIAD B. Y. , AZIZ S. I. 
Published: May 2016

AbstractThe α‐(het)arylmethylidene nitriles (I), which are prepared from the corresponding aldehydes and 2‐substituted acrylonitriles, react with 2‐aminobenzimidazole (II) to yield the pyrimidobenzimidazole derivatives (III), (IV), or (VI).
ChemInform Abstract: Transition‐Metal‐Promoted Reactions of Boron Hydrides. Part 10. Rhodium‐Catalyzed Syntheses of B‐Alkenylborazines.
Authors: LYNCH A. T. , SNEDDON L. G. 
Published: May 2016

AbstractRh catalysis promotes the one‐step reaction of borazine (I) with the alkynes (II) to give the products (III) and (IV) which can be converted to polymeric B‐N materials.
ChemInform Abstract: Synthesis, Reactions, and Stereochemical Correlations of an Optically Active Tervalent Phosphorus Thio Ester.
Authors: SZAFRANIEC L. J. , SZAFRANIEC L. L. , AARON H. S. 
Published: May 2016

AbstractThe optically pure phosphinate (Ia) is converted to the tervalent phosphorus derivative (III) which shows loss of enantiomeric purity due to partial racemization.
ChemInform Abstract: Phosphine‐Substituted Chelate Ligands. Part 22. α‐Phosphorus‐Substituted N‐Methyl Carboxylic Acid (Thio)Amides.
Authors: KUNZE U. , KRUPPA V. 
Published: May 2016

AbstractThe α‐diphenylphosphanocarboxylic thioamide (IIIc) is prepared from diphenylbenzylphosphane (Ic) and methyl isothiocyanate (II) in the presence of butyllithium.
ChemInform Abstract: Reaction of Bulky Monosubstituted Phosphorus(III) Halides with Disodium Pentacarbonylchromate. Steric and Electronic Factors in the Synthesis of Cr(CO)5 Complexes of Diphosphenes, Phosphinidenes, Phosphanes, Diphosphanes, and Cyclopolyphosphanes.
Authors: BARTLETT R. A. , DIAS H. V. R. , FLYNN K. M. , HOPE H. , MURRAY B. D. , OLMSTEAD M. M. , POWER P. P. 
Published: May 2016

AbstractThe title reactions lead to at least nine different types of products (depending on the size and electronic properties of the substituent on P) as to be seen from the scheme.
ChemInform Abstract: Dynamic Behavior of Dicobalt Hexacarbonyl Propargyl Cations and Their Reactions with Chiral Nucleophiles.
Authors: SCHREIBER S. L. , KLIMAS M. T. , SAMMAKIA T. 
Published: May 2016

AbstractThe dynamic behavior of several dicobalt hexacarbonyl propargyl cations is investigated by variable temp. 1H and 13C NMR methods.
ChemInform Abstract: O‐Glycosyl Imidates. Part 29. Reaction of O‐(Glucopyranosyl) Imidates with Electron‐Rich Heterocycles. Synthesis of C‐Glucosides.
Authors: SCHMIDT R. R. , EFFENBERGER G. 
Published: May 2016

AbstractReaction of the glucosylimidates (Ia) or (Ib) with furans (II) yields the derivatives (III) from which various sequential products such as (V) (VII), (IX) are obtained.
ChemInform Abstract: Crystal Structures of Acid Hydrates and Oxonium Salts. Part 28. On the Highest Hydrates of Sulfuric Acid: Formation and Structure of H2SO4·6.5 H2O and H2SO4·8 H2O.
Authors: MOOTZ D. , MERSCHENZ‐QUACK A. 
Published: May 2016

AbstractA reinvestigation of the phase diagram of the H2SO4‐H2O systems in the range 80‐100 mol% H2O (DTA, XRD) confirms the existence of the title hydrates.
ChemInform Abstract: A Non‐Stereospecific Diels‐Alder Reaction.
Authors: MEIER H. , ECKES H.‐L. , NIEDERMANN H.‐P. , KOLSHORN H. 
Published: May 2016

AbstractIn the Diels‐Alder reaction of (II) the E olefin (IIIa) is added strictly stereospecifically, while the configuration of (IIIb) is inverted totally.
ChemInform Abstract: DABCO‐Catalyzed Coupling of Aldehydes with Activated Double Bonds. Part 7. Stereoselective Synthesis of (E)‐3‐Methylene‐4‐alken‐2‐ones from Aldehydes and Methyl Vinyl Ketone and Their Spontaneous Dimerization.
Authors: HOFFMANN H. M. R. , EGGERT U. , POLY W. 
Published: May 2016

AbstractThe reaction of the aldehydes (I) with the ketone (II) yields the products (III) (no yields given).
ChemInform Abstract: Synthesis of 2‐Amino‐3‐aryl‐1,4‐naphthoquinones from 2‐Arylidenindan‐1,3‐diones.
Authors: KRYSIN M. YU. , ANOKHINA I. K. , ZALUKAEV L. P. 
Published: May 2016

AbstractThe 2‐arylidenindandiones (I) react with NaN3 to yield the title compounds (III), which are probably formed via 1,2,3‐triazole intermediates.
ChemInform Abstract: Phosphorus Compounds of Unusual Coordination. Part 23. Mono‐ and Diphosphatricyclo(3.2.1.02,7)oct‐3‐enes: Synthesis from 1,3‐ and 1,4‐ Dienes and a Stable Phosphaalkyne.
Authors: FUCHS E. P. O. , ROESCH W. + , REGITZ M. 
Published: May 2016

AbstractThe title compounds (IV) and (VI) are obtained via Diels‐Alder reaction of the phosphaalkyne (II) with the dienes (I) and (V) followed by ene‐reaction with a second mol of (II) and subsequent intramolecular (4+2) cycloaddition.
ChemInform Abstract: Phosphinecarboxylate Ligands Formed by the Insertion of Carbon Dioxide into Metal‐Phosphido Bonds. Preparation and Structural Characterization of Tetrakis(di‐tert‐butylphosphinecarboxylato)dimolybdenum.
Authors: BUHRO W. E. , CHISHOLM M. H. , FOLTING K. , HUFFMAN J. C. 
Published: May 2016

AbstractThe phosphido‐amido complex (I) and excess CO2 (II) react to give the mixed‐ligand complex (III) with a Mo‐Mo triply bond.
ChemInform Abstract: Conversion of a .mu±eta.2‐Acetylide to a .mu±eta.2‐||‐Acetylene via Successive Nucleophilic Additions. X‐Ray Structure of Os2(CO)6(.mu±eta.2‐C(C(NH‐t‐Bu)(S‐n‐Bu))‐CPh)(μ‐PPh2).
Authors: CHERKAS A. A. , CARTY A. J. , SAPPA E. , PELLINGHELLI M. A. , TIRIPICCHIO A. 
Published: May 2016

AbstractThe diosmium acetylide complex (I) is converted in two stages to the parallel acetylene derivative (V) according to the scheme.
ChemInform Abstract: Reductive Desorption of Iodine from Platinum Electrodes. A Comparison in Protic and Aprotic Solvents.
Authors: BRAVO B. G. , RODRIGUEZ J. F. , MEBRAHTU T. , SORIAGA M. P. 
Published: May 2016

AbstractExperimental measurements based on thin‐layer electrochemical techniques in water, mixed water‐MeCN, and anhydrous MeCN, show the cathodic stripping of chemisorbed iodine to be coupled with hydrogen chemisorption which results in a net two‐electron, reversible and pH‐dependent process.
ChemInform Abstract: Chiral Molecular Recognition in Small Bimolecular Systems: A Spectroscopic Investigation into the Nature of Diastereomeric Complexes.
Authors: PIRKLE W. H. , POCHAPSKY T. C. 
Published: May 2016

AbstractSolution 1H NMR measurements of chemical shift changes as a function of concentration and temp., UV‐VIS studies of CT bands associated with the formation of the diastereomeric complexes, and T1 and intra‐ and intermolecular NOE studies are performed on solutions of each enantiomer of (II) and the (S)‐(I).
ChemInform Abstract: Cyclobutene Photochemistry. Nonstereospecific Photochemical Ring Opening of Simple Cyclobutenes.
Authors: CLARK K. B. , LEIGH W. J. 
Published: May 2016

AbstractThe photochemistry of the title compounds (I), (V), (Xa), and (Xb) is investigated in hydrocarbon solution with monochromatic far‐ultraviolet (185 or 193 nm) light sources.
ChemInform Abstract: N‐(Benzenesulfonyl)indole as Terminator in a Biomimetic Polyene Cyclization: Synthesis of a Pentacyclic Indolosesquiterpene.
Authors: MIRAND C. , DOEE DE MAINDREVILLE M. + , CARTIER D. , LEVY J. 
Published: May 2016

AbstractThe epoxides (III) and (IV) are prepared from the N‐phenylsulfonyl‐2farnesylindole (I) via the bromohydrin (II).
ChemInform Abstract: Synthesis and Properties of 6‐Substituted 4‐Alkoxy‐5,6‐dihydro‐4H‐thienol(3,2‐b)pyrrol‐5‐ones.
Authors: GEFFKEN D. 
Published: May 2016

AbstractRing closure of the N‐alkoxythienylglycolamides (I) in the presence of DCC yields the title compounds (II).
ChemInform Abstract: Chemistry of 2‐Methoxy‐2,5‐cyclohexadienone. Part 5. Photochemical Rearrangement and Oxidation of 2‐Methoxy‐4‐methyl‐4‐phenyl‐2‐cyclohexenone and 2‐Methoxy‐4‐methyl‐4‐phenyl‐2,5‐cyclohexadienone.
Authors: MATOBA K. , NODA H. , YAMAZAKI T. 
Published: May 2016

AbstractPhotoreaction of the methoxycyclohexenone (III) in methanol gives the cyclohexenone (II) and the bicyclohexanone (I).
ChemInform Abstract: Improved Synthesis of Dicyanocobaloximes and the Molecular and Crystal Structure of Potassium Dicyanobis(dimethylglyoximato)cobaltate(III).
Authors: LOPEZ C. , ALVAREZ S. , SOLANS X. , AGUILO M. 
Published: May 2016

AbstractAn improved method for the preparation of (VI) is presented, producing pure products in high yields.
ChemInform Abstract: Binuclear Copper(II) Complexes of Some Tetradentate (N4) Diazine Ligands with Benzimidazole Donor Groups. Crystal Structure of (μ‐3,6‐Bis(N‐ethyl‐2‐benzimidazolylthio)pyridazine‐N,μ‐N5,μ‐N6,N)‐(.mu# .‐hydroxo)(μ‐chloro)dichlorodicopper(II) DMF.
Authors: THOMPSON L. K. , MANDAL S. K. , ROSENBERG L. , LEE F. L. , GABE E. J. 
Published: May 2016

AbstractThe complexes (IIIb) and (IIIc), as well as (IV) and (V) are prepared by reaction of the metal salt in H2O with the ligands (synthesis described) in MeOH.