bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Oxidative Allene Amination for the Synthesis of Azetidin‐3‐ones.
Authors: Burke Eileen G. , Schomaker Jennifer M. 
Published: February 2016

AbstractA highly regioselective aziridination of the distal bond of homoallenic sulfamates leads to fused azetidin‐3‐ones in excellent diastereoselectivity via bicyclic methyleneaziridines and their subsequent rearrangement.
ChemInform Abstract: Highly Stereoselective Synthesis of Isoindole Derivatives Containing an Azetidinone Ring.
Authors: Hosseinkhani Batool , Islami Mohammad Reza , Hosseinkhani Saman 
Published: February 2016

AbstractIsoindolylbutanoic acid (I) reacts with aromatic imines [e.g. (II) and (IV)] to give trans‐β‐lactams [e.g. (III) and (V)] stereoselectively via [2 + 2]‐cycloaddition of a ketene intermediate and imines.
ChemInform Abstract: Highly Enantioselective Michael Addition Reactions of 2‐Substituted Benzofuran‐3(2H)‐ones to Nitroolefins.
Authors: Zhang Zhi‐Pei , Dong Nan , Li Xin , Cheng Jin‐Pei 
Published: February 2016

AbstractAn asymmetric Michael reaction of 2‐alkyl substituted benzofuran‐3(2H)‐ones with nitroolefins via bifunctional tertiary‐amine squaramide catalysis is developed.
ChemInform Abstract: Oxidant‐Controlled Catalytic Transformations of Phenols with Unexpected Cleavage of Aromatic Rings.
Authors: Li Wei , Song Feijie , You Jingsong 
Published: February 2016

AbstractA novel copper‐catalyzed oxidative coupling of electron rich phenols that involves the cleavage of a benzene ring is described to yield 3‐furanyl substituted benzofurans (III) and (V).
ChemInform Abstract: 2‐(Alkylamino)‐3‐aryl‐6,7‐dihydrobenzofuran‐4(5H)‐ones: Improved Synthesis and Their Photophysical Properties.
Authors: Kumar Manoj , Kumawat Lokesh Kumar , Gupta Vinod Kumar , Sharma Anuj 
Published: February 2016

AbstractA solvent‐ and catalyst‐free reaction between dimedone, aryl aldehydes, and an isocyanide under microwave irradiation is presented.
ChemInform Abstract: The Ugi Reaction of Cyanoacetic Acid as a Route to Tetramic Acid Derivatives.
Authors: Alvarez‐Rodriguez Nancy V. , Dos Santos Aurelie , El Kaim Laurent , Gamez‐Montano Rocio 
Published: February 2016

AbstractThe Ugi one‐pot reaction of cyanoacetic acid (I), aromatic aldehydes [e.g. (III)], amines [e.g. (II)], and isocyanides [e.g. (IV)] produces aminopyrrolinone derivatives [e.g. (V)].
ChemInform Abstract: Synthesis of 1‐Hydroxy‐1,5‐dihydro‐2H‐pyrrol‐2‐ones or 1‐Hydroxy‐1,6‐dihydropyridine‐2,5‐diones from N‐Hydroxy‐N‐(2‐oxoalkyl)amides.
Authors: Kulakov Ivan V. , Nikolaenkova Elena B. , Gatilov Yuri V. , Tikhonov Alexsei Ya. , Fisyuk Alexander S. 
Published: February 2016

AbstractAmides (I) and (III) are converted into pyrrole or pyridine derivatives depending on the amount of base.
ChemInform Abstract: A Cascade Synthetic Route to New Bioactive Spiroindolinepyrido[1,2‐a]indolediones from Indirubin.
Authors: Sele Alexander M. , Bremner John B. , Willis Anthony C. , Haritakun Rachada , Griffith Renate , Keller Paul A. 
Published: February 2016

AbstractDerivative (Vb) shows promising activity against three different cancer cell lines.
ChemInform Abstract: Regioselective Friedel—Crafts Reactions of N‐Substituted Glyoxylamide with Indoles Catalyzed by Broensted Acid.
Authors: Zhan Zhen , Li Renjun , Zheng Yang , Zhou Yan , Hai Li , Wu Yong 
Published: February 2016

AbstractThe title reaction gives substituted indoles [e.g. (III)] when AcOH is used as reagent, while bisindoles are obtained when 2 M HCl is used as catalyst.
ChemInform Abstract: One‐Pot Palladium‐Catalyzed Synthesis of Benzo[b]carbazolediones.
Authors: Do Hoang Huy , Tran Hung Quang , Ohlendorf Lars , Ngo Thang Ngoc , Dang Tuan Thanh , Ehlers Peter , Villinger Alexander , Langer Peter 
Published: February 2016

AbstractThe two‐step three component reaction is based on the aryl or alkylamination of 2,3‐dibromonaphthoquinone followed by Suzuki‐coupling with (2‐bromophenyl)boronic acid.
ChemInform Abstract: Efficient Synthesis of Conformationally Restricted Apoptosis Inhibitors Bearing a Triazole Moiety.
Authors: Corredor Miriam , Garrido Maria , Bujons Jordi , Orzaez Mar , Perez‐Paya Enrique , Alfonso Ignacio , Messeguer Angel 
Published: February 2016

AbstractUsing an Ugi four‐component reaction and subsequent treatment of the crude products with base allows the synthesis of β‐lactams (V) and/or pyridazinediones.
ChemInform Abstract: Synthesis and Anticancer Activity of 1,3,4‐Thiadiazole and 1,3‐Thiazole Derivatives Having 1,3,4‐Oxadiazole Moiety.
Authors: Dawood Kamal M. , Gomha Sobhi M. 
Published: February 2016

AbstractThiourea (I) is used as starting material in the synthesis of some 1,3,4‐thiadiazole and 1,3‐thiazole derivatives.
ChemInform Abstract: Pyridine—Hydrazones as N,N′‐Ligands in Asymmetric Catalysis: Pd(II)‐Catalyzed Addition of Boronic Acids to Cyclic Sulfonylketimines.
Authors: Alvarez‐Casao Yolanda , Monge David , Alvarez Eleuterio , Fernandez Rosario , Lassaletta Jose M. 
Published: February 2016

AbstractThe title reaction delivers the products in high yields and with very high enantiomeric excess, and is applicable to the corresponding addition to 1,2,5‐thiadiazole‐1,1‐dioxides.
ChemInform Abstract: Silver Tetrafluoroborate‐Catalyzed Oxa‐Diels—Alder Reaction Between Electrically Neutral Dienes and Aldehydes.
Authors: Zou Xiaodong , Yang Lizheng , Liu Xiangli , Sun Hao , Lu Hongjian 
Published: February 2016

AbstractChemoselective oxa‐Diels—Alder reactions between 1,3‐dienes and various aldehydes are achieved using the commercially available AgBF4 as catalyst.
ChemInform Abstract: Gold(I)/(III)‐Catalyzed Synthesis of 2‐Substituted Piperidines; Valency‐Controlled Cyclization Modes.
Authors: Morita Nobuyoshi , Tsunokake Tomonori , Narikiyo Yuji , Harada Mayuka , Tachibana Tatsuyuki , Saito Yuta , Ban Shintaro , Hashimoto Yoshimitsu , Okamoto Iwao , Tamura Osamu 
Published: February 2016

AbstractDepending on the catalyst propargylic alcohols (I) undergo either Meyer—Schuster rearrangement followed by aza‐Michael addition to give piperidines (II) or undergo direct cyclization to form alkynylated piperidines (III).
ChemInform Abstract: Palladium Catalyzed ortho‐C—H‐Benzoxylation of 2‐Arylpyridines Using Iodobenzene Dibenzoates.
Authors: Zhang Qian , Wang Ying , Yang Tingting , Li Li , Li Dong 
Published: February 2016

AbstractA highly regioselective ortho C‐H benzoxylation of 2‐arylpyridines is developed using hypervalent iodobenzene compounds (II) and (VII) as both the oxidants and reactants.
ChemInform Abstract: Synthesis of Novel 4‐Acyl‐2‐amino‐6‐sulfanylpyridine‐3,5‐dicarbonitriles.
Authors: Grigor'ev Arthur A. , Karpov Sergey V. , Kayukov Yakov S. , Belikov Mikhail Yu. , Nasakin Oleg E. 
Published: February 2016

AbstractThe heterocyclization reaction of the potassium salt (I) with thiols in the presence of Na or NaH in DMSO gives highly functionalized pyridine derivatives (III).
ChemInform Abstract: Aminoketyl Radicals in Organic Synthesis: Stereoselective Cyclization of Five‐ and Six‐Membered Cyclic Imides to 2‐Azabicycles Using SmI2—H2O.
Authors: Shi Shicheng , Szostak Michal 
Published: February 2016

AbstractThe high‐yielding diastereoselective cyclization reactions tolerate a broad range of substituents containing various functional groups.
ChemInform Abstract: Potassium tert‐Butoxide‐Catalyzed Synthesis of Benzofuroazepines via Cyclization of (2‐Alkynylbenzyl)oxy Nitriles.
Authors: Gai Rafaela , Back Davi F. , Zeni Gilson 
Published: February 2016

AbstractThe anionic cyclization of title compounds (I) in the presence of tBuOK proceeds through a sequential intramolecular 5‐exo‐dig mode followed by a 7‐endo‐dig cyclization to give benzofuroazepines (II) via formation of two new C—C bonds.
ChemInform Abstract: Regioselective Oxidative C—H Phosphonation of Imidazo[1,2‐a]pyridines and Related Heteroarenes Mediated by Manganese(III) Acetate.
Authors: Yadav Mahipal , Dara Saidulu , Saikam Varma , Kumar Mukesh , Aithagani Sravan Kumar , Paul Satya , Vishwakarma Ram A. , Singh Parvinder Pal 
Published: February 2016

AbstractThe Mn(III)‐promoted oxidative phosphonation between imidazopyridine (I) and related derivatives is developed.
ChemInform Abstract: Asymmetric Michael Additions of a β‐Oxophosphonate to Nitroalkenes in the Presence of Chiral Diamine Complexes.
Authors: Reznikov Alexander N. , Sibiryakova Anastasiya E. , Rybakov Victor B. , Klimochkin Yuriy N. 
Published: February 2016

AbstractHighly enantioenriched α‐nitroalkyl substituted β‐oxo phosphonates are prepared by the asymmetric Michael addition of dimethyl (2‐oxo‐2‐phenylethyl)phosphonate to nitrostyrenes in the presence of the shown catalyst (NIC).
ChemInform Abstract: Two New Triterpenoid Saponins from Notoginseng Medicinal Fungal Substance.
Authors: Xu Wei , Ding Cai‐Feng , Wang Xin‐Wen , Liu Xiao‐Li , Qiu Zhi‐Dong 
Published: February 2016

AbstractIsolation and structure‐determination of ginsenoside Rh10 (I) and notoginsenoside ST‐6 (II) are presented.
ChemInform Abstract: A Rapid and Efficient One‐Pot Method for the Reduction of N‐Protected α‐Amino Acids to Chiral α‐Amino Aldehydes Using CDI/DIBAL‐H.
Authors: Ivkovic Jakov , Lembacher‐Fadum Christian , Breinbauer Rolf 
Published: February 2016

AbstractN‐Protected amino acids (I) and (III) are readily converted into the corresponding chiral aldehydes in a one‐pot reaction by activation with CDI followed by reduction with DIBAL‐H.
ChemInform Abstract: Chemoselective Hydration of Glycosyl Cyanides to C‐Glycosyl Formamides Using Ruthenium Complexes in Aqueous Media.
Authors: Misra Anup Kumar , Bokor Eva , Kun Sandor , Bolyog‐Nagy Evelin , Katho Agnes , Joo Ferenc , Somsak Laszlo 
Published: February 2016

AbstractA wide variety of glycosyl cyanides such as (I) are converted into the corresponding formamide derivatives in water or water/NMP mixtures as the solvent.
ChemInform Abstract: Recent Advances in the Development of Pharmacologically Active Compounds that Contain a Benzoxazole Scaffold
Authors: Singh Sarbjit , Veeraswamy Gajulapati , Bhattarai Deepak , Goo Ja‐Il , Lee Kyeong , Choi Yongseok 
Published: February 2016

AbstractReview: advancements in the development of these biologically active heterocyclic compounds since the year 2000; 181 refs.
ChemInform Abstract: Recent Advances in First‐Row‐Transition‐Metal‐Catalyzed Dehydrogenative Coupling of C(sp3)‐H Bonds
Authors: Miao Jinmin , Ge Haibo 
Published: February 2016

AbstractReview: [recent progress in two classes of first‐row transition‐metal‐catalyzed dehydrogenative reaction of C(sp3)—H bonds: (1) intramolecular cyclizations for C—C bond formation, and (2) directed site‐selective C—H functionalizations; 33 refs.
ChemInform Abstract: Corrin Syntheses. Part 4. Synthesis of Corrin Complexes via (A→B) Ring Closure. Coupling of Hemicorrinoid A/D und B/C Components to Corrin by Imidoester—Enamine Condensations
Authors: Bertele Erhard , Scheffold Rolf , Gschwend Heinz , Pesaro Mario , Fischli Albert , Roth Martin , Schossig Juergen , Eschenmoser Albert 
Published: February 2016

AbstractReview: [45 refs.
ChemInform Abstract: Corrin Syntheses. Part 6. Corrin Synthesis via (A→D) Ring Closure. The Construction of A/D‐Secocorrin Chromophore Systems by the “Sulfide Contraction” Method and the Photochemical A/B‐Secocorrin→Corrin Cycloisomerization
Authors: Eschenmoser Albert , et al.  
Published: February 2016

AbstractReview: [104 refs.
ChemInform Abstract: Chemical Constituents and Biological Activities of Plants from the Genus Rubus
Authors: Li Jie , Du Long‐Fei , He Ying , Yang Long , Li Yuan‐Yuan , Wang Yue‐Fei , Chai Xin , Zhu Yan , Gao Xiu‐Mei 
Published: February 2016

AbstractReview: 176 refs.
ChemInform Abstract: Transient Electrochemistry: Beyond Simply Temporal Resolution
Authors: Zhou X.‐S. , Mao B.‐W. , Amatore C. , Compton R. G. , Marignier J.‐L. , Mostafavi M. , Nierengarten J.‐F. , Maisonhaute E. 
Published: February 2016

AbstractReview: 93 refs.
Organization of projection neurons and local neurons of the primary auditory center in the fruit fly Drosophila melanogaster
Authors: Matsuo Eriko , Seki Haruyoshi , Asai Tomonori , Morimoto Takako , Miyakawa Hiroyoshi , Ito Kei , Kamikouchi Azusa 
Published: February 2016

ABSTRACTAcoustic communication between insects serves as an excellent model system for analyzing the neuronal mechanisms underlying auditory information processing. The detailed organization of auditory neural circuits in the brain has not yet been described. To understand the central auditory pathways, we used the brain of the fruit fly Drosophila melanogaster as a model and performed a large‐scale analysis of the interneurons associated with the primary auditory center. By screening expression driver strains and performing single‐cell labeling of these strains, we identified 44 types of interneurons innervating the primary auditory center. Five types were local interneurons whereas the other 39 types were projection interneurons connecting the primary auditory center with other brain regions. The projection neurons comprised three frequency‐selective pathways and two frequency‐embracive pathways. Mapping of their connection targets revealed that five neuropils in the brain—the wedge (WED), anterior ventrolateral protocerebrum, posterior ventrolateral protocerebrum (PVLP), saddle (SAD), and gnathal ganglia (GNG)—were intensively connected with the primary auditory center. In addition, several other neuropils, including visual and olfactory centers in the brain, were directly connected to the primary auditory center. The distribution patterns of the spines and boutons of the identified neurons suggest that auditory information is sent mainly from the primary auditory center to the PVLP, WED, SAD, GNG, and thoracico‐abdominal ganglia. Based on these findings, we established the first comprehensive map of secondary auditory interneurons, which indicates the downstream information flow to parallel ascending pathways, multimodal pathways, and descending pathways. J. Comp. Neurol. 524:1099–1164, 2016. © 2016 Wiley Periodicals, Inc.
Ambient Synthesis of One‐/Two‐Dimensional CuAgSe Ternary Nanotubes as Counter Electrodes of Quantum‐Dot‐Sensitized Solar Cells
Authors: Chen Xin Qi , Bai Yang , Li Zhen , Wang Lian Zhou , Dou Shi Xue 
Published: February 2016

AbstractInvited for this month's cover is the group of Prof. Zhen Li. The highlighted study results from a collaboration between the University of Wollongong, University of Queensland, Soochow University, and Central China Normal University. Ternary copper silver selenide nanotubes were prepared and explored as high‐performance counter electrodes in quantum‐dot‐sensitized solar cells. Read the full text of the article at 10.1002/cplu.201500466.
Evaluation of flow cytometric HIT assays in relation to an IgG‐Specific immunoassay and clinical outcome
Authors: Kerényi Adrienne , Beke Debreceni Ildikó , Oláh Zsolt , Ilonczai Péter , Bereczky Zsuzsanna , Nagy Béla , Muszbek László , Kappelmayer János 
Published: February 2016

BackgroundHeparin‐induced thrombocytopenia (HIT) is a severe side effect of heparin treatment caused by platelet activating IgG antibodies generated against the platelet factor 4 (PF4)–heparin complex. Thrombocytopenia and thrombosis are the leading clinical symptoms of HIT.MethodsThe clinical pretest probability of HIT was evaluated by the 4T score system. Laboratory testing of HIT was performed by immunological detection of antibodies against PF4–heparin complex (EIA) and two functional assays. Heparin‐dependent activation of donor platelets by patient plasma was detected by flow cytometry. Increased binding of Annexin‐V to platelets and elevated number of platelet‐derived microparticles (PMP) were the indicators of platelet activation.ResultsEIA for IgG isotype HIT antibodies was performed in 405 suspected HIT patients. Based on negative EIA results, HIT was excluded in 365 (90%) of cases. In 40 patients with positive EIA test result functional tests were performed. Platelet activating antibodies were detected in 17 cases by Annexin V binding. PMP count analysis provided nearly identical results. The probability of a positive flow cytometric assay result was higher in patients with elevated antibody titer. 71% of patients with positive EIA and functional assay had thrombosis.ConclusionsEIA is an important first line laboratory test in the diagnosis of HIT; however, HIT must be confirmed by a functional test. Annexin V binding and PMP assays using flow cytometry are functional HIT tests convenient in a clinical diagnostic laboratory. The positive results of functional assays may predict the onset of thrombosis. © 2016 International Clinical Cytometry Society
Synthesis and low temperature characterization of iso‐oleic ester derivatives
Authors: Ngo Helen , Latona Renee , Wagner Karen M. , Nuñez Alberto , Ashby Richard , Dunn Robert O. 
Published: February 2016

Three new iso‐oleic ester derivatives (i.e., isopropyl ester (IOA‐iPrE, 6), n‐butyl ester (IOA‐n‐BuE, 7), and 2‐ethylhexyl ester (IOA‐2‐EHE, 8)) were synthesized from iso‐oleic acid (IOA, 4) using a standard esterification method. These esterified alcohols were chosen because of their bulky and branched‐chain alkyl groups which can reduce melting point in comparison to a smaller alkyl group such as methyl ester. The differential scanning calorimetry (DSC), cloud point and pour point results showed that esters 6, 7, and 8 had much lower melting transition temperatures and cold flow properties than the methyl (IOA–FAME, 5) and parent 4. The oxidative and thermal stability by pressure (P‐DSC) and thermogravimetric analysis (TGA) results also showed a very similar trend where the bulkier and branched‐chain alkyl esters had better stability than the smaller headgroup esters.Practical applications: Since saturated fats have high melting points, they are solids which can be harmful to our health and can cause damage to machinery. There is an urgent need to develop methods to produce fats with low melting points to replace the unwanted fats. In this paper, a series of modified branched‐chain fatty acid ester derivatives (i.e., iso‐oleic acid esters) that are liquid at room temperature with enhanced fluidity were synthesized. These ester fats have been found to perform much better than the original fatty acids and saturated fats. These findings are important as these iso‐oleic ester fats can potentially replace solid materials which are often problematic at low temperatures.Iso‐oleic ester derivatives containing bulky and branched‐chain alkyl groups exhibit reduce melting point in comparison to a smaller alkyl group such as methyl ester.
Enantiodifferentiating Properties of the Alignment Media PELG and PBLG – A Comparison
Authors: Hansmann Stefanie , Larem (née Montag) Tobias , Thiele Christina M. 
Published: February 2016

AbstractHomopolypeptide‐based alignment media can induce different orientations of enantiomers as a result of their α‐helical structures. This property enables the discrimination of enantiomers through anisotropic NMR parameters such as residual dipolar couplings (RDCs). In this paper, the enantiodiscriminating properties of two alignment media derived from polyglutamic acid derivatives – poly‐γ‐benzyl‐L‐glutamate (PBLG) and poly‐γ‐ethyl‐L‐glutamate (PELG) – are compared and discussed. The two analytes, isopinocampheol and β‐pinene, are investigated, and the role of the lateral side chain of the homopolypeptide in the orientation process is examined.
Rhodium‐Catalysed Enantioselective C–H Functionalization in Asymmetric Synthesis
Authors: Motevalli Somayeh , Sokeirik Yasser , Ghanem Ashraf 
Published: February 2016

AbstractIn this review, recent advances in the utilization of two classes of rhodium catalysts – namely rhodium(I) and rhodium(III) – in complexation with chiral cyclopentadienyl and phosphorus ligands in inter‐ and intramolecular asymmetric C–H bond activation/functionalization of aromatic and vinylic compounds is discussed. Because Rh complexes have been shown to be excellent catalysts for enantioselective alkylation, olefination and allylation of π systems through directed C–H functionalization under very mild conditions, this method has been seen to have broad synthetic potential both in organic chemistry and in biological systems. Moreover, selective conversion of ubiquitous C–H bonds into functional groups without intermediate preactivation is useful for shortening reaction sequences, with high environmental and economic benefits.
An Electrochemical Sensing Strategy for Amantadine Detection Based on Competitive Host‐guest Interaction of Methylene Blue/β‐cyclodextrin/Poly(N‐acetylaniline) Modified Electrode
Authors: Hao Xia , Li Na , Xu Zhen , Li Nian Bing , Luo Hong Qun 
Published: February 2016

AbstractA novel electrochemical strategy for the detection of amantadine (AMD) has been developed based on the competitive host‐guest interaction of AMD and methylene blue (MB) with β‐cyclodextrin (β‐CD). Due to the host‐guest interaction, MB molecules can enter into the hydrophobic inner cavity of β‐CD, and the MB/β‐CD/poly(N‐acetylaniline)/glassy carbon electrode displays a remarkable reduction peak due to MB. In the presence of AMD, competitive association to β‐CD occurs and the MB molecules are displaced by AMD, resulting in a decrease of reduction peak current of MB. The difference value of the cathodic peak current showed a linear relationship with the AMD concentration.
Pressurized Operation of a Planar Solid Oxide Cell Stack
Authors: Jensen S. H. , Sun X. , Ebbesen S. D. , Chen M. 
Published: February 2016

AbstractSolid oxide cells (SOCs) can be operated either as fuel cells (SOFC) to convert fuels to electricity or as electrolyzers (SOEC) to convert electricity to fuels such as hydrogen or methane. Pressurized operation of SOCs provide several benefits on both cell and system level. If successfully matured, pressurized SOEC based electrolyzers can become more efficient both energy‐ and cost‐wise than PEM and Alkaline systems. Pressurization of SOFCs can significantly increase the cell power density and reduce the size of auxiliary components. In the present study, a SOC stack was successfully operated at pressures up to 25 bar. The pressure dependency of the measured current‐voltage (I–V) curves and impedance spectra on the SOC stack are analyzed and the relation between various system parameters and pressure is derived. With increasing pressure the open circuit voltage (OCV) and the reaction kinetics (electrode performance) increases for thermodynamic and kinetic reasons, respectively. Further, the summit frequency of the gas concentration impedance arc and the pressure difference across the stack and heat exchangers is seen to decrease with increasing pressure following a power‐law expression. Finally a durability test was conducted at 10 bar.
Prediction of Climate Change Impact on Corn Grown in the South of Morocco Using the Saltmed Model
Authors: Hirich Abdelaziz , Fatnassi Hicham , Ragab Ragab , Choukr‐Allah Redouane 
Published: February 2016

AbstractClimate change is currently considered a major concern for humanity. Future climate projections carried out for the Souss region in the south of Morocco show that temperature will increase by 3 °C and precipitation will dramatically decrease by 63% towards the end of the twenty‐first century. This will have negative impacts on water resource availability in the Souss region which is already suffering from water scarcity. In this study, 'baseline data' based on field experiments, as well as climate change scenarios, were implemented in the SALTMED model to simulate climate change impact. After successful calibration and validation of the SALTMED model for three growing seasons with supplied ‘baseline data’ for Sweet corn, the SALTMED model was run in forecasting mode to obtain future projections of crop evapotranspiration and crop productivity under a changing climate. The obtained results suggested that with increasing temperature, crop evapotranspiration is expected to increase by 15% while crop water requirements are expected to decrease by 13% as a result of the shortening growth season of corn, expected to be 20 days earlier. Crop productivity could exhibit a reduction of 2.5% towards the end of the twenty‐first century. Copyright © 2016 John Wiley & Sons, Ltd.