bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Molten Lithium Sulfate ‐ Sodium Sulfate ‐ Potassium Sulfate Eutectic: Lux ‐ Flood Acid ‐ Base Reactions of Transition‐Metal Sulfates and Oxides.
Authors: DEARNALEY R. I. , KERRIDGE D. H. , ROGERS D. J. 
Published: May 2016

AbstractThe solubility and reactivity of seven transition‐metal sulfates (Cr(III), Mn(II), Fe(II), Fe(III), Co(II), Ni(II), Cu(II)) in the ternary eutectic (78 mol‐% Li2SO4, 8.5 Na2SO4, 13.5 K2SO4) and in the ternary eutectic containing NazCOa have been studied and the transition‐metal oxide products identified.
ChemInform Abstract: Temperature‐Programmed Reduction of CoO ‐ MoO3/Al2O3 Catalysts.
Authors: ARNOLDY P. , FRANKEN M. C. , SCHEFFER B. , MOULIJN J. A. 
Published: May 2016

AbstractTPR of C00 ‐ MoO3/Al2O3 catalysts has been measured as a function of Co content and calcination temperature.
ChemInform Abstract: Osmiumbromides.
Authors: THIELE G. , WOCHNER H. , WAGNER H. 
Published: May 2016

AbstractReaction of OsCl4 with Br2 in a closed System at 330°C and 120 bar Br2 pressure yields OsBr4, which crystallizes in the orthorhombic system (Pbca, Z=8) in a TcCl4 type structure.
ChemInform Abstract: Ionic Multimers from Heterocyclic Compounds. Clusters of Polymers?
Authors: DOYLE R. J. JUN. , CAMPANA J. E. 
Published: May 2016

AbstractNO Consecutive cleavages of the backbone of ionic multimers of[(CH2NNO2)"H]+ and cyclic oligomers of CHZO are observed: it is concluded that these ionic multimcrs are Clusters and not linear polymers.
ChemInform Abstract: 17O NMR Spectroscopy of Polyoxometalates. Part 3. Mechanistic Polyoxoanion Chemistry: Intramolecular Rearrangements of the α‐Mo8O264‐, C6H5AsMo7O254‐, and (C6H5As)2Mo6O244‐ Anions.
Authors: KLEMPERER W. G. , SCHWARTZ C. , WRIGHT D. A. 
Published: May 2016

AbstractThe dynamic behavior of the title anions (I) as tetrabutylammonium salts in CH3CN has been studied by using variable‐temp.
ChemInform Abstract: Associations of Phenols and Alkyl Ketones: Relationship of Bandwidths and Overall Equilibrium Constants to the Structure of the Phenols.
Authors: MASSAT A. , COSSE‐BARBI A. , DOUCET J.‐P. 
Published: May 2016

AbstractThe overall equilibrium constants, as well as the associated OH bandwidths, for hydrogen bonding between the phenols (I) and acetone or others of 2l α,β‐substituted ketones (not shown) are factorized into a product of reduced constants which express the association capacity of each of the partners (proton donor and acceptor).
ChemInform Abstract: Electrochemical Oxidation of 2,6‐Di‐tert‐butyl‐4‐methylphenol in Basic Methanol.
Authors: OHMORI H. , UEDA C. , TOKUNO Y. , MAEDA H. , MASUI M. 
Published: May 2016

AbstractDie elektrochemische Oxidation des im Titel genannten Phenols (I) führt unter den angegebenen Bedingungen zu den in der Seitenkette oxidierten Produkten (II) bis (IV) sowie den Chinonen (V) und (VI).
ChemInform Abstract: Short Intramolecular Diels‐Alder Approach to Functionalized Spiro[4.5]decanes.
Authors: NYSTROEM J.‐E. + , MCCANNA T. D. , HELQUIST P. , IYER R. S. 
Published: May 2016

AbstractAus dem Chlorhydrin (Ia) erhält man in der angegebenen Weise nach verschiedenen Verfahren die Alkinol‐Derivate (II).
ChemInform Abstract: Cyanoketenes. Cycloadditions of Chlorocyanoketene to Alkynes. Generation of Vinylogous Cyanoketenes.
Authors: FISHBEIN P. L. , MOORE H. W. 
Published: May 2016

AbstractAus dem Keten (I) erhält man mit den Acetylenen (II) bzw. (IVa) die Cyclobutenone (III) bzw. (V), während mit dem Ethoxy‐acetylen (IVb) das Dihydrobenzol (VII) entsteht.
ChemInform Abstract: Palladium‐Catalyzed Polyhetero‐Claisen Rearrangement of 4‐Allylthiopyrimidin‐ 2(1H)‐ones and S‐Allylthib‐1,2,4‐triazin‐3(2H)‐ones.
Authors: MIZUTANI M. , SANEMITSU Y. , TAMARU Y. , YOSHIDA Z. 
Published: May 2016

AbstractThe 4‐allylthiopyrimidin‐ 2(1H)‐ones (III) and the triazin‐3(2H)‐one derivatives (V) are synthesized by reaction of (I) or (IV) with allyl bromide (II).
ChemInform Abstract: Oxidation of Diols with Oxoaminium Salts.
Authors: MIYAZAWA T. , ENDO T. 
Published: May 2016

AbstractDas aus (I) dargestellte Salz (II) oxidiert die Diole (III), (V) und (VIII) selektiv, wobei die Lactone (IV) und (VII), das Acetal (VI) und Acetoin (IX) erhalten werden.
ChemInform Abstract: Enantioselective Synthesis of α‐Functionally Substituted Cyclic Ketones via Chiral Organotin Enamines.
Authors: STETIN C. , DE JESO B. , POMMIER J.‐C. 
Published: May 2016

AbstractDie durch Reduktion der Aminosäuren (I) dargestellten chiralen Aminoalkohole (II) werden mit den Cyclischen Ketonen (III) zu den Iminoalkoholen (IV) umgesetzt, aus denen wie angegeben die chiralen Organo‐Zinnverbindungen (V) erhalten werden.
ChemInform Abstract: Long‐Range Corner Participation by Cyclopropane. Part 3. Synthesis and Study of 1‐Substituted Tetracyclononanes and Tetracyclodecanes.
Authors: CHENIER P. J. , CHRISTIE D. M. , GOETTL V. M. 
Published: May 2016

AbstractDie Herstellung der Tosylate (Vb).
ChemInform Abstract: Unsaturated and Halogenated γ‐Hydroxysulfones: Syntheses and Reactivities.
Authors: MESSINGER P. , VON VIETINGHOFF‐SCHEEL R. 
Published: May 2016

AbstractDie ungesättigten 3‐Oxosulfone (I) und die Z‐Bromß‐oxosulfone (III) werden mit Dimethylaminboran (DMAB) zu den Alkoholen (II) bzw. (IV) reduziert.
ChemInform Abstract: Synthesis of Aromatic Acylisocyanates by Thermolysis of 1,1‐Diacyl‐3,3‐dialkylureas.
Authors: SCHROTH W. , KRIEG R. , KLUGE H. , GAEBLER M. + 
Published: May 2016

AbstractThe N,N‐dialkylureas (I) react with aromatic acid chlorides to the urea derivatives (II), which undergo thermolysis to (III) and (IV).
ChemInform Abstract: 2‐Sulfinyl‐pentane‐1,5‐diones from β‐Oxosulfoxides.
Authors: MESSINGER P. , KUNICK C. 
Published: May 2016

AbstractDie 3‐Oxosulfcxide (1) reagieren mit den Mannich‐Basen (II) oder den Chalkonen (IV) zu den Sul?nylpen‐ Iandionen (III) bzw. (V).
ChemInform Abstract: Electrochemical Reductive Acylation of 2,3‐Disubstituted l‐Indenones.
Authors: TAKANO N. , TAKENO N. , MORITA M. , OTSUJI Y. 
Published: May 2016

AbstractThe electrochemical reductive acetylation of the Zß‐disubstituted indenones (I) in DMF or in other aprotic solvents affords mixtures of the isomeric O‐acetyl products (II) and (III) in good yields.
ChemInform Abstract: Oxonium Ion Electrophiles: Synthesis of the Hypotensive Oudenone.
Authors: BATES H. A. , FARINA J. 
Published: May 2016

AbstractDie Synthesc von Oudenon (VIII) gelingt, wie im Formelschema gezeigt, über ein aus (IV) entstehendes Oxonium‐Ion als Zwischenstufe.
ChemInform Abstract: A Novel Access to Indoles by Ylide‐Amide Condensation.
Authors: LE CORRE M. , HERCOUET A. , LE STANC Y. , LE BARON H. 
Published: May 2016

AbstractEine Reihe von Phosphoniumsalzen des Typs (IV) wird, wie an einigen Beispielen aufgeführt, synthetisiert und zu Indolen vom Typ (X) cyclisiert (Diskussion des Reaktionsmechanis‐ mus).
ChemInform Abstract: Studies on 2,5‐Diaryl‐2,4‐dihydro‐3H‐pyrazol‐3‐ones. Part 2. Synthesis of 4‐Cycloalkyl‐2,5‐diaryl‐2,4‐dihydro‐3H‐pyrazol‐3‐ones Using the Tautomeric Properties of 2,5‐Diaryl‐2,4‐dihydro‐3H‐pyrazol‐S‐ones.
Authors: MATSUGO S. , SAITO M. , TAKAMIZAWA A. 
Published: May 2016

AbstractWährend die Pyrazolone (I) mit Cyclopentanon (IIa) in Abwesenheit einer Base zu den Cyclopentyliden‐Derivaten (III) reagieren, entstehen in Anwesenheit von Triethylamin durch Umsetzung von (I) mit den Cycloalkanonen (II) anstelle der erwarteten Cycloalkylidenverbindungen deren Reduktionsprodukte (IV)‐(VI).
ChemInform Abstract: Heterocyclic Ring‐Closure Reactions. Part 8. Reactions of Isothiocyanates with Cyanothioformamides.
Authors: KHATTAK I. , KETCHAM R. , SCHAUMANN E. , ADIWIDJAJA G. 
Published: May 2016

AbstractCyclization of 5‐Imino‐4‐thioxo‐2‐imidazolidones and S‐Imino‐2,4‐imidazolidinedithiones t0 5,7‐Dihydr0diimidazo[4,5‐b:4′,5′‐e]pyrazine‐ 2,6(lH,3I‐I)‐diones and ‐dithiones.
ChemInform Abstract: Synthesis and Desulphurisation of Substituted 12H‐[l]‐Benzopyrano[3,4‐b][1,4]‐benzothiazin‐6‐ones.
Authors: REDDY B. S. , DARBARWAR M. 
Published: May 2016

AbstractDie Hydroxycumarine (I) reagieren mit dem Aminothiophenol (II) zu den Benzopyranobenzothiazinonen (III), die sich mit Raney‐Nickel zu Anilin‐cumarinen (IV) entschwefeln lassen.
ChemInform Abstract: Methanolic Sodium Acetate Catalysed Rearrangement of 4‐Acylisocoumarins into 3‐Alkylisocoumarins.
Authors: BHAKTA C. 
Published: May 2016

AbstractDas aus der Isocumarincarbonsäure (I) darstellbare Acetylisocumarin (II) läßt sich zum Bromacetylisocumarin (III) bromieren, das mit Naacetat in Essigsäure das Acetoxyacetylcumarin (IV) zugänglich macht; die Hydrolyse von (IV) führt zum Bis‐isocumarmyldloxin (V).
ChemInform Abstract: Reactions of α‐Lithiated 4H‐1‐Benzothiopyran‐4‐one and 1,2‐Dihydrocyclopenta[b][1]benzothiopyran‐9(3H)‐one Derivatives.
Authors: HIRAO I. , YAMAGUCHI M. , TERADA T. , HASEBE K. 
Published: May 2016

AbstractNew derivatives containing the benzothiopyranone structure are synthesized in order to examine the analgesic and anti‐inflammatory activities of these compounds.
ChemInform Abstract: Reactions of β‐Keto Esters with 2‐Cyano‐l,2,5,6‐tetrahydropyridines.
Authors: CHAPMAN R. F. , PHILLIPS N. I. J. , WARD R. S. 
Published: May 2016

AbstractAvariety of methods leading to the β‐keto esters (IV) were investigated.
ChemInform Abstract: Stereochemical Studies. Part 87. Saturated Heterocycles. Part 82.
Authors: FUELOEP F. + , STAJER G. , BERNATH G. , SOHAR P. 
Published: May 2016

AbstractThe diendo‐ and diexo‐bicycloheptanes (III) are synthesized from the β‐amino acid esters (I) in two steps.
ChemInform Abstract: Diastereofacial Selectivity in the Reaction of Allylic Organometallic Compounds with Imines.
Authors: YAMAMOTO Y. , KOMATSU T. , MARUYAMA K. 
Published: May 2016

AbstractAus den Iminen (I) erhält man mit den Allyl‐Metallverbindungen (II) Gemische isomerer Addukte (III) und (IV), deren Anteile in Relation zu Substituenten und Bedingungen bestimmt werden.
ChemInform Abstract: Asymmetric Nucleophilic Acylation via Metalated α‐Amino Nitriles Possessing an Axially Disymmetric Tertiary Amino Group.
Authors: MAIGROT N. , MAZALEYRAT J.‐P. , WELVART Z. 
Published: May 2016

AbstractZunächst werden aus dem racemisehen Binaphthyl (I) durch Umsetzung mit dem optisch aktiven Amid (II) über die Verbindungen (IIIa) und (IVa) die diastereomeren α‐Aminonitrile (IIIb) und (IVb) dargestellt.
ChemInform Abstract: Synthesis of α‐Carbalkoxy Enethiols: A Class of Tautomeric Thiopyruvate Derivatives.
Authors: BUTERA J. , RINI J. , HELQUIST P. 
Published: May 2016

AbstractDas 1.3‐Oxathiolanon (I) addiert über das entsprechende Carbanion Oxoverbindungen (II) zu den Alkoholen (III), deren Mesylate mit DBU zu Methylenverbindungen (IV) gespalten werden.
ChemInform Abstract: Synthesis and Crystal Structure of an Enantiomerically Pure, Internally Coordinated Alkylchloroborane.
Authors: SHINER C. S. , GARNER C. M. , HALTIWANGER R. C. 
Published: May 2016

AbstractThe homoallylic alcohol, (‐)‐Nopol (I), is converted to the methyl ether derivative (II) under phase‐transfer conditions.
ChemInform Abstract: The Effect of Added Silver Nitrate on the Palladium‐Catalyzed Arylation of Allyltrimethylsilanes.
Authors: KARABELAS K. , WESTERLUND C. , HALLBERG A. 
Published: May 2016

AbstractDie Palladium‐katalysierte Umsetzung von Iodbenzol (I) mit dem Silan (II) führt unter den angegebenen Bedingungen zu dem arylierten Siian (III) als Hauptprodukt; Nebenprodukte sind die desilylierten Propene (IV) und (V).
ChemInform Abstract: Organometallic Compounds of Group III. Part 41. Direct Observation of the Initial Insertion of an Unsaturated Hydrocarbon into the Titanium
Authors: EISCH J. J. , PIOTROWSKI A. M. , BROWNSTEIN S. K. , GABE E. J. , LEE F. L. 
Published: May 2016

AbstractCarbon Bond of the Soluble Ziegler Polymerization Catalyst, CpzTiC11‐ MeAlClz.
ChemInform Abstract: Stereochemistry at Iron During Carbonyl "Insertion" Reactions of FeMeI(CO)2(PMe3)2.
Authors: WRIGHT S. C. , BAIRD M. C. 
Published: May 2016

AbstractDie Reaktion des aus Tricarbonyl‐bis‐[trimethylphos‐ phin]‐Fe(0) und MeI synthetisierten Fe(II)‐Komplexes (I) mit CO ergibt den cis‐ Iodoacetyl‐Komplex (II), der sich bei Raumtemp, in das trans‐Isomere (III) umlagert.
ChemInform Abstract: Synthesis and Characterization of Dirhodium Complexes with Four N,N′‐Diphenylbenzamidine Bridging Ligands. Electrochemical Generation and ESR Properties of [Rh2(N2R2CR)4]n Where R: Phenyl and n: 1 and ‐1.
Authors: LE J. C. , CHAVAN M. Y. , CHAU L. K. , BEAR J. L. , KADISH K. M. 
Published: May 2016

AbstractDer aus Tetrakis‐[acetato]‐dirhodium(II,II) mit dem Titelliganden synthetisierte Ligand‐verbrückte Rh(II),Rh(II)‐Komplex (Ia) wird elektrochemisch durch reversible Einelektronentransfer‐Prozesse oxidiert und reduziert.
ChemInform Abstract: Pyrimidyl and Imidazolyl Coumarin Disperse Dyes.
Authors: PADMANABHAN S. , SESHADRI S. 
Published: May 2016

AbstractDas in der angegebenen Weise aus (I) und (II) erhältliche Amidin (III) reagiert mit den Dialdehyden (IV) bzw. mit Benzoin (VII) zu den 3‐I‐Ietary1eumarinen (V) bzw. (VIII).
ChemInform Abstract: Preparation and Acid‐Catalyzed Rearrangement of a C‐17 Isopropylidene and a C‐17 Isopropenyl Sterol.
Authors: LOUGHHEAD D. G. 
Published: May 2016

AbstractWie im Formelschema gezeigt, wird aus (I) das im Titel genannte Isopropylidensterol (VIIIb) dargestellt.
ChemInform Abstract: Synthetic Microbial Chemistry. Part 8. Chiral Synthesis of (R)‐(‐)‐Mellein and (3R,4aS)‐(+)‐Ramulosin.
Authors: MORI K. , GUPTA A. K. 
Published: May 2016

Abstract(‐)‐Mellein (VII), a metabolite of Aspergillus melleus, and (+)‐ramulosin (IX), a metabolite of Pestalotia ramulosa, are synthesized from the hydroxybutanoate (Ia) with Overall yields of 7.3 and 8.2%.
ChemInform Abstract: Directed Openings of 2,3‐Epoxy Alcohols via Reactions with Isocyanates: Synthesis of (+)‐erythro‐Dihydrosphingosine.
Authors: ROUSH W. R. , ADAM M. A. 
Published: May 2016

AbstractDie Epoxyalkohole (I) werden nach Umsetzung zu den Urethanen (II) zu den isomeren Oxazol‐Derivaten (III) und (IV) cyclisiert.
ChemInform Abstract: Total Synthesis of Antitumor Agent At‐125, (αS,5S)‐α‐Amino‐3‐chloro‐4,5‐dihydro‐ S‐isoxazoleacetic Acid.
Authors: BALDWIN J. E. , CHA J. K. , KRUSE L. I. 
Published: May 2016

AbstractDie aus dem bekannten Lacton (Ia) erhältichen Derivate (Ib)‐(Id) werden über die entsprechenden Stufen (II) in die offenkettigen Verbindungen (IV) übergeführt.
ChemInform Abstract: Reaction Sintering of Yttrium Containing α‐Silicon Nitride Solid Solution.
Authors: NAGEL A. , GREIL P. , PETZOW G. 
Published: May 2016

AbstractThe sintering behaviour of (1‐Si3N4 solid solution (a‐ss) ceramics with Y2O3 and AIN has been studied by dynamic high temp. dilatometry and X‐ray analysis.
ChemInform Abstract: The Crystal Structure of Sodium Orthogermanate, Na4GeO4.
Authors: HALWAX E. , VOELLENKLE H. + 
Published: May 2016

AbstractThe structure of Na4GeO4, which has been prepared by reaction of Na2GeO3 and NaOH (1:2, ThO2‐Tiegel, 450‐1100 °C), is determined from single crystal X‐ray diffraction data.
ChemInform Abstract: Nitric Oxide Reduction at Noble Metal Electrodes: A Voltammetric Study in Acid Solution.
Authors: COLUCCI J. A. , FORAL M. J. , LANGER S. H. 
Published: May 2016

AbstractThe electroreduction of NO in aqueous HClO4 (O.33‐ 1.0 M) is studied with several types of noble metal electrodes (Pt, Pd, Rh, and Ru).
ChemInform Abstract: Influence of Minor Alloying Elements on the Passivation Behaviour of Iron‐Chromium Alloys in HCl.
Authors: GOETZ R. , LAURENT J. , LANDOLT D. 
Published: May 2016

AbstractAdded at equal atomic concentration (6 at.%) to ferritic Fe‐ 13 Cr alloys, M0, W, Vand Si increase the pitting potential in 1 M HCl in the order Mo V Si W. Addition of the same elements to an Fe‐24 Cr alloy suppresses pitting entirely.
ChemInform Abstract: Oxide Catalysts. Part 43. Thermoanalytic and Catalytic Investigations of Platinum‐ Containing Zeolites H‐ZSM‐5.
Authors: BREMER H. , RESCHETILOWSKI W. , WENDLANDT K.‐P. , KANAZIREV V. , MINCHEV KH. , PENCHEV V. 
Published: May 2016

AbstractZeolites Pt/H‐ZSM‐5 prepared by impregnation with H2PtCl6 from ethanolic solution show a higher metal dispersion after reduction than those obtained by impregnation from aqueous solution.
ChemInform Abstract: Formation of Silylgermane by a Silylene Insertion Reaction in the IR Photochemistry of Monosilane‐Monogermane Mixtures.
Authors: ZHU P. , PISERCHIO M. , LAMPE F. W. 
Published: May 2016

AbstractThe photodecomposition of SiH4‐ GeH4 mixtures by irradiation with an IR beam of 944.2 cm‐1 from a CO2 TEA laser has been studied (24‐46 Torr, 295‐356 K).
ChemInform Abstract: Three Oxidation Paths of (Ta6Cl12)2+ (I) (Ta6Br12)2+ (II) and Nb6Cl122+ (III) ).
Authors: EISENBRAUN R. , SCHAEFER H. + 
Published: May 2016

AbstractThe title ion (I) is oxidized autocatalytically to give (Ta6Cl12)4+ by HNO3.
ChemInform Abstract: Theoretical Study of the Tautomeric Equilibrium of 4(1H)‐Pyridinone in Solution.
Authors: SORDO J. A. , KLOBUKOWSKI M. , FRAGA S. 
Published: May 2016

AbstractThe solvation of the tautomeric forms 4(1H)‐pyridinone/4‐hydroxy‐pyridine was studied using a semiempirical potential, obtained from accurate ab initio calculations, including 92 water molecules.
ChemInform Abstract: Enantioselective Synthesis of the Depsipeptide Unsaturated Acid Portion of Madumycin II.
Authors: MEYERS A. I. , SPOHN R. F. , LINDERMAN R. J. 
Published: May 2016

AbstractDer ungesättigte Depsipeptidester (X) wird als Baustein beim Aufbau des Madumycins II in der skizzierten enantioselektiven Synthesereihe hergestellt.
ChemInform Abstract: Homolytic Addition of 2‐Ethoxy‐1,3‐dioxolane to Decene‐1.
Authors: KHATUNTSEV I. I. , PASTUSHENKO E. V. , KRUGLOV D. E. , TERENT'EV A. B. 
Published: May 2016

AbstractDer cyclische Orthoester (I) reagiert mit l‐Decen (II) unter radikalischen Bedingungen zu den 2‐ bzw. 4‐Decylverbindungen (III) und (IV), daneben entsteht Dodecylethylcarbonat (V).
ChemInform Abstract: 1‐Phenylsulfonyl‐3,3,3‐trifluoropropene. Part 1. The Michael‐Type Addition Reaction.
Authors: TAGUCHI T. , TOMIZAWA G. , NAKAJIMA M. , KOBAYASHI Y. 
Published: May 2016

AbstractDas im Titel genannte Sulfonylpropen (III) wird wie skizziert hergestellt.
ChemInform Abstract: Stereospecificity of 1,3‐Dipolar Cycloadditions of p‐Nitrobenzonitrile Oxide to cis‐ and trans‐Dideuterioethylene.
Authors: HOUK K. N. , FIRESTONE R. A. , MUNCHAUSEN L. L. , MUELLER P. H. , ARISON B. H. , GARCIA L. A. 
Published: May 2016

AbstractDie 1H‐NMR‐Analyse der Cycloaddition des cis‐ Ethylens (I) an das Nitriloxid (II) ergibt weniger als l‐2% des trans‐Isomers von (III).
ChemInform Abstract: New Synthesis of Heterocycles by Use of Palladium Catalyzed Cyclization of α‐Haloamide with Internal Double Bond.
Authors: MORI M. , KANDA N. , ODA I. , BAN Y. 
Published: May 2016

Abstractα‐Iodoamides (I) with internal double bonds are prepared by methods similar to that shown for‐(Ic) in the scheme.
ChemInform Abstract: The Invention of New Radical Chain Reactions. Part 10. High Yield Radical Addition Reactions of αβ‐Unsaturated Nitroolefins.
Authors: BARTON D. H. R. , TOGO H. , ZARD S. Z. 
Published: May 2016

AbstractThe carboxylic acids (I) are transformed to the thiohydroxamic esters (II), which, upon irradiation, readily react with the nitroalkenes (III) to yield the α‐nitrosulfides (IV).
ChemInform Abstract: Site Selectivity in the Gas‐Phase Ionic Phenylation of Alcohols and Alkyl Chlorides.
Authors: KEHEYAN Y. , SPERANZA M. 
Published: May 2016

AbstractPhenylcations (I), generated from [1,4‐3H2]benzene by spontaneous β‐decay, react in the presence of a radical scavenger with (II), (VIII), and (XII).
ChemInform Abstract: Reaction of Bis(triphenylgermyl)cadmium and ‐mercury with Tetraphenylstibonium Chloride.
Authors: BYCHKOV V. T. , SHARUTIN V. V. , BOLOTOVA O. P. , ERMOSHKIN A. E. , KONKINA T. N. 
Published: May 2016

AbstractTetraphenylstiboniumchlorid (I) reagiert mit Bis‐(triphenylgermyl)‐ cadmium oder ‐quecksilber (II) zu Triphenylgermyl‐tetraphenylantimon (III).
ChemInform Abstract: [3.3]Metacyclophane: A Novel Synthesis and a Study of the Structure Through X‐Ray Diffraction, Molecular Mechanics, and Solution NMR Analysis.
Authors: SEMMELHACK M. F. , HARRISON J. J. , YOUNG D. C. , GUTIERREZ A. , RAFII S. , CLARDY J. 
Published: May 2016

AbstractIn the crystal (space group P2,; Z=2) of [3.3]metacyclophane (V), the molecule assumes a syn geometry with the bridging chains in the chair‐chair conformation as shown.
ChemInform Abstract: Sulfur Compounds of Petroleum. Part 9. Cyclopentathiophenes from 3,5‐Di(β‐naphthyl)‐2,4‐thiophenedicarboxylic Acid Derivatives.
Authors: BOBERG F. , SCHMIDT W. , GARMING A. 
Published: May 2016

AbstractDer Bis‐naphthylthiophendicarbonsäurehalbester (I) cyclisiert nach Umsetzung mit SOCl2 unter AlCl3‐ Katalyse zum Benzindenothiophencarbonsäureester (II), aus dem Diester (IIIa) bzw. der Dicarbonsäure (IIIb) ist in Polyphosphorsäure das Isomer (IV) zugänglich.
ChemInform Abstract: Synthesis of Some Pyrazolinothiazolidino‐2‐ones. Part 1.
Authors: MEHROTRA V. N. , ACHARI R. S. 
Published: May 2016

AbstractDurch cyclisierende Kondensation erhält man aus den substituierten Thiazolidinonen (I) und den Phenylhydrazinen (II) die im Titel genannten Verbindungen (III).
ChemInform Abstract: Synthesis of Some Thiazole Substituted Phenylimino‐4‐thiazolidinones.
Authors: RINDHE S. S. , MANE R. A. , INGLE D. B. 
Published: May 2016

AbstractDie Thioharnstoffe (I) cyclisieren mit Chloressigsäure zu den im Titel genannten Verbindungen (II).
ChemInform Abstract: Studies on 2(1H)‐Quinolinone Derivatives as Gastric Antiulcer Active Agents.
Authors: UCHIDA M. , TABUSA F. , KOMATSU M. , MORITA S. , KANBE T. , NAKAGAWA K. 
Published: May 2016

AbstractDie Hydroxyalkyl‐substituierten Chinolinone (Ia), deren Synthese nach verschiedenen Methoden erfolgt, werden nach Bromierung zu (Ib) in die Malonsäureester‐Derivate (II) übergeführt.
ChemInform Abstract: Catalysis of Hydrosilylation. Part 8. Addition of Tri(chloro, methyl)silanes to Vinyltri(chloro, methyl)silanes Catalyzed by Palladium Phosphine Complexes.
Authors: MARCINIEC B. , MACKOWSKA E. , GULINSKI J. , URBANIAK W. 
Published: May 2016

AbstractThe hydrosilylation of the vinylsilanes (I) by the silane (II) catalyzed by palladium phosphine complexes proceeds according to the scheme shown.
ChemInform Abstract: Synthesis and Reactions of 10‐Amino‐10‐methyl‐9‐oxa‐10‐sila‐9,10‐dihydrophenanthrene.
Authors: MIKHAILOVA A. N. , KRASNOVA T. L. , KUZNETSOVA M. G. , KISIN A. V. , SHVETSOV A. YU. , MOLCHANOV B. V. , BOCHKAREV V. N. , CHERNYSHEV E. A. , ALEKSEEV N. V. 
Published: May 2016

AbstractBei der Ammonolyse des Chlorsilans (I) mit gasförmigem Ammoniak wird das Aminooxasiladihydrophenanthren (II) erhalten, aus dem bei thermischer 100 Behandlung die Verbindungen (III)‐(V) entstehen.
ChemInform Abstract: Hydrophosphorylation of Alkines with Phosphinous Acids.
Authors: NIFANT'EV E. E. , SOLOETSKAYA L. A. , MAGDEEVA R. K. 
Published: May 2016

AbstractDibutylphosphinigsäure (I) reagiert mit den Alkinen (II) in Gegenwart von Dibenzoylperoxid unter Addition an die Dreifachbindung zu Gemischen der cis‐/trans‐ungesättigten Phosphinoxide (III).
ChemInform Abstract: Reaction of Dichlorophosphines Containing Oxavinylic Groups with Alcohols.
Authors: FRIDLAND S. V. , LAPTEVA L. I. , CHERNOVA A. V. , EFREMOV A. I. 
Published: May 2016

AbstractDie Umsetzung der Dihydrofuryl‐ und Dihydropyranylphosphonigsäuredichloride (I) mit aliphatischen Alkoholen in Gegenwart von Basen liefert die Ester (II).
ChemInform Abstract: Cyclothiazeno Complexes of Molybdenum(V), Molybdenum(VI), and Tungsten(VI).
Authors: BERG A. , CONRADI E. , MUELLER U. + , DEHNICKE K. 
Published: May 2016

Abstract2 C?zClz. ‐ Die über einen S2N2‐Ring verknüpften Cyclothiazeno‐Komplexe (II) werden wie aufgezeichnet aus den Hexacarbonylen (I)‐und (NSCI); bzw. S4N4/Br2 synthetisiert.
ChemInform Abstract: Formation of Stable Tungsten Alkene Carbyne Complexes by Carbonyl Substitution Reactions.
Authors: MAYR A. , DORRIES A. M. , MCDERMOTT G. A. , GEIB S. J. , RHEINGOLD A. L. 
Published: May 2016

AbstractReaction of the bis(pyridine) carbyne Wcomplexes (I) with excess NEt4Cl affords the anionic carbyne complexes (II) which are only stable in the presence of excess Chloride.