bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Facile Preparation of Optically Active Bicyclo(3.3.1)nonane‐2,6‐diol and 3,3,7,7‐Tetramethylbicyclo(3.3.1)nonane‐2,6‐diol by Enzyme‐Catalyzed Hydrolysis, and Enantiomer Recognition Behavior of Crown Ethers and Podands Having These Diols as a Chiral Subunit.
Authors: NAEMURA K. , MATSUMURA T. , KOMATSU M. , HIROSE Y. , CHIKAMATSU H. 
Published: May 2016

AbstractThe bicyclononanediol (‐)‐(II) serves as chiral subunit in the synthesis of the crown ether (‐)‐(IV); the crown ether (+)‐(V) is similarly obtained using pig liver esterase as bio‐agent in the first step.
ChemInform Abstract: Synthesis and Structures of Isomeric Alkoxy(aroxy)phosphoryldicyanamides.
Authors: KOEHLER H. + , KRETSCHMANN M. , SKIRL R. , GLANZ D. , JAEGER L. + 
Published: May 2016

AbstractThe isomeric dicyanamides, the cyanocarbodiimides (III) and the dicyanamides (X), are prepared by the synthetic routes shown in the scheme.
ChemInform Abstract: Chemistry of Phosphorus. Part 197. Octa‐tert.‐butyldodecaphosphane(8), P12(tBu)8. Preparation and Structure Determination of Two Constitutional Isomers by Nuclear Magnetic Resonance.
Authors: BAUDLER M. , SCHNALKE M. , WIATEREK CH. , OPIELA S. , HAHN J. 
Published: May 2016

AbstractThe title compound is produced as a mixture of the two constitutional isomers (II) and (III) by thermolysis of (I).
ChemInform Abstract: Main Group Metal Halide Complexes with Sterically Hindered Thioureas. Part 11. Complexes of Antimony(III) and Bismuth(III) Chlorides with a New Bidentate Thiourea ‐ 1,1′‐Methylenebis(3‐methyl‐2H‐imidazole‐2‐thione).
Authors: WILLIAMS D. J. , VANDERVEER D. , JONES R. L. , MENALDINO D. S. 
Published: May 2016

AbstractThe new bidentate title ligand (IV) is obtained according to the scheme.
ChemInform Abstract: Existence of the Anion Trichloro(η‐cyclopentadienyl)titanate(1‐). Crystal Structure of the Salt (Co(C5H5)2)(Ti(C5H5)Cl3).
Authors: HUGHES D. L. , JIMENEZ‐TENORIO M. , LEIGH G. J. 
Published: May 2016

AbstractThe title salt (III) is characterized by elemental and X‐ray crystal structure analysis (space group P21/a, Z=4) as well as by NMR and ESR spectroscopy.
ChemInform Abstract: Selective Synthesis and Multinuclear Magnetic Resonance Study of 2‐Sila‐ and 2‐Stannaindolines. The Intriguing Behaviour of the N,C‐Dilithio Reagent Obtained from ortho‐(N‐Trimethylsilyl)toluidine.
Authors: WRACKMEYER B. , ZHOU H. 
Published: May 2016

AbstractLithiation of the N‐(trimethylsilyl)anilines (I) with one equivalent of BuLi (II) followed by transmetalation with chlorotrimethylstannane (III) produces the N‐trimethylsilyl‐N‐(trimethylstannyl)arylamines (IV).
ChemInform Abstract: Synthesis of Fluorinated Dienylic Stannanes via the Wadsworth‐Emmons Reaction.
Authors: BERGLUND R. A. , FUCHS P. L. 
Published: May 2016

AbstractThe title compounds (XV) and (XVI) are obtained as Z/E‐mixtures via a complex reaction sequence outlined in the reaction scheme starting with the acetonedicarboxylate (I).
ChemInform Abstract: (Cp*(Me)Cr(μ‐Me))2: An Electron‐Deficient Chromium(III) Alkyl with Bridging Methyl Groups and a Cr‐Cr Bond.
Authors: NOH S. K. , SENDLINGER S. C. , JANIAK C. , THEOPOLD K. H. 
Published: May 2016

AbstractThe air‐sensitive, paramagnetic title compound (VII) crystallizes in the space group P21/c with Z=4.
ChemInform Abstract: Organometallic Chemistry with P/N‐Chelating Ligands. Part 1. Molybdenum and Iron(0) Compounds of 2‐Diphenylphosphinomethylpyridine.
Authors: TOM DIECK H. , HAHN G. 
Published: May 2016

AbstractSubstitutions of norbornadiene or acetonitrile ligands by the title ligand lead to the chelate complexes (III)‐(V).
ChemInform Abstract: Synthesis of Transition‐Metal‐Substituted Diarsenes. X‐Ray Structure Analysis of (η5‐C5Me5)(CO)2FeAs(Cr(CO)5)=AsR (R = 2,4,6‐tBu3C6H2).
Authors: WEBER L. , BUNGARDT D. , MUELLER A. + , BOEGGE H. + 
Published: May 2016

AbstractThe reaction of (Ia) with the arsine (II) affords the twice metalated cyclotetraarsine (III).
ChemInform Abstract: A New Molecular Metal: (NHMe3)0.5(Ni(dmit)2) (dmit = 4,5‐Dimercapto‐1,3‐dithiolene‐2‐thione).
Authors: TEJEL C. , POMAREDE B. , LEGROS J.‐P. , VALADE L. , CASSOUX P. , ULMET J. P. 
Published: May 2016

AbstractTransition‐metal complexes of the title dithiolene ligand are used as precursors for the preparation of a number of conducting and superconducting π donor‐acceptor or fractional oxidation state compounds.
ChemInform Abstract: Direct Formation and Reaction of Functionalized Thienyl‐Based Organo‐Copper Reagents.
Authors: RIEKE R. D. , WU T.‐C. , STINN D. E. , WEHMEYER R. M. 
Published: May 2016

AbstractReduction of the thienylcyanocuprate (I) with lithium naphthalenide generates activated zero‐valent copper (II) which converts the halides (III) into the organo‐copper agents (IV).
ChemInform Abstract: Substituted Cyclopentadienyl Complexes. Part 4. The Catalyzed Synthesis and Proton NMR Spectra of (Ru(η5‐C5H4Me)(CO)(L)I) and (Ru(η5‐C9H7)(CO)(L)I) (L: phosphine or isocyanide) and the Crystal Structure Determination of (Ru(η5‐C9H7)(CO)(P(CH2Ph)3)I).
Authors: LOONAT M. S. , CARLTON L. , BOEYENS J. C. A. , COVILLE N. J. 
Published: May 2016

AbstractThe new substituted products (III) (8 examples) and corresponding indenyl compounds such as (IV) (6 examples) are prepared in an iron complex catalyzed reaction as demonstrated for the example given in the scheme.
ChemInform Abstract: Synthesis and Properties of the Orthometalated Rhodium Complex Rh(P(OPh)3)3(P(OC6H4)(OPh)2).
Authors: TRZECIAK A. M. , ZIOLKOWSKI J. J. 
Published: May 2016

AbstractOn the basis of UV/VIS and 31P NMR spectroscopic data the postulated structure of the orthometalated complex (III) is confirmed.
ChemInform Abstract: Reaction of Tryptophan Derivatives with Phenylsulfenyl Chloride and Phenylselenenyl Bromide.
Authors: CRICH D. , DAVIES J. W. 
Published: May 2016

AbstractThe tryptophan derivatives (I) react with the phenylchalcogenyl halides (II) under substitution, forming the 2‐phenylthio(or seleno)indoles (III).
ChemInform Abstract: Diels‐Alder Reactivity of Pyrano(3,4‐b)indol‐3‐ones. Part 4. Synthesis of the Carbazole Alkaloids Carbazomycin A and B and Hyellazole.
Authors: MOODY C. J. , SHAH P. 
Published: May 2016

AbstractThe carbazole alkaloids carbazomycin B (VIII) and A (IX), antibiotics from Streptovertcillium, and the carbazole alkaloid hyellazole (XII) are prepared using the regioselective Diels‐Alder reaction between a pyranoindole and the alkyne (II) as the key step.
ChemInform Abstract: Analogues of the Antiviral Acyclonucleoside 9‐(4‐Hydroxy‐3‐hydroxymethylbutyl)guanine. Part 4. Substitution on the 2‐Amino Group.
Authors: HARNDEN M. R. , JARVEST R. L. 
Published: May 2016

AbstractThe acyclonucleosides (IV) and (XII), analogues of known antiviral guanines, are prepared in order to study whether substitution of the 2‐amino group causes change in activity.
ChemInform Abstract: Nucleosides. Part 25. Synthesis of Alicyclic and Cyclic Nucleosides of 4(5H)‐Oxopyrazolo(3,4‐d)pyrimidine and 4‐Aminopyrazolo(3,4‐d)pyrimidine and Their Antileishmanial Activity.
Authors: KHAN S. I. , MISHRA A. , GURU P. Y. , PRATAP R. , BHAKUNI D. S. 
Published: May 2016

AbstractThe title compounds (V), (VIIb), (IX) and (XIII)‐(XVI), which represent nonclassical nucleosides of the xanthine oxidase inhibitor allopurinol (I) and 4‐aminopyrazolo(3,4‐d)pyrimidine, are prepared in order to evaluate their antileishmanial activity.
ChemInform Abstract: Electronic Wavefunctions and Solution Nuclear Magnetic Resonance Parameters of Some Mixed Fluorochloro‐osmates(IV).
Authors: ALYOUBI A. O. , GREENSLADE D. J. , FORSTER M. J. , PREETZ W. 
Published: May 2016

Abstract19F NMR chemical shifts and spin‐spin splitting parameters are reported for K2(OsF6), Cs2(OsF5Cl), cis‐Cs2(OsF4Cl2), fac‐Cs2(OsF3Cl3), trans‐Cs2(OsF2Cl4), (NBu4)2(OsF5Cl), and fac‐(NBu4)2(OsF3Cl3).
ChemInform Abstract: EMF Investigation of Al‐Si, Al‐Fe‐Si and Al‐Ni‐Si Liquid Alloys.
Authors: BONNET M. , ROGEZ J. , CASTANET R. 
Published: May 2016

AbstractThe partial free enthalpy of Al in liquid Al‐Si, Al‐Ni, Al‐Fe‐Si, and Al‐Ni‐Si melts is determined using the concentration cell method (EMF measurements as a function of temp.).
ChemInform Abstract: Melt‐Processed LnBa2Cu3O7‐x (Ln: Y, Eu, Ho) Superconducting Oxides.
Authors: COSTA G. A. , FERRETTI M. 
Published: May 2016

AbstractThe peritectic decomposition temp. of the title compounds are determined (1 atm O2) to be 1030 (Ln: Y), 1060 (Eu), and 980 °C (Ho).
ChemInform Abstract: Discharge Behavior and Thermal Stability of Synthetic FeS2 Cathode Material
Authors: PEMSLER J. P. , LAM R. K. F. , LITCHFIELD J. K. , DALLEK S. , LARRICK B. F. , BEARD B. C. 
Published: May 2016

Abstractare studied by single‐cell studies, TG, and XPS.
ChemInform Abstract: Electrochemistry of Manganese Dioxide in Lithium Nonaqueous Cell. Part 2. X‐Ray Diffractional and Electrochemical Characterization on Deep Discharge Products of Electrolytic Manganese Dioxide.
Authors: OHZUKU T. , KITAGAWA M. , HIRAI T. 
Published: May 2016

AbstractThe electrochemical reduction of heat‐treated (200‐450 °C) electrolytic MnO2 in 1 M LiClO4/propylene carbonate/DME produces a new LixMnO2 material.
ChemInform Abstract: Influence of Aluminum on the Oxidation of Titanium Between 550 and 750 °C.
Authors: CHAZE A. M. , CODDET C. 
Published: May 2016

AbstractThe oxidation kinetics of binary Ti‐Al alloys containing 1.65, 3, 5, and 10 wt.% Al are studied in the temp. range 500‐750 °C. The results obtained for oxidation in air confirm the beneficial role of Al on the oxidation resistance.
ChemInform Abstract: Trends Across the Periodic Table ‐ A Screening of the Gas‐Phase Chemistry of d‐Block Transition‐Metal Ions with Isocyanides.
Authors: ELLER K. , SCHWARZ H. 
Published: May 2016

AbstractBy screening the reactions of alkyl isocyanides R‐NC with most of the d‐Block transition metal ions several trends are uncovered that permit a deeper insight into the intrinsic properties of the metal ions.
ChemInform Abstract: Electrochemical Codeposition of Gallium and Arsenic from a Room Temperature Chlorogallate Melt
Authors: CARPENTER M. K. , VERBRUGGE M. W. 
Published: May 2016

Abstractconsisting of GaCl3, 1‐methyl‐3‐ethylimidazolium chloride, and AsCl3 is studied over the potential range 0 to ‐2V relative to an aluminum reference electrode.
ChemInform Abstract: Synthesis and Crystal Structure of a New Indium Oxide of Composition Ba8In6O17.
Authors: MADER K. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractSingle crystals of the title compound are prepared by annealing pressed pellets of a BaO‐In2O3 mixture at 1450 °C (3‐4 d).
ChemInform Abstract: A Compound Containing Two (Os2I8)2‐ Ions Fused to Form a (Os4I14)2‐ Ion Containing OsOs Triple Bonds.
Authors: COTTON F. A. , VIDYASAGAR K. 
Published: May 2016

AbstractThe compound (IV) containing the (Os4I14)2‐ anion crystallizes in space group P1 with Z=1.
ChemInform Abstract: Dinuclear Complexes of a (30)Py2N4O4 Macrocyclic Ligand Containing Two α,α′‐Bis(aminomethyl)pyridine Moieties. Comparison with Analogous 22‐ and 24‐Membered Macrocyclic Ligands.
Authors: MENIF R. , CHEN D. , MARTELL A. E. 
Published: May 2016

AbstractThe ligand (Ia) is prepared via its Pb complex from 2,6‐pyridinecarboxaldehyde and the corresponding diamine in the presence of Pb(SCN)2, followed by demetalation (yield 67%).
ChemInform Abstract: Lewis Acid‐Induced Nucleophilic Substitution Reaction of β‐Nitro Sulfides.
Authors: KAMIMURA A. , SASATANI H. , HASHIMOTO T. , ONO N. 
Published: May 2016

AbstractThe nitro group in β‐nitro sulfides such as (I) or (V) is substituted for an allyl or a cyano moiety or hydrogen upon treatment with allylsilane (II), the cyanosilane (VI), or triethylsilane in the presence of Lewis acids.
ChemInform Abstract: Organic Photochemistry. Part 84. Photoactivation of Distal Functional Groups in Polyfunctional Molecules. Intramolecular Aryl Sensitized Ketone Photoreduction via an Internal Singlet‐Triplet Switch.
Authors: WU Z.‐Z. , MORRISON H. 
Published: May 2016

AbstractAn energy relay mechanism is proposed for the self‐sensitized, site‐specific reduction of the 17‐keto group in (I) in which the 11‐keto moiety functions switch as an intermediate singlet‐triplet; singlet excitation of the Dps‐"antenna chromophor"‐group is suggested to be the first step followed by intramolecular singlet‐singlet energy transfer (intra‐SSET) to the 11‐keto moiety.
ChemInform Abstract: Photochemistry of (η1‐C5Cl5)Mn(CO)5 and (η1‐C6H5CH2)Mn(CO)5: Competitive Formation of 16‐ and 17e Intermediates.
Authors: YOUNG K. M. , WRIGHTON M. S. 
Published: May 2016

AbstractIn order to explore the factors that control the reactivity of the complexes (I) and (IV), their photochemistry is investigated.
ChemInform Abstract: Formation and Stabilization of Free Radicals in Mixed‐Crystal Structures of Dicarboxylic and Peroxydicarboxylic Acids.
Authors: NIKISHIN G. I. , KORITZKY A. T. , LINDEMAN S. V. , GERR R. G. , STRUCHKOV YU. T. , STAROSTIN EU. K. 
Published: May 2016

AbstractA new phenomenon is described ‐ the formation of free radicals from peroxydicarboxylic acids (HOOC‐(CH2)n‐CO‐O)2 (n = 2, 3) on their cocrystallization with dicarboxylic acids (succinic, glutaric, and fumaric acids) in the absence of any external action on the matrix.
ChemInform Abstract: The Selective Methylation of 4‐Ethoxycarbonyl‐3‐methylpyrazolin‐5‐one with Dimethyl Sulfate.
Authors: JURSIC B. , BREGANT N. 
Published: May 2016

AbstractDiethyl acetylmalonate (I) undergoes cyclocondensation with the hydrazines (II) to form the pyrazolinones (III).
ChemInform Abstract: Dimethylheptyl(3‐(N‐hetaryl)propyl)silanes: Synthesis, Antimicrobial, and Antiblastic Activity.
Authors: STURKOVICH R. , GOLDBERG Y. , VEROVSKY V. , AUGUSTANE I. , PRODANCHUK N. , DEINEKA S. , LUKEVICS E. 
Published: May 2016

AbstractHydrosilylation of allyl chloride (I) with chlorodimethylsilane (II) in the presence of a platinum catalyst yields (3‐chloropropyl)dimethylsilane (III) which reacts with heptylmagnesium bromide (IV) to give the (3‐chloropropyl)dimethylheptylsilane (V).
ChemInform Abstract: Cobalt‐Catalyzed Photochemical Methoxycarbonylation of Olefins Under Ambient Conditions.
Authors: TAO Y.‐T. , CHOW T. J. , LIN J.‐T. , LIN C.‐C. , CHIEN M.‐T. , LIN C.‐C. , CHOW Y. L. , BUONO‐CORE G. E. 
Published: May 2016

AbstractThe light‐promoted methoxycarbonylation of alkenes such as (I), (VIII) or (X) proceeds under ambient conditions, i.e. 1 atm of CO and room temp., in the presence of a cobalt catalyst.
ChemInform Abstract: The Stereoselective Synthesis of Disubstituted E,Z‐Diene Ester.
Authors: OKAY G. 
Published: May 2016

AbstractThe protected hydroxypropionate (I) is reduced to give the aldehyde (II) which undergoes Wittig‐Horner olefination with the phosphonate (III), yielding the E‐pentenoate (IV).
ChemInform Abstract: Improved Preparation of Aliphatic Propynoic Esters.
Authors: BALAS L. , JOUSSEAUME B. , LANGWOST B. 
Published: May 2016

AbstractPropynoic acid (I) forms the esters (III) or the diester (V) by reaction with the alcohols (IIa) ‐ (IIc) or the diol (IV) in the presence of dicyclohexylcarbodiimide and N,N‐dimethylaminopyridine.
ChemInform Abstract: Cation Radical Pericyclic Reactions: Cyclopropanation.
Authors: BAULD N. L. , STUFFLEBEME G. W. , LORENZ K. T. 
Published: May 2016

AbstractOlefins such as 2,3‐dimethyl‐2‐butene (I), cis‐ and trans‐stilbene (IV), α‐terpinene (VI), 1,1‐dibromo‐4‐methylpenta‐1,3‐diene (VIII), and trans‐anethole (XI) are cyclopropanated with ethyl diazoacetate (II) in the presence of tris(bromophenyl)aminium hexachloroantimonates.
ChemInform Abstract: Nitrobicyclo(2.2.1)heptanes. Part 7. The Synthesis of Eight Isomeric Nitrobicyclo(2.2.1)heptan‐2‐ols and of Four Isomeric Nitrobicyclo(2.2.1)heptan‐2‐ones.
Authors: MICHAEL J. P. , MAQUTU T. L. , HOWARD A. S. 
Published: May 2016

AbstractPreviously published reports of crystallographically discernible intra‐ and intermolecular hydroxy‐to‐nitro hydrogen bonds in a number of nitrobicyclo(2.2.1)heptanols (nitronorbornanols) give rise to the search of further examples of these somewhat uncommon interactions.
ChemInform Abstract: Effect of Copper(I) Iodide and Magnesium Chloride on the Amination of Aryl Grignards with Ketoximes.
Authors: ERDIK E. , AY M. 
Published: May 2016

AbstractPhenylmagnesium bromide (I) is aminated with aceton‐ (IIa) or benzophenonoxime O‐mesitylenesulfonate (IIb) to give aniline (IV) via the intermediate (III).
ChemInform Abstract: Synthesis of p‐Benzoquinones by Oxidation of N‐Arylsulfonamides.
Authors: HEWSON A. T. , SHARPE D. A. , WADSWORTH A. H. 
Published: May 2016

AbstractOxidative cleavage of the N‐arylbenzenesulfonamides (I) with ceric ammonium nitrate gives the p‐benzoquinones (II).
ChemInform Abstract: Sulfinic Acids and Related Compounds. Part 21. Preparation of Crystalline Sulfinic Esters.
Authors: LEE C. , FIELD L. 
Published: May 2016

AbstractThe sulfinic acid (I) is activated by intermediate formation of the corresponding imidazolide which reacts with various alcohols such as (II) to give the sulfinic acid esters (III).
ChemInform Abstract: Syntheses and Crystal Structure of Calix(4)quinone.
Authors: MORITA Y. , AGAWA T. , KAI Y. , KANEHISA N. , KASAI N. , NOMURA E. , TANIGUCHI H. 
Published: May 2016

AbstractThe target quinone (VII) is prepared by three different methods all starting with the calix(4)arene (I).
ChemInform Abstract: Conjugate Addition of Arylacetonitriles to Cinnamic Acid Derivatives. A Case of High Diastereoselective Asymmetric Protonation.
Authors: VITEVA L. , STEFANOVSKY Y. 
Published: May 2016

AbstractN,N‐Dimethylcinnamic amide (Ia) and methyl cinnamate (Ib) undergo predominant 1,4‐addition of the metallated arylacetonitriles (II) to form the γ‐cyanocarboxylic acid derivatives (III) and (IV).
ChemInform Abstract: Additions to the Activated Double Bond of Substituted 3‐Methylene‐2‐azetidinones: Amine Additions.
Authors: GUERTLER S. + , RUF S. , OTTO H.‐H. 
Published: May 2016

AbstractThe methylenazetidinone (I) reacts with amines such as (II) to give in most cases selectively the adducts (R,R)‐(III).
ChemInform Abstract: New Synthesis of Lactams and Spirolactams: Radical Cyclization Induced by Manganese(III) Acetate.
Authors: COSSY J. , LEBLANC C. 
Published: May 2016

AbstractThe N‐allyl or N‐propargylaminocarbonylcycloalkanones (I), (IV), or (VI) are cyclized upon treatment with manganese(III) acetate to form the spiro‐fused lactams (II) and (III), (V), or (VII).
ChemInform Abstract: 1,2,4‐Triazoles. Part 3. New 1,5‐Diaryl‐3‐(Substituted‐amino)‐1H‐1,2,4‐triazoles as Antiinflammatory Agents.
Authors: BOZO E. , SZILAGYI G. , JANAKY J. 
Published: May 2016

AbstractSeventeen aminotriazoles such as (IV) are prepared by cyclization of diacylphenylhydrazines, e.g. (I), to form the oxadiazolium salts (II) and subsequent reaction with cyanamide (III).
ChemInform Abstract: Enantiospecific Synthesis of (+)‐(R)‐6,7‐Dimethoxy‐2‐methyl‐4‐phenyl‐1,2,3,4‐tetrahydroisoquinoline from (+)‐(S)‐2‐Methylamino‐1‐phenylethanol (Halostachine).
Authors: COOTE S. J. , DAVIES S. G. , MIDDLEMISS D. , NAYLOR A. 
Published: May 2016

AbstractThe key step in the preparation of the title compound (VIII) is the acid‐promoted, highly stereoselective cyclization of the tricarbonylchromium complex (VI).
ChemInform Abstract: Synthesis and Antiviral Activity of Spirobromin and Its Analogue.
Authors: FOMINA A. N. , NIKOLAEVA I. S. , PUSHKINA T. V. , KRYLOVA L. YU. , LEVKOVSKAYA L. G. , DEEV V. B. , SAFONOVA T. S. 
Published: May 2016

AbstractStarting with the dinitrosodiazadiazoniadispirohexadecane (I), the bis‐(bromopropionylamino) derivative (VI), an analogue of spirobromin (VII), is prepared via the intermediates (III) and (IV).
ChemInform Abstract: Unusual Spectral Properties of meso‐(N,N‐Dialkylaminophenyl)porphyrins.
Authors: GUNTER M. J. , ROBINSON B. C. 
Published: May 2016

AbstractThe behavior of the porphyrins (I) and (III) (syntheses described) in acidic solution is exmined by UV‐VIS and 1H NMR.
ChemInform Abstract: Synthesis of Some Naphthothiadiazolophanes: Derivatives of 4,10,14‐Ethenylylidene‐7H‐(1,2,3)thiadiazolo(5,4‐e)azacyclotridecine and 4,11,15‐Ethenylylidene(1,2,3)thiadiazolo(5,4‐f)azacyclotetradecine.
Authors: BREMNER J. B. , JATURONRUSMEE W. 
Published: May 2016

AbstractA general methodology, i.e. ring destruction with cyanogen bromide and chloroformate ester is applied to the synthesis of the new thiadiazole‐anellated heterocyclophanes (III) and (VI).
ChemInform Abstract: Chemistry of Boron. Part 198. Reactions of Amino‐imino‐boranes with Dioxaphospholanes, Dioxarsolanes, and Dioxastibolanes.
Authors: BRANDL A. , NOETH H. + 
Published: May 2016

AbstractThe (tert.‐butylimino)piperidinoborane (I) inserts into the exocyclic E‐R bond of the dioxaphospholanes, benzodioxaphospholes, ‐arsole and ‐stibole (II) to give the corresponding products (III).
ChemInform Abstract: Structural Studies of Organoboron Compounds. Part 35. 4,8‐Diethyl‐2,2,6,6‐tetraphenyl‐1,3,5,7‐tetraoxa‐4,8‐diazonia‐2,6‐diborata‐1,2,3,5,6,7‐hexahydronaphthalene.
Authors: KLIEGEL W. , TAJERBASHI M. , RETTIG S. J. , TROTTER J. 
Published: May 2016

AbstractThe title compound (III) (space group P21/n, Z=4) has a novel bis‐six‐membered binuclear chelate structure.
ChemInform Abstract: Preparation and Single‐Crystal X‐Ray Structure Investigations of Some N,N′‐Dimethylurea‐Bridged Diphosphorus Compounds; NMR Studies of a λ4P+λ4P+‐Diphosphorus Compound.
Authors: ERNST L. , JONES P. G. , LOOK‐HERBER P. , SCHMUTZLER R. 
Published: May 2016

AbstractThe λ3Pλ4P+ diphosphorus compounds (IIIb) and (VII) are converted into the λ4P+λ4P+ derivatives (V) and (VIII) by methylation with methyl triflate (IV).
ChemInform Abstract: Reactivity of (C5Me5)2Sm with Aryl‐Substituted Alkenes: Synthesis and Structure of a Bimetallic Styrene Complex That Contains an η2‐Arene Lanthanoid Interaction.
Authors: EVANS W. J. , ULIBARRI T. A. , ZILLER J. W. 
Published: May 2016

AbstractThe complex (I) and its bis‐THF adduct isomerize cis‐stilbene to trans‐stilbene.
ChemInform Abstract: A New Tetranuclear Oxohydroxoiron(III) Cluster: Crystal Structure, Magnetic Properties, and EXAFS Investigation of (L4Fe4(μ‐O)2(μ‐OH)4)I4·3 H2O (L: 1,4,7‐Triazacyclononane).
Authors: DRUEEKE S. + , WIEGHARDT K. , NUBER B. , WEISS J. , BOMINAAR E. L. , SAWARYN A. , WINKLER H. , TRAUTWEIN A. X. 
Published: May 2016

AbstractHydrolysis of the cation (I) in aqueous solution yields the new tetranuclear species (II).
ChemInform Abstract: Fluorine‐Substituted Ferracyclopentadiene Complexes with an Unprecedented Fluorine Bridge Between Boron and Carbon.
Authors: MIRKIN C. A. , LU K.‐L. , GEOFFROY G. L. , RHEINGOLD A. L. 
Published: May 2016

AbstractThe title complexes (III) are the first examples of any type of compound with a fluorine atom bridging between C and B atoms.
ChemInform Abstract: A New Synthetic Route for Transition‐Metal Complexes with Schiff Bases.
Authors: CARBONARO L. , GIACOMELLI A. , SENATORE L. , VALLI L. 
Published: May 2016

AbstractA new preparation method of Schiff base metal complexes is proposed based on the transimination reaction between ammonium or ammonium‐like salts and the imino group of some N‐substituted salicylaldimine chelates.
ChemInform Abstract: (Template)2 Synthesis of a Dinucleating Macrocyclic Ligand and Crystal Structure of Its Dicopper(II) Imidazolate Complex.
Authors: SALATA C. A. , YOUINOU M.‐T. , BURROWS C. J. 
Published: May 2016

AbstractThe novel synthetic procedure shown in the scheme leads to (V), crystallizing in P1 with Z=2.
ChemInform Abstract: Luminescent Extended One‐Dimensional Heterobimetallic Chain Compounds with Relativistic Metal‐Metal Bonds. Synthesis, Crystal Structures, and Spectroscopic Studies of AuTl(MTP)2 and Au2Pb(MTP)4 (MTP: (CH2P(S)Ph2)‐).
Authors: WANG S. , GARZON G. , KING C. , WANG J.‐C. , FACKLER J. P. JUN. 
Published: May 2016

AbstractThe title complexes (III) and (V) form linear chain polymers with short metal‐metal separations in the solid state.