bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Effect of Metal Ions in Organic Synthesis. Part 34. Synthesis, X‐Ray Crystal Structure and NMR Studies of New 3‐Aminocarbonyl‐1‐phosphonoaminopyrroles.
Authors: ATTANASI O. A. , FILIPPONE P. , GUERRA P. , SERRA‐ZANETTI F. , FORESTI E. , TUGNOLI V. 
Published: May 2016

AbstractThe CuCl2‐catalyzed reaction of azoalkenes with β‐keto amides leads to the title compounds, e.g. (III), (V) and (VIII).
ChemInform Abstract: Synthesis and Biological Activity of Substituted 5‐Hydroxy‐6‐bromoindoles.
Authors: PANISHEVA E. K. , FOMINA A. N. , NIKOLAEVA I. S. , GALENKO‐YAROSHEVSKII P. A. , BARTASHEVICH V. V. , CHERKASOVA A. A. , LINCHENKO S. N. , EGIK'YAN A. L. , GOLOVANOVA E. A. , PUSHKINA T. V. 
Published: May 2016

AbstractThe bromomethylindoles (I) react with thiophenol (II) to give the thioethers (III) which are coupled with the formaldehyde N,N‐acetal, producing the dimethylaminomethyl derivatives (V).
ChemInform Abstract: Pyrrolidines by Intramolecular Addition of Kolbe Radicals Generated from β‐Allylaminoalkanoates.
Authors: BECKING L. , SCHAEFER H. J. + 
Published: May 2016

AbstractThe N‐alkenyl or N‐alkynyl formamido acids (VII), prepared from the amines (I) and the acrylonitriles (II) via the nitriles (III) and the acids (IV), are subjected to mixed Kolbe electrolysis with the carboxylic acids (VIII), yielding the pyrrolidines (IX) ‐ (XII).
ChemInform Abstract: Generation, Trapping, and Adduct Rearrangement of 3‐Phenylselenoalk‐1‐enylidene Carbenes: A Novel Direct Route to 1‐Hetero‐substituted 1‐Vinylcyclopropanes.
Authors: LEWIS R. T. , MOTHERWELL W. B. 
Published: May 2016

AbstractCyclohexene (I) and the dihydropyran (VIII) react with the diazophosphonate (II) and the phenylselenenyl ketones (III) or (XII) to give the vinylidenecyclopropanes (IV), (IX) and (X), or (XIII).
ChemInform Abstract: Selenium Analogues of 2‐(Thiopyran‐4‐ylidene)‐1,3‐dithiole as Novel Unsymmetrical Electron Donors.
Authors: SHIOMI Y. , ASO Y. , OTSUBO T. , OGURA F. 
Published: May 2016

AbstractTriethyl phosphite promoted cross‐coupling of the cyclic trithio‐ (Ia) or triselenocarbonates (Ib) with tetrahydrothio‐ (IIa) and tetrahydroselenopyranone (IIb) yields the ylidene derivatives (III) which are dehydrogenated with chloranil, forming the tetraenes (IV).
ChemInform Abstract: Synthesis and Structure of 1,4‐((RCp)2Ti)2Se4 and Its Application to the “Chalcogenospecific” Synthesis of 1,2,5,6‐Se4S4.
Authors: GIOLANDO D. M. , PAPAVASSILIOU M. , PICKARDT J. , RAUCHFUSS T. B. , STEUDEL R. 
Published: May 2016

AbstractThe deselenization of the compounds (I) with phosphines yields the title compounds (III), which can also be prepared from the reaction of (IV) with solutions of Li2Se2 (V).
ChemInform Abstract: Intramolecular Hypervalent Sn‐O Interaction. The Origin for Fixation of Six‐Membered Carbocycles to the 1,3‐Diaxial Conformer and for Stereoselective Osmylations.
Authors: OCHIAI M. , IWAKI S. , UKITA T. , MATSUURA Y. , SHIRO M. , NAGAO Y. 
Published: May 2016

AbstractReplacement of one of the methyl groups of (I) or (III) by an electronegative substituent such as chlorine yields the cyclohexylchlorodimethylstannanes (II) or (IV), which exist in the 1,3‐diaxial conformation as a result of intramolecular hypervalent interaction between the tin and etheric oxygen atoms.
ChemInform Abstract: A Folded Metallacyclopentatriene and a Bicapped‐Tetrahedral M2C4 Cluster Obtained from Coupling of Alkyne Ligands. Structures of CpMoCl(C4Ph4) and (CpMoCl)2(μ,η4‐C4Ar4) (Ar: p‐Tolyl).
Authors: HIRPO W. , CURTIS M. D. 
Published: May 2016

AbstractIn the mixture of compounds (II)‐(IV) compound (II), the first example of this structure type, is produced preferentially at lower temp. and by the addition of excess alkyne to the solution, while formation of (III) is favored by longer reaction times, higher temp., and no added alkyne.
ChemInform Abstract: Reaction of Ferrocene with Bromoadamantane.
Authors: KRAVTSOV D. N. , VIL'CHEVSKAYA V. D. , PETROVSKII P. V. , GORELIKOVA YU. YU. 
Published: May 2016

AbstractFerrocene (I) reacts with 1‐adamantyl bromide (II) under Friedel‐Crafts conditions to give 1‐(1‐adamantyl)ferrocene (III) or after a prolonged reaction (III), together with 1,1'‐bis‐(1‐adamantyl)ferrocene (IV).
ChemInform Abstract: Synthesis and Characterization of 12‐Vertex Dinuclear Cobaltaborane Complexes Containing the Co2(CO)5 Moiety and SEt2 Cage Substituents.
Authors: SCHUBERT D. M. , KNOBLER C. B. , WEGNER P. A. , HAWTHORNE M. F. 
Published: May 2016

AbstractThe reaction of the arachno‐borane (I) with multinuclear cobalt carbonyls results in the formation of the two isomeric closo‐dicobaltaborane complexes (IV) and (V) as main products.
ChemInform Abstract: Synthesis of γ‐Thio‐Substituted Metal β‐Diketonates.
Authors: SVISTUNOV G. M. , REUTOV V. A. , SHAPKIN N. P. 
Published: May 2016

AbstractThe sulfenyl chlorides (I) are treated with ethylene (II) to produce the 2‐chloroethylthio derivatives (III).
ChemInform Abstract: Synthesis, Characterization, and Reactivity of Bis(thioether) Complexes of (Octaethylporphyrinato)ruthenium(II).
Authors: JAMES B. R. , PACHECO A. , RETTIG S. J. , IBERS J. A. 
Published: May 2016

AbstractThe low‐spin complexes (III), obtained from the dimer (I), are investigated crystallographically.
ChemInform Abstract: Linkage Isomerism in Palladium(II)‐Chloranilate Complexes. Synthesis and Mechanistic Studies of Bis(acetonitrile)(chloranilato)palladium(II) and Bis(triphenylphosphine)(chloranilato)palladium(II).
Authors: JEONG W.‐Y. , HOLWERDA R. A. 
Published: May 2016

AbstractThe reaction of the known complex (III), in which the chloranilate ligand has lost its quinoid character, with AgNO3 in acetonitrile (IV) yields the complex (V) by extracting the chloride ion.
ChemInform Abstract: Unusual Isomerization of Ortho‐Chelated Aryliridium(I) Complexes, Involving a Unique Sequence of Intramolecular C‐H Bond‐Making and ‐Breaking Processes. X‐Ray Structure of Ir(I)(C6H3(CH2NMe2)2‐2,4)(COD).
Authors: VAN DER ZEIJDEN A. A. H. , VAN KOTEN G. , LUIJK R. , NORDEMANN R. A. , SPEK A. L. 
Published: May 2016

AbstractThe preparation of the complexes (III) is described.
ChemInform Abstract: A New Method for C‐C Coupling of Terminal Alkenes via a Sulfonylation‐Alkylation‐Desulfinylation Sequence: Synthesis of E‐ and Z‐α‐Bisabolenes.
Authors: BALDWIN J. E. , ADLINGTON R. M. , ICHIKAWA Y. , KNEALE C. J. 
Published: May 2016

AbstractCoupling of (R)‐(+)‐limonene (I) with methanesulfonyl iodide (II) followed by dehydroiodination, yields the α,β‐unsaturated methyl sulfone (III).
ChemInform Abstract: Chiral and Achiral Formamidines in Synthesis. The First Asymmetric Route to (‐)‐Yohimbone and an Efficient Total Synthesis of (.+‐.)‐Yohimbone.
Authors: MEYERS A. I. , MILLER D. B. , WHITE F. H. 
Published: May 2016

AbstractBirch reduction of the desired adduct (S)‐(‐)‐(VI) affords the enol ether (VII); but when the latter compound is treated with 1. AcOH/H2O and 2. HCHO only racemic yohimbenone (±)‐(X) is obtained instead of the expected chiral material.
ChemInform Abstract: New Poly(ethylene Oxide)‐Cu(CF3SO3)2 Polymer Electrolytes.
Authors: BONINO F. , PANTALONI S. , PASSERINI S. , SCROSATI B. 
Published: May 2016

AbstractThe electrochemical characteristics are determined for polymer electrolytes formed by complexes of poly(ethylene oxide), PEO, and Cu(CF3SO3)2 with varying molar ratio.
ChemInform Abstract: Corrosion Measurements Using Microelectrodes.
Authors: WIKIEL K. , OSTERYOUNG J. 
Published: May 2016

AbstractIt is demonstrated that microelectrodes can be used for typical corrosion measurements with the advantages that very high current densities can be achieved at low currents, i.e., reduced effects of IR‐ohmic drops, and that steady‐state diffusional profiles are achieved at short times.
ChemInform Abstract: Potentiometric Determination of the Stabilities of Cobalt(II) Complexes of Polyamine Schiff Bases and Their Dioxygen Adducts.
Authors: MOTEKAITIS R. J. , MARTELL A. E. 
Published: May 2016

AbstractPotentiometric measurements of oxygenation constants are presented (tables) for solutions in 70% dioxane ‐30% water containing cobalt(II) chloride and the following ligand components: 1. (IIIa)/(I); 2. (IIIa)/(II); 3. en/(IIIa)/(IV), and 4. (IIIb)/(IV)/(V).
ChemInform Abstract: pH‐Dependent Alternative Ring Closure of Monoacyl 2‐Aminobenzamide Oximes. A New 2‐Aminobenzimidazole Synthesis.
Authors: KORBONITS D. , KOLONITS P. 
Published: May 2016

AbstractDepending on the reaction conditions, the N‐benzoyl derivative (II) and the O‐benzoyl derivative (IV) afford the cyclized products shown in the scheme.
ChemInform Abstract: Pinacol‐Pinacolone Rearrangement Promoted by Polyphosphoric Acid Trimethylsilyl Ester (PPSE).
Authors: KAKIMOTO M. , SERI T. , IMAI Y. 
Published: May 2016

AbstractThe rearrangements of pinacols (I), (IV), and (VI) promoted by PPSE (= cat.) are suggested to proceed via an ionic stage according to the acceleration effect of the dipolar solvent sulfolane (see (VI) → (VII)); in this solvent (I) rearranges with 1 equiv. cat.
ChemInform Abstract: Infrared Spectra of Matrix‐Isolated CF3S(O)F and Its Photolysis Product CF3OSF.
Authors: BIELEFELDT D. , SCHATTE G. , WILLNER H. 
Published: May 2016

AbstractThe fluorosulfenyl ester (I) decomposes on prolonged UV irradiation to give the product (III) and SF2.
ChemInform Abstract: Singlet‐Oxygen Quenching by Carotenoids: Steady‐State Luminescence Experiments.
Authors: MURASECCO‐SUARDI P. , OLIVEROS E. , BRAUN A. M. , HANSEN H.‐J. 
Published: May 2016

AbstractThe near‐IR luminescence of 1O2 is measured in order to determine the efficiency of 1O2 quenching by canthaxanthin, in comparison with that of all‐trans‐β‐carotene, in CCl4 and CD3OD.
ChemInform Abstract: The Extraordinary Selectivity of Methoxyphenylcarbene. The Case of the Curious “Olefin”.
Authors: MOSS R. A. , WLOSTOWSKA J. 
Published: May 2016

AbstractThe methoxyphenylcarbene (II), generated in situ from the azirine (I), reacts with pure tetramethylethylene (III) to give mixtures of the expected cyclopropane (IV) and the azine (V), together with the by‐products (VI) and (VII).
ChemInform Abstract: Catalytic Hydrogenation of Diketones.
Authors: CORMIER R. A. , MCCAULEY M. D. 
Published: May 2016

AbstractThe 1,3‐diones (I) and (V) are hydrogenated in the presence of palladium on carbon and catalytic amounts of sulfuric acid to form the monoketones (II) or (VI) and (VII).
ChemInform Abstract: A Convenient Procedure for the Reduction of Diarylmethanols with Dichlorodimethylsilane/Sodium Iodide.
Authors: WIGGINS J. J. 
Published: May 2016

AbstractThe aryl carbinols (Ia), (Ib), (III), and (V) are reduced with dichlorodimethylsilane in the presence of sodium iodide to form the (poly)arylmethane derivatives (II), (IV), and (VI).
ChemInform Abstract: A One‐Step Synthesis of Alkyl 2‐Oxo‐3‐alkenoates from Alkenyl Grignard Reagents and Dialkyl Oxalates.
Authors: RAMBAUD M. , BAKASSE M. , DUGUAY G. , VILLIERAS J. 
Published: May 2016

AbstractAddition of the alkenylmagnesium bromides (I) to the dialkyl oxalates (II) in an ether/THF mixture (1:1) at ‐80°C leads to the formation of the title compounds (III).
ChemInform Abstract: Mixed Organocuprates Derived from ortho‐Heterosubstituted ArCu Species. Reactions with Simple α,β‐Unsaturated Ketones.
Authors: AREVALO F. , CASTEDO L. , FERNANDEZ B. R. , MOURINO A. , SARANDESES L. A. 
Published: May 2016

AbstractThe substituted benzenes (I) are lithiated and then treated with the cuprous bromide‐dimethyl sulfide complex (II) to produce the arylcopper compounds (III).
ChemInform Abstract: Phase‐Transfer Catalyzed Alkylation of Anthrone and 10‐Propargylanthrone.
Authors: MAJUMDAR K. C. , CHATTOPADHYAY S. K. , KHAN A. T. 
Published: May 2016

AbstractAlkylation of anthrone (I) with the allylic or propargylic bromides (II) under phase‐transfer conditions gives predominantly the C,C‐dialkylated products (III), whereas 10‐propargylanthrone (VII) and allyl bromide (IIa) form the allyloxyanthracene (VIII).
ChemInform Abstract: A Synthesis of Furans from Epoxycarbonyl Precursors.
Authors: CORMIER R. A. , GROSSHANS C. A. , SKIBBE S. L. 
Published: May 2016

AbstractThe β‐epoxy ketones and aldehydes (I), obtained by consecutive epoxidation and oxidation of the corresponding homoallylic alcohols, are transformed into the furans (II) by thermolysis or treatment with (Lewis) acids.
ChemInform Abstract: Photoinduced Masked‐Formylation of Vinylsulfone Derivatives with 1,3‐Dioxolane. Application to the Synthesis of 3,4‐Disubstituted Pyrroles.
Authors: INOMATA K. , SUHARA H. , KINOSHITA H. , KOTAKE H. 
Published: May 2016

AbstractPhotochemical coupling of the cyanoethylene sulfones (V) with 1,3‐dioxolane (VI) yields the protected cyanoformylethyl sulfones (VII) which are alkylated with the halides (VIII) to give the derivatives (IX).
ChemInform Abstract: Synthesis of the Fused Bicyclic Lactam‐Lactone Terminus of Neooxazolomycin by a Novel Dianion Cyclocondensation.
Authors: KENDE A. S. , DEVITA R. J. 
Published: May 2016

AbstractThe aminomalonic acid ester (I) is converted to its dianion (III) which reacts with the ester (IV) to give the diastereomeric pyrrolidones (V) and (VI).
ChemInform Abstract: A Novel Synthesis of Benzothiazoles.
Authors: KATRITZKY A. R. , SAKIZADEH K. , SWINSON J. , HEILMANN S. M. , KREPSKI L. R. , PATHRE S. V. , RASMUSSEN J. K. 
Published: May 2016

Abstract2‐Aminothiophenol (I) undergoes cyclocondensation with the 2‐phenyloxazol‐5‐ones (II) in acetic acid, yielding the benzoylaminoalkylbenzothiazoles (III).
ChemInform Abstract: Catalytic Asymmetric Synthesis of Alkyl‐Substituted Lactones by Enantioselective and Chemoselective Alkylation of Formyl Esters with Dialkylzincs Using N,N‐Dibutylnorephedrine.
Authors: SOAI K. , YOKOYAMA S. , HAYASAKA T. , EBIHARA K. 
Published: May 2016

AbstractThe ω‐formyl carboxylates (I) are coupled with the dialkylzinc agents (II) in the presence of (‐)‐N,N‐dibutylnorephedrine, yielding selectively the hydroxy esters (‐)‐(III) which are cyclized to form the lactones (S)‐(IV).
ChemInform Abstract: Metalation of Carbamates of 2‐, 3‐ and 4‐Hydroxyquinolines.
Authors: JACQUELIN J. M. , ROBIN Y. , GODARD A. , QUEGUINER G. 
Published: May 2016

AbstractLithiation of the carbamates (I), (V), (IX) and (XI) occurs adjacent to the functional group.
ChemInform Abstract: Reaction of Stabilized Bismuthonium Ylides with Aldehydes. A Novel Reaction Mode of the Heaviest Group V Element Ylide.
Authors: OGAWA T. , MURAFUJI T. , SUZUKI H. 
Published: May 2016

AbstractThe triphenylbismuthonium ylide (I), derived from dimedone, reacts with the aldehydes (II) to produce mixtures of the spiro‐fused furans (III) and (IV) or the cyclopropanes (V) depending on the reaction temperature.
ChemInform Abstract: Synthesis of Aryl‐Substituted 7‐Aminoimidazo(1,5‐b)pyridazines.
Authors: KRUGLENKO V. P. , TIMOSHIN A. A. , IDZIKOVSKII V. A. , KLYUEV N. A. , POVSTYANOI M. V. 
Published: May 2016

AbstractThe diaminoimidazole (I) is coupled with the diketocarboxylic acids (II) to produce the title compounds (III).
ChemInform Abstract: Thiazolo(3,2‐a)pyrimidinium‐2‐sulfonates.
Authors: CHUIGUK V. A. , SUKHOREBRAYA L. N. 
Published: May 2016

AbstractThe aminothiazolium‐5‐sulfonate (I) reacts with the malonaldehyde acetal (II) or the β‐diketones (IV) to give the compounds (III) mentioned in the title.
ChemInform Abstract: Synthesis of 1,4,3‐Oxathiazine 4,4‐Dioxides and 1,2,4‐Thiadiazine 1,1‐Dioxides from 1,3‐Acetonebis(sulfonyl chloride).
Authors: RIED W. , BELLER G. , BATS J. W. 
Published: May 2016

AbstractReaction of acetone‐1,3‐bis(sulfonyl chloride) (II) with the N,N‐dialkylcyanamides (I) at 80°C yields the oxathiazine dioxides (III).
ChemInform Abstract: 4,10a‐(Epidithio)‐4,4a,10,10a‐tetrahydro‐1H‐5‐oxaanthracen‐1‐ones, Tetracycles with a Novel Heterocyclic Ring System.
Authors: KOLLY S. , MEIER H. , RIHS G. , WINKLER T. 
Published: May 2016

AbstractThe structure of the title compounds (III) is confirmed by 1H and 13C NMR spectroscopy.
ChemInform Abstract: Reaction of Bis(ethylthio)phenylmethyllithium with Trimethylchlorosilane and 2,4,4,‐Trimethyl‐2‐chloro‐1,3‐dioxa‐2‐silacyclohexane.
Authors: NIKOLAEVA S. V. , ZORIN V. V. , LARIONOV V. I. , MUSAVIROV R. S. , KUKOVITSKII D. M. , RAKHMANKULOV D. D. 
Published: May 2016

AbstractThe lithium compound (III), prepared from the benzaldehyde S,S‐acetal (I), is coupled with trimethylsilyl chloride (IV) to give the silane (V).
ChemInform Abstract: Aminomethylation Reaction in the Series of Phosphorus‐Containing Heterocycles. Part 6. Synthesis and Steric Structure of the Aminomethyl Derivatives of trans‐1‐Phenyl‐1‐selenoxo‐2,5‐dimethylphosphorinan‐4‐one.
Authors: BOSYAKOV YU. G. , RABETSKAYA T. I. , LOGUNOV A. P. 
Published: May 2016

AbstractAminomethylation of the selenoxophosphorinanone (I) with N‐methylenemorpholinium chloride (II) forms mixtures of the morpholinomethyl derivatives (III) ‐ (VI) and the unsaturated ketones (VII) and (VIII).
ChemInform Abstract: Structure and Reactivity of Lithium Amides. 6Li, 13C, and 15N NMR Spectroscopic Studies and Colligative Measurements of Lithium Diphenylamide and Lithium Diphenylamide‐Lithium Bromide Complex Solvated by Tetrahydrofuran.
Authors: DEPUE J. S. , COLLUM D. B. 
Published: May 2016

AbstractAt low THF concentrations Li diphenylamide exists in a cyclic dimer form as di‐ or trisolvate (I), forming the mixed aggregate (IV) in the presence of LiBr.
ChemInform Abstract: An “Expanded Porphyrin”: The Synthesis and Structure of a New Aromatic Pentadentate Ligand.
Authors: SESSLER J. L. , MURAI T. , LYNCH V. , CYR M. 
Published: May 2016

AbstractThe "expanded porphyrin" ligand of the Cd complex (I) is prepared by direct acid‐catalyzed condensation of o‐phenylenediamine and the corresponding bis(formylpyrrolylmethyl)pyrrole and subsequent reduction.
ChemInform Abstract: Molybdenum Complexes of 1,2‐Bis(diphenylphosphino)benzene. Mononuclear Molybdenum(II) Species Formed by Facile Metal‐Metal Bond Cleavage of the (Mo‐Mo Quadruple Bond)4+ Core.
Authors: BAKIR M. , COTTON F. A. , CUDAHY M. M. , SIMPSON C. Q. , SMITH T. J. , FIORE VOGEL E. , WALTON R. A. 
Published: May 2016

AbstractThe quadruply bonded dimolybdenum(II) complexes (I) and also (NH4)5(Mo2Cl9)·H2O react with the title diphosphine (II) in MeOH at room temp. to afford the binuclear α‐complexes (III) which do not isomerize to the β isomers.
ChemInform Abstract: Mixed Ligand Complexes of Technetium. Part 2. (Tc(dppe)2(R‐NC)2)+ Complexes (dppe: bis(diphenylphosphino)ethane; R: tert.‐butyl, cyclohexyl).
Authors: ABRAM U. , ABRAM S. , BEYER R. , MUENZE R. , KADEN L. , LORENZ B. , FINDEISEN M. 
Published: May 2016

AbstractThe dinitrogen complex (I) is a suitable starting compound for the synthesis of mixed ligand complexes of Tc in its lower oxidation states.
ChemInform Abstract: Reactions of the Dirhenium(II) Complexes Re2X4(dppm)2 (X: Cl, Br; dppm: Ph2PCH2PPh2) with Isocyanides. Part 5. Mixed Carbonyl‐Isocyanide and Carbonyl‐Isocyanide‐Nitrile Complexes of Stoichiometry (Re2Cl3(dppm)2(CO)(CNR)(L))PF6 (R: tBu, Xyl (Xylyl); L: tBuNC, XylNC, MeCN, EtCN). Structural Characterization of the Cation (Cl2(CO)Re(μ‐dppm)2ReCl(CN‐tBu)2)+.
Authors: FANWICK P. E. , PRICE A. C. , WALTON R. A. 
Published: May 2016

AbstractThe reactions of the monocarbonylmonoisonitrile‐Re(II) complexes (I) and (IV) having different structures with further isonitriles and cyanides are studied.
ChemInform Abstract: Spiroferrocenophanes. Part 1. 3‐Spiro(5)ferrocenophane‐1,5‐diones from the Direct Condensation of Diacetylferrocene with Cycloalkanones.
Authors: MIREK J. , RACHWAL S. , GORECKI T. , KAWALEK B. , MILART P. , SZNELER E. 
Published: May 2016

AbstractCondensation reaction of the diacetylferrocene (I) with the cyclohexanones (IIa) ‐ (IIc) yields the spiroferrocenophanediones (III).
ChemInform Abstract: Reactions of Aryloxy Anions with Organometallic Aryl Cation Equivalents. A Route to Substituted Diphenyl Ethers.
Authors: HOSSNER F. , VOYLE M. 
Published: May 2016

Abstract1,4‐Dichlorobenzene(tricarbonyl)chromium (I) undergoes consecutive nucleophilic substitution with sodium phenoxide (II) and methoxide (IV) to form the methoxyphenoxybenzene complex (V).
ChemInform Abstract: Synthesis and Characterization of Triaminecobalt(III) Complexes and Acid Hydrolysis Kinetics of fac‐(Codpt(H2O)nX3‐n)n+ (X: Cl, Br; n = 0, 1, 2).
Authors: MASSOUD S. S. , MILBURN R. M. 
Published: May 2016

AbstractThe title complexes (dpt: NH2‐(CH2)3‐NH‐(CH2)3‐NH2) are prepared by known methods and characterized by their electronic spectra.
ChemInform Abstract: Stereoselectivity in Reactions of Metal Complexes. Part 10. Kinetics and Stereoselectivity of the Inner‐Sphere Electron‐Transfer Reaction Between (Co(bamap)H2O)+ (bamap: 2,6‐Bis(3‐carboxy‐1,2‐dimethyl‐2‐azapropyl)pyridine) and Optically Active Iron(II) Complexes.
Authors: BERNAUER K. , POUSAZ P. , PORRET J. , JEANGUENAT A. 
Published: May 2016

AbstractThe kinetics of the electron‐transfer reaction between racemic or optically active (III) and optically active Fe(II) complexes of the three pentadentate ligands (I) and (II) are investigated.
ChemInform Abstract: Helicates: Tetra‐ and Pentanuclear Double Helix Complexes of Cu(I) and Poly(bipyridine) Strands.
Authors: LEHN J.‐M. , RIGAULT A. 
Published: May 2016

AbstractInorganic double helices having 2 and 2,5 turns are formed by the tetra‐ and penta(bipyridine) ligands (I) on addition of corresponding Cu(I) salts.
ChemInform Abstract: Platinum(II) Complexes with Aryl Tellurols and Diaryl Ditellurides: Syntheses and Spectral Investigations.
Authors: KHANDELWAL B. L. , KUNDU K. , GUPTA S. K. 
Published: May 2016

AbstractThe monomeric aryltellurolate complexes (IIIa) and (IIIb) are prepared by 1:1 and 1:2 molar reaction of the Pt complex (I) and the tellurolate salts (II).
ChemInform Abstract: EPC Syntheses from Bicyclic Dioxanones: (‐)‐5‐Epidehydrofukinone.
Authors: HERRADON B. 
Published: May 2016

AbstractThe starting material (II) can be obtained from the α,β‐unsaturated ketone (I) by highly stereoselective Michael addition of lithium dimethylcuprate and trapping of the resulting enolate with MeI.
ChemInform Abstract: Transformation of Labdanes into Drimanes: Obtention of 11,12‐Diacetoxy‐7‐drimene, Precursor of Biologically Active Drimanes.
Authors: URONES J. G. , MARCOS I. S. , DIEZ MARTIN D. 
Published: May 2016

AbstractUnder the conditions shown in the scheme the ester (I), isolated from Halimium viscosum, can be successfully transformed to the title compound (VII) which is obtained together with its Δ8‐isomer (18%).
ChemInform Abstract: β‐Mannosides from β‐Glucosides by Intramolecular Nucleophilic Substitution with Inversion of Configuration.
Authors: KUNZ H. , GUENTHER W. + 
Published: May 2016

AbstractThe epimerization at C‐2 of β‐glycosides, which is known to be a very difficult process, can be realized by intramolecular nucleophilic attack of a carbamate substituent as is shown for the sequence (VI) → (VIIIa).
ChemInform Abstract: Anthracyclines. Part 17. The Synthesis of 2‐Fluoro‐ and 3‐Fluoro‐4‐demethoxydaunomycin.
Authors: IRVINE R. W. , KINLOCH S. A. , MCCORMICK A. S. , RUSSELL R. A. , WARRENER R. N. 
Published: May 2016

AbstractThe aglycones (VIIIa) and (VIIIb) are synthesized starting from the ketone (I) as shown.
ChemInform Abstract: Crystal Chemistry of MX·MgX2·6 H2O Type Compounds.
Authors: EMONS H.‐H. , BRAND P. , POHL T. , KOEHNKE K. + 
Published: May 2016

AbstractPowder XRD data reveal that the compounds (Ia)‐(Ic) crystallize in the monoclinic space group C2/c and (II) in C2/m. A perovskite‐type structure is formed by corner‐sharing (M+)X6‐ octahedra.
ChemInform Abstract: Magnetism of Europium Clusters in the Intermetallic Compounds EuxSr1‐xMg5.2 and (EuxSr1‐x)3Mg13.
Authors: LUEKEN H. , BRAUERS T. , ERASSME J. , DEUSSEN M. , VON LOEHNEYSEN H. + , SCHROEDER A. + , WOSNITZA J. , SAUER C. 
Published: May 2016

AbstractThe magnetochemical properties of EuxSr1‐xMg5.2 (I) (x = 1, 0.33) with triangular heavy atom clusters and (EuxSr1‐x)3Mg13 (II) (x = 0.11, 0.22, and 0.46) with triangular and octahedral clusters are investigated by magnetic susceptibility and specific heat measurements and 151Eu Moessbauer spectroscopy.