bluuebunny/crossref_metadata_2025_split huggingface dataset:
33.5.10.2 1,4-Dihydrophosphinines and Derivatives (Update 2015)
Authors: Keglevich Gy. , Grün A. 
Published: November 2017

AbstractThis chapter is an update to the earlier Science of Synthesis contribution (Section 33.5.10) describing methods for the synthesis of 1,4-dihydrophosphinines. It focuses on the literature published in the period 2004–2015.
35.3.1.3.8 Synthesis by Substitution of Carbon Functionalities (Update 2015)
Authors: Elliott M. C. , Saleh B. A. 
Published: November 2017

AbstractThis chapter is an update to the earlier Science of Synthesis contribution (Section 35.3.1.3) describing methods for the synthesis of alkyl iodides from carboxylic acids and related compounds. It focuses on the literature published in the period 2005–2014.
35.3.1.5.7 Synthesis by Substitution of Oxygen Functionalities (Update 2015)
Authors: Singh F. V. , Wirth T. 
Published: November 2017

AbstractIodoalkanes are important synthetic intermediates in organic chemistry. These compounds undergo various reactions such as nucleophilic substitution, elimination, and metal-catalyzed C—C bond-forming reactions. This chapter describes various synthetic approaches available for the generation of C—I bonds from different oxygen functionalities and covers the literature published in the period 2007–2014.
35.3.1.8.7 Synthesis by Addition to π-Type C—C Bonds (Update 2015)
Authors: Hennecke U. 
Published: November 2017

AbstractThis chapter is an update to the earlier Science of Synthesis contribution (Section 35.3.1.8) describing methods for the synthesis of iodoalkanes by addition reactions to π-type C—C bonds (mostly alkenes). It focuses mainly on the literature published in the period 2007–2014.
3.12 General Aspects of Immobilized Biocatalysts and Their Applications in Flow
Authors: Bajić M. , Žnidaršič-Plazl P. , Kingston M. , Hessel V. 
Published: November 2017

AbstractThis chapter is a comprehensive review of methods for the immobilization of biocatalysts, namely enzymes and whole cells, in microflow reactors. Immobilization on microchannel surfaces, in monoliths, hydrogels, membranes, or other internal structures within microreactors are described. The characteristics of packed-bed and magnetic-field-assisted microreactors and two-liquid-phase flow systems with immobilized biocatalysts and some applications are presented.
2.1.5 Domino Transformations Initiated by or Proceeding Through [3,3]-Sigmatropic Rearrangements
Authors: Guerrero C. A. 
Published: November 2017

AbstractThis chapter concerns itself with domino transformations (i.e., cascade sequences and/or tandem reactions) that are either initiated by or proceed through at least one [3,3]-sigmatropic rearrangement. Excluded from this discussion are domino transformations that end with sigmatropy. The reactions included contain diverse forms of [3,3]-sigmatropic rearrangements and are followed by both polar chemistry or further concerted rearrangement.
2.2 Intermolecular Alkylative Dearomatizations of Phenolic Derivatives in Organic Synthesis
Authors: Porco Jr. J. A. , Boyce J. 
Published: November 2017

AbstractIntermolecular alkylative dearomatization products have shown promise as synthetic intermediates with diverse capabilities. This chapter describes the available methods for constructing these dearomatized molecules and demonstrates their value as synthetic intermediates for efficient total syntheses.
2.1 Epoxidation and Aziridination Reactions
Authors: Xia F. , Ye S. 
Published: November 2017

AbstractDue to the strain associated with three-membered rings, epoxides and aziridines react with various nucleophiles to give 1,2-difunctionalized products. This makes them valuable intermediates in organic synthesis, including in the synthesis of bioactive natural and nonnatural compounds. This chapter summarizes recent advances in metal-catalyzed epoxidation and aziridination reactions of alkenes, as well as their synthetic applications.
2.3 Pauson–Khand Reactions
Authors: Dominguez G. , Pérez Castells J. 
Published: November 2017

AbstractThe Pauson–Khand (2 + 2 + 1) cycloaddition (PKR) is one of the best ways to construct a cyclopentenone. In this review, standard procedures to perform both stoichiometric and catalytic Pauson–Khand reactions are presented. These include the use of homo- and heterogeneous catalysts as well as different promoters. Asymmetric versions are described, as are cascade processes where the Pauson–Khand reaction is combined with other transformations. The chapter ends with a summary of representative total syntheses of natural products where a Pauson–Khand reaction is used as the key step.
2.7 Metal-Catalyzed (4 + 3) Cycloadditions Involving Allylic Cations
Authors: Jones D. E. , Harmata M. 
Published: November 2017

AbstractThe (4 + 3)-cycloaddition reaction is a reaction between an allylic cation and diene. It is a powerful process and one of the few reactions that directly generates seven-membered ring systems. This reaction exhibits high levels of diastereoselectivity and regioselectivity, which makes it attractive for the rapid construction of complex targets. Several select, reliable, and reproducible methods for the generation and capture of allylic cations by 1,3-dienes using metal catalysis or mediation are presented in this review along with some representative examples of the use of (4 + 3) cycloadditions in the synthesis of natural products.
Offering fleet automation: SmartFleet in the need of Smart Decisions
Authors: Agrawal Anand , Mehta Anupam , Abraham Nishant 
Published: November 2017

In late September 2014, after reviewing the revised financial projection of their new venture, Maui Millan, the CEO and the head of product development, and Mannix Chong, the COO and the head of business development were alarmed. They planned to call their board of advisors to discuss the future of SmartFleet, the new product of the Philippines-based firm called Pahrsek Inc. SmartFleet is a cloud-based fleet management tool that provides enterprise resource planning capability to fleet vehicle operators. For Maui and Mannix, there were numerous challenges ranging from developing a pricing strategy, growing the market as a pioneer in this industry in the Philippines, to proactively managing the potential global competitors who were on the verge of the Philippines market. They were anxious because they knew that only a set of careful, well-thought out and smart decisions could ensure survival and sustainability of this new venture.
What’s in the brain that ink may character ….
Authors: Jacobs Arthur M. , Schuster Sarah , Xue Shuwei , Lüdtke Jana 
Published: November 2017

AbstractIn this theoretical paper, we would like to pave the ground for future empirical studies in Neurocognitive Poetics by describing relevant properties ofShakespeare’s 154 sonnetsextracted via Quantitative Narrative Analysis. In the first two parts, we quantify aspects of the sonnets’ cognitive and affective-aesthetic features, as well as indices of their thematic richness, symbolic imagery, and semantic association potential. In the final part, we first demonstrate how the results of these quantitative narrative analyses can be used for generating testable predictions for empirical studies of literature. Second, we feed the quantitative narrative analysis data into a machine learning algorithm which successfully classifies the 154 sonnets into two main categories, i.e. theyoung mananddark ladypoems. This shows how quantitative narrative analysis data can be combined with computational modeling for identifying those of the many quantifiable sonnet features that may play a key role in their reception.
Perceptual qualities of literary style
Authors: Siefkes Martin 
Published: November 2017

AbstractThis article reports the results of a study that investigated different aspects of the aesthetic perception of literary style. Excerpts from novels belonging to two broadly defined literary style categories, namely modern and postmodern style, were judged by the participants. Semantic scales corresponding to perceptual qualities of modern and postmodern literature were used. The results indicate that these scales can measure perceptual differences between the selected novels, and that the two novels categorized as modern were experienced differently from those categorized as postmodern. Some of the scales also predicted aesthetic preference for novels. Rating differences on the two scalesincoherent – coherentandformal – colloquialpredicted the ability to attribute novel excerpts. This finding seems to indicate that the ability to distinguish styles in regard to perceptual qualities helps readers to judge certain similarities of novels.
Lexical variation, register and explicitation in medical translation
Authors: Jiménez-Crespo Miguel Ángel , Tercedor Sánchez Maribel 
Published: November 2017

AbstractDifferences in register, lexical use, syntactic shifts or determinologization strategies between source and target medical texts can produce usability or comprehensibility issues (Askehave and Zethsen 2000a;Tercedor and López 2012;Nisbeth Zethsen and Jensen 2012;Alarcón, López-Rodríguez, and Tercedor 2016). This study analyzes differences in lexical variation between translated and non-translated online medical texts resulting in potential register shifts, also known as “register mismatches” (Pilegaard 1997). The study uses a corpus methodology to compare (1) the frequency of Latin-Greek (LG) terms in translated medical websites in the USA and in similar non-translated texts in Spain and Latin America, and (2) the frequency of determinologization and explicitation of LG terms in both textual populations. The results show that US medical websites translated into Spanish show lower frequencies of LG terms and higher frequencies of reformulation strategies than similar non-translated ones; they are partly explained through the process of interference from source texts.
Professional interpreters’ job satisfaction and relevant factors
Authors: Lee Jieun 
Published: November 2017

AbstractA study of the job satisfaction of professional interpreters may cast light on the current state of the profession and its prospects. Through a questionnaire-based survey of 150 professional interpreters in South Korea, this study examines various factors contributing to the job satisfaction of professional interpreters, including individual characteristics and job characteristics. Statistically significant correlations were confirmed between job satisfaction and marital status, the length of the interpreting career, average weekly working hours, and the dominant employment type of the respondents. While the respondents overwhelmingly chose income as the most important factor that determines their satisfaction, a multiple regression analysis revealed that job security was the most important factor, which was in turn strongly correlated with social recognition. This case study provides an analysis of the status quo of the profession in South Korea and has implications for the industry and for interpreter training.
Flaubert’s Parrot
Authors: Pralas Jelena , Kusovac Olivera 
Published: November 2017

AbstractThe strict boundaries between disciplines have been seriously challenged by various links established between them through cross-fertilization. Links between literary and translation studies are not new. However, in the (post)-modern world, when interdisciplinarity is starting to give way to transdisciplinarity, a new meeting point has been found in transfiction, enabling translation to become an interpretative paradigm for literature. Attempting to support this rather neglected approach, this paper analyzes Julian Barnes’sFlaubert’s Parrotin the light of the relationship between source and target texts and the concept of the invariant as a reflection of the postmodern quest for truth, claiming that the novel makes a fictional dethronement of the source text and calls for a shift from instrumentalism to the hermeneutic approach in translation.
Optimization of Energy Efficiency and Conservation in Green Building Design Using Duelist, Killer-Whale and Rain-Water Algorithms
Authors: Biyanto T R , Matradji  , Syamsi M N , Fibrianto H Y , Afdanny N , Rahman A H , Gunawan K S , Pratama J A D , Malwindasari A , Abdillah A I , Bethiana T N , Putra Y A 
Published: November 2017

Abstract
The development of green building has been growing in both design and quality. The development of green building was limited by the issue of expensive investment. Actually, green building can reduce the energy usage inside the building especially in utilization of cooling system. External load plays major role in reducing the usage of cooling system. External load is affected by type of wall sheathing, glass and roof. The proper selection of wall, type of glass and roof material are very important to reduce external load. Hence, the optimization of energy efficiency and conservation in green building design is required. Since this optimization consist of integer and non-linear equations, this problem falls into Mixed-Integer-Non-Linear-Programming (MINLP) that required global optimization technique such as stochastic optimization algorithms. In this paper the optimized variables i.e. type of glass and roof were chosen using Duelist, Killer-Whale and Rain-Water Algorithms to obtain the optimum energy and considering the minimal investment. The optimization results exhibited the single glass Planibel-G with the 3.2 mm thickness and glass wool insulation provided maximum ROI of 36.8486%, EUI reduction of 54 kWh/m2·year, CO2 emission reduction of 486.8971 tons/year and reduce investment of 4,078,905,465 IDR.
SPECTRE: a suite of phylogenetic tools for reticulate evolution
Authors: Bastkowski Sarah , Mapleson Daniel , Spillner Andreas , Wu Taoyang , Balvočiūtė Monika , Moulton Vincent 
Published: November 2017

Abstract

Summary
Split-networks are a generalization of phylogenetic trees that have proven to be a powerful tool in phylogenetics. Various ways have been developed for computing such networks, including split-decomposition, NeighborNet, QNet and FlatNJ. Some of these approaches are implemented in the user-friendly SplitsTree software package. However, to give the user the option to adjust and extend these approaches and to facilitate their integration into analysis pipelines, there is a need for robust, open-source implementations of associated data structures and algorithms. Here, we present SPECTRE, a readily available, open-source library of data structures written in Java, that comes complete with new implementations of several pre-published algorithms and a basic interactive graphical interface for visualizing planar split networks. SPECTRE also supports the use of longer running algorithms by providing command line interfaces, which can be executed on servers or in High Performance Computing environments.

Availability and implementation
Full source code is available under the GPLv3 license at: https://github.com/maplesond/SPECTRE. SPECTRE’s core library is available from Maven Central at: https://mvnrepository.com/artifact/uk.ac.uea.cmp.spectre/core. Documentation is available at: http://spectre-suite-of-phylogenetic-tools-for-reticulate-evolution.readthedocs.io/en/latest/

Supplementary information
Supplementary data are available at Bioinformatics online.
Victor Hugo and the Melancholy Novel: Reading the Haitian Revolution in
Bug-Jargal
Authors: Bongie Chris 
Published: November 2017

Abstract

In the two decades following the Haitian Declaration of Independence in 1804, a wide array of French writers from across the political spectrum returned, with obsessive frequency, to the subject of Saint-Domingue/Haiti in an attempt to grapple with the effects of ‘traumatic’ loss through discursive revisitings of the forever lost imperial object. Reflecting on the (largely disavowed) centrality of Haiti to an understanding of Romantic-era French cultural production, this article situates Victor Hugo’s 1826 novel about the Haitian Revolution,
Bug-Jargal
, as the culminating expression of those melancholic narratives lamenting the loss of France’s precious ‘pearl of the Antilles’. It does so, specifically, by discussing the plagiaristic relation of key passages in Hugo’s novel to a hitherto unidentified source, Philippe-Albert de Lattre’s
Campagnes des Français à Saint-Domingue
(1805). The youthful Hugo’s word-for-word reliance on this earlier account of the Haitian Revolution can, to be sure, simply be written off as yet another piece of evidence for the artistic ‘immaturity’ of
Bug-Jargal
. A very different argument will be mounted here, however: this mimetic reliance of Hugo’s novel on a text that mourns the loss of Saint-Domingue, denies the legitimacy of Haitian independence, and consolidates the hierarchies of racial science, needs to be read as exemplifying — in its purest, most ‘mature’ form — a collective practice of retelling colonial stories that is characteristic of what Paul Gilroy has dubbed ‘postimperial melancholia’, and that is arguably one of the constitutive features of the literary habitus in Restoration France.
Compaction trends of full stiffness tensor and fluid permeability in artificial shales
Authors: Beloborodov Roman , Pervukhina Marina , Lebedev Maxim 
Published: November 2017

SummaryWe present a methodology and describe a set-up that allows simultaneous acquisition of all five elastic coefficients of a transversely isotropic (TI) medium and its permeability in the direction parallel to the symmetry axis during mechanical compaction experiments. We apply the approach to synthetic shale samples and investigate the role of composition and applied stress on their elastic and transport properties. Compaction trends for the five elastic coefficients that fully characterize TI anisotropy of artificial shales are obtained for a porosity range from 40 per cent to 15 per cent. A linear increase of elastic coefficients with decreasing porosity is observed. The permeability acquired with the pressure-oscillation technique exhibits exponential decrease with decreasing porosity. Strong correlations are observed between an axial fluid permeability and seismic attributes, namely, VP/VS ratio and acoustic impedance, measured in the same direction. These correlations might be used to derive permeability of shales from seismic data given that their mineralogical composition is known.
Factors influencing women in physical activity programs in Malaysia
Authors: Hanlon C , Khoo S , Morris T , Eime R 
Published: November 2017

Summary
The majority of research on factors associated with women participation in physical activity (PA) has been in developed countries with limited research in developing countries. Few women in Malaysia are active at the recommended levels for health, and activity rates are less than developed countries. Little research has focused specially on physically active Malaysian women and the factors that contribute to them becoming and staying active in PA programs. This lack of knowledge hinders the tailored development and implementation of PA programs to meet their needs. The aim of this study was to identify the factors of participation in PA programs for Malaysian women. The social–ecological model was used to investigate and theme the factors. Focus group discussion was conducted with participants in six PA programs targeted specifically to women. Thirty-seven women were involved in the focus group discussion, with ages ranging from 19 to 82 years. Inductive and deductive content analysis was conducted from verbatim transcripts using NVivo. Inductive content analysis allowed raw data and second-order themes to emerge. Findings revealed social support structures, tailored programs for women, and location were key contributors that encouraged women to participate in these programs. The similarity in contributors between women in non-western and western countries signifies a prime opportunity for bi-lateral relationships to be formed to enable the enhancement of program development relevant to different ethnicities and cultures within or across countries.
Britain Breathing: using the experience sampling method to collect the
seasonal allergy symptoms of a country
Authors: Vigo Markel , Hassan Lamiece , Vance William , Jay Caroline , Brass Andrew , Cruickshank Sheena 
Published: November 2017

Abstract

Objective
Allergies are increasing, but the reasons for this are unclear. Although environmental factors are thought to be important, there is a lack of data on how they contribute to symptom development. To understand this relationship better, we need accurate data about both symptoms and environmental factors. Our objective here is to ascertain whether experience sampling is a reliable approach for collecting allergy symptom data in the general population, allowing us to map symptoms and understand etiology.

Materials and Methods
We conducted a 32-week cross-sectional study where individuals reported their seasonal allergy symptoms and severity via a mobile application. Symptom geographical location and timestamp were also collected automatically.

Results
The experience sampling method reliably infers the incidence of seasonal allergies as indicated by the strong correlation (r = 0.93, P &lt; .003) between the reported lack of wellness and the number of antihistamines prescribed by General Practitioners.

Discussion and Conclusion
The project has resulted in the first dataset to map allergy symptoms over time and place and reveals periods of peak hay fever symptoms in the UK.
Late Presentation for Care Among Patients With Chronic Hepatitis C: Prevalence and Risk Factors
Authors: Hansen Janne Fuglsang , Hallager Sofie , Øvrehus Anne , Weis Nina , Brehm Christensen Peer , Pedersen Court 
Published: November 2017

Abstract
Patients with chronic hepatitis C may have advanced fibrosis at first evaluation. Using the European Association for the Study of the Liver (EASL) definition (FibroScan® &gt;9.5 kPa) for “late presenter for care” (LP), we found that 32% (169 of 527) of patients were LP. Being a LP was associated with increasing age and a history of alcohol overuse.
From pioneer to repressor: Bimodal foxd3 activity dynamically remodels neural crest regulatory landscapein vivo
Authors: Gavriouchkina Daria , Williams Ruth M , Lukoseviciute Martyna , Hochgreb-Hägele Tatiana , Senanayake Upeka , Chong-Morrison Vanessa , Thongjuea Supat , Repapi Emmanouela , Mead Adam , Sauka-Spengler Tatjana 
Published: November 2017

AbstractThe neural crest (NC) is a transient embryonic stem cell population characterised by its multipotency and broad developmental potential. Here, we perform NC-specific transcriptional and epigenomic profiling offoxd3-mutant versus wild type cellsin vivoto define the gene regulatory circuits controlling NC specification. Together with global binding analysis obtained by foxd3 biotin-ChIP and single cell profiles offoxd3-expressing premigratory NC, our analysis shows that during early steps of NC formation, foxd3 acts globally as a pioneer factor to prime the onset of genes regulating NC specification and migration by re-arranging the chromatin landscape, openingcis-regulatory elements and reshuffing nucleosomes. Strikingly, foxd3 then switches from an activator to its canonical role as a transcriptional repressor. Taken together, these results demonstrate that foxd3 acts bimodally in the neural crest as a switch from permissive to repressive nucleosome/chromatin organisation to maintain stemness and define cell fates.