bluuebunny/crossref_metadata_2025_split huggingface dataset:
Analytical Expressions for Thermo‐Osmotic Permeability of Clays
Authors: Gonçalvès J. , Ji Yu C. , Matray J.‐M. , Tremosa J. 
Published: January 2018

AbstractIn this study, a new formulation for the thermo‐osmotic permeability of natural pore solutions containing monovalent and divalent cations is proposed. The mathematical formulation proposed here is based on the theoretical framework supporting thermo‐osmosis which relies on water structure alteration in the pore space of surface‐charged materials caused by solid‐fluid electrochemical interactions. The ionic content balancing the surface charge of clay minerals causes a disruption in the hydrogen bond network when more structured water is present at the clay surface. Analytical expressions based on our heuristic model are proposed and compared to the available data for NaCl solutions. It is shown that the introduction of divalent cations reduces the thermo‐osmotic permeability by one third compared to the monovalent case. The analytical expressions provided here can be used to advantage for safety calculations in deep underground nuclear waste repositories.
Low‐Frequency Variability and the Unusual Indian Ocean Dipole Events in 2015 and 2016
Authors: Zhang Lianyi , Du Yan , Cai Wenju 
Published: January 2018

AbstractAn unusual positive Indian Ocean Dipole (IOD) event occurred in 2015 associated with the 2015/2016 extreme El Niño. Unlike the canonical IOD, sea surface temperature (SST) warming in the west central tropical Indian Ocean (TIO) dominated the strong zonal SST gradient as cooling off Sumatra‐Java was weak. Over the southeastern TIO, deeper thermocline has suppressed the upwelling cooling since 2012. Such deepened thermocline related to a low‐frequency adjustment and curtailed cool anomalies in the 2015 positive IOD but favored warm anomalies in the 2016 negative IOD. Based on statistical analyses, ocean assimilation data confirm that an IOD‐like pattern exists in the TIO on decadal timescale. During a negative decadal IOD‐like phase, thermocline is deeper in the southeastern TIO; the thermocline‐SST feedback is unfavorable for positive IOD occurrence and intensity, but conducive to negative IOD events. Thus, we propose that the 2015–2016 IOD events are modulated by the low‐frequency variability of thermocline.
Alfvénic Dynamics and Fine Structuring of Discrete Auroral Arcs: Swarm and e‐POP Observations
Authors: Miles D. M. , Mann I. R. , Pakhotin I. P. , Burchill J. K. , Howarth A. D. , Knudsen D. J. , Lysak R. L. , Wallis D. D. , Cogger L. L. , Yau A. W. 
Published: January 2018

AbstractThe electrodynamics associated with dual discrete arc aurora with antiparallel flow along the arcs were observed nearly simultaneously by the enhanced Polar Outflow Probe (e‐POP) and the Swarm A and C spacecraft. Auroral imaging from e‐POP reveals 1–10 km structuring of the arcs, which move and evolve on second timescales and confound the traditional single‐spacecraft field‐aligned current algorithms. High‐cadence magnetic data from e‐POP show 1–10 Hz, inferred Alfvénic, perturbations coincident with and at the same scale size as the observed dynamic auroral fine structures. High‐cadence electric and magnetic field data from Swarm A reveal nonstationary electrodynamics involving reflected and interfering Alfvén waves and modulation consistent with trapping in the ionospheric Alfvén resonator (IAR). These observations suggest a role for Alfvén waves, perhaps also the IAR, in discrete arc dynamics on 0.2–10 s timescales and ~1–10 km spatial scales and reinforce the importance of considering Alfvén waves in magnetosphere‐ionosphere coupling.
Meridional Modes and Increasing Pacific Decadal Variability Under Anthropogenic Forcing
Authors: Liguori Giovanni , Di Lorenzo Emanuele 
Published: January 2018

AbstractPacific decadal variability has strong impacts on the statistics of weather, atmosphere extremes, droughts, hurricanes, marine heatwaves, and marine ecosystems. Sea surface temperature (SST) observations show that the variance of the El Niño‐like decadal variability has increased by ~30% (1920–2015) with a stronger coupling between the major Pacific climate modes. Although we cannot attribute these trends to global climate change, the examination of 30 members of the Community Earth System Model Large Ensemble (LENS) forced with the RCP8.5 radiative forcing scenario (1920–2100) suggests that significant anthropogenic trends in Pacific decadal variance will emerge by 2020 in response to a more energetic North Pacific Meridional Mode (PMM)—a well‐known El Niño precursor. The PMM is a key mechanism for energizing and coupling tropical and extratropical decadal variability. In the LENS, the increase in PMM variance is consistent with an intensification of the winds‐evaporation‐SST thermodynamic feedback that results from a warmer mean climate.
Statistically Self‐Consistent and Accurate Errors for SuperDARN Data
Authors: Reimer A. S. , Hussey G. C. , McWilliams K. A. 
Published: January 2018

AbstractThe Super Dual Auroral Radar Network (SuperDARN)‐fitted data products (e.g., spectral width and velocity) are produced using weighted least squares fitting. We present a new First‐Principles Fitting Methodology (FPFM) that utilizes the first‐principles approach of Reimer et al. (2016) to estimate the variance of the real and imaginary components of the mean autocorrelation functions (ACFs) lags. SuperDARN ACFs fitted by the FPFM do not use ad hoc or empirical criteria. Currently, the weighting used to fit the ACF lags is derived from ad hoc estimates of the ACF lag variance. Additionally, an overcautious lag filtering criterion is used that sometimes discards data that contains useful information. In low signal‐to‐noise (SNR) and/or low signal‐to‐clutter regimes the ad hoc variance and empirical criterion lead to underestimated errors for the fitted parameter because the relative contributions of signal, noise, and clutter to the ACF variance is not taken into consideration. The FPFM variance expressions include contributions of signal, noise, and clutter. The clutter is estimated using the maximal power‐based self‐clutter estimator derived by Reimer and Hussey (2015). The FPFM was successfully implemented and tested using synthetic ACFs generated with the radar data simulator of Ribeiro, Ponomarenko, et al. (2013). The fitted parameters and the fitted‐parameter errors produced by the FPFM are compared with the current SuperDARN fitting software, FITACF. Using self‐consistent statistical analysis, the FPFM produces reliable or trustworthy quantitative measures of the errors of the fitted parameters. For an SNR in excess of 3 dB and velocity error below 100 m/s, the FPFM produces 52% more data points than FITACF.
Tectonic Regimes of the Central and Southern Andes: Responses to Variations in Plate Coupling During Subduction
Authors: Horton Brian K. 
Published: January 2018

AbstractConstruction of the Andes has been governed largely by fluctuating contractional, neutral, and extensional tectonic regimes during differing degrees of mechanical coupling along the convergent plate boundary. These three contrasting regimes are likely regulated by geodynamic variations in absolute trenchward motion of South America and episodic regional shifts in the geometry of the subducting oceanic slab. Alternations among these three modes are revealed in syntheses of Mesozoic‐Cenozoic crustal deformation, basin evolution, and arc magmatism along orogen‐perpendicular transects across the central and southern Andes at 23°S, 35°S, and 43°S. Despite considerable along‐strike dissimilarities in the magnitude of deformation, a comparable tectonic regime typified the early Andean history, as defined by a transition from Late Jurassic‐Early Cretaceous postrift thermal subsidence to Late Cretaceous retroarc shortening. A key contradiction is expressed for the late middle Eocene to earliest Miocene, when neutral to extensional conditions affected retroarc to forearc regions, except in parts of the central Andes, which experienced retroarc shortening with only localized forearc extension. This mixed‐mode scenario during Paleogene time may reflect decoupling along the plate boundary (possibly during slab rollback within a retreating subduction system) in which widespread stasis or low‐magnitude extension dominated the southern Andes but was inhibited in the strongly shortened central Andes at 15–25°S where shallow subduction and/or high topography boosted plate coupling. Comparable temporal and spatial shifts in tectonic regime along the Andes and other convergent margins can be related to variable degrees of coupling during first‐order plate‐scale changes in convergence and second‐order regional cycles of slab shallowing and steepening.
Preserved Neoproterozoic Continental Collision in Southeastern North America: The Brunswick Suture Zone and Osceola Continental Margin Arc
Authors: Boote Susannah K. , Knapp James H. , Mueller Paul A. 
Published: January 2018

AbstractA series of exotic terranes were accreted to the eastern margin of southeastern Laurentia beginning in the Siluro‐Devonian (Acadian event), and to the northeastern Laurentian margin beginning earlier (late Taconian). Many of these terranes have unclear tectonostratigraphic relationships to each other and to their parental cratons, but their accretionary history is critical to understanding the evolution of the Appalachian orogen. Two of these, the Gondwanan Suwannee and Charleston terranes, accreted during the Alleghanian orogeny and now lie beneath the Atlantic Coastal Plain in southeastern North America. Reanalysis of deep seismic reflection and well data reveals a preserved Neoproterozoic continental collision zone and associated continental margin arc, the Osceola arc, related to their juxtaposition. The subduction zone and associated strain are recorded in the newly termed Brunswick suture zone (BSZ). The BSZ is readily identified on a series of eight deep seismic reflection transects across the Brunswick Magnetic Anomaly (BMA), which we interpret as the boundary between the Charleston and Suwannee terranes. While originally interpreted to be the Late Paleozoic Alleghanian suture, new age constraints provided by the overlapping Gondwanan Paleozoic Suwannee Basin strata require the BSZ to predate the Early to Middle Paleozoic passive margin sequence of the Suwannee Basin. These results provide new insights into the tectonostratigraphic evolution of the Charleston and Suwannee terranes, the controversy surrounding the age and origin of the dipping seismic reflectors, previously attributed to the suturing of the Suwannee terrane to Laurentia, and the relationship of this suture zone to the origin of the BMA.
Strain Localization Within a Syntectonic Intrusion in a Back‐Arc Extensional Context: The Naxos Monzogranite (Greece)
Authors: Bessiere Eloïse , Rabillard Aurelien , Précigout Jacques , Arbaret Laurent , Jolivet Laurent , Augier Romain , Menant Armel , Mansard Nicolas 
Published: January 2018

AbstractAlthough fundamental to the understanding of crustal dynamics in extensional setting, the relationships between the emplacement of granitic intrusions and activity of detachments still remain very elusive. Through a multiscale approach, we here document a continuous deformation history between the monzogranitic intrusion of Naxos and the Naxos‐Paros Detachment System (Cyclades, Greece). Field observations first show an early magmatic deformation followed by solid‐state, ductile, and then brittle deformation when approaching the detachment zone, as evidenced by the overprinting of mylonites by cataclastes and pseudotachylites. From these observations, we define six strain facies that characterize a positive strain gradient from core to rim of the Naxos monzogranite. Based on field pictures, X‐ray tomography, and electron backscatter diffraction (EBSD) analyses along the strain gradient, we then quantify the intensity of mineralogical fabrics in 2‐D and 3‐D and better characterize the deformation mechanisms. Our measured shape variations of the strain ellipsoid corroborate the large‐scale strain gradient, showing a good correlation between qualitative and quantitative studies. In addition, EBSD data indicate that dislocation creep was predominant during cooling from more than 500°C to temperature conditions of the ductile‐to‐brittle transition. However, (1) a weakening of quartz lattice preferred orientation with increasing strain and (2) evidence of numerous four‐grain junctions in high‐strain shear bands also indicate that grain boundary sliding significantly contributed to the deformation. Although the source of grain boundary sliding remains to be constrained, it provides a consistent approach to account for strain localization in Naxos.
The T‐TEL Method for Assessing Water, Sediment, and Chemical Connectivity
Authors: Ali Genevieve , Oswald Claire , Spence Christopher , Wellen Christopher 
Published: January 2018

AbstractThe concept of connectivity has been the subject of a great deal of recent research and provided new insights and breakthroughs on runoff generation processes and watershed biogeochemistry. However, a consensus definition and cohesive mathematical framework that would permit the consistent quantification of hydrologic connectivity, the examination of the interrelationships between water and material (e.g., sediment and chemicals) connectivity, or rigorous study intercomparison, have not been presented by the water resource community. Building on previous conceptualizations and site‐specific or process‐specific metrics, this paper aimed to review the current state of science on hydrologic connectivity and its role in water‐mediated connectivity of material such as solutes and sediment before introducing a conceptual and a mathematical connectivity assessment framework. These frameworks rely on the quantification of Time scales, Thresholds, Excesses and Losses related to water and water‐mediated material transport dynamics and are referred to as the T‐TEL method. Through a small case study, we show how the T‐TEL method allows a wide range of properties to be quantified, namely the occurrence, frequency, duration, magnitude, and spatial extent of water and water‐mediated material connectivity. We also propose a research agenda to refine the T‐TEL method and ensure its usefulness for facilitating the research and management of connectivity in pristine and human‐impacted landscapes.
Accounting for the Decreasing Reaction Potential of Heterogeneous Aquifers in a Stochastic Framework of Aquifer‐Scale Reactive Transport
Authors: Loschko Matthias , Wöhling Thomas , Rudolph David L. , Cirpka Olaf A. 
Published: January 2018

AbstractMany groundwater contaminants react with components of the aquifer matrix, causing a depletion of the aquifer's reactivity with time. We discuss conceptual simplifications of reactive transport that allow the implementation of a decreasing reaction potential in reactive‐transport simulations in chemically and hydraulically heterogeneous aquifers without relying on a fully explicit description. We replace spatial coordinates by travel‐times and use the concept of relative reactivity, which represents the reaction‐partner supply from the matrix relative to a reference. Microorganisms facilitating the reactions are not explicitly modeled. Solute mixing is neglected. Streamlines, obtained by particle tracking, are discretized in travel‐time increments with variable content of reaction partners in the matrix. As exemplary reactive system, we consider aerobic respiration and denitrification with simplified reaction equations: Dissolved oxygen undergoes conditional zero‐order decay, nitrate follows first‐order decay, which is inhibited in the presence of dissolved oxygen. Both reactions deplete the bioavailable organic carbon of the matrix, which in turn determines the relative reactivity. These simplifications reduce the computational effort, facilitating stochastic simulations of reactive transport on the aquifer scale. In a one‐dimensional test case with a more detailed description of the reactions, we derive a potential relationship between the bioavailable organic‐carbon content and the relative reactivity. In a three‐dimensional steady‐state test case, we use the simplified model to calculate the decreasing denitrification potential of an artificial aquifer over 200 years in an ensemble of 200 members. We demonstrate that the uncertainty in predicting the nitrate breakthrough in a heterogeneous aquifer decreases with increasing scale of observation.
Unraveling the Hydrology of the Glacierized Kaidu Basin by Integrating Multisource Data in the Tianshan Mountains, Northwestern China
Authors: Shen Yan‐Jun , Shen Yanjun , Fink Manfred , Kralisch Sven , Brenning Alexander 
Published: January 2018

AbstractUnderstanding the water balance, especially as it relates to the distribution of runoff components, is crucial for water resource management and coping with the impacts of climate change. However, hydrological processes are poorly known in mountainous regions due to data scarcity and the complex dynamics of snow and glaciers. This study aims to provide a quantitative comparison of gridded precipitation products in the Tianshan Mountains, located in Central Asia and in order to further understand the mountain hydrology and distribution of runoff components in the glacierized Kaidu Basin. We found that gridded precipitation products are affected by inconsistent biases based on a spatiotemporal comparison with the nearest weather stations and should be evaluated with caution before using them as boundary conditions in hydrological modeling. Although uncertainties remain in this data‐scarce basin, driven by field survey data and bias‐corrected gridded data sets (ERA‐Interim and APHRODITE), the water balance and distribution of runoff components can be plausibly quantified based on the distributed hydrological model (J2000). We further examined parameter sensitivity and uncertainty with respect to both simulated streamflow and different runoff components based on an ensemble of simulations. This study demonstrated the possibility of integrating gridded products in hydrological modeling. The methodology used can be important for model applications and design in other data‐scarce mountainous regions. The model‐based simulation quantified the water balance and how the water resources are partitioned throughout the year in Tianshan Mountain basins, although the uncertainties present in this study result in important limitations.
Biomimetic and Superwettable Nanofibrous Skins for Highly Efficient Separation of Oil‐in‐Water Emulsions
Authors: Ge Jianlong , Zong Dingding , Jin Qing , Yu Jianyong , Ding Bin 
Published: January 2018

AbstractDeveloping a feasible and efficient separation membrane for the purification of highly emulsified oily wastewater is of significance but challenging due to the critical limitations of low flux and serious membrane fouling. Herein, a biomimetic and superwettable nanofibrous skin on an electrospun fibrous membrane via a facile strategy of synchronous electrospraying and electrospinning is created. The obtained nanofibrous skin possesses a lotus‐leaf‐like micro/nanostructured surface with intriguing superhydrophilicity and underwater superoleophobicity, which are due to the synergistic effect of the hierarchical roughness and hydrophilic polymeric matrix. The ultrathin, high porosity, sub‐micrometer porous skin layer results in the composite nanofibrous membranes exhibiting superior performances for separating both highly emulsified surfactant‐free and surfactant‐stabilized oil‐in‐water emulsions. An ultrahigh permeation flux of up to 5152 L m−2 h−1 with a separation efficiency of >99.93% is obtained solely under the driving of gravity (≈1 kPa), which was one order of magnitude higher than that of conventional filtration membranes with similar separation properties, showing significant applicability for energy‐saving filtration. Moreover, with the advantage of an excellent antioil fouling property, the membrane exhibits robust reusability for long‐term separation, which is promising for large‐scale oily wastewater remediation.
High‐Performance Hazy Silver Nanowire Transparent Electrodes through Diameter Tailoring for Semitransparent Photovoltaics
Authors: Fang Yunsheng , Wu Zhicong , Li Jia , Jiang Fangyuan , Zhang Kui , Zhang Yanli , Zhou Yinhua , Zhou Jun , Hu Bin 
Published: January 2018

AbstractSolution‐processed metal nanowire networks have attracted substantial attention as clear transparent conductive electrodes (TCEs) to replace metal oxides for low‐cost and flexible touch panels and displays. While targeting photovoltaic applications, TCEs are expected to be more hazy for enhancing light absorption in the active layer, but are still required to retain high transmittance and low sheet resistance. Balancing these properties (haze, transmittance, and conductivity) in TCEs to realize high performance but high haze simultaneously is a challenge because they are mutually influenced. Here, by precisely tailoring the diameter of thick–long silver nanowires using rapid radial electrochemical etching, high hazy flexible TCEs are fabricated with high figure of merit of up to 741 (4 Ω sq−1 at 88.4% transmittance with haze of 13.3%), surpassing those of commercialized brittle hazy metal oxides and exhibiting superiority for photovoltaic applications. Laminating such TCEs onto the perovskite solar cells as top electrodes, the obtained semitransparent devices exhibit power efficiencies up to 16.03% and 11.12% when illuminated from the bottom and top sides, respectively, outperforming reported results based on similar device architecture. This study provides a simple strategy for flexible and hazy TCEs fabrication, which is compatible with mild solution‐processed photovoltaic devices, especially those containing heat‐sensitive or chemical‐sensitive materials.
Copper Iodide Based Hybrid Phosphors for Energy‐Efficient General Lighting Technologies
Authors: Liu Wei , Fang Yang , Li Jing 
Published: January 2018

AbstractSolid‐state‐lighting (SSL) is a new lighting technology that is rapidly replacing conventional lighting sources because it is much more energy efficient, longer lasting, and contributes significantly to environmental protection. A main branch of SSL technology is light‐emitting diodes (LEDs), and white‐light LEDs (WLEDs) are in the greatest demand for general lighting and illumination applications. Current WLED devices rely heavily on rare‐earth elements (REEs), which will likely suffer from cost and supply risks and environmental consequences in the near future. Crystalline inorganic–organic hybrid materials based on I–VII binary semiconductors represent a promising material class as REE‐free phosphor alternatives. This article provides a brief overview of recent advancement on this material family, with a focus on the rational design, energy‐efficient and low‐cost synthesis, systematic modification, and optimization of their electronic, optical, and thermal properties. A particular emphasis will be made on our own progress over the past several years in developing four classes of CuI(L) structures with substantially improved performance as energy‐saving lighting phosphors. General strategies for structural design, synthesis, and property optimization of these materials will also be discussed.