bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Preparation of Styryl Benzyl Sulfones and 1,2‐Bis(styrylsulfonylmethyl)‐4,5‐dimethylbenzenes.
Authors: REDDY D. B. , REDDY N. S. , REDDY S. , REDDY M. V. R. , BALASUBRAMANYAM S. 
Published: May 2016

AbstractCoupling of the benzyl chlorides (I) with thioglycolic acid (II) yields the benzylthioacetic acids (III) which are oxidized to give the sulfones (IV).
ChemInform Abstract: Preparation and Pharmacological Activity of 2‐(4′R′‐Phenyl)‐5R‐benzimidazoles and 2‐(4′‐Pyridinyl)‐5R‐benzimidazoles. Analgesic Activity and Effect on Conditioned Avoidance Response.
Authors: PAGLIETTI G. , PIRISI M. A. , LORIGA M. , GRELLA G. E. , SPARATORE F. , SATTA M. , MANCA P. 
Published: May 2016

AbstractThe o‐phenylenediamines (I) undergo ring closure with the bisulfide adducts (II) of hetaromatic aldehydes to give the 2‐hetarylbenzimidazoles (III).
ChemInform Abstract: Unexpected Loss of the β‐Lactam Ring During Rearrangement of a Penicillin Sulfoxide.
Authors: SCOTT A. I. , SHANKARANARAYAN R. 
Published: May 2016

AbstractThe penicillin sulfoxides (I) are treated with trimethyl phosphite, yielding the thiazolylcarboxylic amides (II) due to an unexpected cleavage of the lactam ring.
ChemInform Abstract: Synthesis of Heterocyclically Substituted 4‐Piperidinyl‐1,4‐dihydropyridines by Ring Closure Reactions at a N‐Acylthioamide or at a N‐Acylisothioamide Side‐Group.
Authors: PRAGST F. , LIEBSCHER J. , BOCHE E. , KOEPPEL H. + 
Published: May 2016

AbstractReaction of the compound (I) with the isocyanates (II) (in situ from benzoyl chloride or methyl chloroformate, resp., and KSCN) gives the products (III).
ChemInform Abstract: Cycloaddition of 2,3,4,5‐Tetrahydropyridine N‐Oxide to Isobutyl Vinyl Ether and Allyl Alcohol; Methyl 2‐Formylmethylpiperidine‐1‐carboxylate.
Authors: CARRUTHERS W. , MOSES R. C. 
Published: May 2016

AbstractIn the search for a method to introduce a formylmethyl group into the α‐position of a piperidine nucleus, the cycloaddition of the nitrone (I) with the vinyl ether (II) or allyl alcohol is studied.
ChemInform Abstract: 1,2,3,6‐Tetrahydropyridines via (4 + 2)Cycloaddition of 1‐Alkoxy‐1,3‐dienes with (Tosyloximino)malononitrile.
Authors: DORMAGEN W. , ROTSCHEIDT K. , BREITMAIER E. 
Published: May 2016

AbstractThe 1‐ethoxy‐1,3‐dienes (I) undergo cycloaddition with the tosyloximinomalononitrile (II) to give the tetrahydropyridines (III).
ChemInform Abstract: Synthesis of 3‐ and 4‐Chloro‐1H‐pyrrolo(3,2‐c)pyridin‐4(5H)‐one.
Authors: CRISTALLI G. , FRANCHETTI P. , GRIFANTINI M. , NASINI E. , VITTORI S. 
Published: May 2016

AbstractThe pyrrolopyridinone (I) is chlorinated with a mixture of PCl5 and POCl3 in the presence of water to form the 4‐chloro derivative (II).
ChemInform Abstract: Synthesis of 2‐(4‐Methoxy‐2‐(2‐(methylsulfinyl)ethoxy)phenyl)‐1H‐imidazo(4,5‐b)pyridine, a Potent Nonglycoside Inhibitor of Na+, K+‐ATPase.
Authors: ROBERTSON D. W. , KRUSHINSKI J. H. 
Published: May 2016

AbstractThe o‐hydroxybenzoate (I) is converted to the methylthioethyl ether (VI) which undergoes cyclocondensation with 2,3‐diaminopyridine (VII), forming the fused imidazole (VIII).
ChemInform Abstract: Oxygen‐Containing Heterocycles. Part 18. Synthesis and Pharmacological Activity of Oxadiazolylbenzodioxanes.
Authors: AVAKYAN A. S. , VARTANYAN S. O. , MARKARYAN E. A. , MARTIROSYAN O. M. , AVAKYAN O. M. 
Published: May 2016

AbstractThe benzodioxanecarbohydrazid (III) is cyclized with triethyl orthoformate (II) or carbon disulfide (IV) to give the oxadiazoles (I) or (V).
ChemInform Abstract: Phosphorus Pentoxide in Organic Synthesis. Part 33. Novel Route for the Synthesis of 3,7‐Dihydro‐4H‐pyrrolo(2,3‐d)pyrimidin‐4‐ones.
Authors: HILMY K. M. H. , MOGENSEN J. , PEDERSEN E. B. 
Published: May 2016

AbstractA series of title compounds of type (IV) containing the biologically interesting pyrrolo(2,3‐d)pyrimidine skeleton, is prepared from the pyrroles (I) and the anilines (II) under the conditions shown.
ChemInform Abstract: A Novel Tris(azo)macrobicyclic Molecule ‐ Synthesis, Photochemistry and Isomer Separation.
Authors: LOSENSKY H.‐W. , SPELTHANN H. , EHLEN A. , VOEGTLE F. + , BARGON J. 
Published: May 2016

AbstractThe novel macrobicyclic systems (III)‐(VI) are available starting from appropriate amino and halo compounds as exemplified in the synthesis of (IIIa), (IIIb).
ChemInform Abstract: Preparation and Structural‐Bonding Characterization of a 50‐Electron Triangular Cobalt Cluster, (Co(C5H4CO2Me))3(S)(NtBu), with Triply Bridging Sulfido and Imido Ligands: Singlet‐Triplet Equilibrium in Solid and Solution States.
Authors: WAKATSUKI Y. , OKADA T. , YAMAZAKI H. , CHENG G. 
Published: May 2016

AbstractThe title cluster (III) crystallizes in the space group P1 with Z=2.
ChemInform Abstract: Kinetics of Electron‐Transfer Reactions Between Transition‐Metal Complexes and the Methyl Viologen Radical Cation.
Authors: HOWES K. R. , PIPPIN C. G. , SULLIVAN J. C. , MEISEL D. , ESPENSON J. H. , BAKAC A. 
Published: May 2016

AbstractKinetic data for the reactions between the title radical cation and eight transition‐metal complexes (of Co, Ru, Cr, and Fe) and the uranyl ion are determined at pH 4 by pulse radiolysis.
ChemInform Abstract: Synthesis and Structure of the Butterfly Cluster Os4(μ‐H)2(CO)13(PMe3).
Authors: MARTIN L. R. , EINSTEIN F. W. B. , POMEROY R. K. 
Published: May 2016

AbstractThe 62‐electron title cluster (III) is obtained by treatment of the Os cluster (I) and the complex (II) in CH2Cl2 with Me3NO.
ChemInform Abstract: Stereo‐ and Regiocontrol of Electrophilic Additions to Cyclohexene Systems by Neighboring Groups: Participation of Allylic and Homoallylic Ester Groups in Hypobromous Acid Addition to Some 5‐Unsaturated Cholestane Derivatives.
Authors: KOCOVSKY P. , STARY I. , ZAJICEK J. , TURECEK F. , VASICKOVA S. 
Published: May 2016

AbstractHypobromous acid addition to some cholestenes such as (I) proceeds with intramolecular participation of the neighboring acetoxy groups.
ChemInform Abstract: Stereoselective Synthesis of Isovaline (Iva) and Iva‐Containing Dipeptides for Use in Peptide Synthesis.
Authors: NEBEL K. , MUTTER M. 
Published: May 2016

AbstractThe synthesis of the title compound (IV) (as hydrochloride) can be accomplished by hydrolysis of the ethylation product (III) from the oxazoline (I) which, in turn, is accessible from D‐alanine.
ChemInform Abstract: Nucleosides. Part 5. Isolation and Characterization of the Stable Cyclic Adducts, (5R,6S)‐ and (5S,6S)‐Bromo‐O6,5′‐cyclo‐5,6‐dihydrouridines in the Bromination of 2′,3′‐O‐Isopropylideneuridine with N‐Bromosuccinimide.
Authors: HIROTA K. , TOMISHI T. , SAKO M. , MAKI Y. 
Published: May 2016

AbstractBromination of the uridine (I) with NBS yields the compounds (II) and (III), whereas in the presence of AcOH the two diastereomeric title compounds (IV) and (V) are obtained.
ChemInform Abstract: Carbanion Fluorination with Xenon Difluoride in the Presence of Sulfur(II) Derivatives.
Authors: PATRICK T. B. , NADJI S. 
Published: May 2016

AbstractThe sodium alkylmalonates (I) are treated with xenon difluoride, dimethyl sulfide, and boron trifluoride etherate, yielding the fluorinated derivatives (II).
ChemInform Abstract: The Reaction of Polysubstituted Aromatics. Part 63. Synthesis and Properties of Dinitromethylated Arenes. Reinvestigation of the Ponzio Reaction.
Authors: SUZUKI H. , TAKAOKA H. , YAMAMOTO H. , OGAWA T. 
Published: May 2016

AbstractModified Ponzio reaction of various substituted arenecarbaldehyde oximes such as (I) yields the dinitromethylated products (III).
ChemInform Abstract: Optically Active 2‐Ethenyl‐1,3‐dioxolanones as 3‐Carbon Synthons. Allylnickel Derivatives as Homoenolate Equivalents.
Authors: KRYSAN D. J. , MACKENZIE P. B. 
Published: May 2016

AbstractThe metal‐centered nucleophile (II) reacts with the dioxolanone (I) to yield the Ni complex (III) which upon in situ treatment with the silane (IV) gives the derivative (V).
ChemInform Abstract: A New Pentafluorothio (SF5) Sultone: Rearrangement and Pathway to SF5CH2SO3H. New Pentafluorothio Fluoro Esters.
Authors: TERJESON R. J. , MOHTASHAM J. , GARD G. L. 
Published: May 2016

AbstractThe new sultone (III) rearranges in the presence of NaF to yield the bifunctional acetyl fluoride (IV).
ChemInform Abstract: 1,3‐Dipolar Cycloadditions to Heterocycles. Part 20. Reaction of Tetrahydrofuroisoxazoles with Molybdenum Hexacarbonyl. A New Route to Preparation of 3‐Substituted Tetrahydro‐ and Dihydrofuran Derivatives.
Authors: FISERA L. , GOLJER I. , JAROSKOVA L. 
Published: May 2016

AbstractThe cycloadducts (I) (from 2,5‐dihydrofuran and nitrile oxides Ar‐CNO) react with Mo(CO)6 to give three products (II)‐(IV); only a mixture (III)/(IV) can be isolated in the case of X: ‐F and ‐Ph.
ChemInform Abstract: Synthesis of 2‐Vinyl‐3,4,5‐trichlorothiophene and 3,4,5‐Trichlorothenyl Acrylates.
Authors: AKOPYAN A. N. , SAAKYAN A. A. , GAVALYAN V. B. , SMBATYAN A. G. , DARBINYAN E. G. 
Published: May 2016

AbstractTwo novel and optimized procedures are described for the preparation of 2‐vinyl‐3,4,5‐trichlorothiophene (V).
ChemInform Abstract: Comparison of Free Energy Changes for Nitrogen Inversion and Electron Loss. Part 2. 8‐Azabicyclo(3.2.1)octyl and 7‐Azabicyclo(2.2.1)heptyl Systems.
Authors: NELSEN S. F. , BLACKSTOCK S. C. , STEFFEK D. J. , CUNKLE G. T. , KURTZWEIL M. L. 
Published: May 2016

AbstractFormal potentials for one‐ and two‐electron oxidation (cyclovoltammetry) of (Ib), (IIIa) and (IIIb) are compared with those of related compounds such as (IIa), the N,N‐dimethyl derivative of (VIII) (obtained in low yield by reductive methylation), and (Ia); (Ib) and (IIIb) are especially hard to oxidize.
ChemInform Abstract: Synthesis, Structure, and Acid Base‐Properties of Enaminones in the Barbituric Acid Series.
Authors: PESTOV D. V. , SLESAREV V. I. , GINAK A. I. , SLESAREVA V. I. 
Published: May 2016

AbstractCondensation reaction of the barbituric acids (I) with the orthoformate (II) and aniline (III) yields the enaminones (IV).
ChemInform Abstract: Substituted Metal Carbonyls. Part 7. Direct Route to Group 6 Tricarbonyl Complexes with Tris(2‐chloroethyl)phosphite as Ligand.
Authors: HOR T. S. A. 
Published: May 2016

AbstractThe tricarbonyl(diimine)phosphite complexes (IV) are prepared as shown and characterized by IR, 1H and 31P NMR spectroscopic data.
ChemInform Abstract: Synthesis and Acetylation of Naphthols as Precursors to Naturally Derived Naphthoquinones; Crystal Structure of the Aphin‐Related 7‐O‐Methyl Quinone A.
Authors: GILES R. G. F. , GREEN I. R. , NIVEN M. L. , YORKE S. C. 
Published: May 2016

AbstractSeveral routes for the synthesis of 3‐acetyl‐4‐naphthols of type (VI) (required as a precursor to natural product derivatives; cf.
ChemInform Abstract: The Structures of Anhydrous Perchloric Acid and of its Anhydride, HClO4 and Cl2O7, resp., in the Crystal.
Authors: SIMON A. , BORRMANN H. 
Published: May 2016

AbstractThe structure of HClO4 which crystallizes in the acentric space group Pca21 with Z=16, is found to be characterized by weakly interacting HClO4 molecules.
ChemInform Abstract: Kinetic Modeling of Grain Growth in Polycrystalline Silicon Films Doped with Phosphorus or Boron.
Authors: KIM H.‐J. , THOMPSON C. V. 
Published: May 2016

AbstractThe effects of P and B doping on grain growth in low pressure CVD Si films on SiO2 substrates are described for wide ranges of dopant concentrations and annealing temperatures.
ChemInform Abstract: Crystal Chemistry of Oxotantalates M4Ta2O9. Part 3. The Crystal Chemistry of Zn4‐xMgxTa2O9 and Zn2.1Mg0.9Ta2O8.
Authors: HALLE G. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractIt is shown that substitution of Mg2+ for Zn2+ in Zn4Ta2O9 at levels of x ≥ 1 causes a change from the Zn4Ta2O9‐type to the Mg4Ta2O9‐type structure (space group P3c1).
ChemInform Abstract: Sintering, Microstructure, Hardness, and Fracture Toughness Behavior of Y2O3‐CeO2‐ZrO2.
Authors: DUH J.‐G. , DAI H.‐T. , CHIOU B.‐S. 
Published: May 2016

AbstractFine powders of Y2O3‐stabilized zirconia containing 10‐12 mol% CeO2 are prepared by a coprecipitation method.
ChemInform Abstract: About a Compound Formation MO:M2O3. Part 10. BaCr2O4.
Authors: CUNO E. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractSingle crystals of the title oxochromate are obtained for the first time by using the CO2‐laser technique (BaO:Cr2O3 = 1:1, > 1600 °C).
ChemInform Abstract: Alternative Routes to the Synthesis of Chevreul′s Salt, Cu(II)(Cu(I)(SO3))2·2 H2O.
Authors: BHATTACHARJEE M. N. , CHAUDHURI M. K. , DEVI M. 
Published: May 2016

AbstractThe mixed valence red Chevreul's salt (IV) can be prepared in aqueous medium by two new synthetic routes starting from freshly prepared Cu(OH)2 or Cu(II)‐acetate, respectively.
ChemInform Abstract: Intramolecular Nucleophilic Addition of Phenolate Oxygen to Double Bonds Activated by Carboxyl and Carboxylate Groups. Relative Reactivity, Stereochemistry, and Mechanism.
Authors: AMYES T. L. , KIRBY A. J. 
Published: May 2016

AbstractThe pH‐rate profiles for the cyclization of the phenolic acids (I) to benzofuran derivatives (II) are determined (general acid catalysis; solvent deuterium isotope effects).
ChemInform Abstract: Chemistry of Singlet Oxygen. Part 50. Hydroperoxide Intermediates in the Photooxygenation of Ascorbic Acid.
Authors: KWON B.‐M. , FOOTE C. S. 
Published: May 2016

AbstractThe reaction of ascorbic acid (Ia) and its methyl derivative (Ib) with 1O2 leads to the hydroperoxy ketone (II) which rearranges to give (III).
ChemInform Abstract: Oxidation of α‐Hydroxy Esters to α‐Keto Esters Using the Dess‐Martin Periodinane Reagent.
Authors: BURKHART J. P. , PEET N. P. , BEY P. 
Published: May 2016

Abstractβ‐Nitrostyrene (I) is hydrogenated and then coupled with the glyoxylic acid monohydrate (III) to produce the 2‐hydroxy‐3‐nitro‐4‐phenylbutyric acid (IV).
ChemInform Abstract: σ Delocalization Induced Stereoselectivity in the Capture of Cumyl Cations and Failure of Stabilizing Substituents to Suppress It.
Authors: LIN M.‐H. , CHEUNG C. K. , LE NOBLE W. J. 
Published: May 2016

AbstractThe syn approach of a nucleophile (OH‐) is favored for the adamantyl cations (I).
ChemInform Abstract: Spirodienones via a Thermal Uncatalyzed (1,3)‐Oxygen‐to‐Carbon Migration.
Authors: MORROW G. W. , WANG S. , SWENTON J. S. 
Published: May 2016

AbstractThe spirobenzoisofurancyclohexadienones (IV) and their acetals (VII) are prepared as shown in the reaction scheme.
ChemInform Abstract: An Expeditious Route to Homocarbaprostacyclin Derivatives.
Authors: BIRD C. W. , COFFEE E. C. J. , COOPER R. 
Published: May 2016

AbstractThe cis‐decalindione (I), obtained from naphthalene‐2,7‐diol by hydrogenation and oxidation, is oxidized to give the oxabicyclo(4.3.0)nonanecarboxylic acid (II), which is converted into the homocarbaprostacyclin (X) as shown in the reaction scheme.
ChemInform Abstract: Addition of Aryllithium Compounds to Oxime Ethers.
Authors: RODRIQUES K. E. , BASHA A. , SUMMERS J. B. , BROOKS D. W. 
Published: May 2016

AbstractThe oxime ethers (II) or (IV) react with the organolithium compounds (I) in the presence of boron trifluoride etherate to give the O‐benzylhydroxylamines (III) or (Va).
ChemInform Abstract: Synthesis and Antiarrhythmic Activity of Cycloalkaneindoles.
Authors: ABOU‐GHARBIA M. , PATEL U. , TOKOLICS J. , FREED M. 
Published: May 2016

AbstractCompounds of type (V) and the carbazole derivative (VIII) are tested for antiarrhythmic activity in the coronary‐ligated rat artery model.
ChemInform Abstract: The Enantioselective Michael Reaction of Tin(II) Enolates.
Authors: YURA T. , IWASAWA N. , MUKAIYAMA T. 
Published: May 2016

AbstractBenzalacetone (I) is coupled with the N‐propionyloxazolidinone (II) in the presence of tin(II) triflate, trimethylsilyl triflate as an activator, N‐ethylpiperidine, and a chiral aminomethylpyrrolidine to produce the Michael adduct (III) with predominance of the anti‐isomer.
ChemInform Abstract: Unexpected Reactivity of the Anion Derived from Benzophenone Benzoylhydrazone in the Presence of Electrophiles.
Authors: ARMESTO D. , GALLEGO M. G. , HORSPOOL W. M. , RAMOS A. 
Published: May 2016

AbstractBenzophenone N‐benzoylhydrazone (I) is converted to the carbanion and then treated with the acid chlorides (II) to form the oxadiazolines (III).
ChemInform Abstract: A Convenient Synthesis of Substituted Quinolines by Thermal or Photochemical Electrocyclic Rearrangement of o‐Vinyl Imidates Under Nonacidic Conditions.
Authors: QIANG L. G. , BAINE N. H. 
Published: May 2016

Abstract2‐Acylaminostyrenes (III) prepared from the corresponding amine (I) are converted to the imino ethers (V).
ChemInform Abstract: Cycloaddition Reactions of 3,4‐Dihydro‐2H‐pyran with Benzylideneanilines.
Authors: GILCHRIST T. L. , STANNARD A.‐M. 
Published: May 2016

AbstractBenzylideneaniline (I) and dihydropyran (II) undergo cycloaddition reaction in the presence of iron(III) chloride, forming the diastereomeric (4 + 2)adducts (III) and (IV).
ChemInform Abstract: Stabilization of Adducts of α‐Dicarbonyl Compounds with Amidine Functions by Formation of Boron Chelates.
Authors: KLIEGEL W. , MOTZKUS H.‐W. 
Published: May 2016

AbstractThe adducts of the amidines (I) with the dicarbonyls (II) are trapped by oxybis(diphenylborane) (III) to give the chelates (IV).
ChemInform Abstract: Formation of Carbonato and Hydroxo Complexes of Vanadium(IV) on Reaction of Carbonylbis(η‐pentamethylcyclopentadienyl)vanadium(II) with Dinitrogen Oxide.
Authors: BOTTOMLEY F. , DARKWA J. 
Published: May 2016

AbstractThe title reaction yields the V(IV) carbonate complex (III), besides a hydroxo‐μ‐oxo‐polymer, in 17% yield.
ChemInform Abstract: Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 78. Reactions of (MoFe(μ‐CC6H4Me‐4)(CO)6(η‐C5H5)) with Alkynes; Crystal Structures of (MoFe(μ‐C(C6H4Me‐4)C(O)C(Et)C(Et))(μ‐CO)(CO)4(η‐C5H5)) and (MoFe(μ‐C(C6H4Me‐4)C(Me)C(C(O)Me))(CO)5(η‐C5H5)).
Authors: GARCIA M. E. , JEFFERY J. C. , SHERWOOD P. , STONE F. G. A. 
Published: May 2016

AbstractThe reaction of (I) with almost equimolar amounts of the alkynes (II) and (V) as well as with a slight excess of (VII) are shown in the scheme.
ChemInform Abstract: Triphenylphosphine Adduct of a Copper(I) Complex Involving an Incompletely Bound N2S2 Macroyclic Ligand.
Authors: WAINWRIGHT K. P. , PATALINGHUG W. , SKELTON B. W. , WHITE A. H. , HEALY P. C. 
Published: May 2016

AbstractThe highly distorted tetrahedral Cu(I) complex (I), prepared from (Cu(NCMe)4)ClO4 and the macrocycle in refluxing ethanol, reacts with PPh3 (II) to form the adduct (III) in which one of the two S donors of the macrocycle has been displaced from the primary coordination sphere resulting in tetrahedral coordination through an N2PS donor set.
ChemInform Abstract: Syntheses and Reactivity of Acetylide‐Containing Clusters of Group 1B Metals. Stepwise Syntheses of Trinuclear (Au2Cu(C2Ph)4)‐ and Pentanuclear (Au3Cu2(C2Ph)6)‐ and (Au3Ag2(C2Ph)6)‐ Clusters.
Authors: ABU‐SALAH O. M. , AL‐OHALY A. R. A. 
Published: May 2016

AbstractThe pentanuclear cluster (IVa) is obtained from the equimolar reaction between the acetylide‐Au polymer (III) and a mixture of the bis(acetylide)aurate (I) and the polymeric Cu‐acetylide (II).
ChemInform Abstract: A New Synthetic Method for Ruthenium Complexes of β‐Diketones from “Ruthenium Blue Solution” and Their Properties.
Authors: ENDO A. , KAJITANI M. , MUKAIDA M. , SHIMIZU K. , SATO G. P. 
Published: May 2016

AbstractThe "ruthenium blue solution", consisting of mixed‐valence chloro complexes, is used as a convenient starting material for the synthesis of 13 Ru(III) complexes such as (I) and 6 Ru(II) complexes such as (II).
ChemInform Abstract: Synthesis and Chemical Characterization of the Hexanuclear Anions (Ir6(CO)14X)‐ (X: Cl, Br, I, or SCN). Crystal and Molecular Structures of (PPh4) (Ir6(μ‐CO)2(CO)12(μ‐Br)) and (N(PPh3)2) (Ir6(μ‐CO)2(CO)12(μ‐X)) (X: I or SCN).
Authors: DELLA PERGOLA R. , GARLASCHELLI L. , MARTINENGO S. , DEMARTIN F. , MANASSERO M. , MASCIOCCHI N. 
Published: May 2016

AbstractThe title anions are prepared and isolated as their salts (VI) as shown in the scheme.
ChemInform Abstract: Coordination Chemistry of Higher Oxidation States. Part 27. Synthesis, Properties, and Electrochemistry of Some cis‐Tetrahalogenoiridium(IV) Complexes: Crystal Structure of (Ir(phen)Cl4).
Authors: CIPRIANO R. A. , HANTON L. R. , LEVASON W. , PLETCHER D. , POWELL N. A. , WEBSTER M. 
Published: May 2016

AbstractThe Ir(IV) cis complexes (V) are prepared by HNO3 oxidation of the corresponding Ir(III) anions (IV) obtained as shown in the scheme.
ChemInform Abstract: Chiroptical Properties of Diastereomeric Five‐Coordinate Pt(II)‐Olefin Complexes. Molecular Structure of (PtCl2((S,S)‐(E)‐CNCH=CHCN)(R,R)‐(C6H5CH(CH3)N(CH3)CH2)2)·C6H6.
Authors: ALBANO V. G. , DEMARTIN F. , DE RENZI A. , MORELLI G. 
Published: May 2016

AbstractThe chiroptical properties of the five‐coordinate diastereomeric complexes (Ib) and (Ic), obtained by olefin exchange in benzene from the corresponding ethylene complex (Ia), are investigated.
ChemInform Abstract: Synthesis of New Thioether Transition Metal Complexes of 2‐(1,3‐Dithiolan‐2‐ylidene)‐1,3‐dithiepin and 2‐(Bis(ethylthio)methylene)‐1,3‐dithiepin.
Authors: LONG C. J. II , BEREMAN R. D. , TUCKER C. , BORDNER J. 
Published: May 2016

AbstractThe appropriate ligands react with K2PtCl4 or PdCl2(PhCN)2 in MeCN to give the complexes (I)‐(III).
ChemInform Abstract: Antitumour Properties of Some Titanocene Chalcogenates.
Authors: KOEPF‐MAIER P. + , KLAPOETKE T. + , KOEPF H. + 
Published: May 2016

AbstractThe chalcogen‐coordinated titanocene chalcogenates (I)‐(III) are tested against fluid Ehrlich ascites tumor for antitumor properties.
ChemInform Abstract: Texture of Electroless Copper Films.
Authors: JUNGINGER R. , ELSNER G. 
Published: May 2016

AbstractThe top surface layer of Cu‐films deposited on titanium‐seeded glass substrates is (100)‐textured when the plating bath contains a surfactant, whereas it is (111)‐textured for surfactant‐free baths.
ChemInform Abstract: Anisotropic Reactive Ion Etching of MoSi2 and in situ Doped n+ and p+ Polysilicon Using Cl2 and BCl3.
Authors: MELE T. C. , ARNEY S. C. , KRUSIUS J. P. , MACDONALD N. C. 
Published: May 2016

AbstractA high resolution Cl2/BCl3 reactive ion etch process is described that can be used to etch simultaneously composite structures of MoSi2 and unannealed in situ doped polysilicon.
ChemInform Abstract: A New Example of Stabilized Zirconia: The Phases (U,Zr)O2+x (0.114 ≤ x ≤ 0.154; 1250 °C) of Fluorite Type with Anion Excess.
Authors: PAPIERNIK R. , FRIT B. 
Published: May 2016

AbstractAn apparently continuous sequence of ordered orthorhombic fluorite superstructures is synthesized in the composition range of title by solid state reaction of ZrO2, U3O8, and UO2.102.
ChemInform Abstract: Oxidation of Saturated Hydrocarbons by Hydrogen Peroxide in Pyridine Solution Catalyzed by Copper and Iron Perchlorates.
Authors: GELETII Y. V. , LAVRUSHKO V. V. , LUBIMOVA G. V. 
Published: May 2016

AbstractOxidation of cyclohexane (I) and 2‐methylbutane (IV) with hydrogen peroxide in the presence of copper(II) perchlorate and pyridinium perchlorate yields cyclohexanone (II) and 2‐methylbutan‐3‐one (V) as the main products.
ChemInform Abstract: Efficient Conversion of Alkyl Halides to Aldehydes Using Pyrazinylsulfinyl Group.
Authors: SHIMAZAKI M. , NAKANISHI T. , MOCHIZUKI M. , OHTA A. 
Published: May 2016

AbstractCoupling of 3,6‐diisopropyl‐2‐pyrazinethiol (II) with the alkyl bromides (I) gives the sulfides (III) which are oxidized with MCPBA as described previously, producing the sulfoxides (IV).
ChemInform Abstract: The Alkylation of Methyl 2‐(1‐Pyrrolyl)acetate. A New Synthetic Method of α‐Amino Acids.
Authors: KASHIMA C. , MARUYAMA T. 
Published: May 2016

AbstractThe pyrrolylacetates (I) are converted to the α‐alkyl derivatives (IIIa), (IIIb), (IIId), and (IIIe) upon lithiation and subsequent treatment with the alkyl halides (II).