bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Preparation of Alkoxy‐Derived Yttrium Vanadate.
Authors: YAMAGUCHI O. , MUKAIDA Y. , SHIGETA H. , TAKEMURA H. , YAMASHITA M. 
Published: May 2016

AbstractHydrolysis of an ethanolic yttrium vanadyl ethoxide solution (prepared by addition of NaOEt to a solution of VO(OEt)3 and YCl3 in EtOH and removal of NaCl) yields either crystalline YVO4 (host material for red phosphors) or an amorphous product depending on the Y2O3:V2O5 ratio.
ChemInform Abstract: Large Magnetic Field Effect on the Decay Rates of Triplet Hydrocarbon Diradicals.
Authors: WANG J. , DOUBLEDAY C. JUN. , TURRO N. J. 
Published: May 2016

AbstractThe lifetimes of the triplet diradicals (Ib) in MeOH are measured directly by nanosecond transient absorption spectroscopy.
ChemInform Abstract: Crystal Structures of Two Salts of N‐(Phosphonomethyl)glycine and Equilibria with Hydrogen and Bicarbonate Ions.
Authors: SMITH P. H. , HAHN F. E. , HUGI A. , RAYMOND K. N. 
Published: May 2016

AbstractThe title glycine, glyphosate (I), is a commercial herbicide in very extensive worldwide use.
ChemInform Abstract: Synthesis of o‐Substituted Phenols by Criegee Rearrangement of Benzylic Hydroperoxides.
Authors: TALJAARD B. , GOOSEN A. , MCCLELAND C. W. 
Published: May 2016

AbstractThe compounds (I), (IV), and (VI) undergo Criegee‐type rearrangements when treated with H2O2 and acid to generate substituted benzophenones (II), (V) as main products (from (I), (IV)) or monoesters (VII) (from the fluorenes (VI)) via Baeyer‐Villiger oxidation of the intermediate 2'‐aroylbiphenyl‐2‐ols.
ChemInform Abstract: Dichloromethane Photodegradation Using Titanium Catalysts.
Authors: TANGUAY J. F. , SUIB S. L. , COUGHLIN R. W. 
Published: May 2016

AbstractSynthetic rutile is the most active catalyst for the photodecomposition of CH2Cl2, one of the waste water contaminating chlorinated hydrocarbons, to give CO2 and HCl.
ChemInform Abstract: Improvement in the Enantioselectivity of the Hydrogen Transfer with NADH Models Bearing Amino Alcohols as Chiral Auxiliaries.
Authors: CAZIN J. , DUFLOS J. , DUPAS G. , BOURGUIGNON J. , QUEGUINER G. 
Published: May 2016

AbstractCompounds of type (I) are readily prepared as NADH models by linking the carbonyl group of a corresponding thieno‐pyridine species with respective chiral amino alcohols.
ChemInform Abstract: Regio‐, Diastereo‐, and Enantioselective Condensation of Chiral Vinylic Borates with Aldehydes.
Authors: BASILE T. , BIONDI S. , BOLDRINI G. P. , TAGLIAVINI E. , TROMBINI C. , UMANI‐RONCHI A. 
Published: May 2016

AbstractA regio‐ and diastereoselective synthesis of enantiomerically enriched syn‐ketols such as (III) is reported starting from the borates (I).
ChemInform Abstract: 2‐Propyn‐1‐ol from Paraformaldehyde and Acetylene in the System KOH‐DMSO.
Authors: TROFIMOV B. A. , SOBENINA L. N. , MIKHALEVA A. I. , NESTERENKO R. N. , VORONKOV M. G. 
Published: May 2016

AbstractThe title compound (III) is prepared by a novel procedure.
ChemInform Abstract: 2‐Chloro‐2‐cyclopropylidenacetate in Synthesis. Part 2. Facile Construction of Various Spirocyclopropane Anellated Heterocycles.
Authors: DE MEIJERE A. , TEICHMANN S. , YU D. , KOPF J. , OLY M. , VON THIENEN N. 
Published: May 2016

AbstractThe ester (I) is used in three different ways for the construction of heterocyclic systems with spirocyclopropane groups.
ChemInform Abstract: Cyclopropanone Equivalents from 3‐Chloropropionic Acid. Use of 1‐Piperidino‐1‐trimethylsilyloxycyclopropane in Synthetic Applications.
Authors: WASSERMAN H. H. , DION R. P. , FUKUYAMA J. 
Published: May 2016

AbstractThe cyclopropane derivatives (III) and (VI) react with various nucleophiles to give the products shown in the scheme.
ChemInform Abstract: Products of N‐Acetylation of the Alkylimines of 2‐Dimethylaminomethylcyclohexanone.
Authors: KAYUKOVA L. A. , ERZHANOV K. B. , DYUSENOVA Z. M. 
Published: May 2016

AbstractAcetylation of the alkylimines (I) proceeds regiospecifically at the imino nitrogen atom to afford a mixture of the N‐acetylated enamines (III) and (IV), the isomers (III) being the main components.
ChemInform Abstract: Functionalized Perfluorophenyl Azides: New Reagents for Photoaffinity Labeling.
Authors: KEANA J. F. W. , CAI S. X. 
Published: May 2016

AbstractNucleophilic aromatic substitution of the pentafluorobenzenes (I) with sodium azide (II) produces the 4‐azido‐substituted compounds (III).
ChemInform Abstract: Reductive Dimerization of Vinyl Halides in an Ni/Pb/Al Three Metal Redox System. A Facile Access to Terphenyl Derivatives.
Authors: TANAKA H. , KOSAKA A. , YAMASHITA S. , MORISAKI K. , TORII S. 
Published: May 2016

AbstractThe styryl bromides (I) are reductively dimerized to yield predominantly the E,E‐diphenylbutadienes (II).
ChemInform Abstract: Chemistry of p,p‐Dibenzenes.
Authors: GAN H. , KING J. L. , YANG N. C. 
Published: May 2016

AbstractThe benzo‐fused p,p‐dibenzene (IV) and its tetrahydro analogue (X) are prepared from the cycloadducts (III) of naphthalene (I) and the benzodioxole derivatives (II) as shown in the reaction scheme.
ChemInform Abstract: Antiaromatic Compounds. Part 24. Steric Effects on Valence Isomerizations in the Dewar Pyridine/Azaprismane/Pyridine System.
Authors: HEES U. , VOGELBACHER U.‐J. , MICHELS G. , REGITZ M. 
Published: May 2016

AbstractThe TFA‐catalyzed isomerization of the 1‐Dewar pyridines (III) is investigated.
ChemInform Abstract: Electroorganic Chemistry. Part 115. Diastereoselectivity in the Addition of Enolate Anions to N‐Methoxycarbonylimines Generated in situ from α‐Methoxy Carbamates.
Authors: SHONO T. , KISE N. , SANDA F. , OHI S. , YOSHIOKA K. 
Published: May 2016

AbstractCoupling of the α‐methoxy carbamates (I) with the ketones or esters (II) in the presence of LDA gives mixtures of the anti‐(III) and syn‐adducts (IV).
ChemInform Abstract: Synthesis of Highly‐Substituted, Diastereomerically and Enantiomerically Pure 3‐Acyltetrahydrofurans from 4‐Hydroxy‐1‐alkenyl Carbamates.
Authors: HOPPE D. , KRAEMER T. + , ERDBRUEGGER C. F. + , EGERT E. 
Published: May 2016

AbstractThe O‐hydroxyalkenyl carbamates mentioned in the title, e.g. (I), react with the aldehydes and ketone (II) or the cyclopentanone acetal (IV) in the presence of boron trifluoride etherate under ring closure and elimination of carbamic acid, forming acyltetrahydrofurans such as (III) or (V).
ChemInform Abstract: 2,3‐Heterocondensed Thiophenes from Substituted 2‐Aminothiophene‐3‐thiol.
Authors: GEWALD K. , HAIN U. , MADLENSCHA M. 
Published: May 2016

AbstractThe novel title compound (II) undergoes reactions which resemble those of 2‐aminobenzenethiol.
ChemInform Abstract: Reactions of Indole Sulfoxides with Dichloroketene: A New Approach to the Physostigmine Alkaloids.
Authors: MARINO J. P. , KIM M.‐W. , LAWRENCE R. 
Published: May 2016

AbstractThe indolyl sulfoxide (I) reacts with dichloroketene, generated from trichloroacetyl chloride (II), to give the dichlorolactone (III) via 3,3‐sigmatropic rearrangement.
ChemInform Abstract: Nucleophilic Substitution of Pentafluorobenzenes with Imidazole.
Authors: FUJII S. , MAKI Y. , KIMOTO H. 
Published: May 2016

AbstractThe nucleophilic aromatic substitution of various polyfluorobenzenes, e.g. (II) and (V), with imidazole (I) occurs predominantly at the para‐position to R, yielding the corresponding 1,4‐substituted benzenes (III) and (VI).
ChemInform Abstract: Reactions of 1,2‐Dihydro‐2,2,4‐trimethylquinoline and Its Derivatives with Hexafluoroacetone and Methyl Trifluoropyruvate.
Authors: KOMAROV K. V. , CHKANIKOV N. D. , SUSKINA V. I. , SHAPIRO A. B. , KOLOMIETS A. F. , FOKIN A. V. 
Published: May 2016

AbstractReaction of the dihydroquinoline derivatives (I) or (V) with hexafluoroacetone (II) produces the hydroxyhexafluoropropyl derivatives (III), (IV), or (VI) depending on the substituents and the molar ratio.
ChemInform Abstract: 6‐(Arylpiperazino‐4‐butyryl)benzoxazolinones and Reduction Products: Chemical and Pharmacodynamic Study.
Authors: MOUSSAVI Z. , BONTE J. P. , LESIEUR D. , LEINOT M. , LAMAR J. C. , TISNE‐VERSAILLES J. 
Published: May 2016

AbstractN‐Methylbenzoxazolidinone (I) reacts with butyrolactone (II) to give the hydroxy ketone (III) which is converted into the bromo ketone (IV).
ChemInform Abstract: Benzodiazepine Receptor Ligands. Synthesis and Preliminary Pharmacological Evaluation of Some 3,7‐Disubstituted‐4H‐(1,2,4)Triazino(3,4‐a)phthalazines and 3,7‐Disubstituted‐4H‐(1,2,4)Triazino(3,4‐a)phthalazin‐4‐ones.
Authors: OCCELLI E. , TARZIA G. , BARONE D. 
Published: May 2016

Abstract1‐Chlorophthalazine (I) reacts with the N‐ or O‐nucleophiles (II) to form the phthalazines (III) which undergo cyclocondensation with the phenacyl bromides (IV) to give the triazinophthalazines (VI) after dehydrogenation.
ChemInform Abstract: Purines, Pyrimidines, and Anellated Systems on Their Basis. Part 6. Reactivity of 7‐ and 9‐Aminoxanthines Towards Oxidants and Electrophiles. Synthesis of the Antibiotics Fervenulin and Reumycin.
Authors: GULEVSKAYA A. V. , KUZ'MENKO V. V. , POZHARSKII A. F. , KUZ'MENKO T. A. , SHORSHNEV S. V. , CHERNYSHEV A. I. , KLYUEV N. A. 
Published: May 2016

AbstractOxidation of the aminoxanthines (I) or (III) gives isofervenulin (II), reumycin (IVa), or fervenulin (IVb).
ChemInform Abstract: Fluoride‐Catalyzed Michael Reaction of α‐Isocyano Esters with α,β‐Unsaturated Carbonyl Compounds.
Authors: MURAKAMI M. , HASEGAWA N. , TOMITA I. , INOUYE M. , ITO Y. 
Published: May 2016

AbstractTetrabutylammonium fluoride mediates the coupling of the α,β‐unsaturated carbonyl compounds (I) with the isocyano carboxylates (II), producing the α‐isocyano δ‐oxo esters (III).
ChemInform Abstract: Regioselective Synthesis of Highly‐Substituted Arylsilanes by the Reaction of the Trimethylsilyl‐Substituted Vinylallenones with Enamines.
Authors: WANG K. K. , ANDEMICHAEL Y. W. , DHUMRONGVARAPORN S. 
Published: May 2016

AbstractThe silylalkynylborane (II) reacts with the monoacetalized 1,3‐dicarbonyl compounds (I) to form the (β‐hydroxy)silylallenes (III) which are dehydrated and hydrolyzed to yield the 1,2,4‐trienes (IV).
ChemInform Abstract: Synthesis, Characterization, and X‐Ray Crystal Structures of the Divalent Titanium Complex Ti(η2‐BH4)2(dmpe)2 and the Unidentate Tetrahydroborate Complex V(η1‐BH4)2(dmpe)2.
Authors: JENSEN J. A. , GIROLAMI G. S. 
Published: May 2016

AbstractThe Ti complex (III), which crystallizes in the space group P21/n, Z=2, is a thermally robust and oxidatively stable paramagnetic species with very weakly bound bidentate BH4‐ groups.
ChemInform Abstract: Structurally Diverse Manganese(III) Schiff Base Complexes: Solution Speciation via Paramagnetic 1H NMR Spectroscopy and Electrochemistry.
Authors: BONADIES J. A. , MARONEY M. J. , PECORARO V. L. 
Published: May 2016

AbstractMn(III) complexes of the Schiff base N,N'‐disalicylidene‐2‐hydroxypropylenediamine have been synthesized and characterized as monomeric, dimeric polymeric and cage complexes (see preceding paper).
ChemInform Abstract: Isolation and Characterization of the Redox Pair (Re2H5(PMe3)6)(PF6)n (n = 1 or 2).
Authors: ROOT D. R. , MEYER K. E. , WALTON R. A. 
Published: May 2016

AbstractWith the view that the chemistry of dirhenium octahydride complexes is dependent upon the phosphine ligand the chemistry of (I) is examined.
ChemInform Abstract: Low‐Spin Tetracyanoferrate(II) and ‐(III) Complexes of meso‐Type 1,2‐Diamines: Synthesis and Steric Effects on Chelate‐Ring Conformation and Rate of Ligand Dehydrogenation.
Authors: KURODA Y. , TANAKA N. , GOTO M. , SAKAI T. 
Published: May 2016

AbstractComplexes (I) are prepared from Fe perchlorate and the diamine ligands by addition of NaCN.
ChemInform Abstract: Analogues of Cisplatin Derived from Diaminodideoxytetritols. Synthesis and Activity Against the ADJ/PC6 Plasmacytoma in Mice.
Authors: HAINES A. H. , MORLEY C. , MURRER B. A. 
Published: May 2016

AbstractReaction of the mesylates (I), (VI), and (IX) with sodium azide (II), followed by catalytic hydrogenation, yields the diamines (III), (VII), and (X).
ChemInform Abstract: An Efficient Synthesis of Sugar Pyruvic Acid Acetals.
Authors: COLLINS P. M. , MCKINNON A. C. , MANRO A. 
Published: May 2016

AbstractTransacetalization of the furanyl ketone dimethyl acetal (I) with the glucopyranoside (II) and subsequent acetylation produce the cyclic acetal (III), which is oxidatively degraded and then esterified to give the carboxylate (IV).
ChemInform Abstract: On the Gif Oxidation of Alicyclic Tertiary Amines.
Authors: BARTON D. H. R. , BOIVIN J. , GAUDIN D. , JANKOWSKI K. 
Published: May 2016

AbstractN‐Methylpyrrolidine (I) is oxidized in the Gif system (combination of Fe, Zn, acetic acid, pyridine, and air) to form moderate yields of a mixture of the lactam (II) and the 3‐ketone (III).
ChemInform Abstract: Quinazoline Antifolates Inhibiting Thymidylate Synthase: 2‐Desamino Derivatives with Enhanced Solubility and Potency.
Authors: JONES T. R. , THORNTON T. J. , FLINN A. , JACKMAN A. L. , NEWELL D. R. , CALVERT A. H. 
Published: May 2016

AbstractThe quinazolinone (I), prepared by cyclization of 2‐amino‐5‐methylbenzoic acid with formamide, is alkylated with the chloromethyl ester (II) to give the quinazolinonylmethyl ester (III) which is then treated with NBS to yield the bromomethyl derivative (IV).
ChemInform Abstract: Preparation and Radiocrystallographic Data for Three New Compounds: TlSb2PO8 (I), TlSbP2O8 (II) and KSb2AsO8 (III).
Authors: ZID M. F. , JOUINI T. , JOUINI N. 
Published: May 2016

AbstractSingle crystals of the title compounds are obtained from stoichiometric mixtures of M2CO3 (M: K, Tl), Sb2O5, and NH4H2PO4 and NH4H2AsO4, resp. (1.
ChemInform Abstract: Solid‐State 113Cd NMR Study of Echanged Montmorillonites.
Authors: BANK S. , BANK J. F. , ELLIS P. D. 
Published: May 2016

AbstractThe solid‐state 113Cd NMR MAS spectra of three Cd exchanged montmorillonite samples are shown to contain cadmium oxoanion components of differing line width with differential sensitivities to preparation conditions.
ChemInform Abstract: The Solubility and Thermodynamics of Hydrogen in Pd1‐xLnx (Ln: Dy, Gd, Sm, and Y; x = 0.05 and 0.08) Solid Solution Alloys.
Authors: RAMAPRABHU S. , RAJALAKSHMI N. , WEISS A. 
Published: May 2016

AbstractThe hydrogen solubility in the title cubic face‐centered alloys is measured in the pressure and temp. ranges 2 ≤ P/mbar ≤ 1000 and 473 ≤ T/K ≤ 873, resp., and thermodynamic parameters are evaluated.
ChemInform Abstract: Radiolytic Production and Properties of Ultrasmall CdS Particles.
Authors: HAYES D. , MICIC O. I. , NENADOVIC M. T. , SWAYAMBUNATHAN V. , MEISEL D. 
Published: May 2016

AbstractThe use of radiation chemistry techniques to release sulfide ions and generate sparingly soluble semiconductor colloids of essentially any desired size is demonstrated.
ChemInform Abstract: Determination of the Phosphorescence Quantum Yield of Singlet Molecular Oxygen (1δg) in Five Different Solvents,
Authors: SCHMIDT R. , SEIKEL K. , BRAUER H.‐D. 
Published: May 2016

Abstracti.e. MeCN, CHCl3, CS2, CCl4, and Freon 113, relative to the respective emission in benzene, using the known 1O2 phosphorescence quantum yield in benzene as standard.
ChemInform Abstract: Reaction of Palladium(II) Hydroxide with Ammonium Salts.
Authors: BLOKHIN A. I. , BLOKHINA M. L. , RYUMIN A. I. , SMIRNOV I. I. 
Published: May 2016

AbstractThe reaction between Pd(OH)2 and NH4Cl conducted in aqueous solution at 90 °C affords β‐trans‐(Pd(NH3)2Cl2) in 90% yield.
ChemInform Abstract: Carcerand Interiors Provide a New Phase of Matter.
Authors: SHERMAN J. C. , CRAM D. J. 
Published: May 2016

AbstractThe carceplex (IV)·DMSO and its analogues containing DMF (yield 54%) and AcNMe2 (49%) are formed by shell closures of (I) under high dilution conditions and are purified by chromatography.
ChemInform Abstract: Selective Homogeneous Hydrogenation of Benzothiophene and Quinoline Catalyzed by Ruthenium, Osmium, Rhodium and Iridium Complexes.
Authors: SANCHEZ‐DELGADO R. A. , GONZALEZ E. 
Published: May 2016

AbstractThe metal complexes used in this work are chosen on the basis of their known catalytic activity for the hydrogenation of polar and/or aromatic molecules.
ChemInform Abstract: Hydrozirconation of 1‐Arylalkenes.
Authors: ANNBY U. , GRONOWITZ S. , HALLBERG A. 
Published: May 2016

AbstractThe hydrozirconation of various 1‐arylhexenes, e.g. (I), (III), and (V) with di‐π‐cyclopentadienylzirconium hydridochloride or its deuterated analogon and subsequent deuterolysis/hydrolysis, yielding deuterated 1‐arylhexanes, e.g. (II), (IV), and (VI), is studied under various conditions.
ChemInform Abstract: Preparation of Perhalogenated Chlorofluoropropanes by Halogen Exchange in the Liquid and Vapour Phases and Their Isomer Analyses by 19F NMR Spectroscopy.
Authors: KVICALA J. , PALETA O. , DEDEK V. 
Published: May 2016

AbstractMixtures of C3Cl5F3‐ and C3Cl4F4‐isomers of defined composition are subjected to several fluorination methods including treatment with SbF3Cl2 under atmospheric and autogenous pressure or with HF in the vapour phase over ferric chloride on charcoal.
ChemInform Abstract: Interannular Diastereoselectivity in the Hydroboration of Functionalized 1‐Cyclohexylcyclohexenes.
Authors: BELL T. W. , VARGAS J. R. , CRISPINO G. A. 
Published: May 2016

AbstractHydroboration of cyclohexylcyclohexenes such as (I), (VI), (VII), and (IX) with thexylborane is studied.
ChemInform Abstract: Electron Transfer Process. Part 45. Substitution Reactions in the β‐Styryl and Phenylethynyl Systems.
Authors: RUSSELL G. A. , NGOVIWATCHAI P. 
Published: May 2016

AbstractIrradiation of the alkenes (I) and the alkynes (IV) in the presence of the tert‐butylmercury reagent (II) yields the substitution products (III) and (V).
ChemInform Abstract: Nitrile‐Formamide Chloride Adducts. Part 13. Functionalized N‐Acylformamidinium Salts and Formamides as Acylating or Iminoformylating Reagents for Semicyclic Amidines and Special Amines.
Authors: BECHSTEIN U. , LIEBSCHER J. 
Published: May 2016

AbstractThe salts (I) or the formamide (V) are suitable reagents for the preparation of acylated amino compounds such as (III), (IV), or (VII).
ChemInform Abstract: Synthesis of 3‐Fluoro‐3‐nitroacrylic Acid Esters.
Authors: ORESHKO G. V. , LAGODZINSKAYA G. V. , EREMENKO L. T. 
Published: May 2016

Abstract1,3‐Difluoro‐1,1,3,3‐tetranitropropane (I) reacts with the alcohols (II) to give the nitrofluoroacrylic acid esters (III).
ChemInform Abstract: The Knoevenagel Reaction of Aldehydes with Methylene Compounds Having Keto Enol Tautomerism.
Authors: HIRAMATSU H. , HARADA K. , KOJIMA Y. , FUJIWARA K. 
Published: May 2016

AbstractThe title reaction between the aldehydes (I) and the activated ketones (II), yielding the condensation products (III) and the rearranged compound (IV), is investigated by means of 1H NMR.
ChemInform Abstract: Sequential Acetalization‐Pyrolysis of α‐Acetyl Benzalacetones. A Method for the Generation of 6‐Substituted 2‐Acetonaphthones.
Authors: ZOELLER J. R. 
Published: May 2016

AbstractThe benzaldehydes (I) are coupled with acetylacetone (II) to give the diacetylstyrenes (III) which are acetalized with the orthoformate (IV).
ChemInform Abstract: Preparation of 3‐Acyl‐5‐iminooxazolidines from α‐(Acylamino) Nitriles and Formaldehyde. Reactivity Studies Directed Towards Peptide Synthesis.
Authors: PASCAL R. , ROUSSET A. , COMMEYRAS A. 
Published: May 2016

AbstractThe hydrolysis of α‐amino nitriles in the presence of aqueous aldehydes and ketones is investigated and discussed in detail.
ChemInform Abstract: Synthesis of 3,4‐Disubstituted 3,4‐Dihydro‐2‐pyrones via 2‐(Silyloxy)pyrylium Salts: Regioselective Introduction of Substituents into 2‐Pyrones.
Authors: KUME T. , KOJIMA T. , IWASAKI H. , YAMAMOTO Y. , AKIBA K. 
Published: May 2016

AbstractSilylation of the pyrone (I) with the silyl triflate (II) gives the pyrylium salt (III) which reacts with the cuprates (IV) to produce regioselectively the pyrans (V).
ChemInform Abstract: Synthesis and Stereochemistry of Tetrahydrothiazolo(3,2‐d)(1,4)benzodiazepin‐3(2H)‐ones.
Authors: ZAPPALA M. , CHIMIRRI A. , GRASSO S. , ROMEO G. , MONFORTE A. M. 
Published: May 2016

AbstractThe thiazolobenzodiazepinones (III) are prepared by cyclization of the benzodiazepines (I) with mercaptoacetic acid (II).
ChemInform Abstract: Radical Substitution of Crown Ethers by 2‐Methylquinoline.
Authors: ZELECHONOK YU. B. , ZORIN V. V. , IVANOVA L. P. , ZLOTSKII S. S. , RAKHMANKULOV D. L. , TIMPE H.‐J. 
Published: May 2016

AbstractDerivatization of the most simple crown ether dioxane is known to take place by the Minisci reaction.
ChemInform Abstract: Difluorenyl(diorganylamino)boranes.
Authors: MARINGGELE W. , NOLTEMEYER M. , MELLER A. 
Published: May 2016

AbstractConsecutive reaction of fluorene (I) with potassium and the dichloro‐(diorganylamino)boranes (II) produces the title compounds (III) which are also obtained by lithiation of (I) with butyllithium and subsequent treatment with the compounds (II).
ChemInform Abstract: Dibutyl Cyanophosphite and Its Properties.
Authors: ROMANOV G. V. , SEMKINA E. P. , PUDOVIK A. N. 
Published: May 2016

AbstractDibutyl cyanophosphite (III), prepared from the chlorophosphite (I) and trimethylsilyl cyanide (II), reacts with tributystannane to give dibutyl phosphonite (IV).
ChemInform Abstract: Preparation, Crystal Structures, and Spectroscopic Characterization of Diaminochalcogenophosphonium Cations.
Authors: BURFORD N. , VON H. SPENCE R. E. , ROGERS R. D. 
Published: May 2016

AbstractTreatment of the bis(amido)thio(seleno)phosphoryl chlorides (I) with AlCl3 (II) afford the ionic dimeric products (III).
ChemInform Abstract: Synthesis and Properties of N‐Bis(trifluoromethyl)nitroxy‐iminoarsine (CF3)2NON=AsH: The First Two‐Coordinate Iminoarsine Containing an As=N Double Bond.
Authors: ANG H. G. , LEE F. K. 
Published: May 2016

AbstractThe title compound (III), the first example of a two‐coordinate iminoarsine, is synthesized as shown.
ChemInform Abstract: ((Li2(Me3SiCCN))12(Et2O)6(C6H14)), Crystal Structure with the Trimethylsilylacetonitrile Dianion.
Authors: ZARGES W. , MARSCH M. , HARMS K. , BOCHE G. 
Published: May 2016

AbstractDeprotonation of Me3Si‐CH2‐CN with either two molequiv.
ChemInform Abstract: Electrocrystallization and X‐Ray Structure of Partially Oxidized Stacked Porphyrin Trimers of the Form ((OEP)Ga)3F2(BF4)2·C7H8.
Authors: GUILARD R. , BARBE J.‐M. , RICHARD P. , PETIT P. , ANDRE J. J. , LECOMTE C. , KADISH K. M. 
Published: May 2016

AbstractSlow galvanostatic electrolysis of (I) in toluene/acetonitrile yields the title compound (III), which is characterized by conductivity measurements and X‐ray analysis (space group P21/c, Z=2).
ChemInform Abstract: Preparation and Characterization of New Terdentate Aminodiphosphines and Corresponding Vanadium(III) Dialkylamides.
Authors: DANOPOULOS A. A. , EDWARDS P. G. 
Published: May 2016

AbstractThe new terdentate aminodiphosphines (IV) are prepared and transformed into their Li amides (VI) according to the scheme.
ChemInform Abstract: Mo2(C6H4S2)5, the Purple Product in Molybdenum‐Dithiol Reactions: A Novel Molybdenum(V) Dimer Dithiolate Structure.
Authors: HALBERT T. R. , STIEFEL E. I. 
Published: May 2016

AbstractThe title compound (I) is formed together with tris‐(benzene‐1,2‐dithiolato)‐Mo by 1:3 molar reaction of MoCl4(THF)2 with benzene‐1,2‐thiol and isolated by column chromatography.
ChemInform Abstract: Cyclopentadienyl Substituted Diethylaminocarbyne Complexes of Tungsten in a Higher Oxidation State.
Authors: FILIPPOU A. C. 
Published: May 2016

AbstractThe equimolar reaction of the carbyne‐W(VI) complex (I) with tert.‐butylisocyanide (II) results in replacement of the CO ligand and formation of the non‐ionic product (III).
ChemInform Abstract: (Li(Me2NCH2CH2NMe2)2) (Li2(Me2NCH2CH2NMe2)2(.mu±eta.5,η5‐MeC5H4)) ((η5‐MeC5H4)6U2(μ‐Me))2: A Compound with Symmetrically Bridging MeC5H4 and Me Groups.
Authors: STULTS S. D. , ANDERSEN R. A. , ZALKIN A. 
Published: May 2016

AbstractThe structure of the paramagnetic title complex (IV) is described (X‐ray data not given).