bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Improvements in the Total Synthesis of Physostigmine: Reductive Cyclization of Oxindoles to Tricyclic Indoleninepyrrolidines with Lithium Aluminum Hydride in Tetrahydrofuran.
Authors: YU Q.‐S. , BROSSI A. 
Published: May 2016

AbstractReductive cyclization of the oxindole (I) and the carbamate (VII), prepared from (I) via the amine (VI), gives the pyrroloindoles (II) and (V).
ChemInform Abstract: 4‐Acetyl‐1‐(R‐benzylidene)‐3‐(5‐nitro‐2‐furfuryl)thiosemicarbazides: Synthons for the Formation of Thiazole and Triazole Rings.
Authors: KRAPIVIN G. D. , USOVA E. B. , KUL'NEVICH V. G. 
Published: May 2016

AbstractThe isothiosemicarbazides (V), prepared from the furfuryl bromide (I) and the thiosemicarbazides (II) via the salts (III), are cyclized in the presence of sodium acetate to give the thiazoles (VI).
ChemInform Abstract: Facile Route to 2,3‐Disubstituted Chromanones via Chromone‐3‐carboxaldehyde Activated by Silylation.
Authors: IWASAKI H. , KUME T. , YAMAMOTO Y. , AKIBA K. 
Published: May 2016

AbstractAldol condensation of chromone‐3‐carboxaldehyde (I) with the active methylene compounds (III) in the presence of tert‐butyldimethylsilyl triflate (II) gives the silylated adducts (IV).
ChemInform Abstract: Reaction of Silylamidophosphites with Chloral and Halonitroso Compounds.
Authors: LERMONTOV S. A. , ZAVORIN S. I. , MARTYNOV I. V. 
Published: May 2016

AbstractThe phoshoramidites (I) are coupled with chloral (II) to give the phosphonates (III) which are converted to the phosphoramidates (IV) upon distillation.
ChemInform Abstract: Analogous α,α′‐Bis‐Carbenoid Triply Bonded Species: Synthesis of a Stable λ3‐Phosphinocarbene‐λ5‐Phosphaacetylene.
Authors: IGAU A. , GRUETZMACHER H. + , BACEIREDO A. , BERTRAND G. 
Published: May 2016

AbstractDepending on the nature of the substituents and the experimental conditions transient or stable phosphinocarbenes are generated from the corresponding α‐diazophosphines such as (III).
ChemInform Abstract: Unbridged and Bridged Isomers of W2(PCy2)2(NMe2)4: Preparations, Characterizations, and Comments on Thermodynamic and Activation Parameters for the Closing of Phosphido Bridges in d3‐d3 Dinuclear Compounds.
Authors: BUHRO W. E. , CHISHOLM M. H. , FOLTING K. , HUFFMAN J. C. , MARTIN J. D. , STREIB W. E. 
Published: May 2016

AbstractThe reaction of (I) with the phosphide (II) yields the unbridged, gauche compound (III), which crystallizes in the space group Pnna with Z=4.
ChemInform Abstract: Semicorrin Metal Complexes as Enantioselective Catalysts. Part 1. Synthesis of Chiral Semicorrin Ligands and General Concepts.
Authors: FRITSCHI H. , LEUTENEGGER U. , SIEGMANN K. , PFALTZ A. , KELLER W. , KRATKY C. 
Published: May 2016

AbstractAn efficient synthesis of chiral semicorrin ligands such as (VI) or (VIII) is described.
ChemInform Abstract: Synthesis of Benzopyran Derivatives. Part 1. Synthesis of Analogues of Natural Precocene I Containing Various 7‐O‐Substituents.
Authors: TIMAR T. , HOSZTAFI S. , JASZBERENYI J. C. , KOEVER K. E. + , BATTA G. 
Published: May 2016

AbstractThe best allatotoxic activity is achieved with the title compounds (Vb) and (Vc).
ChemInform Abstract: Composition of the Reaction Products of the Acidic Triphosphates of Aluminum and Chromium with Hydroxylamine.
Authors: LYUTSKO V. A. , TUCHKOVSKAYA A. V. , SHIFRINA A. L. 
Published: May 2016

AbstractThe reaction between H2MP3O10·2 H2O (M: Al, Cr) and NH2OH in aqueous‐ethanolic solution affords the novel intercalation complexes (I) and (II).
ChemInform Abstract: 5‐Isopropylidene‐1,2‐oxathiole 2‐Oxide (IIIa) by Photoisomerization of 2,2‐Dimethyl‐3(2H)‐thiophenone 1‐Oxide (IIa).
Authors: KOWALEWSKI R. , MARGARETHA P. 
Published: May 2016

AbstractIn contrast to their precursors (I) which react completely differently, the sulfoxides (II) under irradiation (350 nm) isomerize to the oxathioloxides (III), even in the presence of isobutene and stereoselectively in the case (IIb) → (IIIb).
ChemInform Abstract: Hydrogen Peroxide Oxidation Catalyzed by Heteropoly Acids Combined with Cetylpyridinium Chloride: Epoxidation of Olefins and Allylic Alcohols, Ketonization of Alcohols and Diols, and Oxidative Cleavage of 1,2‐Diols and Olefins.
Authors: ISHII Y. , YAMAWAKI K. , URA T. , YAMADA H. , YOSHIDA T. , OGAWA M. 
Published: May 2016

AbstractUsing a combination of heteropoly acids such as H3PMo12O40 or H3PW12O40 with cetylpyridinium chloride as the catalyst, olefins such as (I) and (IV), and allylic alcohols, e.g. (VI), are oxidized with hydrogen peroxide (II) to give the epoxides (III), (V), and (VII).
ChemInform Abstract: Reaction of Hydroxy and Carbonyl Compounds with Sulfur Tetrafluoride. Part 20. Reactions of Glycols with SF4.
Authors: HASSANEIN S. M. , BURMAKOV A. I. , BLOSHCHITSA F. A. , YAGUPOL'SKII L. M. 
Published: May 2016

AbstractThe reactions between 1,2‐, 1,3‐ or 1,4‐diols and SF4, which are carried out according to method A) using the diols (I), (IV), (IX) or (XI) as the substrates, proceed via substitution of a hydroxy group by a fluorine atom to give the fluoro derivatives (III), (VII)/(VIII), (X) or (XII) either directly or after work‐up of the fluorosulfites (cf.
ChemInform Abstract: Syntheses and Flash Vacuum Pyrolyses of Highly Functionalized α‐N‐Hydroxy Amino Acids.
Authors: HUANG N. Z. , MILLER M. J. 
Published: May 2016

AbstractFlash vacuum pyrolysis of the sulfoxide (XII), prepared from L‐methionine (I) via the N‐hydroxy amino acid ester (VI), gives the vinyldihydropyridone (XIII) instead of a carbacephalosporin.
ChemInform Abstract: Thiono and Dithio Esters. Part 45. Properties and Reactions of Thiosuccinic and Thioglutaric Esters.
Authors: HARTKE K. , PFLEGING E. 
Published: May 2016

AbstractThiosuccinic and thioglutaric esters react with LDA to form the dithioenolates, predominantly with a di‐cis configuration concerning S‐.
ChemInform Abstract: Generation and Alkylation Reaction of 1‐Bromoalkenylzincate.
Authors: HARADA T. , HARA D. , HATTORI K. , OKU A. 
Published: May 2016

AbstractThe 1,1‐dibromoalkenes (I) react with lithium tributylzincate (II) at low temperature to give the alkenylzincates (III) which are hydrolyzed with acetic acid, forming the vinylic bromides (IV).
ChemInform Abstract: Lactones. Part 18. Synthesis of Lactone‐Bridged 1,1‐Diarylpropanamines.
Authors: LEHMANN J. , GOSSEN A. 
Published: May 2016

AbstractThe β‐aroylacrylic acids (I) react with the cyclic amines (II), yielding the γ‐keto‐α‐amino acids (III).
ChemInform Abstract: Cycloaddition of Isopropylidene Methylenemalonate to Isosafrole and Analogues.
Authors: STEVENSON R. , WEBER J. V. 
Published: May 2016

AbstractIsosafrole (I) and the styrenes (V) undergo cycloaddition reaction with isopropylidene methylenemalonate (II) to give the trioxaoctalinones (III) and (VI).
ChemInform Abstract: Studies on Ureas. Part 1. Preparation and Antimicrobial Activity of N‐Aryl‐N′‐(2‐(p‐chlorophenyl)‐1,3,4‐oxadiazol‐5‐ylacyl)ureas.
Authors: MEHTA L. , PAREKH H. 
Published: May 2016

AbstractThe hydrazide (I) reacts with p‐chlorobenzoic acid (II) to form the oxadiazole (III) which is saponified, producing the acid (IV).
ChemInform Abstract: Reaction of Chlorosulfonyl Isocyanate with Nitrones: An Efficient Method for the Synthesis of Cyclic Enamides and 2H‐Pyrroles.
Authors: JOSEPH S. P. , DHAR D. N. 
Published: May 2016

AbstractA series of nitrones such as (I) and (III), derived from cyclic conjugated ketones, is treated with chlorosulfonyl isocyanate according to A).
ChemInform Abstract: Polyfunctional Macroheterocycles. Part 1. Synthesis of Macroheterocycles Containing Sulfur with Endocyclic Carboxamide or Sulfonamide Groups.
Authors: VORONKOV M. G. , KNUTOV V. I. , BUTIN M. K. 
Published: May 2016

AbstractMacroheterocycles such as (III), (VI), or (VII) are prepared by coupling of (substituted) diamines with the corresponding dichlorides.
ChemInform Abstract: Synthesis of Boron Analogues of Carbamic Acid Derivatives via the Amine‐Isocyanoethane‐Dihydroboron(III) Cation.
Authors: GYOERI B. + , LAZAR I. , EMRI J. 
Published: May 2016

AbstractAlkylation of the boron complex (I) with triethyloxonium tetrafluoroborate (II) yields the ethyl isocyanide salt (III).
ChemInform Abstract: Synthesis, NMR Spectroscopic Investigation, and Crystal Structures of 1,3‐Dihydro‐2λ4‐benzotellurole‐2,2‐diyl Bis(diethyldithiocarbamate), C8H8Te(S2CNEt2)2; S,S′‐1,3‐Dihydro‐2λ4‐benzotellurole‐2,2‐diyl O,O,O′,O′‐Tetraethyl Bis(dithiophosphate), C8H8Te(S2P(OEt)2)2; and 1,3‐Dihydro‐2λ4‐benzotellurole‐2,2‐diyl Bis(O‐ethyl xanthate), C8H8Te(S2COEt)2.
Authors: DAKTERNIEKS D. , DI GIACOMO R. , GABLE R. W. , HOSKINS B. F. 
Published: May 2016

AbstractThe title compounds (III), (IV), and (V) are prepared by 1:2 molar reaction of the diiodobenzotellurole (I) with the dithiocarbamate (II), potassium O,O'‐diethyl dithiophosphate, or potassium xanthate, respectively.
ChemInform Abstract: Isolation and X‐Ray Crystal Structure of the First Dinitrogen Complex of an f‐Element Metal, ((C5Me5)2Sm)2N2.
Authors: EVANS W. J. , ULIBARRI T. A. , ZILLER J. W. 
Published: May 2016

AbstractSlow crystallization of (η5‐C5Me5)2Sm from toluene over a 4‐week period gives a quantitative yield of the title compound (I).
ChemInform Abstract: Internal Electron Transfer in a Quinone Adduct of a Nickel(II)‐Catecholate Complex.
Authors: BENELLI C. , DEI A. , GATTESCHI D. , PARDI L. 
Published: May 2016

AbstractThe tetrachlorocatecholatonickel(II) complex of the cyclic triamine reacts reversibly with tetrachlorobenzoquinone to give the Ni(I) complex (I), which crystallizes in P21/c with Z=4.
ChemInform Abstract: Photochemical Activation of CO2. Transient Absorbance Kinetic Studies of the Addition of CO2 to a Metal‐to‐Bridging Ligand Charge‐Transfer State of a Binuclear Ni(0) Complex.
Authors: LEMKE F. R. , DELAET D. L. , GAO J. , KUBIAK C. P. 
Published: May 2016

AbstractThe spectroscopy and reactivity of the excited state involved in the photochemical reaction of (I) with CO2 (II) is studied.
ChemInform Abstract: Five‐Coordinate Compounds of Nickel(II) and Copper(II) with the Triamine Diimine Ligands 13‐Imino‐4,4,6,11,11‐pentamethyl‐3,7,10‐triazatetradec‐6‐en‐1‐amine and 4,6,11‐Triethyl‐13‐imino‐4,11‐dimethyl‐3,7,10‐triazapentadec‐6‐en‐1‐amine.
Authors: CURTIS N. F. 
Published: May 2016

AbstractNi(II) dichloride (II) reacts with the tetraaza macrocycles (I) in the presence of ammonia (III) to give the Ni complexes (Va) of the noncyclic title ligands.
ChemInform Abstract: Phosphane‐Stabilized Cu(I) and Ag(I) Silanes.
Authors: COWLEY A. H. , ELKINS T. M. , JONES R. A. , NUNN C. M. 
Published: May 2016

AbstractThe tetrahedral Cu(I) silane (IVa) is obtained according to the scheme and characterized by NMR (31P, 29Si) data and X‐ray structure analysis (space group Cc, Z=4).
ChemInform Abstract: Reversible Metal‐Metal Bond Cleavage Accompanied by the Facile Reversible Addition of H2 to a Ru3 Cluster. Synthesis and X‐Ray Structures of Ru3(CO)8(μ‐H)2(μ‐tBu2P)2 and Ru3(CO)8(μ‐H)2(H)2(μ‐tBu2P)2.
Authors: ARIF A. M. , BRIGHT T. A. , JONES R. A. , NUNN C. M. 
Published: May 2016

AbstractThe bis(phosphido)‐bridged trinuclear cluster (III) is obtained according to the scheme and characterized by IR, 1H and 31P NMR spectroscopic data and X‐ray structure analysis.
ChemInform Abstract: Micro‐Raman Spectra of YBaCuO Superconductors.
Authors: HUONG P. V. , GRENIER J. C. , BEZDICKA P. 
Published: May 2016

AbstractReproducible micro‐Raman polarization spectra can be recorded for Y‐Ba‐Cu‐O superconducting materials under well defined experimental conditions and controversial results reported in the literature are clarified.
ChemInform Abstract: Fluorosilicate Equilibria in Acid Solution.
Authors: CIAVATTA L. , IULIANO M. , PORTO R. 
Published: May 2016

AbstractThe reaction between silicic acid and the fluoride ion in aqueous solutions is investigated at 25 °C in the acidity range 0.3‐3 M in a 3 M LiClO4 medium.
ChemInform Abstract: The Rate Constant of the Gas Phase Reaction of SO3 with H2O
Authors: WANG X. , JIN Y. G. , SUTO M. , LEE L. C. , O'NEAL H. E. 
Published: May 2016

Abstractis measured in He and in N2 at total pressures of 1‐10 torr in a flow tube at room temperature.
ChemInform Abstract: Organocuprate Conjugate Addition to 2,3‐Dihydro‐4H‐pyran‐4‐ones.
Authors: BORING D. L. , SINDELAR R. D. 
Published: May 2016

AbstractReaction of isophorone (I) and the pyranone derivative (VI) with vinylmagnesium bromide (II) or vinyllithium (III) in the presence of copper compounds leads to the formation of the 1,4‐adducts (IV) and (VII), together with minor amounts of the 1,2‐adducts (V) and (VIII).
ChemInform Abstract: Switching of the Reaction Pathway for (1,2)/(1,4)‐ and (2,3)‐Wittig Rearrangements of 3‐Aryl‐2‐propenyl Propargyl Ethers.
Authors: HAYAKAWA K. , HAYASHIDA A. , KANEMATSU K. 
Published: May 2016

AbstractTreatment of the allyl propargyl ethers (I) with butyllithium results in rearrangement, producing the alcohols (II) and the aldehydes (III) with predominance of (II).
ChemInform Abstract: Photochemistry of β,γ‐Enones. Part 11. Photochemical Reactivities of Cyclic α‐Phenyl‐β,γ‐enones. Singlet 1,3‐Acyl Shift, Decarbonylation and Unquenchable Oxa‐di‐π‐methane Reactions Upon Direct Irradiation.
Authors: KOPPES M. J. C. M. , CERFONTAIN H. 
Published: May 2016

AbstractThe photochemistry of the substrates (IIa), (IIb) (VIII) and (XI) is investigated.
ChemInform Abstract: Photochemistry of Aminoketones. Part 13. Synthesis and Photochemistry of Methyl N‐(β‐Benzoylethyl)‐N‐(D‐camphor‐10‐sulfonyl)glycinates (VI).
Authors: HENNING H.‐G. , URBAN B. , KERNCHEN F. 
Published: May 2016

AbstractThe Mannich compounds (IV) are transformed to the title compounds (VI); the diastereomers (VIb) and (VIc) are poorly separable.
ChemInform Abstract: A Short Synthesis of a Pyrrole Derivative Having a Chiral Substituent.
Authors: KIYOOKA S. , SEKIMURA Y. , KAWAGUCHI K. 
Published: May 2016

AbstractN‐Benzyloxycarbonyl‐L‐prolyl chloride (I) is converted to the (2S)‐pyrrolyl‐2‐pyrrolidine (VI) in a three‐step sequence via coupling with the acetal (II), deprotection, and ring closure of the keto aldehyde (IV) with benzylamine (V).
ChemInform Abstract: Synthesis of 2‐Substituted 4‐Pyridylpropionates. Part 1. Claisen Condensation Approach.
Authors: ADGER B. M. , BANNISTER R. , LEWIS N. J. , O'FARRELL C. 
Published: May 2016

AbstractThe pyridylpropionate (VI), which is a key intermediate in the preparation of a histamine H2‐receptor antagonist, is prepared via two different reduction routes.
ChemInform Abstract: New m‐Phenylene‐bis‐disubstituted Phosphanes.
Authors: SCHOPFERER M. , SCHMITT G. , PRITZKOW H. , LATSCHA H. P. 
Published: May 2016

AbstractThe m‐phenylene‐bis(dichlorophosphane) (I) is converted into the derivatives (V), (VI) and (VIII) as well as via (Va) into (IX) as demonstrated in the scheme.
ChemInform Abstract: A Novel Approach to Hetarylmethyl‐ and Hetarylethylphosphonates and Their Free Acids.
Authors: ZBIRAL E. , DRESCHER M. 
Published: May 2016

AbstractThe (hetarylmethyl)triphenylphosphonium bromides (I) react with diethyl phosphite (II) and a base or with ethyl diethoxyphosphorylacetate (V) and a base to produce the hetarylmethyl‐ (III) or hetarylethylphosphonates (VI).
ChemInform Abstract: Synthesis of Mixed Oligomeric Heteroarylenes Containing Thiophene and Selenophene Rings. Their UV Spectra and Oxidation Potentials.
Authors: SHABANA R. , GALAL A. , MARK H. B. JUN. , ZIMMER H. , GRONOWITZ S. , HOERNFELDT A. B. + 
Published: May 2016

AbstractNi(II)‐catalyzed cross‐coupling reaction of the Grignard compounds (I) with the bromoselenophenes (II) and 2,5‐dibromoselenophene (IV) yields the mixed bihetaryls (III) and (V).
ChemInform Abstract: Complexes of Lanthanoid Salts with Macrocyclic Ligands. Part 34. Glasslike Structure in Crystalline Macrocyclic Complexes: Synthesis, X‐Ray Diffraction, and Laser‐Spectroscopic Investigation of Neodymium(III) and Europium(III) Complexes with 4,13‐Dimethyl‐1,7,10,16‐tetraoxa‐4,13‐diazacyclooctadecane.
Authors: NICOLO F. , PLANCHEREL D. , CHAPUIS G. , BUENZLI J.‐C. G. + 
Published: May 2016

AbstractEu and Nd nitrates (I) react with the macrocyclic ligand (II) to yield the complexes (III) with a 4:3 metal:ligand ratio.
ChemInform Abstract: Preparation and Characterization of Tris(trimethylsilyl)silyl and Tris(trimethylsilyl)germyl Derivatives of Zirconium and Hafnium. X‐Ray Crystal Structures of (η5‐C5Me5)Cl2HfSi(SiMe3)3 and (η5‐C5Me5)Cl2HfGe(SiMe3)3.
Authors: ARNOLD J. , RODDICK D. M. , TILLEY T. D. , RHEINGOLD A. L. , GEIB S. J. 
Published: May 2016

AbstractBy reaction of the compounds (II) with the appropriate halide compounds (I) and (IV) the new type of group 4 derivatives (III) and (V) are prepared.
ChemInform Abstract: Transition‐Metal Carbonyl Derivatives of the Germanes. Part 18. Tetracarbonylbis(permethylgermyl)iron Compounds (Fe(CO)4(GeMe3‐xHx)(GeMe3‐yHy)) for x,y = 0‐3.
Authors: AUDETT J. A. , MACKAY K. M. 
Published: May 2016

AbstractThe new mixed‐germyl compounds (III) are prepared by the route shown for the example (IIIa).
ChemInform Abstract: Alkaline Hydrolysis of Bridged and Monodentate Sulfato Complexes of Cobalt(III). X‐Ray Structure of (Co(en)2(OS(O)2O))2ZnCl4·H2O Containing cis‐Bis(μ‐sulfato) Bridges.
Authors: BUCKINGHAM D. A. , CLARK C. R. , SIMPSON J. , ROBINSON W. T. 
Published: May 2016

AbstractBy X‐ray analysis the previously described four‐membered sulfato chelate (Co(en)2(O2SO2))+ is characterized to be the dimeric complex (I), which crystallizes in the space group C2/c with Z=4.
ChemInform Abstract: Reactions of 1,2‐Dicarbonyls with Metallic Copper Under Argon and Dioxygen. Oxidative C‐C Bond Scission by Metallic Copper.
Authors: SPEIER G. , TYEKLAR Z. 
Published: May 2016

AbstractThe diketones (I) react with metallic Cu by electron transfer from Cu to (I) leading to semidionatocopper(I) and μ‐enediolato‐dicopper(I) complexes in low equilibrium concentrations as detected by ESR and electronic spectra.
ChemInform Abstract: Cylopentadienyl Ruthenium and Osmium Chemistry. Part 31. Preparation of Some Complexes Containing 1,1′‐Bis(diphenylphosphino)ferrocene (dppf): X‐Ray Structure of RuH(dppf)(η‐C5H5).
Authors: BRUCE M. I. , BUTLER I. R. , CULLEN W. R. , KOUTSANTONIS G. A. , SNOW M. R. , TIEKINK E. R. T. 
Published: May 2016

AbstractExchange of triphenylphosphine in (I) with the title ligand (II) yields the complex (IVa), which is converted into the hydrido complex (IVb) (X‐ray analysis: space group P1, Z=4).
ChemInform Abstract: Synthesis and Molecular Structures of a Rhoda‐Lactone and Its Alkylation Product. Insertion of a Pendant Alkyne into a Rhodium‐Hydrogen Bond.
Authors: MARDER T. B. , CHAN D. M.‐T. , FULTZ W. C. , MILSTEIN D. 
Published: May 2016

AbstractThe pentynoic acid (II) reacts with the rhodium complex (I) via addition of the acid moiety and subsequent insertion, producing the rhoda‐lactone (III).
ChemInform Abstract: Design and Synthesis of Sulfur‐Containing Morphine and an Opioid Receptor Probe.
Authors: FUJII I. , TOGAME H. , YAMAMOTO M. , KANEMATSU K. , TAKAYANAGI I. , KONNO F. 
Published: May 2016

AbstractMitsunobu reaction of morphine (I), dihydromorphine (IV), and dihydrocodeine (VI) with thioacetic acid (II) yields the thioesters (III), (Vb), and (VII).
ChemInform Abstract: Synthesis of Benzopyran Derivatives. Part 4. Synthesis of Analogues of Natural Precocenes Containing a 8‐Methyl Substituent.
Authors: TIMAR T. , HOSZTAFI S. , JASZBERENYI J. C. 
Published: May 2016

AbstractWith a view to the antijuvenile hormone activity of precocenes the title derivatives (V) are prepared.
ChemInform Abstract: Generation and Characterization of Sulfurous Acid (H2SO3) and Its Radical Cation as Stable Molecules in the Gas Phase.
Authors: SUELZLE D. + , VERHOEVEN M. , TERLOUW J. K. , SCHWARZ H. 
Published: May 2016

AbstractThe radical cation (II) and the neutral species (III) can be generated by dissociative ionization (70 eV) of (I).
ChemInform Abstract: 14N NMR Studies of Amine Release from Platinum Anticancer Drugs: Models and Human Blood Plasma.
Authors: NORMAN R. E. , SADLER P. J. 
Published: May 2016

AbstractThe results show that 14N NMR spectroscopy provides useful information about amine release from cis‐PtCl2(NH3)2 and related complexes under biologically relevant conditions.
ChemInform Abstract: Experimental and Theoretical Studies of the Copper(I) and Silver(I) Dinuclear N,N′‐Di‐p‐tolylformamidinato Complexes.
Authors: COTTON F. A. , FENG X. , MATUSZ M. , POLI R. 
Published: May 2016

AbstractThe two title compounds (I) are characterized by X‐ray crystallography ((Ia): space group Pccn, Z=4 and (Ib): Pnaa, Z=4) and visible spectroscopy.
ChemInform Abstract: The Gas‐Phase Displacement Reaction of Chloride Ion with Methyl Chloride a a Function of Kinetic Energy.
Authors: BARLOW S. E. , VAN DOREN J. M. , BIERBAUM V. M. 
Published: May 2016

AbstractTaking advantage of the high sensitivity of a new tandem Flowing Afterglow‐SIFT‐Drift instrument described elsewhere a rate coefficient of 3.5 · 10‐14 cm3/s is determined for the reaction 37Cl‐ + Me35Cl → 35Cl‐ + Me37Cl (300 K; reaction efficiency = 2 · 10‐5).
ChemInform Abstract: The Chemistry of Organobismuth Reagents. Part 13. Ligand Coupling Induced by Pd(0).
Authors: BARTON D. H. R. , OZBALIK N. , RAMESH M. 
Published: May 2016

AbstractPalladium zero generated from Pd(OAc)2 and NEt3 converts the triarylbismuths (I) quantitatively into the biaryls (II).
ChemInform Abstract: Substituted o‐Iodoso‐ and o‐Iodoxybenzoic Acids: Synthesis and Catalytic Activity in the Hydrolysis of Active Phosphorus Esters and Related Systems.
Authors: KATRITZKY A. R. , DUELL B. L. , DURST H. D. , KNIER B. L. 
Published: May 2016

AbstractThe o‐iodosobenzoic acids (I) and (III) are prepared by oxidative chlorination of the corresponding o‐iodo compounds, while the o‐iodoxybenzoic acids (II) and (IV) are obtained from the same starting materials by oxidation with H2O2/Ac2O. The o‐iodoxybenzoic acids (VII) and (X) are synthesized from the benzoic ester (V).
ChemInform Abstract: A Highly Selective Method for the Synthesis of E‐α‐Methyl‐α,β‐Unsaturated Aldehydes.
Authors: DESMOND R. , MILLS S. G. , VOLANTE R. P. , SHINKAI I. 
Published: May 2016

AbstractThe aldehydes (I) are coupled with the lithiated enamines (II) to give the unsaturated imines (III).
ChemInform Abstract: Organo‐Tin Clusters. Part 5. Crown and Extended Organooxotin Compounds Formed with Phosphinate Ligands. A New Class of Tetranuclear Tin Clusters.
Authors: SWAMY K. C. K. , SCHMID C. G. , DAY R. O. , HOLMES R. R. 
Published: May 2016

AbstractThe synthesis of the three tetranuclear clusters (III), (Va), and (Vb) occurs according to the scheme.
ChemInform Abstract: Synthesis, Magnetism and Crystal Structure of (V2O2(μ‐OH)2(tpen))I2·4 H2O: A Binuclear Complex Containing the syn‐(VO(μ‐OH)2VO)2+ Core (tpen: tetrakis(2‐pyridylmethyl)ethylenediamine).
Authors: NEVES A. , WIEGHARDT K. , NUBER B. , WEISS J. 
Published: May 2016

AbstractThe reaction of the six‐dentate title ligand with VCl3 in refluxing acetonitrile yields the neutral binuclear complex (I) which is hydrolyzed in water in the presence of air affording the title complex (III).
ChemInform Abstract: Monooxo‐Capped Tritungsten Carboxylate Clusters.
Authors: BINO A. , COTTON F. A. , DORI Z. , SHAIA‐GOTTLIEB M. , KAPON M. 
Published: May 2016

AbstractAn improved method for the preparation of the monooxotritungsten hexaacetate cluster (IIIa) is described starting with Na tungstate (I) as demonstrated in the scheme.
ChemInform Abstract: Metathesis‐Like Reactions Between the Carbene Complex (CO)5W=C(OMe)Ph and Organic Nitroso Reagents.
Authors: PILATO R. S. , WILLIAMS G. D. , GEOFFROY G. L. , RHEINGOLD A. L. 
Published: May 2016

AbstractReactions between the carbene complex (I) and various nitroso compounds R‐NO (R: Ph, tBu, 2,4,6‐tri‐tert.‐butylphenyl) and (II) are studied in order to evidence the formation of (OC)5W=NR species on these metathesis‐like reactions.