bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Alkoxylation, Thiolation, and Hydrazination of α,β‐Unsaturated Nitro Olefins Under Aprotic Conditions.
Authors: HWU J. R. , WANG N. 
Published: May 2016

AbstractTreatment of the nitro olefins (I) and (IV) with the nucleophiles (II) or (VII) results in the formation of the Michael adducts (III) or (V).
ChemInform Abstract: HCl‐Catalyzed Photoreduction of 4‐Bromonitrobenzene as a Concomitant of Nucleophilic Aromatic Photosubstitution Involving Radical Intermediates.
Authors: WUBBELS G. G. , SNYDER E. J. , COUGHLIN E. B. 
Published: May 2016

AbstractWhereas 2‐bromonitrobenzene is unreactive toward photosubstitution by Cl‐ (although some other products such as a trichloroaniline resulting from photoreduction may be detected by GC/MS), 4‐bromobenzene (I) on irradiation (313 nm) in acidic solution (AcOH/H2O or aqueous HCl, e.g.) containing LiCl gives the product of photosubstitution (II).
ChemInform Abstract: Diphenylacetic Acid from Benzilic Acid: An Ecologically and Economically Improved Procedure.
Authors: STRAZZOLINI P. , GIUMANINI A. G. , VERARDO G. 
Published: May 2016

AbstractBenzilic acid (I) is dimerized in the presence of p‐toluenesulfonic acid under azeotropic removal of water, yielding the cyclic diester (II).
ChemInform Abstract: Cerium(IV) Oxidations of β‐Amino Ketones. Part 3. A Pathway to 4‐Spiro‐Substituted 1,2,3,4‐Tetrahydroisoquinolines.
Authors: HOLZGRABE U. 
Published: May 2016

AbstractThe dimethylaminomethylcycloalkanones (I) react with the N‐methylbenzylamines (II) to yield the benzylated amino ketones (III) which are oxidatively cyclized with Ce(SO4)2, forming the spiro‐fused tetrahydroisoquinolines (IV).
ChemInform Abstract: Monoiodination of 3‐Chloro‐6‐(2‐methoxybenzyl)pyridazine.
Authors: JONES S. , LEWIS N. , O'FARRELL C. , WALLBANK P. 
Published: May 2016

AbstractMonoiodination of the title compound (I) to give (II) is achieved using iodine in the presence of various oxidants such as ammonium persulfate or nitric acid.
ChemInform Abstract: Synthesis of 5‐Alkyl‐2‐(p‐cyanophenyl)pyrimidines.
Authors: MIKHALEVA M. A. , KOLESNICHENKO G. A. , MAMAEV V. P. 
Published: May 2016

AbstractThe title compounds (V) and (VIII) are prepared either by condensation of the ethoxyacroleins (I) with p‐bromobenzamidine hydrochloride (II) and subsequent treatment of (III) with CuCN (IV) or by condensation of the ethoxyacroleins (VI) with p‐cyanobenzamidine hydrochloride (VII).
ChemInform Abstract: Preparation of Pyrazolo(1,5‐a)pyridine and (1,2,4)Triazolo(1,5‐a)pyridine Derivatives from 1,6‐Diaminopyridine‐2‐thiones.
Authors: MOLINA P. , TARRAGA A. , GARCIA C. 
Published: May 2016

AbstractCyclocondensation of the diaminopyridinethiones (I) with the bromoacetophenones (II) or the nitriles (VI) yields the pyridothiadiazinium bromides (III) or the triazolopyridinethiones (VII).
ChemInform Abstract: Protonation of Decamethylsilicocene (Bis(pentamethylcyclopentadienyl)silicon).
Authors: JUTZI P. , HOLTMANN U. , BOEGGE H. + , MUELLER A. + 
Published: May 2016

AbstractReaction of decamethylsilicocene (I) with the acids (II) gives the adducts (III).
ChemInform Abstract: 2‐Nitroglucals. Preparation and Nucleophilic Addition Reactions.
Authors: HOLZAPFEL C. W. , MARAIS C. F. , VAN DYK M. S. 
Published: May 2016

AbstractReaction of the glucals (I) with nitronium tetrafluoroborate (II) and subsequent treatment with DBN produce the 2‐nitroglucals (IV) via the nitro fluorides (III) which are not isolated in general.
ChemInform Abstract: Model for the Aspartate Proteinases: Hydrolysis of a Distorted Amide Catalyzed by Dicarboxylic Acids Capable of Forming Cyclic Anhydrides.
Authors: SOMAYAJI V. , KEILLOR J. , BROWN R. S. 
Published: May 2016

AbstractThe diacid‐catalyzed hydrolysis of the distorted amide (I) proceeds via an intermediate linear anhydride which is converted into the amino acid (III) and a stable anhydride such as (IV).
ChemInform Abstract: Oxycarbide Glasses in the Mg‐Al‐Si‐O‐C System
Authors: HOMENY J. , NELSON G. G. , RISBUD S. H. 
Published: May 2016

Abstractare produced (1750‐1800 °C,1 h, nitrogen atmosphere) at initial carbon levels of 0‐2.5 wt.% (added to the melt as SiC).
ChemInform Abstract: Synthesis and Structure Determination from Powder Diffraction Data of LaMo5O8, a New Oxomolybdate Containing Mo10 Clusters.
Authors: HIBBLE S. J. , CHEETHAM A. K. , BOGLE A. R. L. , WAKERLEY H. R. , COX D. E. 
Published: May 2016

AbstractA mixture of La2Mo3O12 and Mo corresponding to a composition of La2Mo9O12 is annealed at 1200 °C (evacuated silica ampoule, 5d).
ChemInform Abstract: Characterization of AlPO4 and SAPO Molecular Sieves by 129Xe NMR Spectroscopy.
Authors: DAVIS M. E. , SALDARRIAGA C. , MONTES C. , HANSON B. E. 
Published: May 2016

AbstractThe 129Xe chemical shift observed in the spectra of AlPO4‐n and SAPO‐n molecular sieves moves downfield with decreasing channel and cavity size and decreasing P content in the framework.
ChemInform Abstract: 125Te Moessbauer Spectra of the Intercalation Compound (Te2)2(I2).
Authors: BERRY F. J. , GIBBS C. D. , SARSON M. I. , KNIEP R. , BEISTER H. J. 
Published: May 2016

AbstractThe Moessbauer spectra recorded from (Te2)2(I2) in which monomolecular layers of iodine molecules are intercalated between layers of tellurium, are consistent with a recently proposed model on which the electronic band structure of the compound has been derived.
ChemInform Abstract: DC Conductivity Studies of an Hydroxide Ion Conductor at Intermediate Temperatures.
Authors: CROUCH‐BAKER S. , HUGGINS R. A. 
Published: May 2016

AbstractThe dc conductivity of wet Li5AlO4 is measured as a function of temp. (390‐540 °C) and applied voltage (∼ 0.5‐2 V) and is shown to rise sharply in the temp. range 415‐450 °C at a given voltage, and at ∼ 1 V for a constant temperature.
ChemInform Abstract: Investigation of Phase Formation in the System TiO2‐Sm2O3 by the Method of Shock Wave Synthesis.
Authors: KOLESNIKOV A. V. , SHCHERBAKOVA L. G. 
Published: May 2016

AbstractShock wave treatment of the title system affords, inter alia, two novel compounds: Sm4Ti3O12 and a hexagonal β‐phase (between 43 and 50 mol%).
ChemInform Abstract: Effects of Solution pH on the Voltammetric Behavior of Ferrous/Ferric Ions at Zeolite‐Modified Electrodes.
Authors: IWAKURA C. , MIYAZAKI S. , YONEYAMA H. 
Published: May 2016

AbstractThe redox peak currents in the cyclic voltammograms of iron‐exchanged zeolite‐modified electrodes are shown to increase almost linearly with the H+ ion concentration in the pH region of 2.0‐1.0.
ChemInform Abstract: Oxidation State of Cerium in Cerium‐Based Catalysts Investigated by Spectroscopic Probes.
Authors: LE NORMAND F. , HILAIRE L. , KILI K. , KRILL G. , MAIRE G. 
Published: May 2016

AbstractPd‐Ce catalysts, prepared by coimpregnation on γ‐Al2O3, calcined at 200 °C, and reduced in H2 at 400 °C, are studied by XPS on the 3d core level and XAS on the LIII edge of Ce.
ChemInform Abstract: Effect of Molybdenum Addition to Rh/SiO2 Catalysts: Appearance of a Second Rhodium Dicarbonyl Species.
Authors: WARDINSKY M. D. , HECKER W. C. 
Published: May 2016

AbstractThe IR spectra of SiO2‐supported Rh catalysts prepared by consecutive impregnation with aqueous solutions of (NH4)6Mo7O24 and RhCl3 show a new rhodium dicarbonyl species with characteristic bands at 2110 and 2052 cm‐1 after treatment of the catalyst with CO at room temperature.
ChemInform Abstract: Preparation and X‐Ray Structure of a Mixed‐Metal Double‐Cubane‐Type Aqua Ion ((H2O)9Mo3S4CuCuS4Mo3(H2O)9)8+.
Authors: SHIBAHARA T. , AKASHI H. , KUROYA H. 
Published: May 2016

AbstractThe title cation is prepared by reaction of Mo3S4(aq)4+ with metallic Cu under N2 atmosphere and the structure of the salt (I) obtained by elution of the cation from a cation exchanger (Dowex 50W‐X2) with p‐toluenesulfonic acid is determined.
ChemInform Abstract: Equilibrium and Structural Studies of Silicon(IV) and Aluminum(III) in Aqueous Solution. Part 16. Complexation and Precipitation Reactions in the H+‐Al3+‐Phthalate System.
Authors: HEDLUND T. , BILINSKI H. , HORVATH L. , INGRI N. , SJOEBERG S. + 
Published: May 2016

AbstractPotentiometric and tyndallometric measurements show that the Al complexation is characterized by the formation of binary 1:1 and 1:2 metal to ligand species as well as by polynuclear mixed hydroxo complexes.
ChemInform Abstract: Equilibrium and Kinetic Studies of the Complexing of Iron(III) by 1,2‐Dihydroxybenzene Derivatives.
Authors: XU J. , JORDAN R. B. 
Published: May 2016

AbstractThe formation constants for the complexation of Fe(III) with 2,3‐dihydroxybenzoic acid and 1,2‐dihydroxy‐3,5 benzenedisulfonate (Tiron) are determined and compared with the previously studied salicylic acid system.
ChemInform Abstract: Photochromic Systems. Part 13. Photochromism of Simple 1,8a‐Dihydroindolizines and 1,8a‐Dihydro‐5‐azaindolizines.
Authors: DORWEILER C. , HOLDERBAUM M. , MUENZMAY T. + , SPANG P. , DUERR H. + , KRUEGER C. + , RAABE E. 
Published: May 2016

AbstractThe photochromic title compounds, i.e. 14 derivatives of type (VIII), are prepared from 8 diarylpyrazoles (e.g.
ChemInform Abstract: Thiazines and Thiabenzene 1‐Oxides by Conversion of S,S‐Dimethylsulfoximine and Dimethyloxosulfoniummethanide with 1,3‐Bis‐Electrophiles.
Authors: RIED W. , SAYNOVITS M. 
Published: May 2016

AbstractReactions of the malononitriles (I) with the title compounds (II) and (VI) give rise to the formation of the thiopyrans (III)/(V) and the thiazines (VIII)/(IX).
ChemInform Abstract: Deamination Reactions. Part 50. 2‐Thia‐5‐ and ‐6‐norbornyl Cations and Their S,S‐Dioxides.
Authors: KIRMSE W. , MROTZECK U. 
Published: May 2016

AbstractThe effect of the S or SO2 bridges on the rearrangement of the title cations is studied.
ChemInform Abstract: 5‐Benzylidene‐1,3‐dimethylbarbituric Acid Derivatives, Mild Organic Oxidants for Allylic and Benzylic Alcohols.
Authors: TANAKA K. , CHEN X. , KIMURA T. , YONEDA F. 
Published: May 2016

AbstractThe barbituric acid (I) is coupled with the aromatic aldehydes (II) to give the benzylidene derivatives (III).
ChemInform Abstract: Selective Hydrogenation of Internal and Terminal CC Bonds on Rare Earth Catalysts Formed by Metal Vapor Deposition.
Authors: IMAMURA H. , KITAJIMA K. , TSUCHIYA S. 
Published: May 2016

AbstractRare earth catalysts, obtained from Sm and Yb by metal vapor deposition on a frozen THF matrix, are employed in the hydrogenation of various acetylenic derivatives such as (I) to give the corresponding alkenes, together with regioisomers and dienes.
ChemInform Abstract: Fluorination of Hydrogen‐Containing Olefins with Elemental Fluorine.
Authors: CONTE L. , GAMBARETTO G. P. , NAPOLI M. , GERVASUTTI C. 
Published: May 2016

AbstractSeveral olefins (I) ‐ (V) containing hydrogen and chlorine are fluorinated with elemental fluorine to give good yields of the corresponding addition products.
ChemInform Abstract: Allylation of Active Methylene Compounds with Allyl Oxime Carbonates Catalyzed by Pd(0).
Authors: SUZUKI O. , HASHIGUCHI Y. , INOUE S. , SATO K. 
Published: May 2016

AbstractDiethyl malonate (I) reacts with the allyl oxime ethers (IIa) or the allyl oxime carbonates (IIb) ‐ (IId) in the presence of a Pd catalyst, yielding the mono‐ (III) and diallylated products (IV).
ChemInform Abstract: Regioselective Methylation of Epoxides Using Transition Metal Complexes.
Authors: HASE T. , MIYASHITA A. , NOHIRA H. 
Published: May 2016

AbstractThe oxirane (I) is cleaved with methyl iodide (II) in the presence of tetrakis(triphenylphosphine) complexes, yielding 2,2‐dimethylpropanol (III) as the main product, together with minor amounts of the isomeric alcohol (IV) or the aldehyde (V).
ChemInform Abstract: Liquid Phase Oxidation of 2,3‐Dichloropropene‐1 with Oxygen.
Authors: KYAZIMOV SH. K. , RZAEVA A. M. , PONOMAREVA G. S. , ALIEVA F. M. 
Published: May 2016

Abstract2,3‐Dichloropropene (I) and 2,3‐dichloropropane (II) are waste products in the production of epichlorohydrin.
ChemInform Abstract: Synthesis of 2‐Substituted Methylenecycloalkanes via 1‐(Dialkylborylmethyl)cycloalkenes.
Authors: BUBNOV YU. N. , LAVRINOVICH L. I. 
Published: May 2016

AbstractThe bromomethylcycloalkenes (I) are coupled with the methyl borinate (II) in the presence of aluminum to give the boranes (III) which are deborated upon treatment with alcohols, producing the methylenecycloalkanes (IV).
ChemInform Abstract: Syntheses and Properties of 7,9‐Diphenyl‐ and 7,8,9‐Triphenylcyclopent‐(a)acenaphthylenide Ions.
Authors: KOMATSU K. , FUJIURA R. , OKAMOTO K. 
Published: May 2016

AbstractThe cyclopentadienides (II), generated from (I), react with methyl iodide (III) to give the substitution products (IV) or (V).
ChemInform Abstract: A Radical Substitution on Sulfur of Thioester Group. Formation of β‐ and γ‐Thiolactones.
Authors: TADA M. , MATSUMOTO M. , NAKAMURA T. 
Published: May 2016

AbstractRadical‐induced dehalogenation of the brominated S‐tert‐butyl thiocarboxylates (I) yields the acyclic products (II), together with the thiolactones (III).
ChemInform Abstract: α‐Aminophosphonates. Part 3. Anionic 1,3‐Cycloaddition of α,β‐Unsaturated Esters. Preparation and Transformation of δ1‐Pyrrolines.
Authors: DEHNEL A. , KANABUS‐KAMINSKA J. M. , LAVIELLE G. 
Published: May 2016

AbstractThe title reaction of the phosphonates (I) and (IV) with the esters (II) and (V) leads to the pyrrolidines (III) and (VI), respectively.
ChemInform Abstract: A Novel Synthesis of Pyrrole Derivatives.
Authors: BRUECKNER C. + , SUCHLAND B. , REISSIG H.‐U. 
Published: May 2016

AbstractThe enolates, generated from methyl 2‐siloxycyclopropanecarboxylates, react with phenyl isothiocyanate (II)/methyl iodide (III) to give adducts which, after desilylation with Bu4N+F‐, yield methyl 4,5‐dihydro‐1H‐pyrrole‐3‐carboxylates.
ChemInform Abstract: Synthesis of Hydrazones and Pyrazolones from Dehydro‐L‐ascorbic Acid.
Authors: ATTA K. , WILDE H. , HAUPTMANN S. 
Published: May 2016

AbstractThe mixed bisphenylhydrazone (Ia), derived from dehydro‐L‐ascorbic acid, is converted to the pyrazolinedione o‐chlorophenylhydrazone (IIa).
ChemInform Abstract: Convenient Synthesis of 2‐Thionaphthylmethyl Isocyanide: A Useful Reagent for Methyl Isocyanide Transfer.
Authors: RANGANATHAN S. , SINGH W. P. 
Published: May 2016

AbstractMorpholine (I) reacts with formaldehyde (II), formamide (III), and benzyl iodide (IV) to give the benzyl(formamidomethyl)morpholinium salt (V).
ChemInform Abstract: Heterocycles. Part 62. Synthesis and Characterization of Some 1,3‐Diaryl‐5‐((2‐aryl‐5‐X)thiazol‐4‐yl)pyrazoles.
Authors: SIMITI I. , ZAHARIA V. , COMAN M. , DEMIAN H. , MURESAN A. 
Published: May 2016

AbstractThe formylthiazoles (I) react with the acetophenones (II) to give the heterochalcones (III).
ChemInform Abstract: Simplified Chiral Aminolysis of Prochiral σ‐Symmetric Dicarboxylic Anhydrides with Sodium Salt of 4(S)‐IPTT.
Authors: NAGAO Y. , HAGIWARA Y. , HASEGAWA Y. , OCHIAI M. , INOUE T. , SHIRO M. , FUJITA E. 
Published: May 2016

AbstractThe dicarboxylic anhydrides (II) are coupled with the thiazolidinethione (I) in the presence of sodium hydride and DMSO to form the amido acids (III) which are converted to the corresponding methyl esters (V).
ChemInform Abstract: Synthesis of 1‐Oxo‐1H‐pyrazolo(1,2‐a) (1,2,4)triazol‐4‐ium‐3‐olates. A Ring‐Chain Tautomerism in the Series of Bicyclic Dipolar Heterocycles.
Authors: BOETTCHER A. + , DEBAERDEMAEKER T. , RADZISZEWSKI J. G. , FRIEDRICHSEN W. 
Published: May 2016

AbstractDepending on the state of aggregation, the product obtained from the reaction of (I) with (II) exists either as the dipolar heterocycle (III) or as the isocyanate (IV).
ChemInform Abstract: Synthesis of 1‐(Quinoxalin‐2‐yl)alkane‐1,2‐dithiols and ‐alkene‐1,2‐dithiols of Relevance to the Molybdoenzymes Cofactor, Moco.
Authors: LARSEN L. , ROWE D. J. , GARNER C. D. , JOULE J. A. 
Published: May 2016

Abstract2‐Mesyloxyalkyl N,N‐dimethyl dithiocarbamates such as (I) undergo ring closure in the presence of hydrogen sulfide ions to yield cyclic trithiocarbonates such as (III).
ChemInform Abstract: Cyclizations of 1,2,4‐Triazinium Salts with Bifunctional Nucleophiles. A New Route to Condensed 1,2,4‐Triazines.
Authors: ALEXEEV S. G. , CHARUSHIN V. N. , CHUPAKHIN O. N. , ALEXANDROV G. G. 
Published: May 2016

AbstractThe aminotriazinium salt (II) or the methylthiotriazine (IV) undergo cyclization with the acetoacetamides (I), yielding the pyrrolotriazinones (III) or (VI).
ChemInform Abstract: N‐Tosylaza(2.2)metacyclophane. ‐ Preparation, Structure, Helicity, Chiroptical Properties, and Racemization.
Authors: VOEGTLE F. + , PRZYBILLA K. J. , MANNSCHRECK A. , PUSTET N. , BUELLESBACH P. + , REUTER H. , PUFF H. 
Published: May 2016

AbstractThe title compound (IV), the first monoaza(2.2)phane described so far, exists in a strained anti conformation (shifts of 4.13 and 4.34 ppm for the inner protons; X‐ray analysis: space group P21/n with Z=4).
ChemInform Abstract: Studies on Fluorine‐Containing Heterocyclic Compounds. Part 3. Reactions of 3,5‐Dinitro‐2‐chlorobenzotrifluoride and 3,5‐Dinitro‐4‐chlorobenzotrifluoride with Sulfur‐ and Nitrogen‐Containing Nucleophiles.
Authors: CHI C.‐S. , CHEN M.‐J. , LIANG S.‐Q. , CHEN D.‐H. 
Published: May 2016

AbstractThe chlorodinitrobenzotrifluorides (I) and (IV) mentioned in the title react with methyl thioglycolate (II) and triethylamine at room temperature, forming the benzothiazole N‐oxides (III) or (V).
ChemInform Abstract: A Stable Intermediate in the Sommelet‐Hauser Rearrangement of 1‐Methyl‐ 2‐phenylpiperidinium 1‐Methylides: The Improved Sommelet‐Hauser Rearrangement.
Authors: SHIRAI N. , SUMIYA F. , SATO Y. , HORI M. 
Published: May 2016

AbstractThe intermediates (V) of the Sommelet‐Hauser rearrangement of the piperidinium salts (III) are obtained via the ylides (IV) by methylation of the N‐silylmethyl‐2‐phenylpiperidines (I) followed by desilylation.
ChemInform Abstract: A Simple New Synthesis of Macrolides by a Four Atom Ring Expansion of Cyclic Ketones Through a Consecutive Intramolecular Homolytic Addition ‐ β‐Scission of Alkoxyl Radicals. A New Entry to the Synthesis of 15‐Pentadecanolide (Exaltolide).
Authors: SUGINOME H. , YAMADA S. 
Published: May 2016

AbstractThe 2‐(3‐hydroxypropyl)cycloalkanone (I) is irradiated in the presence of iodine and mercuric oxide in pyridine to form the 2‐iodinated derivative (II) and the macrocyclic iodolactone (III).
ChemInform Abstract: Synthesis and Stereochemistry of Compounds Containing Two Chiral Alkylalkoxythiophosphoryloxy Substituents at the Phosphorus Atom.
Authors: DIMUKHAMETOV M. N. , ISMAEV I. E. 
Published: May 2016

AbstractThe dichlorophosphonite (Ia) or the dichlorophosphonate (Ib) are coupled with the ammonium phosphonate (II) to give the bisphosphoryl phosphonite (IIIa) or the phosphonate (IIIb).
ChemInform Abstract: Chemistry of Boron. Part 188. Synthesis and Structures of New 1,3,2,4‐Diphosphadiboretanes.
Authors: KOELLE P. + , LINTI G. , NOETH H. + , WOOD G. L. , NARULA C. K. , PAINE R. T. 
Published: May 2016

AbstractThe new title compounds (I) are prepared by three methods demonstrated in the scheme for the examples (Ib), (Id), and (Ie).
ChemInform Abstract: The First Monomeric Crystalline Tin(II) Alkyls: X‐Ray Structures of the β‐N‐Functionalized Alkyls Sn(R)X (R‐ = C‐(SiMe3)2C5H4N‐2 and X‐ = R‐, Cl‐, or N‐(SiMe3)2).
Authors: ENGELHARDT L. M. , JOLLY B. S. , LAPPERT M. F. , RASTON C. L. , WHITE A. H. 
Published: May 2016

AbstractThe dimeric organolithium compound (I) reacts with tin(II) chloride (II) to form the tin(II) complex (III).
ChemInform Abstract: Modeling the Oxygen‐Evolving Center of Photosystem II: Synthesis and Characterization of a Tetranuclear Manganese Carboxylate Complex.
Authors: KULAWIEC R. J. , CRABTREE R. H. , BRUDVIG G. W. , SCHULTE G. K. 
Published: May 2016

AbstractThe preparation of (IV), the first mixed‐valence Mn tetramer having an all‐oxygen coordination sphere, which may be biologically relevant, is described.
ChemInform Abstract: Transition Metal‐Substituted Diphosphenes. Part 13. Synthesis of (η5‐C5Me5)(CO)(NO)Re‐P=P‐C6H2(tBu)3‐(2,4,6) and (η5‐C5Me5)(CO)(NO)Re(Cr(CO)5)P=P‐C6H2(tBu)3‐(2,4,6).
Authors: WEBER L. , MEINE G. , BOESE R. , BLAESER D. + 
Published: May 2016

AbstractThe Re bromide (II) generated as shown reacts with the Li phosphide (III) to give the Re disilylphosphido complex (IV).
ChemInform Abstract: Synthesis and Structure of Carbonyliron Complexes of Allenecarboxylates and Allenic Lactones.
Authors: TRIFONOV L. S. , ORAHOVATS A. S. , PREWO R. , HEIMGARTNER H. 
Published: May 2016

AbstractOn irradiation in the presence of Fe(CO)5 (II), the allene carboxylates (I) afford the binuclear carbonyliron complexes (III), whereas the allenic lactone (IV) gives a mixture of one binuclear (VI) and two mononuclear carbonyliron complexes (V) and (VII).
ChemInform Abstract: A Series of Thallium‐Iron Carbonyl Cluster Molecules: Structural Comparisons of (Et4N)2(Tl2Fe4(CO)16), (Et4N)4(Tl4Fe8(CO)30), and (Et4N)6(Tl6Fe10(CO)36).
Authors: WHITMIRE K. H. , CASSIDY J. M. , RHEINGOLD A. L. , RYAN R. R. 
Published: May 2016

AbstractTl trichloride and in situ generated K(HFe(CO)4) react to form K(Tl(Fe(CO)4)2).
ChemInform Abstract: Pentaphosphametallocenes.
Authors: SCHERER O. J. , BRUECK T. + , WOLMERSHAEUSER G. + 
Published: May 2016

AbstractThermolysis of white phosphorus (II) and the dimeric Fe carbonyl (I) as well as the monomeric Ru bromide (IV) affords the mixed sandwich complexes (IIIa) and (IIIb).
ChemInform Abstract: Synthesis of a Novel Hexadentate Chelating Agent Based on 8‐Hydroxyquinoline.
Authors: SHRADER W. D. , CELEBUSKI J. , KLINE S. J. , JOHNSON D. 
Published: May 2016

Abstract8‐Hydroxyquinoline N‐oxide (I) is converted to the carboxylic acid (V).
ChemInform Abstract: Substitution Reactions of Metallic Complexes of 2,2′,2′′‐Triaminotriethylamine. Part 15. Kinetics of the Primary Acid Hydrolysis of the Dichloro(2,2′,2′′‐triaminotriethylamine)cobalt(III) Cation in Water‐Alcohol Mixtures
Authors: WILSON B. A. , MADAN S. K. 
Published: May 2016

Abstract(in H2O/EtOH, H2O/MeOH, and conc.
ChemInform Abstract: Syntheses of New Ferrocenylphosphinecopper(I) Complexes and Their Application to the Valence Isomerization of Norbornadiene to Quadricyclene.
Authors: ONISHI M. , HIRAKI K. , ITOH H. , EGUCHI H. , ABE S. , KAWATO T. 
Published: May 2016

AbstractThe preparation of (III), their stable mononuclear derivatives (V) (structure not defined) and the monomer (VI) is described.
ChemInform Abstract: Ruthenium(II) Tetraammines, a Useful Model to Compare trans‐Effect and trans‐Influence of Phosphanes.
Authors: CARDOSO DO NASCIMENTO FILHO J. , DE REZENDE J. M. , DOS SANTOS LIMA NETO B. , FRANCO D. W. 
Published: May 2016

AbstractThe substitution reaction shown in the scheme is studied in solution.
ChemInform Abstract: Oligophosphane Ligands. Part 28. C‐H Activation of Benzene and Alkylated Arenes by (Chelate‐Phosphane)ruthenium(0) Fragments.
Authors: DAHLENBURG L. , FROSIN K.‐M. 
Published: May 2016

AbstractThe reduction of (I) with sodium amalgam in aromatic solvents yields the complexes (III) or, in the case of toluene, the isomers (V).
ChemInform Abstract: Metal Complexes with Bridging Dimethylphosphido Ligands. Part 9. Reactivity of the Dinuclear Rhodium(II) Complex (C5Me5Rh(μ‐PMe2))2 Toward Chalcogens and Alkynes. An Example of Double Insertion of Oxygen into Two Rh‐PMe2 Bonds.
Authors: KLINGERT B. , RHEINGOLD A. L. , WERNER H. 
Published: May 2016

AbstractThe title complex (I) reacts with oxygen, sulfur, selenium, and tellurium to give the three different types of products (II), (III), and (IV) as shown in the scheme.
ChemInform Abstract: Palladium(II) Complexes of Diphenylvinyl‐ and Phenyldivinylphosphine.
Authors: RAHN J. A. , HOLT M. S. , O'NEIL‐JOHNSON M. , NELSON J. H. 
Published: May 2016

AbstractThe dichlorobis(phosphine)‐Pd complexes (IIIa) are prepared according to the scheme and converted into the halides (IIIb) by metathetic reaction.
ChemInform Abstract: Pyrrole Ring Cyclopalladation of Hydrazones Derived from N‐(p‐Toluenesulfonyl)‐3‐acetylpyrrole with Acetylhydrazine, Methyl Carbazate, and Semicarbazide.
Authors: NONOYAMA M. 
Published: May 2016

AbstractHydrazones (IIIb) and (IIIc) are prepared similarly to (IIIa) using methyl carbazate or semicarbazide.