bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Syntheses and Chiroptical Properties of 4‐Substituted 2‐Adamantylidene Derivatives. A New Sector Rule for Chiral 1,3‐Dienes and α,β‐Unsaturated Carbonyls.
Authors: WALBORSKY H. M. , REDDY S. M. , BREWSTER J. H. 
Published: May 2016

AbstractStarting with the 4‐hydroxyadamantan‐2‐ones (I), 2‐adamantylidene derivatives such as (IV) are prepared by Wittig‐Horner olefination and then subjected to chromatographic separation.
ChemInform Abstract: Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine‐Transition‐Metal Complexes. Part 6. Practical Asymmetric Synthesis of 1,1′‐Binaphthyls via Asymmetric Cross‐Coupling with a Chiral ((Alkoxyalkyl)ferrocenyl)monophosphine/Nickel Catalyst.
Authors: HAYASHI T. , HAYASHIZAKI K. , KIYOI T. , ITO Y. 
Published: May 2016

AbstractCross‐coupling of the naphthyl‐MgBr (III) with the naphthyl bromide (II) in the presence of a Ni catalyst prepared in situ from NiBr2 and the chiral ferrocenylphosphine (I) gives a high yield of the (R)‐binaphthyl (IV).
ChemInform Abstract: Selective Method for the Preparation of Isomeric N‐Alkyl and N‐Aryl‐3(5)‐amino‐5(3)‐hydroxy‐1H‐pyrazole‐1‐carboxamides.
Authors: DRUMMOND J. T. , JOHNSON G. 
Published: May 2016

AbstractThe α‐cyano hydrazides (I) or (IV) are converted to the semicarbazides (III) by reaction with the pyrazolylcarboxamide (II) or the isocyanates (V).
ChemInform Abstract: Pyridinethiones. Part 15. 3‐Methylthio‐2‐pentene‐1,5‐diones as Synthons for 4‐Methylthio‐2(1H)‐pyridinethiones, and Synthesis of 4‐Methylene‐1,4‐dihydropyridines.
Authors: BECHER J. , HANSEN P. 
Published: May 2016

AbstractThe α‐oxo ketene dithioacetals (I) are coupled with the methyl ketones (II) in the presence of tert‐butoxide to give the substitution products (III) and their salts (V) which are methylated, forming the isomers (VII) and (VIII).
ChemInform Abstract: Bisanellated Derivatives of 2,2′‐Bipyridine.
Authors: THUMMEL R. P. , LEFOULON F. , CHIRAYIL S. , GOULLE V. 
Published: May 2016

AbstractHeating of the 3,3'‐anellated 2,2'‐bipyridines (I) with the ω‐dibromoalkanes (II) yields the bisanellated derivatives (III).
ChemInform Abstract: Lithiation and Thiylation of 5‐Bromopyrimidines.
Authors: ARUKWE J. , KEILEN G. , UNDHEIM K. 
Published: May 2016

Abstract5‐Thiylated pyrimidines such as (V) are prepared either by cyclization of the sulfenylacrylaldehydes (III) with urea (IV) or by lithiation and thiylation of silyl‐protected 5‐bromopyrimidinones such as (VI).
ChemInform Abstract: Aminoquinone Reactions. Part 3. 5‐Arylaminobenzo(a)phenazines.
Authors: KALLMAYER H.‐J. , STASS C. 
Published: May 2016

AbstractThe 4‐substituted 1,2‐naphthoquinones (I) and (VI) undergo cyclocondensation with o‐phenylenediamine (II), forming the benzophenazines (III) and (VII) respectively.
ChemInform Abstract: Synthesis and Reactions of Some 6‐(2‐Hydroxy‐1‐naphthyl)‐1,2,4‐triazines.
Authors: EID M. M. , KADRY A. M. , HASSAN R. A. 
Published: May 2016

AbstractThe monohydrazones (III), obtained from the naphthofurandione (I), are cyclized upon treatment with bases to form the triazinones (IV).
ChemInform Abstract: Bismethyleneborane, (B(CH2)2)‐, and Trismethyleneborane, (B(CH2)3)‐, Anions. Do They Exist in the Gas Phase?
Authors: SHELDON J. C. , CURRIE G. J. , BOWIE J. H. 
Published: May 2016

AbstractThe reaction between OH‐ and BMe3 in the chemical ionization source yields Me2B=CH2.
ChemInform Abstract: Chemistry of Boron. Part 195. Synthesis, Structure and Reactions of a 1,3,2,4‐Aza‐λ3‐phosphadiboretidine Derivative.
Authors: KOELLE P. + , NOETH H. + , PAINE R. T. , RATTAY W. 
Published: May 2016

AbstractThe 1,3,2,4‐azaphosphadiboretidines (III) are obtained according to the scheme.
ChemInform Abstract: Synthesis, Structure, and Bonding in the Donor‐Acceptor Complex (tBu2PSe2)·(PNAryl): A Route to the PN Bond.
Authors: NIECKE E. , NIEGER M. , REICHERT F. , SCHOELLER W. W. 
Published: May 2016

AbstractA monophosphadiazonium ion is present in the adduct (IV) which is formed on the reaction of the iminophosphane (I) with gray selenium (II) in the ratio 1:2 via the isolable 1:1 "adduct" (III).
ChemInform Abstract: Thiolato‐Technetium Complexes. Part 1. Synthesis and Characterization of Bis(tertiary diphosphine)technetium(III) Complexes Containing Methanethiolato Ligands. Single‐Crystal Structural Analyses of trans‐(Tc(III)(SCH3)2(DMPE)2)CF3SO3 and trans‐(Tc(III)(SCH3)2(DEPE)2)PF6, Where DMPE: 1,2‐Bis(dimethylphosphino)ethane and DEPE: 1,2‐Bis(diethylphosphino)ethane.
Authors: KONNO T. , HEEG M. J. , DEUTSCH E. 
Published: May 2016

AbstractThe thiolato complexes (III) are investigated by X‐ray diffraction.
ChemInform Abstract: Characterization and Novel Low‐Temperature Reactions of FeCH2 and N2FeCH2.
Authors: CHANG S.‐C. , HAUGE R. H. , KAFAFI Z. H. , MARGRAVE J. L. , BILLUPS W. E. 
Published: May 2016

AbstractThe reactions of iron atoms with diazomethane are investigated in argon matrices by FTIR matrix isolation spectroscopy.
ChemInform Abstract: Synthesis, Characterization and Fungitoxicities of Metal Chelates of a Pentadentate N3S2 Ligand.
Authors: MAJUMDER S. M. M. H. , ALI M. A. , SMITH F. E. , MRIDHA M. A. U. 
Published: May 2016

AbstractS‐Methyldithiocarbazate and 2,6‐diacetylpyridine react in abs.
ChemInform Abstract: Kinetic and Thermodynamic Stabilities of the Geometric Isomers of (R3P)2Ru(CO)2Cl2 and (R3P)3Ru(CO)Cl2 Complexes.
Authors: KRASSOWSKI D. W. , NELSON J. H. , BROWER K. R. , HAUENSTEIN D. , JACOBSON R. A. 
Published: May 2016

AbstractA series of RuCl2(CO)2(phosphine)2 (phosphine: P(CH2‐Ph)3, PPh3, PPh2Me, PMe2Ph, PMe3) complexes are prepared.
ChemInform Abstract: Transformation of Resin Sandaracopimaric Acid into Androstane Analogues.
Authors: BERMEJO GONZALEZ F. , BORDELL MARTIN M. , FERNANDEZ MATEOS A. 
Published: May 2016

AbstractThe ketone (I), derived from methyl sandaracopimarate, is transformed to the title steroid (IV) via acid‐promoted cyclization of the intermediate (III).
ChemInform Abstract: Verrucarins and Roridins. Part 46. Synthesis of New, Unnatural Macrocyclic Trichothecenes: 3‐Isoverrucarin A ((1′′‐O)(3 → 4)abeo‐Verrucarin A), Verrucinol, and Verrucene.
Authors: JEKER N. , TAMM C. 
Published: May 2016

AbstractThe synthesis of the title compounds is envisaged in order to obtain trichothecene analogues which possess the antibiotic, antifungal and cytotoxic activity of the natural trichothecenes but are less toxic than these compounds.
ChemInform Abstract: Electroreduction of 2‐Oxazolines.
Authors: RYAN C. M. , KARIV‐MILLER E. 
Published: May 2016

AbstractPreparative electroreduction of 2‐phenyloxazoline (Ia) leads to aminoalcohol (IV) in high yield via oxazolidine (II) and its ring‐opened tautomer (III) (cyclovoltammetry; equilibrium constants in five solvents).
ChemInform Abstract: Static Structure of a Regular Intermediate Controls the Course of the Thermal 1,3‐Sigmatropic Rearrangement of 6‐Methylenebicyclo(3.1.0)hex‐2‐enyl Derivatives.
Authors: PIKULIN S. , BERSON J. A. 
Published: May 2016

AbstractThe pyrolytic rearrangements (all in benzene‐d6) of the title derivatives (I)‐(Va) and a mixture of (Vb) + (Vc) are studied, all bearing oxygen substituents at C(4).
ChemInform Abstract: Asymmetric Reactions Catalyzed by Chiral Metal Complexes. Part 29. Catalytic Asymmetric Hydrogenation with Rhodium Complexes of Improved DIOPS Bearing p‐Dimethylamino Group on the Basis of Our Designing Concept.
Authors: MORIMOTO T. , CHIBA M. , ACHIWA K. 
Published: May 2016

AbstractThe synthesis of the chiral bisphosphines (III) and (VI) is described.
ChemInform Abstract: Low‐Temperature Condensation of γ‐Butyrolactone with Ethyl Acetate.
Authors: LIPKIN M. A. , MARKEVICH V. S. 
Published: May 2016

AbstractIn the presence of sodium ethylate and at temp. between 40 and 120 °C the reaction between γ‐butyrolactone (I) and ethyl acetate (II) affords 2‐acetyl‐γ‐butyrolactone.
ChemInform Abstract: Scope and Limitations of the Reductive Coupling of Aromatic Aldimine Derivatives with Formation of 1,2‐Diarylethylenediamine Units, Using Low‐Valent Titanium Reagents.
Authors: BETSCHART C. , SCHMIDT B. , SEEBACH D. 
Published: May 2016

AbstractAminals such as (I), iminium salts such as (III), or N‐silylimines such as (IV) can be coupled by the black suspension of a low‐valent Ti species obtained from TiCl4 and Mg turnings in THF to give products such as (II) or (V) with no or low diastereoselectivity.
ChemInform Abstract: Synthesis of Ethylenes with Acyclic Quaternary Carbons by Dehydration of Neopentyl Alcohols. Application of the 2‐D INAPT Technique.
Authors: DRAKE C. A. , RABJOHN N. , TEMPESTA M. S. , TAYLOR R. B. 
Published: May 2016

AbstractTreatment of the alcohols (I), (III), (V), and (VII) with potassium hydrogen sulfate gives the alkenes (II), (IV), (VI), and (VIII).
ChemInform Abstract: Preparation and Surface Active Properties of Alcohol Ethoxylates with an Amide Oxime Terminal Group.
Authors: MASUYAMA A. , OKANO T. , OKAHARA M. 
Published: May 2016

AbstractBase‐catalyzed cyanoethylation of polyglycol ethers such as (III) gives the cyanoethyl derivative (V) which reacts with free hydroxylamine (VI), forming the amidoxime (VII).
ChemInform Abstract: A Practical Photochemical Synthesis of Bicyclo(1.1.1)pentane‐1,3‐dicarboxylic Acid.
Authors: KASZYNSKI P. , MICHL J. 
Published: May 2016

AbstractTreatment of bis(chloromethyl)dibromocyclopropane (I) with methyllithium results in intramolecular cyclization, producing (1.1.1)propellane (II).
ChemInform Abstract: Organosulfur Compounds. Part 47. Alkylation of Sulfinic Acids by O‐Alkylisoureas: O‐ versus S‐Reactivity and Asymmetric Synthesis of Alkyl Sulfinates.
Authors: KIELBASINSKI P. , ZURAWINSKI R. , DRABOWICZ J. , MIKOLAJCZYK M. 
Published: May 2016

AbstractAlkylation of sulfinic acid (I) with the alkylisoureas (II) yields the sulfones (III) and the sulfinates (IV), the latter being formed predominantly.
ChemInform Abstract: Cyclopentaannulation Reactions Between Nitrocycloalkenes and Diacetyl Morpholino Enamine.
Authors: FELLUGA F. , NARDIN G. , NITTI P. , PITACCO G. , VALENTIN E. 
Published: May 2016

AbstractThe α‐ketoenamine (I) reacts with 1‐nitrocyclohexene (II) to give the N‐oxide (III) which is stable in the solid state and can be stored for months at room temperature.
ChemInform Abstract: Use of Bridge Anellation to Retain the syn‐Stereochemistry of (m.n)Metacyclophane Derivatives: A Route to an Elusive syn‐(2.2)Metacyclophanediene.
Authors: LAI Y.‐H. , LEE S.‐M. 
Published: May 2016

AbstractBromination of the anti‐ and syn‐conformers (I) and (II) with N‐bromosuccinimide gives a mixture of the dibromides (III) and (IV) which cannot be separated.
ChemInform Abstract: 3,5‐Diphenyl‐1H‐pyrazole Derivatives. Part. 1. Esters and N‐Substituted Carbamates of 1‐(2‐Hydroxyethyl)‐3,5‐diphenyl‐1H‐pyrazole and Its 4‐Bromo Derivative with Depressant, Antiarrhythmic, Analgesic, and Other Activities.
Authors: BONDAVALLI F. , BRUNO O. , RANISE A. , SCHENONE P. , ADDONIZIO P. , DE NOVELLIS V. , LOFFREDA A. , MARMO E. 
Published: May 2016

AbstractChalcone (I) is transformed into the epoxide (II) which undergoes cyclocondensation with hydrazinoethanol (III), yielding the pyrazoline (IV).
ChemInform Abstract: A Rapid and Efficient Cycloaddition of Simple Imines with Activated Dienes Leading to Amino Sugars. Unusually High “Chelation‐Controlled” Diastereoselectivity in the Addition to an α,β‐Dihydroxyimine Protected as a Ketal.
Authors: MIDLAND M. M. , MCLOUGHLIN J. I. 
Published: May 2016

AbstractLewis acid‐induced hetero‐Diels‐Alder reaction of the imines (I) with the γ,δ‐unsaturated ketene silyl acetal (II) yields the tetrahydropyridine derivatives (III).
ChemInform Abstract: Synthesis of Thiophenacyl‐2‐phenyl‐2‐mercaptovinyl Sulfide ‐ The Precursor of 2,6‐Diphenyl‐1,4‐dithiine.
Authors: VORONKOV M. G. , USOV V. A. , SHAGUN L. G. , USOVA T. L. , PROTASOVA L. E. , KLYBA L. V. 
Published: May 2016

AbstractTreatment of the diphenacyl sulfide (I) with H2S (II) in the presence of H+ affords the sulfide (III).
ChemInform Abstract: 1,2‐Condensed Derivatives of Pyrimidine. Part 4. Synthesis and Pharmacological Properties of N,N‐Disubstituted 4‐Amino‐2H‐pyrido(1,2‐a)pyrimidin‐2‐ones and 2‐Amino‐4H‐pyrido(1,2‐a)pyrimidin‐4‐ones.
Authors: DI BRACCIO M. , ROMA G. , MAZZEI M. , BALBI A. , SCHIANTARELLI P. , CADEL S. , BONGRANI S. 
Published: May 2016

AbstractCyclocondensation of 2‐aminopyridine (IV) with the reagent (III), obtained from the malonamates (I) and phosphorus oxychloride (II), yields the regioisomeric fused pyrimidin‐2‐ones (V) and pyrimidin‐4‐ones (VI).
ChemInform Abstract: Novel Synthesis and Rearrangement of 3,1,5‐Benzoxadiazepines.
Authors: MAZURKIEWICZ R. 
Published: May 2016

AbstractThe reaction of the o‐phenylenediamines (I) according to A) in the presence of NEt3 as HBr acceptor yields the desired benzoxadiazepines (II) in good yields.
ChemInform Abstract: N,N‐Bis(trimethylsilyl)‐S‐methyldithiocarbazate. Preparation, Molecular Structure, and Reactions with Titanium, Niobium, Tantalum, and Molybdenum Halides.
Authors: SCHRENK V. , MATTES R. 
Published: May 2016

AbstractThe title compound (III) crystallizes in Pn21a with Z = 8. It does not react with Cp2TiCl2, CpTiCl3, CpMCl4 (Cp: π‐cyclopentadienyl) and MCl5 (M: Nb, Ta), probably due to a steric shielding of the reactive nitrogen in (III).
ChemInform Abstract: PPh4(As3Br2S4CH2)·CH2Br2, a Thiobromoarsenate with an As‐As Bond.
Authors: SINNING H. , MUELLER U. + 
Published: May 2016

AbstractAs2S3 obtained by precipitation with H2S from aqueous solution not only contains As(III) but also arsenic in a lower oxidation state.
ChemInform Abstract: Crystal Structure of (PPh4)2(Mo2(O2C‐Ph)4Br2)·2 CH2Br2.
Authors: GOESMANN H. , FENSKE D. , SWIDERSKY H.‐W. , DEHNICKE K. 
Published: May 2016

AbstractThe title compound (I) previously obtained from Mo(OOCPh)4 and PPh4Br in CH2Cl2 can also be prepared from Mo(OOCPh)4 and PPh4N3 with the assistance of CH2Br2 in 80% yield.
ChemInform Abstract: Synthesis and Fluxional Behavior of Octahedral Manganese(I) Complexes with a Monodentate 1,8‐Naphthyridine Ligand. X‐Ray Crystal Structure of fac‐(Mn(η1‐1,8‐naph)(η2‐phen)(CO)3)ClO4·1/2 CH2Cl2 (naph: 1,8‐Naphthyridine, phen: o‐Phenanthroline).
Authors: BERMEJO M.‐J. , RUIZ J.‐I. , SOLANS X. , VINAIXA J. 
Published: May 2016

AbstractThe octahedral fac‐complexes (III) with monodentately coordinated 1,8‐naphthyridine (II) are obtained according to the scheme.
ChemInform Abstract: Potential Building Blocks for Molecular Ferromagnets: (Mn12O12(O2CPh)16(H2O)4) with a S = 14 Ground State.
Authors: BOYD P. D. W. , LI Q. , VINCENT J. B. , FOLTING K. , CHANG H.‐R. , STREIB W. E. , HUFFMAN J. C. , CHRISTOU G. , HENDRICKSON D. N. 
Published: May 2016

AbstractThe title complex (IV) crystallizes in the space group P1 with Z=2.
ChemInform Abstract: A Triply Bridged Dinuclear Tris(bipyridine)iron(II) Complex: Synthesis and Electrochemical and Structural Studies.
Authors: SERR B. R. , ANDERSEN K. A. , ELLIOTT C. M. , ANDERSON O. P. 
Published: May 2016

AbstractThe title complex (I), prepared from the ligand in acetone and FeSO4 in water, crystallizes as its triflate salt (Ib) in C2/c, with Z=4.
ChemInform Abstract: Synthesis, Characterization, and Reactivity of (2,3,4,5‐η)‐2E,4E‐Nonadienylphosphonic Acid Tricarbonyliron Dimethyl Ester.
Authors: PINSARD P. , LELLOUCHE J. P. , BEAUCOURT J. P. , GREE R. 
Published: May 2016

AbstractThe cationic tricarbonyliron complex (VI) is prepared from the nonadienal (I) as outlined in the reaction scheme.
ChemInform Abstract: Dipalladium Complexes with N,N′‐Diphenylbenzamidine Bridging and Chelating Ligands. Synthesis and Structural and Electrochemical Studies.
Authors: YAO C.‐L. , HE L.‐P. , KORP J. D. , BEAR J. L. 
Published: May 2016

AbstractThe reaction of trimeric Pd3(O‐Ac)6 with lithium N,N'‐diphenylbenzamidinate in CH2Cl2 gives a product which is shown to have the structure (I) (C2/c, Z = 8) by an X‐ray analysis.
ChemInform Abstract: Asymmetric Synthesis via Heteroconjugate Addition Using Eliel′s Camphor Template.
Authors: ISOBE M. , OBEYAMA J. , FUNABASHI Y. , GOTO T. 
Published: May 2016

AbstractThe Eliel's (1R)‐(+)‐camphor derivative (I) reacts with the organolithium agents (II) to give the adducts (III).
ChemInform Abstract: 81Br NQR and 119Sn Moessbauer Study for MSnBr3 (M: Cs and MeNH3).
Authors: YAMADA K. , NOSE S. , UMEHARA T. , OKUDA T. , ICHIBA S. 
Published: May 2016

AbstractThe title compounds, for which successive structural phase transitions are observed by means of 81Br NQR and DTA are isomorphous and have typical cubic perovskite structure at 20 °C. Especially in the case of MeNH3SnBr3 the 81Br NQR and 119Sn Moessbauer spectra change markedly with decreasing temp. suggesting a change of the tin environment from a regular octahedron at 20 °C to a markedly distorted one at 77 K. These finding are interpreted on the basis of the three‐center‐four‐electron bond model.
ChemInform Abstract: Thermoanalytical Study of the System Pb2+‐Zn2+ Coprecipitated as Binary Carbonates.
Authors: GARCIA‐CLAVEL M. E. , MARTINEZ‐LOPE M. J. , CASAIS‐ALVAREZ M. T. 
Published: May 2016

AbstractPrecipitation from aqueous solutions of Pb(NO3)2 and Zn(NO3)2·4 H2O (1:2, 1:1, and 2:1) with an aqueous solution of (NH4)2CO3 (seven‐time excess) always yields mixtures composed of cerussite (PbCO3) and hydrozincite (Zn5(OH)6(CO3)2).
ChemInform Abstract: Synthesis and Characterization of Chelating Ion‐Exchange Resins: A Spectral Study of Copper(II) Complexes of Chelating Ion‐Exchange Resins Containing Multidentate Imidazole Moieties.
Authors: SAHNI S. K. , DRIESSEN W. L. , REEDIJK J. 
Published: May 2016

AbstractThe synthesis and characterization of several chelating ion‐exchange resins incorporating one or more tridentate ligands containing the imidazole group (bis(benzimidazol‐2‐ylmethyl))amine, anchored on microporous and macroporous styrene‐DVB copolymers and phenol‐formaldehyde condensate matrices, are described.
ChemInform Abstract: Alkylation of Heterocyclic Ketene Aminals with Benzyl Chloride and Ethyl Bromoacetate. Synthesis of Heterobicycles Containing γ‐Lactam‐Fused Diazaheterocycles.
Authors: HUANG Z. , LIU Z. 
Published: May 2016

AbstractHeterocyclic ketene aminals such as (I) react with benzyl chloride (II) or with the bromo ester (IV) in MeCN under reflux to give the alkylation products (III) or (V).
ChemInform Abstract: An Efficient Synthesis of Aromatic Iodides from Aromatic Carboxylic Acids.
Authors: SINGH R. , JUST G. 
Published: May 2016

AbstractThe p‐substituted benzoic acids (I) undergo iododecarboxylation with iodosylbenzene diacetate and iodine upon irradiation in refluxing tetrachloromethane, yielding the iodides (II).
ChemInform Abstract: Mechanism of an Interesting Ring‐Contraction Reaction of a Class of Carbocyclic trans‐Dibromides and Stereoisomeric Bromohydrins Through Solvolysis.
Authors: MANDAL A. N. , BHATTACHARYA S. , RAYCHAUDHURI S. R. , CHATTERJEE A. 
Published: May 2016

AbstractRing contraction by neutral solvolysis to give the lower homologous aldehyde is examined for benzocycloalkene bromohydrins or trans‐dibromides such as (I), (III), (V) and (VII).
ChemInform Abstract: A New Approach to the Construction of Radialenes by the Nickel‐Catalyzed Cyclooligomerization of (3)Cumulenes (Butatrienes).
Authors: IYODA M. , TANAKA S. , OTANI H. , NOSE M. , ODA M. 
Published: May 2016

AbstractCyclooligomerization of the dihalobutadienes (I) or (V), catalyzed by zero‐valent nickel complexes such as Ni(PPh3)4 generated by reduction of NiBr2(PPh3)2/PPh3 with Zn, gives the (4)‐ and (6)‐radialenes (II)‐(IV).
ChemInform Abstract: Cyclization of a Substituted N‐Acetylserine to a 2‐Methyldihydrooxazole with Dimethylaminosulfur Trifluoride.
Authors: DEVI N. , THREADGILL M. D. , TENDLER S. J. B. 
Published: May 2016

AbstractO‐Benzylserine (I) is hydroxymethylated and then cyclized with acetic anhydride (IV) to produce the acetoxymethyl(benzyloxymethyl)oxazolinone (V) which is hydrolyzed, yielding the O,N‐diacetylated derivative (VI) of (III).
ChemInform Abstract: Coupling Reactions of Aryl and Heteroaryl Halides with a Trimethylsilylethynylpyrazine.
Authors: AKITA Y. , KANEKAWA H. , KAWASAKI T. , SHIRATORI I. , OHTA A. 
Published: May 2016

Abstract2‐Chloro‐3,6‐diisobutylpyrazine (I) reacts with trimethylsilylacetylene (II) in the presence of a Pd catalyst and potassium acetate to form the disubstituted alkyne (III).
ChemInform Abstract: Dinuclear Mixed Alkyl Phosphido and Alkyl Aryloxy Complexes of Manganese(II). Crystal Structures of (Mn(CH2CMe3)(μ‐tBu2P))2 and (Mn(CH2CMe2Ph)(μ‐O‐2,4,6‐(tBu)3C6H2))2.
Authors: JONES R. A. , KOSCHMIEDER S. U. , NUNN C. M. 
Published: May 2016

AbstractThe air‐sensitive, paramagnetic title compounds (III) and (VI) are obtained from the polymeric (I) or dimeric Mn compound (IV) according to the scheme.
ChemInform Abstract: Metal‐Containing Heterocycles: Preparation, Properties, Reactions. Part 61. The Behavior of η2‐Thiophosphinito Complexes of Cobalt Towards Electron‐Poor Alkynes.
Authors: LINDNER E. , FRICK K. E. , STAENGLE M. + , FAWZI R. , HILLER W. 
Published: May 2016

AbstractIn the presence of PPh3, the (η2‐thiophosphinito)‐Co complex (I) reacts with the alkynes (II) to give the thiaphosphacobaltacyclopentadienes (III).
ChemInform Abstract: Synthesis and Spectral and Electrochemical Properties of Di‐2‐pyridyl Ketone Complexes of Ruthenium and Their Reactions.
Authors: BASU A. , KASAR T. G. , SAPRE N. Y. 
Published: May 2016

AbstractThe reaction of RuCl3 with the title ligand in stoichiometric amounts in DMF at reflux temp. gives the complex (I) besides a minor amount of (II) (10%), which is prepared directly using a reactant ratio of 1:1.
ChemInform Abstract: Unique Jones′ Oxidation of 12‐Iodolongibornane‐4‐ol Involving Unprecedented Neighboring Group Participation: Formation of Novel 7‐Carboxy‐4,7‐dimethylbicyclo(2.2.1)heptane‐2‐(3′,3′‐dimethyl)propanoic Acid.
Authors: VAIDYA S. P. , NAYAK U. R. 
Published: May 2016

AbstractThe title reaction of the iodide (I) affords the dicarboxylic acid (III) together with the diketone (II).
ChemInform Abstract: Polymer‐Supported Solid‐Phase Synthesis of C‐Terminal Peptide N‐Methylamides Using a Modified Photoremovable 3‐Nitro‐4‐N‐methylaminomethylpolystyrene Support.
Authors: AJAYAGHOSH A. , PILLAI V. N. R. 
Published: May 2016

AbstractThe modified resin (IV) is proved to be a suitable material for the preparation of C‐terminal peptide N‐methylamides by the solid‐phase method.
ChemInform Abstract: Differentiating Metal Sites in Homopolynuclear Systems via Incorporation of π‐Donors: Complexes of Bridging Phosphidoxo (Ph2P=O) Ligands
Authors: FOGG D. E. , CARTY A. J. 
Published: May 2016

AbstractReview: (The Chemistry of Heteronuclear Clusters and Multimetallic Catalysts; Proceedings of the Seminar in Koenigstein, Sept.
ChemInform Abstract: Syngas and HDS Catalysts Derived from Sulfido Bimetallic Clusters
Authors: CURTIS M. D. , PENNER‐HAHN J. E. , SCHWANK J. , BARALT O. , MCCABE D. J. , THOMPSON L. , WALDO G. 
Published: May 2016

AbstractReview: (The Chemistry of Heteronuclear Clusters and Multimetallic Catalysts; Proceedings of the Seminar in Koenigstein, Sept.
ChemInform Abstract: Trigonal Weberites: Structure Refinements of Na2MnCrF7 and Na2MnGaF7.
Authors: COURBION G. , FEREY G. , HOLLER H. , BABEL D. 
Published: May 2016

AbstractThe results of structure refinements of the trigonal title compounds in the space group P3121, Z = 6 confirm isotypism with the weberite type of Na2MnFeF7.
ChemInform Abstract: New Highly Conductive Inorganic Electrolytes. The Liquid SO2 Solvates of the Alkali and Alkaline Earth Metal Tetrachloroaluminates.
Authors: FOSTER D. L. , KUO H. C. , SCHLAIKJER C. R. , DEY A. N. 
Published: May 2016

AbstractThe liquid SO2 solvates of the AlCl4‐ salts of Li+, Na+, Ca2+, and Sr2+ and their mixtures are found to be highly conductive electrolytes with low SO2 vapor pressure.
ChemInform Abstract: X‐Ray Crystal Structure of Tetraacetatobis(tetrathiafulvalene)dirhodium(II) and the Properties of Its Iodine‐Doped Complex.
Authors: MATSUBAYASHI G. , YOKOYAMA K. , TANAKA T. 
Published: May 2016

AbstractThe title complex (I), prepared from the corresponding bis(methanol) complex by exchange of the neutral ligands (29% yield), crystallizes in P21/n with Z=2.