bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Syntheses of Optically Active Insect Pheromones, (2R,5S)‐2‐Methyl‐5‐hexanolide, (3S,11S)‐3,11‐Dimethyl‐2‐nonacosanone, and Serricornin.
Authors: KATSUKI T. , YAMAGUCHI M. 
Published: May 2016

AbstractThe synthesis of the three insect sex pheromones (VI) ‐ (VIII) using newly developed asymmetric reactions as the key steps is described.
ChemInform Abstract: Properties of Chemical Vapor Deposited Tungsten Silicide Films Using Reaction of WF6 and Si2H6.
Authors: SHIOYA Y. , IKEGAMI K. , KOBAYASHI I. , MAEDA M. 
Published: May 2016

AbstractIt is shown that CVD tungsten silicide films prepared by reaction of WF6 and Si2H6 have a higher deposition rate and higher Si content than those obtained from WF6 and SiH4 at the same substrate temperature.
ChemInform Abstract: Synthesis and Pharmacological Evaluation of γ‐Aminobutyric Acid Analogues. New Ligand for GABAB Sites.
Authors: BERTHELOT P. , VACCHER C. , MUSADAD A. , FLOUQUET N. , DEBAERT M. , LUYCKX M. 
Published: May 2016

AbstractReaction of the phenol (I) with the chlorides (II) and subsequent basic ring cleavage yield the amino acids (III).
ChemInform Abstract: A Simple Convenient Method for the Generation of Diborane from NaBH4 and I2.
Authors: NARAYANA C. , PERIASAMY M. 
Published: May 2016

AbstractTreatment of NaBH4 with I2 yields the diborane (I), which is employed in the preparation of the borane/N,N‐diethylaniline complex (V).
ChemInform Abstract: Asteranes. Part 18. Diasterane (Tricyclo(3.1.1.12,4)octane).
Authors: OTTERBACH A. , MUSSO H. 
Published: May 2016

AbstractThe saturated hydrocarbon (I) is converted to the diazoketone (V), which undergoes photolysis and Wolff rearrangement to give the endo‐ester (VI).
ChemInform Abstract: Two‐Step Synthesis of Furans by Mn(III)‐Promoted Annulation of Enol Ethers.
Authors: COREY E. J. , GHOSH A. K. 
Published: May 2016

AbstractThe cyclic enol ethers (I) react with the acetoacetate (II) in the presence of Mn(III) to give the adducts (III).
ChemInform Abstract: Assembling Potentialities of an Anionic Tripod Ligand: Trirhodium and Triiridium Complexes of 1,1,1‐Tris(sulfidomethyl)ethane. Molecular Structure and Crystal Packing of Ir3(CH3C(CH2S)3)(CO)6.
Authors: MAISONNAT A. , DEVILLERS J. , POILBLANC R. 
Published: May 2016

AbstractThe dimers (I) react with (II) quantitatively to yield the trinuclear derivatives (IIIa), (IIIb), which are converted in their carbonyl products (IIIc), (IIId) by reaction with CO.
ChemInform Abstract: Fungal Pigments. Part 52. Chemistry of the Plasmodial Pigments of the Slime Mold Fuligo septica (Myxomycetes).
Authors: CASSER I. , STEFFAN B. , STEGLICH W. 
Published: May 2016

AbstractThe red fuligorubin A (I) which is responsible for the yellow color of the plasmodia of Fuligo septica, represents the first tetramic acid derivative from a slime mold.
ChemInform Abstract: Torsional Motion in Aromatic Molecules. Conformational Analysis of Methyl‐, Ethyl‐, and n‐Propylbenzenes.
Authors: BREEN P. J. , WARREN J. A. , BERNSTEIN E. R. , SEEMAN J. I. 
Published: May 2016

AbstractIt is demonstrated that supersonic molecular jet spectroscopy can provide a novel means a) to determine experimental values for torsional potential barriers in S0 and S1, b) to "freeze out" molecular conformations which have very low (ca.
ChemInform Abstract: Crystal and Molecular Structure of ((Ag(S2P(OEt)2)·PPh3)2).
Authors: DREW M. G. B. , HOBSON R. J. , MUMBA P. P. E. M. , RICE D. A. 
Published: May 2016

AbstractThe reaction of AgSP(S)(OEt)2 with PPh3 yields the title compound (IV), which crystallizes in the space group P21/c with Z=2.
ChemInform Abstract: Design of Transition Metal Chelates with Biological Activity. Potentiometric Study of Complex Formation Equilibria Between 2‐Amino‐N‐hydroxy‐3‐(p‐hydroxyphenyl)propanamide and Nickel(II), Copper(II), and Hydrogen Ions in Aqueous Solution.
Authors: LEPORATI E. 
Published: May 2016

AbstractThe protonation constants of the ligand (I) and the formation constants of several metal complexes (II)‐(VI) are calculated from potentiometric data with the aid of the SUPERQUAD program.
ChemInform Abstract: Transsilylation of Dialkylaminotrimethylsilyliminophosphoranes with Trichlorosilane.
Authors: FILONENKO L. P. , PINCHUK A. M. 
Published: May 2016

AbstractThe trimethylsilyl group in the trimethylsilyliminophosphoranes (I) is substituted for the dichlorosilyl group by trichlorosilane (II), forming the compounds (III).
ChemInform Abstract: Use of Malic Acid as a Chiral Synthon: 24,25‐Dihydroxycholecalciferol.
Authors: STERLING J. , SLOVIN E. , BARASCH D. 
Published: May 2016

AbstractThe enantiomers of malic acid (I) are converted to the chiral synthon (IX) which is employed in the synthesis of the dihydroxycalciferol derivatives (XI).
ChemInform Abstract: Nonferroic Ima2 → Pna21 (X(τ4)) Phase Transition in a SAPO‐II Type Silicoaluminophosphate Molecular Sieve. Structural Investigations on the “as‐Synthesized” (SYN), Calcined (CAL) and Cyclohexane Adsorbed (CYC) Forms.
Authors: MENTZEN B. F. , VEDRINE J. C. , KHOUZAMI R. , COUDURIER G. 
Published: May 2016

AbstractThe calcined form of a polycrystalline material with H2Si2P18Al20O80 (I) composition crystallizes in the orthorhombic space group Pna21.
ChemInform Abstract: Electrocatalysis of the Hydrogen Oxidation and of the Oxygen Reduction Reactions on Pt and Some Alloys in Alkaline Medium.
Authors: COUTURIER G. , KIRK D. W. , HYDE P. J. , SRINIVASAN S. 
Published: May 2016

AbstractElectrode kinetic studies are carried out for the hydrogen oxidation reaction on Pt, Ni, Pt‐Ni, Pt‐Ti, and Ni‐Ti alloys and for oxygen reduction on Pt and the alloys Pt‐Cr, Pt‐Ta, and Pt‐Cr‐Ta in order to find substitutes for Pt as electrocatalysts for alkaline fuel cells.
ChemInform Abstract: Reaction of 1‐(Acyloxy)alkylisocyanates with Carboxylic Acids.
Authors: VOVK M. V. , DOROKHOV V. I. , SAMARAI L. I. 
Published: May 2016

AbstractOrganic isocyanates are known to react with carboxylic acids to afford amides or symmetrically substituted ureas.
ChemInform Abstract: Cycloaddition Reactions of Iminium Compounds.
Authors: MOEHRLE H. + , DWULETZKI H. 
Published: May 2016

AbstractIminium compounds such as (III) undergo a cycloaddition reaction with nucleophilic carbenes, but they are inert to the highly electrophilic methylene carbene which reacts easily with the enamine (I) to form the cyclopropanopiperidine (II).
ChemInform Abstract: D‐β‐Chlorolactic Acid: A Chemical Synthesis.
Authors: MORIN C. , SAWAYA G. 
Published: May 2016

AbstractD‐β‐Chloroalanine (III), prepared from D‐serine methyl ester hydrochloride (I) by a method already described in the literature, is deaminated by nitrous acid with retention of the configuration to yield D‐β‐chlorolactic acid (IV).
ChemInform Abstract: Chemistry of Nitrogen Mustard (2‐Chloro‐N‐(2‐chloroethyl)‐N‐methylethanamine) Studied by NMR Spectroscopy.
Authors: GOLDING B. T. , KEBBELL M. J. , LOCKHART I. M. 
Published: May 2016

AbstractThe reactions of the drug (Ia), converted to the aziridinium compound (IIa), with an extensive range of nucleophiles such as methanethiol, 2‐mercaptoethanol, thiourea, methionine, azide, cyanide, NH3, or thiosulfate are studied by 1H NMR and, for (Ib)/(IIb), by 13C NMR.
ChemInform Abstract: Reactions of Diazoacetonitrile Derivatives with Hydrogen Sulfide.
Authors: KOLOBOV M. YU. , BAKULEV V. A. , MOKRUSHIN V. S. 
Published: May 2016

AbstractThe title compounds (I), on reaction with H2S, afford the expected heterocycles (II) along with the unexpected hydrazones (III), which result from hydrogenation of the diazo function of (I).
ChemInform Abstract: Spiro Derivatives of Tetrahydrothiophene. Synthesis of the Quinolizidine‐3‐spiro‐2′‐tetrahydrothiophene System Using Solid/Liquid or Liquid/ Liquid Phase‐Transfer Catalysis.
Authors: WROBEL J. T. , HEJCHMAN E. 
Published: May 2016

Abstract2‐Cyanotetrahydrothiophene (IV), prepared from chloroacetonitrile (I) and 3‐chloropropanethiol (II), is converted to the title compound (IX) by two different routes.
ChemInform Abstract: An Improved Alkylation of 2H‐1,4‐Benzothiazin‐3(4H)‐one and Related Heterocyclic Anilides.
Authors: MARFAT A. , CARTA M. P. 
Published: May 2016

AbstractThe (hetero)cyclic anilides (I) undergo N‐substitution with the halides (II) in the presence of potassium tert‐butoxide.
ChemInform Abstract: Reactivity of Conjugated Bases of Hydridophosphoranes. Synthesis of Unusual Phosphoranes Bearing P‐S‐, P‐Se‐, P‐P‐S‐, and P‐N‐‐ as Exocyclic Bonds.
Authors: LAMANDE L. , MUNOZ A. , GARRIGUES B. 
Published: May 2016

AbstractHydridophosphoranes such as (I), are deprotonated by pyridine or triethylamine to form the conjugated bases (II) and (III).
ChemInform Abstract: New Oxocadmates of the Alkali Metals: K6(CdO4), Rb6(CdO4), Rb2CdO2 and Rb2Cd2O3.
Authors: BAIER R. , SEIPP E. , HOPPE R. 
Published: May 2016

AbstractThe title compounds have been prepared by annealing stoichiometric mixtures of the binary oxides (closed Ag crucible, 500 °C, 5‐14 d) K6(CdO4) crystallizes in the hexagonal space group P63mc, Z=2, and is isotypic with Na6(ZnO4).
ChemInform Abstract: New Ternary Pnictides with the CaBe2Ge2‐Type Structure in the Systems, Rare‐Earth‐Rh‐P and Rare‐Earth‐Rh‐As.
Authors: MADAR R. , CHAUDOUET P. , SENATEUR J. P. , ZEMNI S. , TRANQUI D. 
Published: May 2016

AbstractEight new ternary compounds, LnRh2X2 with Ln: La, Ce, Pr, Nd and X: P or As, have been prepared by reaction of the elements (two step process: melting of Ln and Rh, 1:2, in a Hukin‐type cold crucible, mixing the product with P or As and subsequent heating at 1000 K, 24 h, no yields given).
ChemInform Abstract: The Interaction of Copper(II) with a Lipotetrapeptide.
Authors: DECOCK‐LE REVEREND B. , LOUCHEUX C. , LIVERA C. , PETTIT L. D. , MIGLIORE‐SAMOUR D. , JOLLES P. 
Published: May 2016

AbstractThe protonation constants of the lauroyl tetrapeptide (I) and the stability constants of its Cu complexes are determined by potentiometry.
ChemInform Abstract: Regioselectivity of Alkoxyisobenzofuran‐Aryne Cycloadditions.
Authors: POLLART D. J. , RICKBORN B. 
Published: May 2016

AbstractThe regiochemistry of the Diels‐Alder reaction between the isobenzofuran (II), derived from the orthoester (I), and the arynes (III), (VI), or (IX) which are generated in situ, is determined.
ChemInform Abstract: Specificity, Catalysis, and Regulation: Effects of Metal Ions on Polyammonium Macrocycle Catalyzed Dephosphorylation of ATP.
Authors: YOHANNES P. G. , PLUTE K. E. , MERTES M. P. , MERTES K. B. 
Published: May 2016

AbstractThe catalytic influence of the combined effects of metal ions and the macrocycle (I) on the dephosphorylation of adenosine triphosphate is examined for M(II) (M: Cd, Zn, Mg, Ca) and La(III).
ChemInform Abstract: Some Novel Heterocyclic Systems Derived from 7‐Amino‐2,3‐dihydro‐8‐nitro‐1H‐pyrrolo(1,2‐a)benzimidazole and the Corresponding Diamine.
Authors: GROVES C. L. , RALPH J. T. , TEMPLE A. F. 
Published: May 2016

Abstract1,4‐Bisacetamidobenzene (Ia) is converted to the dinitro derivative (Ib) which is coupled with pyrrolidine (II) to yield the amine (III).
ChemInform Abstract: Oxidation of N‐Acyl‐pyrrolidines and ‐piperidines with Iron(II)‐Hydrogen Peroxide and an Iron Complex‐Molecular Oxygen.
Authors: MURATA S. , MIURA M. , NOMURA M. 
Published: May 2016

AbstractThe reactions of the pyrrolidines (Ia)‐(Ic) and piperidines (Id)‐(If) with Fe(II)‐H2O2 in aqueous 95% MeCN give the lactams (II).
ChemInform Abstract: A New Regiospecific Synthesis of Enol Boranes of Methyl Ketones.
Authors: HOOZ J. , OUDENES J. , ROBERTS J. L. , BENDERLY A. 
Published: May 2016

AbstractThe boron enolates (III), prepared in situ from dicyclohexylborane (I) and the diazoketones (II), react with Eschenmoser's iodide (IV) to produce the β‐dimethylamino ketones (V).
ChemInform Abstract: Stereochemistry in the Reactions of (Z)‐ and (E)‐Allyltributylstannyl Reagents with Quinones.
Authors: TAKUWA A. , SOGA O. , MISHIMA T. , MARUYAMA K. 
Published: May 2016

AbstractLewis acid‐induced alkylation of the o‐quinones (I) and (VIII) or the p‐quinones (V) with the allylic tributylstannanes (II) or (XI) yields the α‐adducts (III), (VI), and (X) and/or the γ‐adducts (IV), (VII), and (IX).
ChemInform Abstract: New Synthesis of α‐Nitroalkyl‐ and α‐Nitroaralkylcarboxylic Esters from α‐Nitroalkyl‐ and α‐Nitroaralkyl‐2‐oxazolines.
Authors: FEUER H. , BEVINAKATTI H. S. , LUO X.‐G. 
Published: May 2016

AbstractThe oxazoline (I) is cleaved with methanol in the presence of TFA to give the salt (II) which is converted to benzoic acid (III) and the α‐nitro ester (IV) (R1: ‐Ph, R2: ‐Me) upon heating with MeOH/TFA.
ChemInform Abstract: Nitration of Some 3,5‐Disubstituted Pyridine N‐Oxides.
Authors: BISSELL E. R. , SWANSIGER R. W. 
Published: May 2016

Abstract3,5‐Dichloropyridine N‐oxide (I) reacts selectively with methylate to give the chloromethoxypyridine N‐oxide (II) which is nitrated to yield the mononitro (III) and dinitro derivatives (IV).
ChemInform Abstract: Heterocyclic Variants of the Purine System. Part 2. Derivatives of Thiazolo(4,5‐e)‐1,2,4‐triazines, a New Heterocyclic Ring System.
Authors: JACOBSEN N. W. , PHILIPPIDES A. E. 
Published: May 2016

AbstractThe thiazolotriazines (IX) are synthesized by heating the acylaminotriazinones (VIII) which, in turn, are accessible starting from the triazinones (I).
ChemInform Abstract: Novel Addition Products of 2‐Aza‐1‐thiabenzene Derivatives with Methyl Propiolate.
Authors: HORI M. , KATAOKA T. , SHIMIZU H. , MATSUO K. , SUGIMOTO A. , IKEDO K. , HAMADA K. , OGURA H. , TAKAYANAGI H. 
Published: May 2016

AbstractReaction of the azathianaphthalene (I) and the azathiaphenanthrenes (IV) with methyl propiolate (II) yields the 1:2‐adducts (III) and (V).
ChemInform Abstract: Z‐1,2‐Bis(tert‐butyldimethylsilyl)‐1,2‐bis(trimethylsilyl)ethylene. The Most Crowded Known cis‐Olefin.
Authors: SAKURAI H. , EBATA K. , KABUTO C. , NAKADAIRA Y. 
Published: May 2016

AbstractThe dichlorodisilane (I) reacts with lithium to give the silene (II) which yields the disilacyclobutene (IV) by addition of bis(trimethylsilyl)acetylene (III).
ChemInform Abstract: Selective Steroid Chlorinations Directed by Attached Pyridine Ester Templates.
Authors: BRESLOW R. , BRANDL M. , HUNGER J. , ADAMS A. D. 
Published: May 2016

AbstractAccording to experimental procedures described previously, the title reaction converts (Ia) to the major product (Ib) (isolated as (III)) by a radical relay mechanism involving the attachment of a Cl atom to the pyridine nitrogen.
ChemInform Abstract: A New Self‐Aligned Planar Oxidation Technology
Authors: SAKUMA K. , ARITA Y. , DOKEN M. 
Published: May 2016

Abstract(SPOT) using low temp. (900 °C) high pressure (0.8 MPa) oxidation has been developed as an isolation process to obtain highly uniform planar surfaces in very‐high‐speed bipolar LSI's. Planarity is found to be independent of the selective oxidation temp. and is superior to that obtained by conventional LOCOS (local oxidation of silicon) planarizations.
ChemInform Abstract: Unusual Oxidative Behavior of (η5‐C5R5)M(CO)2 (R: H, CH3; M: Rh, Co) Complexes at Mercury and Platinum Electrodes.
Authors: GENNETT T. , GRZESZCZYK E. , JEFFERSON A. , SIDUR K. M. 
Published: May 2016

AbstractThe voltammetric, polarographic, and coulometric data from the oxidation of the complexes (I) in methylene chloride at platinum and mercury electrodes are reported.
ChemInform Abstract: Azo Cope Rearrangements of Nonstabilized Azo Compounds.
Authors: BECK K. , BURGHARD H. , FISCHER G. , HUENIG S. + , REINOLD P. 
Published: May 2016

AbstractThe Diels‐Alder adducts (III) show a one‐step or two‐step Cope rearrangement to give (IV) without loss of nitrogen.
ChemInform Abstract: Acetals of Mesoxalic Aldehyde
Authors: GORDEEVA G. N. , KALASHNIKOV S. M. , POPOV YU. N. , KRUGLOV E. A. , IMASHEV U. B. 
Published: May 2016

AbstractThe reaction between the methylglyoxyl acetals (I) and the alkyl nitrites (II) in the presence of the corresponding alkanols (III) affords the hitherto unknown title compounds (IV).
ChemInform Abstract: Synthesis of Alkyl N‐Cyano‐N‐Substituted Carbamates and N,N‐Disubstituted Cyanamides.
Authors: SUBA L. , SCHAFER T. , RUMINSKI P. G. , D'AMICO J. J. 
Published: May 2016

AbstractThe dithioimidocarbonate (I) is hydrolyzed in a basic alcoholic solution to give the potassium salts (III) which are alkylated by the halides (IV) to yield the cyano carbamates (V).
ChemInform Abstract: Photochemical Generation of 3,3‐Di‐tert‐butyloxaziridine Radicals.
Authors: LAZAREV G. G. , VARLAMOV S. V. , PROKOF'EV A. I. , KOSTYANOVSKII R. G. , LEBEDEV YA. S. 
Published: May 2016

AbstractPhotolysis of a 0,1 M solution of the N‐chlorooxaziridine (I) in toluene generates the radical (II) mentioned in the title.
ChemInform Abstract: Reduction of Ethyl 5,6‐Dihydro‐4H‐oxazine‐3‐carboxylates. A Route to Proline Ethyl Ester and Other Ethyl Pyrrolidine‐2‐carboxylates.
Authors: CHRYSTAL E. J. T. , GILCHRIST T. L. , STRETCH W. 
Published: May 2016

AbstractReductive cleavage of the title oxazines (I) and (III) leads to the pyrrolidine derivatives (II) and (IV), respectively.
ChemInform Abstract: Generation and Interception of 1‐Oxa‐3,4‐cyclohexadiene.
Authors: SCHRECK M. , CHRISTL M. 
Published: May 2016

AbstractThe (2 + 2) cycloadduct (VIIa) is accompanied by the (4 + 2) cycloadduct (VIIIa) (yield 18%) under the conditions of interception.
ChemInform Abstract: Some Novel Observations on the Reaction of 1‐Hydrazinophthalazine with Polycarbonyl Compounds.
Authors: ZIMMER H. , AMER A. 
Published: May 2016

AbstractReaction of 1‐hydrazinophthalazine (I) with acetylacetone (IIa) or ethyl acetoacetate (IIb) yields a mixture of the hydroxypyrazolines (III) and the azines (IV).
ChemInform Abstract: Method for the Preparation of Substituted 2‐ and 4‐Nitrosopyrimidines.
Authors: MOSKALENKO G. G. , SEDOVA V. F. , MAMAEV V. P. 
Published: May 2016

AbstractOxidation of the hydroxylaminopyrimidines (I) with activated MnO2 gives the corresponding nitrosopyrimidines (II).
ChemInform Abstract: Boron Compounds. Part 76. Reactions of (Organo)phosphorus‐Oxygen Compounds with Diorgano‐hydro‐boranes.
Authors: KOESTER R. + , SCHUESSLER W. + , SYNORADZKI L. 
Published: May 2016

AbstractThe reactions of various organophosphorus‐oxygen compounds such as (I)‐(V) with the boranes (VI) are monitored by NMR (11B,31P), MS, IR and a series of analytical characteristic numbers (e.g.
ChemInform Abstract: nido‐Methylenephosphahexaboranes: R2CPB5H8.
Authors: COONS D. E. , GAINES D. F. 
Published: May 2016

AbstractTwo routes to the title compounds (IV), a new class of heteroborane clusters, are developed: 1. preparation by dehydrochlorination of the corresponding phosphino‐bridged pentaborane derivatives (III), obtained by the reaction of (I) and B5H8‐ anion.
ChemInform Abstract: Study of the Reaction of the Dihydroxylation of α,β‐, β,γ‐ and γ,δ‐Alkenylphosphonates by Hydroperoxides and Osmium Tetroxide: Specific Reaction of tert‐Butyl Hydroperoxide.
Authors: PONDAVEN‐RAPHALEN A. , STURTZ G. 
Published: May 2016

AbstractThe dihydroxyalkylphosphonates (II) are obtained by oxidation of the alkenylphosphonates (I) with tert‐butyl hydroperoxide in the presence of osmium tetroxide.
ChemInform Abstract: PN Compounds. Part 28. Phosphaminimides. Part 3. 4‐Nitrobenzylation of Phosphinyl 1,1‐Dimethyl Hydrazides and Formation of a Unique Hydrazinium Inner Salt.
Authors: CATES L. A. , LI V.‐S. 
Published: May 2016

AbstractThe phosphoryl chlorides (I) react with the hydrazine (II) to yield the hydrazides (IIIa), which are transformed into the hydrazinium salts (V), (VI) and (IX) by reaction with the benzyl bromide (IV) or methyl iodide (VIII).
ChemInform Abstract: Electron‐Transfer Processes. Part 40. Reaction of Alkyl Radicals with Diphenylphosphide Anion.
Authors: RUSSEL G. A. , KHANNA R. K. 
Published: May 2016

AbstractThe reaction of alkyl radicals, generated by irradiation of the mercury halides (III) or (VI), with the phosphide (IV) is studied.
ChemInform Abstract: On the Structure of the UV‐Irradiation Product of 5‐Methyl‐2‐phenyl‐ 1,2,3‐diazaphosphole.
Authors: ARBUZOV B. A. , DIANOVA E. N. , ZABOTINA E. YA. 
Published: May 2016

AbstractIrradiation of the diazaphosphole (I) yields the dimer (II).
ChemInform Abstract: Low‐Coordinate Lead(II) Complexes with PbP2C and PbP4 Coordination. Preparations and Structures of Pb((Ph2P)2CH)2 and Pb((Ph2P)2C(SiMe3))2.
Authors: BALCH A. L. , ORAM D. E. 
Published: May 2016

AbstractThe complex (III) crystallizes in the space group P21/c with Z=4 and (V) in P212121 with Z=4.
ChemInform Abstract: Phosphorus Compounds with Unusual Coordination. Part 17. Trapping Reaction of Phenylthioxophosphane with Hexacarbonylbis(cyclopentadienyl)dimolybdenum.
Authors: HUSSONG R. , HEYDT H. , MAAS G. , REGITZ M. 
Published: May 2016

AbstractPhenylthioxophosphane (II), generated in refluxing toluene from endo/exo‐(I), reacts under these conditions with the title Mo complex (III) to yield the two binuclear Mo complexes (IV) and (V).
ChemInform Abstract: Preparation of μ‐Hydrido‐μ‐diphenylphosphido‐bis(tetracarbonylrhenium)·1/2 Xylene and Molecular Structure of the Derivative Re2(CO)6(PPh3)2(μ‐H)(μ‐PPh2) (Ph: C6H5).
Authors: HAUPT H.‐J. , BALSAA P. , FLOERKE U. + 
Published: May 2016

AbstractThe title complex (III) is prepared by equimolar reaction of Re2(CO)10 (I) with diphenylphosphine (II).
ChemInform Abstract: Mixed Polyhydride‐Phosphine Clusters That Contain the Re2Au and Re2Au2 Cores: Reversible Protonation and Auration of the Dirhenium Polyhydride Complex Re2(μ‐H)4H4(PPh3)4.
Authors: MOEHRING G. A. , FANWICK P. E. , WALTON R. A. 
Published: May 2016

AbstractThe dirhenium polyhydride complex (I) reacts reversibly with HBF4·OEt2 to give the monoprotonation product (II) and with the Au(I) cations (III) to afford the heterometallic clusters (IV) and (V).
ChemInform Abstract: 5′‐O‐Alkyl‐5‐fluorouridines: Synthesis and Biological Activity.
Authors: HOLY A. , KOENIG J. + , VESELY J. , CECH D. , VOTRUBA I. , DE CLERCQ E. 
Published: May 2016

AbstractThe preparation of the title compounds (XII) and (XVIII) is reported.
ChemInform Abstract: Raspailynes, Novel Long‐Chain Acetylenic Enol Ethers of Glycerol from the Marine Sponges Raspailia pumila and Raspailia ramosa.
Authors: GUELLA G. , MANCINI I. , PIETRA F. 
Published: May 2016

AbstractThe novel long‐chain glyceryl monoethers (Ia), (Ib) and (II)‐(VI) are isolated from marine sponges.
ChemInform Abstract: Hydrothermal Dissolution of Perovskite: Implications for Synroc Formulation.
Authors: KASTRISSIOS T. , STEPHENSON M. , TURNER P. S. , WHITE T. J. 
Published: May 2016

AbstractThe hydrothermal alteration products formed by perovskite and two titanate‐based "synroc" formulations (synroc B and C) are investigated by TEM.
ChemInform Abstract: Dicadmium Stannate as a Novel Electrode Material for Battery Applications.
Authors: HASHEMI T. , GOLESTANI‐FARD F. , AVANESSIAN J. 
Published: May 2016

AbstractIsostatic pressing of a CdO‐SnO2 (2:1) powder mixture and subsequent sintering at 900‐1000 °C (5 h, ambient atmosphere) yield a porous Cd2SnO4 material which seems to be applicable as electrode material for secondary batteries.
ChemInform Abstract: Resonance and Solvent Effects on Absorption Spectra. Part 5. Substituent and Solvent Effects on IR Spectra of 2‐ and 4‐Substituted Aniline Derivatives.
Authors: YOKOYAMA T. , TAFT R. W. , KAMLET M. J. 
Published: May 2016

AbstractIR spectra of (I) and (II) in various solvents such as CCl4, CHCl3, AcOEt, AcNMe2, or γ‐butyrolactone are employed to examine intramolecular H‐bonding of amine hydrogen atoms with 2‐substituents, or intermolecular H‐bonding with H‐bond‐acceptor solvents.
ChemInform Abstract: Cyanocarbon Acids: Direct Evidence That Their Ionization Is Not an Encounter‐Controlled Process and Rationalization of the Unusual Solvent Isotope Effects.
Authors: HOJATTI M. , KRESGE A. J. , WANG W.‐H. 
Published: May 2016

AbstractThe rate of exchange of 3H of tBu‐C3H(CN)2 is not inhibited by hydronium ions; this rules out the Swain‐Grunwald mechanism.