bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Reactions of Tetrasulfur Tetranitride with Tropolone and Its Several Halogen Derivatives. Preparations of 4H‐Cyclohepta(c) (1,2,5)thiadiazol‐4‐ones, 6H‐Cyclohepta(c) (1,2,5)thiadiazol‐6‐one, and 7H‐Cyclohepta(1,2‐c:3,4‐c′)bis(1,2,5)thiadiazol‐7‐ones.
Authors: MORI A. , NAKASHIMA H. , MATAKA S. , TASHIRO M. , TAKESHITA H. 
Published: May 2016

AbstractReactions of (I) and a series of its halogen derivatives with (II) are investigated.
ChemInform Abstract: 3‐(2‐Imidazo(4,5‐b)pyridine)propionic Acid and Some of Its Derivatives with Suspected Tuberculostatic Activity.
Authors: BUKOWSKI L. , JANOWIEC M. 
Published: May 2016

AbstractCyclocondensation of the aromatic diamine (I) with succinic anhydride (II) yields the substituted propionic acid (III) in two polymorphous forms.
ChemInform Abstract: Synthesis of Nonracemic γ‐Alkoxyallylstannanes by Stereospecific anti‐(1,3)Stannyl Migration.
Authors: MARSHALL J. A. , GUNG W. Y. 
Published: May 2016

AbstractThe unsaturated aldehydes (I) are coupled with tri‐n‐butylstannyllithium (II) and then oxidized to give the stannyl ketones (III).
ChemInform Abstract: A New Type of Organostibonic Molybdate. Synthesis and Structure of a Tetra‐n‐butylammonium Salt of Diphenylstibonomolybdate.
Authors: LIU B. , KU Y. , WANG M. , WANG B. , ZHENG P. 
Published: May 2016

AbstractThe structure of the first organostibonic molybdate (III), produced by reaction of the antimony diiodide (I) with the molybdate (II), is established by X‐ray diffraction analysis.
ChemInform Abstract: β‐Ketophosphines Derived from Ferrocene. Syntheses and Structure of (Ph2CH2C(O)(η5‐C5H4)Fe(η5‐C5H5)) (L1) and trans‐(PdCl2L1 2).
Authors: BRAUNSTEIN P. , CARNEIRO T. M. G. , MATT D. , BALEGROUNE F. , GRANDJEAN D. 
Published: May 2016

AbstractCoupling of acetylferrocene (I) with diphenylchlorophosphine (II) gives the ketophosphine (III).
ChemInform Abstract: Trimethylphosphinecobalt(I) Complexes: Reaction with Cycloheptatriene and Cyclooctatetraene. Crystal Structure of (Co(η4‐C7H8)(PMe3)3)BPh4.
Authors: DE CARVALHO L. C. A. , DARTIGUENAVE M. , DARTIGUENAVE Y. 
Published: May 2016

AbstractReaction of tris(trimethylphosphine)cobalt(I) bromide (I) with cycloheptatriene (II) or cyclooctatetraene (V) yields the cationic polyene complexes (IV) or (VI).
ChemInform Abstract: Synthesis and Coordination Chemistry of 1‐(2′,2′′‐Bipyridyl‐6′‐ylmethyl)‐1,4,7‐triazacyclononane, a Pentaazamacrocycle‐Based on a Triazamacrocycle with a Single Pendent Coordinating Bipyridyl Group.
Authors: ALCOCK N. W. , MCLAREN F. , MOORE P. , PIKE G. A. , ROE S. M. 
Published: May 2016

AbstractThe six‐coordinate Ni complex (III), the seven‐coordinate Zn complex (V), and the five‐coordinate Pd complex (VIII) are prepared by reaction of the ligand (I) mentioned in the title with the metal complexes (II), (IV), or (VI).
ChemInform Abstract: Carbon Dioxide Chemistry of a Binuclear Iridium(0) Complex. Rapid and Reversible Oxygen Atom Transfer from Carbonate.
Authors: REINKING M. K. , NI J. , FANWICK P. E. , KUBIAK C. P. 
Published: May 2016

AbstractThe diphosphine‐bridged tetracarbonyl‐Ir2 complex (IV) prepared as shown is decarbonylated to give the tricarbonyl derivative (V) with a "non‐A‐frame" geometry.
ChemInform Abstract: Polyhedral Organoiridaborane Chemistry. The Reaction of MeNC with (6‐(η5‐C5Me5)‐nido‐6‐IrB9H13). NMR Studies and the Crystal and Molecular Structure of (4,4‐(η5‐C5Me5)(MeNC)‐arachno‐4‐IrB8H12).
Authors: NESTOR K. , FONTAINE X. L. R. , GREENWOOD N. N. , KENNEDY J. D. , THORNTON‐PETT M. 
Published: May 2016

AbstractThe title reaction results in formation of the two new air‐stable arachno metallaboranes (III) and (IV).
ChemInform Abstract: The Sheradsky Rearrangement of α,α′‐Disubstituted Cyclopentanone Aryloximes: A Synthesis of the Sesquiterpenes (.+‐.)‐Aplysin and (.+‐.)‐Filiformin.
Authors: LARONZE J.‐Y. , EL BOUKILI R. , CARTIER D. , LARONZE J. , LEVY J. 
Published: May 2016

AbstractAcidic treatment of the cyclopentanone oxime phenol ether (I) produces the regioisomeric benzofuran derivatives (II) and (III), together with the bromocresol (IV).
ChemInform Abstract: The Palladium‐Mediated Cross‐Coupling of Bromotropolones with Organostannanes. Application to Concise Syntheses of β‐Dolabrin, β‐Thujaplicin, 7‐Methoxy‐4‐isopropyltropolone, and β‐Thujaplicinol.
Authors: BANWELL M. G. , COLLIS M. P. , CRISP G. T. , LAMBERT J. N. , REUM M. E. , SCOBLE J. A. 
Published: May 2016

AbstractPd‐catalyzed reaction of the bromotropolones (I) with the stannane (II) gives the isopropenyltropolones (III).
ChemInform Abstract: Polycyclic Aromatic Alkaloids. Part 2. Synthesis of Onychine and Eupolauridine.
Authors: BRACHER F. 
Published: May 2016

AbstractThe benzoylacetic ester (II) reacts with crotonaldehyde (I) in the presence of hydroxylamine hydrochloride (III) to give the phenylpyridinecarboxylate (IV).
ChemInform Abstract: The Identification and Synthesis of Further Lichen β‐Orcinol para‐Depsides.
Authors: ELIX J. A. , CHESTER D. O. , GAUL K. L. , PARKER J. L. , WARDLAW J. H. 
Published: May 2016

AbstractUnambiguous syntheses are reported for the new depsides (I) and (II) (detected in Erioderma species and Xanthoparmelia duplicata Hale, respectively) and (for the first time) for the already known depsides (III)‐(V); only two examples are given in the scheme.
ChemInform Abstract: Structure of 18‐Molybdodisulfate(VI)(4‐) Ion in (NEt4)4S2Mo18O62·MeCN.
Authors: HORI T. , TAMADA O. , HIMENO S. 
Published: May 2016

AbstractCrystals of the title compound, prepared by a known procedure, are triclinic, space group P1, Z=2.
ChemInform Abstract: 2 SrO·3 Al2O3:Eu2+ (I) and 1.29(Ba,Ca)O, 6 Al2O3:Eu2+ (II). Two New Blue‐Emitting Phosphors.
Authors: SMETS B. , RUTTEN J. , HOEKS G. , VERLIJSDONK J. 
Published: May 2016

AbstractStructure and luminescence properties of the new title phosphors, prepared by solid state reactions of the appropriate oxides (Al2O3, Eu2O3) and carbonates (SrCO3, BaCO3, and CaCO3) at 1100‐1500 °C in forming gas, are studied.
ChemInform Abstract: Fabrication and Characteristics of Vertically Separated Interdigitated Array Electrodes.
Authors: NIWA O. , MORITA M. , TABEI H. 
Published: May 2016

AbstractIn a novel type of interdigitated array electrode the two arrays of microband electrodes are separated by a thin (0.5 μm) insulating SiO2 layer, generated by conventional photolithography and dry‐etching techniques.
ChemInform Abstract: Silicon Etching in CrO3‐HF Solutions. Part 1. High (HF)/(CrO3) Ratios. Part 2. Low (HF)/(CrO3) Ratios.
Authors: VAN DEN MEERAKKER J. E. A. M. , VAN VEGCHEL J. H. C. 
Published: May 2016

AbstractKinetic and mechanistic investigations of the Si dissolution in aqueous CrO3‐HF solution by etching and electrochemical measurements show that the etching process in solutions with (HF)/(CrO3) > 20 is a combination of the reduction of Cr(VI) and the oxidation of Si.
ChemInform Abstract: Dibromoborane‐Dimethyl Sulfide: A Simple Molecular Precursor for the Formation of Bulk Powders and Fiber Coatings of Boron Nitride.
Authors: BECK J. S. , ALBANI C. R. , MCGHIE A. R. , ROTHMAN J. B. , SNEDDON L. G. 
Published: May 2016

AbstractBulk pyrolysis of the Lewis base‐borane adduct Me2S·BHBr2 under NH3 according to the scheme results in the formation of BN powders (diffuse‐reflectance IR, XRD, density measurements, elemental analysis).
ChemInform Abstract: Formation of Mixed‐Ligand Complexes of Cadmium(II) Halide with Tri‐n‐octylphosphine Oxide and Pyridine or Substituted Pyridines in 1,2‐Dichloroethane.
Authors: SATOH K. , TAKAHASHI Y. , SUZUKI T. , SAWADA K. 
Published: May 2016

AbstractThe formation constants are determined by means of solvent extraction.
ChemInform Abstract: Effect of Axially Bound Anions on the Electroreduction of Tin(IV) Porphyrins in Tetrahydrofuran.
Authors: KADISH K. M. , XU Q. Y. Y. , MAIYA G. B. , BARBE J.‐M. , GUILARD R. 
Published: May 2016

AbstractThe first systematic study of the title reaction shows that in all cases electroreduction of (I) leads to porphyrin π anion radical and dianions which are characterized in THF by spectroelectrochemistry and ESR spectroscopy.
ChemInform Abstract: Synthesis of New Heterocycles from Aminopyrazoles.
Authors: RIED W. , ABOUL‐FETOUH S. 
Published: May 2016

AbstractThe 3‐amino‐4‐cyanopyrazoles (I) undergo cyclocondensation with the 1,3‐dicarbonyl compounds (II) or (IV), producing the pyrazolopyrimidines (III) or (V).
ChemInform Abstract: Unusual Rate Acceleration in the Presence of Aldehydes of Distannoxane‐Catalyzed Acetalization of Ketones and Deactivated Aldehydes: A New Mode of Carbonyl Activation.
Authors: OTERA J. , MIZUTANI T. , NOZAKI H. 
Published: May 2016

AbstractThe catalysis of the acetalization of carbonyl compounds such as (I) is studied.
ChemInform Abstract: Long‐Range Triplet Hydrogen Abstraction. Photochemical Formation of 2‐Tetralols from β‐Arylpropiophenones.
Authors: ZHOU B. , WAGNER P. J. 
Published: May 2016

AbstractThe ketones (I) photocyclize to 2‐tetralols (II) via triplet‐state H‐abstraction (quenching experiments); the intermediate 1,6‐biradicals cyclize in 100% efficiency, but the triplets react in very low quantum yields (competition with rapid CT quenching by the β‐aryl group).
ChemInform Abstract: Models for Multicenter Catalysts. Part 3. Facile Hydride Rearrangements in A‐Frame and Related Complexes and the Structure of (RhIr(H)2(CO)2(μ‐Cl)(DPM)2) (BF4)·CH2Cl2, the Product of H2 Addition at One Metal Center in the A‐Frame Pocket.
Authors: VAARTSTRA B. A. , COWIE M. 
Published: May 2016

AbstractThe X‐ray structure determination of (V) as its BF4 salt (P1, Z=2) confirms the mode of H‐bonding proposed from NMR data.
ChemInform Abstract: Reactions of Fluorochloronitromethane with Aldehydes.
Authors: BREL' V. K. , CHEPAKOVA L. A. , KARTAVTSEVA N. F. , MARTYNOV I. V. 
Published: May 2016

AbstractFluorochloronitromethane (I) is coupled with the aldehydes (II) in the presence of alkali to give the carbinols (III).
ChemInform Abstract: A Novel Intramolecular Cyclopropanation Using Iodonium Ylides.
Authors: MORIARTY R. M. , PRAKASH O. , VAID R. K. , ZHAO L. 
Published: May 2016

AbstractIntramolecular cyclopropanation using iodonium ylides is found to be an easy method for the preparation of the desired products in high yields.
ChemInform Abstract: Synthesis and Some Reactions of 3,3,6‐Trisubstituted Tricyclo‐(3.2.0.01,4)heptan‐2‐ones.
Authors: FINCH H. , HIGHCOCK R. M. , ROBERTS S. M. , SHORT K. M. , SIK V. 
Published: May 2016

AbstractThe tricycloheptanones (II) are produced by dehydrobromination of the bicyclic ketones (I) with potassium butoxide.
ChemInform Abstract: Improved and Extended One‐Step Conversion of Primary Amines into Nitriles by Copper‐Catalyzed Oxidation.
Authors: CAPDEVIELLE P. , LAVIGNE A. , MAUMY M. 
Published: May 2016

AbstractEight primary amines such as (I) are converted into the corresponding aliphatic or aromatic nitriles (II) using cuprous chloride in the presence of oxygen and molecular sieves (Kametani's oxidation) in pyridine.
ChemInform Abstract: Reaction of the Aromatic Olefin 1‐(1‐Hexenyl)‐2‐thiomethylbenzene with Cp2Zr(H)Cl. Unexpected Cleavage of the Methyl‐Sulfur Bond.
Authors: ANNBY U. , GRONOWITZ S. , HALLBERG A. 
Published: May 2016

AbstractThe olefin (I) is demethylated with two equivalents of the zirconocene hydride mentioned in the title.
ChemInform Abstract: New Synthetic Method of γ‐ and δ‐Lactones via Successive Alkylation and Reduction of Cyclic Imides.
Authors: YODA H. , MORISHITA H. , KUDO M. , KATAGIRI T. , TAKABE K. 
Published: May 2016

AbstractA new convergent synthetic route to γ‐ and δ‐lactones involves 1. alkylation of imides with Grignard reagents; 2. reduction of the carbinolamide intermediates; 3. cyclization of the resulting hydroxyamides.
ChemInform Abstract: Intermediate in the Reaction of Diketene with 3‐Aminocrotonamides. Part 2.
Authors: GOTO Y. , MASAMOTO K. , ARAI Y. , UEDA Y. 
Published: May 2016

AbstractWhen the reaction of the anilide (I) with diketene is carried out in the presence of NEt3 as catalyst, the stable intermediate (III) (yield given in g) is formed.
ChemInform Abstract: Syntheses and Rearrangements of Spiro‐Fused Dihydroisoquinolones.
Authors: JAHANGIR JAHANGIR , FISHER L. E. , CLARK R. D. , MUCHOWSKI J. M. 
Published: May 2016

AbstractReaction of the o‐toluamide (I) with first LDA and then the imines (II) yields the spiro‐fused isoquinolones (III) which are brominated and subsequently rearranged to produce the cycloheptaisoquinolones (IV).
ChemInform Abstract: Oxidation of Diols with Alkali Hypochlorites Catalyzed by Oxammonium Salts Under Two‐Phase Conditions.
Authors: ANELLI P. L. , BANFI S. , MONTANARI F. , QUICI S. 
Published: May 2016

AbstractHypochlorite oxidation of diols such as (I) in the presence of oxammonium salts gives the hydroxy ketones (II) and the diketones (III).
ChemInform Abstract: Boron Stabilized N,O‐Carbenes. Part 2. X‐Ray Structure of (trans‐4,5‐Dimethyloxazolidin‐2‐ylidene)triphenylboron and N‐Alkylations.
Authors: FEHLHAMMER W. P. , HOFFMEISTER H. , BOYADJIEV B. , KOLREP T. 
Published: May 2016

AbstractThe X‐ray structure analysis of the title compound (Ia) (space group P21/n) reveals a stereochemistry of the carbene ligand which is almost identical with that in transition metal complexes.
ChemInform Abstract: Pentacoordinated Molecules. Part 78. Intramolecular Ligand Exchange of Pentacoordinated Anionic Silicates, R2SiF‐ 3, via 29Si and 19F NMR Spectroscopy. Solution‐ and Solid‐State Structures.
Authors: JOHNSON S. E. , PAYNE J. S. , DAY R. O. , HOLMES J. M. , HOLMES R. R. 
Published: May 2016

AbstractNew pentacoordinated anionic diorganotrifluorosilicates are synthesized as their potassium 18‐crown‐6 salts (IV) according to the scheme.
ChemInform Abstract: Silicon‐Containing Heterocyclic Compounds. Part 54. Synthesis of Alkoxy Derivatives of 9,10‐Dihydro‐9,10‐disilaanthracene.
Authors: CHERNYSHEV E. A. , KOMALENKOVA N. G. , SHASHKOV I. A. , SOBOLEVSKAYA L. V. , KOVALENKO S. I. , UL'YANOVA L. V. , POLIVANOV A. N. , SLYUSARENKO T. F. , NOSOVA V. M. , KISIN A. V. 
Published: May 2016

AbstractReaction of the tetrachlorodisilaanthracene (I) with the alcohols (II) gives the tetraalkoxy (IIIa) ‐ (IIIc) or the diisopropoxy derivative (V) depending on the molar ratio.
ChemInform Abstract: Polyfunctional Molecules. Part 101. Synthesis of a Diphenylphosphine‐Substituted Cyclophosphamide and the X‐Ray Diffraction of Its Oxidation Product.
Authors: ELLERMANN J. , KNOCH F. , MOLL M. , WILL N. 
Published: May 2016

AbstractThe diphenylphosphine‐substituted cyclophosphamide (III) is obtained according to the scheme.
ChemInform Abstract: 1,2λ5σ5‐Oxaphospholenes from Trialkyl Phosphites and Z‐1,1,1,3,3,3‐Hexafluoro‐4‐hydroxy‐3‐penten‐2‐one.
Authors: FRANCKE R. , ROESCHENTHALER G.‐V. + 
Published: May 2016

AbstractThe trialkyl phosphites (I) perform ring closure with the ketone (II) mentioned in the title to give the oxaphospholenes (IIIa) and (IIIb) from the symmetrical phosphites (Ia) and (Ib) or a mixture of the diastereomers (IIIc), (IIId), (IVc), and (IVd) from the cyclic methyl phosphites (Ic) or (Id).
ChemInform Abstract: Preparation and Crystal Structure of a Binuclear Compound of Methylmercury(II) Containing Bismuthiol I as a Bridging Ligand.
Authors: CASTANO M. V. , PLASENCIA M. M. , MACIAS A. , CASAS J. S. , SORDO J. , CASTELLANO E. E. 
Published: May 2016

AbstractThe 2:1 molar reaction of MeHg(OH) (I), freshly prepared in aqueous solution from MeHgCl using Ag2O, with the title ligand (II) leads to the complex (III) (space group I41/a, Z=16; yield not given).
ChemInform Abstract: Synthesis, X‐Ray Characterization, and Q‐Band Electron Spin Resonance Studies of Heterometallic, Polymeric Compounds Formed by Yttrium and Lanthanoid(III) Nitrates with HgL2 (L: C4H6NO, the Anion of 2‐Pyrrolidone): Crystal Structures of ((Hg2EuL4(NO3)3)n) and ((Hg3Tb2L6(NO3)6)n).
Authors: GOODGAME D. M. L. , WILLIAMS D. J. , WINPENNY R. E. P. 
Published: May 2016

AbstractThe polymeric trinuclear and pentanuclear complexes (I) and (II) are obtained by treating hydrated metal(III) nitrates in methanol with an excess of bis(pyrrolidonato)‐Hg.
ChemInform Abstract: Synthesis and Some Reactions of Trineophyltin Hydride.
Authors: CHOPA A. B. , ZUNIGA A. E. , PODESTA J. C. 
Published: May 2016

AbstractIn contrast to other organotin hydrides (Me, Bu, Ph), the relatively stable title compound (III) reacts very slowly with CCl4 to give Nph3SnCl.
ChemInform Abstract: 1‐(N‐(2‐Aminoethyl)aminoalkyl)silatranes and Their Complexes with CuCl2.
Authors: VORONKOV M. G. , BARYSHOK V. P. , LAZAREVA N. F. , SARAEV V. V. , VAKULSKAYA T. I. , HENCSEI P. , KOVACS I. 
Published: May 2016

AbstractReaction of (chloromethyl)triethoxysilane (I) with ethylenediamine (II) produces N‐((2‐aminoethyl)aminomethyl)triethoxysilane (III) which is coupled with triethanolamine (IV) to give the silatrane (Va).
ChemInform Abstract: Synthesis and Crystal Structure of (NiOs3(η‐C5H5)(μ‐H)2(μ‐Cu(PPh3))(CO)9). Hydrogenation‐Dehydrogenation Reactions of Dienes and Alcohols with Heterogeneous Catalysts Derived from (NiM3(η‐C5H5)(μ‐H)2(μ‐X)(CO)9) (M: Ru, X: H; M: Os, X: Cu(PPh3)).
Authors: CASTAGNO F. , CASTIGLIONI M. , SAPPA E. , TIRIPICCHIO A. , TIRIPICCHIO‐CAMELLINI M. , BRAUNSTEIN P. , ROSE J. 
Published: May 2016

AbstractStudies of the title complex (III) (space group P1, Z=2) show that this complex, supported on Chromosorb and thermally activated under H2, forms a heterogeneous catalyst for the hydrogenation‐dehydrogenation of several substrates, in particular alcohols (giving formaldehyde, acetaldehyde, and acetone from methanol, ethanol, and iso‐ or propanol, respectively).
ChemInform Abstract: Diastereoselective Formation of Substituted Cyclic Non‐Proteinogenic α‐Amino Acids by Cyclization of Activated Imines.
Authors: TIETZE L. F. , BRATZ M. 
Published: May 2016

AbstractThe azomethines (III), prepared by reaction of the amine (I) with the glyoxylates (II), are cyclized upon treatment with trimethylsilyl triflate to give the piperidines (IV) and (V).
ChemInform Abstract: The Wittig‐Horner Reaction on 2,3,4,6‐Tetra‐O‐benzyl‐D‐mannopyranose (I) and 2,3,4,6‐Tetra‐O‐benzyl‐D‐glucopyranose (VII).
Authors: ALLEVI P. , CIUFFREDA P. , COLOMBO D. , MONTI D. , SPERANZA G. , MANITTO P. 
Published: May 2016

AbstractThe synthetic utility of the Wittig‐Horner reaction in the synthesis of C‐glycosides is illustrated by the preparation of the α‐ and β‐glycosyl acetates (III)‐(VI) of protected D‐manno‐ and D‐glucopyranose.
ChemInform Abstract: Synthesis and Conformation of 9‐(3′‐C‐Methyl‐β‐D‐xylo‐furanosyl)adenine and 3′‐C‐Methyladenosine, Two Sugar‐Methylated Nucleoside Analogues.
Authors: KOOLE L. H. , BUCK H. M. , VIAL J.‐M. , CHATTOPADHYAYA J. 
Published: May 2016

AbstractThe methyl group of the title nucleoside analogues (V) and (VI) prefers an equatorial location.
ChemInform Abstract: Addition of Grignard Reagents to 4‐O‐TPS Pyrimidine Nucleosides: Synthesis of 6‐Substituted‐5,6‐Dihydropyrimidine Nucleoside Derivatives.
Authors: BISCHOFBERGER N. 
Published: May 2016

AbstractThe pyrimidine nucleosides (I) and (V) react with the Grignard compounds (II) to give the substitution products (III) and (IV) or (VI).
ChemInform Abstract: Cumulated Ylides. Part 20. Syntheses of E‐α,β‐Unsaturated Macrocyclic Lactones by Intramolecular Wittig Olefination via Triphenylphosphoranylidene Ketene.
Authors: BESTMANN H. J. , SCHOBERT R. 
Published: May 2016

AbstractReaction of the protected or unprotected hydroxy aldehydes (II), (VI), and (IX) with the ketene ylide (I) and subsequent intramolecular Wittig reaction produce the macrocyclic lactones (IV) and (XI).
ChemInform Abstract: System (AO)mM2B2n‐2FenO4n+z with m = 2 and n = 1, 2 for A: Bi, Pb and M, B: Sr.
Authors: KEMMLER‐SACK S. , EHMANN A. , FRIES T. , MAYER‐VON KUERTHY G. + , LOESCH S. + , SCHLICHENMAIER M. 
Published: May 2016

AbstractSamples of the new family of iron compounds of the general formula of title are prepared by heating appropriate mixtures of Bi(NO3)3·5 H2O, PbO, Sr(NO3)2, and Fe powder in corundum boats in air at temp. of 860‐880 °C (n = 1) or 930‐950 °C (n = 2) for several days.
ChemInform Abstract: Terlinguaite, Hg4O2Cl2, a Mineral with Unusual Hg3 Units.
Authors: BRODERSEN K. , GOEBEL G. + , LIEHR G. 
Published: May 2016

AbstractRedetermination from a synthetic single crystal shows the structure of terlinguaite (C2/c, Z=4) to consist of a single, highly crosslinked, giant molecule, containing unusual Hg3 clusters with Hg‐Hg bond lengths of 270 pm.
ChemInform Abstract: Transition Metal Peroxofluoro Complexes. Part 9. Crystal Structure of Ba3(Ti(O2)F5)2·2 H2O.
Authors: SCHMIDT R. , PAUSEWANG G. 
Published: May 2016

AbstractThe title compound, which previously has been found to be the sole defined peroxofluoro compound in the BaF2‐TiO2‐HF‐H2O2‐H2O system, crystallizes in the tetragonal system (P42/mbc, Z=4).
ChemInform Abstract: Synthesis and Properties of the Sodium Perxenonate Na3HXeO6·H2O.
Authors: ISUPOV V. K. , OLEINIK A. V. , ALEINIKOV N. N. 
Published: May 2016

AbstractThe novel title compound with octavalent Xe is prepared in 63% yield by dissolving the known Na4XeO6·1.65 H2O in water.
ChemInform Abstract: Preparation, Structure and Properties of Sodium Triamidohydroxocyclotrinitridosulfodiphosphate.
Authors: ROZANOV I. A. , MEDVEDEVA L. YA. 
Published: May 2016

AbstractThe known sodium salt (I) on heating to 150 °C for at least 42 h affords the novel title compound (II) (no yield given), whose structure is deduced from its IR and X‐ray data.
ChemInform Abstract: Compound U2S2SeTe.
Authors: SLOVYANSKIKH V. K. , KUZNETSOV N. T. , GRACHEVA N. V. , CHECHERNIKOV V. I. , MARTYNOVA L. F. 
Published: May 2016

AbstractThe hitherto unknown title compound is prepared from the elements employing the chemical transportation method at 1150 → 1070 K. According to the single‐crystal X‐ray analysis this compound belongs to the space group Pnma with Z=4.
ChemInform Abstract: Ni5HfB2O10 with Ordered Metal Distribution.
Authors: BLUHM K. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractSingle crystals of the hitherto unknown title compound, prepared by reacting NiO and HfO2 in a flux of B2O3 (no yield given), crystallizes in the orthorhombic space group Pnma with Z=4.
ChemInform Abstract: Synthesis, Crystal Structure, and Magnetic Properties of the Ternary Uranium Palladium Selenide PdUSe3.
Authors: DAOUDI A. , NOEL H. 
Published: May 2016

AbstractThe title compound is prepared by annealing a stoichiometric mixture of Pd, USe2, and Se for 24 h at 900 °C and subsequently for 2 d at 1000 °C. Single crystals are grown by chemical vapor transport using iodine as transporting agent and a temp. gradient from 980 to 900 °C. PdUSe3 crystallizes in the orthorhombic space group Pnam, Z=4, and is isotypic with CrUS3.
ChemInform Abstract: Liquid Xenon: An Effective Inert Solvent for C‐H Oxidative Addition Reactions.
Authors: SPONSLER M. B. , WEILLER B. H. , STOUTLAND P. O. , BERGMAN R. G. 
Published: May 2016

AbstractThe photochemical reaction of the dihydride (I) with a variety of organic substrates, e.g. (II) (9 examples) in liquid xenon leads to oxidative addition products of the type (III).
ChemInform Abstract: 1,3‐Dipole Cascade. A New Method for Azomethine Ylide Formation.
Authors: PADWA A. , DEAN D. C. , ZHI L. 
Published: May 2016

AbstractThe diazo compounds (I) react via 1,3‐dipolar cycloaddition of the intermediate azomethine ylides (III) with the alkynes (II) to give the tricyclic products (IV).
ChemInform Abstract: Enantiodifferentiating Functionalization of cis‐Cycloalkane‐1,2‐diols and cis‐endo‐5‐Norbornen‐2,3‐ylenebis(methanol) via Chiral Spiroacetals Derived from l‐Menthone.
Authors: HARADA T. , WADA I. , OKU A. 
Published: May 2016

Abstract(‐)‐Menthone (I) reacts with the cis‐1,2‐bis(siloxy)cycloalkanes(alkenes) (II) in the presence of trimethylsilyl triflate to form the chiral acetals (III) and (IV).