bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Oxoperoxo(citrato)‐ and Dioxo(citrato)vanadates(V): Synthesis, Spectra, and Structure of a Hydroxyl Oxygen Bridged Dimer, K2(VO(O2)(C6H6O7))2·2 H2O.
Authors: DJORDJEVIC C. , LEE M. , SINN E. 
Published: May 2016

AbstractThe first citrato complexes of vanadium, the complexes (I) are prepared by treating potassium, ammonium, or sodium vanadate in aqueous solution with H2O2 (30%) and subsequently with citric acid and for (Ic) with CsCl.
ChemInform Abstract: Multiple Bonds Between Main‐Group Elements and Transition Metals. Part 60. Bridging Lead Atoms in Organometallic Complexes: First Examples.
Authors: HERRMANN W. A. , KNEUPER H.‐J. , HERDTWECK E. 
Published: May 2016

AbstractThe Pb‐bridged Mn2 complexes (III) are obtained by equimolar reaction of the photochemically generated THF‐Mn complex (I) with PbCl2 (II).
ChemInform Abstract: Mixed‐Valence Cu(I)Cu(II) Macrocyclic Complex: A Result of a Cu(II)‐Promoted Oxidation of Aziridines into Cyanide.
Authors: AGNUS Y. , GISSELBRECHT J. P. , LOUIS R. , METZ B. 
Published: May 2016

AbstractThe mixed Cu(I)Cu(II) macrocyclic complex (IV) is obtained by reaction of Cu(II) perchlorate (II) with the macrocycle (I) and N‐methylaziridine (III) in a 2:1:1 ratio.
ChemInform Abstract: Asymmetric Induction in Oxygenation of Styrene Catalyzed by Cobalt Schiff Base Complex.
Authors: NISHINAGA A. , YAMATO H. , ABE T. , MARUYAMA K. , MATSUURA T. 
Published: May 2016

AbstractThe oxidation of styrene (II) to give optically active 1‐phenylethanol (III) is performed in the presence of chiral cobalt Schiff base complexes such as (I).
ChemInform Abstract: Convenient Synthesis of 1,1,1‐Trifluoro‐4,5‐diaza‐2,4‐alkadienes and 1‐Aryl‐3,3,3‐trifluoro‐1‐propanones.
Authors: KAMITORI Y. , HOJO M. , MASUDA R. , OHARA S. , KAWAMURA Y. , EBISU T. 
Published: May 2016

AbstractTreatment of the hydrazones (I) with trifluoroacetic anhydride (II) gives the 1‐trifluoroacetylated hydrazones (III) which react with excess (II) to form the diazaalkadienes (IV).
ChemInform Abstract: Nonsteroidal Antiinflammatory Agents. Part 18. Stereomeric Optically Active Halophenyl(biphenylyl)hydroxypropionic Acids.
Authors: VAROLI L. , BURNELLI S. , GUARNIERI A. , GHEDINI N. , SCAPINI G. , FERRI S. , CAVICCHINI E. 
Published: May 2016

AbstractThe 2‐biphenylyl‐3‐halophenyl‐3‐hydroxypropionic acid esters (IV) and (V) are prepared by coupling the benzaldehydes (I) with the dilithium salt of 4‐biphenylacetic acid (II) followed by esterification with diazomethane (III).
ChemInform Abstract: Highly Enantioselective Claisen‐Type Acylation and Dieckmann Annulation.
Authors: NAGAO Y. , HAGIWARA Y. , TOHJO T. , HASEGAWA Y. , OCHIAI M. , SHIRO M. 
Published: May 2016

AbstractTreatment of the esters (I) with lithium isopropylcyclohexylamide and subsequent acylation with the N‐(acyl)isopropylthiazolidinethiones (II) give the asymmetric β‐keto esters (III).
ChemInform Abstract: Synthesis and Oral Hypoglycemic Properties of 4‐Oxo‐4,5,6,7‐tetrahydroindole‐3‐acetic Acids.
Authors: NAGARAJAN K. , TALWALKER P. K. , GOUD A. N. , SHAH R. K. , SHENOY S. J. , DESAI N. D. 
Published: May 2016

AbstractA series of analogues of (Ia) (= C 8778‐GO) and (Ib) (= C 9001‐GO) are prepared and tested for their hypoglycemic activity.
ChemInform Abstract: Synthesis of Mitomycins. Part 6. Functionalization of Benzopyrrolizines in 1,2‐Position.
Authors: FLITSCH W. , NIEHOFF A. 
Published: May 2016

AbstractWith a view to the synthesis of the mitomycin skeleton, the functionalization of C‐1/C‐2 in the model compounds (II) is envisaged.
ChemInform Abstract: Antitumor Imide Derivatives of 2,3‐Dimethyl‐7‐oxabicyclo(2.2.1)heptane‐2,3‐dicarboxylic Acid.
Authors: WALTER W. G. 
Published: May 2016

AbstractThe title compounds (III) are prepared from the anhydride (I) by reaction with the amines (II).
ChemInform Abstract: 1,3‐Anti Asymmetric Induction in Addition of Organotitanium Reagents to β‐Substituted Aldehydes with a Dithioacetal Group.
Authors: HONDA Y. , TUCHIHASHI G. 
Published: May 2016

AbstractThe 2‐formyl‐1,3‐dithianes (I) are treated with various methylmetallic compounds under different conditions to give the hydroxyethyl derivatives (III).
ChemInform Abstract: A Simple Route to 4,4‐Dialkoxy‐2‐azetidinones: Useful Intermediates for Organic Synthesis.
Authors: GRAZIANO M. L. , CIMMINIELLO G. 
Published: May 2016

Abstract(2 + 2)Cycloaddition reaction of the ketene acetals (I) with the isocyanates (II) yields the title compounds (III).
ChemInform Abstract: Photochemical Formation of a Stable Oxalic Orthoamide with Propellane Structure.
Authors: TAUER E. , GRELLMANN K.‐H. , NOLTEMEYER M. , SHELDRICK G. M. 
Published: May 2016

AbstractThe new quinoxalinoquinoxaline (III) forms the title compound (IV) photochemically (fluorescence, space group for (IV).
ChemInform Abstract: Silsesquioxanes as Models for Silica Surfaces.
Authors: FEHER F. J. , NEWMAN D. A. , WALZER J. F. 
Published: May 2016

AbstractThe hydrolytic condensation of cyclohexyltrichlorosilane (I) affords the products (III), (IV) and (Va), which exhibit very different solubility properties and can be easily separated.
ChemInform Abstract: Cycloaddition Reactions Between Tetrafluorodisilacyclobutene and Cyclic Dienes Mediated by Transition Metal Carbonyls.
Authors: LIN C. H. , LEE C. Y. , JZANG T. T. , LIN C. C. , LIU C. S. 
Published: May 2016

AbstractPhotolysis or thermolysis of the metal complexes (III) or (VI) results in demetalation and cyclization, producing the Si heterocycles (IV) or (VII) and (VIII).
ChemInform Abstract: Synthesis, Taste Properties, and Conformational Analysis of Four Stereoisomeric Cyclopropane Analogs of Aspartame.
Authors: MAPELLI C. , STAMMER C. H. , LOK S. , MIERKE D. F. , GOODMAN M. 
Published: May 2016

AbstractThe N‐protected aminocyclopropanecarboxylic acids (I) are esterified with diazomethane (II) and then deprotected to give the aminocyclopropanecarboxylates (III).
ChemInform Abstract: Vapor Pressure of Promethium Trifluoride.
Authors: GIBSON J. K. , HAIRE R. G. 
Published: May 2016

AbstractThe relative vapor pressures of each component of the ternary mixed fluoride system (Pr1/3Pm1/3Sm1/3)F3 are determined simultaneously over the temp. range 1100‐1280 °C by using Knudsen effusion‐mass spectrometry.
ChemInform Abstract: Voltammetric Study of Polycrystalline Rhodium in Alkaline Solutions at Different Temperatures.
Authors: CATALDI Z. , LEZNA R. O. , GIORDANO M. C. , ARVIA A. J. 
Published: May 2016

AbstractThe voltammetric behavior of Rh in 1 M KOH (pH 13.8) is investigated in the temp. range 273‐353 K, with special emphasis on the different stages of Rh surface oxide electroformation, involving successive formation of RhOH, RhO monolayer, and hydrous Rh oxide layer growth.
ChemInform Abstract: Molten Potassium Pyrosulfate: Reactions of Seven Metal Sulfides.
Authors: MINEELY P. J. , TARIQ S. A. 
Published: May 2016

AbstractStudies of the reactions of Na2S·9 H2O, K2S3, ZnS, CdS, Sb2S3, PbS, and FeS with molten K2S2O7, by using mainly DTA and TG techniques, confirm the presence of SO42‐, SO2, and S in all the reactions.
ChemInform Abstract: Thiono and Dithio Esters. Part 42. Synthesis and Properties of Cyanoacetic Thiono Esters.
Authors: MUELLER H.‐G. + , HARTKE K. 
Published: May 2016

AbstractThe cyanothioacetates (IV) are prepared from malononitrile (I) by reaction with the alcohols (II) in the presence of gaseous HCl and subsequent treatment with hydrogen sulfide.
ChemInform Abstract: Selective Synthesis of Halogen Derivatives from 5‐Acetoxytropolone.
Authors: NAGAO T. , MORI A. , TAKESHITA H. 
Published: May 2016

AbstractIn contrast to 5‐hydroxytropolone (Ib) which gives complex mixtures, its acetyl derivative (Ia) can be successfully halogenated using the tribromide (II) or SOCl2.
ChemInform Abstract: A Facile Entry to β,δ‐Diketo and syn‐β,δ‐Dihydroxy Esters.
Authors: HANAMOTO T. , HIYAMA T. 
Published: May 2016

AbstractThe dianion of the acetoacetate (I) is coupled with the hydroxamates (II) to produce the β,δ‐diketo esters (III).
ChemInform Abstract: Direct Transformation of 2,3‐Epoxy Alcohols into Hydroxy Carbonates Under Mildly Basic Conditions.
Authors: MYERS A. G. , WIDDOWSON K. L. 
Published: May 2016

AbstractVarious optically active (hydroxyalkyl)oxiranes are treated with cesium carbonate in a carbon dioxide (II) atmosphere, forming chiral cyclic hydroxy carbonates.
ChemInform Abstract: Synthesis of Vinylic Lactones via Palladium‐Catalyzed Coupling of Vinylic Halides or Triflates and Unsaturated Carboxylic Acids.
Authors: LAROCK R. C. , LEUCK D. J. , HARRISON L. W. 
Published: May 2016

AbstractCoupling of the 3‐butenoic acids (II) or (VI) with the vinylic halides or triflates (I) or (IV) in the presence of diethylisopropylamine, tetrabutylammonium chloride, and a Pd catalyst yields the vinylic γ‐lactones (III), (V), and (VII).
ChemInform Abstract: Formation, Structure, and Properties of Chelates of 1‐Difluoroboryloxy‐2‐acyl‐ and 2‐Difluoroboryloxy‐1‐acylnaphthalene.
Authors: STARKOV S. P. , PANASENKO A. I. , POLYANSKAYA N. L. , VOLKOTRUB M. N. 
Published: May 2016

Abstractα‐Naphthol (I) is coupled with the carboxylic acids (II) in the presence of boron trifluoride (III) to give the chelates (IV) which are hydrolyzed, producing the ketones (V).
ChemInform Abstract: Synthesis and X‐Ray Structure of the First Dinuclear Homoleptic Chromium(II) Amide, (((i‐Pr)2N)Cr(μ‐(i‐Pr)2N))2.
Authors: EDEMA J. J. H. , GAMBAROTTA S. , SPEK A. L. 
Published: May 2016

AbstractThe quadruply bonded dimer (I) reacts with the amine (II) to yield the title complex (III), (space group P1 with Z=2).
ChemInform Abstract: Thiolate Complexes of Osmium(III) with Tertiary Phosphines and Their Dicarbonyl Derivatives of Osmium(II): X‐Ray Crystal Structure of trans,trans,trans‐(Os(SC6F5)2(CO)2(PEt2Ph)2).
Authors: CRUZ‐GARRITZ D. , SOSA P. , TORRENS H. , HILLS A. , HUGHES D. L. , RICHARDS R. L. 
Published: May 2016

AbstractThe new paramagnetic Os(III) complexes (III), are probably dimers in solution.
ChemInform Abstract: A New Photoinduced Rearrangement of Steroidal α,β‐Unsaturated Cyclic Ketone Oximes into the β,γ‐Unsaturated Isomer Involving an Intramolecular Stereospecific Hydrogen Transfer.
Authors: SUGINOME H. , OHKI T. 
Published: May 2016

AbstractCholest‐1‐en‐3‐one (I) is converted into E‐1,4,4‐trimethylcholest‐1‐en‐3‐one oxime (IIa) and the deuterated derivatives (IIb) and (IIc) which undergo stereospecific isomerization on irradiation, forming the methylene derivatives (III).
ChemInform Abstract: Synthetic Studies on an Antitumor Antibiotic, Bleomycin. Part 25. An Efficient Synthesis of erythro‐β‐Hydroxy‐L‐histidine, The Pivotal Amino Acid of Bleomycin‐Fe(II)‐O2 Complex.
Authors: OWA T. , OTSUKA M. , OHNO M. 
Published: May 2016

AbstractThe optically active N‐(bromoacetyl)oxazolidinone (I) is converted to the boron enolate and then coupled with the formylimidazole (II) to give the syn‐bromohydrin (III).
ChemInform Abstract: Colchicine Models: Synthesis and Antitubulin Activity of 2′‐Monosubstituted and 2′,5‐Disubstituted 2,3,4,4′‐Tetramethoxy‐1,1′‐biphenyls. Synthesis of 4,4′,5′,6′‐Tetramethoxy‐1,1′‐biphenyl‐2,3′‐dicarboxylic Acid.
Authors: ITOH Y. , BROSSI A. , HAMEL E. , FLIPPEN‐ANDERSON J. L. , GEORGE C. 
Published: May 2016

AbstractThe 2'‐monosubstituted and 2',5'‐disubstituted title compounds (III) and (IV) as well as the dicarboxylic acid (V) are prepared as models for colchicine (VI); however, only (III) shows appreciable activities in the tubulin binding assay or as inhibitor of tubulin polymerization.
ChemInform Abstract: A Kinetic Study of the Oxidation of Water by CeIV Ions in Different Acid Media, Mediated by Thermally Activated Ruthenium Dioxide Hydrate.
Authors: MILLS A. , GIDDINGS S. 
Published: May 2016

AbstractThermally activated RuO2·yH2O* is able to ediate the oxidation of water to O2 by Ce(IV) ions in 0.5 M H2SO4 and 1 M HClO4/3.5·10‐2 M H2SO4.
ChemInform Abstract: Photochemical Rearrangements of Stable Silenes.
Authors: BAINES K. M. , BROOK A. G. , FORD R. R. , LICKISS P. D. , SAXENA A. K. , CHATTERTON W. J. , SAWYER J. F. , BEHNAM B. A. 
Published: May 2016

AbstractThe photolysis of the acylsilanes (III) gives silenes (IV), whose subsequent chemistry is dependent on the steric size of the substituents R1 and R2 and on their facile photochemical excitation by UV light.
ChemInform Abstract: Oxidation Using Quaternary Ammonium Polyhalides. Part 2. A Convenient Haloform Reaction Using Benzyltrimethylammonium Tribromide.
Authors: KAJIGAESHI S. , KAKINAMI T. , YAMAGUCHI T. , UESUGI T. , OKAMOTO T. 
Published: May 2016

AbstractThe use of the title ammonium salt, a stable crystalline red compound, renders possible a facile synthesis of carboxylic acids from aliphatic and aromatic ketones such as (I) (26 examples) or from the alcohols (IV) in almost quantitative yield.
ChemInform Abstract: Potential Cardiotonica Agents. Part 2. Synthesis and Pharmacological Properties of 5‐(4‐Pyridyl)‐ and 5‐Phenyl‐Substituted 3‐Cyano‐6‐methyl‐2‐(oxaalkylamino)pyridines.
Authors: KLAUSCHENZ E. , RUMLER A. , HAGEN V. , HAGEN A. , HEER S. , MITZNER R. , NIEDRICH H. 
Published: May 2016

AbstractTreatment of the pyridones (I) with POCl3 yields the chloropyridines (II) which react with the amines (III) to give the corresponding aminopyridines (IV).
ChemInform Abstract: Preparation and Interconversion of Dimeric Di‐μ‐hydroxo and Tri‐μ‐hydroxo Complexes of Platinum(II) and Palladium(II) with 2,2′‐Bipyridine and 1,10‐Phenanthroline.
Authors: WIMMER S. , CASTAN P. , WIMMER F. L. , JOHNSON N. P. 
Published: May 2016

AbstractThe dinitrato complexes (III) are prepared according to the scheme.
ChemInform Abstract: The Chemistry of Thujone. Part 14. Synthesis of Biologically Active Aryl Terpenoid Analogues.
Authors: CARVALHO C. , CULLEN W. R. , FRYZUK M. D. , JACOBS H. , JAMES B. R. , KUTNEY J. P. , PIOTROWSKA K. , SINGH V. K. 
Published: May 2016

AbstractThe isoprenoid ethers (II), readily available from thujone (I), are subjected to a series of epoxidation reactions.
ChemInform Abstract: The Effect of Boron on ZSM‐5 Zeolite Shape Selectivity and Activity. Part 2. Coincorporation of Aluminum and Boron in the Zeolite Lattice.
Authors: SAYED M. B. , AUROUX A. , VEDRINE J. C. 
Published: May 2016

AbstractThe title zeolite is synthesized in the presence of NaAlO2 and NaBO2 to yield a crystalline phase of almost unchanged Al + B site population, but with increased B/Al ratio.
ChemInform Abstract: Conjugate Addition vs. Vinyl Substitution in Palladium‐Catalyzed Reaction of Aryl Halides with β‐Substituted‐α,β‐enones and ‐enals.
Authors: AMORESE A. , ARCADI A. , BERNOCCHI E. , CACCHI S. , CERRINI S. , FEDELI W. , ORTAR G. 
Published: May 2016

AbstractThe outcome of the reaction of β‐substituted‐α,β‐enones, e.g. (I), and ‐enals with aryl halides such as (II), (VI), or (VII), depends greatly on the nature of the added base.
ChemInform Abstract: Rhodium‐Catalyzed Isomerization of 1,3‐Diene Monoepoxides to α,β‐Unsaturated Carbonyl Compounds.
Authors: SATO S. , MATSUDA I. , IZUMI Y. 
Published: May 2016

AbstractThe α‐bromo ketones (I) react with the vinyl Grignard reagent (II) to give the vinyloxiranes (III) which rearrange in the presence of a rhodium catalyst, forming the unsaturated ketones (IV).
ChemInform Abstract: (4.3.0)‐Fused Pyrazolidinones as Potential Antibacterial Agents.
Authors: TERNANSKY R. J. , DRAHEIM S. E. 
Published: May 2016

AbstractThe N‐protected aminopyrazolidinone (I) reacts with methyl bromoacetate (II) to give the N‐substituted product (III) which is reduced and sulfonated to form the mesylate (V) and via sulfonate ‐ iodide exchange the iodide (VI).
ChemInform Abstract: Synthesis and Antibacterial Activity of Some New 2‐Aryloxymethyl 3‐Substituted Quinazolin‐4(3H)‐ones.
Authors: KHAN A. , SAKSENA R. K. 
Published: May 2016

AbstractCyclocondensation of anthranilic acid (I) with the phenoxyacetyl chlorides (II) leads to the formation of the benzoxazin‐4‐ones (III) which form the quinazolin‐4(3H)‐ones (V) upon ring closure with the aniline derivatives (IV) in boiling pyridine.
ChemInform Abstract: Wittig Reactions of 1‐Alkoxycarbonyl‐2‐hydroxypyrrolidines and ‐piperidines: Synthesis of (.+‐.)‐Hygrine and (.+‐.)‐2‐Epilasubine II.
Authors: NAGASAKA T. , YAMAMOTO H. , HAYASHI H. , WATANABE M. , HAMAGUCHI F. 
Published: May 2016

AbstractWittig olefination of the cyclic hydroxy carbamates (I) with the phosphoranes (II) followed by intramolecular addition reaction of the intermediate aminoacrylates yields the α‐alkylated pyrrolidines and piperidines (III).
ChemInform Abstract: Temperature Dependence of the Lattice Constants and Thermal Expansion Coefficients of UMn2Si2 and UMn2Ge2 Compounds.
Authors: BUDKOWSKI A. , SZYTULA A. , BAN Z. 
Published: May 2016

AbstractThe lattice constants of polycrystalline samples of the title ferromagnets are measured between 80 and 300 K and the corresponding temp. dependences of the thermal expansion coefficients αa, αc, and βv are calculated.
ChemInform Abstract: Sulfur‐Induced Breakdown of the Passive Film and Pitting Studied on Nickel and Nickel Alloys.
Authors: MARCUS P. , TALAH H. 
Published: May 2016

AbstractSamples of Ni and Ni75Fe25 alloys are doped with sulfur by treatment in a H2S/H2 gas mixture at 1100‐1200 °C. After passivation of the bare metal surface, sulfur present in the metal accumulates at the metal‐passive film interface and causes the breakdown of the passive film.
ChemInform Abstract: Reactivity of tert.‐Butoxy Radicals Toward Thiols, Alkyl Sulfides, and Alkyl Disulfides.
Authors: ENCINAS M. V. , LISSI E. A. , MAJMUD C. , OLEA A. F. 
Published: May 2016

AbstractThe kinetics of the reaction of tBuO· (from (tBu‐O‐O‐CO)2) with Me‐(CH2)5‐SH, R‐S‐R (R: ‐Me, ‐tBu), and R‐S‐S‐R (R: ‐Me, ‐sBu, ‐iPr) are measured at 310 K in benzene and compared to those found for the deactivation of the benzophenone triplet.
ChemInform Abstract: Halogenations of Aromatic Compounds with Halide Anions in the Presence of Nitrobenzenesulfonyl Peroxides. A Novel Method for the Formation of Positive Halogens.
Authors: YOSHIDA M. , MOCHIZUKI H. , KAMIGATA N. 
Published: May 2016

AbstractToluene and anisole (I) are treated with triethylammonium chloride or bromide in the presence of p‐nitrobenzenesulfonyl peroxide to form the p‐ and o‐halogenated derivatives (II) and (III).
ChemInform Abstract: Carbon‐Carbon Bond Formation at the γ‐Position of Dienolates via the Germanium‐Masked Dienolates.
Authors: YAMAMOTO Y. , HATSUYA S. , YAMADA J. 
Published: May 2016

AbstractLithiation of the α,β‐unsaturated carboxylate (I) and subsequent germylation yield the β,γ‐unsaturated α‐germyl ester (III) which is coupled with the acetals (IV), benzaldehyde (VI), or the halides (VIII) in the presence of a Lewis acid to give E/Z‐mixtures of the esters (V), (VII), and (IX).
ChemInform Abstract: Chemistry of Phthalide‐3‐carboxylic Acid. Part 5. Reaction of the Acid with Imines.
Authors: CHIEFARI J. , JANOWSKI W. K. , PRAGER R. H. 
Published: May 2016

AbstractPhthalidecarboxylic acids such as (I) decarboxylate readily in the presence of imines such as (II) or (VI) the product depending on the solvent used.
ChemInform Abstract: Acidity and Alkylation of 4‐Phenyl‐3,5‐dihydroxypyrazole and Its Derivatives. C versus O and N Alkylation.
Authors: ZVILICHOVSKY G. , DAVID M. 
Published: May 2016

AbstractThe tautomers of 4‐phenyl‐3,5‐dihydroxypyrazole (I) are alkylated with diazomethane (II) to give the O‐ and N‐methylation products (III) and (IV).
ChemInform Abstract: Preparation of 1‐(Benzyloxycarbonyl)hexahydro‐3‐pyridazinecarboxylic Acid, a Protected Piperazic Acid.
Authors: ADAMS C. E. , AGUILAR D. , HERTEL S. , KNIGHT W. H. , PATERSON J. 
Published: May 2016

Abstract4‐Phenyl‐1,2,4‐triazolidine (I) is converted to the urazole (II) and then subjected to Diels‐Alder reaction with 1,3‐butadiene‐1‐carboxylic acid (III), yielding the cycloadduct (IV).
ChemInform Abstract: A New and Convenient Synthesis of N‐Substituted Perhydroazepines from Adipaldehyde and Primary Amines with Tetracarbonylhydridoferrate, HFe(CO)4‐, as a Selective Reducing Agent.
Authors: SHIM S. C. , DOH C. H. , KIM T. J. , LEE H. K. , KIM K. D. 
Published: May 2016

AbstractThe iron hydrido complex mentioned in the title is generated in situ from pentacarbonyliron and carbon monoxide in ethanolic KOH.
ChemInform Abstract: Synthesis of Bis(oxydimethylene)tetrathiafulvalene (BODM‐TTF) and BEDSe‐TTF.
Authors: HSU S.‐Y. , CHIANG L. Y. 
Published: May 2016

AbstractThe bis(ethylenediseleno)tetrathiafulvalene (BEDSe‐TTF) (IV) is prepared by complete lithiation of the TTF (I), followed by addition of selenium (II) and quenching with 1,2‐dibromoethane (III).
ChemInform Abstract: Preparation and Properties of Alkyl Diarylbismuthinates. A New Class of Organic Pentavalent Bismuth Compounds.
Authors: OGAWA T. , MURAFUJI T. , IWATA K. , SUZUKI H. 
Published: May 2016

AbstractThe triarylbismuthines (Ia) and (Ib) react with chloramine T (II) in the presence of methanol (III) to form the methyl diarylbismuthinates (IV).
ChemInform Abstract: Chemistry of Complexes of Perhalogenated Cyclopentadienes and Alkynes. Part 4. Preparation, Reactions, and Structures of Alkylthio‐ and Phenylthio‐Substituted (Cyclopentadienyl)manganese and ‐rhodium Complexes.
Authors: SUENKEL K. + , STEINER D. 
Published: May 2016

AbstractPreparations and reactions of the title compounds are shown in the scheme.
ChemInform Abstract: Metallomacrocycles: Synthesis, X‐Ray Structure, Electrochemistry, and ESR Spectroscopy of Mononuclear and Heterodinuclear Complexes.
Authors: VAN VEGGEL F. C. J. M. , HARKEMA S. , BOS M. , VERBOOM W. , VAN STAVEREN C. J. , GERRITSMA G. J. , REINHOUDT D. N. 
Published: May 2016

AbstractThe Ba2+‐templated (1:1) macrocyclization of dialdehydes such as (I) and (II) with 1,2‐diamino‐2‐methylpropane and o‐phenylenediamine offers a convenient route to heterodiligating ligands with two very different cavities.
ChemInform Abstract: A Study of the Sensitization of Gd3+ Luminescence by Pb2+ Ions
Authors: KILIAAN H. S. , BLASSE G. 
Published: May 2016

Abstractis performed for the Tb3+‐activated compounds GdBO3: Pb, Tb (I) GdB3O6: Pb, Tb (II), Ba3‐x(La, Gd)1+x(PO4)3‐x(SiO4)x: Pb, Tb (x = 0, 1) (III) and Sr2(Ln, Gd)8(SiO4)6O2: Pb, (Tb, Mn) with Ln: Y, La (IV).
ChemInform Abstract: Effect of Coprecipitated Metal Ions on the Electrochemistry of Nickel Hydroxide Thin Films: Cyclic Voltammetry in 1 M KOH.
Authors: CORRIGAN D. A. , BENDERT R. M. 
Published: May 2016

AbstractBinary 9:1 composite hydroxides of Ni with Cd, Ce, Cr, Co, Cu, Fe, La, Pb, Mg, Mn, Ag, Y, or Zn, prepared by cathodic deposition from mixed metal nitrate solutions, are characterized by cyclic voltammetry in 1 M KOH.
ChemInform Abstract: Coordination Chemistry of Sterically Hindered Thiolate Ligands. Preparation and Structural Characterization of the Oligomeric Homoleptic Complexes (Cu(SC6H4‐o‐SiMe3))12 and ((Ag(SC6H4‐o‐SiMe3))4)2 and a Comparison to the Structure of the Mononuclear Species (Et4N)2(Cd(SC6H4‐o‐SiMe3)4).
Authors: BLOCK E. , GERNON M. , KANG H. , OFORI‐OKAI G. , ZUBIETA J. 
Published: May 2016

AbstractThe thiolato ligand is prepared by a known method.
ChemInform Abstract: Substitution Reactions Which Proceed via Radical Anion Intermediates. Part 34. Electron‐Transfer Substitution Reactions: Facilitation by the Cyano Group.
Authors: KORNBLUM N. , FIFOLT M. J. 
Published: May 2016

AbstractIt has been known for some time that benzylic halides react with nitroparaffin salts of type (II) to yield O‐alkylation products such as (III), except for the p‐nitrobenzyl system where an electron‐transfer substitution reaction results in C‐alkylation (cf.
ChemInform Abstract: Synthesis of Bridgehead Halides by Barton Halodecarboxylation.
Authors: DELLA E. W. , TSANAKTSIDIS J. 
Published: May 2016

AbstractThe products of the title reaction (5 out of the 14 transformations studied are given in the scheme) are isolated in generally good yield if a solvent/halogenating agent of appropriate volatility is employed.