bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Bicyclic Pyrazolidinone Antibacterial Agents. Synthesis of Side Chain Analogues of Carbapenems PS‐5 and Thienamycin.
Authors: JUNGHEIM L. N. 
Published: May 2016

AbstractThe key precursors for the preparation of the target compounds are the pyrazolidinium methylides (VIII), prepared by cyclization of the acrylates (I) or (VI) with hydrazine (II).
ChemInform Abstract: Displacement with Nitrogen Nucleophiles at C‐3′ of 7‐Aminocephalosporanic Acid and Derivatives Promoted by Trialkylsilyl Trifluoromethanesulfonates.
Authors: ACTON D. G. , ROGERS K. J. , POYSER J. P. 
Published: May 2016

AbstractThe acetate (I) reacts with N‐ethylbenzaldimine (II) in the presence of trimethylsilyl triflate to give the amine (III).
ChemInform Abstract: Synthesis of Basic Substituted Pyridines: A New Class of Antiasthmatic‐Antiallergic Agents.
Authors: ANAGNOSTOPULOS H. , BARTLETT R. R. , ELBEN U. , STOLL P. 
Published: May 2016

AbstractTwenty title compounds of type (IV)‐(VI) are prepared by the methodology shown in the scheme; they all display various pharmacological properties.
ChemInform Abstract: Non‐Basic Histamine H1‐Antagonists. Part 1. Synthesis and Biological Evaluation of Some Substituted 2‐(2‐Pyridylaminoalkylamino)pyrimidones and Related Compounds.
Authors: IFE R. J. , CATCHPOLE K. W. , DURANT G. J. , GANELLIN C. R. , HARVEY C. A. , MEESON M. L. , OWEN D. A. A. , PARSONS M. E. , SLINGSBY B. P. , THEOBALD C. J. 
Published: May 2016

AbstractBesides the most active title compound (IV), 25 further derivatives with a modified pyridylaminoalkylamino moiety as in (V) are prepared by similar procedures.
ChemInform Abstract: Vapor Phase Deposition of Palladium for Electroless Copper Plating.
Authors: THOMAS R. R. , PARK J. M. 
Published: May 2016

AbstractAllylcyclopentadienylpalladium, (III), exhibits unusual volatility at room temp. and its photochemical decomposition in the gas phase results in the deposition of a film consisting of a homogeneous mixture of Pd particles in an organic polymer matrix.
ChemInform Abstract: Improved Dielectric Properties for Anodic Aluminum Oxide Films by Soft/Hard Two‐Step Electrolytic Anodization.
Authors: DICKEY J. R. , DAVIDSON J. L. , TZENG Y. 
Published: May 2016

AbstractIt is demonstrated that the developed two‐step anodization process (soft/hard process) can be successfully used for the fabrication of high quality dielectrics.
ChemInform Abstract: Electrical Resistivity and Magnetic Ordering of Gadolinium and Terbium Bromide Deuterides, LnBrDx (2/3 < x ≤ 1)
Authors: COCKCROFT J. K. , BAUHOFER W. , MATTAUSCH HJ. , SIMON A. 
Published: May 2016

Abstractare studied as a function of the D content.
ChemInform Abstract: Sodium/V6O13 Polymer Electrolyte Cells.
Authors: MUNSHI M. Z. A. , GILMOUR A. , SMYRL W. H. , OWENS B. B. 
Published: May 2016

AbstractThe electrochemical behavior of an all solid state cell utilizing a Na anode, a polyethylene oxide (PEO) based electrolyte (NaCF3SO3/PEO) and a V6O13 insertion cathode is studied.
ChemInform Abstract: Influence of Oxygen Impurity on the Hydrogenation Properties of LaNi5, LaNi4.7Al0.3 and MmNi4.5Al0.5 During Long‐Term Pressure‐Induced Hydriding‐Dehydriding Cycling
Authors: HAN J. I. , LEE J.‐Y. 
Published: May 2016

Abstract(Mm: mischmetal).
ChemInform Abstract: Metal Ion Binding by Amino Acids. ‐ The Crystal Structure of Racemic Magnesium Bis(hydrogenaspartate) Tetrahydrate Mg(L‐AspH)(D‐AspH)·4 H2O.
Authors: SCHMIDBAUR H. , BACH I. , WILKINSON D. L. , MUELLER G. + 
Published: May 2016

AbstractThe title compound (I) is prepared from equiv. quantities of racemic aspartic acid and Mg(OH)2 in water and crystallizes in P21/c with Z=2.
ChemInform Abstract: Electroorganic Synthesis. Part 40. Oxidative Cyclization of 3‐Anilinocyclohex‐2‐enones to Tetrahydrocarbazoles.
Authors: SCHAEFER H. J. + , EILENBERG W. 
Published: May 2016

AbstractThe dihydrocarbazolones (IV) and (IX) are prepared from the enaminones (I) and (VII) by electrochemical oxidation and cyclization or by oxidative cyclization.
ChemInform Abstract: Substitution Reactions of Cyclic 2‐Benzenesulfonyl Ethers with Silyl Enol Ethers Promoted by Aluminum Trichloride.
Authors: BROWN D. S. , LEY S. V. , BRUNO M. 
Published: May 2016

AbstractThe sulfones (I), (IV), and (VII) react with the silyl enol ethers (II) and (VIII) or the trimethylsilanes (XI) to give the C‐alkylation products as outlined in the reaction scheme.
ChemInform Abstract: Michael Additions with an Enaminoester: Reaction of Phenyl 4‐Chromone‐3‐sulfonate with Methyl 3‐Amino‐2‐pentenoate.
Authors: LOEWE W. + , KRADEPOHL A. 
Published: May 2016

AbstractThe products (III)‐(V) of the title reaction can be separated by TLC (yield of the mixture given in mg).
ChemInform Abstract: α‐Amidoalkylation of CH‐Acids by Means of N‐(1,2,2,2‐Tetrachloroethyl) Amides.
Authors: IVANOV C. , DOBREV A. , NECHEV L. , NIKIFOROV T. 
Published: May 2016

AbstractThe N‐tetrachloroethyl carboxamides (I) are coupled with the sodium salts (II) of ethyl acetoacetate or diethyl malonate, yielding the α‐amidoalkyl carboxylates (III).
ChemInform Abstract: Bis(trifluoroacetylacetonato)cobalt(II)‐Catalyzed Oxidation‐Reduction Hydration of Olefins. Selective Formation of Alcohols from Olefins.
Authors: INOKI S. , KATO K. , TAKAI T. , ISAYAMA S. , YAMADA T. , MUKAIYAMA T. 
Published: May 2016

AbstractThe olefinic compounds (I) are hydrated with molecular oxygen/2‐propanol in the presence of bis(trifluoroacetylacetonato)cobalt(II) to produce the alcohols (II).
ChemInform Abstract: The Mechanism of Formation of Grignard Reagents: Trapping of Free Alkyl Radical Intermediates by Reaction with Tetramethylpiperidine‐N‐oxyl.
Authors: ROOT K. S. , HILL C. L. , LAWRENCE L. M. , WHITESIDES G. M. 
Published: May 2016

AbstractIn the presence of the free radical scavenger (II), Mg, and tert.‐amyl alcohol the sum of the yields of (III) and (IV) accounts for > 90%, the product ratio depending on the initial concentration of (II).
ChemInform Abstract: Stereospecific Preparation of trans‐Glycidic Esters.
Authors: POLNIASZEK R. P. , BELMONT S. E. 
Published: May 2016

AbstractThe benzaldehydes (I) are coupled with S‐tert‐butyl bromothioloacetate (II) in the presence of dicyclopentadienylboron triflate and diisopropylethylamine to form the anti‐α‐bromo‐β‐hydroxythiocarboxylates (III).
ChemInform Abstract: The Behaviour of 4‐Benzoyl‐2‐azetidinones with Bases. Regioselectivity in Their Alkylation Reactions.
Authors: ALCAIDE B. , DOMINGUEZ G. , MARTIN‐DOMENECH A. , MARTIN I. , CATIVIELA C. , MAYORAL J. A. , PLUMET J. 
Published: May 2016

AbstractAlkylation of the β‐lactam (I) with ethyl iodide (II) gives the ethyl‐β‐lactam (III).
ChemInform Abstract: A New Synthetic Route to the Key Precursor of 1β‐Methylcarbapenem Antibiotics from Methyl (S)‐3‐Hydroxy‐2‐methylpropanoate.
Authors: SHIRAI F. , NAKAI T. 
Published: May 2016

AbstractThe key step in the synthesis of the carbapenem precursor (VII) is the selective aldol reaction of the silylketene acetal (I) with the benzyloxyisobutyraldehyde (II), yielding almost exclusively the anti‐diastereomer of (III).
ChemInform Abstract: Monofunctionalization Study of Furan‐2,5‐dicarboxaldehyde. Conformational Analysis and Model Reactions.
Authors: HERNANDEZ‐FUENTES I. , ABRADELO C. , DOMINGUEZ C. , CSAKY A. G. , PLUMET J. , CATIVIELA C. , MAYORAL J. A. , GASET A. , RIGAL L. 
Published: May 2016

AbstractFuran‐2,5‐dicarbaldehyde (I) undergoes base‐catalyzed coupling with the (het)aryl methyl ketones (II) to give a mixture of the keto alcohols (III) and the enones (IV).
ChemInform Abstract: Pyrrolidine Derivatives: An Efficient Synthesis of 3‐Substituted (2S,5S)‐Pyrrolidine‐2,5‐dicarboxylic Acids.
Authors: HONMA T. , TADA Y. , ADACHI I. , IGARASHI K. 
Published: May 2016

AbstractStarting from L‐aspartic acid via L‐(I) the pyrrolidone dicarboxylate (Va) is prepared in high stereoselectivity by two routes.
ChemInform Abstract: Synthesis of the Enantiomeric Polyether Fragment of Tetronomycin.
Authors: HORI K. , NOMURA K. , YOSHII E. 
Published: May 2016

AbstractThe phenyl sulfone (IV), prepared from L‐rhamnal diacetate (I), is coupled with the tetrahydropyrancarboxaldehyde (V) to give the alcohol (VI).
ChemInform Abstract: Synthesis of 5‐Azaindoles by Substitution‐Rearrangement of 7‐Azaindoles Upon Treatment with Certain Primary Amines.
Authors: GIRGIS N. S. , LARSON S. B. , ROBINS R. K. , COTTAM H. B. 
Published: May 2016

AbstractThe 7‐azaindole (I) undergoes a nucleophilic substitution‐rearrangement upon treatment with various prim. amines (II) at elevated temp. to yield the substituted 5‐azaindoles (III).
ChemInform Abstract: A Novel Photo‐Induced Substitution of Alkyl 2‐Cyano‐3‐quinolinecarboxylates.
Authors: ONO I. , FUJIKI Y. , FUJINAMI N. , HOSHI T. 
Published: May 2016

AbstractThe cyanoquinolinecarboxylates (I) are irradiated in the primary alcohols (II) or (V) to perform transesterification, followed by intramolecular substitution of the cyano group, yielding the fused lactones (III) or (VI) as the main products.
ChemInform Abstract: Formation of Heterocyclic Hazardous Compounds by Thermal Degradation of Organic Compounds.
Authors: BIENIEK D. , BAHADIR M. , KORTE F. 
Published: May 2016

Abstract2,4,6‐Tribromophenol undergoes cyclization reaction upon thermolysis at 800°C, producing tetrabromodibenzodioxins, the structures of which are not defined.
ChemInform Abstract: 1,3‐Dipolar Cycloaddition of Diazomethane to Azolopyridazines. The Synthesis of Isomeric 7‐Methyl‐7H‐ and 8‐Methyl‐8H‐pyrazolo(4,3‐d)azolopyridazines.
Authors: MERSLAVIC M. , PETRIC A. , ROZMAN D. , STANOVNIK B. , TISLER M. 
Published: May 2016

AbstractThe products (III) and (IV) of a 1,3‐dipolar cycloaddition of the components (I) and (II) react with corresponding nucleophiles (V) to give the title compounds (VI) or (VII).
ChemInform Abstract: Diazapolycyclic Compounds. Part 28. Reaction of Acetylated Terpenoids with Diazaquinones.
Authors: GOMEZ CONTRERAS F. , LORA‐TAMAYO M. , SANZ A. 
Published: May 2016

AbstractThe enol acetate (III) of carvone (I) undergoes cycloaddition reaction with diazaquinones, prepared from the cyclic hydrazides (IV) by oxidation, to give the fused pyridazinediones (V).
ChemInform Abstract: Benzimidazole Condensed Ring Systems. Part 4. New Approaches to the Synthesis of Substituted Pyrimido(1,6‐a)benzimidazole‐1,3(2H,5H)‐diones.
Authors: BADAWEY E.‐S. A. M. , RIDA S. M. , SOLIMAN F. S. G. , KAPPE T. 
Published: May 2016

AbstractThe novel title compounds (III) are prepared by condensation of the benzimidazoles (I) with ethoxycarbonyl isocyanate (II).
ChemInform Abstract: An Unexpected Aminolysis in the Synthesis of 5‐Substituted 3‐(1H‐Tetrazol‐5‐yl)pyrazolo(1,5‐a)quinazolines.
Authors: PEET N. P. 
Published: May 2016

AbstractThe pyrazolo(1,5‐a)quinazolines (V) are prepared as given in the scheme.
ChemInform Abstract: Heterocyclic Photorearrangements‐Photoinduced Rearrangements of Some 3‐Aroylamino‐5‐methyl‐1,2,4‐oxadiazoles.
Authors: BUSCEMI S. , VIVONA N. 
Published: May 2016

AbstractPhotolysis of the 5‐benzamido‐1,2,4‐oxadiazoles (I) leads to the formation of the quinazolinones (II).
ChemInform Abstract: 6‐Aza‐5,8,10‐trideaza Analogues of Tetrahydrofolic Acid and Tetrahydroaminopterin: Synthesis and Biological Studies. Part 38.
Authors: ROSOWSKY A. , BADER H. , MORAN R. G. , FREISHEIM J. H. 
Published: May 2016

AbstractStarting from the pyrido(4,3‐d)pyrimidinone (I) the derivatives (V) and (VIII) are prepared via their key intermediates (III) and (VII), respectively.
ChemInform Abstract: Cyclization Reactions of 3‐Hydrazino(1,2,4)triazino(5,6‐b)indole.
Authors: ABDEL‐LATIF F. F. , SHAKER R. M. , MAHGOUB S. A. , BADR M. Z. A. 
Published: May 2016

AbstractThe title compound (Ia) is converted to the azide (Ib) as well as to various heterocycles such as (III), (IV), (VIII), (XI), (XII), (XV) and (XVII) by the routes shown in the scheme.
ChemInform Abstract: Synthesis of 1‐Hydroxy‐7‐azatricyclo(6.3.1.02,7)dodecan‐9‐ones: Potential Intermediates for the Total Synthesis of Securinines.
Authors: COTE R. , BOUCHARD P. , COUTURE Y. , FURSTOSS R. , WAEGELL B. , LESSARD J. 
Published: May 2016

Abstractp‐Methoxyphenol (I) is converted into the cyclic acetal carbamate (II) which eliminates methanol to give the enol ethers (III).
ChemInform Abstract: Syntheses of 3‐Cyano‐2H‐thiin S‐Imines and Ylides and Their Base‐Promoted Rearrangement.
Authors: MOTOKI S. , TAKAHASHI N. , EGUCHI K. , SAITO T. 
Published: May 2016

AbstractThe 2H‐thiins (I) react with chloramine T (II) to give the sulfilimines (III) which are rearranged and degraded in the presence of DBU, forming the fused 3‐cyanopyridines (IV).
ChemInform Abstract: Synthesis of Tetraorganosilanes Containing a Benzo(b)thiophene Fragment.
Authors: POLOSIN V. M. , ASTAKHOV A. A. , IVASHCHENKO A. V. , RYASHENTSEVA M. A. , BELANOVA E. P. , SHASHKOV A. S. , MINACHEV KH. M. 
Published: May 2016

AbstractBenzo(b)thiophene (I) is lithiated and subsequently coupled with the chlorosilanes (II) or (VI) to give the tetraorganosilanes (III) or (VII).
ChemInform Abstract: Silicon Compounds with Strong Intramolecular Steric Interactions. Part 36. A Bicyclic Disilane from the Reaction of 1,2‐Dichlorotetramesityldisilane with Lithium tert.‐Butylamide.
Authors: WEIDENBRUCH M. , PAN Y. , PETERS K. , VON SCHNERING H. G. 
Published: May 2016

AbstractTreatment of the disilane (I) with an excess Li tert.‐butylamide (II) gives the 4b,9b‐disilaindeno(2.1‐a)indene derivative (III) whose 1H and 13C NMR spectra in solution show a hindered rotation about the Si‐C(mesityl) bonds even at high temperatures.
ChemInform Abstract: Strained Ring Compounds of Silicon and Germanium.
Authors: WEIDENBRUCH M. , SCHAEFER A. + , GRIMM F.‐T. , THOM K.‐L. 
Published: May 2016

AbstractThe di(tert‐butyl)silicon(germanium) diiodides (I) are treated with lithium naphthalenide to give the three‐membered rings (II).
ChemInform Abstract: Di‐ and Trimethylene‐Bridged Diphosphorus(III) Compounds: Synthesis and Reaction with Hexafluoroacetone.
Authors: WEFERLING N. , SCHMUTZLER R. 
Published: May 2016

AbstractThe methylene‐bridged diphosphorus(III) compounds (V), (IX), and (XII) are synthesized in a sequence of reactions as shown in the scheme.
ChemInform Abstract: Synthesis of Heterocycles with Phosphorus‐Phosphorus Bond: Reactions of Phosphano‐Substituted Cyano(triphenylphosphoranylidene)methanes with Dichloroorganylphosphines.
Authors: GRUETZMACHER H. + , PRITZKOW H. 
Published: May 2016

AbstractThe reaction of the phosphinyl‐substituted cyano(triphenylphosphoranylidene)methanes (III) and (V), synthesized as shown, with dichloroorganylphosphines such as (II) and (VII) in the presence of NaBH4 or AlCl3 leads to the new heterocycles of the type (VI) and (VIII) in high yields.
ChemInform Abstract: Reactions of Aminophosphazenes (P‐NH2) with and without Rearrangement.
Authors: FINCHAM J. K. , SHAW R. A. 
Published: May 2016

AbstractReaction of the 1,1‐diaminotetrachlorophosphazene (I) with the alkoxides (II) in the corresponding alcohols gives the rearranged products (III), while in pyridine, the unrearranged diaminotetraalkoxy derivatives (IV) are formed.
ChemInform Abstract: Structure and Reactivity of 2‐Hydroxyiminobenzyl‐2‐oxo‐4,4,5,5‐tetramethyl(1,3,2)dioxaphospholanes.
Authors: BREUER E. , KARAMAN R. , GIBSON D. , GOLDBLUM A. 
Published: May 2016

AbstractThe benzoylphospholane (I) reacts with hydroxylamine (II) to produce the E‐oxime (III) and benzonitrile (VI).
ChemInform Abstract: Hydrotelluration of Acetylenes: Synthesis of Vinylic Tellurides, Divinyl Tellurides, and 1‐(Organyltelluro)‐1,3‐butadienes.
Authors: BARROS S. M. , DABDOUB M. J. , DABDOUB V. M. B. , COMASSETO J. V. 
Published: May 2016

AbstractOrganyltellurols generated in situ by NaBH4 reduction of diorganyl ditellurides react with acetylenes in refluxing ethanol to give vinylic tellurides of Z configuration.
ChemInform Abstract: Synthesis and Characterization of Diallyl Telluride and Allyl Methyl Telluride.
Authors: HIGA K. T. , HARRIS D. C. 
Published: May 2016

AbstractThe title compounds (III) and (VII) are prepared as shown and characterized by 1H, 13C, and 125Te NMR, IR, and UV spectroscopy.
ChemInform Abstract: A Convenient Method of Synthesis of Dialkyl Tellurides and Dialkyl Ditellurides.
Authors: FERREIRA J. T. B. , DE OLIVEIRA A. R. M. , COMASSETO J. V. 
Published: May 2016

AbstractTellurium (I) is converted to the dialkyl tellurides (V) by treatment with sodium hydroxide (II) and two equivalents of thiourea dioxide in aqueous tetrahydrofuran, followed by reaction of the intermediate disodium telluride (III) with the alkyl halides (IV) in the presence of a phase‐transfer catalyst.
ChemInform Abstract: Synthesis of Bis(trifluoromethyl)phenylthallium and Bis(trifluoromethyl)thallium Acetate. Oxidative Trifluoromethylation with Bis(trifluoromethyl)thallium(III) Compounds.
Authors: NAIR H. K. , MORRISON J. A. 
Published: May 2016

AbstractThe possibility of utilizing the easily prepared title Tl compounds (III) and (V) in oxidative trifluoromethylation reactions is screened by employing several classic low‐valent metallic species as substrate.
ChemInform Abstract: Heterometallic Binuclear Complexes. Part 1. Reactive Zr(IV)‐M(0) Compounds (M: Cr, Mo, W) with Bridging Diphenylphosphinocyclopentadienide Ligands.
Authors: SCHENK W. A. , LABUDE C. 
Published: May 2016

AbstractThe binuclear complexes (III) are synthesized according to the scheme and characterized by elemental analysis, spectral data (IR, 31P NMR), and chemical reactions.
ChemInform Abstract: Thermal Decomposition of Organotin Sulfamates: A One‐Pot Synthesis of Vinyltributyltin Compounds.
Authors: RATIER M. , KHATMI D. , DUBOUDIN J. G. , MINH D. T. 
Published: May 2016

AbstractMethoxycarbonylsulfamoyl chloride (III), prepared from chlorosulfonyl isocyanate (I), is converted to the inner salt (V) which reacts with the α‐stannyl alcohols, generated from the ketones (VI) and tributylstannylmagnesium chloride (VII), to produce the intermediate stannyl sulfamates (VIII).
ChemInform Abstract: The Synthesis of Phosphino‐, Arsino‐, and Stibino‐Substituted Sulfur Diimide Heterocycles in Transition Metal Complexes.
Authors: HERBERHOLD M. , SCHAMEL K. , GIEREN A. , HUEBNER T. + 
Published: May 2016

AbstractCoupling of the phosphino complex (Ia) with the sulfur diimide dipotassium salt (II) forms the six‐membered ring (IIIa), while in the same reaction with the stibino complex (Ic), only the eight‐membered ring (IVc) is produced.
ChemInform Abstract: Addition of Organometallic Nucleophiles to Coordinated 1,3‐Dienes, Trimethylenemethane, and Cycloheptatrienyl: Heterobimetallic Carbonyl Molybdenum Rhenium Complexes with σ,π‐C4 and ‐C7 Hydrocarbon Bridges.
Authors: MUELLER H.‐J. + , NAGEL U. , STEIMANN M. , POLBORN K. , BECK W. 
Published: May 2016

AbstractAs demonstrated with the diene derivatives (I), the addition of organometallic nucleophiles to cyclopentadienyldicarbonyl molybdenum compounds of dienes, cyclopentadiene, cyclohexadiene and trimethylenemethane gives the heterobimetallic η1:η3‐hydrocarbon‐bridged complexes (III)‐(V).
ChemInform Abstract: A Metal Pentadienyl Prepared by Reacting a Metal Carbyne with an Enyne.
Authors: SIVAVEC T. M. , KATZ T. J. , CHIANG M. Y. , YANG G. X.‐Q. 
Published: May 2016

AbstractCombining the enyne (I) with the tungsten carbyne (II), a metal pentadienyl compound (III) is obtained which unlike essentially all isolable metal pentadienyl has a sickle shape, crystallizing in P1 with Z=2.
ChemInform Abstract: Methylthiovinyl as a New Ligand ‐ Deprotonation of Dicarbonyl(η5‐cyclopentadienyl)(η2‐methyl(methylthio)carbene)tungsten Tetrafluoroborate.
Authors: KREISSL F. R. , ULLRICH N. 
Published: May 2016

AbstractTriethylamine deprotonates the C‐methyl group in (I) affording the neutral, diamagnetic methylthiovinyl complex (II).
ChemInform Abstract: Stability Range of Heterometal Cubane‐Type Clusters MFe3S4: Assembly of Double‐Cubane Clusters with the ReFe3S4 Core.
Authors: CIURLI S. , CARNEY M. J. , HOLM R. H. , PAPAEFTHYMIOU G. C. 
Published: May 2016

AbstractThe stability range of the cubane‐type title clusters hitherto only is tested by those with M=V and is now extended with implications for the stabilities of as yet unrealized clusters.
ChemInform Abstract: Protonation of the 1,1‐Dithiolene Ligands in the (Cu8(L)6)4‐ Cubanes (L: (S2C=C(COOR)2)2‐) and Synthesis of the (Cu8(L)6‐n(H‐L)n)‐(4‐n) Clusters. Synthesis and Structural Characterization of the (Cu10(H‐L)6(L)2) Decanuclear Cluster.
Authors: COUCOUVANIS D. , SWENSON D. , BAENZIGER N. C. , PEDELTY R. , CAFFERY M. L. , KANODIA S. 
Published: May 2016

AbstractAddition of 1, 2, or 3 equiv. of acid to MeCN solutions of the cubane cluster complexes (I) results in formation of protonated complexes (II) which are isolated as crystalline tetraarylphosphonium or tetraalkylammonium salts.
ChemInform Abstract: Methyl Difluoroacetate Copper Reagent. Remarkable Solvent Effect on the 19F NMR Spectrum, Stability, and Reactivity.
Authors: KITAGAWA O. , TAGUCHI T. , KOBAYASHI Y. 
Published: May 2016

AbstractThe reagent (III) mentioned in the title is generated from the iododifluoroacetate (I) and copper (II) in various aprotic solvents and then treated with the bromides (IV) to form the substituted acetates (V).
ChemInform Abstract: Bridging Rather Than Chelation in the Substitution Chemistry of the Osmium(I) Complex (Os2(MeCO2)2(CO)6) with Potentially Chelating Phosphines and Arsines.
Authors: DEEMING A. J. , NUEL D. , RANDLE N. P. , WHITTAKER C. 
Published: May 2016

AbstractReaction of (I) with an excess of diarsine gives the disubstituted complex (IIIa), similarly the reactions with diphosphines leads to (IIIb) and (IIIc).
ChemInform Abstract: New Metallacyclic Compounds of Rhodium, Molybdenum, and Germanium Derived from Novel Heterodifunctional P‐N Ligands.
Authors: CAVELL R. G. , KATTI K. V. 
Published: May 2016

AbstractThe new ligands (III) are produced by oxidation of the phosphanes (I) with the azide (II).
ChemInform Abstract: Unusual Reactions of Steroidal and Non‐Steroidal 1,5‐Dioximes. Stereochemistry and Mechanism of Formation of N‐Hydroxypiperidine Analogues.
Authors: PRADHAN S. K. , AKAMANCHI K. G. , DIVAKARAN P. P. , PRADHAN P. M. 
Published: May 2016

AbstractReduction of 4,5‐secocholestane‐3,5‐dione dioxime (I) with sodium borohydride results in cyclization to yield the N‐hydroxymethylazacholestanes (II) and (III).
ChemInform Abstract: Synthesis, Structure, and Reactions of Secosteroids Containing a Medium‐Sized Ring. Part 27. New Types of Steroidal Isoxazolidines.
Authors: MIHAILOVIC M. LJ. , LORENC L. , RAJKOVIC M. , JURANIC I. , MILOVANOVIC A. 
Published: May 2016

AbstractThe secosteroids (I) and (VI) undergo cycloaddition reaction with N‐methylhydroxylamine hydrochloride (II), forming the isoxazolidines (III), (IV), and (VII).
ChemInform Abstract: Synthesis and Structural Characteristics of Hydroxyethylglycosylamines.
Authors: LAPENKO V. L. , SIROTKINA G. G. , SUNTSOVA N. S. , VOISHCHEVA O. V. , SLIVKIN A. I. 
Published: May 2016

AbstractD‐Glucose (I) reacts with hydroxyethylamine (II) to give the glucosamine (III).
ChemInform Abstract: Studies on Nucleosides. Part 20. Synthesis and Antileishmanial Activity of 4,6‐Substituted Pyrazolo(3,4‐d)pyrimidine Nucleosides.
Authors: HASAN A. , TRIPATHI R. P. , PRATAP R. , BHAKUNI D. S. , PAL R. , MISHRA A. , GURU P. Y. , KATIYAR J. C. 
Published: May 2016

AbstractA series of title nucleosides are prepared following known procedures and tested for their antileishmanial activity.
ChemInform Abstract: Microbial Synthesis of Optically Pure α‐Methoxy‐α‐trifluoromethyl‐α‐phenylacetic Acid.
Authors: OHTA H. , MIYAMAE Y. , KIMURA Y. 
Published: May 2016

AbstractThe key step in the synthesis of the chiral acid (R)‐(VIII) mentioned in the title is the enantioselective hydrolysis of the racemic nitrile (±)‐(IV) using Bacillus coagulans.
ChemInform Abstract: The LPCVD of Silicon Oxide Films Below 400 °C from Liquid Sources.
Authors: HOCHBERG A. K. , O'MEARA D. L. 
Published: May 2016

AbstractThe applicability of various organosilane compounds such as alkyl‐ and alkoxysilanes, ethoxy‐ and acetoxysilanes, and cyclic siloxanes as SiO2 sources for the preparation of high quality deposits below 400 °C is studied.