bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Barbier‐Type Allylation of Acetals with Allyl Bromide in a Pb/Al Bimetal Redox System.
Authors: TANAKA H. , YAMASHITA S. , IKEMOTO Y. , TORII S. 
Published: May 2016

AbstractThe acetals (I) react with allyl bromide (II) in the presence of aluminum tribromide, aluminum metal, and catalytic amounts of lead dibromide to yield the homoallylic methyl ether (III).
ChemInform Abstract: α‐Silyl Trimethylsilyl Esters from Aliphatic Carboxylic Acid Dianions.
Authors: BELLASSOUED M. , DUBOIS J. E. , BERTOUNESQUE E. 
Published: May 2016

AbstractIn contrast to results when the reaction of dilithiated acids (I) with Me3SiCl (II) is conducted only at ‐78 °C (literature), the products (III) and (IV) formed after 24 h equilibration at 50 °C are the result of thermodynamic control promoting C‐silylation.
ChemInform Abstract: A General Method for the Synthesis of Both Enantiomers of Optically Pure β‐Hydroxy Esters from (S)‐(p‐Chlorophenylsulfinyl)acetone Easily Obtainable by Kinetic Resolution with Bakers′ Yeast.
Authors: FUJISAWA T. , FUJIMURA A. , SATO T. 
Published: May 2016

AbstractKinetic resolution of the racemic sulfoxide (±)‐(I) using bakers' yeast yields the enantiomer (S)‐(I), which undergoes alkylation and subsequent diastereoselective reduction to give either one of the optically pure diastereomeric hydroxysulfoxides (IV) or (VIII); the diastereoselectivity of this reduction is controlled via the complexation with ZnCl2.
ChemInform Abstract: Fulvenes with Inverse Ring Polarization. Charge Separation on Molecular Basis: Chemoselectivity, Regio‐, and Stereoselectivity of C‐C Bond Formation as Probes for Electron‐Transfer Processes.
Authors: AURBACH I. , PONTI P. P. , SALBECK E. , SCHMUCK H. , DAUB J. 
Published: May 2016

AbstractThe Li enolate (II) (formed in situ from the amide (I)) containing the cross‐conjugated heptafulvene structural unit is studied with respect to SET (single‐electron transfer)type and polar mechanisms in reactions with methyl iodide or with carbonyl compounds such as (II), (VI), (VII), or (IX).
ChemInform Abstract: Diastereo‐ and Enantioselective Synthesis of Dihydro‐ and Tetrahydropyrimidines. A New Strategy for the Asymmetric Synthesis of β‐Amino Ketones and γ‐Amino Alcohols.
Authors: BARLUENGA J. , OLANO B. , FUSTERO S. , FOCES‐FOCES C. , CANO F. H. 
Published: May 2016

AbstractThe chiral tetrahydropyrimidines (V) are prepared by cyclocondensation of the iminoenamines (I) with the aldehydes (II) followed by reduction with sodium borohydride.
ChemInform Abstract: Acetylenic Chemistry. Part 10. Cycloisomerization of 3‐Acetyl‐3‐(prop‐2‐ynyl)indol‐2‐one to 3‐Acetyl‐2‐methyl‐2H‐furo(2,3‐b)indole.
Authors: REISCH J. , LABITZKE H. , BATHE A. 
Published: May 2016

AbstractThe propynylindolinone (I) reacts with PPA and water to form the propanone (II).
ChemInform Abstract: Flavonoids. Part 41. Stereospecific Synthesis of 2,3‐Dihydro‐c‐3‐Substituted‐t‐3‐methyl‐r‐2‐phenyl‐4H‐1‐benzopyran‐4‐ones.
Authors: PATONAY T. , PATONAY‐PELI E. , LITKEI G. , SZILAGYI L. , BATTA G. , DINYA Z. 
Published: May 2016

AbstractThe benzopyranone (I) is oxidized using the Algar‐Flynn‐Oyamada method, yielding the hydroxy ketone (II) which is treated with mesyl chloride (III) to produce a mixture of the mesylate (IV) and the sultone (V).
ChemInform Abstract: The Synthesis of 1‐((2‐Thiazolyl)methyl)quinolones. The Reactivity of the Methylene Bridge at Position‐1 and Its Involvement in the Formation of a Stable Carbon‐Nitrogen Ylid.
Authors: IZZO P. T. , LEE V. J. 
Published: May 2016

AbstractReaction of the quinolinone (I) with bromoacetonitrile (II) yields the N‐cyanomethyl derivative (III) which is converted to the thioamide (IV).
ChemInform Abstract: Pethidine Analogs with Restricted Conformation. Part 1. Synthesis of cis‐ and trans‐4‐Methyl‐10b‐carbethoxymethyl‐1,2,3,4,4a,5,6,10b‐octahydrobenzo(f)quinoline.
Authors: REIMANN E. , BRACHER F. 
Published: May 2016

AbstractThe keto ester (I) reacts with acrylonitrile (II) to give the cyanoethylated derivative (III) which is cyclized upon catalytic hydrogenation, yielding the octahydrobenzoquinolines (IV).
ChemInform Abstract: Selective Instability of Trifluoromethyl Linked to Carbon. A Prerequisite for New Heterocyclizations with Ethyl 4,4,4‐Trifluoroacetoacetate Arylhydrazones.
Authors: PILGRAM K. H. , SKILES R. D. 
Published: May 2016

AbstractTreatment of the arylhydrazone (I), derived from ethyl trifluoroacetoacetate, with NaH in aprotic solvents produces a mixture of the pyrazole (II) and the pyrazolopyridazinone (III).
ChemInform Abstract: Synthesis and Biological Activity of Amino‐Substituted‐pyrrolo(3,2‐d)pyrimidines.
Authors: MODNIKOVA G. A. , TITKOVA R. M. , GLUSHKOV R. G. , SOKOLOVA A. S. , SILIN V. A. , CHERNOV V. A. 
Published: May 2016

AbstractThe dichloropyrrolopyrimidine (V), prepared from the nitromethyluracil (I) via the enamine (III), is converted to the amino derivatives (VII) or (VIII).
ChemInform Abstract: Single‐Step Conversion of Aliphatic, Aromatic and Heteroaromatic Primary Amines into Piperazine‐2,6‐diones.
Authors: KRUSE C. G. , TROOST J. J. , COHEN‐FERNANDES P. , VAN DER LINDEN H. , VAN LOON J. D. 
Published: May 2016

AbstractTwenty‐five title compounds of type (V) are synthesized in a one‐pot procedure according to the conditions indicated (yield: 63‐98%).
ChemInform Abstract: Synthesis and Properties of 3‐Alkoxy‐3,4‐dihydro‐2H‐1,3‐benzothiazine‐2,4‐diones.
Authors: GEFFKEN D. 
Published: May 2016

AbstractReaction of 2‐mercaptobenzoic acid (I) with the O‐alkylhydroxylamines (II) in the presence of carbonyldiimidazole yields the dihydrobenzothiazinediones (III).
ChemInform Abstract: Synthesis, Reactions, and Biological Evaluation of Some 1,2,4‐Triazine Derivatives.
Authors: MANSOUR A. K. , EID M. M. , HASSAN R. A. , HAEMERS A. , PATTYN S. R. , VANDEN BERGHE D. A. , VAN HOOF L. 
Published: May 2016

AbstractHydrolysis of the azlactones (I) followed by treatment with the thiosemicarbazide (II) yields the thioxo‐1,2,4‐triazinones (III).
ChemInform Abstract: Syntheses of Apogalanthamine Analogs as α‐Adrenergic Blocking Agents. Part 9. Syntheses of Optically Active 8‐Hydroxy‐6‐methyl‐5,6,7,8‐tetrahydrodibenz(c,e)azocines.
Authors: KIHARA M. , OHNISHI K. , KOBAYASHI S. 
Published: May 2016

Abstracto‐Iodobenzaldehyde (I) is coupled with ethanolamine (II) to give the racemic amino alcohol (IV) via the intermediate monoadduct (III).
ChemInform Abstract: Synthesis and Structure Determination of Isomeric 7‐ and 8‐Chloro‐1,5‐benzodiazepine Derivatives.
Authors: PENNINI R. , CERRI A. , TAJANA A. , NARDI D. , GIORDANO F. 
Published: May 2016

AbstractCyclocondensation of the o‐phenylenediamine (I) with the dimercaptopropenyl phenyl ketone (II) produces a mixture of the regioisomeric benzodiazepines (III).
ChemInform Abstract: Synthesis and Molecular Structure of Tetrathia(34)(1,2,4,5)cyclophane.
Authors: ASOH T. , TANI K. , HIGUCHI H. , KANEDA T. , TANAKA T. , SAWADA M. , MISUMI S. 
Published: May 2016

AbstractCyclocondensation of the tetrabromide (I) with the tetrakis(isothiuronium) salt (II) using a high dilution technique leads to the formation of a 1:1 mixture of the tetrathiacyclophanes (III) and (IV).
ChemInform Abstract: Phosphonomethylation of Anesthesin and Radioprotective Activity of the Reaction Products.
Authors: KHAIRULLIN V. K. , VASYANINA M. A. , MUSIN R. Z. , PUDOVIK A. N. , VATULINA G. G. 
Published: May 2016

AbstractPhosphonomethylation of anesthesin (I) with paraformaldehyde (III) and the dialkyl phosphites (II) or triethyl phosphite (V) gives the ethoxycarbonylphenylaminomethylphosphonates (IV).
ChemInform Abstract: Synthesis, Properties and Structure of Hexaaquo‐tris(N,N‐dimethylformamide)lanthanoid Trifluoromethanesulfonates.
Authors: ARAUJO MELO D. M. , VICENTINI G. , ZINNER L. B. , DE SIMONE C. A. , CASTELLANO E. E. 
Published: May 2016

AbstractHydrated lanthanoid trifluoromethanesulfonates react with a small excess of DMF to give the title complexes (I) (no yields given).
ChemInform Abstract: Transition‐Metal Functionalized Phosphaarsenes (η5‐C5H4R)(CO)(PPh3)Fe‐As=P‐C6H2(tBu)3(2,4,6) (R: H, Me) and 1,3,2,4‐Diphosphadiarsetanes ((η5‐C5Me5)(CO)2Fe‐As‐P‐C6H2Me3(2,4,6))2.
Authors: WEBER L. , BUNGARDT D. , BOESE R. , BLAESER D. + 
Published: May 2016

AbstractThe title compounds (III) and (VI) are characterized by IR and 31P NMR spectroscopy, confirming the E configuration for (III).
ChemInform Abstract: New Cardenolide Glycosides from the Defence Glands of Chrysolinina Beetles (Coleoptera : Chrysomelidae).
Authors: VAN OYCKE S. , RANDOUX T. , BRAEKMAN J. C. , DALOZE D. , PASTEELS J. M. 
Published: May 2016

AbstractBesides the known cardenolide aglycones sarmentogenin and oleandrigenin 14 new cardiac glycosides such as (I) are isolated.
ChemInform Abstract: α‐Cyano‐β‐styrenyl Esters for Amide Bond Formation.
Authors: ROOSE B. , ANTEUNIS M. J. O. , TAVERNIER D. 
Published: May 2016

AbstractIn view of the interest in peptide syntheses the rate constants (10‐2·mol‐1·s‐1·L) for coupling of the styrenyl esters (IV) with aminoacid ester (V) are determined by 1H NMR.
ChemInform Abstract: Synthesis of Trypsin Inhibitor CMTI I from Squash Seeds (Cucurbita maxima).
Authors: KUPRYSZEWSKI G. , RAGNARSSON U. , ROLKA K. , WILUSZ T. , POLANOWSKI A. 
Published: May 2016

AbstractUsing the solid‐phase procedure, a 29‐peptide with the reported sequence (I) of the trypsin inhibitor CMTJ I is synthesized.
ChemInform Abstract: Effects of Temperature and Magnetic Fields on the Luminescence of Single Crystal (NH4)2TeCl6
Authors: MEIDENBAUER K. , GLIEMANN G. 
Published: May 2016

Abstractare studied in the range 1.9‐180 K at applied magnetic fields of 0‐6 T. The temp. dependence of the luminescence indicates the existence of a metastable excited state, energetically located ∼ 80 cm‐1 below a second excited state.
ChemInform Abstract: Photoelectrochemistry of Cadmium Sulfide. Part 2. Influence of Surface‐State Charging.
Authors: MEISSNER D. , LAUERMANN I. , MEMMING R. , KASTENING B. 
Published: May 2016

AbstractThe energy bands at the surface of clean CdS become unpinned upon illumination and are shifted in the anodic direction by several hundred mV.
ChemInform Abstract: The Effect of Palladium on Hydrogen Absorption and Mobility in AISI 4130 Steels.
Authors: FONDEUR F. , MOZHL T. A. , WILDE B. E. 
Published: May 2016

AbstractThe effect of the addition of 0, 0.05, 0.1, 0.5, and 1 wt.% Pd to AISI 4130 steel on the hydrogen absorption and mobility is studied in 1 N NaOH by cathodic polarization and hydrogen permeation techniques.
ChemInform Abstract: Comparison of the Acidities of WO3/Al2O3 and Ultrastable Faujasite Catalysts
Authors: SOLED S. L. , MCVICKER G. B. , MURRELL L. L. , SHERMAN L. G. , DISPENZIERE N. C. JUN. , HSU S. L. , WALDMAN D. 
Published: May 2016

Abstractis performed by temp.‐programmed desorption of NH3, high‐temp.
ChemInform Abstract: Electronic Structures of XMo12O40 Heteropolyanions (X: P, As, Si, and Ge) and Their Reduction Behavior.
Authors: EGUCHI K. , SEIYAMA T. , YAMAZOE N. , KATSUKI S. , TAKETA H. 
Published: May 2016

AbstractPolarographic results show that the relative reducibility of the title anions is in the order (AsMo12O40)3‐ > (PMo12O40)3‐ > (GeMo12O40)4‐ > (SiMo12O40)4‐.
ChemInform Abstract: Multinuclear Magnetic Resonance (31P, 77Se, 199Hg) and Electrochemical Studies of Nonlabile Mercury(II) Complexes with Group 15/Group 16 Donor Ligands.
Authors: BOND A. M. , COLTON R. , EBNER J. 
Published: May 2016

AbstractThe studies are carried out on Hg(II) perchlorate complexes of the bidentate ligands as well as the free ligands.
ChemInform Abstract: Organic Synthesis Using PTC. Part 5. Nucleophilic Aromatic Substitution Under Liquid‐Liquid and Solid‐Liquid Phase‐Transfer Conditions.
Authors: SINGH P. , ARORA G. 
Published: May 2016

AbstractTreatment of thiourea (I) with the α,ω‐dibromoalkanes (II) affords the bis‐thiouronium salts (III).
ChemInform Abstract: Substrate Specificity and Enantioselectivity of Penicillinacylase‐Catalyzed Hydrolysis of Phenacetyl Esters of Synthetically Useful Carbinols.
Authors: FUGANTI C. , GRASSELLI P. , SERVI S. , LAZZARINI A. , CASATI P. 
Published: May 2016

AbstractImmobilized penicillinacylase from E.coli catalyzes the hydrolysis of a set of O‐phenylacetate esters of prim. alcohols, e.g. (I), (III)‐(XI), using the conditions indicated in the scheme for the example (I) → (S)‐(II).
ChemInform Abstract: Synthesis and Reactivity of Binuclear Tropocoronand and Related Organocopper(I) Complexes. Catalytic Enantioselective Conjugate Addition of Grignard Reagents to 2‐Cyclohexen‐1‐one.
Authors: VILLACORTA G. M. , RAO CH. P. , LIPPARD S. J. 
Published: May 2016

AbstractThe conjugate addition of Grignard reagents (XIV) to 2‐cyclohexen‐1‐one (XIII) is promoted by a series of new catalysts (0,006‐0,04 mol fraction) prepared from Cu(I) species and either the tropocoronand salt (I) (such as (IV)) or the new chiral ligand (XII).
ChemInform Abstract: Alkylation of Pentaerythritol by Phase‐Transfer Catalysis. Part 2. Crucial Effect of the Aqueous Sodium Hydroxide Solution.
Authors: NOUGUIER R. , MCHICH M. 
Published: May 2016

AbstractThe reaction between pentaerythritol (I) and alkyl halides, e.g. heptyl bromide (II), conducted under phase‐transfer catalysis conditions, is known to yield a mixture of the trialkyl derivative (III) and the tetraalkyl derivative (IV).
ChemInform Abstract: Rhodium Catalyzed Reductive Esterification Reactions.
Authors: LIN I. J. B. , ZAHALKA H. A. , ALPER H. 
Published: May 2016

AbstractHydrogenation of the acrylic acids (I) in methanol (II) using rhodium(III) chloride as the catalyst produces the saturated methyl esters (III).
ChemInform Abstract: Remarkable Effects of Lithium Salt in Grignard Reaction.
Authors: KIM W.‐J. , KO K.‐Y. , PAIK S.‐U. , KIM H. 
Published: May 2016

AbstractThe normal Grignard reaction of aldehyde (I) with either MeMgBr (II) or MeMgI leads to the desired carbinol (III) only in less than 30% yield together with 10% recovered (I) and 50% lactone (IV).
ChemInform Abstract: Cyclopentane Synthesis via Free‐Radical‐Mediated Addition of Functionalized Alkenes to Substituted Vinylcyclopropanes.
Authors: FELDMAN K. S. , ROMANELLI A. L. , RUCKLE R. E. JUN. , MILLER R. F. 
Published: May 2016

AbstractA novel (3 atom + 2 atom) bond construction strategy for the synthesis of highly functionalized cyclopentane rings is presented.
ChemInform Abstract: Cyclopentenones form the Reaction of Alkynes with Cyclopropylcarbene‐Chromium Complexes.
Authors: HERNDON J. W. , TUMER S. U. , SCHNATTER W. F. K. 
Published: May 2016

AbstractThe title reaction of the alkynes (II), (V) with the complexes (I) provides the trans configurated cyclopentenones (III) or (VI) with little or no formation of the respective cis isomers.
ChemInform Abstract: Stereochemically Controlled Synthesis of Unsaturated 2,5‐Dialkylfurans.
Authors: NUNEZ M. T. , RODRIGUEZ M. L. , MARTIN V. S. 
Published: May 2016

AbstractThe siloxyepoxy benzoate (I) is desilylated to give the alcohol (II) which undergoes acid catalyzed rearrangement, forming enantioselectively the dihydrofuran (III).
ChemInform Abstract: Synthesis and Characterization of Alkyl‐, Halo‐ and Heterosubstituted Derivatives of the Potent Phototoxin α‐Terthienyl.
Authors: MACEACHERN A. , SOUCY C. , LEITCH L. C. , ARNASON J. T. , MORAND P. 
Published: May 2016

AbstractA series of derivatives of the known phototoxic title compound (I) including the compounds (III), (IV), (V), (X), (XI), (XII), (XIV), and (XV) are synthesized as outlined in the scheme.
ChemInform Abstract: Asymmetric Synthesis. Part 12. Stereocontrolled Electrophilic‐Nucleophilic α,α′‐Substitution of the Pyrrolidine Ring.
Authors: ARSENIYADIS S. , HUANG P. Q. , PIVETEAU D. , HUSSON H.‐P. 
Published: May 2016

AbstractLithiation of the chiral pyrrolidine synthon (VI) followed by alkylation proceeds at position 2 to give the 2‐alkyl derivative (VIII) as 1:1 mixtures of diastereomers.
ChemInform Abstract: Polyhydroxylated Pyrrolidines from Sugar Lactones: Synthesis of 1,4‐Dideoxy‐1,4‐imino‐D‐glucitol from D‐Galactonolactone and Syntheses of 1,4‐Dideoxy‐1,4‐imino‐D‐allitol, 1,4‐Dideoxy‐1,4‐imino‐D‐ribitol, and (2S,3R,4S)‐3,4‐Dihydroxyproline from D‐Gulonolactone.
Authors: FLEET G. W. J. , SON J. C. 
Published: May 2016

AbstractThe title compounds (VIII), (XII)‐(XIV) are synthesized as outlined in the scheme starting from D‐galactonolactone (I) or D‐gulonolactone (VIII).
ChemInform Abstract: Simple Synthesis of 3‐Alkyl‐1H‐indazoles Having Functional Groups at the ω‐Position.
Authors: SASAKURA K. , KAWASAKI A. , SUGASAWA T. 
Published: May 2016

AbstractThe 2‐(ω‐chloroalkanoyl)anilines (I) are diazotized and then cyclized in the presence of tin(II) chloride to form the chloroalkylindazoles (III).
ChemInform Abstract: Disilylated Compounds as Precursors of Heterocycles: Synthesis of Benzimidazoles, Triazoles, Furan, and Pyrrole.
Authors: RIGO B. , VALLIGNY D. , TAISNE S. , COUTURIER D. 
Published: May 2016

AbstractCarboxylic amide derivatives such as (I), (VII), or (XIII) are silylated with chlorotrimethylsilane (II) or hexamethyldisilazane (VI), yielding intermediates which undergo desilylative cyclization to form heterocycles, e.g. the triazolone (V), the pyrrolidinotriazole (VIII), or the benzimidazoles (XV) and (XVI).
ChemInform Abstract: Silyl‐Cupration of Allene. A New Route to Silylated Synthons.
Authors: CUADRADO P. , GONZALEZ A. M. , PULIDO F. J. , FLEMING I. 
Published: May 2016

AbstractStarting with allene (I), the 2‐iodo‐3‐silylpropene (IV) is prepared via the cuprate (III).
ChemInform Abstract: Medium‐Sized Silicon Rings. Part 2. N‐Hydroxyethyl‐Substituted‐1,3‐dioxa‐6‐aza‐2‐silacyclooctanes. Synthesis, Transformations, and Mass Spectra.
Authors: D'YAKOV V. M. , MAKAROV A. F. , KIR'YANOVA A. N. , CHERNYSHEV A. E. , BOCHKAREV V. N. 
Published: May 2016

AbstractReaction of the diethoxysilanes (I) with triethanolamine (II) gives the dioxaazasilacyclooctanes (III).
ChemInform Abstract: 1,2‐Alkanediol Bis(dihydrogenphosphates).
Authors: DHAWAN B. , REDMORE D. 
Published: May 2016

AbstractThe alkane‐1,2‐diols (I) are converted to the disodium salts and then coupled with di(tert‐butyl) phosphorochloridate (II), yielding the bisphosphates (III).
ChemInform Abstract: Unusual Direction of the Arbuzov Reaction of Dialkoxymethylphosphonites and Their Analogues.
Authors: LUTSENKO I. F. , PIRSHCHENKO A. A. , LIVANTSOV M. V. 
Published: May 2016

AbstractThe phosphonite (I) reacts with the alkyl iodides (II) to form the phosphinates (III) in an usual Arbuzov rearrangement reaction along with the phosphinates (IV) and (V).
ChemInform Abstract: Phosphorylated Acid Anilides as New Insecticides.
Authors: NADASY M. , VASS A. K. , SAGI K. 
Published: May 2016

AbstractThe anilines (I) react with formaldehyde (II) to give the triarylhexahydrotriazines (III) which are cleaved by the carboxylic acid chlorides (IV), yielding the N‐chloromethyl anilides (V).
ChemInform Abstract: Reactions of Arsinic and Arsonic Acids with H2S and H2Se: Crystal Structure of 3,5‐Diphenyl‐1,2,4‐triselena‐3,5‐diarsacyclopentane.
Authors: APPLEGATE C. A. , MEYERS E. A. , ZINGARO R. A. , MERIJANIAN A. 
Published: May 2016

AbstractThe reaction of arsinic acids such as (I) or of arsonic acids such as (IV) with hydrogen sulfide (II) leads mainly to the formation of the trithiadiarsacyclopentanes (III) or (V).
ChemInform Abstract: Circular Dichroism of Chromium(III) Hexadentate EDTA‐Type Complexes. Part 2. Ethylenediaminetetra‐3‐propionatochromate(III) Ion.
Authors: RADANOVIC D. J. , DJURAN M. I. , DJOROVIC M. M. , DOUGLAS B. E. 
Published: May 2016

AbstractThe hexadentate Cr(III) title complex ion is prepared, isolated as its Li salt (I), and resolved.
ChemInform Abstract: Synthesis and Characterization of Coordinately Unsaturated Phosphine Complexes of Divalent V, Cr, Mn, Fe, and Co. Crystal Structures of (CrCl2(dippe))2 and FeCl2(dippe).
Authors: HERMES A. R. , GIROLAMI G. S. 
Published: May 2016

AbstractThe dihalidodiphosphine‐metal(II) complexes (III), (V), (VIII) are prepared according to the scheme.
ChemInform Abstract: Lewis‐Base Adducts of Group 11 Metal(I) Compounds. Part 38. Conformational Isomerism in Mixed‐Ligand Complexes of 2,2′‐Bipyridine and Triphenylphosphine with Copper(I) Halides.
Authors: BARRON P. F. , ENGELHARDT L. M. , HEALY P. C. , KILDEA J. D. , WHITE A. H. 
Published: May 2016

AbstractThe Cu(I) compounds (I) are prepared from CuX, PPh3, and 2,2'‐bipyridine in acetonitrile at room temp. or in the case of (Ia) under reflux (no yields given).
ChemInform Abstract: Synthesis and Characterization of the Luminescent Dithiolate‐Bridged Dimer (n‐Bu4N)2(Au(i‐MNT))2 (i‐MNT: S2C2(CN)2‐ 2) and Its Structurally Characterized, Metal‐Metal Bonded Gold(II) Oxidation Product (Ph4As)2(Au(i‐MNT)Cl)2.
Authors: KHAN M. N. I. , FACKLER J. P. JUN. , KING C. , WANG J. C. , WANG S. 
Published: May 2016

AbstractThe parent compound (I) displays a strong visible luminescence at 77 K in MeCN, as do the complexes (III).
ChemInform Abstract: Diastereoselective Synthesis of the First 2,3,4‐Trisubstituted Platina(IV)cyclobutanes.
Authors: NEILSEN W. D. , LARSEN R. D. , JENNINGS P. W. 
Published: May 2016

AbstractThe diastereoselective preparation of the first two trisubstituted platina(IV)cyclobutanes (Va) and (Vb) occurs by treating the epimeric alcohol mixture (IIIa) + (IIIb), obtained as shown, with Zeise's dimer (IV).
ChemInform Abstract: Noninvasive Tagging of Proteins with an Inorganic Chromophore. Selectivity of Chloro(terpyridine)platinum(II) Toward Amino Acids, Peptides, and Cytochromes c.
Authors: BROTHERS H. M. II , KOSTIC N. M. 
Published: May 2016

AbstractThe title complex (I) exhibits unexpected selectivity toward amino acid side chains in cytochromes c from Candida krusei and bakers' yeast.
ChemInform Abstract: Characterization of Ni‐Exchanged Montmorillonites by X‐Ray Photoelectron Spectroscopy.
Authors: STOECKER M. + , JENS K.‐J. , RIIS T. , GREPSTAD J. K. 
Published: May 2016

AbstractXPS binding energies and Auger‐electron kinetic energies are determined for 11 Ni‐exchanged montmorillonites prepared using different exchange, drying, and calcination conditions and the results are discussed in terms of the bonding states of the elements and their relation to the montmorillonite structure.
ChemInform Abstract: In situ Moessbauer Effect Spectroscopy of a Model Iron Perovskite Electrocatalyst.
Authors: FIERRO C. , CARBONIO R. E. , SCHERSON D. , YEAGER E. B. 
Published: May 2016

AbstractIt is found that the fraction of Fe(IV) sites in SrFeO2.91 dispersed on high area carbon gradually and irreversibly decreases upon exposure to an alkaline solution (0.1 M KOH).
ChemInform Abstract: Electrolyte Solutions in Liquid Ammonia. Part 10. A Cyclic Voltammetric Examination of Electron Transfer Between Solvated Ruthenium(III) and Ruthenium(II) Cations, and Anodic Passivation of Platinum Electrodes.
Authors: GILL J. B. , HALL M. , TAYLOR N. 
Published: May 2016

AbstractSingle electron transfer between Ru(NH3)63+ and Ru(NH3)62+ at a Pt electrode in liquid NH3 closely follows Nernstian behavior during the first voltammetric cycle if the voltage sweep rate is low.
ChemInform Abstract: Modification of Oxide Films by Ion Implantation: TiO2‐Films Modified by Ti+ and O+ as Example.
Authors: SCHULTZE J. W. , ELFENTHAL L. , LEITNER K. , MEYER O. 
Published: May 2016

AbstractBesides the stoichiometric changes caused by the ion implantation, amorphization of the oxide film and homogenization are significant effects.
ChemInform Abstract: Low‐Temperature Synthesis of the Fluorite Modification of Lanthanoid(II) Chlorides.
Authors: LIU G. , EICK H. A. 
Published: May 2016

AbstractSmCl2, EuCl2, and YbCl2·THF are prepared at room temp. by solvolytic decomposition (THF) of mixed valence lanthanoid chloride phases (obtained by hydrogen reduction of the corresponding trichlorides).