bluuebunny/crossref_metadata_2025_split huggingface dataset:
Metallogels from Coordination Complexes, Organometallic, and Coordination Polymers
Authors: Dastidar Parthasarathi , Ganguly Sumi , Sarkar Koushik 
Published: July 2016

AbstractA supramolecular gel results from the immobilization of solvent molecules on a 3D network of gelator molecules stabilized by various supramolecular interactions that include hydrogen bonding, π–π stacking, van der Waals interactions, and halogen bonding. In a metallogel, a metal is a part of the gel network as a coordinated metal ion (in a discrete coordination complex), as a cross‐linking metal node with a multitopic ligand (in coordination polymer), and as metal nanoparticles adhered to the gel network. Although the field is relatively new, research into metallogels has experienced a considerable upsurge owing to its fundamental importance in supramolecular chemistry and various potential applications. This focus review aims to provide an insight into the development of designing metallogelators. Because of the limited scope, discussions are confined to examples pertaining to metallogelators derived from discrete coordination complexes, organometallic gelators, and coordination polymers. This review is expected to enlighten readers on the current development of designing metallogelators of the abovementioned class of molecules.
Impacts of early cardiac catheterization for children with congenital heart disease supported by extracorporeal membrane oxygenation
Authors: Kato Atsuko , Lo Rito Mauro , Lee Kyong‐Jin , Haller Christoph , Guerguerian Anne Marie , Sivarajan Venkatesan Ben , Honjo Osami 
Published: July 2016

BackgroundCardiac catheterization is often required for patients on extracorporeal membranous oxygenation (ECMO) support, though its efficacy remains unclear. This study aimed to assess the impact of catheterization on successful ECMO weaning.MethodsThis is a single‐center retrospective study from 2000 to 2014. Patients with congenital heart disease who underwent cardiac catheterization while on cardiac ECMO support were included. Logistic regression analysis and Kaplan–Meier survival analysis with log‐rank test were performed to determine predictors for successful weaning and patient outcome.ResultsForty‐nine catheterizations in 47 patients with the median age of 65 days (range: 1 day–12 years) and the median body weight of 4.2 kg (range: 1.9–32.7 kg) were included. Median duration between ECMO cannulation and catheterization was 1 day (range: 0–11 days). Thirty‐three patients (70%) succeeded in decannulation and 24 patients (51%) survived to hospital discharge. Absence of renal (P = 0.045) and respiratory complications (P = 0.031) were significant prognostic factors for successful weaning in multivariate analysis. Patients who received catheterization within 48 hr after ECMO cannulation demonstrated less respiratory complications (P = 0.006) and better survival at 30 days after ECMO initiation (P = 0.039) than those who underwent later catheterization. There was no mortality; however, nine major catheterization‐related complications (18%) were detected.ConclusionCatheterization for pediatric patients on ECMO support can be performed, although this group contained high risk of serious adverse events. The absence of ECMO complications is a predictor for successful weaning. An earlier catheterization appears to be associated with better short‐term survival in this cohort. © 2016 Wiley Periodicals, Inc.
Deposition of Gold Nanoparticles on Niobium Pentoxide with Different Crystal Structures for Room‐Temperature Carbon Monoxide Oxidation
Authors: Murayama Toru , Ueda Wataru , Haruta Masatake 
Published: July 2016

AbstractNanoparticulate gold catalysts (NPGCs) supported on niobium oxides (Nb2O5) were prepared by different deposition methods. Au nanoparticles (NPs) with a mean diameter of approximately 5 nm were deposited by conventional deposition methods, which include the deposition‐precipitation (DP) and deposition‐reduction (DR) methods, on layered‐type Nb2O5 that possesses a deformed orthorhombic structure. Moreover, Au NPs with a mean diameter of approximately 2.7 nm could be deposited by the sol immobilization method on several crystalline forms of Nb2O5 (deformed orthorhombic, pseudohexagonal, and orthorhombic). NPGCs deposited on deformed orthorhombic Nb2O5 had a higher catalytic activity for CO oxidation. The temperature for 50 % CO conversion was 11 °C for 1 wt % Au/Nb2O5 (deformed orthorhombic) prepared by the sol immobilization method, and the CO conversion was 91 % at 28 °C. As far as we know, this is the first report of highly active Au NPGCs (smaller than 3 nm in diameter) supported on Nb2O5. NPGCs supported on acidic metal oxides will expand the utilization of gold catalysts for new applications.
Ammonium Bicarbonate as Nutrient Substitute for Improving Biomass Productivity of Chlorella variabilis
Authors: Bhattacharya Sourish , Soundarya Ramya , Mishra Sandhya 
Published: July 2016

AbstractSodium bicarbonate was replaced with ammonium bicarbonate, recovered from effluent of the pigment industry, for cultivation of CSMCRI's Chlorella variabilis (ATCC PTA 12198) with enhanced biomass and lipid productivity. Compared to Zarrouk's medium, utilizing ammonium bicarbonate in the medium instead of sodium bicarbonate yielded better biomass and lipid productivity in a shorter production time of 9 d in a 5‐L flask. The modified medium containing ammonium bicarbonate also yielded a higher total content of reducing sugar, which can be used for bioethanol production or as carbon source for further mixotrophic growth of C. variabilis.
Interfacial Architectures Derived by Lithium Difluoro(bisoxalato) Phosphate for Lithium‐Rich Cathodes with Superior Cycling Stability and Rate Capability
Authors: Han Jung‐Gu , Park Inbok , Cha Jiho , Park Suhyeon , Park Sewon , Myeong Seungjun , Cho Woograe , Kim Sung‐Soo , Hong Sung You , Cho Jaephil , Choi Nam‐Soon 
Published: July 2016

AbstractLithium difluoro(bisoxalato)phosphate (LiDFBP) is introduced as a novel lithium‐salt‐type electrolyte additive for lithium‐rich cathodes in lithium‐ion batteries. The investigation reveals that LiDFBP is oxidized to form a uniform and electrochemically stable solid electrolyte interphase (SEI) on the lithium‐rich cathode. The LiDFBP‐derived SEI layer effectively suppresses severe electrolyte decomposition at high voltages and mitigates the voltage decay of the lithium‐rich cathodes caused by undesirable phase transformation to spinel‐like phases during cycling. Furthermore, the cell with electrolyte containing LiDFBP achieves substantially improved cycling performance and delivers a high discharge capacity of 116 mA h g−1 at a high C rate (20 C). The unique function of the LiDFBP additive on the surface chemistry of lithium‐rich cathodes is confirmed through X‐ray photoelectron spectroscopy, SEM, and TEM analyses.
Modular Construction of Fluoroarenes from a New Difluorinated Building Block by Cross‐Coupling/Electrocyclisation/Dehydrofluorination Reactions
Authors: Percy Jonathan M. , Emerson Helena , Fyfe James W. B. , Kennedy Alan R. , Maciuk Sergej , Orr David , Rathouská Lucie , Redmond Joanna M. , Wilson Peter G. 
Published: July 2016

AbstractPalladium‐catalysed coupling reactions based on a novel and easy‐to‐synthesise difluorinated organotrifluoroborate were used to assemble precursors to 6π‐electrocyclisations of three different types. Electrocyclisations took place at temperatures between 90 and 240 °C, depending on the central component of the π‐system; nonaromatic trienes were most reactive, but even systems that required the temporary dearomatisation of two arenyl subunits underwent electrocyclisation, albeit at elevated temperatures. Photochemical conditions were effective for these more demanding reactions. The package of methods delivered a structurally diverse set of fluorinated arenes, spanning a 20 kcal mol−1 range of reactivity, by a flexible route.
Tuning of Supramolecular Architectures of l‐Valine‐Containing Dicyanoplatinum(II) 2,2′‐Bipyridine Complexes by Metal–Metal, π–π Stacking, and Hydrogen‐Bonding Interactions
Authors: Fu Heidi Li‐Ki , Po Charlotte , He Hexiang , Leung Sammual Yu‐Lut , Wong Kam Sing , Yam Vivian Wing‐Wah 
Published: July 2016

AbstractA series of newly synthesized dicyanoplatinum(II) 2,2′‐bipyridine complexes exhibits self‐assembly properties in solution after the incorporation of the l‐valine amino units appended with various hydrophobic motifs. These l‐valine‐derived substituents were found to have critical control over the aggregation behaviors of the complexes in the solution state. On one hand, one of the complexes was found to exhibit interesting circularly polarized luminescence (CPL) signals at low temperature due to the formation of chiral spherical aggregates in the temperature‐dependent studies. On the other hand, systematic transformation from less uniform aggregates to well‐defined fibrous and rod‐like structures via Pt⋅⋅⋅Pt and π–π stacking interactions has also been observed in the mixed‐solvent studies. These changes were monitored by UV/Vis absorption, emission, circular dichroism (CD), and CPL spectroscopies, and morphologies were studied by electron microscopy.
Macroscopic Responsive Liquid Quantum Dots Constructed via Pillar[5]arene‐Based Host‐Guest Interactions
Authors: Ma Junkai , Shi Fangdan , Tian Demei , Li Haibing 
Published: July 2016

AbstractLiquid quantum dots (QDs) have been used as a fluorescent films sensor. Constructing a macroscopic, responsive, liquid QD system for lysine (Lys) is a challenging task. To achieve a selective macroscopic response towards Lys, herein we present a new strategy for integrating host–guest chemistry into a liquid QD system. Water‐soluble pillar[5]arene WP5 was designed and synthesized as a host. WP5 was introduced onto the surface of PEG1810‐modified QDs by host–guest interactions to obtain liquid WP5‐1810‐QDs. The interaction between WP5 and Lys is stronger than that between WP5 and PEG‐1810, causing WP5 to be released from the 1810‐QDs surface in the presence of Lys, resulting in macroscopic fluorescence quenching. This smart material shows promise in amino acid sensing and separation.
ChemInform Abstract: Aromatic‐Like Behavior of Germanium Nanocrystals.
Authors: Behzadi Hadi , khalilnia Zahra 
Published: July 2016

AbstractAromatic Ge18H12 and Ge19H12 nanocrystals composed of three parallel, planar hexagons with one additional Ge atom close to the cluster center in the latter are predicted by DFT calculations.
ChemInform Abstract: Rietveld Refinement, Electronic Structure and Ionic Conductivity of Sr4La6(SiO4)6F2 and Sr4La6(SiO4)6O Ceramics.
Authors: Boughzala Khaled , Debbichi Mourad , Njema Hela , Bouzouita Khaled 
Published: July 2016

AbstractThe title compounds are prepared by solid state reaction of SrCO3, La2O3, and SiO2 and SrF2 in the case of the fluoroapatite (1173 K for 12 h and 1723 K for 6 h).
ChemInform Abstract: Facile Hydrolysis Synthesis of Bi4O5Br2 Photocatalyst with Excellent Visible Light Photocatalytic Performance for the Degradation of Resorcinol.
Authors: Li Min , Cui Yujin , Jin Yongsheng , Li Hui 
Published: July 2016

AbstractBi4O5Br2 (I) is prepared by a one‐step hydrolysis route employing a 1:1 molar solution of Bi(NO3)3 and KBr in ethylene glycol to which aqueous NH3 is given (25 °C, 1 h).
ChemInform Abstract: A Novel Europium (III) Nitridoborate Eu3[B3N6]: Synthesis, Crystal Structure, Magnetic Properties, and Raman Spectra.
Authors: Aydemir Umut , Kokal Ilkin , Prots Yurii , Foerster Tobias , Sichelschmidt Joerg , Schappacher Falko M. , Poettgen Rainer , Ormeci Alim , Somer Mehmet 
Published: July 2016

AbstractThe title compound is prepared from a 1:1 molar mixture of Eu3(BN2)2 and Br2 (1073 K, 12 h) and characterized by powder and single crystal XRD, ESR, Raman and Moessbauer spectroscopy, and DFT quantum chemical calculations.
ChemInform Abstract: Synthesis, Structure, and Characterization of Two New Bismuth(III) Selenite/Tellurite Nitrates: [(Bi3O2)(SeO3)2](NO3) and [Bi(TeO3)](NO3).
Authors: Meng Chang‐Yu , Wei Ming‐Fang , Geng Lei , Hu Pei‐Qing , Yu Meng‐Xia , Cheng Wen‐Dan 
Published: July 2016

AbstractBoth compounds (III) and (V) crystallize in the monoclinic space group P21/c with Z = 4 (single crystal XRD).
ChemInform Abstract: Palladium‐Catalyzed Enantioselective Allylic Alkylation of Trifluoromethyl Group Substituted Racemic and Acyclic Unsymmetrical 1,3‐Disubstituted Allylic Esters with Malonate Anions.
Authors: Ikeda Kazunori , Futamura Takashi , Hanakawa Taisyun , Minakawa Maki , Kawatsura Motoi 
Published: July 2016

AbstractThis Pd‐catalyzed dynamic kinetic asymmetric allylic alkylation proceeds with high yields and good to excellent enantioselectivity.
ChemInform Abstract: Addition of Nucleophiles to Fluorinated Michael Acceptors.
Authors: Ramb Daniel C. , Lerchen Andreas , Kischkewitz Marvin , Beutel Bernd , Fustero Santos , Haufe Guenter 
Published: July 2016

AbstractThe Michael addition of different nucleophiles including malonates and nitromethane as carbon nucleophiles, thiols, primary and secondary amines as well as primary alcohols is achieved in the presence of K2CO3 or Et3N as the base.
ChemInform Abstract: Chiral Anion Directed Asymmetric Carbocation‐Catalyzed Diels—Alder Reactions.
Authors: Ni Shengjun , Ramesh Naidu Veluru , Franzen Johan 
Published: July 2016

AbstractThe combination of a tritylium ion salt and an axial chiral anion catalyzes the Diels—Alder reactions with up to 53% enantiomeric excess.
ChemInform Abstract: Oxa‐ and Azacycle Formation via Migrative Cyclization of Sulfonylalkynol and Sulfonylalkynamide with N‐Heterocyclic Carbene.
Authors: Wang Yinli , Oriez Raphael , Kuwano Satoru , Yamaoka Yousuke , Takasu Kiyosei , Yamada Ken‐ichi 
Published: July 2016

AbstractFuran, pyran, and pyrrole derivatives are obtained by cyclization of sulfonylalkynols and sulfonylalkynamides.
ChemInform Abstract: Photooxygenation of Furylalkylamines: Easy Access to Pyrrolizidine and Indolizidine Scaffolds.
Authors: Kalaitzakis Dimitris , Triantafyllakis Myron , Sofiadis Manolis , Noutsias Dimitris , Vassilikogiannakis Georgios 
Published: July 2016

AbstractEmploying green reagents and conditions, unprotected primary furylalkylamines are subjected to photooxygenation conditions which initiate a complex cascade reaction sequence.
ChemInform Abstract: Direct Oxidation of Aliphatic C—H Bonds in Amino‐Containing Molecules under Transition‐Metal‐Free Conditions.
Authors: Li Xin , Che Xing , Chen Gui‐Hua , Zhang Jun , Yan Jia‐Lei , Zhang Yun‐Fei , Zhang Li‐Sheng , Hsu Chao‐Ping , Gao Yi Qin , Shi Zhang‐Jie 
Published: July 2016

AbstractA wide variety of phthaloyl protected amines, amino acids, and dipeptides are oxidized to carbonyls with good regioselectivities using a simple, inexpensive and transition‐metal free oxidation system.
ChemInform Abstract: Enantioselective Iridium‐Catalyzed Hydrogenation of β,β‐Disubstituted Nitroalkenes.
Authors: Yu Yan‐Bo , Cheng Lei , Li Yi‐Pan , Fu Yue , Zhu Shou‐Fei , Zhou Qi‐Lin 
Published: July 2016

AbstractSaturated nitroalkanes are prepared by asymmetric hydrogenation of nitroalkenes using iridium complexes with a newly prepared chiral spiro aminophosphine ligand as catalyst.
ChemInform Abstract: A Metal‐Free Diverse Synthesis of Difluoromethylthioethers and Difluorobis(arylthio)methanes from RSX (X = SR, Cl, SO2Ph) and TMSCF2H.
Authors: Han Jia‐Bin , Qin Hua‐Li , Ye Su‐Hong , Zhu Lei , Zhang Cheng‐Pan 
Published: July 2016

AbstractSuccess and outcome of these reactions strongly depend on the molar ratio of the reactands and the nature of the base.
ChemInform Abstract: Copper‐Catalyzed Hydroamination of Terminal Allenes.
Authors: Blieck Remi , Bahri Janet , Taillefer Marc , Monnier Florian 
Published: July 2016

AbstractThe hydroamination of terminal aryl and alkyl substituted allenes using cyclic secondary amines or anilines affords (E)‐allylamines in often high yields.
ChemInform Abstract: Fe‐Promoted Chlorobenzylation of Terminal Alkynes Through Benzylic C(sp3)—H Bond Functionalization.
Authors: Shi Jiang‐Ling , Zhang Ji‐Cheng , Wang Bi‐Qin , Hu Ping , Zhao Ke‐Qing , Shi Zhang‐Jie 
Published: July 2016

AbstractThe title process provides alkenyl chlorides with complete regio‐ and high E‐selectivity.
ChemInform Abstract: Efficient and Environmentally Friendly Glaser Coupling of Terminal Alkynes Catalyzed by Multinuclear Copper Complexes under Base‐Free Conditions.
Authors: Zhang Ling‐Juan , Wang Yan‐Hong , Liu Jie , Xu Mei‐Chen , Zhang Xian‐Ming 
Published: July 2016

Abstract1,3‐Diynes are prepared by the title coupling using a dinuclear copper complex (COP) as catalyst in high yields.
ChemInform Abstract: A Step‐Wise Reduction of Nonracemic α‐Ketoamides to α‐Methine Amides under Mild Conditions.
Authors: Wang Bing , Wang Min , Jia Tao , Lou Yazhou , Liao Jian , Cao Peng 
Published: July 2016

AbstractA step‐wise reductive method that converts nonracemic γ‐chiral α‐ketoamides into amide derivatives is developed under mild conditions.
ChemInform Abstract: Preparation of Alkyl Alkynyl Sulfones and Cyclic Vinyl Sulfones from Alkynyl(aryl)iodonium Salts.
Authors: Rodriguez Arantxa , Moran Wesley J. 
Published: July 2016

AbstractThe reaction of alkynyl(aryl)iodonium salts with alkyl sulfinates proceeds via 1,2‐rearrangements or 1,5‐insertion to furnish acyclic or cyclic sulfones which are difficult to prepare by other methods.
ChemInform Abstract: Cyclopropenes in Metallacycle‐Mediated Cross‐Coupling with Alkynes: Convergent Synthesis of Highly Substituted Vinylcyclopropanes.
Authors: O'Rourke Natasha F. , Micalizio Glenn C. 
Published: July 2016

AbstractThe cross‐coupling reactions proceed with high diastereoselectivity and favor the formation of 1,2,3‐trisubstituted cyclopropanes.
ChemInform Abstract: Michael Addition of Malonic Esters to endo‐Tricyclo[5.2.1.02,6]deca‐4,8‐dien‐4‐bromo‐3‐one: A Novel Entry to Highly Functionalized cis—anti—cis Fused Triquinane Framework/Skeleton.
Authors: Dinesh Tarur Konikkaledom , Palani Namasivayam , Balasubramanian Sengottuvelan 
Published: July 2016

AbstractDepending on the conditions the reaction of substrate (I) with malonic esters (II) provides Michael adducts (III) or unexpected compounds (IV) as main or single product.
ChemInform Abstract: Synthesis of Redshifted Azobenzene Photoswitches by Late‐Stage Functionalization.
Authors: Konrad David B. , Frank James A. , Trauner Dirk 
Published: July 2016

AbstractSince tetra‐ortho‐chloro azabenzenes are important for the photoswitch from UV to VIS (cis‐trans isomerization), an efficient method for their preparation is required.
ChemInform Abstract: Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents.
Authors: Brown Michael , Kumar Ravi , Rehbein Julia , Wirth Thomas 
Published: July 2016

AbstractThis oxidative rearrangement of 1,1‐disubstituted alkenes provides simple access to enantioenriched α‐arylated ketones.
ChemInform Abstract: Palladium‐Catalyzed Aminocarbonylation of Aryl Halides with 2,4,6‐Trichloro‐1,3,5‐triazine/Formamide Mixed Reagent.
Authors: Iranpoor Nasser , Panahi Farhad , Roozbin Fatemeh , Erfan Soodabeh , Rahimi Sajjad 
Published: July 2016

AbstractThe reaction of N‐substituted or N,N‐disubstituted formamides with cyanuric chloride generates Vilsmeier iminium type intermediates which are applied as new amidating reagents in Pd‐catalyzed aminocarbonylations of aryl halides.
ChemInform Abstract: Triisopropyl Borate Mediated N‐Sulfinyl Imine Formation.
Authors: Visco Michael D. , Reeves Jonathan T. , Marsini Maurice A. , Volchkov Ivan , Busacca Carl A. , Mattson Anita E. , Senanayake Chris H. 
Published: July 2016

AbstractSulfinyl imines are prepared by condensation of aldehydes with sulfinamides in high yields.
ChemInform Abstract: Nickel‐Catalyzed Cross‐Coupling of Organolithium Reagents with (Hetero)Aryl Electrophiles.
Authors: Heijnen Dorus , Gualtierotti Jean‐Baptiste , Hornillos Valentin , Feringa Ben L. 
Published: July 2016

AbstractA nickel N‐heterocyclic carbene complex allows for the selective cross‐coupling of aromatic electrophiles with (hetero)aryllithium compounds, including those prepared via metal‐halogen exchange or direct metallation, whereas an electron‐rich nickel‐biphosphine complex smoothly converts alkyllithium species into the corresponding coupled products.
ChemInform Abstract: In situ Generation of ArCu from CuF2 Makes Coupling of Bulky Aryl Silanes Feasible and Highly Efficient.
Authors: delPozo Juan , Casares Juan A. , Espinet Pablo 
Published: July 2016

AbstractA bimetallic system of Pd/CuF2, catalytic in Pd and stoichiometric in Cu, is efficient and selective for the coupling of fairly hindered aryl silanes with aryl iodides of conventional size.
ChemInform Abstract: Metal Catalyst‐Free Substitution of Allylic and Propargylic Phosphates with Diarylmethyl Anions
Authors: Kawashima Hidehisa , Ogawa Narihito , Saeki Ryohei , Kobayashi Yuichi 
Published: July 2016

Abstractderived from diarylmethanes with BuLi or LDA
ChemInform Abstract: Manganese‐Catalyzed Sonogashira Coupling of Aryl Iodides.
Authors: Qi Xinxin , Jiang Li‐Bing , Wu Xiao‐Feng 
Published: July 2016

AbstractCatalyzed by in situ generated manganese nanoparticles the Sonogashira coupling affords a variety of diarylacetylenes in moderate to good yields.
ChemInform Abstract: General and Cost‐Effective Synthesis of 1‐Heteroaryl/Arylcycloalkylamines and Their Broad Applications.
Authors: Zhang Dehui , Zheng Hongchao , Wang Xiaodong 
Published: July 2016

AbstractThe new method to synthesize 1‐(hetero)arylsubstituted cycloalkylamines from readily available heteroarylacetate is reported.
ChemInform Abstract: Oxy‐Wittig Reactions of 1‐Naphthyl(aryl)methylphosphonates: A New Approach to Naphthylarylketones.
Authors: Zubair Khalid M. B. , Pallikonda Gangaram , Prasad Tulichala R. N. , Chakravarty Manab 
Published: July 2016

AbstractSynthetically unexposed and expensive naphthylarylketones are prepared from phosphonates (I) and (III) using an operationally simple procedure at room temperature.
ChemInform Abstract: Rh‐Catalyzed One‐Pot Sequential Asymmetric Hydrogenation of α‐Dehydroamino Ketones for the Synthesis of Chiral Cyclic trans‐β‐Amino Alcohols.
Authors: Hu Qiupeng , Chen Jianzhong , Zhang Zhenfeng , Liu Yangang , Zhang Wanbin 
Published: July 2016

AbstractThe desired trans‐alcohols are obtained with moderate diastereoselectivity and, in most cases, with excellent enantioselectivity.
ChemInform Abstract: Facile Synthesis of New 3,5‐Dispiro Substituted Piperidine Analogues via Microwave‐Assisted One Pot Multicomponent Reaction.
Authors: Chidurala Praveen , Jetti Venkateshwarlu , Meshram Jyotsna S. 
Published: July 2016

AbstractAn eco‐efficient microwave method for the synthesis of sulfur‐containing dispirosubstituted piperidines starting from thiobarbituric acid, formaldehyde, and a variety of aromatic amines is presented.
ChemInform Abstract: Four‐Component Reaction for Efficient Construction of Spiro[acenaphthylene‐1,2′‐quinoline] Skeleton
Authors: Zhu Dan , Sun Jing , Yan Chao‐Guo 
Published: July 2016

Abstractstarting from various anilines, dialkyl acetylenedicarboxylate, acenaphthenequinone, and cyclic 1,3‐dicarbonyl compounds
ChemInform Abstract: Cu‐Mediated C2‐Dehydrogenative Homocoupling of Indoles via C—H Activation Assisted by a Removable N‐Pyrimidyl Group.
Authors: Le Jun , Gao Yadong , Ding Yousong , Jiang Chao 
Published: July 2016

AbstractThe use of 2‐pyrimidinyl as directing group allows the highly regioselective homocoupling of indoles via C—H activation.
ChemInform Abstract: Microwave Energized Synthesis of 2‐Aroylindole Derivatives: Piperidine/DMF as an Effective Medium
Authors: Soora Haranath Jayaprakash , Balam Satheesh Krishna , Chereddy Syama Sundar , Sthanikam Siva Prasad , Sarva Santhisudha , Gundluru Mohan , Cirandur Suresh Reddy 
Published: July 2016

Abstractby reaction of aminoketones with phenacyl bromides
ChemInform Abstract: Redox Condensation of o‐Halonitrobenzene with 1,2,3,4‐Tetrahydroisoquinoline: Involvement of an Unexpected Auto‐Catalyzed Redox Cascade.
Authors: Nguyen T. B. , Ermolenko L. , Al‐Mourabit A. 
Published: July 2016

AbstractFused benzimidazoles are prepared by the title redox condensation.