bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Thermal Cyclization of a 1,3‐Diphosphaallene. Formation of a 1,2,3,4‐Tetrahydro‐1‐phosphanaphthalene.
Authors: YOSHIFUJI M. , NIITSU T. , TOYOTA K. , INAMOTO N. , KARSCH H. H. , REISACHER H.‐U. 
Published: May 2016

AbstractThe diphosphaallene (I) undergoes ring closure upon heating to form the phosphanaphthalene (II) which equilibrates with its stereoisomer (III).
ChemInform Abstract: Synthesis and Structure of Cp3U=CHPMe3: A Compound with a U=C Multiple Bond.
Authors: CRAMER R. E. , BRUCK M. A. , EDELMANN F. , AFZAL D. , GILJE J. W. , SCHMIDBAUR H. 
Published: May 2016

AbstractThe title compound (III) is synthesized according to the scheme.
ChemInform Abstract: A Novel Coordination Mode for the Squarate Ligand (Dihydroxycyclobutenedionate(2‐)): Synthesis, Crystal Structure, and Magnetic Properties of catena‐Diaqua(2,2′‐bipyridyl)‐μ‐(squarato‐O1,O2)‐nickel(II) Dihydrate.
Authors: SOULES R. , DAHAN F. , LAURENT J.‐P. , CASTAN P. 
Published: May 2016

AbstractThe title complex (I) is obtained by 1:1:1 molar reaction of NiCl2·6 H2O, squaric acid, and 2,2'‐bipyridine in water.
ChemInform Abstract: The Heteronuclear Cluster Chemistry of the Group 1B Metals. Part 5. X‐Ray Crystal Structure and Dynamic Behavior of the Heptanuclear Mixed‐Metal Cluster (Au3Ru4(μ‐H)(CO)12(μ‐Ph2PCH2PPh2)(PPh3)).
Authors: ADATIA T. , MCPARTLIN M. , SALTER I. D. 
Published: May 2016

AbstractThe X‐ray structure analysis of the title cluster (I) (space group P21/n, Z=4) shows that the Au3Ru4 skeleton may be described as a distorted Au2Ru3 square pyramid, capped on two adjacent triangular faces by a Ru(CO)3 and a Au(PPh3) unit.
ChemInform Abstract: Synthetic Studies Toward the Pinguisanes; Synthesis of 4‐epi‐Pinguisone.
Authors: BAKER R. , SELWOOD D. L. , SWAIN C. J. , WEBSTER N. M. H. , HIRSHFIELD J. 
Published: May 2016

AbstractThe key intermediate (Va) for the synthesis of the title compound (XII) is synthesized by two approaches from reactions of the Diels‐Alder components (IV) + (III) or the Michael reaction components (VI) (available from (IV)) + (III), resp., as shown in the scheme.
ChemInform Abstract: Petuniasterones, Novel Ergostane‐Type Steroids of Petunia hybridia Vilm. (Solanaceae) Having Insect‐Inhibitory Activity. X‐Ray Molecular Structure of the 22,24,25‐((Methoxycarbonyl)orthoacetate) of 7α,22,24,25‐Tetrahydroxyergosta‐1,4‐dien‐3‐one and of 1α‐Acetoxy‐24,25‐epoxy‐7α‐hydroxy‐22‐(methylthiocarbonyl)acetoxyerg# ost‐4‐en‐3‐one.
Authors: ELLIGER C. A. , BENSON M. E. , HADDON W. F. , LUNDIN R. E. , WAISS A. C. JUN. , WONG R. Y. 
Published: May 2016

AbstractPetuniasterone A (Ia) is isolated from the title species as main component together with the compounds (IIa)‐(IIc) and (IIIa)‐(IIIc).
ChemInform Abstract: Phosphorylated Sugars. Part 24. Methyl 3‐Deoxy‐α‐D‐manno‐oct‐2‐ulopyranosidonic Acid 4‐(Dihydrogen Phosphate): Synthesis, Stability in Acidic Medium, and Colorimetric Estimation.
Authors: SARFATI S. R. , LE DUR A. , SZABO L. 
Published: May 2016

AbstractThe synthesis of the title compound (II) is accomplished starting from the compound (I).
ChemInform Abstract: Optical Outer‐sphere Ligand to Metal Charge Transfer in the Ion Pair (Ru(NH3)6)3+(Rh(CN)6)3‐.
Authors: VOGLER A. , KUNKELY H. 
Published: May 2016

AbstractElectronic absorption spectra are recorded for an aqueous solution of (Ru(NH3)6)(NO3)3 (I) and a mixture of (I) and K3(Rh(CN)6) (II).
ChemInform Abstract: An Aluminum/Chlorine Rechargeable Cell Employing a Room Temperature Molten Salt Electrolyte.
Authors: GIFFORD P. R. , PALMISANO J. B. 
Published: May 2016

AbstractA 1.5:1 AlCl3: 1,2‐dimethyl‐3‐propylimidazolium chloride electrolyte is used for the new secondary cell with an Al negative electrode and a graphite positive electrode, which serves as a reversible chlorine intercalation electrode, thus eliminating the need of a separation membrane between anolyte and catholyte compartments.
ChemInform Abstract: Reductive Desorption of Iodine Chemisorbed on Smooth Polycrystalline Gold Electrodes.
Authors: RODRIGUEZ J. F. , SORIAGA M. P. 
Published: May 2016

AbstractAt potentials ∼ 900 mV negative of that at which reduction of I2 to I‐ takes place in aqueous solution, adsorbed I is reduced to I‐ (ads) in a single‐electron step resulting in the desorption of I‐ from the Au surface.
ChemInform Abstract: Trigonal Bipyramidal Heteronuclear Metal Atom Clusters of the Type closo‐Fe3(CO)9(μ3‐MRe(CO)5)2 (M = Ge, Sn).
Authors: HAUPT H.‐J. , GOETZE A. + , FLOERKE U. + 
Published: May 2016

AbstractThe diamagnetic title compounds (I) are prepared by reaction of SnCl2 (or Ge/GeCl4) with MnRe(CO)10 and Fe(CO)5 at 220 °C in a glass tube.
ChemInform Abstract: Anodic Transformation of Cycloheptatriene to Tropone and Tropolone.
Authors: SHONO T. , NOZOE T. , MAEKAWA H. , KASHIMURA S. 
Published: May 2016

AbstractAnodic oxidation of cycloheptatriene (I) in the presence of methanol (II) produces the methoxycycloheptatriene (III) and benzaldehyde dimethyl acetal (IV).
ChemInform Abstract: Thermal Cycloaddition Reaction of Tropone to 1,1‐Diethoxyethene. Structure Revision of Cantrell′s Diels‐Alder Adduct.
Authors: TAKESHITA H. , NAKASHIMA H. , SUGIYAMA S. , MORI A. 
Published: May 2016

AbstractThe title reaction between (I) and (II) under the conditions indicated affords the products (III)‐(V).
ChemInform Abstract: Intramolecular Trapping of a Cyclopropylidenamine During the Favorskii Rearrangement of α‐Chloro Ketimines.
Authors: DE KIMPE N. , STANOEVA E. , SCHAMP N. 
Published: May 2016

AbstractThe chloroimines (I) are lithiated and then substituted to give the siloxyalkyl derivatives (III) which are cyclized upon treatment with tert‐butoxide, producing the tetrahydrofuranylimines (IV) and the fused aminotetrahydropyrans (V).
ChemInform Abstract: Photoreactions of Ir8(CO)2‐ 22. Homolytic Cleavage of an Unsupported Metal‐Metal Bond Linking Two Tetrahedral Iridium Carbonyl Clusters.
Authors: VANDENBERG D. M. , FRIEDMAN A. E. , FORD P. C. 
Published: May 2016

AbstractSolutions of (I) under CO in various solvents are indefinitely stable in the dark.
ChemInform Abstract: Cerium(IV) Induced Hydroxylation of C‐Alkylated Hydrocarbons and Phenols.
Authors: CHAWLA H. M. , SHARMA S. K. , CHAKRABARTY K. , BHANUMATI S. 
Published: May 2016

AbstractThe hydroxylation of some C‐alkylated phenols such as (I) proceeds via radical intermediates to give the products of hydroxylation (II), oxidative coupling (III) or nitration (IV).
ChemInform Abstract: Reaction of Phenylnitrenium Ion with Sulfides. A Novel Synthetic Method for Aminophenyl Sulfide Derivatives.
Authors: TAKEUCHI H. , HIRAYAMA S. , MITANI M. , KOYAMA K. 
Published: May 2016

AbstractIn the presence of a mixture of TFA and CF3SO3H the reaction between phenyl azide (I) and the dialkyl sulfides (II) affords the o‐aminophenyl sulfides (IV) along with the p‐aminophenyl sulfides (V).
ChemInform Abstract: Hydrocarbonylating Cyclization of Dienes. Part 4. Regio‐ and Stereochemistry of the Cobalt‐ and Rhodium‐Catalyzed Synthesis of Substituted Cyclopentanones.
Authors: EILBRACHT P. , ACKER M. , HAEDRICH I. + 
Published: May 2016

AbstractHydrocarbonylating cyclization of the diene (I) yields mixtures of the (E)‐ and (Z)‐cyclopentanones (III) and (IV) and the exo‐methylene product (V).
ChemInform Abstract: Aminophenylpentafulvene‐6,6‐dicarbonitrile Dyes with Absorptions in the Near Infrared Region. Syntheses with Nitriles. Part 76.
Authors: JUNEK H. , URAY G. , ZUSCHNIG G. 
Published: May 2016

AbstractDicyanomethylenetetrachlorocyclopentadiene (I) is coupled with various anilines.
ChemInform Abstract: Regio‐ and Stereoselectivity of Intramolecular Diels‐Alder Reactions of Fumarates: An Unusual Rearrangement‐Cyclization.
Authors: EBERLE M. K. , WEBER H.‐P. 
Published: May 2016

AbstractThe fumarates of the hexadienols (I) undergo intramolecular cyclization, yielding the octahydroisobenzofuranones (IV).
ChemInform Abstract: Cycloadditions of Vinylindoles to Anellated Indole Derivatives. Part 5. New Reactions of 3‐Vinyl‐ and 3‐(2‐Propenyl)indoles with N‐Phenylmaleimide: (4 + 2) Cycloaddition, Ene Reaction and Dimerization.
Authors: PFEUFFER L. , PINDUR U. 
Published: May 2016

AbstractStereospecific (4 + 2) cycloadditions ("endo"‐preference) and dimerizations take place when the vinylindoles (I), (IV), (VII), or (XI) react with N‐phenylmaleimide (II) depending on the substitution pattern of the aminobutadiene subunit in the vinylindoles to give the products shown in the scheme.
ChemInform Abstract: o‐Nitroaniline Derivatives. Part 9. Benzimidazole N‐Oxides Unsubstituted at N‐1 and C‐2.
Authors: HARVEY I. W. , MCFARLANE M. D. , MOODY D. J. , SMITH D. M. 
Published: May 2016

AbstractNovel and general routes to the title compounds (VII) and (XIII) are described.
ChemInform Abstract: A Convenient Palladium‐Catalyzed Coupling Approach to 2,5‐Disubstituted Pyridines.
Authors: TILLEY J. W. , ZAWOISKI S. 
Published: May 2016

Abstract2,5‐Dibromopyridine (I) is selectively coupled with the terminal acetylenes (II) or the arylzinc chlorides (XI) in the presence of a Pd(II) catalyst to form the 2‐substituted derivatives (IIIb), (IIIc), or (XII).
ChemInform Abstract: (4 + 2) Cycloaddition of α,β‐Unsaturated Hydrazones to Pyridine‐2,3‐dicarboximides via 1,4‐Dihydropyridine Derivatives.
Authors: WALDNER A. 
Published: May 2016

AbstractThe cycloaddition of α,β‐unsaturated hydrazones of the type (I) with maleimide (e.g.
ChemInform Abstract: Formation of Three‐Membered Rings from γ‐Iodo Ketones and γ‐Iodo Esters via 1,3‐Elimination.
Authors: MORI M. , KANDA N. , BAN Y. , AOE K. 
Published: May 2016

AbstractPd catalyzed cyclization of the unsaturated iodo sulfonamido ketone (I) results in the formation of the piperidines (II) and the hexahydroazepines (III).
ChemInform Abstract: Sila‐Pharmaca. Part 38. Structure and Pharmacological Effectiveness of Sila‐Substituted Analogues of the Psychopharmacological Agent Dimetacrine.
Authors: WANNAGAT U. , WIESE D. , STRUCKMEIER G. , THEWALT U. , DEBAERDEMAEKER T. 
Published: May 2016

AbstractThe silaacridane (V) and its methiodide (VII) are prepared as shown in the scheme; the salts (VIII) and the respective parent (V)‐analogues, most of which are known, are obtained similarly.
ChemInform Abstract: Diels‐Alder Reactions of 1,3λ3‐Azaarsinines with Alkyne Dienophiles. A Facile Approach to the λ3‐Arsinine Ring System.
Authors: MAERKL G. + , DIETL S. 
Published: May 2016

AbstractDimethyl acetylenedicarboxylate (II) reacts with 2,4,6‐triphenyl‐1,3λ3‐azaarsinine (I) in refluxing toluene to form the 2:1 adduct (VI) via the intermediates (III) and (V).
ChemInform Abstract: Intramolecular Hydrostannation ‐ Cyclic and Bicyclic Stannanes.
Authors: KRECH F. , ISSLEIB K. 
Published: May 2016

AbstractReductions of the 2‐allyl‐4‐pentenyltin chlorides (IV) prepared as shown lead to the expected dihydride (V) and/or to the intramolecular hydrostannation products (VIa) and (VIb).
ChemInform Abstract: Reactions at a Dimolybdenum(V) Sulfur Bridge. Alkyne Additions.
Authors: LIZANO A. C. , NOBLE M. E. 
Published: May 2016

AbstractReactions of the dimer anion (I), generated in situ of the neutral tetramer and acetic acid in the presence of NEt3, with the alkynes (II) in the presence of excess acid result in formal S,H‐addition to (II) giving the S‐bridged alkenethiolate complexes (III).
ChemInform Abstract: Halogeno‐Bridged Heteronuclear Metal Atom Clusters of the Three Types Re2(CO)4L2(μ‐X)2(μ‐Y) (L = (C6H5)3P; X = Br, I; Y = GaRe(CO)4ax‐L), Re2(CO)6L2(μ‐X)(μ‐GaX2) (X = I), and Re3(CO)9L3(μ‐X)3(μ3‐Y) (X = Cl).
Authors: HAUPT H.‐J. , BALSAA P. , FLOERKE U. + 
Published: May 2016

Abstract(I) and (II) are prepared by reaction of the appropriate gallium halide with Re2(CO)8L2 in boiling mesitylene.
ChemInform Abstract: Stability Studies in Relation to IR Data of Some Schiff Base Complexes of Transition Metals and Their Biological and Pharmacological Studies.
Authors: PARASHAR R. K. , SHARMA R. C. , KUMAR A. , MOHAN G. 
Published: May 2016

AbstractThe 1:1 Cu, Ni and Co complexes of the Schiff bases (Ia) and the 1:2 complexes of (Ib) are prepared and characterized by their elemental analysis, TGA, IR and electronic spectral studies, molar conductance and magnetic susceptibility measurements.
ChemInform Abstract: Transition‐Metal‐Promoted Oxidation of Organic Sulfides. Synthesis, Characterization, and Structure of (μ4‐Oxo)hexakis(μ2‐chloro)tetrakis(dialkyl sulfoxide)tetracopper(II).
Authors: GUY J. T. JUN. , COOPER J. C. , GILARDI R. D. , FLIPPEN‐ANDERSON J. L. , GEORGE C. F. JUN. 
Published: May 2016

AbstractThe direct reaction of CuCl2 in an acetone suspension with alkyl thioethers gives the air oxidation products (I), characterized by IR and electronic spectra and X‐ray diffraction.
ChemInform Abstract: Metal‐Catalyzed Organic Photoreactions. Iron(III)‐Catalyzed Photoreactions of Aldo‐ and Ketohexoses.
Authors: ICHIKAWA S. , TOMITA I. , HOSAKA A. , SATO T. 
Published: May 2016

AbstractThe transformation of either glucose (I) or mannose (IV) to compound (III), and of fructose (V) to the product (VI) by the title reaction in pyridine involves the selective cleavage of the C‐1/C‐2 bond.
ChemInform Abstract: Incorporation of Gold Cyanide in Electrodeposited Gold.
Authors: HOLMBOM G. , JACOBSON B. E. 
Published: May 2016

Abstract50 nm thick Au films are electrodeposited onto different substrates from a citrate buffered (pH 4.7) KAu(CN)2 solution at 40 °C, and the presence and location of AuCN impurities in the films are investigated by TEM with selected area diffraction and Auger electron spectroscopy.
ChemInform Abstract: X‐Ray Photoelectron and Ion Scattering Studies of Tungsten Oxides and Tungsten Oxide Catalysts
Authors: CHAPPELL P. J. C. , KIBEL M. H. , BAKER B. G. 
Published: May 2016

Abstractare undertaken in an attempt to understand how such compounds function as catalysts, in particular as isomerization catalyst following the Fischer‐Tropsch process.
ChemInform Abstract: Electrolytical Studies on Vinylazides. Part 7. Cathodic Synthesis of 2‐Amino‐2‐propen‐1‐ones.
Authors: KNITTEL D. , RAO V. S. 
Published: May 2016

AbstractThe cathodic preparation of enamino ketones from enazidoketones such as (I) is generalized to include heteroaromatic and aliphatic derivatives.
ChemInform Abstract: Lithiation of the 6‐Dimethylamino‐1‐azafulvene Dimer. A Versatile Synthesis of 5‐Substituted Pyrrole‐2‐carboxaldehydes.
Authors: MUCHOWSKI J. M. , HESS P. 
Published: May 2016

AbstractThe 6‐dimethylamino‐1‐azafulvene dimer (I) is lithiated and then coupled with the electrophilic reagents (III) to form the substitution products (IV) which equilibrate with the monomers (V).
ChemInform Abstract: Selective Palladium‐Catalyzed Deprotection of the Allyl and Allyloxycarbonyl Groups in Phosphate Chemistry and in the Presence of Propargyl and Propargyloxycarbonyl Groups.
Authors: ZHANG H. X. , GUIBE F. , BALAVOINE G. 
Published: May 2016

AbstractThe allyl units in the phosphates (I) are substituted for tributylstannyl moieties in the presence of a Pd catalyst while propargyl, alkyl, and aryl groups remain unchanged.
ChemInform Abstract: Synthesis of 2‐Alkylputrescines from 3‐Alkylpyrroles.
Authors: GARRIDO D. O. , BULDAIN G. , OJEA M. I. , FRYDMAN B. 
Published: May 2016

AbstractThe 3‐acylpyrroles (VII) are prepared by 4‐acylation of 2‐trichloroacetylpyrrole (I) followed by saponification and degradation of the substituent at position 2. Wolff‐Kishner reduction of (VII) yields the 3‐alkylpyrroles (VIII) which are cleaved upon treatment with hydroxylamine hydrochloride (IX) to form the intermediate dioximes (X).
ChemInform Abstract: A Stereoselective Synthesis of Z‐α,β‐Disubstituted Acrylates.
Authors: SHIMAGAKI M. , SHIOKAWA M. , SUGAI K. , TERANAKA T. , NAKATA T. , OISHI T. 
Published: May 2016

AbstractSelective reduction of the α‐phenylsulfenyl β‐keto esters (I) produces mixtures of the syn‐ and anti‐β‐hydroxy esters (II).
ChemInform Abstract: Synthesis of cis‐1,2,3,4,4a,9,10,10a‐Octahydrophenanthrene.
Authors: BANSAL R. C. , BROWNE C. E. , EISENBRAUN E. J. , THOMSON J. S. 
Published: May 2016

AbstractSeveral pathways of preparing the title compound (V) from the α‐hydroxymethylene ketone (I) are tested.
ChemInform Abstract: Palladium‐Catalyzed Asymmetric Intramolecular Allylation Forming Optically Active Vinylcyclopropane and Vinyldihydrofurans.
Authors: HAYASHI T. , YAMAMOTO A. , ITO Y. 
Published: May 2016

AbstractThe 2‐butenylene dicarbonates (I) react with dimethyl malonate (II) in the presence of a chiral ferrocenylphosphine Pd complex to give the vinylcyclopropanedicarboxylate (R)‐(III).
ChemInform Abstract: Antibiotics from Algae. Part 38. Base‐Catalyzed Reactions of Multiple Hydroxylated Diphenyl Ethers.
Authors: GLOMBITZA K.‐W. , WOELWER‐RIECK U. + 
Published: May 2016

AbstractThe substitution pattern is investigated for a series of 33 hydroxylated diphenyl ethers such as (I).
ChemInform Abstract: Robinson‐Schopf Condensations with Succinaldehyde.
Authors: MCINTOSH J. M. 
Published: May 2016

AbstractSuccinaldehyde, in situ generated by acidic cleavage of the dimethoxytetrahydrofuran (I), reacts with the amines (II) and potassium cyanide (III) to produce the dicyanopyrrolidines (IV) and/or (V).
ChemInform Abstract: Synthesis of Aminoalkanol and Aminoethyl Derivatives of 4,9‐Dihydroxy‐7‐ethyl‐5H‐furo(3,2‐g) (1)benzopyran‐5‐one.
Authors: KOSSAKOWSKI J. , ZAWADOWSKI T. 
Published: May 2016

AbstractThe title compound (IV) is synthesized starting from khellin (I).
ChemInform Abstract: A New Synthesis of Carboxylic Acid Hydrazides via Organoaluminum Reagents.
Authors: BENDERLY A. , STAVCHANSKY S. 
Published: May 2016

AbstractThe hydrazines (I) react with trimethylaluminum (II) to form the dimethylaluminum derivatives (III) which are treated with the esters (IV), producing the hydrazides (V).
ChemInform Abstract: Metal Catalyzed Brooke Rearrangement of 3‐Halo‐1‐(trimethylsilyl)propan‐2‐one (Halo = Cl or Br).
Authors: JONES M. D. , KEMMITT R. D. W. 
Published: May 2016

AbstractThe halosilylacetones (III) are prepared from the acid anhydrides (I) by Grignard reaction with the silylmethylmagnesium chloride (II).
ChemInform Abstract: The Chemistry of α‐Silyl Carbonyl Compounds. Part 17. Methyldiphenylsilylation of Ester and Lactone Enolates.
Authors: LARSON G. L. , CRUZ DE MALDONADO V. , FUENTES L. M. , TORRES L. E. 
Published: May 2016

AbstractThe enolates derived from the esters (I) react with methyldiphenylsilyl chloride (II) to give mainly the α‐C‐silylated esters (III).
ChemInform Abstract: Reaction of Alkene‐ and Halophosphonates with Bases. Prototropic Isomerization and H/D Exchange.
Authors: BELYKH O. A. , DOGADINA A. V. , IONIN B. I. , PETROV A. A. 
Published: May 2016

AbstractAlk‐1‐enephosphonates such as (I) isomerize on treatment with bases, producing the corresponding alk‐2‐enephosphonates (II).
ChemInform Abstract: Sterically Hindered Magnesium Aryloxides.
Authors: CALABRESE J. C. , CUSHING M. A. JUN. , ITTEL S. D. 
Published: May 2016

AbstractReaction of (I) with sterically hindered phenols (II) gives the dimeric compounds (III), characterized by an X‐ray determination at ‐70 °C. (IIIa) crystallizes in C2/c with Z=4, (IIIb) in Pc21b (Z not given).
ChemInform Abstract: Synthesis and Molecular Structure of (Al(CH3)3) (12)aneS4: A Novel Example of an Axially Stabilized Trigonal Bipyramidal Coordination of Aluminum.
Authors: ROBINSON G. H. , SANGOKOYA S. A. 
Published: May 2016

AbstractThe title complex (III) crystallizes in the space group P21/n with Z=4.
ChemInform Abstract: Synthetic and Mechanistic Features of Dinuclear Reductive Elimination Between Re2H8(PMe2Ph)4 and Several Tin(II) Reagents.
Authors: WESTERBERG D. E. , SUTHERLAND B. R. , HUFFMAN J. C. , CAULTON K. G. 
Published: May 2016

AbstractThe reactions leading to (III) (P21/a, Z=4) show the results of attempts to incorporate a carbene‐like tin(II) fragment into a rhenium polyhydride as a first step toward understanding the patterns of composition, structure and reactivity of Pt/Re/Sn petroleum reforming catalysts.
ChemInform Abstract: Intermediacy of Paramagnetic Metal‐Hydrocarbyl Species in Organometallic Reactions. Detection and Characterization of a Novel Paramagnetic Iron(II)‐Benzyl Compound in the Coupling of Benzyl Halides.
Authors: HILL D. H. , SEN A. 
Published: May 2016

AbstractDetection and characterization by NMR spectroscopy of the novel paramagnetic Fe(II)‐benzyl compound (IV) is reported which is the key intermediate in the coupling of benzyl halides (II) by complex (I) giving dibenzyl (VI).
ChemInform Abstract: Photochemical Disproportionation Reactions of the W2(CO)2‐ 10 and Fe2(CO)2‐ 8 Complexes.
Authors: SILAVWE N. D. , PAN X. , TYLER D. R. 
Published: May 2016

AbstractIrradiation of the anionic complexes (I) and (V) in the presence of phosphines results in disproportionation of the dimers according to the scheme.
ChemInform Abstract: Reactions of (μ‐PhPLi)2Fe2(CO)6 with Metal Halides.
Authors: SEYFERTH D. , HENDERSON R. S. , WOOD T. G. 
Published: May 2016

AbstractThe metal carbonyl cluster complexes (III), (V), (X), and (XII) are prepared by reactions of the title complex (I) with the appropriate metal chlorides (II), (IV), (IX) and (XI) according to the scheme.
ChemInform Abstract: Crystal and Molecular Structure of ((η5‐C5H5)Fe(CO)2Re(CO)5) and the Reactions of ((η5‐C9H7)Fe(CO)2Re(CO)5) with RNC (R: tBu, 2,6‐Me2C6H3).
Authors: JOHNSTON P. , DICKSON C.‐A. , MARKWELL A. J. , DENNER L. , BOEYENS J. C. A. , COVILLE N. J. 
Published: May 2016

AbstractThe structure of the title complex (space group P21/c, Z = 8) is determined by X‐ray analysis.
ChemInform Abstract: Cobalt(II) and μ‐Oxodiiron(III, IV) Complexes of Salen Analog with Aromatic Thioether Pendant Group, N,N′‐Disalicylidene‐2‐methyl‐4‐(2‐methylthiophenyl)‐1,2‐butanediamine.
Authors: HORIUCHI K. , KOIKAWA M. , BABA S. , OKAWA H. , MAEDA Y. , OSHIO H. , KIDA S. 
Published: May 2016

AbstractThe preparation of the Schiff base ligand (I) is described.
ChemInform Abstract: Synthesis and Characterization of Novel Tri‐ and Tetra Metallic Isopropoxides of Later “3d” Metals.
Authors: DUBEY R. K. , SHAH A. , SINGH A. , MEHROTRA R. C. 
Published: May 2016

AbstractThe title compounds (III)‐(VIII) are prepared by the reaction of bi‐ or tri‐metallic chloride isopropoxides with a potassium isopropoxymetallate in an appropriate molar ratio as shown for the example of (III).
ChemInform Abstract: Transition Metal Ion Complexes of 2‐Thio‐6‐picoline N‐Oxide.
Authors: WEST D. X. , HINES J. L. , BUNTING R. K. , SYMONS M. C. R. , MALIK N. A. 
Published: May 2016

Abstract6‐Methyl‐2‐chloropyridine is oxidized with 30% H2O2.
ChemInform Abstract: Reactions of CO2 with Tetrahydroborato Copper(I) Complexes in Moist Solvents: Synthesis and Reactions of ((phen)2Cu) ((HO)3B(O2CH)) and (phen)(Ph3P)Cu(O2COH) (phen = 1,10‐Phenanthroline).
Authors: LA MONICA G. , ANGARONI M. A. , CARIATI F. , CENINI S. 
Published: May 2016

AbstractCO2 (II) or aqueous formic acid (III) react with the tetrahydridoborato‐Cu(I) complex (I) in the presence of phenanthroline (IV) to give the ionic title compound (V).
ChemInform Abstract: Transition‐Metal Coordination Compounds of a Chelating Imidazole‐Thioether Ligand. The Molecular Structure of Diisothiocyanato(1,6‐bis(5‐methyl‐4‐imidazolyl)‐2,5‐dithiahexane)nickel(II).
Authors: BOUWMAN E. , DE GELDER R. , DE GRAAFF R. A. G. , DRIESSEN W. L. , REEDIJK J. 
Published: May 2016

AbstractAppropriate hydrated metal salts in ethanol or methanol react with the ligand L in refluxing ethanol to produce the complexes (I)‐(IV).
ChemInform Abstract: Reactions of Monoazadienes with Metal Carbonyl Complexes. Part 2. Reactions of N‐Alkyl‐(E)‐crotonaldimine with Ru3(CO)12. The X‐Ray Crystal Structure of Ru3(CO)6(CH3‐C=CH‐CH=N‐C3H7‐i)2, an Acyclic Cluster Which is Isolobally Related to Ruthenocene.
Authors: MUL W. P. , ELSEVIER C. J. , VRIEZE K. , SMEETS W. J. J. , SPEK A. L. 
Published: May 2016

AbstractThe title reaction yields the γ‐metalated products (III) in two stereoisomeric forms, together with several other products.