bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Studies on Activating Methods of Functional Groups. Part 18. Novel Reactions of S,S′‐Bis(1‐phenyl‐1H‐tetrazol‐5‐yl) Dithiocarbonate.
Authors: TAKEDA K. , TSUBOYAMA K. , TAKAYANAGI H. , SHIROKAMI R. , TAKEURA M. , OGURA H. 
Published: May 2016

AbstractThe phenylthiotetrazole (I) reacts with trichloromethyl chloroformate (II) in the presence of a base to give the dithiocarbonate (III) which is acylated with the carboxylic acids (IV), forming a mixture of the tetrazoles (V) and (VI).
ChemInform Abstract: Alkylation of 1,2,3,4,10,10a‐Hexahydropyrimido(1,2‐a)indol‐2‐one Derivatives.
Authors: DYAGUTITE R. YU. , SHACHKUS A. A. 
Published: May 2016

AbstractThe fused indoles (I) mentioned in the title are alkylated with the alkyl halides (II) to give the O‐substituted derivatives (III) and minor amounts of the indoles (IVa) and (IVc).
ChemInform Abstract: Cyclophanes. Part 7. Synthesis and Structures of Dioxazolo(32)metacyclo(2,5)thiophenophane and a Higher Homolog.
Authors: SASAKI H. , KAWANISHI K. , KITAGAWA T. , SHINGU T. 
Published: May 2016

AbstractThe bis(isocyanotosylethyl)benzene (I) and thiophene‐2,5‐dicarbaldehyde (II) undergo cyclization reaction in the presence of a base to produce a mixture of the dioxazolometacyclothiophenophane (III) and the tetraoxazolo analogue (IV).
ChemInform Abstract: Synthesis and Reactivity Studies of the Small Carborane closo‐2,3‐Et2C2B5H5.
Authors: BECK J. S. , SNEDDON L. G. 
Published: May 2016

AbstractThe cluster expansion reaction for the title carborane (III) at 170 °C yields, beside (III), a two‐boron and a three‐boron expansion product.
ChemInform Abstract: Further Studies of the Kinetic Coordination Template Effect in the Metal Ion Catalyzed Formation of Arylphosphonium Salts.
Authors: ALLEN D. W. , CROPPER P. E. 
Published: May 2016

AbstractThe reactions of a series of bis‐imines such as (III) with tertiary phosphines such as (IV) in the presence of NiBr2 proceed with replacement of the o‐halogen to form the related salts such as (V).
ChemInform Abstract: Reaction of Chloromethyltrimethylsilane with Sodium Diorganophosphides.
Authors: WOLFSBERGER W. 
Published: May 2016

AbstractThe alkyldiphenylphosphines (Ia), (Ib), and triphenylphosphine (Ic) are monodephenylated with sodium in liquid ammonia and directly treated with chloromethyltrimethylsilane (II), forming the (silylmethyl)phosphines (III) as the main products, together with the methylphosphines (IV).
ChemInform Abstract: Synthesis and Crystal Structures of the Lithiated Silylphosphanes (CMe3)2SiFP(Mes)Li(THF)3, (CMe3)2SiFLi(TMEDA)PMes, and of the Cyclic Silylphosphanes ((CMe3)2SiPMes)2.
Authors: ANDRIANARISON M. , KLINGEBIEL U. , STALKE D. , SHELDRICK G. M. 
Published: May 2016

AbstractThe silylphosphane (III), prepared by reaction of the silane (I) with the lithium phosphide (II), reacts with tert‐butyllithium (IV) in the presence of THF or TMEDA to give the lithium complexes (VI).
ChemInform Abstract: Alkyne Cleavage as a Novel Route to Low‐Valent Carbyne‐Metal Complexes.
Authors: FILIPPOU A. C. , VOELKL C. + , GRUENLEITNER W. + , KIPROF P. 
Published: May 2016

AbstractReversal of a carbyne‐isocyanide coupling allows the preparation of the electron‐rich carbyne complex (X) (P21, Z=2).
ChemInform Abstract: Tris(trimethylsilyl)arsane as a Starting Compound for Tri‐ and Tetraferrioarsonium Salts; Crystal Structure of ((Cp(CO)2Fe)3AsOH)B(C6H5)4.
Authors: LORENZ I.‐P. , EFFINGER G. , HILLER W. 
Published: May 2016

AbstractTris(trimethylsilyl)arsane (I) reacts with an excess of the iron complex (II) to give the tetraferrioarsonium compound (III).
ChemInform Abstract: Linked Bis(μ‐phosphido) and Related Ligands for Metallic Clusters. Part 8. Heterosite Reactivity of Linked Bis(μ‐phosphido)‐Bound Isostructural CoxMo4‐x Clusters (x = 2, 3). Characterization and Reactivity of a Novel μ4‐η2‐NO Cluster.
Authors: KYBA E. P. , KERBY M. C. , KASHYAP R. P. , MOUNTZOURIS J. A. , DAVIS R. E. 
Published: May 2016

AbstractThe related Co‐Mo clusters (III) and (IV) show significant differences in reactivity with two electrophiles NO+ and H+.
ChemInform Abstract: A Convenient Preparation and the Molecular Structure of trans‐Bis(dimethylglyoximato)(trifluoromethyl)(pyridine)cobalt(III): A Cobaloxime with a Very Short Co‐C(sp3) Bond.
Authors: TOSCANO P. J. , KONIECZNY L. , LIU S. , ZUBIETA J. 
Published: May 2016

AbstractIn the new synthesis an undesirable reductive defluorination is avoided via the usage of a minimum of reducing agent.
ChemInform Abstract: Ruthenium‐Containing Cumulenes: Generation of 2,3,4‐Pentatrienylidene and 3‐Oxo‐1,4‐pentadienyl Complexes.
Authors: ROMERO A. , VEGAS A. , DIXNEUF P. H. 
Published: May 2016

AbstractThe novel complexes (IV), whose structure is confirmed by an X‐ray analysis of (IVa) ( P21/n, Z=4), are presumably formed via an unstable metallacumulene intermediate.
ChemInform Abstract: Synthesis of N‐Octadecylsquarylium Dyes Under High Pressure.
Authors: TANAKA M. , YASUMOTO M. , SHIBUYA I. , KAWABATA Y. , NAKAMURA T. , TACHIBANA H. , MANDA E. , SEKIGUCHI T. 
Published: May 2016

AbstractThe coupling of the N‐octadecyl methylbenzazolium salts (Ia) ‐ (Ic) or the methylquinolinium salts (Id) and (IV) with squaric acid (II) is achieved under high pressure, producing the squarylium dyes (III) and (V) respectively.
ChemInform Abstract: Structures of Three Pseudoguaianolides: Parthenin, Hymenolin (11β,13‐Dihydroparthenin) and Bipinnatin.
Authors: FRONCZEK F. R. , VARGAS D. , FISCHER N. H. , CHIARI G. , BALZA F. , TOWERS G. H. N. 
Published: May 2016

AbstractThe seven‐membered rings of hymenolin (II) (space group P21 with Z=4) and bipinnatin (III) (space group P212121 with Z=4) both adopt two different conformations while that of parthenin (I) (space group P41 with Z=4) has chair conformation.
ChemInform Abstract: Synthesis of (.+‐.)‐Marasmic Acid via 1‐Oxaspirohexane Rearrangement.
Authors: TOBE Y. , YAMASHITA D. , TAKAHASHI T. , INATA M. , SATO J. , KAKIUCHI K. , KOBIRO K. , ODAIRA Y. 
Published: May 2016

AbstractThe title compound (VII), an antimicrobial sesquiterpene, is active against Staphylococcus aureus and Escherichia coli.
ChemInform Abstract: Synthesis of β‐Lactams from Sugar Vinyl Ethers and Isocyanates.
Authors: KALUZA Z. , FUDONG W. , BELZECKI C. , CHMIELEWSKI M. 
Published: May 2016

AbstractCycloaddition reaction of sugar vinyl ethers such as (I) with tosyl isocyanate (II) produces N‐tosyl β‐lactams such as (III) which are N‐deprotected upon treatment with sodium in liquid ammonia.
ChemInform Abstract: Stereocontrolled Synthesis of (+)‐Valienamine.
Authors: NICOTRA F. , PANZA L. , RONCHETTI F. , RUSSO G. 
Published: May 2016

AbstractStarting from the easily available enone (I) an improved and stereoselective synthesis of the title compound (V) (22% overall yield) and of its epimer (IX) (no yield given) is described.
ChemInform Abstract: Asymmetric, Stereocontrolled Total Synthesis of (‐)‐Brevianamide B.
Authors: WILLIAMS R. M. , GLINKA T. , KWAST E. , COFFMAN H. , STILLE J. K. 
Published: May 2016

AbstractThe title compound (XIII) is a secondary metabolite of Penicillium brevicompactum.
ChemInform Abstract: Vibrational Spectroscopy of the Hydrated Hydronium Cluster Ions H3O+·(H2O)n (n = 1, 2, 3).
Authors: YEH L. I. , OKUMURA M. , MYERS J. D. , PRICE J. M. , LEE Y. T. 
Published: May 2016

AbstractUsing a new spectroscopic method, the gas phase IR spectra of the title cluster ions, produced in a high pressure corona discharge source, are observed between 3550 and 3800 cm‐1.
ChemInform Abstract: Aging of Single‐Crystal TiO2 Rutile Electrodes.
Authors: KIWIET N. J. , FOX M. A. 
Published: May 2016

AbstractAging effects caused by prolonged photoelectrolysis in acidic and alkaline media, or by anodic biasing in the dark are investigated for reduced ((001) and (011) orientations) and substitutionally doped (Nb‐doped (001))TiO2.
ChemInform Abstract: Characterization of Silica‐Supported Cu Monometallic and Ru‐Cu Bimetallic Catalysts by Hydrogen Chemisorption and NMR of Adsorbed Hydrogen.
Authors: WU X. , GERSTEIN B. C. , KING T. S. 
Published: May 2016

AbstractThe results obtained by the title methods for a series of Ru,Cu/SiO2 bimetallic catalysts clearly show hydrogen spillover from Ru to Cu.
ChemInform Abstract: Diamond Film Preparation by Arc Discharge Plasma Jet Chemical Vapor Deposition in the Methane Atmosphere.
Authors: OHTAKE N. , YOSHIKAWA M. 
Published: May 2016

AbstractThe plasma jet used for the diamond film deposition consists of H2 and argon and is continuously generated for more than 12 h. CH4 is used as an atmospheric gas and mixed into the plasma jet, which is subsequently sprayed onto a cool‐down substrate.
ChemInform Abstract: Preparation and Properties of Aluminum Hydroxide. Part 1. Boehmite from Aluminum Nitrate and Ammonia.
Authors: HILLE J. , BOLLMANN U. , WEINHOLD W. , BECKER K. , BREMER H. , VOGT F. , BERROUSCHOT H.‐D. 
Published: May 2016

AbstractThe influence of the precipitation conditions (pH, temp., concentration, and residence time in the precipitation solution) on composition, structure, and texture of mainly boehmite containing precipitations, obtained by continuous precipitation from Al(NO3)3 solution with ammonia water using technical raw materials and test conditions similar to those applied in production, is investigated.
ChemInform Abstract: Intracage Reactions in Sodalites.
Authors: WELLER M. T. , WONG G. , ADAMSON C. L. , DODD S. M. , ROE J. J. B. 
Published: May 2016

AbstractSodalites containing thiocyanate, Na8(AlSiO4)6(SCN)2·xH2O (I), and nitrite, Na8(AlSiO4)6(NO2)2·xH2O (II), are precipitated from sodium aluminosilicate solutions containing NaSCN or NaNO2 (110 °C, 24 h).
ChemInform Abstract: A New Electrochemical Synthesis of Iron Spinel Oxide in LiOH
Authors: MATSUMOTO Y. , HOMBO J. , CHEN Q. 
Published: May 2016

Abstractis carried out galvanostatically in 4 M KOH, 4 M LiOH, and their mixture using a Fe plate, a Ni plate, and Hg/HgO as working‐, counter‐, and reference electrodes.
ChemInform Abstract: IR Spectroscopic Studies on the Photocatalytic Hydrogenation of Norbornadiene by Group 6 Metal Carbonyls. Part 1. The Role of H2 and the Characterization of Nonclassical Dihydrogen Complexes, (η4‐Norbornadiene)M(CO)3(η2‐H2).
Authors: JACKSON S. A. , HODGES P. M. , POLIAKOFF M. , TURNER J. J. , GREVELS F.‐W. 
Published: May 2016

AbstractThe experiments reported demonstrate that d6 metal centers form nonclassical H2 complexes rather than dihydrides under conditions in which photocatalytic hydrogenation of dienes occurs.
ChemInform Abstract: Ring Construction of Bicyclic γ‐Lactams by Use of Electrochemical Oxidation.
Authors: MORI M. , WATANABE Y. , KAGECHIKA K. , SHIBASAKI M. 
Published: May 2016

AbstractElectrolysis of pyroglutamic acid (I) in the presence of sodium acetate (II) results in decarboxylative substitution to give the 5‐acetoxypyrrolidone (III).
ChemInform Abstract: Solvolysis of 2‐(Trifluoromethyl)‐2‐adamantyl Tosylate. Unexpectedly High Reactivity in Carbocation Formation.
Authors: ALLEN A. D. , KRISHNAMURTI R. , PRAKASH G. K. S. , TIDWELL T. T. 
Published: May 2016

AbstractKinetic measurements reveal that tosylate (I) converts to isomer (IVa) at a rate 3 times more rapid than the rate of formation of (IVb) from (IVa).
ChemInform Abstract: Preparation of Seven‐Membered Ring Cyclic Ethers and 3‐Alkylidenetetrahydropyrans from the Cyclization of Oxonium Cations Derived from Unsubstituted and Silicon‐Containing 4‐Alken‐1‐ols.
Authors: CASTANEDA A. , KUCERA D. J. , OVERMAN L. E. 
Published: May 2016

AbstractTreatment of the unsaturated acetals (I) and (IV) with ethylaluminum dichloride results in cyclization to give the chlorooxepans (II) and (III) or the chlorooxepan (V) and the chloropropyltetrahydrofuran (VI).
ChemInform Abstract: The Far‐UV Photochemistry of Alkylcyclopropenes in Solution.
Authors: FAHIE B. J. , LEIGH W. J. 
Published: May 2016

Abstract1,3,3‐Trimethyl‐ (I), 1‐tert.‐butyl‐3,3‐dimethylcyclopropene (VII), and 1,3,3‐trimethyl‐(1‐13C)cyclopropene are photolyzed in hydrocarbon, MeOH, and 1‐hexene solution.
ChemInform Abstract: Photocycloaddition Reaction of Tricyclo(3.3.1.02,8)nona‐3,6‐dien‐9‐one (Barbaralone) and Carbonyl Compounds.
Authors: MIYASHI T. , KONNO A. , TAKAHASHI Y. , KANEKO A. , SUZUKI T. , MUKAI T. , KOGA N. , IWAMURA H. 
Published: May 2016

AbstractThe tricyclic dienone (II) is irradiated in the presence of the benzophenones (Ia), (Ib), or chloranil (Ic) in various solvents.
ChemInform Abstract: Thermolysis of 2‐Acyloxy‐δ3‐1,3,4‐oxadiazolines. Evidence for a Preferred Sense of Cycloreversion to Carbonyl Ylides and for Fast 1,4‐Sigmatropic Ylide Rearrangement.
Authors: MAJCHRZAK M. W. , WARKENTIN J. 
Published: May 2016

AbstractA range of 8 title compounds such as (II) + (III) are prepared (unseparable cis/trans mixtures) from acetylhydrazones (I) in which the trans isomers (II) predominate in all cases.
ChemInform Abstract: Dioxirane Chemistry. Part 15. Rate Studies on Epoxidations by Dimethyldioxirane.
Authors: MURRAY R. W. , SHIANG D. L. 
Published: May 2016

AbstractRelative rates are determined of epoxidation of the (E)‐cinnamates (I) by (II) (from Me‐CO‐Me + KHSO5, stable in solution).
ChemInform Abstract: A Fast Procedure for the Reduction of Azides and Nitro Compounds Based on the Reducing Ability of Sn(SR)‐ 3 Species.
Authors: BARTRA M. , ROMEA P. , URPI F. , VILARRASA J. 
Published: May 2016

AbstractTin(II) complexes prepared by treatment of SnCl2 or Sn(S‐Ph)2 with Ph‐SH and Et3N appear to be the best agents reported so far for reducing azides such as (I) to amines such as (II).
ChemInform Abstract: Ruthenium‐Catalyzed C‐H Bond Activation Oxidation of Bridged Bicyclic and Tricyclic Alkanes.
Authors: TENAGLIA A. , TERRANOVA E. , WAEGELL B. 
Published: May 2016

AbstractThe norbornanes (I) react with ruthenium tetroxide, generated in situ, to give the exo‐norbornanols (II).
ChemInform Abstract: C‐Hydroxyalkylation Reactions of N‐Adamantylanilines with Hexafluoroacetone and Methyl Trifluoropyruvate.
Authors: SVIRIDOV V. D. , CHKANIKOV N. D. , SHAPIRO A. B. , KLIMOVA N. V. , PYATIN B. M. , KOLOMIETS A. F. , FOKIN A. V. 
Published: May 2016

AbstractThe N‐adamantyl‐4‐(hydroxytrifluoroethyl)anilines (III), compounds with potential psychotropic activity, are prepared by C‐hydroxyalkylation of the N‐adamantylanilines (I) with the polyfluoro carbonyl compounds (II).
ChemInform Abstract: Reaction of 4‐Nitrophthalonitrile with Carbonate, Nitrite, and Fluoride.
Authors: WOEHRLE D. + , KNOTHE G. 
Published: May 2016

Abstract4‐Nitrophthalonitrile (I) is heated with potassium or sodium fluoride, carbonate, or nitrite in dimethylformamide or dimethyl sulfoxide to form mainly the tetracyanodiphenyl ether (II), together with the phenol (III).
ChemInform Abstract: Synthesis of Stable o‐Sulfonylbenzonitrile Oxides.
Authors: MAMAEVA O. O. , STOYANOVICH F. M. , KRAYUSHKIN M. M. 
Published: May 2016

AbstractStarting with the sulfones (I) or (X), the stable nitrile oxides (VI), (IX), and (XIII) are prepared via the corresponding aldehydes and oximes.
ChemInform Abstract: Oxygenation of Alkenylsilanes in the Presence of Thiophenol. Direct and Regiospecific Conversion to α‐Phenylthio Carbonyl Compounds.
Authors: YOSHIDA J. , NAKATANI S. , ISOE S. 
Published: May 2016

AbstractThe substituted vinylsilanes (I) react with thiophenol (II) and oxygen in acetic acid to give the phenylthio ketones (III).
ChemInform Abstract: β‐Keto Carboxylic Acids Stabilized by Steric Effects.
Authors: MEIER H. , WENGENROTH H. , LAUER W. , KRAUSE V. 
Published: May 2016

AbstractThe diazo‐1,3‐diketones (I) are photolytically deaminated to form the isomeric carboxylic acids (II) ‐ (IV).
ChemInform Abstract: The Reformatskii‐Type Reaction of Gilman and Speeter in the Preparation of Valuable β‐Lactams in Carbapenem Synthesis: Scope and Synthetic Utility.
Authors: PALOMO C. , COSSIO F. P. , ARRIETA A. , ODRIOZOLA J. M. , OIARBIDE M. , ONTORIA J. M. 
Published: May 2016

AbstractReaction of the α‐bromo carboxylates (I) and (IV) with Schiff bases in the presence of zinc dust leads to the formation of β‐lactams as outlined in the reaction scheme.
ChemInform Abstract: Studies on Lactams. Part 83. Synthesis of Azetidine‐2,3‐diones (α‐Keto β‐Lactams) via 3‐(Phenylthio)‐2‐azetidinones.
Authors: VAN DER VEEN J. M. , BARI S. S. , KRISHNAN L. , MANHAS M. S. , BOSE A. K. 
Published: May 2016

AbstractConsecutive reaction of potassium phenylthioacetate (II) with cyanuric chloride (I) and the aldimines (IV) in the presence of a base produces the β‐lactams (V) via the intermediate esters (III).
ChemInform Abstract: Lewis Acid‐Promoted Condensation of Allylalkoxysilanes with Carbonyl Compounds. Synthesis of Tetrahydropyrans.
Authors: WEI Z. Y. , WANG D. , LI J. S. , CHAN T. H. 
Published: May 2016

AbstractThe allylalkoxysilane (I) reacts with the aldehydes (II) in the presence of aluminum trichloride to yield the cis‐4‐chloro‐2,6‐disubstituted tetrahydropyrans (III).
ChemInform Abstract: Addition and Lithiation Reactions of N‐(1‐Phenylalkylidene)anilines with Lithium Dialkylamides.
Authors: STREKOWSKI L. , PATTERSON S. , CEGLA M. T. , WYDRA R. L. , CZARNY A. , HARDEN D. B. 
Published: May 2016

AbstractReaction of the benzylideneanilines (I) with lithium diisopropylamide (II) results in amination and/or double bond isomerization, yielding the diamino compounds (III), together with the enamines (IV).
ChemInform Abstract: Synthesis and Crystal Structure of Naphtho(2,1‐b)(1,5)naphthyridine.
Authors: TAKEUCHI I. , HAMADA Y. , OKAMURA K. 
Published: May 2016

Abstract2‐Aminobenzo(f)quinoline (I) and glycerol (II) undergo modified Skraup reaction to produce naphtho(2,1‐b)(1,5)naphthyridine (III).
ChemInform Abstract: Synthesis, Structural and Conformational Study of Several Acyl Derivatives of 9‐(2′‐Hydroxyethyl)‐9‐azabicyclo(3.3.1)nonan‐3α(and β)‐ols (III) and (IV).
Authors: LORENTE A. , IRIEPA I. , GALVEZ E. 
Published: May 2016

AbstractThe β‐ (III) and α‐isomers (IV) are prepared as given in the scheme ((IVa), (IVc), (IVd) yield 70‐89%) except (IVb) which is obtained from the respective diol + R‐CO‐Cl in CH2Cl2 (yield 33%).
ChemInform Abstract: Synthesis of New Chiral Auxiliaries Derived from L‐Threitol.
Authors: GRAS J.‐L. , PELLISSIER H. , NOUGUIER R. 
Published: May 2016

AbstractAcetylation of threitol diformal (I) with acetic anhydride (II) in the presence of sulfuric acid yields the di‐O‐acetylbis(acetoxymethyl)threitol (III) which is deprotected and cyclized, producing the 2,3‐O‐methylenethreitol (IV).
ChemInform Abstract: Nucleophilic Substitution of 6H‐1,2‐Oxazines via Azapyrylium Ions.
Authors: ZIMMER R. , REISSIG H.‐U. 
Published: May 2016

Abstract6‐Methoxy‐6H‐1,2‐oxazines (I) react with nucleophiles such as triethylsilane, allyltrimethylsilane (III), the silyl enol ethers (V), or the electron rich (het)arenes (X) in the presence of Lewis acids to form 6‐substituted 6H‐1,2‐oxazines via oxazinium ions.
ChemInform Abstract: New Porphyrinoids. Part 9. Synthesis of a Bisvinylogous Porphyrin with a (22)Annulene System.
Authors: GOSMANN M. , VOGT A. , FRANCK B. 
Published: May 2016

AbstractThe twofold vinylogously enlarged porphyrin (III) is prepared by vinylogous bisformylation of (I) to give (II) and subsequent acid‐catalyzed condensation of these compounds.
ChemInform Abstract: A Novel Rearrangement Forming 4,5,6,11‐Tetrahydrobenzo(6,7)cycloocta‐(1,2‐b)thiophen‐6,11‐imines.
Authors: ROBINSON R. P. , DONAHUE K. M. , SACCOMANO N. A. 
Published: May 2016

AbstractThe crude carbamates (V), prepared as shown in the reaction scheme, are treated with hydrobromic acid to perform a rearrangement, yielding the tetracyclic carbamates (VII) via the spiro compounds (VI).
ChemInform Abstract: 2‐Alkylperhydro‐1,3,2‐dioxazepines.
Authors: SHTAMBURG V. G. , RUDCHENKO V. F. , CHERVIN I. I. , GRINEV V. M. , SKOBELEV O. L. , KOSTYANOVSKII R. G. 
Published: May 2016

AbstractThe (dimethoxyamino)isobutyrate (I) and the (chloromethoxyamino)pivalate (IV) are coupled with 1,4‐butanediol (II) to give the 2‐(methoxycarbonylalkyl)perhydrodioxazepines (III).
ChemInform Abstract: Derivatives of Borole. Part 15. Borole Dianions: Metalation of 1‐(Dialkylamino)‐2,5‐dihydro‐1H‐boroles and the Structure of Li2(C4H4BNEt2)·TMEDA.
Authors: HERBERICH G. E. , HOSTALEK M. , LAVEN R. , BOESE R. 
Published: May 2016

AbstractThe metalation of the boroles (I) with the sterically demanding lithium 2,2,6,6‐tetramethylpiperidide (II) occurs with formation of powdery dilithium borolediides (III).
ChemInform Abstract: Reactivity of Ethyl‐ and 1‐Phenylethylphosphonic Acid.
Authors: KARIMOV K. R. , SHAKHIDOYATOV KH. M. , ALOVITDINOV A. B. 
Published: May 2016

AbstractIn the presence of catalytic amounts of triethylammonium hydroxide, the alkylation of the phosphonic acids (I) with the primary alkyl halides (II) leads to the formation of the dialkyl phosphonates (III).
ChemInform Abstract: (2 + 4)‐Cycloadducts of Labile Diphosphenes and Phosphaarsenes of the Type RE=E′R′ (E,E′: P, As; R,R′: Me, tBu, Ph, CF3).
Authors: GROBE J. , LE VAN D. , MARTIN S. 
Published: May 2016

AbstractThe unsymmetrically substituted title diphosphenes and phosphaarsenes are generated in situ by the novel method shown in the scheme and trapped as the (2 + 4) cycloadducts (IV).
ChemInform Abstract: 3‐Hydroxy‐λ3‐phosphinine ‐ 2‐Hydroxy‐λ3‐phosphinine.
Authors: MAERKL G. + , KALLMUENZER A. + 
Published: May 2016

AbstractThe siloxy dienes (II), (IV), and (VI) are subjected to hetero‐Diels‐Alder reaction with the silylphosphaethenes (I).
ChemInform Abstract: Synthesis and Spectroscopic Studies on Transition‐Metal Nitrates and Thiocyanates of a Chelating Imidazole‐Thioether Ligand. The Crystal Structures of Diaquobis(5‐methyl‐4‐(ethyl‐mercaptomethyl)imidazole)nickel(II) Dinitrate, Diaquobis(5‐methyl‐4‐(ethyl‐mercaptomethyl)imidazole)copper(II) Dinitrate and Bis(5‐methyl‐4‐(ethyl‐mercaptomethyl)imidazole)bis(thiocyanato‐N)cobalt(II).
Authors: BOUWMAN E. , WESTHEIDE C. E. , DRIESSEN W. L. , REEDIJK J. 
Published: May 2016

AbstractThe novel ligand, prepared from ethanethiol and the corresponding 4‐hydroxy‐imidazole derivative with 73% yield, reacts with hydrated metal nitrates in EtOH to give (I).
ChemInform Abstract: One‐Electron Transfer Processes in the Reaction of Elemental Gallium, Indium, and Tin with Tetrahalogeno‐ortho‐benzoquinones.
Authors: ANNAN T. A. , TUCK D. G. 
Published: May 2016

AbstractThe reaction of metallic tin with tetrachloro‐o‐benzoquinone (I) leads to Sn(IV) compounds, whereas in the case of In and Ga in analogous reactions derivatives of M(III) or M(II), (XII), are obtained.
ChemInform Abstract: Preparation of Copper(II) and Nickel(II) Complexes of 2‐(2′‐Acetoxyethylamino)ethylamine.
Authors: NOLAN K. B. , RAHOO H. 
Published: May 2016

AbstractAddition of the Cu(II) halides (I) to the dihydrochloride (II) of the title ligand results in the formation of the complex salts (III).
ChemInform Abstract: 2,4,6‐Trinitrophenylgold(I) Complexes. X‐Ray Crystal Structures of (Au(SbPh3)4)(Au(C6H2(NO2)3‐2,4,6)2)·Et2O and (Au(C6H2(NO2)3‐2,4,6)(dmphen)) (dmphen: 2,9‐dimethyl‐1,10‐phenanthroline).
Authors: VICENTE J. , ARCAS A. , JONES P. G. , LAUTNER J. 
Published: May 2016

AbstractThe 2:1 molar reaction of the dichloroaurate (I) with diaryl‐Hg (II) in the presence of excess of NMe4Cl leads to the chloro(aryl)aurate (III).
ChemInform Abstract: Cyclometalation Reactions of 6‐Phenyl‐2,2′‐bipyridine: A Potential C,N,N‐Donor Analogue of 2,2′:6′,2′′‐Terpyridine. Crystal and Molecular Structure of Dichlorobis(6‐phenyl‐2,2′‐bipyridine)ruthenium(II).
Authors: CONSTABLE E. C. , HENNEY R. P. G. , LEESE T. A. , TOCHER D. A. 
Published: May 2016

AbstractThe ligand (I), which may be regarded as a potential C,N,N donor analogue of terpyridine, bonds to transition metals in a variety of manners as demonstrated in the scheme.
ChemInform Abstract: Electrophilic Attack on a Cluster‐Coordinated Nitrosyl Ligand: Crystal and Molecular Structure of Ru3(NOCH3)(CO)10 and Observation of an O‐H to M‐H Tautomerization.
Authors: STEVENS R. E. , GUETTLER R. D. , GLADFELTER W. L. 
Published: May 2016

AbstractO‐Methylation of the μ2‐NO ligand to give (III) occurs in the reaction of the anionic cluster (I) with (II).