bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Structural Studies of Organoboron Compounds. Part 33. 4,4‐Dimethyl‐2,2‐diphenyl‐1,3‐dioxa‐4‐azonia‐2‐boratacyclohexane and 3,3‐Dimethyl‐2‐phenoxy‐2‐phenyl‐1‐oxa‐3‐azonia‐2‐boratacyclopentane.
Authors: EBELING E. , KLIEGEL W. , RETTIG S. J. , TROTTER J. 
Published: May 2016

AbstractThe intramolecular hydrogen bond in (II) can be replaced by the diphenylborenium ion giving the six‐membered chelate compound (IV).
ChemInform Abstract: Synthesis of Some Novel 9‐Organo‐Substituted o‐ and m‐Carboranes.
Authors: KOVREDOV A. I. , SHAUGUMBEKOVA ZH. S. , PETROVSKII P. V. , ZAKHARKIN L. I. 
Published: May 2016

Abstract9‐Iodo‐o‐carborane (I) is coupled with Grignard compounds, prepared directly or via the lithium derivatives, to give the 9‐substituted o‐carboranes (III).
ChemInform Abstract: Reactive π Complexes of Electron‐Rich Transition‐Metals. Part 9. Polycyclic Polyphosphorus Hydrocarbons.
Authors: HU D. , SCHAEUFELE H. + , PRITZKOW H. , ZENNECK U. 
Published: May 2016

AbstractOn the reaction of an great excess tert.‐butylphosphaacetylene with (η4‐1‐methylnaphthalene)(η6‐toluene)‐Fe in toluene, aside of known complexes also the compounds (I)‐(IV) can be isolated.
ChemInform Abstract: Synthesis of Selenilimines from Diphenylselenium Dimethylate and Their Mass Spectroscopic Investigation.
Authors: NADDAKA V. I. , KNYAZEV A. P. , AVANESYAN K. V. 
Published: May 2016

AbstractReaction of diphenylselenium dimethylate, obtained in situ from diphenylselenium dichloride (I), with the amides (II) produces the selenilimines (III).
ChemInform Abstract: Reactivity of Ceric Ammonium Nitrate with Sodium Cyclopentadiene. X‐Ray Crystal Structure of Ce(NO3)3(DME)2.
Authors: GRADEFF P. S. , YUNLU K. , DEMING T. J. , OLOFSON J. M. , ZILLER J. W. , EVANS W. J. 
Published: May 2016

AbstractThe reactions of ceric ammonium nitrate (I) with sodium cyclopentadienide (II) in THF (III) are examined.
ChemInform Abstract: Isodicyclopentadienes and Related Molecules. Part 46. Stereoselective Formation from a (1S,5S)‐(‐)‐Verbenone‐Derived Cyclopentadiene of Dimeric and Mixed Titanium and Zirconium Dichloride Complexes.
Authors: MORIARTY K. J. , ROGERS R. D. , PAQUETTE L. A. 
Published: May 2016

AbstractThe optically active (1R,8R)‐cyclopentadienide compound (I), synthesized from (1S,5S)‐(‐)‐verbenone, undergoes reaction with TiCl3·3 THF (II), ZrCl4 (III), (η5‐C5H5)TiCl3 (V), and (η5‐C5Me5)ZrCl3 (VII) to form a single complex in each case, viz.
ChemInform Abstract: Synthesis, Structure, and Bonding of Mononuclear Aryloxide Derivatives of Niobium in Oxidation States +5, +3, +2, and +1.
Authors: COFFINDAFFER T. W. , STEFFY B. D. , ROTHWELL I. P. , FOLTING K. , HUFFMAN J. C. , STREIB W. E. 
Published: May 2016

AbstractThe reduction of the Nb(V) aryloxides (I) in the presence of the diphosphine (II) results in the formation of the bis(aryloxy)‐Nb(II) products (IIIa) (space group P1, Z=2) and (IIIb).
ChemInform Abstract: Synthesis, Structure, and Reactivity of Stable Alkyl and Aryl Iodide Complexes of the Formula ((η5‐C5H5)Re(NO)(PPh3)(IR))+BF‐ 4.
Authors: WINTER C. H. , VEAL W. R. , GARNER C. M. , ARIF A. M. , GLADYSZ J. A. 
Published: May 2016

AbstractThe reaction of the methyl complex (I) with HBF4 and then with the iodides (II) represents a facile synthetic route to the title complexes (III).
ChemInform Abstract: Organometallic Lewis Acids. Part 38. Monomeric and Bridged Pentacarbonyldiphosphanerhenium Complexes and Their Reactions with Nucleophiles.
Authors: STEIL P. , NAGEL U. , BECK W. 
Published: May 2016

AbstractThe rhenium complex (I) reacts with the diphosphanes (II), yielding the complexes (III) or (IV) depending on the ratio of the reactants.
ChemInform Abstract: Structure and Properties of the Hydride‐Containing Cluster Ion Pt(H)(PPh3)(AuPPh3)2+ 7.
Authors: KANTERS R. P. F. , BOUR J. J. , SCHLEBOS P. P. J. , BOSMAN W. P. , BEHM H. , STEGGERDA J. J. , ITO L. N. , PIGNOLET L. H. 
Published: May 2016

AbstractThe title cluster ion can be prepared by reaction of H2 (III) with the Au(I) compound (I) and the Pt(0) complex (II) (ratio 6:1) as its nitrate (IV) as well as by reaction of (Pt(AuPPh3)8)2+ with PPh3 and an acid.
ChemInform Abstract: Chiral Lactols. Part 8. A Way for the Asymmetric Induction in the Formation of Sugars.
Authors: NOE C. R. , KNOLLMUELLER M. + , ETTMAYER P. 
Published: May 2016

AbstractThe glycol aldehyde (I), which bears an enantiomerically pure acetal‐type protective group exhibiting the configuration of an α‐L‐sugar at the acetal center, is subjected to aldolization under basic conditions.
ChemInform Abstract: Synthesis of Galanthamine and Related Alkaloids ‐ New Approaches. Part 1.
Authors: VLAHOV R. , KRIKORIAN D. , SPASSOV G. , CHINOVA M. , VLAHOV I. , PARUSHEV S. , SNATZKE G. , ERNST L. , KIESLICH K. , ABRAHAM W.‐R. , SHELDRICK W. S. 
Published: May 2016

AbstractThe dienone (IV), which is synthesized by an improved procedure using the Pmb protecting group, is transformed to the (‐)‐epi‐galanthamine derivative (V) (space group P21/c with Z=4) and to the galanthamine derivative (VI) (space group P212121 with Z=4).
ChemInform Abstract: Stereoselective Nucleophilic Additions to the Carbon‐Nitrogen Double Bond. Part 2. Chiral Iminium Ions Derived from “Second Generation” Chiral Amines.
Authors: POLNIASZEK R. P. , KAUFMAN C. R. 
Published: May 2016

AbstractThe "second generation" chiral amines (III) are ‐ as shown for (IIIb) ‐ incorporated into chiral iminium ions of type (VII).
ChemInform Abstract: Synthesis of 10,10‐Difluorothromboxane A2, a Potent and Chemically Stable Thromboxane Agonist.
Authors: FRIED J. , JOHN V. , SZWEDO M. J. JUN. , CHEN C.‐K. , O'YANG C. , MORINELLI T. A. , OKWU A. K. , HALUSHKA P. V. 
Published: May 2016

AbstractSelective enzymatic hydrolysis of the diacetate (±)‐(I) leads to the enantiomerically pure monoacetate (II) which is transformed to the title compound (VII) by known methods.
ChemInform Abstract: Synthetic Studies on 1,2‐Dehydro‐1‐carbacephem Compounds.
Authors: SAITO H. , MATSUSHIMA H. , SHIRAKI C. , HIRATA T. 
Published: May 2016

AbstractReaction of the diethoxyphosphorylglycinate (I) with the aldehyde (II) yields the enamine (III).
ChemInform Abstract: Porphyrin‐Quinone Compounds as Synthetic Models of the Reaction Center of Photosynthesis
Authors: BOROVKOV V. V. , EVSTIGNEEVA R. P. , STREKOVA L. N. , FILIPPOVICH E. I. , KHAIRUTDINOV R. F. 
Published: May 2016

AbstractReview: (113 refs.
ChemInform Abstract: Copper Disodium Tetrahydroxide.
Authors: RIOU A. , CUDENNEC Y. , GERAULT Y. 
Published: May 2016

AbstractCuNa2(OH)4 (prepared from CuO, NaOH, and H2O at room temp.) crystallizes in the orthorhombic space group Pna21 with Z=4.
ChemInform Abstract: The Structures of Thallous Perbromate at 294 and 169 K.
Authors: GALLUCCI J. C. , GERKIN R. E. , REPPART W. J. 
Published: May 2016

AbstractAt both temp., TlBrO4 crystallizes in the BaSO4‐type structure, orthorhombic, Pnma, Z=4.
ChemInform Abstract: Stabilization of Strontium Analogues of Barium Yttrium Cuprate Perovskites via Chemical Substitution.
Authors: SUNSHINE S. A. , SCHNEEMEYER L. F. , SIEGRIST T. , DOUGLASS D. C. , WASZCZAK J. V. , CAVA R. J. , GYORGY E. M. , MURPHY D. W. 
Published: May 2016

AbstractCrystals of Sr2YCu3‐xMxOy, M: Al, Pb, Fe, and Co, analogues of the Ba2YCu3O7 superconductor (Tc = 92 K), are grown from CuO‐rich melts containing appropriate impurities or from lead oxide based melts.
ChemInform Abstract: Effect of Cobalt on Fibrous Nickel Hydroxide Electrodes.
Authors: LAW H. H. , SAPJETA J. 
Published: May 2016

AbstractIt is found that the incorporation of at least 5 mol% cobalt hydroxide into fibrous nickel hydroxide electrodes changes the mechanical properties of the active material, i.e., the material becomes less brittle and less sensitive to the stress incurred during cycling.
ChemInform Abstract: Spectroscopic Characterization and Photochemical Behavior of a Titanium Hydroxyperoxo Compound.
Authors: MUNUERA G. , GONZALEZ‐ELIPE A. R. , FERNANDEZ A. , MALET P. , ESPINOS J. P. 
Published: May 2016

AbstractStructure and thermal behavior of a titanium hydroxyperoxide (referred to as TiO(O2)), prepared by reaction of TiCl4 with H2O2, are examined using TG‐MS, XRD, and TPD whereas XPS, IR, ESR, and UV‐VIS reflectance spectroscopy are applied to characterize the types of peroxo species present in the oxide.
ChemInform Abstract: Growth of Polycrystalline CaF2 via Low‐Temperature Organometallic Chemical Vapor Deposition.
Authors: BENAC M. J. , COWLEY A. H. , JONES R. A. , TASCH A. F. JUN. 
Published: May 2016

AbstractLow temp. CVD of polycrystalline CaF2 is achieved at 150 °C using bis(pentamethylcyclopentadienyl)calcium (Cp2Ca) as calcium source and SiF4 or NF3 as fluorine source.
ChemInform Abstract: Homolytic Cyclization of O‐Alkenyl Se‐Phenyl Selenocarbonates. Synthesis of Lactones.
Authors: BACHI M. D. , BOSCH E. 
Published: May 2016

AbstractTreatment of the unsaturated selenocarbonates (I) and (IV) with tributylstannane and AIBN results in cyclization, forming the lactones (II) and (V), together with unsaturated formates in two cases as outlined in the reaction scheme.
ChemInform Abstract: Experimental and Theoretical Studies of the Gas‐Phase Protonation of Vinyl Ethers, Vinyl Sulfides, and Vinyl Selenides.
Authors: OESAPAY K. + , DELHALLE J. , NSUNDA K. M. , ROLLI E. , HOURIET R. , HEVESI L. 
Published: May 2016

AbstractProtonation occurs at the β‐carbon of (I)‐(III).
ChemInform Abstract: Stereoselective syn‐Reduction of (R)‐4‐Acyl‐2,2‐dimethyl‐1,3‐dioxolanes with Metal Hydride Reagents.
Authors: CHIKASHITA H. , NIKAYA T. , UEMURA H. , ITOH K. 
Published: May 2016

AbstractL‐Selectride and LiAlH4 are found to be efficient reducing agents for the selective preparation of the syn‐glycerol derivatives (II) or (IV) from the dioxolanes (I) or (III).
ChemInform Abstract: Halogenation Using Quaternary Ammonium Polyhalides. Part 19. Aromatic Chlorination of Arenes with Benzyltrimethylammonium Tetrachloroiodate.
Authors: KAJIGAESHI S. , UEDA Y. , FUJISAKI S. , KAKINAMI T. 
Published: May 2016

AbstractThe reaction of arenes such as those depicted in the scheme with a calculated amount of benzyltrimethylammonium tetrachloroiodate in AcOH gives chlorosubstituted arenes in fairly good yields as exemplified in the scheme.
ChemInform Abstract: Reaction of Grignard Reagents with 1,2,4‐Trichloro‐2‐butene.
Authors: MKRTCHYAN A. M. , GASPARYAN S. M. , SARKISYAN V. YU. , MARTIROSYAN Z. A. , VOSKANYAN E. S. 
Published: May 2016

AbstractThe reaction between the easily available title compound (I) and some Grignard reagents (II) is investigated with the aim to work out a reliable and simple procedure for the preparation of various chloroalkenes.
ChemInform Abstract: Reaction of Phenol with 3‐Methylenebicyclo(3.3.1)nonan‐7‐one in the Presence of Aluminum Diphenyldithiophosphate.
Authors: KOZLIKOVSKII YA. B. , KOSHCHII V. A. , RODIONOV V. N. , YURCHENKO A. G. , OLIFIROV D. I. 
Published: May 2016

AbstractThe reaction between the title compounds (I) and (II), which proceeds only in the presence of aluminum diphenyldithiophosphate, is investigated between 110 and 160 °C. The molar ratios chosen for (I):(II):aluminum compound are 3‐1:1:0.5‐1.2.
ChemInform Abstract: 9‐Acridinylthioacetic Acid Esters and Amides.
Authors: MARTYNOVSKII A. A. , OMEL'YANCHIK L. A. , PANASENKO A. I. , KLYUEV N. A. , PANASENKO T. V. 
Published: May 2016

AbstractThe acridinethiones (I) are coupled with the bromoacetates (II) to give the 9‐acridinylthioacetates (III) of which (IIIa) and (IIIb) are transformed into their hydrochlorides (IVa) and (IVb), the amides (VIa) and (VIb), and acridone (VII).
ChemInform Abstract: Stereospecific syn‐Acylamidation of Olefins.
Authors: GRIDNEV I. D. , BUEVICH A. V. , SERGEYEV N. M. , BALENKOVA E. S. 
Published: May 2016

Abstract1‐Methylcyclopentene (I) reacts with acetyl tetrafluoroborate (II) and acetonitril (III) to form the fused 1,3‐oxazine derivative (IV), together with the acetylcyclopentene (V).
ChemInform Abstract: Anionic‐Initiated Coupling of Tungsten Carbene Complexes: Synthesis of the First (μ‐Tris(carbene))trimetallic Complex.
Authors: MACOMBER D. W. , HUNG M.‐H. 
Published: May 2016

AbstractThe sodium alkoxide (I) reacts with the pentacarbonyl carbene complex (II) to yield a mixture of the coupling products (IIIa), (IIIb), (IVa), and (IVb).
ChemInform Abstract: Bis(2,2′‐bipyridine)ruthenium(II)‐Hexacyanochromate(III) Chromophore‐Luminophore Complexes. Intramolecular Energy Transfer, Excited‐State Intervalence Transfer, and Doublet‐Doublet Annihilation.
Authors: BIGNOZZI C. A. , INDELLI M. T. , SCANDOLA F. 
Published: May 2016

AbstractThe photophysical behavior of the binuclear and trinuclear bimetallic complexes (I) and (II) is studied.
ChemInform Abstract: Isolation, Structure, and Magnetic Properties of a Novel Mononuclear Rhodium(II) Complex.
Authors: DUNBAR K. R. , HAEFNER S. C. , PENCE L. E. 
Published: May 2016

AbstractThe pseudo‐octahedral Rh(II) monomer (III) is obtained according to the scheme and characterized by X‐ray structure analysis (space group Pbcn, Z=4), spectroscopic (1H NMR, electronic, EPR) and magnetic techniques.
ChemInform Abstract: Syntheses of cis‐Dichlorodiammineplatinum Analogs Having Steroidal Hormones Bound to the Metal Atom via Malonato Bridges.
Authors: GANDOLFI O. , APFELBAUM H. C. , MIGRON Y. , BLUM J. 
Published: May 2016

AbstractIn search for neutral, chemically stable, antitumor agents with target specificity, twenty‐seven steroidal Pt(II) malonate conjugates such as (III) are prepared as outlined in the scheme.
ChemInform Abstract: Ligand‐Assisted Hydride Delivery: An Expeditious Stereoselective Total Synthesis of (.+‐.)‐Norsedamine and Its Pyrrolidino Analog.
Authors: TIREL P.‐J. , VAULTIER M. , CARRIE R. 
Published: May 2016

AbstractThe cyclic imines (I) are lithiated and then coupled with benzaldehyde (III) to produce the lithium alkoxides (IV) which are selectively hydrogenated, forming racemic norsedamine (±)‐(Vb) and its pyrrolidino analogue (Va).
ChemInform Abstract: Histamine Analogues. Part 32. Synthesis and Pharmacology of Sopromidine, a Potent and Stereoselective Isomer of the Achiral H2‐Agonist Impromidine.
Authors: ELZ S. , GERHARD G. , SCHUNACK W. 
Published: May 2016

AbstractThe methylhistamine derivatives (VI), chiral analogues of impromidine (VII), display high stereoselectivity ((R):(S) > 1000) towards the atrial H2‐receptor of the guinea pig.
ChemInform Abstract: InP Etch Pit Morphologies Revealed by Novel HCl‐Based Etchants.
Authors: HUO D. T. C. , WYNN J. D. , YAN M. F. , WILT D. P. 
Published: May 2016

AbstractThe new dislocation etchant for InP, consisting of HBr/H2O2/HCl/H2O in the volume ratio 20:2:20:20, is used to etch (001) and (111)P oriented wafers (2 min, room temp.).
ChemInform Abstract: Preparation, Structure and Photoelectric Properties of Glasses in the System Sb‐S.
Authors: SHTETS P. P. , BLETSKAN D. I. , TURYANITSA I. D. , BODNAR M. P. , RUBISH V. M. 
Published: May 2016

AbstractIn the title system glass formation is observed between 55 and 65 at.% of S. The samples are prepared from the elements.
ChemInform Abstract: Characterization of Electrodeposited Molybdenum Black Surface Coatings.
Authors: FARMAKIS K. S. , POULIOS I. G. 
Published: May 2016

AbstractThin coatings (3 μm) of Mo‐black are electrodeposited on Al surfaces from a solution containing (NH4)6Mo7O24·4 H2O and NiSO4·6 H2O. The chemical composition of the quasi‐amorphous, semiconducting material, forming a Schottky barrier at the coating‐metal interface, is 90 wt.% MoO2·2 H2O + 10 wt.% Ni(OH)2.
ChemInform Abstract: MnFe and NiFe Thin Films and Magnetic Exchange Bilayers.
Authors: RUSSAK M. A. , ROSSNAGEL S. M. , COHEN S. L. , MCGUIRE T. R. , SCILLA G. J. , JAHNES C. V. , BAKER J. M. , CUOMO J. J. , HWANG C. 
Published: May 2016

AbstractIon beam sputter deposition of Permalloy (Ni80Fe20) is used in combination with dc magnetron sputtering of MnFe to produce MnFe/NiFe bilayer exchange structures with high exchange fields and low coercivity (Hc).
ChemInform Abstract: Hydrous Silicon(IV)‐Titanium(IV) Oxide Ion Exchanger. Part 1. A Method of Synthesis and Some Properties.
Authors: YAMAZAKI H. , KANNO Y. , INOUE Y. 
Published: May 2016

AbstractFrom a detailed investigation of the dependence of the ion exchange properties on the composition of the material and on the precipitation conditions, a reproducible synthetic procedure for the title ion exchanger starting from TiCl4 and Na2SiO3 solutions is developed.
ChemInform Abstract: The Iridium Complex Catalyzed Reduction of Carbon Dioxide to Methoxide by Alkylsilanes.
Authors: EISENSCHMID T. C. , EISENBERG R. 
Published: May 2016

AbstractCatalyzed by the Ir(I) complex, CO2 can be reduced under very mild conditions to the methoxide level by alkylsilanes such as (I), Me2SiH2 and Et2SiH2.
ChemInform Abstract: Synthesis and Prototropic Isomerization of 1‐Nitrophenyl‐2‐acylpyrrole.
Authors: PINA M. DEL C. , BUDYLIN V. A. , RODRIGUEZ M. , BUNDEL' YU. G. 
Published: May 2016

AbstractAcylation of the nitrophenylpyrroles (I) yields the 2‐acylated derivatives (III) or mixtures of (III) with the 3‐acylpyrroles (IV).
ChemInform Abstract: 2‐Chloro‐3H‐indol‐3‐one and Its Reactions with Nucleophiles.
Authors: KATRITZKY A. R. , FAN W.‐Q. , KOZIOL A. E. , PALENIK G. J. 
Published: May 2016

AbstractIt is shown that formula (I), the title compound, is the correct structure of the chloroisatin produced from isatin and PCl5.
ChemInform Abstract: Enantioselective Synthesis of (1S,3S,5S)‐ and (1R,3S,5R)‐2‐Azabicyclo‐(3.3.0)octane‐3‐carboxylic Acid Starting from L‐Serine.
Authors: URBACH H. , HENNING R. 
Published: May 2016

AbstractL‐Serine methyl ester hydrochloride (II) is transformed into the cyclopentenylaminoiodopropionate (VI) which undergoes radical‐promoted cyclization to yield a mixture of the diastereomeric 2‐azabicyclo(3.3.0)octanecarboxylates (VII).
ChemInform Abstract: Synthesis of 4‐Highly‐Branched Imidazole Derivatives via Cine‐Substitution and SRN1 Substitution of 5‐Nitroimidazoles with Anions of Nitroalkanes.
Authors: CROZET M. P. , VANELLE P. , JENTZER O. , BERTRAND M. P. 
Published: May 2016

AbstractThe anion of 2‐nitropropane (II) reacts with the nitroimidazole (I) to yield the nitroalkylimidazole (III) as the main product.
ChemInform Abstract: Synthesis of Nitrogen‐Containing Heterocycles. Part 3. Formation and Structure of New 1,2,4‐Triazole Derivatives.
Authors: MIYAMOTO Y. , YAMAZAKI C. 
Published: May 2016

AbstractTreatment of the hydrazones (I), (IV), (VI) or (XI) (obtained according to literature methods) with hot acetic acid results in formation of the various products shown in the scheme.
ChemInform Abstract: Ring‐Degenerate Rearrangement of 5‐Amino‐4‐iminomethyl‐1,2,3‐triazoles.
Authors: L'ABBE G. , VANDENDRIESSCHE A. 
Published: May 2016

AbstractThe triazole (I) undergoes a thermal conversion leading to the amidino‐substituted triazole (IV) via the iminomethyltriazole (III).
ChemInform Abstract: Simple Synthesis of Dimethyl 2‐Pyridone‐4,5‐dicarboxylate Derivatives.
Authors: KAWAHARA N. , SHIMAMORI T. , ITOH T. , TAKAYANAGI H. , OGURA H. 
Published: May 2016

AbstractTreatment of the readily available isocrotonate derivatives (I) with base yields the pyridone‐tricarboxylates (II) along with the heterocycle (III).
ChemInform Abstract: Diels‐Alder Reactions of 3,6‐Diphenyl‐1,2,4,5‐tetrazine and 3,6‐Di(2‐pyridyl)‐1,2,4,5‐tetrazine with Some 1‐Morpholinocycloalkenes.
Authors: ATFAH M. A. 
Published: May 2016

AbstractThe reactions of the tetrazines (I) or (IV) with the enamines (II) derived from cyclic ketones and morpholine leads to a series of pyridazines (III) or (VI), most of which are new.
ChemInform Abstract: An Expeditious Synthesis of 2‐Dialkylamino‐4‐chloropyrimidines from Silylated Primary Enamines and Phosgeniminium Salts.
Authors: GUILLOT N. , JANOUSEK Z. , VIEHE H. G. 
Published: May 2016

AbstractConsecutive reactions of the aromatic nitriles (I) with the Grignard compounds (II) and trimethylsilyl chloride (III) yield a mixture of the tautomers (IV) and (V) which are coupled with the phosgeniminium chloride (VI), producing the cyanines (VII).
ChemInform Abstract: Synthesis and Reactions of Isoquinoline Derivatives. Part 5. Synthesis and Reactions of 3‐Chloroisoquinoline‐4‐carboxylic Acids.
Authors: BARTMANN W. , KONZ E. , RUEGER W. + 
Published: May 2016

AbstractOxidation of the isoquinoline‐4‐carboxaldehyde (I) yields the carboxylic acid (II) which is converted into the carboxamides (IV).
ChemInform Abstract: Oxidative Cyclization of 1,3,4‐Oxadiazol‐2‐ylmethyl‐N‐aryldithiocarbamates to 1,3,4‐Oxadiazolo(3,2‐d) (1,3,4)‐dithia‐ and ‐thiadiazines.
Authors: SINGH H. , DWIVEDI R. , YADAV L. D. S. 
Published: May 2016

AbstractThe products (III), (IV) and (V) (6 examples respectively) are screened for their antifungal activity.
ChemInform Abstract: Synthesis and Pharmacological Activity of a Pyrido(3′,4′:5,4)pyrrolo‐(1,2‐c)(1,4)benzodiazepine‐3,10‐dione, a New Benzodiazepine‐β‐carboline Type Hybrid Molecule.
Authors: DODD R. H. , DOISY X. , POTIER P. , POTIER M.‐C. , ROSSIER J. 
Published: May 2016

Abstract2,4‐Lutidine (I) is nitrated to give a mixture of the isomeric dimethylnitropyridines (III) and (IV).
ChemInform Abstract: Three‐, Four‐, and Five‐Membered Rings from Disilenes.
Authors: WEST R. , GILLETTE G. R. , YOKELSON H. B. , MILLEVOLTE A. J. 
Published: May 2016

AbstractReaction of tetraaryldisilenes such as (I) or (VIII) with various reagents results in the formation of three‐, four‐, and five‐membered rings containing two silicon atoms.
ChemInform Abstract: Metal‐Templated Synthesis of Macrocyclic (Triphosphine)molybdenum Complexes.
Authors: DIEL B. N. , BRANDT P. F. , HALTIWANGER R. C. , HACKNEY M. L. J. , NORMAN A. D. 
Published: May 2016

AbstractThe fac‐tris(phosphine)‐Mo complexes (III) and the cis‐bis(phosphine)‐Mo complexes (V) are synthesized according to the scheme.
ChemInform Abstract: Redox Reactions of the Dirhenium(II) Complexes Re2X4(dppm)2 (X: Cl, Br; dppm: Ph2PCH2PPh2). The Reductive Coupling of Nitriles with Retention of a Metal‐Metal‐Bonded Dirhenium Unit.
Authors: ESJORNSON D. , DERRINGER D. R. , FANWICK P. E. , WALTON R. A. 
Published: May 2016

AbstractDirhenium(II) complexes such as (I) react with acetonitrile (II) to give the paramagnetic compounds (III), containing the coupling product of two acetonitriles as a new ligand.
ChemInform Abstract: Terpenoids. Part 88. Synthesis of 1,1‐Dimethyl‐7‐isobutyryltetralin, and Its Conversion into 7‐tert.‐Butyl‐1,1‐dimethyltetralin, a Rearrangement Product of 10‐Methylenelongibornane.
Authors: SUDALAI A. , RAO G. S. K. 
Published: May 2016

AbstractSince 1,1‐dimethyltetralins are, inter alia, of interest in the preparation of musk odorants, the title compound (V) (a musk odorant class of compound) is synthesized.
ChemInform Abstract: Synthesis and Chiroptical Properties of 5α‐Cholest‐2‐eno(2,3‐b)pyrazine Derivatives.
Authors: HAJOS G. , SNATZKE G. 
Published: May 2016

AbstractThe cyclocondensation reaction of 5α‐cholestane‐2,3‐dione (I) with glycineamide hydrochloride (II) yields the cholestenopyrazinone (III) which reacts with phenylphosphonic acid dichloride to give the chloropyrazine (IV).
ChemInform Abstract: Reactive Ion Etching of Indium‐Tin‐Oxide Films.
Authors: CALAHORRA Z. , MINAMI E. , WHITE R. M. , MULLER R. S. 
Published: May 2016

AbstractIt is demonstrated that reactive ion etching of indium‐tin‐oxide films using HI as etchant results in good anisotropy and edge definition.
ChemInform Abstract: A Change of Structure Type in the Oxides BaCoGd2O5 (I), BaCoDy2O5 (II), and BaCoY2O5 (III).
Authors: MEVS H. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractThe title compounds are synthesized for the first time by heating intimate mixtures of Ln2O3 (Ln: Gd, Dy, Y), BaCO3 and Co(OAc)2·4 H2O (1:1:1; 1. 150 °C; 2. 1000 °C, 12 h under N2; 3. 1800 °C, 10 min (CO2 laser)), are investigated by X‐ray analyses.
ChemInform Abstract: The Semiconductor‐Metal Transition in Pyrochlores of the Systems Ln2‐xCuxRu2O7‐z (Ln: Pr, Sm, Eu, Gd, Dy).
Authors: MAYER‐VON KUERTHY G. + , WISCHERT W. , KEMMLER‐SACK S. 
Published: May 2016

AbstractIn the system Pr2‐xCuxRu2O7‐z homogeneous cubic pyrochlores are formed in the range 0 ≤ x ≤ 0.375.