bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Stereoselective Synthesis of cis‐4‐(Substituted) Monobactams from Ethyl Acetoacetate.
Authors: FERNANDEZ‐RESA P. , HERRANZ R. , CONDE S. , ARRIBAS E. 
Published: May 2016

Abstract4‐Substituted monobactams show enhanced antibacterial activity compared with their 4‐unsubstituted analogues.
ChemInform Abstract: Synthesis of N‐Pyrrolyl Acids.
Authors: NEGRO A. , DIEZ M. T. , ALEMANY M. T. 
Published: May 2016

AbstractCondensation reaction of the amino acid ester hydrochlorides (I) with 2,5‐dimethoxytetrahydrofuran (II) yields the 2‐(1‐pyrrolyl) derivatives (III) which are hydrolyzed to give the acids (IV).
ChemInform Abstract: Substituted 1‐Alkoxy‐2‐methyl‐2H‐isoindoles. Part 1. Reactive o‐Quinonoid Hetarenes with Unsymmetrical Molecular Structure.
Authors: KREHER R. P. , KONRAD M. R. 
Published: May 2016

AbstractStarting with the substituted phthalic acid anhydrides (I), the 2‐methylisoindolin‐1‐ones (IV) are prepared by chemoselective reduction of the intermediate phthalic acid amides (III).
ChemInform Abstract: Vinylogous Carbinolamine Tumor Inhibitors. Part 23. Synthesis and Antileukemic Activity of Bis(((carbamoyl)oxy)methyl)‐Substituted Pyrrolo‐(2,1‐a)isoquinolines, Pyrrolo(1,2‐a)quinolines, Pyrrolo(2,1‐a)isobenzazepines, and Pyrrolo(1,2‐a)benzazepines.
Authors: ANDERSON W. K. , HEIDER A. R. , RAJU N. , YUCHT J. A. 
Published: May 2016

Abstract1,3‐Dipolar cycloaddition of the heterocyclic α‐amino acids (I) with dimethyl acetylenedicarboxylate (II) forms the adducts (III) which are reduced, yielding the diols (IV).
ChemInform Abstract: An Efficient Synthesis of Acetylated Bicyclic (n.3.0)Hydroxypyrroles from Cyclic Lactams via Flash‐Vacuum Pyrolysis of Meldrum′s Acid Derivatives.
Authors: POMMELET J.‐C. , DHIMANE H. , CHUCHE J. , CELERIER J.‐P. , HADDAD M. , LHOMMET G. 
Published: May 2016

AbstractThe Meldrum's acid derivatives (I) are subjected to high temperature gas‐phase pyrolysis and subsequent trapping in methanol at ‐78°C to yield the enol forms (II) of the bicyclic hydroxypyrroles mentioned in the title.
ChemInform Abstract: Conversion of an Unsaturated Metallacycle into a Carbon‐Rich nido‐Metallacarborane. The BH Fragment as a Cluster Functional Group.
Authors: HONG F.‐E. , EIGENBROT C. W. , FEHLNER T. P. 
Published: May 2016

AbstractThe reaction of the metallacycle (I) with monoboranes containing at least one B‐H bond provides a new route to the formation of the nido‐metallacarborane (III).
ChemInform Abstract: Triammineruthenium(II) Complexes Bound with the Novel Bridging Ligand 2,3,5,6‐Tetrakis(2‐pyridyl)pyrazine (tppz).
Authors: RUMINSKI R. , KIPLINGER J. , COCKROFT T. , CHASE C. 
Published: May 2016

AbstractThe reduction of (Ru(NH3)5(OH2)) (CF3SO3)3 with Zn amalgam in refluxing anhydrous ethanol in the presence of appropriate amounts of the title ligand leads to formation of the corresponding mono‐ and binuclear complexes which are isolated as their perchlorate salts (I) and (II) by chromatography.
ChemInform Abstract: IR Spectroscopic Studies on Metal Carbonyl Compounds. Part 24. Observation of the IR Spectrum of an Acylrhodium Tetracarbonyl During the Hydroformylation of Olefins with Rhodium‐Containing Catalyst Precursors.
Authors: GARLAND M. , BOR G. 
Published: May 2016

AbstractDuring the low‐temp.
ChemInform Abstract: New Addition Reaction of Active Ester or Cyclic Ester with Epoxy Compounds Catalyzed by Insoluble Polystyrene‐Bound Quaternary Phosphonium or Ammonium Salts.
Authors: NISHIKUBO T. , SHIINA A. , ISOBE N. 
Published: May 2016

AbstractThe phenoxymethyloxirane (I) is cleaved with S‐phenyl thioacetate (II) in the presence of polymer‐bound phosphonium or ammonium chlorides to produce 1‐phenoxy‐2‐acetoxy‐3‐(phenylthio)propane (III).
ChemInform Abstract: Reductive Phosphorylation of 1,2‐Dithiolanes with Dialkyl Phosphites.
Authors: TAZAKI M. , NAGAHAMA S. , TAKAGI M. 
Published: May 2016

Abstract4,4‐Diethyl‐1,2‐dithiolane (I) is cleaved with the dialkyl(aryl) phosphites (II) in triethylamine, forming the thiophosphates (III).
ChemInform Abstract: Synthesis and Molecular Structure of EtGe(SePh)3: An Unusual Example of Alkylation by LiEt3BH.
Authors: GYSLING H. J. , LUSS H. R. 
Published: May 2016

AbstractThe reaction of GeCl4 (III) with 4 equiv. LiSePh (IV) generated in situ by the reductive cleavage of (I) with (II) yields, in addition to the expected product (V), the compound (VI) resulting from germanium ethylation.
ChemInform Abstract: Reactions of the 17‐Electron Bis(dimethylglyoximato)(triphenylphosphine)rhodium(II) Radical with Cobalt(III) Complexes.
Authors: HOWES K. R. , BAKAC A. , ESPENSON J. H. 
Published: May 2016

AbstractThe title Rh(II) radical, formed by laser flash photolysis of its dimer, is oxidized by a range of Co(III) complexes such as Co(NH3)5X2+, where X is a halogen or pseudohalogen.
ChemInform Abstract: The Tellurium Analogue of the Hydroxide Ion: Syntheses and Structure of (PPh4)TeH.
Authors: HUFFMAN J. C. , HAUSHALTER R. C. 
Published: May 2016

AbstractThe title compound (IV), which is the first example of a well characterized solid containing the TeH‐ anion, can be prepared by treatment of the ethylenediamine extracts of the alloys K2SiTe3 or K2GeTe3 with (PPh4)Br.
ChemInform Abstract: Contributions to the Chemistry of Phosphorus. Part 191. Reaction Behavior of Sodium Tetraphosphinoborate NaB(PH2)4.
Authors: BAUDLER M. , BLOCK C. , BUDZIKIEWICZ H. , MUENSTER H. + 
Published: May 2016

AbstractThe title compound (I) rearranges to the heptaphosphinodiborate (II) in THF at moderate temperatures.
ChemInform Abstract: The Crystal Structures of Chloro Mercury(II) Salts Found for Some CrN3+ 6 Cations and Their Cr‐N Bond‐Ruptured Hydrolysis Products.
Authors: HOUSE D. A. , MCKEE V. , ROBINSON W. T. 
Published: May 2016

AbstractCrystal structures are determined for chloromercury(II) salts formed from (Cr(en)3)Cl3 and isomeric forms of (Cr(dien)2)3+ (dien: NH2‐(CH2)2‐NH‐(CH2)2‐NH2) on crystallization from HCl containing excess HgCl2.
ChemInform Abstract: Reactivity of Polycyclic Aromatic Aryl Radicals.
Authors: CHEN R. H. , KAFAFI S. A. , STEIN S. E. 
Published: May 2016

AbstractResults of theoretical (MNDO) and experimental studies of the properties and reactions of phenyl, 1‐ and 2‐naphthalenyl, and 9‐anthracenyl radicals with toluene and naphthalene (gas phase at 400 and 450 °C) are reported.
ChemInform Abstract: Palladium‐Catalyzed Coupling of N‐Substituted Isocyanide Dichlorides with Alkynyltin Compounds: New Synthesis of Dialkynyl Ketones.
Authors: ITO Y. , INOUYE M. , MURAKAMI M. 
Published: May 2016

AbstractThe isocyanide dichlorides (I) react with the alkynyltin derivatives (II) in the presence of a Pd catalyst to give the disubstitution products (III); (IIIb) and (IIIc) are hydrolyzed, yielding the ketones (IV).
ChemInform Abstract: Amino Ethers of 1,3,3‐Trimethyl‐5‐(phenylmethylene)‐2‐oxabicyclo‐(2.2.2)octane‐6‐hydroxyimine with Antiarrhythmic Activity.
Authors: MARIANI E. , BARGAGNA A. , LONGOBARDI M. , SCHENONE P. , RUSSO S. , FILIPPELLI W. , MOLINARIO L. , MARMO E. 
Published: May 2016

AbstractThe β‐dialkylaminoethyl or γ‐dialkylaminopropyl ethers (V) are prepared by alkylation of the sodium salt of the bicyclic oxime (III) with β‐chloroethyl‐ or γ‐chloropropyldialkylamines (IV).
ChemInform Abstract: Ph4SbI‐Catalyzed Selective Formation of γ‐ and δ‐Lactones from Oxiranes or Oxetanes with Ketenes.
Authors: FUJIWARA M. , IMADA M. , BABA A. , MATSUDA H. 
Published: May 2016

AbstractCycloaddition of the epoxides (I) with the ketenes (II) in the presence of catalytic amounts of tetraphenylstibonium iodide yields the γ‐butyrolactones (III) or the ketene acetals (IV), depending on the substituents of (I).
ChemInform Abstract: Structural and Electronic Consequences of Protonation in (Mn4O6)4+ Cores: pH Dependent Properties of Oxo‐Bridged Manganese Complexes.
Authors: HAGEN K. S. , WESTMORELAND T. D. , SCOTT M. J. , ARMSTRONG W. H. 
Published: May 2016

AbstractThe 1:1:3 molar reaction of Mn(II) triflate (I), the triamine L1 (II), and NEt3, after exposure to atmospheric O2, leads to the novel mixed oxo/hydroxo‐bridged tetranuclear Mn(IV) complex (III) which can be deprotonated to give the oxo‐bridged derivative (IVa).
ChemInform Abstract: 14‐Fluoroanthracyclines. Novel Syntheses and Antitumor Activity.
Authors: MATSUMOTO T. , OHSAKI M. , YAMADA K. , MATSUDA F. , TERASHIMA S. 
Published: May 2016

AbstractBromination of the (‐)‐7‐deoxydaunomycinones (I) with pyridinium bromide perbromide and subsequent Br‐F exchange form the α‐fluoro ketones (II) which are converted into the acetals (IV).
ChemInform Abstract: Construction of Novel Chiral Synthons with Enzymes and Application to Natural Product Synthesis. Part 24. Revisit to Meinwald Rearrangement of Electron‐Deficient Systems.
Authors: NIWAYAMA S. , KOBAYASHI S. , OHNO M. 
Published: May 2016

AbstractEnzymatic hydrolysis of the epoxy diesters (I) yields the monoanions (II) which rearrange to form the bicyclo(3.1.0)hexenes (IV).
ChemInform Abstract: Effect of Temperature on Cyclic Voltammograms During the Electrodeposition of Lead.
Authors: GIRGIS M. , GHALI E. 
Published: May 2016

AbstractElectrodeposition of Pb from a PbCl2/NH4OAc/HOAc solution is performed by linear and cyclic sweep perturbation in the temp. range 25‐75 °C using polycrystalline Pb, Cu, Ag, and C substrates.
ChemInform Abstract: Reactions with Hydroxamoyl Halides: Synthesis of Several Isoxazole, Imidazo(1,2‐a)pyridine, Imidazo(1,2‐a)pyrimidine, and 1,2,4‐Benzotriazine Derivatives.
Authors: ABDELHAMID A. O. , NEGM A. M. , ABDEEN T. M. S. 
Published: May 2016

AbstractBenzofuroylhydroxamoyl chloride (V), synthesized from the bromo ketone (I) via nitrosation of the sulfonium salt (III), undergoes cyclization with the olefinic compounds (VI) or the activated methylene derivatives (VIII), forming the isoxazolines (VII) or the isoxazoles (IX).
ChemInform Abstract: Facile Interconversion of the Isomeric Acid Chlorides Derived from Half Methyl Esters of 3‐Methoxyphthalic Acid.
Authors: GUPTA D. N. , HODGE P. , HURLEY P. N. 
Published: May 2016

AbstractThe isomeric acid chlorides obtained by treating either half ester (I) and (V) with SOCl2 interconvert readily with the acid chloride from (V) being the main isomer.
ChemInform Abstract: Manganese(III)‐Mediated Formylation of Aromatic Compounds in the Presence of Malonic Acid.
Authors: NISHINO H. , TSUNODA K. , KUROSAWA K. 
Published: May 2016

AbstractWhile the known reaction of aromatic compounds with Mn(III) acetate (V) gives mainly acetoxymethylated products (by attack of carboxymethyl radicals), aldehydes such as (II)/(VII) and/or acids such as (III)/(VIII) are obtained in the presence of malonic acid (IV).
ChemInform Abstract: 6‐Chloro‐1,2,4‐triazolo(4,3‐b)pyrido(2,3‐d)((3,2‐d))pyridazines. Synthesis and Structure Determination.
Authors: HASSAN M. A. , FAHMY A. F. M. 
Published: May 2016

AbstractThe dichloropyridopyridazine (II), obtained by chlorination of the dione (I), is coupled with hydrazine hydrate (III) to produce the regioisomeric chlorohydrazinopyridopyridazines (IV) and (V) which are not separated.
ChemInform Abstract: One‐Electron‐Transfer Processes in the Reaction of Tin(II) Halides with Substituted o‐Quinones; Crystal Structure of Bis(3,5‐di‐t‐butylcatecholato)tin‐1,10‐Phenanthroline‐Dimethylformamide (1/1/2).
Authors: ANNAN T. A. , MCGARVEY B. R. , OZAROWSKI A. , TUCK D. G. , CHADHA R. K. 
Published: May 2016

AbstractThe reaction of the quinone (I) with the tin(II) halides (II) in the presence of the diamines (III) gives the adducts (IV), formed by oxidative addition.
ChemInform Abstract: Synthesis and Proton NMR Studies of the Electronic and Magnetic Properties of Low‐Spin Ferric Isocyanide Tetraphenylporphyrin Complexes.
Authors: SIMONNEAUX G. , HINDRE F. , LE PLOUZENNEC M. 
Published: May 2016

AbstractComplexes with MeCN and o‐xylyl isocyanide as axial ligands are prepared similarly to (III).
ChemInform Abstract: Photoelimination of Benzoyl Chloride from Benzoylchlorobis(triphenylphosphine)palladium(II) and ‐platinum(II).
Authors: KUBOTA M. , KEIL R. N. , HALL K. A. 
Published: May 2016

AbstractAs demonstrated in the scheme, photoinduced reductive elimination of carboxylic acid chlorides occurs from trans complexes such as (I) in the presence of PPh3 and CS2.
ChemInform Abstract: IR Spectra and Photochemistry of Isodiazene and Its Deuterated Isotopomers.
Authors: TELES J. H. , MAIER G. , HESS B. A. JUN. , SCHAAD L. J. 
Published: May 2016

AbstractThe H2, HD, and D2 isotopomeric isodiazenes are obtained by the 313‐ or 254‐nm photolysis of the corresponding aminoisocyanates in an argon matrix.
ChemInform Abstract: Stabilization of Cadmium Selenide Molecular Clusters in Zeolite Y: EXAFS and X‐Ray Diffraction Studies.
Authors: MOLLER K. , EDDY M. M. , STUCKY G. D. , HERRON N. , BEIN T. 
Published: May 2016

AbstractSmall ensembles of CdSe are synthesized within the cages of zeolite Y via ion exchange with Cd(NO3)2 and subsequent treatment with H2Se.
ChemInform Abstract: Cadmium Sulfide‐Assisted Photoreduction of Dinitrogen.
Authors: HETTERICH W. , KISCH H. 
Published: May 2016

AbstractIt is shown that unloaded and metal‐loaded CdS powders can assist the photoreduction of N2 to NH3 in the presence of 2,5‐dihydrofuran as reducing agent.
ChemInform Abstract: Effective Transformation of Photocyclization Products of 2‐Alkenoyl‐3‐alkylthio‐1,4‐benzoquinones into 9H‐(1,3)Oxathiolo(4,5‐f) (1)benzopyran‐9‐ones.
Authors: IWAMOTO H. 
Published: May 2016

AbstractSince the photochemical reactions of alkylthio‐1,4‐benzoquinones are largely unknown, the behavior of the derivatives (I) is examined.
ChemInform Abstract: Synthesis and Mesomorphous Properties of cis,trans‐2‐Alkyl‐5‐methyl‐5‐carboxy‐1,3‐dioxanes and Their Derivatives.
Authors: BEZBORODOV V. S. 
Published: May 2016

AbstractThe title compounds (III) and (IV) and their derivatives (VI) and (VII) are prepared.
ChemInform Abstract: Nenitzescu Synthesis of 5‐Hydroxyindoles. Part 3. A Diazaheptalenedione from 3‐Aminocinnamic Ester.
Authors: PALAGHITA M. , RAILEANU D. 
Published: May 2016

AbstractReaction of ethyl 3‐aminocinnamate (I) with p‐benzoquinone (II) in refluxing butanol gives a mixture of the diazaheptalene (III) and the indole derivative (IV).
ChemInform Abstract: Isomerization, Fluorine Exchange, and Stereoselective Synthesis of cis‐ and trans‐F2TePh3Cl: Application of the Coordination Model of Reaction Mechanisms.
Authors: JANZEN A. F. , JANG M. 
Published: May 2016

AbstractStarting with the mer‐compound (V) the trans‐(VIII) and cis‐(XI) title compounds are stereoselectively synthesized via the five‐coordinate cations (VI) and (IX).
ChemInform Abstract: β‐Trifluoromethyldicarbocyanines and δ‐Trifluoromethylmerocyanines.
Authors: PAZENOK S. V. , GERUS I. I. , CHAIKA E. A. , YAGUPOL'SKII L. M. 
Published: May 2016

AbstractDicarbocyanine dyes with a trifluoromethyl group attached to the polymethine chain are hitherto unknown.
ChemInform Abstract: FT‐IR and 2‐D NOE 31P NMR Spectroscopic Studies on Stereochemically Nonrigid, Octahedral Organochromium(0) Complexes.
Authors: ISMAIL A. A. , SAURIOL F. , BUTLER I. S. 
Published: May 2016

AbstractIt is demonstrated for the first time that the favored mechanism of the isomerization of the complexes (I) is an intramolecular rearrangement via trigonal‐prismatic intermediates.
ChemInform Abstract: Magnetic Exchange Interactions in Semiquinone Complexes of Iron. Structural and Magnetic Properties of Tris(3,5‐di‐tert.‐butylsemiquinonato)iron(III) and Tetrakis(3,5‐di‐tert.‐butylsemiquinonato)tetrakis(3,5‐di‐tert.‐butylcatecholato)tetrairon(III).
Authors: BOONE S. R. , PURSER G. H. , CHANG H.‐R. , LOWERY M. D. , HENDRICKSON D. N. , PIERPONT C. G. 
Published: May 2016

AbstractThe complex (III), formed when (I) is used in excess, crystallizes in the space group P21/n with Z=4; the complex (IV) with semiquinone and catecholate ligands in P1, Z=1.
ChemInform Abstract: Intramolecular Dissociative Isomerization and the Presence of Trans Influence in 12‐Sb‐6 Ate Complexes and Their Protonolysis.
Authors: YAMAMOTO Y. , FUJIKAWA H. , FUJISHIMA H. , AKIBA K. 
Published: May 2016

AbstractThe title 12‐Sb‐6 ate complexes such as (I) (8 examples, all formed from a 10‐Sb‐5 compound and organolithiums) are obtained at ‐78 °C as a single isomer (structure shown in the scheme).
ChemInform Abstract: Ring Conversion of 2‐Amino‐4,5‐dihydro‐3‐furancarbonitriles Catalyzed by Halide Ions.
Authors: YAMAGATA K. , MARUOKA H. , HASHIMOTO Y. , YAMAZAKI M. 
Published: May 2016

AbstractThe reaction of the aminodihydrofurans (I) and (IV) with methylamine hydrochloride (II) results in ring cleavage, forming the N‐methylcyclopropanecarboxamides (III).
ChemInform Abstract: Evidence for Intramolecular C‐H Bond Activation and the Formation of a “Tucked‐In” Complex of Hexamethylbenzene at a Tantalum(III) Center.
Authors: BALLARD K. R. , GARDINER I. M. , WIGLEY D. E. 
Published: May 2016

AbstractThe reactions of the d2 Ta complex (I) with (III) or (V) are proposed in both cases to arise through the intermediacy of an unprecedented d0 "tucked‐in" compound (II).
ChemInform Abstract: Five‐Coordinate Complexes of 21‐Thiaporphyrin. Preparations, Spectra, and Structures of Iron(II), Nickel(II), and Copper(II) Complexes.
Authors: LATOS‐GRAZYNSKI L. , LISOWSKI J. , OLMSTEAD M. M. , BALCH A. L. 
Published: May 2016

AbstractThe metal(II) chlorides react with the title ligand to give the complexes (I), all crystallizing in P1 with Z=2.
ChemInform Abstract: Simple Amidinium Carboxylates (I) ‐ An MO Treatment of Molecular Geometry and Electronic Structure.
Authors: KRECHL J. , BOEHM S. + , SMRCKOVA S. , KUTHAN J. 
Published: May 2016

AbstractThe title formates and acetates (I) are prepared and studied by ab initio 3‐21G, 1H, and 13C NMR.
ChemInform Abstract: Stereochemistry of the Conversion of γ‐Substituted E‐Vinyl Sulfones to the Corresponding Allyl Sulfones. Determination of the Relative Degree of “Syn‐Effect”.
Authors: INOMATA K. , HIRATA T. , SUHARA H. , KINOSHITA H. , KOTAKE H. , SENDA H. 
Published: May 2016

AbstractBase‐induced isomerization of the vinylic tolyl sulfones (I) yields the allylic sulfones (II).
ChemInform Abstract: Oxidation of Secondary Cycloalkanoles with the System Lead Tetraacetate/ Metal Halide.
Authors: KAPUSTINA N. I. , POPKOV A. YU. , NIKISHIN G. I. 
Published: May 2016

AbstractCyclopentanol (I) is oxidized with lead(IV) acetate in the presence of metal halides or the rhodanide (IV) to give the aldehydes (II) or (V), together with no or minor amounts of cyclopentanone (III).
ChemInform Abstract: Reversible Redox Processes in Main‐Group/Transition‐Metal Clusters: The (Sb2Co4(CO)10(μ‐CO))‐/2‐ Couple.
Authors: LEIGH J. S. , WHITMIRE K. H. , YEE K. A. , ALBRIGHT T. A. 
Published: May 2016

AbstractThe clusters (Ia) and (Ib), which donot obey any current electron‐counting formalism, are related by a reversible one‐electron redox cycle in which the molecular framework is maintained.
ChemInform Abstract: Stable Pyridophenanthridinium Salts with Acyliminium Partial Structure. Part 1.
Authors: KROEGER E. + 
Published: May 2016

AbstractPhenanthridine (I) is hydrogenated and then coupled with β‐chloropropionyl chloride (II) to give the amide (III) which is cyclized in the presence of AlCl3, yielding the pyridophenanthridinone (IV).
ChemInform Abstract: Adducts of Trimethylaluminum with Phosphine Ligands: X‐Ray Crystal Structures of Me3AlPPh3 and Me3AlP(o‐tolyl)3.
Authors: WIERDA D. A. , BARRON A. R. 
Published: May 2016

AbstractIn order to test the validity of 13C and 31P NMR data as a structural probe for complexes of the type (I), the structures of the title compounds are determined.
ChemInform Abstract: Chromium(IV) Complexes Mediated Oxidations with tert‐Butyl Hydroperoxide.
Authors: MUZART J. 
Published: May 2016

AbstractActivated methylene groups, e.g. in indan (I), fluorene (IV), or the alkyne (VIII), are oxidized with tert‐butyl hydroperoxide in the presence of pyridinium chromyl halides to give the corresponding ketones, e.g. (III), (VII), or (IX).
ChemInform Abstract: Stereoselective Isomerization of 2‐(4‐Methylphenyl)‐2‐adamantol in Trifluoroacetic Acid.
Authors: KOVALEV V. V. , ROZOV A. K. , SHOKOVA E. A. , LUZIKOV YU. N. , SAVEL'EV YU. I. 
Published: May 2016

AbstractOn treatment with TFA, the title compound (I) undergoes stereoselective isomerization to yield the Z‐configurated isomer (II) as the main product whose formation is caused by an intermolecular hydridic shift.
ChemInform Abstract: A Facile Route to 4,5,6,7‐Tetrahydrobenzothiophenes and Benzothiophenes.
Authors: NISHIO T. , OKUDA N. , KASHIMA C. 
Published: May 2016

AbstractReaction of the 2‐(2‐oxoalkyl)cycloalkanones (I) with Lawesson's reagent (II) results in sulfuration and cyclization, yielding the fused thiophenes (III).
ChemInform Abstract: Condensation of γ‐Butyrolactone with Ethyl Acetate.
Authors: LIPKIN M. A. , MARKEVICH V. S. , KIRSANOV A. T. , YURKEVICH A. M. 
Published: May 2016

AbstractThe condensation reaction of butyrolactone (I) with ethyl acetate (II) in the presence of sodium ethylate and traces of water to give α‐acetylbutyrolactone (III) and the by‐products (IV) ‐ (VIII) is studied in detail.
ChemInform Abstract: Synthesis and Cytostatic Activity of Geiparvarin Analogues.
Authors: BARALDI P. G. , GUARNERI M. , MANFREDINI S. , SIMONI D. , BALZARINI J. , DE CLERCQ E. 
Published: May 2016

AbstractThe nitrile oxides, generated in situ from the primary nitro compounds (I) under Mukaiyama conditions, perform a (3 + 2)cycloaddition reaction with the acetylenes (II) to give the isoxazoles (III).
ChemInform Abstract: Reactions of Ferrocenes and Ferrocenium Ions with Ground and Excited States of Tris(2,2′‐bipyridine)chromium Ions.
Authors: LEE S. , BAKAC A. , ESPENSON J. H. 
Published: May 2016

AbstractThe kinetics of quenching of the title Cr complex by d6 metallocenes (I)‐(III) and by ferrocenium ions are evaluated by laser flash photolysis.
ChemInform Abstract: Reaction of Triphenylphosphine with the Anionic Cluster (HRu3(CO)11)Revisited: Isolation, Crystal Structure, and Isomerization of (NEt4)(HRu3(CO)8(PPh3)(PPhC6H4)).
Authors: JUNGBLUTH H. , SUESS‐FINK G. + , PELLINGHELLI M. A. , TIRIPICCHIO A. 
Published: May 2016

AbstractThe reaction of (HRu3(CO)11)‐ generated from Ru3(CO)12 (I) in situ with PPh3 (II) results in the formation of the orthometalation product (III).
ChemInform Abstract: Synthesis and NMR Studies of Palladium(II) and Platinum(II) Complexes with Hybrid Bidentate Ligands Ph2P(CH2)2SR.
Authors: DEL ZOTTO A. , MEZZETTI A. , RIGO P. , BRESSAN M. , MORANDINI F. , MORVILLO A. 
Published: May 2016

AbstractIn dependence on stoichiometric ratio, temp., nature of anion and substituent R, and solvent, the reactions of the hybrid, potentially bidentate ligands Ph2P(CH2)2SR with Pt(II) and Pd(II) salts lead to a variety of cationic and neutral complexes of the type (I)‐(V) containing chelating or monodentate P‐bound ligands.
ChemInform Abstract: The Oxidation Behavior of Silver‐ and Copper‐Based Brazing Filler Metals for Silicon Nitride/Metal Joints
Authors: KAPOOR R. R. , EAGAR T. W. 
Published: May 2016

Abstractis studied at 600 °C, using the following alloys: 80%Cu‐10Sn‐10Ti, Ag‐Cu eutectic + 5% Ti, and Ag‐Cu eutectic + 5% Zr.
ChemInform Abstract: Kinetic and Thermodynamic Behavior Inside Occluded Corrosion Cells Interpreted by Potential/pH Diagrams.
Authors: ZUO J. , POURBAIX M. , XU C. , LIU Y. 
Published: May 2016

AbstractThe electrochemical behavior of occluded cell corrosion is investigated by simulating occluded solutions of different pH values and Cl‐ concentrations.
ChemInform Abstract: A Simple Method of Dethioacetalization.
Authors: STORK G. , ZHAO K. 
Published: May 2016

Abstract2‐Monosubstituted 1,3‐dithianes such as (I) are cleaved upon treatment with bis(trifluoroacetoxy)iodobenzene in aqueous acetonitrile to give the corresponding aldehydes such as (II).