bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: The Reaction of Organocuprates with Bridgehead Enones.
Authors: KRAUS G. A. , YI P. 
Published: May 2016

AbstractThe 1‐bromobicyclo(3.3.1)nonan‐3‐ones (I) and (IV) undergo bridgehead alkylation with the cuprates (II) or (V) to form the derivatives (III) or (VI) via intermediate bridgehead enones.
ChemInform Abstract: Modified Pyridinium Chlorochromate Oxidation of Aldehydes to Carbamoyl Azides/Acyl Azides or Carboxylic Acids.
Authors: REDDY P. S. , YADAGIRI P. , LUMIN S. , SHIN D.‐S. , FALCK J. R. 
Published: May 2016

AbstractThe aldehydes (I) are oxidized with pyridinium chlorochromate in the presence of sodium azide (II) to produce the carbamoyl azides (III) and the acyl azides (IV).
ChemInform Abstract: Electronic Structure of Organylthiochloroacetylenes and Their Reactions with O‐Containing Nucleophiles.
Authors: MIRSKOVA A. N. , SEREDKINA S. G. , SHAGUN V. A. , KALIKHMAN I. D. , MODONOV V. B. , LUTSKAYA N. V. , VORONKOV M. G. 
Published: May 2016

AbstractThe chloromercaptoacetylenes (I) are coupled with the phenolates (II) to give mixtures of the products (III) and (IV).
ChemInform Abstract: Effect of the Base on the Stereoselectivity of the Reaction of a Carbanion with an Aldehyde.
Authors: RAMESH M. , BIELLMANN J.‐F. 
Published: May 2016

AbstractIsopropyl phenyl sulfoxide (I) is deprotonated in α‐position with butyllithium or lithium diisopropylamide and then coupled with benzaldehyde (II), producing the β‐hydroxy sulfoxide (III).
ChemInform Abstract: Synthesis of Newer 5‐Chloro‐2‐phenylbenzimidazoles as Potential Antiviral Agents. Part 53.
Authors: SINGH V. A. , VARMA R. S. 
Published: May 2016

AbstractCyclization of 1,2‐diamino‐4‐chlorobenzene (I) with p‐hydroxybenzoic acid (II) yields the 2‐(p‐hydroxyphenyl)benzimidazole (III) which is converted to the hydrazide (VII) via the acetate (V).
ChemInform Abstract: A New Route to 1,3,4‐Thiadiazolines. Part 3. Consequences of the Aza‐enamine Concept.
Authors: MUEHLSTAEDT M. + , WEBER L. , BIRNER P. 
Published: May 2016

AbstractThe N,N‐disubstituted hydrazones (I) react with the sulfenyl chloride (II) to give the C‐ and N‐sulfenyl products (III) and (IV).
ChemInform Abstract: Reaction of Benzonitrile N‐(p‐Nitrophenyl)imide with 5‐Substituted Tetrazoles: A New Route to Substituted 1,2,4‐Triazoles via N‐Hydrazonoyltetrazoles.
Authors: BUTLER R. N. , FITZGERALD K. J. 
Published: May 2016

AbstractThe reaction of the tetrazoles (I) with benzonitrile N‐(p‐nitrophenyl)imide (generated in situ from the hydrazonoyl bromide (II)) gives rise to the regioisomeric hydrazonoyltetrazoles (III) and (IV).
ChemInform Abstract: Synthesis of a New Naturally Occurring 3‐Phenyl‐4H‐1‐benzopyran‐4‐one.
Authors: PARMAR V. S. , SINGH S. , JAIN R. 
Published: May 2016

AbstractThe isoflavone (IV) isolated from Tephrosia maxima is prepared by thallium(III) nitrate‐induced rearrangement of the chalcone (III) which is obtained by aldol condensation of the acetophenone (I) with piperonal (II).
ChemInform Abstract: 1,2,3‐Benzotriazine 2‐Oxides.
Authors: BOULTON A. J. , KISS M. , SAKA J. D. K. 
Published: May 2016

AbstractN‐oxidation of the benzotriazine (I) proceeds at the 2‐position to give the N‐oxide (II), which is converted to the derivatives (IV) or (VI).
ChemInform Abstract: Reaction of Carboranes with Alkyl Derivatives of Group III Metals.
Authors: BREGADZE V. I. , USYATINSKII A. YA. , ANTONOVICH V. A. , GODOVIKOV N. N. 
Published: May 2016

AbstractReaction of the o‐carboranes (I) with trimethylgallium (II) in the presence of tetramethylethylenediamine (III) gives the dicarbaundecaboranates (IV).
ChemInform Abstract: Cycloaddition Reactions of Tetrafluorodisilacyclobutene with Conjugated Dienes Mediated by Metal Carbonyls. Part 4. Stereoselective 1,4‐Addition and Conformations of 1,4‐Disilacycloocta‐2,6‐dienes.
Authors: JZANG T. , LEE C. , LIU C. 
Published: May 2016

AbstractReaction of the disilacyclobutene (I) with Ni(CO)4 (II) yields the metallacycle (III), which reacts with various conjugated dienes such as (IV) to give the disilacyclooctadienes (V).
ChemInform Abstract: Selective Binding of One Enantioface of Monosubstituted Alkenes to the Chiral Transition Metal Lewis Acid ((η5‐C5H5)Re(NO)(PPh3))+.
Authors: BODNER G. S. , FERNANDEZ J. M. , ARIF A. M. , GLADYSZ J. A. 
Published: May 2016

AbstractAddition of the alkenes (III) to the chiral Lewis acid (II), prepared from (I) as shown, gives a mixture of alkene complex diastereomers (RR,SS)‐(IV) and (RS,SR)‐(V).
ChemInform Abstract: Formation and Characterization of Copper(II) 1,4‐Benzenediolate and p‐Semiquinonate Complexes.
Authors: BALOGH‐HERGOVICH E. , SPEIER G. 
Published: May 2016

AbstractThe strongly oxidizing p‐quinones (I) undergo stepwise oxidative addition reactions with Cu(I) chloride and bromide (II) in pyridine (III) resulting in Cu(II) p‐semiquinone (V) and dinuclear Cu(II) 1,4‐benzenedithiolate pyridine complexes (IV).
ChemInform Abstract: The Photochemistry of Cyclopentadienyl Platinum Carbonyl Dimers: Characterization of (Pt2(μ‐CO)(η5‐C5R5)2) (R: H or Me) Using Matrix Isolation and Fast Time‐Resolved Infrared Spectroscopy.
Authors: DIXON A. J. , FIRTH S. , HAYNES A. , POLIAKOFF M. , TURNER J. J. , BOAG N. M. 
Published: May 2016

AbstractUV photolysis of the complexes (I), isolated in argon, N2 or CO matrices at 20 K, yields the photoproducts (II) with only one bridging CO group.
ChemInform Abstract: Aromatization of 7β,17β‐Diacetoxy‐4‐methyleneandrost‐5‐ene.
Authors: HANSON J. R. , TRUNEH A. 
Published: May 2016

AbstractAcid treatment of the title compound (I) leads to aromatization of ring A and yields the steroid (II) as major product rather than an anthrasteroid (yields given in g).
ChemInform Abstract: Steroidal Allylic and Homoallylic Rearrangements During Halogenation with Triphenylphosphine and Carbon Tetrachloride.
Authors: HANSON J. R. , HITCHCOCK P. B. , REESE P. B. , TRUNEH A. 
Published: May 2016

AbstractTreatment of the hydroxyandrostane (I) with PPh3/CCl4 yields the 3α‐ and 3β‐chloroandrostanones (IIa) + (IIb) together with the cyclosteroid (III).
ChemInform Abstract: Stereoselective Total Syntheses of the Naturally Occurring Enantiomers of N‐Acetylneuraminic Acid and 3‐Deoxy‐D‐manno‐2‐octulosonic Acid. A New and Stereospecific Approach to Sialo and 3‐Deoxy‐D‐manno‐2‐octulosonic Acid Conjugates.
Authors: DANISHEFSKY S. J. , DENINNO M. P. , CHEN S. 
Published: May 2016

AbstractThe highly diastereoselective cycloaddition reaction of the components (S)‐(I) and (II) yields a mixture of the epimers (III).
ChemInform Abstract: Synthetic Studies Relevant to Biosynthetic Research on Vitamin B12. Part 6. Synthesis of Chlorins by a Photochemical Approach.
Authors: BATTERSBY A. R. , DUTTON C. J. , FOOKES C. J. R. , TURNER S. P. D. 
Published: May 2016

AbstractThe chlorins (III) are prepared from (Ia) (unstable, formed in situ from its tert. butyl 9‐carboxylate) and (Ib), respectively, by condensation with (II) via the seco‐chlorin (not isolated), followed by photocyclization.
ChemInform Abstract: Irreversible Inhibition of Papain by Epoxysuccinyl Peptides. 13C NMR Characterization of the Site of Alkylation.
Authors: YABE Y. , GUILLAUME D. , RICH D. H. 
Published: May 2016

AbstractIn order to determine the basis of the remarkable chemical selectivity of cysteine proteinase inhibition observed with, e.g., Ep‐475 (VIIa), the reaction of the labeled analogue (VIIb) with papain is investigated in detail; the results of the 13C NMR studies identify the site of attack in this reaction.
ChemInform Abstract: Neodymium‐Rich Phases in Nd‐Fe‐B Magnets.
Authors: TANG W. , ZHOU S. , WANG R. 
Published: May 2016

AbstractAs shown by using XRD, TEM, and SEM, the Nd‐rich phase in the Nd‐Fe‐B system changes its structure during the conventional sintering process from the double h.c.p. structure in the ingot to the f.c.c. structure in the sintered magnets.
ChemInform Abstract: Influence of Carbon on the Mechanical Properties of High‐Manganese Dual‐Phase Steels.
Authors: TERAO N. , SHAM E. L. , BAUGNET A. 
Published: May 2016

AbstractHigh‐manganese (≈ 3 wt.%) dual‐phase steels containing 0.2‐0.5 wt.% C show increasing mechanical resistance with C content.
ChemInform Abstract: Non‐Stoichiometry and Physical Properties of the Ferromagnetic Semiconductor CdCr2Se4.
Authors: BEL'SKII N. K. , OCHERTYANOVA L. I. , ZHEGALINA V. A. , KOROLEVA L. I. 
Published: May 2016

AbstractThe electric and magnetic properties of samples, whose compositions correspond to the borderline of the field of homogeneity, are investigated.
ChemInform Abstract: Synthesis of the New Boron Hydride nido‐Undecaborane(15), B11H15, and the X‐Ray Structure of Its Conjugate Base Tetradecahydroundecaborate(1‐), (B11H14)‐.
Authors: GETMAN T. D. , KRAUSE J. A. , SHORE S. G. 
Published: May 2016

AbstractProtonation of K(B11H14) with anhydrous HCl at ‐78 °C gives undecaborane(15) (III) in quantitative yield.
ChemInform Abstract: Solvolysis of Alkyl Azoxytosylates: The Link Between Solvolytic Deamination and Tosylate Solvolysis.
Authors: CONNER J. K. , MASKILL H. 
Published: May 2016

AbstractThe products of solvolysis of the adamantyl azoxytosylate (I) in acetic acid as well as pure and aqueous ethanol and trifluoroethanol are analyzed by GLC and HPLC.
ChemInform Abstract: PTC Induced Acylation of Active Methylenes.
Authors: NAIK S. N. , PANDEY B. , AYYANGAR N. R. 
Published: May 2016

AbstractThe activated methylene groups in indene (I) and fluorene (V) undergo twofold acylation with the acyl halides (II) in the presence of sodium hydride and a phase‐transfer catalyst to form the carbonyloxymethylene derivatives (III) and (VI).
ChemInform Abstract: Thermal and Photochemical Reactions of 10‐Methyl‐9‐phenylacridinium Chloride in Alcohols.
Authors: ZHOU B. , KANO K. , HASHIMOTO S. 
Published: May 2016

AbstractThe adduct of type (III) which is obtained from the title compound (I) and an alcohol such as (II) shows coexistence of MeO‐ and the acridinium cation; photoreduction gives (IV) via the lowest excited singlet state of (III) (ionic mechanism).
ChemInform Abstract: Substitution Reactions which Proceed via Radical Anion Intermediates. Part 33. Carbanions that Function Both as Electron Transfer Agents and as Hydrogen Atom Donors: A New Electron Transfer Chain Reaction.
Authors: KORNBLUM N. , CHEN S. I. , KELLY W. J. 
Published: May 2016

AbstractThe β‐nitro nitrile (I) induces the dimerization of the carbanion salts (II) upon exposure to fluorescent light, yielding the compounds (III) and the denitrated nitrile (IV) via radicalic intermediates.
ChemInform Abstract: A Facile Synthesis of Oxetane Derivatives for Preparing Cross‐Linked Polyoxetane Resins Bearing the Bromide at the Spacer End.
Authors: MOTOI M. , SUDA H. , SHIMAMURA K. , NAGAHARA S. , TAKEI M. , KANOH S. 
Published: May 2016

AbstractCationic polymerization of the oxetane derivatives (III) yields viscous oily materials which are soluble in acetone, CHCl3, Et2O and benzene.
ChemInform Abstract: Synthesis of Azetidin‐3‐ones by Heterocyclization of α‐Cyclohexylamino‐α′,β′‐epoxy Ketones.
Authors: ZVONOK A. M. , KUZ'MENOK N. M. , STANISHEVSKII L. S. 
Published: May 2016

AbstractThermal treatment of the boron trifluoride complexes (I) of amino epoxy ketones gives hydroxymethylazetidinones (II) which are converted to the derivatives (III), (V), and (VI).
ChemInform Abstract: A Convenient Synthesis of 3‐Phenacylidenephthalides.
Authors: HORI K. , TAKAISHI N. 
Published: May 2016

AbstractCondensation of phthalic anhydride (I) with the acetophenones (II), followed by dehydration of the intermediates (III), gives the title compounds as separable mixtures of the E and Z isomers (IV) and (V).
ChemInform Abstract: Chemistry of Constrained Heteroaromatics. Part 4. Synthesis and Properties of Novel Analogs of Viologen.
Authors: KAWASHIMA T. , SHIOMI Y. , TOHDA Y. , ARIGA M. , MORI Y. , SAKATA Y. , MISUMI S. 
Published: May 2016

AbstractThe novel title compounds (IVa)‐(IVe) are synthesized.
ChemInform Abstract: Ambidentate Poly(diphenylphosphino)ethanes and ‐ethenes.
Authors: SCHMIDBAUR H. , PASCHALIDIS C. , REBER G. , MUELLER G. + 
Published: May 2016

AbstractBase‐catalyzed hydrophosphorylation of the 1,1‐bis(phosphino)ethene (I) with (II) results in the formation of the tris(phosphino)ethane (II).
ChemInform Abstract: 1,3‐Digermapropane and 1,3,5‐Trigermacyclohexane.
Authors: SCHMIDBAUR H. , ROTT J. , REBER G. , MUELLER G. + 
Published: May 2016

AbstractFrom the Cu(0)‐catalyzed reaction of Ge powder with CH2Cl2 at 350 °C, a mixture of alkylchlorogermanes is obtained in which MeGeCl3 and the chlorinated bis(germyl)methane (I) and trigermacyclohexane (III) are the major products.
ChemInform Abstract: Preparation and Properties of the Mo2X4(PMe3)4 Compounds with X = NCS and NCO.
Authors: COTTON F. A. , MATUSZ M. 
Published: May 2016

AbstractThe title compounds (I) are formed in a one‐pot reaction from the dimeric Mo acetate and Me3SiNCZ (Z: S, O) in the presence of phosphine.
ChemInform Abstract: Tetrafluoroferrole, (CO)3Fe‐cyclic(Fe‐CF=CF‐CF=CF)(CO)3.
Authors: LENTZ D. , MICHAEL H. 
Published: May 2016

AbstractThe title compound (IV) is obtained as a by‐product in the synthesis of the triiron complex (III) from pentacarbonyliron (I) and tribromofluoromethane (II).
ChemInform Abstract: Complexes with Carbon Sulfides and Selenides as Ligands. Part 21. Cobalt Complexes Containing Monohapto and Dihapto Bonded CS2R Ligands.
Authors: KOLB O. , WERNER H. 
Published: May 2016

AbstractThe cobalt complex (I) is alkylated at the exo‐sulfur atom to form the complexes (IV).
ChemInform Abstract: Electrochemical Reactions at Sacrificial Electrodes. Part 3. Electrochemical Synthesis of Unique Copper(II) Alkoxides.
Authors: BANAIT J. S. , PAHIL P. K. 
Published: May 2016

AbstractThe aldehydes and ketones (I) are electrochemically reduced using a copper anode and a platinum cathode in a tetrabutylammonium chloride/ DMF solution to yield the copper(II) alkoxides (III).
ChemInform Abstract: Synthesis and X‐Ray Structure of Reactive α‐Amino Ethers Stabilized via Metal Complexation.
Authors: ALBINATI A. , ARZ C. , PREGOSIN P. S. 
Published: May 2016

AbstractThe reaction of Pt‐benzimidazole and ‐benzoxazole derivatives and with alcohols affords the α‐amino ether complexes (III) and (IV) in good yields (numerical values not given), which are characterized by selected 1H and 13C NMR data and a crystal structure determination of (IVb) (P1, Z=2).
ChemInform Abstract: The Hydrolytic Reactivity of Homoprostacyclin: Implications for the Physiological Control of Bleeding.
Authors: CHIANG Y. , KRESGE A. J. 
Published: May 2016

AbstractIn contrast to prostacyclin (Ia) (lifetime at physiological pH only 3 min) its homolog (Ib) (lifetime 30 min) is only 8 times more reactive in its carboxylate than in its carboxylic acid form (as a result of intramolecular catalysis), whereas prostacyclin (Ia) itself has a 100‐fold increase in reactivity.
ChemInform Abstract: Effect of N‐Bromosuccinimide (NBS) and Other N‐Brominating Agents on the Bromination of α,β‐Unsaturated Ketones in Methanol.
Authors: HEASLEY V. L. , LOUIE T. J. , LUTTRULL D. K. , MILLAR M. D. , MOORE H. B. , NOGALES D. F. , SAUERBREY A. M. , SHEVEL A. B. , SHIBUYA T. Y. , STANLEY M. S. , SHELLHAMER D. F. , HEASLEY G. E. 
Published: May 2016

AbstractWhen the α,β‐unsaturated ketones (I) are treated with bromine in methanol (II) in the absence or presence of NBS, a concurrency between bromination and methoxybromination is observed.
ChemInform Abstract: General Approach to the Synthesis of Polyquinenes via the Weiss Reaction. Part 6. Progress Toward the Synthesis of Dicyclopentapentalenes.
Authors: LANNOYE G. , SAMBASIVARAO K. , WEHRLI S. , COOK J. M. , WEISS U. 
Published: May 2016

AbstractThe Weiss reaction is the key step in the synthesis of the tetraquinanes (IX) ‐ (XI).
ChemInform Abstract: Reactions of Organic Anions. Part 139. Vicarious Nucleophilic Substitution of Hydrogen in 1,2,4‐Triazine Derivatives.
Authors: RYKOWSKI A. , MAKOSZA M. 
Published: May 2016

AbstractThe triazines (I) react with carbanions derived from various CH‐acidic compounds such as (II) containing leaving groups at the carbanionic center to give predominantly the 5‐substituted products (III).
ChemInform Abstract: Peracid Oxidation of Naphtho(1,8‐cd)‐1,2‐diselenole: Structure and Chemistry of the Monooxidation Product.
Authors: KICE J. L. , KANG Y.‐H. , MANEK M. B. 
Published: May 2016

AbstractOxidation of the diselenole (I) mentioned in the title with 3 moles of m‐chloroperbenzoic acid yields the anhydride (II).
ChemInform Abstract: Binuclear Complexes. Part 3. Synthesis and Reactivity of a Family of Copper Monooxygenase Model Systems.
Authors: CASELLA L. , GULLOTTI M. , PALLANZA G. , RIGONI L. 
Published: May 2016

AbstractThe binuclear Cu(I) complexes (I) (yields 30‐50%) are prepared by template synthesis from the amine or L‐amino acid ester and benzene‐1,3‐ or ‐1,4‐dicarboxaldehyde in MeOH in the presence of an excess of (Cu(MeCN)4)ClO4.
ChemInform Abstract: Linear Oligophosphaalkanes. Part 22. (Cu8(iPrPCH2PiPr)2Cl4(py)5), a Novel Cu(I) Cluster with Five‐Coordinate Phosphorus in μ3‐PRR′ Bridges (R: iPr; R′: CH2PiPr).
Authors: GOL F. , KNUEPPEL P. C. + , STELZER O. , SHELDRICK W. S. 
Published: May 2016

AbstractThe diamagnetic title cluster (IV) is prepared by 4:1 molar reaction of CuCl (I) with the diphosphine (III) in the presence of excess pyridine (II).
ChemInform Abstract: Oxygen Scrambling in Pentaamminenitritocobalt(III) Revisited.
Authors: JACKSON W. G. 
Published: May 2016

AbstractFrom 17O NMR experiments it is concluded that the rapid nitrosation reaction of (NH3)5Co‐17OH2+ in water leads to the oxygen bound nitrite ion product (NH3)5Co‐ONO2+ having one 17O per Co but distributed equally between inner and outer sites.
ChemInform Abstract: Structural Study of Potassium Gallate Glasses by Moessbauer Spectroscopy and Differential Thermal Analysis.
Authors: NISHIDA T. , SARUWATARI S. , TAKASHIMA Y. 
Published: May 2016

AbstractThe Moessbauer spectra of a series of Ga2O3‐based glasses containing 35‐70 mol% K2O and 10 mol% Fe2O3 as a Moessbauer probe indicate that all the Fe3+ ions are located at substitutional sites of the tetrahedral Ga3+ ions which constitute the skeleton of the network structure.
ChemInform Abstract: Evidence of the Presence of (MgH4)2‐ Tetrahedra in the Cs3MgH5 and Rb3MgH5 Phases.
Authors: PARK H.‐H. , PEZAT M. , DARRIET B. 
Published: May 2016

AbstractThe isotypic title phases, prepared starting from the binary hydrides (400 °C, 2 d; under H2, 30 bar), crystallize in the tetragonal system, space group P4/ncc.
ChemInform Abstract: The Effect of Pulsed Laser Irradiation on the Properties of Glassy Carbon Electrodes
Authors: STULIK K. , BRABCOVA D. , KAVAN L. 
Published: May 2016

Abstractand in addition of graphite and Pt electrodes is studied in air by using an iodine laser (λ = 1.315 μm, pulse length 15 μs, pulse intensities 0.037, 0.13, and 0.4 MW/cm2).
ChemInform Abstract: Cyclodehydration of Non‐Aromatic Diols on Al(III)‐Montmorillonite Clay: Reactivity and Mechanism.
Authors: KOTKAR D. , MAHAJAN S. W. , MANDAL A. K. , GHOSH P. K. 
Published: May 2016

AbstractAl(III)‐montmorillonite‐catalyzed reactions of non‐aromatic diols or thiols such as (I) or (III) yields the heterocycles (II) or (IV).
ChemInform Abstract: Synthetic Photochemistry. Part 41. Photorearrangement of 5‐Alkyl‐1‐hydroxy‐8‐oxabicyclo(3.2.1)octa‐3,6‐dien‐2‐ones to 2‐Alkyl‐3‐oxatricyclo(3.3.0.02,8)octane‐4,6‐diones.
Authors: MORI A. , KASAI S. , TAKESHITA H. 
Published: May 2016

AbstractIn connection with the study of the photorearrangement of bicyclic dienones and trienones via ketene intermediates the photorearrangement of the dienones (I) is investigated.
ChemInform Abstract: 2σ‐1σ* Three‐Electron‐Bonded Radical Cations from Alkylthio(halogeno)alkanes (I).
Authors: ANKLAM E. , MOHAN H. , ASMUS K.‐D. 
Published: May 2016

AbstractA wide range of compounds (I), homologous in alkyl chain and/or R as well, is studied.
ChemInform Abstract: Formation of 1,4,2,5‐Dithiadiazines as a Heterocyclic System by Reaction of 1,4,2‐Dithiazolium Salts with Sulfenamides.
Authors: YONEMOTO K. , SHIBUYA I. , HONDA K. 
Published: May 2016

AbstractThe title reaction (I) → (III) (X‐ray analysis of (IIIc): space group Pca21 with Z = 8) represents the first example of ring expansion by an N atom using sulfenamides (besides (II), various other sulfenamides and N‐expansion reagents are evaluated).
ChemInform Abstract: Remarkably Stable Fluorinated Conjugated Cations and a Dication.
Authors: CHAMBERS R. D. , SALISBURY M. , APSEY G. , MOGGI G. 
Published: May 2016

AbstractThe polyfluoroalkanes (I) and (VI) react with antimony pentafluoride (II) to give the salts (III) and (VII).
ChemInform Abstract: Amylthioacetyl Alkyl(Aryl) Disulfides as Admixtures to Lubricating Oils.
Authors: KULIEV A. B. , MAMEDOV A. G. , KURBANOV M. M. 
Published: May 2016

AbstractThe anticorrosive properties of the title compounds (III), which are applied as admixtures to the lubricating oil M‐11, are investigated.
ChemInform Abstract: Preparation of 1,3,5‐Tribromoadamantane.
Authors: DELIMARSKII R. E. , RODIONOV V. N. , YURCHENKO A. G. 
Published: May 2016

AbstractThe optimum reaction conditions of the bromination of adamantane (I) to give 1,3,5‐tribromoadamantane (II) are given in the reaction scheme.
ChemInform Abstract: Cadmium Metal‐Mediated Allylation of Carbonyl Compounds.
Authors: ARAKI S. , ITO H. , BUTSUGAN Y. 
Published: May 2016

AbstractCd‐powder mediated coupling of allylic halides such as (II), (V), or (VIII) with the aldehydes (IV) and (VII) or ketones (I) leads to the formation of homoallylic alcohols, e.g. (III), (VI), or (IX).
ChemInform Abstract: α,β‐Epoxy Sulfoxides as Useful Intermediates in Organic Synthesis. Part 15. A Novel and Stereoselective Synthesis of E‐1‐Acylbutadienes from 1‐Chloroalkyl Phenyl Sulfoxides and 4‐(Phenylthio)butanal Through α,β‐Epoxy Sulfoxides.
Authors: SATOH T. , MOTOHASHI S. , YAMAKAWA K. 
Published: May 2016

AbstractThe sulfoxides (I) react with the substituted butanal (II) to give the chlorohydrins (III) which are treated with potassium thiophenolate, forming the bis(phenylthio) ketones (V).
ChemInform Abstract: Palladium(0)‐Catalyzed Cyclization Followed by Allylation of Allylic Alkynoates and the Related System.
Authors: TSUDA T. , OHASHI Y. , NAGAHAMA N. , SUMIYA R. , SAEGUSA T. 
Published: May 2016

AbstractPd(0)‐catalyzed cyclization of the allylic alkynoates (I) yields the γ‐alkylidene‐γ‐butyrolactones (II).
ChemInform Abstract: Imidazole Derivatives. Part 23. Synthesis and Biological Activity of 4‐Nitro‐5‐mercaptoimidazole Derivatives.
Authors: IRADYAN M. A. , AIVAZYAN A. KH. , MIRZOYAN V. S. , STEPANYAN G. M. , ARSENYAN F. G. , GARIBDZHANYAN B. T. , PARONIKYAN G. M. , SARKISYAN T. P. 
Published: May 2016

AbstractThe mercaptides (I) are coupled with epoxypropanes (II) or the glycerol chlorohydrin (IV) to give the thioethers (III) and (V).
ChemInform Abstract: Cyclization of Isothiosemicarbazones. Part 8. Formation and Structure of gem‐Bis(3‐alkylthio‐1H‐1,2,4‐triazol‐1‐yl)alkanes and Related Compounds.
Authors: YAMAZAKI C. , TAKAHASHI T. , HATA K. 
Published: May 2016

AbstractSym. bis(triazolyl)alkanes such as (III) are directly obtained by the reaction of the aliphatic ketone isothiosemicarbazones (I) with the methylenenitroacetate (II) (1:2 E:Z‐mixture) as a methine donor.
ChemInform Abstract: Synthetic Uses of 1‐((Methylthio)thiocarbonylmethyl)pyridinium Iodide. Synthesis of New Benzimidazole Derivatives.
Authors: CUADRO A. M. , ALVAREZ‐BUILLA J. , VAQUERO J. J. 
Published: May 2016

AbstractThe dithioester (I) undergoes cyclocondensation with the o‐phenylenediamines (II) to give the benzimidazoles (III).
ChemInform Abstract: 1,4‐Additions of Amines to 5‐Methoxyfuran‐2(5H)‐one. An Efficient Synthesis of Amino Diols.
Authors: FERINGA B. L. , DE LANGE B. 
Published: May 2016

AbstractThe methoxybutenolide (I), synthesized from 2‐formylfuran in 2 steps by photooxidation and methanolysis, reacts with the amines (II) to form the aminolactones (III).