bluuebunny/crossref_metadata_2025_split huggingface dataset:
A Near‐Infrared Retinomorphic Device with High Dimensionality Reservoir Expression
Authors: Leng Yan‐Bing , Lv Ziyu , Huang Shengming , Xie Peng , Li Hua‐Xin , Zhu Shirui , Sun Tao , Zhou You , Zhai Yongbiao , Li Qingxiu , Ding Guanglong , Zhou Ye , Han Su‐Ting 
Published: October 2024

AbstractPhysical reservoir‐based reservoir computing (RC) systems for intelligent perception have recently gained attention because they require fewer computing resources. However, the system remains limited in infrared (IR) machine vision, including materials and physical reservoir expression power. Inspired by biological visual perception systems, the study proposes a near‐infrared (NIR) retinomorphic device that simultaneously perceives and encodes narrow IR spectral information (at ≈980 nm). The proposed device, featuring core‐shell upconversion nanoparticle/poly (3‐hexylthiophene) (P3HT) nanocomposite channels, enables the absorption and conversion of NIR into high‐energy photons to excite more photo carriers in P3HT. The photon‐electron‐coupled dynamics under the synergy of photovoltaic and photogating effects influence the nonlinearity and high dimensionality of the RC system under narrow‐band NIR irradiation. The device also exhibits multilevel data storage capability (≥8 levels), excellent stability (≥2000 s), and durability (≥100 cycles). The system accurately identifies NIR static and dynamic handwritten digit images, achieving recognition accuracies of 91.13% and 90.07%, respectively. Thus, the device tackles intricate computations like solving second‐order nonlinear dynamic equations with minimal errors (normalized mean squared error of 1.06 × 10⁻3 during prediction).
A Prediction of All‐Inorganic Lead‐Free Halide Perovskites for Photovoltaic Application: Rb3Mo2Br9 and Rb3Mo2Cl9
Authors: Deng Xinxin , Zhang Zhesi , Zhang Zili , Wu Yunyi , Song Hongzhou , Li Huanxin , Luo Bingcheng 
Published: October 2024

AbstractLead‐based organic‐inorganic hybrid perovskites show promise as photovoltaic materials due to their high energy conversion efficiencies. However, concerns regarding lead toxicity and the poor environmental and operational stability of the organic cationic group have limited their widespread application. To address these challenges, the design of all‐inorganic lead‐free halide perovskites offers potential solutions for photovoltaic applications. Here, two layered perovskite derivatives, Rb3Mo2Cl9 and Rb3Mo2Br9, are explored, and their electronic, structural, and photovoltaic properties are analyzed using advanced theoretical calculations. Rb3Mo2Br9 exhibits a suitable direct bandgap of 1.60 eV, making it a promising candidate for use as a light absorber in low‐cost, high‐efficiency solar cells. On the other hand, Rb3Mo2Cl9 demonstrates a wide direct bandgap exceeding 1.70 eV, positioning it as a viable option for use as a top cell in tandem photovoltaic systems alongside silicon. Both materials display ideal optical properties in the visible light region and hold promise as excellent inorganic lead‐free perovskite alternatives.
Lithium Localization by Anions in Argyrodite Solid Electrolytes from Machine‐Learning‐based Simulations
Authors: Lee Hyun‐Jae , Kim Hyeonjung , Ji Sungyoung , Choi Kyuri , Choi Ho , Lim Woosang , Lee Byungju 
Published: October 2024

AbstractThe introduction of density functional theory (DFT) has improved the study of material properties. This has enabled significant breakthroughs in solid electrolytes, which have emerged as promising candidates for next‐generation energy storage systems. However, DFT faces limitations due to the extremely high computational costs required for large atomic cells and long simulation times. In the current study, AI‐based simulations using neural network potentials (NNPs) are introduced to extend the capabilities of DFT to explore the effect of anions on lithium diffusion in Li argyrodite (Li6PS5X, X = Cl and Br). The investigation categorizes lithium frameworks into two distinct cages, demonstrating that sulfur ions in these cage centers bind the surrounding lithium ions. From the results, a strategy is proposed to enhance lithium ion conductivity by minimizing the occupation of sulfur ions in cage centers. This research provides a benchmark for evaluating lithium ionic conductivity based on anion configuration in cage centers and advances the understanding of ionic transport in Li argyrodite, informing potential improvements in energy‐storage technologies.
Conformal Li2O2 Growth and Decomposition Within 3D Lithiophilic Nanocages of Metal–Organic Frameworks for High‐Performance Li─O2 Batteries
Authors: Kang Shin Joon , Hong Minjoon , Won Jong Ho , Han Byungchan , Kang Jeung Ku , Jeong Hyung Mo 
Published: October 2024

AbstractLi─O2 batteries (LOBs) have the largest theoretical capacity among current batteries, but the irreversible growth and decomposition of Li2O2 products in positive electrodes cause dramatic degradation of their capacities over charging–discharging cycles. Herein, a metal–organic framework is reported with bipyridinic N linkers attached to graphene (bpyN‐MOF/g) as a positive electrode material to overcome the challenge. The bpyN‐MOF/g promotes conformal Li2O2 growth during discharging, while allowing Li2O2 decomposition at a low overpotential (0.487 V vs Li+/Li at 200 mA gc−1) during charging process, outperforming the Pt/C‐based electrode (0.857 V). Moreover, 3D‐tomography and density functional theory calculations consistently support the Li2O2 growth and decomposition mechanism inside bpyN‐MOF/g. Furthermore, bpyN‐MOF/g//Li LOBs achieve an exceptional discharge capacity (17 275 mAh gc−1 at 100 mA gc−1) and steady cycling for 270 cycles at 1000 mAh gc−1 under 2000 mA gc−1. Additionally, high gravimetric capacity at low mass loadings (0.27–0.44 mg cm−2) and stable cycle operation at a high areal current density (0.5 mA cm−2) open new opportunities for various practical applications.
A Versatile InF3 Substituted Argyrodite Sulfide Electrolyte Toward Ultrathin Films for All‐Solid‐State Lithium Batteries
Authors: Li Dabing , Liu Xinyu , Li Yang , Zhao Xiaoxue , Wu Meng , Qi Xiang , Gao Lei , Fan Li‐Zhen 
Published: October 2024

AbstractAll‐solid‐state lithium batteries (ASSLBs) incorporating sulfide solid electrolytes capture great attention due to their intrinsic safety features and high energy density. Nevertheless, the implementation of sulfide solid electrolytes faces significant challenges, including moisture sensitivity, narrow intrinsic electrochemical windows, and excessively thick solid electrolyte layers. Here, the substitution of In for P and F for Cl in argyrodite sulfide Li5.7PS4.7Cl1.3 is presented. With appropriate elemental substitutions, the Li symmetric cells exhibit a high critical current density value of 2.5 mA cm−2 and deliver prolonged plating/stripping over 1000 h at 1 mA cm−2 and 25 °C. Further, the Li5.82P0.94In0.06S4.7Cl1.12F0.18 displays high chemical stability toward organic solvents, which is further demonstrated by the density functional theory (DFT) calculations. Using polyisobutylene as a binder, a uniform sulfide film (35 µm) is prepared by slurry casting and hot pressing process, delivering a high ionic conductivity of 1.4 mS cm−1 at 25 °C. Coupled with FeS2 and LiCoO2 cathode, the all‐solid‐state lithium metal cell exhibits a long cycling life and excellent rate performance. This study provides a design strategy and reveals the importance of high‐performance sulfide SEs in the scalable production of sulfide film.
Atomically precise Cu32 nanoclusters with selenide doping: Synthesis, bonding, and catalysis
Authors: Huo Rong , Ren Rui , Wang Lin , Xu Qinghua , Yan Bingzheng , Zhang Jiangwei , Guo Qingxiang , Guan Zongjie , Shen Hui , Zheng Nanfeng 
Published: October 2024

AbstractCopper nanoclusters with stable compositions and precise structures have long been sought after, as they possess properties that are absent in gold and silver counterparts. However, the creation of copper nanoclusters with novel compositions, structures, and functionalities remains largely unexplored in the literature. In this study, we demonstrate that selenide doping is an effective method for fabricating stable copper nanostructures through controlled synthesis and structure determination of a copper–selenide nanocluster. The nanocluster of [Cu32Se7(BnSe)18(PPh3)6]+ (denoted as Cu32Se7, Bn is benzyl) has been prepared by reducing copper salts in the presence of organic diselenides. The atomic structure of the Cu32Se7 cluster, accurately determined through single‐crystal X‐ray diffraction, reveals a core–shell arrangement of Cu20Se7@Cu12(BnSe)18(PPh3)6, where Se2− anions are well dispersed in the Cu20 framework. Notably, this cluster represents a rare example of copper–selenide semiconductor nanoclusters. Experimental and theoretical analysis shows strong interactions between Se ligands and metal atoms, resulting in high stability of the Cu32Se7 cluster. Furthermore, the cluster exhibits excellent catalytic performance in the hydroboration reaction of alkynes, producing a range of vinylboron compounds with adjustable structures and functions. Importantly, the cluster undergoes no structural or nuclearity changes during the reaction, as confirmed by extended X‐ray absorption fine structure and X‐ray photoelectron spectroscopy studies. This study not only presents a molecular cluster model highlighting the effectiveness of selenide dopants in fabricating new copper nanostructures but also paves the way for utilizing stable copper nanoclusters in diverse and exciting areas beyond catalysis.
Finely tunable NIR‐II organic scaffolds for fluorescence/photoacoustic duplex imaging–guided noninvasive photothermal therapy of glioblastoma
Authors: Song Yufei , Tong Xingyu , Han Yujie , Zhang Qi‐Wei 
Published: October 2024

AbstractOrganic agents possessing NIR‐II and photoacoustic duplex imaging capabilities, coupled with high‐efficiency photothermal conversion, offer significant potential for noninvasive and precise phototheranostics of glioblastoma, which is further augmented when these agents can concurrently exhibit tumor targeting and blood–brain barrier (BBB) permeability. This study reports a series of finely tunable NIR‐II molecular luminophores based on the aza‐BODIPY scaffold, featuring unique twisted and rotatable structures. They are further constructed to folate‐decorated polymeric nanoparticles, exhibiting remarkable NIR‐II/photoacoustic imaging performance and superior photothermal conversion efficiency (49.7%). Folate modification enables tumor targeting and BBB permeability through receptor‐mediated transcytosis, allowing for precise and efficient phototherapy in 4T1‐/glioblastoma‐bearing mice after a single intravenous injection and irradiation. This study presents a rational molecular engineering approach and a versatile structural scaffold for designing NIR‐II emitters with tailored photophysical properties and desirable phototherapeutic efficacy, thereby offering novel perspectives on the development of advanced depth imaging probes and brain tumor therapeutics.
Retrospective quality review of Department of Transportation (DOT) commercial drivers medical examination forms
Authors: Starchook‐Moore Maria , Nadeau Ashley , Dabrowski Dominik , Briggs John , Kool LaDonna , Belt Mezzie , Bovard Ralph , Anderson Paul , Kim Hyun , Montoya‐Barthelemy Andre , McKinney Zeke J. 
Published: October 2024

AbstractObjectiveThis study aimed to evaluate the quality of completion among both drivers and medical examiners in filling out Commercial Driver's (CD) Medical Examination Report Forms.MethodsThis was a cross‐sectional retrospective study of abstracted data from the year 2019. CD Medical Examination Report Forms, collected from a single nationally‐based employer and initially reviewed by corporate medical directors, were evaluated by the study team for completeness of documentation provided by both drivers and medical examiners (MEs). Relevant findings included unanswered questions, inconsistency between responses, and lack of necessary elaboration for positive responses.ResultsAmong 1603 examinations, MEs completed the Medical Examination Report Form incompletely or incorrectly in 30% of examinations (n = 484). Drivers inconsistently filled out their health history with elaborations 38.7% of the time. Most commonly, they failed to elaborate on positive health history responses in 28.7% of examinations, but other types of errors were noted as well.ConclusionsA considerable proportion of drivers or examiners (n = 890, 55%) failed to adequately or correctly complete CD Medical Examination Report forms.
Prevalence of COVID‐19 and Long COVID by Industry and Occupation: Behavioral Risk Factor Surveillance System 2022
Authors: Silver S. R. , Li J. , Ford N. D. , Shi D. , Saydah S. H. 
Published: October 2024

ABSTRACTBackgroundWorkers in healthcare and other essential occupations had elevated risks for COVID‐19 infection early in the pandemic. No survey of U.S. workers to date has comprehensively assessed the prevalence of both COVID‐19 and Long COVID across industries and occupations (I&O) at a detailed level.MethodsBehavioral Risk Factor Surveillance System data for 2022 from 39 states, Guam, and the U.S. Virgin Islands were used to estimate prevalence of self‐reported history of COVID‐19 and Long COVID, as well as the prevalence of Long COVID among those reporting prior COVID‐19, by broad and detailed I&O. Adjusted prevalence ratios were used to compare outcome prevalence in each I&O to prevalence among all other workers combined.ResultsBy broad I&O, workers in healthcare, protective services, and education had elevated prevalences of COVID‐19. The prevalence of Long COVID was elevated in healthcare and protective service but not education workers. Detailed I&O with significantly elevated prevalences of COVID‐19 but not Long COVID included Dairy Product Manufacturing industry workers and subsets of mining workers. Both COVID‐19 and Long COVID were elevated among bartenders/drinking places and personal care and appearance workers. The prevalence of Long COVID was elevated among farmworkers who reported having had COVID‐19.ConclusionsIndustries and occupations with elevated levels of COVID‐19 or Long COVID in this study may warrant increased measures to prevent transmission of airborne respiratory viruses. Accommodations are a key component for supporting workers in all workplaces. This new information about the distribution of Long COVID by I&O suggests where employer understanding and implementation of tailored workplace supports and accommodations are most needed to support continued employment of affected workers.
Managing CDH1 Cancer Risks in a Child: Complex Decision Making in a Family With Hereditary Diffuse Gastric Cancer
Authors: Agaoglu Nihat Bugra , Ng Ozden Hatirnaz , Zemheri Itir Ebru , Unal Busra , Gerenli Nelgin , Tosun Ilkay , Yazıcı Hulya , Ozbek Ugur , Kamihara Junne , Rana Huma Q. 
Published: October 2024

ABSTRACTGermline pathogenic variants (PVs) in CDH1 cause hereditary diffuse gastric cancer. The management of CDH1 cases with a positive family history includes total prophylactic gastrectomy or intensive surveillance. In this study, we report a 16‐year‐old boy with intramucosal gastric signet ring cells in the setting of a germline CDH1 PV and a family history of early‐onset gastric cancer. The approach to managing both the proband and their 9‐year‐old sister, who also had the CDH1 PV, presented a challenge to both clinicians and the family. Herein, we present the complexities of managing gastric cancer risk when a CDH1 PV is identified in childhood in the setting of a family history of early‐onset gastric cancer.
A Distinctive Type of Mosaic Variegated Aneuploidy: Case Report and Review of the Literature
Authors: Frattini Annalisa , Micheloni Giovanni , Musio Antonio , Antunes Marika Bini , Barbot José , Costa Emília , Seabra Patricia , Righi Rossana , Orsini Francesco , Montalbano Giuseppe , Acquati Francesco , Porta Giovanni , Pasquali Francesco , Valli Roberto 
Published: October 2024

ABSTRACTMosaic variegated aneuploidy (MVA) is an autosomal recessive disorder characterized by mosaic aneuploidies, predominantly trisomies, involving multiple different chromosomes and tissues. The proportion of aneuploid cells varies, and most patients present with intrauterine growth delay, microcephaly, and a broad spectrum of congenital abnormalities. We report a patient with a distinctive type of MVA discovered in bone marrow (BM) when she was 3‐month‐old due to neutropenia and hypocellular bone marrow. She was followed up for more than 20 years, and different trisomic cells were repeatedly discovered in different tissues, whereas her clinical picture has never been severe. The main sign remained intermittent neutropenia, not cyclic and often not too severe, occasionally with anemia and thrombocytopenia. Retromicrognathia was the only dysmorphic sign. Unlike other patients with MVA, the trisomies in all tissues involved almost invariably chromosomes 18 and 19. Therefore, the peculiarities of our patient were the clinical and the atypical cytogenetic pictures. Nevertheless, we looked for mutations in the seven causative genes of the known types of MVA, but the results were negative. Then, we analyzed the entire exome to find out other possible causing mutations, but also this attempt failed to discover a possible cause of this distinctive form of MVA.
Bullous Lung Disease in Turner Syndrome: An Underrecognized Comorbidity?
Authors: Lu Stevin , Starr Lois J. , Taylor Rachel A. , Yetman Anji T. 
Published: October 2024

ABSTRACTCongenital pulmonary anomalies in Turner syndrome (TS) are rarely reported. Herein, we describe a female with TS who presented with emphysema in infancy and developed pulmonary hypertension in adulthood. A 4‐month‐old patient presented with recurrent emesis and failure to thrive. Diagnostic testing indicated cardiomegaly and echocardiogram revealed abnormalities including left aortic arch with aberrant right subclavian artery, aortic coarctation, and left ventricular (LV) dysfunction. At 19‐months, she underwent surgical intervention through a lateral thoracotomy which exposed numerous small air‐filled blebs over the left lung. She had persistent LV dysfunction postoperatively. At 12‐years‐old, genetic testing revealed 45,X/46,Xidic(Y)(q11.22) and she subsequently received routine treatment for Turner syndrome. At 23‐years‐old, this patient presented to the emergency department with dyspnea, worsening cough, and edema. Echocardiogram demonstrated a reduced LVEF, aortic valve insufficiency, and pulmonary artery (PA) hypertension. CT chest showed multiple apical blebs and cardiac catheterization demonstrated pulmonary hypertension. She was treated with intravenous diuresis and cessation of Humira, which normalized LVEF and reduced PA pressure. Repeat cardiac catheterization 6 months later indicated elevated LVEDP, pulmonary vascular resistance, and mean PA pressures. Altered lymphatic drainage in utero of patients with TS may lead to emphysematous changes in the lungs. These changes may not raise concern in infancy but can possibly contribute to cardiopulmonary pathology in the future. We recommend ongoing routine care to monitor for acquired cardiopulmonary co‐morbidities. Bullous lung disease may occur due to altered lymphatic drainage in patients with TS and may be a risk factor for developing or contributing to pulmonary hypertension.
APOE ε4 carrier status moderates the effect of lifestyle factors on cognitive reserve
Authors: O'Shea Deirdre M. , Zhang Andrea S. , Rader Katana , Shakour Rebecca L. , Besser Lilah , Galvin James E. 
Published: October 2024

AbstractINTRODUCTIONThis study examines the role of lifestyle factors in cognitive reserve among older adults, focusing on the moderating effect of apolipoprotein E (APOE) ε4 status.METHODSData from 157 participants aged 45 and older from the Healthy Brain Initiative (HBI) were analyzed. Cognitive reserve was estimated using residual scores from Cognivue Clarity tests after accounting for brain atrophy and white matter hyperintensities (WMHs). Lifestyle factors included education, occupational attainment, physical activity, social engagement, diet, and mindfulness. Structural equation models were conducted to assess interactions.RESULTSSignificant interactions were found between APOE ε4 status and mindfulness and social engagement on cognitive reserve, indicating stronger associations for APOE ε4 carriers.DISCUSSIONAPOE ε4 carriers may benefit more from certain lifestyle factors, potentially through stress reduction and anti‐inflammatory pathways. These findings support integrating APOE ε4 genetic screening into personalized prevention strategies to enhance interventions aimed at preserving cognitive function and delaying dementia onset in at‐risk populations.Highlights
Mindfulness and social engagement have increased cognitive reserve in APOE ε4 carriers.
Study uses residual scores from Cognivue Clarity tests to estimate cognitive reserve.
APOE ε4 carriers show stronger associations with certain lifestyle factors on cognitive reserve.
Personalized interventions could enhance cognitive resilience in genetically at‐risk populations.
Comprehensive assessment of multiple lifestyle factors highlights targeted intervention benefits.
Mechanical Thrombectomy for Pediatric Stroke: Focal Cerebral Arteriopathy Versus Cardioembolic Etiologies—Pooled Analysis of the Save ChildS and KidClot Cohort
Authors: Boucherit Julien , Psychogios Marios , Kossorotoff Manoëlle , Fiehler Jens , Kerleroux Basile , Kemmling André , Naggara Olivier , Lee Sarah , Nguyen‐Kim Thi Dan Linh , Eugene François , Wildgruber Moritz , Boulouis Gregoire , Sporns Peter B. ,   the Kid Clot and Save ChildS Study Groups
Published: October 2024

BackgroundThe study aimed to compare outcomes of mechanical thrombectomy (MT) in pediatric patients with acute ischemic stroke (AIS) caused by focal cerebral arteriopathy (FCA) versus cardioembolism (CE).MethodsData from the Save ChildS and KidClot cohorts were merged. Children with AIS because of FCA or CE that underwent MT were included. The study used the Childhood Arterial Ischemic Stroke Standardized Classification and Diagnostic Evaluation (CASCADE) for stroke cause assessment. Descriptive statistics and multivariable regression models were used to analyze final modified thrombolysis in cerebral infarction (mTICI) scores, periprocedural complications, and functional outcomes assessed by the modified Rankin scale (mRS) at 6 to 12 months.ResultsThe analysis included 60 children with 14 FCA and 46 CE cases. CE etiology was associated with better revascularization (good to excellent thrombolysis in cerebral infarction scores) and shift toward better outcomes (common adjusted odds ratio of mRs for CE vs FCA: 0.27, 95% CI: [0.06–0.97], p = 0.039), with no difference in favorable outcome rates. FCA was associated with significantly lower rates of excellent revascularization (21% vs 65%, p < 0.001). No difference in complications' rates was observed between the groups (7.2% in FCA vs 5.5%, p = 0.69).InterpretationWe found that pediatric AIS because of CE etiology has more favorable procedural outcomes compared to FCA following MT. This translated to mixed functional outcomes that may be more favorable in the CE group. These findings highlight the need for further research to refine treatment protocols for pediatric stroke, particularly in understanding and managing FCA in children. ANN NEUROL 2025;97:195–201