bluuebunny/crossref_metadata_2025_split huggingface dataset:
Preparation and properties of fluorinated VAc-VeoVa10 latex emulsified with allyl nonyl phenoxy propyl alcohol polyoxyethylene ether ammonium sulphate
Authors: Chen Lijun , Zhao Wanting , Gong Zheqing 
Published: September 2024

Purpose
The traditional VeoVa10-VAc copolymer latex, which prepared via the emulsion polymerization of the mixed monomers of VAc and VeoVa10, has the poor water resistance and thermal stability because of the migration of the conventional emulsifier molecules and the low bond energy of C-C bond. The purpose of this work is that the fluorinated monomer is used to modify the latex. The film of the resultant latex has the C-F bond with high bond energy and low surface energy, which can effectively improve the heat resistance and water resistance of the resultant film. In addition, the reactive emulsifier is used to replace the conventional emulsifier. The drawbacks of the conventional emulsifier molecules migrate and desorb can be avoided when the polymer latex is stored, thereby also improving the water resistance.

Design/methodology/approach
The modified VAc-VeoVa10 latex has been successfully synthesized via the semi-continuous seeded emulsion polymerization, which VAc and VeoVa10 is used as the main monomers and HFMA was used as the functional monomer. KPS and reactive surfactants of SE-10 were used as the initiator and emulsifier, respectively. The structure of resultant latex film was characterized by Fourier transform infrared spectroscopy (FTIR). The latex films were tested by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and contact angle (CA). The particle size and its distribution of the latex were measured by the nano particle size analyzer.

Findings
The factors that had an influence on the properties of the latex and the film were investigated in detail. The stability of the resultant latex is good. The average particles of the latex and its distribution are small and uniform, respectively. In comparison with the conventional latex film, the thermal stability and hydrophobicity of the resultant latex film are improved obviously.

Practical implications
The resultant latex can be used in both the waterborne interior and exterior wall coatings, pickering stabilized waterborne polymer dispersions, polymer powders, environmentally friendly polymer-modified waterproof mortar and other fields, which can be satisfied with the high demand of thermal stability and hydrophobicity.

Originality/value
The modification of poly (VAc-VeoVa10) by reactive surfactant and fluorinated monomer is seldom reported. In this study, the fluorinated poly (VAC-VeoVa) latex is prepared via the reactive surfactants, which VAc and VeoVa10 is used as the main monomers and hexafluorobutyl methacrylate is used as the functional monomer. Potassium persulfate (KPS) and allyl nonyl phenoxy propyl alcohol polyoxyethylene ether ammonium sulfate are used as the initiator and emulsifier, respectively.
A review on sustainability challenges of flame retardants for textiles
Authors: Venant Haule Liberato 
Published: September 2024

Purpose
A review of sustainability challenges of flame retardants (FRs) for textiles has been conducted. Specifically, the purpose of this paper is to identify and recommend solutions to sustainability challenges emanating from the raw material, processing technology and performance of the FRs used for textiles.

Design/methodology/approach
The approach used in preparing this paper was based on the review of various scholarly databases about the subject matter. The review approach is designed to inform the readers about the sustainability challenges of FRs for textiles. The science of burning and FRs for synthetic and cellulosic fibres were reviewed. Both synthetic and natural biodegradable FRs for textiles has been identified. The obtained literature was then synthesised to get information about sustainable challenges of non-halogenated FRs both synthetic and natural biodegradable. Finally, possible approaches for mitigating the identified challenges have been recommended.

Findings
The sustainability challenges of the FRs in terms of raw material, processing, affordability and performance have been identified. Synthetic FRs suffer from sustainability challenges in terms of raw materials, processing and non-renewability. Despite the environmental friendliness and sustainability in terms of being renewability, processability and biodegradability, natural biodegradable FRs have poor performance compared to synthetic ones. Moreover, natural biodegradable FRs depend on geographical condition and lack economic variability data. Potentially, the challenges of FRs can be mitigated through eco-friendly synthesis, chemical modification and sustainable methods of applications. Because of its renewability and environmental friendliness, biodegradable FRs have a potential to becoming sustainable if researched more.

Originality/value
In this review, a collection of literature about sustainability challenges of FRs and the approaches to overcome the challenges has been provided. The collected information was analysed and synthesised to bring understanding of the science of burning, types and application of FRs for textiles and biodegradable FRs. Sustainability challenges have been identified, and mitigation approaches are provided.
Budworms, beetles and wildfire: Disturbance interactions influence the likelihood of insect‐caused disturbances at a subcontinental scale
Authors: Howe Michael , Hart Sarah J. , Trowbridge Amy M. 
Published: September 2024

Abstract

Irruptive forest insects are a leading biotic disturbance across temperate and boreal forests. Outbreaks of forest insects are becoming more frequent and extensive due to anthropogenic drivers (e.g. climate and land‐use), perhaps increasing the likelihood that forests will experience multiple insect‐caused disturbances.

Across the fire‐prone Douglas‐fir forests of western North America, recent outbreaks of the western spruce budworm and Douglas‐fir beetle have impacted large expanses of forests, with a higher degree of overlap than expected in some ecoregions. Outbreaks of both insects are positively related to host availability and exhibit density‐dependent population dynamics that are affected by climate and weather.

Here, we leverage data from aerial detection surveys, estimates of host availability, climate and weather, and categorized fire severity to describe the spatial overlap between western spruce budworm and Douglas‐fir beetle and assess: (1) how climate and host availability influence the biogeography of outbreaks; (2) how weather incites outbreaks; and finally, (3) how prior disturbances (fire and biotic) affect the subsequent outbreak likelihood of western spruce budworm and Douglas‐fir beetle.

Models demonstrate that western spruce budworm and Douglas‐fir beetle share similar predisposing drivers of outbreaks. Outbreaks of both insects were more likely to occur following warm weather, but only beetle outbreaks were more likely following drought. When controlling for differences in outbreak distribution and inciting factors, results indicate that both prior fire and interspecific disturbance altered the likelihood of subsequent insect‐caused disturbance.

Specifically, Douglas‐fir beetle outbreaks were more likely to occur for several years following low severity fire, but less likely otherwise. Prior defoliation, especially longer duration defoliation, increased the likelihood of beetle outbreak within stands and across the landscape. On the contrary, western spruce budworm outbreaks were less likely to occur following fire, while prior beetle activity dampened budworm outbreak likelihood for several years, and then eventually increased outbreak likelihood.

Synthesis: Biotic–biotic disturbance interactions have the potential to amplify the incidence of insect‐caused disturbance across subcontinental scales. Our findings highlight the need for future work on mechanistic linkages between biotic disturbance agents as well as the ramifications for forest trajectories and function.
Rural but not radical right: The rural‐urban cleavage in Norway
Authors: Auerbach Kiran R. , Eidheim Marta R. , Fimreite Anne L. 
Published: September 2024

AbstractConventional wisdom claims that rural voters are politically mobilized by right‐wing and culturally conservative forces, while urban voters are left‐leaning and have progressive cultural views. Leveraging original survey data from Norway, our work challenges this dichotomy. We build on cleavage theory and recent research on place identitiesto develop a latent measure of rural attachment. Using regression analysis, we investigate how well this measure maps onto five different cultural attitudes, left‐ right ideology, and partisan voting. The findings show that people with rural identities are not more right‐wing, reluctant towards immigration, or anti‐environmental than their urban counterparts. Instead, the geographic cleavage relates to dissatisfaction with the way the central government treats rural areas, resistance to the EU, and voting for the agrarian Center Party. The findings from Norway therefore show that it is possible to mobilize rural identifiers without disparaging immigrants or adopting other radical‐right stances. Our work suggests that the supply of political parties plays a decisive role in how rural identities are activated and contributes to a more nuanced understanding of the urban‐rural divide in advanced, multi‐party democracies.
DentAge: Deep learning for automated age prediction using panoramic dental X‐ray images
Authors: Bizjak Žiga , Robič Tina 
Published: September 2024

AbstractAge estimation plays a crucial role in various fields, including forensic science and anthropology. This study aims to develop and validate DentAge, a deep‐learning model for automated age prediction using panoramic dental X‐ray images. DentAge was trained on a dataset comprising 21,007 panoramic dental X‐ray images sourced from a private dental center in Slovenia. The dataset included subjects aged 4 to 97 years with various dental conditions. Transfer learning was employed, initializing the model with ImageNet weights and fine‐tuning on the dental image dataset. The model was trained using stochastic gradient descent with momentum, and mean absolute error (MAE) served as the objective function. Across the test dataset, DentAge achieved an MAE of 3.12 years, demonstrating its efficacy in age prediction. Notably, the model performed well across different age groups, with MAEs ranging from 1.94 (age group [10–20]) to 13.40 years (age group [90–100]). Visual evaluation revealed factors contributing to prediction errors, including prosthetic restorations, tooth loss, and bone resorption. DentAge represents a significant advancement in automated age prediction within dentistry. The model's robust performance across diverse age groups and dental conditions underscores its potential utility in real‐world scenarios. Our model will be accessible to the public for further adjustments and validation, ensuring DentAge's effectiveness and trustworthiness in practical scenarios.
Psychosis Prognosis Predictor: A continuous and uncertainty‐aware prediction of treatment outcome in first‐episode psychosis
Authors: van Opstal Daniël P. J. , Kia Seyed Mostafa , Jakob Lea , Somers Metten , Sommer Iris E. C. , Winter‐van Rossum Inge , Kahn René S. , Cahn Wiepke , Schnack Hugo G. 
Published: September 2024

AbstractIntroductionMachine learning models have shown promising potential in individual‐level outcome prediction for patients with psychosis, but also have several limitations. To address some of these limitations, we present a model that predicts multiple outcomes, based on longitudinal patient data, while integrating prediction uncertainty to facilitate more reliable clinical decision‐making.Material and MethodsWe devised a recurrent neural network architecture incorporating long short‐term memory (LSTM) units to facilitate outcome prediction by leveraging multimodal baseline variables and clinical data collected at multiple time points. To account for model uncertainty, we employed a novel fuzzy logic approach to integrate the level of uncertainty into individual predictions. We predicted antipsychotic treatment outcomes in 446 first‐episode psychosis patients in the OPTiMiSE study, for six different clinical scenarios. The treatment outcome measures assessed at both week 4 and week 10 encompassed symptomatic remission, clinical global remission, and functional remission.ResultsUsing only baseline predictors to predict different outcomes at week 4, leave‐one‐site‐out validation AUC ranged from 0.62 to 0.66; performance improved when clinical data from week 1 was added (AUC = 0.66–0.71). For outcome at week 10, using only baseline variables, the models achieved AUC = 0.56–0.64; using data from more time points (weeks 1, 4, and 6) improved the performance to AUC = 0.72–0.74. After incorporating prediction uncertainties and stratifying the model decisions based on model confidence, we could achieve accuracies above 0.8 for ~50% of patients in five out of the six clinical scenarios.ConclusionWe constructed prediction models utilizing a recurrent neural network architecture tailored to clinical scenarios derived from a time series dataset. One crucial aspect we incorporated was the consideration of uncertainty in individual predictions, which enhances the reliability of decision‐making based on the model's output. We provided evidence showcasing the significance of leveraging time series data for achieving more accurate treatment outcome prediction in the field of psychiatry.
A matter of trust? Analyzing the relationship between attitudes toward COVID‐19 countermeasures and right‐wing ideology in Germany
Authors: Klebba Lea‐Johanna , Winter Stephan 
Published: September 2024

AbstractThe COVID‐19 pandemic has divided societies, especially regarding vaccine mandates. While research suggests that political ideology plays a crucial role in whether people support or oppose COVID‐19 countermeasures, the relationship between these attitudes and political ideology remains unclear, with varying results across different countries. The present research focuses on right‐wing authoritarianism (RWA) in Germany, examining its role as a predictor. Prior studies highlight that, conservatives and right‐wing authoritarians, particularly in the USA, tend to hold more negative attitudes toward COVID‐19 countermeasures despite RWA's usual association with unwavering support for state authorities. Therefore, the present survey study (N = 1063) investigated whether trust in politics and science moderates this relationship. Contrary to expectations, the findings revealed that RWA consistently predicted support for vaccine mandates independent of trust levels. Results are discussed about the specifics of the German case and more general relationships between political ideology and the support of state authorities.
Impact of codeine rescheduling on prescribing of codeine and other opioids: Interrupted time series analyses using Australian general practice data
Authors: Cangadis‐Douglass Helena , Xia Ting , Bell J. Simon , Nielsen Suzanne 
Published: September 2024

AbstractAimsWe aimed to determine the impact of codeine rescheduling on prescribing of codeine and other opioids, with a focus on demographic and diagnoses associated with codeine prescribing before and after rescheduling of codeine to prescription‐only in February 2018.MethodsWe used interrupted time series analysis (February 2016‐February 2020) and probit regression to examine prescribing of codeine and other opioids according to primary care data from 464 general practice clinics in Victoria, Australia.ResultsThe rate of codeine prescribing increased in the month following rescheduling (additional 76 people/10000, 95% confidence interval [CI] 49‐103), then declined to baseline rates (slope −2.02, 95% CI 3.79, −0.25). Prescribing of other opioids did not change. Post rescheduling, females were more likely to receive codeine prescriptions compared to males (β = 0.094, 95% CI 0.08‐0.108) and those aged 70‐79 years were more likely to receive codeine compared to those aged <30 years. Those residing in the least disadvantaged areas had a greater probability of being prescribed codeine than those in more disadvantaged areas after rescheduling (β = 0.154, 95% CI 0.129‐0.179). A documented mental health diagnosis (β = 0.067, 95% CI 0.052‐0.082) or migraine diagnosis (β = 0.057, 95% CI 0.037‐0.078) was associated with increased likelihood of receiving a codeine prescription after rescheduling compared to before in contrast to those without such a diagnosis.ConclusionCodeine rescheduling did not result in a sustained increase in codeine prescribing nor a change in the prescribing of other opioids. Patient factors associated with increased codeine prescribing after compared to before rescheduling included female sex, older age, migraine diagnosis and comorbid mental health conditions.RegistrationEU PAS Register (EUPAS43218).
A randomized phase I study of the safety and pharmacokinetics of BI 1291583 in healthy Japanese male subjects
Authors: Tadayasu Yusuke , Sarubbi Donald , Furuichi Takumi , Eleftheraki Anastasia , Nakamura Shuhei , Sauter Wiebke , Hanada Ryuzo 
Published: September 2024

AimsBronchiectasis patients face an unmet need for treatment options that reduce inflammation. Cathepsin C inhibition is expected to achieve this by reducing the activation of neutrophil‐derived serine proteases. Here, we present safety and pharmacokinetic (PK) data from a Phase I trial evaluating the novel cathepsin C inhibitor BI 1291583 in healthy Japanese male subjects.MethodsThis randomized, double‐blind, placebo‐controlled, parallel‐group study investigated BI 1291583 in healthy Japanese male subjects (jRCT2071210111) and consisted of a single‐rising‐dose (SRD) part and a multiple‐dose (MD) part. The primary endpoint was the percentage of subjects with drug‐related treatment‐emergent adverse events (AEs). Secondary PK endpoints (SRD: AUC0‐∞ and Cmax; MD: AUCτ,1 and Cmax,1 after first dose and AUCτ,ss and Cmax,ss after last dose), as well as further safety and PK endpoints, were also assessed.ResultsOverall, 36 subjects (n = 24 for SRD part; n = 12 for MD part) entered this Phase I trial. BI 1291583 was safe and well tolerated across the doses tested. All AEs were of mild intensity, with no drug‐related treatment‐emergent AEs, deaths, serious AEs or AEs of special interest reported in either part of the trial. Following both SRD and MD administration, BI 1291583 was readily absorbed, and PK was supraproportional over the doses assessed.ConclusionThe results show that BI 1291583 has an appropriate benefit–risk ratio for Japanese patients, with no safety or exposure concerns at the doses studied. Japanese patients with bronchiectasis can be safely integrated into future global clinical trials of BI 1291583, with no dose adjustment required.
Hierarchical Spherical Cross‐Parameterization for Deforming Characters
Authors: Cao Lizhou , Peng Chao 
Published: September 2024

AbstractThe demand for immersive technology and realistic virtual environments has created a need for automated solutions to generate characters with morphological variations. However, existing approaches either rely on manual labour or oversimplify the problem by limiting it to static meshes or deformation transfers without shape morphing. In this paper, we propose a new cross‐parameterization approach that semi‐automates the generation of morphologically diverse characters with synthesized articulations and animations. The main contribution of this work is that our approach parameterizes deforming characters into a novel hierarchical multi‐sphere domain, while considering the attributes of mesh topology, deformation and animation. With such a multi‐sphere domain, our approach minimizes parametric distortion rates, enhances the bijectivity of parameterization and aligns deforming feature correspondences. The alignment process we propose allows users to focus only on major joint pairs, which is much simpler and more intuitive than the existing alignment solutions that involve a manual process of identifying feature points on mesh surfaces. Compared to recent works, our approach achieves high‐quality results in the applications of 3D morphing, texture transfer, character synthesis and deformation transfer.
The role of visitor studies in shaping visitor‐centered museums
Authors: Hayde Donnelley , Weiss Laura , Meyer Justin Reeves 
Published: September 2024

AbstractVisitor studies are an important source of knowledge within museum practice: They inform what we believe about our audiences, what kinds of interpretation we develop, and how we conceptualize success. As visitor studies professionals, we see firsthand that the ways we gather data have implications for how we and our colleagues view visitors and how visitors perceive our institutions. Meanwhile, we also see opportunities for visitor studies within museums' broader aspirations to become more visitor‐centered, as defined by meaningful two‐way engagement with visitors. Using real‐world project examples, this paper explores possibilities for moving toward a more visitor‐centered approach to data collection, in which practitioners can more clearly privilege meaning, transparency, and care. As starting points, we suggest that active attention to four considerations should inform more visitor‐centered visitor studies: comfort (i.e., the well‐being of people); context (i.e., the circumstances of museum experiences and study implementation); flexibility (i.e., responsiveness to dynamics that imply a need for change); and value (i.e., supporting relations of mutual benefit).
Beyond Compensation: Reparations and the Ongoing Colonization of Australia
Authors: Klein Elise 
Published: September 2024

ABSTRACTThis article examines the relationship between reparations as compensation and reparations as transformation in settler colonial Australia. Much of the global reparations debate on colonization and slavery has focused on important demands confronting the historic damages and ongoing accumulation of disadvantage from colonization in ex‐colonies or from plantation slavery. Much less has been said about reparations for settler colonialism which is a specific form of ongoing colonization in the here and now. Drawing on long‐standing work around reparations for colonization by Indigenous peoples in Australia, and the woeful compensatory responses the state and judiciary have offered, this article argues that reparations for ongoing colonization could consider options beyond monetary compensation. This includes the critical domain of reparations as transformation that aim less to offset damage and reconcile suffering, but rather to comprehensively transform colonial relations.