bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Reaction of Dimethyl(chloromethyl)chlorosilane with Trimethylsilyl Derivatives of 1‐Phenyl‐2‐acetyl and 1‐Phenyl‐2‐trifluoroacetylhydrazines.
Authors: KALIKHMAN I. L. , BANNIKOVA O. B. , VOLKOVA L. I. , BELOYSOVA L. I. , YUSHMANOVA T. I. , LOPYREV V. A. , VYAZANKINA O. A. , VYAZANKIN N. S. , PESTUNOVICH V. A. 
Published: May 2016

AbstractThe hydrazones (I) react with the silane (II) to give the transsilylation products (III).
ChemInform Abstract: An Unusual Substitution Reaction at a Twofold Coordinate Phosphorus Atom.
Authors: ROMANENKO V. D. , DRAPAILO A. B. , RUBAN A. V. , MARKOVSKII L. N. 
Published: May 2016

AbstractReaction of the iminophosphine (I) with the N‐haloamines (II) gives the aminoiminophosphines (III) which are also synthesized from the phosphorous amide dichloride (IV) and the silylamide (V).
ChemInform Abstract: Synthesis of Substituted Alkoxymethylphosphines and Their Derivatives.
Authors: LIVANTSOV M. V. , PRISHCHENKO A. A. , LUTSENKO I. F. 
Published: May 2016

AbstractThe alkoxymethylphosphines (III) are synthesized from the chlorophosphines (I) and the Grignard compounds (II).
ChemInform Abstract: Synthesis of Phosphorylated Nitrones by Reaction of α‐Oximinophosphonates with Diazoalkanes.
Authors: KHOKHLOV P. S. , MIKITYUK A. D. , KASHEMIROV B. A. , CHERVIN I. I. , KOSTYANOVSKII R. G. 
Published: May 2016

AbstractReaction of the oximinophosphonates (I) with diazomethane yields the phosphorylated nitrones (II) and the oxime ethers (III).
ChemInform Abstract: Phosphite‐Phosphonate of Pentaerythrol.
Authors: GUBAIDULLIN R. N. , MUKMENEV E. T. 
Published: May 2016

AbstractThe diphosphite (I) reacts with two moles ethyl bromide (II) to give the phosphite‐phosphonate (III) and the isomeric spirocyclic diphosphonate (IV).
ChemInform Abstract: An Oligomer of 5,6‐Benzo‐1,3,2‐oxazaphosphorin‐4‐one and Some of Its Properties.
Authors: KULIEV A. K. , MOSKVA V. V. , AKHMEDZADE D. A. , PUDOVIK M. A. 
Published: May 2016

AbstractDehydrochlorination of the phosphorinane (I) gives the oligomeric benzoxazaphosphorines (II).
ChemInform Abstract: Stereoselection in the Hypervalent Iodine Oxidation of Chromium Tricarbonyl Complexes of Benzocyclanones.
Authors: MORIARTY R. M. , ENGERER S. C. , PRAKASH O. , PRAKASH I. , GILL U. S. , FREEMAN W. A. 
Published: May 2016

AbstractOxidation of the tricarbonylchromium complexes (I) of aromatic ketones with iodobenzene diacetate (II) in methanol stereoselectively produces the complexed α‐hydroxy acetals (III).
ChemInform Abstract: Phosphorus‐Tellurium Compounds. Part 3. Cyclopentadienyliron Tellurophosphorane Complexes: Tellurium‐Bridged Iron Phosphine Compounds?
Authors: KUHN N. , SCHUMANN H. 
Published: May 2016

AbstractThe tellurophosphoranes (II) react with the cation (I) to yield the complexes (III).
ChemInform Abstract: Transition‐Metal Compounds of Two Tetradentate Pyrazole Derivatives of Piperazine.
Authors: LOCHER K. , DRIESSEN W. L. , REEDIJK J. 
Published: May 2016

AbstractThe N,N'‐bis(pyrazolylmethyl)piperazines R4L1, newly synthesized from corresponding N‐hydroxymethylpyrazoles and piperazine, form with transition‐metal salts complexes of the type (I), (II), and (III).
ChemInform Abstract: Dinuclear Palladium(II) Complex of Pyridine‐2‐thiol.
Authors: UMAKOSHI K. , KINOSHITA I. , OOI S. 
Published: May 2016

AbstractThe reaction of palladium(II) acetate with pyridine‐2‐thiol in dioxane at room temp. yields the cis‐isomer of a complex, whose structure is formulated as the dimer (I) by single‐crystal X‐ray analysis (P21/c; Z=2).
ChemInform Abstract: Complexes of Hybrid Ligands. Synthesis, Reactions, and Structures of Platinum Complexes Derived from a Diphenylphosphino‐Substituted Fluorinated Tertiary Alcohol.
Authors: MONTGOMERY C. D. , PAYNE N. C. , WILLIS C. J. 
Published: May 2016

AbstractThe Pt(II) complexes (II), (III), (IV), (VI), and (VIII) are prepared as shown.
ChemInform Abstract: A Short, Efficient Synthesis of (.+‐.)‐Valerane.
Authors: GARRATT P. J. , PIELKE M. , PORTER J. R. 
Published: May 2016

AbstractDilithiated dimethyl 1,2‐cyclohexanedioate (I) is coupled with the diiodide (II) to give the isomeric diesters (III) which are reduced to give the isomeric diols (IV).
ChemInform Abstract: New Trihydroxy Bile Acids Produced by Cunninghamella blakesleeana ST‐22 from Lithocholic Acid.
Authors: JODOI Y. , NIHIRA T. , NAOKI H. , YAMADA Y. , TAGUCHI H. 
Published: May 2016

AbstractThe microbiological transformation of lithocholic acid (I) by the title fungus first yields the dihydroxy acid (II) which is further metabolized to give the trihydroxy acids (III)‐(V).
ChemInform Abstract: The Use of Crown Ethers in Peptide Chemistry. Part 1. Syntheses of Amino Acid Complexes with the Cyclic Polyether 18‐Crown‐6 and Their Oligomerization in Dicyclohexylcarbodiimide‐Containing Solutions.
Authors: MASCAGNI P. , HYDE C. B. , CHARALAMBOUS M. A. , WELHAM K. J. 
Published: May 2016

AbstractThe amino acid complexes (I) and (II) with the cyclic polyether 18‐crown‐6 are prepared with 77‐97% yield.
ChemInform Abstract: 3‐(Dimethylamino)‐2,2‐dimethyl‐2H‐azirine as an α‐Aminoisobutyric‐Acid (Aib) Equivalent: Cyclic Depsipeptides via Direct Amide Cyclization.
Authors: OBRECHT D. , HEIMGARTNER H. 
Published: May 2016

AbstractThe diamides (III) which are accessible by the reported reaction of the title compound (I) with the hydroxy acids (II) react to give the morpholinediones (V) by treatment with HCl/toluene.
ChemInform Abstract: Octahydropyrazino(2′,3′:3,4)pyrido(1,2‐a)indoles. A New Class of Potent Antihypertensive Agents.
Authors: JIRKOVSKY I. , SANTROCH G. , BAUDY R. , OSHIRO G. 
Published: May 2016

AbstractCyclization of 3‐methylindole (I) yields the ketone (II) which is converted to the pyrazinopyridoindoles (V).
ChemInform Abstract: Synthesis and Antiviral Activity of Various 3′‐Azido, 3′‐Amino, 2′,3′‐ Unsaturated, and 2′,3′‐Dideoxy Analogues of Pyrimidine Deoxyribonucleosides Against Retroviruses.
Authors: LIN T.‐S. , CHEN M. S. , MCLAREN C. , GAO Y.‐S. , GHAZZOULI I. , PRUSOFF W. H. 
Published: May 2016

AbstractAnalogues of pyrimidine deoxyribonucleosides such as (II), (Vb), (VIII), (IX), and (X) are prepared and their antiviral activities against Moloney‐murine leukemia virus and HTLV‐III/LAV/AAV virus are determined.
ChemInform Abstract: 5‐Amino‐5‐(diazoacetyl)‐1‐β‐D‐ribofuranosylimidazole, a New Antileukemia Agent.
Authors: THOMAS H. J. , AVERY L. N. , BROCKMAN R. W. , MONTGOMERY J. A. 
Published: May 2016

AbstractThe amino‐β‐D‐ribofuranosylimidazole‐4‐carboxamide (I) is converted into the derivatives (VI) and (VII) as outlined in the reaction scheme.
ChemInform Abstract: Synthesis of 6‐Thiosialic Acids and 6‐Thio‐N‐acetyl‐D‐neuraminic Acid.
Authors: MACK H. , BROSSMER R. 
Published: May 2016

AbstractThe 6‐thiosialic acids (V) and (VI) and 6‐thio‐N‐acetyl‐D‐neuraminic acid (Xa) are prepared and some transformations of the compound (Xa) are studied, as outlined in the reaction scheme.
ChemInform Abstract: Hydrothermal Reactions in the SrO‐Al2O3‐H2O System
Authors: AHMED A. H. M. , SIKDER A. P. , MANDAL R. , BARMAN A. K. 
Published: May 2016

Abstractusing different SrO/Al2O3 ratios are carried out at temp. in the range 20‐200 °C under saturated steam pressure and the products are identified by chemical analysis, XRD, IR‐spectroscopy, and thermogravimetry.
ChemInform Abstract: The Effects of Adding Tl(I) to the Electrolyte on the Electrochemical and Photoelectrochemical Behaviour of Passivated Lead in H2SO4 in the Potential Range Between the PbSO4/PbO and PbO2/O2 Regions.
Authors: BARRADAS R. G. , NADEZHDIN D. S. 
Published: May 2016

AbstractThe presence of Tl(I) in the H2SO4 electrolyte inhibits β‐PbO2 formation to some degree, lowers the O2 evolution potential on PbO2 and decreases the rate of cathodic PbO2 reduction significantly.
ChemInform Abstract: Reactions of Crystalline (R)‐(‐)‐ and (S)‐(+)‐Mandelic Acid with Amines. Crystal Structure and Dipole Moment of (S)‐Mandelic Acid. A Method of Determining Absolute Configuration of Chiral Crystals.
Authors: PATIL A. O. , PENNINGTON W. T. , PAUL I. C. , CURTIN D. Y. , DYKSTRA C. E. 
Published: May 2016

AbstractThe known phenomenon that gaseous (R)‐(I) reacts more quickly with single crystals of (S)‐(II) than its enantiomer (S)‐(I) is studied (furthermore, brief descriptions of the microscopically observed solid‐gas reactions of (S)‐(II) with (III) are given).
ChemInform Abstract: New Syntheses with α‐Acylketenimines and α‐Acylketenes.
Authors: CAPUANO L. , DJOKAR K. , SCHNEIDER N. , WAMPRECHT C. 
Published: May 2016

AbstractReaction of the acylketenimines (III) ‐ generated in situ from (Ia) or (Ib) and (II) ‐ with the ketene diacetal (V) or the enamine (VI) yields the iminopyrans (IV).
ChemInform Abstract: The Reaction of Sodium 1,3‐Diphenyl‐2‐azapropenide with 1,2‐Epoxycyclohexane.
Authors: BRADAMANTE S. , FERRACCIOLI R. , PAGANI G. A. 
Published: May 2016

AbstractRing opening of the epoxycyclohexane (I) with the title anion generated from (IV) by method A) affords a mixture of anions, the quenching and hydrolysis of which under various conditions leads to the products (V)‐(IX) (yields in g).
ChemInform Abstract: Reaction of Singlet Oxygen with Methylenecyclopropanes: Formation of 4‐Methylene‐1,2‐dioxolanes.
Authors: AKASAKA T. , ANDO W. 
Published: May 2016

AbstractThe fused methylenecyclopropanes (I), (IV), and (VI) react with singlet oxygen to give the photooxygenation products (II), (V) or (VII) and (VIII), together with traces of 2‐adamantanone (III).
ChemInform Abstract: Organic Reactions at High Pressure. Conversion of Cyclic Alkanones and Enones to 1,3‐Dioxolanes.
Authors: DAUBEN W. G. , GERDES J. M. , LOOK G. C. 
Published: May 2016

AbstractTwo procedures for the conversion of sterically hindered or less reactive ketones to the corresponding dioxolanes using high pressure are carried out as shown in the reaction scheme.
ChemInform Abstract: Carbon‐Carbon Bond Formation Using Hypervalent Iodine Under Lewis Acid Conditions: Scope of the Method for the Synthesis of Butane‐1,4‐diones.
Authors: MORIARTY R. , PRAKASH O. , DUNCAN M. P. 
Published: May 2016

AbstractHypervalent iodine oxidation of the silyl enol ethers (I) derived from various acetyl arenes yields the butanediones (II).
ChemInform Abstract: Polysulfide‐Promoted Conversions of Ene Carbonyls. Arrangements of o‐Methoxy‐Substituted Chalcone Units Incorporated into Product Thiolanes.
Authors: LALONDE R. T. , CODACOVI L. M. , HE C. , XU C. , CLARDY J. , KRISHNAN B. S. 
Published: May 2016

AbstractThe chalcones (I) react with sodium polysulfide to give the thiolanes (II) and (III).
ChemInform Abstract: Studies on Pyrrolidinones. Michael Reaction of Glutamic Acid and Diethyl Glutamate.
Authors: RIGO B. , COUTURIER D. , KOLOCOURIS N. 
Published: May 2016

AbstractThe pyroglutamic acid (I) is converted to the diester (IIa) which is hydrolyzed to form the dicarboxylic acid (IIb).
ChemInform Abstract: A Direct Preparation of 2‐Aryl‐4‐ethoxycarbonyl‐3‐pyrazolin‐5‐ones from Aryl Hydrazines.
Authors: TAYLOR A. W. , COOK R. T. 
Published: May 2016

AbstractReaction of the hydrazine (Ia) with the diester (II) in tBuOK/tBuOH yields the desired title compound (IIIa) in poor yield.
ChemInform Abstract: Reaction of 2‐Thiopyrrolidones with Monochloroacetic Acid and Its Methyl Ester.
Authors: BESPALOVA G. V. , SEDAVKINA V. A. , PONOMAREVA E. V. , SHEBALDOVA A. D. , LABUNSKAYA V. I. 
Published: May 2016

AbstractThe thiopyrrolidone (I) reacts with chloroacetic acid (IIa) and its methyl ester (IIb) to give the S‐alkylation products (III) or the bicyclic compound (IV) depending on the reaction conditions.
ChemInform Abstract: Synthesis of Pyrido(1′,2′:1,2)imidazo(4,5‐b)pyrazines from 2‐Amino‐3chloro‐5,6‐dicyanopyrazine with Substituted Pyridines.
Authors: MITSUHASHI K. , NAGAE Y. , SUZUKI T. 
Published: May 2016

Abstract2,3‐Dichloro‐5,6‐dicyanopyrazine (I) is converted to the monoamine (II) which couples with the pyridines (III), yielding the pyridoimidazopyrazines (IV).
ChemInform Abstract: Intramolecular Sulphonyl‐Amidomethylation. Part 1. Cyclization of Benzylsulphonamides.
Authors: ORAZI O. O. , CORRAL R. A. , BRAVO R. 
Published: May 2016

AbstractReaction of the benzylsulfonamides (I) with the aldehydes (II) in the presence of strong acids yields the tetrahydrobenzothiazine dioxides (III) or the kinetically favoured products (IV) depending on the reaction conditions.
ChemInform Abstract: Antitumor Imidazotetrazines. Part 12. Reactions of Mitozolomide and Its 3‐Alkyl Congeners with Oxygen, Nitrogen, Halogen, and Carbon Nucleophiles.
Authors: BAIG G. U. , STEVENS M. F. G. 
Published: May 2016

AbstractThe 3‐alkyl congeners (Ia) of the antitumor agent (Ic) ring‐open in aqueous Na2CO3 or in alcohols (III) to form the products (II), (IV) or (V) (most yields in g).
ChemInform Abstract: Organoboranes. Part 50. Preparation and Characterization of Organyl‐1‐alkynylborinic Esters.
Authors: BROWN H. C. , SREBNIK M. 
Published: May 2016

AbstractThe title esters (IV) are obtained in high purity and yield by addition of a lithioacetylide (II) to a boronic ester (I), followed by treatment with either HCl in ether or acetyl chloride.
ChemInform Abstract: Reaction of (Arylthio(chloro)methyl)trimethylsilanes with Arenes and Alk‐1‐enes in the Presence of Lewis Acid: Syntheses of (Aryl(arylthio)methyl)‐ and (1‐Arylthioalk‐3‐enyl)‐trimethylsilanes.
Authors: ISHIBASHI H. , NAKATANI H. , UMEI Y. , YAMAMOTO W. , IKEDA M. 
Published: May 2016

AbstractTreatment of the electron‐rich arenes (I) and the trimethylsilanes (II) with a Lewis acid gives the Friedel‐Crafts products (III), which undergo desulfurization to afford (IV).
ChemInform Abstract: Ambident Reactivity of Diphenylphosphinous and Phenylphosphonous Amides in Reactions with N‐Acetoxymethyl Substituted Diethylamine, Benzamide, and Acetamide.
Authors: IVANOV B. E. , KROKHINA S. S. , CHICHKANOVA T. V. , AGEEVA A. B. 
Published: May 2016

AbstractThe aminomethylacetates (I) react with the phosphonous or phosphinous amides (II) to give the Arbuzov‐type products (III) or the mixed anhydrides (IV) depending on the substituents in (I).
ChemInform Abstract: Selenoglucosinolates: Synthesis and Enzymatic Hydrolysis.
Authors: KJAER A. , SKRYDSTRUP T. 
Published: May 2016

AbstractThe corresponding selenolate anion generated from the isoselenurium salt (I) reacts with the hydroximinoyl chloride (II) to give the crystalline hydroximate (III) which can be transformed to the benzylselenoglucosinolate (Va) via the intermediate (IVa).
ChemInform Abstract: Metal Complexes of Some 5‐Nitrosopyrimidine Derivatives.
Authors: CRUZ‐BERMUDEZ G. , GARCIA‐RODRIGUEZ A. , MORENO‐CARRETERO M. , SALAS‐PEREGRIN J. M. , VALENZUELA‐CALAHORRO C. 
Published: May 2016

AbstractThe complexes (I) and (II) are prepared by 1:2 molar reaction of corresponding metal chlorides with 6‐amino‐1,3‐dimethyl‐5‐nitrosouracil or 1,3‐dimethyl violuric acid in aqueous or ethanolic solution.
ChemInform Abstract: Synthesis of 2,6‐Dimethyl‐6‐(8‐methyl‐4‐methylene‐7‐nonenyl)‐2‐cyclohexene‐1‐methanols from α‐Santonin.
Authors: NAGANO H. , MASUNAGA Y. , MATSUO Y. , SHIOTA M. 
Published: May 2016

AbstractThe eudesmanolides (I) (prepared by a known procedure from α‐santonin) are converted to the title compounds (XI) as shown in the scheme.
ChemInform Abstract: Antimycotic Imidazolyl‐alkenes: Synthesis and X‐Ray Crystal Structure of Omoconazol.
Authors: THIELE K. , ZIRNGIBL L. , PFENNINGER M. H. , EGLI M. , DOBLER M. 
Published: May 2016

AbstractReaction of the ketone (I) with the bromide (II) followed by treatment with HNO3 yields the salt (IIIa)·HNO3 as major product (yield given in g for (IIIb)·HNO3).
ChemInform Abstract: Electrolyte Solutions in Liquid Ammonia. Part 9. Electrodeposition and Electrodissolution of Metals from Their Salts
Authors: GILL J. B. , HALL M. , MACINTOSH D. 
Published: May 2016

AbstractReview: (a survey of the anodic dissolution and cathodic deposition of 20 transition metals in acidic solutions in NH3(l).
ChemInform Abstract: EPR and Ligand Field Spectra of Chlorovanadates(IV). Crystal Structure of PPh4(VxTi2‐xCl9) (x = 0.15).
Authors: FRIEBEL C. , SCHERFISE K.‐D. , WILLING W. , MUELLER U. + , DEHNICKE K. 
Published: May 2016

AbstractAddition of CCl4 to a solution of TiCl4 and PPh4(VCl5) in CH2Cl2 results in the precipitation of the title compound (yield 52%).
ChemInform Abstract: Reaction of OH with ClNO: Kinetics and Mechanisms
Authors: FINLAYSON‐PITTS B. J. , EZELL M. J. , WANG S. Z. , GRANT C. E. 
Published: May 2016

Abstracthave been studied in a fast flow discharge system with resonance fluorescence detection of the OH (formed by reaction of H with NO2) decay in excess ClNO (262‐373 K).
ChemInform Abstract: Arsenate Hydroxyapatite: a Physico‐Chemical and Thermodynamic Investigation.
Authors: MAHAPATRA P. P. , MAHAPATRA L. M. , MISHRA B. 
Published: May 2016

AbstractA pure and homogeneous sample of arsenate hydroxyapatite (I) is synthesized by precipitation from an aqueous solution of Ca(NO3)2 and (NH4)2HAsO4 at 100 °C and pH 12. (I) is found to be isomorphous with hydroxyapatite belonging to the space group P63/m. Between 308 and 323 K in the pH range 4.0‐8.0 it shows a decreasing trend in solubility with increasing pH and temperature.
ChemInform Abstract: New Nesozincates: K4(ZnO3), Rb7Na(ZnO3)2.
Authors: BAIER R. , HOPPE R. 
Published: May 2016

AbstractPowders of the title compounds have been prepared by annealing stoichiometric mixtures of the binary oxides (Ag crucible, Ar atmosphere, 450 °C (Rb7Na(ZnO3)2: 500 °C), 14 d, no yields given).
ChemInform Abstract: The Anomeric Effect in Seven‐Membered Rings: A Conformational Study of 2‐Oxa Derivatives of Benzocycloheptene by NMR.
Authors: DESILETS S. , ST‐JACQUES M. 
Published: May 2016

AbstractIn order to better assess the importance of the anomeric effect in seven‐membered rings, the 2‐benzoxepins (I) are prepared according to the literature and investigated by variable temp. high field 1H and 13C NMR methods.
ChemInform Abstract: How Does an Allene Distort to Accommodate Negative Charge? 1,1,3,3‐Tetraphenylallene.
Authors: RAJCA A. , TOLBERT L. M. 
Published: May 2016

AbstractThe treatment of (I) with Li or Na leads to two equilibrating structures of the monomeric allenide (IX), adopting C2 symmetry.
ChemInform Abstract: Laser Photolysis of 1‐(2H)‐2‐Diazonaphthalenone Derivatives.
Authors: DELAIRE J. A. , FAURE J. , HASSINE‐RENOU F. , SOREAU M. , MAYEUX A. 
Published: May 2016

AbstractThe photochemical reaction of the diazonaphthalenones (Ia) and (Ib) by laser photolysis is studied in different solvents.
ChemInform Abstract: Iodide Reduction of Sulfilimines. Part 2. Evidence for Concurrent Stepwise and Concerted Mechanisms for the Decomposition of Sulfurane Intermediates.
Authors: YOUNG P. R. , HUANG H. C. 
Published: May 2016

AbstractThe title reaction is first order in proton activity and iodide concentration in the pH range 0.5‐5. The inverse solvent isotope effect (0.26‐0.48 for (Ia) and (Ib)), the Bronsted βl.g.
ChemInform Abstract: Bis(neopentyloxy)triphenylphosphorane: A Versatile, Nonalkylating Cyclodehydration Reagent.
Authors: KELLY J. W. , EVANS S. A. JUN. 
Published: May 2016

AbstractThe phosphorane (V) mentioned in the title is prepared from triphenylphosphine (I) as shown in the reaction scheme.
ChemInform Abstract: Dication Ethers. Part 12. Reaction of Enaminones with Triflic Anhydride: 3‐Trifloxypropeniminium‐ and Bis(3‐amino‐2‐propenylio) Ether Salts.
Authors: SINGER B. , MAAS G. 
Published: May 2016

AbstractVarious enaminones such as (I) are reacted with triflic anhydride (II) in a 1:1 or 2:1 molar ratio to give either the O‐sulfonylated products (III) (part of which are obtained as E/Z‐mixtures) or the bistriflates (IV).
ChemInform Abstract: Vinylic Organoboranes. Part 7. Stereoselective Synthesis of (E)‐(1‐Substituted‐1‐Alkenyl)boronic Esters by the Nucleophilic Substitution of (Z)‐(1‐Bromo‐1‐alkenyl)boronic Esters with Organolithium or Grignard Reagents. Isolation and Oxidation to Ketones.
Authors: BROWN H. C. , IMAI T. , BHAT N. G. 
Published: May 2016

AbstractThe alkynes (I) react with the dibromoborane complex (II) and the diol (III), yielding 1‐bromoalkenylboranes, which are coupled with the organometallic reagents (IV) to produce the alkenylboranes (V).
ChemInform Abstract: Allylic Stereocenter Directed Asymmetric Conjugate Addition. Enantioselective Synthesis of 3‐Alkylsuccinaldehydic Acid Methyl Esters.
Authors: BERNARDI A. , CARDANI S. , POLI G. , SCOLASTICO C. 
Published: May 2016

AbstractThe optically active oxazolidines (III), derived from benzyloxycarbonylnorephedrine (I) and the acetal (II) as decribed in the literature, react with the cuprates (IV) to form the products (V) of conjugate addition with high π‐face selectivity.
ChemInform Abstract: Thioimidate N‐Oxides: Nitrones of Thio Esters.
Authors: COATES R. M. , FIRSAN S. J. 
Published: May 2016

AbstractThe N‐substituted thiohydroxamic acids (III) are prepared either from the thiono esters (II) and methylhydroxylamine (Ia) or from thiobenzoyl thioglycolic acid (IV) and the hydroxylamines (I).
ChemInform Abstract: Synthesis, Structure and Hypocholesterolemic Activity of a Series of Substituted 4‐Aryl‐4‐oxobutyric Acids.
Authors: COUSSE H. , MOUZIN G. , RIEU J.‐P. , DELHON A. , BRUNIQUEL F. , FAURAN F. 
Published: May 2016

AbstractThe 2‐methylenebutyric acids (IV) are obtained as the major products of the Friedel‐Crafts acylation of (I); 17 analogues of (IV) with various aromatic residues are prepared in a similar fashion (the 3‐methylene derivatives (V) are accessible from (II) via Mannich reaction in 36‐50% yield).
ChemInform Abstract: Synthesis and Biological Activity of Oxanilic Acid 2‐Oxoindolinylidene‐ 3‐hydrazides.
Authors: BOLOTOV V. V. , NAMBELBAI A. , DROGOVOZ S. M. , VEREITINOVA V. P. 
Published: May 2016

AbstractThe hydrazones (III) are synthesized from the oxanilic acid hydrazides (II) and the isatins (I).
ChemInform Abstract: Synthesis and Antimicrobial and Antifungal Activities of Some New 2‐(N‐(2′‐Mercapto‐1′,3′,4′‐thiadiazol‐5′‐yl)amino)‐4‐arylthiazole Derivatives.
Authors: AHLUWALIA V. K. , DUTTA U. , SHARMA H. R. 
Published: May 2016

AbstractTitle compounds of type (V) and (VII) are synthesized as shown in the scheme.
ChemInform Abstract: Synthesis of Choline Ester of 9‐Oxo‐10‐acridineacetic Acid and of Congeners as Potential Interferon Inducers.
Authors: SZULC Z. , MLOCHOWSKI J. 
Published: May 2016

AbstractThe ester (IVa) is a potential interferon inducer in vivo and in vitro but is less active compared with the title acid.
ChemInform Abstract: Reactions of O,O‐Dialkyl Thiophosphates with Nitriles and Rhodanides.
Authors: ZIMIN M. G. , ZABIROV N. G. , KAMALOV R. M. , PUDOVIK A. N. 
Published: May 2016

AbstractThe benzonitriles (I) react with the dialkyl thiophosphates (II) to give the phosphorylated thiobenzamides (III), the thiobenzamides (IV), and the thiopyrophosphate (V).
ChemInform Abstract: Synthesis and Characterization of tert‐Butyl(tert‐butyltellurio)mercury(II).
Authors: HARRIS D. C. , NISSAN R. A. , HIGA K. T. 
Published: May 2016

AbstractThe title compound (III) is prepared as shown in the scheme and characterized by 1H, 13C, 125Te, and 199Hg NMR, IR, UV, and mass spectra.
ChemInform Abstract: Syntheses of Heterotetranuclear Metallacarboranes Containing a Planar M2Cu2 (M: Mo, W) Rhomb and B‐H‐Cu Bridges: Structure of (Mo2Cu2(μ‐CO)4(CO)2(μ‐H)2(C2B9H10)2)2‐.
Authors: DO Y. , KNOBLER C. B. , HAWTHORNE M. F. 
Published: May 2016

AbstractThe clustered metallacarboranes (III) with the highest known nuclearity are prepared as shown.
ChemInform Abstract: Polyaza Cavity Shaped Molecules. Part 11. Ruthenium Complexes of Annelated 2,2′‐Biquinoline and 2,2′‐Bi‐1,8‐naphthyridine.
Authors: THUMMEL R. P. , LEFOULON F. 
Published: May 2016

AbstractThe Ru(II) complexes of the type (I) or (II) containing 2,2'‐biquinoline, 2,2'‐bis‐1,8‐naphthyridine, or their 3,3'‐polymethylene‐bridged derivatives and 2,2'‐bipyridine are prepared by reaction of RuCl3·3 H2O or cis‐RuCl2(bipyridyl)2 with the corresponding NN ligands in refluxing ethanol.