bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Reactivity of Dithiocarbamates of Dimolybdenum. Part 3. Crystal and Molecular Structure of Oxobis((diethyldithiocarbamato)(tetrahydrofuran)iodooxomolybdenum(V)).
Authors: BAIRD D. M. , RHEINGOLD A. L. , CROLL S. D. , DICENSO A. T. 
Published: May 2016

AbstractThe title Mo(V) complex (III) is synthesized by iodine oxidation of (II), which is obtained from reaction of 4 equiv. of sodium diethyldithiocarbamate with 1 equiv. of (I) (no yields given).
ChemInform Abstract: The Complex Ions (C5H5M(CO)3)‐ (M: Mo, W) as 6e‐Ligands: Synthesis and Molecular Structure of ((η4‐C4Me4)Co(μ‐CO)3M(η5‐C5H5)) (M: Mo, W).
Authors: HAERTER P. + , PFISTERER H. , ZIEGLER M. L. 
Published: May 2016

AbstractThe title compounds (IV) are the first example of a sym. coordination of (η5‐C5H5)M(CO)3 (M: Mo, W) in binuclear, sandwich‐like structures.
ChemInform Abstract: Stepwise Formation of Heterometallic Trinuclear and Tetranuclear Clusters from Dipalladium(I) Compounds and Carbonylmetallate Anions. The Crystal and Molecular Structure of (C5H5)2(CO)3(PiPr3)2MoPd2.
Authors: WERNER H. , THOMETZEK P. , KRUEGER C. + , KRAUS H.‐J. 
Published: May 2016

AbstractThe carboxylate‐ or halide‐bridged dinuclear complexes (I) or (IV) react with carbonylmetallate anions to give the heterotrimetallic clusters (III) or (V).
ChemInform Abstract: A Reactive Intermediate Formed by Triflate Rearrangement. A New Displacement Reaction for Carbohydrate Synthesis.
Authors: BINKLEY R. W. , SIVIK M. R. 
Published: May 2016

AbstractThe triflate (Ib), prepared from (Ia) in the presence of the hinderedbase (II), rearranges to give (VI).
ChemInform Abstract: Fluorides and Fluoro Acids. Part 12. Complex‐Anion Homology and Isomerism in the Crystal Structures of Two Potassium Poly(hydrogen fluorides), KF·2.5 HF and KF·3 HF.
Authors: MOOTZ D. , BOENIGK D. 
Published: May 2016

AbstractSingle crystals of the title compounds, obtained by combining in PTFE vessels and ampoules weighed amounts of KHF2 and HF and subsequent miniature zone melting, belong to the space groups P21/a (Z = 8) and R3c (Z = 6), respectively.
ChemInform Abstract: Synthesis and Electrical Properties of the Solid Solutions La1‐xCaxCryCo1‐yO3 (0 ≤ x ≤ 0.3; 0 < y ≤ 1).
Authors: TOLOCHKO S. P. , KONONYUK I. F. 
Published: May 2016

AbstractThe title solid solutions are prepared by calcination of the corresponding nitrates and Cr2O3 at 1270‐1470 K (10‐30 h).
ChemInform Abstract: Electrochemistry of Dinuclear, Thiolato‐Bridged Transition‐Metal Compounds. Part 1. Electrochemical Behaviour of ((η5‐C5H5)(CO)3M(μ‐SR)W(CO)5) (R: Me, M: Mo or W; R: Ph, M: W) Complexes in Non‐aqueous Media.
Authors: COURTOT‐COUPEZ J. , GUERCHAIS J. E. , PETILLON F. Y. , TALARMIN J. 
Published: May 2016

AbstractThe compounds (I) have been studied by cyclic voltammetry, controlled‐potential electrolysis, and coulometry.
ChemInform Abstract: Effect of a β‐Silyl Group on the Regiochemistry of Enolization of Ketones.
Authors: ENGEL W. , FLEMING I. , SMITHERS R. H. 
Published: May 2016

AbstractThe pentanone (I) is deprotonated and silylated to give a 7:3 mixture of the enol ethers (III) and (IV), both existing as E/Z‐isomers.
ChemInform Abstract: Benzopyrones. Part 23. Cyclization of o‐Amino Carboxamides and Related Compounds.
Authors: BEVAN P. S. , ELLIS G. P. , HUDSON H. V. , ROMNEY‐ALEXANDER T. M. , WILLIAMS J. M. 
Published: May 2016

AbstractThe benzopyranopyrimidines (IIIa) and (IIIb) are obtained from the oxochromenes (Ia) or (Ib).
ChemInform Abstract: Diels‐Alder Reactions of (1E),(3E)‐2‐Methyl‐1‐trimethylsiloxy‐1,3‐pentadiene and the Synthesis of Multistriatins from the Adducts.
Authors: MORI Y. , INABA M. , SUZUKI M. 
Published: May 2016

AbstractThe Diels‐Alder reaction between the silyloxy butadiene (I) and the acrylates (II) gives mixtures of the four isomeric hydroxycyclohexene carboxylic acid esters (III) ‐ (VI).
ChemInform Abstract: Linear Oligopeptides. Part 147. Chemical and Crystallographic Study of the Reaction Between Benzyloxycarbonyl Chloride and α‐Aminoisobutyric Acid.
Authors: VALLE G. , FORMAGGIO F. , CRISMA M. , BONORA G. M. , TONIOLO C. , BAVOSO A. , BENEDETTI E. , DI BLASIO B. , PAVONE V. , PEDONE C. 
Published: May 2016

AbstractThe title reaction yields the N‐protected amino acid (I) and the corresponding dipeptide (II) as by‐product.
ChemInform Abstract: Electrochemical Oxidation of N‐Nitrosopiperidines: Dual Pathways for N‐Nitramine Formation.
Authors: OHMORI H. , MAEDA H. , UEDA C. , SAYO H. , MASUI M. 
Published: May 2016

AbstractThe N‐nitrosopiperidines (I) are electrochemically oxidized to the corresponding N‐nitramines (II).
ChemInform Abstract: Mechanism of Hydrogenolysis. Part 1. Catalytic Hydrogenation of Vinyl and Aryltrifluoromethanesulfonates.
Authors: GARCIA MARTINEZ A. , MARTINEZ ALVAREZ R. , ARRANZ AGUIRRE J. , SUBRAMANIAN L. R. 
Published: May 2016

AbstractCatalytic hydrogenation of the triflate (I) leads to benzene (II) only, whereas the ether (III) is reduced to give predominantly cyclohexanes with and without hydrogenolysis of the ether bond.
ChemInform Abstract: Kinetics and Mechanism of Transamination Reaction of L‐Phenylalanine with Hydrophobic Pyridoxal in Vesicular and Micellar Phases.
Authors: MURAKAMI Y. , KIKUCHI J. , AKIYOSHI K. , IMORI T. 
Published: May 2016

AbstractThe metal ion catalyzed transamination of the pyridoxal derivative (I) with Phe is more effective in vesicular (→ (V)) than in CTAB micelles due to differences in the microenvironmental properties.
ChemInform Abstract: A Convenient Synthesis of 4‐Oxoalkanals.
Authors: MIYAKOSHI T. 
Published: May 2016

AbstractThe tributylphosphine‐catalyzed Michael addition of the nitroalkanes (I) to acrolein (II) yields the adducts (III) which are converted to the title compounds (IV) by an electrochemical oxidative Nef reaction, followed by hydrolysis.
ChemInform Abstract: Synthesis of Heterocyclic Propellanes. Preparation and Transannular Reactions of 5‐Ethoxycarbonylmethylene‐cyclooctanone and the Corresponding Oximes and Hydrazones.
Authors: MALAMIDOU‐XENIKAKI E. , NICOLAIDES D. N. 
Published: May 2016

AbstractWittig olefination of the dione (I) depends on the reaction conditions and at 160‐170 °C yields the cyclooctanone (IIIa) as main product.
ChemInform Abstract: Preparation of Arylazo‐bis‐acetoximes.
Authors: NIZAMUDDIN NIZAMUDDIN , PUROHIT D. N. 
Published: May 2016

AbstractDurch Umsetzung der Diazoniumsalze (I) mit Acetoxim (II) erhält man die im Titel genannten Verbindungen (III), die sich durch Reaktion mit α‐Naphthylamin nachweisen lassen.
ChemInform Abstract: Preparation and Photoisomerization of 2‐Formylcinnamaldehyde in Solution.
Authors: LARSON R. A. , GARRISON W. J. , MARLEY K. A. 
Published: May 2016

AbstractThe ozonization of naphthaline (I) at pH 5 yields a mixture of the cinnamaldehydes (II) which equilibrate upon irradition.
ChemInform Abstract: Photochromic Systems. Part 2. Studies on the Photoreactions and the Photopolychromic Properties of (E)‐(2,5‐Dimethoxyphenyl‐substituted)methylene Isopropylidenesuccinic Anhydrides.
Authors: CRESCENTE O. , HELLER H. G. , PATHARAKORN S. 
Published: May 2016

AbstractIrradiation of the yellow fulgide (E)‐(Ia) in toluene leads to a purple colored solution which contains the red (thermally stable) dihydronaphthalene derivative (IIIa) and its blue (unstable) isomer (IVa).
ChemInform Abstract: Convenient Synthesis of 6‐Methoxyindole and 6‐Methoxytryptophyl Bromide.
Authors: FELDMAN P. L. , RAPOPORT H. 
Published: May 2016

AbstractNitration of p‐cresol carbonate (II) followed by hydrolysis and methylation gives the 4‐methoxy‐2‐nitrotoluene (V).
ChemInform Abstract: Conversion of Triazolides into Oxazoles by Flash‐Vacuum Pyrolysis.
Authors: MAQUESTIAU A. , PUK E. , FLAMMANG R. 
Published: May 2016

AbstractThe triazolides (I) rearrange upon pyrolysis to produce the intermediates (II) which are converted to the oxazoles (IV) via the diradicals (III).
ChemInform Abstract: Synthesis of Optically Active Forms of Hydroxy‐Y Base, the Minor Component of Rat Liver Phenylalanine Transfer Ribonucleic Acid.
Authors: ITAYA T. , WATANABE N. , MIZUTANI A. 
Published: May 2016

AbstractThe heterocyclic compound (I) is converted to the diol which is transformed into the carbonate and then hydrogenated, yielding (II).
ChemInform Abstract: Photoreactions of Succinimides with an N‐Acyl Group in the Side Chain. Synthesis and Stereochemistry of Tricyclic Pyrrolo(1,2‐a)pyrazine Ring System.
Authors: TAKECHI H. , TATEUCHI S. , MACHIDA M. , NISHIBATA Y. , AOE K. , SATO Y. , KANAOKA Y. 
Published: May 2016

AbstractPhotolysis of the succinimides (I) produces the perhydropyrrolopyrazinones (II).
ChemInform Abstract: Heterocyclic Ethers Derived from 6,11‐Dihydrodibenzo(b,e)thiepin‐11‐ols and 4,9‐Dihydrothieno(2,3‐c)‐2‐benzothiepin‐4‐ol; a New Series of Potential Antidepressants and Antihistamine Agents.
Authors: POLIVKA Z. , METYS J. , PROTIVA M. 
Published: May 2016

AbstractThe known tricyclic alcohols (IIa) and (IV) are prepared by new methods from the ketones (I) or (III).
ChemInform Abstract: The Reactivity of Diphosphenes Towards Electrophilic and Nucleophilic Reagents.
Authors: COWLEY A. H. , KILDUFF J. E. , NORMAN N. C. , PAKULSKI M. 
Published: May 2016

AbstractThe reaction of the diphosphene (Ia) with HCl gives the phosphine (IIa), whereas reaction of (Ib) with HCl leads either to the phosphine (IIb) or to a diastereomeric mixture of the compounds (III); each diastereomer consists of a D,L enantiomeric pair.
ChemInform Abstract: Synthesis of the New Bidentate Tellurium Ligands, (p‐EtOC6H4)Te(CH2)nTe(C6H4OEt‐p) (n = 1, 5, 6, 7, 9, or 10).
Authors: PATHIRANA H. M. K. K. , MCWHINNIE W. R. 
Published: May 2016

AbstractThe reaction between NaTeAr, generated from the ditelluride (I), and CH2I2 or α,ω‐dibromoalkanes gives the bis(tellurides) (II).
ChemInform Abstract: Bis(η5‐cyclopentadienyl)‐pyrocatecholato‐titanium(IV) ‐ an Oligomeric Polynuclear Complex.
Authors: KOEPF H. + , KLAPOETKE T. + 
Published: May 2016

AbstractTitanocene dichloride reacts with stoichiometric amounts of the freshly prepared dilithium salt or pyrocatechol in benzene at 20 °C to give the title complex (54% yield).
ChemInform Abstract: Reactions of Co‐ordinated Ligands. Part 38. Reactions of 1,2‐Dienes, 1,3‐Dienes, and Alkynes with the μ‐Allylidene Complex (Mo2(μση3‐CHCHCMe2)(CO)4(η‐C5H5)2); Molecular Structures of (Mo(CO)2(η‐C5H5)(μη3:η3‐CH2C(CH2)CHCHCMe2)Mo(CO)2(η‐C5H5)), Cyclic (Mo2(μη4‐CMe2CHCHCHC(tBu)CO)(CO)2(η‐C5H5)2) and (Mo(CO)2(η‐C5H5)(μη2:η3‐C(Me)C(Me)C(O)CHCHCMe2)Mo(CO)2(η‐C5H# 5)).
Authors: GREEN M. , MERCER R. J. , ORPEN A. G. , SCHAVERIEN C. J. , WILLIAMS I. D. 
Published: May 2016

AbstractReaction of the μ‐allylidene complex (II) with allene or 3‐methylbuta‐1,2‐diene leads to cleavage of the Mo‐Mo bond and formation of the bis‐allylic complexes (I).
ChemInform Abstract: Synthesis of (C5H5)Fe(CO)2(η1‐C5H7), (C5H5)Fe(CO)(η3‐C5H7), and (C5H5)Fe(η5‐C5H7) Involving the η1 → Syn‐η3 →η5 Route.
Authors: LUSH S.‐F. , LIU R.‐S. 
Published: May 2016

AbstractReaction of the ferrate complex (I) with trans‐1‐chloropenta‐2,4‐diene (II) gives the pentadienyl derivative (III).
ChemInform Abstract: 2‐Methyl‐ and 2‐Ethylamino‐3‐picoline N‐Oxide Complexes Formed from Various Copper(II) Salts.
Authors: WEST D. X. , NIPP C. A. 
Published: May 2016

AbstractThe title complexes are isolated from anhydrous ethanolic solutions of various copper salts and the ligands (I) (no yields given).
ChemInform Abstract: Effect of Oxidation State of Plastocyanin on the Remote Binding Site pKa.
Authors: MCGINNIS J. , SINCLAIR‐DAY J. D. , SYKES A. G. 
Published: May 2016

AbstractThe variation of rate constants for (Co(phen)3)2+ (phen = 1,10‐phenanthroline), (Co(terpy)2)2+ (terpy = 2,2';6',2''‐terpyridine), and (Ru(NH3)5(py))2+ reductions of parsley plastocyanin PCu(II) with pH indicate an acid dissociation pKa at the remote east face of 5.05, whereas for the oxidant (Co(phen)3)3+ with PCu(I) the value is 5.8.
ChemInform Abstract: Bimetallic Systems. Part 14. Mixed Iridium(I)‐Platinum(II) Acetylide Complexes Containing Bridging Ph2PCH2PPh2 Ligands.
Authors: MCEWAN D. M. , MARKHAM D. P. , PRINGLE P. G. , SHAW B. L. 
Published: May 2016

AbstractThe heterobimetallic Ir(I)‐Pt(II) complexes (II) prepared as shown react with H2 to yield the μ‐hydrido Ir‐hydride derivatives (III).
ChemInform Abstract: Tris‐μ‐(bis(diphenylphosphino)methane)‐diplatinum(0).
Authors: MANOJLOVIC‐MUIR L. , MUIR K. W. , GROSSEL M. C. , BROWN M. P. , NELSON C. D. , YAVARI A. , KALLAS E. , MOULDING R. P. , SEDDON K. R. 
Published: May 2016

AbstractThe synthesis of the title compound (II) occurs either by reduction of the dichloro‐Pt(II) monomer (I) by NaBH4 in aqueous EtOH in the presence of two molequiv.
ChemInform Abstract: Inhibitors of Porcine Pancreatic Elastase. Peptides Incorporating α‐Aza‐amino Acid Residues in the P1 Position.
Authors: DUTTA A. S. , GILES M. B. , WILLIAMS J. C. 
Published: May 2016

AbstractA large number of peptide derivatives, e.g. (I)‐(X), based on one of the repeating peptide sequences (Gly‐Val‐Gly‐Val‐Ala) present in elastin are prepared using conventional procedures and tested as inhibitors of porcine pancreatic elastase.
ChemInform Abstract: An Improved Synthesis of N‐Hydroxylamino Acids and Their Esters Using (Z)‐2‐Furaldehyde Oxime.
Authors: GOTO G. , KAWAKITA K. , OKUTANI T. , MIKI T. 
Published: May 2016

AbstractFuraldehyde (V) and hydroxylamine sulfate (IV) react to produce the (E)‐oxime (E)‐(III) which is alkylated with chloroacetamide (II) to give the oxime ether (I).
ChemInform Abstract: Studies on Stereospecific Formation of P‐Chiral Internucleotide Linkage. Synthesis of Diastereoisomeric 2′‐Deoxyadenylyl(3′,5′)2′‐deoxyadenylyl S‐Methylphosphorothioates via Nucleoside Hydroxyl Activation.
Authors: LESNIKOWSKI Z. J. , SIBINSKA A. 
Published: May 2016

AbstractTreatment of the deoxyadenosine (I) with the phosphoramidochloridate (II) gives the diastereomeric (Sp)‐ and (Rp)‐phosphoranilidates (IIIa) and (IIIb), which are separated by chromatography with only moderate efficiency.
ChemInform Abstract: Structures Containing Anionic Layers in the Class of Alkali Metal Halide Azides Rb2IN3, Cs2BrN3, and Cs2IN3.
Authors: JACOBS H. , PETERS D. 
Published: May 2016

AbstractThe title compounds are obtained in the course of experiments to synthesize halide azides M2XN3 (M: K, Rb, Cs; X: Cl, Br, I) starting from the corresponding halides and azides under widely varied conditions.
ChemInform Abstract: Electrodeposition Mechanism of CdTe from Acidic Aqueous Solutions.
Authors: SELLA C. , BONCORPS P. , VEDEL J. 
Published: May 2016

AbstractOn the basis of voltammetric results for the codeposition of CdTe from acidic aqueous Cd2+/HTeO2+ solutions it is shown that the adsorption of HTeO2+ plays an important role in the deposition process.
ChemInform Abstract: Photochemical Reactions in Organized Assemblies. Part 46. Energy‐ and Electron‐Transfer Quenching of Surfactant trans‐Stilbenes in Supported Multilayers: The Use of Hydrophobic Substrate Chromophores to Determine Short‐Range Distance Dependence in Assemblies.
Authors: MOONEY W. F. , WHITTEN D. G. 
Published: May 2016

AbstractFluorescence quenching of surfactant trans‐stilbenes by the thiacyanine (I) occurs over 80‐90 Å, but no excitation transfer is shown among the stilbenes themselves (lack of prominent antenna effect).
ChemInform Abstract: Barriers to Rotation Adjacent to Double Bonds. Part 2. n‐Propyl vs. Isopropyl Groups.
Authors: WIBERG K. B. 
Published: May 2016

AbstractThe barriers to rotation about the C‐C bonds adjacent to the carbonyl groups of isobutyraldehyde, methyl isopropyl ketone, and isobutyric acid were calculated.
ChemInform Abstract: Solid‐State Structural Characterization of 1,3‐Cyclohexanedione and of a 6:1 Cyclohexanedione:Benzene Cyclamer, a Novel Host‐Guest Species.
Authors: ETTER M. C. , URBANCZYK‐LIPKOWSKA Z. , JAHN D. A. , FRYE J. S. 
Published: May 2016

Abstract1,3‐Cyclohexanedione crystallizes form a variety of organic solvents such as THF as flat, clear trapezoidal crystals (space group P21/a, Z=4) containing strongly H‐bonded anti‐anti configurated chains.
ChemInform Abstract: Membrane‐Bound Cytochrome P‐450 Mimic. Polymerized Vesicles as Microreactors.
Authors: VAN ESCH J. , ROKS M. F. M. , NOLTE R. J. M. 
Published: May 2016

AbstractA synthetic model system of cytochrome P‐450 which incorporates all features of the natural enzyme system is described.
ChemInform Abstract: Terminal Epoxidation of Farnesate Attached to Helical Peptides.
Authors: BUDT K.‐H. , VATELE J.‐M. , KISHI Y. 
Published: May 2016

AbstractAsym. induction in the terminal epoxidation of a terpene such as farnesic acid should be possible if the terpene is coupled to a chiral helical molecule, for instance to a coiled polypeptide.
ChemInform Abstract: Absence of Stereoelectronic Control in Hydrolysis of Cyclic Amidines.
Authors: PERRIN C. L. , NUNEZ O. 
Published: May 2016

AbstractProduct ratios obtained from the hydrolysis of cyclic amidines (I) show that stereoelectronic control is only weakly operative in the case of (Ia) leading predominantly to the aminoamide (IIa).
ChemInform Abstract: Lewis Acid Catalysis of Photochemical Reactions. Part 6. Selective Isomerization of β‐Furylacrylic and Urocanic Esters.
Authors: LEWIS F. D. , HOWARD D. K. , OXMAN J. D. , UPTHAGROVE A. L. , QUILLEN S. L. 
Published: May 2016

AbstractPhotostationary states are obtained from the esters (I) and (III) and their Z‐isomers under irradiation (313 nm).
ChemInform Abstract: Organic Photochemistry. Part 4. Light‐Induced Oxidation of α‐Ketoalcohols by Free Radicals from Benzoyl Peroxide and N‐Bromosuccinimide.
Authors: SHARMA K. S. , KUMARI S. , GOEL V. K. 
Published: May 2016

AbstractPhotochemical oxidation of the α‐ketoalcohols benzoin, 4‐methoxybenzoin, 4,4'‐dimethoxybenzoin and 2,2'‐furoin in the presence of benzoyl peroxide or NBS leads to the corresponding 1,2‐diketones.
ChemInform Abstract: Dramatic Differences in Intramolecular Reactivities of Singlet Arylcarbenes and Benzyl Cations.
Authors: KIRMSE W. , KUND K. , RITZER E. , DORIGO A. E. , HOUK K. N. 
Published: May 2016

AbstractThe product ratios (III)/(IV) depend strongly on the solvent acidity which increases the rate of formation of the cation of type (II) from the corresponding carbene.
ChemInform Abstract: Dioxygenyl Hexafluoroantimonate: A Useful Reagent for Preparing Cation Radical Salts in Good Yield.
Authors: DINNOCENZO J. P. , BANACH T. E. 
Published: May 2016

AbstractIn Freon solvents at temperatures ranging from ‐120 ° to ‐145 °C, the title reagent (I) cleanly converts (II)‐(IV) to the corresponding cation radical salts in yields of 97, 89 and 40%, resp. (the salt prepared from (IV) cannot be isolated).
ChemInform Abstract: The Geometry of Displacements at Nonstereogenic Atoms: The Formal Displacement of Alkoxide from Alkoxyamines by Organolithium Reagents.
Authors: BEAK P. , BASHA A. , KOKKO B. , LOO D. 
Published: May 2016

AbstractThe amination of organolithium reagents (I) can be achieved by reactions with a methyllithium (Ia)‐alkoxamine (e.g.
ChemInform Abstract: Chiral Synthesis via Organoboranes. Part 7. Diastereoselective and Enantioselective Synthesis of erythro‐ and threo‐β‐Methylhomoallyl Alcohols via Enantiomeric (Z)‐ and (E)‐Crotylboranes.
Authors: BROWN H. C. , BHAT K. S. 
Published: May 2016

Abstract1. Successive metalation of (Z)‐butene (Ia) (→ (VI)) and reaction with methoxydiisopinocampheylborane (II) derived from (+)‐α‐pinene leads to a borone species (VII) which reacts immediately with the aldehydes (IV) in a highly regioselective and stereoselective manner to yield the erythro alcohols (V).
ChemInform Abstract: Synthesis of Derivatives of the Novel Tricyclo(4.4.2.01,5)dodecane Skeleton.
Authors: JEFFREY D. A. , COGEN J. M. , MAIER W. F. 
Published: May 2016

AbstractOxidation of the diol (I) gives the trans‐dione (II) which is converted to the hydroxytricyclododecanone (V).
ChemInform Abstract: Liquid‐Phase Oxidation of Deactivated Methylbenzenes by Aqueous Sodium Hypochlorite Catalyzed by Ruthenium Salts Under Phase‐Transfer Catalytic Conditions.
Authors: SASSON Y. , ZAPPI G. D. , NEUMANN R. 
Published: May 2016

AbstractThe deactivated methylbenzenes (I) react with hypochlorite in the presence of a Ru‐catalyst, yielding the carboxylic acids (II).
ChemInform Abstract: Nucleophilic Aromatic Substitution with Elimination in a Dinitrosalicylic Lactone or Ester via Meisenheimer Intermediates.
Authors: JONES P. R. , ROTHENBERGER S. D. 
Published: May 2016

AbstractThe cyclic or acyclic 3,5‐dinitrobenzoic acid glycolesters (I) or (II) react with the nucleophiles (III) to produce the derivatives (IV).
ChemInform Abstract: The Oxidative Decarboxylation of N‐Aroylglycines to N‐(Acetoxymethyl)benzamides and N‐Formylbenzamides with Lead(IV) Acetate.
Authors: GLEDHILL A. P. , MCCALL C. J. , THREADGILL M. D. 
Published: May 2016

AbstractThe substituted N‐benzoyl glycines (I) except the derivatives (If) and (Ih) are oxidized with lead tetraacetate to give the acetoxymethyl benzamides (II) and/or the N‐acyl benzamides (III).
ChemInform Abstract: Chemistry of 1‐(Trimethylsiloxy)‐1‐methoxy‐3‐(alkyl(aryl)thio)‐1,3‐butadienes and the Synthesis of Aryl Sulfides via a Cycloaromatization Reaction.
Authors: CHAN T. H. , PRASAD C. V. C. 
Published: May 2016

AbstractMethyl acetoacetate (I) reacts with the thiols (II) to produce thioenols (III) which then are silylated, yielding ketene acetals (IV).
ChemInform Abstract: Synthesis and Pharmacological Activity of 1‐Aryl‐2‐alkylaminopropane Derivatives.
Authors: ANICHKOV S. V. , DUMPIS M. A. , KRASNOVA E. I. 
Published: May 2016

AbstractThe alkylaminoalkyl 2‐naphthyl ketones (III) are obtained from the corresponding bromoalkyl ketones (I) and reduced to give the tetrahydronaphthylcarbinols (IV) or the naphthylcarbinols (V).
ChemInform Abstract: Method of Preparing 1‐(2‐Aminoethyl)aziridine by Reaction of Nickel Bromide with Aziridine.
Authors: UKRAINTSEV V. B. , KUKUSHKIN YU. N. 
Published: May 2016

AbstractIn the presence of NiBr2· 3 H2O aziridine (I) can be transformed to 1‐(2‐aminoethyl)aziridine (II).
ChemInform Abstract: A Simple Method for Distinguishing Optical Isomers of Chiral Amines, Hydroxylamines, Amino Acids, and Peptides.
Authors: KOLASA T. , MILLER M. J. 
Published: May 2016

AbstractThe optically active anhydride (I) reacts with the O‐phenethylhydroxylamine (II) to give the imide (III) which is used as a tool in the determination of purity and optical configuration.
ChemInform Abstract: Conversion of L‐Pyroglutamic Acid to 4‐Alkyl Substituted L‐Prolines. The Synthesis of trans‐4‐Cyclohexyl‐L‐proline.
Authors: THOTTATHIL J. K. , MONIOT J. L. , MUELLER R. H. , WONG M. K. Y. , KISSICK T. P. 
Published: May 2016

AbstractL‐Pyroglutamic acid (I) is converted to the O,N‐acetal (III) which produces the trans‐L‐prolinol (VI) after alkylation and reduction.
ChemInform Abstract: Derivatives of 6,7‐Dihydro‐5H‐pyrrolo(1,2‐a)imidazole.
Authors: KOVTUNENKO V. A. , DEMCHENKO A. M. , TYLTIN A. K. , BABICHEV F. S. 
Published: May 2016

AbstractThe 2‐aminopyrrolinium salts (I) are cyclized to give the amidinium salts (II) which yield the bicyclic imidazoles (III) after treatment with a base.
ChemInform Abstract: Synthesis of trans‐2,6‐Dialkylpiperidines by 1,3‐Cycloaddition of Alkenes to 2‐Alkyl‐2,3,4,5‐tetrahydropyridine Oxides.
Authors: CARRUTHERS W. , WILLIAMS M. J. 
Published: May 2016

AbstractA stereocontrolled synthesis of solenopsin (VII) from 2‐methyl‐N‐hydroxypiperidine (I) is reported.
ChemInform Abstract: Synthesis of 4‐(4‐Substituted arylamino)‐7‐chloroquinolines and Their Antimalarial and Antifilarial Activities.
Authors: CHAUHAN P. M. S. , SHARMA S. , BHAKUNI D. S. 
Published: May 2016

Abstract4,7‐Dichloroquinoline (I) serves as starting compound for the synthesis of the derivatives (III) as shown in the scheme.
ChemInform Abstract: Oxazoline‐Mediated Asymmetric Alkylation of Amines
Authors: GAWLEY R. E. , HART G. , GOICOECHEA‐PAPPAS M. , SMITH A. L. 
Published: May 2016

AbstractThe chiral oxazoline (I) reacts with triethyloxonium tetrafluoroborate, giving the imino ester (II) which is coupled with the tetrahydroisoquinoline (III) to yield (IV).