bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Crystal Structure of Tetramethylammonium catena‐μ4‐Chloro‐di‐μ‐chloro‐dicuprate(I), [N(CH3)4][Cu2Cl3].
Authors: ANDERSSON S. , JAGNER S. 
Published: May 2016

AbstractThe title compound cryslallizes in the space group Pnma with Z=4.
ChemInform Abstract: Effect of Titanium‐Titanium Interactions on the Electronic Spectrum of Titanium(II) Ions in the Layer Lattice MgCl2.
Authors: WILSON D. R. , BROWN D. H. , SMITH W. E. 
Published: May 2016

AbstractThe optical spectra of four different Ti(ll)‐doped MgCl2 cryslals with Tito Mg atomic ratios of l :lO0 1o I25 have been studied.
ChemInform Abstract: Solid‐State 27Al NMR Studies on Polycrystalline Aluminates of the System CaO ‐ Al2O3.
Authors: MUELLER D. + , GESSNER W. , SAMOSON A. , LIPPMAA E. , SCHELER G. 
Published: May 2016

Abstract7 different calcium aluminates have been studied by static and MAS NMR.
ChemInform Abstract: Interfacial Phenomena of Polycrystalline Mg‐Doped p‐Type Iron(III) Oxide Photo electrodes.
Authors: TINNEMANS A. H. A. , KOSTER T. P. M. , MACKOR A. , SCHOONMAN J. 
Published: May 2016

AbstractThe small‐signal a.c. response of polycrystalline Mg‐doped α‐Fe2O3 photocathode/aqueous electrolyte junctions has been studied in the frequency range 10‐2 ‐ 10‐4 H2 utilizing the non‐linear least‐squares analysis of the admittance/ impedance spectra.
ChemInform Abstract: Structural and Magnetic Properties of Mn1‐tFetP (0.80 ⩽ t ⩽ 1.00).
Authors: FJELLVAG H. , KJEKSHUS A. , ANDRESEN A. F. 
Published: May 2016

AbstractSamples of thc title compounds have been prepared by heating ( 1000°C) appropriate amoums of MnP and FeP.
ChemInform Abstract: Relaxation in ZnO (1010), (0001), and (0001) Surfaces and the Adsorption of CO.
Authors: ANDERSON A. B. , NICHOLS J. A. 
Published: May 2016

AbstractAn atom superposition and electron delocalization molecular orbital study using cluster models shows surface zinc and oxygen ions relax into the (0001), (0001), and (1010) surfaces.
ChemInform Abstract: The Copper‐ Molybdenum Antagonism in Ruminants. Part 3. Reaction of Copper(II) with Tetrathiomolybdate(VI).
Authors: LAURIE S. H. , PRATT D. E. , RAYNOR J. B. 
Published: May 2016

AbstractThe stoichiometry of the title reaction in neutral aqueous solution is found to proceed with a l.5:l Cu:Mo ratio.
ChemInform Abstract: (NbAs8)3‐, a Novel Type of Complex and an Unexpected One‐dimensional Chain Structure
Authors: VON SCHNERING H. G. , WOLF J. , WEBER D. , RAMIREZ R. , MEYER T. 
Published: May 2016

AbstractThe title complex ion is obtained by an undesired side reaction during the synthesis of Rb,As7 in a sealed Nb tube (too much Rb was added erroneously) and is isolated as the salt (V).
ChemInform Abstract: Benzo[c]benzo[3,4]cinnolino[1,2‐a]cinnoline, a Chiral Hydrazine Derivative.
Authors: FISCHER H. , KRIEGER C. , NEUGEBAUER F. A. 
Published: May 2016

AbstractThe structure of the title compound (I) is investigated by X‐ray diffraction (space group: P21; Z=4).
ChemInform Abstract: Structure Determination of Pentatetraenes. Comparison of Structures of Cumulenes..
Authors: IRNGARTINGER H. , GOETZMANN W. + 
Published: May 2016

AbstractThe pentatetraene (Ib) was synthesized by dichlorocarbene addition to the butatriene (Ia) to give the unexpected enynol (IIIa), followed by hydroxyl group‐chlorine exchange and dechlorination of (IIIb) by zinc dust (no yields given).
ChemInform Abstract: Towards a Hemocyanin Model. Relation Between Molecular und Electronic Structure in Binuclear Complexes: Effect of Bridging Group Length und Angle Between Metal Planes.
Authors: BUTCHER R. J. , DIVEN G. , ERICKSON G. , MOCKLER G. M. , SINN E. 
Published: May 2016

AbstractBinuclear complexes of the type (I) have been used to investigate geometric requirements for magnetic coupling.
ChemInform Abstract: Efficient Detection und Evaluation of Cyclodextrin Multiple Complex Formation
Authors: ARMSTRONG D. W. , NOME F. , SPINO L. A. , GOLDEN T. D. 
Published: May 2016

AbstractEquations are derived to determine α‐cyclodextrin ‐ substrate complex stoichiometries as well as prim. and sec. binding constants by using liquid chromatographic retention values.
ChemInform Abstract: Low Temperature Electrochemistry of Metalloporphyrins in Dichloromethane: Characterization of Transient Species.
Authors: BOND A. M. , SWEIGART D. A. 
Published: May 2016

AbstractCyclic voltammetry at temp. down to ‐90°C has been used to characterize (Ia) and the transienl high‐spin complex (ll).
ChemInform Abstract: Cyclization Reactions of Electrochemically Generated o‐(3‐Butenyl)phenyl Anions and Radicals to 1‐Methylindan.
Authors: KOPPANG M. D. , ROSS G. A. , WOOLSEY N. F. , BARTAK D. E. 
Published: May 2016

AbstractThe electrochemical reduction of (I), which is carried out analogously to the generation of phenyl anions by cyclic voltammetry, leads to the products (III) and (IV) (2:1) via the anion (II).
ChemInform Abstract: Indirect Electrochemical Radical Cyclization of Bromo Acetals by Cobaloxime(I) as an Electron‐Transfer Catalyst.
Authors: TORII S. , INOKUCHI T. , YUKAWA T. 
Published: May 2016

AbstractIn Gegenwart von Cobaloxim werden die Brompropargylverbindungen (I) elektrochemisch zu den Bicyclen (II) umgesetzt.
ChemInform Abstract: On the Selectivity of Rh Catalysts in the Formation of Oxygenates.
Authors: VAN DER LEE G. , SCHULLER B. , POST H. , FAVRE T. L. F. , PONEC V. 
Published: May 2016

AbstractIn order to gain information on the factors which determine the selectivity ofcatalysts in the syngas reactions, a number of Rh catalysts with various carriers have been studied.
ChemInform Abstract: Reaction of the Dimethylhydrazone of Formaldehyde wich Methyl Acrylate and Acrylonitrile.
Authors: KOLDOBSKII A. B. , LUZIKOV YU. N. , LUNIN V. V. 
Published: May 2016

AbstractThe reaction of the title compound (I) with methyl acrylate (II) and with acrylonitrile (IV), i.e. the reaction with the most simple alkenes containing electron acceptors, is studied.
ChemInform Abstract: Organic Thermal Reactions. Part 62. The Intramolecular Nitrene‐Type 1,1‐Cycloaddition Reaction of Ally1‐Substituted Diazomethanes.
Authors: MIYASHI T. , NISHIZAWA Y. , FUJII Y. , YAMAKAWA K. , KAMATA M. , AKAO S. , MUKAI T. 
Published: May 2016

AbstractTreatment of the Cycloalkanones (I) with ethyl bromoacetate (II) gives the alcohols (III), which undergo dehydration, saponification, and phenylation to afford the ketones (V).
ChemInform Abstract: Diels‐Alder Reaction in the Presence of Zeolite.
Authors: IPAKTSCHI J. 
Published: May 2016

AbstractCu(I) ion exchanged Y‐zeolite catalyzed Diels‐Alder reaction of furan, cyclopentadiene, 1,5‐cyclohexadiene, isoprene and 2,3‐dimethylbutadiene with a series of dienophiles such as methylvinylketonc, acrolein, methylacrylate or dimethylacetylenedicarboxylate is reported.
ChemInform Abstract: Reaction of Unsaturated Compounds with Diazoalkanes. Part 3. Cyclopropanation of Cyclooctatetraene with Diazomethane.
Authors: TOMILOV YU. V. , MITENINA T. L. , LUTSENKO A. I. , DOLGII I. E. , KOLESNIKOV S. P. , NEFEDOV O. M. 
Published: May 2016

AbstractDie Umsetzung von Cyclooctatetraen (I) mit Diazomethan (II) führt in Abhängigkeit vom Molverhältnis der Komponenten zu Gemischen der Cyclopropanierungsprodukte (III)‐(VII), die teilweise in Form mehrerer Isomerer anfallen.
ChemInform Abstract: Ring Enlarging Dipolar Cycloadditions of Chlorosulfonylisocyanate to Epoxides.
Authors: LORINCZ T. , ERDEN I. 
Published: May 2016

AbstractDie Umsetzung von Chlorsulfonylisocyanat (I) mit verschiedenen Epoxiden führt in mäßigen Ausbeuten zu Oxazolidinonen bzw. cyclischen Carbonaten.
ChemInform Abstract: Functionalized Ethylene Oligomers as Phase‐Transfer Catalysts.
Authors: BERGBREITER D. E. , BLANTON J. R. 
Published: May 2016

AbstractAus Polyethylenen mit endständigen Lithioethyl‐Gruppen werden Polyethylene mit funktionellen Gruppen wie (III), (V), (VIII) oder (IX) hergestellt.
ChemInform Abstract: Nucleophilic Reactions at the Vinylic Center. Part 17. Formation of Derivatives of 1,3,4‐Thiadiazole and 1,3,4‐Oxadiazole by the Reactions of 2,2‐Dichlorovinyl Sulphones with Thiosemicarbazide and Semicarbazide.
Authors: SHAINYAN B. A. , INDYUKOVA L. N. , KALIKHMAN I. D. , MIRSKOVA A. N. 
Published: May 2016

AbstractThe reactions of the 2,2‐dichlorovinylsulphones (I) with thiosemicarbazide (II) and with semicarbazide (IV) proceed analogously to afford the respective products, the 1,3,4‐thiadiazoles (III) and the 1,3,4‐oxadiazoles (V).
ChemInform Abstract: Stereochemistry of Intramolecular Cyclopropanation of an Organoiron Reagent.
Authors: IYER R. S. , KUO G.‐H. , HELQUIST P. 
Published: May 2016

Abstract4‐Pentenyl‐bromid (I) liefert das lodid (II), das in den Eisen‐cyclopentadienyl‐carbonyI‐Komplex (III) übergeführt wird, der bei der sauren Zersetzung über eine Carben‐Zwischenstufe Norcaran (IV) in schlechter Ausbeute ergibt.
ChemInform Abstract: Photoisomerization of 2‐(Trimethylsilyl)pyrroles.
Authors: BARTON T. J. , HUSSMANN G. P. 
Published: May 2016

AbstractDie Photolyse der 2‐Trimelhy . silylpyrrole (I) oder (III) führt zu einer Umlagerung in B‐Trimethylsilyhbe?vate i (H) bzw. (IV) und (V) über diskutierte bicyclische Zwischenstufen.
ChemInform Abstract: Oxidations with Lead Tetraacetate. Part 6. Oxidations of Benzimidazoles, Benzoxazoles and Benzothiazoles.
Authors: COLE E. R. , CRANK G. , SUMANTRI SUMANTRI 
Published: May 2016

AbstractBenzimidazole (Ia) is oxidized by various amounts of lead tetraacetate to give the products (IIa) to (IIIb) as shown in the scheme [with excess oxidant, oxidation also occurs in the benzene ring at C‐5. The compound (IIc) 37 is formed in very smaII amounts.] Benzoxazole (Ib) is much more reactive and a variety of products [(IV)‐(VII)] formed by oxidation of both rings.
ChemInform Abstract: Oxidation of Methylquinolines with Nickel Peroxide.
Authors: LADNER D. W. 
Published: May 2016

AbstractAuf der Suche nach einem Oxidationsmittel zur Umsetzung von (Ia) und (Ib) zu der als Herbizid‐Zwischenprodukt benötigten Acridinsäure (II) erweist sich in situ hergestelltes Nickelper; oxid als gut geeignet.
ChemInform Abstract: An Accelerated Diastereoselective Variant of the Amide Acetal Claisen Rearrangement.
Authors: WELCH J. T. , ESWARAKRISHNAN S. 
Published: May 2016

AbstractAus den Amiden (I) bzw. (VI) werden die Salze (II) bzw. (VII) hergeste 3 und diese mit dem Li‐butenolat (III) zu Mischungen der substituierten Amide (I und (V) bzw. (VIII) und (IX) umgesetzt.
ChemInform Abstract: Novel Route from Thiocarbamate to Isocyanate: 2,2,2‐Trinitroethyl Isocyanate.
Authors: SITZMANN M. E. , GILLIGAN W. H. 
Published: May 2016

AbstractTrinitromethan (I) reagiert mit Formaldehyd und Thiocarbaminat (II) zur Mannich‐Verbindung (III), die mit Phenylsulfenylchlorid (IV) oder Chlor über die Carb‐ ,n amlusaurecnlona‐otule (v) zu uem Isocyanat n1) gespalten wlru.
ChemInform Abstract: Reaction of Chlororhodan and Dirhodan with Cyclopropene Hydrocarbons.
Authors: KARTASHOV V. R. , SKOROBOGATOVA E. V. , AFANAS'EV P. S. , AKIMKINA N. F. , GRUDZINSKAYA E. YU. , ZEFIROV N. S. 
Published: May 2016

AbstractThe reactions of dirhodan (Ia) and of chlororhodan (Ib) with the cyclopropenes (II) and (IV) and with propene (VIII) are investigated for a comparison with the known results of the reactions of sulphenyl chlorides with these hydrocarbons.
ChemInform Abstract: The Synthesis und Tuberculostatic Activity of N‐Alkyl‐N‐[6‐(dimethylaminomethylene)cyclohexene‐1‐yl‐1]amides or Carboxylic Acids.
Authors: KAYUKOVA L. A. , DYUSENOVA Z. M. , BLEKHMAN I. M. , URAZOV K.‐B. S. , ERZHANOV K. B. 
Published: May 2016

AbstractDie Cyclohexanonimine (I) werden durch Umsetzung mit Carbonsäurechloriden (II) in N‐Acyl‐enamine (III) umgewandelt.
ChemInform Abstract: The Wittig‐Horner Reaction in Heterogenous Media. Part 8. Cyclisation During the Aldolisation Step from Aqueous Glutaraldehyde.
Authors: VILLIERAS J. , RAMBAUD M. , GRAFF M. 
Published: May 2016

AbstractLegt man Glutaraldehyd (I) in wäßrig‐basischer Lösung im Überschuß vor und dosiert die Phosphonate (IIa)‐(Ilc) zu, so erfolgt Cyclisierung zu den Cyclohexenolen (IIIa)‐(IIIc).
ChemInform Abstract: Synthesis of anti‐9‐Bromo‐ and anti‐9‐Chlorobicyclo[4.2.1]nonatriene via Bicyclo[4.2.l]nonatriene → Bicyclo[4.2.l]nonatriene Rearrangement.
Authors: GOLDSTEIN M. J. , BARREN J. P. 
Published: May 2016

AbstractThe title compounds (IV) and (V) can be synthesized Starting from the ketone (I).
ChemInform Abstract: α,β‐Unsaturated Thio Compounds. Part 17. Synthesis and Some Chemical Conversions of the Thio Derivatives of 2‐Aryl‐indanones und the 2‐Aryl‐1,3‐indandiones.
Authors: PETRIASHVILI K. A. , USOV V. A. , VORONKOV M. G. 
Published: May 2016

AbstractThe Z‐aryl‐1‐indanones (I) and the 2‐arylindane‐L3‐diones (III) are converted 3 the novel I‐mercapto‐Zarylindenes (II) and to the 3‐mercapto‐2‐aryl‐1‐indenethio nes (IV) by H,S/H . The reactivity of the novel l‐mercapto‐2‐phenylindene (I1a)i5 investigated.
ChemInform Abstract: α,β‐Unsaturated Thio Compounds. Part 19. Synthesis of Monothiocarbonyl Analogues of 2‐Benzoyl‐1,3‐indanedione.
Authors: KORCHEVIN N. A. , USOVA T. L. , VASIL'EV A. V. , DOROFEEV I. A. , USOV V. A. , VORONKOV M. G. 
Published: May 2016

AbstractThe title compound (I) is converted to (h; in danethione (II) by HZS/H . The reactions of (I) with HCl or HBr in the pfesenoc P2O5 yield the Z‐(a‐halobenzylidenc)‐indane‐1,3‐diones (IIIa) or(IIIb), These m casily with H2S in thc presence of NEt3 to form 2‐thiobenzoyl derivatives a; 5110m by the conversion of (IIIb) 1o the novel compound (IV).
ChemInform Abstract: Studies on Antiinflammatory Activity Among a Series of Substituted Indan Acids.
Authors: MUKHOPADHYAY A. , ROY A. , LAHIRI S. C. 
Published: May 2016

AbstractDie lndancarbonsäuren (Ia)‐(Ic) werden über ihre Säurechloride mit Diazomethan in die homologen Carbonsäurederivate (IIa)‐(IIc) bzw. weiter in (IIIa)‐(IIIc) übergefühn und auf ihre entzündungshemmende Wirkung untersucht.
ChemInform Abstract: Synthesis and Photochemical Properties of Phenoxy Derivatives of Benzanthrone.
Authors: GERASIMENKO YU. E. , SOKOLYUK N. T. , PISULINA L. P. 
Published: May 2016

AbstractThe title compounds (III), (IV) and (V) are prepared in order to compare the UV/ VIS absorptions of their solutions in benzene to those of heterocyclic Jt‐electronic analogues, i.e. phenoxyanthraceno‐ and naphthacenopyridines.
ChemInform Abstract: Vinyl Ethers Containing an Epoxy Group. Part 10. Vinylepoxyacetals.
Authors: NEDOLYA N. A. , KHIL'KO M. YA. , TROFIMOV B. A. 
Published: May 2016

AbstractThe reaction between glycidol (I) and the divinyl compounds (II) or (V) is catalyzed by acids, e.g. C3F7COOH, to afford the desircd monoadducts, i.e. the vinylic epoxyacelals (III) and (VI) along with the bis‐adducts (IV) and (VII) as by‐products.
ChemInform Abstract: Pyrroles from Ketoximes and Acetylene. Part 31. A Study of the Reaction of Cyclohexanone Oxime with Vinyl Halides in Superbasic Media.
Authors: ALIEV I. A. , MIKHALEVA A. I. , BAIRAMOVA S. KH. , AKHMEDOV E. I. 
Published: May 2016

AbstractThe reactlon of cycla hexanone oxime (I) with the vinyl halides (II) in t‐he presgncg of KOH/DMso a? fords the tetrahydroindole (III) along with its N‐vmyl denvauve (IV) Wlth a comb′? ned yield of up to 60%.
ChemInform Abstract: The Synthesis, Properties and Biological Activity of 2,6‐Dioxa‐3,3,6,6‐ tetraphenylpyrrolino[3,2‐f]indoline‐1,7‐diacetic Acid.
Authors: BOLOTOV V. V. , NAMBELBAI A. , DROGOVOZ S. M. , VEREITINOVA V. P. 
Published: May 2016

AbstractDas aus dem Bis‐oxamsäureester (I) durch Umsetzung mit Phenylmagnesiumbromid (II) hergestellte Derivat (III) wird mit konzentrierter Schwefelsäure zu Dioxo‐pyrrolino‐indolin (IV) cyclisiert.
ChemInform Abstract: Facile Conversion of 4(5)‐Nitro‐5(4)‐methylimidazoles into 4(5)‐Nitro‐5(4)‐cyano‐imidazoles.
Authors: HOSMANE R. S. , BHAN A. , RAUSER M. E. 
Published: May 2016

AbstractAus dem Nitro‐dimethylimidazol (I) (bzw. seinem Isomeren) erhält man mit Dimethylformamidacctal und Trifluoressigsäure das Enamin (II), das mit Natriumnitrit in das Oxim (III) übergeführt wird.
ChemInform Abstract: Synthesis of Thiazolyldithiocarbamates und Their Metal Complexes as Potential Antifungal and Antibacterial Agents.
Authors: AHLUWALIA V. K. , ARORA K. K. , KAUR G. 
Published: May 2016

AbstractAus den Thiazolen (I) erhält man die fungizid ; wirkenden sauren Dithiocarbamate (II) und ihre Metallkomplexe (III).
ChemInform Abstract: Transformation of 3,3‐Bis(trifluoromethyl)‐2,2‐dihydro‐1,4,2‐oxaza‐ phosphol‐ 4‐enes and ‐1,4,2‐thiazaphosphol‐4‐enes into 5‐Fluoro‐4‐(trifluoromethyl)oxazoles und ‐thiazoles.
Authors: BURGER U. , HUEBL D. + 
Published: May 2016

AbstractDie im Titel genannten Verbindungen (I) werden mit Zinn(II)‐chlorid in die Heterocyclen (II) umgewandelt.
ChemInform Abstract: Synthesis of Heptazolidine.
Authors: ROY S. , CHATTERJEE S. K. , CHAKRABORTY D. P. 
Published: May 2016

AbstractDas Heptazolidin (VII) gewinnt man aus dem Cy hexanon (I) und dem Phenylhydrazin (II) durch eine Fnschersche Indolsynthesy (III) und Reaktion mit Dimethylacrylsäurechlorid (IV), gefolgt von einer Dehy rung und Reduktion.
ChemInform Abstract: Studies on Positive Inotropic Agents. Part 2. Synthesis of (4‐Substituted 1‐Piperazinylcarbonyl)‐2‐(1H)‐quinolinone Derivatives.
Authors: TOMINAGA M. , YO E. , OGAWA H. , YAMASHITA S. , YABUUCHI Y. , NAKAGAWA K. 
Published: May 2016

AbstractDie Chinoloncarbonsäuren (I) Dihydrochinoloncarbonsäuren (V1), deren Herstellung beschrieben ist, wel‐dcn′ die Piperazide (V) bzw. (VII) übergeführt.
ChemInform Abstract: Heterocyclic Compounds with Bridgehead Nitrogen. Part 2. The Synthesis of Indeno[1,2:4,5]pyrimido[1,2‐a]benzimidazole‐13‐ones, Indeno[1,2‐b]pyrazolo[4,3‐e]pyridine‐3,5‐dione and Related Compounds.
Authors: METWALLY M. A. , ETMAN H. A. 
Published: May 2016

AbstractThe indanediones (Ia) and (Ib) react with 2‐aminobenzimidazole (II) to give (III).
ChemInform Abstract: Synthesis of 7‐Alkylbenzofuro[2′,3′:5,6]pyrimido[2,1‐a]isoindol‐6‐ones.
Authors: BABICHEV F. S. , MEL'NICHENKO A. V. , TYLTIN A. K. , KOVTUNENKO V. A. 
Published: May 2016

AbstractDie Kondensation von o‐Chlormethylbenzonitril (I) mit Aminobenzofurancarbonsäureestern (II) liefert Benzofuropyrimidoisoindolone (III), aus denen durch Alky die Salze (IV), die Anhydrobasen (V) und weiter deren Derivate (VI) erhalten wcf′ den.
ChemInform Abstract: Synthesis and Pharmacology of Some New Methyl 4‐[2‐Alkylthio‐4(3H)‐quinazolo‐3‐yl]phenyl Acetates.
Authors: SHRIDHAR D. R. , SASTRY C. V. R. , LAL B. , GURUMURTHY R. , PARIHAR P. , SINGH P. P. , NAIDU M. U. R. , RAO C. S. , JUNNARKAR A. Y. 
Published: May 2016

AbstractUm die emzündungshemmende Wirkung der Thiochin lone (V), (VII), (IX) sowie (X) zu untersuchen, werden diese Derivate auf dem: gegebenen Wege hergestellt.
ChemInform Abstract: [1,3]Dioxolo[4,5‐g]pyrimido[1,2‐a][3,l]benzothiazin‐6‐one.
Authors: GAKHAR H. K. , SACHDEV P. , GUPTA S. B. 
Published: May 2016

AbstractDer Anthranilsäureester (I) cyclisiert mit dem Thioisocyanal (II) über ein primär gebildetes Thioharnstoffderivat zu dem Heterocyclus (III), der unter Basenkatalyse zu dem Tetracyclus (IV) weiterreagiert.
ChemInform Abstract: The Synthesis and Biological Activity of Bisiodomethylates of sym‐Triazine‐Containing Dicarboxylic Acid Aminoesters.
Authors: ANTONYAN S. G. , ZAPLISHNYI V. N. , POGOSYAN G. M. , LIBINZON R. E. , LAVRETSKAYA E. F. , PYZHOV V. K. , BESSUDNOVA N. V. , SAKRISYAN D. A. , VATOLKINA O. E. 
Published: May 2016

AbstractAus den Z‐substituierten 4,6‐Bis‐(p‐carb‐ oxyphenoxy)‐triazinen bzw. deren Säurechloriden (I) werden durch Umsetzung mit Aminoalkoholen (II) die Ester (III) hergestellt und diese mit Methyliodid in die besser wasserlöslichen Bis‐methoiodide (IV) umgewandelt.
ChemInform Abstract: Bicyclic Host Cavities Derived from Triphenylamine ‐ Guest Selectivity und Redox Properties.
Authors: SCHRAGE H. , FRANKE J. , VOEGTLE F. + , STECKHAN E. 
Published: May 2016

AbstractChain‐elongation of the amine (Ia) with the dibromohexane (III) gives (Ib), which on treatment with (Ia) affords the bicyclic host compound (IIa).
ChemInform Abstract: Preparation of Pentamethyldisilanyl Trifluoromethanesulfonate and Some Pentamethyldisilanyl Ethers.
Authors: CUNICO R. F. 
Published: May 2016

AbstractDie im Titel genannte Verbindung (II), die aus Hexamethyldisilan (I) hergestellt wird, wird dazu verwendet, Alkohole (III) als Pentamethyldisilanylether (IV) zu schützen.
ChemInform Abstract: [2,2‐Difluoro‐1‐(trifluoromethyl)ethenyl]phosphonic Acid‐bis‐(trimethylsilyl) Ester.
Authors: HEINE J. , ROESCHENTHALER G.‐V. + 
Published: May 2016

AbstractDie im Titel genannte Verbindung (III) wird aus (I) oder (IV) erhalten.
ChemInform Abstract: Facile Stereospecific Synthesis of a Dihydroxyindenoindene Unit from a Alkyne and CO via Samarium‐Mediated CO and CH Activation.
Authors: EVANS W. J. , HUGHES L. A. , DRUMMOND D. K. , ZHANG H. , ATWOOD J. L. 
Published: May 2016

AbstractThe compound (II) reacts with CO via two intcrmediates, which were not isolated, to yield the new complex (III) (Overall yicld 70%), crystallizing in thc spacc group P21/n with Z=2.
ChemInform Abstract: Intramolecular Activation of Aliphatic Carbon ‐ Hydrogen Bonds at Tantalum(V) Metal Centers: A Comparison of Activation by Methyl and Methylidene Functional Groups.
Authors: CHAMBERLAIN L. R. , ROTHWELL I. P. , HUFFMAN J. C. 
Published: May 2016

AbstractThe thermal and photochemical reactivity of the trigonal bipyramidal Ta complexcs (II) containing sterically demanding aryloxide ligands, prepared as shown, are investigated.
ChemInform Abstract: cyclo‐P5 as a Complex Ligand ‐ the Phosphorus Analogue of the Cyclopentadienyl Ligand.
Authors: SCHERER O. J. , SCHWALB J. , WOLMERSHAEUSER G. + , KAIM W. , GROSS R. 
Published: May 2016

AbstractThe dimeric Cr complex (I) (Cra Cr) reacts with P4 ,to give the param tic p,n5‐P5 tripledeckcr complex (II) and onIy traces of thc n′‐P3‐complex (III).
ChemInform Abstract: Mixed Valence, Phosphine Stabilized Sulfido Clusters of the Transition Metals. Synthesis and Structure of Cr3(μ3‐S)2(μ2‐S)3(dmpe)3, Cr(III,III,IV) (dmpe: Bis(1,2‐dimethylphosphino)ethane). A Structurally Characterized Cr3 Cluster.
Authors: ARIF A. M. , HEFNER J. G. , JONES R. A. , ALBRIGHT T. A. , KANG S.‐K. 
Published: May 2016

AbstractThe title complex (I) is prepared by 1:2 molar reaction of anhydrous CrCl2 with NaSH in MeOH at ‐ 78 °C followed of addition of excess of the diphosphine and warming slowly to room temperature.
ChemInform Abstract: Preparation und Properties of Molybdenum and Tungsten Dinitrogen Complexes. Part 23. Synthesis and Characterization of Alkenyldiazenido, Alkenylhydrazido(2‐), and Diazoalkane Complexes of Tungsten and Molybdenum.
Authors: HIDAI M. , ARAMAKI S. , YOSHIDA K. , KODAMA T. , TAKAHASHI T. , UCHIDA Y. , MIZOBE Y. 
Published: May 2016

AbstractStarting with the dinitrogen complex (I) a novel alkenyldiazenido complex (II) was obtained.
ChemInform Abstract: Synthesis and Reactivity of Metallacyclic Manganese α‐Hydroxyalkyl Complexes Containing Aliphatic Bridges and Phosphorus and Nitrogen Donor Atoms. First Carbonylation of an Isolable α‐Hydroxyalkyl Complex.
Authors: VAUGHN G. D. , GLADYSZ J. A. 
Published: May 2016

AbstractReaction of the Mn hydride (I) with the phosphinopropionaldehyde (II) gives the complex (III) with monodentately P‐bound Iigand, which cannot be induced to cyclize to the corresponding α‐hydroxyalkyl complex.
ChemInform Abstract: η3‐1‐Phosphaallylic Iron Complexes with Additional W(CO)5 Coordination at the Phosphorus ‐ the 1‐Phosphaallylic Ligand as a 5e‐Donor.
Authors: MERCIER F. , FISCHER J. , MATHEY F. 
Published: May 2016

AbstractThe W(CO)5‐stab; i vinylphosphancs (II) prepared as shown react with the dimcric Fe complex ("Die yield the binuclear WFe complexes (IVa) and (IVb) containing a phosphaauy?c bridge.
ChemInform Abstract: Metalloporphyrins Obtained in Aqueous Solution Based on the 5,10,15,20‐Tetra‐p‐ (N,N‐dimethyl)anilinporphyrin.
Authors: SZULBINSKI W. , LAPKOWSKI M. 
Published: May 2016

AbstractIn order to transform (Ia) into a water soluble compound (Ib), (Ia) was treated with (EtO)2SO2, then the mixture was heated to the boiling point (yield 98%).