bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Azidocuprates(II). Crystal Structure of (PPh4)2(Cu2(N3)6).
Authors: FENSKE D. , STEINER K. , DEHNICKE K. 
Published: May 2016

AbstractReactions of the chlorocuprates (I) and (V) with excess silver azide in dichloromethane suspensions yield the tetraazidocuprate (VI) and the already known acidocuprate (III).
ChemInform Abstract: Mn2+/Mn3+ and Mn3+/Mn4+ Mixed Valence Binuclear Manganese Complexes of Biological Interest.
Authors: DISMUKES G. C. , SHEATS J. E. , SMEGAL J. A. 
Published: May 2016

AbstractThe tetraphenylporphyrin ligand forms stable complexes with Mn2+, Mn3+, and Mn4+.
ChemInform Abstract: Adducts of Titanium Tetrahalides with Neutral Lewis Bases. Part 1. Structure and Stability: A Vibrational and Multinuclear NMR Study.
Authors: TURIN E. , NIELSON R. M. , MERBACH A. E. 
Published: May 2016

AbstractIn contrast to the analogous tin adducts where a cis‐trans equilibrium prevails, the adducts (Ia) and (Ib) are found in CH2Cl2 solution to have the cis configuration only.
ChemInform Abstract: Supramolecular Catalysis of Phosphoryl Transfer: Pyrophosphate Synthesis from Acetyl Phosphate Mediated by Macrocyclic Polyamines.
Authors: HOSSEINI M. W. , LEHN J.‐M. 
Published: May 2016

AbstractThe rate of hydrolysis of the anhydride (IV) is enhanced by the factor 5 in the presence of protonated polyamine (Ia) at 40 °C. At pH 11 neither acceleration nor formation of the intermediate (Ib) is observed.
ChemInform Abstract: A Diels‐Alder Approach to 4,4′‐Thiobis(phthalic Acid) Derivatives.
Authors: STAHLY P. 
Published: May 2016

AbstractThermolysis of the thiobis(sulfolene) (II) yields the bis(butadienyl) sulfide (III) which reacts in situ with the maleimides (IVa) and (IVb) and maleic anhydride (IVc), producing the cycloadducts (V).
ChemInform Abstract: O‐Allyl Ether as a New Protective Group for Oximes and Its PalladiumCatalyzed Deprotection.
Authors: YAMADA T. , GOTO K. , MITSUDA Y. , TSUJI J. 
Published: May 2016

AbstractThe oxime allyl ethers (III), prepared from the oximes (I), are deprotected in the presence of a Pd catalyst to give the oximes (I) and propene (IV).
ChemInform Abstract: Hydrogenation of Diaryl and Aryl Alkyl Ketones by Sodium Borohydride and Aluminum Chloride.
Authors: ONO A. , MARUYAMA T. , SUZUKI N. 
Published: May 2016

AbstractThe aryl ketones (I) are reduced with sodium borohydride in the presence of aluminum trichloride to give the hydrocarbons (II) as the main products.
ChemInform Abstract: A New Synthesis of 1,1‐Bis(trifluoromethyl) Substituted Alkenes.
Authors: HANACK M. , KORHUMMEL C. 
Published: May 2016

AbstractThe title compounds (III) are prepared by reaction of 2,2‐dichlorohexafluoropropane (I) with triphenylphosphine and the aldehydes (II).
ChemInform Abstract: Carboxylation of Arenes.
Authors: MENEGHELI P. , REZENDE M. C. , ZUCCO C. 
Published: May 2016

AbstractThe benzoic acids (IV) are prepared by oxidative basic hydrolysis of the 1‐aryl‐2,2,2‐trichloroethanols (III) which are obtained from the arenes (I) and chloral (II) or its hydrate.
ChemInform Abstract: Control of the Birch Reduction of m‐Anisic Acid to Produce Specific 3‐Oxocyclohexenecarboxylic Acids.
Authors: WEBSTER F. X. , SILVERSTEIN R. M. 
Published: May 2016

Abstractm‐Anisic acid (I) is subjected to a reaction sequence of Birch reduction, potassium hydroxide isomerization, and acidic hydrolysis to form 5‐oxo‐1‐cyclohexenecarboxylic acid (II).
ChemInform Abstract: Reaction in Low‐Hydrated Solid‐Liquid Heterogeneous Medium: Thiirane Synthesis from Epoxides.
Authors: BOUDA M. , BORREDON E. , DELMAS M. , GASET A. 
Published: May 2016

AbstractThe epoxides (I) are converted to the corresponding thiiranes (II) by treatment with potassium thiocyanate either in the solid state or in an ethanolic solution.
ChemInform Abstract: Synthesis of Multisulfur‐Containing Substituted Dibenzothiophenes.
Authors: DUNKERTON L. V. , BAROT B. C. , NIGAM A. 
Published: May 2016

AbstractDibenzothiophene (Ia) is converted to the mercaptomethyl derivatives (If), (Ik), and (IIf) as outlined in the reaction scheme.
ChemInform Abstract: Iminophosphorane‐Mediated Synthesis of 4‐Heteroarylmethylene‐2‐aryl‐2‐ oxazolin‐5‐ones.
Authors: MOLINA P. , FRESNEDA P. M. , HURTADO F. 
Published: May 2016

AbstractThe iminophosphoranes (I) and (IV), obtained from the corresponding 2‐azido‐3‐arylacrylates and triphenylphosphine, undergo cyclocondensation with the aroyl chlorides (II) to produce the heteroarylmethylenearyloxazolinones (III) or (V).
ChemInform Abstract: Photosensitized (SET) Conversion of 2′‐Hydroxychalcones to Flavonoids. A Probable Biogenetic Pathway.
Authors: PANDEY G. , KRISHNA A. , KUMARASWAMY G. 
Published: May 2016

AbstractIrradiation of the 2‐hydroxychalcones (I) in the presence of 9,10‐dicyanoanthracene yields the flavonoids (III) ‐ (V).
ChemInform Abstract: A New Synthesis of cis‐1,6‐Diphenyl‐2,5,7,10‐tetraoxabicyclo(4.4.0)decane and Related Six Membered Cyclic Oxido Compounds.
Authors: LOPEZ L. , CALO V. , STASI F. 
Published: May 2016

AbstractThe title compounds (III) are obtained by one‐electron‐transfer oxidation of the dihydrodioxins (I) with tris(4‐bromophenyl)ammonium tetrafluoroborate in a mixture of ethylene glycol (II) and methylene chloride.
ChemInform Abstract: Hydrazino‐Bridged Annulenes. Part 6. Synthesis and Properties of 10b,10c‐Diazadicyclopenta(ef,kl)heptalenes (Diazaazupyrenes).
Authors: FLITSCH W. , LUETTIG F.‐J. + , RUTKOWSKI K. 
Published: May 2016

AbstractStarting from the tetraester (I), the dihydrodiazaazupyrenes (VI) and (VII) are prepared via the Dieckmann condensation products (II) and the reduction products (III).
ChemInform Abstract: Synthesis and Determination of the Chirality Sense of (+)‐(R)‐1‐Azabicyclo(3.3.1)nonan‐2‐one.
Authors: BREHM R. , OHNHAEUSER D. + , GERLACH H. 
Published: May 2016

AbstractThe title compound (VII) is synthesized as shown in the scheme starting from the alcohol (I) which is obtained by resolution of the respective known racemate.
ChemInform Abstract: Synthesis of Aminophosphonic Acid Derivatives of 2‐Aminoglutaric Acid Analogues.
Authors: OSHIKAWA T. , YAMASHITA M. 
Published: May 2016

AbstractAllyl iodide (I) reacts with chlorosulfonyl isocyanate (II) to give the β‐lactam (III) which is converted to the phosphonic acid ester (V) by heating with triethyl phosphite (IV).
ChemInform Abstract: Synthesis and Thermodecomposition of Some Organylcadmium Alkoxides.
Authors: DODONOV V. A. , PANKRATOVA V. N. , SORVACHEVA T. M. , NAZAROVA G. E. 
Published: May 2016

AbstractThe cadmiumorganyls (I) react with the alcohols (II) or (VII) to give the alkoxy compounds (III) and (VIII).
ChemInform Abstract: Organometallic Synthesis of II‐VI Semiconductors. Part 1. Formation and Decomposition of Bis(organotelluro)mercury and Bis(organotelluro)cadmium Compounds.
Authors: STEIGERWALD M. L. , SPRINKLE C. R. 
Published: May 2016

AbstractThe product (IIIa), which is soluble only in coordinating media, is prepared as shown.
ChemInform Abstract: Carbonyl Addition Reaction by Means of β‐Silyl‐ and β‐Stannylphosphorus Ylides: Diastereoselective E‐Propenylation of α‐Chiral Aldehydes.
Authors: TSUKAMOTO M. , IIO H. , TOKOROYAMA T. 
Published: May 2016

AbstractThe β‐silyl or β‐stannyl phosphorus ylides (IIIb) ‐ (IIIf) react with phenylpropionaldehyde (IV) to give the allyl silyl or stannyl ethers (VI), together with neglegible amounts of the olefins (V).
ChemInform Abstract: Models for Iron‐Oxo Proteins: A Mixed‐Valence Iron(II)‐Iron(III) Complex.
Authors: BOROVIK A. S. , MURCH B. P. , QUE L. JUN. , PAPAEFTHYMIOU V. , MUENCK E. + 
Published: May 2016

AbstractThe title complex (II) is formed from (I) by reversible electrochemical reduction and by treatment of a MeOH solution of (I) with β‐mercaptoethanol and excess NMe4Cl in the presence of NaOAc/HOAc under N2.
ChemInform Abstract: Crown Thioether Chemistry of Iron(II/III). Synthesis and Characterization of Low‐Spin Bis(1,4,7‐trithiacyclononane)iron(III) and Crystal Structure of (Fe(II)((9)aneS3)((9)aneS3(O)))(ClO4)2·2 NaClO4·H2O.
Authors: KUEPPERS H.‐J. + , WIEGHARDT K. , NUBER B. , WEISS J. , BILL E. , TRAUTWEIN A. X. 
Published: May 2016

AbstractThe oxidation of (I) with PbO2 affords the low‐spin Fe(III) complex (II), characterized by magnetic susceptibility measurements, electronic and Moessbauer spectra, whereas the oxidation in aqueous solution with Na2S2O8 leads to oxidation of the ligand yielding (III) together with mixed crystals containing the cations of (I) and (III).
ChemInform Abstract: Potassium Fluoride‐Celite as a Heterogeneous Catalyst in Arylation of 1,3‐Dicarbonyl Compounds by Arenes Activated by Complexation with the Ironcyclopentadienyl Moiety.
Authors: SUTHERLAND R. G. , ABD‐EL‐AZIZ A. S. , PIORKO A. , LEE C. C. 
Published: May 2016

AbstractThe iron cyclopentadienyl chloroarene or nitroarene complexes (I) are coupled with the 1,3‐dicarbonyl compounds (II) in the presence of potassium fluoride absorbed on celite to form the substituted arenes (III).
ChemInform Abstract: Multiply Bonded Octahalodiosmate(III) Anions. Part 4. Reactions with Nitrogen and Phosphorus Donor Ligands That Lead to Cleavage of the OsOs Bond.
Authors: FANWICK P. E. , FRASER I. F. , TETRICK S. M. , WALTON R. A. 
Published: May 2016

AbstractSalts of the octahalodiosmate(III) anions (Os2X8)2‐ (X: Cl, Br) react with monodentate phosphines in alcohol solvents to give the various mononuclear Os(III) and Os(II) species (Ia), (Ib), and (II)‐(IV), or the halide‐bridged Os(II) complexes (V).
ChemInform Abstract: Chemistry of Pyrrole Pigments. Part 74. Control of the Diastereomeric and Conformational Equilibria of Bilatrienes‐abc by 10‐Heteroaryl Substituents with Hydrogen Bonding Acceptor and Donor Functions.
Authors: FALK H. , MUELLER N. + , WOESS H. + 
Published: May 2016

AbstractWhereas (IIIa) and (IIIb) adopt the common circular helical arrangement of the bilin chromophor in a variety of solvents like CHCl3, MeOH, and DMSO, (IIIc) exhibits a dramatic solvent dependence of its geometry.
ChemInform Abstract: Synthesis of Deoxyfluoroglycosides and Cleavage of Silyl Groups by the Triethylamine Hydrofluoric Acid Complex.
Authors: PICQ D. , ANKER D. 
Published: May 2016

AbstractGlycosides such as (I), (III), or (V) react with the triethylamine hydrofluoric acid complex to give the deoxyfluoro sugars (II), (IV), and (VI).
ChemInform Abstract: Reactions of CrO2Cl2, FeCl2, FeCl3, CoCl2, MoCl5 and AlCl3 with Benzofuroxan. Part 2.
Authors: MURO C. , FERNANDEZ V. 
Published: May 2016

AbstractThe compounds (I)‐(III) are obtained by reaction of benzofuroxan with CrO2Cl2, FeCl2 and AlCl3, respectively.
ChemInform Abstract: Molecular Modeling of Zeolite Structure. Part 1. Properties of the Sodalite Cage.
Authors: MABILIA M. , PEARLSTEIN R. A. , HOPFINGER A. J. 
Published: May 2016

AbstractThe major finding of free‐valence geometry molecular mechanics calculations on a sodalite cage is that the incorporation of Al atoms into the sodalite cage has little effect on the optimized molecular geometry, but plays a major role on structural stability.
ChemInform Abstract: Interfacial Energetics of Electrodeposited Cadmium Selenide in Acetonitrile.
Authors: SZABO J. P. , COCIVERA M. 
Published: May 2016

AbstractPolycrystallinic thin film CdSe, prepared by cathodic electrodeposition from aqueous selenosulfite solution and annealed in either air or oxygen has similar interfacial properties to single crystal CdSe, which exhibits Fermi level pinning in the presence of various redox couples in MeCN.
ChemInform Abstract: Metal Pseudohalogenides. Part 44. On the Influence of Potassium Tricyanmethanide and Dicyanamide on the Anodic Behavior of Copper in Aqueous Solutions.
Authors: KOEHLER J. M. , KOEHLER H. 
Published: May 2016

AbstractKC(CN)3 and KN(CN)2 show a strong tendency to passivate copper in aqueous solutions.
ChemInform Abstract: Migration of Molybdenum into Intracrystalline Cavities in Molybdate‐Impregnated NaY Zeolite.
Authors: FIERRO J. L. G. , CONESA J. C. , LOPEZ AGUDO A. 
Published: May 2016

AbstractMoY zeolites are prepared by thermal decomposition of molybdate‐impregnated NaY zeolites using a constant‐rate decomposition at very low H2O pressure (10 N m‐2).
ChemInform Abstract: A New Route to Potassium and Ammonium Pentaborate Dihydrates, A(B5O6(OH)4)·2 H2O (A: K or NH4) (I), and Synthesis and Structural Assessment of New Fluoro(hydroxo)oxoborate Dihydrates, A2(B2O2F2(OH)2)·2 H2O (A: K or NH4) (II).
Authors: CHAUDHURI M. K. , DAS B. 
Published: May 2016

AbstractThe compounds (I) have been prepared by the reaction of boric acid (suspension in water) with KOH or NH3 (pH 9) and subsequent addition of acetylacetone (yields: A = K, 34%; A = NH4, 32%).
ChemInform Abstract: Electronic Structure of Cyclopropenone and Its Relationship to Methylenecyclopropene. Evaluation of Criteria for Aromaticity.
Authors: STALEY S. W. , NORDEN T. D. , TAYLOR W. H. , HARMONY M. D. 
Published: May 2016

AbstractThe heavy‐atom microwave (rs) structure of cyclopropenone is recomputed to be r(C1O) = 1.212 Å, r(C1C2) = 1.423 Å, and r(C2C3) = 1.349 Å.
ChemInform Abstract: Intramolecular Transformations of 2‐Cyclopropylazobenzenes Catalyzed by Protic Acids.
Authors: FEDOTOV A. N. , SHISHKINA I. N. , KUTATELADZE T. G. , MOCHALOV S. S. , SHABAROV YU. S. 
Published: May 2016

AbstractThe cyclopropylazobenzenes (III) are prepared by known methods.
ChemInform Abstract: Effective Photoreduction of CO2/HCO‐ 3 to Formate Using Visible Light.
Authors: MANDLER D. , WILLNER I. 
Published: May 2016

AbstractIn a system composed of aqueous NaHCO3, deazariboflavin (as photosensitizer), methyl viologen (as primary electron acceptor), oxalate (as sacrificial electron donor), and a β‐cyclodextrin stabilized Pd colloid CO2 is photoreduced (> 400 nm) to HCOOH (quantum yield = 1.1).
ChemInform Abstract: A Stable and Easily Prepared Catalyst for the Enantioselective Reduction of Ketones. Applications to Multistep Syntheses.
Authors: COREY E. J. , BAKSHI R. K. , SHIBATA S. , CHEN C.‐P. , SINGH V. K. 
Published: May 2016

AbstractThe B‐methylated oxazaborolidine (IV) which is accessible from pyroglutamic acid (I) via the ligand (II) is an effective and stereoselective catalyst for the BH3 reduction of ketones such as (V) ( → (VI)) (VII), (VIII) (analogous reaction) as well as (IX) ‐ an important prostaglandin precursor ‐ or (XI).
ChemInform Abstract: Chemistry of Aryl‐Lead(IV) Tricarboxylates. Reaction with Vinylogous β‐Keto Esters.
Authors: ACKLAND D. J. , PINHEY J. T. 
Published: May 2016

AbstractHagemann's ester (IIa) and the demethyl analogue (VI) (in equilibrium with the isomer (VII)) in Py/CHCl3 or in DMSO undergo regiospecific arylation at C‐1 with aryl‐lead triacetates (I) to yield (III) and (VIII), respectively.
ChemInform Abstract: Thermal Generation and Dimerization of (4)Metacyclophane.
Authors: KOSTERMANS G. B. M. , VAN DANSIK P. , DE WOLF W. H. , BICKELHAUPT F. 
Published: May 2016

AbstractThe title species (II) is generated by thermolysis of its Dewar isomer (I); the ratio of the sequential dimeric products (III)‐(VIII) formed is depending on the thermolysis conditions as outlined in the scheme.
ChemInform Abstract: The Correct Synthesis of 2,3‐Dihydro‐2‐aryl‐4‐R‐(1)benzopyrano(4,3‐c)pyrazole‐3‐ones.
Authors: COLOTTA V. , CECCHI L. , MELANI F. , PALAZZINO G. , FILACCHIONI G. 
Published: May 2016

AbstractThe benzoylacetate (I) reacts with the arylhydrazines (II) to give the pyrazolinones (III) which are debenzylated to form the phenols (IV).
ChemInform Abstract: Exceptional Stereochemical Control in the Pictet‐Spengler Reaction.
Authors: BAILEY P. D. , HOLLINSHEAD S. P. , MCLAY N. R. 
Published: May 2016

AbstractThe synthesis of the β‐carbolines (III) from tryptophane methyl ester (I) and the aldehydes (II) by Pictet‐Spengler reaction is performed under various conditions.
ChemInform Abstract: Synthesis of 1,2,3,4‐Tetrahydro‐β‐carboline Derivatives as Hepatoprotective Agents. Part 4. Positional Isomers of 1,2,3,4‐Tetrahydro‐2‐methylthiocarbonyl‐β‐carboline‐3‐carboxylic Acid and Its 1‐Alkylated Derivatives.
Authors: SAIGA Y. , IIJIMA I. , ISHIDA A. , MIYAGISHIMA T. , TAKAMURA N. , OH‐ISHI T. , MATSUMOTO M. , MATSUOKA Y. 
Published: May 2016

AbstractThe β‐carbolines (I) are converted to the corresponding dithiocarbamates (IV) by reaction with carbon disulfide (II) and methyl iodide (III) in the presence of a base.
ChemInform Abstract: Photoinduced Reactions. Part 96. Photochemistry of Conjugated Nitrogen‐ Thiocarbonyl Systems. Part 5. Two‐Fold Photoaddition of Vinyl Ethers to Aza‐Aromatic Thiones.
Authors: SATO E. , IKEDA Y. , KANAOKA Y. 
Published: May 2016

AbstractIrradiation of mixtures of the heterocyclic thiones (I), (V), and (VIII) with the vinyl ethers (II) results in addition and insertion of (II), forming the di(alkoxyethyl) sulfides (III), (VI), or (IX), together with the disulfides (IV) or (Xa) or the sulfides (VII).
ChemInform Abstract: Paramagnetic Derivatives of Hexahydroimidazo(1,5‐c)pyrimidines.
Authors: REZNIKOV V. A. , VOLODARSKII L. B. 
Published: May 2016

AbstractReaction of the 4‐nitromethylenimidazolidine‐1‐oxyl (I) with formaldehyde (II) and the amines (III) or (V) gives the anellated products (IV) or (VI).
ChemInform Abstract: Chemistry of Multidentate Ligands. Part 8. Crown and Azacrown Ethers with Pendant Adenine Group.
Authors: HOLY P. , BELOHRADSKY M. , STIBOR I. , KOUDELKA J. , SAMAN D. , HODACOVA J. , HOLY A. , ZAVADA J. 
Published: May 2016

AbstractRing‐opening reaction of the epoxides (II) with adenine (I) yields the compounds (III) as major products (for (IV) and (V) no yields given).
ChemInform Abstract: Synthesis of New Type Silybin Analogues: 2‐(1,5‐Benzodioxepan‐7‐yl)chromonoids.
Authors: PATONAY T. , LITKEI G. , PELI E. , KHILYA V. P. , AITMAMBETOV A. 
Published: May 2016

AbstractVarious 2‐hydroxyacetophenones (I) are coupled with benzaldehydes such as (II), forming the chalcones (III) which are cyclized to give the flavanones (IV).
ChemInform Abstract: A Simple One‐Pot Synthesis of tert‐Butyldimethylsilyl‐Protected Cyanohydrins.
Authors: YONEDA R. , HISAKAWA H. , HARUSAWA S. , KURIHARA T. 
Published: May 2016

AbstractConversion of the aldehydes (I) to the protected cyanohydrins (III) is carried out using tert‐butyldimethylsilyl chloride (II) and lithium cyanide.
ChemInform Abstract: Silicon‐Sulfur Compounds. Part 49. Reaction of Silicon‐Sulfur Compounds with Glycols.
Authors: FELCYN E. W. , WOJNOWSKI W. 
Published: May 2016

AbstractReactions of Ph3SiSH, (Alk‐O)3SiSH (Alk: iPr, sBu, tBu), (Alk‐O)2Si(SH)2 (Alk: iPr, tBu), cyclo‐((tBuO)2SiS)2, and SiS2 with aliphatic glycols are investigated.
ChemInform Abstract: Macrocycles Containing Tin. Through Space Cooperative Binding and High Size Selectivity in the Complexation of Chloride Ion by Lewis Acidic Macrobicyclic Hosts.
Authors: NEWCOMB M. , HORNER J. H. , BLANDA M. T. 
Published: May 2016

AbstractThe neutral Lewis acidic macrobicycles (Va) (from (Ia) via (IIa) and (IVa)), (VI), and (VII), in which both the dynamics and energetics of binding of chloride anion are highly size dependent, are studied comparatively.
ChemInform Abstract: Reactions of the Dianion of (η6:η6‐Biphenyl)bis(tricarbonylchromium) with Electrophiles. A Highly Regioselective Route from Biphenyl to 2‐Alkylbiphenyls and 5‐Alkyl‐5‐phenyl‐1,3‐cyclohexadienes.
Authors: SCHULTE L. D. , RIEKE R. D. 
Published: May 2016

AbstractChemical reduction of the biphenyldichromium complex (I) yields the stable dianion (II) which reacts with one equivalent of various electrophiles (III) to produce the monoanions (IV).
ChemInform Abstract: σ‐Assisted Exchange Interactions in Linear Adducts of Nitroxides with Dirhodium Tetrakis(trifluoroacetate).
Authors: COGNE A. , GRAND A. , REY P. , SUBRA R. 
Published: May 2016

AbstractThe nitronyl (I) and imino nitroxides (II) have two conjugated coordination sites.
ChemInform Abstract: A Note on the Use of Porous Silver Silicates as Promoter in Carbohydrate Coupling Reactions.
Authors: VAN BOECKEL C. A. A. , BEETZ T. , KOCK‐VAN DALEN A. C. , VAN BEKKUM H. 
Published: May 2016

AbstractDifferent insoluble silver‐salt promoters show different activity in the title reaction of the compounds (I) and (II) but do not influence the α/β ratio of the products (III).
ChemInform Abstract: Applications of the Stereochemically‐Controlled Horner‐Wittig Reaction: Synthesis of Feniculin, (E)‐Non‐6‐en‐1‐ol, a Pheromone of the Mediterranean Fruit Fly, (E)‐ and (Z)‐Dec‐5‐en‐1‐ol, Trisubstituted Alkenes, and (Z)‐α‐Bisabolene.
Authors: BUSS A. D. , GREEVES N. , MASON R. , WARREN S. 
Published: May 2016

AbstractStereoselective reduction of the Horner‐Wittig adduct (III) derived from (I) and (II) affords the threo alcohol (IV).
ChemInform Abstract: Electrochemistry of Iron Oxides: An in situ Moessbauer Study.
Authors: FIERRO C. , CARBONIO R. E. , SCHERSON D. , YEAGER E. B. 
Published: May 2016

AbstractThe in situ Moessbauer study of the electrochemical oxidation of Fe(OH)2 dispersed on high surface area carbon in 4 M KOH shows that an ensemble of small magnetite particles of varying size is formed when the reaction is performed by stepping the potential to ‐0.3 V (vs.
ChemInform Abstract: A SERS Study on Inhibition Mechanisms of Benzotriazole and Its Derivatives for Copper Corrosion in Sulfate Solutions.
Authors: YOUDA R. , NISHIHARA H. , ARAMAKI K. 
Published: May 2016

AbstractIt is shown that the inhibition effect with respect to Cu corrosion in sulfate solution for the compounds studied is in the order (Ib) > (Ia) > (Ic) (see scheme).
ChemInform Abstract: Elucidation of Structural Relationships and Assignment of 1H NMR Spectra of Transition‐Metal Cyclidene Complexes by 2‐D NMR Techniques.
Authors: MEADE T. J. , FENDRICK C. M. , PADOLIK P. A. , COTTRELL C. E. , BUSCH D. H. 
Published: May 2016

AbstractA complete assignment of the 1H NMR spectra of the five cyclidene complexes (I) is given.
ChemInform Abstract: Molecular Stereochemistry of Aquomanganese(III) Porphyrins. Demonstrable Effect of π‐Arene‐Porphyrin Interaction on the Metal Coordination Environment in a Metalloporphyrin.
Authors: WILLIAMSON M. M. , HILL C. L. 
Published: May 2016

AbstractThe complexes (III) or (IV) are formed in non‐polar organic solvents depending on the amount of water added.
ChemInform Abstract: The Trityl Cation Mediated Michael Reaction of Ethylthio Ketene Dithioacetals with Silyl Enol Ethers.
Authors: HASHIMOTO Y. , SUGUMI H. , OKAUCHI T. , MUKAIYAMA T. 
Published: May 2016

AbstractStarting from (I) or (V), the ethylthioalkyl ketene dithioacetals (IV) are prepared.
ChemInform Abstract: Chemistry of Silylated Thioketones. Part 2. Cycloaddition Reactions with 1,3‐Dienes.
Authors: BONINI B. F. , LENZI A. , MACCAGNANI G. , BARBARO G. , GIORGIANNI P. , MACCIANTELLI D. 
Published: May 2016

AbstractThe reaction of the thiones (II) with cyclopentadiene (I) is diastereoselective yielding only the endo‐adducts (III).
ChemInform Abstract: The Rearrangement of Aromatic Nitro Compounds. Part 1. The Reactions of Nitroanilines in Aqueous Sulfuric Acid.
Authors: MURPHY J. T. , RIDD J. H. 
Published: May 2016

AbstractIn accordance with previous results, nitroanilines such as (I) and (IVa) show 1,3‐migration of the 2‐NO2 groups.
ChemInform Abstract: Enzyme‐Mediated H2O2 Oxidation of (E)‐Stilbene‐3,4‐diol.
Authors: DONNELLY D. M. X. , MURPHY F. G. , POLONSKI J. , PRANGE T. 
Published: May 2016

AbstractThe title reaction of (I) is investigated in order to gain insight into oxidation processes of natural stilbenes.
ChemInform Abstract: Selective Reduction of α,β‐Unsaturated Esters in the Presence of Olefins.
Authors: HUDLICKY T. , SINAI‐ZINGDE G. , NATCHUS M. G. 
Published: May 2016

Abstractα,β‐Unsaturated esters such as (I), (III), (V), and (VII) are selectively reduced with magnesium in methanol to give the corresponding saturated esters.
ChemInform Abstract: Synthesis and Transannular Diels‐Alder Reaction of a 13‐Membered Macrocyclic Triene Having a Tetrasubstituted Enol Ether as a Dienophile.
Authors: BERUBE G. , DESLONGCHAMPS P. 
Published: May 2016

AbstractThe triene (III) mentioned in the title is formed by cyclization of the ω‐chloroalkatrienylmalonate (II).