bluuebunny/crossref_metadata_2025_split huggingface dataset:
Unconventional Crystal Structure of the High-Pressure Superconductor
La3Ni2O7
Authors: Puphal P. , Reiss P. , Enderlein N. , Wu Y.-M. , Khaliullin G. , Sundaramurthy V. , Priessnitz T. , Knauft M. , Suthar A. , Richter L. , Isobe M. , van Aken P. A. , Takagi H. , Keimer B. , Suyolcu Y. E. , Wehinger B. , Hansmann P. , Hepting M. 
Published: October 2024

The discovery of high-temperature superconductivity in La3Ni2O7 at pressures above 14 GPa has spurred extensive research efforts. Yet, fundamental aspects of the superconducting phase, including the possibility of a filamentary character, are currently subjects of controversial debates. Conversely, a crystal structure with NiO6 octahedral bilayers stacked along the c-axis direction was consistently posited in initial studies on La3Ni2O7. Here, we reassess this structure in optical floating zone-grown La3Ni2O7 single crystals that show signs of filamentary superconductivity. Employing scanning transmission electron microscopy and single-crystal x-ray diffraction under high pressures, we observe multiple crystallographic phases in these crystals, with the majority phase exhibiting alternating monolayers and trilayers of NiO6 octahedra, signifying a profound deviation from the previously suggested bilayer structure. Using density functional theory, we disentangle the individual contributions of the monolayer and trilayer structural units to the electronic band structure of La3Ni2O7, providing a firm basis for advanced theoretical modeling and future evaluations of the potential of the monolayer-trilayer structure for hosting superconductivity.

Published by the American Physical Society
2024
Magnetic interactions in the cooperative paramagnet
Tb2Ti2O7
Authors: Roll A. , Balédent V. , Robert J. , Ollivier J. , Decorse C. , Guitteny S. , Mirebeau I. , Petit S. 
Published: October 2024

For about two decades, Tb2Ti2O7 has remained an enigma in condensed matter physics and frustrated magnetism. This material evades long-range order down to temperature as low as 20 mK, and, as in spin ice, its ground state exhibits puzzling diffuse magnetic scattering. To shed light on this issue, we present spin dynamics measurements by inelastic neutron scattering, which we confront with random phase approximation calculations (RPA) to determine exchange couplings capable of reproducing the dispersion of the first excited crystal electric field level. These couplings suggest that Tb2Ti2O7 lives at the boundary between several phases, in particular the spin ice and planar antiferromagnetic ones.

Published by the American Physical Society
2024
Advancing the understanding of spearfisher‐fish behavioural interactions and its management implications
Authors: Sbragaglia Valerio , Cecapolli Enrico , Morroni Lorenzo , Januchowski‐Hartley Fraser A. 
Published: October 2024

Abstract

Fish behaviour is intimately linked to fishing catchability. Measurements of fish behaviour may provide quantitative indicators that inform about the impact of fishing pressure and help design effective management strategies. The implications of spearfishing pressure on fish behaviour have mainly been characterized using single quantitative indicators such as flight initiation distance (FID), which provide incomplete views of spearfisher‐fish behavioural interactions.

We used an integrative approach to advance the understanding of spearfisher‐fish behavioural interactions by complementing FID estimates with post‐flight responses (i.e. individual fish behaviour after fleeing), and the decreasing probability to catch a fish at increasing distance from a speargun. We first collected empirical observations of white seabream (Diplodus sargus) FID and post‐flight behaviour in response to an approaching human (spearfisher or snorkeler) inside and outside marine protected areas. We then combined these observations with simulations based on an innovative model representing how catchability changes during a spearfisher‐fish behavioural interaction.

Empirical results showed that the likelihood of a still‐vulnerable post‐flight response after fleeing was inversely related to increasing exposure to spearfishers. This demonstrates that post‐flight response can be used as an indicator of spearfishing pressure. Moreover, post‐flight responses provided complementary information to that provided by FID, suggesting that these two indicators should be integrated for a holistic view of spearfishing‐fish interactions, such as in the model and simulations presented here.

The simulations demonstrated that: (i) accounting for post‐flight responses may increase likelihood of approach by spearfisher within speargun range by up to 20%; and (ii) accounting for post‐flight responses and decreasing probability of capture with increasing distance from speargun drastically reduces estimates of likelihood of capture of white seabream at minimum catch length limit outside marine protected areas compared with using FID as single indicator of catchability.

Synthesis and applications. First, integrating flight initiation distance (FID) measurement with post‐flight responses provides a more realistic indicator to measure fish behavioural reaction to spearfishing pressure. Second, the model presented here showed that spearfishing mortality may drastically decrease when accounting for both prey behaviour (i.e. FID and post‐flight responses) and spearfishers effectiveness (i.e. probability to catch a fish at increasing distance from a speargun). This must be considered to understand population dynamics and potential changes in catchability when spearfishing is managed through temporal restrictions (e.g. seasonal or periodic closures).
Use of rice flour to produce plant‐based yogurt alternatives
Authors: Morris Anita , Boeneke Charles , Prinyawiwatkul Witoon , King Joan M. 
Published: October 2024

AbstractPlant‐based yogurt alternatives (YAs) are in demand due to the societal prevalence of milk sensitivities and allergies and some consumers abstaining from animal‐derived products. Producing rice flour YAs has considerable potential because rice flour is hypoallergenic, more economical compared to plant milks, and there are no commercial rice‐based YAs. A new higher protein variety of rice was developed, Frontière, which is sold as both brown and white rice. Therefore, the overall goals of this study were (1) to compare physicochemical properties of YAs from Frontière brown (Frontière brown rice flour [FBRF]) and white (Frontière white rice flour [FWRF]) high‐protein rice flours to regular protein level rice flours and (2) to evaluate the sensory quality of Frontière YAs compared to commercial plant‐based oat yogurt. Rice flours were fermented with Streptococcus thermophilus, Lactobacillus delbrueckii subsp. bulgaricus, and Lacticaseibacillus rhamnosus (a probiotic) to produce FBRF‐ and FWRF‐YAs. A consumer study was conducted to compare FBRF‐ and FWRF‐YAs to a commercially available oat‐based YA. Consumers rated the YAs using 9‐point hedonic and just‐about‐right (JAR) scales. Protein, fat, and ash levels were greater, whereas starch levels and peak viscosities were lower for BRFs than for WRFs. The use of BRF resulted in longer fermentation times but higher bacteria counts for YAs. FWRF‐YA was preferred in terms of overall flavor and liking, sweetness, and tartness. Purchase intent (PI) for FWRF‐YA increased 2.6 times after providing a health claim. This research showed that rice flour can be used to produce YAs with probiotic counts above the minimum recommended, which provides added health benefits for consumers.Practical ApplicationThis research provides a possible new use of Frontière high‐protein rice flour to produce plant‐based yogurts. This will help the rice industry by adding value, and those who are vegan, allergic to casein, or lactose‐intolerant will have another option for a plant‐based yogurt. Moreover, the greater levels of probiotic bacteria found in the brown rice flour YAs can potentially provide greater health benefits, making brown rice flour a better choice for making rice‐based YAs.
Linking intraspecies variability of Salmonella enterica isolates under acidic conditions to genotype
Authors: Godínez‐Oviedo Angélica , Arvizu‐Medrano Sofia M. , Bowman John P. , Tamplin Mark L. , Garcés‐Vega Francisco J. , Cabrera‐Diaz Elisa , Gómez‐Baltazar Adrián , Hernández‐Iturriaga Montserrat 
Published: October 2024

AbstractThere is a lack of information about Salmonella enterica strains under acidic conditions and their association with their genome. This study characterized intraspecies variability in the growth of 167 S. enterica isolates under two acid conditions (pH 4 and 5) and linked to the whole genome sequencing (WGS) data. A total of 1002 curves for each condition were obtained using turbidimetry measurements, and Baranyi and Roberts model was used to estimate the maximum rate of change (rcmax; OD600 nm h−1). Strains were categorized into slow, intermediate, and fast; and associations with their WGS data were performed. Huge variability in was observed at both conditions (pH 5 = 0.016–0.066 OD600nm h−1 and pH 4 = 0.003–0.028 OD600nm h−1). The majority of isolates was classified as intermediate (59.5% at pH 5 and 46.1% at pH 4). Strains classified as fast had a low frequency of allABCD genes at both pHs, and any of them having the presence of pefABCD, spvBCR, aadA2, dfrA12, and gyrA_D87G genes were linked to virulence or antimicrobial resistance. This study suggests that strains with fast capacity for growth under acidic conditions could have a fitness cost in their virulence or resistance potential.Practical ApplicationData presented in this study could be used to select representative strains to evaluate the exposure assessment in different food items, mainly the growth and survival in acidic foods.
Study on the differentiation of sensory quality of mainstream Jiang‐flavor baijiu in the Chinese market based on Pivot Profile
Authors: Yang Yubo , Niu Junjie , Shi Bolin , Yang Fan , Cao Nian , Wang Houyin , Xiong Xiaolin , Zhao Lei , Xu Yang , Zhong Kui , Zhang Yao , Gao Haiyan , Wang Li , Yun Zhenyu 
Published: October 2024

AbstractJiang‐flavor baijiu (JFB) is a prominent type of Chinese baijiu, known for its unique flavor attributes, sensory experience, and high tasting value. Previous research has mainly focused on the detection and identification of its flavor substances, but in‐depth studies on the precise sensory description and differentiation of its flavor qualities are still lacking. In this study, a rapid sensory analysis method, Pivot Profile (PP), was applied to 30 mainstream JFBs in the Chinese market, generating 91 sensory attributes with independent definitions, from which 29 main sensory attributes were established that were easy to perceive and descriptive, as well as convenient for transmitting their sensory qualities and distinguishing differences in price and production region, including color (one descriptor), aroma (21 descriptors), taste, and mouthfeel (seven descriptors). The nine key sensory attributes that distinguish JFB quality are as follows: Jiang, Grain, Chen, Qu, Rancid, Acid, Sweet, Fullness, and Harmony. It was found that price was positively correlated with sensory quality, with greater variation in the quality of samples within the medium price range (RMB 500–1000). All samples from MTCQ1 (the core production area of Maotai Town) performed better in sensory quality. In addition, salted vegetable showed a high degree of regional characteristics, concentrated in most of the production regions of Guizhou Province. Aroma attributes were more suitable than taste and mouthfeel as sensory indicators for distinguishing production regions. This study has opened the direction of systematic construction of sensory description of JFB and provided a successful case for the evaluation of Chinese baijiu using novel sensory analysis techniques.
Unlocking the secrets of Neapolitan pizza: A concise review of wood‐fired, electric, and gas pizza ovens
Authors: Falciano Aniello , Masi Paolo , Moresi Mauro 
Published: October 2024

AbstractThis review explores the Neapolitan pizza baking process in a traditional wood‐fired oven, employing visual color analysis and IR thermal scanning to detail heat exchange mechanisms. During cooking, the oven floor temperature in the pizza area decreased proportionally to the pizza's mass, whereas the free area maintained a constant temperature of 439 ± 3°C. An IR thermal camera indicated that the oven dome temperature reached approximately 480°C with a weak flame and 500°C with a strong flame. The pizza's bottom achieved a maximum temperature of 100 ± 9°C, facilitated by the Pizzaiolo's skill in lifting and rotating the pizza for uniform cooking. Top temperatures varied: up to 180°C for white pizza and 84°C and 67°C for tomato and Margherita pizzas, respectively. IRIS electronic eye analysis revealed more browning and blackening on the pizza's top compared to its bottom, with peaks of about 26% and 8% for white pizza, respectively. Rapid baking is pivotal in Neapolitan pizza‐making, necessitating precise heat and mass transfer management to influence sensory attributes. European Commission Regulation No. 97/2010 mandates wood‐fired ovens for true Neapolitan pizza, but environmental concerns prompted the Associazione Verace Pizza Napoletana to certify gas or electric ovens when wood‐fired ovens are impractical. Operating costs vary: liquefied petroleum gas ovens are the costliest, with costs ranging from €5.38 to €6.19/h, whereas natural gas and electric ovens have operating costs between €2.70 and €4.10/h. At €0.15/kg, firewood is the most economical, supporting traditionalist views. However, natural gas and electric ovens present competitive costs under stringent antipollution laws, making them viable alternatives.
Haematococcus pluvialis meets gellan gum: Rheological and thermal exploration of a new resource food and biomedical gel matrix
Authors: Zhang Guangming , Cheng Ping , Wang Zhengping , Han Jun , Fan Zhiping 
Published: October 2024

AbstractThe increasing interest in hydrogel matrices and their diverse applications has fueled extensive research. However, single‐component gels have a limited adjustable performance range, and multi‐component gels raise concerns about biological safety, hindering their widespread use. This study focuses on harnessing high‐speed shearing and ultrasound‐assisted methods to incorporate active natural Haematococcus pluvialis (HP), creating novel composite hydrogels in conjunction with biological macromolecule gellan gum, and eliminating the need for structural modifications or chemical crosslinking. Rich astaxanthin, proteins, polysaccharides, and other components in HP can fill and promote the formation of a unified functional network. The study aims to explore the potential of HP as a rheology regulator and investigate its impact on the rheological properties of the gels. Various rheological models, including Power‐Law, Herschel–Bulkley, and Arrhenius, were employed for comparative analysis. This pioneering report on gellan/HP hydrogels holds significant importance as they exhibit optimized elasticity, thermal stability, enhanced injectability, and self‐recovery, making them suitable for a wide range of applications in specialized medical food and biomedicine.
Artificial intelligence‐based prediction of pathogen emergence and evolution in the world of synthetic biology
Authors: Danchin Antoine 
Published: October 2024

AbstractThe emergence of new techniques in both microbial biotechnology and artificial intelligence (AI) is opening up a completely new field for monitoring and sometimes even controlling the evolution of pathogens. However, the now famous generative AI extracts and reorganizes prior knowledge from large datasets, making it poorly suited to making predictions in an unreliable future. In contrast, an unfamiliar perspective can help us identify key issues related to the emergence of new technologies, such as those arising from synthetic biology, whilst revisiting old views of AI or including generative AI as a generator of abduction as a resource. This could enable us to identify dangerous situations that are bound to emerge in the not‐too‐distant future, and prepare ourselves to anticipate when and where they will occur. Here, we emphasize the fact that amongst the many causes of pathogen outbreaks, often driven by the explosion of the human population, laboratory accidents are a major cause of epidemics. This review, limited to animal pathogens, concludes with a discussion of potential epidemic origins based on unusual organisms or associations of organisms that have rarely been highlighted or studied.
Engineering bacterial biocatalysts for the degradation of phthalic acid esters
Authors: Durante‐Rodríguez Gonzalo , de Francisco‐Polanco Sofía , Fernández‐Arévalo Unai , Díaz Eduardo 
Published: October 2024

AbstractPhthalic acid esters (PAEs) are synthetic diesters derived from o‐phthalic acid, commonly used as plasticizers. These compounds pose significant environmental and health risks due to their ability to leach into the environment and act as endocrine disruptors, carcinogens, and mutagens. Consequently, PAEs are now considered major emerging contaminants and priority pollutants. Microbial degradation, primarily by bacteria and fungi, offers a promising method for PAEs bioremediation. This article highlights the current state of microbial PAEs degradation, focusing on the major bottlenecks and associated challenges. These include the identification of novel and more efficient PAE hydrolases to address the complexity of PAE mixtures in the environment, understanding PAEs uptake mechanisms, characterizing novel o‐phthalate degradation pathways, and studying the regulatory network that controls the expression of PAE degradation genes. Future research directions include mitigating the impact of PAEs on health and ecosystems, developing biosensors for monitoring and measuring bioavailable PAEs concentrations, and valorizing these residues into other products of industrial interest, among others.
Comparing Glucagon‐like peptide‐1 receptor agonists versus metformin in drug‐naive patients: A nationwide cohort study
Authors: Sørensen Kathrine Kold , Gerds Thomas Alexander , Køber Lars , Loldrup Fosbøl Emil , Poulsen Henrik Enghusen , Møller Amalie Lykkemark , Andersen Mikkel Porsborg , Pedersen‐Bjergaard Ulrik , Torp‐Pedersen Christian , Zareini Bochra 
Published: October 2024

AbstractBackgroundGlucagon‐like peptide‐1 receptor agonists (GLP‐1 RA) are increasingly being prescribed in drug‐naive patients. We aimed to contrast add‐on therapy, adherence, and changes in biomarkers, 1 year after treatment initiation with GLP‐1 RA or metformin.MethodsUsing Danish nationwide registers, we included incident GLP‐1 RA or metformin users from 2018 to 2021 with glycated hemoglobin (HbA1c) ≥ 42 mmol/mol. GLP‐1 RA initiators were matched to metformin initiators in a ratio of 1:1 to assess outcomes in prediabetes and diabetes. Main outcomes analyzed were 1‐year risk of add‐on glucose‐lowering medication and 1‐year risk of nonadherence. One‐year risks were estimated with multiple logistic regression and standardized. Multiple linear regression was used to estimate the average differences in biomarker changes.ResultsIn total, 1778 individuals initiating GLP‐1 RA and metformin were included. After standardizing for various factors, GLP‐1 RA compared with metformin was associated with reduced 1‐year risk of add‐on glucose‐lowering treatment in patients with prediabetes (1‐year risk ratio [RR]: 0.27, 95% confidence interval [CI]: 0.10–0.44) and diabetes (RR: 0.67, 95% CI: 0.37–0.98). GLP‐1 RA was associated with higher 1‐year risk of nonadherence among patients with prediabetes (RR: 1.60, 95% CI: 1.45–1.75), but no difference in patients with diabetes (RR: 0.88, 95% CI: 0.70–1.06). Compared to metformin, GLP‐1 RA was associated with greater HbA1c reduction (prediabetes: −2.59 mmol/mol 95% CI: −3.10 to −2.09, diabetes: −3.79 mmol/mol, 95% CI: −5.28 to −2.30).ConclusionsGLP‐1 RA was associated with a reduced risk of additional glucose‐lowering medication, achieving better glycated hemoglobin control overall. However, among patients with prediabetes, metformin was associated with better adherence.image
Feeling overlooked: A rural–urban divide in recognition
Authors: Hyland Marie , Mascherini Massimiliano , Lamont Michèle 
Published: October 2024

AbstractThe farmers' protests sweeping across Europe during the early month of 2024 have highlighted the discontent felt by many residing in rural areas. Protests have been motivated by increasing input costs, falling prices of agricultural produce and more stringent regulations. In this paper, we go beyond the economic rationale for the protests and ask what broader sociological factors could be driving rural discontent. To this aim, we investigate political ‘recognition gaps’ between rural residents and their urban counterparts – that is, the differences in the degree to which people feel respected and recognised by their governments. Using data collected in the spring of 2022 across the 27 Member States of the European Union, we document that a sizeable proportion of the sample perceive a lack of fair treatment and respect from their governments. Notably, these gaps in perceived respect are significantly larger in rural compared to urban areas. The differences in perceived recognition between rural and urban areas hold even after controlling for a wide range of sociodemographic characteristics, showing that it is not just differences in the observable characteristics between rural and urban residents that are driving these different levels of perceived recognition.
New insights from old data: the complex migration and breeding patterns of the bogong moth, Agrotis infusa (Boisduval) (Lepidoptera: Noctuidae), in eastern Australia
Authors: McDonald Garrick , Maino James L. , Smith A. Mark , Gregg Peter C. , Ridland Peter M. 
Published: October 2024

AbstractThe bogong moth, Agrotis infusa, an endemic noctuid moth of Australia, is known for its extensive long‐distance movement and summer aestivation in the Australian Alps. Recent studies have focused on moth activity in the Alps, but there are limited data for other regions. This study aims to build on the current understanding of bogong moth movement and breeding patterns using unpublished historical data across eastern Australia. We analysed historical data from moth traps in Victoria, New South Wales (NSW) and South Australia (SA) from the 1960s to early 1990s. The study employed the HYSPLIT model for trajectory analysis of moth flight paths and DARABUG2 for phenological modelling. We examined moth catches across different seasons to infer movement patterns, breeding sources and over‐summering activity. Our findings question several long‐standing assumptions about the spatial ecology of the bogong moth. The trajectory analysis suggests that many aspects of A. infusa movement can be explained via dynamic migration, without fully relying on inherent navigation abilities. Important breeding areas may be beyond the self‐mulching clays of NSW and southern Queensland and include far western NSW, south and central SA and southern Victoria. Substantial moth activity during summer in many traps suggests alternative over‐summering strategies including local breeding or even aestivation in areas other than the Alps. Furthermore, the autumn and winter data imply return migrations from diverse source areas and potential local breeding, expanding the understanding of the moth's life cycle beyond a univoltine pattern. In conclusion, the bogong moth appears to exhibit a more complex and adaptable migration and breeding strategy than previously understood, utilising a range of habitats across eastern Australia for breeding and possibly aestivation. This underscores the need for a revised understanding of bogong moth ecology, which is crucial for its conservation and management, especially considering its recent classification as ‘Endangered’ on the IUCN Red List.