bluuebunny/crossref_metadata_2025_split huggingface dataset:
Editorial
Authors: Carvalho Mauricio 
Published: May 2016

Inicia-se com este número o ano 3 da Revista Médica da UFPR (RMU). A missão da RMU, como política editorial, baseia-se na promoção e disseminação do conhecimento médico. Ela é voltada a todos com interesse em ciências da saúde, principalmente a acadêmicos de medicina, médicos, professores e outros profissionais da saúde. É claro que todo autor, ao enviar seu artigo para publicação, busca divulgação, reconhecimento e visibilidade de seu estudo. Para aumentar a visibilidade da RMU, nosso objetivo é buscar o mérito científico, aprimorar os critérios de aceitação e manter a periodicidade. Com isso, podemos nos candidatar a indexação nas diversas bases (Index Medicus, Lilacs, SciELO, etc.) e a avaliação pelo sistema Qualis de periódicos científicos. Sem sombra de dúvida, um trabalho para algumas gerações. Mas, toda grande jornada começa com um primeiro passo. Guimarães Rosa já dizia em seu clássico Grande Sertão: Veredas, que a vida pede coragem. Somos uma revista registrada, vamos em busca das indexações.Realço nesta edição o trabalho de pesquisadores da Pontifícia Católica do Paraná (PUCPR) que avaliaram uma coorte de 983 portadores de diabetes mellitus tipo 2, atendidos nas unidade de saúde pública de Curitiba. Os autores quantificaram o impacto desta afecção na qualidade de vida destes pacientes. Os resultados demonstraram forte impacto nos aspectos social, físico e emocional, principalmente naqueles com mais de 10 anos de doença e em uso de insulina.Um relato de caso também merece destaque. Trata-se da descrição de provável síndrome de Guillain-Barré em um paciente de 12 anos de idade. De particular interesse é a relação desta afecção com as arboviroses (Dengue; Chikungunya e Zika) em nosso país. Por este motivo, a Secretaria de Estado da Saúde do Paraná implantou um protocolo de vigilância (http://www.saude.pr.gov.br/arquivos/File/SESA_PR_Protoc_Vigil_Sind_Neuro_14_03_2016.pdf, acessado em 26.03.2016) de casos de Síndrome de Guillain-Barré e outras doenças neurológicas agudas graves pós-infecciosas. De acordo com este protocolo, o caso aqui relatado seria considerado como suspeito.Boa leitura,
Multiplexed Biosensors for Mycotoxins
Authors: Maragos Chris M 
Published: May 2016

Abstract
Significant progress has been made in the development of biosensors that can be used to detect low-MW toxins produced by fungi (mycotoxins). The number of formats that have been investigated is impressive and is an indication of the importance attached to finding easy-to-use, accurate, and rapid methods for detecting these toxins in commodities and foods. This review explores the details of multiplexed biosensors based on many formats, including multiplexed immunoassays, suspension arrays, membrane-based devices (flow-through and immunochromatographic), and planar microarrays. Each assay format has its own strengths and areas that need improvement. Certain formats, such as multiplexed immunochromatographic devices, are well developed and relatively easy to use, and in some cases, commercial products are being sold. Others, such as the suspension arrays and microarrays, are laboratory-based assays that, although more complicated, are also more amenable to a larger scale of multiplexing. The diversity of such efforts and the multitude of formats under investigation suggest that multiple solutions will be found to satisfy the need for multiplexed toxin detection.
Motion of the MMS spacecraft relative to the magnetic reconnection structure observed on 16 October 2015 at 1307 UT
Authors: Denton R. E. , Sonnerup B. U. Ö. , Hasegawa H. , Phan T. D. , Russell C. T. , Strangeway R. J. , Giles B. L. , Gershman D. , Torbert R. B. 
Published: May 2016

AbstractWe analyze a magnetopause crossing by the Magnetospheric Multiscale (MMS) spacecraft at 1307 UT on 16 October 2016 that showed features of electron‐scale reconnection. For this event, we find orthonormal LMN coordinates from the magnetic field, with N and L varying respectively along the maximum gradient and maximum variance directions. We find the motion along N from the Spatio‐Temporal Difference analysis and motion along L from measured particle velocities. We locate the position of the magnetic X point, finding that MMS‐4 passed within about 1.4 km from the X point and that MMS‐3 and MMS‐2 passed within about 1.7 km and 2.4 km, respectively, from the position of maximum out of plane current.
Compact resonator on leather for nonradiative inductive power transfer and far‐field data links
Authors: Monti G. , Corchia L. , De Benedetto E. , Tarricone L. 
Published: May 2016

AbstractIn this paper, a wearable resonator suitable to be used for both power and data transmission is presented. The basic element is a complementary split ring resonator that has been optimized to operate both as a dipole‐like antenna at 2.45 GHz and as the receiver of a resonant energy link operating at 915 MHz when coupled with an identical external resonator connected to a power source. Experimental data referring to a prototype fabricated by using a conductive adhesive fabric on a leather substrate are reported and discussed. With regard to the wireless resonant energy link (WREL), it is demonstrated that at 915 MHz, the RF‐to‐RF power transfer efficiency of the link is approximately 78.1%. As for the performance obtained when the resonator is used as an antenna, a gain of approximately −0.43 dB was obtained. Additionally, the performance of the proposed link when connected to a Power Management Unit (PMU) that converts the radio frequency (RF) energy received by the wearable resonator into DC energy that can be directly used for recharging a thin‐film battery was also investigated. Experimental tests were performed in order to evaluate both the total efficiency of the wireless charger (i.e., the WREL link connected to the PMU) and the time necessary to recharge a THINERGY MEC201 battery. The obtained results demonstrate the feasibility of using the proposed WREL for implementing a battery charger; in particular, by providing an input power higher than 8 dBm, the time necessary to recharge the considered thin‐film battery is shorter than 38 min.
Large‐Scale Synthesis of Highly Luminescent Perovskite‐Related CsPb2Br5 Nanoplatelets and Their Fast Anion Exchange
Authors: Wang Kun‐Hua , Wu Liang , Li Lei , Yao Hong‐Bin , Qian Hai‐Sheng , Yu Shu‐Hong 
Published: May 2016

AbstractAll‐inorganic cesium lead‐halide perovskite nanocrystals have emerged as attractive optoelectronic nanomaterials owing to their stabilities and highly efficient photoluminescence. Herein we report a new type of highly luminescent perovskite‐related CsPb2Br5 nanoplatelets synthesized by a facile precipitation reaction. The layered crystal structure of CsPb2Br5 promoted an anisotropic two‐dimensional (2D) crystal growth during the precipitation process, thus enabling the large‐scale synthesis of CsPb2Br5 nanoplatelets. Fast anion exchange has also been demonstrated in as‐synthesized CsPb2Br5 nanoplatelets to extend their photoluminescence spectra to the entire visible spectral region. The large‐scale synthesis and optical tunability of CsPb2Br5 nanoplatelets will be advantageous in future applications of optoelectronic devices.
Genome‐scale RNA interference screen identifies antizyme 1 (OAZ1) as a target for improvement of recombinant protein production in mammalian cells
Authors: Xiao Su , Chen Yu Chi , Buehler Eugen , Mandal Swati , Mandal Ajeet , Betenbaugh Michael , Park Myung Hee , Martin Scott , Shiloach Joseph 
Published: May 2016

ABSTRACTFor the purpose of improving recombinant protein production from mammalian cells, an unbiased, high‐throughput whole‐genome RNA interference screen was conducted using human embryonic kidney 293 (HEK 293) cells expressing firefly luciferase. A 21,585 human genes were individually silenced with three different siRNAs for each gene. The screen identified 56 genes that led to the greatest improvement in luciferase expression. These genes were found to be included in several pathways involved in spliceosome formation and mRNA processing, transcription, metabolic processes, transport, and protein folding. The 10 genes that most enhanced protein expression when downregulated, were further confirmed by measuring the effect of their silencing on the expression of three additional recombinant proteins. Among the confirmed genes, OAZ1—the gene encoding the ornithine decarboxylase antizyme1—was selected for detailed investigation, since its silencing improved the reporter protein production without affecting cell viability. Silencing OAZ1 caused an increase of the ornithine decarboxylase enzyme and the cellular levels of putrescine and spermidine; an indication that increased cellular polyamines enhances luciferase expression without affecting its transcription. The study shows that OAZ1 is a novel target for improving expression of recombinant proteins. The genome‐scale screening performed in this work can establish the foundation for targeted design of an efficient mammalian cell platform for various biotechnological applications. Biotechnol. Bioeng. 2016;113: 2403–2415. © 2016 Wiley Periodicals, Inc.
Preliminary Report of Clinical Outcomes After Single Crossover Bioresorbable Scaffold Implantation Without Routine Side Branch Strut Dilation
Authors: Tanaka Akihito , Jabbour Richard J. , Kawamoto Hiroyoshi , Mangieri Antonio , Pagnesi Matteo , Montalto Claudio , Chieffo Alaide , Carlino Mauro , Montorfano Matteo , Latib Azeem , Colombo Antonio 
Published: May 2016

ObjectivesThe objective of this study was to investigate clinical outcomes following single crossover bioresorbable scaffold (BRS) implantation without routine side branch (SB) strut dilation.BackgroundIt is unknown whether SB strut dilation is routinely required after single crossover BRS implantation if there is no compromise of the jailed SB.MethodsAmong 187 bifurcation lesions treated with Absorb BRS, 115 lesions (101 patients) were treated with single crossover BRS implantation. Strut dilation toward SB was considered only when SB was compromised (SB TIMI flow < 3 or SB ostium > 75%) after main branch (MB) BRS implantation. Clinical outcomes including cardiac death, follow‐up myocardial infarction (MI), target lesion revascularization (TLR), target vessel revascularization (TVR), and definite scaffold thrombosis (ST) were investigated.ResultsThe majority of target lesions were in the left anterior descending artery (73.0%) and the rate of true bifurcation lesions was 42.6%. SB strut dilation was performed in only 20% of lesions (n = 23), and intravascular imaging was used in most cases (90.4%). The rates of TLR per lesion at 1‐year was 3.1% in MB, and 0% in SB. In all patients, the cumulative rate of cardiac death was 1.1% at 1‐year, follow‐up MI 2.2%, TVR 3.5%, and definite ST 1.0%.ConclusionClinical outcomes were acceptable in bifurcation lesions treated with single crossover BRS implantation without routine SB strut dilation. © 2016 Wiley Periodicals, Inc.
Heterogeneous Hydrogenation of Esters under Mild Conditions using Solid‐Supported Phosphorus–Ruthenium Catalysts
Authors: Heutz Frank J. L. , Erken Christina , Aguila Mae Joanne B. , Lefort Laurent , Kamer Paul C. J. 
Published: May 2016

AbstractThe catalytic reduction of esters by using H2 is a sustainable alternative to the use of classic stoichiometric reagents. Nowadays, a wide range of highly efficient homogeneous catalysts are known, but these suffer from poor catalyst recoverability. Therefore, most industrial applications are based on heterogeneous catalysts, but these processes are generally operated under harsh conditions (>200 °C, >10.0 MPa). Herein, we describe the first catalytic system that combines the activity of a homogeneous catalyst with the recoverability of a heterogeneous catalyst. The presented system is capable of hydrogenating esters under very mild conditions (25 °C, 5.0 MPa) and can easily be recovered. The catalyst is based on phosphorus ligands covalently attached to a polymeric support and is readily obtained by a facile solid‐phase synthetic protocol in high yields with minimal workup.
Ensemble Correntropy‐Based Mooney Viscosity Prediction Model for an Industrial Rubber Mixing Process
Authors: Liu Yi , Fan Yu , Zhou Lichun , Jin Fujiang , Gao Zengliang 
Published: May 2016

AbstractThe development of accurate soft sensors for online prediction of Mooney viscosities in industrial rubber mixing processes is a difficult task because the modeling dataset often contains various outliers. A correntropy kernel learning (CKL) method for robust soft sensor modeling of nonlinear industrial processes with outlier samples is proposed. Simultaneously, the candidate outliers can be identified once the CKL‐based soft sensor model is built. An index for describing the uncertainty of the CKL model is designed. Furthermore, to obtain more robust and accurate predictions, an ensemble CKL (ECKL) method is formulated by introducing the simple bagging strategy. Consequently, by detecting the outliers in a sequential manner, the database becomes more reliable for long‐term use. The application results for the industrial rubber mixing process demonstrate the superiority of ECKL in terms of better prediction performance.
Kinetics of Isophorone Synthesis via Self‐Condensation of Supercritical Acetone
Authors: Mei Jun , Chen Zhirong , Yuan Shenfeng , Mao Jianyong , Li Haoran , Yin Hong 
Published: May 2016

AbstractA kinetic study on isophorone synthesis via self‐condensation of supercritical acetone catalyzed by aqueous KOH in a tubular flow reactor was conducted. The intention was to improve the isophorone selectivity, with the main approach to reduce the by‐products higher‐boiling than isophorone. A higher isophorone selectivity was obtained with increased reaction temperature. The structures of main products were determined by gas chromatography‐mass spectrometry and nuclear magnetic resonance analysis. The key reaction pathways and a corresponding kinetic model were proposed. The fitted apparent activation energies indicated the reason of isophorone selectivity improvement in that high temperature favors reversion of reversible by‐products.
ChemInform Abstract: Isomerization of Dihydropentalenes and Reaction with Tetracyanoethylene.
Authors: PAULI A. , KOLSHORN H. , MEIER H. 
Published: May 2016

AbstractThe six isomeric dihydropentalenes (I)‐(VI) are connected by various H‐shifts, which are investigated in gas phase pyrolyses at 700‐1200 °C. Thermodynamic control leads irreversibly from the equilibria between (I)‐(VI) to styrene (VIII) via 1‐vinylfulvene (VII).
ChemInform Abstract: Reactions with Aziridines. Part 40. Nucleophilic Ring Opening of 2,2‐Dimethylaziridines by the Anions of Fluorene and Carbazole. Control of Regioselectivity by the Kind of Aziridine Activation.
Authors: ASSITHIANAKIS P. , ONISTSCHENKO A. , STAMM H. 
Published: May 2016

AbstractFluorene (Ia) and carbazole (Ib) are converted to the corresponding anions which react with the N‐benzoylaziridines (II), forming the 1,1‐dimethyl‐2‐acrylaminoethyl derivatives (III).
ChemInform Abstract: Stereocontrolled Route to 2,3,5‐Trisubstituted Tetrahydrofurans. Intermediates for the Total Synthesis of Polyether Antibiotics.
Authors: FRAUENRATH H. , RUNSINK J. 
Published: May 2016

AbstractDouble‐bond isomerization of the 4,7‐dihydro‐1,3‐dioxepins (III) gives the corresponding 4,5‐dihydro‐1,3‐dioxepins (IV).
ChemInform Abstract: Reaction of Mesoionic Thiazol‐4‐ones with Azodicarbonyl Dipolarophiles. Cleavage Modes of the Bi‐ and Tricyclic Adducts.
Authors: SHERADSKY T. , ITZHAK N. 
Published: May 2016

AbstractThe reaction of the mesoionic heterocycles (I) with (II) gives the adducts (III) which, on heating in benzene, undergo rearrangement to yield (IV).
ChemInform Abstract: A New Mode of Formation of the Phosphorus‐Phosphorus Bond: Synthesis and Crystal Structure Determination of 1,5‐Dichloro‐2,4‐dimethyl‐2,4‐diaza‐1,5‐diphospha‐1,5‐diphenylpentan‐3‐one and of 1,4‐Dimethyl‐2,3‐Diphenyl‐1,4,3,2‐diazadiphospholidin‐5‐one‐2‐oxide and Its Oxidation with Tetrachloroorthobenzoquinone.
Authors: BETTERMANN G. , SCHMUTZLER R. , POHL S. , THEWALT U. 
Published: May 2016

AbstractThe structure of the title compounds (III) and (V) is established by X‐ray analysis (space groups P1 and P21/n with Z=2 and Z = 8, respectively).
ChemInform Abstract: Preparation and Physical Properties of Trinuclear Oxo‐Centered Manganese Complexes of the General Formulation (Mn3O(O2CR)6L3)0,+ (R: Me or Ph; L: a Neutral Donor Group) and the Crystal Structures of (Mn3O(O2CMe)6(pyr)3)(pyr) and (Mn3O(O2CPh)6(pyr)2(H2O))·0,5 MeCN.
Authors: VINCENT J. B. , CHANG H.‐R. , FOLTING K. , HUFFMAN J. C. , CHRISTOU G. , HENDRICKSON D. N. 
Published: May 2016

AbstractThe reaction of a polymeric Mn(III) acetate, readily obtained from the oxidation of Mn(II) acetate‐tetrahydrate with Bu4NMnO4, with acetic acid or benzoic acid in the presence of an excess of neutral donor ligands leads to the high‐yield formation of the trinuclear oxo‐centered Mn complexes (I).
ChemInform Abstract: Synthesis and Structure of the Iron‐Selenium Cubane Cluster ((η5‐C5H5)4Fe4Se4)3+: The Fourth Member of the ((η5‐C5H5)4Fe4Se4)n Series (n = 0 to 4+).
Authors: OGINO H. , TOBITA H. , YANAGISAWA K. , SHIMOI M. , KABUTO C. 
Published: May 2016

AbstractOn the basis of the redox behavior of (II), prepared in quantitative yield by the reaction of (I) with 3/8 molar equiv. red selenium (II) as shown, the bulk electrolysis of (II) leads to the dication salt (III).
ChemInform Abstract: Electrochemical and Spectroscopic Analyses of the Thermodynamics of the Reversible Dimerization of Cyanine Radical Dications.
Authors: LENHARD J. R. , PARTON R. L. 
Published: May 2016

AbstractThe results of thermodynamic and kinetic characterization of the reversible dimerization of radical dications formed by chemical (ferric chloride in MeOH/H2O) and/or electrochemical oxidation of a range of 15 thia‐ and quinodicarbocyanines (I)‐(VI) are given.
ChemInform Abstract: Hetero Diels‐Alder Reactions in Carbohydrate Chemistry: A New Strategy for Multichiral Arrays Synthesis.
Authors: CHAPLEUR Y. , EUVRARD M.‐N. 
Published: May 2016

AbstractThe dibenzylidene methyl pyranoside (I) is treated with butyllithium and then coupled with the aldehydes (II), yielding the carbinols (III) as a mixture of isomers.
ChemInform Abstract: Luminescence Properties of (Sr,Ca)‐hexaborate:Pb2+, Gd3+.
Authors: TEWS W. , BECKER P. , HERZOG G. , KUENZLER G. + 
Published: May 2016

AbstractUnder Hg‐low‐pressure excitation (Sr,Ca)O·3 B2O3:Pb2+, Gd3+ (prepared by solid state reaction of intimate mixtures of H3BO3, SrCO3, and/or CaCO3, PbCO3, and Gd2O3 at 700 °C) emits in the UV region (λem(Pb)Sr‐hexaborate = 303 nm; λem(Pb)Ca‐hexaborate = 284 nm; λem(Gd) = 311‐313nm).
ChemInform Abstract: Standard Potentials of the (MO2+ 2/MO+ 2) Systems for Uranium and Other Actinides.
Authors: RIGLET CH. , VITORGE P. , GRENTHE I. 
Published: May 2016

AbstractThe formal potentials of the UO22+/UO2+ couple have been determined in NaClO4 media of varying ionic strength and the data are interpreted by the Broensted‐Guggenheim‐Scatchard specific ionic interaction theory (SIT) yielding a standard potential/E ° of +0.089 V vs.
ChemInform Abstract: Improvement of Charge Transfer Kinetics at Transparent SnO2 Counterelectrodes by Means of a Radiolytic Grafting of Metallic Nanoaggregates.
Authors: BRUNEAUX J. , CACHET H. , FROMENT M. , AMBLARD J. , BELLONI J. , MOSTAFAVI M. 
Published: May 2016

AbstractA new radiolytic process has been developed to graft metallic nanoaggregates on SnO2 transparent counter electrodes (tce) in order to improve their electrochemical behavior.
ChemInform Abstract: Synthesis of Lithium Dialuminate by Salt Imbibition.
Authors: POEPPELMEIER K. R. , HWU S.‐J. 
Published: May 2016

AbstractLiAl2(OH)7·2 H2O (I), prepared by reaction of solid lithium hydroxide, polycrystalline bayerite, and water vapor at 20 °C appears to be identical with that prepared by precipitation from supersaturated aluminate solutions or by reaction of lithium salts with freshly precipitated aluminum hydroxide in aqueous solution (TGA, IR, XRD).
ChemInform Abstract: Polyvanadates of Rubidium and Cesium.
Authors: VOLKOV V. L. , ZAKHAROVA G. S. , IVAKIN A. A. , PESINA Z. M. 
Published: May 2016

AbstractSolutions of rubidium and cesium peroxovanadates are prepared from V2O5, H2O2 and RbVO3 or CsVO3.
ChemInform Abstract: β‐Oxido‐Functionalized Organolithium Intermediates from Ketones: A Simple New Access.
Authors: BARLUENGA J. , FERNANDEZ‐SIMON J. L. , CONCELLON J. M. , YUS M. 
Published: May 2016

AbstractThe ketones (I) are coupled with chloromethyllithium (II) and then directly treated with lithium naphthalenide to yield the dilithium intermediates (III) which react with various electrophiles (IV), forming the hydroxy compounds (V).
ChemInform Abstract: Cycloaddition of the Trimethylenemethane‐Palladium Complex to Activated Six‐Membered and Medium‐Size Ring Enones.
Authors: CLEARY D. G. , PAQUETTE L. A. 
Published: May 2016

AbstractThe cyclohexenones (I) react with the acetoxymethylallylsilane (II) in the presence of a Pd(0) catalyst generated in situ to produce the methylenecyclopentanocyclohexanones (III).
ChemInform Abstract: The Photocycloaddition of Acetylacetone with Naphthols and Their Methyl Ethers.
Authors: CHOW Y. L. , BUONO‐CORE G. E. , LIU X.‐Y. , ITOH K. , QIAN P. 
Published: May 2016

AbstractPhotochemical reaction of the naphthols (Ia) and (Va) and their methyl ethers (Ib) and (Vb) with the enol form (II) of acetylacetone only takes place when (II) is excited by irradiation.
ChemInform Abstract: A Mild Neutral Reagent for the Oxidation of Alcohols to Carbonyl Compounds.
Authors: MOISEENKOV A. M. , CHESKIS B. A. , VESELOVSKII A. B. , VESELOVSKII V. V. , ROMANOVICH A. YU. , CHIZHOV O. S. 
Published: May 2016

AbstractTrimethylsilyl chromate, the title reagent, is prepared in situ by heating hexamethylsiloxane and CrO3 to 60 °C. The novel reagent oxidizes primary alcohols as e.g. (I) and secondary alcohols as e.g. (III) under neutral and mild conditions.
ChemInform Abstract: Electron Transfer. Part 87. Autocatalysis in the Reductions of Vanadium(IV) and Molybdenum(VI) with Vitamin B12s (Cob(I)alamin).
Authors: PILLAI G. C. , BOSE R. N. , GOULD E. S. 
Published: May 2016

AbstractVitamin B12s reduces vanadium(IV) and molybdenum(VI) in aqueous solution.
ChemInform Abstract: 2‐(Chloromethyl)‐3,5‐dioxahex‐1‐ene. An Effective Acetonylating Reagent.
Authors: GU X.‐P. , NISHIDA N. , IKEDA I. , OKAHARA M. 
Published: May 2016

AbstractThe reagent (II) mentioned in the title is prepared from the dichloro acetal (I) under solid‐liquid phase‐transfer conditions.
ChemInform Abstract: Reaction of Acetylenic and Vinylic Organolithium Reagents with Triethoxycarbenium Tetrafluoroborate: Preparation of α‐Acetylenic and α‐Ethylenic Triethyl Orthocarboxylates.
Authors: PICOTIN G. , MIGINIAC P. 
Published: May 2016

AbstractThe reaction mentioned in the title yields selectively the triethyl orthocarboxylates (III).
ChemInform Abstract: Hydroformylation of Formaldehyde to give Glycolaldehyde with Halide‐ Promoted Rh4(CO)12.
Authors: MARCHIONNA M. , LONGONI G. 
Published: May 2016

AbstractHydroformylation of paraformaldehyde (I) or 37% aqueous formaldehyde with syngas (II) in the presence of Rh4(CO)12 and bulky onium halides yields glycolaldehyde (III), together with methanol (IV) and methyl formate (V).
ChemInform Abstract: Action of Dinitrogen Tetroxide on the 5‐Hydroxy‐3,5‐dimethyl‐4‐oximido‐2‐isoxazoline System.
Authors: FRUTTERO R. , FERRAROTTI B. , GASCO A. 
Published: May 2016

AbstractThe isoxazoline (I) reacts with dinitrogen tetroxide to form the O‐acetyloxime (II).
ChemInform Abstract: Synthesis and Reactions of Regioisomeric Epoxides of the Tricyclo(4.2.2.02,5)decane Series.
Authors: ZEFIROV N. S. , KIRIN V. N. , YUR'EVA N. M. , KOZ'MIN A. S. 
Published: May 2016

AbstractThe oxidation of the tricyclotriene (I) with peracids or with MoO5·2 HMPA complex yields the exo‐3,4‐epoxide (II), the endo‐7,8‐epoxide (III) and/or the exo‐3,4‐endo‐7,8‐diepoxide (IV) or mixtures of these epoxides.