bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Structure of Silver(I) Solvate and Sodium Diiodoargentate(I) in Acetonitrile Solution.
Authors: NILSSON K. , PERSSON I. 
Published: May 2016

AbstractFrom large‐angle X‐ray scattering data it is concluded that the Ag(I) ion is tetrahedrally solvated by four MeCN molecules whereas the diiodoargentate(I) polymerizes forming chains in concentrated solutions.
ChemInform Abstract: Zinc‐Zinc Chloride Composite Electrodeposited Steel Sheet.
Authors: SUZUKI I. , WADA S. 
Published: May 2016

AbstractColloids of 4 Zn(OH)2·ZnCl2 have been codeposited with metallic zinc on steel under various electrodepositing conditions, in order to accelerate the formation of a stable corrosion product layer in a Cl‐ environment (in natural environment, the corrosion rate of zinc becomes constant after exposure of several months).
ChemInform Abstract: Activity Development of Unsupported and Al2O3 Supported Co‐Mo Catalysts in Thiophene HDS.
Authors: KORANYI T. , DOBROVOLSZKY M. , PAAL Z. 
Published: May 2016

AbstractThe activity of Al2O3 supported and unsupported Co‐Mo catalysts for thiophene hydrodesulfurization has been investigated as a function of Co:Mo ratio, and sulfidation degree.
ChemInform Abstract: Synthesis and Identification of K2H3P3O10·2 H2O.
Authors: SHASHKOVA I. L. , LYUTSKO V. A. , PRODAN E. A. 
Published: May 2016

AbstractThe crystalline phases, which are formed on adding methanol to the system K3H2P3O10‐H5P3O10‐H2O at 0‐5 °C and pH 0.6‐5.4 are investigated.
ChemInform Abstract: Bis(undecatungstogermanate) Lanthanates of Potassium.
Authors: RONG C. , LIU J. , CHEN X. , WANG E. 
Published: May 2016

AbstractThe compounds K13(Ln(GeW11O39)2) (Ln: Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Tm, Yb) have been prepared by addition of a concentrated solution of potassium acetate to an aqueous solution of Ln(NO3)3 and H4GeW12O40 (Ge:Ln = 2:1, 70 °C).
ChemInform Abstract: Gallium Pertechnetate and Its Crystalline Hydrates.
Authors: ZAITSEVA L. L. , VELICHKO A. V. , SOLOMENTSEV A. V. 
Published: May 2016

AbstractThe title compound, Ga(TcO4)3·7 H2O, is prepared for the first time by reacting freshly precipitated Ga(OH)3 with HTcO4 in aqueous solution.
ChemInform Abstract: Deuterium Isotope Effects as a Probe for C‐C Hyperconjugation.
Authors: BERGER S. , DIEHL B. W. K. , KUENZER H. + 
Published: May 2016

AbstractThe deuterium isotope effects on 13C NMR chemical shifts of compounds (I)‐(VIII) bearing a perdeuterated tert. butyl are shown to correlate linearly with π bond orders.
ChemInform Abstract: A Dynamic 1H NMR and ab initio MO Investigation of the Barrier to Pyramidal Inversion in Azetidine.
Authors: DUTLER R. , RAUK A. , SORENSEN T. S. 
Published: May 2016

AbstractCoalescence of the α‐ and β‐proton signals is observed with ΔG‡ (154 K) = 30 kJ/mol.
ChemInform Abstract: The Triphenylphosphine Cone Angle and Restricted Rotation About the Chromium‐Phosphorus Bond in Dicarbonyl(η6‐hexa‐alkylbenzene)(triphenylphosphine)chromium(0) Complexes. Crystal and Molecular Structure of Dicarbonyl(η6‐hexa‐n‐propylbenzene)(triphenylphosphine)chromium(0).
Authors: HUNTER G. , WEAKLEY T. J. R. , WEISSENSTEINER W. 
Published: May 2016

AbstractThe variable‐temp.
ChemInform Abstract: 7‐Arylbicyclo(4.2.0)oct‐1‐enes. Synthesis by (2 + 2) Cycloadditions of 1,2‐Cyclohexadiene and 1‐Methyl‐1,2‐cyclohexadiene and Thermal Equilibration of the exo/endo Isomers.
Authors: CHRISTL M. , SCHRECK M. 
Published: May 2016

AbstractThe stepwise cycloaddition of the diene (V), which is obtained in situ with MeLi from the dibromide (I), to styrene (II) yields a mixture of isomers, the ratio of which depends on the temperature.
ChemInform Abstract: Stereospecific Dicobalt Octacarbonyl Mediated Enyne Cyclization for the Synthesis of the Cytotoxic Sesquiterpene (.+‐.)‐Quadrone.
Authors: MAGNUS P. , PRINCIPE L. M. , SLATER M. J. 
Published: May 2016

AbstractThe enyne (I) cyclizes stereospecifically in the presence of dicobalt octacarbonyl to form the bicyclic enone (II).
ChemInform Abstract: CHO vs. CH=CH2 Competition in Radical Cyclizations: Is the 5‐Hexenyl Radical Really Supreme?
Authors: TSANG R. , DICKSON J. K. JUN. , PAK H. , WALTON R. , FRASER‐REID B. 
Published: May 2016

AbstractThe predominant formation of (III) from the radical derived from (I) indicates the higher reactivity of the aldehydo group compared with the alkene, irrespective of its cis or trans relationship to the radical‐bearing moiety or the rigidity of the backbones as is shown by the exclusive formation of (VI) from (V).
ChemInform Abstract: Mechanism‐Based Inactivation of the Flavoenzyme Cyclohexanone Oxygenase During Oxygenation of Cyclic Thiol Ester Substrates.
Authors: LATHAM J. A. , WALSH C. 
Published: May 2016

AbstractIn contrast to cyclohexylsulfide, which forms the thiane‐S‐oxide in the presence of FAD‐linked cyclohexanone oxygenase (E‐FAD), no sulfoxidation is observed to compete with the Baeyer‐Villiger oxidation.
ChemInform Abstract: Competing Nucleophilic Displacement and Radical Chain Reduction in Reactions of Transition‐Metal Hydride Anions with Alkyl Bromides.
Authors: ASH C. E. , HURD P. W. , DARENSBOURG M. Y. , NEWCOMB M. 
Published: May 2016

AbstractSince the reduction of (V) is sluggish toward SN2 displacement, the product ratio is directly dependent on the anionic metal hydride concentration.
ChemInform Abstract: Selective Palladium‐Catalyzed Substitution of 1,1‐Dichloroethylene.
Authors: RATOVELOMANANA V. , HAMMOUD A. , LINSTRUMELLE G. 
Published: May 2016

Abstract1,1‐Dichloroethylene (I) reacts with the acetylenes (II) in the presence of a Pd(0) catalyst to give the enynes (III).
ChemInform Abstract: Unsymmetrical Alkenes by Carbene Coupling from Diazirine Decomposition in the Presence of Diazo Compounds.
Authors: DOYLE M. P. , DEVIA A. H. , BASSETT K. E. , TERPSTRA J. W. , MAHAPATRO S. N. 
Published: May 2016

AbstractHeating the thermally unstable halophenyldiazirines (I) in the presence of the diazo compounds (II) yields the olefins (III).
ChemInform Abstract: Preparation of Chiral Allylic Alcohols Using Rhizopus nigricans. Use of the Harada‐Nakanishi Exciton Chirality Method for Verifying Configurational Assignments of Allylic Alcohols.
Authors: ITO S. , KASAI M. , ZIFFER H. , SILVERTON J. V. 
Published: May 2016

AbstractEnantioselective hydrolysis of racemic acetates such as (I), (III), (V), (XI) the preparation of which is described yields (R)‐alcohols such as (II), (IV), (VI), or (XII).
ChemInform Abstract: Synthesis and Hydroboration/Oxidation of Tricyclo(5.2.1.04,10)dec‐8‐ene‐2,5‐dione (Bis‐acetal): New Synthetic Entry to Tricyclo(5.2.1.04,10)decane‐2,5,8‐trione.
Authors: CARCELLER E. , GARCIA M. L. , SERRATOSA F. , FONT‐ALTABA M. , SOLANS X. 
Published: May 2016

AbstractThe lactone (I) is transformed to the bis‐acetal (VIII) via the diketones (IV).
ChemInform Abstract: 3‐Chloro‐2‐((diethoxyphosphoryl)oxy)‐1‐propene: A New Reagent for a “One‐Pot” Cyclopentenone Annelation. Syntheses of Desoxyallethrolone, cis‐Jasmone, and Methylenomycin B.
Authors: WELCH S. C. , ASSERCQ J.‐M. , LOH J.‐P. , GLASE S. A. 
Published: May 2016

AbstractReaction of dichloroacetone (I) with triethyl phosphite (II) gives the propene derivative (III).
ChemInform Abstract: An Example of Spontaneous Resolution by Sublimation.
Authors: PAQUETTE L. A. , LAU C. J. 
Published: May 2016

AbstractAcid‐catalyzed hydration of the bridged bis(bicyclobutane) (I) yields the anti‐7‐norborneol (II), the enantiomers of which are separated by sublimation under reduced pressure.
ChemInform Abstract: Reactivity of tert‐Butyldimethylsilyl Ethers: A Facile Conversion into Bromides.
Authors: MATTES H. , BENEZRA C. 
Published: May 2016

AbstractThe silyl ether (I) is cleaved with tetrabromomethane (II) and triphenylphosphine (III) in acetone to give the dibromomethylene derivatives (IV) and (V).
ChemInform Abstract: N‐Unsubstituted (Carbamoyloxy)nitrostyrenes: A New Series of Aryl‐β‐nitroalkenes with Fungicidal Properties.
Authors: LATIF N. , ASAAD F. M. , HOSNI H. 
Published: May 2016

AbstractThe title compounds (IV) exhibit fungicidal but no molluscicidal activity.
ChemInform Abstract: Cationic Cyclocodimerization. Part 4. Syntheses and Structures of (3.3)Metacyclophane Derivatives. Cyclization Controlled by an Orbital Interaction and a Steric Constraint.
Authors: NISHIMURA J. , OHBAYASHI A. , HORIUCHI Y. , OKADA Y. , YAMANAKA S. , OKU A. 
Published: May 2016

AbstractAcid‐catalyzed reaction of the bisstyrenes (I) with the styrene derivatives (II) yields the isomeric metacyclophanes (III) ‐ (V), depending on the chain length n of (I).
ChemInform Abstract: Some Transformations and the Structure of 2,5,7‐Trinitro‐4‐cyanofluorenone C14H4N4O7.
Authors: SEMIDETKO O. V. , CHETKINA L. A. , BEL'SKII V. K. , MYSYK D. D. , PEREPICHKA I. F. , ANDRIEVSKII A. M. 
Published: May 2016

AbstractHydrolysis of the title compound (I) leads to the substitution of the 5‐nitro group in the first step, followed by hydratization of the nitrile group, producing the hydroxy amide (III) or the hydroxy acid (IV).
ChemInform Abstract: A Synthesis of Protected Aminoalkyl Epoxides from α‐Amino Acids.
Authors: LULY J. R. , DELLARIA J. F. , PLATTNER J. J. , SODERQUIST J. L. , YI N. 
Published: May 2016

AbstractThe reduction of the N‐protected amino esters (I) produces the amino aldehydes (II) which are converted to the amino alkenes (IV) by Wittig reaction.
ChemInform Abstract: Thermolysis and CoTTP‐Catalyzed Rearrangement of Endoperoxides Derived from 2,3‐Dihydro‐1(2H)azulenone: A New Endoperoxide‐Endoperoxide Rearrangement.
Authors: AKBULUT N. , MENZEK A. , BALCI M. 
Published: May 2016

AbstractThe trienone (I) reacts with singlet oxygen to yield the cyclic peroxides (II) ‐ (IV) and the ketones (V) and (VI).
ChemInform Abstract: Dipolar Cycloaddition Reactions of (Phenylsulfonyl)alkynes and (Phenylsulfonyl)propadiene with C,N‐Diphenylnitrone.
Authors: PARPANI P. , ZECCHI G. 
Published: May 2016

Abstract1,3‐Dipolar cycloaddition reaction of the nitrone (II) with the alkynes (I) yields the acylindoles (IV) via the unstable cycloadducts (III).
ChemInform Abstract: 3‐Aroyl‐1‐aryl‐1H‐(1,2,4)triazolo(3,4‐c)‐1,2,4‐triazoles: Investigation of the Reaction Pathway by X‐Ray Analysis and Molecular Modelling.
Authors: GRAF H. , KLEBE G. 
Published: May 2016

AbstractThe readily accessible hydrazones (I) with electron‐withdrawing substituents in the acetophenone moiety react with aminotriazole (II) to give the monocyclic substitution products (III) which are cyclized to the bicyclic compounds (IV).
ChemInform Abstract: Photochemical Formation of Heteromethylenecyclopropanes. Part 15. Synthesis, Photolysis, and Thermolysis of a 1,4,4‐Trialkyl‐4,5‐dihydro‐5‐methylene‐1H‐1,2,3‐triazole. Highly Diastereoselective Formation of (E)‐2,2‐Dimethyl‐N‐neopentyl‐1‐cyclopropaneimine.
Authors: QUAST H. , MEICHSNER G. 
Published: May 2016

AbstractThe dihydrotriazolone (I) adds smoothly the organolithium compounds (II) or (III) to give the tert. alcohols (IV).
ChemInform Abstract: Cyclic Nitronates from the Diastereoselective Addition of 1‐Trimethylsilyloxycyclohexene to Nitroolefins. Starting Materials for Stereoselective Henry Reactions and 1,3‐Dipolar Cycloadditions.
Authors: BROOK M. A. , SEEBACH D. 
Published: May 2016

AbstractThe Ti‐induced combination of the cyclohexene (I) with the E‐nitroolefins (II) yielding the separable prim. products (III)‐(V) proceeds preferentially with relative topicity ul, opposite to the corresponding reaction of enolates or enamines.
ChemInform Abstract: New 2‐Pyridone Derivatives via 1,3‐Dipolar Cycloadditions of Novel Mesoionic Compounds.
Authors: MOORE D. R. , MATHIAS L. J. 
Published: May 2016

AbstractThermal reaction of the N‐chloroacetyl lactam (I) with dimethyl acetylenedicarboxylate (II) produces the pyridone (III) via ring closure of (I) to form an isomunchnone and subsequent 1,3‐dipolar cycloaddition.
ChemInform Abstract: Regiospecific Functionalization of the Monoterpene Ether 1,3,3‐Trimethyl‐2‐oxabicyclo(2.2.2)octane (1,8‐Cineole). Synthesis of the Useful Bridged γ‐Lactone 1,3‐Dimethyl‐2‐oxabicyclo(2.2.2)octan‐3→5‐olide.
Authors: DE BOGGIATTO M. V. , DE HELUANI C. S. , DE FENIK I. J. S. , CATALAN C. A. N. 
Published: May 2016

AbstractChromyl acetate oxidation of the oxabicyclooctane (I) gives the ketone (II) as the main product, together with the six by‐products (III) ‐ (VIII).
ChemInform Abstract: Identification of the endo,exo Isomer of 6,9‐(PMe2Ph)2‐arachno‐B10H12 by NMR Spectroscopy.
Authors: FONTAINE X. L. R. , KENNEDY J. D. 
Published: May 2016

AbstractReaction of the nido‐borane (I) with the phosphine (II) results in a mixture of the title endo,exo isomer (III) and the exo,exo isomer (IV).
ChemInform Abstract: 1,3‐Bis(2‐benzoylphenyl)‐1,1,3,3‐tetramethyldisiloxane.
Authors: WIESE D. , WANNAGAT U. , THEWALT U. , DEBAERDEMAEKER T. 
Published: May 2016

AbstractThe silylbenzoyl chlorides (IV) are prepared starting from (I) and (II); other routes to (IVa) are described.
ChemInform Abstract: tert‐Butyl Esters of Phosphorous Acid. Synthesis and Thermal Rearrangement.
Authors: GAZIZOV T. KH. , CHUGUNOV YU. V. , PUDOVIK A. N. 
Published: May 2016

AbstractContrary to data in other literature tert‐butyl diethyl phosphite (III), obtained from the enol phosphite (I), is thermally stable up to 170°C. (III) and tri‐tert‐butyl phosphite (VI) are also obtained in the usual way from the phosphorous chlorides (IV) or (V) with an excess of triethylamine.
ChemInform Abstract: Lithium‐Halogen Exchange‐Initiated Cyclization Reactions. Part 3. Intramolecular Conjugate Addition Reactions of Unsaturated Acylphosphoranes.
Authors: COOKE M. P. JUN. , WIDENER R. K. 
Published: May 2016

AbstractTreatment of the iodine‐containing unsaturated acylphosphoranes (I) and (VI) with organolithium causes a lithium‐halogen exchange reaction which is followed by cyclization.
ChemInform Abstract: Reactions of 2‐Halo‐1,3,2‐dioxaphosphorinanes with Hexafluoroacetone.
Authors: HACKLIN H. , ROESCHENTHALER G.‐V. + 
Published: May 2016

AbstractThe chlorodioxaphosphorinane (II) is fluorinated by SbF3 to form the fluorodioxaphosphorinane (I) or brominated by trimethylbromosilane (III), yielding the bromodioxaphosphorinane (IV).
ChemInform Abstract: Reactions of Chromium(III) Complexes of 1,10‐Phenanthroline, 2,2′‐Bipyridyl, and Oxalate with the Pulse Radiolytically Generated Aquated Electron, Zinc(I), and Cadmium(I).
Authors: LAWRANCE G. A. , SANGSTER D. F. 
Published: May 2016

AbstractThe Cr(III) complex ions (I) react rapidly with the aquated electron to form the Cr(II) analogues.
ChemInform Abstract: Bimetallic Systems. Part 19. Chromium(0)‐, Molybdenum(0)‐, or Tungsten(0)‐Iron(0) Carbonyl Complexes Containing One or Two Bridging Ph2PCH2PPh2 Ligands: Crystal Structure of ((OC)3Mo(μ‐Ph2PCH2PPh2)2Fe(CO)3).
Authors: JACOBSEN G. B. , SHAW B. L. , THORNTON‐PETT M. 
Published: May 2016

AbstractTreatment of the mer‐complexes (I) with the Fe carbonyls (II) or (III) leads to the bimetallics (IV).
ChemInform Abstract: Mixed Oxidation State Trinuclear Cobalt Complexes with Bridging Sulfito and Schiff‐Base Ligands. Part 1. Preparation of the Complexes (Co(II)(μ‐SO3)2(μ‐L)2Co(III)2(ROH)2) (L: Schiff Base Anion, R: Alkyl) and Structure Determination of (Co(II)(μ‐SO3)2(.mu±alpha.,α′‐Me2‐salpd)2Co(III)2(nPrOH)2)·2 nPrOH.
Authors: FUKUHARA C. , ASATO E. , SHIMOJI T. , KATSURA K. , MORI M. , MATSUMOTO K. , OOI S. 
Published: May 2016

AbstractFor the preparation of the trinuclear title complexes (I) an alcoholic solution of a monomeric Co(III) complex of the corresponding sym. Schiff base containing additionally the anion of acetylacetone, salicylaldehyde, or α‐hydroxyacetophenone (or a reaction mixture of a Co(II) complex of the Schiff base and o‐hydroxyacetophenone in the case of (Ic)) is exposed to SO2 in a closed system.
ChemInform Abstract: The First Monophosphacyclobutadiencobalt(I) Complex by Codimerization of tert‐Butylphosphaacetylene with Bis(trimethylsilyl)acetylene.
Authors: BINGER P. , MILCZAREK R. , MYNOTT R. 
Published: May 2016

AbstractThe title compound (IV) is synthesized from the starting materials (I) and (II) in the presence of equimolar amounts of the η5‐cyclopentadiene diethene cobalt complex (III) as outlined in the reaction scheme.
ChemInform Abstract: Synthetic and Mechanistic Features of Alcohol Elimination Between Gold Alkoxides and Rhenium Polyhydrides. Metal Polyhedron Reconstruction Upon Protonation.
Authors: SUTHERLAND B. R. , FOLTING K. , STREIB W. E. , HO D. M. , HUFFMAN J. C. , CAULTON K. G. 
Published: May 2016

AbstractThe monomeric Au(I) alkoxides (III) are obtained as shown.
ChemInform Abstract: Electron and Energy Shuttling Between Redox Sites on Soluble Polymers.
Authors: OLMSTED J. III , MCCLANAHAN S. F. , DANIELSON E. , YOUNATHAN J. N. , MEYER T. J. 
Published: May 2016

AbstractIt is demonstrated that through a series of energy and electron transfer reactions 9‐methylanthracene can convert the initially stored MLCT excited state energy of a polymer‐bound polypyridyl complex of Ru(II) into transiently stored oxidative and reductive redox equivalents on separated polymeric units.
ChemInform Abstract: Pentamethylcyclopentadienyl Transition Metal Complexes. Part 11. Organometallic Monoglyoximato Complexes of Co and Rh.
Authors: KOELLE U. + , RAABE E. , KRUEGER C. + , ROTZINGER F. P. 
Published: May 2016

AbstractReaction of the halide complexes (I) with dimethylglyoxime gives the monoglyoxime complexes (III) or (IV).
ChemInform Abstract: Cyclopalladation to Form Planar Tridentate (N‐C‐N)‐ Intramolecular Coordination Systems Involving Pyridine Donor Groups, Including Ligand Synthesis and X‐Ray Structural Studies.
Authors: CANTY A. J. , MINCHIN N. J. , SKELTON B. W. , WHITE A. H. 
Published: May 2016

AbstractReaction of Pd(II) acetate with 1,3‐bis(1‐(pyridin‐2‐yl)ethyl)benzene or 1,3‐bis(2‐pyridinecarbonyl)benzene in glacial acetic acid results in cyclopalladation and formation of the complexes (Ia) and (II), respectively.
ChemInform Abstract: Bimetallic Systems. Part 21. Synthesis of Vinylidene‐ and Phenylene‐Bridged Complexes of Dinickel(II), Nickel(II)‐Palladium(II), and Nickel(II)‐Platinum(II) Containing Ph2PCH2PPh2 (dppm): Crystal Structures of ((SCN)Ni(μ‐dppm)2(μ‐C=CH2)Ni(NCS)) and (ClPd(μ‐dppm)2(μ‐C=CCl2)NiCl).
Authors: FONTAINE X. L. R. , HIGGINS S. J. , SHAW B. L. , THORNTON‐PETT M. , WU Y. 
Published: May 2016

AbstractThe vinylidene‐ and phenylene‐bridged "A‐frame" complexes (IVa), (IVd)‐(IVf) and (VI) are prepared by reaction of the α‐chlorovinyl‐Ni complex (I), its trichlorovinyl analogue, or the aryl analogues (V) with bis(diphenylphosphino)methane (III) and Ni(COD)2 (II), Pd(PPh3)4 (V), or corresponding Pd(0) and Pt(0) complexes (1:2:1 molar ratio).
ChemInform Abstract: Reactions of the Esters of 2H‐Perfluorocarboxylic Acids with Secondary Amines. Simple Synthesis of Perfluorinated β‐Enamino Esters and β‐Keto Esters.
Authors: PORTELLA C. , IZNADEN M. 
Published: May 2016

AbstractThe cholestanyl fluorocarboxylate (I) reacts with the secondary amines (II) to give a Z/E‐mixture of the enamino esters (III).
ChemInform Abstract: Synthetic Studies in Carbohydrates. Part 49. Selective Phosphorylation of the Primary Hydroxyl Groups of Methyl 2‐O‐α‐D‐Mannopyranosyl‐α‐D‐ mannopyranoside.
Authors: JAIN R. K. , ABBAS S. A. , MATTA K. L. 
Published: May 2016

AbstractTreatment of the disaccharide (Ia) with diphenyl phosphorochloridate (II) gives selectively the monophosphorylated derivative (Ib).
ChemInform Abstract: Novel Applications of the Modified Polonovski Reaction. Part 9. A New Route to Wenkert′s Enamine.
Authors: LOUNASMAA M. , KARVINEN E. , KOSKINEN A. , JOKELA R. 
Published: May 2016

AbstractThe title compound (XI), a key intermediate in the synthesis of several clinically useful antihypertensive eburnane alkaloids, is prepared starting from the bromide (I) via the title reaction (IV) → (VII).
ChemInform Abstract: Synthesis of Z‐Marginalin and Identification of the Natural Product as the E Isomer (IIIb).
Authors: BARBIER M. 
Published: May 2016

AbstractFrom UV and MS data it is shown that the single isomer (IIIa) which is isolated by thin‐layer chromatography is the Z isomer (IIIa) in contrast to the natural marginalin (IIIb).
ChemInform Abstract: Studies in Anthracyclinone Synthesis. The Oxidative Decyanation Route to Aklavinone (VI) and 4,11‐Dideoxy‐α‐rhodomycinone
Authors: RAO J. A. , RAVICHANDRAN K. , O'MALLEY G. J. , CAVA M. P. 
Published: May 2016

Abstract(XIII).
ChemInform Abstract: Synthesis of Tricyclic Azetidinones by Intramolecular Free Radical Cyclization.
Authors: JUST G. , SACRIPANTE G. 
Published: May 2016

AbstractThe title reaction of the azetidinones (I) and (IIIa) yields the benzo carbapenems (II) and (V), resp., which are unstable in solution.
ChemInform Abstract: Chiral Building Units from Carbohydrates. Part 13. Identification of the Absolute Configuration of endo‐Brevicomin from Dendroctonus frontalis and Synthesis of Both Enantiomers from D‐Ribose.
Authors: REDLICH H. , BRUNS W. , FRANCKE W. , SCHURIG V. , PAYNE T. L. , VITE J. P. 
Published: May 2016

AbstractThe title compounds (‐)‐(XII) and (+)‐(XVI) are prepared starting from D‐ribose via the key intermediate (VII) (in part no yields given).
ChemInform Abstract: Crystal Structure of Cesium Molybdenum Alum, Cs(Mo(H2O)6)(SO4)2·6 H2O, at 110 K.
Authors: BRORSON M. , GAJHEDE M. 
Published: May 2016

AbstractThe title compound crystallizes in space group Pa3, Z=4, and belongs to the β class of alums.
ChemInform Abstract: Preparation and Characterization of Quantum Size Zinc Oxide: A Detailed Spectroscopic Study.
Authors: BAHNEMANN D. W. , KORMANN C. , HOFFMANN M. R. 
Published: May 2016

AbstractTransparent colloidal suspensions of small ZnO particles (2000‐3000 molecules) have been prepared in H2O, iPrOH, and MeCN, and UV/VIS absorption spectra are recorded at various times during the preparation.
ChemInform Abstract: 51V NMR Spectroscopy of Tungstovanadate Polyanions. Chemical Shift and Line‐Width Patterns for the Identification of Stereoisomers.
Authors: LEPARULO‐LOFTUS M. A. , POPE M. T. 
Published: May 2016

Abstract51V NMR spectra are reported for several tungstovanadate polyoxoanions, including VxW6‐xO(2+x)‐ 19 (I) (x = 1‐3), α‐SiVxW12‐xO(4+x)‐ 40 (II) (x = 1‐3), β1‐, β2‐, and β3‐SiVW11O35‐9 (III), α‐PV2W10O45‐0 (IV) (mixtures of isomers), VV2W10O45‐0 (V) (mixtures of isomers), and VV3W9O46‐0 (VI) (mixtures of isomers).
ChemInform Abstract: Silicon Surface Barrier Modification by Low‐Energy Nitrogen Ion Implantation.
Authors: RINGEL S. A. , ASHOK S. 
Published: May 2016

AbstractThe formation of ultrathin (≤ 5 nm) SiNx films by very low energy (200‐600 eV) nitrogen ion implantation into Si is shown to alter the properties of subsequently fabricated Schottky diodes.
ChemInform Abstract: Substrate Transformation Phenomena During the Nucleation of Silver on Polyfaced Platinum Single Crystal Electrodes. Part 2. Characterization of the Platinum Surface
Authors: MILCHEV A. , CHIERCHIE T. , JUETTNER K. + , LORENZ W. J. 
Published: May 2016

Abstractby means of combined voltammetric and pulse potentiostatic methods.
ChemInform Abstract: Trace Metal Speciation by ASV. Part 7. Interaction of Zinc with Cl‐, NO‐ 3, I‐, SO2‐ 4, and OH‐.
Authors: KOMORSKY‐LOVRIC S. , BRANICA M. 
Published: May 2016

AbstractThe stability constants of complexes of zinc with the title anions have been determined by the pseudo‐polarographic method at a zinc concentration level of 10‐8 mol/dm3.
ChemInform Abstract: AC Impedance Studies of Aluminum Alloy 6061 in Chloride Solutions. The Role of Oxygen, Hydrogen Ions, and Aluminum Ions in Initiating Crevice Corrosion.
Authors: REISING R. F. 
Published: May 2016

AbstractCorrosion‐potential and ac‐impedance measurements show that the pH is the dominant factor in crevice corrosion initiation of the title alloy in aqueous chloride solution, which is in accordance with the crevice‐corrosion mechanism proposed by Fontana and Greene.