bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Mechanism of Photocatalytic Decomposition of Water into H2 and O2 over NiO‐SrTiO3.
Authors: DOMEN K. , KUDO A. , ONISHI T. 
Published: May 2016

AbstractThe activities of NiO‐SrTiO3 powder catalysts for the photocatalytic H2O decomposition, as well as for H2 evolution from aqueous MeOH and O2 evolution from aqueous AgNO3 solution have been determined and the results are discussed in terms of the structure of the catalyst.
ChemInform Abstract: Solution Properties of Cu(II)‐L‐α‐alaninehydroxamic Acid.
Authors: KURZAK B. , KURZAK K. , JEZIERSKA J. 
Published: May 2016

AbstractPotentiometric, ESR and electronic spectroscopic results show that the title acid CH3CH(NH2)CONHOH coordinates to Cu(II) via the α‐amino nitrogen and the nitrogen atom of the NHOH group and that aqueous solutions contain dimeric species in the pH range 4‐6. At pH 7.4‐8.3 only 1:2 Cu/ligand species appear to be present.
ChemInform Abstract: Ene Reactions with α‐Chloronitroso Compounds: Asymmetric Synthesis of N‐Allylhydroxylamines.
Authors: KRESSE G. , VASELLA A. , FELBER H. , RITTER A. , ASCHERL B. 
Published: May 2016

AbstractThe nitroso compound (I) reacts with the alkenes (II) to afford the nitrone hydrochlorides (III) which are easily hydrolyzed to the hydroxylamines (IV).
ChemInform Abstract: Heterocyclic β‐Enamino Esters. Part 44. Dihalotriphenylphosphoranes in Heterocyclic Synthesis. Part 11. 2,3,3a,7a‐Tetrahydrobenzofurans, ‐benzo(b)thiophene, and 2,3,3a,7a‐Tetrahydroindole by Cycloaddition with Cyanoacetylene.
Authors: WAMHOFF H. , FASSBENDER F.‐J. , HERMES D. , KNOCH F. , APPEL R. 
Published: May 2016

AbstractThe triphenylphosphoranes (I) react with cyanoacetylene (II) to give the fused heterocycles (III).
ChemInform Abstract: Cycloadditions. Part 9. Intramolecular Diels‐Alder Reaction of Allenecarboxanilides; Incorporation of the Amide Nitrogen Atom in Benzo‐ and Dibenzo‐Condensated Five‐, Six‐, and Seven‐Membered Rings.
Authors: DIEHL K. , HIMBERT G. 
Published: May 2016

AbstractThe allenecarboxanilides (VI) are synthesized from the amines (I) via the phosphorus ylides (IV).
ChemInform Abstract: Formation of the Tetracyclo(5.4.2.02,6.02,9)tridecane Ring System by a Novel Transannular Aldolization Reaction.
Authors: DESHPANDE M. N. , WEHRLI S. , JAWDOSIUK M. , GUY J. T. JUN. , BENNETT D. W. , COOK J. M. , DEPP M. R. , WEISS U. 
Published: May 2016

AbstractThe glyoxal (III), prepared from cyclopentene carboxylic acid (I), reacts with the ketodiester (IV) to form the bicyclooctanediones (V).
ChemInform Abstract: Photoelectrochemistry of Dianionic Maleonitriledithiolate Complexes of Nickel and Platinum in Ion‐Exchange Films on Transparent Tin Oxide Electrodes.
Authors: PERSAUD L. , LANGFORD C. H. 
Published: May 2016

AbstractThe water‐insoluble compounds (I) are ion‐exchanged into films of quaternized poly(vinylpyridine).
ChemInform Abstract: An Azimine‐Triaziridine Transformation by Laser Photolysis.
Authors: KAUPP G. , DOEHLE J. A. + 
Published: May 2016

AbstractThe triaziridine (II) is obtained from the azimine (I) in a two‐photon laser process at 10‐85 K. One‐photon excitation does not alter (I).
ChemInform Abstract: Synthesis of Pyrethroids with α‐Trichloromethyl Groups in the Alcohol Fragment.
Authors: VOLKOV YU. P. , YANOVSKAYA L. A. , KRYSHTAL' G. V. , KALINEVICH V. M. , TRUSOVA E. I. 
Published: May 2016

AbstractThe trichloromethyl arylmethyl alcohols (III) are prepared from the substituted benzaldehydes (I) via their acylals (II) and react with theacyl chlorides (IV) to yield the title compounds (V).
ChemInform Abstract: Functional Derivatives of Perfluorodecaline.
Authors: MAKAROV K. N. , PLETNEV S. I. , GERVITS L. L. , NATAROV V. P. , PROKUDIN I. P. , KNUNYANTS I. L. 
Published: May 2016

AbstractThe perfluorooctaline (I) is treated with sodium hypochlorite to givethe epoxide (II), which is transformed to the stable cesium perfluorodecane‐5‐olate (III).
ChemInform Abstract: Synthesis of Medium and Large Rings. Part 16. Boat‐Shaped Arenes ‐ Synthesis, Structure, and Properties of (7)Paracyclophanes and (7)(1,4)Naphthalenophanes.
Authors: HUNGER J. , WOLFF C. , TOCHTERMANN W. , PETERS E.‐M. , PETERS K. , VON SCHNERING H. G. 
Published: May 2016

AbstractThe cyclononafuran (I) ‐ obtained from cyclononanone by a known procedure ‐ is converted to the heptanooxepin (IIa).
ChemInform Abstract: Synthesis and Analgesic Evaluation of 4‐(2‐Heptyloxy)‐7‐((Z)‐(3‐hydroxycyclohexyl))indole: A Caveat on Indole‐Phenol Bioisosterism.
Authors: SOLL R. M. , HUMBER L. G. , DEININGER D. , ASSELIN A. A. , CHAU T. T. , WEICHMAN B. M. 
Published: May 2016

AbstractThe aldehyde (Ia) is etherified to (Ib) and then coupled with methyl azidoacetate (III) to yield the azidoester (IV) which cyclizes, forming the indole (Va).
ChemInform Abstract: Synthesis and β‐Adrenergic Receptor Blocking Potency of 1‐(Substituted amino)‐3‐(4‐indolyloxy)propan‐2‐ols.
Authors: TEJANI‐BUTT S. M. , BRUNSWICK D. J. 
Published: May 2016

Abstract4‐Hydroxy‐indole (I) reacts with epichlorohydrine (II) to produce theepoxide (III) which is converted to the aminoalcohols (V).
ChemInform Abstract: Chemistry of CO and CS Functional Pentaazaspiro(4.5)decanes: Ring Opening and Ring Contraction Reactions.
Authors: HEITZ H. , HERRMANN G. , SUESS‐FINK G. + 
Published: May 2016

AbstractThe spiropentaazacycles (Ia), (Ic) or (Id) react according to method A) to give the Wittig products (Ib) or (Ie).
ChemInform Abstract: Ligand‐Receptor Interactions via Hydrogen‐Bond Formation. Synthesis and Pharmacological Evaluation of Pyrrolo and Pyrido Analogues of the Cardiotonic Agent 7‐Hydroxycyclindole.
Authors: DIONNE G. , HUMBER L. G. , ASSELIN A. , MCQUILLAN J. , TREASURYWALA A. M. 
Published: May 2016

AbstractThe enamine (I) reacts with the dinitrochlorobenzene (II), producing the substituted cyclohexanone (III).
ChemInform Abstract: Chemical Properties of Ylidene Derivatives of Azines. Part 3. Synthesis and Reactions of Ylidene Derivatives of Halopyrimidines with Nucleophilic Reagents.
Authors: ZAGULYAEVA O. A. , SEMUSHKINA I. V. , MAMAEV V. P. 
Published: May 2016

AbstractDie Mono‐ und Dichlorpyrimidine (I) reagieren mit dem Natriumsalz desCyanessigsäureesters (II) unter Substitution eines Chloratoms zur Verbindung (III).
ChemInform Abstract: Cardiovascular Activity of Azolo(1,5‐a)pyrimidine Nitro Derivatives.
Authors: RUSINOV V. L. , PILICHEVA T. L. , CHUPAKHIN O. N. , KOVALEV G. V. , KOMINA E. R. 
Published: May 2016

AbstractThe azolopyrimidine derivatives (III) are prepared from the azoles (I) and nitromalonic dialdehyde sodium salt (II).
ChemInform Abstract: An Acid‐Catalyzed Hydroxyalkylation of Uracil: A Facile Synthesis of 5‐(Arylhydroxymethyl)uracils.
Authors: LAM B. L. , PRIDGEN L. N. 
Published: May 2016

AbstractUracil (I) reacts with the electron‐deficient aldehydes (II) in an aqueous acidic solution to form the arylhydroxymethyl derivatives (III).With electron‐rich aldehydes, e.g. benzaldehyde (IV), only 2:1‐adductssuch as (V) are isolated.
ChemInform Abstract: Analogues of 1,3‐Dipropyl‐S‐phenylxanthine: Enhancement of Selectivity at A1‐Adenosine Receptors by Aryl Substituents.
Authors: DALY J. W. , PADGETT W. L. , SHAMIM M. T. 
Published: May 2016

AbstractThe analogues (III) of 1,3‐dipropyl‐8‐phenylxanthine are produced by reacting the uracil (I) with the aromatic aldehydes (II) under oxidative conditions.
ChemInform Abstract: Fused Imidazo‐1,2,4‐azines. Part 14. Synthesis and Reactivity of 3‐Chloro‐Substituted Imidazo(1,2‐b)‐1,2,4‐triazines.
Authors: KRUGLENKO V. P. , TIMOSHIN A. A. , KLYUEV N. A. , LOGACHEV E. V. , POVSTYANOI M. V. 
Published: May 2016

AbstractBeim Erhitzen des Imidazotriazinons (Ia) mit Phosphorpentachlorid undPhosphoroxychlorid wird neben dem 3‐Chlor‐imidazotriazin (IIa) auch das Dichlorderivat (IIIa) erhalten, während mit Thionylchlorid nur (IIa)entsteht.
ChemInform Abstract: Synthesis of the First Examples of Fully Unsaturated Monocyclic 1,4‐Oxazepines.
Authors: KURITA J. , IWATA K. , TSUCHIYA T. 
Published: May 2016

AbstractStarting with the pyridines (I), the 2‐aza‐bicyclo‐hexenes (II) can be obtained via one intermediate step.
ChemInform Abstract: Unsaturated Silicon Containing Diols.
Authors: MUSTAFAEV R. M. , KULIEVA L. G. , SADYKH‐ZADE S. I. , MUSTAFAEV S. N. 
Published: May 2016

AbstractPropargyloxy propandiol (II) is hydrosilylated with the silanes (I) in the presence of hexachloroplatinic acid, giving the vinyl silanes (III).
ChemInform Abstract: Acid Catalyzed Isomerization of the (2 + 1) Cyclodimer of an Iminophosphane to the Diazadiphosphetidine.
Authors: NIECKE E. , GUDAT D. , SYMALLA E. 
Published: May 2016

AbstractThe oxidation of the iminophosphane (I) with Br2 yields the dibromo derivative (II).
ChemInform Abstract: Synthesis and Properties of Open‐Chain and Cyclic 1λ3,3λ3‐Diphosphaalkanes RR′P‐CH2‐PR′R.
Authors: SCHMIDBAUER H. , SCHNATTERER S. 
Published: May 2016

AbstractThe disecondary methylenediphosphanes (IV) and (VI), which with their adjustable positive or negative polarity are useful building blocks for organophosphorus synthesis, are prepared by multi‐step substitution of the Cl atoms in (I) as shown in the scheme.
ChemInform Abstract: Synthesis and 119Sn NMR of η1‐O‐Coordinated Sulfine‐Dimethyltin Dichloride Complexes and Thermal C=S and S=O Bond Cleavage Reactions. X‐Ray Structure (130 K) of Me2SnCl2(η1‐O‐(Me(Ph)NC(Ph)=S=O)).
Authors: JANS R. J. F. , VAN KOTEN G. , ANDREA R. R. , VRIEZE K. , SPEK A. L. , KOJIC‐PRODIC B. , DE BOER J. L. 
Published: May 2016

AbstractAddition of the aminosulfines to a CH2Cl2 solution of an equimolar amount of Me2SnCl2 results in the formation of the 1:1 complexes (I) (no yields given).
ChemInform Abstract: Anticancer Activity of Organometallic Compounds. Part 3. The Reaction of Dimethyltin Dichloride with Nucleosides Under Biologically Relevant Conditions.
Authors: CARDIN C. J. , ROY A. 
Published: May 2016

AbstractThe reaction of Me2SnCl2 with adenosine, guanosine and inosine in aqueous solution (pH 4.5) yields amorphous powders.
ChemInform Abstract: Derivatization of the Cuboidal Mo4S4‐Aquo Ion: Preparation and Structure of Mo4S4(HB(pz)3)4(pz) (pz: Pyrazolyl, C3N2H‐ 3).
Authors: COTTON F. A. , DORI Z. , LLUSAR R. , SCHWOTZER W. 
Published: May 2016

AbstractThe title compound (I) is formed by addition of an excess of potassium hydrido‐tris(pyrazolyl)borate to a solution of the cuboidal Mo4S4‐aquo ion.
ChemInform Abstract: Reactive π Complexes of the Group VIII Transition Metals. Part 2. Bis(η2‐ethene)(η6‐toluene)iron.
Authors: ZENNECK U. , FRANK W. 
Published: May 2016

AbstractCocondensation reactions of iron atoms with toluene yield the product (II) which reacts in situ at ‐60 °C with ethylene to give the novel reactive title complex (III).
ChemInform Abstract: CC‐Coupling of CO2 and Butadiene on Iron(0) Complexes ‐ a Novel Route to α,ω‐Dicarboxylic Acids.
Authors: HOBERG H. , JENNI K. , KRUEGER C. + , RAABE E. 
Published: May 2016

AbstractThe C1‐building block CO2 can add via CC‐coupling to the η4‐butadiene‐Fe(0) complex (I) to give the very stable η3‐allylic carboxylate complex (II).
ChemInform Abstract: Synthesis and Characterization of (Fe2OX6)2‐ (X: Cl, Br, I) Complexes. Crystal and Molecular Structure of (BzPh3P)2(Fe2OCl6).
Authors: PETRIDIS D. , TERZIS A. 
Published: May 2016

AbstractThe phosphonium salts of the title complexes (Ia) are prepared by reaction of FeX2 with benzyltriphenylphosphonium halide in refluxing acetonitrile followed by air‐oxidation or in the case of X: I by H2O2 oxidation.
ChemInform Abstract: Radiation Synthesis of Organometallic Compounds. Radiolysis of Benzene Solutions of Co2(CO)8.
Authors: CASTIGLIONI M. , CETINI G. , OPERTI L. , VOLPE P. 
Published: May 2016

AbstractAfter repeated separation, the novel complexes (I) and (II) were isolated from the title reaction, besides two well‐known compounds Co2(CO)6(C2H2) and Co4(CO)12.
ChemInform Abstract: ((C3Ph3)Ni(μ‐Br)3Ni(C3Ph3))(C3Ph3). A Triple‐Decker‐like Complex with Triphenylcyclopropenyl as Ligand.
Authors: CECCONI F. , GHILARDI C. A. , MIDOLLINI S. , MONETI S. , ORLANDINI A. 
Published: May 2016

AbstractIn the course of attempts to prepare the complex Ni2(C3Ph3)2Br2 by the reaction of (I) with (II) in THF, the complex (III) is isolated.
ChemInform Abstract: Compounds of L‐Ascorbic Acid with Metals. Part 4. Ligand Properties of the Monoanion of L‐Ascorbic Acid, C6H7O‐ 6.
Authors: JABS W. , GAUBE W. 
Published: May 2016

AbstractThe ascorbates (I) (prepared as described previously) are characterized by their hydrolytic and conductivity properties, magnetic moments, electronic, and IR spectra.
ChemInform Abstract: Intermolecular C‐C Bond Formation of Azanickelacyclopentanones, α,ω‐Diacid Amides from Alkenes and Phenyl Isocyanate.
Authors: HOBERG H. , HERNANDEZ E. 
Published: May 2016

AbstractThe azanickelacyclopentanones (IV), prepared by reacting the alkenes (I) with phenyl isocyanate (II) and the Ni(0) complexes (III), are oxidized by FeCl3 or I2 to yield a mixture of the acrylic acid anilides (V) and the adipic acid anilides (VI).
ChemInform Abstract: Metal Chelates of Heterocyclic Nitrogen‐containing Ketones. Part 19. Some Acetato‐ and Nitrato‐Copper(II) Complexes of Phenyl‐2‐picolyl Ketone Hydrazone and Phenyl‐2‐picolyl Ketone Phenyl Hydrazone.
Authors: EL‐DISSOUKY A. , HINDAWEY A. M. , ABDEL‐SALAM A. 
Published: May 2016

AbstractThe hydrazones prepared from phenyl 2‐picolyl ketone and hydrazine hydrate or phenyl hydrazine react with hydrated Cu(II) acetate or nitrate in ethanol in molar ratio 1:1 or 2:1 to give the trigonal bipyramidal complexes (I) and (II), or the tetrahedral (R: H) and square planar (R: Ph) complexes (III).
ChemInform Abstract: Chemistry Derived from Ruthenium Atoms. Part 2. Synthesis and Reactivity of the Monocarbonyl Complexes Formed from Ruthenium‐Cyclohexadiene Cocondensates.
Authors: COX D. N. , ROULET R. 
Published: May 2016

AbstractThe reaction of Ru atoms, generated by means of the positive hearth electron beam technique, with a cyclohexadiene (III) or (IV) and CO yields the thermally labile C6H7/C6H9 complex (Ia), which can be converted to (IIa) and (VI) at higher temperatures.
ChemInform Abstract: Dicarbonyl(η5‐cyclopentadienyl)ruthenium Complexes of Cycloheptatrienylidene and Two Isomeric Benzocycloheptatrienylidenes.
Authors: LISKO J. R. , JONES W. M. 
Published: May 2016

AbstractLithiation of the mixture of bromides (I) followed by reaction with (V) gives the corresponding Ru complexes (II).
ChemInform Abstract: Synthesis and Chemistry of Alkylpalladium Compounds Prepared via Vinylpalladation of Bicyclic Alkenes.
Authors: LAROCK R. C. , HERSHBERGER S. S. , TAKAGI K. , MITCHELL M. A. 
Published: May 2016

AbstractNorbornene (I) or norbornadiene (XI) react with the vinylmercuric chlorides (II) and Li2PdCl4 (III) to give the palladium compounds (IV) and (XII) respectively.
ChemInform Abstract: Sulfonato Complexes of Ruthenium, Osmium and Iridium; the X‐Ray Crystal Structure of Ru(O3SC6H4CH3‐p)2(H2O)(CO)(PPh3)2.
Authors: HARDING P. A. , PREECE M. , ROBINSON S. D. , HENRICK K. 
Published: May 2016

AbstractA preliminary report on the synthesis of the new title complexes is given (see scheme).
ChemInform Abstract: Preparation and Reactions of Cyclopentadienylplatinum Complexes: Coupling with Coordinated Cyclooctadiene.
Authors: ANDERSON G. K. 
Published: May 2016

AbstractCleavage of the chloro‐bridged Pt dimer (I) with TlC5H5 produces the monomeric η5‐cyclopentadienyl‐Pt complex (II).
ChemInform Abstract: An Asymmetric Synthesis of cis‐5‐Alkylproline Derivatives.
Authors: HO T. L. , GOPALAN B. , NESTOR J. J. JUN. 
Published: May 2016

AbstractThe N‐protected L‐glutamic acid (I) is converted to the ketolactone (IIIc) via (IIIa) and (IIIb).
ChemInform Abstract: Synthesis of Anatoxin‐a.
Authors: WISEMAN J. R. , LEE S. Y. 
Published: May 2016

AbstractBromination of the azabicyclononanol (Ib) prepared from (Ia) gives the amino ketone (II) which is converted to N‐methylanatoxin‐a (Va) by abis‐homologation procedure using first Wittig‐Horner reaction with (III) and then an oxygenation/reduction step.
ChemInform Abstract: The Pitting Corrosion Behavior of Rapidly Solidified Aluminum Alloys
Authors: YOSHIOKA H. , YOSHIDA S. , KAWASHIMA A. , ASAMI K. , HASHIMOTO K. 
Published: May 2016

Abstractcontaining Mg, Ti, Mn, Cr, Fe, Ni, Cu, Zn, Zr, Nb and/or Si (binary or ternary alloys) has been investigated in 0.5 N NaCl at 30 °C. Rapid solidification by melt spinning improves the pitting potential by several hundred millivolts except for the alloys containing Mg, Fe or Zn.
ChemInform Abstract: XPS Study of Silica‐Supported Copper Catalyst Derived from Binuclear Copper(II) Acetate Monohydrate or Mononuclear Tetraammine Copper(II) Complex.
Authors: KAKUTA N. , KAZUSAKA A. , MIYAHARA K. 
Published: May 2016

AbstractThe XPS results together with the results of a recent EXAFS study are consistent with a highly dispersed one‐ or two‐dimensional copper oxide cluster on SiO2 in the case of the catalyst prepared from Cu2(OAc)4·2 H2O, while a three dimensional one is observed on the catalyst derived from the tetraammine copper(II) complex.
ChemInform Abstract: Catalytic and Stoichiometric Hydrogen Formation by UV Irradiation of Sodium and Zinc Sulfide.
Authors: KISCH H. , FERNANDEZ A. , MILLINI R. 
Published: May 2016

AbstractUV irradiation (λ≧ 248 nm) of an aqueous Na2S solution results in a stoichiometric H2 evolution with a quantum yield of Φ(H2) = 0.34 at 254 nm.
ChemInform Abstract: A Structural and Isotopic NO‐ 2 Exchange Rate Comparison of trans‐(Co(ao‐H‐ao)(NO2)2) and cis‐(Co(Hao)2(NO2)2)NO3.
Authors: MURRAY D. E. , SCHLEMPER E. O. , SIRIPAISARNPIPAT S. , MURMANN R. K. 
Published: May 2016

AbstractThe X‐ray crystal structures of the two non‐isomeric title compounds (I) and (II) are determined.
ChemInform Abstract: Electrochemistry of Dinuclear, Thiolato‐Bridged Transition‐Metal Compounds. Part 2. Reductive Electrochemistry of Metal‐Metal Bonded Complexes Cyclic ((η5‐C5H5)(CO)2Mo(μ‐SMe)W(CO)4L) (L: CO or P(OMe)3).
Authors: COURTOT‐COUPEZ J. , GUEGUEN M. , GUERCHAIS J. E. , PETILLON F. Y. , TALARMIN J. 
Published: May 2016

AbstractThe title complexes have been studied by usual electrochemical methods in propylene carbonate.
ChemInform Abstract: Mercury(II)‐Promoted Cyclization of Some 2‐Alkenylphenols and Some Cyclic 2‐Alkenyl‐1,3‐diketones, 3‐Keto Esters, and 3‐Keto Amides: Synthesis of 2,3‐Dihydrofuran, 3,4‐Dihydro‐2H‐pyran, and 2,3,4,5‐Tetrahydrooxepin Rings Fused on Carbocyclic or on Oxygen and Nitrogen Heterocyclic Systems.
Authors: BRAVO P. , DE VITA C. , TICOZZI C. , VIANI F. , CAVICCHIO G. 
Published: May 2016

AbstractMercuration of the corresponding hetero or carbocyclic compounds bearing a hydroxyl and a proper alkenyl side chain in o‐position leads to the chloromercurymethyl substituted oligocyclic systems (II), (IV), (VI), and (VIII); furthermore, (IX) is obtained from the corresponding 4‐acetoxyphenol (yield 87%).
ChemInform Abstract: Synthesis of Oxygen Heterocycles from 2‐Arylidene‐1,3‐diketones.
Authors: CILLER J. A. , MARTIN N. , QUINTEIRO M. , SEOANE C. , SOTO J. L. 
Published: May 2016

AbstractTreatment of the 3‐arylidene‐2,4‐pentanediones (I) with potassium cyanide yields the nitriles (II) which cyclize as a result of basic treatment in the presence of the aromatic aldehyde (III), forming the 2‐aminofurans (IV) and (V).
ChemInform Abstract: Structural Influences on the Isomerization of 4‐Benzyl‐ and 4‐Allyl‐1,2‐naphthoquinones to Quinonemethides and Their Stereochemistry.
Authors: TAKUWA A. , IWAMOTO H. , SOGA O. , MARUYAMA K. 
Published: May 2016

AbstractThe benzylnaphthoquinones (IIIa) are prepared from the naphthol (I).
ChemInform Abstract: Asymmetric Oxidation of Olefins to Vicinal Diols with Osmium Tetroxide.
Authors: TOKLES M. , SNYDER J. K. 
Published: May 2016

Abstract(‐)‐(R,R)‐N,N,N',N'‐tetramethyl‐cyclohexane‐1,2‐trans‐diamine (I) is employed as a chiral ligand for the osmium tetroxide cis‐hydroxylation of olefins in order to stimulate asymmetric induction.
ChemInform Abstract: Chemoselective Oxidation of the Primary Alcohol Function of Diols Catalyzed by Zirconocene Complexes.
Authors: NAKANO T. , TERADA T. , ISHI Y. , OGAWA M. 
Published: May 2016

AbstractThe diols (I) with at least one primary alcohol group are oxidized selectively using cyclohexanone (II) and the zirconium complex (III) to produce the hydroxyaldehydes (IV).
ChemInform Abstract: Cyclic Voltammetric Behaviour of Some Cationic η3‐Allyl Complexes of Pd(II) and Pt(II) in Comparison with Hydride Reduction.
Authors: CARTURAN G. , BIASIOLO M. , DANIELE S. , MAZZOCCHIN G. A. , UGO P. 
Published: May 2016

AbstractThe title complexes (I) are reduced on reaction with stoichiometric amounts of LiBEt3H in THF at ‐80 °C and by cathodic electron transfer.
ChemInform Abstract: Syntheses of α‐Iodocarbonyl Compounds Using Bis(sym‐collidine)iodine(I) Tetrafluoroborate/Dimethyl Sulfoxide.
Authors: EVANS R. D. , SCHAUBLE J. H. 
Published: May 2016

AbstractThe reagent (II) mentioned in the title is used to convert alkenes into the corresponding α‐iodocarbonyl compounds such as (III), (V), (VI), (VIII), (X), (XII), and (XIV).
ChemInform Abstract: The Invention of New Radical Chain Reactions. Part 12. Improved Methods for the Addition of Carbon Radicals to Substituted Allylic Groups.
Authors: BARTON D. H. R. , CRICH D. 
Published: May 2016

AbstractA procedure is developed for the allylation of carbon radicals which are formed from (I) under the conditions shown in the scheme using the hydroxythiopyridone (II) and various allylation reagents (V) (table; detailed discussion of the mechanism).
ChemInform Abstract: Flash Vacuum Pyrolysis of 5‐(Indol‐2‐ and ‐3‐ylmethylene)‐2,2‐dimethyl‐1,3‐dioxane‐4,6‐diones.
Authors: BENZIES D. W. M. , MARTINEZ FRESNEDA P. , JONES R. A. , MCNAB H. 
Published: May 2016

AbstractPyrolytic fragmentation of the title compounds (III) and (XI) (obtained by condensation of (I) or the corresponding 3‐formylindole resp. with Meldrum's acid (II)) leads to the methylene ketenes (IV) and (XII) as intermediates.
ChemInform Abstract: Thiazolylalkylamines: Synthesis of Imidazolylethylamine Analogues and Their Influence on Gastric Secretion.
Authors: VITALI T. , IMPICCIATORE M. , PLAZZI P. V. , BORDI F. , MORINI G. 
Published: May 2016

AbstractNach bekannten Methoden werden die Thiazolylalkylamine (I) hergestellt und ihre Wirkung auf die Magensekretion untersucht.
ChemInform Abstract: Aromatic Annelation by Reaction of Arylimidoyl Radicals with Alkynes: Evidence for the Intervention of a Spirocyclohexadienyl Radical in the Synthesis of Substituted Quinolines.
Authors: LEARDINI R. , NANNI D. , PEDULLI G. F. , TUNDO A. , ZANARDI G. 
Published: May 2016

AbstractThe benzylideneanilines (Ia) and (Ib) react with phenylacetylene in the presence of diisopropyl peroxydicarbonate to give the quinolines (II) and (III).
ChemInform Abstract: The Synthesis and Antitumor Activities of Tropolone and 8‐Hydroxyquinoline Derivatives.
Authors: YAMATO M. , HASHIGAKI K. , YASUMOTO Y. , SAKAI J. , TSUKAGOSHI S. , TASHIRO T. , TSURUO T. 
Published: May 2016

AbstractThe aromatic aldehyde acetals (I) are coupled with 8‐hydroxyquinoline (II) in the presence of the hydroperoxide (III) to form the bisquinolylaryl methanes (IV) which are active antitumor compounds.
ChemInform Abstract: Stereochemical Studies. Part 100. Saturated Heterocycles. Part 104. Synthesis, and NMR and X‐Ray Study of 1‐Substituted Azeto(2,1‐a)isoquinoline Diastereomers.
Authors: BERNATH G. , KOBOR J. , FUELOEP F. + , SOHAR P. , ARGAY G. , KALMAN A. 
Published: May 2016

AbstractThe title compounds (VII) are synthesized with a view to their biological activity.
ChemInform Abstract: Synthesis and Physiological Activity of Thiazolidinylbenzoxazines.
Authors: SUDHAKAR C. , SURYACHANDER V. , RAJAMOHAN K. 
Published: May 2016

AbstractDie im Titel genannten Verbindungen (V) werden durch Umsetzung des Benzoxazinons (I) mit den substituierten Benzaldehyden (II) und Kondensation der daraus resultierenden Schiffschen Basen (III) mit Mercaptoessigsäure (IV) dargestellt und auf ihre fungizide Wirkung untersucht.