bluuebunny/crossref_metadata_2025_split huggingface dataset:
Synthesis, Electrochemistry, and Photophysics of Aza‐BODIPY Porphyrin Dyes
Authors: Pascal Simon , Bucher Léo , Desbois Nicolas , Bucher Christophe , Andraud Chantal , Gros Claude P. 
Published: March 2016

AbstractThe synthesis of dyad and triad aza‐BODIPY‐porphyrin systems in two steps starting from an aryl‐substituted aza‐BODIPY chromophore is described. The properties of the resulting aza‐BODIPY‐porphyrin conjugates have been extensively investigated by means of electrochemistry, spectroelectrochemistry, and absorption/emission spectroscopy. Fluorescence measurements have revealed a dramatic loss of luminescence intensity, mainly due to competitive energy transfer and photoinduced electron transfer involving charge separation followed by recombination.
Triple Helix Formation in a Topologically Controlled DNA Nanosystem
Authors: Yamagata Yutaro , Emura Tomoko , Hidaka Kumi , Sugiyama Hiroshi , Endo Masayuki 
Published: March 2016

AbstractIn the present study, we demonstrate single‐molecule imaging of triple helix formation in DNA nanostructures. The binding of the single‐molecule third strand to double‐stranded DNA in a DNA origami frame was examined using two different types of triplet base pairs. The target DNA strand and the third strand were incorporated into the DNA frame, and the binding of the third strand was controlled by the formation of Watson–Crick base pairing. Triple helix formation was monitored by observing the structural changes in the incorporated DNA strands. It was also examined using a photocaged third strand wherein the binding of the third strand was directly observed using high‐speed atomic force microscopy during photoirradiation. We found that the binding of the third strand could be controlled by regulating duplex formation and the uncaging of the photocaged strands in the designed nanospace.
1,3‐Alternate Tetraamido‐Azacalix[4]arenes as Selective Anion Receptors
Authors: Canard Gabriel , Edzang Judicaelle Andeme , Chen Zhongrui , Chessé Matthieu , Elhabiri Mourad , Giorgi Michel , Siri Olivier 
Published: March 2016

AbstractSix tetraaza[1.1.1.1]cyclophane derivatives bearing peripheral amide groups were prepared according to two distinct synthetic strategies that depend on the connection pattern between the aryl units. NMR experiments combined with the X‐ray structures of two tetraamide derivatives 4 b and 10 show that these cavitands adopt a 1,3‐alternate conformation both in solution and in the solid state. Consequently, the four amide groups of the aza[1.1.1.1]‐m,m,m,m‐cyclophane isomer 10 can contribute to the same recognition process towards neutral water molecules or anion guests. NMR experiments, mass spectrometry analyses and single‐crystal X‐ray structures confirm the anion‐binding ability of this receptor. Absorption spectrophotometric titrations in nonpolar solvents provided evidence for the selectivity of 10 to chloride anions in the halide series, with a corresponding association constant Ka reaching 2.5×106 m−1.
ChemInform Abstract: Pressure‐Induced Phase Transitions of Hexagonal Perovskite‐Like Oxides.
Authors: Aoba Tomoya , Tiittanen Taneli , Suematsu Hisayuki , Karppinen Maarit 
Published: March 2016

AbstractTwo new cubic (3C structured) A2B′B′′O6‐type double‐perovskite phases, Ba2CoSbO6 (I) and Ba2ZnTeO6 (II) are prepared and stabilized by high pressure heat treatment of the corresponding hexagonal (6H and 12R structured, resp.) non‐perovskite phases (Au capsule in cubic anvil apparatus, 4 GPa, 1000 °C, 1 h).
ChemInform Abstract: Growth, Structure and Optical Properties of Nonlinear Optical Crystal BaZnBO3F.
Authors: Xia Mingjun , Li R. K. 
Published: March 2016

AbstractA nonlinear optical crystal of BaZnBO3F with a size of ≈20 x 20 x 0.5 mm3 is grown from a BaF2—NaF flux containing a 1:1:1:0.5:0.3 molar mixture of BaCO3, ZnO, H3BO3, BaF2, and NaF (seed crystal over Pt crucible, 850 °C, 12 h, cooling at a rate of 0.2 °C/h) The compound crystallizes in the space group P$\bar 6$ (Z = 1, single crystal XRD) and comprises BO3 planar triangles interconnected via O from ZnO3F2 trigonal bipyramids to form (Zn3B3O6F6) twelve‐membered rings which are stacked along c.
ChemInform Abstract: Synthesis, Structure, and Magnetic Characterization of Cr4US8.
Authors: Ward Matthew D. , Chan Ian Y. , Malliakas Christos D. , Lee Minseong , Choi Eun Sang , Ibers James A. 
Published: March 2016

AbstractCr4US8 is prepared by reaction of a 1:1:6 molar mixture of U, Cr, and S in a PbI2 flux (1073 K, 12 h; 75% yield).
ChemInform Abstract: Phase Relations in the Na2MoO4—Cs2MoO4 and Na2MoO4—Cs2MoO4 —ZnMoO4 Systems, Crystal Structures of Cs3Na(MoO4)2 and Cs3NaZn2(MoO4)4.
Authors: Zolotova Evgeniya S. , Solodovnikova Zoya A. , Yudin Vasiliy N. , Solodovnikov Sergey F. , Khaikina Elena G. , Basovich Olga M. , Korolkov Iliya V. , Filatova Irina Yu. 
Published: March 2016

AbstractIn view of incomplete data, the binary systems Na2MoO4—Cs2MoO4 and Na2MoO4—ZnMoO4 bounding the Na2MoO4—Cs2MoO4 —ZnMoO4 phase system are reinvestigated by annealing appropriate amounts of monomolybdates (420—700 °C, 50—200 h).
ChemInform Abstract: Hydrothermal Synthesis and Characterization of the Lutetium Borate—Nitrate Lu2B2O5 (NO3)2·2H2O.
Authors: Ortner Teresa S. , Wurst Klaus , Hejny Clivia , Huppertz Hubert 
Published: March 2016

AbstractThe title compound is prepared by hydrothermal reaction of equimolar amounts of Lu(NO3)3 and H3BO3 (autoclave, 513 K, 3 d; cooling to 373 K at a rate of 1 °C/h).
ChemInform Abstract: Semiconductive Nanotube Array Constructed from Giant [PbII18I54(I2)9] Wheel Clusters.
Authors: Wang Guan‐E , Xu Gang , Liu Bin‐Wen , Wang Ming‐Sheng , Yao Ming‐Shui , Guo Guo‐Cong 
Published: March 2016

AbstractThe first example of a metal‐halide‐based crystalline nanotube array, (Pr2DABCO)21 [Pb18I54(I2)9] [Pb2I9] 2I5·13H2O is prepared by solvothermal reaction ofPbI2, DABCO, conc.
ChemInform Abstract: Synthesis and Catalytic Use of Gold(I) Complexes Containing a Hemilabile Phosphanylferrocene Nitrile Donor.
Authors: Skoch Karel , Cisarova Ivana , Stepnicka Petr 
Published: March 2016

AbstractThe gold complex AFCN is prepared and successfully applied as catalyst for the cycloisomerization of enynols (I) and (III) to 2,3‐dimethylfuran (II) and rosefuran (IV), respectively.
ChemInform Abstract: Copper‐ and Silver‐Catalyzed Diastereo‐ and Enantioselective Conjugate Addition Reaction of 1‐Pyrroline Esters to Nitroalkenes: Diastereoselectivity Switch by Chiral Metal Complexes.
Authors: Koizumi Akihiro , Kimura Midori , Arai Yuri , Tokoro Yuichiro , Fukuzawa Shin‐ichi 
Published: March 2016

AbstractA stereodivergent asymmetric conjugate addition of pyrroline esters to nitroalkanes provides access to syn and anti adducts using copper and silver catalytic systems.
ChemInform Abstract: Chiral Ion‐Pair Organocatalyst Promotes Highly Enantioselective 3‐Exo Iodo‐Cycloetherification of Allyl Alcohols.
Authors: Shen Zhigao , Pan Xixian , Lai Yisheng , Hu Jiadong , Wan Xiaolong , Li Xiaoge , Zhang Hui , Xie Weiqing 
Published: March 2016

AbstractAn efficient catalytic system is found for the enantioselective 3‐exo iodo‐cycloetherification of allyl alcohols (I) and (VI).
ChemInform Abstract: Addition of Terminal Alkynes to α‐Ketone Esters to Synthesize α‐Tertiary‐hydroxy Esters Promoted by Zinc and an Alkyl Halide.
Authors: Zhang Wen , Cao Yuan , Chen Wei , Zhao Gang , Pu Lin 
Published: March 2016

AbstractThis simple method is extended to the reaction of alkynes with aldehydes and electron‐deficient ketone (VII).
ChemInform Abstract: Lithium Bromide/Water as Additives in Dearomatizing Samarium‐Ketyl (Hetero)Arene Cyclizations.
Authors: Rao Chintada Nageswara , Bentz Christoph , Reissig Hans‐Ulrich 
Published: March 2016

AbstractThe cyclization of N‐acylated indole derivative (I) proceeds readily in the presence of SmI2 and LiBr in water/THF.
ChemInform Abstract: Substrate‐ and Base‐Dependent Reactivities of Acylketene Toward Aryl Aldimines Derived from 2‐Amino‐4‐methylpyridine.
Authors: Ocal Nuket , Mor Necla , Erden Ihsan 
Published: March 2016

AbstractThe triethylamine mediated reaction of arylaldimine (I) with substrate (II) provides the expected adduct (III), whereas aldimine (IV) and (VI) give different, rather unexpected products.
ChemInform Abstract: Platinum‐Catalyzed, Terminal‐Selective C(sp3)—H Oxidation of Aliphatic Amines.
Authors: Lee Melissa , Sanford Melanie S. 
Published: March 2016

AbstractA Pt‐catalyzed oxidation of aliphatic amines is achieved with high selectivity for the terminal methyl group using CuCl2 as the oxidant.
ChemInform Abstract: Copper‐Catalyzed Oxyboration of Unactivated Alkenes.
Authors: Itoh Taisuke , Matsueda Takumi , Shimizu Yohei , Kanai Motomu 
Published: March 2016

AbstractThe direction of the copper‐catalyzed borylative difunctionalization of alkenes (I) with TEMPO and dipinacolyl hypodiborate depends on the catalyst used leading to the adducts (IV) or its regioisomers (V).
ChemInform Abstract: Magnesium‐Catalyzed Hydrosilylation of α,β‐Unsaturated Esters.
Authors: Lampland Nicole L. , Pindwal Aradhana , Neal Steven R. , Schlauderaff Shealyn , Ellern Arkady , Sadow Aaron D. 
Published: March 2016

AbstractA novel magnesium complex is prepared and successfully applied as catalyst for the hydrosilylation of α,β‐unsaturated esters (I) and dihydropyranone (IV).
ChemInform Abstract: Deoxygenative C—C Bond‐Forming Processes via a Net Four‐Electron Reductive Coupling.
Authors: Todd David P. , Thompson Benjamin B. , Nett Alex J. , Montgomery John 
Published: March 2016

AbstractDeoxygenative coupling of enones or enals with alkynes is rendered possible with a reagent combination of Et3SiH and Ti(OiPr)4 and a nickel carbene complex as catalyst furnishing skipped dienes in moderate to good yields.
ChemInform Abstract: Direct C—H Bond Arylation of Thienyl Thioamides Catalyzed by Pd—Phenanthroline Complexes.
Authors: Yamauchi Takayuki , Shibahara Fumitoshi , Murai Toshiaki 
Published: March 2016

AbstractDepending only on a slight increase of catalyst loading, regioselective 2‐monoarylation of thienyl‐3‐thioamides (I) alters to 2,5‐diarylation.
ChemInform Abstract: Development and Application of a Multielectron‐Accepting Organic Oxidant for the Catalytic Transition‐Metal‐Free Oxidative Homocoupling of Grignard Reagents in Air.
Authors: Korenaga Toshinobu , Nitatori Kaoru , Muraoka Hiroki , Ogawa Satoshi , Shimada Kazuaki 
Published: March 2016

AbstractAmong a number of synthesized perfluoro‐1,2‐diarylcyclopentenes, PFC catalyzes the homocoupling of aryl, benzyl, and α‐phenylvinyl Grignard substrates with the highest yields.
ChemInform Abstract: Carboxylative Coupling Reaction of Five‐Membered (Chloromethyl)heteroarenes with Allyltributylstannane Catalyzed by Palladium Nanoparticles.
Authors: Sun Jian , Bao Ming , Feng Xiujuan , Yu Xiaoqiang , Yamamoto Yoshinori , Almansour Abdulrahman I. , Arumugam Natarajan , Kumar Raju Suresh 
Published: March 2016

AbstractThe precatalyst Pd(acac)2 reacts with stannane (II) in the presence of the stabilizer Bu4NBr to furnish palladium nanoparticles which catalyze the three‐component coupling to afford β,γ‐unsaturated esters.
ChemInform Abstract: One‐Pot Asymmetric Synthesis of Cyclopropanes with Quaternary Centers Starting from Bromonitroalkenes under Aminocatalytic Conditions.
Authors: Luis‐Barrera Javier , Mas‐Balleste Ruben , Aleman Jose 
Published: March 2016

AbstractA novel approach towards the title compounds is presented, using bromonitrostyrenes as starting materials instead of the established synthesis with bromine‐activated methylene derivatives.
ChemInform Abstract: Mechanism‐Driven Elaboration of an Enantioselective Bromocyclopropanation Reaction of Allylic Alcohols.
Authors: Taillemaud Sylvian , Diercxsens Nicolas , Gagnon Alexandre , Charette Andr� B. 
Published: March 2016

AbstractSpectroscopic studies to monitor the formation of transient intermediates lead to the development of a more‐atom‐economical halocyclopropanation reaction and also highlight the unique role of the ether additives in the process.
ChemInform Abstract: Synthesis of Highly Strained Bicyclic[3.n.1]alkenes by a Metal‐Catalyzed Conia‐ene Reaction.
Authors: Kallepu Shivakrishna , Gollapelli Krishna Kumar , Nanubolu Jagadeesh Babu , Chegondi Rambabu 
Published: March 2016

AbstractThe Conia‐ene reaction of 2‐acetylenic ketones (I) and (III) enables the synthesis of a wide variety of bicyclic systems, e.g. (II) and (IV), via an efficient 6‐endo‐dig‐cyclization protocol.
ChemInform Abstract: Direct Alkylation of Amines with Alcohols Catalyzed by Base.
Authors: Li Qiang‐Qiang , Xiao Zu‐Feng , Yao Chuan‐Zhi , Zheng Hong‐Xing , Kang Yan‐Biao 
Published: March 2016

AbstractBoth sulfonamides and arylamines are alkylated with alcohols and a novel hemiaminal model is proposed as the possible intermediate.
ChemInform Abstract: A Mild and Efficient Amide Formation Reaction Mediated by P(OEt)3 and Iodine.
Authors: Chen Pei‐Jiang , Wang Hai‐Yang , Peng Ai‐Yun 
Published: March 2016

AbstractCarboxylic acids react with various primary and secondary amines affording a range of amides, including peptides without racemization.
ChemInform Abstract: An Effective Method for the Construction of Esters Using Cs2CO3 as Oxygen Source.
Authors: Ren Lanhui , Wang Lianyue , Lv Ying , Li Guosong , Gao Shuang 
Published: March 2016

AbstractThe scalable reaction is based on the transformation of acylchlorides with alkyl halogenides and has a broad substrate scope, thus affording functionalized products in high yields.
ChemInform Abstract: A Diphenyl Ether Derived Bidentate Secondary Phosphine Oxide as a Preligand for Nickel‐Catalyzed C—S Cross‐Coupling Reactions.
Authors: Wellala Nadeesha P. N. , Guan Hairong 
Published: March 2016

AbstractA new bidentate secondary phosphine oxide, only the second of the kind bearing a covalent backbone, is synthesized from diphenyl ether via ortho‐lithiation, phosphorylation with PhP(Cl)NEt2, and hydrolysis in an acidic medium.
ChemInform Abstract: Synthesis of α,α‐Disulfenylated Aldehydes via Oxidative Transformation of Tertiary Amines.
Authors: Huang Xin , Wang Jichao , Ni Zhangqin , Wang Sichang , Pan Yuanjiang 
Published: March 2016

AbstractThe reaction proceeds regioselectively in modest to good yields with thiophenols only.
ChemInform Abstract: Palladium‐Catalyzed Intermolecular Carbene Insertion Prior to Intramolecular Heck Cyclization: Synthesis of 2‐Arylidene‐3‐aryl‐1‐indanones.
Authors: Arunprasath Dhanarajan , Muthupandi Pandi , Sekar Govindasamy 
Published: March 2016

AbstractTosylhydrazones from arylaldehydes and 2‐iodochalcones react under Pd catalysis to give the title compounds in high yields.
ChemInform Abstract: Copper‐Catalyzed Formation of α‐Alkoxycycloalkenones from N‐Tosylhydrazones.
Authors: Su Naijing , Theorell Juliana A. , Wink Donald J. , Driver Tom G. 
Published: March 2016

AbstractReadily available N‐tosylhydrazones bearing an ortho alkene part with pendant ester substituent are subjected to conditions A).
ChemInform Abstract: Palladium‐Catalyzed Dearomative Cyclization by a Norbornene‐Mediated Sequence: A Route to Spiroindolenine Derivatives.
Authors: Wu Xin‐Xing , Shen Yi , Chen Wen‐Long , Chen Si , Xu Peng‐Fei , Liang Yong‐Min 
Published: March 2016

AbstractAn unprecedented tandem ortho‐alkylation dearomative cyclization reaction, leading to a new class of spirocyclic indolenine derivatives (IV) bearing an all‐carbon quaternary spirocenter is developed.
ChemInform Abstract: Stereodivergent Synthesis of N‐Heterocycles by Catalyst‐Controlled, Activity‐Directed Tandem Annulation of Diazo Compounds with Amino Alkynes.
Authors: Liu Kai , Zhu Chenghao , Min Junxiang , Peng Shiyong , Xu Guangyang , Sun Jiangtao 
Published: March 2016

AbstractThe title reaction is carried out under conditions A), B), and C) to produce 2,3‐dihydropyrroles, 2‐methylene pyrrolidines as (E)‐isomers, and 3‐methylene pyrrolidines, respectively.
ChemInform Abstract: Asymmetric [3 + 2] Annulation Approach to 3‐Pyrrolines: Concise Total Syntheses of (‐)‐Supinidine, (‐)‐Isoretronecanol, and (+)‐Elacomine.
Authors: Chogii Isaac , Njardarson Jon T. 
Published: March 2016

AbstractThe asymmetric [3 + 2] annulation reaction of Ellman imines with ester (I) yields enantiopure 3‐pyrroline products.
ChemInform Abstract: Synthesis of Functionalized Pyrazoles via Vanadium‐Catalyzed C—N Dehydrogenative Cross‐Coupling and Fluorescence Switch‐On Sensing of BSA Protein.
Authors: Sar Dinabandhu , Bag Raghunath , Yashmeen Afsana , Bag Subhendu Sekhar , Punniyamurthy Tharmalingam 
Published: March 2016

AbstractAlkenyl hydrazones are generated in‐situ from alkenyl ketones and arylhydrazines and give pyrazoles using commercially available, nontoxic, and recyclable VOSO4 as the catalyst and air as the oxidant.
ChemInform Abstract: Reversal of Diastereoselection in the Conjugate Addition of Cuprates to Unsaturated Lactams.
Authors: Wright Stephen W. , Choi Chulho , Chung Seungwon , Boscoe Brian P. , Drozda Susan E. , Mousseau James J. , Trzupek John D. 
Published: March 2016

AbstractPyroglutaminol‐derived bicyclic α,β‐unsaturated lactams in which the aminal moiety originates from ketones afford products from syn‐conjugate addition whereas the corresponding lactams with an aldehyde‐derived aminal moiety deliver anti‐conjugate products.
ChemInform Abstract: An Efficient Copper‐Catalyzed One‐Pot Synthesis of 1‐Aryl‐1,2,3‐triazoles from Arylboronic Acids in Water under Mild Conditions.
Authors: Hao Changbo , Zhou Changjian , Xie Jianwei , Zhang Jie , Liu Ping , Dai Bin 
Published: March 2016

AbstractThe procedure involves an one‐pot two‐step 1,3‐dipolar cycloaddition reaction of various aryl boronic acids, sodium azide followed with terminal alkynes under environmentally friendly reaction conditions.
ChemInform Abstract: Lewis Acid Catalyzed Tandem Polycyclization of Internal Alkynols and Vinyl Azides.
Authors: Siyang Hai Xiao , Ji Xiao Yue , Wu Xu Rui , Wu Xin Yan , Liu Pei Nian 
Published: March 2016

AbstractVarious [2‐(arylethinyl)phenyl]methanols are reacting with 1‐(1‐azidovinyl)arenes and hetarenes to deliver polycyclic pyran‐based indeno[1,2‐c]isochromene scaffolds in moderate to high yields.
ChemInform Abstract: Sequential Morita—Baylis—Hillman/Achmatowicz Reactions: An Expeditious Access to Pyran‐3(6H)‐ones with a Unique Substitution Pattern.
Authors: Guidotti Bruno B. , Coelho Fernando 
Published: March 2016

AbstractA simple and straightforward approach to the synthesis of hydroxy‐2H‐pyranones with a unique substitution pattern is described.
ChemInform Abstract: Cp*Co(III)‐Catalyzed Annulations of 2‐Alkenylphenols with CO: Mild Access to Coumarin Derivatives.
Authors: Liu Xu‐Ge , Zhang Shang‐Shi , Jiang Chun‐Yong , Wu Jia‐Qiang , Li Qingjiang , Wang Honggen 
Published: March 2016

AbstractThe reaction is successfully applied in the syntheses of the natural products herniarin (Vc) and seselin (IX).
ChemInform Abstract: Efficient One‐Pot Access to 2,9‐Dihydrothiopyrano[2,3‐b]indole Scaffolds Showing Large Stokes Shifts.
Authors: Singh Shivendra , Samanta Sampak 
Published: March 2016

AbstractThe title compounds are efficiently obtained by a three‐component tandem reaction of N‐protected formylindoles, sodium hydrosulfide, and β‐substituted nitroolefins or δ‐substituted nitrodienes using DABCO as organocatalyst and subsequent dehydration in the presence of activated molecular sieves.
ChemInform Abstract: Iodine‐Catalyzed Aerobic Oxidative Formal [4 + 2] Annulation for the Construction of Polyfunctionalized Pyridines.
Authors: Zhu Chunyin , Bi Benwei , Ding Ya , Zhang Te , Chen Qiu‐Yun 
Published: March 2016

AbstractTri‐ and tetrasubstituted pyridines are conveniently prepared by iodine‐catalyzed formal [4 + 2] cycloaddition of α,β‐unsaturated carbonyl compounds, ammonium acetate, and ketones or aldehydes using molecular oxygen as oxidant.
ChemInform Abstract: Ruthenium‐Porphyrin‐Catalyzed [4 + 2] Cycloaddition of α,β‐Unsaturated Imines and Aldehydes.
Authors: Maeda Kazuki , Terada Takuma , Iwamoto Takahiro , Kurahashi Takuya , Matsubara Seijiro 
Published: March 2016

AbstractThe title reaction affords unsymmetrically substituted dihydropyridines, which cannot be prepared by conventional methods.
ChemInform Abstract: Oxidative Cross‐Coupling of sp3‐ and sp2‐Hybridized C—H Bonds: Vanadium‐Catalyzed Aminomethylation of Imidazo[1,2‐a]pyridines.
Authors: Kaswan Pinku , Porter Ashley , Pericherla Kasiviswanadharaju , Simone Marissa , Peters Sean , Kumar Anil , DeBoef Brenton 
Published: March 2016

AbstractIn addition to the coupling of substituted imidazo[1,2‐a]pyridines with N‐methylmorpholine oxide, the corresponding coupling of indoles is successfully performed.
ChemInform Abstract: Regioselective Palladium(II)‐Catalyzed Aerobic Oxidative Heck‐Type C3 Alkenylation of Sulfocoumarins.
Authors: Kim Namhoon , Min Minsik , Hong Sungwoo 
Published: March 2016

AbstractAn efficient method for the regioselective C—H olefination of sulfocoumarins with a wide range of alkenes is developed using O2 as the sole oxidant.
ChemInform Abstract: Graphene Oxide (GO) or Reduced Graphene Oxide (rGO): Efficient Catalysts for One‐Pot Metal‐Free Synthesis of Quinoxalines from 2‐Nitroaniline.
Authors: Roy Babli , Ghosh Sujit , Ghosh Pranab , Basu Basudeb 
Published: March 2016

AbstractReduced graphene oxide is an equally effective catalyst.
ChemInform Abstract: Iodine(III)‐Mediated Construction of the Dibenzoxazepinone Skeleton from 2‐(Aryloxy)benzamides Through Oxidative C—N Formation.
Authors: Guo Xuliang , Zhang‐Negrerie Daisy , Du Yunfei 
Published: March 2016

AbstractThe title procedure tolerates a wide range of functional groups and proceeds under transition‐metal‐free and mild reaction conditions.
ChemInform Abstract: Aniline Dearomatization and Silver‐Catalyzed [3 + 3] Dipolar Cycloaddition: Efficient Construction of Oxocino[4,3,2‐cd]indoles from 2‐Alkynylanilines and 2‐Alkynylbenzaldoximes.
Authors: Han Dandan , He Qiuqin , Fan Renhua 
Published: March 2016

AbstractThe approach involves an oxidative dearomatization of 2‐alkynylanilines, a silver‐catalyzed [3+3] cycloaddition with 2‐alkynylbenzaldoximes, and a subsequent thermal radical skeletal rearrangement and aromatization.
ChemInform Abstract: Reductive Transformation of CO2 with Hydrosilanes Catalyzed by Simple Fluoride and Carbonate Salts.
Authors: Motokura Ken , Naijo Masaki , Yamaguchi Sho , Miyaji Akimitsu , Baba Toshihide 
Published: March 2016

AbstractThe method is suitable for the synthesis of silyl formate and formamide derivatives.
ChemInform Abstract: Pd(0)‐Catalyzed Carbene Insertion into Si—Si and Sn—Sn Bonds.
Authors: Liu Zhenxing , Tan Haocheng , Fu Tianren , Xia Ying , Qiu Di , Zhang Yan , Wang Jianbo 
Published: March 2016

AbstractThe first Pd‐catalyzed carbene insertion into Si—Si and Sn—Sn bonds is presented by using N‐tosylhydrazones as carbene precursors.
ChemInform Abstract: Sustainable Synthesis of Chiral Tetrahydrofurans Through the Selective Dehydration of Pentoses.
Authors: Foster Robert W. , Tame Christopher J. , Bucar Dejan‐Kresimir , Hailes Helen C. , Sheppard Tom D. 
Published: March 2016

AbstractThe reaction of pentoses such as arabinose (I) with 1,1‐dimethylhydrazine leads to open‐chain hydrazones [cf.
ChemInform Abstract: Synthesis of α‐Chiral Butyrolactones by Highly Stereoselective Radical Transfer or Sequential Asymmetric Alkylations: Concise Preparation of Leupyrrin Moieties.
Authors: Schrempp Michael , Thiede Sebastian , Herkommer Daniel , Gansaeuer Andreas , Menche Dirk 
Published: March 2016

AbstractTwo novel stereoselective methods are reported for the synthesis of chiral butyrolactones (VIII)/(IX) and (XVI).
ChemInform Abstract: Phialomustin A—D, New Antimicrobial and Cytotoxic Metabolites from an Endophytic Fungus, Phialophora mustea.
Authors: Nalli Yedukondalu , Mirza Dania N. , Wani Zahoor A. , Wadhwa Bhumika , Mallik Fayaz A. , Raina Chand , chaubey Asha , Riyaz‐Ul‐Hassan Syed , Ali Asif 
Published: March 2016

AbstractPhialomustin A (Ia), B (II), C (Ib), and D (III) are isolated and screened for their antifungal and cytotoxic potential.