bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Intercalation in the Linear‐Chain Compound MoO2HPO4·H2O.
Authors: GILSON T. R. , WELLER M. T. 
Published: May 2016

AbstractThe one‐dimensional title material is shown to undergo reversible intercalation reactions with H2O, MeOH, EtOH, and Me2CHOH to form crystalline phases in which the molybdenyl phosphate double chains of the host structure remain essentially unaltered.
ChemInform Abstract: Formation of the Metal‐Sulfide Aggregate (W3S10)2‐ Through a Novel Balanced Intramolecular Condensation Redox Process with Principal Relevance to the Formation of Amorphous Metal Sulfides Like WS3.
Authors: MUELLER A. + , DIEMANN E. , WIENBOEKER U. + , BOEGGE H. + 
Published: May 2016

AbstractA novel isopoly anion (W3S10)2‐ containing the hitherto unknown ligand (WS5)2‐ is obtained in the mixed‐crystal compounds (I), (II) and (III) by controlled acidification of a methanolic solution of (NH4)2(WS4) with gaseous HCl.
ChemInform Abstract: Electroreductive Coupling of Trifluoromethylarenes with Electrophiles: Synthetic Applications.
Authors: SABOUREAU C. , TROUPEL M. , SIBILLE S. , PERICHON J. 
Published: May 2016

AbstractElectrolysis of the trifluoromethylarenes (I) in the presence of carbon dioxide (II) or N,N‐dimethylformamide (VII) followed by treatment with methanol (III) or acetic anhydride (VIII) results in the formation of the methyl esters (IV) or the diacetates (IX).
ChemInform Abstract: The Scope and Mechanism of Rearrangement of 4,6‐Dialkoxy‐2‐pyrones.
Authors: VENKATARAMAN H. , CHA J. K. 
Published: May 2016

AbstractThe carboxymethyldihydropyrancarboxylates (I) are subjected to acidic cleavage of the ester group and then cyclized upon treatment with acetic anhydride.
ChemInform Abstract: Thermolysis of N‐Benzyl‐2,2‐dichlorocyclopropanecarboxaldimines: A Novel Ring Enlargement to 2‐Phenylpyridines.
Authors: KAGABU S. , NARUSE S. , TAGAMI Y. , WATANABE Y. 
Published: May 2016

AbstractThe thermolysis of the title compounds (I) is catalyzed by tungsten(VI) oxide to give the pyridines (II) and (III).
ChemInform Abstract: Design and Synthesis of 4‐Oxoquinolin‐2‐yl‐6‐heptenoic Acid Derivatives as HMG‐CoA Reductase Inhibitors.
Authors: COPPOLA G. M. , SCALLEN T. J. , DELPRETE A. , MONTANO R. 
Published: May 2016

AbstractThe isatoic anhydride (I) undergoes cyclization reaction with the dianions of the β‐keto phosphonates (II) to produce the dihydroquinolinones (III) which are converted into the diols (IX) and (X) via the α,β‐unsaturated aldehydes (VI).
ChemInform Abstract: Synthesis of Hydroxy‐ and Methoxy‐Substituted Octahydrobenzo(g)isoquinolines as Potential Ligands for Serotonin Receptors.
Authors: PAPAGEORGIOU C. , PETCHER T. J. , WALDVOGEL E. 
Published: May 2016

AbstractThe 9‐methoxy‐ (VIIa) and the 6‐methoxysubstituted octahydrobenzoisoquinolines (VIIb), their hydroxy analogues (VIIIa) and (VIIIb) and their N‐alkyl derivatives (X) and (XI), resp., are tested for their activity as serotonine‐like ligands.
ChemInform Abstract: Imidazole Derivatives. Part 2. Synthesis of Imidazo(1,2‐a)pyridin‐5‐ones.
Authors: KNOELKER H.‐J. + , BOESE R. , HITZEMANN R. 
Published: May 2016

AbstractBenzoylation of 2‐methylimidazole (I) with benzoyl chloride (II) results in the formation of the vinyl ester (III) which is hydrolyzed with acids to yield 2‐phenacylimidazole (IV).
ChemInform Abstract: Dithiatetrazocines and Dithiadiazolium Salts.
Authors: AMIN M. , REES C. W. 
Published: May 2016

AbstractTreatment of benzamidine (I) or 2‐thienylamidine (IX) with sulfur dichloride (II) results in cyclization, forming the diphenyldithiatetrazocine (III) or the thienyldithiadiazolium chloride (X) as the major products.
ChemInform Abstract: A New Phosphorylation Method via O‐Diethylboryl Intermediates.
Authors: DAHLHOFF W. V. , TABA K. M. 
Published: May 2016

AbstractDiphenylchlorophosphine and diethylchlorophosphite (I) react with acetylacetone (II) to generate intermediate phosphine enolates (III) which are quenched with the O‐diethylboryl derivatives (IV) and then oxidized with H2O2 to give the diphenylphosphinates and diethylphosphates (V).
ChemInform Abstract: Synthetic and Structural Studies of a Series of Soluble Cerium(IV) Alkoxide and Alkoxide Nitrate Complexes.
Authors: EVANS W. J. , DEMING T. J. , OLOFSON J. M. , ZILLER J. W. 
Published: May 2016

AbstractThe reactions of (NH4)2Ce(NO3)6 with 2‐8 equiv. of NaOtBu in THF, leading to a series of complexes (I) (56‐82% yield) and (II) (65% yield), are studied.
ChemInform Abstract: ((Cp′(CO)2Mn)2PbStBu)‐; Completion of an Isoelectronic Series of Binuclear Complexes with Trigonal‐Planar Coordinated Main Group Elements.
Authors: ETTEL F. , HUTTNER G. , ZSOLNAI L. 
Published: May 2016

AbstractIt is shown that also an element of the fourth main group can function as a central atom in complexes of type (III), which hitherto was known only for elements of the fifth and sixth main group.
ChemInform Abstract: Effect of Steric Crowding on the Rates of Reactions of a Nickel(I) Tetraaza Macrocycle with Organic Halides and Hydroperoxides.
Authors: SADLER N. , SCOTT S. L. , BAKAC A. , ESPENSON J. H. , RAM M. S. 
Published: May 2016

AbstractThe reactions of the sterically crowded complex (I) with organic halides, H2O2 and tBu‐O‐OH occur some 104 times more slowly than the corresponding reactions of (II).
ChemInform Abstract: Application of the Dimethyl(phenyl)silyl Group as a Masked Form of the Hydroxy Group in the Synthesis of an L‐Glycero‐D‐manno‐heptopyranoside‐Containing Trisaccharide from the Dephosphorylated Inner Core Region of Neisseria meningitidis.
Authors: BOONS G. J. P. H. , OVERHAND M. , VAN DER MAREL G. A. , VAN BOOM J. H. 
Published: May 2016

AbstractAn efficient route to immunologically relevant oligosaccharides of type (VIII) makes use of the SiMe2Ph group which functions thereby as an equivalent of a protected hydroxy function.
ChemInform Abstract: Total Synthesis of Allonojirimycin (5‐Amino‐5‐deoxy‐D‐allopyranose).
Authors: AUBERSON Y. , VOGEL P. 
Published: May 2016

AbstractThe stereospecific synthesis of the title compound (XII), which is of interest as a glucosidase inhibitor, starts with the educt (III) which is converted to the ketone (IV) with recovery of the chiral auxiliary.
ChemInform Abstract: Natural Products from Medicinal Plants. Part 25. Isolation and Structure Determination of New Compounds from the Aqueous Sodium Carbonate Extract of Picrorhiza kurrooa.
Authors: WEINGES K. , SCHICK H. , NEUBERGER K. , ZIEGLER H. J. , LICHTENTHAELER J. + , IRNGARTINGER H. 
Published: May 2016

AbstractAcetylation of the title extract leads to the seven novel crystalline acetates (I)‐(V) (space group P212121 with Z=4) and three known catalpol derivatives.
ChemInform Abstract: Chemical Vapor Deposition in the System Ti‐N‐B: TiN as a Diffusion Barrier for Boron.
Authors: BECHT J. G. M. , VAN DER PUT P. J. , SCHOONMAN J. 
Published: May 2016

AbstractIn addition to a review of the phase relations in the Ti‐N‐B system, results of a study of the interactions between TiN and B under CVD conditions are reported.
ChemInform Abstract: Synthesis of Surface Nitride on Pd(100) Surface by a Reaction of NO with H2.
Authors: MATSUO I. , NAKAMURA J. , HIRANO H. , YAMADA T. , TANAKA K. , TAMARU K. 
Published: May 2016

AbstractFor the first time, a c(2 · 2) overlayer of surface nitride is synthesized on a Pd(100) surface by catalytic reaction of NO and H2 at 500‐600 K and several torr (e.g.
ChemInform Abstract: Active Sites of Molybdenum Sulfide Catalysts Supported on Al2O3 and TiO2 for Hydrodesulfurization and Hydrogenation.
Authors: OKAMOTO Y. , MAEZAWA A. , IMANAKA T. 
Published: May 2016

AbstractThe results of laser Raman spectroscopy and XPS reveal that sulfided MoO3/Al2O3 catalysts consist of MoS2‐like phases and Mo(V) species, while sulfided MoO3/TiO2 catalysts are completely sulfided to MoS2‐like phases.
ChemInform Abstract: Structure and Reactivity of Oxovanadate Anions in Layered Lithium Aluminate Materials.
Authors: TWU J. , DUTTA P. K. 
Published: May 2016

AbstractThe ion exchange of vanadate ions from aqueous solution into (LiAl2(OH)6)+ is studied over a wide pH range (XRD, diffuse reflectance, and Raman spectroscopy).
ChemInform Abstract: Preparation of the Ordered Perovskite (SrLa)(MgMo)O6 and Its Physicochemical Characterization.
Authors: CHOY J.‐H. , HONG S.‐T. 
Published: May 2016

AbstractThe title compound is prepared by thermal treatment (1350 °C, flowing N2, alumina boat) of a pelletized oxide mixture prepared from stoichiometric amounts of Sr(NO3)2, La(NO3)3·6 H2O, Mg(NO3)2·6 H2O and MoO3.
ChemInform Abstract: Diels‐Alder and Ene Reactions of Nitrosyl Hydride and Nitrosoformaldehyde.
Authors: ENSLEY H. E. , MAHADEVAN S. 
Published: May 2016

AbstractFormylhydroxamic acid (I) undergoes periodate oxidation in the presence of 9,10‐dimethylanthracene (II) to give the cycloaddition product (III) which is deformylated with anhydrous ammonia, forming the compound (IV).
ChemInform Abstract: Oxidative Transformations of 4‐(ω‐Hydroxyalkyl)‐2,6‐di‐tert‐butylphenols.
Authors: KRYSIN A. P. , FEDORENKO A. N. 
Published: May 2016

AbstractOxidation of the sterically hindered phenols (Ia) and (Ib) produces the quinone methides (IIa) and (IIb) which are transformed into oligomers on storage.
ChemInform Abstract: The Vinylcyclopropane Moiety as an Efficient Intramolecular Trap for Carbocations. A High Yield Process for the Formation of Eleven‐Membered Carbocyclic Structures.
Authors: GASSMAN P. G. , RIEHLE R. J. 
Published: May 2016

AbstractThe unsaturated carboxylic acid ester (I) is converted to the vinyl cyclopropane (XII) as outlined in the reaction scheme.
ChemInform Abstract: Carbon Silicon Bond Cleavage in the Oxidation of Benzylic Silanes by Cerium(IV) Ammonium Nitrate.
Authors: BACIOCCHI E. , DEL GIACCO T. , ROL C. , SEBASTIANI G. V. 
Published: May 2016

AbstractThe substituted benzyltrimethylsilanes (I) react with ceric ammonium nitrate (II) in acetic acid (III) to give mixtures of the nitrates (IV) and the acetates (V).
ChemInform Abstract: Rhodium‐Catalyzed C‐C Coupling Reactions Involving Ring Opening of Strained Molecules. Part 3. Reaction of N‐Allylamides of Organic Acids.
Authors: CHIUSOLI G. P. , COSTA M. , PIVETTI F. 
Published: May 2016

AbstractCoupling of (diphenylmethylene)cyclopropane (I) with the N‐allylamides (II) in the presence of RhCl(PPh3)3 leads to the formation of mixtures of the isomeric N‐dienylamides (III) ‐ (V).
ChemInform Abstract: Ring Transformations of 2‐Phenacylidenimidazolidines: Synthesis of 5‐(β‐Aminoethyl)anilinopyrazoles and 2‐Acyl‐3‐(β‐aminoethyl)aminothiophenes.
Authors: DANNHARDT G. , LAUFER S. 
Published: May 2016

AbstractThe synthesis of pyrazoles mentioned in the title, e.g. (III), is achieved by reaction of 2‐(acylmethylen)imidazolidines such as (I) with hydrazinium sulfate (II).
ChemInform Abstract: Some Reactions of 2‐Mercapto‐3,5,7‐triphenylpyrido(2,3‐d)pyrimidin‐4(3H)‐one Synthesis of Pyridotriazolo and Pyridotetrazolopyrimidine Derivatives.
Authors: YOUSSEF M. S. K. , EL‐ZOHRY M. F. , HASSAN K. M. , ABO EL‐WAFA R. 
Published: May 2016

AbstractCyclocondensation of the 2‐hydrazinopyrido(2,3‐d)pyrimidinone (III), generated from the compound (I) by reaction with hydrazine hydrate (II), with the carboxylic acids (IV) produces the pyridotriazolopyrimidinones (V).
ChemInform Abstract: 2,2′,7,7′‐Tetrahydroxy‐1,1′‐Binaphthyl: A Versatile Chiral Spacer for Monotopic and Ditopic Cyclophane Hosts with Apolar Binding Sites.
Authors: HESTER M. R. , UYEKI M. A. , DIEDERICH F. 
Published: May 2016

AbstractThe two novel chiral cyclophanes (III) are prepared via regioselective coupling of the benzyloxynaphthol (I) to give the major groove‐protected binaphthol (II), which is converted to the title compounds by common methods.
ChemInform Abstract: Catalytic Cyclophanes. Part 4. Supramolecular Catalysis of Benzoin Condensations by a Thiazolium Cyclophane.
Authors: DIEDERICH F. , LUTTER H.‐D. 
Published: May 2016

AbstractAs a model for thiamine pyrophosphate dependent ligases, the thiazolium‐bridged cyclophane (VI) is prepared as shown in the scheme starting from the compound (I) which, in turn, is readily obtained from a known tetraoxaparacyclophane precursor.
ChemInform Abstract: Organo‐Polylithium Compounds. Part 11. Two Stable Conformational Isomers of 1,4‐Disila(6)radialene, Twist and Chair, Which do not Interconvert at Room Temperature.
Authors: MAERCKER A. , BRAUERS F. , BRIEDEN W. , ENGELEN B. 
Published: May 2016

AbstractThe reactions of the dichlorosilanes (II) and (V) with the dilithium compound (I) yield 1,4‐disila(6)radialenes as the two stable conformational chair and twist isomers (III) and (IV) as well as (VI) and (VII), which do not interconvert at room temperature.
ChemInform Abstract: Characterization and Properties of Some Dialkyl 1‐(N,N‐Dialkylamino)alkylphosphonates and Their Hydrochloride Salts.
Authors: CHARANDABI M. R. M. D. , ETTEL M. L. , KAUSHIK M. P. , HUFFMAN J. H. , MORSE K. W. 
Published: May 2016

AbstractCoupling of the alkyl phosphites (I) with the aldehydes (II) and the dialkylamines (III) produces the phosphonates (IV) which form the corresponding salts (V).
ChemInform Abstract: Substituted 4,5‐Dioxo‐1,3,2λ3,4λ4‐diazadiphospholane and Related Compounds.
Authors: CHEN R.‐U. , CHENG L. 
Published: May 2016

AbstractCyclocondensation of the phosphonoamidate (I) with phenyldichlorophosphine (II) leads to the formation of the 1,3‐diazadiphospholane (III) which is oxidized with DMSO, sulfurated, or treated with 2,3‐butanedione (VI) to yield the derivatives (IV), (V), and (VII) as shown in the reaction scheme.
ChemInform Abstract: Synthesis of (R)‐1,1,2‐Triphenyl‐1,2‐ethanediol‐Derived Phosphonates.
Authors: BRODESSER B. , BRAUN M. 
Published: May 2016

AbstractReaction of (R)‐1,2,2‐triphenyl‐1,2‐ethanediol (III) with methylphosphonic dichloride (II) and subsequent hydrolysis with hydrochloric acid or sodium hydroxide lead to the formation of the methylphosphonic acid ester (I).
ChemInform Abstract: Synthesis and Reactivity of Aminomethyldiphenylphosphine Complexes of Molybdenum. Crystal Structure of cis‐(Mo(CO)4(Ph2PCH2NHC6H4Me‐p)2).
Authors: DAVIES D. L. , HEALEY F. I. , HOWARTH J. , RUSSELL D. R. , SHERRY L. J. S. 
Published: May 2016

AbstractThe phosphines (II) react with the Mo complexes (I) to give the cis‐bis(aminomethylphosphine) complexes (III) ((IIIb): space group P21/c, Z=4).
ChemInform Abstract: Transient Generation of the Reactive Carbene Complex (Cp(CO)2W=CH(Tol))+ and Its Reactions with Alkynes to Form Vinylcarbene, Allyl, Naphthol, Diene, and Metallafuran Complexes.
Authors: GARRETT K. E. , SHERIDAN J. B. , POURREAU D. B. , FENG W. C. , GEOFFROY G. L. , STALEY D. L. , RHEINGOLD A. L. 
Published: May 2016

AbstractAlthough the p‐tolylcarbyne‐W complex (I) does not itself react with alkynes, its protonation product, the title carbene, readily incorporates 1,2‐diphenylacetylene (II) or 1,2‐dimethylacetylene (IX) to give the vinylcarbene complex (III) and the η4‐naphthol complex (XI), respectively.
ChemInform Abstract: Transition‐Metal Ketene Compounds. Part 33. Synthesis of η3‐Phosphino‐, Arsino‐, and Thioketene Complexes of Tungsten.
Authors: WOLFGRUBER M. , STEGMAIR C. M. , KREISSL F. R. 
Published: May 2016

AbstractDicarbonyl(η5‐cyclopentadienyl)carbyne‐W complexes of the type (I) react with halo‐phosphines such as (II), ‐arsines or 2‐nitrobenzenesulfenyl chloride to give the corresponding η3‐coordinated phosphino‐, arsino‐ and thioketene complexes (III) and (IV) as shown for the examples (IIIa) and (IIIb).
ChemInform Abstract: Synthesis and Molecular Structure of a Novel Binuclear Cobalt Carbonyl Complex with Mixed Valence Co0CoI(μ‐Ph2Ppy)2(μ‐CO)(CO)Cl (Ph2Ppy: Diphenylphosphinopyridine).
Authors: ZHANG Z.‐Z. , WANG H.‐K. , XI Z. , YAO X.‐K. , WANG R.‐J. 
Published: May 2016

AbstractReduction of a 1:2 molar mixture of CoCl2·6 H2O (I) and the phosphine ligand (II) in THF in the presence of CO (III) leads to the formation of the title complex (IV) (space group Cc, Z=4).
ChemInform Abstract: The Synthesis of Complexes of Novel Structurally Reinforced Tetraazamacrocyclic Ligands of High Ligand Field Strength. A Structural and Molecular Mechanics Study.
Authors: HANCOCK R. D. , NGWENYA M. P. , WADE P. W. , BOEYENS J. C. A. , DOBSON S. M. 
Published: May 2016

AbstractThe three complexes (V) ( P21/n, Z=4), (VIII) (Pmcn, Z = 8) and (IX) (C2/c, Z = 8) contain novel ligands which have higher ligand‐field strength than the tetraazamacrocycles currently known, generated by means of increasing the donor strength of the nitrogens in a system of low steric strain.
ChemInform Abstract: Synthesis of N6‐Adenosine Adducts Expected from Cyclopenta‐Ring Activation of Acenaphthylene and Aceanthrylene.
Authors: BARTCZAK A. W. , SANGAIAH R. , KELMAN D. J. , TONEY G. E. , DETERDING L. J. , CHARLES J. , MARBURY G. D. , GOLD A. 
Published: May 2016

AbstractAcenaphthenone (I) is converted to a mixture of the trans‐ and cis‐acenaphthenaminols (V) and (VI) with the predominance of (V).
ChemInform Abstract: Total Synthesis of the Triquinane, (.+‐.)‐Silphinene by Means of a Cyclopropene.
Authors: FRANCK‐NEUMANN M. , MIESCH M. , LACROIX E. 
Published: May 2016

AbstractReaction of the cyclopropene (I) with the enamine (II) gives the (2 + 2)cycloadduct (III) as a minor product, together with the cyclopropylcyclopentanone (IV).
ChemInform Abstract: Preparation and Spectroscopic Characterization of Difluorophosphorane, PH3F2. 31P NMR Spectrum of Protonated Diphosphine, P2H+ 5.
Authors: MINKWITZ R. , LIEDTKE A. 
Published: May 2016

AbstractA previously reported procedure to prepare PH3F2 (III) from P2H4 (I) and HF (II) is optimized and convincing evidence for the existence for this fluorophosphorane is obtained (multinuclear (1H, 19F, 31P) NMR, MS, complete IR and Raman low‐temp.
ChemInform Abstract: Highly Diastereoselective Diels‐Alder Reaction of Optically Active 2‐(p‐Tolylsulfinyl)‐2‐cycloalkenones with Cyclopentadiene.
Authors: ALONSO I. , CARRETERO J. C. , GARCIA RUANO J. L. 
Published: May 2016

AbstractThe p‐tolylsulfinylcycloalkenones (I) react with cyclopentadiene (II) to form the Diels‐Alder adducts (III) and (IV) in ratios depending on the Lewis acid catalysts employed.
ChemInform Abstract: Intramolecular C‐H Insertion Reactions of (Cyclopentadienyl)dicarbonyliron Carbene Complexes.
Authors: ZHAO S.‐K. , KNORS C. , HELQUIST P. 
Published: May 2016

AbstractCopper‐promoted addition of the Grignard compounds (II) to the cyclohexenone (I) followed by enolate addition to the known stable thiocarbene complex (III) gives the adducts (IV).
ChemInform Abstract: Acid‐Catalyzed Rearrangement of Spiro(adamantane‐2,1′‐cyclobutane). The Case for a Transannular Alkyl Shift.
Authors: FARCASIU D. , SEPPO E. , KIZIRIAN M. , LEDLIE D. B. , SEVIN A. 
Published: May 2016

AbstractThe title compound (I) is prepared from 2‐methyleneadamantane and dichloroketene (47% yield) with subsequent reductive dechlorination and Wolff‐Kishner reduction (94%).
ChemInform Abstract: High‐Pressure Aminolysis of Lactones to Hydroxy Amides.
Authors: MATSUMOTO K. , HASHIMOTO S. , UCHIDA T. , OKAMOTO T. , OTANI S. 
Published: May 2016

AbstractThe preparation of hydroxyamides such as (III), (V) or (X) is efficiently achieved at 9 kbar at 30 °C or ca. 60 °C from lactones such as (I), (IV), or (VIII) and amines such as (II) or even (IX) which are extremely unreactive compounds.
ChemInform Abstract: Synthesis of New Fluorinated Amphiphiles RF‐CH2CH2CONH2 and RF‐(CH2)n‐CH(CO‐NH2)‐(CH2)m‐RH by Photoamidation of the Corresponding Olefins.
Authors: GAUTIER M. , RICO I. , LATTES A. 
Published: May 2016

AbstractPhotoamidation of several fluorinated olefins such as (I) give the corresponding amides (III) and in the case of 1,2‐disubstituted olefines, the regioisomers (IV).
ChemInform Abstract: Stereoselection in CO Trapping by the 1‐Methyl‐3‐chlorocyclopentyl Cation. Absence of Chlorine Coordination in a γ‐Chloroacyl Cation.
Authors: FARCASIU D. , RICH R. , ROSE K. D. 
Published: May 2016

AbstractChloride‐abstraction from trans‐1,2‐dichlorocyclohexane (I) gives the cyclopentyl cation (II) which is consecutively treated with carbon monoxide (III) and methanol (V) to produce the cis‐ and trans‐cyclopentanecarboxylates (VI) and (VII).
ChemInform Abstract: Scope of the Cobalt‐Catalyzed (2 + 2 + 2) Homo‐Diels‐Alder Reaction.
Authors: LAUTENS M. , CRUDDEN C. M. 
Published: May 2016

AbstractA variety of acetylenes react with norbornadiene (I) to give adducts, e.g. (III).
ChemInform Abstract: A Simple Convenient Method for the Preparation of Difluoromethyl Ethers Using Fluorosulfonyldifluoroacetic Acid as a Difluorocarbene Precursor.
Authors: CHEN Q.‐Y. , WU S.‐W. 
Published: May 2016

AbstractThe aliphatic, fluoroaliphatic, and aromatic alcohols (I) react with the title reagent (II) in the presence of catalytic amounts of sodium sulfate or cuprous iodide to form the corresponding difluoromethyl ethers (III).
ChemInform Abstract: (3.2)Paracyclophane‐10‐enes and (3.2.3.2)Paracyclophane‐10,27‐dienes: A Convenient Synthesis by the McMurry Reaction and Dynamic Stereochemistry.
Authors: GRUETZMACHER H.‐F. + , NEUMANN E. , EBMEYER F. , ALBRECHT K. , SCHELENZ P. 
Published: May 2016

AbstractCyclization of the bis(4‐acylphenyl)propanes (I) by reductive coupling with low‐valent titanium (McMurry reaction) can be directed either to the (3.2)paracyclophanenes (II) or to the (3.2.3.2)paracyclophanedienes (III).
ChemInform Abstract: A Cycloisomerization Approach to Tetrahydrofurans.
Authors: TROST B. M. , ESTROM E. D. , CARTER‐PETILLO M. B. 
Published: May 2016

AbstractPd(II)‐catalyzed ring closure of the allyl propargyl ethers (I) and (III) yields the tetrahydrofurans (II) and (IV).
ChemInform Abstract: Syntheses and Structures of Indolo(6,7‐g)indoles, a New Heteroaromatic System.
Authors: NAGAWA Y. , GOTO M. , HONDA K. , NAKANISHI H. 
Published: May 2016

AbstractPhotolysis of the bis‐triazolonaphthalenes (I) yields the isolable triazolylbenzindoles (II), which are characterized by their IR, UV and MS data.
ChemInform Abstract: Synthesis and Evaluation of N,N‐Di(n‐propyl)tetrahydrobenz(f)indol‐7‐amine and Related Congeners as Dopaminergic Agonists.
Authors: NICHOLS D. E. , CASSADY J. M. , PERSONS P. E. , YEUNG M. C. , CLEMENS J. A. , SMALSTIG E. B. 
Published: May 2016

AbstractThe dopaminergic activity of the indole (VII), the tetrahydrobenzindole (XIX), and of the related compounds (IX) and (XXI), synthesized as shown in the reaction scheme, is evaluated.
ChemInform Abstract: Azoles. Part 25. Isomeric 3‐ and 5‐Aminopyrazole Derivatives.
Authors: BERNARD M. K. , WRZECIONO U. , KOEHLER T. + , NUHN P. 
Published: May 2016

AbstractReaction of the β‐chlorocinnamic acid nitriles (I) with methylhydrazine (II) leads to the formation of the pyrazoles (III) and (IV).
ChemInform Abstract: Pecularities in (2 + 3)Cycloaddition Reactions of Trifluoroacetonitrile Oxide.
Authors: TRUSKANOVA T. D. , VASIL'EV N. V. , GONTAR' A. F. , KOLOMIETS A. F. , SOKOL'SKII G. A. 
Published: May 2016

AbstractTrifluoroacetonitrile oxide, formed in situ from the hydroximoyl chloride (I), is coupled with the dipolarophiles (II), (IV), (VII), or (IX) to give the isoxazoles (III), (V), (VI), and (VIII) or the oxadiazole (X).
ChemInform Abstract: New Anticancer Agents: Chiral Isomers of Ethyl 5‐Amino‐1,2‐dihydro‐2‐methyl‐3‐phenylpyrido(3,4‐b)pyrazine‐7‐carbamate.
Authors: TEMPLE C. JUN. , RENER G. A. 
Published: May 2016

AbstractThe enantiomerically pure (R)‐ and (S)‐pyrido(3,4‐b)pyrazine derivatives (V) are prepared from the pyridine compound (I) and (+)‐ or (‐)‐norephedrine (II) as shown in the reaction scheme.
ChemInform Abstract: Crystal Structure and Photochemical Behavior of 2,2,4,6‐Tetraphenyldihydro‐1,3,5‐triazine and Its Inclusion Compounds.
Authors: MORI Y. , OHASHI Y. , MAEDA K. 
Published: May 2016

AbstractThe title compound (I), which displays photocoloration, is known to form 1:1 inclusion compounds such as e.g. (II), which are photostable as e.g. (II) or photolabile, depending on the included species of molecules.