bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthetic Inorganic Ion‐Exchange Materials. Part 58. Hydrothermal Synthesis of a New Layered Lithium Titanate and Its Alkali Ion Exchange.
Authors: SUGITA M. , TSUJI M. , ABE M. 
Published: May 2016

AbstractThe new inorganic ion exchanger (Li1.81, H0.19)Ti2O5·2.2 H2O is synthesized by hydrothermal reaction of hydrous TiO2 with LiOH solution at 190 °C. The layered compound crystallizes in a C‐based orthorhombic system.
ChemInform Abstract: Morphology and Activity of MoS2 on Various Supports: Genesis of the Active Phase.
Authors: PRATT K. C. , SANDERS J. V. , CHRISTOV V. 
Published: May 2016

AbstractThe morphology and catalytic activity for the hydrodesulfurization of thiophene of unpromoted MoS2 supported on Al2O3, SiO2, TiO2, and ZrO2 are studied.
ChemInform Abstract: Free Energies of Electron Attachment to Tris(acetylacetonate) and Tris(hexafluoroacetylacetonate) Transition‐Metal Complexes in the Gas Phase: Experimental Results and Ligand Field Analysis.
Authors: SHARPE P. , EYLER J. R. , RICHARDSON D. E. 
Published: May 2016

AbstractThe results of Fourier transform ion cyclotron resonance mass spectrometry of the thermochemistry of electron attachment to gas‐phase title complexes are discussed.
ChemInform Abstract: Bond Strengths of Ethylene and Acetylene.
Authors: ERVIN K. M. , GRONERT S. , BARLOW S. E. , GILLES M. K. , HARRISON A. G. , BIERBAUM V. M. , DEPUY C. H. , LINEBERGER W. C. , ELLISON G. B. 
Published: May 2016

AbstractNegative ion photoelectron spectroscopy and gas‐phase proton transfer kinetics are employed to determine the CH bond dissociation energies of HC≡CH, H2C=CH2, and vinyl radical.
ChemInform Abstract: Single‐Atom NCS Bridging in Binuclear Complexes of MnII, FeII, CoII, NiII, and CuII of Macrocyclic 20‐ and 22‐Membered Ligands: A Spectroscopic, Crystallographic, and Molecular Mechanics Study.
Authors: HARDING C. , MCDOWELL D. , NELSON J. , RAGHUNATHAN S. , STEVENSON C. , DREW M. G. B. , YATES P. C. 
Published: May 2016

AbstractUsing the macrocyclic ligands (I) and (II) NCS‐(N)‐bridged binuclear complexes (20 examples, table) of the title metals are obtained by transmetalation reactions of Ba precursor compounds BaL(ClO4)2 (L: (Ia), P21cn, Z=4; L: (Ib), Aa, Z=4).
ChemInform Abstract: Metal‐Amides in Organic Synthesis. Part 7. Stereodivergent Synthesis of the Enolates of a β‐Amino Ester by Using Lithium N‐Benzyltrimethylsilylamide.
Authors: ASAO N. , UYEHARA T. , YAMAMOTO Y. 
Published: May 2016

AbstractThe stereoselective generation of the enolates (III) and (X) is shown by transformation to the corresponding acetals (V) (no yield given) and (XI), respectively.
ChemInform Abstract: Catalytic Asymmetric Induction in the Homo Diels‐Alder Reaction.
Authors: LAUTENS M. , LAUTENS J. C. , SMITH A. C. 
Published: May 2016

AbstractFor the first time a highly enantioselective cobalt‐promoted homo Diels‐Alder reaction is performed using catalytic amounts of external chiral phosphine ligands to give the deltacyclenes (III) with varying enantioselectivities (the e.e.
ChemInform Abstract: The Elusive Methyleneoxirane: Preparation and Characterization by Flash‐Vacuum Pyrolysis and Neutralization‐Reionization Mass Spectrometry.
Authors: TURECEK F. , DRINKWATER D. E. , MCLAFFERTY F. W. 
Published: May 2016

AbstractCollisional activated dissociation of (I) leads to the appearance of the title compound and the radical cation (II).
ChemInform Abstract: Enantio‐ and Diastereoselective Aldol Reactions of Achiral Ethyl and Methyl Ketones with Aldehydes: The Use of Enol Diisopinocampheylborinates.
Authors: PATERSON I. , GOODMAN J. M. , LISTER M. A. , SCHUMANN R. C. , MCCLURE C. K. , NORCROSS R. D. 
Published: May 2016

AbstractEnol diisopinocampheylborinates, derived from achiral ethyl and methyl ketones such as (I) or (IV) in the presence of a base undergo enantio‐ and diastereoselective aldol reactions with aldehydes such as (II) or (V).
ChemInform Abstract: Mechanistic Aspects of Decarboxylation Reactions of Group 10 (PCy3)2M(H)O2CH Derivatives.
Authors: DARENSBOURG D. J. , WIEGREFFE P. , RIORDAN C. G. 
Published: May 2016

AbstractKinetic studies for the 13CO2 exchange reactions of the complexes (I) indicate carbon dioxide extrusion to be rate‐determining, with concomitant formation of the dihydride complex followed by rapid reincorporation of carbon dioxide.
ChemInform Abstract: Hexafluoroacetone Alkoxycarbonylimines.
Authors: KORENCHENKO O. V. , SOKOLOV V. B. , AKSINENKO A. YU. , MARTYNOV I. V. 
Published: May 2016

AbstractThe isocyanate (I) is coupled with the alcohols (II) or (V) to give the urethanes (III) or (VI) and, in the case of ethanol (II), the α‐ethoxy isocyanate (IV).
ChemInform Abstract: Catalytic Transformations of C3‐Cyclic Olefins in the Presence of Metal Complexes. Part 4. Ni Complexes as Catalysts of the (2 + 2)Cyclodimerization of Spiro(2,3)hex‐1‐ene.
Authors: FURMAN D. B. , RUDASHEVSKAYA T. YU. , KUDRYASHEV A. V. , IVANOV A. O. , ISAEVA L. S. , MOROZOVA L. N. , PEGANOVA T. A. , BOGDANOV V. S. , KRAVTSOV D. N. , BRAGIN O. V. 
Published: May 2016

AbstractThe dimerization of the spirohexene (I) to produce the compound (II) is studied in the presence of various nickel complexes.
ChemInform Abstract: Comparative Analysis of Diastereoselection Levels Attainable During Controlled Exo and Endo Addition of Chiral Cyclopentenyl Organometallics to Optically Pure and Racemic 1‐Vinylnorbornan‐2‐ones.
Authors: PAQUETTE L. A. , DERUSSY D. T. , VANDENHESTE T. , ROGERS R. D. 
Published: May 2016

AbstractThe levels of diastereoselection attainable during the addition of the cyclopentenyl organometallics (II) and (VII) to the norbornanones (I) and (VI) are tested.
ChemInform Abstract: Synthesis and Structure‐Activity Relationship of Some New β‐Blocking Agents with Possible α‐Adrenoreceptor Activity.
Authors: BERGMANN J. , TAKACS K. 
Published: May 2016

AbstractThe nitrophenols (I) are coupled with epichlorohydrin (II) to yield the glycidyl ethers (III) which are cleaved with the amines (IV), forming the amino alcohols (V).
ChemInform Abstract: Reaction of o‐Benzoquinone Dioxime with Aldehydes: An Improved Procedure for 1‐Hydroxybenzimidazole‐3‐oxides.
Authors: PAETZOLD F. + , NICLAS H.‐J. , GRUENDEMANN E. + 
Published: May 2016

AbstractThe title compounds (IV) are obtained with isolation of the intermediate salts (III) from the reaction of the dioximes (I) with the aldehydes (II); the derivatives (V) are prepared analogously.
ChemInform Abstract: Asymmetric Synthesis: Modification of Chiral Ferrocenylamine Ligands for the Gold(I)‐Catalyzed Aldol Reaction.
Authors: PASTOR S. D. , TOGNI A. 
Published: May 2016

AbstractMethyl acrylate (II) is treated with excess N,N'‐dimethylethylenediamine (I) to form the β‐aminopropionate (III) which is coupled with the ferrocenylethyl acetate (IV), yielding the chiral amino phosphine complex (V).
ChemInform Abstract: Pecularities in the Heterocyclization of Triketones in the 2‐(3‐Oxopropyl)‐1,3‐cyclohexanedione Series with Hydroxylamine Hydrochloride.
Authors: MARKOVA L. I. , KAZARINOVA T. D. , YUDOVICH L. M. , KHARCHENKO V. G. 
Published: May 2016

AbstractThe oxopropylcyclohexanediones (I) are coupled with hydroxylamine hydrochloride (II) to give mixtures of the isomeric tetrahydroquinolone oximes (III) and (IV).
ChemInform Abstract: Organic Azides in Heterocyclic Synthesis. Part 11. Ring Closure of 3‐Acetyl‐4‐azido‐2‐quinolones to Isoxazolo(4,3‐c)quinolones.
Authors: ROSCHGER P. , STADLBAUER W. 
Published: May 2016

AbstractThe azide (VIII) is prepared by improved literature methods (→ (III) → (IV)) and use of tosylate (VI) in order to introduce the azide group instead of the 4‐chloro derivative (normally used but does not work in this case).
ChemInform Abstract: Synthesis of Some 1‐(Dihydroxypropyl)pyrazolo(3,4‐d)pyrimidines and in vivo Evaluation of Their Antileishmanial and Antitrypanosomal Activity.
Authors: GATTA F. , PEROTTI F. , GRADONI L. , GRAMICCIA M. , ORSINI S. , PALAZZO G. , ROSSI V. 
Published: May 2016

AbstractThe title compounds, e.g. (VII), are evaluated for their activity against Leishmania infantum.
ChemInform Abstract: Synthesis and Crystal Structure of 6‐Amino‐2‐(p‐aminophenyl)‐4‐phenylquinazoline.
Authors: LINDEMAN S. V. , PONOMAREV I. I. , STRUCHKOV YU. T. , VINOGRADOVA S. V. 
Published: May 2016

AbstractThe title compound (II), which is of interest for the synthesis of copolyamides, copolyimides, and copolyquinazolones, is prepared by hydrogenation of the corresponding dinitro compound (I).
ChemInform Abstract: Fused Quinazoline N‐Oxides.
Authors: MOEHRLE H. + , LESSEL J. 
Published: May 2016

AbstractThe o‐aminobenzaldehydes (III) are converted to the oximes (V) which undergo oxidative ring closure upon treatment with mercuric disodium ethylenediaminetetraacetate, forming the fused quinazoline N‐oxides (VIa) ‐ (VId).
ChemInform Abstract: On the Existence of 2‐Imino‐2H‐1,3‐thiazines.
Authors: SCHROTH W. , SPITZNER R. , EZZAT M. M. , RICHTER M. , FREITAG S. 
Published: May 2016

AbstractTitle compounds such as (II) are liberated from the thiazinium salts (I) by base treatment.
ChemInform Abstract: Synthesis of Fungitoxic 1,2,4‐Triazolo(3,4‐b)(1,3)thiazin‐5‐ones Involving Ring Transformation of Michael Adducts of 4‐Benzylidene‐5‐oxazolones and 3‐Mercapto‐1,2,4‐triazoles.
Authors: YADAV L. D. S. , SHUKLA K. N. , SINGH H. 
Published: May 2016

AbstractTitle compounds such as (III) (12 examples) are prepared for the first time and also through a new route.
ChemInform Abstract: Photochemical Ring Expansion of Diazidonaphthalenes: Formation of the First Examples of Azepinoazepines.
Authors: SAWANISHI H. , MURAMATSU H. , TSUCHIYA T. 
Published: May 2016

AbstractIrradiation of 1,8‐diazidonaphthalene (I) in the presence of sodium methoxide (II) produces the azidomethoxybenzazepine (III), the dimethoxyazepinoazepine (IV) and benz(cd)indazole (V).
ChemInform Abstract: Acylsilane Chemistry. Synthesis of Regio‐ and Stereoisomerically Defined Enol Silyl Ethers Using Acylsilanes.
Authors: REICH H. J. , HOLTAN R. C. , BOLM C. 
Published: May 2016

AbstractThe preparation of enol silyl ethers such as (III), (VI) or (X) using a carbonyl addition/Brook rearrangement/elimination sequence is studied.
ChemInform Abstract: Counterattack Reagent Bis(trimethylsilyl)acetamide in the Disilylation of Diols.
Authors: HWU J. R. , ANDERSON D. A. , WANG N. , BUCHNER M. M. , GANI P. , TSAY S.‐C. 
Published: May 2016

AbstractTreatment of various diols such as (I) with the title reagent (II) leads to disilylated products such as (III).
ChemInform Abstract: Triaryl (Dialkoxyphosphorylimido)phosphates: Synthesis and Properties.
Authors: TIKHONINA N. A. , KHODAK A. A. , GILYAROV V. A. 
Published: May 2016

AbstractThe phosphites or phosphines (I) are coupled with the azidophosphates (II) to give the phosphorylimidophosphates (IIIa) ‐ (IIIc) or the phosphine imides (IIId) ‐ (IIIf).
ChemInform Abstract: Formation of Tri‐tert.‐butyl‐nonaphosphane(3); P9(CMe3)3.
Authors: FRITZ G. , REUTER J. , LANG S. 
Published: May 2016

AbstractThe known title compound is formed by the reaction of Na3P/K3P with tBuPCl2 in a yield of 15‐20%.
ChemInform Abstract: Bis(arene)vanadium Anions, a New Class of Organovanadium Complexes: Syntheses, Reactivity Towards Carbon Oxides, and Electron Spin Resonance Investigation.
Authors: FOCHI G. , XU R. , COLLIGIANI A. 
Published: May 2016

AbstractFrom solutions obtained on reduction of (I) with potassium sand in coordinating ether solvents, solvated K salts (II) can be isolated.
ChemInform Abstract: Electron Paramagnetic Resonance and Electrochemical Study of the Oxidation Chemistry of Mononuclear and Binuclear Chromium Carbonyl Thiolates.
Authors: SPRINGS J. , JANZEN C. P. , DARENSBOURG M. Y. , CALABRESE J. C. , KRUSIC P. J. , VERPEAUX J.‐N. , AMATORE C. 
Published: May 2016

AbstractWith regards to ligand‐ vs.
ChemInform Abstract: Isolation of Chromium(0) Thiols: Molecular Structure of (tBuSH)Cr(CO)5.
Authors: DARENSBOURG M. Y. , LONGRIDGE E. M. , PAYNE V. , REIBENSPIES J. , RIORDAN C. G. , SPRINGS J. J. , CALABRESE J. C. 
Published: May 2016

AbstractThe two routes outlined in the scheme are used to prepare the complexes (III) and (V), the first examples of a thiol bound to Cr(0).
ChemInform Abstract: Technetium(V) and Rhenium(V) Complexes of 2,3‐Bis(mercaptoacetamido)propanoate. Chelate Ring Stereochemistry and Influence on Chemical and Biological Properties.
Authors: RAO T. N. , ADHIKESAVALU D. , CAMERMAN A. , FRITZBERG A. R. 
Published: May 2016

AbstractThe Tc complexes are prepared by reduction of TcO4‐ in the presence of the ligand, whereas the Re complexes are obtained by exchange reactions of (V) with the ligand.
ChemInform Abstract: Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 102. Alkylidyne Ligand Migration from Manganese to a Rhodacarbaborane Cluster; Crystal Structure of (Rh(σ,η5‐CH(C6H4Me‐4)‐C2B9H10)(CO)(PPh3)).
Authors: PILOTTI M. U. , STONE F. G. A. 
Published: May 2016

AbstractTreatment of CO‐saturated CH2Cl2 solutions of the anions (I) with the reagent (II) affords the Rh complexes (III) ((IIIa): space group P21/a, Z=4).
ChemInform Abstract: New Nickel(II) and Palladium(II) Complexes with Unsymmetrical Quadridentate Schiff Bases Derived from 8‐Amino‐4‐methyl‐5‐azaoct‐3‐en‐2‐one. Crystal and Molecular Structure of (4,10‐Dimethyl‐3‐(nitroso‐ϰN)‐5,9‐(diaza‐ϰ2N)‐trideca‐3,10‐diene‐2,# 12‐(dionato‐ϰO)(2‐))nickel(II).
Authors: KWIATKOWSKI M. , KWIATKOWSKI E. , OLECHNOWICZ A. , HO D. M. , DEUTSCH E. 
Published: May 2016

Abstract(I) is used as a precursor to form new unsym. Schiff bases such as (III).
ChemInform Abstract: Hydrolysis and Dimerization of Nitrile to Diacetamide and Crystal Structures of Chloro(2,2,2,2′,2′,2′‐hexachlorodiacetamido)(dimethyl sulfoxide)platinum(II) and cis‐Aquodichloro(dimethyl sulfoxide)platinum(II).
Authors: ROCHON F. D. , KONG P. C. , MELANSON R. 
Published: May 2016

AbstractIn continuing studies on Pt complexes with MeCN which were isolated with different colors but identical structures, similar reactions were performed with another nitrile.
ChemInform Abstract: Studies of Enzyme‐Mediated Reactions. Part 16. Stereochemical Course of the Formation of 5‐Hydroxytryptamine (Serotonin) by Decarboxylation of (2S)‐5‐Hydroxytryptophan with the Aromatic L‐Amino Acid Decarboxylase (E.C. 4.1.1.28) from Hog Kidney.
Authors: BATTERSBY A. R. , SCOTT A. , STAUNTON J. 
Published: May 2016

AbstractThe labeled 5‐hydroxytryptophan (I) is prepared and then incubated with mammalian aromatic L‐amino acid decarboxylase from hog kidney.
ChemInform Abstract: N‐Aryl‐O‐(α‐aminoacyl)hydroxylamines: Model Reactions with Deoxyguanosine, Guanosine and 5′‐Guanosinemonophosphate for the Activation of Monocyclic Aromatic Amines (e.g. Phenacetin) into Ultimate Carcinogens.
Authors: MEIER C. , BOCHE G. 
Published: May 2016

AbstractIn vitro model reactions of the activation of monocyclic aromatic amines by α‐amino acids show that α‐aminohydroxamic acids such as (I) rearrange under base catalysis to the title compounds (II) which react with bionucleophiles such as deoxyguanosine (III) to form the adducts (IV).
ChemInform Abstract: Chemistry and Stereochemistry of Iridoids. Part 13. Synthesis of Enantiomerically Pure Methyl (1R,2S,2′′Z)‐(+)‐Jasmonate (XI) Starting from Catalpol (I).
Authors: WEINGES K. , LERNHARDT U. 
Published: May 2016

AbstractWhereas first of all (‐)‐methyljasmonate (XII) had been regarded as the characteristic fragrance of the jasmine flower oil, later reports (Nishida et al., 1985; Weinges et al., 1987) have demonstrated the (+)‐diastereomer (XI) to be the real scent.
ChemInform Abstract: Chiral Synthesis via Organoboranes. Part 26. An Efficient Synthesis of Isoprenyl Derivatives of Borane ‐ Valuable Reagents for the Isoprenylboration of Aldehydes. A Convenient Route to Both Enantiomers of Ipsenol and Ipsdienol in High Optical Purity.
Authors: BROWN H. C. , RANDAD R. S. 
Published: May 2016

AbstractThe preparation of racemic and optically active B‐isoprenyldialkylboranes such as (I) is achieved by adopting the Brandsma modification of the Schlosser procedure, namely metalation of isoprene with potassium 2,2,6,6‐tetramethylpiperidide followed by sequential treatment with B‐methoxydialkylborane and BF3·OEt2.
ChemInform Abstract: Synthesis of a Biologically Active Isomer of Frontalin and Some New Products from Acylative Decarboxylation of 3‐Methyltricarballylic Acid.
Authors: STRUNZ G. M. , YU C.‐M. , YA L. , WHITE P. S. , DIXON E. A. 
Published: May 2016

AbstractIn order to provide (III) the reaction of the tricarballylic acid (I) with (II) is studied in a scaled‐up process.
ChemInform Abstract: Photoelectrochemistry in Semiconductor Particulate Systems. Part 16. Photophysical and Photochemical Aspects of Coupled Semiconductors. Charge‐Transfer Processes in Colloidal CdS‐TiO2 and CdS‐AgI Systems.
Authors: GOPIDAS K. R. , BOHORQUEZ M. , KAMAT P. V. 
Published: May 2016

AbstractTEM, emission measurements, and picosecond transient absorption spectroscopy are used to study the mechanism and kinetics of the charge injection from excited CdS into the large bandgap semiconductors AgI and TiO2 in the mixed semiconductor colloids.
ChemInform Abstract: Electric Properties of Ce2PbSe4, Ce2Pb4Se7 and (Ce2Se3)x(PbSe)1‐x.
Authors: SHAFAGATOVA G. G. , NASIBOV I. O. , SULTANOV T. I. 
Published: May 2016

AbstractThe temp. dependence of the electric conductivity and of the coefficient of the thermo‐EMF of the title compounds (x = 0.02; 0.03) are investigated in a wide range of temperature.
ChemInform Abstract: Disproportionation in Nd16Fe76B8‐Type Hydrides.
Authors: MCGUINESS P. J. , ZHANG X. J. , FORSYTH H. , HARRIS I. R. 
Published: May 2016

AbstractIt is shown that heating of Nd16Fe76B8‐type materials in H2 atmosphere and subsequent vacuum annealing at T > 750 °C produces coercive powders which are suitable for the production of polymer‐bonded magnets.
ChemInform Abstract: Isolated Redox Centers within Microporous Environments. Part 1. Cobalt‐Containing Aluminophosphate Molecular Sieve Five
Authors: MONTES C. , DAVIS M. E. , MURRAY B. , NARAYANA M. 
Published: May 2016

Abstract(CoAPO‐5) is synthesized by heating a gel of composition 1.5 Et3N·0.8 Al2O3·0.4 CoO·P2O5·40 H2O to 200 °C at autogeneous pressure.
ChemInform Abstract: Synthesis and Structure of Alkali Metal Cobalt Chalcogenides A6CoX4 (A: Na or K, X: S or Se) with Isolated (CoX4) Anions.
Authors: BRONGER W. , BOMBA C. 
Published: May 2016

AbstractK6CoS4, Na6CoSe4, and K6CoSe4 are prepared by reaction of a mixture of Na2CO3 or K2CO3 and Co‐powder with a H2‐stream loaded with the chalcogen component (1030 K, 10 h).
ChemInform Abstract: Near IR Dyes. An Air‐Stable Radical Anion (V).
Authors: MILLER L. L. , LIBERKO C. A. 
Published: May 2016

AbstractCyclic voltammetry of (III) (prepared according to Aumueller and Huenig (1986)) shows four reversible one‐electron couples at E° = 0.10, ‐0.15, ‐0.91, and ‐1.11 V (SCE).
ChemInform Abstract: Stereoselectivity in Intramolecular 1,3‐Dipolar Cycloaddition. Nitrile Oxides versus Silyl Nitronates.
Authors: DEHAEN W. , HASSNER A. 
Published: May 2016

AbstractThe nitro compounds (I) react with phenyl isocyanate (II) in the presence of triethylamine to give the nitrile oxides (III).
ChemInform Abstract: Fluoroalkyl‐Containing β,β′‐Tricarbonyl Compounds: Tautomerism, Reaction with N‐Nucleophiles.
Authors: KROKHALEV V. M. , SALOUTIN V. I. , ROMAS' A. D. , ERSHOV B. A. , PASHKEVICH K. I. 
Published: May 2016

AbstractAccording to 1H NMR data, the β,β'‐tricarbonyl compounds (IIIa) and (IIIb) exist in the enol form, whereas for (IIIc) ‐ (IIIe) 55:45 mixtures with the triketo form are obtained.
ChemInform Abstract: Synthetic Photochemistry. Part 54. The Photoaddition Reaction of Methyl 2,4‐Dioxopentanoate with 2,5‐Dimethyl‐2,4‐hexadiene, a Sterically Crowded Conjugated Diene.
Authors: HATSUI T. , NOJIMA C. , TAKESHITA H. 
Published: May 2016

AbstractIn order to investigate the electronic effects on the regioselectivity of the photoaddition of (I), it is treated with diene (II).
ChemInform Abstract: The Temperature‐ and Viscosity‐Dependent Photostationary E/Z Ratio in Triplet‐Sensitized Photoisomerization of Cyclooctene.
Authors: INOUE Y. , YAMASAKI N. , TAI A. , DAINO Y. , YAMADA T. , HAKUSHI T. 
Published: May 2016

AbstractIn the triplet‐sensitized photoisomerization with benzene, toluene, or p‐xylene, the photostationary E/Z ratio of cyclooctene, (II)/(I), dramatically increases with lowered irradiation temp. or with increased solvent viscosity, whereas the E/Z ratio of oct‐2‐ene, (III)/(IV), stays unchanged over the temp. range indicated.
ChemInform Abstract: Photochemical Reactivity of Halofuran and Halothiophene Derivatives in the Presence of Arylalkenes and Arylalkynes.
Authors: D'AURIA M. , PIANCATELLI G. , FERRI T. 
Published: May 2016

AbstractIrradiation of the haloarenes (Ia) ‐ (Ic) in the presence of the vinylarenes (II) forms the diarylalkenes (III).
ChemInform Abstract: Photochemistry of 4‐Acylisoxazoles.
Authors: SAUERS R. R. , HADEL L. M. , SCIMONE A. A. , STEVENSON T. A. 
Published: May 2016

AbstractThe photolysis of 4‐acylisoxazoles such as (I), (IV), and (VII) proceeds depending on the solvents employed.
ChemInform Abstract: ESR and ENDOR Spectroscopy of Furan Radical Cations Obtained by Cyclization of 1,4‐Diketones in Electrophilic Media.
Authors: LAZANA M. C. R. L. R. , FRANCO M. L. T. M. B. , HEROLD B. J. 
Published: May 2016

AbstractIdentical ESR spectra are obtained when either the (Z)‐(I) or (E)‐(III) ethylenes or even ethane (IV) react with strong electrophiles by generation of the radical cations (II).
ChemInform Abstract: cis‐Selective Wittig Olefination of α‐Alkoxy Ketones and Its Application to the Stereoselective Synthesis of Plaunotol.
Authors: INOUE S. , HONDA K. , IWASE N. , SATO K. 
Published: May 2016

AbstractWittig reaction of the alkoxy ketones (Ia‐c) and the ylide (II) yields olefins with high (Z)‐stereoselectivity.
ChemInform Abstract: Coupling of Anion Radicals with Sterically Hindered Alkyl Halides.
Authors: DAASBJERG K. , HANSEN J. N. , LUND H. 
Published: May 2016

AbstractThe radical anion derived from anthracene (I) in the presence of (II) or its endo isomer yields the same 1:1 mixture of (III) and (IV) in both cases.
ChemInform Abstract: Asymmetric Synthesis of Tertiary Alcohols from α‐Halo Boronic Esters.
Authors: MATTESON D. S. , HURST G. D. 
Published: May 2016

AbstractReaction of the pinanediol boronates (I) with the anion of 1,1‐dichloroethane (II) and subsequent zinc chloride‐induced rearrangement give diastereoselectively the α‐chloro boronic acid esters (R)‐(III) or (S)‐(VII).
ChemInform Abstract: Stereoselective Synthesis of (E)‐2‐Hydroxyimino‐2‐phenylacetonitrile (V) by Photolysis of 4‐Azido‐3‐phenylfurazan 2‐Oxide
Authors: KUNAI A. , DOI T. , NAGAOKA T. , YAGI H. , SASAKI K. 
Published: May 2016

Abstract(IV).
ChemInform Abstract: Orthoamides. Part 44. Alkynoic Acid Orthoamides.
Authors: KANTLEHNER W. , SPEH P. , LEHMANN H. , BRAEUNER H.‐J. + , HAUG E. , MERGEN W. W. 
Published: May 2016

AbstractReaction of the guanidinium salts (II) with the sodium salts of the acetylenes (I) produces the alkynoic acid orthoamides (III).
ChemInform Abstract: (Benzo(4,5)cyclohepta(1,2‐b)thiophen‐4‐ylidene)acetic Acids: Novel Non‐ulcerogenic Antiinflammatory Agents.
Authors: BOLLINGER P. , COOPER P. , GUBLER H. U. , LEUTWILER A. , PAYNE T. 
Published: May 2016

AbstractIn order to find new antirheumatic and antiphlogistic agents some derivatives such as (IX) are prepared via the key intermediates (IV), which are formed by a new route.
ChemInform Abstract: Chemistry of Isoindoles and Isoindolenines. Part 37. Symmetrically Substituted 2‐Alkyl‐2H‐isoindoles.
Authors: KREHER R. P. , SEWARTE‐ROSS G. , VOGT G. 
Published: May 2016

AbstractThe tetramethyl isoindole (IV) and the tetrachloro derivative are prepared in good yields.