bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Novel Basic Ligands for the Homogeneous Catalytic Carbonylation of Methanol. Part 23. The Influence of (Ether‐Phosphane) Ligands on Alkyl Migration in Rhodium Complexes.
Authors: LINDNER E. , NORZ H. 
Published: May 2016

AbstractThe unstable tricarbonyl‐bis(ether‐phosphane) complexes (V) lose CO to give the four‐coordinate monocarbonyl‐Rh(I) complexes (VI).
ChemInform Abstract: Synthesis and Characterization of Rh2(O2CCH3)3((C6H2(OMe)3)2P(C6H2(OMe)2O))(MeOH) with a Novel Tridentate Ligand Derived from Tris(2,4,6‐trimethoxyphenyl)phosphine.
Authors: CHEN S. J. , DUNBAR K. R. 
Published: May 2016

AbstractThe title complex (III) crystallizes in P1‐ with Z=2.
ChemInform Abstract: (Malonato)bis(sulfinylbis(methane)‐S)platinum(II) Compounds: Versatile Synthons for a New General Synthesis of Antitumor Symmetrical and Dissymmetrical (Malonato)platinum(II) Complexes.
Authors: BITHA P. , MORTON G. O. , DUNNE T. S. , DELOS SANTOS E. F. , LIN Y. , BOONE S. R. , HALTIWANGER R. C. , PIERPONT C. G. 
Published: May 2016

AbstractThe reactions of the new (malonato)‐Pt(II) complexes (III) with various amines (trans‐1,2‐cyclohexanediamine, 2,2‐dimethyl‐1,3‐propanediamine, tetrahydro‐4H‐pyran‐4,4‐dimethanamine, cyclohexylamine, propylamine, benzylamine) lead to a new general synthesis of antitumor sym. and dissym.
ChemInform Abstract: Synthesis and Oxidation of Pregna‐3,5‐dien‐20‐ols and ‐20‐one and Selective Reduction of Pregna‐3,5‐dien‐20‐one.
Authors: GOENDOES G. + , ORR J. C. 
Published: May 2016

AbstractNaBH4 reduction of progesterone (I) affords the (20S)‐ and (20R)‐alcohols (II) and (III).
ChemInform Abstract: N,N‐Diisopropyl‐bis(4‐chlorobenzyl)phosphoramidite: A Versatile Phosphitylating Agent for the Phosphorylation of Hydroxy Amino Acids and Preparation of Protected Phosphopeptides.
Authors: DE BONT H. B. A. , VAN BOOM J. H. , LISKAMP R. M. J. 
Published: May 2016

AbstractThe phosphorylated amino acids and peptides (III) and (IV), resp., are synthesized for structural investigations.
ChemInform Abstract: Syntheses of Undecose Derivatives as D‐Galactose Analogues for Specific Modification of Galactose‐Binding Proteins.
Authors: LEHMANN J. , SCHEURING M. 
Published: May 2016

AbstractThe potential photoaffinity reagent (VIII) is prepared starting from the D‐galactohexodialdopyranose (I) via twofold chain elongation and subsequent modifications of the alkyl chain.
ChemInform Abstract: Mevinic Acids and Analogs: A Novel Efficient Route to Chiral Synthons from 1,6‐Anhydro‐D‐glucose.
Authors: DAVID C. , GESSON J. P. , JACQUESY J. C. 
Published: May 2016

AbstractThe ditosylate (I) of levoglucosan is treated with thiophenol (II) in an alkaline medium to give the bissulfide (III) which is desulfurated, yielding the bicyclic hydroxy acetal (IV).
ChemInform Abstract: 2‐Acetylthiazole as a Three‐Carbon Homologating Reagent of Aldehydes. Application Toward the Synthesis of Amino Hexoses from L‐Serinal.
Authors: DONDONI A. , FANTIN G. , FOGAGNOLO M. 
Published: May 2016

Abstract2‐Acetylthiazole (II) reacts with the aldehydes (I) to form the aldols (III) which are selectively reduced with tetramethylammonium triacetoxyboranate to give the anti‐diols (IV).
ChemInform Abstract: Silyl Nitronates in Carbohydrate Chemistry. Chain‐Extension Reactions.
Authors: MARTIN O. R. , HAMIS F. E. , EL‐SHENAWY H. A. , RAO S. P. 
Published: May 2016

AbstractThe aldehydo sugars (I) react with the silyl nitronate (II) to form the nitro alcohols (III).
ChemInform Abstract: Synthesis and Reactivity of Nitro Sugar‐Derived Silyl Nitronates.
Authors: MARTIN O. R. , KHAMIS F. E. , RAO S. P. 
Published: May 2016

AbstractThe nitromethyl sugars (I), (VI), and (VIII) are treated with the silyl chloride (II) in the presence of bases to form the silyl nitronates (III), (VII), and (IX) respectively.
ChemInform Abstract: Efficient Synthesis of 1,2‐seco and 1,2‐seco‐2‐nor Pyrimidine and Purine Nucleosides.
Authors: AZYMAH M. , CHAVIS C. , LUCAS M. , IMBACH J.‐L. 
Published: May 2016

AbstractThe silylated cytosine (II) is coupled with the acetoxymethylated acyclic sugar analogues (I) to form the nucleosides (III).
ChemInform Abstract: O‐Debenzylation of a Pyrrolo(2,1‐c)(1,4)benzodiazepine in the Presence of a Carbinolamine Functionality: Synthesis of DC‐81.
Authors: THURSTON D. E. , MURTY V. S. , LANGLEY D. R. , JONES G. B. 
Published: May 2016

AbstractThe naturally occurring antitumor antibiotic DC‐81 (VIII) is prepared from 4‐hydroxy‐3‐methoxybenzoic acid (I) in six steps.
ChemInform Abstract: The Effect of Hydrogen‐Water Atmospheres on Corrosion and Flexural Strength of Sintered α‐Silicon Carbide
Authors: KIM H.‐E. , MOORHEAD A. J. 
Published: May 2016

Abstractis studied for H2 atmospheres with H2O partial pressures in the range 5·10‐6‐2·10‐2 atm at 1300 and 1400 °C. The room temp. flexural strength of α‐SiC is not significantly affected by exposure to H2 atmospheres with low H2O content (P(H2O) = 5·10‐6 atm), and for high H2O contents (> 5·10‐3 atm), the strength is even higher than that of the as‐received material.
ChemInform Abstract: The Influence of Small Amounts of Added Elements on Various Anode Performance Characteristics for LaNi2.5Co2.5‐Based Alloys.
Authors: SAKAI T. , MIYAMURA H. , KURIYAMA N. , KATO A. , OGURO K. , ISHIKAWA H. , IWAKURA C. 
Published: May 2016

AbstractIt is found that the addition of Si to the LaNi2.5Co2.5 alloy suppresses the capacity decay, but the overpotential and self‐discharge rate are increased.
ChemInform Abstract: The Effect of Support on the Surface Characteristics of Supported Molybdena Catalysts
Authors: CACERES C. V. , FIERRO J. L. G. , LAZARO J. , LOPEZ AGUDO A. , SORIA J. 
Published: May 2016

Abstractis studied for TiO2, Al2O3, SiO2, SiO2·Al2O3, and carbon supports.
ChemInform Abstract: Enhanced Polymerization of Molybdate Ions in the Presence of Antimonic Acid.
Authors: KONE M. , COURTIN P. , LEMERLE J. 
Published: May 2016

AbstractPolymeric compounds containing Sb and Mo are prepared by mixing solutions of antimonic and molybdic acid, freshly prepared from potassium hexahydroxyantimonate and sodium molybdate solutions by ion exchange.
ChemInform Abstract: Synthesis of Monolithic Uranium Hydride and Uranium Deuteride.
Authors: COSTANTINO M. S. , LAKNER J. F. , BASTASZ R. 
Published: May 2016

AbstractUHx (UDx) crystals are grown from the melt at temp. above 1065 °C under 125 MPa H2 (D2) pressure.
ChemInform Abstract: Crystal Structure of BaNiN, a Low Valency Nitridoniccolate(I).
Authors: GUDAT A. , HAAG S. , KNIEP R. , RABENAU A. 
Published: May 2016

AbstractBaNiN is prepared by reaction of metallic Ba with dry nitrogen in a Ni crucible (1000 °C, 1 atm N2, 15 h).
ChemInform Abstract: Photoinduced Electron Transfer in Viologen‐Linked Porphyrins (p‐PCnV).
Authors: NODA S. , HOSONO H. , OKURA I. , YAMAMOTO Y. , INOUE Y. 
Published: May 2016

AbstractThe fluorescence decay profiles of (I) consist of a sum of two first‐order decays with longer and shorter lifetimes, the former depending hardly on n in contrast to the latter (direct quenching of the photoexcited singlet).
ChemInform Abstract: Palladium‐Catalyzed Synthesis of Aromatic Acids from Carbon Monoxide and Aromatic Compounds Via the Aromatic C‐H Bond Activation.
Authors: JINTOKU T. , FUJIWARA Y. , KAWATA I. , KAWAUCHI T. , TANIGUCHI H. 
Published: May 2016

AbstractWith Pd(II) catalysts the reaction is electrophilic and proceeds with ortho‐para orientation when an electron‐donating group is attached to the benzene ring (table).
ChemInform Abstract: Photoinduced Electron‐Transfer Reactions of 1,4‐Dimethyl‐ and 1,2,3,4,5,6‐Hexamethylbicyclo(2.2.0)hexanes. Evidence for Boat Cyclohexane‐1,4‐diyl Radical Cation and Its Stereospecific Cleavage.
Authors: TSUJI T. , MIURA T. , SUGIURA K. , NISHIDA S. 
Published: May 2016

AbstractThe sensitized photolysis of both (I) is practically acceptor (cat.)‐independent and leads to the stereospecific formation of (E,E)‐(IIa) + (IIIa) or (IIb) (exclusively, with lesser stereospecificity), respectively.
ChemInform Abstract: Photochemistry of Diarylsubstituted 2H‐Tetrazoles. Part 11. Sydnones. Part 5. Flash Photolytic Investigations with 2,5‐Diaryl‐2H‐tetrazoles and 3,4‐Diarylsydnones. Absolute Rate Constants of Cycloaddition Reactions of Diarylnitrile Imines to Dipolarophiles.
Authors: LEIHKAUF P. , LOHSE V. , CSONGAR CH. , TOMASCHEWSKI G. 
Published: May 2016

AbstractNitrile imines such as (II) are generated from 17 p‐ or p'‐monosubstituted tetrazoles such as (I) (and 7 analogous sydnones such as (III) as well) by flash photolysis and detected spectroscopically.
ChemInform Abstract: 1,3‐Dipolar Cycloadditions between Nitrile Oxides and Substituted 7‐Oxabicyclo(2.2.1)heptenes.
Authors: ARJONA O. , DOMINGUEZ C. , FERNANDEZ DE LA PRADILLA R. , MALLO A. , MANZANO C. , PLUMET J. 
Published: May 2016

Abstract1,3‐Dipolar cycloaddition reaction of the aromatic nitrile oxides (II) with the 7‐oxabicyclo(2.2.1)heptenes (I) forms the corresponding exo‐adducts (III) and (IV).
ChemInform Abstract: Thermolysis of Trifluoromethylsilanes. Novel Fluoromethylsilanes by Insertion of CF2 and CHF into Si‐H Bonds.
Authors: BECKERS H. , BUERGER H. + 
Published: May 2016

AbstractThermal decomposition of CF3‐SiH3 and (CF3)2SiH2 in the gas phase are investigated in the absence and in the presence of various carbene trapping agents.
ChemInform Abstract: Applications of ENDOR Spectroscopy to Radical Cations in Freon Matrices. Part 8. Structure of the Paramagnetic Species Formed Upon γ‐Irradiation of Hexamethyl(Dewar benzene) in a CF2ClCFCl2 Matrix. An ESR and ENDOR Study.
Authors: ARNOLD A. , GERSON F. 
Published: May 2016

Abstractγ‐Irradiation of (I) in CFCl3 and in CF2Cl‐CFCl2 leads to completely different ESR spectra as observed by Rhodes (1988).
ChemInform Abstract: Proton Abstraction from Dimethyl(2‐substituted‐9‐fluorenyl)sulfonium Ions. Evidence for Changes in Transition‐State Structure.
Authors: MURRAY C. J. , JENCKS W. P. 
Published: May 2016

AbstractThe rate and equilibrium constants of the proton removal from the title ions (I) by oxygen and nitrogen bases to give the sulfonium ylides are determined.
ChemInform Abstract: Hydride Abstraction. The Reaction of IrX(CO)(dppe) with Cp2TaH3.
Authors: DEUTSCH P. P. , MAGUIRE J. A. , JONES W. D. , EISENBERG R. 
Published: May 2016

AbstractThe title reaction is extremely rapid and leads to clean formation of the fac‐Ir(III) complex (III) and the halogeno‐Ta(III) compounds (IV) which in the presence of added ligands form 1:1 adducts (η5‐C5H5)2TaX(L) (L: CH2=CH2, Pr‐C=C‐Pr, CO).
ChemInform Abstract: Transition‐State Analogue Inhibitors of Chorismate Mutase.
Authors: CLARKE T. , STEWART J. D. , GANEM B. 
Published: May 2016

AbstractThe synthesis of seven bi‐ and tricyclic chorismate analogues (IV), (VII), (XII), (XIII) is accomplished using a tandem Cope rearrangement/Diels‐Alder cycloaddition strategy as shown in the scheme.
ChemInform Abstract: An Efficient Chiral Promoter in the Aldol Type Reaction. Chiral Diamine Coordinated Tin(II) Triflate‐Dibutyltin Diacetate Complexes.
Authors: MUKAIYAMA T. , UCHIRO H. , KOBAYASHI S. 
Published: May 2016

AbstractThe aldehyde (I) is coupled with the ketene O,S‐acetal (II) in the presence of tin(II) triflate, an alkyltin(IV) compound, and a chiral diamine to yield the syn‐ (III) and anti‐adduct (IV) with predominance of the former.
ChemInform Abstract: Photochemical Rearrangement of 1,2‐Dihydronaphthalenes into 1,4‐Dihydronaphthalenes Induced by Amines.
Authors: CUPPEN TH. J. H. M. , BERENDSEN N. , LAARHOVEN W. H. 
Published: May 2016

AbstractThe synthetic usefulness of the deprotonation/protonation reaction of excited 1,2‐dihydronaphthalenes such as (I) into 1,4‐dihydronaphthalenes such as (II) induced by amines is investigated using a total of 13 educts.
ChemInform Abstract: Conjugated Azoalkenes. Part 7. Reaction of Some Conjugated Azoalkenes with Activated Methinic Compounds.
Authors: ATTANASI O. A. , SANTEUSANIO S. , SERRA‐ZANETTI F. 
Published: May 2016

AbstractReaction of the azoalkenes (I) with cyclic β‐dicarbonyl compounds (II), (IV), or (VI) gives rise to the products (IIIa), (IIIb), (Va), (Vb) or (VII).
ChemInform Abstract: Studies on Organosilicon Chemistry. Part 105. α‐Oxo Ketene Dithioacetals in Organic Synthesis. A New Access to 1‐Siloxy‐1,3‐butadienes and Their Selective Reactions with Electrophiles.
Authors: TOMINAGA Y. , KAMIO C. , HOSOMI A. 
Published: May 2016

AbstractThe α‐oxo ketene dithioacetals (I) react with the trimethylsilylmethyl Grignard compound (II) to give the siloxybutadienes (IV) via rearrangement of the intermediates (III).
ChemInform Abstract: Cycloaddition Reaction of α‐Oxo Sulfines and 2‐Trimethylsilyloxy‐1,3‐butadienes.
Authors: REWINKEL J. B. M. , ZWANENBURG B. 
Published: May 2016

AbstractCycloaddition reactions of in situ generated α‐oxo sulfines, e.g. (III), with the silyloxydienes (II) lead regioselectively to thiacyclohexanone S‐oxides such as (IV) and (V).
ChemInform Abstract: Potential Cardiotonic Agents. Part 4. Synthesis, Cardiovascular Activity, Molecular, and Crystal Structure of 5‐Phenyl‐ and 5‐(4‐Pyridinyl)‐Substituted 2(1H)‐Pyridinethiones.
Authors: HAGEN V. , RUMLER A. , RECK G. , HAGEN A. , LABES D. , HEER S. 
Published: May 2016

AbstractThe butenones (I) are cyclized with cyanothioacetamide (II) to form the pyridinethiones (III).
ChemInform Abstract: Synthesis of Some Benzofuranyl Pyridine and Pyridone Derivatives with Possible Biological Activities.
Authors: HISHMAT O. H. , MIKY J. A. A. , SALEH N. M. 
Published: May 2016

AbstractThe condensation reaction of the benzofuran derivatives (I) with activated methylene compounds such as (II), (IV), or (VI) yields the corresponding pyridines (III), (V), and (VII) respectively.
ChemInform Abstract: Antimitotic Agents: Synthesis of Imidazo(4,5‐c)pyridin‐6‐ylcarbamates and Imidazo(4,5‐b)pyridin‐5‐ylcarbamates.
Authors: TEMPLE C. JUN. 
Published: May 2016

AbstractThe nitropyridine (I) is reduced and subsequently cyclized with carbon disulfide (III) to produce the imidazopyridines (IV) and (V).
ChemInform Abstract: 1,9‐Alkano‐Bridged 2,3,4,5‐Tetrahydro‐1H‐3‐benzazepines with Affinity for the α2‐Adrenoceptor and the 5‐HT1A Receptor.
Authors: CLARK R. D. , WEINHARDT K. K. , BERGER J. , FISHER L. E. , BROWN C. M. , MACKINNON A. C. , KILPATRICK A. T. , SPEDDING M. 
Published: May 2016

AbstractThe bicyclic acids (I) are coupled with the ethanolamine (II) and subsequently reduced to form the amines (III) which undergo ring closure upon consecutive heating with PCl5 and AlCl3 to give the benzazepines (IV).
ChemInform Abstract: Synthesis and Antiinflammatory Activity of cis‐ and trans‐6,6a,7,8,9,10,10a,11‐Octahydro‐11‐oxadibenzo(b,e)thiepinacetic and ‐oxepinacetic Acids.
Authors: KUROKAWA M. , UNO H. , NAKAMURA H. , SATO F. , NARUTO S. 
Published: May 2016

AbstractThe diastereomeric dibenzoxepin(dibenzothiepin)acetic acids (IV) and (V) are prepared on two synthetic routes as outlined in the reaction scheme.
ChemInform Abstract: Sulfonation of 2,6‐Dimethyl‐3,5‐dimethoxycarbonyl‐4‐(2‐difluoromethoxyphenyl)‐1,4‐dihydropyridine (Foridon).
Authors: LIEPIN'SH E. E. , SKRASTIN'SH I. P. , KASTRON V. V. , DUBUR G. YA. 
Published: May 2016

AbstractTreatment of the dihydropyridine (I) with conc.
ChemInform Abstract: Stabilization of Tris(trifluoromethyl)borane in Complexes with Primary, Secondary and Tertiary Amines. Crystal and Molecular Structure of (CF3)3B·NHEt2 and (CF3)3B·NH2Et.
Authors: BRAUER D. J. , BUERGER H. + , DOERRENBACH F. + , KRUMM B. , PAWELKE G. , WEUTER W. 
Published: May 2016

AbstractNucleophilic trifluoromethylation of dichloro(amino)boranes such as (I) and subsequent protonation lead to adducts of the unknown Lewis acid B(CF3)3 with sec. amines of the type (III) ((IIIb): space group Pnma, Z=4).
ChemInform Abstract: Reaction of tert‐Butyl Tetraethyldiamidophosphite with Carbon Tetrachloride and Chloroform.
Authors: GAZIZOV T. KH. , SAL'KEEVA L. K. , CHUGUNOV YU. V. 
Published: May 2016

AbstractReaction of the phosphorodiamidite (I) with carbon tetrachloride (II) produces the phosphorodiamidic chloride (III), isobutene (IV), and chloroform (V).
ChemInform Abstract: Ambident Reactivity of Chlorophosphonium Compounds in Nucleophilic Reactions. Part 1. Reactions with Phosphorous Acid Esters.
Authors: TIMOKHIN B. V. , KAZANTSEVA M. V. , DONSKIKH V. I. , RATOVSKII G. V. , CHUVASHEV D. D. 
Published: May 2016

AbstractThe phosphonium salts (I) are coupled with phosphorous acid esters such as the phosphorochloridite (II) to give the phosphonous dichlorides (III) or the phosphonic dichlorides (V) depending on the polarity of the solvent used.
ChemInform Abstract: Chlorotropy in the Diade P‐C. Part 2. Chlorotropic Transformations of α‐Chloroalkylphosphonous Bis(diisopropylamides).
Authors: KOLODYAZHNYI O. I. , GOLOKHOV D. B. 
Published: May 2016

AbstractTreatment of the phosphonous diamides (I) with carbon tetrachloride gives the P‐chloro ylides (II) of which (IIa) and (IIb) are transformed into the α‐chloroalkylphosphonous diamides (IIIa) and (IIIb) upon storage in toluene.
ChemInform Abstract: Synthesis and Structure of Pyrocatechol Phosphite.
Authors: NIFANT'EV E. E. , KUKHAREVA T. S. , SOLDATOVA I. A. 
Published: May 2016

AbstractCoupling of pyrocatechol silyl phosphite (I) with trifluoroacetic acid gives the title compound (II) which is hydrolyzed, producing the hydroxyphenyl phosphite (III).
ChemInform Abstract: Phosphorotropic Isomerization of Oxazaphospholines.
Authors: MALENKO D. M. , NESTEROVA L. I. , LUK'YANENKO S. N. , SINITSA A. D. 
Published: May 2016

AbstractThe N‐acylglycines (I) react with the dichlorophosphite (II) in the presence of triethylamine to give the oxazaphospholine (IIIa) or a mixture of the isomeric oxazaphospholines (IIIb) and (IVb).
ChemInform Abstract: Ring‐Closure Reactions Initiated by the Peroxodisulfate Ion Oxidation of Diphenyl Diselenide.
Authors: TIECCO M. , TESTAFERRI L. , TINGOLI M. , BARTOLI D. , BALDUCCI R. 
Published: May 2016

AbstractThe oxidation of diphenyl diselenide (I) with peroxodisulfate represents an efficient method to produce phenylselenium cations in the absence of nucleophilic counterions.
ChemInform Abstract: Organoaluminum‐Phosphine Chemistry. Synthesis and Molecular Structure of (Ph2P(O)2·AlCl2)2 and (Ph2P·Al(iBu)2)2.
Authors: SANGOKOYA S. A. , PENNINGTON W. T. , ROBINSON G. H. , HRNCIR D. C. 
Published: May 2016

Abstract(III) is alternatively prepared by reaction of the disproportionation product of ethylaluminum sesquichloride instead of (II).
ChemInform Abstract: Synthesis, Structure, and Reactivity of a Zirconocene Complex of Cyclobutene.
Authors: FISHER R. A. , BUCHWALD S. L. 
Published: May 2016

AbstractThe first structurally characterized transition‐metal complex (V) (space group P21/n, Z=4) of cyclobutene is formed by elimination of methane from the complex (III) with subsequent trapping by trimethylphosphine.
ChemInform Abstract: Chemistry of C‐Trimethylsilyl‐Substituted Main‐Group Heterocarboranes. Part 6. Lead(II)‐Inserted η5‐closo‐Plumbacarboranes and Their Reactivity Toward a Bidentate Lewis Base: Crystal Structures of closo‐1‐Pb‐2‐(SiMe3)‐3‐(R)‐2,3‐C2B4H4 and 1‐Pb(C10H8N2)‐2,3‐(SiMe3)2‐2,3‐C2B4H4 (R: SiMe3, Me).
Authors: HOSMANE N. S. , LU K.‐J. , ZHU H. , SIRIWARDANE U. , SHET M. S. , MAGUIRE J. A. 
Published: May 2016

AbstractThe monosodium salts of the nido‐carboranes (I) react with PbCl2 (II) to produce the closo‐plumbacarboranes (III), which are characterized by IR, 1H, 11B, 13C NMR and mass spectroscopy.
ChemInform Abstract: Preparation and Structure of Tetrafluoro(η5‐pentamethylcyclopentadienyl) Niobium and Tetrafluoro(η5‐cyclopentadienyl) Niobium.
Authors: ROESKY H. W. , SOTOODEH M. , XU Y. M. , SCHRUMPF F. , NOLTEMEYER M. 
Published: May 2016

AbstractBy using AsF3 (II) as a fluorinating agent the title compounds (III) are obtained in a facile manner.
ChemInform Abstract: Main‐Group‐Organotransition‐Metal Chemistry: The Cyclopentadienylchromium Polyiodides Including ((C5Me5)2Cr2I+ 3)2(I2‐ 16).
Authors: MORSE D. B. , RAUCHFUSS T. B. , WILSON S. R. 
Published: May 2016

AbstractThe reaction of the dimer (I) and I2 affords a compound, which is shown by single‐crystal X‐ray diffraction (space group P21/c, Z=2) to be the polymer (III).
ChemInform Abstract: Synthesis and Characterization of Tetraruthenaborane Clusters: Molecular Structure of (HRu4(CO)12Au2(PPh3)2B).
Authors: CHIPPERFIELD A. K. , HOUSECROFT C. E. , RHEINGOLD A. L. 
Published: May 2016

AbstractDeprotonation of the tetraruthenaborane cluster (III) to (IV) occurs via the loss of a Ru‐H‐B bridging proton.
ChemInform Abstract: Reactions of Primary and Secondary Silanes with Binuclear Rhodium Complexes. Formation of μ‐Silylene Complexes and P‐Si Bonds with Facile P‐C Bond Cleavage.
Authors: WANG W.‐D. , EISENBERG R. 
Published: May 2016

AbstractThe bis(μ‐silylene) complexes (III) ((IIIb): space group C2/c, Z=4) are synthesized via the air sensitive and thermally unstable intermediates (IVa)‐(IVc) and (V), correspondingly, which are characterized by NMR and IR spectroscopies.
ChemInform Abstract: Phosphoranimine Phosphines and Arsines as Heterodifunctional Coordinating Ligands. Synthesis and Characterization of New Palladium(II) Metallacycles Cyclic RN=PPh2(CH2)nEPh2PdCl2 (R: SiMe3, GeMe3, H; n = 1, 2; E: P, As) and the Crystal and Molecular Structure of Cyclic HN=PPh2CH2PPh2PdCl2, the First Structural Example of a Phosphoranimine Phosphine Complex.
Authors: KATTI K. V. , BATCHELOR R. J. , EINSTEIN F. W. B. , CAVELL R. G. 
Published: May 2016

AbstractA first example of partial oxidation of diphosphines leads to heterodifunctional ligands such as (IIIa).
ChemInform Abstract: Hydroformylation of Chiral Terpenes with PtCl(SnCl3)(bis‐phosphine) as Catalyst.
Authors: KOLLAR L. , BAKOS J. , HEIL B. , SANDOR P. , SZALONTAI G. 
Published: May 2016

Abstract(+)‐(I) and (‐)‐(IV) are hydroformylated regiospecifically to give exclusively the linear aldehydes (III) and (V) without any trace of branched isomers.
ChemInform Abstract: Asymmetric Synthesis of 2‐Aminonorbornane‐2‐carboxylic Acids by Diels‐Alder Reaction.
Authors: CATIVIELA C. , LOPEZ P. , MAYORAL J. A. 
Published: May 2016

AbstractReaction of the menthyl dehydroalaninate (I) with cyclopentadiene (II) in the presence of TiCl4 gives rise to the isomers (III)‐(VI).
ChemInform Abstract: Synthesis of Aristotelia‐Type Alkaloids. Part 5. Biomimetic Synthesis of (.+‐.)‐Aristomakine and (.+‐.)‐Aristomakinine.
Authors: BURKARD S. , BORSCHBERG H.‐J. 
Published: May 2016

AbstractThe biomimetic syntheses of the title compounds (V) and (VII) are described.
ChemInform Abstract: Synthesis, Antiretrovirus Effects, and Phosphorylation Kinetics of 3′‐Isocyano‐3′‐deoxythymidine and 3′‐Isocyano‐2′,3′‐dideoxyuridine.
Authors: HIEBL J. , ZBIRAL E. , BALZARINI J. , DE CLERCQ E. 
Published: May 2016

AbstractThe deoxynucleosides (I) are coupled with the chlorosilane (II) and subsequently dehydrated to give the cyclonucleosides (III).
ChemInform Abstract: Synthesis of Benzopyran Derivatives. Part 6. Synthesis of Analogues of Precocenes Containing 6‐Chloro‐ or 6‐tert‐Butyl Substituents.
Authors: SEBOEK P. , TIMAR T. , JASZBERENYI J. C. , JEKOE J. 
Published: May 2016

AbstractPrecocenes are insect juvenile‐hormone antagonists.
ChemInform Abstract: Degradation of Electrochromic Amorphous WO3 Film in Lithium‐Salt Electrolyte.
Authors: HASHIMOTO S. , MATSUOKA H. , KAGECHIKA H. , SUSA M. , GOTO K. S. 
Published: May 2016

AbstractSIMS results obtained for an amorphous WO3 film (prepared by electron‐beam deposition) after coloring/bleaching cycles in LiClO4/propylene carbonate solution show that lithium accumulates in the WO3 films.
ChemInform Abstract: The Influence of Tungsten on the Pitting of Aluminum Films.
Authors: SHAW B. A. , FRITZ T. L. , DAVIS G. D. , MOSHIER W. C. 
Published: May 2016

AbstractAl‐8.5% W and Al‐10.3% W alloy films are prepared by co‐sputter deposition and their corrosion behavior is studied by potentiodynamic polarization in 0.1 M KCl.
ChemInform Abstract: Se2‐ 10, a Bicyclic Polyselenide.
Authors: FENSKE D. , KRAEUTER G. + , DEHNICKE K. 
Published: May 2016

AbstractBlack crystals of (III) containing the bicyclic Se12‐0 anion are prepared and the structure is studied by XRD (space group C2, Z=2; ‐70 °C).