bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis and Characterization of Binuclear Manganese Complexes: Redox Models for the Water Oxidation Cofactor of Photosystem II.
Authors: MATSUSHITA T. , SPENCER L. , SAWYER D. T. 
Published: May 2016

AbstractNew binuclear Mn complexes are prepared which exhibit a two‐electron‐redox chemistry that is compatible with the reversible oxidation of water to oxygen.
ChemInform Abstract: Phosphido‐Bridged Diiron Complexes from Low‐Coordinate Phosphorus Compounds.
Authors: WISIAN‐NEILSON P. , ONAN K. D. , SEYFERTH D. 
Published: May 2016

AbstractThe (methylene)phosphido‐bridged diiron complex (III) is prepared by reaction of the (methylene)phosphinous chloride (II) with the anionic complex (Ia) generated in situ from Fe3(CO)12, tBuSH, and LiBu.
ChemInform Abstract: Oxygen Atom Transfer Reactions to Metal Carbonyls. Kinetics and Mechanism of CO Substitution Reactions of M3(CO)12 (M: Fe, Ru, Os) in the Presence of (CH3)3NO.
Authors: SHEN J.‐K. , SHI Y.‐L. , GAO Y.‐C. , SHI Q.‐Z. , BASOLO F. 
Published: May 2016

AbstractThe rates of reaction and activation parameters for CO substitution reactions of (I) with L (II) in the presence of the amine oxide (III) are determined.
ChemInform Abstract: Surface‐Enhanced Raman Scattering from OH‐ Adsorbed on a Ag Electrode in Dilute Mg2+ Electrolytes.
Authors: DORAIN P. B. 
Published: May 2016

AbstractThe SERS spectra obtained for an Ag electrode immersed in 1·10‐2‐1·10‐3 M MgCl2 containing 50 μM KMnO4 or Cl2 are found to be near ly identical with those obtained in ≥ 1 M MgCl2.
ChemInform Abstract: In situ Modification of the Energetic Structure of the n‐GaP/NH3 Junction in the Presence of Solvated Electrons.
Authors: GUYOMARD D. , MATHIEU C. , HERLEM M. 
Published: May 2016

AbstractThe band‐edge position of the n‐GaP/electrolyte junction in different ammonia solutions can be followed without removing the electrode from the electrolyte.
ChemInform Abstract: Molybdenum Oxide Structure on Silica‐Supported Catalysts Studied by Raman Spectroscopy and Extended X‐Ray Absorption Fine Structure Spectroscopy.
Authors: KAKUTA N. , TOHJI K. , UDAGAWA Y. 
Published: May 2016

AbstractThe Raman spectrum of a calcined (773 K, 5 h, air) Mo/SiO2 catalysts of high Mo loading (20 wt.%) is identical with that of MoO3, whereas EXAFS results indicate that MoO3 is not the dominant species in the 20 wt.% Mo catalyst.
ChemInform Abstract: Oligophosphane Ligands. Part 27. RuH2(P(CH2CH2CH2PMe2)3): Formation, Protonation, CO2 Insertion, and Oxidative Addition of Benzene.
Authors: ANTBERG M. , DAHLENBURG L. , FROSIN K.‐M. , HOECK N. + 
Published: May 2016

AbstractAn extremely labile intermediate (IV) (yield in g) is isolated during the formation of the title complex (V).
ChemInform Abstract: Novel Basic Ligands for the Homogeneous Catalytic Carbonylation of Methanol. Part 16. (Ether‐Phosphane)‐Rhodium Complexes as Model Compounds in the Carbonylation of Methanol.
Authors: LINDNER E. , ANDRES B. 
Published: May 2016

AbstractIn the cationic (ether phosphine)‐Rh(I) complexes (III), prepared as shown, cyclooctadiene is easily displaced by CO (IV) with formation of the tricarbonyl analogues (V).
ChemInform Abstract: Tri‐ and Tetranuclear Palladium‐Cobalt Clusters Containing Bridging Ph2PCH2PPh2(dppm) Ligands. Crystal Structures of (Pd2Co2(μ3‐CO)2(CO)5(μ‐dppm)2) and (Pd2Co(μ3‐CO)2(CO)2(μ‐dppm)2) (PF6).
Authors: BRAUNSTEIN P. , DE MERIC DE BELLEFON C. , RIES M. , FISCHER J. , BOUAOUD S.‐E. , GRANDJEAN D. 
Published: May 2016

AbstractThe heterotetranuclear cluster (III) is synthesized according to the scheme and characterized by X‐ray structure analysis ((III)·2,5 THF: space group P1, Z=2).
ChemInform Abstract: Synthesis, Structure, and Catalytic Reactions of Dioxycarbene Complexes of Iron and Osmium.
Authors: WANG S.‐J. , MILLER L. L. , JACOBSON R. A. , ANGELICI R. J. 
Published: May 2016

AbstractThe triosmium carbonyl (I) reacts with ethylene oxide (II) in the presence of Br‐ under the described conditions to the dioxycarbene cluster compounds (III) and (IV).
ChemInform Abstract: Efficient Synthesis of 4‐Substituted 2,3‐Anhydro Sugars from 2,4‐Di‐O‐tosylates.
Authors: KOWOLLIK W. , VOELTER W. 
Published: May 2016

AbstractReaction of (I) with MeO‐, and subsequently N3‐ (or MeO‐) under more drastic conditions yields azide (VIa) (or methyl ether (VIb), respectively).
ChemInform Abstract: Blue Emitting Phosphors for Projection Cathode Ray Tubes: (La,Y)OBr:Ce and (La,Gd)OBr:Ce.
Authors: DE LEEUW D. M. , MUTSAERS C. A. H. A. , MULDER H. , KLAASSEN D. B. M. 
Published: May 2016

AbstractIt is demonstrated that by optimization of the preparation conditions for Ce3+ activated LaOBr and by substitution of Y or Gd for La efficient blue‐emitting cathode ray (CR) phosphors with emission colors comparable to that of ZnS:Ag can be produced.
ChemInform Abstract: Corrosion of Metal Oxide Ceramics in Molten Lithium‐Potassium Carbonates.
Authors: LESSING P. A. , YANG Z. Z. , MILLER G. R. , YAMADA H. 
Published: May 2016

AbstractIn order to develop alternative cathode materials for use in molten carbonate fuel cells (MCFC), the corrosion behavior of a great variety of metal oxides is studied (e.g., sintered pellets and powders of MTiO3, MZrO3, M: Ca, Sr, Ba, Mg, Li2; ZrTiO4, Co2TiO4, Ba2TiO4).
ChemInform Abstract: Preparation and Crystal Structures of Compounds Containing the TexS2+ 6‐x and TexSe2+ 6‐x Cations.
Authors: BURNS R. C. , COLLINS M. J. , EICHER S. M. , GILLESPIE R. J. , SAWYER J. F. 
Published: May 2016

AbstractThe study of the reactions between Se/Te mixtures and SbF5 or AsF5, resp., and between Se4(AsF6)2 and Te4(AsF6)2 results in the preparation of the compounds (I)‐(V) which contain the title cations (reactions in SO2, except for (IV) where a SO2/SO2ClF mixture is used as solvent, ratios of the starting materials and reaction times are given in a table, yields not given).
ChemInform Abstract: Production and Spectroscopic Identification of Bromothioborine, BrB=S from the Thermolysis of 2,4,6‐Trisbromo‐cyclo‐1,3,5‐trithia‐2,4,6‐triborane, (BrBS)3.
Authors: AZIZ S. G. , PORWOL T. , WATTS J. D. , SUFFOLK R. J. 
Published: May 2016

AbstractThe title compound (IV) is prepared in low yield (given in g) as outlined in the scheme and its thermolysis is studied by on line FTIR and He I photoelectron spectroscopy.
ChemInform Abstract: Two Extended Metal Chain Compounds, Y4I5C and Y6I7C2. Synthesis, Structure, Properties, and Bonding.
Authors: KAUZLARICH S. M. , HUGHBANKS T. , CORBETT J. D. , KLAVINS P. , SHELTON R. N. 
Published: May 2016

AbstractThe title compounds (IV) and (V) crystallize in the space group C2/m with Z=2.
ChemInform Abstract: Lawrencium Chemistry: No Evidence for Oxidation States Lower than 3+ in Aqueous Solution.
Authors: SCHERER U. W. , KRATZ J. V. , SCHAEDEL M. + , BRUECHLE W. + , GREGORICH K. E. , HENDERSON R. A. , LEE D. , NURMIA M. , HOFFMAN D. C. 
Published: May 2016

Abstract260Lr (T1/2:3 min) and other actinides (254Md, 255Md, 250Fm‐255Fm) are produced by 18O bombardment of a 249Bk target.
ChemInform Abstract: Deprotection of Tetrahydropyranyl and Silyl Ethers Catalyzed by Organotin Phosphate Condensates.
Authors: OTERA J. , NIIBO Y. , CHIKADA S. , NOZAKI H. 
Published: May 2016

AbstractThe catalyst, prepared from dibutyltin oxide and tributylphosphate at 250°C, mediates the cleavage of the tetrahydropyranyl ethers (I) or the siloxyalkanes (III) to produce the corresponding alcohols (II) and (IV).
ChemInform Abstract: Vinylspiropentane.
Authors: ZEFIROV N. S. , KOZHUSHKOV S. I. , KUZNETSOVA T. S. , LUKIN K. A. , KAZIMIRCHIK I. V. 
Published: May 2016

AbstractIn the presence of Pd(OAc)2 the cyclopropanation of the allene (II) by diazomethane (III) affords a 27:63 mixture of the 2‐bromoethylspiropentane (IV) and 1‐bromo‐3‐cyclopropylidenepropane.
ChemInform Abstract: Synthesis of Some 4‐Aryl‐2‐(5′‐mercapto‐1′,3′,4′‐oxadiazol‐2′‐ylmethylmercapto)thiazoles and Their Derivatives.
Authors: AHLUWALIA V. K. , ARORA K. K. , MEHTA B. 
Published: May 2016

AbstractThe title compounds (VI) as well as their S‐methyl derivatives (yield: 75‐82%) are tested for their in vitro antifungal and antibacterial activity.
ChemInform Abstract: Synthesis and Copper‐Dependent Antimycoplasmal Activity of 1‐Amino‐3‐(2‐pyridyl)isoquinoline Derivatives. Part 1. Amides.
Authors: DE ZWART M. A. H. , VAN DER GOOT H. , TIMMERMAN H. 
Published: May 2016

AbstractThe synthesis of the aminoisoquinoline (III) is improved.
ChemInform Abstract: Preparation and Ligand Properties of Thionylimino Derivatives of Arsenic(III). X‐Ray Crystal Structure of Cr(CO)5(Ph2AsNSO).
Authors: CHIVERS T. , DHATHATHREYAN K. S. , LENSINK C. , RICHARDSON J. F. 
Published: May 2016

AbstractThe thionylimino‐As(III) compounds (III) are prepared according to the scheme shown.
ChemInform Abstract: The Ligational Behavior of Thiosemicarbazones and Semicarbazones with Tellurium(IV): Reactions with TeCl4.
Authors: BASUMATARY J. K. , SINGH A. K. , KHANDELWAL B. L. , MCWHINNIE W. R. 
Published: May 2016

AbstractTeCl4 dissolved in dry benzene reacts with thiosemicarbazones without any phenolic group to yield the complexes (I).
ChemInform Abstract: Synthesis and X‐Ray Crystal Structure of a Weak Molecular Adduct of Diphenylmercury(II) with 1,2‐Bis(diphenylphosphinothioyl)ethane.
Authors: LOBANA T. S. , SANDHU M. K. , TIEKINK E. R. T. 
Published: May 2016

AbstractThe title compounds react in CHCl3 at reflux temp. to give an 1:1 adduct with weak Hg‐S interactions, which crystallizes in P1 with Z=1.
ChemInform Abstract: Synthesis, Magnetic Properties, Redox Behavior, and Crystal Structure of the Bridged Binuclear Nickel(II) Complex (Ni2(μ‐OH)(μ‐CH3CO2)2L2)ClO4·H2O.
Authors: CHAUDHURI P. , KUEPPERS H.‐J. + , WIEGHARDT K. , GEHRING S. , HAASE W. , NUBER B. , WEISS J. 
Published: May 2016

AbstractThe binuclear title complex (III) crystallizes in the space group P41212 with Z=4.
ChemInform Abstract: Synthesis, Spectroscopy, and Crystal Structure of a Thiocyanato‐Bridged Mixed‐Valence Copper(I)‐Copper(II) Compound with the Ligand 1,6‐Bis(5′‐methylimidazol‐4′‐yl)‐2,5‐dithiahexane.
Authors: BOUWMAN E. , DRIESSEN W. L. , REEDIJK J. 
Published: May 2016

AbstractThe catena‐title complex (I) is synthesized by reaction of Cu(NO3)2 and NH4SCN with the ligand in ethanol (no yield given).
ChemInform Abstract: Formation and Properties of the Binuclear Complex (NH3)5Ru(III)NCFe(II)(CN)‐ 5.
Authors: BUREWICZ A. , HAIM A. 
Published: May 2016

AbstractKinetics and mechanism of the formation reaction of the title complex from (Ru(NH3)5(H2O))3+ and (Fe(CN)6)4‐ are studied under anaerobic conditions at pH 4.0 to 5.32 spectrophotometrically.
ChemInform Abstract: Hexacoordinated Mixed Halogeno Anions of Te(IV): Crystallographic and Raman Spectroscopic Investigation of Rb2TeBr3.5Cl2.5.
Authors: ABRIEL W. , EHRHARDT H. 
Published: May 2016

AbstractThe title compound, prepared by precipitation from TeBr4 (obtained from the elements) solution in HCl containing Rb cations, crystallizes in the space group Fm3m with Z=4 (K2PtCl6 type).
ChemInform Abstract: Characterization of the Polycrystalline n‐CuInSe2‐Indium Oxide/Polyiodide Junction by Electrolyte Electroreflectance, Cyclic Voltammetry, and Scanning Electron Microscopy.
Authors: RAZZINI G. , PERALDO BICELLI L. , SCROSATI B. , PUJADAS M. , SALVADOR P. 
Published: May 2016

AbstractSystematic electrolyte electroreflectance measurements of the flatband potential (VFB) are performed on etched and In‐oxide coated polycrystalline n‐CuInSe2 electrodes in contact with a polyiodide electrolyte at different pH values.
ChemInform Abstract: Interaction Between Electron Donor and Acceptor Groups in Some Trisubstituted Benzenes. Part 1. Relative Reactivities of 4‐Substituted 1,2‐Dinitrobenzenes Toward Sodium Methoxide.
Authors: PATIL S. D. , NAIR P. M. 
Published: May 2016

AbstractThe rates of displacement of the 2‐nitro group in (I) to give (III) are in the order expected from the inductive effect of the substituents.
ChemInform Abstract: Competing Formation of Endoperoxides and Hydroperoxides in the Reaction of 1O2 with Cyclic Conjugated Dienes.
Authors: MATUSCH R. , SCHMIDT G. 
Published: May 2016

AbstractContrary to claims in the literature 1O2 does not react with (R)‐α‐phellandrene (I) and α‐terpinene (X) to give exclusively the endoperoxides (III) + (IV) and (XI), resp., by (4 + 2) cycloaddition; hydroperoxides (see scheme) are formed as well.
ChemInform Abstract: Electron Transfer. Part 92. Reductions of Vitamin B12a (Hydroxocobalamin) with Formate and Related Formyl Species.
Authors: LINN D. E. JUN. , GOULD E. S. 
Published: May 2016

AbstractStudies show that vitamin B12a is reduced to B12r (cob(II)alamine) with formate in aqueous media.
ChemInform Abstract: Ureas and Amides Derived from N‐(5‐Norbornen‐2‐ylmethyl)bornan‐2‐exo‐amine with Antiarrhythmic and Other Activities.
Authors: RANISE A. , BONDAVALLI F. , SCHENONE P. , ANGRISANI M. , LISA M. , MARRAZZO R. , MARMO E. 
Published: May 2016

AbstractCoupling of camphor nitrimine (I) with the norbornenylmethylamine (II) yields the imine (III) which is reduced to give the amine (IV).
ChemInform Abstract: Studies on Lactams. Part 80. Antipodal Forms of β‐Lactams via Stereospecific Reactions.
Authors: WAGLE D. R. , GARAI C. , MONTELEONE M. G. , BOSE A. K. 
Published: May 2016

Abstract3,4‐Disubstitued 1‐aryl‐2‐azetidinones such as the compounds (I) ‐(III), which are possible precursors of various natural products, are prepared by enantiospecific synthesis.
ChemInform Abstract: Synthesis and Pharmacological Activity of Aminoalkyl Esters in the Benzofuran Series.
Authors: ZOTOVA S. A. , GOLOLOBOVA T. M. , GALENKO‐YAROSHEVSKII P. A. , IVANOVA N. I. , EGIK'YAN A. L. , TIKHONOVA N. A. , LINCHENKO S. N. , BARTASHEVICH V. V. 
Published: May 2016

AbstractIn the search for compounds with local anesthetic activity, the diethylaminoethyl benzofurancarboxylates (III) and their Mannich bases (V) and (VI) are prepared from the sodium salts (I).
ChemInform Abstract: Titanium as a Regio‐ and Stereoselective Control Element in the Reaction of α‐Alkoxyallylic Phosphine Oxide Anions with Carbonyl Compounds.
Authors: BIRSE E. F. , MCKENZIE A. , MURRAY A. W. 
Published: May 2016

AbstractCondensation of the methoxyallylphosphine oxides (I) with the aldehydes (III) proceeds at the α‐position of the allyl system to give the diastereomeric adducts (IV) and (V).
ChemInform Abstract: X‐Ray Structural Analysis of the Ethylation Product of 1‐(Trimorpholinophosphazido)‐2,4,6‐trinitrobenzene.
Authors: CHERNEGA A. N. , ANTIPIN M. YU. , STRUCHKOV YU. T. , BOLDESKUL I. E. , PONOMARCHUK M. P. , KASUKHIN L. F. , KUKHAR' V. P. 
Published: May 2016

AbstractEthylation of the phosphazido compound (I) with the oxonium salt (II) regioselectively produces the ethyl derivative (III) with retention of the E‐configuration in the PN3 fragment.
ChemInform Abstract: Investigation of 2‐(1‐Imidazolyl)‐5,5‐dimethyl‐1,3,2‐dioxaphosphorinane.
Authors: NIFANT'EV E. E. , GRACHEV M. K. , BEKKER A. R. , VASYANINA L. K. , KOROTEEV A. M. 
Published: May 2016

AbstractThe title compound (III) is prepared by reaction of the halodioxaphosphorinanes (I) with sodium imidazolide (II).
ChemInform Abstract: Effect of the Counterion on the Structures of Tetraphenylantimony(V)‐Stibonium Compounds: Crystal and Molecular Structures of Tetraphenylantimony(V) Bromide, Perchlorate, and Tetraphenylborate.
Authors: FERGUSON G. , GLIDEWELL C. , LLOYD D. , METCALFE S. 
Published: May 2016

AbstractFollowing studies of the length of ylidic Sb‐C bonds, crystal and molecular structures of stibonium salts are investigated.
ChemInform Abstract: Divinyl Ditellurides: Synthesis and Reactivity.
Authors: DABDOUB M. J. , COMASSETO J. V. 
Published: May 2016

AbstractTreatment of the Grignard compounds (I) with tellurium (II) and subsequent oxidation of the intermediate bromomagnesium ethenetellurates with air yield the divinyl ditellurides (III).
ChemInform Abstract: Generation of (α‐(Alkoxycarbonyl)vinyl)aluminum and Aluminum Allenolates by the Hydroalumination of α,β‐Acetylenic Carbonyl Compounds and Their Reaction with Carbonyl Compounds.
Authors: TSUDA T. , YOSHIDA T. , SAEGUSA T. 
Published: May 2016

AbstractTreatment of the α,β‐acetylenic carbonyl compounds (I) or (IV) with di‐isobutylaluminum hydride (II) in the presence of HMPA generates the α‐(alkoxycarbonyl)vinyl aluminum (III) and the aluminum allenolates (V) which are studied spectroscopically.
ChemInform Abstract: Preparation of a Thallium(I) Diazotate. Structure, Physicochemical Characterization, and Conversion to Novel N‐Nitroso Compounds.
Authors: KEEFER L. K. , WANG S. , ANJO T. , FANNING J. C. , DAY C. S. 
Published: May 2016

AbstractTl(I) (E)‐methanediazotate (IV) is prepared as shown and characterized.
ChemInform Abstract: Antitumor Activity of Organotin Compounds. Reaction, Synthesis and Structure of Et2SnCl2(phen) with 5‐Fluorouracil.
Authors: WAN J. , HUANG J. , HUANG L. , SHI D. , HU S. 
Published: May 2016

AbstractThe antitumor agent (I) reacts with 5‐fluorouracil (II) to form (III) by a basic catalytic process.
ChemInform Abstract: Photochemical Synthesis Method of Tungsten(II) Complexes (WCl2(CO)3(PPh3)2) and (WCl2(CO)2(dppe)).
Authors: SZYMANSKA‐BUZAR T. 
Published: May 2016

AbstractThe reaction course, leading via intermediates (generated by the use of light) to stable complexes (IV) or (VI) is discussed.
ChemInform Abstract: High‐Spin Iron(II) Complexes of ortho‐Functionalized Paraquinones as Models for Quinone Binding Sites in Reaction Centers of Photosynthetic Bacteria.
Authors: PADHYE S. , GARGE P. , GUPTA M. P. 
Published: May 2016

AbstractIn an attempt to mimic the iron‐quinone couple of the bacterial reaction center the IR spectral, magnetic and Moessbauer characterization of the high‐spin Fe(II) complexes (I) is reported.
ChemInform Abstract: Reactions of 1‐(2‐Halomethyl)ethylenediamines in Nickel(II) Complexes. Intraspherical Synthesis of 1,4‐Bis((2‐aminoethyl)aminoethyl)piperazine.
Authors: UKRAINTSEV V. B. , RADZHABOV T. , BOBYLEV V. A. , KUKUSHKIN YU. N. , YAKOVLEV S. V. 
Published: May 2016

AbstractTreatment of the haloethylethylendiamine complexes (I) with gaseous ammonia (II) give the piperazine complexes (III).
ChemInform Abstract: Tri‐, Tetra‐, Penta‐, and Hexanuclear Phenylphosphinidene‐Capped Products from the Reaction of Dodecacarbonyltriruthenium with Phenylphosphine: Crystal Structures of (Ru4(μ4‐PPh)2(μ‐CO)(CO)10), (Ru5(μ4‐PPh)(μ‐PPh(OPrn))(μ‐H)(CO)13), (Ru6(μ4‐PPh)2(μ3‐PPh)2(CO)12), and (Ru6(μ4‐PPh)3‐(μ3‐PPh)2(CO)12).
Authors: FIELD J. S. , HAINES R. J. , SMIT D. N. 
Published: May 2016

AbstractThe reaction of Ru3(CO)12 with phenylphosphine in refluxing toluene affords a range of products (I)‐(X), the nature and yields of which are dependent on the reaction times and the molar ratios employed.
ChemInform Abstract: Transition‐Metal Complexes with Sulfur Ligands. Part 35. Elementary Reactions at Metal‐Sulfur Centers: Base‐Induced Substitution of PPh3 in (Ru(PPh3)2(bmae)).
Authors: SELLMANN D. , KAEPPLER O. + 
Published: May 2016

AbstractIn order to gain an understanding of the mode of interaction of numerous oxidoreductases (from sulfite oxidase to nitrogenases) model reactions are carried out on the Ru complexes (I) and (IV).
ChemInform Abstract: Ascorbic Acid Photoreductions of Zinc(II) Chlorophyll Derivatives: Access to Metal‐Free Isobacteriochlorins.
Authors: SIMPSON D. J. , SMITH K. M. 
Published: May 2016

AbstractThe photoreduction of the pyropheophorbide a (I) in the presence of a large excess of DABCO leads to the cis‐ethylidene derivative (II) as the main product, which can be demetalated to the free base at low temp. under exclusion of oxygen.
ChemInform Abstract: Acid‐Catalyzed Rearrangements of Steroid Alkenes. Part 2. A Reinvestigation of the Backbone Rearrangement of Cholest‐5‐ene.
Authors: PEAKMAN T. M. , ELLIS K. , MAXWELL J. R. 
Published: May 2016

AbstractThe rearrangement of the title steroid (I) leads to the products (II) and (III).
ChemInform Abstract: Synthesis and Nuclear Magnetic Resonance Studies of Some N‐Acylated Methyl 4‐Amino‐4,6‐dideoxy‐α‐D‐mannopyranosides.
Authors: KENNE L. , UNGER P. , WEHLER T. 
Published: May 2016

AbstractThe aminomannopyranoside (IIIa) is prepared from the bromide (I) via the corresponding azide.
ChemInform Abstract: 3‐(3‐Pyrrolyl)thiopyrrolidones as Precursors of Benzo(1,2‐b:4,3‐b′)dipyrroles. Synthesis of Intermediates and Analogues Related to the Phosphodiesterase Inhibitors PDE I and PDE II and Antitumor Antibiotic CC‐1065.
Authors: SUNDBERG R. J. , HAMILTON G. S. , LAURINO J. P. 
Published: May 2016

AbstractCyclization of the 3‐(3‐pyrrolyl)thiopyrrolidone (I) gives the benzo‐(1,2‐b:4,3‐b')dipyrrole (III).
ChemInform Abstract: Use of Bistrimethylsilylated Intermediates in the Preparation of Semisynthetic 7‐Amino‐3‐Substituted‐cephems. Expedient Syntheses of a New 3‐((1‐Methyl‐1‐pyrrolidinio)methyl)cephalosporin.
Authors: WALKER D. G. , BRODFUEHRER P. R. , BRUNDIDGE S. P. , SHIH K. M. , SAPINO C. JUN. 
Published: May 2016

AbstractTreatment of the 7‐aminocephalosporin (I) with hexamethyldisilazane (II) gives the bistrimethylsilylated intermediate which is converted to the iodomethyl compound (IV).
ChemInform Abstract: Silicon Nitride Passivant for HgCdTe n+p Diodes.
Authors: KAJIHARA N. , SUDO G. , MIYAMOTO Y. , TANIKAWA K. 
Published: May 2016

AbstractA SiNx film deposited by electron cyclotron resonance (ECR) plasma CVD is successfully applied as surface passivating coating for Hg0.7Cd0.3Te n+p diodes.
ChemInform Abstract: Dinitrogen Sulfide, N2S, Revealed by Photoelectron Spectroscopy.
Authors: BENDER H. , CARNOVALE F. , PEEL J. B. , WENTRUP C. 
Published: May 2016

AbstractHe I photoelectron spectroscopic measurements confirm that the reactive N2S molecule is a major product of the thermal decomposition of (I).
ChemInform Abstract: Structural and Magnetic Properties of Mn1‐tCrtAs1‐xPx
Authors: FJELLVAG H. , KJEKSHUS A. , STOELEN S. , ANDRESEN A. F. 
Published: May 2016

Abstractare studied for samples in the ranges 0 < t < 1.0 and 0 < x < 0.2 by X‐ray and neutron diffraction, DTA, and magnetic susceptibility measurements.
ChemInform Abstract: Synthesis and Properties of Tetrafluorochlorates(III) of Alkali Metals.
Authors: POPOV A. I. , KISELEV YU. M. , SUKHOVERKHOV V. F. , CHUMAEVSKII N. A. 
Published: May 2016

AbstractThe title compounds, MClF4 (M: K, Rb, Cs), are prepared by reaction between MF (M: K, Rb, Cs) and ClF3.
ChemInform Abstract: Stereoselective Synthesis of 3,5‐Alkadienoic Esters from 2,4‐Dienoic Isomers.
Authors: TSUBOI S. , SAKAMOTO J. , KURODA A. , UTAKA M. , TAKEDA A. 
Published: May 2016

AbstractTreatment of the (2E,4Z)‐esters (I) according to the conditions indicated yields the (3E,5E) isomers (II) together with (IV) (stereoselectivity: 81‐98%).
ChemInform Abstract: Cycloaddition Reactions of 2‐Hydroxy‐, 2‐Amino‐, and 2‐Mercapto‐1‐azaazulenes with Reactive Acetylenes.
Authors: ABE N. , TAKEHIRO T. 
Published: May 2016

AbstractThe title compounds (I), (VIII) or (XI) undergo cycloaddition with the dicarboxylate (II) to give a variety of products.
ChemInform Abstract: Condensation and Cyclization Reactions of 2‐Hydrazinobenzimidazole, ‐benzoxazole, and ‐benzothiazole.
Authors: BADR M. Z. A. , MAHMOUD A. M. , MAHGOUB S. A. , HOZIEN Z. A. 
Published: May 2016

AbstractStarting from the title compounds (III), a variety of cyclization products such as (I), (V) or (VI) and condensation products such as (VIII) are prepared.
ChemInform Abstract: Salt Effects in Electron‐Transfer‐Induced Photooxygenation of 1,1‐Diphenyl‐2‐vinylcyclopropane.
Authors: SHIM S. C. , LEE H. J. 
Published: May 2016

AbstractThe quantum yield of the dioxolane (II) is increased dramatically in the presence of Mg(ClO4)2.
ChemInform Abstract: Palladium‐Catalyzed Allylic Alkylation of Carbonucleophiles with Allylic Borates or Allylic Alcohols and Boron Oxide Under Neutral Conditions.
Authors: LU X. , JIANG X. , TAO X. 
Published: May 2016

AbstractTriallyl borate (I) reacts with the carbonucleophiles (II) in the presence of a Pd phosphine catalyst, yielding the bisallylated products (III).