bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Synthesis and Characterization of Novel Flavin‐Linked Porphyrins. Mechanism for Flavin‐Catalyzed Inter‐ and Intramolecular 2e/1e Electron‐Transfer Reactions.
Authors: TAKEDA J. , OHTA S. , HIROBE M. 
Published: May 2016

AbstractThe synthesis of the novel title porphyrins (Va) and (XIIIa) is described, the precursor compound (XIIb) is obtained analogously to (XIIa).
ChemInform Abstract: Dialkylamino Phosphorus Metal Carbonyls. Part 4. Novel Phosphorus‐Bridging Carbonyl Derivatives and Triphosphine Derivatives from Reactions of Tetracarbonylferrate(‐II) with (Dialkylamino)dichlorophosphines.
Authors: KING R. B. , WU F.‐J. , HOLT E. M. 
Published: May 2016

AbstractThe major products from reaction of the sterically hindered aminodichlorophosphines (II) with Na2Fe(CO)4 (I) in ether are the air‐stable, crystalline, binuclear complexes (III).
ChemInform Abstract: Effects of TiO2 Addition to LiNbO3 on the Cation Vacancy Content, Curie Temperature, and Lattice Constants.
Authors: GALLAGHER P. K. , O'BRYAN H. M. 
Published: May 2016

AbstractIt is shown that the Curie temp. (Tc) and the limits of solubility are determined by the cation vacancy content regardless of whether these are formed by Li deficiency or the addition or substitution of aliovalent ions.
ChemInform Abstract: Hydrogen‐Induced TiOx Migration onto Metallic Rh in Real Rh/TiO2 Catalysts
Authors: MUNUERA G. , GONZALEZ‐ELIPE A. R. , ESPINOS J. P. , CONESA J. C. , SORIA J. , SANZ J. 
Published: May 2016

Abstractis observed by XPS combined with sputtering methods.
ChemInform Abstract: Study of Oxidic and Reduced Alumina‐Supported Molybdate and Heptamolybdate Species by in situ Laser Raman Spectroscopy.
Authors: PAYEN E. , GRIMBLOT J. , KASZTELAN S. 
Published: May 2016

AbstractThe Mo‐loading of the γ‐Al2O3 support is investigated in situ during the preparation of molybdate‐ and heptamolybdate‐supported catalysts (impregnation, calcination, reduction, reoxidation) and the influence of Ni or Co promoter ions on reduction and reoxidation of the heptamolybdate catalysts is also being studied.
ChemInform Abstract: Breakdown of Passive Films on Iron.
Authors: BIRD H. E. H. , PEARSON B. R. , BROOK P. A. 
Published: May 2016

AbstractPitting breakdown of pure iron has been studied in NaCl solutions in the pH range 10‐14. The experimental results show that pit initiation is a function of the Cl‐/OH‐ ratio at the surface, i.e., the first stages of localized passive film breakdown depend on the competition for adsorption, at the oxide/liquid interface, between OH‐ and aggressive anions such as Cl‐.
ChemInform Abstract: The Pitting Corrosion Characteristics of Borides‐Strengthened Nickeland Iron‐Based Microcrystalline Alloys
Authors: CHEN T. Y. , SZKLARSKA‐SMIALOWSKA Z. 
Published: May 2016

Abstractis studied by the cyclic potentiodynamic technique in 1 M NaCl solution at 25‐80 °C. A higher Cr content in the microcrystalline alloys is found to provide greater resistance to pitting.
ChemInform Abstract: A2Ln2Ti3O10 (A: K or Rb; Ln: La or Rare Earth Metal): A New Series of Layered Perovskites Exhibiting Ion Exchange.
Authors: GOPALAKRISHNAN J. , BHAT V. 
Published: May 2016

AbstractThe title perovskites are synthesized by heating appropriate mixtures of A2CO3, Ln2O3 (Ln: La, Nd, Sm, Gd, Dy), and TiO2 in air at 1000 °C for 2 d. The hygroscopic compounds and their monohydrates both crystallize in a tetragonal structure similar to Sr4Ti3O10.
ChemInform Abstract: Metal‐Nucleotide Interactions: Crystal Structures of Ca(Cu(5′‐GMP)2(en)(H2O)2)·8 H2O (5′‐GMP = Guanosine 5′‐Monophosphate, en = Ethylenediamine) and Ca(Cu(5′‐IMP)2(H2O)4)·6.7 H2O (5′‐IMP = Inosine 5′‐Monophosphate).
Authors: MANGANI S. , ORIOLI P. 
Published: May 2016

AbstractBoth the title complexes are prepared by mixing in aqueous solution stoichiometric amounts of (Cu(en)(OH2)2)SO4 and the sodium salt of 5'‐GMP or 5'‐IMP in the presence of Ca(II) ions (pH ∼ 7)(no yields given).
ChemInform Abstract: Acyl Derivatives of Cyclic Secondary Amines. Part 1. Dipole Stabilization of Anions: The Cumulative Effect of Two Stabilizing Groups.
Authors: KATRITZKY A. R. , MURUGAN R. , LUCE H. , ZERNER M. , FORD G. P. 
Published: May 2016

AbstractLithiation studies (iPr2N‐Li or tBu‐Li) with acyl derivatives (Ia), (Ib), (IIa), (IIb), (IIIa), and (IIIb) indicate that no substantial increase in carbanion stability occurs as a result of the introduction of the second stabilizing group.
ChemInform Abstract: Organic Synthesis Using Haloboration Reactions. Part 13. E‐(2‐Bromomethyl)dibromoborane. A New Precursor for E‐1,2‐Disubstituted Ethenes.
Authors: HYUGA S. , CHIBA Y. , YAMASHINA N. , HARA S. , SUZUKI A. 
Published: May 2016

Abstractβ‐Bromovinyldibromoborane (III), prepared from acetylene (I) and boron tribromide (II), reacts with the organozinc chlorides (IV) in the presence of a Pd(0) catalyst, generated from PdCl2(PPh3)2 in situ, to give the 1‐alkenylboron dibromides (V).
ChemInform Abstract: Nucleophilic Aromatic Substitution: Effect of Complexation on the Alkaline Hydrolysis of 4‐Aminophenylazobenzothiazolium Dyes.
Authors: D'ROZARIO A. P. , WILLIAMS A. , PARTON B. 
Published: May 2016

AbstractThe hydrolysis of (Ia) is inhibited by substituted benzoate and benzenesulfonate anions and phenolate ions due to complexation.
ChemInform Abstract: Synthesis and Structure of 2′‐Fluoro‐2′,2′‐dinitroethyl‐2′′‐fluoro‐2′′‐ nitroethylene Carboxime O‐Bis(2‐fluoro‐2,2‐dinitroethyl)nitromethyl Ether.
Authors: EREMENKO L. T. , ATOVMYAN L. O. , GOLOVINA N. I. , ORESHKO G. V. , FADEEV M. A. 
Published: May 2016

AbstractThe title compound (II) is obtained by decomposition of the nonanitro compound (I) in solution.
ChemInform Abstract: Reduction of Azides to Amines with Nickel Boride.
Authors: SARMA J. C. , SHARMA R. P. 
Published: May 2016

AbstractReduction of azides such as (I), (III), and (V), yielding the corresponding amines (II), (IV), and (VI), is carried out with nickel boride generated in situ from sodium borohydride and nickel chloride.
ChemInform Abstract: Preparation of 1‐Nitro‐1,3‐dienes via Nitrotrifluoroacetoxylation of 1,3‐Dienes.
Authors: BLOOM A. J. , MELLOR J. M. 
Published: May 2016

AbstractThe 1,3‐dienes (I) react with trifluoroacetyl nitrate generated in situ from (II) and (III) to give mixtures of 1,2‐ and 1,4‐nitrotrifluoroacetates, which without isolation undergo base treatment to afford the title compounds (IV).
ChemInform Abstract: Stereoselective Synthesis of Ethyl 2E,4Z‐Decadienoate from Glyoxal Monoacetal.
Authors: STAMBOULI A. , AMOUROUX R. , CHASTRETTE M. 
Published: May 2016

AbstractThe glyoxal monoacetals (II) react with the phosphonate (III) to yield the α,β‐unsaturated esters (IV).
ChemInform Abstract: Hydrocarboxylation of Unsaturated Carboxylic Acids and Their Esters with Cobalt Carbonyl/Pyridine Complex Catalyst Systems.
Authors: FELL B. , JIN Z. 
Published: May 2016

AbstractThe hydrocarboxylation of all regioisomeric n‐hexenoic acids (Ia) ‐ (IVa) or their methyl esters (Ib) ‐ (IVb) with 200 bar CO (V) at 160 ‐ 180°C in the presence of Co2(CO)8 or a Co2(CO)8/pyridine catalyst system is investigated.
ChemInform Abstract: Boron Trifluoride‐Promoted Reaction of Benzenesulfenanilides with Alkenes in Acetonitrile and Benzonitrile: Amidino‐ and Amidosulfenylation of Alkenes.
Authors: BENATI L. , MONTEVECCHI P. C. , SPAGNOLO P. 
Published: May 2016

AbstractBenzenesulfenanilides (I) react at room temp. with alkenes (III) or (VIII) in MeCN (IV) in the presence of BF3·Et2O to give amidino sulfides (V), (IX), (XI) as the main products together with various yields of the arylamino sulfides (VI), (XII) and amidosulfides (VII), (X).
ChemInform Abstract: Synthesis of Some Esters by the Reactions of 1,4‐Dichloro‐ and 1,4‐Dibromo‐2‐methylbut‐2‐ene with Carboxylic Acids.
Authors: MAGERRAMOV M. N. , ALEKPEROV K. A. , LYUTFALIEV A. G. , MIRZOEV B. M. , GUSEINOVA R. T. 
Published: May 2016

AbstractA 1:2 molar mixture of the 1,4‐dihalo‐2‐methylbutenes (I) and the potassium alkanoates (II) reacts to produce the diesters (III) in good yields.
ChemInform Abstract: Trimethylsilyl Chlorochromate. An Efficient Reagent for Oxidation of Arylmethanes to Aromatic Aldehydes.
Authors: LEE J. G. , LIM H. J. , HA D. S. 
Published: May 2016

AbstractOxidation of toluene and methyl‐ or halo‐substituted toluenes with the title reagent or with chromyl chloride leads to similar yields of the corresponding monoaldehydes.
ChemInform Abstract: Fluorine‐Containing Imines. Part 6. Reaction of Hexafluoroacetone Perfluoropivaloylimine with Dimethylaniline and Dimethylbenzylamine.
Authors: GAMBARYAN N. P. , DEL'TSOVA D. P. , SAFRONOVA Z. V. , KAITMAZOVA G. S. 
Published: May 2016

AbstractDuring the reaction of the acyl imine (I) with N,N‐dimethylaniline (II) C‐alkylation takes place, producing the isocyanate (III).
ChemInform Abstract: Reactions of 2,4‐Dimethylphenylmercury and Pentamethylphenylmercury Acetate with Olefins in the Presence of Pd(II) and Pt(IV) Complexes.
Authors: NIZOVA G. V. , SHUL'PIN G. B. 
Published: May 2016

AbstractStyrene (II) is arylated by the phenylmercury acetates (I) to give the trans‐stilbenes (III).
ChemInform Abstract: Regioselective Preparation of Tricyclic Terpene Ring Systems by Cycloaddition of 1,3,3‐Trimethyl‐2‐vinylcyclohexene with Unsymmetrical Quinones.
Authors: ENGLER T. A. , NAGANATHAN S. , TAKUSAGAWA F. , YOHANNES D. 
Published: May 2016

AbstractThe trimethylsilylvinylcyclohexene (II) is coupled with the unsymmetrical quinones (Ia) ‐ (Ic) in the presence of ZnBr2 under elevated pressure to give the Diels‐Alder adducts (III).
ChemInform Abstract: Synthesis of a Functionalized 4‐Prenylated Indole Using a Carboxylic Cleavage Reaction.
Authors: HATTINGH W. C. , HOLZAPFEL C. W. , VAN DYK M. S. 
Published: May 2016

Abstract8‐Nitro‐1,4‐dihydronaphthalene (I) is allowed to react with the nitrosonium salt (II) to form cycloadducts which are trapped by addition of potassium cyanide (III), producing the regioisomers (IV) and (V).
ChemInform Abstract: Cyclic Hydroxamic Acids: Synthesis of 4‐Hydroxy‐1H‐1,2,4‐triazolin‐5ones.
Authors: SCHAPER W. 
Published: May 2016

AbstractThe acylhydrazines (I) are acylated with the acid chlorides (II) to give the diacylhydrazines (III) which are cyclized with hydroxylamine (IV) to yield the N‐hydroxytriazolinones (V).
ChemInform Abstract: Synthesis and Biological Activity of (Acridin‐9‐ylmercapto)acetic Acids and Their Derivatives.
Authors: GAIDUKEVICH A. N. , KAZAKOV G. P. , KRAVCHENKO A. A. , POROKHNYAK L. A. , PINCHUK V. V. , VELIKII D. L. 
Published: May 2016

AbstractStarting with the 9‐chloroacridines (I), the thioacetic acid derivatives (V) and their salts (VI) are prepared.
ChemInform Abstract: The Use of Some Activated Nitriles in Heterocyclic Syntheses.
Authors: MARTIN N. , PASCUAL C. , SEOANE C. , SOTO J. L. 
Published: May 2016

Abstractα‐Cyanocinnamonitrile (I) is coupled with acetylacetone (II) to give the 2:1‐adduct (III) and the 1:1‐adduct (IV).
ChemInform Abstract: New Method of Preparation, Structure, and Properties of 3‐Aryl‐4‐thiono‐6‐cyano‐7‐aryliminothiopyrano(2,3‐d)pyrimidines.
Authors: KULAEVA L. N. , PEL'KIS P. S. , LOZINSKII M. O. , SOKOLOVA YU. A. , D'YACHENKO O. A. , ATOVMYAN L. O. 
Published: May 2016

AbstractThe title compounds (III) are prepared in a one‐step reaction from the cyanothioacetanilides (I) and the orthoformate (II).
ChemInform Abstract: Synthesis of Unsymmetrical N,N′‐Diaminophosphoryl Derivatives of Aminocyclohexane and Stereoisomeric 4‐Aminocyclohexanecarboxylic Acids.
Authors: KOSYKHOVA L. A. , PIKSHILINGAITE YU.‐V. K. , MIKUL'SKIS P. P. , KARPAVICHYUS K. I. , KNUNYANTS I. L. 
Published: May 2016

AbstractThe phosphoramidic dichlorides (I) are treated with the cyclohexylamines (II) followed by reaction with the cyclic amines (III) to give the phosphoric acid triamides (IV).
ChemInform Abstract: Reaction of Bis(hydroxymethyl)phenylphosphine with Dimethylformamide Dimethyl Acetal.
Authors: IONKIN A. S. , ERASTOV O. A. , ARBUZOV B. A. 
Published: May 2016

AbstractThe title reaction gives the dioxaphosphorinane (III), together with the dimethylaminomethylenephosphine (IV).
ChemInform Abstract: Synthesis of 1,4‐Diphenyl‐3‐(2‐hydroxyphenyl)‐6,7‐benzo‐2,8,9‐trioxa‐4‐ phospha‐1‐boratabicyclo(3.3.1)nonane Triethylammonium Salt.
Authors: NIKONOV G. N. , KARASIK A. A. , ERASTOV O. A. , ARBUZOV B. A. 
Published: May 2016

AbstractPhenylphosphine (I), salicylaldehyde (II), and phenylboronic acid anhydride (III) react in the presence of triethylamine (IV) to give the salt (V).
ChemInform Abstract: Synthesis, Structural Characterization, and Properties of the Organothorium Alkylthiolate Complex ((CH3)5C5)2Th(SCH2CH2CH3)2.
Authors: LIN Z. , BROCK C. P. , MARKS T. J. 
Published: May 2016

AbstractThe title complex (III) is prepared according to the scheme and characterized by X‐ray structure analysis (space group C2/c, Z=4).
ChemInform Abstract: Neurotropic Activity of Organo‐Germanium Derivatives of Adamantane and Nitrogen‐Containing Heterocycles.
Authors: LUKEVITS E. , GERMANE S. K. , TRUSHULE M. A. , MIRONOV V. F. , GAR T. K. , VIKTOROV N. A. , CHERNYSHEVA O. N. 
Published: May 2016

AbstractReaction of 1‐adamantylamine (I) with the acid chloride (II) gives the germylpropionic acid adamantylamide (III).
ChemInform Abstract: σ‐Alkynyl Complexes of Manganese(I) as η2‐Bonding Ligands for Group 1B Metal‐Ligand Fragments. X‐Ray Crystal Structure of (Mn2Cu(μ‐CCtBu)2(CO)6(dppe)2)PF6·0.5 CH2Cl2.
Authors: CARRIEDO G. A. , MIGUEL D. , RIERA V. , SOLANS X. 
Published: May 2016

AbstractThe σ‐alkynyl Mn complexes (I) react with various metal compounds to give complexes such as (III) and (V) containing the σ‐alkynyl group as η2‐bonding ligand.
ChemInform Abstract: Reaction of Di‐t‐butoxyethyne with Fe2(CO)9: X‐Ray Crystal Structure of (Tetra‐t‐butoxycyclopentadienone)tricarbonyliron(0) and an Improved Formal Synthesis of Hydrocroconic Acid and the Croconate Dianion.
Authors: FORNALS D. , PERICAS M. A. , SERRATOSA F. , VINAIXA J. , FONT‐ALTABA M. , SOLANS X. 
Published: May 2016

AbstractTreatment of the pentadienone title complex (III), obtained as shown, with trimethylamine oxide affords the cyclopentadienone (IV), which has been previously converted into hydrocroconic acid and the croconate dianion.
ChemInform Abstract: Structure and Electrochemical Properties of Bis(pyridine)cobalt(III) Complexes of N,N′‐Ethylenebis(salicylideneimine) Homologues with an Aryl Substituent on the Ethylene Backbone. Crystal Structures of (Co(salpen)(py)2)PF6·0.5 Et2O and (Co(salcppn)(py)2)PF6·2 py (py = pyridine).
Authors: KITAURA E. , NISHIDA Y. , OKAWA H. , KIDA S. 
Published: May 2016

AbstractThe title complexes (Ia) are prepared by known methods.
ChemInform Abstract: Synthesis and Stereochemistry of New Cobalt Azo‐Nitroso Complexes.
Authors: MASOUD M. S. , EL‐DISSOUKY A. , GHATWARY E. E. 
Published: May 2016

AbstractThe Co(II) complexes (I)‐(IV) are obtained by refluxing of Co(II) chloride with 2,5 equiv. of corresponding substituted phenylazo 2,4‐dinitrosoresorcinol in ethanol.
ChemInform Abstract: Crystal Structure of a Copper Complex of 2‐Carboxypentonic Acid: A Decomposition Product of Dehydroascorbic Acid.
Authors: NORMAN R. E. , ROSE N. J. , STENKAMP R. E. 
Published: May 2016

AbstractThe insoluble crystalline product (V) can be prepared starting with ascorbic acid (I) via dehydroascorbic acid (III) or diketogulonic acid (VI).
ChemInform Abstract: Syntheses and Crystal Structures of Complexes (M2R2) (M: Cu, Ag, or Au; R: 2‐C(SiMe3)2C5H4N) and (Cu4R′4) (R′: 2‐CH(SiMe3)C5H4N); Electrochemical Generation of (Cu2R2)2+.
Authors: PAPASERGIO R. I. , RASTON C. L. , WHITE A. H. 
Published: May 2016

AbstractReaction of the corresponding Li derivative of (I) or (IV) with CuCl, AgBF4, or Au(CO)Cl (II) yields the binuclear complexes (III) of relative thermal stabilities (IIIa) > (IIIc) > (IIIb) and the tetranuclear species (V), which rapidly decomposes in solution at ambient temp. to elemental Cu.
ChemInform Abstract: Mono‐ and Binuclear Gold(I) and Gold(III) Complexes with S2C‐PR3 Ligands. X‐Ray Crystal Structures of (Au(C6F5)3(S2C‐PEt3)) and (Au2(μ‐S2C‐PEt3)(C6F5)6)·CH2Cl2.
Authors: USON R. , LAGUNA A. , LAGUNA M. , CASTILLA M. L. , JONES P. G. , FITTSCHEN C. 
Published: May 2016

AbstractExchange reactions of the neutral ligand in precursor compounds with the phosphonium dithiocarboxylates (II) to give the different title complexes are described.
ChemInform Abstract: Synthesis and Chemistry of trans‐(RhX(CO)L2) (X: Anionic Ligand, L: Tertiary Phosphine).
Authors: OHGOMORI Y. , YOSHIDA S. , WATANABE Y. 
Published: May 2016

AbstractA novel preparation of a wide variety of complexes (IV) from (I), (II), and (III) in 1,3‐dimethylimidazolidin‐2‐one, 1,1,3,3‐tetramethylurea, or Et2O is described.
ChemInform Abstract: Reactions of Allene with Triosmium and Triruthenium Clusters Including Coupling and Oxidative Addition: X‐Ray Structure of the Coupled Allene Compound (Os3(C6H8)(CO)10).
Authors: DEEMING A. J. , ARCE A. J. , DE SANCTIS Y. , BATES P. A. , HURSTHOUSE M. B. 
Published: May 2016

AbstractAllene (II) reacts with the monoacetonitrile cluster (I) to give the known μ3‐allene cluster (III), but with the bis(acetonitrile) cluster (IV) to afford the cluster (V).
ChemInform Abstract: Dinuclear Rhodium and Iridium Complexes of Dicarboxyimidazolates; Crystal Structure of (NBu4) ((cod)Rh(dcbi)Rh(cod))·2 iPrOH.
Authors: BAYON J. C. , NET G. , RASMUSSEN P. G. , KOLOWICH J. B. 
Published: May 2016

AbstractThe ligands (II) react with dinuclear metal compounds (M(cod)Cl)2 (M: Rh, Ir) in the presence of appropriate amines in MeCN to give the title complexes (III).
ChemInform Abstract: Synthesis, Characterization and Antitumor Properties of Some Metal(II) Complexes of 2‐Pyridinecarboxaldehyde 2′‐Pyridylhydrazone and Related Compounds.
Authors: MOHAN M. , GUPTA M. P. , CHANDRA L. , JHA N. K. 
Published: May 2016

AbstractThe ligands, prepared by known methods, react in hot EtOH with solutions of the appropriate metal(II) salts in EtOH (equimolar amounts) or an aqueous solution of K2PtCl4 under reflux to give the title complexes.
ChemInform Abstract: BaO‐TiO2‐WO3 Microwave Ceramics and Crystalline BaWO4.
Authors: NISHIGAKI S. , YANO S. , KATO H. , HIRAI T. , NONOMURA T. 
Published: May 2016

AbstractThe effect of WO3 addition on the microwave properties (dielectric constant ε, high‐temp.
ChemInform Abstract: The Kinetics of Charging and Discharging of Iridium Oxide Films in Aqueous and Non‐Aqueous Media.
Authors: PICKUP P. G. , BIRSS V. I. 
Published: May 2016

AbstractFrom the results of cyclic voltammetric and chronocoulometric measurements it is concluded that electron transport through the electrochemically generated Ir oxide film is rate limiting for the main redox wave in acidic (H2SO4) and basic (LiClO4) aqueous solutions, whereas ion transport limits the charging/discharging kinetics in LiClO4 + MeCN solutions.
ChemInform Abstract: Anodic Oxidation of Nickel in Alkaline Media Studied by Spectroelectrochemical Techniques.
Authors: ZHANG C. , PARK S.‐M. 
Published: May 2016

AbstractThe results of cyclic voltammetry, chronoamperometry, and in situ near normal incidence reflectance spectroscopy indicate that the Ni(OH)2 layer formed on Ni in KOH solutions near the transpassive region is further oxidized to NiOOH.
ChemInform Abstract: Nature of CO Adsorption During H2 Oxidation in Relation to Modeling for CO Poisoning of a Fuel Cell Anode.
Authors: DHAR H. P. , CHRISTNER L. G. , KUSH A. K. 
Published: May 2016

AbstractCO poisoning losses of a Pt anode have been measured in a half‐cell in the temp. range 110‐190 °C in 100 wt.% H3PO4 for various mixtures of H2, CO, and CO2 gases.
ChemInform Abstract: Carbonyl Difluoride: A Fluorinating Reagent for Inorganic Oxides.
Authors: MALLELA S. P. , GUPTA O. D. , SHREEVE J. M. 
Published: May 2016

AbstractIt is demonstrated that the reaction of COF2 with main‐group and transition‐metal oxides provides a new simple route to fluorinated compounds in high yields.
ChemInform Abstract: New Method for Oxidative Carbon‐Carbon Bond Formation by the Reaction of Allyl Ethers, 2,3‐Dichloro‐5,6‐dicyano‐p‐benzoquinone (DDQ) and Silyl Carbon Nucleophiles.
Authors: HAYASHI Y. , MUKAIYAMA T. 
Published: May 2016

AbstractThe allyl ether (I) reacts with trimethylsilyl cyanide (II) in the presence of DDQ and catalytic amounts of LiClO4 to give the cyanohydrin ether (III).
ChemInform Abstract: Hydrogenolysis and Homologation of Linear and Branched Pentenes on Ru/SiO2 Catalysts: Implication in the Mechanism of C‐C Bond Formation and Cleavage on Metal Surfaces.
Authors: RODRIGUEZ E. , LECONTE M. , BASSET J. M. , TANAKA K. , TANAKA K.‐I. 
Published: May 2016

AbstractHydrogenolysis and homologation of pentenes such as 1‐pentene to butenes, methane (5%), and hexenes take place simultaneously and at the same rate over a Ru/SiO2 catalyst at 110 °C. Unlabeled 1‐butene and labeled hexenes are obtained from (1‐13C)‐1‐pentene.
ChemInform Abstract: Regioselective Trans‐Cis Photoisomerization of m‐Styrylstilbenes.
Authors: ITO Y. , UOZU Y. , DOTE T. , UEDA M. , MATSUURA T. 
Published: May 2016

AbstractIrradiation of the trans,trans isomers (IV) (only one rotameric form shown in the scheme) leads to the trans,cis, cis,trans, and cis,cis isomers what is studied in detail (unsensitized, sensitization by benzophenone, quantum yields, fluorescence).
ChemInform Abstract: Facile Reduction of Saturated and Unsaturated Carboxylic Acids and Their Salts to Aldehydes by Thexylbromoborane‐Dimethyl Sulfide.
Authors: CHA J. S. , KIM J. E. , LEE K. W. 
Published: May 2016

AbstractThe tert‐hexylbromoborane dimethylsulfide complex (III), generated from bromoborane.SMe2 (I) and 2,3‐dimethyl‐2‐butene (II), is employed in the reduction of the carboxylic acids and their corresponding lithium and sodium salts (IV), producing the aldehydes (V).
ChemInform Abstract: Fluorinations with Complex Metal Fluorides. Part 9. Fluorinations of Toluene and Xylene Derivatives by Means of Caesium Tetrafluorocobaltate III.
Authors: BAILEY J. , PLEVEY R. G. , TATLOW J. C. 
Published: May 2016

AbstractThe fluorination reaction of benzotrifluoride (I), toluene (VII), 1,3‐bis(trifluoromethyl)benzene (XIII), and para‐xylene (XVII) with CsCoF4 yields predominantly the derivatives shown in the reaction scheme.
ChemInform Abstract: Sulfuration of the Norbornene Double Bond.
Authors: BARTLETT P. D. , GHOSH T. 
Published: May 2016

AbstractThe norbornene and norbornadiene derivatives (I) are heated with elemental sulfur in the presence or absence of ammonia to yield either exclusively the trithiolanes (II) or a mixture of (II) and the pentathiolanes (III).
ChemInform Abstract: Syntheses with Sulfones. Part 48. Stereoselective Synthesis of 2‐Isopropyl‐1,4‐dienes Through the Iron‐Catalyzed Cross‐Coupling Reaction of 2‐Benzenesulfonyl‐1,4‐dienes and Isopropylmagnesium Chloride.
Authors: ALVAREZ E. , CUVIGNY T. , HERVE DU PENHOAT C. , JULIA M. 
Published: May 2016

AbstractThe preparation of the title substrates (I) is described; for instance, the erythro/threo mixture (IVa)/(IVb) obtained from the components (II) and (III) is readily transformed to the derivatives (V).
ChemInform Abstract: Unusual Polymethylenation of Vinylidenecyclopropane in the Presence of Palladium Catalysts.
Authors: LUKIN K. A. , ZEFIROV N. S. 
Published: May 2016

AbstractIn the presence of Pd(OAc)2 the reaction between the title compound (I) and diazomethane (II) yields the expected dispiroheptane (III) along with a large number of unsaturated compounds.
ChemInform Abstract: Synthesis and Properties of Hydroxyiminoacetonitriles of the Adamantane Series.
Authors: KALININA M. I. , MOISEEV I. K. 
Published: May 2016

AbstractTreatment of the 3‐substituted adamantyl dioximes (I) with equimolar quantities of NaOH affords the hitherto unknown title compounds (II) in high yields.
ChemInform Abstract: Synthesis of 2‐Fluoro Thiocyanates.
Authors: ELLOUZE W. , CHAABOUNI M. M. , BAKLOUTI A. 
Published: May 2016

AbstractReaction of the 2‐fluoro tosylates (I), (IV), and (VI) with potassium thiocyanate (II) yields the corresponding 2‐fluoro thiocyanates.