bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Chemical Transport of Dichromium‐Mercury Tetraselenide.
Authors: POLULYAK E. S. , MISTRYUKOV V. E. , LEVSHIN V. A. , ZHUKOV E. G. , MIKHAILOV YU. N. 
Published: May 2016

AbstractThe known title compound, HgCr2Se4, a magnetic semiconductor, is prepared from the elements in evacuated quartz ampoules at 870‐970 K. Using CrCl3 as transportation agent the mass transfer of the title compound is investigated between 870 and 1020 K in order to optimize the conditions for the preparation of single crystals.
ChemInform Abstract: Substitution of Allylic Hydrogen by an External Nucleophile ‐ A Novel Type of Reaction of Alkenes with Sulfenyl Chlorides.
Authors: BODRIKOV I. V. , SHEBELOVA I. YU. , BORISOV A. V. , KORCHAGINA D. V. , GATILOV YU. V. , RYBALOVA T. V. , TATAROVA L. E. , NISNEVICH G. A. , BARKHASH V. A. 
Published: May 2016

AbstractIn the presence of LiClO4 the concerted reaction between the alkenes (I), the arylsulfenyl chlorides (II) and dimethyl sulfide (III) yields the sulfonium salts (IV).
ChemInform Abstract: High‐Pressure Asymmetric Michael Additions of Thiols, Nitromethane, and Methyl Oxoindancarboxylate to Enones.
Authors: SERA A. , TAKAGI K. , KATAYAMA H. , YAMADA H. , MATSUMOTO K. 
Published: May 2016

AbstractThe reactions of the thiols (I) with cyclohexenone (II) or of nitromethane (V) with chalcone (IV) or of the indanonecarboxylate (VII) with methyl vinyl ketone (VIII) are catalyzed by (‐)‐quinine or the diastereomeric alkaloid (+)‐quinidine to give optically active Michael adducts.
ChemInform Abstract: Stereochemical Aspects of Sulfur Dioxide Insertion into Cyclohex‐2‐enylstannanes.
Authors: YOUNG D. , KITCHING W. 
Published: May 2016

AbstractInsertion of SO2 (III) into mixtures of the cis‐ and trans‐stannanes (I) and (II) or (VI) and (VII) proceeds γ‐regiospecifically with allylic rearrangement to give the O‐sulfinates (IV) and (V) or (VIII) and (IX), respectively.
ChemInform Abstract: Chemistry of 1,1,2,2‐Tetracyanoethane. Part 10. 1,1,2,2‐Tetracyanoethane in Michael Condensation Processes.
Authors: ZIL'BERG S. P. , NASAKIN O. E. , LUKIN P. M. , TURKHANOV V. L. , D'YACHENKO O. A. , ZOLOTOI A. B. , KONOVALIKHIN S. V. , TERENT'EV P. B. , BULAI A. KH. 
Published: May 2016

AbstractIn the preceding publications the authors showed that the title compound (I), which is a strong carbon acid, reacts with α,β‐unsaturated carbonyl compounds to form cyclopentenes, bicyclo(2.2.1)heptanes, spiro derivatives or linear products.
ChemInform Abstract: Sulfuration of Polyfluorinated α‐Keto Esters by 2,4‐Di(methylthio)‐2,4‐dithio‐1,3,2,4‐dithiadiphosphetane.
Authors: SALOUTIN V. I. , BOBROV M. B. , PASHKEVICH K. I. 
Published: May 2016

AbstractThe polyfluorinated 2‐keto esters (I) do not react with sulfurizing agents, such as the Lawesson reagent or P4S10 at temp. up to 140 °C. The reagent (II), specified in the title, however, is found to react with the keto esters (I) under comparatively mild conditions to give the 2‐methylthio derivatives (III) instead of the expected 2‐thioketo esters.
ChemInform Abstract: Ruthenium‐Catalyzed Addition Reaction of Acetic Acid to Propargylic Alcohol Derivatives: Reagents for Palladium‐Catalyzed 2‐Acetoxylation of Carbonucleophiles.
Authors: HORI Y. , MITSUDO T. , WATANABE Y. 
Published: May 2016

AbstractThe propargylic carbonates (I) react with acetic acid (II) in the presence of a ruthenium COD phosphine complex and maleic anhydride to produce the 2‐acetoxyallyl carbonates (III) as the main products.
ChemInform Abstract: Reactions of Methyl Esters of N‐(2,4‐Dinitrophenyl)glycine and N‐Methyl‐N‐(2,4‐dinitrophenyl)glycine with Sodium Methoxide.
Authors: MACHACEK V. , STERBA V. , KOLB I. , LYCKA A. 
Published: May 2016

AbstractThe reaction under investigation (see foregoing ref.
ChemInform Abstract: Regioselective Palladium‐Catalyzed Arylation of Vinyl Ethers with 4‐Nitrophenyl Triflate. Control by Addition of Halide Ions.
Authors: ANDERSSON C.‐M. , HALLBERG A. 
Published: May 2016

Abstract4‐Nitrophenyl triflate (I) reacts with tert‐butyl vinyl ether (II) and lithium halides to yield mixtures of the arylated vinyl ethers (III) and (IV).
ChemInform Abstract: Double Stereoselection in the Sulfoxidation Reaction Catalyzed by Titanium Complexes of N‐Salicylidene‐L‐amino Acids.
Authors: COLONNA S. , MANFREDI A. , SPADONI M. , CASELLA L. , GULLOTTI M. 
Published: May 2016

AbstractOxidation of the optically active sulfide (I) with the oxotitanium complex of N‐salicylidene‐L‐leucine A) gives the diastereomeric sulfoxides (IIa) and (IIb) with 24% e.e.
ChemInform Abstract: Metal‐Ammonia Reduction of α‐Tetralone. Competition between Ring Reduction, Carbonyl Reduction, and Dimer Formation.
Authors: MARCINOW Z. , RABIDEAU P. W. 
Published: May 2016

Abstractα‐Tetralone (I) is reduced with alkali metals in liquid ammonia, yielding a mixture of up to seven products.
ChemInform Abstract: A Skeletal Rearrangement of γ‐(Acyloxy)‐β‐keto Phosphonates: Studies on the Formation of 2(3H)‐Furanones.
Authors: ROUSSIS V. , GLOER K. B. , WIEMER D. F. 
Published: May 2016

AbstractThe γ‐siloxy‐β‐keto phosphonate (I) is coupled with the 18O‐labelled dimethylbutyryl chloride (II) to yield the ester (III) which is subjected to sodium hydride promoted rearrangement, forming the 2(3H)‐furanone (IV), together with the regioisomer (V).
ChemInform Abstract: Polycyclic Aromatic Hydrocarbons via 1‐(Arylmethyl)isobenzo‐ and ‐naphtho(2,3‐c)furans.
Authors: SMITH J. G. , DIBBLE P. W. 
Published: May 2016

AbstractReduction of the phthalides (I) yields the hemiacetals (II) which are dehydrated to give the dihydrofurans (III).
ChemInform Abstract: Catalzyed Reaction of Diazodiphenylethanone and Related Diazoketones with Enaminones as a Source of Pyrroles.
Authors: EBERLIN M. N. , KASCHERES C. 
Published: May 2016

AbstractThe acyclic enaminones (I) react with the carbene, derived from the diazo ketone (II), to yield the pyrroles (III).
ChemInform Abstract: Regioselectivity of Electrophilic Aromatic Substitution: Syntheses of 6‐ and 7‐Sulfamoylindolines and ‐indoles.
Authors: BORROR A. L. , CHINOPOROS E. , FILOSA M. P. , HERCHEN S. R. , PETERSEN C. P. , STERN C. A. , ONAN K. D. 
Published: May 2016

AbstractDirect chlorosulfination of the N‐acylated bromoindoline (I) yields the 6‐substituted derivative (III) which is converted to the desired 6‐sulfamoylindole (VIII) in 4 steps as shown in the reaction scheme.
ChemInform Abstract: Synthesis of Indolo(3,2‐c)quinolines and Indolo(3,2‐d)benzazepines and Their Interaction with DNA.
Authors: IBRAHIM E.‐S. , MONTGOMERIE A. M. , SNEDDON A. H. , PROCTOR G. R. , GREEN B. 
Published: May 2016

AbstractA number of indolo(3,2‐c)quinolines such as (IV) and tetrahydroindolo(3,2‐d)benzazepines such as (VII) are synthesized by Fischer indolization of the ketones (I) or (V) (yield of (VII) not given).
ChemInform Abstract: Synthesis and Biological Activity of Some New 1‐Amino‐3‐(4‐oxazolyl)phenoxy‐2‐propanols.
Authors: RAM B. , SINGH A. N. , REDDY G. J. , SHRIDHAR D. R. , SASTRY C. V. R. , REDDI G. S. , TRIPATHI R. M. , VARMA R. K. , SINGH K. V. 
Published: May 2016

AbstractTwenty‐four title compounds of type (IV) (yield: 68‐88%) are prepared from the phenols (Ia) as shown for (IVa).
ChemInform Abstract: A Facile Synthesis of 2‐Amino‐ and 2‐Mercapto‐tetrahydrodibenzofuranylthiazoles as Potential Antifungal and Antibacterial Agents.
Authors: AHLUWALIA V. K. , ADHIKARI R. , DUTTA U. , BALA S. 
Published: May 2016

AbstractFourteen title compounds (6 of the amino type and 8 of the mercapto type) are synthesized from the ketones (I) (yields of the a series given in g) and tested for their pharmacological activity.
ChemInform Abstract: 1‐Substituted (S)‐3‐(p‐Tolyl)sulfinyl‐1,4‐dihydropyridines: Novel NADH Model Compounds.
Authors: IMANISHI T. , HAMANO Y. , YOSHIKAWA H. , IWATA C. 
Published: May 2016

AbstractThe Grignard compound (I) and the sulfoxide (V) are converted into the NADH model compounds (II) and (VI).
ChemInform Abstract: Thermal and Trimethylsilyl Triflate Catalyzed Additions of Allylsilanes to Nitrones.
Authors: WUTS P. G. M. , JUNG Y.‐W. 
Published: May 2016

AbstractTrimethylsilyl triflate catalyzed cycloaddition reaction of the nitrones (I) with the allylsilane (II) yields the isoxazolidines (III).
ChemInform Abstract: Synthesis and Biological Activity of 2‐Substituted 6‐Carbethoxy‐5(H)‐oxo‐1,3,4‐oxadiazolo(4,5‐a)pyrimidines.
Authors: MURTY M. S. R. , RAMALINGAM T. , DIWAN P. V. , SATTUR P. B. 
Published: May 2016

AbstractSince 1,3,4‐oxadiazole derivatives as well as pyrimidine derivatives are of current interest in view of their biological activity, title compounds of type (III) are synthesized in order to evaluate their pharmacological effects.
ChemInform Abstract: Synthesis and Dimerization of (1,2,4)Triazolo(4,3‐a)pyrimidinium 3‐Aminides.
Authors: MARLEY H. , MCCULLOUGH K. J. , PRESTON P. N. , WRIGHT S. H. B. 
Published: May 2016

AbstractThe thiosemicarbazides (III) and (V), prepared from the corresponding hydrazines, undergo intramolecular cyclization upon treatment with DCC, producing the heterocyclic betaines (IV) and (VI).
ChemInform Abstract: Heterocycles from Nitrile Imines. Part 1. 1,2,3,4‐Tetrahydro‐1,2,4,5‐tetrazines.
Authors: EL‐ABADELAH M. M. , HUSSEIN A. Q. , KAMAL M. R. , AL‐ADHAMI K. H. 
Published: May 2016

AbstractThe nitrilimines, generated from the hydrazonoyl chlorides (I) by treatment with triethylamine, undergo ring closure with the hydrazones (II) to give the tetrahydrotetrazines (III).
ChemInform Abstract: 1,3‐Dipolar Cycloadditions to Heterocycles. Part 18. Cycloaddition of Arylnitrile Oxides to 2H,5H‐1,6‐Benzodioxocine and Related Compounds.
Authors: FISERA L. , JAROSKOVA L. , SCHROTH W. , GAEBLER M. + , ORAVEC P. 
Published: May 2016

Abstract1,3‐Dipolar cycloaddition of benzonitriles (III), (VI), formed in situ from the precursors (II) or (V), to the benzodioxocine (I) yield the heterocycles (IV) or (VII).
ChemInform Abstract: A Carbon‐to‐Boron‐Bridged Benzo‐o‐carborane.
Authors: WU S. , JONES M. JUN. 
Published: May 2016

AbstractThe carbon‐to‐boron‐bridged benzo‐o‐carborane (III) is prepared according to the scheme and characterized by MS, UV, and 1H NMR spectral data.
ChemInform Abstract: Chemistry of Boron. Part 189. Crystal and Molecular Structure of Bis(1,3‐dithiaborolan‐2‐yl)sulfide.
Authors: NOETH H. + , POMMERENING H. , STAUDIGL R. 
Published: May 2016

AbstractThe title compound (III), an unexpected product of the dehalogenation of (I) with Na/K alloy, can be obtained more easily according to the scheme.
ChemInform Abstract: Arylazomethylenetriphenylphosphoranes: A Study of the Alkylation Reaction.
Authors: ALEMAGNA A. , DEL BUTTERO P. , LICANDRO E. , PAPAGNI A. 
Published: May 2016

AbstractAlkylation of the title compounds (I) takes place regiospecifically at the β‐nitrogen to give an ylide by demethoxycarbonylation which in the presence of protonating species (EtI or MeCN, e.g.) is trapped as product (III); otherwise the ylide rearranges to yield products (IV) and (V).
ChemInform Abstract: Synthesis and Structural Characterization of a Tetramolybdate, (Mo4O12(C8H6N4))2‐, Containing a Bridging Phthalazine‐1‐hydrazido(2‐) Ligand. Comparison to the Structure of (Mo4O10(OMe)2(NNMePh)2)2‐, a Tetramolybdate Species Exhibiting Ligation to a Terminal Monodentate Hydrazido(2‐) Group.
Authors: SHAIKH S. N. , ZUBIETA J. 
Published: May 2016

AbstractThe reaction of the molybdate (I) with the hydrazine (II) yields the tetranuclear oxomolybdate complex (III).
ChemInform Abstract: Formation of a Tungsten Vinylvinylidene Complex from Addition of Alkyne to (dppe)(OC)3W=C=CHPh.
Authors: GAMBLE A. S. , BIRDWHISTELL K. R. , TEMPLETON J. L. 
Published: May 2016

AbstractReaction of the title complex (I) with dimethyl acetylenedicarboxylate (II) results in formation of Z and E isomers of the vinylvinylidene product (III).
ChemInform Abstract: Dinuclear (Pt,Pt) and Heteronuclear (Pt,Pd) Complexes of Uracil Nucleobases with Identical and Mixed Amine (NH3, en, bpy) Ligands on the Two Metals. Effects of the Heterometal and Amine on the Oxidizability.
Authors: MICKLITZ W. , RIEDE J. , HUBER B. , MUELLER G. + , LIPPERT B. 
Published: May 2016

AbstractBinuclear complexes of type (III) are prepared as shown and characterized by elemental analysis, spectroscopic methods (IR, Raman, 1H NMR, UV), and by an X‐ray structure analysis of the Pt, Pd compound (IIIa) (space group P1, Z=2).
ChemInform Abstract: O‐2,4‐Dichlorophenyl S‐Methyl Phosphorochloridothioate: A Versatile Agent in the Formation of the 3′‐5′ Internucleotidic Linkage by the Phosphotriester Approach to Oligonucleotide Synthesis.
Authors: CARUSO P. B. , SINDONA G. , LIGUORI A. , UCCELLA N. 
Published: May 2016

AbstractThe development of a 3'‐5'‐phosphate linkage in oligonucleotide synthesis by the phosphorotriester approach requires the use of nucleotides suitably protected at the phosphate moiety, such as the building block (I), which is converted by known methods into the protected dinucleotides (II).
ChemInform Abstract: Effect of Milling Medium on the Properties of Superconducting YBa2Cu3O7‐x.
Authors: DOU S. X. , LIU H. K. , BOURDILLON A. J. , ZHOU J. P. , TAN N. X. , SUN X. Y. , SORRELL C. C. 
Published: May 2016

AbstractUsing conventional ball milling, a density higher than 90% of theoretical can be attained, which is useful in the most applications of the new ceramic superconductors.
ChemInform Abstract: Anion‐Receptor Molecules: Macrocyclic and Macrobicyclic Effects on Anion Binding by Polyammonium Receptor Molecules.
Authors: HOSSEINI M. W. , LEHN J.‐M. 
Published: May 2016

AbstractThe stability constants for anion binding by (I)‐(III) in their protonated forms are reported.
ChemInform Abstract: Photochemical Reaction of (4‐(4′‐Alkoxybenzoyl)phenylmethyl)phosphonic Acids. Application to a Photo‐Degradable Surfactant.
Authors: OKAMOTO Y. , YOSHIDA H. , TAKAMUKU S. 
Published: May 2016

AbstractThe 4‐alkoxy‐4'‐methylbenzophenones (I) are brominated and then treated with triethyl phosphite (III) to give the phosphonates (IV) which are converted to the acids (VII).
ChemInform Abstract: A Novel Synthesis of Thiocarboxylic Acid S‐Esters from 1‐(Acylthio)ethaniminium Halides and Alkyl Halides Using Liquid‐Liquid Phase‐Transfer Catalysis.
Authors: TAKIDO T. , TORIYAMA M. , ITABASHI K. 
Published: May 2016

AbstractAcylation of thioacetamide (II) followed by alkylation with the alkyl halides (III) yields the thioloesters (IV).
ChemInform Abstract: Quaternary Ammonium Tetrakis(diperoxotungsto)phosphates(3‐) as a New Class of Catalysts for Efficient Alkene Epoxidation with Hydrogen Peroxide.
Authors: VENTURELLO C. , D'ALOISIO R. 
Published: May 2016

AbstractEpoxidation of the olefins (I), (III), (V), and (VII) with hydrogen peroxide, yielding the corresponding epoxides (II), (IV), (VI), and (VIII), is catalyzed by quaternary ammonium tetrakis(diperoxotungsto)phosphates.
ChemInform Abstract: Enhanced Formation of 8π(4n) Conjugated Cyclic Carbanions in the Excited State: First Example of Photochemical C‐H Bond Heterolysis in Photoexcited Suberene.
Authors: WAN P. , KROGH E. , CHAK B. 
Published: May 2016

AbstractIn contrast to suberane and fluorene, suberene (I) undergoes proton exchange on photolysis at the benzylic 5‐position to give (II) and (III).
ChemInform Abstract: Reactivity of α‐Metal (Group 4) Esters. Lewis Acid Mediated Reactions of α‐Triphenyltin Esters with Aldehydes and Acetals.
Authors: KIYOOKA S. , NAKATA M. 
Published: May 2016

AbstractThe α‐stannylcarboxylates (II) are coupled with the aldehydes (I) in the presence of titanium tetrachloride to form the β‐hydroxy esters (III).
ChemInform Abstract: The Scope of a New Masked Michael Reaction Involving a Pummerer Intermediate.
Authors: HUNTER R. , SIMON C. D. 
Published: May 2016

AbstractThe allylic sulfoxide (I) reacts with Huenig's base (II) and trimethylsilyl triflate (III) to give the salt (IV) which is coupled with the malonate (V) in the presence of a Pd(0) catalyst to yield the phenylthioisobutenylmalonate (VI).
ChemInform Abstract: Polynuclear Aromatic Hydrocarbons. Part 26. Acid‐Catalyzed Rearrangement Through Spirocyclic Systems: Synthesis of 5,8‐Dimethylphenanthro(1,2‐a)anthracene.
Authors: SHARMA K. S. , TANEJA K. L. , SARITA SARITA , MUKHERJI S. M. 
Published: May 2016

AbstractTreatment of the anthracene (III) according to A) does not yield the expected product (IV) but the hexacycle (V).
ChemInform Abstract: Photocyclization Reactions of 1‐Benzyl‐1‐pyrrolinium Salts by Diradical and Diradical Cation Pathways. Novel Photochemical Pictet‐Spengler Cyclizations.
Authors: CHO I.‐S. , MARIANO P. S. 
Published: May 2016

AbstractPhotocyclizations of the substituted 1‐benzyl‐1‐pyrrolinium perchlorates (I), (IV), and (VII), yielding the benzopyrrolizidines (II), (III), (V), (VI), and (VIII), and the benzindolizidine (IX) are achieved either by direct irradiation or by triplet‐sensitized reaction.
ChemInform Abstract: A General Method for the Synthesis of Tetramic Acid Derivatives.
Authors: DESHONG P. , CIPOLLINA J. A. , LOWMASTER N. K. 
Published: May 2016

AbstractBromination of 5‐methylisoxazole (I) yields the bromomethyl derivative (II) which reacts with triethyl phosphite (III) to give the phosphonate (IV).
ChemInform Abstract: Synthesis of (α‐Hydroxyalkyl)silanes from Formyltrimethylsilane. A New Route to Acetylenic Acylsilanes.
Authors: LINDERMAN R. J. , SUHR Y. 
Published: May 2016

AbstractSwern oxidation of trimethylsilylmethanol (I) generates the intermediate formyltrimethylsilane (II) which reacts with the Grignard or organolithium reagents (III) to give the (α‐hydroxyalkyl)silanes (IV).
ChemInform Abstract: Model Complexes with Hydrazone Chelates of (S)‐ and (R)‐1‐Amino‐2‐methoxymethylpyrrolidine (“SAMP” and “RAMP”) and Dimethylhydrazine ‐ Structure of (Pyridine‐2‐aldehyde‐RAMP‐hydrazone)tetracarbonyl‐molybdenum.
Authors: EHLERS J. , TOM DIECK H. 
Published: May 2016

AbstractThe hydrazones of glyoxal, diacetyl, pyridine‐2‐carbaldehyde (I), and 2‐actylpyridine with (S)‐ and (R)‐1‐amino‐2‐methoxymethylpyrrolidine (II) and with dimethylhydrazine are synthesized.
ChemInform Abstract: Diallyl‐ and Bis(2‐methylallyl)tetrakis(dimethylamido)ditungsten: W2(.mu±eta.3‐C3H5)2(NMe2)4 and W2(η1‐C4H7)2(NMe2)4 (MM). Comments on Ligand‐Metal π‐Interactions at (WW)6+ Centers.
Authors: CHISHOLM M. H. , HAMPDEN‐SMITH M. J. , HUFFMAN J. C. , MOODLEY K. G. 
Published: May 2016

AbstractThe reaction of the d3‐d3 dinuclear W compound (I) with two equiv. of allyl‐ and 2‐methylallyl‐Mg compounds (II) or (IV) leads to the different title complexes (III) and (IV) (gauche isomer).
ChemInform Abstract: Deprotonation of a Heterodinuclear Transition‐Metal Hydride Complex and Reactions of the Anion with Electrophiles: X‐Ray Crystal Structures of ((η5‐C5H5)(OC)2Mo(μ‐Ag(PPh3))(μ‐PPh2)Mn(CO)4) and ((η‐C5H5)(OC)2Mo(μ‐I)(μ‐PPh2)Mn(CO)4).
Authors: HORTON A. D. , MAYS M. J. , ADATIA T. , HENRICK K. , MCPARTLIN M. 
Published: May 2016

AbstractDeprotonation of the hydride‐bridged MoMn complex (I) leads to an anion which is isolated as its tetraethylammonium salt (II).
ChemInform Abstract: Adenosine 5′‐(α,β‐Imido)triphosphate, a Substrate for T7 RNA Polymerase and Rabbit Muscle Creatine Kinase.
Authors: MA Q. , BABBITT P. C. , KENYON G. L. 
Published: May 2016

AbstractThe tris(tetrabutylammonium) salt of the monoacid of imidodiphosphate is coupled directly with 5'‐tosyladenosine in MeCN at 25 °C (24 h) to give adenosine 5'‐(α,β‐imido)diphosphate as the triethylammonium salt (yield 22%) which is incubated for 24 h at 5 °C with phosphocreatine, creatine kinase in glycine buffer, pH 9, and Mg(OAc)2 to give adenosine 5'‐(α,β‐imido)triphosphate (77%).
ChemInform Abstract: The Crystal Structure of (NH4)3F(WF4O(O2)) at 290 K and a Refinement of the Crystal Structure of the Isomorphous (NH4)3F(MoF4O(O2)) at 250 and 290 K.
Authors: STOMBERG R. 
Published: May 2016

AbstractThe isostructural title compounds crystallize in the orthorhombic space group Pbca with Z = 8. The (MF4O(O2))2‐ (M: Mo, W) anions have a pentagonal‐bipyramidal configuration with the peroxo‐group in the equatorial plane.
ChemInform Abstract: Fluoride Complexes of Copper(II). Part 8. The Ternary NaF‐BaF2‐CuF2 System
Authors: DE KOZAK A. , SAMOUEL M. , RENAUDIN J. , FEREY G. 
Published: May 2016

Abstractis studied in the temp. range 520‐580 °C and the 520 °C isothermal section of the phase diagram is given.
ChemInform Abstract: Pulse and AC Impedance Studies of the Electrochemical Systems of Titanium in LiCl‐KCl Eutectic Melt at 743 K.
Authors: FERRY D. M. , PICARD G. S. , TREMILLON B. L. 
Published: May 2016

AbstractThe standard potentials of the redox systems Ti(0)/Ti(II), Ti(II)/Ti(III), and Ti(III)/Ti(IV) are determined.
ChemInform Abstract: Role of Ti‐O‐Zr Bonding in TiO2‐ZrO2 Catalyst for Dehydrogenation of Ethylbenzene.
Authors: HIRASHIMA Y. , NISHIWAKI K. , MIYAKOSHI A. , TSUIKI H. , UENO A. , NAKABAYASHI H. 
Published: May 2016

AbstractTiO2‐ZrO2 catalysts are prepared either by hydrolysis of a (iPrO)4Ti/(PrO)4Zr mixed solution or mechanical mixing of TiO2 and ZrO2 powders.
ChemInform Abstract: New Investigations on α‐PtCl2: Preparation and Structure.
Authors: KREBS B. , BRENDEL C. , SCHAEFER H. + 
Published: May 2016

Abstractα‐PtCl2, the HT modification of platinum(II) chloride, can be prepared in pure form as single crystals by chemical transport, using Ga2Cl6 (GaCl3) as the transportation agent.
ChemInform Abstract: Specific Sequestering Agents for the Actinoids. Part 17. Coordination Chemistry of Lanthanoid Catecholates.
Authors: ZHU D.‐H. , KAPPEL M. J. , RAYMOND K. N. 
Published: May 2016

AbstractPotentiometric and spectrophotometric measurements are used to study the solution complexation chemistry of Eu(III) and Lu(III) with the catechol ligands (I)‐(III).
ChemInform Abstract: Mechanism of Aromatic Nucleophilic Substitution in Aprotic Solvents.
Authors: ONUOHA G. N. , ONYIDO I. , HIRST J. 
Published: May 2016

AbstractThe effect of various H‐bond acceptors (such as DMSO, HMPA, Py, nitrobenzene, cyclohexanone) on the reaction of (I) with morpholine (II) is studied kinetically.
ChemInform Abstract: Organoboranes for Synthesis. Part 9. Rapid Reaction of Organoboranes with Iodine Under the Influence of Base. A Convenient Procedure for the Conversion of Alkenes into Iodides via Hydroboration.
Authors: BROWN H. C. , RATHKE M. W. , ROGIC M. M. , DE LUE N. R. 
Published: May 2016

AbstractThe reaction of the organoboranes derived from the alkenes (I) with iodine to give the anti‐Markovnikov iodides (III) is accelerated by NaOH.
ChemInform Abstract: ZnTPPS‐Sensitized Photodebromination of 2,3‐Dibromo‐3‐phenylpropionic Acids. Electron‐Transfer Initiated Chain Debromination.
Authors: TAKAGI K. , MIYAKE N. , NAKAMURA E. , SAWAKI Y. , KOGA N. , IWAMURA H. 
Published: May 2016

AbstractIrradiation of the erythro‐2,3‐dibrom‐3‐phenylpropionates (I) at >355 nm in the presence of catalytic amounts of zinc tetrasodium tetrakis‐(sulfonatophenyl)porphyrin (ZnTPPS) and triethanolamine leads to the formation of the trans‐cinnamates (II).
ChemInform Abstract: N,N′‐Dibenzyl‐N,N′‐ethylenetartramide: A Rationally Designed Chiral Auxiliary for the Allylboration Reaction.
Authors: ROUSH W. R. , BANFI L. 
Published: May 2016

AbstractThe design and synthesis of the title species (III) (= (R,R)‐enantiomer) and the derived allylboronate (V) is described; the (S,S)‐enantiomer (VI) is prepared analogously.
ChemInform Abstract: Synthesis of Ethyl 1‐Phenyl‐ and 1‐Alkyl‐1‐indene‐2‐carboxylates.
Authors: JALANDER L. 
Published: May 2016

AbstractThe methoxyindenecarboxylate (I) reacts with the Grignard compounds (II) to form the 1‐substituted indenecarboxylates (III).
ChemInform Abstract: Stereoselective Synthesis of Hydroxy‐Substituted Tetrahydrofurans.
Authors: KIM Y. G. , CHA J. K. 
Published: May 2016

AbstractIodine‐induced cyclization of the 3,5‐dioxy‐1‐pentenes (I) or (IV) yields the 2‐iodomethyl‐3‐oxytetrahydrofurans (II) and (III) or (V) and (VI).