bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Reaction of 3,7‐Dimethylenebicyclo(3.3.1)nonane with the Pyridinium Salts of Perfluorocarboxylic Acids.
Authors: SOLOSHONOK V. A. , KHOTKEVICH A. B. , SERGUCHEV YU. A. 
Published: May 2016

AbstractA molten mixture of the title compounds (I) and (II) undergoes exothermic reaction to give the adamantyl esters (III) in fair yields.
ChemInform Abstract: Host‐Guest Complexation. Part 51. Cyanospherands, a New Type of Salt Binder.
Authors: PAEK K. , KNOBLER C. B. , MAVERICK E. F. , CRAM D. J. 
Published: May 2016

AbstractFrom 1H NMR data the conformations of the spherands (III)‐(V), the degree of hindrance to rotation about the aryl‐aryl bonds in the tetramer (IIb), and thermodynamic data and conformations of the spheraplexes derived from (III)‐(V) with some cations such as Li+, Na+, K+, R‐NH3+ (R: ‐H, ‐Me, ‐tBu) are deduced.
ChemInform Abstract: Selective Ion Extraction by a Calix(6)arene Derivative Containing Azo Groups.
Authors: NOMURA E. , TANIGUCHI H. , TAMURA S. 
Published: May 2016

AbstractThe tert‐butylcalixarene (I) is dealkylated with AlCl3 and then coupled with phenyldiazonium chloride (III) to give the phenylazocalix(6)arene (IV).
ChemInform Abstract: Synthesis and Reactions of 3,4‐Bis(trimethylsilyl)furan and 2‐Methyl‐3,4‐bis(trimethylsilyl)furan.
Authors: HO M. S. , WONG H. N. C. 
Published: May 2016

AbstractThe oxazoles (I) react with bis(trimethylsilyl)acetylene (II) to give the bis(trimethylsilyl)furans (III).
ChemInform Abstract: A Convenient One‐Flask Synthesis of α‐Methylene Aldehydes from Primary Alcohols.
Authors: TAKANO S. , INOMATA K. , SAMIZU K. , TOMITA S. , YANASE M. , SUZUKI M. , IWABUCHI Y. , SUGIHARA T. , OGASAWARA K. 
Published: May 2016

AbstractThe hydroxyethyl derivatives (I) are subjected to Swern oxidation to form the aldehydes (II) which are directly treated with the iminium salt (III), yielding the α‐substituted acroleines (IV).
ChemInform Abstract: Palladium‐Assisted Heteroannulation of Acetoxy‐1,3‐dienes.
Authors: LAROCK R. C. , SONG H. 
Published: May 2016

Abstract2‐(Chloromercurio)benzoic acid (I) undergoes ring closure reaction with the acetoxydienes (II) or (IV) in the presence of lithium chloropalladates to form the dihydrobenzopyranones (III) or (V).
ChemInform Abstract: Synthesis in the Phenanthridine Series. Part 1. Preparation of 6‐Alkylphenanthridines and Their Salts.
Authors: LION C. , BOUKOU‐POBA J. P. , CHARVY C. 
Published: May 2016

AbstractPhenanthridines show interesting biological activities, e.g. antileukemic and antidepressive activity.
ChemInform Abstract: Methods for Controlling the Regioselection in the Reaction of 3‐Amino‐5‐benzylthio‐1,2,4‐triazole with Acetylacetaldehyde Dimethyl Acetal.
Authors: MONTE W. T. , KLESCHICK W. A. , MEIKLE R. W. , SNIDER S. W. , BORDNER J. 
Published: May 2016

AbstractDepending on the conditions, the reaction between the title compounds (I) and (II) affords the triazolo(1,5‐a)pyrimidine (III) or its 7‐methyl isomer (IV).
ChemInform Abstract: Benzimidazole Condensed Ring Systems. Part 5. Studies on the Synthesis of Pyrimido(1,6‐a)benzimidazole‐1,3(2H,5H)‐diones.
Authors: BADAWEY E. A. M. , RIDA S. M. , SOLIMAN F. S. G. , KAPPE T. 
Published: May 2016

AbstractThe reaction between ethyl 1H‐benzimidazole‐2‐acetate (I) and the alkyl isocyanates (II) yields the expected title compounds (III), which are further converted to the 5‐alkyl derivatives (V) and the 4‐chloro derivatives (VI).
ChemInform Abstract: Potential Antidepressants. Synthesis of 6,11‐Dihydrodibenzo(b,e)thiepin‐11‐yl 4‐(Dimethylaminomethyl)phenyl Ketone and of Some Related Compounds.
Authors: SINDELAR K. , HOLUBEK J. , SVATEK E. , MATOUSOVA O. , METYSOVA J. , PROTIVA M. 
Published: May 2016

AbstractNumerous attempts to convert the alcohols (III) and (V) into the corresponding ketones remain unsuccessful.
ChemInform Abstract: Phosphaalkenes from Monochlorophosphanes and Alkylidenetriphenylphosphoranes.
Authors: MAERKL G. + , BAUER W. 
Published: May 2016

AbstractThe mono‐ and disubstituted, nonstabilized methylenetriphenylphosphoranes (I) can be converted by transylidation with the monochlorophosphane (II) into the kinetically more stable phosphaalkenes (IV).
ChemInform Abstract: Generation, Stereochemistry, and Molecular Dynamics of a 1,3‐Bis(phosphonio)propenide Cation.
Authors: SCHMIDBAUR H. , PASCHALIDIS C. , STEIGELMANN O. , MUELLER G. + 
Published: May 2016

AbstractA useful model for the free allyl anion is the methyldiphosphoniopropenide (IV) (space group P21/n, Z=4).
ChemInform Abstract: 1,1‐Dimetallagermacyclopent‐3‐enes: Precursors to Transition Metal‐Substituted Germylenes (Germanediyls).
Authors: LEI D. , SMITH M. J. H. 
Published: May 2016

AbstractThe germacyclopentenes (I) are coupled with the metal carbonyl complexes (II) to give the 1,1‐ditransition metal‐substituted germacyclopentenes (III).
ChemInform Abstract: Optically Active Isoprene(tricarbonyl)iron(0) and Methyltrimethylenemethane(tricarbonyl)iron(0).
Authors: KAPPES D. , GERLACH H. , ZBINDEN P. , DOBLER M. , KOENIG W. A. + , KREBBER R. , WENZ G. 
Published: May 2016

AbstractIonic hydrogenation of (I) gives rise for the first time to the optically active title complexes (II) and (III).
ChemInform Abstract: Reactions of Cobalt(II) Macrocycles with Alkyl and Alkylperoxy Radicals.
Authors: BAKAC A. , ESPENSON J. H. 
Published: May 2016

AbstractThe Co‐C bond formation in the reactions of complexes such as (I)‐(IV) with primary alkyl and substituted primary alkyl radicals takes place with rate constants in the range 107‐109 M‐1 s‐1 The kinetics are influenced by the nature of the macrocycle to a much greater extent than by the nature of the radicals, such that all the rate constants for a given cobalt complex fall within a factor of ∼2.
ChemInform Abstract: (Tetramethylthiophene)ruthenium Dichloride Dimer: A Versatile Synthetic Intermediate in Thiophene Coordination Chemistry.
Authors: LOCKEMEYER J. R. , RAUCHFUSS T. B. , RHEINGOLD A. L. , WILSON S. R. 
Published: May 2016

AbstractThermal arene exchange in (I) yields the title dimer (III).
ChemInform Abstract: Preparation and X‐Ray Crystal Structure of (RhPh(OCOCF3)(C10H4NO2)(P(p‐FC6H4)3)(H2O)), an Octahedral Complex Containing a σ‐RhPh Bond.
Authors: CANO M. , HERAS J. V. , LOBO M. A. , PINILLA E. , GUTIERREZ E. , MONGE M. A. 
Published: May 2016

AbstractNew complexes of the title type (I) (space group P1, Z=2) are obtained by elimination of Hg from the intermediate heterobimetallic complexes Rh(OCOCF3)(HgPh)(O‐N)(CO)L (L: P(p‐RC6H4)3; R: Cl, F, Me, OMe).
ChemInform Abstract: Hydrocarbon‐Bridged Complexes. Part 14. Directed Synthesis of Trinuclear Hydrocarbon‐Bridged Complexes Such as ((CO)5ReCH2CH2Os(CO)4CH2CH2Re(CO)5).
Authors: BECK W. , NIEMER B. , WAGNER B. 
Published: May 2016

AbstractNucleophilic addition of carbonyl metalates to coordinated, unsaturated hydrocarbons in cationic complexes is used for the title reaction as shown for the example of (III).
ChemInform Abstract: Inter‐ and Intramolecular Photochemical C‐H Activation with (η6‐Arene)(carbonyl)osmium Complexes in Matrices and in Solution.
Authors: MCCAMLEY A. , PERUTZ R. N. , STAHL S. , WERNER H. 
Published: May 2016

AbstractArene‐osmium complexes (I), (IV) and (V) undergo inter‐ or intramolecular C‐H activation reactions on photolysis in low‐temp.
ChemInform Abstract: Characterization of (Methylcyclopentadienyl)trimethylplatinum and Low‐Temperature Organometallic Chemical Vapor Deposition of Platinum Metal.
Authors: XUE Z. , STROUSE M. J. , SHUH D. K. , KNOBLER C. B. , KAESZ H. D. , HICKS R. F. , WILLIAMS R. S. 
Published: May 2016

AbstractThin films of platinum are used extensively in microelectronics device processing and electrodeless metal plating.
ChemInform Abstract: A Formal Stereocontrolled Synthesis of (.+‐.) Isoclovene.
Authors: AHMAD Z. , GOSWAMI P. , VENKATESWARAN R. V. 
Published: May 2016

AbstractThe diketone (XVII) and the tricyclic ketone (XVIII) represent immediate precursors of isoclovene (XIX), the artifact isolated from extensive rearrangement of caryophyllene.
ChemInform Abstract: Improved Synthesis of the Biologically Active Methionine Analog, L‐2‐Amino‐4‐methoxy‐cis‐but‐3‐enoic Acid (L‐cis‐amb) Using an Electrophilic Glycinate Synthon.
Authors: ALKS V. , SUFRIN J. R. 
Published: May 2016

AbstractThe methyl glyoxylate hemiacetal (I) is treated with acetamide (II) and then subjected to substitution of the hydroxy group, producing the N‐acetylbromoglycinate (IV).
ChemInform Abstract: N‐Formylglycine tert‐Butyl Ester.
Authors: MEDUNA V. , SAWLEWICSZ P. , VOGT R. 
Published: May 2016

AbstractTwo methods of preparing the title compound (III) are described: the first procedure consists in coupling deprotonated formamide (I) with tert‐butyl chloroacetate (II) to yield a mixture of (III) and its N,N‐diformyl derivative (IV).
ChemInform Abstract: C‐Stannylated Carbohydrate Derivatives. Part 3. 1,2:5,6‐Di‐O‐isopropylidene‐3‐C‐(organostannyl)methyl‐α‐D‐allofuranose Derivatives. Crystal and Molecular Structure of 3‐C‐(Dibutyliodostannyl)methyl‐1,2:5,6‐di‐O‐isopropylidene‐α‐D‐allofurano# se.
Authors: COX P. J. , DOIDGE‐HARRISON S. M. S. V. , HOWIE R. A. , NOWELL I. W. , TAYLOR O. J. , WARDELL J. L. 
Published: May 2016

AbstractWhen the organostannyl carbohydrates (III) are treated with TFA, the expected β‐elimination reaction does not occur.
ChemInform Abstract: Stereochemical Variations in Aqueous Cycloadditions Using Glycoorganic Substrates as a Consequence of Chemical Manipulations on the Sugar Moiety.
Authors: LUBINEAU A. , QUENEAU Y. 
Published: May 2016

AbstractIn the cycloaddition between the dienes (I) and methacrolein (II), the introduction of a sugar moiety induces chirality and water solubility of the starting materials and causes a stereofacial selectivity between the four possible adducts (III)‐(VI).
ChemInform Abstract: Synthesis of (+)‐Sesbanimide A. Structure of the Crucial Silyl Ether AB Ring Intermediate.
Authors: VLOON W. J. , VAN DEN BOS J. C. , WILLARD N. P. , KOOMEN G.‐J. , PANDIT U. K. 
Published: May 2016

AbstractSilylation of the known sesbanimide precursor (I) does not result in the expected protection of the hydroxy group but rather leads to the tricyclic structure (III) (confirmed by an X‐ray structure analysis of (IV)), which is subsequently converted to the title alkaloid (V).
ChemInform Abstract: Synthesis of 2‐(2′,3′‐Dihydroxypropyl)‐5‐amino‐2H‐1,2,4‐thiadiazol‐3‐one and 3‐(2′,3′‐Dihydroxypropyl)‐5‐amino‐3H‐1,3,4‐thiadiazol‐2‐one.
Authors: PARKANYI C. , YUAN H. L. , CHO N. S. , JAW J.‐H. J. , WOODHOUSE T. E. , AUNG T. L. 
Published: May 2016

AbstractThe hitherto unknown title compounds (VIII) and (XII) are the acyclic nucleoside analogues of their precursors i.e. of the thiadiazoles (VI) or (XI), respectively (no yield given for (XI)).
ChemInform Abstract: Synthesis of Some 13‐Oxaprostanoids.
Authors: MJALLI A. M. M. , ROBERTS S. M. 
Published: May 2016

AbstractKey step in the new preparation of 13‐oxaprostaglandins, biologically interesting compounds, is the reaction of Dps‐Cl (II) with an encumbered secondary hydroxy group in the presence of an adjacent hindered secondary hydroxy group to give the synthon (V).
ChemInform Abstract: The Conformational Analysis of Derivatives of Erythromycin A. X‐Ray Crystallographic and NMR Spectroscopic Studies of (E)‐11‐O‐(2‐Dimethylaminoethoxy)methyl‐9‐deoxo‐9‐methoxyiminoerythromycin A (I).
Authors: EVERETT J. R. , HATTON I. K. , HUNT E. , TYLER J. W. , WILLIAMS D. J. 
Published: May 2016

AbstractThe title compound (I) is synthesized from erythromycin A (e.A) in 4 steps and has space group P212121 with Z=4.
ChemInform Abstract: The Rotational Spectrum and Structure of Chlorine Peroxide.
Authors: BIRK M. , FRIEDL R. R. , COHEN E. A. , PICKETT H. M. , SANDER S. P. 
Published: May 2016

AbstractWith a view to resolving some of the discrepancies concerning the ClO dimer as well as to clarifying its role in the atmosphere the ClO self‐reaction is studied in a flowing chemical reactor using submillimeter wave spectroscopy.
ChemInform Abstract: Photoelectrochemically Synthesized Interfacial Oxides on Silicon: Composition and Electronic Properties.
Authors: LEWERENZ H. J. , STUMPER J. , PETTENKOFER C. , GREEF R. 
Published: May 2016

AbstractPhotoelectrochemically grown oxides on a‐Si:H and Si single crystals are studied by in situ ellipsometry and XPS.
ChemInform Abstract: Enantioselective Microbial Reduction of 5‐Acetylisoxazolines ‐ A Novel Method for Stereochemical Control on Yeast Reduction.
Authors: TICOZZI C. , ZANAROTTI A. 
Published: May 2016

AbstractThe kinetics and stereoselectivity of the baker's yeast reduction of the racemic isoxazole (I) depends strongly on the 2‐propanol/water ratio; at a ratio of 4:1 the reduction allows kinetic resolution leading to ketone (R)‐(‐)‐I and alcohol(+)‐II.
ChemInform Abstract: Addition of N‐Diphenylmethylene(2‐furfuryl)amine to Benzylideneacetophenones.
Authors: POPANDOVA‐YAMBOLIEVA K. 
Published: May 2016

AbstractLewis acid‐catalyzed reaction of benzophenone (I) with furfurylamine (II) prouces the imine (III) which is coupled with the aromatic enones (IV) under phase‐transfer conditions, yielding the Michael type adducts (V) as the main products.
ChemInform Abstract: Quantitative Synthesis of L‐ or D‐N2‐tert‐Butoxycarbonyl‐2,3‐diaminopropanoic Acid from Protected L‐ or D‐Serine‐β‐lactone.
Authors: KUCHARCZYK N. , BADET B. , LE GOFFIC F. 
Published: May 2016

AbstractWhen the N‐protected amino‐β‐lactone L‐(I) is treated with gaseous ammonia (II) in ethers or with liquid ammonia (II), the serine carboxamide (III) is exclusively formed.
ChemInform Abstract: Electrochemical Synthesis of Bi‐1,4‐naphthoquinonyl Derivatives.
Authors: SCHUTTE J. H. P. , DU PLESSIS J. A. K. , LACHMANN G. , VILJOEN A. M. , NELSON H. D. 
Published: May 2016

AbstractElectrolysis of 1,4‐naphthoquinone (I) or a mixture of (I) and 2‐amino‐1,4‐naphthoquinone (III) results in the formation of the 2,2'‐bi‐1,4‐naphthoquinones (II) or (V).
ChemInform Abstract: Homochiral Ketals in Organic Synthesis. Diastereoselective Cyclopropanation of Medium and Large Ring α,β‐Unsaturated Ketals Derived from 1,4‐Di‐O‐benzyl‐L‐threitol.
Authors: MASH E. A. , MATH S. K. , ARTERBURN J. B. 
Published: May 2016

AbstractThe cyclic acetals (III), obtained by reaction of the ketones (I) with the threitol derivative (II), are converted into the unsaturated cis‐and trans‐configurated cycloalkenone acetals (IV).
ChemInform Abstract: A New Class of Room Temperature Luminescent Organometallic Complexes: Luminescence and Photophysical Properties of Permethylscandocene Chloride in Fluid Solution.
Authors: PFENNIG B. W. , THOMPSON M. E. , BOCARSLY A. B. 
Published: May 2016

AbstractWith the view to searching for organometallic complexes that emit in fluid solution at room temp., photophysics of the d° first row transition‐metal complex (I) are investigated.
ChemInform Abstract: Metal Complexes of Functional Isocyanides. Part 18. (Alkylideneamino)carbenes by Nucleophilic Addition to Pentacarbonylchromium‐Coordinated 1,1‐Dichloromethyl, 1,1,2‐Trichloroethyl and 1‐Chlorovinyl Isocyanide.
Authors: FEHLHAMMER W. P. , BECK G. 
Published: May 2016

AbstractPyrrolidine (II) adds to the isocyano group of the Cr complex (I) with concomitant loss of HCl to give the (ethylideneamino)carbene complex (III) in which the α‐chlorine can be replaced by a second molecule of pyrrolidine (II) producing (IVa).
ChemInform Abstract: Organometallic and Coordination Chemistry on Phosphazenes. Part 1. Zn(II), Pd(II) and Pt(II) Complexes on Schiff Base‐Containing Cyclophosphazenes.
Authors: BERTANI R. , FACCHIN G. , GLERIA M. 
Published: May 2016

AbstractHexakis(4‐amino‐3‐methylphenoxy)cyclophosphazene (III) is prepared from hexachlorocyclophosphazene (I) according to the scheme.
ChemInform Abstract: A New Structure Type with Face Connected BaO6‐Octahedra: Ba6Nd2Al4O15.
Authors: RUETER I. + , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractIn order to prepare single crystals of the title compound, an intimate mixture of BaCO3, Nd2O3, and Al2O3 (6:1:2) is pressed into pellets and heated (more than 2 months) between 1020 and 1250 °C using BaCl2 as a flux.
ChemInform Abstract: YBa2Cu3O7‐x: Transport Properties and Defects at High Temperature.
Authors: CHIODELLI G. , CAMPARI‐VIGANO G. , FLOR G. 
Published: May 2016

AbstractResistivity measurements in the temp. range 300‐1023 K under oxygen partial pressures of 5·10‐7‐1 atm indicate a metallic behavior for polycrystalline YBa2Cu3O7‐x equilibrated in the p(O2) range 5·10‐4‐1 atm, a transition between metallic and semiconducting behavior at 920 K for the sample equilibrated at p(O2) = 2·10‐5 atm, and semiconducting behavior for the sample equilibrated at p(O2) = 5·10‐7 atm.
ChemInform Abstract: Difluoro‐ and Dichlorodioxasilirane.
Authors: PATYK A. , SANDER W. , GAUSS J. , CREMER D. 
Published: May 2016

AbstractReactions of difluoro‐ and dichlorosilylene with molecular oxygen in Ar matrices are found to produce the dioxasiliranes (III) under irradiation with UV/VIS, while no thermal reaction of (I) with oxygen is observed in the gas phase or in O2‐doped Ar matrices at low temp. (10‐45 K).
ChemInform Abstract: ESR Observation of Enamine Radical Cations from Thiamine (Vitamin B1) and Related Compounds.
Authors: RUEEGGE D. + , FISCHER H. 
Published: May 2016

AbstractThe reduction of thiamine and thiazolium salts by photochemically generated radicals such as ·CMe2‐OH and ·CH2OH leads to radical cations such as (I) and (II); (IIb) is accompanied by (III).
ChemInform Abstract: Thermal Decomposition of Energetic Materials. Part 34. Decarbonylation, Decarboxylation, and Coupling Reactions of Metal Propiolates, M(O2CCCH).
Authors: STONER C. E. JUN. , BRILL T. B. 
Published: May 2016

AbstractThe slow and rapid thermal decomposition of group IA (Na+, K+, Rb+) and first‐row transition‐element (Co2+, Ni2+, Zn2+) propiolate salts is investigated by TGA, DSC, and IR spectroscopy.
ChemInform Abstract: Topological and Steric Effects in Mechanism of Intramolecular (2 + 2)‐Photocycloadditions.
Authors: BECKER D. , HADDAD N. , SAHALI Y. 
Published: May 2016

AbstractThe 2‐alkenylcyclohexenones (I) undergo photo‐induced ring closure, yielding the tricyclic ketones (II) and (III).
ChemInform Abstract: Heterocyclization of Thionocarboxylic Acid Derivatives to 1,3,4‐Thiadiazoles by tert‐Butyl Hypochlorite.
Authors: DEMCHUK D. V. , LUTSENKO A. I. , TROYANSKII E. I. , NIKISHIN G. I. 
Published: May 2016

AbstractThe thiobenzohydrazides (I) undergo heterocyclization upon treatment with tert‐butyl hypochlorite, producing the symmetrically substituted 1,3,4‐thiadiazoles (II).
ChemInform Abstract: Reaction of (Z)‐β‐Enamino λ5‐Phosphazenes and Dimethyl Acetylenedicarboxylate.
Authors: BARLUENGA J. , LOPEZ F. , PALACIOS F. 
Published: May 2016

AbstractEnamines of type (I) with a substituent ≠ H at the α‐position of the phosphorus atom react with the diester (II) in MeCN at room temperature to give P‐heterocycles of type (IV).
ChemInform Abstract: Synthesis and Solid‐ and Liquid‐State Characterization of a Hexameric Cluster of Titanium(IV): Ti6(μ2‐O)2(μ3‐O)2(μ2‐OC4H9)2(OC4H9)6(OCOCH3)8.
Authors: DOEUFF S. , DROMZEE Y. , TAULELLE F. , SANCHEZ C. 
Published: May 2016

AbstractAir‐moisture sensitive crystals of the title cluster (I) (space group P21/c, Z=2) are obtained from the 1:2 molar reaction of Ti tetrabutoxide and acetic acid within a few days.
ChemInform Abstract: Mono‐ and Dicarbonyl Complexes of Decamethylchromocene. A CO‐Induced η5 → η3 Ring Shift.
Authors: VAN RAAIJ E. U. , BRINTZINGER H. H. , ZSOLNAI L. , HUTTNER G. 
Published: May 2016

AbstractDecamethylchromocene (I) reacts with CO (II) at ambient pressure to form the 18‐electron complex (III).
ChemInform Abstract: Structures of SF5‐Substituted Metal Complexes.
Authors: DAMERIUS R. , LEOPOLD D. , SCHULZE W. , SEPPELT K. 
Published: May 2016

AbstractThe complexes (III) and (VI) (for both space group P21/n Z=4) are formed as expected; the complex (IX) (space group Pmcn, Z=4) is a product of an unclear reaction pathway.
ChemInform Abstract: Investigations on the UV/VIS Spectroscopic Behavior of Azo Dyes. Part 22. Blue Azo Dyes Based on 3‐Cyano‐6‐hydroxy‐2‐pyridones.
Authors: MUSTROPH H. 
Published: May 2016

AbstractA variety of title dyes such as (III) are prepared and their UV/VIS spectroscopic data are compared with those of the corresponding pyrazolone dyes (IV).
ChemInform Abstract: A Concise Route to (S)‐Phenylalanine from (R)‐Epichlorohydrin.
Authors: TAKANO S. , YANASE M. , OGASAWARA K. 
Published: May 2016

Abstract(R)‐Epichlorohydrin (I) is cleaved with phenyllithium (II) to give 3‐chloro‐2‐hydroxy‐1‐phenylpropane (III) which is cyclized to produce the benzyloxirane (IV).
ChemInform Abstract: Chromium Carbide Electrodeposition in Molten Fluorides.
Authors: STERN K. H. , ROLISON D. R. 
Published: May 2016

AbstractThe chemistry and electrochemistry related to the electrodeposition of chromium carbide from fluoride melts (i.e., the ternary (Li, Na, K) F fluoride eutectic, FLINAK) is studied.
ChemInform Abstract: Relative and Absolute Configurational Assignments of Acyclic Polyols by Circular Dichroism. Part 1. Rationale for a Simple Procedure Based on the Exciton Chirality Method.
Authors: WIESLER W. T. , NAKANISHI K. 
Published: May 2016

AbstractA general procedure for assigning multiple stereocenters in acyclic polyols is presented.
ChemInform Abstract: Unequivocal Proof of Slowed Chromium Tricarbonyl Rotation in a Sterically Crowded Arene Complex: An X‐Ray Crystallographic and Variable‐Temperature High‐Field NMR Study of (C6Et5COCH3)Cr(CO)3.
Authors: DOWNTON P. A. , MAILVAGANAM B. , FRAMPTON C. S. , SAYER B. G. , MCGLINCHEY M. J. 
Published: May 2016

AbstractThe title compound (I) crystallizes in the space group P1 with Z=2.
ChemInform Abstract: Use of β‐Sulfonylvinyl Ketones as Equivalents to Vinyl Ketones in Robinson Anellation. Convergent, Highly Stereoselective Preparation of a Hydrindanol Related to Vitamin D from 2‐Methylcyclopent‐2‐enone and Lithiated E‐But‐2‐enyldiphenylphosphine Oxide.
Authors: HAYNES R. K. , VONWILLER S. C. , HAMBLEY T. W. 
Published: May 2016

AbstractConjugate addition of lithiated butenyldiphenylphosphine oxide to the cyclopentenone (III) yields the intermediate enolate (IV) which reacts with the β‐sulfonylvinyl ketones (V) to form the unsaturated diketones (VI).
ChemInform Abstract: Photochemical Addition of Methanol to Stilbenes.
Authors: WONING J. , OUDENAMPSEN A. , LAARHOVEN W. H. 
Published: May 2016

AbstractThe photochemical addition of methanol (II) to stilbene (I) involves two competitive pathways: direct addition of methanol to the alkenic bond or insertion of a carbene (VI), emerging from a 1,2‐H shift in (I) to methanol.
ChemInform Abstract: Convenient Unimolecular Sources of Aryloxyl Radicals. Part 1. Aryloxyoxalyl Chlorides.
Authors: MODARELLI D. A. , ROSSITTO F. C. , LAHTI P. M. 
Published: May 2016

AbstractThe phenols (I) are consecutively treated with butyllithium and oxalyl chloride (II) to give the aryloxyoxalyl chlorides (III).
ChemInform Abstract: Oxidation by Cobalt(III) Acetate. Part 12. Stereoselective Formation of threo‐1‐Phenylpropane‐1,2‐diol Monoacetate in Oxidation of β‐Methylstyrenes Unsubstituted and Substituted with Electron‐Donating Groups by Cobalt(III) and Manganese(III) Acetate in Acetic Acid.
Authors: HIRANO M. , HAMAGUCHI T. , ZHANG X. , MORIMOTO T. 
Published: May 2016

AbstractThe oxidation of (E)‐ or (Z)‐β‐methylstyrenes such as (I) by Co(O‐Ac)3 or Mn(O‐Ac)3 in AcOH or AcOH/TFA leads to the threo mono‐ and diacetates (III) and (V) as main products.
ChemInform Abstract: Oxidation of Sulfide by Iodylarenes in the Presence of Vanadyl Acetylacetonate as a Catalyst.
Authors: BARRET R. , PAUTET F. , BORDAT P. , TINLAND B. , DAUDON M. 
Published: May 2016

AbstractOxidation of the aryl sulfides (I) with iodylbenzene in the presence of vanadyl acetylacetonate gives the sulfoxides (II), sulfones (III), and disulfides (IV).