bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Studies in Spiroheterocycles. Part 16. Synthesis of New Fluorine‐Containing Spiro‐3‐indoline Derivatives.
Authors: JOSHI K. C. , DANDIA A. , SANAN S. 
Published: May 2016

AbstractKnoevenagel reaction of the indole‐2,3‐diones (I) with the cyclic ketones (II) yields the oxocycloalkylideneindolones (III).
ChemInform Abstract: β‐Silyl Carbenes.
Authors: CREARY X. , WANG Y.‐X. 
Published: May 2016

AbstractThe trimethylsiloxychloronorbornene (I) is converted to the tosylhydrazone anion salt (IVc) which is subjected to flash vacuum pyrolysis, forming the norbornenylsilane (VIII) and the tricyclic compound (IX) via the carbene (VII).
ChemInform Abstract: Reaction of 2‐Chloro‐1,3‐dioxa‐2‐silacyclohexanes with Metallic Lithium.
Authors: NIKOLAEVA S. V. , ZORIN V. V. , KAZHDAN V. D. , KUKOVITSKII D. M. , LARIONOV V. I. , MUSAVIROV R. S. , RAKHMANKULOV D. L. 
Published: May 2016

AbstractThe dioxasilacyclohexanes (I) are coupled with elemental lithium to give the dimers (II).
ChemInform Abstract: Copper Chloride‐Cyanopyridine Complexes as Catalysts for the Decomposition of Fluorophosphonate Esters.
Authors: KATRITZKY A. R. , OFFERMAN R. J. , DURST H. D. , WARD J. R. , HOVANEC J. W. , ALBIZO J. M. 
Published: May 2016

AbstractSeveral copper(II) pyridine complexes such as (IV) are prepared.
ChemInform Abstract: Phosphorylation of Aromatic Compounds Containing Electron‐Donating Substituents with Phosphorus Tribromide.
Authors: TOLMACHEV A. A. , IVONIN S. P. , KHARCHENKO A. V. , KOZLOV E. S. 
Published: May 2016

AbstractPhosphorus tribromide (I) is coupled with N,N‐dimethylaniline (II) to give the phosphines (III) ‐ (V) depending on the molar ratio.
ChemInform Abstract: Novel Ditopic Receptors Based on the P2N2 Diphosphazane Ring: Synthesis and X‐Ray Structural Characterization of Cis and Trans Bis(crown ether) Anellated 1,3,2λ5,4λ5‐Diazadiphosphetidine 2,4‐Disulfide.
Authors: DUTASTA J.‐P. , DECLERCQ J.‐P. , ESTEBAN‐CALDERON C. , TINANT B. 
Published: May 2016

AbstractThe 1,3,2,4‐diazadiphosphetidine ring is used for the construction of the trans (VII) (space group P1, Z=1) and cis isomers (VIII) (P1, Z=2) of the bis(crown ether) derivative as shown in the scheme.
ChemInform Abstract: Synthesis and Structure of the First Example of a Borazinylcyclotri‐phosphazene.
Authors: WELKER M. F. , MANNERS I. , PARVEZ M. , ALLCOCK H. R. 
Published: May 2016

AbstractReaction of the aminophoshazene (I) with the chloroborazine (II) yields the title compound (III).
ChemInform Abstract: Synthesis and Reactions of 1,6‐Bis(2‐butyltellurophenyl)‐2,5‐diazahexa‐1,5‐diene and Related Compounds. The Crystal and Molecular Structures of 2‐(Butyldichlorotelluro)benzaldehyde and Bis(2‐(hydroxyiminomethyl)phenyl) Ditelluride.
Authors: ABID K. Y. , AL‐SALIM N. I. , GREAVES M. , MCWHINNIE W. R. , WEST A. A. , HAMOR T. A. 
Published: May 2016

AbstractThe title compound (VI) is prepared as shown.
ChemInform Abstract: (Tris(pyrazolyl)hydroborato)magnesium and ‐aluminum Alkyl Derivatives: Alkyl Exchange with Methyl Iodide and Enolate Formation with Acetone.
Authors: HAN R. , LOONEY A. , PARKIN G. 
Published: May 2016

AbstractThe methyl derivatives (III) and (VIII) of the title compounds are synthesized according to the scheme.
ChemInform Abstract: Calcium Complexation to Derivatives of Isonicotinic Acid: (Tetraaquabis(isonicotinamide)calcium) Dichloride and Tetraaquabis(isonicotinato)calcium, C12H20CaCl2N4O6 and C12H16CaN2O8.
Authors: COLE L. B. , HOLT E. M. 
Published: May 2016

AbstractThe both title compounds (I) (space group P1, Z=2) and (II) (P21/a, Z=4) are prepared by treating CaCl2 with aqueous solution of isonicotinamide or sodium isonicotinate.
ChemInform Abstract: Synthesis, Structure and Spectroscopic Properties of Some 2‐Phenylphenoxide Derivatives of Molybdenum.
Authors: BARTOS M. J. , KRILEY C. E. , YU J. S. , KERSCHNER J. L. , FANWICK P. E. , ROTHWELL I. P. 
Published: May 2016

AbstractBoth the Mo‐dimethylamido compounds (II) and (IV) react with 2‐phenylphenol (I) to yield the aryloxide complexes (III) and (V), respectively.
ChemInform Abstract: Thermal Isomerization of a Secondary Vinylphosphine into a Phosphaalkene.
Authors: MERCIER F. , HUGEL‐LE GOFF C. , MATHEY F. 
Published: May 2016

AbstractThe dihalomesitylphosphines (I) react with 2‐propenylmagnesium bromide (II) to give the substitution products (III).
ChemInform Abstract: Ferrapyrrolinone and Ferraazetine Complexes Formed from the Reaction of Fe2(μ‐CH2)(CO)8 with Phosphinimines.
Authors: MIRKIN C. A. , LU K.‐L. , GEOFFROY G. L. , RHEINGOLD A. L. , STALEY D. L. 
Published: May 2016

AbstractThe reaction of the ketenediiron complex (I) with the phosphinimines (II) leads to the isolable initial products (III) ((IIIa): space group Pbc21, Z = 8) which slowly deinsert CO to form the 2‐ferra‐3‐azetine complexes (IV) ((IVa): P21/n, Z = 8).
ChemInform Abstract: Electrochemical Synthesis and Structure of the First Example of a Ferrocene Dication: Propane‐1,3‐diyl‐1,1′‐bis(tetramethylcyclopentadienyl)iron(2+).
Authors: OGINO H. , TOBITA H. , HABAZAKI H. , SHIMOI M. 
Published: May 2016

AbstractThe ferrocenophane (III), prepared by lithiation of the ligand (I) and further reaction with iron dichloride (II), is electrochemically oxidized to give the cationic (V) and the dicationic complex (VII).
ChemInform Abstract: (2‐Stannylated‐Butadiene)tricarbonyliron Complexes: Practical Reagents for the Synthesis of 2‐Acyldienes.
Authors: COLSON P.‐J. , FRANCK‐NEUMANN M. , SEDRATI M. 
Published: May 2016

AbstractThe 2‐stannylbuta‐1,3‐dienes (I) are converted to the cis‐dienyliron complexes (III) which undergo Pd‐catalyzed acylation with the acid chlorides (IV), producing the 2‐acyldienyliron tricarbonyl complexes (V).
ChemInform Abstract: Complexes of Ligands Providing Endogenous Bridges. Part 7. The Concurrent Formation of 1 + 1 and 2 + 2 Oxaazamacrocycles; the X‐Ray Crystal Structure of an Exocyclic Dinuclear Copper(II) Complex.
Authors: BAILEY N. A. , FENTON D. E. , WILLIAMS M. G. , WINTER D. J. 
Published: May 2016

AbstractThe 1 + 1 oxaazamacrocycles (III) are prepared according to the scheme.
ChemInform Abstract: Binary Alloys of 2,5‐Disubstituted DCNQI Radical Anion Salts of Copper and Their Electrical Conductivity.
Authors: ERK P. , GROSS H.‐J. , HUENIG S. + , LANGOHR U. , MEIXNER H. , WERNER H.‐P. , VON SCHUETZ J. U. + , WOLF H. C. 
Published: May 2016

AbstractElectrocrystallization or even reaction with a copper wire leads to conversion of two DCNQIs such as (I) and (II) into the alloy (IV) (all having space group I41/a).
ChemInform Abstract: Platinum Metal Thioether Macrocyclic Complexes: Synthesis, Electrochemistry, and Single‐Crystal X‐Ray Structures of cis‐(RhCl2L2)PF6 and trans‐(RhCl2L3)PF6 (L2: 1,4,8,11‐tetrathiacyclotetradecane, L3: 1,5,9,13‐tetrathiacyclohexadecane).
Authors: BLAKE A. J. , REID G. , SCHROEDER M. + 
Published: May 2016

AbstractThe equimolar reaction of RhCl3·3 H2O (II) with the S4‐macrocycles (I) and (IV) affords the title complexes (III) and (V) (for both space group C2/c, Z=4) which are characterized by X‐ray structure analysis.
ChemInform Abstract: Cyclopentadienyldifluorophosphine and Its Homologues as Ligands in cis‐Dichloroplatinum(II) Complexes ‐ Structure of cis‐(C5Me5PF2)2PtCl2 and cis‐(C9H7PF2)((C9H7)3P)PtCl2 (C5Me5: Pentamethylcyclopentadienyl, C9H7: Indenyl).
Authors: HEUER L. , BODE U. K. , JONES P. G. , SCHMUTZLER R. 
Published: May 2016

AbstractThe preparation of cyclopentadienyldifluorophosphines such as (III) using appropriate organolithium compounds and PF2Cl and their reactivity toward the Pt‐complex (IV) are investigated.
ChemInform Abstract: Diastereoselective Synthesis of an α,β‐Diaminocarboxylic Acid: An Efficient Synthesis of FR900490, an Immunomodulating Peptide Isolated from a Fungus.
Authors: SETOI H. , KAYAKIRI H. , HASHIMOTO M. 
Published: May 2016

AbstractReductive amination of the chiral ketone (I) with methyl L‐histidinate (II) results in the stereoselective formation of the α,β‐diaminobutyric acid derivative (III), together with minor amounts of its diastereomer (IV).
ChemInform Abstract: Reactions of Sugars with Amidrazones and Hydrazidines. Part 2. The Synthesis of C‐Nucleoside Precursors. Part 2. Synthesis and Conformational Analysis of 3‐(Pentahydroxypentyl)‐6‐phenyl‐1,2,4‐triazolo(3,4‐a)phthalazines.
Authors: SHABAN M. A. E. , TAHA M. A. M. 
Published: May 2016

AbstractReaction of the hydrazine (I) with D‐glucose (II) results in cyclization of the thereby formed hydrazone to give the triazolophthalazine (III).
ChemInform Abstract: An Electrochemical Variant in the Syntheses of Exaltone and Muscone: Anodic Fragmentation of α,β‐Unsaturated Tosylhydrazones.
Authors: LIMACHER L. L. , DELAY F. D. , BEDERT N. , TISSOT P. 
Published: May 2016

AbstractRing enlargement of the bicyclic tosylhydrazones (I) under mild and controlled anodic oxidation conditions yields the monocyclic γ‐ynones (II) as main products.
ChemInform Abstract: Ethylene Biosynthesis. Part 10. Synthesis and Study of Racemic, (1R,2S)‐, and (1S,2R)‐1‐Amino‐2‐(hydroxymethyl)cyclopropanecarboxylic Acid.
Authors: PIRRUNG M. C. , DUNLAP S. E. , TRINKS U. P. 
Published: May 2016

AbstractAs shown for the (1S,2R)‐derivative (X), the title compounds are prepared by a route involving cycloalkylation of the malonate (III) with optically active epichlorohydrin and subsequent Hofmann rearrangement of the resulting amide.
ChemInform Abstract: A New Approach to the Synthesis of Aminoimidazoles: Application to the Cephalosporin Series.
Authors: JUNG F. , OLIVIER A. , BOUCHEROT D. , LOFTUS F. 
Published: May 2016

AbstractThe weakly basic 7‐aminocephalosporanates (I) or (VII) are coupled with the carbodiimides (II) or (VI), yielding the guanidinium salts (III) or (IX).
ChemInform Abstract: On Compound Formation of M′O:M2O3. Part 11. Crystal Structure of BaIn2O4.
Authors: LALLA A. , MUELLER‐BUSCHBAUM HK. + 
Published: May 2016

AbstractSingle crystals of the title compound, obtained from a melt after reacting intimate mixtures of BaCO3 and In2O3 at 840 °C (12 h), belong to the monoclinic space group P21/a with Z=16.
ChemInform Abstract: Structural Transformation in Nb2O5‐Promoted Rh Catalysts During Calcination and Reduction Treatments.
Authors: HU Z. , NAKAMURA H. , KUNIMORI K. , YOKOYAMA Y. , ASANO H. , SOMA M. , UCHIJIMA T. 
Published: May 2016

AbstractIt is found that the Nb2O5‐promoted Rh/SiO2 catalyst, which exhibits no significant SMSI effect (strong metal‐support interaction) after calcination in air at 773 K, shows a pronounced SMSI behavior after calcination at higher temp. (973 and 1173 K).
ChemInform Abstract: Evidence from XPS for the Stabilization of High‐Valent Molybdenum by Addition of Potassium in Mo/Al2O3 Catalysts.
Authors: DECANIO S. J. , CATALDO M. C. , DECANIO E. C. , STORM D. A. 
Published: May 2016

AbstractXPS analyses are performed for a series of Mo/Al2O3 catalysts with varying Mo (3‐15 wt.%) and K (0.5‐6.0 wt.%) content.
ChemInform Abstract: Introduction of Two‐Dimensional NMR Spectral Information to an Automated Structure Elucidation System, CHEMICS. Utilization of 2D‐INADEQUATE Information.
Authors: FUNATSU K. , SUSUTA Y. , SASAKI S. 
Published: May 2016

AbstractBy introduction of 13C NMR data and 13C‐13C signal connectivity information into CHEMICS, the number of probable candidate structures is drastically decreased, e.g., for menthol, thujopsene (4450 candidates without 2D‐INADEQUATE information), and linalool only one correct structure results.
ChemInform Abstract: Biological Method for the Preparation of Both Pure Enantiomers of a Chiral Compound: The Case of 2‐Amino‐1‐phenylethanol.
Authors: YAMAZAKI Y. , MOCHIZUKI K. , HOSONO K. 
Published: May 2016

AbstractBacteria which belong to the genera Staphylococcus (FRI‐52), Micrococcus (FRI‐121), Rhodococcus (FRI‐125) and Neisseria (FRI‐319), isolated from soil, are found to assimilate enantioselectively racemic 2‐amino‐1‐phenylethanol to give either the (S) or (R) enantiomer with high optical purity.
ChemInform Abstract: Highly Diastereoselective Aldol‐Type Reaction Using 3‐Acetylthiazolidine‐2‐thione.
Authors: JEONG T. M. , PARK K. H. 
Published: May 2016

AbstractThe amino alcohol‐derived thiazolidinethione moiety in (I) serves as efficient chiral auxiliary in the tin‐mediated aldol condensation.
ChemInform Abstract: Syntheses via Vinyl Sulfones. Part 35. SN2′ Addition of Organometallic Reagents to β′‐Amino Cyclohexenyl Sulfone Derivatives.
Authors: PAN Y. , HARDINGER S. A. , FUCHS P. L. 
Published: May 2016

AbstractThe amino(siloxy)cyclohexenyl sulfone (X) and the related quaternary ammonium salt (XIII) are prepared as shown in the reaction scheme via cleavage of the oxirane (IV).
ChemInform Abstract: Rhodium‐Catalyzed Hydrogenation of Quinolines and Isoquinolines Under Water‐Gas Shift Conditions.
Authors: MURAHASHI S.‐I. , IMADA Y. , HIRAI Y. 
Published: May 2016

AbstractA variety of quinolines and isoquinolines such as (I) or (III) can be hydrogenated selectively in the N‐containing ring by means of carbon monoxide and water in the presence of a rhodium carbonyl cluster.
ChemInform Abstract: Selective Reduction of Dienones. Synthesis of Intermediates for Sesqui‐and Diterpenes.
Authors: BHATTACHARYYA S. , KARPHA T. K. , MUKHERJEE D. 
Published: May 2016

AbstractThe indanone (I) is converted to the tricyclic dienediones (III) via TFA‐induced cyclization of the diazo ketones (II).
ChemInform Abstract: Alkylation of Enol Silyl Ethers by Pummerer‐Generated Vinylthionium Ions: A Novel Masked Michael Reaction.
Authors: HUNTER R. , CARLTON L. , CIRILLO P. F. , MICHAEL J. P. , SIMON C. D. , WALTER D. S. 
Published: May 2016

AbstractThe title reaction represents a novel method for the construction of C‐C bonds and generally proceeds with high regio‐ and stereocontrol.
ChemInform Abstract: A Convenient General Access to α‐Sulfenylated Acetophenones and Alkanones.
Authors: ISHIBASHI H. , TAKAMURO I. , MIZUKAMI Y. , IRIE M. , IKEDA M. 
Published: May 2016

AbstractThe sulfenylated acetyl chlorides (I) react with the benzenes (II) or the heterocycles (IV) in the presence of excess aluminum trichloride or tin tetrachloride to produce the (het)aromatic sulfenylmethyl ketones (III) and (V) respectively.
ChemInform Abstract: Synthesis of Substituted trans‐1,6‐Dimethylbicyclo(4.3.0)non‐2‐enes Using a Claisen Rearrangement of α‐(Thioalkoxy) Esters.
Authors: RICHARDSON S. K. , SABOL M. R. , WATT D. S. 
Published: May 2016

AbstractThe crucial step in the synthesis of the target compounds (V) is the Claisen rearrangement of the allylic α‐mercapto esters (III).
ChemInform Abstract: Facile Formation of Hindered Epoxides from Lithium Bromide‐Mediated Decomposition of 4,5‐Tri‐ and Tetrasubstituted‐1,3,2λ5‐dioxaphospholanes.
Authors: MURRAY W. T. , EVANS S. A. JUN. 
Published: May 2016

AbstractThe highly substituted diols (I) are converted to the dioxaphospholanes (III) which undergo LiBr‐mediated decomposition, forming the epoxides (IV).
ChemInform Abstract: Reactions of Unsaturated Compounds. Part 148. Synthesis of 5‐Substituted Furans by Reaction of 1,3‐Alkadiynes with β‐Dicarbonyl Compounds.
Authors: MELIKYAN G. G. , SARGSYAN A. B. , BADANYAN SH. O. 
Published: May 2016

AbstractThe diynes (I) are coupled with the β‐dicarbonyl compounds (II) to give the alkynylfurans (III) and, from the linear diynes (Ia) ‐ (Ic), the bifuryls (IVa) ‐ (IVc).
ChemInform Abstract: Mechanism of the Debromination in Heterocyclization Using α,α‐Dibromocarbonyl Compounds as Synthons.
Authors: AHLUWALIA V. K. , MEHTA B. , KUMAR R. 
Published: May 2016

AbstractCyclocondensation of the dibromoacetophenones (I) with phenylacetic acid (II) in the presence of triethylamine yields the debrominated diphenylfuranones (III).
ChemInform Abstract: Chemistry of Isoindoles and Isoindolenines. Part 35. 1‐Alkoxy‐2‐alkyl‐2H‐isoindoles ‐ o‐Quinoid Hetarenes with Unsymmetric Structure.
Authors: KREHER R. P. , HENNIGE H. , JELITTO F. , PREUT J. 
Published: May 2016

AbstractRegioselective O‐alkylation of (I) gives the isoindolium salt (III).
ChemInform Abstract: Aromatic Nucleophilic Nitrogen‐Nitrogen Exchange Reaction of N,N‐Dimethyl‐2,4‐bis(trifluoroacetyl)‐1‐naphthylamine with Amino Acid Derivatives: A Facile Synthesis of Fluorine‐Containing 1H‐Benzo(g)indolines and 1H‐Benzo(g)indoles.
Authors: HOJO M. , MASUDA R. , OKADA E. , MIYA H. 
Published: May 2016

AbstractDisplacement of the dimethylamino group in the naphthalene derivatives (I) by the amino acid ester hydrochlorides (II) produces the N‐naphthyl amino acid esters (III) which are cyclized under basic conditions, forming the benzo(g)indolines (IV).
ChemInform Abstract: Thienoisothiazoles. Part 3. The Synthesis and Reactions of 3‐Phenyl‐5‐alkylthioisothiazole‐4‐carbonitriles and 3‐Phenylthieno(3,2‐d)isothiazoles.
Authors: KREBS H.‐D. 
Published: May 2016

AbstractWith a view to investigating electrophilic substitution reactions of thieno(3,2‐d)isothiazoles, the derivative (III) is synthesized via ring closure of the title nitrile (IIa) and transformed to the target compound (VIII).
ChemInform Abstract: Fused Heterocyclic Systems. Part 1. Pyrano(3,4‐c)pyrrole‐4,7(2H,6H)‐dione. Synthesis and General Pharmacological Screening.
Authors: CARONNA S. , LAMARTINA L. , PETRUSO S. , SPRIO V. , CARUSO A. , FELICE A. 
Published: May 2016

AbstractThe aromatic aldehydes (I) are coupled with the chloromethyl pyrrolyl ketone (II) to give the acyl epoxides (III) which undergo intramolecular cyclization, producing the pyranopyrrolediones (IV).
ChemInform Abstract: (.+‐.)‐erythro‐γ,δ‐Dihydroxycarboxylic Acid Lactones from a β‐Lithiopropionate Equivalent and α‐Chloro Aldehydes.
Authors: PLEWE M. , SCHMIDT R. R. 
Published: May 2016

AbstractThe dilithium salt of β‐ethylthioacrylic acid (I) reacts with the α‐chloro aldehydes (III) to form predominantly the erythro‐adducts (IV) which produce the hydroxyalkyllactones (V) upon standing at room temperature or the chloroalkyllactones (VII) upon acidic hydrolysis.
ChemInform Abstract: Synthesis of Some 9‐(Aminoalkyl)‐6,7‐dihydropyrimido(2,1‐f)purine‐2,4,8(1H,3H,9H)‐triones.
Authors: PAWLOWSKI M. , BUSCHAUER A. , SCHUNACK W. 
Published: May 2016

AbstractThe protected amines (III), obtained by reaction of the pyrimidopurine (I) with the bromides (II) under phase‐transfer conditions, are converted to the theophyllinepropanoic acids (IV).
ChemInform Abstract: Synthesis of 7‐Alkyl‐8‐mercaptoxanthines.
Authors: ROMANENKO N. I. , FEDULOVA I. V. , PONOMARENKO N. I. , GNATOV N. I. , KLYUEV N. A. , PRIIMENKO B. A. , KOZIK T. A. , ALEKSANDROVA E. V. 
Published: May 2016

AbstractThe 7‐alkyl‐8‐bromoxanthines (I) react with sodium sulfide to give the 8‐mercapto derivatives (II).
ChemInform Abstract: Tilcotil Studies. (3 + 2) Additions with Isothiazol‐3(2H)‐one 1,1‐Dioxide.
Authors: BURRI K. F. 
Published: May 2016

AbstractIsothiazole derivatives, e.g. (I) and (VIII), react regiospecifically with 1,3‐dipolar agents such as (II) and (IX).
ChemInform Abstract: An Easy and Concise Synthesis of Aza Analogues of Calcium Antagonistic Benzothiazole Derivatives.
Authors: COUTURE A. , HUGUERRE E. , GRANDCLAUDON P. 
Published: May 2016

AbstractCyclocondensation of the tolylthiocarboxylate (V) with the aminochloropyridines (VI) produces the tolylthiazolopyridines (VII).
ChemInform Abstract: Phosphorus‐Containing Enamines. Part 5. Formation of 1,4‐Azaphosphorines During the Phosphorylation of Enamides.
Authors: ROZINOV V. G. , IZHBOLDINA L. P. , DONSKIKH V. I. , RASTOVSKII G. V. , SERGIENKO L. M. , DOLGUSHIN G. V. , DMITRICHENKO M. YU. 
Published: May 2016

AbstractThe vinylacetamides (I) are coupled with phosphorus pentachloride (II) to give the azaphosphonia compounds (III).
ChemInform Abstract: Aliphatic Bis(acyl) Selenides ‐ Synthesis and Characterization.
Authors: KAGEYAMA H. , TSUTSUMI H. , MURAI T. , KATO S. 
Published: May 2016

AbstractThe title compounds (III) are prepared as shown and characterized spectroscopically (IR, 1H and 13C NMR, MS).
ChemInform Abstract: Transition‐Metal Complexes with Sulfur Ligands. Part 46. Zn, Cd, Hg, Sn, Pb, Bi and Ti Complexes with the Bi‐ and Tetradentate Thiolato Ligands ′buS2′2‐: 3,5‐Di(tert.‐butyl)benzene‐1,2‐dithiolate(2‐), ′S4′2‐: 1,2‐Bis(2‐mercaptophenylthio)ethane(2‐) and ′buS4′2‐: 1,2‐Bis(3,5‐di(tert.‐butyl)‐2‐mercaptophenylthio)ethane(2‐).
Authors: SELLMANN D. , FREYBERGER G. , MOLL M. 
Published: May 2016

AbstractNeutral and anionic complexes with the title metals are prepared by reacting the neutral sulfur ligands (I) and (II) or their alkali salts with the metal halides or alkoxides.
ChemInform Abstract: Isolation and Characterization of Ti(O)(OAr‐2,6iPr2)2(NC5H4‐4NC4H8)2 (OAr‐2,6iPr2: 2,6‐Diisopropylphenoxide; NC5H4‐4NC4H8: 4‐Pyrrolidinopyridine): A Mononuclear Aryloxide Compound Containing a Terminal Titanium(IV)‐Oxo Group.
Authors: HILL J. E. , FANWICK P. E. , ROTHWELL I. P. 
Published: May 2016

AbstractThe title compound (IV) (space group C2/c, Z = 8) is formed by hydrolysis of the η2‐iminoacyl‐Ti(IV) compound (I) in the presence of 4‐pyrrolidinopyridine (III) and characterized by X‐ray analysis.
ChemInform Abstract: Conversion of η6‐Arylphosphine to η6‐Benzene Complexes of Molybdenum by Use of Strong Acids to Cleave the Phosphorus‐Carbon Bonds. The Crystal and Molecular Structure of (Mo(H)(η6‐C6H6)(PPh2CH2CH2PPh2)(PPh2F))BF4.
Authors: MORRIS R. H. , SAWYER J. F. , SCHWEITZER C. T. , SELLA A. 
Published: May 2016

AbstractThe major products in solution from the reaction between aqueous HBF4 (II) or HF and the η6‐phenylphosphine‐Mo complexes (I) are the fluxional hydrido (η6‐benzene) complex cations (IV) and the corresponding phosphonium cations (V).
ChemInform Abstract: Synthesis, Structure, and Electronic Properties of Octakis(μ3‐sulfido)hexakis(triethylphosphine)hexatungsten as a Tungsten Analogue of the Molecular Model for Superconducting Chevrel Phases.
Authors: SAITO T. , YOSHIKAWA A. , YAMAGATA T. , IMOTO H. , UNOURA K. 
Published: May 2016

AbstractThe title complex (V) (space group P1, Z=2) is synthesized according to the scheme.
ChemInform Abstract: Voltamperometric and Spectroscopic Studies of the Behavior of Manganese(II) and Manganese(III) Porphyrins with Dioxygen and Superoxide. Evidence for the Formation of a Mixed‐Valence Dimeric Manganese Porphyrin.
Authors: PERREE‐FAUVET M. , GAUDEMER A. , BONVOISIN J. , GIRERD J. J. , BOUCLY‐GOESTER C. , BOUCLY P. 
Published: May 2016

AbstractIn order to detect the existence, in solution, of reaction products between O2 or O·‐ 2 and manganese porphyrins, which may be intermediates in the oxidation reactions, the reaction of superoxide ion with Mn(II) and Mn(III) tetraphenylporphyrin is studied.
ChemInform Abstract: Multiple Bonds Between Main Group Elements and Transition Metals. Part 120. First Arylrhenium Oxides (σ‐Aryl)ReO3.
Authors: HERRMANN W. A. , LADWIG M. , KIPROF P. , RIEDE J. 
Published: May 2016

AbstractCoupling of the diarylzinc agents (I) with dirhenium heptoxide (II) leads to the formation of the (σ‐aryl)trioxorhenium(VII) compounds (III), together with the zinc perrhenate (IV).
ChemInform Abstract: Kinetics and Mechanism of the Decomposition of Cobalt Dioxygen Complexes of the Binucleating Macrocyclic Ligand BISBAMP.
Authors: GARCIA BASALLOTE M. , CHEN D. , MARTELL A. E. 
Published: May 2016

AbstractIn solution at pH 9‐12 and 50 °C the complexes (I) and (II) are present and undergo irreversible metal‐centered autoxidation to form Co(III) complexes.
ChemInform Abstract: Metal Complexes of Dimethyl Phthalimidomethylphosphine Oxide.
Authors: DODOFF N. I. , SPASSOVSKA N. CHR. , VARBANOV S. G. , BORISOV G. 
Published: May 2016

AbstractThe metal complexes (I)‐(VII) are synthesized in yields of 65‐95% by stoichiometric reactions of the title ligand with corresponding metal salts in solvents.
ChemInform Abstract: Synthesis, Spectroscopy, Magnetism and X‐Ray Structure of Bis(dichloromercury(II)‐μ‐Cl)mercury Bis(tris(2‐aminoethanethiolato)nickelate(II)) Tetrahydrate.
Authors: VAN DIEPEN M. G. W. , DE GRAAFF R. A. G. , HULSBERGEN F. B. , REEDIJK J. 
Published: May 2016

AbstractThe title compound (IV) (space group C2/n, Z=4) is obtained as shown.