bluuebunny/crossref_metadata_2025_split huggingface dataset:
Assessment of hydrological alteration and environmental flow requirements for Srisailam dam on Krishna River, India
Authors: Uday Kumar A. , Jayakumar K. V. 
Published: October 2018

Abstract
Natural flow plays a vital role in forming biotic diversity by controlling essential environmental conditions within the river channel and floodplain. This paper assesses the changes in streamflow and ecology caused on Krishna River by Srisailam dam. Regulated and unregulated river flow discharge data were collected at Nagarjuna Sagar gauge station which is located downstream of Srisailam dam. Flow Health (FH) software developed by the International Water Centre, Brisbane is used to calculate the hydrological alteration and environmental flow requirements due to Srisailam dam. Results show that impoundment of the dam mainly decreases the high flows by storing flood flow for water supply, irrigation purposes, etc., and enhances low flows due to hydropower operation. Regulation of the dam significantly affected the mean flow in August, September, and October. Mean annual flow (MAF) decreased considerably and seasonal flow shifted. The minimum flow released from the dam to downstream was calculated by two options, namely, low risk and medium risk to the environment. Low risk achieved a score of 0.61 FH and 0.5 FH was achieved by high risk, with a MAF volume of 40% (i.e., 7,225 m3) and 30% (5,847 m3), respectively.
Water quality modeling for determination of suitability of water for shrimp farming in tidal rivers
Authors: Farahani Navid Dolatabadi , Shahraiyni Hamid Taheri , Sheikhi Reza 
Published: October 2018

Abstract
In this study, the water quality of the Bahmanshir River and its water channels where Choebdeh Shrimp Farms (the largest shrimp culture complex in Iran) are located were simulated using MIKE11 software. First, an integrated hydraulic and salinity model of the river and its water channels was developed. Then, Manning and dispersion coefficients of the river were calibrated and validated. The most important parameters in the water quality model were determined by sensitivity analysis and these parameters were calibrated using in situ measured water quality data. The errors of salinity, temperature, nitrate, ammonia and dissolved oxygen (DO) models in the verification step were 7.9, 1.2, 0.34, 0.79 and 12%, respectively. Then, two scenarios were applied to the river and the effects of these scenarios on the water quality of the river and its channels were evaluated. The results demonstrated that the site selection of the shrimp culture complex had been performed well because different scenarios could not affect the water quality in the channels. Finally, the water quality in the channels was compared with the standard values of shrimp survival parameters. All of the parameters in the channels were in the range of standard values except DO, which was slightly under the standard value.
Modeling and validation of chlorination breakpoint with nitrite in wastewater treatment
Authors: Khawaga Rehab I. , Al-Asheh Sameer , Jabbar Nabil Abdel , Abouleish Mohamed 
Published: October 2018

Abstract
Chlorination in wastewater treatment is regarded as a complicated process due to its ammonia and nitrite content. Chlorine added to such systems reacts with ammonia undergoing episodes of complex reactions resulting in the chlorination breakpoint behavior. Most of the available chlorination mechanistic models are not easily applied which has restricted their practical utilization in treatment plants. In this study, a new mechanistic model for the chlorination breakpoint in ammonia-nitrite systems is suggested with a user-friendly interface and to be applicable with conditions occurring in wastewater treatment plants. The model was validated against laboratory studies reported in the literature and was also applied to forecast chlorine residual in a wastewater treatment plant in the region. The model simulated both experimental and field data reasonably well.
Modification of tea biochar with Mg, Fe, Mn and Al salts for efficient sorption of PO43− and Cd2+ from aqueous solutions
Authors: Akgül Gökçen , Maden Tuğba Bolat , Diaz Elena , Jiménez Eduardo Moreno 
Published: October 2018

Abstract
There is a requirement to provide more efficient, sensitive, low-cost materials for remediation of contaminated water. Biochar as a sorbent is an effective and low-cost material to remove contaminants in water but its adsorption properties can be improved by impregnation of metals on the surface. In this study, a biochar derived from industrial tea waste was modified with Mg, Fe, Mn and Al salts to create different composites, which were tested for PO43− and Cd2+ sorption. The modifications created biochars with the (hydr)oxides of each metal and changed the characterization parameters and surface functionality. Cd2+ was efficiently removed by all the materials even at high Cd2+ loadings in the water (100 mg Cd2+ L−1), the biochar with Mg being the most efficient in Cd2+ removal. The biochar with Mg also achieved the best sorption of PO43−, sorbing up to 30% at 20 mg PO43− L−1. Tea waste biochar can be modified with metal salts to enhance inorganic pollutant removal from waters, especially with Mg salts.
Effectiveness of termite hill as an economic adsorbent for the adsorption of alizarin red dye
Authors: Ayanda Olushola S. , Amodu Olusola S. , Adubiaro Habibat , Olutona Godwin O. , Ebenezer Oluwapese T. , Nelana Simphiwe M. , Naidoo Eliazer B. 
Published: October 2018

Abstract
The adsorption of alizarin red (AR) dye onto termite hill sample (THs) was investigated. Prior to the adsorption studies, the elemental, morphological, surface and structural properties of THs were examined by modern analytical methods. Instrumental analysis showed that the homogenous micro-structured THs are comprised of iron oxide, silica oxide, and alumina as major components. Experiments showed that the adsorption capacity of AR decreases with increasing pH and initial AR concentrations, and increases with increasing contact time, stirring speed and temperature. The equilibrium study obeyed the Langmuir adsorption model and the kinetics followed the pseudo-second-order model. About 95.0% AR reduction (1.425 mg/g) was achieved when 0.8 g of THs was mixed with 30 mL of 40 mg/L AR solution for 120 min at 400 rpm and a pH of 2. Thermodynamic study suggested that AR adsorption onto THs is spontaneous at higher temperatures of 323 K and above (ΔGo values are negative). However, ΔGo are positive at lower temperatures of 293–313 K, which implies that the adsorption process is not spontaneous at these temperatures. This study showed that THs could be used as alternative, low-cost, natural adsorbents for the removal of dyes from wastewater.
Pipe replacement by age only, how misleading could it be?
Authors: Pardo M. A. , Valdes-Abellan J. 
Published: October 2018

Abstract
Traditional methods for prioritizing the renewal of water are based on heuristic models, such as the number of breaks per length, rule-of-thumb, and records held by the water utility companies. Efficient management of water distribution networks involves factoring in water and energy losses as the key criteria for planning pipe renewal. Prioritizing the replacement of a pipe according to the highest value of unit headloss due to ageing does not consider the impact on water and energy consumption for the whole network. Thus, this paper proposes a methodology to prioritize pipe replacement according to water and energy savings per monetary unit invested – economic prioritization. This renewal plan shows different results if comparing with replacing pipelines with regard to age and it requires calculating water and energy audits of the water distribution networks. Moreover, the required time to recover the investment performed needs to be calculated. The methodology proposed in this work is compared with the unit headloss criterion used in a real water-pressurized network. The results demonstrate that using the unit headloss criterion neither water, energy nor the investment is optimized. Significant water and energy savings are not fully exploited.
Discharge capacity evaluation and hydraulic design of a piano key weir
Authors: Guo Xinlei , Liu Zhiping , Wang Tao , Fu Hui , Li Jiazhen , Xia Qingfu , Guo Yongxin 
Published: October 2018

Abstract
A piano key weir (PKW) is a new type of labyrinth weir that increases the unit discharge at the unregulated spillway inlet of the weir. It is considered to be an important structure in water supply and drainage systems. However, its complex geometry makes it difficult to achieve an optimal hydraulic design, and only a few design equations and criteria are available. This study investigates the discharge capacity of a PKW and evaluates the characteristics of its discharge using various sources of experimental data from a database. First, previously proposed discharge capacity formulas are summarized and analyzed. Then, a new formula that integrates the existing test data with the results of dimensional analysis and multiparameter optimization is proposed. The weir characteristics are evaluated using the proposed formula and a mathematical model. The results show that both the proposed formula and numerical model are promising approaches to evaluate the discharge capacity of an A-type PKW and can guide its design.
Variations in the key hydrological elements of the Yarlung Zangbo River basin
Authors: Li Dian , Li Jia , Zhang Linglei , Deng Yun , Zhang Yaowen 
Published: October 2018

AbstractBased on the monthly water level, runoff, precipitation and evaporation data from the four main hydrometric stations in the middle section of the Yarlung Zangbo River basin from 1956 to 2000, the periodic oscillations, trends and transformation characteristics at different time-scales are investigated via wavelet analysis. Moreover, the main periods of each time-series are identified by estimating the wavelet variance. The results show that the transformation scales of the monthly variation of the key hydrological elements over the last 44 years were 80–120, 40–70 and 16–24 months and that a high level of consistency was maintained at 16–24 months, where the periodic oscillation was the most significant. In addition, the first and second main periods of all hydrological elements were 18 and 9 months, respectively.
Optimal water allocation in Iran: a dynamic bi-level programming model
Authors: Yao Liming , Xu Zhongwen , Moudi Mahdi , Li Zongmin 
Published: October 2018

Abstract
Water resource scarcity increases societal instability, poverty, and economic recession. Therefore, sound water resource management is vital to alleviating water crises in the agricultural, domestic, and industrial sectors. Southeast Iran, which currently lacks good water resource management, is experiencing a severe water crisis. Taking Zabol and Zahedan as examples, this paper seeks to optimize water allocation between the two cities using a dynamic bi-level programming model; the upper level objective minimizes the deviation between water demand and supply, and the lower level objective maximizes the net economic benefits in each sector. A sensitivity analysis is then conducted on the different sources of available water to provide more information on water allocation over time.
Modified tannins and their application in wastewater treatment
Authors: Arismendi W. A. , Ortiz-Ardila Andrés E. , Delgado C. V. , Lugo Lorena , Sequeda-Castañeda Luis G. , Celis-Zambrano Crispín A. 
Published: October 2018

Abstract
The bio-flocculants used in this study were synthesised by the Mannich reaction, which includes three reagents: a substrate (tannin extracts of Acacia, Quebracho, and Castanea), formaldehyde, and an amine derivative (ethanolamine, diethanolamine, ammonium chloride). Nine natural flocculants were prepared by combining extracts and amines; these products were evaluated in three different wastewater samples in two experimental phases. In phase I, five physicochemical parameters were analysed. From the data obtained, a multivariate, completely randomised design (CRD-Manava) was used, with a factorial arrangement and mean plots. In phase II, the three bio-flocculants with the most statistically significant responses and their mixtures were examined, evaluating 14 biological and physicochemical parameters. Statistical analysis was guided in this phase by CRD blocks, finding a significant removal in the physicochemical parameters analysed in the different types of wastewater and obtaining removal rates between 50 and 90%, depending on the parameter. At the end of both phases, the bio-flocculants acacia-ammonium chloride and quebracho-diethanolamine were the most efficient in the removal of turbidity (34–99%), true colour (93–100%) and total solids (12–99%). In addition, the natural flocculants showed low mutagenicity index (MI: 0.33–0.93) compared to aluminium sulphate (MI: 4.87–8.81).
Co3O4/TiO2 hetero-structure for methyl orange dye degradation
Authors: Chowdhury Mahabubur , Kapinga Sarah , Cummings Franscious , Fester Veruscha 
Published: October 2018

Abstract
Advanced oxidation processes based on sulphate radical generated by peroxymonosulphate (PMS) activation is a promising area for environmental remediation. One of the biggest drawbacks of heterogeneous PMS activation is catalyst instability and metal ion leaching. In this study, a simple organic binder mediated route was explored to substitute Ti4+ ions into the Co3O4 host lattice structure to create a Co-O-Ti bond to minimise cobalt leaching during methyl orange degradation. The catalyst was characterised by X-ray diffraction, and scanning and transmission electron microscopy. The as-prepared catalysts with Co3O4:TiO2 ratio of 70:30 exhibited minimal leaching (0.9 mg/L) compared to other ratios studied. However, the pristine Co3O4 exhibited highest catalytic activity (rate constant = 0.41 min−1) and leaching (26.7 mg/L) compared to composite material (70:30 Co3O4:TiO2). Interestingly, the morphology of the composite and leaching of Co2+ ions were found to be temperature dependent, as an optimum temperature ensured strong Co-O-Ti bond for prevention of Co2+ leaching. The classical quenching test was utilised to determine the presence and role of radical species on methyl orange degradation. The fabricated catalyst also exhibited good catalytic activity in degrading mixed dyes and good recyclability, making it a potential candidate for commercial application.
Removal of methyl orange dye and copper (II) ions from aqueous solution using polyaniline-coated kapok (Ceiba pentandra) fibers
Authors: Herrera Marvin U. , Futalan Cybelle M. , Gapusan Rontgen , Balela Mary Donnabelle L. 
Published: October 2018

Abstract
Hollow tubular structured kapok fibers (Ceiba pentandra) were coated with polyaniline (PANI) molecules using an in situ oxidative polymerization technique. The tubular morphology of the kapok fibers was retained after PANI coating. The Fourier transform infrared (FT-IR) spectrum of the PANI-coated kapok fibers illustrated the vibration modes associated with the presence of PANI molecules. The PANI-treated kapok fibers achieved complete wettability with water molecules (zero water contact angle) from initially being highly hydrophobic (contact angle = 120°). In the present work, the removal of contaminants such as methyl orange dye and Cu(II) from aqueous solution using polyaniline-coated kapok fibers was investigated. Isotherm studies show that the removal of methyl orange dye (R2 ≥ 0.959) and Cu(II) (R2 ≥ 0.972) using PANI-coated kapok fibers follow the Langmuir isotherm model with maximum sorption capacities determined to be 75.76 and 81.04 mg/g, respectively. Based from thermodynamic studies, the sorption of methyl orange dye and Cu(II) are endothermic, feasible and spontaneous. Furthermore, kinetic studies show that the both processes follow a pseudo-second-order model, implying that the rate-determining step is chemisorption.
Quantification of water purification in South African palmiet wetlands
Authors: Rebelo Alanna J. , Emsens Willem-Jan , Esler Karen J. , Meire Patrick 
Published: October 2018

Abstract
Despite the importance of water purification to society, it is one of the more difficult wetland ecosystem services to quantify. It remains an issue in ecosystem service assessments where rapid estimates are needed, and poor-quality indicators are overused. We attempted to quantify the water purification service of South African palmiet wetlands (valley-bottom peatlands highly threatened by agriculture). First, we used an instantaneous catchment-scale mass balance sampling approach, which compared the fate of various water quality parameters over degraded and pristine sections of palmiet wetlands. We found that pristine palmiet wetlands acted as a sink for water, major cations, anions, dissolved silicon and nutrients, though there was relatively high variation in these trends. There are important limitations to this catchment-scale approach, including the fact that at this large scale there are multiple mechanisms (internal wetland processes as well as external inputs) at work that are impossible to untangle with limited data. Therefore, secondly, we performed a small field-scale field survey of a wetland fragment to corroborate the catchment-scale results. There was a reasonable level of agreement between the results of the two techniques. We conclude that it appears possible to estimate the water purification function of these valley-bottom wetlands using this catchment-scale approach.
Application of the advanced oxidative process on the degradation of the green leaf and purple açaí food dyes with kinetic monitoring and artificial neural network modelling
Authors: Charamba Lívia Vieira Carlini , da Rocha Santana Rayany Magali , do Nascimento Graziele Elisandra , Charamba Bruno Vieira Carlini , de Moura Maiara Celine , Coelho Luana Cassandra Breitenbach Barroso , de Oliveira Julierme Gomes Correia , Duarte Marta Maria Menezes Bezerra , Napoleão Daniella Carla 
Published: October 2018

AbstractThe study evaluated the advanced oxidative processes concerning the degradation of green leaf and purple açaí dyes, as well as the prediction of data through artificial neural networks (ANNs). It was verified that percentage of degradation on the wavelengths (λ) of 215, 248, 523 and 627 nm was 5.95, 49.99, 98.17 and 95.99%, respectively, when UV/H2O2 action and UV-C radiation was applied. A non-linear kinetic model proposed by Chan and Chu presented a good fit to the experimental data, reaching an R2 value between 0.978 and 0.999, for the studied λ. Within the ANN simulations through Statistica 6.0, the multilayer perceptron (MLP) (3-9-4) presented a better fit to the experimental data. However, higher values of R² were obtained when utilizing the sklearn package with Python language and an MLP (4-5-4) model. Assays with Staphylococcus aureus and Staphylococcus pyogenes bacteria isolates were performed and it was verified that after employing the UV/H2O2 process, there was a decrease in the toxicity of the solution of dyes. In evaluating S. aureus toxicity, normal growth was observed. However, for S. pyogenes bacteria, it was found that when using the UV/H2O2 process, toxicity was evidenced at post-treatment solution concentrations of 100, 70 and 50%.
Effects of the bottom slope and guiding wall length on the performance of a vortex drop inlet
Authors: Rhee Dong Sop , Park Yong Sung , Park Inhwan 
Published: October 2018

Abstract
Laboratory experiments were conducted to assess the performance of a vortex drop inlet with a spiral intake in subcritical and supercritical flow conditions. The water surface elevation at multiple locations was measured for different flowrates by varying the extent of the guiding wall and the longitudinal and radial bottom slopes. The measurements show that a steeper longitudinal bottom slope decreases the water surface elevation at the beginning of the intake, resulting in a transcritical flow in the intake structure. However, a steeper longitudinal bottom slope also causes the maximum water surface elevation to occur within the spiral intake. For an effective vortex drop inlet design, achieving a low water surface elevation throughout the entire spiral intake structure is required. Experimental results show that the two seemingly conflicting design criteria, namely, achieving a low water surface elevation in the approach channel and reducing the maximum water surface elevation in the intake structure, can be simultaneously achieved by adding a radial bottom slope.
Performance and bacterial diversity of bioreactors used for simultaneous removal of sulfide, solids and organic matter from UASB reactor effluents
Authors: Azevedo L. S. , Castro I. M. P. , Leal C. D. , Araújo J. C. , Chernicharo C. A. L. 
Published: October 2018

Abstract
Two bioreactors were investigated as an alternative to post-treatment of effluent from an upflow anaerobic sludge blanket (UASB) reactor treating domestic sewage, with an aim of oxidizing sulfide into elemental sulfur, and removal of solid and organic material. The bioreactors were operated at different hydraulic retention times (HRTs) (6, 4, and 2 h) and in the presence or absence (control) of packing material (polypropylene rings). Greater sulfide removal efficiencies – 75% (control reactor) and 92% (packed reactor) – were achieved in both reactors for an HRT of 6 h. Higher organic matter (COD) and solid (TSS) removal levels were observed in the packed reactor, which produced effluent with low COD (100 mg CODL−1) and TSS concentrations (30 mg TSSL−1). Denaturing gradient gel electrophoresis results revealed that a metabolically diverse bacterial community was present in both bioreactors, with sequences related to heterotrophic bacteria, sulfur bacteria (Thiocapsa, Sulfurimonas sp., Chlorobaculum sp., Chromatiales and Sulfuricellales), phototrophic purple non-sulfur bacteria (Rhodopseudomonas, Rhodocyclus sp.) and cyanobacteria. The packed reactor presented higher extracellular sulfur formation and potential for elemental sulfur recovery was seen. Higher efficiencies related to the packed reactor were attributed to the presence of packing material and higher cell retention time. The studied bioreactors seemed to be a simple and low-cost alternative for the post-treatment of anaerobic effluent.
Alternative use of Pseudomonas aeruginosa as indicator for greywater disinfection
Authors: Teodoro Anderson , Júnior Amilcar Machulek , Boncz Marc Árpád , Paulo Paula Loureiro 
Published: October 2018

Abstract
Greywater presents great potential for reuse; if treated correctly and efficiently, it can be used for several residential uses. The objective of this work was to test advanced oxidation for greywater disinfection through UV/TiO2, UV/TiO2/H2O2, photo-Fenton, UV/H2O2 and photolysis (UV) processes, using Pseudomonas aeruginosa as an alternative indicator. In general, the processes with hydrogen peroxide (150 mg.L−1) mixed in the pretreated greywater and exposed to solar radiation or artificial radiation from UV lamps were the most efficient in the disinfection experiments, with total inactivation of P. aeruginosa. These processes (UV/H2O2 and photo-Fenton) were better fitted to the log-linear/caudal decay model with remaining microorganism for the hydrogen peroxide concentration of 25 mg.L−1. The use of P. aeruginosa as an alternative indicator for the greywater disinfection was very promising due to its high resistance and high natural concentration in the effluent used in the experiments. The treatment applied with the UV/H2O2 process with the hydrogen peroxide concentration at 150 mg.L−1 was the only one that showed acute toxicity, even though it removed a good part of the surfactant concentration from the pre-treated greywater.