bluuebunny/crossref_metadata_2025_split huggingface dataset:
Quasar Properties from the Sloan Digital Sky Survey. II. The Quasars Obtained by the SDSS-IV in the First Two Years
Authors: Chen Zhi-Fu , Yi Shuang-Xi , Pang Ting-Ting , Chen Zhe-Geng , Gui Run-Jin , Wang Zhi-Wen , Mo Xiao-Hua , Yi Ting-Feng 
Published: October 2019

Abstract
This work aims to measure the properties of continuum and emission lines around C iv, Mg ii, Hβ, and Hα for the quasars observed by the extended Baryon Oscillation Spectroscopic Survey (eBOSS) during the first two years. We determine the quasar redshifts based on narrow [O iii] λ5007, broad Mg ii
λ2799, and/or C iv
λ1548 emission lines. The comparisons between the visual inspection redshifts included in DR14Q and the redshifts determined by us suggest that the visual inspection redshifts would be robust. We also infer the virial black hole mass of quasars based on C iv, Mg ii, Hβ, and/or Hα broad emission lines, using empirical relationships reported by previous studies. Systematic differences are remarkable among different line-based mass estimators reported by previous studies. Using the empirical relationship (Equation (1)), we improve the line-based mass estimators by recalibrating new coefficient (a, b), so that different line-based mass estimators are more consistent. We find that (a, b) = (0.96, 0.5), (0.91, 0.5), (0.82, 0.5), and (0.77, 0.5) are the best choices for the Hα-, Hβ-, Mg ii-, and C iv-based mass estimators, respectively. All these above properties are publicly available. We also find that the line and continuum luminosities are tightly correlated with each other. The Balmer lines show a negative Baldwin effect, while the metal lines display a positive Baldwin effect. In addition, we find that tight correlations are indwelled in different line luminosities.
10-Year Results of Small Incision Lenticule Extraction
Authors: Blum Marcus , Lauer Anna S. , Kunert Kathleen S. , Sekundo Walter 
Published: October 2019

PURPOSE:
To evaluate the 10-year results of refractive lenticule extraction using the small incision lenticule extraction (SMILE) technique for treatment of myopia and myopic astigmatism.

METHODS:
In 2008–2009, the first 91 eyes were treated using a novel surgical technique (SMILE), in which a refractive lenticule of intrastromal corneal tissue is removed through a small incision, completely eliminating flap cutting. A total of 56 of 91 eyes of the original treatment group volunteered for reexamination 10 years after surgery, including uncorrected and corrected distance visual acuity, objective and manifest refraction, and evaluation of the interface and corneal surface by slit-lamp examination. Late side effects such as corneal scarring, corneal ectasia, persistent dry eye symptoms, or cataract were documented.

RESULTS:
At 10 years postoperatively, there was no significant change from the 6-month results. Spherical equivalent was −0.35 ± 0.66 diopters and therefore close to target refraction. Sixteen of the 56 eyes (29%) had gained one to two Snellen lines. There was no loss of two or more lines in the long term. Regression was −0.35 ± 0.66 diopters over the 10-year period.

CONCLUSIONS:
This 10-year long-term study demonstrates SMILE to be an effective, stable, and safe procedure for the treatment of myopia and myopic astigmatism.

[
J Refract Surg.
2019;35(10):618–623.]
Burnout among Moroccan Oncologists: A National Survey
Authors: Benbrahim Zineb , Ibtihal Ahalli , Boujarnija Raihana , Atassi Mariam , Amaadour Lamiaa , Oualla Karima , Arifi Samia , El Fakir Samira , Mellas Nawfel 
Published: October 2019

Abstract
Introduction: Burnout is an unwanted outcome of chronic occupational stressors. Oncology staff is expected to suffer from burnout more than other health-care professionals. The aim of this survey was to determine the prevalence of burnout among Moroccan oncologists and to determine potential causal factors. Methods: We conducted a cross-sectional analytical study using an online self-administered questionnaire to oncologists in Morocco. We used the Maslach Burnout Inventory and additional questions exploring work and lifestyle factors. The questionnaire was sent in January 2018. Results: A total of 100 oncologists answered the questionnaire with predominance of women (75%), young participants (74%), and medical oncologists (60%). Eighty-five percent of the oncologists showed evidence of burnout. The rates of high scores of emotional exhaustion, depersonalization, and low scores of personal accomplishment were, respectively, 57%, 44%, and 56%. In the univariate linear analysis, age younger than 35 years (p = 0.014), being in residency training (p = 0.004), not having extra professional activities (p = 0.009), having an experience less than 10 years (p = 0.02) and estimating vacation time as not adequate (p = 0.05) were all significantly associated with increased burnout scores. In the multivariate analysis, only age &lt;35 years (p = 0.028), being in residency training (p = 0.026), and having an experience less than 10 years (p = 0.01) were independent risk factors of burnout. Conclusion: These findings reveal that burnout in oncologists is higher than those reported internationally. Multidimensional interventions should be implemented to reduce burnout rates among Moroccan oncologists.
MILLIMETER WAVE ABSORPTION IN HYDROXYAPATITE AND 3YSZ CERAMICS IN WIDE TEMPERATURE RANGE
Authors: Eremeev Anatoly , Egorov Sergei , Kholoptsev Vladislav 
Published: October 2019

In the field of ceramic-based materials processing the last three decades has been marked by significant academic and industry interest in Additive Manufacturing (AM) technology due to its capability to produce ceramic parts with complex geometry and customizable materials properties. Conceptually, AM technology is a layer-by-layer fabrication of three dimensional physical parts directly from computer-aided design [1]. Solidification of the parts prepared from substances containing ceramic powder may be performed either by conventional heat treatment of a part as whole or by directed energy deposition. Both these strategies can be implemented using gyrotron-based millimeter-wave facilities allowing alternatively both the uniform heating of large-size parts in multi-mode cavities and local heating by focused wave-beams [2]. Hydroxyapatite- and yttria-stabilized zirconia-based ceramics are widely used in biomedical applications due to their high biocompatibility. The knowledge of their microwave absorption variation with temperature and porosity as the materials are densified, is necessary to optimize the scheme of microwave heating. 8 mm diameter disks for the measurements were prepared by uniaxial compacting from commercially available hydroxyapatite (HA) powder and yttria-stabilized zirconia (3YSZ) powder (Tosoh corp.). The measurements were performed at 24 GHz 3 kW gyrotron system. Samples for measurements were placed into the gyrotron system applicator and surrounded with porous alumina based thermal insulation. The design of the applicator and insulation allowed performing optical measurements of both the sample size and temperature distribution over the surface of the sample using a digital monochrome CCD camera. Measurements were made by the calorimetric method, when the microwave power absorbed in the sample is determined basing on the difference of the heating/cooling rates at the moments of intentional abrupt change of the microwave power at different sample temperatures. Absorption coefficient was determined as a division of the absorbed power to the incident microwave power. Special calibration experiments were made for determining microwave power density in the applicator and inside the thermal insulation. The method allows to measure absorption coefficients in situ during the sintering process. Absorption coefficients of HA were obtained in the range of 200 C - 1200 C, and for 3YSZ - in the range of 400 C - 1400 C both in situ during sintering and for as sintered samples. Dependencies of the absorption coefficients on the temperature and porosity are discussed. References Vaezi, M., et al., Int. J. Adv. Manuf. Technol., 2013, 67, 1721–1759. Bykov, Yu., Eremeev, A., et al., IEEE Trans. Plasma Science, 2004, 32, 67–72.
CONTINUOUS INDUSTRIAL-SCALE MICROWAVE-ASSISTED EXTRACTION OF HIGH-VALUE INGREDIENTS FROM NATURAL BIOMASS
Authors: Splinter Steven , Radoiu Marilena 
Published: October 2019

An innovative technology for the continuous extraction of bioactive compounds from a wide range of biological materials has been developed, scaled up and successfully demonstrated at commercially-relevant scales. The technology, known as MAPTM, or “Microwave-Assisted Process”, robustly transfers from laboratory to continuous, industrial scale operation. In wide-ranging trials, MAPTM has comprehensively demonstrated its ability to outperform many KPIs of conventional extraction processes, while offering biomass throughput, product consistency and low operational costs not attainable by other emerging technologies. Radient’s proprietary continuous-flow MAPTM extractor, Figure 1, was designed for continuous processing of up to 200 kg/h of biomass material. Verification of the mechanical integrity of the system was confirmed by flow testing of biomass / solvent slurries. Testing and verification of the efficiency of microwave energy transfer to the extractor cavity was completed at various microwave power settings using flowing water at 870 kg/h. The microwave energy transfer to the system was verified to be &gt;95 % in each case. As an example of performance, continuous flow MAPTM extraction of the antioxidant SDG from flax biomass was performed using 70 % ethanol / water as the solvent at two different conditions: - 75 kg/h flax / 5 L/kg solvent / 15 kW microwave power / extractor residence time 24 min; - 110 kg/h flax / 5 L/kg solvent / 20 kW microwave power / extractor residence time 16 min. The industrial-scale conditions for these runs were determined by extrapolating from optimized conditions previously obtained from batch lab-scale MAPTM experiments. The continuous flow approach eliminates the requirement for having geometric similarity between scales, i.e the equipment shape and dimensions do not have to scale proportionately.
Synergetic effect of microwave plasma and catalysts in CO2 methanation
Authors: Polaert Isabelle , Alrafei Bachar , Delgado-Liriano Jose , Ledoux Alain 
Published: October 2019

The reduction of CO2 concentration in our atmosphere consists in a big challenge for researchers, who are trying to explore novel technologies in order to transform CO2 into high added-value products. CO2 conversion into methane using microwave plasma (MWP) manifests as a very promising solution due to the ease of transport of methane and its storage. Microwave plasma represents a source of high-energy electrons, active ions and radicals that enhance or enable chemical reaction. It can be supplied by electricity generated from renewable resources. Then, MWP does not require any electrode to be generated and thus, the cost of those electrodes and of maintenance is reduced compared to glow discharge or DBD plasmas. MWP also can be generated over wide range of pressure (between 10 mbar-1bar). In addition, in the case of MWP, more electrons and active species are produced in comparison with other type of plasma[1–4]. MWP is a very suitable medium for this chemical reaction and leads to an efficient dissociation of CO2. The catalytic reduction of CO2 with H2 using MWP has been investigated in this work and the synergetic effects between the plasma and several catalysts were studied. First, the reaction was carried out without any catalysts and the effect of CO2/H2 ratio, total flow rate and input energy were evaluated. Then, a microwave generated plasma process was coupled with several Nickel catalysts that we prepared and characterized [5] in order to lead the reaction into methane formation. Multiple configurations were studied by changing the position of the catalyst bed. Obtained results were compared with conventional catalytic tests made with the same catalysts. It was found that the conversion of CO2 and energy efficiency increased using plasma assisted catalytic methanation of CO2 in comparison with conventional process. Operating conditions were studied in order to optimize methane production and energy efficiency of Plasma-catalytic process. References Qin, Y., G. Niu, X. Wang, D. Luo, Y. Duan, J. CO2 Util., 2018, 28, 283–291. De la Fuente, J.F., S.H. Moreno, A.I. Stankiewicz, G.D. Stefanidis, Int J Hydrogen Energy, 2016, 41, 21067–21077. Ashford, B., X. Tu, Curr Opin Green Sustain Chem, 2017, 3, 45–49. Vesel, A., M. Mozetic, A. Drenik, M. Balat-Pichelin, Chem Phys., 2011, 382, 127–131. Alrafei, B., I. Polaert, A. Ledoux, F. Azzolina-Jury, Catal. Today, Available online 12 March 2019, In Press, Accepted Manuscript. https://doi.org/10.1016/j.cattod.2019.03.026
MICROWAVE PYROLYSIS OF BIOMASS IN A ROTATORY KILN REACTOR: DEEP CHARACTERIZATION AND COMPARATIVE ANALYSIS OF PYROLYTIC LIQUIDS PRODUCTS
Authors: Polaert Isabelle , Ubiera Lilivet , Abdelouahed Lokmane , Taouk Bechara 
Published: October 2019

The pursuit of sustainable relationship between the production and consumption of energy has accelerated the research into new fuels alternatives, and mainly focused on new technologies for biomass based fuels. Microwave pyrolysis of biomass is a relatively new process which has been long recognized to provide better quality bio-products in shorter reaction time due to the direct sample heating and the particular heating profile resulting from the interaction of biomass with the electric field component of an electromagnetic wave [1,2]. During the course of this research, flax shives were pyrolysed using a rotatory kiln reactor inside a microwave single mode cavity using a range of power between 100 and 200 watts, to reach a temperature range between 450 °C and 650°C. The liquid bio-oil samples recovered in each case were analyzed though gas chromatography-mass spectrometry (GC-MS) and gas chromatography-flame ionization detection (GC-FID) to identify and quantify the different molecules presents and paying a particular attention to the BTX’s concentration. More than two hundred compounds were identified and grouped into families such as carboxylic acids, alcools, sugars for a deep analysis of the results. The effect of the operating conditions on the proportion of gas, liquid and char produced were studied as well as some properties of the pyrolysis products. In most cases, carboxylic acids were the dominating chemical group present. It was also noticed that the increase of temperature enhanced the carboxylic acids production and diminished the production of other groups, as sugars. Finally, pyrolysis oils were produced in higher quantities by microwaves than in a classical oven and showed a different composition. The examination of the pyrolytic liquid products from different biomass components helped to determine the provenance of each molecule family. On the operational side, the rotatory kiln reactor provided a fast and homogeneous heating profile inside the reactor, desired for fast pyrolysis. The high temperature was maintained without making hot spots during the reaction time. The microwave irradiation setup consisted in a single-mode cavity, a system of plungers, incident and reflected power monitors, an isolator and a 2.45 GHz continuous microwave generator with a power upper limit of 2000 watts. The plunger system was calibrated to maintain a range of reflective wave between 5 and 15%, taking advantage of a minimum of 85 percent of the applied power. In conclusion, the developed microwave pyrolysis process gives a clear way to produce an exploitable bio-oil with enhanced properties. References Beneroso, D., Monti, T., Kostas, E., Robinson, J., CEJ, 2017.,316, 481- 498. Autunes E., Jacob M., Brodie, G., Schneider, A., JAAP, 2018,129, 93-100.
Numerical simulation of the activation process of supersonic gas flows by a microwave discharge.
Authors: Bobrov Maxim , Hrebtov Mikhail , Rebrov Alexey Kuzmich 
Published: October 2019

Supersonic gas flows activated by microwave discharge are commonly used to obtain thrust for spacecraft. When using a mixture of hydrocarbons and hydrogen as a working gas, the proposed method generates high-speed plasma streams with a high concentration of radicals, allowing it to be used for efficient deposition of diamond films . To optimize diamond synthesis processes, it is necessary to study the effect of various system parameters (geometrical dimensions, radiation power, pressure and others). This abstract presents a numerical simulation of the formation of high-speed gas flow activated by a microwave discharge. The conjugate problem of hydrodynamics and plasma dynamics was solved in the continuum approximation, taking into account impact ionization and thermal dissociation, due to microwave heating of the gas. The simulations were carried out in an axisymmetric formulation. The region of plasma flow formation was a cylindrical chamber (radius 5 cm, height 7 cm). At this stage, hydrogen was chosen as the working gas. The flow outlet is a hole at the center of the lower boundary with fixed pressure of 2 torr. The gas entered the domain at a constant flow rate of 20 l/min through the openings in side wall along its normal. Such flow rate sustained the mean pressure in the chamber at the level 200 torr. Microwave radiation was injected by a coaxial port located above the plasma chamber. The geometrical dimensions of the resonant chamber were selected in order to form the maximum of the electric field intensity over the gas outflow region (total deposited power 1000W). The distributions of velocity, temperature, and concentrations of all components of the hydrogen plasma were estimated. Optimal characteristics of the system were found to reach a high mole fraction of atomic hydrogen, necessary diamond deposition.
Microwave influenced laminar premixed hydrocarbon flames: Spectroscopic investigations
Authors: Eckart Sven , Behrend Ralph , Krause Hartmut 
Published: October 2019

Low laminar burning velocity’s and slow reactions propagation are among a key problem in combustion processes with low calorific gas mixtures. The mixtures have a laminar burning velocity of 10 cm/s to 15 cm/s or even below which is 37% of natural gas. Thermal use of these gases could save considerable amounts of fossil fuel and reduce CO2 emissions. Due to low burning velocities and low enthalpy of combustion, ignition and stable combustion is complex, often preventing utilization of these gases. Microwave-assisted combustion can help to solve these problems. With microwave assistance, these gas mixtures could be burned with a higher burning velocity without preheating or co-firing. Therefore, this effect could be used for flame stabilization processes in industry applications. Microwaves could also change the combustion properties, for example radical formation and flame thickness. In this paper, we explore a possibility of using microwaves to increase the burning velocity of propane as one component in low calorific gas mixtures and also show higher productions of OH* and CH* radicals with an increase of the input microwave power. Different compositions of low calorific fuels were tested within a range of equivalence ratios from φ= 0.8 to φ= 1.3 for initial temperatures of 298 K and atmospheric conditions and microwave powers from 120 W to 600 W. For the experiments, a standard WR340 waveguide was modified with a port for burner installation and filter elements allowing for flue gas exhaust and optical access from the side. A 2.45 GHz CW magnetron was used as microwave source, microwave measurements were carried out with a 6-port- reflectometer with integrated three stub tuner. An axisymmetric premixed burner was designed to generate a steady conical laminar premixed flame stabilized on the outlet of a contoured nozzle under atmospheric pressure. The burner was operated with a propane mass flow of 0.2-0.4 nl/min at an equivalence ratio of φ= 0.8 to φ= 1.3. The optical techniques used in the current study are based on the flame contours detection by using the OH* chemiluminescence image technique. For every experimental case, 150 pictures were taken and averaged. Additionally, spectroscopic analysis of the flames was undertaken. The results suggest that production of OH* radicals in the flame front increases with microwave power. For evaluation, a picture based OH* chemiluminescence and a spectrographic method was used. In addition, a 9.9% increase of the burning velocity was observed in the premixed propane-air mixture for a 66 Watt absorbed microwave power. This effect is attributed to the increased OH* (~310nm) and CH* (~420nm) radical formation, which also reduces the flame thickness. It was found that absorption of microwaves in flames is generally low, but could be improved by a customized applicator design.
LOW-COST MEASUREMENT SYSTEM AND FILTER FOR REDUCTION OF EMC INTERFERENCES IN RADIO-FREQUENCY APPLICATIONS
Authors: Roland Ulf , Sallier René , Nietner Lutz , Trommler Ulf , Kraus Markus , Holzer Frank , Hoyer Christian , Schlayer Detlef 
Published: October 2019

For drying building structures [1], dielectric heating using RF energy (in this case 13.56 MHz) is an efficient and fast alternative to conventional heating methods based on heat transfer from the surface to the interior of the masonry. Another innovative application of volumetric RF heating is the chemical-free pest control in wood-based materials [2]. For such applications where the RF systems often are not completely shielded, the propagation or coupling of the electromagnetic wave into wires that are placed inside the field cannot be neglected which represents a certain risk. Depending on the different electromagnetic coupling mechanisms, several interference signals can be generated. In order to protect electrical equipment in the surrounding, these interferences have to be significantly reduced by electrical filters. For this purpose, initially a cost-effective (at least in comparison to standard RF measurement systems) and more robust measuring concept was developed. With the help of this system, the common mode (I_CM) interference could be identified as the dominant part and the differential mode (I_DM) interference as a minor disturbance. Based on the experimental evaluation, a cost-effective filter for the respective disturbance was constructed and successfully tested.
High Efficiency Microwave Flow Chemistry Towards Synthesis of Functional Materials and Pharmaceutical Cores
Authors: Barham Joshua Philip , Norikane Yasuo , Egami Hiromichi , Hamashima Yoshitaka 
Published: October 2019

Microwave (MW) heating benefits organic synthesis by affording higher product yields in shorter time periods than conventional heating, yet it suffers from poor scalability and is limited to polar solvents in typical batch mode reactors. Herein, we report a microwave flow reactor using a solid-state semiconductor MW generator. The tunable, single-mode MW heating allows high efficiency, scalable organic synthesis, rapid reaction optimization and is applicable to non-polar solvents (o-Xylene and CPME can be rapidly heated to ca. 260 oC). Auto-frequency tuning compensates for changes in the microwave absorption properties (permittivity, epsilon) with increasing temperature, affording excellent temperature and process control. This technology unlocked unprecedented g/h productivity of C60/fullerene-indene monoadduct (IC60MA) and facilitated a novel, transition metal-free amide-styrene coupling reaction for synthesis of amide-containing pharmaceutical cores in up to 65 g/h (Figure 1). An ortho-Claisen rearrangement reaction was rapidly optimised.