bluuebunny/crossref_metadata_2025_split huggingface dataset:
Synthesis and Characterization of Pd(II) and Ni(II) Complexes of Schiff Bases and Catalytic Activity of Pd(II) Complexes
Authors: Mohd Tajuddin Amalina , Bahron Hadariah , Ahmad Shahrul Nizam 
Published: March 2019

Six new Pd(Il) and Ni(Il) metal complexes of N, O-bidentate (LI, L2) and ONNO-tetradentate (L3) Schiff base ligands have been synthesized. The compounds were characterized via various physicochemical and spectroscopic techniques namely elemental analysis (CHN), FT-IR, 1H and 13C NMR. as well as magnetic susceptibility measurement. All complexes showed diamagnetism indicating that they are square planar complexes. Catalytic performance of Pd(L1)2 and Pd(L2)2 were investigated for Heck cross-coupling reaction under optimum operating parameters, monitored using GC-FID for 6 h of reaction time in inert conditions. High catalytic activities of up to 90% were observed in the presence of triethylamine as base and DMA as solvent at 100C with 1 mmol% catalyst loading. The mechanism of catalyzed Heck reaction is proposed to go through a series of conversion of Pd(0)/Pd(II).
Determining Influence of Culture Media and Dose-Dependent Supplementation with Basic Fibroblast Growth Factor on the Ex Vivo Proliferative Activity of Domestic Cat Dermal Fibroblasts in Terms of Their Suitability for Cell Banking and Somatic Cell Cloning of Felids
Authors: Młodawska Wiesława , Mrowiec Patrycja , Grabowska Beata , Waliszewska Joanna , Kochan Joanna , Nowak Agnieszka , Migdał Anna , Niżański Wojciech , Prochowska Sylwia , Partyka Agnieszka , Pałys Marcin , Grega Teresa , Skotnicki Józef 
Published: March 2019

Abstract
Dermal fibroblasts are commonly used as donors of genetic material for somatic cell nuclear transfer in mammals. Basic fibroblast growth factor (bFGF) is a cytokine that regulates proliferation and differentiation of different cell types. The study was aimed at optimizing the cell culture protocol for cat dermal fibroblasts by assessing the influence of culture media and different doses of bFGF on proliferation of fibroblasts and their viability in terms of cell banking and somatic cloning of felids. In Experiment I, skin biopsies of domestic cats were cultured in DMEM (D) and/or DMEM/F12 (F), both supplemented with 5 ng bFGF/ml (D-5, F-5, respectively). After the primary culture reached ~80% of confluency, the cells were passaged (3–4 times) and cultured in media with (D-5, F-5) or without (D-0, F-0) bFGF. To determine the optimal doses of bFGF, in Experiment II, secondary fibroblasts were cultured in DMEM with 0 (D-0), 2.5 (D-2.5), 5 (D-5) or 10 (D-10) ng bFGF/ml. The results showed that in D-5 the cells proliferated faster than in D-0, F-5 and F-0. Due to their poor proliferation, passages IV were not performed for cells cultured in F-0. In experiment II, a dose-dependent effect of bFGF on proliferation of cat dermal fibroblasts was found. In D-5 and D-10, the cells exhibited higher (P<0.05) proliferation compared with D-0. In D-2.5 the cells showed a tendency to proliferate slower than in D-5 and D-10 and at the same faster than in D-0. In conclusion. DMEM supplemented with bFGF provides better proliferation of domestic cat dermal fibroblasts culture than DMEM/F12. Supplementation of culture medium with bFGF has a beneficial effect on cat dermal fibroblast proliferation and could be recommended for addition to culture media.
The optimal position of a pumping station in the mining area based on the digital terrain model
Authors: Poniewiera Marian , Jelonek Iwona , Błaszczak-Bąk Wioleta 
Published: March 2019

Abstract
The purpose of the work described in the article was to find the optimal location of the pumping station for the mining area Krzyżowice III Hard Coal Mine “Pniówek”. Mining exploitation causes lowering of the area and changes in water relations. Hence, it is necessary to perform a gravitational, and if it is impossible, forced outflow of water. Localization of the pumping station should assure removal of excess water and prevent flooding. Not only was the present relief taken into account, but also the entire period of the mine’s existence. On the basis of the results of airborne laser scanning a digital terrain model (DTM) was generated. Then a catchment division was made for the entire analyzed area. The article presents the workflow of performing the simulation as the area will be changed due to forecasted mining operations. A practical way to solve the problem of simplifying large amounts of data was also shown. The obtained source materials were developed with the use of the Geolisp software. The system operates in a CAD graphic environment and allows for automation of the most frequently performed works in the field of mining map preparation. The Geolisp cooperates with EDN-OPN program. Thanks to this fact it is possible to combine the obtained results of calculations of predicted deformations of the mining area and the rock mass with the digital map.
Correlating soil and urban planning for sustainable water cycle
Authors: Sharma Sheetal 
Published: March 2019

Abstract
Hydrological modelling and processes using modern hydrological models like SCS Curve Number, HCS, HSPF (Hydrologic Simulation Package-Fortran) and kinematic wave models are widely used nowadays in various researches. But using these modelling in drawing the attention of urban planners for challenges and multiple interactions in heterogeneous urban catchments and water systems is still a shortcoming in water sensitive, planning principle. The art of urban planning and technical implementation using behavioural changes in water responses to urban catchments is the need of present urban planning. The complexities of effects and behavioural changes in the water system or urban catchments and incomplete knowledge of these interactions result in failures of sustainable urban developments. Urban planning needs water sensitive methodology to synchronize soil, water and land cover operational with the population over it. The paper reviews the water sensitive urban planning considering the role of soil in urban planning for water and lands correlations, with the purpose of identifying current limitations and opportunities for future urban planning.
Data availability and simplified methods are still a strong limitation for urban planners. Therefore, urban hydrology is often simplified either as a study of surface runoff over impervious surfaces or hydraulics of piped systems. Hence the paper provides approach and universal solution to forecast the behaviour of urban catchment for urbanization in terms of natural land-water cycles and its application in planning existing or new urban catchments. The methodology consists of observing Urban watershed catchment areas with different soil groups and built-up induction over them. A detailed study of water levels in hydrological wells and runoff pattern for the period of 40 years have provided a linear correlation of soil, roughness, land cover, infiltration, ground water and built upon the basis of soil behaviours. These correlations conclude to make regression equations as the blueprint for future urban planning norms to be followed by the planners, engineers, and hydrologists for planning.
Forecasted estimation of the efficiency of agricultural drainage on drained lands
Authors: Rokochinskiy Anatoliy , Volk Pavlo , Pinchuk Oleg , Turcheniuk Vasyl , Frolenkova Nadiia , Gerasimov Ievgenii 
Published: March 2019

Abstract
In the article we developed the design principles and implementation of a complex model and optimized the design parameters of drainage. The study was based on the implementation of interconnected structural and technological forecasting simulation and optimization model blocks, which in turn allowed to justify the optimal design parameters and drainage considering multiple natural and agronomic conditions and reclamation facilities. Example of evaluating the performance of drainage on drained lands was made for the conditions of a real project, implemented on lands of agricultural holding “May Day” located within of drainage system “Ikva” in the Rivne region. For the object conditions (average decade formation conditions of the drainage flow module for growing perennial grasses, winter cereals and potatoes) the estimated duration of the growing season was 214 days (100%), of which the total duration of drainage was 60% and included different levels of efficiency: 39% – ecological, 15.5% – technological and 5.5% – economic. The duration of its critical operations (forming module drainage flow exceeds the design of its value) does not exceed 5%. Thus, this approach enables the assessment of drainage with predetermined or specified parameters in the construction or renovation of drainage systems on different levels of effectiveness. It can be effectively used in the overall complex predictive and optimization calculations to substantiate the design and parameters of agricultural drainage, taking into account the variability of natural agrotechnical and reclamation conditions of a real object.
Resenha de Escritos ficcionais:
Authors: Berriel Carlos Eduardo Ornelas 
Published: March 2019

Resenha do livro:
MARX, Karl. Escritos ficcionais: Escorpião e Félix e Oulanem. Tradução Claudio Cardinali, Flavio Aguiar e Tercio Redondo. São Paulo: Boitempo, 2018.
Procedimentos narrativos na contística rawetiana
Authors: Klidzio Natalia Inês 
Published: March 2019

Situa a obra de Rawet na contemporaneidade e analise as técnicas narrativas. O procedimento técnico rawetiano se contrapõe ao tradicional e propõe novas possibilidades, de interpretações de perfil de novo leitor, crítico capaz de perceber a infinitude da subjetividade humana. Pontua a aproximação da constística rawetiana com a ensaística. A fragmentação do enredo, os personagens no domínio infinito e a prosa poético-filosófica são as principais (in)variáveis presentes nos contos transgressores de Samuel Rawet. Rawet no ofício de escritor e de engenheiro têm pontos de convergência. A construção da ficção rawetiana concede amostra dessa aproximação.
Pembuatan Kompos Granul Ela Sagu Diperkaya Pupuk Majemuk 15:15:15 dan Aplikasinya Pada Budidaya Tanaman Bawang Merah
Authors: La Habi Maimuna 
Published: March 2019

Effort to reduce the high dependence of farmers on urea fertilizers is adding sago pith waste granular compost as organic fertilizer. This research is conducted to develop granular-enriched compost and evaluate the effectiveness of granular-enriched compost on red onion cultivation. The application of granular-enriched compost was designed in a Randomized Block Design with three replicates. Treatments included 1) without fertilizers (KGES1); 2) the granular-enriched compost (8 t/ha) (KGES2); 3) recommended dosage of inorganic fertilizers such as Urea, SP-36, and KCl (KGES3); 4) inorganic fertilizer + granular-enriched compost (8 t/ha) (KGES4); 5) ½ x dosage of inorganic fertilizer + granular-enriched compost (8 t/ha) (KGES5); 6) 2× dosage of inorganic fertilizer + granular-enriched compost (8 t/ha) (KGES6); 7) ½× dosage of inorganic fertilizer + granular-enriched compost (12 t/ha) (KGES7) and 8) 2× dosage of inorganic fertilizer + granular-enriched compost (4 t/ha) (KGES8). The granular-enriched compost used in this research has characteristic such as N 2.43 %, P 0.59 %, and K 0.87 %. Based on this study it could be stated that reduction a half dose of inorganic fertilizer combined with compost granule 12 t/ha (KGES7) could give profitable dry bulb yield (13 t/ha) or increased 32% over the inorganic fertilizer. This combination could possibly reduce the amount of the inorganic fertilizer; therefore, it can be used for improving the effectiveness of fertilizer application on the red onion cultivation.
Keywords: granular-enriched compost, inorganic, red-onion

ABSTRAK
Upaya untuk dapat mengurangi tingginya ketergantungan petani terhadap pupuk urea yang paling murah yaitu dengan penambahan pupuk organik kompos atau kompos granul. Penelitian ini bertujuan untuk mengembangkan pupuk organik diperkaya bentuk granul dari kompos ela sagu dan mengevaluasi efektifitasnya pada budidaya tanaman bawang merah. Rancangan penelitian yang digunakan yaitu rancangan acak kelompok dengan tiga kali ulangan. Perlakuan terdiri atas: tanpa pupuk (KGES1), kompos granul (8 t/ha) (KGES2), pupuk anorganik (Urea, SP-36, dan KCl) dosis anjuran (KGES3), pupuk anorganik + kompos granul (8 t/ha) (KGES4), ½× dosis pupuk anorganik + kompos granul (8 t/ha) (KGES5), 2 kali dosis pupuk anorganik + kompos granul (8 t/ha) (KGES6), ½× dosis pupuk anorganik + kompos granul (12 t/ha) (KGES7) dan 2 kali dosis pupuk anorganik + kompos (4 t/ha) (KGES8). Pupuk kompos granul diperkaya dengan pupuk phonska yang digunakan dalam penelitian memiliki karakteristik sebagai berikut: kandungan N = 2,43%, P = 0,59% dan K= 0,87%. Hasil Penelitian menunjukkan bahwa pengurangan setengah dosis pupuk anorganik yang dikombinasikan dengan kompos granul 12 t/ha menghasilkan bobot kering umbi tertinggi (13 t/ha) atau meningkatkan hasil 32% dari aplikasi pupuk anorganik.
Kata kunci: bawang merah, inorganik, kompost granula diperkaya
ANALYTICAL APPROACH TO TECHNOLOGICAL SUPPORT OF FATIGUE LIMIT
Authors: Тотай Анатолий , Totay Anatoliy 
Published: March 2019

In the paper on the basis of the theory of metal plastic deformation there are obtained analytical de-pendences of dislocations critical density and cycle number up to destruction caused by factors technological impact upon the surface under working.
For the first time in complex there are taken into account such physical characteristics as an effort, temperature and speed of deformation in the area of cutting and strengthening.
A tie between such parameters of surface layer state as a steel grain size and dislocations density is defined.
ASSESSMENT MODEL OF COMMODITY-MATERIAL STOCKS SUPPLIER APPEAL OF LOGISTICS COMPANIES
Authors: Зёрнышкин Алексей , Zernyshkin Aleksey , Сизов Александр , Sizov Aleksandr , Добрица Вячеслав , Dobrica Vyacheslav , Головин Алексей , Golovin Aleksey , Халин Юрий , Halin Yuriy 
Published: March 2019

The work is devoted to the consideration of the approach to effectiveness increase in socialeconomic system operation through the fuzzy model development for the supplier choice of commoditymaterial stocks in logistic companies. The problem urgency is conditioned on the system approach absence in the overwhelming majority of companies to the formation of procurement logistics strategy which makes difficulties in the process rapid management and charges efficient control.
The theory of fuzzy sets is a methodological ba-sis of the work.
The model developed has a practical value for the leadership of logistics companies.
REDAKSI DAN DAFTAR ISI
Authors: Jurnal Ilmu Hukum DIH 
Published: March 2019

ISSN: 0216-6534DiH Jurnal Ilmu HukumVolume 13 Nomor 25Februari 2017Â Pemimpin RedaksiDr. Endang Prasetyawati, S.H., M.Hum.Â Sekretaris RedaksiTomy Michael, S.H., M.H.Â Dewan PenyuntingProf. Dr. Made Warka, S.H., M.Hum.Dr. Slamet Suhartono, S.H., M.H.Dr. Otto Yudianto, S.H., M.Hum.Dr. Hufron, S.H., M.H.Â Penyunting BahasaSugeng Hadi Purnomo, S.H., M.H.Â Mitra BebestariProf. Dr. Mashudi, S.H., M.H.Prof. Dr. Teguh Prasetyo, S.H., M.Si.Prof. Dr. I Dewa Gede Atmaja, S.H.Prof. Dr. Tjuk Wirawan, S.H.Prof. Dr. IB. Supancana, S.H., M.H.Prof. Dr. Zudan Arif F, S.H., M.H.Prof. Dr. I Nyoman Nurjaya, S.H., M.H.Dr. Harjono, S.H., M.C.L.Â Pelaksana AdministrasiKasdi, S.Sos.Â PenerbitLaboratorium HukumFakultas Hukum Universitas 17 Agustus 1945 SurabayaJl. Semolowaru 45 Surabaya Telp. 031-5905442http://jurnal.untag-sby.ac.id/lab-hukum@untag-sby.ac.id
PEMULIHAN ASET HASIL KEJAHATAN SEBAGAI BENTUK PERLINDUNGAN HUKUM TERHADAP KORBAN KEJAHATAN
Authors: Jerman Heri 
Published: March 2019

Saat ini sistem hukum pidana Indonesia juga belum sepenuhnya menjadikan pemulihan dampak kejahatan sebagai bagian substansi dari sistem hukum pidana nasional, sehingga pemulihan aset hasil kejahatan tidak menjadi sasaran/fokus materi hukum pidana. Tidak adanya formulasi tentang aturan/pedoman perampasan aset dalam undang-undang di luar KUHP yang mencantumkan secara khusus dalam rumusan deliknya, maka akan menimbulkan permasalahan dalam penerapannya. Rumusan masalah penelitian antara lain: Bagaimana Norma Hukum pemulihan aset hasil kejahatan menjadi salah satu tujuan pemidanaan? Bagaimana kebijakan formulasi pemulihan aset hasil kejahatan sebagai upaya perlindungan hukum terhadap korban kejahatan? Penelitian dilakukan dengan metode penelitian normatif. Perlu ada perubahan paradigma dalam sistem pemidanaan nasionalÂ sebagai bentuk pemulihan terhadap korban kejahatan dengan mempertimbangkan bentuk perampasan in rem (tanpa pemidanaan) dimasukkan ke dalam sistem hukum yang berlaku umum (lex generalis) pada semua jenis kejahatan dan dibuat Undang-UndangÂ yang terpisah (lex specialis) dengan extra ordinary system. Kebijakan formulasi peraturan perundang-undangan yang ada di Indonesia dengan merekonstruksi sistem hukum pemidanaan yang berorientasi pada pemulihan aset terhadap korban kejahatan. Sebagai konsekuensi dari ratifikasi konvensi internasional yang mengatur tentang perampasan aset sehingga pemerintah Indonesia harus menyesuaikan ketentuan-ketentuan perundang-undangan yang mengatur mengenai penyitaan dan perampasan hasil dari instrumen tindak pidana terpisah dengan KUHAP tentang Hukum Acaranya dan KUHP tentang sistem pemidanaannya.
REDAKSI DAN DAFTAR ISI
Authors: Jurnal Ilmu Hukum DiH: 
Published: March 2019

DiH: Jurnal Ilmu HukumVolume 15 Nomor 1Februari 2019 â€“ Juli 2019Â EditorÂ in Chief Dr. Endang Prasetyawati, S.H., M.Hum.Â Assistant EditorBudiarsih, S.H., M.H., Ph.D.Â Editor on BoardÂ Prof. Dr. Made Warka, S.H., M.Hum.Dr. Slamet Suhartono, S.H., M.H.Dr. Otto Yudianto, S.H., M.Hum.Dr. Evi Kongres, S.H., M.Kn.Dr. Sri Setyadji, S.H., M.Hum.Â Subscription ManagerSunarsih, S.S.Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â PenerbitProgram Doktor Ilmu HukumFakultas Hukum Universitas 17 Agustus 1945 SurabayaJl. Semolowaru 45 Surabaya Telp. 031-5905442http://jurnal.untag-sby.ac.id/jurnaldih@untag-sby.ac.id
Evaluasi Penerapan E-Learning sebagai Media Pembelajaran Perkuliahan Online bagi Mahasiswa Universitas Sahid Surakarta
Authors: Saputro Firdhaus Hari , Pakarti Moch. Bagoes 
Published: March 2019

ELUSS (E-Learning University of Sahid Surakarta) adalah sebuah website yang dikelola oleh Universitas Sahid Surakarta untuk menyediakan informasi dan sebagai media pembelajaran perkuliahan secara online. Selama ini, belum pernah dilakukan penelitian untuk mengetahui tingkat kepuasan mahasiswa dalam menggunakan ELUSS. Dalam penelitian ini digunakan variabel pengukuran yang meliputi tingkat kepuasan (satisfaction), efisiensi (efficiency), dan kemudahan untuk dipelajari (learnability) sebagai faktor untuk mengetahui tingkat penggunaan ELUSS oleh mahasiswa Universitas Sahid Surakarta. Responden dalam penelitian ini ialah 100 mahasiswa yang mewakili semua mahasiswa Universitas Sahid Surakarta. Analisis data dilakukan menggunakan Partial Least Square (PLS) dengan bantuan perangkat lunak SmartPLS. Hasil penelitian menunjukkan bahwa pengguna merasa puas dan nyaman dalam menggunakan ELUSS. Pengguna juga menyatakan bahwa dengan ELUSS, mereka mudah mendapatkan materi-materi perkuliahan. Ketidakpuasan yang dirasakan olehpengguna ialah saat dimana akses website lambat dan terputus-putus sehingga memerlukan waktu yang relatif lama dan biaya yang mahal, dan menjemukan.
Kata kunci : e-learning, kepuasan, efisiensi, kemudahan, usabilitas
Usulan Tata Letak Area Parkir Tepi Jalan Umum Menggunakan Simulasi
Authors: Lucitasari Dyah Rachmawati , Berlianty Intan , Rakadiputra Andana Dwi Aprilia , Soejanto Irwan , Astanti Yuli Dwi 
Published: March 2019

Parkir merupakan aktifitas berhentinya kendaraan pada waktu dan lokasi tertentu. Meningkatnya jumlah kendaraan yang tidak diikuti dengan ketersediaan area parkir menyebabkan banyak kendaraan yang parkir di badan jalan atau sering disebut parkir Tepi Jalan Umum (TJU). TJU yang seringkali digunakan dengan posisi kendaraan yang sembarangan menyebabkan kemacetan di beberapa jalan terutama area perbelanjaan. Salah satu jalan yang mengalami permasalahan tersebut adalah jalan C. Simanjuntak yang terletak di Yogyakarta. Jl. C. Simanjuntak merupakan jalan yang cukup ramai dilalui masyarakat kota Yogyakarta. Jalan tersebut strategis karena banyaknya pusat perbelanjaan, tempat pendidikan formal dan non formal, serta berbagai jenis usaha di sepanjang jalan. Namun, keramaian yang terjadi justru mendatangkan masalah bagi jalan tersebut. Hal ini dikarenakan kendaraan yang akan menuju beberapa lokasi pada jalan tersebut terhalang oleh kendaraan yang posisi parkirnya kurang tertata rapi. Oleh karena itu, penelitian ini bertujuan untuk mensimulasikan pemilihan pola parkir kendaraan yang paling tepat untuk empat lokasi teramai di Jalan C. Simanjuntak. Berdasarkan hasil simulasi tersebut dapat dilihat jumlah kendaraan yang seharusnya dapat masuk dan keluar dari lokasi penelitian. Berdasarkan hasil simulasi diketahui bahwa skenario posisi parkir dengan sudut 60° merupakan skenario terbaik karena jumlah kendaraan yang dapat ditampung lebih banyak dibandingkan skenario lainnya.
Kata kunci: manajemen parkir, perancangan tata letak, simulasi
КЛАСТЕРНИЙ АНАЛІЗ УРОЖАЙНОСТІ СОРТІВ ТА ГІБРИДІВ РІПАКУ ОЗИМОГО В РІЗНИХ АГРОКЛІМАТИЧНИХ ЗОНАХ УКРАЇНИ
Authors: Мельник А. В. , Присяжнюк О. І. , Бондарчук І. Л. 
Published: March 2019

Обґрунтовано використання кластерного аналізу для підбору сортів та гібридів ріпаку озимого сучасної селекції. Дослідження проводились у 2013–2015 рр. у чотирьох різних агрокліматичних регіонах України. За вирощування в господарствах різних сортів та гібридів потрібно уникати підбору для центрального регіону Клеопатра, ПР44В30, ДК Секвоя, Демерка та ПР45Д05. Для господарств південного регіону небажаним є поєднання двох груп сортів, а саме: Клеопатра, Черемош, НК Октан та ПР45Д05 або ж: Снігова королева, Джампер, Сітро, Демерка, Абакус, Белана, ПР44В30, ДК Секвоя та ДК Секюр. Для західного регіону близькими за продуктивністю в розрізі років досліджень є Клеопатра, ДК Секюр, НК Октан, ПР45Д06, ДК Секвоя та Сітро, а для східного регіону відповідно: Клеопатра, ПР44В30, ДК Секюр, Снігова королева та Сітро. Тобто сорти та гібриди з різних груп кластерів можна висівати в умовах одного господарства, а от в межах однієї групи кластерів – небажано.
The application of cluster analysis for the assortment of winter rape varieties and hybrids of current selection has been grounded. The research was conducted in 2013–2015 in four different agro-climatic regions of Ukraine. To get a stable and high performance of winter rape under the conditions of major agro-climatic zones of cultivation we need to adhere to the principles of production saturation with different varieties and hybrids to reduce the risk of loss of crops in the autumn–winter period and harvest shortfall due to the unfavorable factors of environment. For the farm cultivation of different varieties and hybrids, we should avoid selecting for the central region Cleopatra PR44V30, DK Sequoia, and Demerka and PR45D05. For the farms of southern region, it is undesirable to combine two groups of varieties, namely Cleopatra, Cheremosh, NK Oktan and PR45D05 or Snow Queen, Jumper, Sitro, Demerka, Abakus, Belana, PR44V30, DK and DK Sequoia and DK Sekyur. For the western region Cleopatra, DK Sekyur, NK Oktan, PR45D05, DK Sequoia and Sitro are similar in performance in terms of years of the research, and for the eastern region, there are the following varieties of Cleopatra, PR44V30, DK Sekyur, Snow Queen and Sitro. We mean the varieties and hybrids with different groups of clusters can be sown under the conditions of one farm, but within the same group of clusters, it is undesirable.