bluuebunny/crossref_metadata_2025_split huggingface dataset:
Intrareticular Exciton Effects Regulate Photocatalytic Activity in Donor–Acceptor Olefin‐Linked Covalent Organic Frameworks
Authors: Zhang Jie , Zhou Wenwen , Zhao Jianfeng , Xu Liangliang , Jiang Xuekai , Li Zhiwen , Peng Yongwu , Li Gao 
Published: November 2024

AbstractOlefin‐linked covalent organic frameworks (OL‐COFs) show great promise for visible‐light‐driven photocatalysis. Manipulating atomic‐level donor–acceptor interactions in OL‐COFs is key to understanding their exciton effects in this system. Here, three OL‐COFs are presented with orthorhombic lattice structures, synthesized via Knoevenagel polycondensation reaction of terephthalaldehyde and tetratopic monomers featuring phenyl, benzo[c][1,2,5]oxadiazole, and benzo[c][1,2,5]thiadiazole moieties. These OL‐COFs feature tunable donor–acceptor interactions, making them ideal for studying exciton effects in olefin‐linked systems. Comprehensive analyses, including temperature‐dependent photoluminescence spectra, ultrafast spectroscopy, and theoretical calculations, reveal that stronger donor–acceptor interactions lead to reduced exciton binding energy (Eb), accelerated exciton dissociation, and longer‐lived photogenerated charges, thereby enhancing photocatalytic performance. Notably, The TMO‐BDA COF, with the lowest Eb, demonstrates superior photocatalytic activity in one‐pot sequential organic transformation and excellent catalytic performance in gram‐scale reactions, highlighting its potential for practical applications. This work provides valuable insights into regulating the exciton effect at the molecular level in OL‐COFs, offering pathways to enhance photocatalytic efficiency.
Photo‐Induced Radical Generation of Supramolecular Gel with Sign‐Inverted and White‐Light Circularly Polarized Luminescence
Authors: Ji Lukang , Li Jinqi , Meng Tianzi , Li Zujian , Zhu Huajie , Ouyang Guanghui , Liu Minghua 
Published: November 2024

AbstractThe realization of persistent luminescence and in particular circularly polarized luminescence (CPL) of organic radicals remains a challenge due to their sensitivity to oxygen at ambient conditions and elusive excited state chirality control. Here, it is reported that UV‐irradiation on a supramolecular gel from a chiral triarylamine derivative, TPA‐Ala, led to the formation of luminescent radicals with bright CPL. TPA‐Ala can form an organogel in chloroform with blue emission and supramolecular chirality as demonstrated by both CD and CPL signals. Upon UV 365 nm irradiation, an emission color change from blue to cyan is observed due to the formation of photo‐induced radicals. Interestingly, it is found that the supramolecular gel radicals showed stable luminescence with a lifetime ≈ 10 days in dark environments and inverted CPL, which represents a scarce example with persistent CPL from doublet‐state due to oxygen isolation ability of the gel network. Furthermore, doping a guest dye, Rhodamine B (RhB), into the supramolecular gel (RhB/TPA‐Ala = 30% in molar ratio) successfully obtained a transient white‐light CPL through the superposition of photo‐induced radical and guest dye emissions. This work provides a useful methodology for the fabrication of radical‐based CPL materials via a supramolecular assembly approach.
Comparison of the Effect of Adding Different Levels of Zinc Chloride, Curcumin, Zinc Oxide Nanoparticles (Zano‐NPs), Curcumin Loaded on Zano‐NPs on Post‐Thawing Quality of Ram Semen
Authors: Omidi Fatemeh , Hajarian Hadi , Karamishabankareh Hamed , Soltani Leila , Dashtizad Mojtaba 
Published: November 2024

ABSTRACTObjectiveThis study looked at how different concentrations of curcumin (Curc), zinc chloride (ZnCl2), zinc oxide nanoparticles (ZnO‐NPs) and Curc loaded on ZnO‐NPs (Curc‐co‐ZnO‐NPs) in cryopreservation dilution affected the quality of ram sperm after thawing.MethodsZnO‐NPs were synthesised using Berberis vulgaris leaf aqueous extract. Then, Curc was loaded on the ZnO‐NPs that had been synthesised. We used analytical methods to look at the composition, morphology and size of green synthesised ZnO‐NPs and Curc‐co‐ZnO‐NPs, including UV‐Vis, zeta potential, EDX, DLS, FE‐SEM and FT‐IR. Using a Tris‐base extender containing various concentrations of Curc, ZnCl2, ZnO‐NPs and Curc‐co‐ZnO‐NPs (0, 1, 10 and 100 µg/mL), semen samples from four rams were combined. Sperm motility, viability, DNA and plasma membrane integrity, total abnormalities and malondialdehyde (MDA) generation were all evaluated in treatment groups after thawing.ResultsThe results showed that adding 1 µg/mL of ZnO‐NPs and Curc‐co‐ZnO‐NPs significantly reduced the level of MDA and total abnormalities (p < 0.05). Additionally, following the freeze‐thawing procedure, the presence of 1 µg/mL of Curc‐co‐ZnO‐NPs in the diluent of ram sperm significantly increased the percentage of sperm viability and motility in comparison to the control and other treatment groups (p < 0.05). Furthermore, as compared to the control group and other treatments, treatments containing 1 µg/mL of Curc‐co‐ZnO‐NPs significantly improved membrane and DNA integrity (p < 0.05).ConclusionsIt appears that following freeze‐thawing, the Curc‐co‐ZnO‐NPs (1 µg/mL) enhanced sperm parameters.
Development and Application of an Indirect Enzyme‐Linked Immunosorbent Assay Based on a Recombinant Matrix Protein for the Serological Study of Porcine Deltacoronavirus in Mexican Pigs
Authors: Castañeda Montes Francisco Jesus , Cerriteño Sánchez José Luis , Cuevas‐Romero Julieta Sandra , Castañeda Montes María Azucena , Mendoza Elvira Susana 
Published: November 2024

ABSTRACTPorcine deltacoronavirus (PDCoV) is an infectious disease that causes diarrhoea in pigs of different ages; however, piglets are more susceptible. PDCoV was first reported in 2012 in China and Hong Kong. Later, it was first reported in the USA in 2014 and in Mexico in 2019. Several studies have shown that M protein is highly conserved and, therefore, suitable for diagnostic systems. In this study, for the first time, an indirect enzyme‐linked immunosorbent assay (iELISA) based on a recombinant M protein (rM‐PDCoV) was developed to evaluate the seroprevalence of PDCoV in four states in Mexico. High sensitivity (83%) and specificity (100%) were observed for the iELISA. The kappa index calculated a nearly perfect agreement (0.8831) compared to the Western blot (gold standard test), suggesting acceptable statistical value support. In this study, 50.38% of the serum samples from backyard pigs were PDCoV‐positive. The serological comparison showed that PDCoV/PEDV coinfections occurred in 31.98% of the analysed sera. These results can enrich our understanding of how this virus spreads and enable the evaluation of PDCoV infections. Moreover, it highlights the importance of continually investigating the seroprevalence of PDCoV in Mexico because there is also no information about the current prevalence of the disease.
First Molecular Identification and Whole Genome Sequencing of Listeria monocytogenes Isolated From an African Lion
Authors: Xu Ping , Qi Xinyong , Wang Xiaoxu , Xu Feng , Zhao Hongjin , Shen Liping , Zhang Yujie , Huang Shixin , Wang Jian 
Published: November 2024

ABSTRACTListeria monocytogenes (LM) is a zoonotic pathogen that causes sporadic infectious listeriosis, which is a foodborne disease associated with consumption of contaminated food or feed. The internal organs of an African lion from a zoo in Shanghai were analysed to determine the cause of death. LM infection was suspected on the basis of the clinical symptoms and pathological changes and confirmed by polymerase chain reaction, whole genome sequencing and phylogenetic analysis. This is the first report of LM infection of an African lion in China.
Migration as Adaptation? The Falepili Union Between Australia and Tuvalu
Authors: Barnett Jon , Farbotko Carol , Kitara Taukiei , Aselu Bateteba 
Published: November 2024

ABSTRACTAustralia and Tuvalu recently signed a unique treaty called the Australia‐Tuvalu Falepili Union Treaty, on climate change adaptation, migration, and security. Here we analyze the treaty's migration provision which will enable citizens of Tuvalu to live and work in Australia. We ground our analysis in the state of knowledge about climate change and migration in Tuvalu, explaining the Falepili Union and the ways in which its migration provision may be either a mechanism for adaptation or maladaptation. We then describe a range of policy conditions to maximize the adaptation outcomes for Tuvalu and Tuvaluans. These include measures from the Australian government to support Tuvaluans who migrate as well as the Tuvaluan‐Australians who will be key to their integration, and invest in key sectors in Tuvalu such as coastal protection, ICT, and transport. Cooperation between the Tuvalu and Australian governments will also be needed to help direct remittances into public goods and adaptive technologies and practices, to harness the benefits of skills and training for both economies and to monitor the scheme to ensure it delivers adaptation outcomes to Tuvalu and Tuvaluans. Further policy measures discussed include the selection of people eligible for migration and improved communications about the benefits and risks and governance of the scheme. Most if not all of these will be necessary if the migration provision of the Faleplili Union is to be a mechanism for adaptation.
A Constrained Geometry Fluorenyl Amido Magnesium Catalyst for Amine‐Borane Dehydrocoupling
Authors: Lambert Jessica , Morgenstern Bernd , Schäfer André 
Published: November 2024

AbstractA fluorenyl amido constrained geometry magnesium complex is described, which was obtained by deprotonation of the corresponding neutral ligand system with dibutyl magnesium. Its structure was determined by SC‐XRD and it was shown to be a potent catalyst for amine‐borane dehydrogenation/dehydrocoupling.
Transmission coefficient of super-Janus solution
Authors: Baig Saba Asif , Karch Andreas , Wang Mianqi 
Published: November 2024

Abstract
We calculate the transmission coefficient of the super-Janus interface conformal field theory, both at weak and at strong coupling, where latter is described holographically as a domain-wall solution on AdS2 × S2 × M4 × Σ. Surprisingly we find perfect agreement between the free and strong coupling answer, mirroring a similar unexpected equivalence previously found for the entanglement entropy.
Improved precision on 2–3 oscillation parameters using the synergy between DUNE and T2HK
Authors: Agarwalla Sanjib Kumar , Kundu Ritam , Singh Masoom 
Published: November 2024

Abstract
A high-precision measurement of $$ \Delta {m}_{31}^2 $$
∆

m
31
2

and θ23 is inevitable to estimate the Earth’s matter effect in long-baseline experiments which in turn plays an important role in addressing the issue of neutrino mass ordering and to measure the value of CP phase in 3ν framework. After reviewing the results from the past and present experiments, and discussing the near-future sensitivities from the IceCube Upgrade and KM3NeT/ORCA, we study the expected improvements in the precision of 2–3 oscillation parameters that the next-generation long-baseline experiments, DUNE and T2HK, can bring either in isolation or combination. We highlight the relevance of the possible complementarities between these two experiments in obtaining the improved sensitivities in determining the deviation from maximal mixing of θ23, excluding the wrong-octant solution of θ23, and obtaining high precision on 2–3 oscillation parameters, as compared to their individual performances. We observe that for the current best-fit values of the oscillation parameters and assuming normal mass ordering (NMO), DUNE + T2HK can establish the non-maximal θ23 and exclude the wrong octant solution of θ23 at around 7σ C.L. with their nominal exposures. We find that DUNE + T2HK can improve the current relative 1σ precision on sin2θ23$$ \left(\Delta {m}_{31}^2\right) $$

∆

m
31
2

by a factor of 7 (5) assuming NMO. Also, we notice that with less than half of their nominal exposures, the combination of DUNE and T2HK can achieve the sensitivities that are expected from these individual experiments using their full exposures. We also portray how the synergy between DUNE and T2HK can provide better constraints on (sin2θ23–δCP) plane as compared to their individual reach.
Effects of final state interactions on Landau singularities
Authors: Sakthivasan A. S. , Mai M. , Rusetsky A. , Döring M. 
Published: November 2024

Abstract
In certain kinematic and particle mass configurations, triangle singularities may lead to line-shapes which mimic the effects of resonances. This well-known effect is scrutinized here in the presence of final-state rescattering. The goal is achieved first by utilizing general arguments provided by Landau equations, and second by applying a modern scattering formalism with explicit two- and three-body unitarity.
A mass for the dual axion
Authors: Platschorre Arthur 
Published: November 2024

Abstract
In this article we study a modification of axion physics in which the dual axion acquires a mass. This mass explicitly breaks the shift symmetry of the dual axion. The potential breaking of this shift symmetry poses a dual axion quality problem. When the dual axion acquires a mass, the axion gets eaten and becomes the longitudinal degree of freedom of a massive vector field. In this phase, axion strings are screened and far-separated instanton configurations are exponentially suppressed. This confinement of instantons corresponds to the worldline action of a particle-like soliton traveling between the instantons analogous to Abrikosov/Nielsen-Oleson vortex solitons that stretch between confined magnetic monopoles in a superconductor. We calculate the cost of this additional worldline suppression and provide several models in which both the confined instantons and confining worldline are dynamical.
The impact of a large-scale natural disaster on local economic activity: evidence from the 2003 Bam earthquake in Iran
Authors: Farzanegan Mohammad Reza , Fischer Sven 
Published: November 2024

Abstract
This study provides new causal evidence for the impact of a large-scale natural disaster on local economic activity in Iran using nighttime light intensity. We apply the synthetic control method (SCM) to nighttime light (NTL) data from 1992 to 2013 to study the impact of the 2003 Bam earthquake on Bam County in Iran and its neighboring counties. According to the results and statistical inference tests for the SCM, Bam County and its neighboring counties experienced a statistically significant boost in economic activity in the years following the earthquake. Bam’s GDP economic activity increases by an accumulated US$620 million in the post-earthquake period. We find that the average economic gain in Bam following the 2003 earthquake is approximately 5% of Bam’s GDP. We also discuss possible contributing factors to the post-disaster economic boom in Bam.
Within-Site Variations in Soil Physicochemical Properties Explained the Spatiality and Cohabitation of Arbuscular Mycorrhizal Fungi in the Roots of Cryptomeria Japonica
Authors: Djotan Akotchiffor Kevin Geoffroy , Matsushita Norihisa , Fukuda Kenji 
Published: November 2024

AbstractArbuscular mycorrhizal fungi (AMF) live in a community in the roots of host plants. Still, the patterns and factors that drive their spatiality and cohabitation remain uncovered, particularly that of trees in planted forests, which we aimed to clarify in Cryptomeria japonica, a major plantation tree in Japan. We analyzed 65 paired root and soil samples of Cryptomeria japonica trees collected from 11 microsite (MS) plots at two environmentally different forest sites in central Japan and measured soil pH, total phosphorus (TP), C, N, and the carbon-to-nitrogen ratio. Root AMF communities were recovered using Illumina’s next-generation amplicon sequencing targeting the small subunit of ribosomal DNA. We detected more than 500 AMF OTUs at each site but only three belonging to Dominikia, Rhizophagus, and Sclerocystis were dominant in the roots of C. japonica, detected each at an average relative abundance higher than 20%. Two showed negatively correlated spatial distributions and different associations with soil pH. Similarly, the physicochemical properties at MSs significantly determined the AMF assemblages in the roots of C. japonica. Dominikia, Rhizophagus, and Sclerocystis coexist in the roots of C. japonica where soil physicochemical properties, particularly pH, determine their spatial dynamic, turnovers, and cohabitation patterns. These findings highlight the importance of simultaneous colonization of plants by multiple AMF.
Experience of rescue therapy with [177Lu]Lu-rhPSMA-10.1 in patients with primary or acquired resistance to [177Lu]Lu-PSMA-I&T
Authors: Gäble Alexander , Dierks Alexander , Rinscheid Andreas , Patt Marianne , Wienand Georgine , Pfob Christian H. , Kircher Malte , Fukushima Kazuhito , Nikolić Ana Antić , Enke Johanna S. , Janzen Tilman , Steinestel Julie , Kempter Hildegard , Trepel Martin , Weckermann Dorothea , Lapa Constantin , Bundschuh Ralph A. 
Published: November 2024

Abstract

Purpose
Radioligand therapy is an increasingly important option for the treatment of metastatic castrate-resistant prostate cancer (mCRPC). Radiohybrid ligands targeting prostate-specific membrane antigen (PSMA) are a novel group of theranostic radioligand therapy agents for which higher tumour absorbed radiation doses have been demonstrated compared to established PSMA ligands. Here, we report data from ten patients who were treated within a compassionate use program with the radiohybrid PSMA-ligand [177Lu]Lu-rhPSMA-10.1 after experiencing disease progression under treatment with [177Lu]Lu-PSMA-I&T.

Methods
Ten patients with advanced PSMA-positive prostate cancer who showed progression under treatment with [177Lu]Lu-PSMA-I&T received up to three cycles of rescue therapy with [177Lu]Lu-rhPSMA-10.1 (7.4–8.1 GBq per cycle). Efficacy (PSA response according to PCWG3 and RECIP) and overall survival were evaluated. Adverse events were recorded from first application.

Results
Despite progression with [177Lu]Lu-PSMA-I&T, after the first cycle of [177Lu]Lu-rhPSMA-10.1 rescue therapy, five patients (50%) showed a decrease in serum PSA level. In imaging, three of the ten patients (30%) showed a partial radiologic response. Four of the five patients with a decrease of serum PSA under [177Lu]Lu-rhPSMA-10.1 had initially responded to treatment with [177Lu]Lu-PSMA-I&T but had become resistant. However, the remaining patient had shown continuous disease progression during [177Lu]Lu-PSMA-I&T therapy but showed an immediate response to [177Lu]Lu-rhPSMA-10.1. The additional treatment with [177Lu]Lu-rhPSMA-10.1 was generally well tolerated by all patients.

Conclusions
Patients showing tumour progression while receiving [177Lu]Lu-PSMA-I&T radioligand therapy may benefit from rescue therapy with the novel radiohybrid PSMA ligand, [177Lu]Lu-rhPSMA-10.1. Higher tumour absorbed radiation doses with [177Lu]Lu-rhPSMA-10.1 may overcome primary and acquired radiation resistance.

Graphical Abstract
In-situ observations of gelatinous zooplankton aggregations in inshore and offshore Arctic waters
Authors: Pantiukhin Dmitrii , Soto-Angel Joan J. , Hosia Aino , Hoving Henk-Jan , Havermans Charlotte 
Published: November 2024

AbstractGelatinous zooplankton (GZ), play a crucial role in marine food webs, nutrient cycling, and carbon sequestration, however, quantifying their abundances remains challenging due to their delicate body structure, complex life cycles and variable population dynamics. Their tendency to form sporadic, large-scale aggregations further complicate the differentiation between true ecosystem alterations and stochastic variations in their abundance. In the Arctic Ocean, our understanding of GZ aggregations remains generally incomplete. Using in-situ observations from a towed pelagic camera system, we assessed the diversity and vertical distributions of GZ in fjord and offshore environments in northern Norway and the Svalbard archipelago. We found that Atlantic water masses harbored the highest GZ abundance, while intermediate waters showed the highest diversity. We documented dense aggregations of Beroe spp. in Van Mijenfjorden in Svalbard (observed during ascent of the camera system, not quantified in ind. m−3) and Bolinopsis infundibulum in the open Barents Sea (> 2.67 ind. m−3 at 100 m). Other observed taxa included the hydrozoans Aglantha digitale, Melicertum octocostatum, Solmundella bitentaculata, Pandeidae sp. and Physonectae spp., the scyphozoan Cyanea capillata and the ctenophores Mertensia ovum and Euplokamis sp. By linking the vertical distribution and observations of local aggregations with physical and biotic factors, we described the potential drivers of the distributional patterns observed. Towed camera surveys contribute to accurate in-situ observations, thereby improving our understanding of GZ aggregations and distributions in the Arctic Ocean.
Association of ovarian teratoma with anti-N-methyl-D-aspartate receptor encephalitis: a case report and narrative review
Authors: Joseph Konrad , van der Hock Sarah , Seth Ishith , Hapangama Nipuni , Gibson Lara , Cuomo Roberto , Rozen Warren M. , Dhupar Nita 
Published: November 2024

Abstract
Background
Anti-N-methyl-D-aspartate receptor (NMDAR) encephalitis is a potentially life-threatening autoimmune disorder which is strongly associated with ovarian teratomas in young female patients. The primary aim is to highlight the importance of considering NMDAR encephalitis in the differential diagnosis of young female patients presenting with acute or subacute neuropsychiatric symptoms, especially when accompanied by ovarian teratomas.

Case description
This case report and literature review detail the presentation, diagnosis, and treatment of a 35-year-old G4P3 Indigenous woman who initially presented with neuropsychiatric symptoms and fever, having a history of extensive drug and alcohol use. Misdiagnosed initially, the patient's lack of response to standard treatments led to further investigations, revealing paraneoplastic anti-NMDAR encephalitis secondary to a left ovarian teratoma. The report examines the treatment regimen followed, including prednisolone, intravenous immunoglobulin, rituximab injections, and laparoscopic bilateral salpingo-oophorectomy.

Conclusions
This case underscores the critical need for increased clinical vigilance for anti-NMDAR encephalitis in patients, particularly young females, presenting with neuropsychiatric symptoms and potential ovarian teratomas. The literature review accompanying the case report provides valuable insights into the presentation, diagnosis, and management of this complex condition. Lastly, this study emphasised the diagnostic challenges inherent in paraneoplastic neuropsychiatric syndromes, advocating for a multidisciplinary approach in similar clinical scenarios.