bluuebunny/crossref_metadata_2025_split huggingface dataset:
Highly Efficient and Reusable Pd/AlO(OH) Catalyzed Synthesis of Acridinedione Derivatives
Authors: Kilbas Benan , Ergen Sinem , Cakici Davut 
Published: July 2019

Background:
Synthesis of acridinedione derivatives via one-pot multi-component approaches
using highly active and reusable Pd/AlO(OH) heterogenous catalyst was studied. This process
provided a convenient method to obtain various acridinediones with potential biological activities.
The reactions were performed in mild conditions such as low temperature and short reaction
time with desirable yields.

Methods:
Commercially available Pd/AlO(OH) nanoparticles characterized by XRD and SEM methods
were afforded for the synthesis of acridinedione derivatives with high yields. Crude products
were analyzed by GC and 1H NMR. The reactions were completed within 1h at 40°C by the assistance
of ultrasound system.

Results:
Optimization of reaction conditions is of critical case for successful synthesis. Solvent, temperature,
time and amount of catalyst were studied. At the end of the experiments, the synthesis of 1
mmol of acridinedione was optimized by using 25 mg of Pd/AlO(OH) NPs, 3 ml of DMF for 60 min
at 40°C in the ultrasound system. An experimental work to check the reusability of the catalyst was
also studied. Pd/Al(O)OH catalyst in the first run was higher than that of the reused catalyst in the
fifth run. ICP-OES analyses showed palladium leaching into the reaction medium was only 1.1%
which is negligible. Nanocatalyst employed a high activity and good reusability.

Conclusion:
A convenient and versatile method was developed for the synthesis of acridinediones in
a mild condition with absolute conversion and high yield using ultrasound system in the presence of
nanocatalyst.
A Kinetic Study on the Synthesis of N-arylation of Indole Under Synergetic Effect of Multi-Site Phase Transfer Catalysis System
Authors: Sathiyaraj Manickam , Venkatesh Perumal 
Published: July 2019

Background:Phase transfer catalysis technique is recognized as an attractive method for synthesizing several organic compounds under heterogeneous reaction.Methods:In this study, the effect of Multi-site Phase-Transfer Catalyst (MPTC) was tested during the synthesis of 1-(4-nitrophenyl)-1-indole from 1-chloro-4-nitrobenzene (CNB) and indole in a heterogeneous solid-liquid condition using sodium hydroxide at 50°C.Results:In a synergetic condition, in the presence of MPTC the conversion of 1-chloro-4- nitrobenzeneyield was increased, which is proved the efficacy of this catalyst. In addition, the rate of this reaction was also enhanced by the change in volume of water.Conclusion:The apparent reaction rate was found to be of pseudo-first-order kinetics. MPTC is a promising tool for many organic reactions. Therefore, increase the rate constant can be achieved by various parameters, such as temperature, MPTC, sodium hydroxide, and stirring speed.
Macroalgas marinas del litoral rocoso Neovolcánico de Veracruz, México
Authors: Landa-Cansigno Cristina , Mateo-Cid Luz Elena , Mendoza-González Angela Catalina , Guerrero-Analco José Antonio 
Published: July 2019

Antecedentes y Objetivos: Los ambientes de los litorales rocosos del estado de Veracruz, México, son sitios únicos en los que la riqueza específica macroalgal ha sido poco estudiada, ya que se carece de listados florísticos completos y de un seguimiento a los cambios en las poblaciones algales. El objetivo de este trabajo fue contribuir al conocimiento de algas de los ambientes rocosos veracruzanos ubicados en Playa Paraíso, Playa Villa Rica y Playa Muñecos, los cuales están influenciados por las estribaciones del Eje Neovolcánico.Métodos: Las algas se recolectaron durante la época de lluvias (septiembre 2016) y de secas (mayo 2017) en Playa Paraíso (PP), Playa Villa Rica (PVR) y Playa Muñecos (PM). Las muestras se preservaron en una solución de agua de mar y formol al 4%. Se realizaron observaciones morfométricas externas e internas de los talos y se determinaron las especies de acuerdo con literatura taxonómica especializada.Resultados clave: Se determinaron un total de 45 especies, de las cuales 18 fueron Chlorophyta, 16 Rhodophyta y 11 Ochrophyta. Las familias mejor representadas fueron Corallinaceae, Rhodomelaceae, Cladophoraceae y Dictyotaceae. La mayor riqueza de especies se observó en PP durante la época de secas. Se mencionan nuevos registros para las localidades de estudio; de éstos, Centroceras gasparrinii, Gracilaria apiculata y G. flabelliformis son nuevos registros para el estado de Veracruz.Conclusiones: La flora algal del litoral rocoso Neovolcánico de Veracruz es de tipo tropical y alberga 31% de la flora algal regional del estado de Veracruz. Los nuevos registros en cada una de las localidades reflejan que aún prevalece una brecha en el conocimiento de la riqueza algal de esta región. Por lo tanto, se sugiere continuar con el registro de especies en la zona con la finalidad de integrar los listados florísticos correspondientes.
Modul tutorial sebagai media pembelajaran pencak silat untuk siswa sekolah menengah kejuruan
Authors: Saputro Guntur Eko , Hanief Yulingga Nanda , Herpandika Reo Prasetiyo , Saputro Deny Pradana 
Published: July 2019

Penelitian bertujuan untuk menghasilkan modul tutorial pembelajaran pencak silat yang dapat digunakan guru SMK dalam mata pelajaran Penjasorkes. Penelitian ini melalui 9 tahapan dengan mengadaptasi penelitian dan pengembangan pendidikan model Sugiyono. Subjek penelitian adalah siswa SMK 1 Ngunut Kabupaten Tulungagung. Instrumen berupa kuesioner. Hasil penelitian berupa modul tutorial pembelajaran pencak silat yang terdiri dari: (1) teknik dasar pukulan; (2) teknik dasar tendangan; dan (3) sikap pencak silat. Model disusun dalam bentuk buku panduan dengan judul “Modul Pembelajaran Pencak Silat untuk kelas XI SMA dan SMK”. Berdasarkan penilaian para ahli materi, ahli media dan guru, dapat disimpulkan bahwa pengembangan modul tutorial pembelajaran pencak silat untuk siswa SMK layak digunakan dalam pembelajaran pencak silat untuk siswa SMK. Tutorial module as learning media to pencak silat for vocational students AbstractThis research aimed to produce a tutorial module as learning media for pencak silat which can be used by vocational teachers in Physical Education. This study was a research and development conducted in 9 steps by adapting educational research and development according to Gall, Gall, & Borg’s model. The results of the research were a tutorial module as learning media for pencak silat consisting of: (1) basic blow technique; (2) basic kick technique; and (3) stance on pencak silat. Models arranged in a handbook entitled “Modul Pembelajaran Pencak Silat untuk kelas XI SMA dan SMK”. Based on the assessment of matter experts, media experts and teachers, it can be concluded that the development of tutorial module as learning media to pencak silat for vocational students is suitable for learning pencak silat for vocational students.
Implementasi pendidikan jasmani dalam international primary curriculum
Authors: Nugroho Kristanto Adi , Kristiyanto Agus , Doewes Muchsin 
Published: July 2019

Tujuan penelitian ini adalah mengetahui keterkaitan dan implementasi pendidikan jasmani dalam International Primary Curriculum (IPC) sebagai salah satu kurikulum internasional. IPC adalah kurikulum yang komprehensif, tematik, dinamis dan berwawasan global. Pelaksanaan kurikulum terstruktur dan terencana memungkinkan siswa untuk beradaptasi dengan tantangan global di masa mendatang. Metode penelitian adalah metode penelitian kualitatif deskriptif. Hasil penelitian, pelaksanaan pendidikan jasmani di IPC telah ditentukan oleh sekolah melalui data dengan pemutakhiran terbaru. Tema yang dipilih kemudian disesuaikan dengan tujuan sekolah, budaya lokal, kebutuhan siswa. Kesimpulannya adalah IPC sangat dinamis sehingga dapat diselaraskan untuk mencapai tujuan sekolah yang ingin dicapai dengan menyesuaikan budaya budaya lokal, kondisi siswa dan sekolah. AbstractThe purpose of this research is determine relationship and implementation of physical education in International Primary Curriculum (IPC) as an international curriculum. IPC is comprehensive, thematic, dynamic and global-minded curriculum. The implementation of a structured and planned curriculum allows students to adapt to global challenges in the future. The research method is descriptive qualitative research. As a result, implementation of physical education in IPC has been determined by school through the latest update data. The choosen theme is then adjusted to school goals, local culture, student needs. The conclusion is that IPC is very dynamic so that it can be harmonized to achieve the school goals by adjusting the culture of the local culture, conditions of students and schools.
Pelaksanaan trias usaha kesehatan sekolah (UKS) di sekolah dasar
Authors: Apriani Leni , Gazali Novri 
Published: July 2019

Penelitian ini bertujuan untuk mengetahui pelaksanaan Trias UKS di Sekolah Dasar Negeri Gugus II Bukit Raya Kota Pekanbaru. Jenis penelitian yang digunakan adalah metode deskriptif. Populasi dalam penelitian ini adalah seluruh siswa kelas V SD Gugus II Bukit Raya Kota Pekanbaru sebanyak 118 orang. Sampel dalam penelitian ini diambil dengan cara total sampling yang berjumlah 118 orang. Instrumen dalam penelitian ini menggunakan angket yang dibuat berdasarkan buku pedoman untuk tenaga kesehatan usaha kesehatan sekolah. Teknik analisis data menggunakan analisis deskriptif, sedangkan perhitunganya menggunakan persentase. Untuk mengetahui kriteria dalam pensekoran data tiap faktor maka dilakukan pengkategorian, sesuai dengan instrumen, yaitu: sangat baik, baik, cukup baik dan tidak baik. Berdasarkan hasil penelitian dari 5 sekolah maka dapat disimpulkan pelaksanaan program usaha kesehatan sekolah (UKS) di Sekolah Dasar Negeri Gugus II Bukit Raya Kota Pekanbaru secara keseluruhan berkategori kurang baik. Hal ini dapat dilihat dari tiga aspek, yaitu: (1) aspek lingkungan kehidupan sekolah yang sehat dengan kategori cukup, (2) aspek pendidikan atau penyuluhan di sekolah dengan kategori kurang baik, (3) aspek pelayanan kesehatan di sekolah dengan kategori kurang baik. The implementation of trias school health unit (Trias UKS) at primary school AbstractThis research aims to know the implementation of the trias UKS in elementary school the country Cluster II Bukit Raya Pekanbaru. This type of research method used is descriptive. The population in this research is the whole grade V SD Cluster II Bukit Raya as much as 118 people. The sample in this study is taken by way of sampling a total of 118 people. Technique of data analysis using descriptive analysis, while the calculation using percentage. To know the criteria in data scoring each factor then done categorization, in accordance with the instrument, namely: very good, good, good enough and not good. Based on the results of research from 5 schools it can be concluded the implementation of the program school health (UKS) in State Elementary School Gugus II Bukit Raya Pekanbaru as a whole is categorized less good. This can be seen from three aspects, : (1) environmental aspects of healthy school life with sufficient category, (2) aspects of education or counseling in schools with less good category, (3) aspects of health services in schools with less good category.
Efektivitas penggunaan macromedia flash 8 terhadap hasil belajar siswa materi penyakit menular seksual di sekolah menegah atas
Authors: Raharja Andri Tria , Mahardhika Nanda Alfian , Jusuf Jeane Betty Kurnia , Julianur Julianur , Santoso Januar Abdilah 
Published: July 2019

Penelitian ini bertujuan untuk tingkat efektivitas penggunaan macromedia flash 8 terhadap hasil belajar materi penyakit menular seksual di SMA Negeri 1 Loa Kulu. Penelitian ini menggunakan metode pendekatan kuantitatif. Jenis penelitian yang digunakan pada penelitian ini adalah posttest-only control design. Analisis data yang digunakan dalam penelitian ini adalah One way anova. Subyek uji coba diambil menggunakan purposive sampling. Tempat penelitian dibatasi pada Sekolah Menengah Atas yang berada di SMAN 1 Loa Kulu dengan jumlah 60 siswa. Hasil analisis data yang diperoleh pada data uji normalitas yang didapat adalah nilai Sig. Kolmogorov-Smirnov Post Test A atau kelompok dengan menggunakan treatment = 0,087 dan Sig. Kolmogorov-Smirnov Post Test B atau kelompok tidak menggunakan treatment = 0,068 lebih besar dari taraf uji signifikan 0,05. Maka dapat disimpulkan bahwa nilai berdistribusi normal. Sedangkan pada uji homogenitas nilai Sig. Post Test A dan Post Test B diketahui sebesar 0,263. Maka dapat disimpulkan data homogenitas = 0,263 0,05 dan nilai post test A dan post test B memiliki varian yang sama dan homogen. Setelah melakukan uji normalitas dan homogenitas, langkah selanjutnya adalah uji-F dengan one way anova. Data yang diperoleh Fhitung Ftabel yaitu 12,64 4,01. Maka dapat disimpulkan bahwa data ada perbedaan yang signifikan. Effectiveness of the use of macromedia flash 8 on learning outcomes of students of sexually transmitted diseases in Senior high school AbstractThis study aims to determine the effectiveness of the use of macromedia flash 8 on the results of learning sexually transmitted diseases material at State Senior High School 1 Loa Kulu. This study uses a quantitative approach. The type of research used in this study was posttest-only control design. The data analysis used in this study is One way ANOVA. The subjects of the trial were taken using purposive sampling. The research location is limited to senior high schools located at SMAN 1 Loa Kulu with a total of 60 students. The results of data analysis obtained on the normality test data obtained are the Sig. Kolmogorov-Smirnov Post Test A or group using treatment = 0.087 and Sig. Kolmogorov-Smirnov Post Test B or group not using treatment = 0.068 greater than the significant test level of 0.05. Then it can be concluded that the value is normally distributed. While the test homogeneity of the Sig. Post Test A and Post Test B are known to be 0.263. Then it can be concluded that homogeneity data = 0.263 0.05 and the post test A and post test B values have the same and homogeneous variants. After conducting the normality and homogeneity test, the next step is the F-way test with one way ANOVA. Data obtained by Fcount Ftable is 12.64 4.01. Then it can be concluded that the data have significant differences.
The development of early childhood sex education materials for early childhood education (ECE) teachers
Authors: Astuti Budi , Sugiyatno Sugiyatno , Aminah Siti 
Published: July 2019

The objective of this research was to create early childhood sex education materials for Early Childhood Education Teachers. The research was initiated by conducting need assessment in the form of identification of the needs of sex education materials that appropriate for early childhood and the role of teachers and parents in the sex education. The subjects were chosen by using the purposive technique. The subjects of this study were 28 Early Childhood Education teachers in Sleman Regency. The data collection in this research was using a questionnaire. The data analysis technique was using quantitative descriptive techniques. The results of the research provided a description that the materials about the skills to protect themselves from sexual violence is the most needed matter of Early Childhood Education teachers. Further, respectively according to the level of need, the material that needs to be included in a Early Childhood Sex Education is the introduction of the gender, the introduction of self-identity, the relationship of men and women and ways to maintain the health, and the introduction of reproductive organs and functions. Materials product is expected to be a guideline and reference in providing early sex education.
Keberdayaan perempuan pasca pelatihan mengolah sampah bagi kelompok pemberdayaan dan kesejahteraan keluarga
Authors: Nugroho Rivo 
Published: July 2019

Kelompok pemberdayaan dan kesejahteraan keluarga sebagai salah satu unit desa dapat dioptimalkan untuk mewujudkan keberdayaan masyarakat melalui program pelatihan mengolah sampah. Desain penelitian yang digunakan adalah penelitian survai, yaitu penelitian yang bertujuan untuk mencari informasi faktual yang memperlihatkan gejala yang ada, mengidentifikasi masalah atau untuk mendapatkan justifikasi keadaan dan kegiatan yang sedang berjalan, serta untuk mengetahui hal-hal yang dilakukan oleh orang-orang yang menjadi sasaran penelitian dalam memecahkan masalah. Metode yang digunakan dalam penelitian ini adalah observasi dan wawancara. Keberdayaan perempuan yang didasarkan dari hasil perhitungan menunjukkan jumlah persentase 82,5%. Nilai tersebut termasuk dalam kategori sangat baik karena berada pada interval koefisien 80% - 100% berdasarkan pedoman untuk memberikan interpretasi terhadap persentase. Women's Empowerment Post Training Processing Waste for Family Welfare and Empowerment Group AbstractThe family empowerment and welfare group as one of the village units can be optimized to realize community empowerment through waste processing program. The research design used is survey research, which is a research that aims to find factual information showing symptoms, identify problems or to justify the circumstances and activities that are running, and to know the things done by the people who were targeted research in solving problems. The method used in this research is observation and interview. The empowerment of women based on calculations shows the percentage of 82.5%. The value belongs to the very good category because it is at the interval coefficient of 80% - 100% based on the guidelines to provide interpretation of the percentage.
Partisipasi masyarakat dalam pengembangan organisasi wahana kesejahteraan sosial berbasis masyarakat (WKSBM)
Authors: Aminah Shobichatul , Prasetyo Iis 
Published: July 2019

Penelitian ini bertujuan untuk mendeskripsikan: (1) tahapan partisipasi masyarakat dalam pengembangan WKSBM melalui komunikasi multitrack, (2) bentuk partisipasi masyarakat dalam pengembangan WKSBM melalui komunikasi multitrack, dan (3) faktor-faktor yang mempengaruhi partisipasi masyarakat dalam pengembangan WKSBM melalui komunikasi multitrack. Penelitian ini menggunakan analisis penelitian deskriptif. Hasil penelitan ini adalah: (1) tahapan partisipasi masyarakat dalam pengembangan WKSBM melalui model komunikasi multitrack adalah penilaian, penyusunan rencana dan desain, pelaksanaan komunikasi dan evaluasi, (2) bentuk-bentuk partisipasi masyarakat dalam pengembangan WKSBM melalui komunikasi multitrack adalah kontribusi, tanggung jawab dan peran, (3) faktor-faktor yang mempengaruhi partisipasi masyarakat dalam Pengembangan WKSBM melalui komunikasi multitrack adalah faktor internal dan eksternal. Faktor internal yang mempengaruhi adalah usia, pekerjaan dan komunikasi. Faktor eksternal yang muncul yaitu tanggapan dari masyarakat, kebijakan pemerintah dan kebermanfaatan WKSBM untuk masyarakat. Community participation in organization development of society-based social welfare (WKSBM) AbstractThis study aims to describe: (1) the steps of community participation in the development of WKSBM through multitrack communication, (2) forms of community participation in the development of WKSBM through multitrack communication, (3) affecting factors of community participation in developing WKSBM through multitrack communication. This research were used qualitative research with description method. The results of this research were: (1) the steps community participation in the development of WKSBM through multitrack communication, (2) forms of community participation in the development of WKSBM through multitrack communication ,and (3) affecting factors of community participation in the development of WKSBM through multitrack communication are internal and external factors. Internal factors that affect the age, work and communication. External factors that arise are the responses from the community, government policies and the usefulness of WKSBM for the community.
Edukasi pelestarian sumberdaya dan lingkungan pantai pada nelayan perikanan bagan
Authors: Sulistiono Sulistiono , Zulkarnaen Zulkarnaen , Nugroho Thomas 
Published: July 2019

Perikanan bagan merupakan salah satu pekerjaan yang umum dilakukan masyarakat Desa Saramaake, Halmahera Timur. Kegiatan edukasi pelestarian sumberdaya dan lingkungan pantai ini dilaksanakan pada Juni, Agustus, September dan Desember 2018, bertujuan untuk memberikan edukasi pemahaman tentang pelestarian sumberdaya dan lingkungan pantai di desa tersebut. Metode yang digunakan adalah penyuluhan, diskusi dan monitoring dan evaluasi. Sasaran kegiatan merupakan nelayan dan istri nelayan yang merupakan anggota Kelompok Usaha Bersama (KUB) atau Koperasi. Beberapa kegiatan yang telah dilakukan antara lain penyuluhan tentang perikanan bagan (Agustus), penyuluhan tentang konservasi lingkungan dan sumberdaya (Juni), dan kegiatan monitoring dan evaluasi (September, Desember 2018). Dari hasil kegiatan dapat diketahui bahwa secara umum masyarakat nelayan telah mengetahui dan mengimplementasikan kegiatan perikanan yang baik, dan menjaga kondisi lingkungannya dengan lebih baik, dengan tidak membuang sampah di laut, tidak melakukan penebangan hutan pantai, tidak mengubur ikan by catch di pantai, dan mengingatkan pada sesama nelayan, keluarga dan aparat pemerintah untuk tetap menjaga lingkungan laut. Education on the environmental and resource conservations of the lift-net fishermen AbstractLift-net fisheries is a commonly job of the coastal community at Saramaake Village, East Halmahera. This education activity on environmental and resource conservations was done on June, August, September and December 2018, aimed to educate resource and environment conservation in the village. Methods used in this activity were survey in the fied, discussion and filling in the questionnaire form. Objects of the activity were fisherman and their wives who were member of the Common Business Group (KUB-Indonesian) and Cooperative (Koperasi-Indonesian). A number of activities were carried out to educate the fisherman community such as extension on the lift net fisheries, extension on the resource and environmental conservation, and monitoring and evaluation. The community commonly knew and implemented a good fishing activity and environmental and resource care better such as no drop garbage to the sea, no using the sea for toilet, no cutting mangrove tree, no burying by catch in coastal area, encouraging to families, fishermen and village officials to keep the sea better.