bluuebunny/crossref_metadata_2025_split huggingface dataset:
The Relationship Between Maternal Motivation And The Role Of Cadres With Adherence To Vitamin A Administration Among Toddlers At The Posyandu In The Working Area Of Puskesmas Watas Marga, 2024
Authors: Rosita Pera , Putri Yesi , Jumita Jumita 
Published: December 2024

Deficiency vitamin A deficiency increases the risk of children becoming susceptible to infectious diseases such as upper respiratory tract infections, measles and diarrhoea. Among children among pre-school children there are an estimated 6-7 million new cases of xeropthalmia (night blindness) each year, approximately 10% of which suffer from corneal damage. corneal damage. Among those who suffer corneal damage, 60% die within one year, while among the living 25% become blind and 50-60% half-blind. blind. The aim of the study was to determine the relationship between Mother's Motivation and the Role of Cadres with Adherence to Vitamin A Giving to Toddlers in the Posyandu Watas Marga Health Centre Working Area in 2024. This study This study used analytical research with a cross sectional design. Technique purposive sampling technique, which is sampling based on the consideration of the researcher and in accordance with the inclusion and exclusion criteria. Sample The sample used by mothers had as many as 75 people. Chi-square test results show
that the variable of Maternal Motivation with Adherence to Vitamin A Giving to Toddlers is obtained chi-square results p-value 0.001 (α <0.05), the role of cadres with compliancVitamin A administration in toddlers obtained a chi-square p-value of 0.001 (α<0.05), so it can be concluded that there is a relationship between maternal motivation and the role of cadres with adherence to vitamin A administration in toddlers. Cadres with Adherence to Vitamin A Giving to Toddlers in Posyandu Area Watas Marga Health Centre Work Area in 2024. It is recommended that th health centre improve
health services, especially in Maternal and Child Health.
The Plasticity of Thought in Translation
Authors: Shread Carolyn 
Published: December 2024

My first translation of French philosopher Catherine Malabou’s work is “An Eye at the Edge of Discourse” (2007), in which she asks “What is it to see a thought? To see a thought coming?” This question prompted me to ask in turn, “What is it to see a thought coming in translation?” I put this question to readers of translations and, in a self-reflexive move, as a translator of her French thought into English. Engaging a seminar on this topic in which Malabou offered a retrospective account of how plasticity has emerged in her work over more than two decades, I consider its transdisciplinary potential specifically as it manifests in the field of translation, and here in the translation of scholarly thought.
Following this retrospective gaze, I consider a recent article that is still untranslated from the French, Malabou’s “Quand on n’a que le discours: Réflexions sur la forme” (2022a). Drawing on the intersection of thinking and seeing, I refer to three artists—Kader Attia, Sophia Wallace, and Pearl Shread—to explore the valences of visibility and intelligibility, as well as routes of access to thought and knowledge.
I conclude my discussion with brief reflections on my recent Malabou translation Stop Thief! Anarchism and Philosophy (2023), suggesting that the act of translation offers a possible route to autonomy and self-determination in the face of dominating effects of governance.
« De sur a norte » : traduire la posture ch’ixi de Silvia Rivera Cusicanqui vers l’anglais
Authors: Kancepolsky Teichmann Ana 
Published: December 2024

En 2019, dix ans après sa publication originale en espagnol, apparaît le premier livre traduit vers l’anglais de l’activiste, théoricienne, historienne et sociologue bolivienne Silvia Rivera Cusicanqui : Ch’ixinakax utxiwa. On Practices and Discourses of Decolonization (Polity Press). Le contexte de cette traduction est problématique : alors que, dans son texte, Rivera Cusicanqui adresse une forte critique aux théories et théoricien·nes de la décolonisation issu·es des universités nord-américaines, ce sont ces mêmes universités qui la traduisent quelques années plus tard. Cet article propose une analyse de la posture (Meizoz, 2009) de Rivera Cusicanqui qui se développe à partir du concept aymara ch’ixi, une couleur grise constituée d’un noir et d’un blanc qui ne se mélangent pas. L’étude de quelques extraits de Ch’ixinakax utxiwa. On Practices and Discourses of Decolonization servira à démontrer que la posture auctoriale est transformée dans le processus traductif, où certains de ses traits sont effacés ou nuancés, et que ces transformations sont indissociables du contexte de production de la traduction.
Et si on lisait les préfaces ? Regards d’écrivain·es contemporain·es sur la (re)traduction
Authors: Delcour Manon , Hambursin Olivier 
Published: December 2024

Cet article se propose d’étudier quelques retraductions publiées par des écrivain·es entre 2008 et 2021, en observant plus précisément le lieu de mise en perspective que constituent leurs préfaces.
Nous analyserons surtout les préfaces accompagnant les nouvelles traductions de Mrs Dalloway de Virginia Woolf par Nathalie Azoulai (2021), de Bartleby, the Scrivener d’Herman Melville et La Maison maudite de Phillips Howard Lovecraft par François Bon (2015 et 2017), des Métamorphoses d’Ovide par Marie Cosnay (2020), de Tristes pontiques d’Ovide et d’Un lieu à soi de Virginia Woolf par Marie Darrieussecq (2008 et 2016) ainsi que de Des souris et des hommes de John Steinbeck par Agnès Desarthe (2022).
Nous passerons en revue les fonctions généralement dévolues aux préfaces depuis la publication de Seuils de Gérard Genette, en particulier aux préfaces accompagnant des traductions (Letawe, 2018; Hersant, 2018). Le premier objectif de cet article sera, en considérant la préface comme le lieu d’un discours sur le texte traduit et le travail accompli, de mettre en évidence plusieurs questionnements et prises de position relatifs aux procédés, difficultés et enjeux inhérents à la traduction et, le cas échéant, la retraduction. Nous entendons ensuite décrire la posture adoptée par les écrivain·es de notre corpus dans leurs (re)traductions. Dans le troisième pan de notre étude, nous étudierons la manière dont ces auteur·ices se positionnent vis-à-vis de l’exercice particulier qu’est la retraduction, ce qui nous donnera l’occasion de nous pencher sur les intentions présidant à ces retraductions et sur la problématique du vieillissement des traductions.
Transient receptor potential V4 channel stimulation induces reversible epithelial cell permeability in MDCK cell monolayers
Authors: Mukaiyama Minagi , Yamasaki Yohei , Usui Takeo , Nagumo Yoko 
Published: June 2019

The transient receptor potential V4 channel (TRPV4) is responsive to a variety of physical and chemical stimuli, including a synthetic agonist GSK1016790A (GSK). Here, we show that TRPV4 is functionally expressed in, and that GSK induces the reversible opening of tight junctions (TJs) in epithelial Madin–Darby canine kidney II monolayers. Stimulation of TRPV4 by GSK induces an increase in fluorescein isothiocyanate‐conjugated dextran (4 kDa) permeability and a reduction in transepithelial resistance, and these responses are blocked by pretreatment with the specific TRPV4 antagonist. Small conductance, but not large conductance Ca2+‐activated K+ channels, TRPA1 channel, and cofilin activation are involved in TRPV4‐mediated reversible opening of TJs. These results suggest that a novel mechanism underlies TRPV4‐mediated regulation of the tightness of epithelial barriers.
Exploring site‐specific activation of bis‐N,N’‐dialkylaminophosphordiamidites and the synthesis of morpholinophosphoramidate oligonucleotides
Authors: Krishna Heera , Jastrzebska Katarzyna , Caruthers Marvin 
Published: June 2019

Morpholinos are six‐membered rings that may provide higher conformational rigidity when incorporated into an oligonucleotide (ODN) backbone. Phosphorodiamidate morpholinos are chemically modified ODNs containing morpholinos in place of 2’‐deoxyribose moieties throughout their backbone and have garnered much interest in recent years due to their ability to function as highly effective steric blockers in exon skipping therapy. To further explore the biophysical and biological properties of ODNs derived from morpholino nucleosides, we have replaced the 2’‐deoxyribonucleotides of phosphodiester DNA with morpholinonucleotides to generate phosphoramidate ODNs. Here, we evaluate the mechanistic pathways observed during the solution‐phase synthesis of morpholinonucleoside phosphoramidites, solid‐phase synthesis of morpholinonucleotide phosphoramidates of mA, mG, mC and mT (prefix ‘m’ represents morpholino) and our first attempts directed at the solid‐phase synthesis of chimeric DNA‐phosphoramidate ODNs, as well as fully modified 22‐mer phosphoramidate ODNs.
Interpersonal prosodic correlation in frontotemporal dementia
Authors: Pressman Peter S. , Ross Elliott D. , Cohen Kevin B. , Chen Kuan‐Hua , Miller Bruce L. , Hunter Lawrence E. , Gorno‐Tempini Maria Luisa , Levenson Robert W. 
Published: June 2019

AbstractCommunication accommodation describes how individuals adjust their communicative style to that of their conversational partner. We predicted that interpersonal prosodic correlation related to pitch and timing would be decreased in behavioral variant frontotemporal dementia (bvFTD). We predicted that the interpersonal correlation in a timing measure and a pitch measure would be increased in right temporal FTD (rtFTD) due to sparing of the neural substrate for speech timing and pitch modulation but loss of social semantics. We found no significant effects in bvFTD, but conversations including rtFTD demonstrated higher interpersonal correlations in speech rate than healthy controls.
Progress in the Design of Cooperative Heterogeneous Catalytic Materials for C–C Bond Formation
Authors: Khoury Christine , Gadipelly Chandrakanth , Pappuru Sreenath , Shpasser Dina , Gazit Oz M. 
Published: June 2019

AbstractThe application of cooperative heterogeneous catalysts for the promotion of C–C bond formation is of great potential for making such chemical processes more sustainable. In the design of such materials, the main challenges are to form specific catalytic sites and to control the cooperative interactions. Because of the high complexity inherent to cooperative active site interactions, much of the research is focused on so called “enzyme inspired‐materials.” The current Progress Report identifies three material subgroups that are characterized by a rigid‐ordered backbone (layered material), a flexible backbone (polymer based), or a constrained‐flexible‐ordered backbone (metal organic frameworks). In each of these material types, examples that illustrate how key structural and chemical characteristics functions are associated with the efficient promotion of the cooperative mechanism are highlighted. The limitations and strengths of each of the systems are considered with the aim of providing an outlook with regard to the minimum requirements needed to construct an efficient cooperative catalytic material. Given the current accumulated common knowledge in this area, it is suggested that getting inspiration from the synthetic existing systems is perhaps more beneficial than from enzymes.
Dynamic Photomask‐Assisted Direct Ink Writing Multimaterial for Multilevel Triboelectric Nanogenerator
Authors: Chen Kaijuan , Zhang Lei , Kuang Xiao , Li Vincent , Lei Ming , Kang Guozheng , Wang Zhong Lin , Qi Hang Jerry 
Published: June 2019

AbstractTriboelectric nanogenerator (TENG) devices are extensively studied as a mechanical energy harvester and self‐powered sensor for wearable electronics and physiological monitoring. However, the conventional TENG fabrication involving assembling steps and using the single property of matrix material suffers from simple devices shape and a single level of mechanical response for sensing and energy harvesting. Here, the printed multimaterial matrix for multilevel mechanical‐responsive TENG with on‐demand reconfiguration of shape is reported. A multimaterial 3D printing approach by using dynamic photomask‐assisted direct ink writing printing together with a two‐stage curing hybrid ink is first developed. Multimaterial structures with location‐specific properties, such as tensile modulus, failure stress, and glass transition temperature for controlled deformation, crack propagation path, and sequential shape memory, are directly printed. The printed multimaterial structure with sequential deformation behavior is used to fabricate a multilevel‐TENG (mTENG) device for multiple level mechanical energy harvesters and sensors. It is demonstrated that the mTENG can be embedded in shoe insoles to achieve both comfortable wearing and motion state monitoring. This work provides a new approach to combine multimaterial 3D printing with TENG devices for functional wearable electronics as energy harvester and sensors.
Kinetic Stabilization of the Sol–Gel State in Perovskites Enables Facile Processing of High‐Efficiency Solar Cells
Authors: Wang Kai , Tang Ming‐Chun , Dang Hoang X. , Munir Rahim , Barrit Dounya , De Bastiani Michele , Aydin Erkan , Smilgies Detlef‐M. , De Wolf Stefaan , Amassian Aram 
Published: June 2019

AbstractPerovskite solar cells increasingly feature mixed‐halide mixed‐cation compounds (FA1−x−yMAxCsyPbI3−zBrz) as photovoltaic absorbers, as they enable easier processing and improved stability. Here, the underlying reasons for ease of processing are revealed. It is found that halide and cation engineering leads to a systematic widening of the anti‐solvent processing window for the fabrication of high‐quality films and efficient solar cells. This window widens from seconds, in the case of single cation/halide systems (e.g., MAPbI3, FAPbI3, and FAPbBr3), to several minutes for mixed systems. In situ X‐ray diffraction studies reveal that the processing window is closely related to the crystallization of the disordered sol–gel and to the number of crystalline byproducts; the processing window therefore depends directly on the precise cation/halide composition. Moreover, anti‐solvent dripping is shown to promote the desired perovskite phase with careful formulation. The processing window of perovskite solar cells, as defined by the latest time the anti‐solvent drip yields efficient solar cells, broadened with the increasing complexity of cation/halide content. This behavior is ascribed to kinetic stabilization of sol–gel state through cation/halide engineering. This provides guidelines for designing new formulations, aimed at formation of the perovskite phase, ultimately resulting in high‐efficiency perovskite solar cells produced with ease and with high reproducibility.
Ferroelectric Extended Nanofluidic Channels for Room‐Temperature Microfuel Cells
Authors: Pihosh Yuriy , Kazoe Yutaka , Mawatari Kazuma , Seo Hangyeol , Tabata Osamu , Tsuchiya Toshiyuki , Kitamura Kenji , Tosa Masahiro , Turkevych Ivan , Kitamori Takehiko 
Published: June 2019

AbstractIntegration of fuel cells into microfluidic devices requires development of innovative proton conductors. Conventional Nafion membranes are incompatible with planar‐type microfluidic devices and require a high operation temperature of over 100 °C to achieve rapid proton transfer. In contrast, glass nanochannels (NCs) work as proton conductors even at room temperature and can be seamlessly integrated into microfluidic devices, which in turn makes microfuel cells (µFCs) attractive for a wide range of practical applications, such as power sources for ultrasmall autonomous electronics and chemo‐ or biosensors. However, the conductivity of NCs is limited by their small cross‐sectional area. It is revealed that spontaneous polarization of lithium niobite (LiNbO3) used as the NC material enhances a surface charge of a SiO2 layer formed on LiNbO3 and induces a fast proton transfer in water in the NCs. It is demonstrated that a µFC containing the LiNbO3 NCs demonstrates a proton diffusion coefficient that is 1.8 times higher than that of a reference device with bare glass NCs. In addition, such a µFC achieves a remarkable power output of up to ≈54 mW cm−2 at room temperature, which is 1.4 times higher than that of the similar device with bare glass NCs.
Stable Cross‐Conjugated Tetrathiophene Diradical
Authors: Zhang Cheng , Medina Rivero Samara , Liu Wuyue , Casanova David , Zhu Xiaozhang , Casado Juan 
Published: June 2019

AbstractA tetracyano quinoidal tetrathiophene, having a central bi(thieno[3,4‐c]pyrrole‐4,6‐dione) acceptor, has been studied. The recovered aromaticity of the thiophenes produces a diradical species with cross‐conjugation between the inter‐dicyano and inter‐dione acceptor paths. A diradical character of y0=0.61 and a singlet–triplet gap of −2.76 kcal mol−1 were determined. Competition between the two cross‐conjugated paths enhances the disjointed character of the SOMOs and results in the confinement of the diradical to the molecular center, enabling a thermodynamic diradical stabilization featuring a half‐life of 262 hours. Cross‐conjugation effects have been also addressed in the anionic species (up to a radical trianion).
Tunable Surface Area, Porosity, and Function in Conjugated Microporous Polymers
Authors: Chen Jie , Yan Wei , Townsend Esther J. , Feng Jiangtao , Pan Long , Del Angel Hernandez Veronica , Faul Charl F. J. 
Published: June 2019

AbstractSimple inorganic salts are used to tune N‐containing conjugated microporous polymers (CMPs) synthesized by Buchwald–Hartwig (BH) cross‐coupling reactions. Poly(triphenylamine), PTPA, initially shows a broad distribution of micropores, mesopores, and macropores. However, the addition of inorganic salts affects all porous network properties significantly: the pore size distribution is narrowed to the microporous range only, mimicking COFs and MOFs; the BET surface area is radically improved from 58 m2 g−1 to 1152 m2 g−1; and variations of the anion and cation sizes are used to fine‐tune the surface area of PTPA, with the surface area showing a gradual decrease with an increase in the ionic radius of salts. The effect of the salt on the physical properties of the polymer is attributed to adjusting and optimizing the Hansen solubility parameters (HSPs) of solvents for the growing polymer, and named the Beijing–Xi'an Jiaotong (BXJ) method.
Oxidative Amide Coupling from Functionally Diverse Alcohols and Amines Using Aerobic Copper/Nitroxyl Catalysis
Authors: Piszel Paige E. , Vasilopoulos Aristidis , Stahl Shannon S. 
Published: June 2019

AbstractThe aerobic Cu/ABNO catalyzed oxidative coupling of alcohols and amines is highlighted in the synthesis of amide bonds in diverse drug‐like molecules (ABNO=9‐azabicyclo[3.3.1]nonane N‐oxyl). The robust method leverages the privileged reactivity of alcohols bearing electronegative hetero‐ atoms (O, F, N, Cl) in the β‐position. The reaction tolerates over 20 unique functional groups and is demonstrated on a 15 mmol scale under air. Steric constraints of the catalyst allow for chemoselective amidation of primary amines in the presence of secondary amines. All catalyst components are commercially available, and the reaction proceeds under mild conditions with retention of stereocenters in both reaction partners, while producing only water as a by‐product.
Inhibition of Pathogen Adhesion by Bacterial Outer Membrane‐Coated Nanoparticles
Authors: Zhang Yue , Chen Yijie , Lo Christopher , Zhuang Jia , Angsantikul Pavimol , Zhang Qiangzhe , Wei Xiaoli , Zhou Zhidong , Obonyo Marygorret , Fang Ronnie H. , Gao Weiwei , Zhang Liangfang 
Published: June 2019

AbstractAnti‐adhesion therapies interfere with the bacterial adhesion to the host and thus avoid direct disruption of bacterial cycles for killing, which may alleviate resistance development. Herein, an anti‐adhesion nanomedicine platform is made by wrapping synthetic polymeric cores with bacterial outer membranes. The resulting bacterium‐mimicking nanoparticles (denoted “OM‐NPs”) compete with source bacteria for binding to the host. The “top‐down” fabrication of OM‐NPs avoids the identification of the adhesins and bypasses the design of agonists targeting these adhesins. In this study, OM‐NPs are made with the membrane of Helicobacter pylori and shown to bind with gastric epithelial cells (AGS cells). Treatment of AGS cells with OM‐NPs reduces H. pylori adhesion and such anti‐adhesion efficacy is dependent on OM‐NP concentration and its dosing sequence.
Structural Engineering of Luminogens with High Emission Efficiency Both in Solution and in the Solid State
Authors: Wu Hongwei , Chen Zhao , Chi Weijie , Bindra Anivind Kaur , Gu Long , Qian Cheng , Wu Bing , Yue Bingbing , Liu Guofeng , Yang Guangbao , Zhu Liangliang , Zhao Yanli 
Published: June 2019

AbstractDeveloping molecules with high emission efficiency both in solution and the solid state is still a great challenge, since most organic luminogens are either aggregation‐caused quenching or aggregation‐induced emission molecules. This dilemma was overcome by integrating planar and distorted structures with long alkyl side chains to achieve DAπAD type emitters. A linear diphenyl–diacetylene core and the charge transfer effect ensure considerable planarity of these molecules in the excited state, allowing strong emission in dilute solution (quantum yield up to 98.2 %). On the other hand, intermolecular interactions of two distorted cyanostilbene units restrict molecular vibration and rotation, and long alkyl chains reduce the quenching effect of the π–π stacking to the excimer, eventually leading to strong emission in the solid state (quantum yield up to 60.7 %).
Diagonally Related s‐ and p‐Block Metals Join Forces: Synthesis and Characterization of Complexes with Covalent Beryllium–Aluminum Bonds
Authors: Paparo Albert , Smith Cory D. , Jones Cameron 
Published: June 2019

AbstractAdditions of beryllium–halide bonds in the simple beryllium dihalide adducts, [BeX2(tmeda)] (X=Br or I, tmeda=N,N,N′,N′‐tetramethylethylenediamine), across the metal center of a neutral aluminum(I) heterocycle, [:Al(DipNacnac)] (DipNacnac=[(DipNCMe)2CH]−, Dip=2,6‐diisopropylphenyl), have yielded the first examples of compounds with beryllium–aluminum bonds, [(DipNacnac)(X)Al‐Be(X)(tmeda)]. For sake of comparison, isostructural Mg–Al and Zn–Al analogues of these complexes, viz. [(DipNacnac)(X)Al‐M(X)(tmeda)] (M=Mg or Zn, X=I or Br) have been prepared and structurally characterized. DFT calculations reveal all compounds to have high s‐character metal–metal bonds, the polarity of which is consistent with the electronegativities of the metals involved. Preliminary reactivity studies of [(DipNacnac)(Br)Al‐Be(Br)(tmeda)] are reported.
σ‐Noninnocence: Masked Phenyl‐Cation Transfer at Formal NiIV
Authors: Steen Jelte S. , Knizia Gerald , Klein Johannes E. M. N. 
Published: June 2019

AbstractReductive elimination is an elementary organometallic reaction step involving a formal oxidation state change of −2 at a transition‐metal center. For a series of formal high‐valent NiIV complexes, aryl–CF3 bond‐forming reductive elimination was reported to occur readily (Bour et al. J. Am. Chem. Soc. 2015, 137, 8034–8037). We report a computational analysis of this reaction and find that, unexpectedly, the formal NiIV centers are better described as approaching a +II oxidation state, originating from highly covalent metal–ligand bonds, a phenomenon attributable to σ‐noninnocence. A direct consequence is that the elimination of aryl–CF3 products occurs in an essentially redox‐neutral fashion, as opposed to a reductive elimination. This is supported by an electron flow analysis which shows that an anionic CF3 group is transferred to an electrophilic aryl group. The uncovered role of σ‐noninnocence in metal–ligand bonding, and of an essentially redox‐neutral elimination as an elementary organometallic reaction step, may constitute concepts of broad relevance to organometallic chemistry.