bluuebunny/crossref_metadata_2025_split huggingface dataset:
Multistep Removal System of Gaseous Toluene: Adsorption, Electrochemical, and Photolytic Treatments
Authors: Bolaños‐Romero Karla Verónica , López‐Carbajal Rosa Luz , Sandoval‐González Antonia , Oza Goldie , Manríquez Rocha Juan , Gaucin‐Gutiérrez Susana Citlaly , Romero‐Ibarra Issis Claudette , Frausto‐Castillo Roberto Fernando , Rodríguez‐López Joaquín , Bustos Bustos Erika 
Published: December 2024

AbstractA large amount of atmospheric emissions result from various anthropogenic activities worldwide. Given the complexity of volatile organic compounds (VOCs) and their different adsorption capacities, redox potentials, and photolytic properties, an air purification system for the removal of VOCs that combines multiple physical processes was proposed in this study using toluene as an example. These processes include, in the first step, an adsorption treatment (AT) with activated carbon (AC), where toluene adsorption results from the insertion of aromatic rings (nonpolar groups) between the graphitic carbon planes, as demonstrated by the Raman spectroscopy; in the second step, electrochemical treatment (ECT) using TiO2,nt|Ti||SS‐304 electrodes applying an electric field to accelerate the oxidation of toluene through the production of free radicals (⋅OH), hydroperoxyl radicals and benzyl groups, followed by the rupture of aromatic rings to generate aliphatic compounds and the consequent mineralization to CO, CO2, and H2O; in the third step, photolytic treatment (PT) with a 254‐nm UV lamp for toluene degradation is used, which is influenced by the addition of radicals, such as ⋅OH or ⋅O−2ad, to transform toluene into either benzene or phenol. The multistep system integrating AT, ECT and PT was more efficient overall (99.58 %) than the individual treatments (AT=50.29 %, ECT=44.38 %, and PT=52.71 %) as evaluated by gas chromatography with a BID detector; it showed enhanced efficiency enabled by the synergistic effects of combining multiple technologies to enhance the overall toluene degradation efficiency and flexibility. The multistage systems can be adapted to specific contamination conditions and process requirements with the generation of residual toluene, phenol, and aliphatic compounds and possible mineralization to molecules such as CO2, CO, and H2O. This small and portable multistep system provides a novel approach for treating outdoor and/or indoor air contaminated with toluene.
Upcycling Textile Waste into Anionic and Cationic Cellulose Nanofibrils and Their Assembly into 2D and 3D Materials
Authors: Ruiz‐Caldas Maria‐Ximena , Apostolopoulou‐Kalkavoura Varvara , Pacoste Laura , Jaworski Aleksander , Mathew Aji P. 
Published: December 2024

AbstractExtracting high‐performance nanomaterials from waste presents a promising avenue for valorization. This study presents two methods for extracting cellulose nanofibrils (CNFs) from discarded textiles. Post‐consumer cotton fabrics are chemically treated through either cationization with (2,3‐epoxypropyl)trimethylammonium chloride or TEMPO/NaBr‐catalyzed oxidation, followed by fibrillation to produce Cat‐CNFs and TO‐CNFs, respectively. Molecular models indicate variations in the effective volume of each grafted group, influencing the true densities of the functionalized fibers. Significant differences in the morphology of the CNFs arise from each functionalization route. Both CNF types exhibit high surface charge (>0.9 mmol g−1), small cross‐sections (<10 nm), and high aspect ratios (>35). TO‐CNFs have a higher surface charge, whereas Cat‐CNFs exhibit a higher aspect ratio and greater colloidal stability across a broader pH range. Cat‐CNFs exhibit cross‐sections at the elementary fibril level, highlighting the steric impact of the grafted surface groups on fibrillation efficiency. Nanopapers from these CNFs demonstrate high optical transmittance and haze, whereas anisotropic foams show mechanical properties comparable to foams made from wood‐based CNFs. This work highlights the potential of post‐consumer cotton textiles as a CNF source and the impact of chemical treatment on the properties of the fibers, CNFs, and resulting lightweight materials.
Glucose‐induced LINC01419 reprograms the glycolytic pathway by recruiting YBX1 to enhance PDK1 mRNA stability in hepatocellular carcinoma
Authors: Liu Yanfang , Song Junjiao , Shi Qili , Chen Bing , Qiu Wenying , Liu Yizhe , Huang Shenglin , He Xianghuo 
Published: December 2024

AbstractMetabolic reprogramming provides the necessary energy for the development of malignant tumours and is emerging as a novel tumour treatment strategy. However, the widespread expression of metabolic enzymes in diverse cell types makes the development of specific drugs that target cancer cells without affecting normal cellular functions challenging. Accumulating evidence has demonstrated the essential roles of long non‐coding RNAs (lncRNAs) in the regulatory network associated with glucose metabolism in tumour cells. The mechanism and therapeutic potential of cancer‐specific lncRNAs in modulating tumour glucose metabolism warrant in‐depth exploration. Here we revealed that glucose‐induced LINC01419 promoted the growth and metastasis of HCC cells by driving metabolic reprogramming. Mechanistically, LINC01419 directly interacted with Y‐box binding protein 1 (YBX1) in the cytoplasm and facilitated its binding to PDK1 mRNA, thus enhancing PDK1 mRNA stability and increasing lactate production. Furthermore, YY1 contributed to the transcriptional activation of LINC01419 in HCC under high‐glucose conditions. Notably, administration of an N‐acetylgalactosamine (GalNAc)‐conjugated siRNA specifically targeting LINC01419 markedly retarded the growth of orthotopic xenograft tumours. These findings provide evidence for an unprecedented regulatory mechanism of LINC01419 involving metabolic reprogramming in human cancer. The newly identified LINC01419/YBX1‐PDK1 axis may represent a promising therapeutic target for HCC. Moreover, GalNAc‐siLINC01419 holds significant potential for clinical application.Key points
This study highlights the considerable regulatory role of LINC01419 in the metabolism of HCC.
The newly identified LINC01419/YBX1‐PDK1 axis constitutes a valuable target.
Hepatic‐specific delivery of GalNAc‐siLINC01419 presents a promising therapeutic strategy for HCC.
Genomic Signatures of Domestication in European Seabass (Dicentrarchus labrax L.) Reveal a Potential Role for Epigenetic Regulation in Adaptation to Captivity
Authors: Moulistanos Aristotelis , Papasakellariou Konstantinos , Kavakiotis Ioannis , Gkagkavouzis Konstantinos , Karaiskou Nikoleta , Antonopoulou Efthimia , Triantafyllidis Alexandros , Papakostas Spiros 
Published: December 2024

ABSTRACTGenome scans provide a comprehensive method to explore genome‐wide variation associated with traits under study. However, linking individual genes to broader functional groupings and pathways is often challenging, yet crucial for understanding the evolutionary mechanisms underlying these traits. This task is particularly relevant for multi‐trait processes such as domestication, which are influenced by complex interactions between numerous genetic and non‐genetic factors, including epigenetic regulation. As various traits within the broader spectrum of domestication are selected in concert over time, this process offers an opportunity to identify broader functional overlaps and understand the integrated genetic architecture underlying these traits. In this study, we analyzed approximately 600,000 SNPs from a Pool‐Seq experiment comparing eight natural‐origin and 12 farmed populations of European seabass in the Mediterranean Sea region. We implemented two genome scan approaches and focused on genomic regions supported by both methods, resulting in the identification of 96 candidate genes, including nine CpG islands, which highligt potential epigenetic influences. Many of these genes and CpG islands are in linkage groups previously associated with domestication‐related traits. The most significantly overrepresented molecular function was “oxidoreductase activity”. Furthermore, a dense network of interactions was identified, connecting 22 of the candidate genes. Within this network, the most significantly enriched pathways and central genes were involved in “chromatin organization”, highlighting another potential epigenetic mechanism. Altogether, our findings underscore the utility of interactome‐assisted pathway analysis in elucidating the genomic architecture of polygenic traits and suggest that epigenetic regulation may play a crucial role in the domestication of European seabass.
Phylogeography of Cold Water Soft Coral Alcyonium spp. (Anthozoa, Octocorallia: Alcyonacea) Between South America and the West Antarctic Peninsula
Authors: Bruning Paulina , Archaumbault Phillippe , Garrido Ignacio , de Lecea Ander M. , Morley Simon A. , Brante Antonio , Ortiz Paula , Cárdenas Leyla 
Published: December 2024

ABSTRACTThe Antarctic marine environment has a unique geologic and climatic history that has contributed to the evolution of high species diversity. Given the current trend of environmental warming, understanding the history of Antarctic species is crucial for predicting the impact of climate change on ecosystem function. Soft corals are a group of striking presence in the benthic marine assemblages in the Southern Ocean, which is recognized as a biodiversity hotspot. DNA sequences (Cox1, mtMutS, and 28S rDNA) were utilized for molecular phylogenetic reconstructions, species delimitations, and divergence estimations to investigate the spatial patterns of genetic diversity in Alcyonium species in the southern South American‐Antarctic region. Significant genetic divergence was observed between regions, with a clear genetic break between South America and the West Antarctic Peninsula and the identification of four putative species. Divergence time estimates indicated that Alcyonium's diversification began about 41.1 million years ago (Ma), coinciding with the opening of the Drake Passage and the formation of the Antarctic Circumpolar Current (ACC, ~42 Ma). This indicates that Alcyonium has persisted in situ for an extensive period, enduring a wide range of environmental conditions.
Do It Well or Not at All: Alternative Flight Solutions for Alpine Insects
Authors: McCulloch Graham A. , Foster Brodie J. , Ingram Travis , Waters Jonathan M. 
Published: December 2024

ABSTRACTExposed and isolated alpine ecosystems present evolutionary challenges for flying species worldwide. Many insects have undergone dramatic wing reduction in response to these harsh conditions, losing the ability to fly. By contrast, some taxa have countered alpine conditions by evolving larger wings to improve flight ability. In this study, we investigated how two independent clades of Zelandoperla fenestrata stoneflies respond to upland environments. Our results revealed strikingly different adaptations to elevation across the two closely related clades. In Clade 1 (southern South Island), wing length decreases sharply with increasing elevation. In contrast, wing length in the geographically adjacent Clade 2 (northern South Island, and North Island) increases with elevation. These contrasting strategies highlight the diverse adaptive pathways that may exist even for closely related lineages encountering similar environmental challenges.
Fish and invertebrate communities show greater day–night partitioning on tropical than temperate reefs
Authors: Jones Tyson R. , Edgar Graham J. , Trebilco Rowan , Mellin Camille , Stuart‐Smith Rick D. , Denis‐Roy Lara , Johnson Olivia J. , Rose Matthew , Ling Scott D. 
Published: December 2024

AbstractDiel partitioning of animals within ecological communities is widely acknowledged, yet rarely quantified. Investigation of most ecological patterns and processes involves convenient daylight sampling, with little consideration of the contributions of nocturnal taxa, particularly in marine environments. Here we assess diel partitioning of reef faunal assemblages at a continental scale utilizing paired day and night visual census across 54 shallow tropical and temperate reefs around Australia. Day–night differences were most pronounced in the tropics, with fishes and invertebrates displaying distinct and opposing diel occupancy on coral reefs. Tropical reefs in daytime were occupied primarily by fishes not observed at night (64% of all species sighted across day and night, and 71% of all individuals). By night, substantial emergence of invertebrates not otherwise detected during sunlit hours occurred (56% of all species, and 45% of individuals). Nocturnal emergence of tropical invertebrates corresponded with significant declines in the richness and biomass of predatory and herbivorous diurnal fishes. In contrast, relatively small diel changes in fishes active on temperate reefs corresponded to limited nocturnal emergence of temperate invertebrates. This reduced partitioning may, at least in part, be a result of strong top‐down pressures from fishes on invertebrate communities, either by predation or competitive interference. For shallow reefs, the diel cycle triggers distinct emergence and retreat of faunal assemblages and associated trophic patterns and processes, which otherwise go unnoticed during hours of regular scientific monitoring. Improved understanding of reef ecology, and management of reef ecosystems, requires greater consideration of nocturnal interactions. Without explicit sampling of nocturnal patterns and processes, we may be missing up to half of the story when assessing ecological interactions.
A comparison of role‐related physical fitness between British Army trainees and trained soldiers
Authors: Rue Carla , Needham‐Beck Sarah , Maroni Tessa , Siddall Andrew , Ashdown Kimberly , Lee Ben , Walker Faye , Osofa Joshua , Doherty Julianne , Vine Christopher , Wardle Sophie , Greeves Julie , Saunders Paul , Fieldhouse Anne , Blacker Sam , Myers Stephen 
Published: December 2024

AbstractBritish Army basic training (BT) and initial trade training (ITT) enable personnel to develop role‐related physical capability to perform in‐service job‐roles. The study aimed to compare physical performance of trainees (completing ITT) and trained soldiers, on a series of gym‐based fitness tests and representative military tasks. A total of 316 British Army personnel [68 trainees (63 men: 22 ± 3 years, 71.6 ± 8.4 kg and 1.74 ± 0.07 m) and 248 trained soldiers (225 men: 27 ± 6 years, 78.7 ± 12.7 kg and 1.76 ± 0.08 m)] completed two sessions. Session 1; body mass, stature, age and gym‐based tests (2 km run, broad jump, seated medicine ball throw, hex bar deadlift, 100 m shuttle sprints, pull‐ups and mid‐thigh pull). Session 2; representative military tasks (loaded carriage [stage 1, 4 km, 35–40 kg and 4.8 km h−1 fixed pace and stage 2, 2 km, 20–25 kg and individual best‐effort speed], tactical movement, casualty drag, stretcher carry, vertical lift, repeated carry and incremental lift). Independent sample t‐tests were employed to examine group differences. Compared to trainees, trained soldiers were older (p < 0.001), heavier (p < 0.001) and scored higher on broad jump (p = 0.024), medicine ball throw (p = 0.007) and mid‐thigh pull (p = 0.048), but were slower on 2 km run (p = 0.047), loaded carriage (p < 0.019), tactical movement (p < 0.001) and casualty drag (p < 0.001). Overall, trainees achieve higher scores on aerobic/anaerobic tests, whereas trained soldiers outperform trainees in strength/power‐based tests. Although a cross‐sectional comparison does not provide strong evidence, the results may indicate that cardiovascular fitness is developed during BT, whereas muscle strength/power develops post BT/ITT. These findings would need confirming by a longitudinal study and could inform the development/management of role‐related fitness during BT, ITT and through career.
Ankle proprioception and functional performance in patients with Achilles tendinopathy
Authors: Zhang Tongzhou , Zhao Yilin , Wang Shuhui , Luan Lijiang , Adams Roger , Ganderton Charlotte , Malliaras Peter , Han Jia 
Published: December 2024

AbstractThe purpose of this study was to investigate differences in ankle plantar flexion proprioception and lower extremity function between Achilles tendinopathy (AT) patients and healthy controls. 17 patients with midportion AT (age 22.0 ± 3.0, 7 females, and 10 males) and 17 healthy controls (age 21.5 ± 2.1, 7 females, and 10 males) were recruited. The following tests were performed randomly: the ankle plantar flexion active movement extent discrimination assessment (AMEDA), weight‐bearing lunge test (WBLT), single leg hop test, figure‐of‐eight hop test, Y Balance Test (YBT), and lower extremity functional test (LEFT). Group comparisons were made between the AT and healthy groups, and receiver operator characteristic (ROC) curves were used to analyze the ability of tests to differentiate between participants with and without AT. Results showed that the AT group performed significantly worse in the ankle proprioception test (p = 0.016), single leg hop test (p = 0.001), figure‐of‐eight hop test (p < 0.001), unilateral LEFT (p = 0.001), and LEFT injury risk score (p = 0.001) than healthy controls. No significant between group difference was found in WBLT and YBT. Diagnostic analysis showed that the AMEDA (p = 0.018), single leg hop test (p = 0.003), figure‐of‐eight hop test (p = 0.002), and LEFT (p = 0.001) could differentiate between patients with AT and the healthy individuals. The current study demonstrated that ankle proprioception and functional performance involving explosive jump are impaired in patients with AT, suggesting poorer dynamic neuromuscular function and a higher risk of lower limb injury in this population, and furthermore, these tests should be considered in the assessment for AT.
Influence of Silane‐Treated Jute/Kenaf Fibers on the Mechanical Properties of Polymer Composites for Biomedical Applications: Optimization Using RSM and ANN Approaches
Authors: Saravanan R. , Arunachalam S. Jothi , Sathish T. , Giri Jayant , Ammarullah Muhammad Imam 
Published: December 2024

ABSTRACTThis study investigates the effect of silane‐treated jute/kenaf fibers on the flexural and hardness properties of polymer composites for potential biomedical applications, such as prosthetics and bio‐implants. Using response surface methodology (RSM) and artificial neural network (ANN), the optimal combination of nanoparticle percentage, silane concentration, and silane dipping duration was identified to enhance the mechanical properties of the composites. RSM, coupled with analysis of variance (ANOVA), evaluated the influence of these variables on composite performance, revealing that silane treatment significantly improved flexural strength, while all fiber‐related variables impacted both flexural strength and hardness. The silane dipping duration emerged as the most influential factor, with nanoparticle addition enhancing fiber–matrix interactions and promoting better agglomeration. The ANN model accurately predicted the composite's properties, with results strongly correlating to experimental data. The optimized formulation, consisting of 5% nanoparticle content, 10% silane treatment, and a 20‐min silane dipping duration, demonstrated a 26.22% increase in flexural strength and a 33.15% improvement in hardness. This optimized composite formulation holds promise for use in biomedical applications requiring high mechanical strength and durability, such as in prosthetic materials and orthopedic implants, where enhanced flexural strength and hardness are critical for longevity and performance.
Forecasting carbon emissions peak in Chinese household consumption and selecting low‐carbon development strategies: A study based on the extended SPIRPAT model
Authors: Li Chuang , Wang Xiaoman , Wang Liping 
Published: December 2024

AbstractResidential carbon emissions have emerged as a primary driver of future carbon emissions in China. Investigating the influential factors affecting demand‐side carbon emissions and elucidating future pathways for regional carbon reduction in consumption can provide a scientific basis for regional carbon peak and carbon‐neutral action plans. This study incorporated the development of digital technology into the STIRPAT model. The technical components of the STIRPAT model were expanded upon to better understand the factors influencing the household consumption sector and the carbon emission reduction effects of these various factors. The results indicated that: (i) per capita residential carbon emissions in China exhibit a slow fluctuating rise followed by accelerated growth, with the sequence of emissions being highest in the eastern region, followed by the northeastern region, western region, and finally the central region; (ii) population size, shared prosperity, urbanization development, and digitalization collectively influence residential carbon emissions in different regions, with population size and consumption structure playing the most significant promoting and inhibiting roles, respectively; (iii) societal development scenarios and low‐carbon development scenarios demonstrate a significant advantage in achieving the timely realization of China's overall residential carbon reduction plan. In most provinces, peak emissions are projected to occur around 2035 under various scenarios, necessitating substantial efforts for provinces to meet the 2030 carbon peak target.
Constructing the “moralization shock”: The role of contingency in the translation of anticorruption policy in France
Authors: Wickberg Sofia 
Published: December 2024

AbstractThis article applies the concept of transaction to the process of policy transfer, through the case of conflict of interest regulation in France, using archives, documentary sources, and interviews with stakeholders. It contributes to the literature on policy translation by clarifying the role of contingency, which remains underspecified. It shows that timing matters in two ways: it affects actors' ability to open a policy window, and it ultimately affects problem definition and future implementation instruments and practices. It explores the construction of the situation as a scandal, making it necessary to adapt transferred ideas to the political context, where a “shock of moralization” was seen as necessary. It also offers an opportunity to enrich the scholarship on policy transaction with an application to transnational policymaking, where problem definitions and policy solutions are imported from elsewhere and where foreign or transnational actors contribute to the co‐construction of actors and issues.