bluuebunny/crossref_metadata_2025_split huggingface dataset:
Pharmaceutical‐Oriented Iron‐Catalyzed Ethoxylation of Aryl C(sp2)‐H Bonds with Cobalt Co–Catalyst
Authors: Zhang Guofu , Zhu Jianfei , Ding Chengrong 
Published: September 2018

AbstractA novel and mild pharmaceutical‐oriented iron‐catalyzed ethoxylation of aryl C(sp2)‐H bonds with cobalt co‐catalyst was successfully developed. The reaction occurs efficiently with broad substrate scope tolerance and high regioselectivity. It's the first example of C−H alkoxylation using inexpensive and low biotoxicity iron as a catalyst.
Penta‐Nuclear Fe(III) Cluster: Synthesis, Structure, Magnetic Properties and Hirshfeld Surface Analysis
Authors: Chen Zhonghang , Fan Yipeng , Wang Jiming , Yang Li , Zhang Shuhua 
Published: September 2018

AbstractA new penta‐nuclear Fe(III) cluster, [Fe5(μ3‐O)2L3(HL)(ATZ)4]⋅4H2O (1), (H2L is 2‐(((1H‐tetrazol‐5‐yl)imino)methyl)phenol, HATZ is 5‐Amino‐1H‐tetrazole) was synthesized through micro‐vial method. Complex 1 was characterized by elemental analysis, fourier transform infrared (FTIR), X‐ray single crystal diffraction, powder X‐ray diffraction (Powder XRD) and thermogravimetric analysis. Moreover, the magnetic properties and Hirshfeld surface analysis of 1 were investigated and discussed in detail.
DFT, QTAIM and NBO Investigation of the Interaction of Rare Gases with Pristine and Decorated Boron Nitride Nanotube
Authors: Nemati‐Kande Ebrahim , Abbasi Mahdi , Doust Mohammadi Mohsen 
Published: September 2018

AbstractIn this work, the interactions of pristine, Al‐ and Ga‐doped single walled armchair (5,5) boron nitride nanotubes (BNNTs) with He, Ne, Ar and Kr rare gases (RGs) were fully investigated using several different density functional theory (DFT) functionals including pure‐GGA (PBEPBE), hybrid‐GGA (B3LYP), meta‐hybrid‐GGA (M062X) and long‐range‐corrected B3LYP (CAM−B3LYP) in combination with two 6–31G(d) and 6–311+G(d) basis sets. Natural bond orbital (NBO) and quantum theory of atoms in molecule (QTAIM) analyses were also performed to better understand the intermolecular interaction between RGs and nanotubes. The adsorption energies (Eads) indicate that RGs could be adsorbed on the surface of the BNNTs with the following trend: Ne > Kr > Ar > He. The Eads energies obtained using CAM−B3LYP method have also been found to be 13–18%, (for Ne−Kr) and 32–44% (for He−Ar) higher than those obtained from normal B3LYP functional. Moreover, analysis of the natural partial charges reveals the small charge transfer from RGs to BNNTs, which confirms the sensing of RGs by BNNTs. QTAIM analysis also supports the existence of close‐shell (non‐covalent) interactions between BNNTs and RGs. Generally, according to the obtained results, it can be concluded that, Al‐ and Ga‐doped BNNTs are remarkably more sensitive to RGs than pristine‐BNNT, and may be good candidates in designing new RG sensors.
Unusual Pericyclic Reactivity of 4‐Nitrobenzofuroxans in 1,3‐Dipolar Cycloaddition with N‐Benzyl Azomethine Ylide – A New Example of Multiple C–C‐Bond Forming Transformations.
Authors: Starosotnikov Alexey M. , Bastrakov Maxim A. , Kachala Vadim V. , Fedyanin Ivan V. , Shevelev Svyatoslav A. , Dalinger Igor L. 
Published: September 2018

AbstractA series of 4‐nitrobenzofuroxans were examined in [3+2]‐cycloaddition reactions with N‐benzyl azomethine ylide. The reaction outcome was found to be dependent on the nature of substituent 7‐R: for R=H and SR’ the products of double cycloaddition of the dipole were isolated, whereas for R=CH3, OR’ and NR'R” tetrahydroisoindoles annelated with furoxan ring were the sole products. As a result efficient chemoselective method for the synthesis of mono‐ and bis‐pyrrolidine fused benzofuroxan derivatives was developed.
Persons and Human Capital
Authors: Dalziel Paul , Saunders Caroline , Saunders Joe 
Published: September 2018

AbstractThe wellbeing economics framework begins with individual persons seeking to create the kinds of lives they value, and have reason to value. These persons are able to make time-use choices they reason will promote wellbeing, influenced by cultural values, personal abilities and social capabilities. The attention to choices about time-use is because persons have equal time to allocate each day, and because time-use choices influence monetary values recorded in market transactions. Persons can expand capabilities through formal education and through relevant experience, which are time-use choices that economists describe as investment in human capital. Progress in wellbeing can be monitored using measures of subjective and objective wellbeing, exemplified in the Organisation for Economic Co-operation and Development’s Better Life Initiative.
Households, Families and Cultural Capital
Authors: Dalziel Paul , Saunders Caroline , Saunders Joe 
Published: September 2018

AbstractThis chapter focuses on wellbeing within households and families, paying careful attention to child development. This is important from the perspective of the child, of the child’s parents, of wider society and globally. Investment in cultural capital enhances wellbeing by creating opportunities for persons to express, develop, transform and pass on to the next generation their cultural inheritance. Men and women can have equal capabilities for wellbeing; yet studies show that significant sacrifices of time and financial costs for parents are carried disproportionately by women, who are also more vulnerable to intimate violence. After accounting for housing costs, nearly one in three children in the United Kingdom are growing up in households with income below 60 per cent of the country’s median equivalised income. Thus, the chapter reveals serious problems that can be overlooked when policy advice focuses on economic growth rather than on wellbeing.
Civil Society and Social Capital
Authors: Dalziel Paul , Saunders Caroline , Saunders Joe 
Published: September 2018

AbstractThis chapter explores how humans collaborate with others outside their families and households to expand capabilities for wellbeing, particularly by creating and participating in civil society institutions. The chapter also analyses social capital and how it can be increased through mechanisms that include: learning in schools; participation in networks; enforcement of norms; development of societal aspirations; and efforts for social inclusion. There are tensions between cultural capital (discussed in the previous chapter) and social capital (this chapter) since access to the services of social capital—especially to bridging social capital—is much easier for people who share the cultural capital of the community’s dominant social group. Policy can enhance capabilities for wellbeing by ensuring persons are not disadvantaged as a result of ethnicity or other personal characteristic in their equitable access to services from all forms of capital.
The Nation State and Knowledge Capital
Authors: Dalziel Paul , Saunders Caroline , Saunders Joe 
Published: September 2018

AbstractThis chapter analyses how a Nation State can contribute to enhanced wellbeing. It begins with its responsibility to act on behalf of citizens as wise custodian of the market economy and welfare state within its borders. This requires central government to adopt an integrated and balanced approach to all its economic and welfare policies. The second half of the chapter focuses on the concept of knowledge capital as a driver of wellbeing. Knowledge creation can be an economic public good, which creates a distinctive opportunity for a well-functioning state to contribute to expanded capabilities for wellbeing through policies that foster the growth and use of knowledge. Knowledge is essential to the operations of the Nation State, whose civil service can offer a specialist capability for creating, collating, synthesising, utilising and disseminating knowledge capital for the common good.
Urinary IgM excretion: a reliable marker for adverse pregnancy outcomes in women with chronic kidney disease
Authors: Leaños-Miranda Alfredo , Campos-Galicia Inova , Ramírez-Valenzuela Karla Leticia , Berumen-Lechuga María Guadalupe , Isordia-Salas Irma , Molina-Pérez Carlos José 
Published: September 2018

Abstract
Objective
Chronic kidney disease (CKD) pregnancies are at high risk of developing adverse outcomes. In non-pregnant subjects with CKD, higher urinary IgM levels are associated with poor renal survival and higher rates of cardiovascular deaths. In this study, we assessed whether urinary IgM levels are associated with an increased risk of adverse pregnancy outcomes (APO) in CKD pregnancies.

Methods
We performed a nested case–control study within a cohort of CKD patients with singleton pregnancies attended at a tertiary care hospital. The study included 90 CKD patients who eventually developed one or more APO and 77 CKD patients who did not. Urinary IgM excretion was determined from the 24-h urine samples at enrollment by an ultrasensitive enzyme immunoassay.

Results
The risk for combined APO and for preeclampsia (PE) was higher among women with urinary IgM and proteinuria levels values in the highest quartile or with CKD stages 4–5 (odds ratios, OR ≥ 2.9), compared with the lowest quartile or with CKD stage 1. Urinary IgM levels were more closely associated with the risk of either combined or specific APO (PE, preterm birth, and for having a small-for-gestational-age infant; OR ≥ 5.9) than either the degree of total proteinuria or CKD stages. Among patients with CKD stage 1, the risk of combined APO, PE, and preterm birth was higher in women with urinary IgM levels values in the highest quartile (OR ≥ 4.8), compared with the three lower quartiles, independently of proteinuria.

Conclusion
In CKD pregnancies, at the time of initial evaluation, proteinuria and CKD stage are associated with increased risk of combined APO. However, urinary IgM concentrations appear to be better predictors of an adverse outcome and may be useful for risk stratification in CKD pregnancies.
Supervisor-Subordinate (Dis)agreement on Ethical Leadership: An Investigation of its Antecedents and Relationship to Organizational Deviance
Authors: Kuenzi Maribeth , Brown Michael E. , Mayer David M. , Priesemuth Manuela 
Published: September 2018

ABSTRACT:We examine supervisor-subordinate (dis)agreement regarding perceptions of the supervisor’s ethical leadership and its relationship to organizational deviance. We find that, on average, supervisors rate themselves more favorably on ethical leadership compared to how followers rate them. In addition, polynomial regression results reveal that unit-level organizational deviance is higher when there is agreement about lower levels of ethical leadership, and disagreement when supervisors rate themselves higher on ethical leadership than subordinates’ ratings of the supervisors. Finally, drawing on social influence theories, we look at antecedents of (dis)agreement and find that supervisors’ beliefs about themselves (that they were “better-than-average” ethical leaders) and others (their assumptions about whether the morality of their subordinates is malleable or not) are associated with self-other (dis)agreement on ethical leadership.
No Longer Lost in Translation: Evidence that Google Translate Works for Comparative Bag-of-Words Text Applications
Authors: de Vries Erik , Schoonvelde Martijn , Schumacher Gijs 
Published: September 2018

Automated text analysis allows researchers to analyze large quantities of text. Yet, comparative researchers are presented with a big challenge: across countries people speak different languages. To address this issue, some analysts have suggested using Google Translate to convert all texts into English before starting the analysis (Lucas et al. 2015). But in doing so, do we get lost in translation? This paper evaluates the usefulness of machine translation for bag-of-words models—such as topic models. We use the europarl dataset and compare term-document matrices (TDMs) as well as topic model results from gold standard translated text and machine-translated text. We evaluate results at both the document and the corpus level. We first find TDMs for both text corpora to be highly similar, with minor differences across languages. What is more, we find considerable overlap in the set of features generated from human-translated and machine-translated texts. With regard to LDA topic models, we find topical prevalence and topical content to be highly similar with again only small differences across languages. We conclude that Google Translate is a useful tool for comparative researchers when using bag-of-words text models.
Consideration of Freshwater and Multiple Marine Reservoir Effects: Dating of Individuals with Mixed Diets from Northern Sweden
Authors: Dury Jack P R , Eriksson Gunilla , Fjellström Markus , Wallerström Thomas , Lidén Kerstin 
Published: September 2018

ABSTRACTHuman burials from the cemetery at the Rounala church, northern Sweden, were radiocarbon (14C) dated to shed light on the use of the cemetery. Carbon, nitrogen and sulfur stable isotope analysis of bone collagen from 19 distinct individuals indicated that these individuals had a mixed diet consisting of freshwater, marine and terrestrial resources. Dietary modeling using FRUITS was employed to calculate the contributions of the different resources for each individual. These data were then used to calculate individual ΔR values, taking into account freshwater and multiple marine reservoir effects, the latter caused by Baltic and Atlantic marine dietary inputs, respectively. 14C dating of tissues from modern freshwater fish species demonstrate a lack of a freshwater reservoir effect in the area. Two OxCal models were used to provide endpoint age estimates. The calibrated data suggest that the site’s cemetery was most likely in use already from the 14th century, and perhaps until at least the late 18th century.
From corps to discipline, part one: Charles d'Almeida, Pierre Bertin and French experimental physics, 1840–1880
Authors: MITCHELL DANIEL JON 
Published: September 2018

AbstractAcademic careers in French science during the mid-nineteenth century were made within the Université de France, an integrated state system of secondary and higher education controlled by a centralized Parisian educational administration. Among the most respected members of thecorps universitairewere Charles d'Almeida and Pierre Bertin, two historically obscurephysicienswhose significance derives from their substantial contributions to the social organization, teaching and communication of French experimental physics. This two-part comparative biography uses their entwined careers to make a case for the emergence of a discipline of French experimental physics from the corps during the tumultuous politico-cultural transition from the Second Empire to the Third Republic. Of fundamental importance are disciplinary regimes of teaching and inspection within the corps, the foundation of the Société française de physique and theJournal de physique, and the diversification of the traditional pedagogical role of the Ecole normale supérieure, which, from around 1860, began to offer a career pathway for aspiring scientific researchers. Having established in this paper the socio-institutional mechanisms for the stabilization of a distinct field, in part two I characterize the epistemological–methodological aspects of French experimental physics.
SUITABILITY OF CURRENT EVALUATION FRAMEWORKS FOR USE IN THE HEALTH TECHNOLOGY ASSESSMENT OF MOBILE MEDICAL APPLICATIONS: A SYSTEMATIC REVIEW
Authors: Moshi Magdalena Ruth , Tooher Rebecca , Merlin Tracy 
Published: September 2018

Objectives:To identify and appraise existing evaluation frameworks for mobile medical applications (MMA) and determine their suitability for use in health technology assessment (HTA) of these technologies.Methods:Systematic searches were conducted of seven bibliographic databases to identify literature published between 2008 and 2016 on MMA evaluation frameworks. Frameworks were eligible if they were used to evaluate at least one of the HTA domains of effectiveness, safety, and/or cost and cost-effectiveness of an MMA. After inclusion, the frameworks were reviewed to determine the number and extent to which other elements of an HTA were addressed by the framework.Results:A total of forty-five frameworks were identified that assessed MMAs. All frameworks assessed whether the app was effective. Of the thirty-four frameworks that examined safety, only seven overtly evaluated potential harms from the MMA (e.g., the impact of inaccurate information). Only one framework explicitly considered a comparator. Technology specific domains were sporadically addressed.Conclusion:None of the evaluation frameworks could be used, unaltered, to guide the HTA of MMAs. To use these frameworks in HTA they would need to identify relevant comparators, improve assessments of harms and consider the ongoing effect of software updates on the safety and effectiveness of MMAs. Attention should also be paid to ethical issues, such as data privacy, and technology specific characteristics. Implications: Existing MMA evaluation frameworks are not suitable for use in HTA. Further research is needed before an MMA evaluation framework can be developed that will adequately inform policy makers.
Dual band- dual polarized planar inverted F-antenna for MBAN applications
Authors: Bhattacharjee Shankar , Midya Manas , Mitra Monojit , Bhadra Chaudhuri S.R. 
Published: September 2018

AbstractA planar inverted F-Antenna with the dual band-dual polarization property is presented for medical body area networks applications. The designed antenna covers the 2.45 GHz industrial, scientific and medical, 4 G long term evolution (2.5–2.69 GHz) bands for ON body communication and Wi-Fi and WLAN (3.5–3.6 GHz) bands for OFF body communication. At the lower band, an equivalent offset fed magnetic microstrip type dipole has been utilized that generate field parallel to the surface of the body for supporting ON body communication. The broadside radiation pattern has been realized using the slotted patch counterpart for supporting OFF body communication. This technique has resulted in a design of dual band dual mode property using a single radiator. The footprint of the antenna is only 0.35λg × 0.17λg × 0.08λg. Owing to its compactness, lightweight, and easy mountable property (due to foam substrate), the proposed antenna is found to be robust for MBAN applications. The maximum permissible transmitted power for the 1st band is 25.78 and 20.3 dBm for the 2nd one to maintain standard specific absorption rate limitations of 1.6 W/Kg. Experimental investigations over human body showed minimal deviations from the free space conditions which makes it a potential candidate for body-centric communications.
Recover recovery style from psychosis: a psychometric evaluation of the German version of the Recovery Style Questionnaire (RSQ)
Authors: Gruber M. , Rumpold T. , Schrank B. , Sibitz I. , Otzelberger B. , Jahn R. , Amering M. , Unger A. 
Published: September 2018

Abstract

Aims
The way an individual handles the experience of psychosis, the so-called ‘recovery style’, has been shown to substantially affect long-term outcomes. The Recovery Style Questionnaire (RSQ) measures this psychological dimension. The aim of this study was to provide a validation of the German version of the RSQ and to raise awareness for recovery-oriented approaches.

Methods
The RSQ was translated into German according to the guidelines of the WHO and patients were administered this questionnaire and measures of internalised stigma, psychotic symptoms, illness concept, empowerment, self-esteem and quality of life. Descriptive statistics were demonstrated to characterise the sample. Reliability was assessed in different forms: internal consistency, test–retest reliability and split-half reliability. Items were evaluated with descriptive data and item-total correlations. Convergent and discriminant validity were shown, and a confirmatory factor analysis was performed. In order to ameliorate the model, a post hoc model modification was done.

Results
The sample consisted of 138 patients diagnosed with schizophrenia spectrum disorders (mean age: 35.7 years; 53.6% men; mean duration of illness: 20.6 years) with a mean RSQ overall percentage of 66.12 (s.d. ± 17.43%), mainly representing the categories ‘mixed picture’ and ‘tends towards integration’. The reliability of the RSQ was acceptable with a Cronbach's α of 0.741 and a test–retest coefficient of 0.502. Item-total correlations were not acceptable for 27 of 39 items. Moderate evidence for convergent validity of the RSQ was found. Confirmatory factor analysis revealed that the 13-factor model with 39 items originally proposed was partially poorly replicated in the present sample (χ2 ratio to degrees of freedom (χ2/df) of 1.732, Comparative Fit Index (CFI) of 0.585, Normed Fit Index (NFI) of 0.414, Tucker–Lewis Index (TLI) of 0.508, root mean square error of approximation (RMSEA) of 0.095). The RSQ was modified based on item-total correlations and path coefficients of the single items. The confirmatory factor analysis of the resulting one-factor model with 11 items showed adequate fit to the data (χ2/df of 1.562, CFI of 0.936, NFI of 0.847, TLI of 0.910, RMSEA of 0.083) and demonstrated good model fit.

Conclusions
Despite partially insufficient psychometric data of the original RSQ, the concept of recovery style is beneficial to psychiatric research and clinical practice. The underlying idea is valuable, and the questionnaire needs further development. Therefore, a short version of the RSQ is proposed.
Generation of Lower L Shell Dayside Chorus by Energetic Electrons From the Plasma Sheet
Authors: He Yihua , Xiao Fuliang , Su Zhenpeng , Zheng Huinan , Yang Chang , Liu Si , Zhou Qinghua 
Published: September 2018

AbstractCurrently, the generation mechanism for the lower L shell dayside chorus has still remained an open question. Here we report two storm events: 6–7 March 2016 and 20–21 January 2016, when Van Allen Probes observed enhanced dayside chorus with lower and higher wave normal angles (the angles between the wave vector and the geomagnetic field) in the region of L = 3.5–6.3 and MLT = 5.6–13.5. Hot and energetic (∼ 1–100 keV) electrons displayed enhancements in fluxes and anisotropy when they were injected from the plasma sheet and drifted from midnight through dawn toward the dayside. Calculations of chorus local growth rates under different waves normal angles show that the upper cutoff and peak wave frequencies display similar patterns to the observations. Chorus growth rates maximize for the parallel propagation and drop with increasing wave normal angles. The current results confirm that the observed lower L shell dayside chorus can be excited by anisotropic electrons originating from the plasma sheet in drifting from the nightside to the dayside.