bluuebunny/crossref_metadata_2025_split huggingface dataset:
DAMPAK DEKRUITMEN, MUTASI, DAN PENGEMBANGAN ORGANISASI TERHADAP MOTIVASI KERJA KARYAWAN PT. PERKEBUNAN NUSANTARA IX (PERSERO) PG. REJOSARI MAGETAN
Authors: Suprihati Suprihati 
Published: August 2018

Tujuan Penelitian ini adalah untuk menganalisis pengaruh dekruitmen, mutasi, dan pengembangan organisasi terhadap motivasi kerja karyawan PT. Perkebunan Nusantara IX (Persero) PG. Rejosari, dan menganalisis faktor yang paling dominan dalam mempengaruhi motivasi kerja karyawan PT. Perkebunan Nusantara IX (Persero) PG. Rejosari, Magetan. Dalam dalam penelitian ini menggunakan satu model regresi logistik binary. Koefisien regresi logistic diketahui bahwa semua variabel independen berpengaruh signifikan terhadap variabel motivasi kerja karyawan. Menurut prediksi karyawan yang merasa memiliki motivasi rendah dengan kode nol (0) adalah 16 responden, sedangkan observasi keseluruhan sebanyak 19. Jadi ketepatan klasifikasi 84,2% (16/19), sedangkan prediksi karyawan yang merasa memiliki motivasi tinggi dengan kode satu (1) ada 48 responden, sedangkan hasil observasi keseluruhan sebanyak 50 jadi ketepatan klasifikasi 96% (48/50) atau secara keseluruhan ketepatan klasifikasi adalah 92,8% (92,8/100). Pada penelitian ini menghasilkan bahwa Variabel dekruitmen, mutasi, dan pengembangan organisasi mempunyai pengaruh yang positif dan signifikan terhadap motivasi kerja, yang ditunjukkan dengan nilai chi square Hosmer and Lemeshow Test sebesar 5,173 dan nilai sig Hosmer and Lemeshow test yang sebesar 0,739 dan variabel pengembangan organisasi memberikan sumbangan pengaruh yang paling besar terhadapmotivasi kerja dibandingkan dengan variabel dekruitmen dan mutasi, hal ini ditunjukkan dengan nilai koefisien beta sebesar 0,679 dan nilai ekspektasi B sebesar 1,972.Kata Kunci : Dekruitmen, Mutasi, Pengembangan Organisasi, Motivasi
PERENCANAAN PENGANGGARAN DAERAH
Authors: Ibrahim Ibrahim 
Published: August 2018

erencanaan dan penganggaran antara lain mengacu kepada Undang-undang Nomor 25 tahun 2004 tentang system pembangunan nasional, yang mengatur tahapan perencanaan dan Undang-Undang No 32 tahun 2004 tentang pemerintah daerah. tujuan perencanaan penganggaran adalah untuk membantu pemerintah mencapai tujuan, membantu menciptakan efisiensi dalam menyediakan barang dan jasa publik, memungkinkan pemerintah untuk memenuhi prioritas belanja, dan meningkatkan transparansi dan pertanggungjawaban pemerintah kepada DPRD/DPR dan masyarakat luas. Alur perencanaan dan penganggaran daerah kepada UU No. 25 tahun 2004 tentang system perencanaan pembangunan nasional yang mengatur alur perencanaan dan UU No. 32 Tahun 2004 tentang pemerintahan daerah yang mengatur kembali system perencanaan pembangunan daerah yang telah ditetapkan dalam Undang-undang No. 25 tahun 2004. Kata Kunci: perencanaan, penganggaran
ANALISIS PENGARUH KUALITAS PELAYANAN TERHADAP KEPUASAN PASIEN PADA RUMAH SAKIT UMUM DAERAH SUKOHARJO
Authors: Ma’ruf Muhammad Hasan 
Published: August 2018

Tujuan dari penelitian adalah untuk mengetahui pengaruh layanan dokter/perawat, ketersediaan fasilitas, layanan administrasi dan keuangan dengan kepuasan pasien yang berobat di RSUD Sukoharjo. Jenis penelitian yang digunakan adalah deskriptif kuantitatif. Sesuai dengan tujuan penelitian ini maka sampel yang digunakan adalah pasien yang pernah berobat di RSUD Sukoharjo. Metodologi yang digunakan adalah analisis statistik regresi linear berganda. Melalui penelitian ini diketahui terdapat hubungan yang positif dan signifikan antara pelayanan yang meliputi layanan dokter/perawat, layanan fasilitas, layanan administrasi dan keuangan dengan Kepuasan Pasien di RSUD Sukoharjo. Dari hasil ini RSUD Sukoharjo dapat menentukan strategi pengembangan layanan untuk mencapai tujuan Rumah Sakit.Kata Kunci : Layanan, Kepuasan Pasien, RSUD Sukoharjo
PENGARUH PEMAHAMAN, KESADARAN, KUALITAS PELAYANAN, DAN KETEGASAN SANKSI TERHADAP KEPATUHAN WAJIB PAJAK ORANG PRIBADI DI KPP PRATAMA SUKOHARJO
Authors: Subarkah Johny , Dewi Maya Widyana 
Published: August 2018

Tujuan dari penelitian ini adalah untuk menganalisis secara individu dan bersama-sama pengaruh pemahaman, kesadaran, kualitas pelayanan, dan ketegasan sanksi terhadap kepatuhan wajib pajak orang pribadi. Penelitian ini menggunakan pendekatan kuantitatif dengan melakukan survei lapangan. Populasiny adalah pembayar pajak individu yang terdaftar dan melakukan pembayaran pajak pribadi di KPP Pratama Sukoharjo, sampel 35 orang dengan teknik sampling quota sampling non probability sampling. Metode pengumpulan data menggunakan kuesioner dengan skala Likert 1-5 poin. Metode analisis data meliputi: uji instrumen penelitian, uji asumsi klasik, uji regresi linier berganda dan uji hipotesis. Hasil penelitian menunjukkan: Pemahaman wajib pajak berpengaruh positif dan tidak signifikan terhadap kepatuhan pajak individu pada KPP Sukoharjo. Kesadaran berpengaruh positif dan signifikan pada kepatuhan pajak individu pada KPP Sukoharjo. Kualitas layanan berpengaruh positif dan signifikan terhadap kepatuhan pajak di KPP Sukoharjo perorangan. Ketegasan sanksi positif dan signifikan berpengaruh terhadap kepatuhan pajak di KPP Sukoharjo perorangan. Pengertian, kesadaran, kualitas pelayanan dan ketegasan memberikan sanksi berpengaruh positif dan signifikan terhadap kepatuhan pajak di KPP Sukoharjo wajib pajak pribadi.Kata kunci : Pemahaman, Kesadaran, Kualitas Pelayanan, Ketegasan Sanksi, Kepatuhan Wajib Pajak Pribadi
Microalgas adheridas a raíces de Rhizophora mangle
Authors: Cuenca Zambrano Mayra , Duque Marín Richard , Solano Vera Yadira 
Published: August 2018

El trabajo tuvo por objetivo identificar diversas especies de microalgas adheridas a las raíces de Rhizophora mangle. Obteniéndose muestras de tres estaciones, mediante un raspado en la raíz del mangle, las muestras fueron preservadas en frascos de 250 ml. Para el reconocimiento de las especies se utilizó microscopio y claves de identificación. Obteniendo como resultado: Cianophyta el 10,75%; Chlorophyta el 6,1%; Crysophyta el 83,15%. El alto porcentaje de estas se debe a los niveles de nitrógeno en el medio acuático por lo que se recomienda análisis de calidad de agua.
De l’accession et de l’ouvrage dans le Code civil
Authors: Lesquins Jean-Louis 
Published: August 2018

Selon le Code civil français de 1804, « la propriété des biens s’acquiert et se transmet par succession, par donation entre vifs ou testamentaire et par l’effet des obligations » (art. 711). « La propriété s’acquiert également par accession ou incorporation et par prescription » (art. 712). La présente étude est consacrée à l’articulation de deux de ces modes d’acquisition : par droit d’accession et par l’effet des obligations (en particulier par l’effet du louage d’ouvrage). Une approche généalogique peut déboucher sur des questions de grande actualité et des perspectives d’évolution pour le contrat de travail, le contrat d’entreprise et le contrat de société.
Chemotherapy administration standards and guidelines: The development of a resource document
Authors: Eedes David J. , Bailey Belinda , Burger Henriette 
Published: August 2018

There are no nationally recognised guidelines for the handling and administration of chemotherapy in South Africa. The Independent Clinical Oncology Network’s Chemotherapy Administration Standards and Guidelines Resource Documentwas developed over 2 years and first introduced at a South African international oncology conference in 2017. A working group consisting of oncologists and oncology nurses was set up to address this deficiency. Pragmatic guidelines suitable to a wide range of local chemotherapy administration practices were developed using an iterative, multidisciplinary, collaborative process. The consensus was that these guidelines should be appropriate to the South African context. Safety, standard operational procedures, recommended professional competencies and training were central to the document. Guidelines for prescribing, storing, mixing, dispensing, administering and disposing of chemotherapy were included. Patient consent and involvement, patient and staff safety, recommended professional competencies, management of accidents and errors, error reporting and local legal requirements are dealt with in detail. The hope is that these guidelines will be used as a resource document for South African chemotherapy practices, both public and private. The document is supported by standard operating procedures and action steps. These were developed to promote the use of the guidelines and to support pragmatic quality assurance measures at practice level. These standards and guidelines will be regularly updated, based on needs identified and deficiencies noted.
Usefulness of Culturing the Periprosthetic Membrane or Neosynovium for the Diagnosis of Infection During Hip and Knee Revision Arthroplasty
Authors: Muñoz-Mahamud Ernesto , Molinas Ignacio , Lozano Luis , Bosch Jordi , Morata Laura , Combalia Andrés , Soriano Álex , Bori Guillem 
Published: August 2018

Introduction:
Identification of microorganisms is critical for correct management of an infected arthroplasty. Our hypothesis is that the culture yield depends on the location around the prosthesis from which samples are obtained.

Methods:
This prospective study included 298 revisions of the hip (123) and knee (175). We compared the yield of the intraoperative samples obtained, which included synovial fluid (two), neosynovium (two), and periprosthetic membrane (two).

Results:
Cultures were positive in 28 cases, in which 15 had the same diagnosis considering either the neosynovium or the membrane, and there were 3 cases in which the infection could have been diagnosed only by considering the combination of both. In all, there were 8 cases in which the infection might have been misdiagnosed unless considering a combination of both solid tissue samples (P = 0.004).

Conclusions:
The yields of the periprosthetic membrane and neosynovium do not differ significantly, and we recommend considering a combination of both.

Level of Evidence:
Diagnostic Level II
Existence and Uniqueness Fourth-order Differential Equations in Banach Space Having Fourier Type
Authors: Rachid Bahloul , Abdelouahed El Maroufi 
Published: August 2018

The aim of this work is to study the existence of a periodic solutions of differential equations $\frac{d^{4} }{ dt^{4} }x(t) = Ax(t) + f(t)$. Our approach is based on the M-boundedness of linear operators, Fourier type, $B^{s}_{p, q}$-multipliers and Besov spaces.
Design and Simulation of Temperature Sensor based on Long Period Grating in Liquid Filled Photonic Crystal Fiber
Authors: Boufenar R. , Bouamar M. , Hocini A. 
Published: August 2018

In this paper, a high sensitivity temperature sensor based on photonic crystal fiber long period grating (PCF-LPG) filled with ethanol is proposed and simulated by full vector finite element method. The relationship between the resonant wavelength shift, and the temperature was analyzed. The results show that the resonant wavelength of the ethanol filled photonic crystal fiber long period grating is proportional linearly with temperature and the highest sensitivity of was achieved, which is 90 times higher than that of conventional LPG temperature sensors.
The triheme cytochrome PpcF from Geobacter metallireducens exhibits distinct redox properties
Authors: Ferreira Marisa R. , Dantas Joana M. , Salgueiro Carlos A. 
Published: August 2018

Electrogenic bacteria, such as Geobacter, can couple the oxidation of carbon sources to the reduction of extracellular electron acceptors; such acceptors include toxic and radioactive metals, as well as electrode surfaces, making Geobacter a suitable candidate for applied use in bioremediation and bioenergy generation. Geobacter metallireducens is more promising in this regard than the better studied Geobacter sulfurreducens, as it has more efficient Fe (III) reduction rates and can convert nitrate to ammonia. The operon responsible for nitrate reductase activity in G. metallireducens includes the gene encoding the cytochrome PpcF, which was proposed to exchange electrons with nitrate reductase. In the present work, we perform a biochemical and a biophysical characterization of PpcF. Spectroscopic techniques, including circular dichroism (CD), UV‐visible, and nuclear magnetic resonance (NMR), revealed that the cytochrome is very stable (Tm > 85 °C), contains three low‐spin hemes, and is diamagnetic (S = 0) and paramagnetic (S = 1/2) in the reduced and oxidized states, respectively. The NMR chemical shifts of the heme substituents were assigned and used to determine the heme core architecture of PpcF. Compared to the PpcA‐family from G. sulfurreducens, the spatial disposition of the hemes is conserved, but the functional properties are clearly distinct. In fact, potentiometric titrations monitored by UV‐visible absorption reveal that the reduction potential values of PpcF are significantly less negative (−56 and −64 mV, versus the normal hydrogen electrode at pH 7.0 and 8.0, respectively). NMR redox titrations showed that the order of oxidation of the hemes is IV‐I‐III, a feature not observed for G. sulfurreducens. The different redox properties displayed by PpcF, including the small redox‐Bohr effect and low reduction potential value of heme IV, were structurally rationalized and attributed to the lower number of positively charged residues located in the vicinity of heme IV. Overall, the redox features of PpcF suggest that biotechnological applications of G. metallireducens may require less negative working functional redox windows than those using by G. sulfurreducens.
Tf2O‐Promoted Trifluoromethythiolation of Various Arenes Using NaSO2CF3
Authors: Liu Jie , Zhao Xiaochun , Jiang Lvqi , Yi Wenbin 
Published: August 2018

AbstractA sulfonic anhydride‐promoted direct trifluoromethylthiolation using NaSO2CF3 has been developed. The simple and practical strategy enabled the direct introduction of SCF3 moiety into unexplored arene scaffolds under reductant‐ and metal‐free condition at room temperature.magnified image
Sexual dimorphism in the ontogeny of second (2D) and fourth (4D) digit lengths, and digit ratio (2D:4D)
Authors: Manning John T. , Fink Bernhard 
Published: August 2018

AbstractObjectiveSex differences are often reported in digit lengths and digit ratio (2D:4D). However, the ontogeny of these sex differences and their interrelationships are less well known.MethodsWe considered sex differences in the lengths of the 2nd (2D) and 4th (4D) digit and 2D:4D in children aged 2 to 18 years (Sample I, n = 680) and adults aged 18 to 30 years (Sample II, n = 89,246). Digit length was determined by direct experimenter‐measurement (Sample I) and direct self‐measurement (Sample II). The data were tested with two‐factor ANOVA's (sex and year‐group).ResultsIn both samples, there were significant main effects of sex and year‐group, and a significant interaction effect on digit length. Digit length was positively related to age in both samples. Boys had longer digits than girls but only after 13 years. Men had longer digits than women and the dimorphism increased from 18 to 30 years. There were significant sex differences in 2D:4D (males < females), but no significant effect of age and no interaction effect of age and sex on 2D:4D in children or adults.ConclusionsBetween 2 and 30 years, the lengths and the sexual dimorphisms of 2D and 4D are dependent on age. In contrast, 2D:4D is not age‐dependent. We discuss our findings in the context of the ontogeny of digits and in the light of recent claims on the presence of static allometry in 2D and 4D lengths.
Tuning Gold Nanoparticles with Chelating Ligands for Highly Efficient Electrocatalytic CO2 Reduction
Authors: Cao Zhi , Zacate Samson B. , Sun Xiaodong , Liu Jinjia , Hale Elizabeth M. , Carson William P. , Tyndall Sam B. , Xu Jun , Liu Xingwu , Liu Xingchen , Song Chang , Luo Jheng‐hua , Cheng Mu‐Jeng , Wen Xiaodong , Liu Wei 
Published: August 2018

AbstractCapped chelating organic molecules are presented as a design principle for tuning heterogeneous nanoparticles for electrochemical catalysis. Gold nanoparticles (AuNPs) functionalized with a chelating tetradentate porphyrin ligand show a 110‐fold enhancement compared to the oleylamine‐coated AuNP in current density for electrochemical reduction of CO2 to CO in water at an overpotential of 340 mV with Faradaic efficiencies (FEs) of 93 %. These catalysts also show excellent stability without deactivation (<5 % productivity loss) within 72 hours of electrolysis. DFT calculation results further confirm the chelation effect in stabilizing molecule/NP interface and tailoring catalytic activity. This general approach is thus anticipated to be complementary to current NP catalyst design approaches.
Intermetalloide Cluster: Moleküle und Festkörper im Dialog
Authors: Mayer Kerstin , Weßing Jana , Fässler Thomas F. , Fischer Roland A. 
Published: August 2018

AbstractAtompräzise und ligandenstabilisierte metalloide Cluster haben sich als herausragende Modellsysteme für grundlegende Struktur‐ und Bindungssituationen in kompositionell verwandten Molekülen und Festkörperphasen erwiesen. Dieses faszinierende Forschungsfeld ist jedoch noch immer stark auf Systeme homometallischer und pseudo‐homometallischer verwandter d‐Block‐Metalle beschränkt. In diesem Aufsatz möchten wir unsere eigenen sowie die Leistungen anderer hervorheben, um die strukturelle und kompositionelle Vielfalt intermetallischer Phasen mit ungleichen d‐ und p‐Block‐Metallkombinationen auf molekularem Level darzustellen, im Besonderen anhand der Zintl‐ und Hume‐Rothery‐Phasen. Ziel ist es, die Kluft zwischen der heterometallischen molekularen Koordinationschemie und den Festkörperphasen zu überbrücken. Hierbei werden grundlegende synthetische Herangehensweisen sowie strukturelle und elektronische Eigenschaften solcher “molekularer Legierungen” angesprochen und ihre außergewöhnliche Position als Zwischenschritt auf dem Weg zu Nanomaterialien hervorgehoben.
Supramolekulare Metallopolymere: Von linearen Materialien zu infiniten Netzwerken
Authors: Bentz Kyle C. , Cohen Seth M. 
Published: August 2018

AbstractKoordinationspolymere (coordination polymers, CPs) und supramolekulare Metallopolymere (supramolecular metallopolymers, SMPs) sind seit Jahrzehnten Gegenstand ausgiebiger Forschung. Spektakuläre Fortschritte in beiden Feldern haben neue Verbindungen hervorgebracht, die an der Grenze zwischen diesen beiden organisch‐anorganischen Gebieten liegen. An dieser Schnittstelle wurden Materialien entwickelt auf Basis unterschiedlicher Konzepte wie molekularem Flechten, supramolekularen Clustern und Hybriden aus Metall‐organischen Gerüstverbindungen und Polymeren. Dieser Kurzaufsatz gewährt einen Einblick in die intellektuelle Entstehung sowie die Verbindungen zwischen verschiedenen supramolekularen Konstrukten und den Stand der Wissenschaft bezüglich neuer Materialien an dieser Schnittstelle.
Supramolecular Assemblies with Near‐Infrared Emission Mediated in Two Stages by Cucurbituril and Amphiphilic Calixarene for Lysosome‐Targeted Cell Imaging
Authors: Chen Xu‐Man , Chen Yong , Yu Qilin , Gu Bo‐Han , Liu Yu 
Published: August 2018

AbstractA two‐stage mediated near‐infrared (NIR) emissive supramolecular assembly for lysosome‐targeted cell imaging is presented. 4,4′‐Anthracene‐9,10‐diylbis(ethene‐2,1‐diyl))bis(1‐ethylpyridin‐1‐ium) bromide (ENDT) was synthesized as an organic dye with weak fluorescence emission at 625 nm. When ENDT complexes with cucurbit[8]uril (CB[8]), this binary supramolecular complex assembles into nanorods with a near‐infrared fluorescence emission (655 nm) and fluorescence enhancement as the first stage. Such supramolecular complexes interact with lower‐rim dodecyl‐modified sulfonatocalix[4]arene (SC4AD) to form nanoparticles for further fluorescence enhancement as the second stage. Furthermore, based on a co‐staining experiment with LysoTracker Blue, such nanoparticles can be applied in NIR lysosome‐targeted cell imaging.
A Carboxylate to Amide Substitution That Switches Protein Folds
Authors: Gianni Stefano , McCully Michelle E. , Malagrinò Francesca , Bonetti Daniela , De Simone Alfonso , Brunori Maurizio , Daggett Valerie 
Published: August 2018

AbstractMetamorphic proteins are biomolecules prone to adopting alternative conformations. Because of this feature, they represent ideal systems to investigate the general rules allowing primary structure to dictate protein topology. A comparative molecular dynamics study was performed on the denatured states of two proteins, sharing nearly identical amino‐acid sequences (88 %) but different topologies, namely an all‐α‐helical bundle protein named GA88 and an α+β‐protein named GB88. The analysis allowed successful design of and experimental validation of a site‐directed mutant that promotes, at least in part, the switch in folding from GB88 to GA88. The mutated position, in which a glutamic acid was replaced by a glutamine, does not make any intramolecular interactions in the native state of GA88, such that its stabilization can be explained by considering the effects on the denatured state. The results represent a direct demonstration of the role of the denatured state in sculpting native structure.
Stereospecific β‐l‐Rhamnopyranosylation through an SNi‐Type Mechanism by Using Organoboron Reagents
Authors: Nishi Nobuya , Sueoka Kazuhiro , Iijima Kiyoko , Sawa Ryuichi , Takahashi Daisuke , Toshima Kazunobu 
Published: August 2018

AbstractStereospecific β‐l‐rhamnopyranosylations were conducted using a 1,2‐anhydro‐l‐rhamnopyranose donor and mono‐ol or diol acceptors in the presence of a glycosyl‐acceptor‐derived borinic or boronic ester. Reactions proceeded smoothly to provide the corresponding β‐l‐rhamnopyranosides (β‐l‐Rhap) with complete stereoselectivity in moderate to high yields without any further additives under mild conditions. Mechanistic studies of the borinic ester mediated glycosylation using 13C kinetic isotope effect (KIE) measurements and DFT calculations were consistent with a concerted SNi mechanism with an exploded transition state. In addition, the present glycosylation method was applied successfully to the synthesis of a trisaccharide, α‐l‐Rhap‐(1,2)‐β‐l‐Rhap‐(1,4)‐Glcp, derived from Streptococcus pneumoniae serotypes 7B, 7C, and 7D.
Photo‐Organocatalytic Enantioselective Radical Cascade Reactions of Unactivated Olefins
Authors: Bonilla Pablo , Rey Yannick P. , Holden Catherine M. , Melchiorre Paolo 
Published: August 2018

AbstractRadical cascade processes are invaluable for their ability to rapidly construct complex chiral molecules from simple substrates. However, implementing catalytic asymmetric variants is difficult. Reported herein is a visible‐light‐mediated organocatalytic strategy that exploits the excited‐state reactivity of chiral iminium ions to trigger radical cascade reactions with high enantioselectivity. By combining two sequential radical‐based bond‐forming events, the method converts unactivated olefins and α,β‐unsaturated aldehydes into chiral adducts in a single step. The implementation of an asymmetric three‐component radical cascade further demonstrates the complexity‐generating power of this photochemical strategy.
Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework
Authors: Godfrey Harry G. W. , da Silva Ivan , Briggs Lydia , Carter Joseph H. , Morris Christopher G. , Savage Mathew , Easun Timothy L. , Manuel Pascal , Murray Claire A. , Tang Chiu C. , Frogley Mark D. , Cinque Gianfelice , Yang Sihai , Schröder Martin 
Published: August 2018

AbstractMFM‐300(Al) shows reversible uptake of NH3 (15.7 mmol g−1 at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm−3 at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro‐spectroscopy on ND3@MFM‐300(Al) confirms reversible H/D site exchange between the adsorbent and adsorbate, representing a new type of adsorption interaction.