bluuebunny/crossref_metadata_2025_split huggingface dataset:
The Politics of Religion in Sisworo Gautama Putra’s and Joko Anwar’s Pengabdi Setan
Authors: Sutandio Anton 
Published: June 2019

This research compares two films, the original Pengabdi Setan and its remake, in the context of politics of religion to show how the two films depict the issue of religion at two different eras based on the released years of the two films. The display of religion in the two films is viewed as an allegorical representation as well as critical responses to the socio-political situation of the two eras. Separated by almost four decades, Joko Anwar’s nostalgic remake and the original film subtly converse with each other, share distinctive similarities yet also polarized differences that underlie their endeavor to allegorically bring back and relive public memory of certain national trauma; that is repression during the New Order regime and marginalization of the minority in contemporary Indonesia. By focusing on the films’ cinematography and mise-en-scene, this research attempts to locate those allegorical moments within the depiction of religious practice that challenge, criticize or accentuate the dominant ideology of their respective eras.

Keywords: allegorical moment, religion, national trauma, politicization
A Universal Influenza Nanovaccine for “Mixing Vessel” Hosts Confers Potential Ability to Block Cross‐Species Transmission
Authors: Ding Peiyang , Jin Qianyue , Zhou Wen , Chai Yongxiao , Liu Xiao , Wang Yao , Chen Xinxin , Guo Junqing , Deng Ruiguang , Gao George F. , Zhang Gaiping 
Published: July 2019

AbstractInfluenza A virus (IAV), a deadly zoonotic pathogen, poses a tremendous threat and burden to global health systems. Pigs act as “mixing vessel” hosts to support and generate new pandemic viruses. Preventing the spread of IAV in pigs effectively can delay or even block cross‐species transmission. Universal vaccines based on the highly conserved ectodomain of influenza matrix protein 2 (M2e) have been widely reported, but have not been applied due to inadequate protection. Porcine circovirus type 2 (PCV2) causes immunosuppression and promotes swine influenza virus (SIV) infection. Here, M2e is inserted into capsid protein of PCV2 without burying the neutralizing epitopes and self‐assembles to form a bivalent nanovaccine. Inoculation with the nanovaccine induces robust M2e‐ and PCV2‐specific immune responses. The nanovaccine confers protection against lethal challenges of IAV from different species in mice, and significantly reduces SIV titers in pigs' respiratory tract and blocks SIV transmission. These results indicate that the nanovaccine is an economical and promising PCV2 and universal IAV bivalent vaccine, and it will synergistically and powerfully offer potential ability to block IAV cross‐species reassortment and transmission.
Phase Transformation Contributions to Heat Capacity and Impact on Thermal Diffusivity, Thermal Conductivity, and Thermoelectric Performance
Authors: Agne Matthias T. , Voorhees Peter W. , Snyder G. Jeffrey 
Published: July 2019

AbstractThe accurate characterization of thermal conductivity κ, particularly at high temperature, is of paramount importance to many materials, thermoelectrics in particular. The ease and access of thermal diffusivityDmeasurements allows for the calculation of κ when the volumetric heat capacity,ρcp, of the material is known. However, in the relation κ =ρcpD, there is some confusion as to what value ofcpshould be used in materials undergoing phase transformations. Herein, it is demonstrated that the Dulong–Petit estimate ofcpat high temperature is not appropriate for materials having phase transformations with kinetic timescales relevant to thermal transport. In these materials, there is an additional capacity to store heat in the material through the enthalpy of transformation ΔH. This can be described using a generalized model for the total heat capacity for a materialwhere φ is an order parameter that describes how much latent heat responds “instantly” to temperature changes. Here,Cpφis the intrinsic heat capacity (e.g., approximately the Dulong–Petit heat capacity at high temperature). It is shown experimentally in Zn4Sb3that the decrease inDthrough the phase transition at 250 K is fully accounted for by the increase in cp, while κ changes smoothly through the phase transition. Consequently, reports of κ dropping near phase transitions in widely studied materials such as PbTe and SnSe have likely overlooked the effects of excess heat capacity and overestimated the thermoelectric efficiency,zT.
Corrosion Motivated ROS Generation Helps Endow Titanium with Broad‐Spectrum Antibacterial Abilities
Authors: Wang Donghui , Li Qianwen , Qiu Jiajun , Zhang Xianming , Ge Naijian , Liu Xuanyong 
Published: July 2019

AbstractMaterials that spontaneously generate reactive oxygen species (ROS) possess various industrial applications, such as organocatalysis, wastewater, and waste gas government. Given that bacteria, especially the more resistant Gram‐negative (Gram‐) species, are sensitive to ROS, endowing biomaterials with ROS producing abilities may be a useful strategy to fight against bacteria. Herein a minocycline‐loaded Mg–Fe layered double hydroxides film is constructed on the surface of biomedical titanium. The prepared films possess excellent ROS generating capabilities driven by the corrosion process of titanium, which can continuously release hydroxyl radicals without external stimuli. Both Gram‐positive (Gram+) Staphylococcus aureus and (Gram‐) Escherichia coli cells can be killed by the constructed platform under the synergistic effect of the released minocycline and ROS. Besides, the in vitro cell culture assay reveals good cytocompatibility of the as‐prepared films.
Juvenile cystic adenomyosis: A case report and review of the literature
Authors: Deblaere Lieselot , Froyman Wouter , Van den Bosch Thierry , Van Rompuy Anne‐Sophie , Kaijser Jeroen , Deprest Jan , Timmerman Dirk 
Published: July 2019

AbstractThis report describes a case of a uterine cystic myometrial lesion in a 16‐year‐old adolescent girl presenting with pelvic pain and severe progressively worsening dysmenorrhoea. Patient’s symptoms, ultrasound and MRI were suggestive of juvenile cystic adenomyosis (JCA). Medical treatment and alcohol sclerotherapy had a moderate and transient effect. The symptoms rapidly recurred, and the lesion was successfully excised via laparoscopic surgery. The treatment of JCA depends on patient’s age, the symptoms’ severity and the cyst location. Although rare, juvenile cystic adenomyosis should be considered in young women with severe dysmenorrhoea.
Mechanically Initiated Bulk‐Scale Free‐Radical Polymerization
Authors: Wang Zhao , Ayarza Jorge , Esser‐Kahn Aaron P. 
Published: July 2019

AbstractMechanical initiation of polymerization offers the chance to generate polymers in new environments using an energy source with unique capabilities. Recently, a renewed interest in mechanically controlled polymerization has yielded many techniques for controlled radical polymerization by ultrasound. However, other types of polymerizations induced by mechanical activation are rare, especially for generating high‐molecular‐weight polymers. Herein is an example of using piezoelectric ZnO nanoparticles to generate free‐radical species that initiate chain‐growth polymerization and polymer crosslinking. The fast generation of high amounts of reactive radicals enable the formation of polymer/gel by ultrasound activation. This chemistry can be used to harness mechanical energy for constructive purposes in polymeric materials and for controlled polymerizations for bulk‐scale reactions.
The Energetic Significance of Metallophilic Interactions
Authors: Zheng Qingshu , Borsley Stefan , Nichol Gary S. , Duarte Fernanda , Cockroft Scott L. 
Published: July 2019

AbstractMetallophilic interactions are increasingly recognized as playing an important role in molecular assembly, catalysis, and bio‐imaging. However, present knowledge of these interactions is largely derived from solid‐state structures and gas‐phase computational studies rather than quantitative experimental measurements. Here, we have experimentally quantified the role of aurophilic (AuI⋅⋅⋅AuI), platinophilic (PtII⋅⋅⋅PtII), palladophilic (PdII⋅⋅⋅PdII), and nickelophilic (NiII⋅⋅⋅NiII) interactions in self‐association and ligand‐exchange processes. All of these metallophilic interactions were found to be too weak to be well‐expressed in several solvents. Computational energy decomposition analyses supported the experimental finding that metallophilic interactions are overall weak, meaning that favorable dispersion and orbital hybridization contributions from M⋅⋅⋅M binding are largely outcompeted by electrostatic or dispersion interactions involving ligand or solvent molecules. This combined experimental and computational study provides a general understanding of metallophilic interactions and indicates that great care must be taken to avoid over‐attributing the energetic significance of metallophilic interactions.
From a Binary to a Quaternary Cocrystal: An Unusual Supramolecular Synthon
Authors: Paul Mithun , Desiraju Gautam R. 
Published: July 2019

AbstractFormation of a stoichiometric quaternary cocrystal consisting of resorcinol (RES), tetramethylpyrazine (TMP), phenazine (PHE) and pyrene (PYR) is described. A closed tetrameric resorcinol‐heterocycle synthon, unusual in that it has two different linker bases rather than just one, is observed in this four‐component solid. The tetrameric synthon is formed by two RES molecules and the two pyridine bases TMP and PHE. The stoichiometric quaternary cocrystal grows in an epitaxial fashion on the surfaces of a RES.PHE binary cocrystal which is initially obtained from the mother liquor. By indexing the common crystal faces of the binary and quaternary cocrystals, and noting that no ternary solid is obtained, a plausible mechanism has been proposed for the formation of this rare supramolecular architecture.
The First Study on the Reactivity of Water Vapor in Metal–Organic Frameworks with Platinum Nanocrystals
Authors: Ogiwara Naoki , Kobayashi Hirokazu , Concepción Patricia , Rey Fernando , Kitagawa Hiroshi 
Published: July 2019

AbstractWe first studied the reactivity of H2O vapor in metal–organic frameworks (MOFs) with Pt nanocrystals (NCs) through the water–gas shift (WGS) reaction. A water‐stable MOF, UiO‐66, serves as a highly effective support material for the WGS reaction compared with ZrO2. The origin of the high catalytic performance was investigated using in situ IR spectroscopy. In addition, from a comparison of the catalytic activities of Pt on UiO‐66, where Pt NCs are located on the surface of UiO‐66 and Pt@UiO‐66, where Pt NCs are coated with UiO‐66, we found that the competitive effects of H2O condensation and diffusion in the UiO‐66 play important roles in the catalytic activity of Pt NCs. A thinner UiO‐66 coating further enhanced the WGS reaction activity of Pt NCs by minimizing the negative effect of slow H2O diffusion in UiO‐66.
Purely Organic Crystals Exhibit Bright Thermally Activated Delayed Fluorescence
Authors: Cai Xinyi , Qiao Zhenyang , Li Mengke , Wu Xiao , He Yanmei , Jiang Xiaofang , Cao Yong , Su Shi‐Jian 
Published: July 2019

AbstractThermally activated delayed fluorescent (TADF) materials generally suffer from severe concentration quenching. Efficient non‐doped TADF emitters are generally highly twisted aromatic amine‐based compounds with isolated chemical moieties. Herein we demonstrate that co‐facial packing and strong π–π intermolecular interactions give rise to bright TADF emissions in non‐doped film and crystalline states within the compound 2,4‐diphenyl‐6‐(thianthren‐1‐yl)‐1,3,5‐triazine (oTE‐DRZ). Quantum chemistry simulations indicate that a disperse outer orbital of sulfur atoms, a folded thianthrene plane (for a reduced donor–acceptor distance), and a triazine acceptor with n–π* character, generate a spatially conjugated transition with a small singlet–triplet splitting energy. In company with a highly emissive non‐doped film, the corresponding organic light‐emitting diode achieved a 20.6 % external quantum efficiency, verifying its potential for high‐performance optoelectronic applications. In a crystalline state, it was verified that intra‐ and intermolecular dual TADF assisted by a hidden room‐temperature phosphorescent state. This state could preserve the long‐lived excitons while suppressing non‐radiation, and it could serve as a “spring‐board” for cascade up‐conversion processes. The oTE‐DRZ crystal showed greenish‐blue emission with a very high photoluminescent quantum yield of approximately 87 %, which is the highest among all TADF crystals reported to date.
Ultraschallaktivierte Sensibilisatoren
Authors: Lin Xiahui , Song Jibin , Chen Xiaoyuan , Yang Huanghao 
Published: July 2019

AbstractDurch Licht ausgelöste Verfahren in der Krebstherapie sind üblicherweise durch ihre geringe Penetrationstiefe limitiert. Die Sonotheranostika, insbesondere die sonodynamische Therapie (SDT), die sich von der photodynamischen Therapie (PDT) unterscheidet und hoch penetrierende Schallwellen zur Aktivierung einer Klasse von schallresponsiven Materialien verwendet, die als Sonosensibilisatoren bezeichnet werden, hat in den letzten Jahren an erheblichem Interesse gewonnen. Der Effekt der SDT hängt eng mit den strukturellen und physikochemischen Eigenschaften der Sonosensibilisatoren zusammen, was die Entwicklung von neuen schallaktivierbaren Materialien als Sonosensibilisatoren für diverse biomedizinische Anwendungen erforderlich gemacht hat. Dieser Aufsatz enthält eine Zusammenfassung und Diskussion der neuartigen Typen von Sonosensibilisatoren, die in den letzten Jahren entwickelt wurden. Anwendungen von Sonosensibilisatoren mit vielfältigen Funktionen wie Bildgebung, Wirkstofftransport und die Kombination mit anderen Behandlungsmethoden sollten neue Strategien für die Krankheitstherapie zur Verfügung stellen.
Atomically Dispersed Semimetallic Selenium on Porous Carbon Membrane as an Electrode for Hydrazine Fuel Cells
Authors: Wang Tongzhou , Wang Qiang , Wang Yucheng , Da Yunli , Zhou Wu , Shao Yue , Li Debao , Zhan Sihui , Yuan Jiayin , Wang Hong 
Published: July 2019

AbstractElectrochemically functional porous membranes of low cost are appealing in various electrochemical devices used in modern environmental and energy technologies. Herein we describe a scalable strategy to construct electrochemically active, hierarchically porous carbon membranes containing atomically dispersed semi‐metallic Se, denoted SeNCM. The isolated Se atoms were stabilized by carbon atoms in the form of a hexatomic ring structure, in which the Se atoms were located at the edges of graphitic domains in SeNCM. This configuration is different from that of previously reported transition/noble metal single atom catalysts. The positively charged Se, enlarged graphitic layers, robust electrochemical nature of SeNCM endow them with excellent catalytic activity that is superior to state‐of‐the‐art commercial Pt/C catalyst. It also has long‐term operational stability for hydrazine oxidation reaction in practical hydrazine fuel cell.
ATP‐Mediated Transient Behavior of Stomatocyte Nanosystems
Authors: Che Hailong , Zhu Jianzhi , Song Shidong , Mason Alexander F. , Cao Shoupeng , Pijpers Imke A. B. , Abdelmohsen Loai K. E. A. , van Hest Jan C. M. 
Published: July 2019

AbstractIn nature, dynamic processes are ubiquitous and often characterized by adaptive, transient behavior. Herein, we present the development of a transient bowl‐shaped nanoreactor system, or stomatocyte, the properties of which are mediated by molecular interactions. In a stepwise fashion, we couple motility to a dynamic process, which is maintained by transient events; namely, binding and unbinding of adenosine triphosphate (ATP). The surface of the nanosystem is decorated with polylysine (PLL), and regulation is achieved by addition of ATP. The dynamic interaction between PLL and ATP leads to an increase in the hydrophobicity of the PLL–ATP complex and subsequently to a collapse of the polymer; this causes a narrowing of the opening of the stomatocytes. The presence of the apyrase, which hydrolyzes ATP, leads to a decrease of the ATP concentration, decomplexation of PLL, and reopening of the stomatocyte. The competition between ATP input and consumption gives rise to a transient state that is controlled by the out‐of‐equilibrium process.
Elucidating Molecule–Plasmon Interactions in Nanocavities with 2 nm Spatial Resolution and at the Single‐Molecule Level
Authors: Zhang Fan‐Li , Yi Jun , Peng Wei , Radjenovic Petar M. , Zhang Hua , Tian Zhong‐Qun , Li Jian‐Feng 
Published: July 2019

AbstractThe fundamental understanding of the subtle interactions between molecules and plasmons is of great significance for the development of plasmon‐enhanced spectroscopy (PES) techniques with ultrahigh sensitivity. However, this information has been elusive due to the complex mechanisms and difficulty in reliably constructing and precisely controlling interactions in well‐defined plasmonic systems. Herein, the interactions in plasmonic nanocavities of film‐coupled metallic nanocubes (NCs) are investigated. Through engineering the spacer layer, molecule–plasmon interactions were precisely controlled and resolved within 2 nm. Efficient energy exchange interactions between the NCs and the surface within the 1–2 nm range are demonstrated. Additionally, optical dressed molecular excited states with a huge Lamb shift of ≈7 meV at the single‐molecule (SM) level were observed. This work provides a basis for understanding the underlying molecule–plasmon interaction, paving the way for fully manipulating light–matter interactions at the nanoscale.
Meta-analysis of randomized clinical trials of early versus delayed cholecystectomy for mild gallstone pancreatitis
Authors: Moody N , Adiamah A , Yanni F , Gomez D 
Published: July 2019

Abstract

Background
Gallstones account for 30–50 per cent of all presentations of acute pancreatitis. While the management of acute pancreatitis is usually supportive, definitive treatment of gallstone pancreatitis is cholecystectomy. Guidelines from the British Society of Gastroenterology suggest definitive treatment on index admission or within 2 weeks of discharge, whereas joint recommendations from the International Association of Pancreatology and the American Pancreatic Association recommend definitive treatment on index admission. Evidence suggests that uptake of these guidelines is low.

Methods
Embase, MEDLINE and Cochrane databases were searched for RCTs investigating early versus delayed cholecystectomy in patients with a confirmed diagnosis of mild gallstone pancreatitis. The pooled synthesis was undertaken using a random-effects meta-analysis of the primary outcome of recurrent biliary complications causing hospital readmission. Secondary outcomes included intraoperative and postoperative complications, and total length of hospital stay (LOS). All analyses were performed using RevMan5 software.

Results
Five RCTs were identified, which included 629 patients (318 in the early cholecystectomy (EC) group and 311 in the delayed cholecystectomy (DC) group). Recurrent biliary events that required readmission were reduced in patients undergoing EC compared with the number in patients having DC (odds ratio (OR) 0·17, 95 per cent c.i. 0·09 to 0·33). There was no difference in the rate of intraoperative (OR 0·58, 0·17 to 1·92) or postoperative (OR 0·78, 0·38 to 1·62) complications.

Conclusion
EC following mild gallstone pancreatitis does not increase the risk of intraoperative or postoperative complications, but reduces the readmission rate for recurrent biliary complications.
Do board sustainability committees contribute to corporate environmental and social performance? The mediating role of corporate social responsibility strategy
Authors: Orazalin Nurlan 
Published: July 2019

AbstractThe purpose of this study is to investigate the impact of board sustainability committees on environmental and social performance and to examine the mediating effect of corporate social responsibility (CSR) strategy on the relationship between the presence of board sustainability committees and corporate sustainability performance. Using data of U.K. listed firms for the period of 2009–2016, the study employs panel regression analysis and bootstrapping techniques to test study hypotheses. The results suggest that the presence of a sustainability committee improves the effectiveness of CSR strategies. The results also indicate that firms with effective CSR strategies exhibit better environmental and social performance. Further, the empirical results show that the effectiveness of CSR strategy explains the positive relationship between board sustainability committees and corporate environmental and social performance, thus supporting the theoretical framework of the study. The findings of the study shed new light on this research direction and could be of interest to board members, managers, practitioners, investors, policy makers, and regulators that plan to promote sustainability practices and strategies needed for sustainable development.
A Reaction‐Induced Localization of Spin Density Enables Thermal C−H Bond Activation of Methane by Pristine FeC4+
Authors: Geng Caiyun , Li Jilai , Weiske Thomas , Schwarz Helmut 
Published: July 2019

AbstractThe reactivity of the cationic metal‐carbon cluster FeC4+ towards methane has been studied experimentally using Fourier‐transform ion cyclotron resonance mass spectrometry and computationally by high‐level quantum chemical calculations. At room temperature, FeC4H+ is formed as the main ionic product, and the experimental findings are substantiated by labeling experiments. According to extensive quantum chemical calculations, the C−H bond activation step proceeds through a radical‐based hydrogen‐atom transfer (HAT) mechanism. This finding is quite unexpected because the initial spin density at the terminal carbon atom of FeC4+, which serves as the hydrogen acceptor site, is low. However, in the course of forming an encounter complex, an electron from the doubly occupied sp‐orbital of the terminal carbon atom of FeC4+ migrates to the singly occupied π*‐orbital; the latter is delocalized over the entire carbon chain. Thus, a highly localized spin density is generated in situ at the terminal carbon atom. Consequently, homolytic C−H bond activation occurs without the obligation to pay a considerable energy penalty that is usually required for HAT involving closed‐shell acceptor sites. The mechanistic insights provided by this combined experimental/computational study extend the understanding of methane activation by transition‐metal carbides and add a new facet to the dizzying mechanistic landscape of hydrogen‐atom transfer.
Separation and determination of tetracycline hydrochloride in real water samples using binary small molecule alcohol‐salt aqueous two‐phase system coupled with high‐performance liquid chromatography
Authors: Guo Dong‐gang , Ni Liang , Wang Liang , Shao Li 
Published: July 2019

AbstractAn environmental and sensitive sample pretreatment method was established and combined with high‐performance liquid chromatography (HPLC) for the analysis of tetracycline hydrochloride (TC) in feed water and lake water. One element small molecule alcohol‐salt aqueous two‐phase system (ATPS) cannot effectively adjust the polarity of the system, but binary small molecule alcohol‐salt ATPS can adjust the polarity and improve the extraction efficiency of antibiotics. In this work, a binary ATPS based on ethanol +2‐propanol + (NH4)2SO4 system was formed and applied to the separation and purification of TC in real water samples. The influence factors on partition behaviors of TC were discussed, including the types and the concentration of phase salts, the volume ratio of alcohol, the pH value, extraction temperature, and the standing time. The response surface methodology was used to determine the best experimental conditions for multi‐factor experiments. Under this optimal condition, the extraction efficiency of TC reached 95.7%. This new method is considered to have significant application in the divorce of antibiotics.