bluuebunny/crossref_metadata_2025_split huggingface dataset:
High Entropy Oxide Duplex Yolk–Shell Structure with Isogenic Amorphous/Crystalline Heterophase as a Promising Anode Material for Lithium‐Ion Batteries
Authors: Zhang Chunyan , Su Mengfei , Luo Yana , Zhang Xinyu , Li Shengfa , Gao Feng , Lu Qingyi 
Published: November 2024

AbstractAchieving composition and structure regulation on high entropy materials is a big challenge but will give this kind of new materials a huge boost in energy storage. Herein, a novel high entropy oxide ((CrMnFeCoNi)3O4) duplex yolk–shell structure (DYSHEO) with isogenic amorphous/crystalline heterophase are designed and successfully prepared through a simple microthermal solvothermal reaction followed by mesothermal calcination. The microthermal solvothermal reaction results in high entropy precursor with duplex yolk–shell structure, while the mesothermal calcination (annealing temperature at 450 °C) realizes the precursor transformation to (CrMnFeCoNi)3O4 (DYSHEO‐450) with isogenic amorphous/crystalline heterophase structure. The high entropy effect, the duplex yolk–shell structure, and the isogenic amorphous/crystalline heterophase endow DYSHEO‐450 great advantages as lithium‐ion battery anode including reducing ion migration obstruction, accommodating volume expansion, and alleviating the stress. Accordingly, DYSHEO‐450 exhibits high capacities of 1721 mAh g−1@0.5 A g−1, and 1356 mAh g−1@1 A g−1 after 500 cycles with a capacity retention rate of 90.3%. It also shows excellent performances in practical application as anode of a coin‐type full cell. This work provides new ideas and directions for the structural regulation of high‐entropy materials.
Balancing Defects and Microcrystals in Carbon Anodes by Molecular Chemistry Method for Sodium‐Ion Batteries
Authors: Zhang Yong , Yang Qi , Zhang Yi , Lu Puda , Liu Ziqiang , Jiang Na , Qu Keqi , Ren Zhengbing , Tao Zui , Hou Yifei , Tang Yongchao , Wang Jianli , Qiu Jieshan 
Published: November 2024

AbstractCarbon materials with large capacity and low potential serve as promising anode materials for sodium‐ion batteries (SIBs). Carbon defects offer active sites for sodium storage but sacrifice reversibility, whereas carbon microcrystals improve conductivity but may suffer from low capacity. Herein, the balance between defects and microcrystals is realized by the molecular chemistry method of cross‐linking and defect repairing. Real‐time spectroscopic analyses reveal that the decomposition of tetrabromophthalic anhydride (TBPA) molecule induces the dehydrogenation of pitch to release small gas molecules to form pseudo‐closed pores, followed by the cross‐linking of C═O bonds in TBPA with the dehydrogenated pitch to form C─O─C bonds and thus suppress the excessive microcrystal growth. Meanwhile, the decomposition products of TBPA can also react with the dehydrogenated pitch to repair carbon defects. Thanks to the microstructure balance, the as‐synthesized carbon material exhibits a smoother ion mass transfer channel (d(002) = 0.386 nm, La = 4.56 nm) and a larger storage space (Vpseudo‐closed pore = 0.086 cm3 g−1) than the pitch carbon (PC, d(002) = 0.349 nm, La = 5.90 nm, Vpseudo‐closed pore = 0.041 cm3 g−1), increasing the capacity from 162.5 to 336.5 mAh g−1. This work sheds a chemical light on regulating carbon material microstructure for advanced SIBs.
Selective Laser Doping and Dedoping for Phase Engineering in Vanadium Dioxide Film
Authors: Ma He , Li Yuan , Hao Jianhua , Wu Yonghuang , Shi Run , Peng Ruixuan , Shan Linbo , Cai Yimao , Tang Kechao , Liu Kai , Zhang Xinping 
Published: November 2024

AbstractVanadium dioxide (VO2), renowned for its reversible metal‐to‐insulator transition (MIT), has been widely used in configurable photonic and electronic devices. Precisely tailoring the MIT of VO2 on micro‐/nano‐scale is crucial for miniaturized and integrated devices. However, existing tailoring techniques like scanning probe microscopy, despite their precision, fall short in efficiency and adaptability, particularly on complex or curved surfaces. Herein, this work achieves the local engineering of the phase of VO2 films in high efficiency by employing laser writing to assist in the hydrogen doping or dedoping process. The laser doping and laser dedoping technique is also highly flexible, enabling the fabrication of reconfigurable, non‐volatile, and multifunctional VO2 devices. This approach establishes a new paradigm for creating reconfigurable micro/nanophotonic and micro/nanoelectronic devices.
JAK Inhibitors: A Double‐Edged Sword in Immune‐Mediated Diseases Management
Authors: Bertin Luisa , Savarino Edoardo Vincenzo 
Published: November 2024

ABSTRACTJAK inhibitors are pivotal in treating immune‐mediated inflammatory diseases (IMIDs) like rheumatoid arthritis (RA) and inflammatory bowel disease. However, emerging safety concerns warrant careful evaluation. A recent analysis of the FDA Adverse Event Reporting System (FAERS) revealed that RA patients using JAK inhibitors face nearly double the risk of gastrointestinal perforations (GIPs) compared to those on biologics, particularly with concurrent steroid or NSAID use. Additionally, the FDA's ORAL Surveillance study linked tofacitinib with higher rates of cancer and cardiovascular events, prompting regulatory restrictions. These findings highlight the importance of balancing JAK inhibitors' therapeutic benefits with potential risks, emphasizing the need for patient‐centred risk assessment and vigilant monitoring to optimize outcomes.
Oxidative Stress Biomarkers and Metabolic Parameters in Healthy Holstein Dairy Cows and Cows With Left Displacement Abomasum During the Transitional Period
Authors: Mirzaei Ahmadreza , Hajimohammadi Ali , Nasrian Amirhossein , Nikzad Mohammad , Rowshan‐Ghasrodashti Abbas , Nazifi Saeed , Naeini Aboutorab Tabatabaei 
Published: November 2024

ABSTRACTBackgroundDuring the transitional period, dairy cows experience oxidative stress and are more susceptible to diseases, including left displacement of the abomasum (LDA).ObjectivesThis study aimed to compare oxidative stress biomarker levels in cows with LDA to those in healthy conditions and investigate the associations between predictive metabolites linked to LDA and oxidative stress biomarkers.MethodsIn this case–control study, 400 healthy multiparous Holstein cows were matched for lactation number, milk production and calving date. Blood samples were collected at four time points: 21 and 7 days before, as well as 7 and 21 days after parturition from all animals. During the observation period, seven cows diagnosed with LDA in the main population, and seven healthy cows were randomly selected as controls for the comparison of oxidative stress, liver enzymes and metabolic parameters. Analysis of blood parameters utilized repeated measures ANOVA, and the degree of relationship between oxidative stress biomarkers and other measured parameters was assessed using Pearson correlations.ResultsThe LDA group exhibited significantly higher levels of urea, blood urea nitrogen (BUN), gamma‐glutamyl transferase, glucose, cholesterol, triglyceride (TAG), β‐hydroxybutyric acid (BHBA), aspartate aminotransferase (AST), sorbitol dehydrogenase, serum amyloid A (SAA), chloride, sodium, potassium, total antioxidant capacity (TAC) and malondialdehyde (MDA) compared to the control cows (p < 0.05). Positive correlations were observed among BUN, glucose, TB, AST, SAA, BHBA, TAG and MDA. Conversely, these parameters displayed negative correlations with TAC. Negative correlations were found among chloride, sodium, potassium, calcium, phosphorus and MDA, whereas positive correlations were observed with TAC.ConclusionsThese findings highlight the elevated level of oxidative stress and compromised antioxidant defence in cows with LDA and the intricate interplay among oxidative stress, metabolic parameters and liver enzymes.
Inflammatory pseudotumour presenting as a cervical extradural mass in a 1‐year‐old Bernese Mountain dog
Authors: Castro Carnes Lucia , Gutierrez‐Quintana Rodrigo , Marchesi Francesco , Morris Joanna , Kaczmarska Adriana 
Published: November 2024

AbstractA 1‐year‐old, male, neutered Bernese Mountain dog presented with a 2‐week history of acute‐onset progressive signs of right C6–T2 myelopathy and neck pain. Magnetic resonance imaging of the cervical vertebral column revealed a right‐sided extradural mass at the level of the C6 vertebra causing severe spinal cord compression. A right C5–C7 modified dorsal laminectomy was performed to remove the mass, resulting in its complete excision, except for residual tissue attachments to the ligamentum flavum. Successful spinal cord decompression was achieved, as confirmed by postoperative magnetic resonance imaging. Histopathology and immunochemistry showed a proliferative lesion dominated by a mixture of spindle and histiocytic cells, with associated infiltrates of T‐lymphocytes, B‐lymphocytes and plasma cells suggestive of an inflammatory pseudotumour. Subsequently, the dog underwent a 2‐month course of prednisolone treatment and showed complete recovery. At the 2‐year follow‐up, the dog was neurologically normal.
Ecological and socio‐political conflicts in the Turga Hydroelectric Project: An examination through the lens of political ecology
Authors: Kar Surajit , Sundberg Trude , Mukherjee Subham 
Published: November 2024

AbstractThe present paper critically examines water‐assisted developmental projects and their associated conflicts through the lens of political ecology, with a particular focus on hydroelectric power generation in the Global South. These projects often catalyze localized socio‐cultural, political, and ecological tensions, especially in indigenous territories where human–nature relationships have evolved through colonial and postcolonial ecological transformations. Our approach conceptualizes political ecology to explore the multidimensional conflicts tied to such projects, using the Turga Pumped Storage Hydroelectric Project in the Purulia district of West Bengal, India, as a case study. This region exemplifies the socio‐ecological conflicts between state‐led hydroelectric initiatives and the local indigenous communities, providing critical insights into the broader dynamics of water‐based development in the Global South. The five primary areas of inquiry in this paper include (1) the environmental ramifications of the Turga Pumped Storage Hydroelectric Project on Purulia's landscapes, wildlife, and ecosystems; (2) the social consequences that have emerged, including displacement, resource access disparities, and challenges to local livelihoods; (3) the power dynamics that shape the decision‐making processes surrounding the project, shedding light on the role of government policies and corporate interests; (4) comparative analyses with similar hydroelectric projects globally, providing valuable insights into the uniqueness of the Purulia case; and (5) the policy implications and recommendations to ameliorate the conflicts and foster a more sustainable and equitable approach to hydroelectric development. This study highlights the critical role of political ecology in understanding human–nature conflicts and resource management. It emphasizes the need for an integrative approach that considers both technological and socio‐political aspects. The Turga Pumped Storage Project in Purulia offers broader insights into the global challenges of sustainable energy and climate change, underscoring the importance of inclusive and environmentally responsible energy production and resource management.
Systematic User Evaluation of a Second Device Based Cast-as-Intended Verifiability Approach
Authors: Hilt Tobias , Berens Benjamin , Truderung Tomasz , Udovychenko Margarita , Neumann Stephan , Volkamer Melanie 
Published: November 2024

AbstractEnd-to-end verifiable e-voting schemes enhance the verifiability of individual votes during the election process. Specifically, methods for cast-as-intended verifiability empower voters to confirm that their cast votes have not been manipulated by the voting client. There are mainly three approaches to implement cast-as-intended verifiability in remote e-voting systems: (1) return-code based, (2) challenge-based and (3) second-device-approach. To investigate the usability, perceived trustworthiness and manipulation effectiveness for the second-device-approach, we conducted a user study with 133 participants. The results are similar to those from related work investigating the other two approaches.
Global fit to the 2HDM with generic sources of flavour violation using GAMBIT
Authors: Athron Peter , Crivellin Andreas , Gonzalo Tomás E. , Iguro Syuhei , Sierra Cristian 
Published: November 2024

Abstract
We perform a global statistical analysis of the two-Higgs-doublet model with generic sources of flavour violation using GAMBIT. This is particularly interesting in light of deviations from the Standard Model predictions observed in $$ b\to c\tau \overline{\nu} $$
b
→
cτ

ν
¯

and b → sℓ+ℓ− transitions as well as the indications for a charged Higgs with a mass of 130 GeV in top quark decays. Including all relevant constraints from precision, flavour and collider observables, we find that it is possible to simultaneously explain both the charged and neutral current B anomalies. We study the impact of using different values for the W mass and the Standard Model prediction for the anomalous magnetic moment of the muon and provide predictions for observables that can probe our model in the future such as lepton flavour violation searches at Belle II and Higgs coupling strength measurements at the high-luminosity LHC.
Multiparametrische Magnetresonanztomographie der Brust
Authors: Prinz Daniela , Bartsch Silvester J. , Ehret Viktoria , Friske Joachim , Pinker Katja , Helbich Thomas H. 
Published: November 2024

Zusammenfassung

Hintergrund
Die Kombination unterschiedlicher Methoden in der Magnetresonanztomographie (MRT) wird als multiparametrische MRT (mpMRT) beschrieben und nimmt in der Brustkrebsdiagnostik einen großen Stellenwert ein. Derzeit inkludiert die mpMRT die kontrastmittelverstärkte und diffusionsgewichtete MRT. Für eine umfassendere Charakterisierung der Schlüsselprozesse der Krebsentstehung sind zusätzliche MRT-Methoden, welche funktionelle Vorgänge auf zellulärer und molekularer Ebene erfassen, notwendig. Im Rahmen von präklinischen Studien werden MRT-Methoden, welche eine kontrastmittelfreie Evaluierung der Schlüsselprozesse auf metabolischer und molekularer Ebene ermöglichen, für zukünftige klinische Anwendungen entwickelt.

Fragestellung
Wie sieht die mpMRT der Brust in Zukunft aus?

Material und Methoden
Systematische Literaturanalyse fokussiert auf präklinische Forschung in Bezug auf mpMRT sowie Entwicklung und Modifizierung von nichtinvasiven MRT-Methoden.

Ergebnisse
Einige vielversprechende MRT-Methoden für die Mammadiagnostik, die funktionelle als auch metabolische Fragen beantworten können, sind BOLD („blood oxygen level dependent“), IVIM („intravoxel incoherent motion“), DMI (Deuterium-MRT) und CEST („chemical exchange saturation transfer“). Eine Kombination, und somit ein multiparametrischer Ansatz, ermöglicht die nichtinvasive Differenzierung der Subtypen sowie die frühe Evaluierung des Therapieansprechens und ist somit entscheidend für den weiteren Verlauf der Krankheit.

Schlussfolgerung
Standardisierung der Quantifizierung sowie Verbesserung und Erweiterung der MRT-Methoden ermöglichen solch eine multiparametrische, funktionelle und metabolische Einschätzung des Tumors. Viele davon werden zunächst in der Präklinik entwickelt, bevor die Translation in die Klinik erfolgen kann.
Rewriting History in Integrable Stochastic Particle Systems
Authors: Petrov Leonid , Saenz Axel 
Published: November 2024

AbstractMany integrable stochastic particle systems in one space dimension (such as TASEP—Totally Asymmetric Simple Exclusion Process—and its q-deformation, the q-TASEP) remain integrable if we equip each particle with its own speed parameter. In this work, we present intertwining relations between Markov transition operators of particle systems which differ by a permutation of the speed parameters. These relations generalize our previous works (Petrov and Saenz in Probab Theory Relat Fields 182:481–530, 2022), (Petrov in SIGMA 17(021):34, 2021), but here we employ a novel approach based on the Yang-Baxter equation for the higher spin stochastic six vertex model. Our intertwiners are Markov transition operators, which leads to interesting probabilistic consequences. First, we obtain a new Lax-type differential equation for the Markov transition semigroups of homogeneous, continuous-time versions of our particle systems. Our Lax equation encodes the time evolution of multipoint observables of the q-TASEP and TASEP in a unified way, which may be of interest for the asymptotic analysis of multipoint observables of these systems. Second, we show that our intertwining relations lead to couplings between probability measures on trajectories of particle systems which differ by a permutation of the speed parameters. The conditional distribution for such a coupling is realized as a “rewriting history” random walk which randomly resamples the trajectory of a particle in a chamber determined by the trajectories of the neighboring particles. As a byproduct, we construct a new coupling for standard Poisson processes on the positive real half-line with different rates.
Impacts of Sea Level Rise on Danish Coastal Wetlands – a GIS-based Analysis
Authors: Canal-Vergés Paula , Frederiksen Lars , Egemose Sara , Ebbensgaard Torben , Laustsen Kristian , Flindt Mogens R. 
Published: November 2024

AbstractIntergovernmental Panel on Climate Change (IPCC) scenarios run by an ensemble of models developed by the Coupled Model Intercomparison Project (CMIP) projects an average sea level rise (SLRs) of 0.6 to 1.2 m for the low and high emission scenarios (SSP1-1.9, SSP5-8.5), during the next century (IPCC 2021). The coastal zone will experience an increase in the flooding of terrestrial habitats and the depth of marine productive areas, with potential negative consequences for these ecosystems. The coast in Denmark is highly modified due to anthropogenic uses. Dikes, dams, and other coastal infrastructure are widespread, causing a coastal squeeze that prevents natural coastal development and inland migration of coastlines. We performed a national-scale analysis on the impacts of mean sea level rise (MSLR) in 2070 and 2120, and a 1 in 10-year storm surge water level (10SS) in 2120 MSLR for the Danish coast. Our study shows extensive permanent flooding of coastal habitats (~14%), whereas only 1.6% of urban areas will be flooded. Finally, very large agricultural areas (~191,000 ha) will be frequently flooded by 10SS if no extra protective measures are planned. With the present coastal protection structures, key habitats will be affected by permanent flooding or coastal squeeze while even larger extents will be subjected to intermittent marine flooding. About 45% (199 km2) of all Danish coastal wetlands will be permanently flooded by 2120, while areas occupied by forest, lakes and freshwater wetlands will be more frequently flooded by marine water. This study highlights the importance of including coastal habitats as dynamic elements in climate adaptation plans. Conservation and restoration of key habitats such as coastal wetlands should be prioritized in management plans. If Denmark does not change its current priorities, it may face the complete loss of coastal wetlands habitat in the 22nd century.
Effect of inspiratory lung volume on bronchial and arterial dimensions and ratios on chest computed tomography in patients with chronic obstructive pulmonary disease
Authors: Chen Yuxin , Latisenko Rudolfs , Lynch David A. , Ciet Pierluigi , Charbonnier Jean-Paul , Tiddens Harm A. W. M. 
Published: November 2024

Abstract
Background
The assessment of bronchus–artery (BA) metrics on chest CT is important for detecting airway abnormalities. It is less clear how BA metrics are dependent on lung volume.

Methods
CTs were obtained from a COPDGene substudy investigating the impact of radiation dose on lung density. Patients with chronic obstructive pulmonary disease underwent a full-dose and a reduced-dose CT in the same imaging session. CTs were automatically analyzed by measuring diameters of the bronchial outer edge (Bout), bronchial inner wall (Bin), artery (A), and bronchial wall thickness (Bwt) from segmental (G0) and distal generations. BA ratios were computed: Bout/A, Bin/A, Bwt/A, and bronchial wall area/bronchial outer area (Bwa/Boa). The total lung volume of the CT (TLC-CT) was computed. Differences between the volumes between the two CTs were expressed as % of the highest TLC-CT (ΔTLC-CT%). For the BA metrics of each CT, we computed the median of measurements in G1–6. Mixed-effect models were used to investigate the influence of TLC-CT on BA metrics adjusted for dose protocol.

Results
One thousand three hundred nineteen patients with a mean (SD) age of 64.4 (8.7) years were included. Three hundred twenty-nine (124) BA pairs were analyzed per CT. No significant difference was found for TLC-CT in relation to dose (p = 0.17). A ΔTLC-CT% of >10% (found in 121, 9%) led to 0.03 and 0.05 decreases in Bout/A and Bin/A and 0.008 and 0.11 decrease in log (Bwt/A) and log (Bwa/Boa), and a 0.03 increase in Bin and 0.06, 0.12, and 0.04 decrease in Bout, log (Bwt), and log (A) (all p < 0.001).

Conclusions
Variations in TLC over 10% between time points significantly influence bronchial dimensions, affecting BA metrics. Standardizing volumes is recommended for sensitive tracking of airway disease changes over time.

Key Points
QuestionAre BA metrics dependent on total lung capacity (TLC), and if so, how?
FindingsTLC variations over 10% between time points significantly influence bronchial dimensions, affecting BA metrics. Variations below 10% between CT scans have little effect on BA metrics.
Clinical relevanceSmall lung volume differences between chest CTs have little impact on bronchus and artery metrics; it is imperative to standardize chest CT lung volumes to ensure precise diagnosis and monitoring of airway disease.