bluuebunny/crossref_metadata_2025_split huggingface dataset:
Two New Luminescent Metal–Organic Frameworks as Fluorescent Sensors of Nitrobenzene, Fe3+, and Cr2O72−
Authors: Xiong Bin‐Bin , Yue Tian‐Cai , Yao Xiao‐Yan , Wang Lu‐Lu , Wang Duo‐Zhi 
Published: November 2024

ABSTRACTTwo new luminescent metal–organic frameworks (MOFs), namely, [Zn2(HL)2]n (1) and {[Cd2(HL)2(H2O)2]⋅(H2O)0.5}n (2) [H3L = 5‐((4‐(1H‐1,2,4‐triazol‐1‐yl)benzyl)amino)isophthalic acid ligand], have been solvothermally synthesized and characterized. Single‐crystal x‐ray diffraction shows that 1 exhibits a 3D framework, whereas 2 features 2D network. Furthermore, the fluorescence studies demonstrated that 1 and 2 exhibited luminescent sensing activity for nitrobenzene (NB), Fe3+ ions, and Cr2O72− anions with high selectivity, high sensitivity, and low detection limit, the corresponding detection limits of 1 were 6.40 × 10−7, 1.26 × 10−7, and 1.44 × 10−7 M, respectively, and that of 2 were 2.42 × 10−6, 3.41 × 10−7, and 2.90 × 10−7 M, respectively. 1 and 2 exhibited excellent solvent, pH, and thermal stabilities. The results suggested that both 1 and 2 can be considered as potential fluorescent sensors of NB, Fe3+ ions, and Cr2O72− anions.
Partner of Choice: Australian National Interest in Infrastructure Development Programs in Papua New Guinea
Authors: Pennington Lucy 
Published: November 2024

ABSTRACTAustralian‐funded development programs aim to support the needs of partner governments but ultimately advance Australiaʼs national interests. This research unpacks this discourse on the major Australian‐funded infrastructure development programs in Papua New Guinea. It has two key findings: first, the way program reporting speaks about geopolitics is implicit, while partnerships are made explicit. DFAT speaks between the lines on geopolitics in aid. Yet, external media and the aid community outside government bureaucracy are quick to speculate about links between the two. Second, political “goals” are achieved everywhere, and not through DFAT effort alone. In this dataset, individual advisers are a key vector of this under‐reported influence. They often perform as political actors despite their position outside formal aid structures. Ultimately, actors are aware of the many aims of the aid program yet seem to make only a certain portion explicit and visible, just to ensure things work in practice.
Utilization of cardiopulmonary bypass at radical nephrectomy for renal cell carcinoma with tumour thrombus
Authors: Suk‐Ouichai Chalairat , Huang Mitchell M. , Neill Clayton , Mehta Christopher K. , Ross Ashley E. , Kundu Shilajit D. , Perry Kent T. , Pham Duc T. , Patel Hiten D. 
Published: November 2024

AbstractObjectivesThe objective of this study is to evaluate preoperative factors associated with cardiopulmonary bypass (CPB) utilization and outcomes for patients with renal cell carcinoma (RCC) and tumour thrombus (TT). Radical nephrectomy with thrombectomy is a standard treatment for patients with RCC and associated TT. Morbidity and mortality rates tend to correlate with aggressiveness of tumour and TT level.MethodsPatients undergoing radical nephrectomy with thrombectomy (2006–2023) were retrospectively identified. Inclusion criteria included RCC histology and preoperative imaging available for thrombus‐level categorization based on the Mayo Clinic grading system. Logistic regression assessed predictors for utilizing CPB, and Cox regression identified factors associated with survival.ResultsA total of 72 patients with RCC and associated TT were identified. The median age was 67 years. RCC‐related symptoms were present in 83%, and 28% had Levels 3 and 4 thrombi. Eleven patients (15.3%) had undergone neoadjuvant therapy, and 81% had clear‐cell RCC. CPB was utilized in eight (11.1%) cases. The median tumour size was 10.5 cm. Metastatic disease was greater in the CPB cohort (75% vs. 28%, p = 0.008). All cases performed on CPB were Levels 3 and 4 thrombi (100% vs. 19% in the non‐CPB group, p < 0.001). CPB cases had significantly longer operative time, and hospital stays and rates of Clavien ≥ 3 complications. On multivariate analysis, metastatic disease was a predictor of CPB utilization. Median survival was 74 and 25 months in the non‐CPB and CPB cohorts, respectively (p = 0.01). Pulmonary disease and metastatic disease with CPB utilization were significantly associated with worse survival on multivariate analysis.ConclusionsSurgical extirpation of kidney tumours with associated TT remains the standard of care among patients with locally advanced RCC. CPB can be utilized to increase the feasibility of resection for high‐level thrombi. Preoperative planning and cooperation among surgical teams are key given the perioperative morbidity and mortality.
Effectiveness of ultrasound‐guided vacuum‐assisted excision for treating benign breast lesions
Authors: Tan Xuanni , Xuhong Juncheng , Ai Xiang , Niu Qin , Liu Jing , Zhang Yi , Qi Xiaowei , Jiang Jun 
Published: November 2024

AbstractBackgroundUltrasound‑guided vacuum‐assisted excision (UGVAE) and breast biopsy are widely used for the diagnosis and treatment of both benign and suspicious breast lesions. In this retrospective study, we aimed to determine the safety of UGVAE for benign breast lesions and provide guidance for clinical practice.MethodsWe analyzed clinical and pathological data of female patients who had undergone UGVAE between January 2015 and December 2017 at our institution. All breast lesions were categorized according to the Breast Imaging Reporting and Data System (BI‐RADS) before performing UGVAE.ResultsIn our study cohort, UGVAE was used to resect 10,378 breast lesions from 5789 patients, and selected clinical and histopathological data were analyzed. The most common adverse events were postoperative bleeding (0.24%) and skin hypersensitivity (0.67%). The residual lesion rate was 2.27%. Fibroadenomas accounted for most of the benign lesions (7932 of 10,193; 77.82%). Breast cancer was diagnosed in 150 lesions from 128 patients. Multivariable binary logistic regression analyses showed that older age (odds ratio [OR] = 2.034, 95% confidence interval [CI]: 1.668–2.480, p < 0.001), higher BI‐RADS category (OR = 9.514, 95% CI: 6.790–13.332, p < 0.001), and larger legion size (OR = 1.048, 95% CI: 1.019–1.077, p = 0.001) were associated with an increased likelihood of breast cancer. Ninety‐six patients with breast cancer had undergone follow‐up treatment, achieving a 3‐year disease‐free survival rate of 97.2% and a 3‐year overall survival rate of 100%.ConclusionsUGVAE is a safe and effective means of removing benign breast lesions, causing minimal postoperative trauma and fewer complications compared with open surgery. Moreover, UGVAE had little impact on the follow‐up treatment and survival of patients diagnosed with breast cancer.
Enhancing Front‐End Security: Protecting User Data and Privacy in Web Applications
Authors: Tkachenko Oleksandr , Goncharov Vadim , Jatkiewicz Przemysław 
Published: November 2024

ABSTRACTConducting research on this subject remains relevant in light of the rapid development of technology and the emergence of new threats in cybersecurity, requiring constant updating of knowledge and protection methods. The purpose of the study is to identify effective front‐end security methods and technologies that help ensure the protection of user data and their privacy when using web applications or sites. A methodology that defines the steps and processes for effective front‐end security and user data protection is developed. The research identifies the primary security threats, including cross‐site scripting (XSS), cross‐site request forgery (CSRF), and SQL injections, and evaluates existing front‐end security methods such as Content Security Policy (CSP), HTTPS, authentication, and authorization mechanisms. The findings highlight the effectiveness of these measures in mitigating security risks, providing a clear assessment of their advantages and limitations. Key recommendations for developers include the integration of modern security protocols, regular updates, and comprehensive security training. This study offers practical insights to improve front‐end security and enhance user data protection in an evolving digital landscape.
Synthesis of MoS₂/Graphene Hetero‐Film Photocatalyst and Li‐Oxygen Battery Application
Authors: Can Çelt Ali , Çayirli Meltem , Can Özden Reşat , Lökçü Ersu , Anik Mustafa 
Published: November 2024

AbstractIn this study, bilayer MoS2 was synthesized on graphene film using chemical vapor deposition (CVD) to get a hetero‐film photo‐catalyst for the photo‐assisted charging of Li‐oxygen battery. The synthesized hetero‐film exhibited an optical band gap of 1.8 eV and a valence band edge potential of −1.23 VAg/AgCl (2.04 VLi+/Li). Fast‐responding photocurrents in the microampere range were achieved through on‐off cycles under visible‐light irradiation. The anodic nature of the photocurrents indicated that the synthesized semiconductor film was n‐type. Photo‐assisted testing demonstrated that the MoS2/graphene hetero‐film photo‐catalyst significantly reduced the charging potential and increased the discharging potential at a current density of 0.1 mA cm−2, thereby greatly enhancing the cyclic performance of the Li‐oxygen battery.
Synergetic monitoring of pressure and temperature stimulations in multisensory electronic skin based on time decoupling effect
Authors: Gao Zhiyi , Zhang Ye , Hu Zhenyu , Zhang Dongdong , Li Shengbin , Xiao Huiyun , Xiang Ziyin , Xu Dan , Zhang Haifeng , Wu Yuanzhao , Liu Yiwei , Shang Jie , Li Runwei 
Published: November 2024

AbstractThe progress from intelligent interactions requires electronic skin (E‐skin) to shift from single‐functional perception to multisensory capabilities. However, the intuitive and interference‐free reading of multiple sensory signals without involving complex algorithms is a critical challenge. Herein, we propose a flexible multisensory E‐skin by developing a highly homogeneous dispersion of BaTiO3 nanoparticles in polydimethylsiloxane dielectric layer. The E‐skin is sensitive to externally applied pressure as well as temperature and can distinguish dual synergetic stimuli by the time decoupling effect. The pressure and temperature perception was achieved in an individual device, which greatly reduced the structural complexity compared with multifunctional integrated devices. The sensitivity of E‐skin for pressure detection is as high as 0.0724 kPa−1 and the detection range reaches as wide as 15.625–10 MPa. The sensitivity to temperature detection is as high as −1.34°C−1 and the detection range reaches 20–200°C. More importantly, by equipping with a multilayer neural network, the evolution from tactile perception to advanced intelligent tactile cognition is demonstrated.
Precision Orthodontic Force Simulation Using Nodal Displacement‐Based Archwire Loading Approach
Authors: Ahmad Waheed , Liang Kanhui , Xiong Jing , Dai Juan , Cao Jun , Xia Zeyang 
Published: November 2024

ABSTRACTPrecision in force simulationis critical for forecasting tooth movement and optimizing orthodontic treatment strategies. While traditional techniques have provided valuable insights, there remains a need for improved methodologies that can seamlessly integrate with fixed orthodontic practices. This study aims to refine orthodontic force simulation techniques by integrating a nodal displacement approach within finite element analysis, specifically designed to enhance prediction accuracy in tooth movement and optimize orthodontic treatment planning. Three‐dimensional patient‐specific models of the Tooth, Periodontal Ligament, and Bone Complex (TPBC) of five volunteers were created, along with models of brackets and wires. The simulation involved an initial step of estimating node displacements to align the archwire with the brackets, followed by a subsequent step to attain the required tooth movement and determine the orthodontic force. Experimental validation of the simulation results was performed using an orthodontic force tester (OFT). Utilizing the nodal displacement approach, the simulation successfully positioned the archwire onto the brackets. When benchmarked against the OFT, 80% of the simulated force directions exhibited angular discrepancies of less than 5°. Additionally, the absolute differences in force magnitude reached 20.06 cN, and in moments, up to 71.76 cN mm. The relative differences were as high as 9.55% for force and 13.83% for moments. These findings represent an improvement of up to 10.45% in force accuracy and 8.87% in moment accuracy compared to median values reported in most recent literature. In this research, a nodal displacement methodology was employed to simulate orthodontic forces with precision across the dental arch. The results demonstrate the approache's potential to enhance the accuracy of force prediction in orthodontic treatment planning, thereby advancing our understanding of orthodontic biomechanics.
Influence of Process Conditions During Aqueous and Direct Recycling of NMC811 Cathodes
Authors: Nagler Felix , Kolb Leonhard , Christian Nino , Flegler Andreas , Hofmann Michael , Giffin Guinevere A. 
Published: November 2024

AbstractThis study investigated the impact of various process conditions on the aqueous, direct recycling of LiNi0.8Mn0.1Co0.1O2 (NMC811) cathodes. Three model systems were used. The first system assumes that the current collector delamination is performed in a dry environment without the use of water as a process medium. Consequently, the NMC811 is only exposed to water during classification, where no aluminum foil is present. The second model system assumes that the current collector delamination occurs in water. Therefore, the NMC811 is exposed to water in the presence of aluminum foil. Due to the pH increase caused by the Li+/H+ exchange reaction, the pH value surpasses the stability window of the aluminum‐oxide passivation layer (pH 4.5–8.5), resulting in the deposition of aluminum‐containing species on the NMC811 surface. The third model system is identical to the second, with the exception that H3PO4 is added. This causes the pH to decrease and prevents corrosion of the aluminum foil. The findings reveal that process conditions significantly affect the surface chemistry on NMC811, influencing electrochemical performance. Notably, aluminum‐containing species increase polarization. Heat treatment simulating regeneration led to cation mixing as surface species diffused into the NMC811 bulk structure, highlighting the need to control recycling process conditions.
A Mixed Method Systematic Review Into the Impact of ED Treatment in Autistic People and Those With High Autistic Traits
Authors: Nimbley Emy , Sharpe Helen , Maloney Ellen , Gillespie‐Smith Karri , Tchanturia Kate , Duffy Fiona 
Published: November 2024

ABSTRACTObjectiveOur understanding of the impact of eating disorders (ED) treatment in Autistic people remains elusive. Research has begun to explore ED treatment outcomes and experiences in this population, however current understandings are poorly integrated. The current review therefore sought to explore the impact of ED treatment on Autistic people and those with higher Autistic traits.MethodA convergent, segregated approach was used, independently evaluating quantitative then qualitative studies before integrating findings into a coherent narrative synthesis.ResultsAutistic people and people with higher Autistic traits report poorer experiences of treatment and may be at increased risk of inpatient admission and prolonged inpatient treatment, possibly explained by difficulties with treatment timeframes and a lack of autism‐informed support. Both groups reported similar improvements in ED symptoms and BMI. Higher rates of psychosocial difficulties pre‐and post‐treatment were reported in those with higher Autistic traits, and emotion‐focused interventions were felt to be particularly relevant to Autistic presentations of EDs. Concerns were reported as to how well aligned group‐based programs and cognitive‐based interventions are for Autistic individuals and those reporting higher Autistic traits.DiscussionFuture research in diagnosed autism samples is urgently needed to develop a more robust understanding of Autistic outcomes and experiences. Review findings demonstrate the need for increased understanding of ED presentations and the possible need for treatment adaptations, for Autistic people or those with higher Autistic traits.
Elevating the Field of Eating Disorders Through Scholarship and Thoughtfulness: Honoring the Legacy of Dr. Michael Strober
Authors: Bulik Cynthia M. , Barnhart Wesley R. , Feusner Jamie , Flatt Rachael E. , Munn‐Chernoff Melissa A. , Ortiz Shelby N. , Pisetsky Emily M. , Presskreischer Rachel , Thornton Laura M. , Yilmaz Zeynep 
Published: November 2024

ABSTRACTThis Virtual Issue of the International Journal of Eating Disorders honors the legacy of the late Dr. Michael Strober in the eating disorders and child psychiatry fields. Having served as Editor‐in‐Chief of the International Journal of Eating Disorders from 1983 to 2012, Dr. Strober elevated the quality of science conducted in the eating disorders field. His frank feedback and encouraging words inspired many junior researchers to sharpen their work and to think deeply about their results. An incisive thinker, eloquent writer, and gifted clinician, Dr. Strober was a role model for psychologists in clinical leadership positions and demonstrated that it is indeed possible to be a highly effective all‐rounder. In this issue, we present an annotated selection of Dr. Strober's publications in the journal over the past decades to illustrate the evolution of his thinking and the seeds of what have become major directions in the field, including fear conditioning and genetics. By presenting this collection of his work, we encourage all investigators to read broadly and deeply and to identify and acknowledge those incisive scholars who have built the foundation upon which our work today stands.
Noninvasive Methods Unveil the Trophic Transmission of the Tapeworm Ligula intestinalis in Gull‐Billed Terns
Authors: Capasso Sofía , Parejo Manuel , Reyes‐González José Manuel , Navedo Juan G. , Morán‐López Ricardo , Masero José A. , Gutiérrez Jorge S. 
Published: November 2024

ABSTRACTRecent developments in microscopic and molecular tools have allowed the implementation of new approaches for assessing parasitic infections in wildlife populations. This is particularly important for the noninvasive detection and quantification of endoparasites in live animals. Here, we combined copromicroscopic (Mini‐FLOTAC) and molecular (qPCR) techniques to detect the infection of the macroparasite Ligula intestinalis (Cestoda, Pseudophyllidea) in fresh droppings of Gull‐billed Terns Gelochelidon nilotica (Charadriiformes, Laridae) breeding in southwestern Spain. Additionally, we sequenced the cytochrome b gene in parasite isolates from Gull‐billed Terns (definitive host) and Common Bleak Alburnus alburnus (second intermediate host) sampled around tern colonies to explore potential genetic differences between the isolates. The qPCR test showed a higher prevalence (18%; in 13/73 samples) than Mini‐FLOTAC (9%; in 8/88 samples), indicating that qPCR was more sensitive for diagnostic purposes than fecal flotation alone. Although the agreement between both techniques was substantial (84.2%) mainly due to the large number of uninfected samples, only Mini‐FLOTAC allowed us to quantify parasite shedding. When combining techniques, the prevalence of infection did not differ between adults and chicks, suggesting frequent trophic transmission from parents to their offspring via food provisioning. Phylogenetic analyses identified four haplotypes in the isolates from Gull‐billed Terns and Bleak, all of which were placed within a European clade composed of tapeworms recovered exclusively from phylogenetically derived cyprinid fish. This, combined with the short lifespan of mature tapeworms, suggests that Gull‐billed Terns became infected after consuming infected fish around their breeding colonies rather than on their West African wintering grounds. Altogether, our results represent the first record of L. intestinalis in Gull‐billed Terns and the first molecular characterization of the parasite in the Iberian Peninsula. This integrative coprodiagnostic protocol can be applied to other host–parasite systems, allowing researchers to study helminth infections in wild populations using a noninvasive approach.
Borole Ring Expansion Reactions with Boron Azides: A Versatile Pathway to Borylated Azaborinines
Authors: Lindl Felix , Thiess Torsten , Goettel James T. , Dotzauer Simon , Ernst Moritz Johannes , Bélanger‐Chabot Guillaume , Braunschweig Holger 
Published: November 2024

AbstractThe reaction of boroles with organic azides is known to straightforwardly yield 1,2‐azaborinines, which have generated significant interest as benzene bioisosteres. We show that this powerful synthetic pattern extends to a variety of structurally and chemically diverse boron azides, including recently reported diborane(4) azides. This provides a general, powerful borylation method to expand the chemistry of 1,2‐azaborinines.
Research and Implementation of a Classification Method of Industrial Big Data for Security Management
Authors: Huang Haibo , Yan Min , Yan Qiang , Zhang Xiaofan 
Published: November 2024

ABSTRACTPurpose/SignificanceWith the extensive adoption of cloud computing, big data, artificial intelligence, the Internet of Things, and other novel information technologies in the industrial field, the data flow in industrial companies is rapidly increasing, leading to an explosion in the total volume of data. Ensuring effective data security has become a critical concern for both national and industrial entities.Method/ProcessTo tackle the challenges of classification management of industrial big data, this study proposed an Information Security Triad Assessment‐Support Vector Machine (AIC‐ASVM) model according to information security principles. Building on national policy requirements, FIPS 199 standards, and the ABC grading method, a comprehensive classification framework for industrial data, termed “two‐layer classification, three‐dimensional grading,” was developed. By integrating the concept of Data Protection Impact Assessment (DPIA) from the GDPR, the classification of large industrial data sets was accomplished using a Support Vector Machine (SVM) algorithm.Result/ConclusionSimulations conducted using MATLAB yielded a classification accuracy of 96.67%. Furthermore, comparisons with decision tree and random forest models demonstrated that AIC‐ASVM outperforms these alternatives, significantly improving the efficiency of big data classification and the quality of security management.