bluuebunny/crossref_metadata_2025_split huggingface dataset:
Accelerating Photogenerated Charge Kinetics via the Synergetic Utilization of 2D Semiconducting Structural Advantages and Noble‐Metal‐Free Schottky Junction Effect
Authors: She Xiaojie , Xu Hui , Yu Yahui , Li Li , Zhu Xingwang , Mo Zhao , Song Yanhua , Wu Jingjie , Yuan Shouqi , Li Huaming 
Published: February 2019

AbstractAlthough photocatalysis is one of the most promising technologies for environmental and energy issues, the irreconcilable contradiction between the absorption of the visible light and the strong redox capability of the photocatalyst and the low photocatalytic reaction kinetics result in the poor efficiency. Here, a composite photocatalyst is reported with high redox capability and accelerated reaction kinetics synergistically utilizing 2D semiconducting structural advantages and the noble‐metal‐free Schottky junction effect. The 2D structure can not only increase the bandgap of the photocatalyst but also improve the transfer and separation of the photogenerated charge carriers. Furthermore, the introduction of the noble‐metal‐free Schottky junction effect accelerates the photocatalytic reaction kinetics. The Schottky barrier can also prevent the photogenerated charges trapped by the electron acceptor from flowing back to the semiconductor, which can further boost the photocatalytic performance. The transfer process of the photogenerated charge carriers is also researched in detail by the comprehensive characterization methods, which enable the photocatalytic mechanism to be revealed.
Multifunctional van der Waals Broken‐Gap Heterojunction
Authors: Srivastava Pawan Kumar , Hassan Yasir , Gebredingle Yisehak , Jung Jaehyuck , Kang Byunggil , Yoo Won Jong , Singh Budhi , Lee Changgu 
Published: February 2019

AbstractThe finite energy band‐offset that appears between band structures of employed materials in a broken‐gap heterojunction exhibits several interesting phenomena. Here, by employing a black phosphorus (BP)/rhenium disulfide (ReS2) heterojunction, the tunability of the BP work function (Φ
BP) with variation in flake thickness is exploited in order to demonstrate that a BP‐based broken‐gap heterojunction can manifest diverse current‐transport characteristics such as gate tunable rectifying p–n junction diodes, Esaki diodes, backward‐rectifying diodes, and nonrectifying devices as a consequence of diverse band‐bending at the heterojunction. Diversity in band‐bending near heterojunction is attributed to change in the Fermi level difference (Δ) between BP and ReS2 sides as a consequence of Φ
BP modulation. No change in the current transport characteristics in several devices with fixed Δ also provides further evidence that current‐transport is substantially impacted by band‐bending at the heterojunction. Optoelectronic experiments on the Esaki diode and the p–n junction diode provide experimental evidence of band‐bending diversity. Additionally, the p+–n–p junction comprising BP (38 nm)/ReS2/BP(5.8 nm) demonstrates multifunctionality of binary and ternary inverters as well as exhibiting the behavior of a bipolar junction transistor with common‐emitter current gain up to 50.
Escape dynamics of a forced‐damped classical particle in an infinite‐range potential well
Authors: Naiger D. , Gendelman O. V. 
Published: February 2019

AbstractThe paper is devoted to analysis of the escape of periodically forced and damped particle from one‐dimensional potential well. The particle is initially at rest, and the forcing is switched on at a certain time instance. The present work is an extension of previous results, obtained in Hamiltonian setting, for much more realistic case with viscous damping. Assuming primary 1:1 resonance, one can consider the problem in terms of averaged transient dynamics. It turns out that, similar to the undamped case, the escape process can be reliably described in terms of topology of special trajectories on the resonant manifold. A theoretical prediction to the minimal force required for the escape as function of the excitation frequency for various damping coefficients is provided. In the explored frequency range, numeric simulations are in complete qualitative and reasonable quantitative agreement with the theoretical predictions except for small frequencies under 0.3. These discrepancies are related to quasistatic asymptotic limit of the considered model.
Pectobacterium and Dickeya species detected in vegetables in Northern Ireland
Authors: Zaczek-Moczydłowska Maja A. , Fleming Colin C. , Young Gillian K. , Campbell Katrina , O’Hanlon Richard 
Published: February 2019

Abstract
Destructive soft rot Pectobacteriaceae affect a number of vegetable crops and cause high economic loses in the field and storage. The diversity of Pectobacterium and Dickeya causing soft rot of vegetables in Northern Ireland is unknown. This study provides details of Pectobacterium and Dickeya spp. detected in vegetables from several locations in Northern Ireland in the years 2015–2017. Soft rot Pectobacteriaceae were identified based on DNA sequences. Thirty one strains were selected for further phylogenetic analysis based on the recA gene region. Results from the testing of over 3456 potato samples for plant health statutory purposes in years 2005–2017 demonstrated that Dickeya spp. is not the major pathogen causing soft rot or blackleg in Northern Ireland. The most predominant species causing soft rot of vegetables in Northern Ireland were Pectobacterium atrosepticum and Pectobacterium carotovorum subsp. carotovorum. Pectobacterium atrosepticum was also detected on hosts other than potato. Testing of bacteria isolated from carrots led to the detection of P. carotovorum and Dickeya sp. This is the first study to provide knowledge about Pectobacterium and Dickeya spp. diversity causing soft rot of vegetables in Northern Ireland confirmed by real-time PCR and DNA sequences. This is also the first report of the detection of D. aquatica from a source other than water.
Wearable technology-based metrics for predicting operator performance during cardiac catheterisation
Authors: Currie Jonathan , Bond Raymond R. , McCullagh Paul , Black Pauline , Finlay Dewar D. , Gallagher Stephen , Kearney Peter , Peace Aaron , Stoyanov Danail , Bicknell Colin D. , Leslie Stephen , Gallagher Anthony G. 
Published: February 2019

Abstract
Introduction
Unobtrusive metrics that can auto-assess performance during clinical procedures are of value. Three approaches to deriving wearable technology-based metrics are explored: (1) eye tracking, (2) psychophysiological measurements [e.g. electrodermal activity (EDA)] and (3) arm and hand movement via accelerometry. We also measure attentional capacity by tasking the operator with an additional task to track an unrelated object during the procedure.

Methods
Two aspects of performance are measured: (1) using eye gaze and psychophysiology metrics and (2) measuring attentional capacity via an additional unrelated task (to monitor a visual stimulus/playing cards). The aim was to identify metrics that can be used to automatically discriminate between levels of performance or at least between novices and experts. The study was conducted using two groups: (1) novice operators and (2) expert operators. Both groups made two attempts at a coronary angiography procedure using a full-physics virtual reality simulator. Participants wore eye tracking glasses and an E4 wearable wristband. Areas of interest were defined to track visual attention on display screens, including: (1) X-ray, (2) vital signs, (3) instruments and (4) the stimulus screen (for measuring attentional capacity).

Results
Experts provided greater dwell time (63% vs 42%, p = 0.03) and fixations (50% vs 34%, p = 0.04) on display screens. They also provided greater dwell time (11% vs 5%, p = 0.006) and fixations (9% vs 4%, p = 0.007) when selecting instruments. The experts’ performance for tracking the unrelated object during the visual stimulus task negatively correlated with total errors (r = − 0.95, p = 0.0009). Experts also had a higher standard deviation of EDA (2.52 µS vs 0.89 µS, p = 0.04).

Conclusions
Eye tracking metrics may help discriminate between a novice and expert operator, by showing that experts maintain greater visual attention on the display screens. In addition, the visual stimulus study shows that an unrelated task can measure attentional capacity.
Trial registration This work is registered through clinicaltrials.gov, a service of the U.S. National Health Institute, and is identified by the trial reference: NCT02928796.
Influence of the culture preparation and the addition of an adjunct culture on the ripening profiles of hard cheese
Authors: Cuffia Facundo , Bergamini Carina Viviana , Wolf Irma Verónica , Hynes Erica Ruth , Perotti María Cristina 
Published: February 2019

AbstractThe aim of this work was to evaluate the impact of two factors on the ripening profiles of hard cooked cheeses: (F1) the growth medium for the primary and adjunct cultures, constituted by autochthonous strains: Lactobacillus helveticus 209 (Lh209) and Lactobacillus paracasei 90 (Lp90), respectively, and (F2) the addition of L. paracasei Lp90 as adjunct culture. Four types of cheeses were made: W and M cheeses in which only Lh209 was added after its growth in whey and MRS, respectively; Wa and Ma cheeses in which both strains (Lh209 and Lp90) were added after their growth in whey and MRS, respectively. Physicochemical and microbial composition, proteolysis and profiles of organic acids and volatile compounds were analyzed. According to the methodology of the cultures preparation, W and Wa cheeses showed a higher level of secondary proteolysis and lower level of primary proteolysis (P < 0·05), lower content of citric and acetic acids and higher amount of propionic acid (P < 0·05), in comparison with M and Ma cheeses. The incorporation of Lp90 increased the secondary proteolysis (P < 0·05), decreased the citric acid (P < 0·05), and increased the propionic acid only when was added after their growth in whey (P < 0·05). Both factors significantly modified the percentages of the volatile compounds grouped in chemical families; in addition, for the half of the compounds detected, significant differences were found. Based on the obtained results, the use of Lp90 as an adjunct in hard cooked cheeses, and the preincubation of the cultures in whey are strategies to accelerate the cheese ripening and to enhance the production of some characteristic compounds of this type of cheeses, such as propan-2-one, hexan-2-one, 2- and 3-methyl butanal, heptan-2-ol, acetic and 3-methylbutanoic acids and 3-hydroxy butan-2-one.
Ecological plasticity of the European eel Anguilla anguilla in a tidal Atlantic lake system in Ireland
Authors: Arai Takaomi , Kotake Aya , Harrod Chris , Morrissey Michelle , McCarthy T. Kieran 
Published: February 2019

AbstractRecent studies have shown that anguillid eel populations in habitats spanning the marine–freshwater ecotone can display extreme plasticity in the range of catadromy expressed by individual fish. The apparent use of marine and freshwater habitats by the European eel Anguilla anguilla was examined by analysing the strontium (Sr) and calcium (Ca) concentrations in otoliths of eels collected from a tidal Atlantic lake system in Ireland. Variations of the Sr:Ca ratio in the otoliths indicated that a variety of environmental salinities had been experienced in the habitats that were occupied during the growth phase of these individuals in the tidal Atlantic lake system. The otolith microchemistry of these eels indicated that most of the eels had entered each salinity environment (freshwater (FW); brackish water (BW); marine-dominated water (MW) and full seawater (SW)) from fresh water to full seawater just after recruitment and had stayed in each environment until maturation without movement to other salinity environments. Only 2 of 93 (2%) eels had shifted their habitat once in their lives. This result suggests that each individual might have an environmental habitat preference, although each individual could move along a short (<2 km) salinity gradient.
School-age social behavior and pragmatic language ability in children with prenatal serotonin reuptake inhibitor exposure
Authors: Smearman Erica L. , Hendrix Cassandra L. , Winiarski Dominika A. , Johnson Katrina C. , Smith Alicia K. , Ousley Opal Y. , Stowe Zachary N. , Newport D. Jeffrey , Brennan Patricia A. 
Published: February 2019

AbstractStudies examining associations between fetal serotonin reuptake inhibitor (SRI) exposure and child autism spectrum disorder (ASD) diagnoses or delayed language remain mixed and rarely prospectively follow children or employ gold-standard assessments. We prospectively followed a cohort of mother–child dyads from pregnancy through early elementary school (N= 178), and obtained maternal and alternate–caregiver ratings of behaviors related to ASD (N= 137), as well as direct, gold-standard assessments of child ASD symptoms and pragmatic language among dyads who experienced prenatal depression and either took SRIs or were medication free during pregnancy (N= 44). Prenatal SRI exposure was related to maternal ratings of ASD-related behaviors (β = 0.24 95% confidence interval; CI [0.07, 0.48]), and, among boys, alternative caregiver ratings (males-only β = 0.28 95% CI [0.02, 0.55], females-only β = −0.21 95% CI [–0.63, 0.08]). However, results of our direct assessments suggest an association between SRI exposure and reduced pragmatic language scores (β = –0.27, 95% CI [–0.53, –0.01], but not ASD (Autism Diagnostic Observation Schedule β = 0.14 95% CI [–0.15, 0.41]; Social Responsiveness Scale β = 0.08 95% CI [–0.25, 0.40]). These discrepancies point to issues regarding how ASD is assessed, and the possibility that SRIs may be more strongly associated with language or other broader behaviors that coincide with ASD. Larger prospective studies that incorporate thorough, gold-standard assessments of ASD, language, and other ASD-related behaviors are needed.
Multidomain risk factors in early childhood and depression symptoms in 6-year-olds: A longitudinal pathway model
Authors: Hopkins Joyce , Gouze Karen R. , Lavigne John V. , Bryant Fred B. 
Published: February 2019

AbstractThis study examined effects of risk factors in multiple domains measured in preschool and kindergarten on age 6 depression symptoms, and on changes in symptom levels between ages 4 and 6. Two models were examined in a large, diverse (N= 796) community sample of children and parents. Risk variables included SES, stress, conflict, parental depression, parental hostility, support, scaffolding, child negative affect (NA), effortful control (EC), sensory regulation (SR), and attachment security. Model 1 included effects of risk factors at ages 4 and 5 on child depression symptoms at age 6. Model 2 also included depression symptoms at all three ages to examinechangesin these symptoms. Model 1 revealed that age 4 and 5 parental depression, NA, EC, and SR predicted age 6 child depression levels, Several age 4 variables had indirect pathways to age 6 depression via age 5 EC. Model 2 revealed that preschool depression was the only age 4 variable, and EC and SR were the only age 5 variables that significantly predicted increases in age 6 depression. These findings highlight the role of self-regulation in child depression and suggest that targeting self-regulation may be an effective prevention and intervention strategy.
Extending the positive bias in Williams syndrome: The influence of biographical information on attention allocation
Authors: Boulton Kelsie A. , Porter Melanie A. 
Published: February 2019

AbstractThere is evidence that individuals with Williams syndrome (WS) show an attention bias toward positive social-perceptual (happy) faces. Research has not yet considered whether this attention bias extends beyond social-perceptual stimuli to perceptually neutral stimuli that are paired with positive (trustworthy) biographical information. Fourteen participants with WS (mean age = 21 years, 1 month) learned to associate perceptually neutral faces with trustworthy (positive), neutral, or untrustworthy (negative) biographical information, before completing a dot-probe task where the same biographical faces were presented. The performance of the WS group was compared to two typically developing control groups, individually matched to the WS individuals on chronological age and mental age, respectively. No between-group bias toward untrustworthy characters was observed. The WS group displayed a selective attention bias toward trustworthy characters compared to both control groups (who did not show such a bias). Results support previous findings that indicate WS individuals show a preference for positive social-perceptual stimuli (happy faces) at the neurological, physiological, and attentional levels. The current findings extend this work to include a “top-down” positive bias. The implications of a positive bias that extends beyond social-perceptual stimuli (or “bottom-up” processes) in this syndrome are discussed.
An SOC Approach to Study the Solar Wind‐Magnetosphere Energy Coupling
Authors: Banerjee Adrija , Bej Amaresh , Chatterjee T. N. , Majumdar Abhijit 
Published: February 2019

AbstractSolar wind‐magnetosphere interaction and the injection of large quantity of plasma particles into the Earth's magnetosphere are the primary reasons behind geomagnetic storm, auroral effects, and, in general, all the fluctuations observed in the terrestrial magnetic field. In this paper, we analyzed the perturbed magnetosphere as a sandpile‐like cellular automata model based on the concept of self‐organized criticality and many‐body interactive system and proposed a solar wind‐magnetosphere energy coupling function in terms of interplanetary magnetic field BZ, the zth component of interplanetary magnetic field. The function determines the cusp width W depending on the intensity of (−BZ − BTh) where BTh is the threshold value. The model generates two output series, which are the numerical representation of the real‐time Dst index and AE index series, respectively. For our study, the range of years 1997–2007 of the 23rd solar cycle had been considered here. The threshold value BTh plays a significant role in the analysis and exhibits a proportional relationship with the yearly mean total number of sunspots for each year of the range 1997–2007 of the 23rd solar cycle. For each year, the two resultant output time series of the model display high‐correlation coefficients with the real‐time Dst and AE indexes, respectively, which denotes the acceptability of the proposed energy coupling function and its relation with the solar activities.
Increased Global Land Carbon Sink Due to Aerosol‐Induced Cooling
Authors: Zhang Yuan , Goll Daniel , Bastos Ana , Balkanski Yves , Boucher Olivier , Cescatti Alessandro , Collier Mark , Gasser Thomas , Ghattas Josefine , Li Laurent , Piao Shilong , Viovy Nicolas , Zhu Dan , Ciais Philippe 
Published: February 2019

AbstractAnthropogenic aerosols have contributed to historical climate change through their interactions with radiation and clouds. In turn, climate change due to aerosols has impacted the C cycle. Here we use a set of offline simulations made with the Organising Carbon and Hydrology In Dynamic Ecosystems (ORCHIDEE) land surface model driven by bias‐corrected climate fields from simulations of three Coupled Model Intercomparison Project Phase 5 (CMIP5) Earth system models (ESMs; IPSL‐CM5A‐LR, CSIRO‐Mk3.6.0, and GISS‐E2‐R) to quantify the climate‐related impacts of aerosols on land carbon fluxes during 1860–2005. We found that climate change from anthropogenic aerosols (CCAA) globally cooled the climate, and increased land carbon storage, or cumulative net biome production (NBP), by 11.6–41.8 PgC between 1860 and 2005. The increase in NBP from CCAA mainly occurs in the tropics and northern midlatitudes, primarily due to aerosol‐induced cooling. At high latitudes, cooling caused stronger decrease in gross primary production (GPP) than in total ecosystem respiration (TER), leading to lower NBP. At midlatitudes, cooling‐induced decrease in TER is stronger than that of GPP, resulting in NBP increase. At low latitudes, NBP was also enhanced due to the cooling‐induced GPP increase, but precipitation decline from CCAA may negate the effect of temperature. The three ESMs show large divergence in low‐latitude CCAA precipitation response to aerosols, which results in considerable uncertainties in regional estimations of CCAA effects on carbon fluxes. Our results suggest that better understanding and simulation of how anthropogenic aerosols affect precipitation in ESMs is required for a more accurate attribution of aerosol effects on the terrestrial carbon cycle.
Effect of Water on Fracture Mechanical Properties of Shales
Authors: Chen Xiaofeng , Eichhubl Peter , Olson Jon E. , Dewers Thomas A. 
Published: February 2019

AbstractRecognition of the potential for subcritical fracture growth of rocks is essential for the evaluation of long‐term stability of fluids trapped in geologic structures. In shales, subcritical fracture growth may control migration of hydrocarbons in source rock and unconventional reservoirs and of sequestered CO2 across top seals. Using the double torsion method, we investigated the mode‐I fracture mechanical properties of three shales of different composition, namely, Woodford Shale, Mancos Shale, and Marcellus Shale, under water‐saturated conditions, in ambient air, and in dry CO2 gas conditions to systematically investigate the effect of water on the fracture growth properties of shales. The clay‐rich (illite with minor kaolinite) Woodford and Mancos Shales demonstrate a strong water‐weakening effect despite their low smectite content, with the fracture toughness reduced by up to 54% and the subcritical fracture growth index by up to 77% under water‐saturated conditions compared to tests in ambient air. Carbonate‐rich Marcellus Shale, in contrast, displays negligible water‐weakening effects. The clay‐CO2 interaction is minor for the three shales. Specimens treated with a hydrophobic surface coating were also tested to limit water‐weakening effects to the fracture tip. Data from these tests reveal rate‐dependent stress intensity factor‐velocity curves for clay‐rich Woodford and Mancos Shales suggesting a competition between mechanical fracture growth and physicochemical water‐rock interactions. Our results suggest that subcritical failure by water‐enhanced subcritical fracture growth could significantly increase brittle failure in clay‐rich shales.