bluuebunny/crossref_metadata_2025_split huggingface dataset:
Conversion of Iron Ore into an Active Catalyst for the Oxygen Evolution Reaction
Authors: Sayeed Md Abu , Fernando Joseph F. S. , O'Mullane Anthony P. 
Published: May 2018

AbstractThe storage of electricity from intermittent renewable energy sources in the form of hydrogen via water electrolysis is an attractive approach to reducing CO2 levels, as well as powering future transportation with hydrogen fuel cells. Earth‐abundant transition metal oxide like materials are synthesized and extensively studied in research laboratories to replace expensive IrO2 and RuO2 anodes for the oxygen evolution half reaction. However, pristine materials mined from the earth's crust are yet to be explored for such an application. Here the electrocatalytic activity of iron ore is investigated and a novel approach is reported to significantly improve its catalytic properties via formation of a nickel hydroxide layer on the surface. This electrocatalyst achieves a current density of 10 mA cm−2 at a low overpotential of 280 mV and maintains its activity for extended periods of electrolysis under alkaline conditions. This simple process to convert an abundant commodity into a value‐added product should be of considerable interest.
An Ultrahigh Capacity Graphite/Li2S Battery with Holey‐Li2S Nanoarchitectures
Authors: Ye Fangmin , Noh Hyungjun , Lee Hongkyung , Kim Hee‐Tak 
Published: May 2018

AbstractThe pairing of high‐capacity Li2S cathode (1166 mAh g−1) and lithium‐free anode (LFA) provides an unparalleled potential in developing safe and energy‐dense next‐generation secondary batteries. However, the low utilization of the Li2S cathode and the lack of electrolytes compatible to both electrodes are impeding the development. Here, a novel graphite/Li2S battery system, which features a self‐assembled, holey‐Li2S nanoarchitecture and a stable solid electrolyte interface (SEI) on the graphite electrode, is reported. The holey structure on Li2S is beneficial in decomposing Li2S at the first charging process due to the enhanced Li ion extraction and transfer from the Li2S to the electrolyte. In addition, the concentrated dioxolane (DOL)‐rich electrolyte designed lowers the irreversible capacity loss for SEI formation. By using the combined strategies, the graphite/holey‐Li2S battery delivers an ultrahigh discharge capacity of 810 mAh g−1 at 0.1 C (based on the mass of Li2S) and of 714 mAh g−1 at 0.2 C. Moreover, it exhibits a reversible capacity of 300 mAh g−1 after a record lifecycle of 600 cycles at 1 C. These results suggest the great potential of the designed LFA/holey‐Li2S batteries for practical use.
Bifunctional Nitrogen and Cobalt Codoped Hollow Carbon for Electrochemical Syngas Production
Authors: Song Xiaokai , Zhang Hao , Yang Yuqi , Zhang Bin , Zuo Ming , Cao Xin , Sun Jianhua , Lin Chao , Li Xiaopeng , Jiang Zheng 
Published: May 2018

AbstractElectrochemical conversion of CO2 and H2O into syngas is an attractive route to utilize green electricity. A competitive system economy demands development of cost‐effective electrocatalyst with dual active sites for CO2 reduction reaction (CO2RR) and hydrogen evolution reaction (HER). Here, a single atom electrocatalyst derived from a metal–organic framework is proposed, in which Co single atoms and N functional groups function as atomic CO2RR and HER active sites, respectively. The synthesis method is based on pyrolysis of ZnO@ZIF (zeolitic imidazolate framework). The excess in situ Zn evaporation effectively prevents Co single atoms (≈3.4 wt%) from aggregation and maintains appropriate Co/N ratio. The as‐prepared electrocatalyst is featured with high graphitic degree of carbon support for rapid electron transport and sponge‐like thin carbon shells with hierarchical pore system for facilitating active site exposure and mass transport. Therefore, the electrocatalyst exhibits a nearly 100% Faradic efficiency and a high formation rate of ≈425 mmol g−1 h−1 at 1.0 V with the gaseous product ratio (CO/H2) approximating ideal 1/2. With the assistance of an extensive material characterization and density functional theory (DFT) calculations, it is identified that Co single atoms are uniformly coordinated in the form of Co–C2N2 moieties, and act as the major catalytic sites for CO2 reduction.
Fabrication of Sub‐Micrometer‐Thick Solid Electrolyte Membranes of β‐Li3PS4 via Tiled Assembly of Nanoscale, Plate‐Like Building Blocks
Authors: Hood Zachary D. , Wang Hui , Pandian Amaresh Samuthira , Peng Rui , Gilroy Kyle D. , Chi Miaofang , Liang Chengdu , Xia Younan 
Published: May 2018

AbstractSolid electrolytes represent a critical component in future batteries that provide higher energy and power densities than the current lithium‐ion batteries. The potential of using ultrathin films is among the best merits of solid electrolytes for considerably reducing the weight and volume of each battery unit, thereby significantly enhancing the energy density. However, it is challenging to fabricate ultrathin membranes of solid electrolytes using the conventional techniques. Here, a new strategy is reported for fabricating sub‐micrometer‐thick membranes of β‐Li3PS4 solid electrolytes via tiled assembly of shape‐controlled, nanoscale building blocks. This strategy relies on facile, low‐cost, solution‐based chemistry to create membranes with tunable thicknesses. The ultrathin membranes of β‐Li3PS4 show desirable ionic conductivity and necessary compatibility with metallic lithium anodes. The results of this study also highlight a viable strategy for creating ultrathin, dense solid electrolytes with high ionic conductivities for the next‐generation energy storage and conversion systems.
Aufwärtskonvertierende NaYF4:Yb,Er/NaYF4‐Kern/Schale‐Nanokristalle mit hoher Lumineszenzquantenausbeute
Authors: Homann Christian , Krukewitt Lisa , Frenzel Florian , Grauel Bettina , Würth Christian , Resch‐Genger Ute , Haase Markus 
Published: May 2018

AbstractEine modifizierte Syntheseroute auf der Basis wasserfreier Seltenerdacetate wurde zur Synthese aufwärtskonvertierender Kern/Schale‐Nanokristalle mit mittleren Größen zwischen 15 bis 45 nm eingesetzt. Die nahezu monodispersen Partikel bestehen aus einem NaYF4:Yb,Er‐Kern, dotiert mit 18 % Yb3+ und 2 % Er3+, und einer inerten Schale aus NaYF4, wobei die Dicke der Schale dem jeweiligen Radius des Kernpartikels entspricht. Absolutmessungen der Photolumineszenz‐Quantenausbeuten bei verschiedenen Anregungsleistungsdichten zeigen, dass die Quantenausbeuten von 45 nm Kern/Schale‐Partikeln schon fast an die Quantenausbeute des mikrokristallinen aufwärtskonvertierenden Leuchtstoffs heranreichen. Kleinere Kern/Schale‐Partikel, die nach der gleichen Methode hergestellt wurden, zeigen nur eine moderate Abnahme der Quantenausbeute. Beispielsweise ist die Quantenausbeute von 15 nm großen Kern/Schale‐Partikeln bei hohen Leistungsdichten (100 W cm−2) nur um einen Faktor drei kleiner als die des mikrokristallinen Leuchtstoffpulvers und um ungefähr einen Faktor 10 kleiner bei niedrigen Leistungsdichten (1 W cm−2).
Two Amphoteric Silver Carbene Clusters
Authors: Tskhovrebov Alexander G. , Goddard Richard , Fürstner Alois 
Published: May 2018

AbstractTwo highly labile silver carbene cluster complexes are described, which are unique in that they mark the transition point at which the carbene center transmutes from a fairly common NHC‐like nucleophilic behavior to an electrophilic character befitting reactive silver carbene intermediates of relevance in various catalytic transformations. This amphoteric character is the distinguishing attribute of a μ‐bridged donor/donor carbene entity that connects two silver atoms of triangular or tetrahedral metallic core units.
Nondestructive measurement of layer thickness in water‐assisted coinjection‐molded product by ultrasonic technology
Authors: Xia Neng , Zhao Peng , Kuang Tangqing , Zhao Yao , Zhang Jianfeng , Fu Jianzhong 
Published: May 2018

ABSTRACTLayer thickness is an important factor in judging the quality of a water‐assisted coinjection molding (WACIM) part. Here, a novel nondestructive method for measuring layer thickness via ultrasonic technology is proposed. The reflected signals from the interface of a WACIM part were measured by an immersed pulse‐echo method and calculated using a transfer function of the medium. Two objective functions were employed to describe the nonsimilarity between the measured signals and the calculated signals. By solving a multiobjective optimization problem, the optimum parameter was obtained and used to calculate the thickness of each layer in a WACIM part. The proposed method was employed to measure the layer thickness of WACIM specimens with different cross sections along the flow direction. Experimental results showed that the proposed method can correctly measure the variation in layer thickness of each layer of a WACIM part. The proposed method has broad application prospects in nondestructively measuring the layer thickness of polymeric parts. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46540.
Crystallization kinetics, morphology, and hydrolytic degradation of novel bio‐based poly(lactic acid)/crystalline silk nano‐discs nanobiocomposites
Authors: Patwa Rahul , Kumar Amit , Katiyar Vimal 
Published: May 2018

ABSTRACTIn this work, novel biodegradable crystalline silk nano‐discs (CSNs) having a disc‐like morphology have been utilized for fabrication of poly(lactic acid) (PLA) nanocomposites by melt‐extrusion. The main focus is to investigate the effect of CSN on isothermal melt crystallization kinetics, spherulitic growth rates, morphology, and hydrolytic degradation of PLA. Spherulitic morphology and growth rates are examined over a wide range of crystallization temperatures (90–120 °C). With incorporation of CSN, the isothermal crystallization kinetics of PLA/CSN increases, however, the crystallization mechanism remains unaltered. The apparent activation energy and surface energy barrier for crystallization process decreases upon addition of CSNs. At lower isothermal crystallization temperatures (Tc) viz. (90–100 °C), reduced growth rates of PLA spherulites is observed. Both PLA and PLA/CSN exhibit highest crystallization rates at around ∼107 °C. The hydrolytic degradation rates calculated from molecular weight reduction shows that PLA/CSN nanocomposites' degradation rates are lower as compared to PLA in acidic, neutral, and alkaline media at pH = 2, 7, and 12, respectively, due to hydrophobic nature of CSN. Scanning electron microscopy study demonstrated the surface erosion mechanism of hydrolytic degradation of PLA and PLA/CSN nanocomposites. This work provides valuable insight for the application and reclamation of PLA/CSN bionanocomposites in moist and wet working environments. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46590.
PANI/PPY blend thin films electrodeposited for use in EGFET sensors
Authors: Mello Hugo José Nogueira Pedroza Dias , Mulato Marcelo 
Published: May 2018

ABSTRACTGalvanostatic electrodeposited thin films of polyaniline (PANI)/polypyrrole (PPY) blend were tested as chemical sensors and evaluated according to the relative monomer concentration in polymerization solution aiming to obtain a reliable reference field‐effect transistor able to be used as contrast sensing film. The blend material presented properties that can be controlled by the polymerization process. The films were produced using aniline (0.25 M) and pyrrole (0.25 M) mixed in five different proportions (90/10, 70/30, 50/50, 30/70, 10/90) with HCl (1.0 M) in an aqueous solution. The current density was 1 mA/cm2 for 300 s. The films were analyzed by their chronopotentiometric curves, thickness, reflectance spectroscopy, optical color parameters, and surface morphology. The characteristics and properties analyzed were correlated to the relative monomer concentration in the polymerization solution. The polymerization of PANI is favorable in aqueous acid solution compared to PPY, which resulted in thin films with properties varying from PANI down to PPY. The blend films presented controllable sensitivity when applied as sensing stage in field‐effect transistor devices as function of the relative monomer concentration. The sensitivity varied from 57 ± 1 mV/pH for the PANI sample, down to 25 ± 1 mV/pH for the PPY sample, presenting an exponential behavior. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46625.
Improvement of Lotus japonicus hairy root induction and development of a mycorrhizal symbiosis system
Authors: Xu Yunjian , Liu Fang , Han Guomin , Wang Wei , Zhu Suwen , Li Xiaoyu 
Published: May 2018

Premise of the StudyWe describe a highly efficient in vitro Lotus japonicus hairy root transformation system that is useful for the investigation of mycorrhizal symbiosis.Methods and ResultsThe Agrobacterium rhizogenes–mediated transformation method was improved based on the binary plasmid (pCAMBIA1304) harboring green fluorescent protein and β‐glucuronidase genes for rapid detection. Transgenic hairy roots were grown within 13 days. These in vitro–cultured hairy roots can be inoculated with Rhizophagus irregularis, thus facilitating the investigation of the symbiosis between L. japonicus and arbuscular mycorrhizal fungi.ConclusionsCompared with existing techniques, our protocol provides a simple and efficient A. rhizogenes–mediated transformation system for L. japonicus. The rapid induction of hairy roots can shorten the experimental time by at least one week.
Risk Factors and Biomarkers for the Occurrence of Uveitis in Juvenile Idiopathic Arthritis
Authors: Tappeiner Christoph , Klotsche Jens , Sengler Claudia , Niewerth Martina , Liedmann Ina , Walscheid Karoline , Lavric Miha , Foell Dirk , Minden Kirsten , Heiligenhaus Arnd 
Published: May 2018

ObjectiveTo analyze the prognostic value of demographic, clinical, and therapeutic factors and laboratory biomarkers and to assess their role in predicting uveitis occurrence in patients with juvenile idiopathic arthritis (JIA).MethodsPatients with JIA were enrolled within the first year after JIA diagnosis. Demographic and clinical parameters were documented. Serum samples were collected at study enrollment, at 3‐month follow‐up visits within the first year, and then every 6 months. A multivariable Cox regression analysis was performed to evaluate the impact of demographic, clinical, laboratory, and therapeutic parameters on uveitis onset.ResultsWe included 954 JIA patients (67.2% female, 54.2% antinuclear antibody [ANA] positive, mean ± SD age at onset 7.1 ± 4.6 years). Uveitis occurred in 133 patients (observation period 44.5 months). Young age at JIA onset and ANA positivity were significantly associated with the onset of uveitis (both P < 0.001). Treatment of arthritis with methotrexate alone (hazard ratio [HR] 0.18 [95% confidence interval (95% CI) 0.12–0.29], P < 0.001) or combined with etanercept (HR 0.10 [95% CI 0.04–0.23], P < 0.001) or adalimumab (HR 0.09 [95% CI 0.01–0.61], P = 0.014) reduced the risk of uveitis onset and the occurrence of uveitis‐related complications. Predictors of uveitis onset included elevated erythrocyte sedimentation rate at baseline (HR 2.36 [95% CI 1.38–4.02], P = 0.002) and continuing moderate or high disease activity during follow‐up as measured by the 10‐joint clinical Juvenile Arthritis Disease Activity Score (HR 4.30 [95% CI 2.51–7.37], P < 0.001). Additionally, S100A12 levels ≥250 ng/ml at baseline were significantly associated with the risk of uveitis (HR 2.10 [95% CI 1.15–3.85], P = 0.016).ConclusionApart from demographic risk factors and treatment modalities, JIA disease activity scores and laboratory biomarkers could be used to better define the group of JIA patients at high risk of uveitis onset.
Functional Characterization of the Osteoarthritis Genetic Risk Residing at ALDH1A2 Identifies rs12915901 as a Key Target Variant
Authors: Shepherd Colin , Zhu Dongxing , Skelton Andrew J. , Combe Jennifer , Threadgold Harrison , Zhu Linyi , Vincent Tonia L. , Stuart Paul , Reynard Louise N. , Loughlin John 
Published: May 2018

ObjectiveTo identify the functional single‐nucleotide polymorphisms (SNPs) and mechanisms conferring increased risk of hand osteoarthritis (OA) at the ALDH1A2 locus, which is a retinoic acid regulatory gene.MethodsTissue samples from 247 patients with knee, hip, or hand OA who had undergone joint surgery were included. RNA‐sequencing analysis was used to investigate differential expression of ALDH1A2 and other retinoic acid signaling pathway genes in cartilage. Expression of ALDH1A2 in joint tissues obtained from multiple sites was quantified using quantitative reverse transcription–polymerase chain reaction. Allelic expression imbalance (AEI) was measured by pyrosequencing. The consequences of ALDH1A2 depletion by RNA interference were assessed in primary human chondrocytes. In silico and in vitro analyses were used to pinpoint which, among 62 highly correlated SNPs, could account for the association at the locus.ResultsALDH1A2 expression was observed across multiple joint tissue samples, including osteochondral tissue from the hand. The expression of ALDH1A2 and of several retinoic acid signaling genes was different in diseased cartilage compared to non‐diseased cartilage, with ALDH1A2 showing lower levels in OA cartilage. Experimental depletion of ALDH1A2 resulted in changes in the expression levels of a number of chondrogenic markers, including SOX9. In addition, reduced expression of the OA risk–conferring allele was witnessed in a number of joint tissues, with the strongest effect in cartilage. The intronic SNP rs12915901 recapitulated the AEI observed in patient tissues, while the Ets transcription factors were identified as potential mediators of this effect.ConclusionThe ALDH1A2 locus seems to increase the risk of hand OA through decreased expression of ALDH1A2 in joint tissues, with the effect dependent on rs12915901. These findings indicate a mechanism that may now be targeted to modulate OA risk.
Dynamics and Noncollocated Model‐Free Position Control for a Space Robot with Multi‐Link Flexible Manipulators
Authors: Yang Xinxin , Ge Shuzhi Sam , Liu Jinkun 
Published: May 2018

AbstractIn this paper, both the dynamics and noncollocated model‐free position control (NMPC) for a space robot with multi‐link flexible manipulators are developed. Using assumed modes approach to describe the flexible deformation, the dynamic model of the flexible space robotic system is derived with Lagrangian method to represent the system dynamic behaviors. Based on Lyapunov's direct method, the robust model‐free position control with noncollocated feedback is designed for position regulation of the space robot and vibration suppression of the flexible manipulators. The closed‐loop stability of the space robotic system can be guaranteed and the guideline of choosing noncollocated feedback is analyzed. The proposed control is easily implementable for flexible space robot with both uncertain complicated dynamic model and unknown system parameters, and all the control signals can be measured by sensors directly or obtained by a backward difference algorithm. Numerical simulations on a two‐link flexible space robot are provided to demonstrate the effectiveness of the proposed control.
Using machine learning to identify patterns of lifetime health problems in decedents with autism spectrum disorder
Authors: Bishop‐Fitzpatrick Lauren , Movaghar Arezoo , Greenberg Jan S. , Page David , DaWalt Leann S. , Brilliant Murray H. , Mailick Marsha R. 
Published: May 2018

Very little is known about the health problems experienced by individuals with autism spectrum disorder (ASD) throughout their life course. We retrospectively analyzed diagnostic codes associated with de‐identified electronic health records using a machine learning algorithm to characterize diagnostic patterns in decedents with ASD and matched decedent community controls. Participants were 91 decedents with ASD and 6,186 sex and birth year matched decedent community controls who had died since 1979, the majority of whom were middle aged or older adults at the time of their death. We analyzed all ICD‐9 codes, V‐codes, and E‐codes available in the electronic health record and Elixhauser comorbidity categories associated with those codes. Diagnostic patterns distinguished decedents with ASD from decedent community controls with 75% sensitivity and 94% specificity solely based on their lifetime ICD‐9 codes, V‐codes, and E‐codes. Decedents with ASD had higher rates of most conditions, including cardiovascular disease, motor problems, ear problems, urinary problems, digestive problems, side effects from long‐term medication use, and nonspecific lab tests and encounters. In contrast, decedents with ASD had lower rates of cancer. Findings suggest distinctive lifetime diagnostic patterns among decedents with ASD and highlight the need for more research on health outcomes across the lifespan as the population of individuals with ASD ages. As a large wave of individuals with ASD diagnosed in the 1990s enters adulthood and middle age, knowledge about lifetime health problems will become increasingly important for care and prevention efforts. Autism Res 2018, 11: 1120–1128. © 2018 International Society for Autism Research, Wiley Periodicals, Inc.Lay SummaryThis study looked at patterns of lifetime health problems to find differences between people with autism who had died and community controls who had died. People with autism had higher rates of most health problems, including cardiovascular, urinary, respiratory, digestive, and motor problems, in their electronic health records. They also had lower rates of cancer. More research is needed to understand these potential health risks as a large number of individuals with autism enter adulthood and middle age.
Typical use of inverse dynamics in perceiving motion in autistic adults: Exploring computational principles of perception and action
Authors: Takamuku Shinya , Forbes Paul A. G. , Hamilton Antonia F. de C. , Gomi Hiroaki 
Published: May 2018

There is increasing evidence for motor difficulties in many people with autism spectrum condition (ASC). These difficulties could be linked to differences in the use of internal models which represent relations between motions and forces/efforts. The use of these internal models may be dependent on the cerebellum which has been shown to be abnormal in autism. Several studies have examined internal computations of forward dynamics (motion from force information) in autism, but few have tested the inverse dynamics computation, that is, the determination of force‐related information from motion information. Here, we examined this ability in autistic adults by measuring two perceptual biases which depend on the inverse computation. First, we asked participants whether they experienced a feeling of resistance when moving a delayed cursor, which corresponds to the inertial force of the cursor implied by its motion—both typical and ASC participants reported similar feelings of resistance. Second, participants completed a psychophysical task in which they judged the velocity of a moving hand with or without a visual cue implying inertial force. Both typical and ASC participants perceived the hand moving with the inertial cue to be slower than the hand without it. In both cases, the magnitude of the effects did not differ between the two groups. Our results suggest that the neural systems engaged in the inverse dynamics computation are preserved in ASC, at least in the observed conditions. Autism Res 2018, 11: 1062–1075. © 2018 International Society for Autism Research, Wiley Periodicals, Inc.Lay SummaryWe tested the ability to estimate force information from motion information, which arises from a specific “inverse dynamics” computation. Autistic adults and a matched control group reported feeling a resistive sensation when moving a delayed cursor and also judged a moving hand to be slower when it was pulling a load. These findings both suggest that the ability to estimate force information from motion information is intact in autism.