bluuebunny/crossref_metadata_2025_split huggingface dataset:
Les influences disciplinaires de la criminologie (1991-2014)
Authors: Nadeau1 France , Mongeon Philippe , Larivière Vincent 
Published: May 2018

Au cours de son histoire, la criminologie a été influencée par de nombreuses disciplines. Elle est d’abord marquée, au début duxxesiècle, par la sociologie positiviste aux États-Unis et par la psychiatrie en Grande-Bretagne, avant d’être fortement influencée par des courants critiques issus de la sociologie. Puis, à partir des années 1990, elle s’ouvre à nouveau aux perspectives de différentes disciplines. Basée sur les références citées par un ensemble de revues de criminologie principalement de langue anglaise, cette étude analyse la place qu’y ont occupée les différentes disciplines entre 1991 et 2014. Il en ressort que les articles de criminologie sont de plus en plus interdisciplinaires, avec 65 % des articles de 2014 citant plus de trois disciplines. Au sein de ces articles, la proportion des références occupée par la psychologie est en progression, au détriment des références faites aux sciences sociales et au droit. Lorsqu’on examine les références citées par les revues et l’affiliation de leurs auteurs, on observe que 42 % des revues étudiées ont un profil interdisciplinaire alors que 22 % s’inscrivent dans une perspective sociocriminologique, 22 % sont centrées sur la psychologie et 4 % sur le droit. L’analyse du réseau de citations de ces revues montre enfin que les revues centrales de la discipline ont des influences disciplinaires variées : des revues ancrées dans la criminologie et les sciences sociales y côtoient des revues interdisciplinaires ainsi que des publications centrées sur la psychologie.
Les paradigmes de la revue Criminologie : auteurs, revues et disciplines qui ont marqué son histoire
Authors: Leclerc1 Chloé , Ream Fyscillia , Décary-Hétu David , Macaluso Benoît , Larivière Vincent 
Published: May 2018

Cet article vise à décrire les influences intellectuelles de la revueCriminologie. Pour ce faire, les 19 813 références faites par les articles publiés dans la revueCriminologieau cours des 40 dernières années sont analysées de manière à dégager l’influence qu’elles ont pu avoir sur les auteurs de la revue. Les auteurs, revues et disciplines les plus influents sont répertoriés et mis en relation avec les caractéristiques des articles qui les citent. Les résultats montrent que le savoir qui inspire les auteurs de la revue est très décentralisé : aucun auteur ou revue ne peut prétendre avoir un ascendant sur un nombre important d’auteurs deCriminologie. Les auteurs et les revues les plus cités sont ceux qui ont su se diversifier et retenir l’attention d’un large auditoire qui travaille avec des traditions de recherches différentes.
Le criminel tel qu’il est représenté et étudié dans la revue Criminologie entre 1968 et 2016
Authors: Ouellet1 Frédéric , Thomas Valérie 
Published: May 2018

Cet article examine la couverture et le traitement du criminel dans la revue Criminologie. Pour observer la représentation du criminel et son étude à travers le temps, des articles empiriques publiés entre 1968 et 2016 qui répondent à certains critères ont été retenus : ils devaient avoir pour objet d’étude principal le criminel et s’appuyer sur une méthodologie détaillée, rigoureuse et ayant un devis reproductible. Ainsi, 24 articles ont été retenus. Dans ceux-ci, la définition du criminel repose sur un présupposé opératoire. Alors que la manière d’identifier le criminel varie très peu et qu’elle se fait le plus souvent sur la base des antécédents criminels officiels, la nomination du criminel varie en fonction de diverses caractéristiques. L’étude du criminel, elle, se centre surtout autour des conduites ou des carrières criminelles, comme en témoigne la majorité des études qui en font leur question d’étude. Les devis sont variés, mais il y a une forte majorité de devis quantitatifs, et bien que les devis longitudinaux doivent être favorisés dans l’étude des carrières criminelles, ils se font rares. Les données autorapportées sont davantage employées dans l’étude du criminel que les données officielles, ce qui souligne la limite de celles-ci dans l’étude de cette thématique. Des pistes de recherche sur l’étude du criminel sont proposées dans la conclusion.
Association of epilepsy and asthma: a population-based retrospective cohort study
Authors: Chiang Kuo-Liang , Kuo Fang-Chuan , Lee Jen-Yu , Huang Chin-Yin 
Published: May 2018

Background
Epidemiologic data supporting the epilepsy–asthma association are insufficient. Therefore, we examined this association in this study.

Methods
By using claims data from the National Health Insurance Research Database (Taiwan), we executed a retrospective cohort analysis. Analysis 1 entailed comparing 150,827 patients diagnosed as having incident asthma during 1996–2013 with disease-free controls who were selected randomly during the same period, frequency matched in terms of age and sex. Similarly, analysis 2 entailed comparing 25,274 patients newly diagnosed as having epilepsy with sex- and age-matched controls who were selected randomly. At the end of 2013, we evaluated in analysis 1 the epilepsy incidence and risk and evaluated in analysis 2 the asthma incidence and risk. We applied Kaplan–Meier analysis to derive plots of the proportion of asthma-free seizures.

Results
In analysis 1, the asthma group exhibited a higher epilepsy incidence than did the control group (3.05 versus 2.26 per 1,000 person-years; adjusted hazard ratio: 1.39, 95% CI [1.33–1.45]). We also noted a greater risk of subsequent epilepsy in women and girls. In analysis 2, we determined that the asthma incidence between the control and epilepsy groups did not differ significantly; however, some age subgroups including children and individuals in their 30s had an increased risk. A negative association was found in adolescents. The Kaplan–Meier analysis revealed epilepsy to be positively associated with subsequent onset of asthma within seven years of epilepsy diagnosis.

Discussion
Asthma may be associated with high epilepsy risk, and epilepsy may be associated with high asthma risk among children and individuals in their 30s. Nevertheless, people with epilepsy in other age subgroups should be aware of the possibility of developing asthma within seven years of epilepsy diagnosis.
Distinct Optoelectronic Signatures for Charge Transfer and Energy Transfer in Quantum Dot–MoS2 Hybrid Photodetectors Revealed by Photocurrent Imaging Microscopy
Authors: Li Mingxing , Chen Jia‐Shiang , Routh Prahlad K. , Zahl Percy , Nam Chang‐Yong , Cotlet Mircea 
Published: May 2018

AbstractAtomically thin transition metal dichalcogenides (TMDCs) have intriguing nanoscale properties like high charge mobility, photosensitivity, layer‐thickness‐dependent bandgap, and mechanical flexibility, which are all appealing for the development of next generation optoelectronic, catalytic, and sensory devices. Their atomically thin thickness, however, renders TMDCs poor absorptivity. Here, bilayer MoS2 is combined with core‐only CdSe QDs and core/shell CdSe/ZnS QDs to obtain hybrids with increased light harvesting and exhibiting interfacial charge transfer (CT) and nonradiative energy transfer (NET), respectively. Field‐effect transistors based on these hybrids and their responses to varying laser power and applied gate voltage are investigated with scanning photocurrent microscopy (SPCM) in view of their potential utilization in light harvesting and photodetector applications. CdSe–MoS2 hybrids are found to exhibit encouraging properties for photodetectors, like high responsivity and fast on/off response under low light exposure while CdSe/ZnS–MoS2 hybrids show enhanced charge carrier generation with increased light exposure, thus suitable for photovoltaics. While distinguishing optically between CT and NET in QD–TMDCs is nontrivial, it is found that they can be differentiated by SPCM as these two processes exhibit distinctive light‐intensity dependencies: CT causes a photogating effect, decreasing the photocurrent response with increasing light power while NET increases the photocurrent response with increasing light power, opposite to CT case.
The Drive Force of Electrical Breakdown of Large‐Area Molecular Tunnel Junctions
Authors: Yuan Li , Jiang Li , Nijhuis Christian A. 
Published: May 2018

AbstractThe origin of electrical breakdown of molecular tunnel junctions is systematically studied by determination of the breakdown voltages as a function of six types of bottom‐electrodes (Au, Ag, Pt, Pd, Ni, and Cu) and different thickness of self‐assembled monolayers of n‐alkanethiolates, S(CH2)n–1CH3 with n = 2, 4, …, 18, with GaOx/EGaIn top contacts. It is found that at positive bias, the migration of metallic atoms is dominated by the wind force, but, at negative bias, both the wind force and direct force are involved in the mechanism of filament formation. Remarkably, the breakdown voltage is independent of the molecular length for short molecules (n < 10), and the breakdown field could be improved by a factor of ≈2 from 0.80 to 1.5 GV m−1 by replacing the Ag with Pt (or Ni) bottom electrodes. These findings give insights into the design of stable molecular junctions.
3D DNA Origami Crystals
Authors: Zhang Tao , Hartl Caroline , Frank Kilian , Heuer‐Jungemann Amelie , Fischer Stefan , Nickels Philipp C. , Nickel Bert , Liedl Tim 
Published: May 2018

Abstract3D crystals assembled entirely from DNA provide a route to design materials on a molecular level and to arrange guest particles in predefined lattices. This requires design schemes that provide high rigidity and sufficiently large open guest space. A DNA‐origami‐based “tensegrity triangle” structure that assembles into a 3D rhombohedral crystalline lattice with an open structure in which 90% of the volume is empty space is presented here. Site‐specific placement of gold nanoparticles within the lattice demonstrates that these crystals are spacious enough to efficiently host 20 nm particles in a cavity size of 1.83 × 105 nm3, which would also suffice to accommodate ribosome‐sized macromolecules. The accurate assembly of the DNA origami lattice itself, as well as the precise incorporation of gold particles, is validated by electron microscopy and small‐angle X‐ray scattering experiments. The results show that it is possible to create DNA building blocks that assemble into lattices with customized geometry. Site‐specific hosting of nano objects in the optically transparent DNA lattice sets the stage for metamaterial and structural biology applications.
Visualization and Quantitative Detection of Friction Force by Self‐Organized Organic Layered Composites
Authors: Terada Hideto , Imai Hiroaki , Oaki Yuya 
Published: May 2018

AbstractVisualization and quantitative detection of external stimuli are significant challenges in materials science. Quantitative detection of friction force, a mechanical stress, is not easily achieved using conventional stimuli‐responsive materials. Here, the quantitative detection of friction force is reported, such as the strength and accumulated ammount, from the visible color of organic layered composites consisting of polydiacetylene (PDA) and organic amines without an excitation light source. The composites of the layered diacetylene monomer crystal and interlayer organic amine are synthesized through self‐organization from the precursor solution. After topochemical polymerization, the layered composites based on PDA show tunable temperature‐responsive and mechanoresponsive color‐change properties depending on the types of interlayer amines. The layered composites are homogeneously coated on a filter paper. The change in color of the paper is quantitatively used to visualize the strength and accumulated amount of the applied friction force. Furthermore, writing pressure is measured by friction force using the paper device.
Design of Multifunctional Soft Doming Actuator for Soft Machines
Authors: Tang Yichao , Yin Jie 
Published: May 2018

AbstractBilayer bending‐based soft actuators are widely utilized in soft robotics for locomotion and object gripping. However, studies on soft actuators based on bilayer doming remain largely unexplored despite the often‐observed dome‐like shapes in undersea animals such as jellyfish and octopus suction cup. Here, based on the simplified model of bending‐induced doming of circular bilayer plates with mismatched deformation, the design of a soft doming actuator upon pneumatic actuation and its implications in the design of multifunctional soft machines are explored. The bilayer actuator is composed of a patterned embedded pneumatic channel on top for radial expansion and a solid elastomeric layer on the bottom for strain‐limiting. It is shown that both the cavity volume and bending angle at the rim of the actuated dome can be controlled by tuning the height gradient of the pneumatic channel along the radial direction. Its potential multifunctional applications are demonstrated in swimming, adhesion, and gripping, including high efficient jellyfish‐inspired underwater soft robots with locomotion speed of 84 cm min−1and rotation‐based soft grippers with low energy cost by harnessing the large rim bending angle, and octopus‐inspired soft adhesion actuators with strong and switchable adhesion force of over 10 N by utilizing the large cavity volume.
Photoassisted Electric Field Modulation of Multiple Nonvolatile Resistance States in Highly Strained Epitaxial BiFeO3 Heterostructures
Authors: Li Dong , Zheng Dongxing , Jin Chao , Li Peng , Liu Xinjun , Zheng Wanchao , Bai Haili 
Published: May 2018

AbstractFor developing the high‐density and high‐speed nonvolatile memory storage, the photoassisted electric field modulation of resistive switching in ferroelectric heterostructures is studied. Highly strained epitaxial BiFeO3 heterostructures are fabricated on LaAlO3 substrates by magnetron sputtering. The electric field‐modulated wide range multilevel resistance and switchable photovoltaic effects are observed in these heterostructures. It is found that the electric field‐modulated interfacial barrier can be further affected by the photogenerated excitons. Therefore, a co‐modulation of light illumination and electric field on the resistive switching behavior is demonstrated, which generates four nonvolatile resistance states.
Mit sichtbarem Licht induzierte, organische photochemische Reaktionen über Energietransferrouten
Authors: Zhou Quan‐Quan , Zou You‐Quan , Lu Liang‐Qiu , Xiao Wen‐Jing 
Published: May 2018

AbstractPhotokatalyse mit sichtbarem Licht ist eine sich schnell entwickelnde und wirksame Strategie zur Initiierung organischer Umwandlungen, und sie folgt den Prinzipien einer grünen und nachhaltigen Chemie. Im Allgemeinen verlaufen die Reaktionspfade der meisten durch sichtbares Licht induzierten photokatalytischen Reaktionen über einen Einelektronentransfer (single‐electron transfer, SET). Neuerdings erfahren auch Energietransferreaktionen (EnT‐Reaktionen), welche durch sichtbares Licht induziert werden, beträchtliche Aufmerksamkeit, da diese Strategie einen spezifischen Reaktionsweg aufweist und bemerkenswerte Fortschritte in diesem Feld erzielt wurden. In diesem Aufsatz diskutieren wir die neuesten Fortschritte im Bereich der durch sichtbares Licht induzierten EnT‐Reaktionen.
Spaltung nicht aktivierter Si‐C(sp3)‐Bindungen mit Reedschen Carboransäuren: Bildung bekannter und unbekannter Silyliumionen
Authors: Wu Qian , Qu Zheng‐Wang , Omann Lukas , Irran Elisabeth , Klare Hendrik F. T. , Oestreich Martin 
Published: May 2018

AbstractEs wird über eine effiziente Methode zur benzeniumionvermittelten Spaltung reaktionsträger Si‐C(sp3)‐Bindungen berichtet. Damit werden verschiedene Tetraalkylsilane in die entsprechenden gegenanionstabilisierten Silyliumionen überführt. Die Reaktion ist im Falle von Hexamethyldisilan chemoselektiv. Berechnungen decken einen Mechanismus mit Rückseitenangriff des Protons an einer der Alkylgruppen auf. Eine Vielzahl aktivierter Si‐C(spn)‐Bindungen (n=3–1) reagieren gleichermaßen gut, und die Reaktionsvorschrift lässt sich auf die Erzeugung von Stannyliumionen übertragen.
Synthesis, characterization, spectroscopic and theoretical studies of transition metal complexes of new nano Schiff base derived from l‐histidine and 2‐acetylferrocene and evaluation of biological and anticancer activities
Authors: Mahmoud Walaa H. , Omar M.M. , Sayed Fatma N. , Mohamed Gehad G. 
Published: May 2018

A new Schiff base derived from the condensation of 2‐acetylferrocene with l‐histidine was prepared and characterized using elemental analyses and spectroscopic methods. Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) complexes of the Schiff base were prepared and characterized using various physicochemical methods such as elemental analysis, Fourier transform infrared and UV–visible spectroscopies, molar conductance, thermal analysis and scanning electron microscopy (SEM). Both ligand and complexes were investigated for their biological and anticancer activities. The elemental analyses showed that complexes were formed in a metal‐to‐ligand ratio of 1:1 stoichiometry. The spectral analyses proved that the ligand was tridentate and all complexes had an octahedral geometry, except the Zn(II) complex that was tetrahedral. SEM showed that the ligand and its Cd(II) complex were of nanometric structure. The molecular and electronic structure of the free ligand was optimized theoretically and the quantum chemical parameters were calculated. The molecular structure can be used to investigate the coordination sites and the total charge density around each atom. According to anticancer studies, Cd(II) complex was recommended to be used as anti‐breast cancer drug as it had very low IC50 (3.5 μg ml−1). Molecular docking was used to predict the binding between the free ligand and its Cd(II) complex and crystal structure of Staphylococcus aureus (PDB ID: 3Q8u), receptors of breast cancer mutant oxidoreductase (PDB ID: 3Hb5) and crystal structure of Escherichia coli (PDB ID: 3 T88) and to identify the binding mode and the crucial functional groups interacting with the three proteins.
A robust UV–visible light‐driven SBA‐15‐PS/phthalhydrazide nanohybrid material with enhanced photocatalytic activity in the photodegradation of methyl orange
Authors: Tayebee R. , Mohammadzadeh Kakhki R. , Audebert P. , Amini M. M. , Salehi M. , Mahdizadeh Ghohe N. , Mandanipour V. , Karimipour G.R. 
Published: May 2018

SBA‐15‐PS/phthalhydrazide (PHD) is presented as a new heterogeneous inorganic–organic nanohybrid photocatalyst with high stability, superior recyclability and remarkable performance in the degradation of methyl orange (MO). Distinctive parameters, including photocatalyst and dye concentrations, pH and degradation time, were assessed for MO degradation catalysed by SBA‐15‐PS/PHD. This new heterogeneous nanocatalyst was characterized using Fourier transform infrared and UV–visible spectroscopies, thermogravimetric analysis, scanning and transmission electron microscopies and elemental analysis. Photodegradation of MO of up to 92% under the optimum conditions (photocatalyst = 0.015 g, [MO] = 4 ppm, pH = 2) was accomplished in 25 min using SBA‐15‐PS/PHD. A preliminary kinetic investigation was performed, and pseudo‐first‐order kinetics with a high rate constant (0.068 min−1) was found for MO degradation. Additional results showed that the photodegradation of MO was increased in the presence of hole scavengers. Therefore a photoreduction mechanism for MO degradation is proposed.
Sulfur/PAN/acetylene black composite prepared by a solution processing technique for lithium–sulfur batteries
Authors: K Krishnaveni , R Subadevi , M Raja , T PremKumar , M Sivakumar 
Published: May 2018

ABSTRACTA sulfur/poly(acrylonitrile)–PAN/acetylene black–AB composite, comprising sulfur and PAN encapsulated in the pores of AB was prepared by a solution‐based technique with dimethyl sulfoxide as the solvent. The composite was characterized by TGA, X‐ray diffraction, FTIR, Raman, SEM, TEM, and BET studies. The composite exhibited a high discharge capacity of 1330 mAh/g in the first cycle. The AB additive plays multiple roles in the composite, acting as a conducting matrix for electron transport and as a porous framework that adsorbs and retains electrolyte. The presence of PAN along with the porous carbon matrix in the composite provides the necessary resilience to absorb strains due to volume expansion during cycling. The observed improved performance of the composite is primarily attributed to the small size and homogeneous distribution of sulfur in the composite. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46598.
Reagent‐induced asymmetric induction in addition reaction of reduced glutathione onto bis‐Mannich chalcones
Authors: Bernardes Aline , D'Oliveira Giulio D. C. , Silezin Aneta , Kuzma Mónika , Molnár Szilárd , Noda Pérez Caridad , Perjési Pál 
Published: May 2018

AbstractThe stereochemistry of non‐enzyme catalyzed nucleophilic addition of GSH to 4′‐hydroxychalcone 1 and its bis‐Mannich derivative 2 was investigated at different pH values (pH 3.2, 6.1, 7.4, and 8.0). The stereochemical outcome of the reactions was evaluated by HPLC‐UV‐Vis method. Under strongly acidic conditions (pH 3.2), an unexpected diastereoselective addition of GSH onto the bis‐Mannich derivative 2 was observed. Such a selectivity could not be observed in the similar reaction of 2 with N‐acetylcysteine. The observed stereoselectivity can be rationalized by ion‐pair formation between the protonated Mannich nitrogens and the deprotonated GSH(glutamate)‐carboxylate. To the best of our knowledge, this is the first example of reagent‐induced asymmetric induction in Michael‐type additions of thiols.
N‐Heterocyclic Carbene‐Protected Ag Nanoparticles Immobilized on Polyacrylonitrile Fiber as Efficient Catalysts for a Three‐Component Coupling Reaction
Authors: Cao Jian , Tian Hongqi 
Published: May 2018

AbstractMetal nanoparticles (NPs) are routinely stabilized by the introduction of capping agents or their distribution on supports. In this context, we report the preparation and characterization of N‐heterocyclic carbene (NHC)‐stabilized silver NPs supported on polyacrylonitrile fiber (PANF). As a result, Ag loadings of up to 8 % and particle sizes of 11.0±3.2 nm were achieved. This novel nanocomposite catalyst demonstrated high activity in addition to excellent stability and reusability in the three‐component reaction between alkynes, haloalkanes, and amines. In this system, the AgNPs were stabilized by both a support effect and a ligand effect. The unique NHC‐protected AgNP structure and the PANF support provide a synergistic effect in the deprotonation of Csp−H bonds, with turnover numbers of up to 3500. This catalyst was successfully recycled over eight runs without any significant loss in activity, and with no significant aggregation of the AgNPs. Moreover, implementation of a flow system with PANF‐NHC@Ag as catalyst leads to an efficient productivity of 57 mmol h−1.