bluuebunny/crossref_metadata_2025_split huggingface dataset:
O COMPLIANCE CRIMINAL COMO INSTRUMENTO DE GOVERNANÇA CORPORATIVA
Authors: Rochel Filho Paulo Alves 
Published: November 2024

A pesquisa analisa a importância da adoção de uma política de compliance criminal aplicada à governança corporativa, como instrumento de prevenção contra a prática de delitos e direcionado à mitigação de riscos. Neste contexto, procedeu-se à análise crítica da efetividade de seu emprego na autorregulação e sua contribuição ao aperfeiçoamento da governança corporativa. Procedeu-se a breve investigação das origens do instituto até os dias atuais, incluindo histórico legislativo no exterior e no Brasil, de forma a demonstrar a evolução do sistema regulatório e da legislação penal em relação ao meio corporativo. Neste particular, observou-se o emprego de normas penais no campo administrativo e o delineamento de novos modelos de imputação direcionados ao ambiente corporativo e aos atores de governança. Foram abordados e delineados os conceitos de governança corporativa, compliance, riscos e, especificamente, do compliance criminal. Analisou-se a necessidade e validade da implementação de programas de compliance criminal como modelo de prevenção e redução de riscos corporativos, bem como no estabelecimento de responsabilidade em relação à prática de ilícitos criminais. Para tanto, foi realizado levantamento bibliográfico e pesquisa em fontes doutrinárias e na legislação, bem como buscou-se o posicionamento de organismos de referência acerca do assunto. Ao final, apresenta-se uma análise crítica da validade do emprego do compliance criminal como instrumento de autorregulação e de conformidade e sua contribuição à melhoria da governança corporativa.
Anatomo-clinical correlations between total or partial edentation and digestive disorders
Authors: Gavra A.S. , Bonţea M.G. , Moga I. , Todor L. , Todor S.A. , Moga T. 
Published: November 2024

The functions of the dento-maxillary apparatus are essential for the preparation and formation of the food bowl, which reaches the lower segments of the digestive tract.	In the absence of teeth, the process of digestion is much more difficult, which leads to significant disorders in food absorption. At the same time, due to the lack of teeth, dysfunctions occur at the temporomandibular joint, movements of the mandible (left-right laterality, propulsion/retropulsion, opening/closing the mouth) are no longer performed properly which ultimately leads to loading the stomach with food incorrectly processed, as well as prolonging digestion time. Following the anamnesis performed on the group of patients, we noticed that there is a correlation between totally or partially edentulous patients and the appearance of digestive tract diseases. There is a causal relationship between edentations and the appearance of digestive disorders at patients over 45 years old.
The impact of doctor–patient communication on medication adherence and blood pressure control in patients with hypertension: a systematic review
Authors: Zeng Jianwei , Gao Yuqiang , Hou Chen , Liu Tao 
Published: November 2024

Background
This systematic review aims to present existing evidence concerning the effects of doctor–patient communication on medication adherence and blood pressure control in hypertensive patients.

Methods
Two researchers independently conducted comprehensive searches of five databases and screened relevant studies published from the inception of these databases up to July 21, 2024. The titles, abstracts, and full texts of all the retrieved articles subsequently underwent rigorous duplicate screening, according to predefined inclusion and exclusion criteria. We then synthesized the findings in a narrative format of the included studies. Finally, two researchers independently assessed study quality.

Results
Eighteen observational studies encompassing 21,542 patients and seven randomized controlled trials with 2,804 patients were included in the systematic review. Diverse approaches were employed for evaluating doctor–patient communication and medication adherence in these studies, with identified themes including communication content and communication skills. Various facets of doctor–patient communication, including patient satisfaction with doctor–patient communication, the specific content discussed, the style of communication, the comprehensive communication skills of doctors, and the duration of these conversations, were scrutinized. In general, the results suggest a promising link between effective doctor–patient communication and increased medication adherence and blood pressure control. Nonetheless, the presence of nuanced variations and subtle distinctions within the literature underscores the imperative for deeper exploration and consideration in clinical practice. Additionally, effective communication interventions must attain a certain threshold of intensity and endure for an adequate duration.

Conclusion
This review underscores the pivotal role of robust doctor–patient communication in improving both medication adherence and blood pressure control. Nevertheless, additional research may be warranted to address the disparities and subtleties in the literature and to establish precise implications for clinical practice. Moreover, in clinical practice, strategies to enhance doctor–patient communication should be incorporated, given the potential to improve medication adherence and blood pressure control among hypertensive patients.

Trial registration
Systematic review registration: PROSPERO with registration number CRD42024503112.
Variations of Infiltration and Electronic Contact in Mesoscopic Perovskite Solar Cells Revealed by High‐Resolution Multi‐Mapping Techniques
Authors: Lakhiani Harry , Dunlop Tom , De Rossi Francesca , Dimitrov Stoichko , Kerremans Robin , Charbonneau Cécile , Watson Trystan , Barbé Jérémy , Tsoi Wing Chung 
Published: April 2019

AbstractA combination of high‐resolution mapping techniques is developed to probe the homogeneity and defects of mesoscopic perovskite solar cells. Three types of cells using a one‐step infiltration process with methylammonium lead iodide (MAPbI3) or 5‐ammoniumvaleric acid‐MAPbI3 solutions, or two‐step process with MAPbI3 solution are investigated. The correlation between photoluminescence, photocurrent, electroluminescence, and Raman maps gives a detailed understanding of the different infiltration mechanisms, electronic contact at interfaces, and effect on local photocurrent for the cells. The one‐step MAPbI3 cell has very limited infiltration of the perovskite solution which results in poor device performance. High loading of the mesopores of the TiO2 and ZrO2 scaffold is observed when using 5‐ammoniumvaleric acid, but some micrometer‐sized non‐infiltrated areas remain due to dense carbon flakes hindering perovskite infiltration. The two‐step cell has a complex morphology with features having either beneficial or detrimental effects on the local photocurrent. The results not only provide key insights to achieving better infiltration and homogeneity of the perovskite film in mesoporous devices but can also aid further work on planar devices to develop efficient extraction layers. Moreover, this multi‐mapping approach allows the correlation of the local photophysical properties of full perovskite devices, which would be challenging to obtain by other techniques.
Improved Epitaxy of AlN Film for Deep‐Ultraviolet Light‐Emitting Diodes Enabled by Graphene
Authors: Chen Zhaolong , Liu Zhiqiang , Wei Tongbo , Yang Shenyuan , Dou Zhipeng , Wang Yunyu , Ci Haina , Chang Hongliang , Qi Yue , Yan Jianchang , Wang Junxi , Zhang Yanfeng , Gao Peng , Li Jinmin , Liu Zhongfan 
Published: April 2019

AbstractThe growth of single‐crystal III‐nitride films with a low stress and dislocation density is crucial for the semiconductor industry. In particular, AlN‐derived deep‐ultraviolet light‐emitting diodes (DUV‐LEDs) have important applications in microelectronic technologies and environmental sciences but are still limited by large lattice and thermal mismatches between the epilayer and substrate. Here, the quasi‐van der Waals epitaxial (QvdWE) growth of high‐quality AlN films on graphene/sapphire substrates is reported and their application in high‐performance DUV‐LEDs is demonstrated. Guided by density functional theory calculations, it is found that pyrrolic nitrogen in graphene introduced by a plasma treatment greatly facilitates the AlN nucleation and enables fast growth of a mirror‐smooth single‐crystal film in a very short time of ≈0.5 h (≈50% decrease compared with the conventional process), thus leading to a largely reduced cost. Additionally, graphene effectively releases the biaxial stress (0.11 GPa) and reduces the dislocation density in the epilayer. The as‐fabricated DUV‐LED shows a low turn‐on voltage, good reliability, and high output power. This study may provide a revolutionary technology for the epitaxial growth of AlN films and provide opportunities for scalable applications of graphene films.
Cation Substitution Induced Adjustment on Lattice Structure and Photoluminescence Properties of Mg14Ge5O24:Mn4+: Optimized Emission for w‐LED and Thermometry Applications
Authors: Liang Sisi , Li Guogang , Dang Peipei , Wei Yi , Lian Hongzhou , Lin Jun 
Published: April 2019

AbstractCurrently, Mn4+‐activated red‐emitting materials are the research hotspot due to their promising application in phosphor‐converted white light‐emitting diodes (w‐LEDs). Here, a typical cation substitution strategy is reported to optimize Mn4+‐doped germinate phosphor for improving luminescence performances. The effect of cation substitution for Ge4+ ions by Ti4+, Sn4+, and Si4+ ions on lattice structure, photoluminescence properties, and thermal stability of the as‐prepared Mn4+‐doped germinates is systematically investigated. A significant improvement of emission intensity with Ti4+ doping should benefit from the resonance emission enhancement effect. Some lattice distortion defects contribute to the thermal stability enhancement, which plays a role in driving the excited phonon traps to compensate the energy loss of nonradiative transition. Surprisingly, abnormal variation in intensity of anti‐Stokes and Stokes emission peaks with changing temperature is first observed, revealing a potential application in thermometry. The electroluminescence performances of as‐fabricated w‐LED devices using Mg14Ge5Ti0.5O24:Mn4+ red phosphor are evaluated, which possess higher color rendering index (Ra = 87.3) and luminous efficiency (109.42 lm W−1) as well as lower color correlated temperature (3566 K) than those using Cs2GeF6:Mn4+ and CaAlSiN3:Eu2+ red phosphors. The results reflect the superiority of the studied phosphor in w‐LEDs and optical thermometry areas.
Microlens Arrays above Interlaced Plasmonic Pixels for Optical Security Devices with High‐Resolution Multicolor Motion Effects
Authors: Jiang Hao , Kaminska Bozena , Porras Hector , Raymond Mark , Kapus Tyler 
Published: April 2019

AbstractOptical security devices based on high‐density microlens arrays on top of printed microimages or interlaced patterns can display high‐resolution image frames with attractive motion effects. However, the effects are so far restricted to a single color due to challenges in printing multiple colors with sufficiently high resolution and precision. This article introduces a viable solution based on microlens arrays above plasmonic colors to enable high‐resolution multicolor image frames with multidirectional motion effects. Plasmonic color pixels comprised of metalized nanowell arrays are implemented to print 2D interlaced patterns with super‐high resolution and nanoscale precision. Using a 2D microlens array of 25 µm lens pitch, 50 color image frames are obtained from a plasmonic color pattern printed with resolution of 10 160 dots per inch. The image frames show multiple colors, which significantly boost the color performance of microlens‐based security devices. The display resolution of image frames reaches 1016 pixels per inch, which is at least six times higher than conventional lenticular images. The color image frames also show excellent motion effects when moving the view point along any arbitrary direction. The presented devices can be advantageous for commercial applications in security, authentication, and product branding.
Structure and Transport Properties of Water and Hydrated Ions in Nano‐Confined Channels
Authors: Zhu Huajian , Wang Yuying , Fan Yiqun , Xu Junbo , Yang Chao 
Published: April 2019

AbstractNano‐confined flow is ubiquitous in modern engineering and biomedical applications. As the peculiar phenomena of nano‐confined flow were continuously reported and traditional theories failed to describe them accurately, simulation efforts have been made to gain deeper insight. The objective of this paper is to provide an overview of the recent progress on nano‐confined flow, including water flow and hydrated ions transport. This report starts with the water behavior under nano‐confinement, summarizing the water structures, flow properties and their dependence on wall wettability, channel size, etc. The report also presents the efforts made to modify the existing theories to describe nano‐confined flows. Then, the report goes to the hydrated ions. The dehydration process of hydrated ions and ions sieving are discussed in detail, and the effects of membrane surface charge, grafting functional groups, and external field on ions transport are reviewed. In this Progress Report, the transport properties of water and hydrated ions in nano‐confined channels are highlighted, which is critical to the design and application of nanofluidic devices, such as nanofiltration membranes, biosensors, and other related fields.
Cadmium Free Cu2ZnSnS4 Solar Cells with 9.7% Efficiency
Authors: Larsen Jes K. , Larsson Fredrik , Törndahl Tobias , Saini Nishant , Riekehr Lars , Ren Yi , Biswal Adyasha , Hauschild Dirk , Weinhardt Lothar , Heske Clemens , Platzer‐Björkman Charlotte 
Published: April 2019

AbstractCu2ZnSnS4(CZTS) thin‐film solar cell absorbers with different bandgaps can be produced by parameter variation during thermal treatments. Here, the effects of varied annealing time in a sulfur atmosphere and an ordering treatment of the absorber are compared. Chemical changes in the surface due to ordering are examined, and a downshift of the valence band edge is observed. With the goal to obtain different band alignments, these CZTS absorbers are combined with Zn1−xSnxOy (ZTO) or CdS buffer layers to produce complete devices. A high open circuit voltage of 809 mV is obtained for an ordered CZTS absorber with CdS buffer layer, while a 9.7% device is obtained utilizing a Cd free ZTO buffer layer. The best performing devices are produced with a very rapid 1 min sulfurization, resulting in very small grains.
Characterization of porous media by chemical tracers using time‐of‐flight and residence time distribution concept
Authors: Balikram Archana , Sinha Supriya , Kumar N.P. Deva , Ojha Keka 
Published: April 2019

AbstractChemical tracer proves itself an efficient and economic means for in‐depth and accurate reservoir characterization, where other known technology fails. In the present study, a new combination of conservative and partitioning tracer, that is, (VI) and 1‐Hexanol, was evaluated for their applicability in field. Laboratory investigation was carried out to characterize a porous medium in terms of heterogeneity, porosity, permeability, and residual oil saturation in addition to swept pore volume determination under enhanced recovery mechanism, with the help of volume balance as well as theoretical models. The tracers were first evaluated for their adsorption characteristics on sandstone at simulated temperature conditions, with more than 98% recovery. The investigation is based upon the tracer concentration measurement at the exit point as a function of time, and the response was used to infer reservoir parameters like swept pore volume, sweep efficiency, average residual oil saturation, and the Lorentz coefficient using method of moment, residence time distribution, and time‐of‐flight (TOF) concept. In the flow condition, interstitial velocity of conservative tracer was measured and used to calculate the TOF. Tortuosity and heterogeneity of the sand pack were determined from various theoretical correlations. The analytically evaluated heterogeneity values were found to match with the experimental data.
Second order sliding mode control with MARS speed estimation of linear induction motors considering unknown longitudinal end effects
Authors: Zhang Lei , Zhang Hui , Liu Yongwen , Liu Dongqing 
Published: April 2019

AbstractThis paper presents a novel sensorless second order sliding mode control (SOSMC) scheme for linear induction motor (LIM), considering the longitudinal end effects. An adaptive super twisting controller (ASTC) is developed to eliminate the influence of the unknown bounded longitudinal end effects in mechanical loop scheme. Two super twisting controllers (STCs) are applied in electric loop schemes to overcome the high nonlinearity and reduce chattering. Moreover, a Model Adaptive Reference System (MARS) is designed to estimate LIM speed and the secondary flux. Finally, the proposed MARS based SOSMC scheme is validated with the Hardware‐in‐the‐loop (HIL) experiment test system.
HPV‐vaccination and cancer cervical screening in 53 WHO European Countries: An update on prevention programs according to income level
Authors: Altobelli Emma , Rapacchietta Leonardo , Profeta Valerio F. , Fagnano Roberto 
Published: April 2019

AbstractHuman papillomavirus (HPV) is the most common sexually transmitted disease in the world. The aim of our study is to describe the differences in HPV‐vaccination coverage and screening programs in WHO European Countries notably according to income levels. Multiple correspondence analysis was applied to examine the association among the following variables: Gross National Income (GNI) levels (Lower‐Middle Income, LMI; Upper‐Middle Income, UMI; and High Income, HI); type of CC screening program (coverage; opportunistic/organized); vaccination payment policies (free or partial or total charge); mortality rates/100 000 (≤3; >3‐6; >6‐9; >9); incidence rates/100 000 (≤7; >7‐15; >15‐21; >21). Data HPV‐vaccination start (years) (2006‐2008; 2009‐2011; 2012‐2014; >2014; no program); coverage HPV‐vaccination percentage (≤25; 26‐50; 51‐75; >75); data screening start (years) (<1960; 1960‐1980; 1981‐2000; >2000); primary screening test (HPV, cytology), and screening coverage percentage (≤25; >25‐50; >50‐75; >75). A high income is associated with: start of screening before 1960, medium‐high screening coverage, organized screening, start of vaccination in the periods 2009‐2011 and 2012‐2014 and high immunization coverage. On the other hand, lower‐middle income is associated with: late start of vaccination and screening programs with cytology as primary test, high mortality and incidence rates and lower‐medium vaccination coverage. Our results show a useful scenario for crucial support to public health decision‐makers. Public health authorities should monitor the HPV‐vaccinated population in order to determine more precisely the effects on short‐ and long‐term incidence and mortality rates. In fact, the greater the vaccination coverage, the greater will be the efficacy of the program for the prevention of CC and other HPV‐related diseases.
Intraoperative quantification of meningioma cell proliferation potential using rapid flow cytometry reveals intratumoral heterogeneity
Authors: Oya Soichi , Yoshida Shinsuke , Tsuchiya Tsukasa , Fujisawa Naoaki , Mukasa Akitake , Nakatomi Hirofumi , Saito Nobuhito , Matsui Toru 
Published: April 2019

AbstractBackgroundStandard sampling methods to evaluate the proliferative ability of meningioma have not been established.MethodsThis prospective study was conducted to evaluate the effectiveness of intraoperative rapid flow cytometry (iFC) using raw samples for the quantitative assessment of proliferative ability in meningioma cells and to investigate intratumoral heterogeneity. Proliferation index (PI) was defined as the ratio of aneuploid cells with an abnormal number of chromosomes to the total cells.ResultsFrom 50 patients, 118 specimens were analyzed. There was a statistically significant correlation between the postoperative MIB‐1 labeling index (LI) and PI (R = 0.59, P < 0.0001). A higher PI was correlated with a higher annual growth rate (AGR, cm3/y) (R = 0.50, P = 0.0002, 26 patients). AGR showed a correlation with the intratumoral distribution of PI. PI was the highest at the center or the peripheral section of the tumor in tumors with high AGR, whereas it was highest at the dural attachment in tumors with low AGR (P = 0.039, n = 20). Pial feeders were more frequently observed when PI was high in the center or in the peripheral section (P = 0.006, n = 37).ConclusionsRapid iFC may thus become a substitute for MIB‐1 LI. Intratumoral heterogeneity of cellular proliferative potential exists in meningiomas and is related to tumor biological characteristics such as AGR and development of pial feeders. This observation underscores the importance of standardization in the sampling method to accurately estimate the risk of meningioma recurrence.
Palladium‐Catalyzed Intramolecular Self‐Alkylation of Polyfluoroarene via Heck and Decarboxylation Process
Authors: Wei Wan‐Xu , Chen Si , Xia Yu , Li Ming , Li Xue‐Song , Han Ya‐Ping , Wang Cui‐Tian , Liang Yong‐Min 
Published: April 2019

AbstractAn efficient palladium‐catalyzed cyclization and polyfluorophenylation of γ,δ‐unsaturated polyfluorobenzoyl oxime ester via iminopalladation/polyfluorobenzoyloxy decarboxylation cascade reaction is developed. The protocol provides a practical and atom‐economical access to a broad scope of various polyfluorophenylated dihydropyrrole derivatives. The reaction effectively utilizes the polyfluorobenzoyloxy leaving group as polyfluorophenylated source for the first time, precluding the need of additional polyfluoroarene. This is the first example of the introduction of electron‐deficient arenes in the further transformation of Narasaka‐Heck‐type reaction. Additionally, the reaction is conducted in a short time.
Preparation and Performance of Porous Polyetherimide/Al2O3 Separator for Enhanced Lithium‐Sulfur Batteries
Authors: Zhu Fangfang , Liu Jiuqing , Zhao Haijun , Li Jie , Li Qihou , Xi Yang , Liu Meng , Wang Cheng 
Published: April 2019

AbstractAs an important component of lithium‐sulfur batteries, the separator has a critical role in battery safety and the corresponding electrochemical performance. In this study, a high‐performance polyetherimide (PEI)/Al2O3 separator was prepared through the non‐solvent‐induced phase separation (NIPS) technique. It was demonstrated that the existence of Al2O3 affects the morphology, thermal stability, electrolyte uptake, ionic conductivity, and electrochemical properties of the PEI/Al2O3 separator. The results indicate that PEI/Al2O3 separators containing 5 and 6 wt % Al2O3 possess high porosity, good electrolyte uptake, excellent thermal stability (thermal shrinkage ratio is only 0.78 % even at a high temperature of 200 °C), and ionic conductivity of practical significance (up to 2.20 mS ⋅ cm−1). Consequently, the assembled cell with the prepared PEI/Al2O3 separator exhibits a better cycling performance (724.9 mA h g−1 after 200 cycles at 0.2 C) than that with the commercial Celgard 2320 separator. Therefore, the PEI/Al2O3 separator prepared by NIPS is a potential separator candidate for high‐safety and high‐performance dischargeable lithium‐sulfur batteries.
Total Synthesis of Aspidosperma and Strychnos Alkaloids through Indole Dearomatization
Authors: Saya Jordy M. , Ruijter Eelco , Orru Romano V. A. 
Published: April 2019

AbstractMonoterpenoid indole alkaloids are the major class of tryptamine‐derived alkaloids found in nature. Together with their structural complexity, this has attracted great interest from synthetic organic chemists. In this Review, the syntheses of Aspidosperma and Strychnos alkaloids through dearomatization of indoles are discussed.