Measurement of Acrylamido Tertiary Butyl Sulfonate Polymer Retention on Limestone by Three Methods Under Varying Temperature and Oil Presence
Authors: Sebastian Anoo , Mushtaq Muhammad , Al-Shalabi Emad W. , AlAmeri Waleed , Mohanty Kishore , Masalmeh Shehadeh , AlSumaiti Ali M. 
Published: November 2024

Summary
Polymer retention poses a significant challenge in polymer flooding applications, emphasizing the importance of accurately determining retention levels for successful project design. In carbonate reservoirs of the Middle East, where temperatures exceed 90°C, conducting adsorption tests under similar temperature conditions becomes crucial for the precise determination of adsorption values. The choice of analytical method potentially impacts the accuracy of retention measurements from effluent analysis. This study investigates the effect of temperature on the performance of a polymer, specifically its rheological behavior and retention. Rheological and polymer flooding experiments were carried out using an acrylamido tertiary butyl sulfonate (ATBS)-based polymer in formation water (167,114 ppm) at different temperatures (25°C, 60°C, and 90°C) with required oxygen control measures. Dynamic polymer retention was conducted in both the absence of oil (single-phase tests) and the presence of oil (two-phase tests). In addition, different analytical techniques were evaluated, including viscosity measurements, ultraviolet (UV)-visible spectroscopy, and total organic carbon-total nitrogen (TOC-TN) analysis, to determine the most accurate method for measuring the polymer concentration with the least associated uncertainty. Furthermore, the study investigates the effects of these uncertainties on the final dynamic polymer retention values by applying the propagation of error theory.
The effluent polymer concentration was determined using viscosity correlation, UV spectrometry, and TOC-TN analysis, all of which were reliable methods with coefficient of determination (R2) values of ~0.99. The study analyzed the effects of flow through porous media and backpressure regulator on polymer degradation. The results showed that the degradation rates were around 2% for flow through porous media and 16% for mechanical degradation due to the backpressure regulator for all temperature conditions. For the effluent sample, the concentration of polymer was lower when using the viscosity method due to polymer degradation. However, the TOC-TN and UV methods were unaffected as they measured the TN and absorbance at a specific wavelength, respectively. Therefore, all viscosity results were corrected for polymer degradation effects in all tests. During the two-phase coreflooding experiment conducted at 25°C, the accuracy of the UV spectrometry and viscosity measurements was affected by the presence of oil, rendering these methods unsuitable. However, the TOC-TN measurements were able to determine effluent polymer concentration and, subsequently, the retention value. Moreover, the use of glycerin preflush to inhibit oil production during polymer injection in the two-phase studies showed that all three methods were appropriate. The error range was obtained using the propagation of error theory for all the methods. Accordingly, it was noted that the temperature did not affect the dynamic retention values in both single-phase and two-phase conditions. The findings of this study highlight that when adequate oxygen control measures are implemented, the temperature does not exhibit a statistically significant impact on the retention of the ATBS-based polymer under investigation. Furthermore, TOC-TN has been identified as the optimal analytical method due to its minimal uncertainties and ease of measuring polymer concentration under varying experimental conditions.