bluuebunny/crossref_metadata_2025_split huggingface dataset:
Co-disposal of lignite fly ash and coal mine waste rock for neutralisation of AMD
Authors: Qureshi Asif , Maurice Christian , Öhlander Björn 
Published: April 2021

AbstractWaste rocks (WRs) from a lignite-producing coalfield and fly ash (FA) produced from the same lignite have been investigated in this study with a primary objective to determine the potential for co-disposal of WRs and FA to reduce the environmental contamination. Mixing WRs with FA and covering WRs with FA have been investigated. Particle size effect caused ≤2 mm particles to produce low pH (~2) and metal-laden leachates, indicating higher sulphide minerals’ reactivity compared to larger particles (≤10 mm, pH ~ 4). Co-disposal of FA as mixture showed an instantaneous effect, resulting in higher pH (~3–6) and better leachate quality. However, acidity produced by secondary mineralisation caused stabilisation of pH at around 4.5–5. In contrast, the pH of the leachates from the cover method gradually increased from strongly acidic (pH ~ 2) to mildly acidic (pH ~ 4–5) and circumneutral (pH ~ 7) along with a decrease in EC and elemental leaching. Gradually increasing pH can be attributed to the cover effect, which reduces the oxygen diffusion, thus sulphide oxidation. FA cover achieved the pH necessary for secondary mineralisation during the leaching experiment. The co-disposal of FA as cover and/or mixture possesses the potential for neutralisation and/or slowing down AMD and improving leachate quality.
A review of combined sewer overflows as a source of wastewater-derived emerging contaminants in the environment and their management
Authors: Petrie Bruce 
Published: April 2021

AbstractEmerging contaminants such as pharmaceuticals, illicit drugs and personal care products can be released to the environment in untreated wastewater/stormwater mixtures following storm events. The frequency and intensity of combined sewer overflows (CSOs) has increased in some areas due to increasing urbanisation and climate change. Therefore, this review provides an up-to-date overview on CSOs as an environmental source of emerging contaminants. Other than compounds with high removal, those chiral species subject to enantioselective changes (i.e. degradation or inversion) during wastewater treatment can be effective markers of CSO discharge in the environment. A proposed framework for the selection of emerging contaminants as markers of CSOs is outlined. Studies have demonstrated that CSOs can be the main source of emerging contaminants with high removal efficiency during wastewater treatment (e.g. > 90%). However, the impact of CSOs on the environment is location specific and requires decision-making on their appropriate management at catchment level. This process would be aided by further studies on CSOs which incorporate the monitoring of emerging contaminants and their effects in the environment with those more routinely monitored pollutants (e.g. pathogens and priority substances). Mitigation and treatment strategies for emerging contaminants in CSOs are also discussed.
Iodoprophylaxis and thyroid autoimmunity: an update
Authors: Teti Claudia , Panciroli Marta , Nazzari Elena , Pesce Giampaola , Mariotti Stefano , Olivieri Antonella , Bagnasco Marcello 
Published: April 2021

AbstractAdequate iodine intake is necessary for normal thyroid function. Iodine deficiency is associated with serious complications, but also iodine excess can lead to thyroid dysfunction, and iodine supplementation aimed to prevent iodine deficiency disorders has been associated with development of thyroid autoimmunity. The epidemiology of thyroid diseases has undergone profound changes since the implementation of iodoprophylaxis, notably by means of iodine-enriched salt, specifically resulting in decreased prevalence of goiter and neonatal hypothyroidism, improved cognitive function development in infancy, and reduced incidence of more aggressive forms of thyroid cancer. The main question we address with this review is the clinical relevance of the possible effect on autoimmunity exerted by the use of iodine-enriched salt to correct iodine deficiency. In animal models, exogenous iodine is able to trigger or exacerbate thyroid autoimmunity, but it is still not clear whether the observed immunological changes are due to a direct effect of iodine on immune response, or whether they represent a secondary response to a toxic effect of iodine on thyroid tissue. Previous iodine status of a population seems to influence the functional thyroid response to increased iodine intake and possibly the development of thyroid autoimmunity. Moreover, the prevalence of thyroid antibodies, regarded as hallmark of autoimmune thyroid disease, varies between populations under the influence of genetic and environmental factors, and the presence of thyroid antibodies does not always coincide with the presence of thyroid disease or its future development. In addition, the incidence of autoimmune diseases shows a general increasing trend in the last decades. For all these reasons, available data are quite heterogeneous and difficult to analyze and compare. In conclusion, available data from long-term population surveys show that a higher than adequate population iodine intake due to a poorly controlled program of iodine prophylaxis could induce thyroid dysfunction, including thyroid autoimmunity mostly represented by euthyroid or subclinical hypothyroid autoimmune thyroiditis. Close monitoring iodine prophylaxis is therefore advised to ensure that effects of both iodine deficiency and iodine excess are avoided.
Monitoring deformations of Istanbul metro line stations through Sentinel-1 and levelling observations
Authors: Halicioglu Kerem , Erten Esra , Rossi Cristian 
Published: April 2021

AbstractTurkey, as a developing country, is designing and performing massive construction projects around Istanbul. Beginning from the 1960s, rapid urbanization has been taking place due to industrialization, which brings an increase in the population. Yet, construction projects have been accelerated especially during the last decade, and many new projects are scheduled to be completed in a short time. Ground-based observations are generally carried out to monitor the deformations within construction sites, especially through geometric levelling, and GNSS techniques. However, in most cases, these monitoring measurements are only scheduled within the period of the construction process, and ensuing deformations are usually not considered. In addition to these techniques, the space-based interferometric technique can also be used to define the line of sight surface displacements with high accuracy, using the phase difference between image result for synthetic aperture radar images. In particular, Persistent Scatter Interferometry is one of the interferometric methods that are capable of defining the two-dimensional (vertical and horizontal) deformation for the desired epoch with a high temporal resolution. Thus it can be used as a complementary method for monitoring ground deformations, where the measurement is made by ground-based observations. In this study, the deforming areas related to underground metro construction are investigated through significant displacements between 2015 and 2018 of Sentinel-1 space-borne SAR data using the PSI technique. These results are validated by comparison with available levelling data corresponding to the new metro line.
Prevention of Ischemic Myocardial Contracture Through Hemodynamically Controlled DCD
Authors: Wahlquist Ylva , Soltesz Kristian , Liao Qiuming , Liu Xiaofei , Pigot Henry , Sjöberg Trygve , Steen Stig 
Published: April 2021

Abstract
Purpose
Ischemic myocardial contracture (IMC) or “stone heart” is a condition with rapid onset following circulatory death. It inhibits transplantability of hearts donated upon circulatory death (DCD). We investigate the effectiveness of hemodynamic normalization upon withdrawal of life-sustaining therapy (WLST) in a large-animal controlled DCD model, with the hypothesis that reduction in cardiac work delays the onset of IMC.

Methods
A large-animal study was conducted comprising of a control group ($$n=6$$

n
=
6

) receiving no therapy upon WLST, and a test group ($$n=6$$

n
=
6

) subjected to a protocol for fully automated computer-controlled hemodynamic drug administration. Onset of IMC within 1 h following circulatory death defined the primary end-point. Cardiac work estimates based on pressure-volume loop concepts were developed and used to provide insight into the effectiveness of the proposed computer-controlled therapy.

Results
No test group individual developed IMC within $${1} \text { h}$$

1

h

, whereas all control group individuals did (4/6 within $${30}{\text { min}}$$

30

min

).

Conclusion
Automatic dosing of hemodynamic drugs in the controlled DCD context has the potential to prevent onset of IMC up to $${1}{\text { h}}$$

1

h

, enabling ethical and medically safe organ procurement. This has the potential to increase the use of DCD heart transplantation, which has been widely recognized as a means of meeting the growing demand for donor hearts.
Mechanisms of CO2 reduction into CO and formic acid on Fe (100): a DFT study
Authors: Kwawu Caroline R. , Aniagyei Albert , Konadu Destiny , Antwi Boniface Yeboah 
Published: April 2021

AbstractUnderstanding the mechanism of CO2 reduction on iron is crucial for the design of more efficient and cheaper iron electrocatalyst for CO2 conversion. In the present study, we have employed spin-polarized density functional theory calculations within the generalized gradient approximation (DFT-GGA) to elucidate the mechanism of CO2 reduction into carbon monoxide and formic acid on the Fe (100) facet. We also sort to understand the transformations of the other isomers of adsorbed CO2 on iron as earlier mechanistic studies are centred on the transformations of the C2v geometry alone and not the other possible conformations i.e., flip-C2v and Cs modes. Two alternative reduction routes were considered i.e., the direct CO2 dissociation against the hydrogen-assisted CO2 transformation through formate and carboxylate into CO and formic acid. Our results show that CO2 in the C2v mode is the precursor to the formation of both products i.e., CO and formic acid. Both the formation and transformation of CO2 in the Cs and flip-C2v is challenging kinetically and thermodynamically compared to the C2v mode. The formic acid formation is favoured over CO via the reverse water gas shift reaction mechanism on Fe (100). Both formic acid formation and CO formation will proceed via the carboxylate intermediate since formate is a stable intermediate whose transformation into formic acid is challenging both kinetically and thermodynamically.
Graphic abstract
Influence of two polyphenols on the structure and lubrication of salivary pellicle: An in vitro study on astringency mechanism
Authors: Lei Lei , Tang Yue , Zheng Jing , Ma Genlei , Zhou Zhongrong 
Published: April 2021

AbstractThis study investigated the influence of two polyphenols on the structure and lubrication of the salivary pellicle, aiming to extend the understanding of astringency mechanisms. The salivary pellicle was prepared by the adsorption of human whole saliva on the enamel substrate. Low-astringency catechin and high-astringency tannic acid were used as astringents. The changes induced by the two polyphenols in the structure and lubrication of the salivary pellicle were examined using quartz crystal microbalance with dissipation (QCM-D) and nano-indentation/scratch technique. The salivary pellicle suffers from changes in structure and physical properties owing to protein dehydration and protein-polyphenol complexation when encountering polyphenolic molecules, causing increases in the roughness and contact angle but a decrease in the load-bearing capacity. Therefore, the lubrication performance of the salivary pellicle is impaired, leading to an increase and fluctuation of the friction coefficient. The intensity of astringency has a strong positive correlation with the water contact angle, surface roughness, and friction coefficient of the salivary pellicle. In summary, astringency is a tactile perception driven by the roughness and wettability of the salivary pellicle rather than oral lubrication, and increased intraoral friction is an inevitable consequence of astringency. The findings of this study will help promote and assist the objective evaluation of astringency.
Efficient Personalized Influential Community Search in Large Networks
Authors: Wu Yanping , Zhao Jun , Sun Renjie , Chen Chen , Wang Xiaoyang 
Published: April 2021

AbstractCommunity search, which aims to retrieve important communities (i.e., subgraphs) for a given query vertex, has been widely studied in the literature. In the recent, plenty of research is conducted to detect influential communities, where each vertex in the network is associated with an influence value. Nevertheless, there is a paucity of work that can support personalized requirement. In this paper, we propose a new problem, i.e., maximal personalized influential community search. Given a graph G, an integer k and a query vertex u, we aim to obtain the most influential community for u by leveraging the k-core concept. To handle larger networks efficiently, two algorithms, i.e., top-down algorithm and bottom-up algorithm, are developed. In real-life applications, there may be a lot of queries issued. Therefore, an optimal index-based approach is proposed in order to meet the online requirement. In many scenarios, users may want to find multiple communities for a given query. Thus, we further extend the proposed techniques for the top-r case, i.e., retrieving r communities with the largest influence value for a given query. Finally, we conduct extensive experiments on 6 real-world networks to demonstrate the advantage of proposed techniques.
BODIPY-based fluorescent polymeric probes for selective detection of Fe3+ ions in aqueous solution
Authors: Xiao Li , Li Chunqing , He Xiantinglv , Cheng Xinjian 
Published: April 2021

AbstractIt is of scientific and practical significance to sense and to remove heavy metal ions in the environment. In this work, four BODIPY-based fluorescent polymeric probes with the ability to sense and separate Fe3+ ions have been prepared via thiol-ene click reaction. The polymers have good thermal stability. Meanwhile, the results show that they have selective recognition capabilities only for Fe3+, which are mainly manifested as significant quenching of fluorescence and color modulation under visible light. The sensitivity is good, and the limit of detection reaches as low as 0.14 µM. They can also be used as reversible chemical probes to detect Fe3+. Therefore, the click reaction provides us with a facile method for preparing fluorescent polymer probes.
Modular Approach to Ultra-fast Charging Stations
Authors: Leone Carola , Longo Michela 
Published: April 2021

AbstractRoad transport electrification is essential for meeting the European Union's goals of decarbonization and climate change. In this context, an Ultra-Fast Charging (UFC) system is deemed necessary to facilitate the massive penetration of Electric Vehicles (EVs) on the market; particularly as medium-long distance travels are concerned. Anyway, an ultra-fast charging infrastructure represents the most critical point as regards hardware technology, grid-related issues, and financial sustainability. Thus far, this paper presents an impact analysis of a fast-charging station on the grid in terms of power consumption, obtained by the Monte Carlo simulation. Simulation results show that it is not economical convenient size the assumed ultra-fast charging station for the maximum possible power also considering its high impact on the grid. In view of the results obtained from the impact analysis, the last part of the paper focuses on finding a method to reduce the power installed for the DC/DC stage while keeping the possibility for the electric vehicle to charge at their maximum power. To achieve this goal a modular approach is proposed. Finally, two different modular architectures are presented and compared. In both the solutions, the probability of having EVs charging at limited power is less than 5%.
The performance of ultra-lightweight foamed concrete incorporating nanosilica
Authors: Abd Elrahman Mohamed , Sikora Pawel , Chung Sang-Yeop , Stephan Dietmar 
Published: April 2021

Abstract
This paper aims to investigate the feasibility of the incorporation of nanosilica (NS) in ultra-lightweight foamed concrete (ULFC), with an oven-dry density of 350 kg/m3, in regard to its fresh and hardened characteristics. The performance of various dosages of NS, up to 10 wt.-%, were examined. In addition, fly ash and silica fume were used as cement replacing materials, to compare their influence on the properties of foamed concrete. Mechanical and physical properties, drying shrinkage and the sorption of concrete were measured. Scanning electron microscopy (SEM) and X-ray microcomputed tomography (µ-CT) and a probabilistic approach were implemented to evaluate the microstructural changes associated with the incorporation of different additives, such as wall thickness and pore anisotropy of produced ULFCs. The experimental results confirmed that the use of NS in optimal dosage is an effective way to improve the stability of foam bubbles in the fresh state. Incorporation of NS decrease the pore anisotropy and allows to produce a foamed concrete with increased wall thickness. As a result more robust and homogenous microstructure is produced which translate to improved mechanical and transport related properties. It was found that replacement of cement with 5 wt.-% and 10 wt.-% NS increase the compressive strength of ULFC by 20% and 25%, respectively, when compared to control concrete. The drying shrinkage of the NS-incorporated mixes was higher than in the control mix at early ages, while decreasing at 28 d. In overall, it was found that NS is more effective than other conventional fine materials in improving the stability of fresh mixture as well as enhancing the strength of foamed concrete and reducing its porosity and sorption.
Unicorn paths and hyperfiniteness for the mapping class group
Authors: Przytycki Piotr , Sabok Marcin 
Published: April 2021

Abstract
Let S be an orientable surface of finite type. Using Pho-on’s infinite unicorn paths, we prove the hyperfiniteness of orbit equivalence relations induced by the actions of the mapping class group of S on the Gromov boundaries of the arc graph and the curve graph of S. In the curve graph case, this strengthens the results of Hamenstädt and Kida that this action is universally amenable and that the mapping class group of S is exact.
Three-dimensional stromatolites from Maastrichtian–Danian Yacoraite Formation, Argentina: modelling and assessing hydrodynamic controls on growth patterns
Authors: Villafañe Patricio Guillermo , Cónsole-Gonella Carlos , Citton Paolo , Díaz-Martínez Ignacio , de Valais Silvina 
Published: April 2021

AbstractStromatolites are biogenic sedimentary structures formed by the interplay of biological (microbial composition) and environmental factors (local hydrodynamic conditions, clastic input and/or water chemistry). Well-preserved, three-dimensional (3D) fossil stromatolites are key to assessing the environmental factors controlling their growth and resulting morphology in space and time. Here, we report the detailed analysis of well-exposed, highly informative stromatolite build-ups from a single stratigraphic horizon within the Maastrichtian–Danian Yacoraite Formation (Argentina). This study focuses on the analysis of depositional processes driving intertidal to shallow subtidal stromatolites. Overall depositional architecture, external morphology and internal arrangement (mega, macro, meso and microstructures) of stromatolite build-ups were analysed and combined with 3D photogrammetric models, allowing us to decipher the links between stromatolite structure and tidal dynamics. Results suggest that external morphology and architecture of elongated and parallel clusters grew under the influence of run-off channels. The internal morphology exhibits columnar structures where the space between columns is interpreted as recharge or discharge channels. This work supports the theory that stromatolites can be used as a high-resolution tool in the assessment of water dynamics, and provides a new methodological approach and data for the dynamic reconstruction of intertidal stromatolite systems through the geological record.
Evaluating resident involvement and the ‘July effect’ in parotidectomy
Authors: Benito D A , Mamidi I , Pasick L J , Sparks A D , Badger C , Thakkar P , Goodman J F , Joshi A S 
Published: April 2021

AbstractObjectiveThis study aimed to evaluate the effect of resident involvement and the ‘July effect’ on peri-operative complications after parotidectomy.MethodThe American College of Surgeons National Surgical Quality Improvement Program database was queried for parotidectomy procedures with resident involvement between 2005 and 2014.ResultsThere were 11 733 cases were identified, of which 932 involved resident participation (7.9 per cent). Resident involvement resulted in a significantly lower reoperation rate (adjusted odds ratio, 0.18; 95 per cent confidence interval, 0.05–0.73; p = 0.02) and readmission rate (adjusted odds ratios 0.30; 95 per cent confidence interval, 0.11–0.80; p = 0.02). However, resident involvement was associated with a mean 24 minutes longer adjusted operative time and 23.5 per cent longer adjusted total hospital length of stay (respective p < 0.01). No significant difference in surgical or medical complication rates or mortality was found when comparing cases among academic quarters.ConclusionResident participation is associated with significantly decreased reoperation and readmission rates as well as longer mean operative times and total length of stay. Resident transitions during July are not associated with increased risk of adverse peri-operative outcomes after parotidectomy.
Physicians and Lawyers: Science, Art, and Conflict
Authors: Gibson Joan M. , Schwartz Robert L. 
Published: April 2021

Abstract
The relations between physicians and lawyers have deteriorated rapidly
over the past several decades, most particularly since the early 70s when
the perception that a medical malpractice crisis existed in America became
widespread. Some believe that the factors dividing the two professions are
linked (1) to professional jealousy, (2) to sometimes conflicting economic
interests, or (3) to difficulties in communication, since both professions
use many of the same words, or terms of art, but with different intended
meanings.
While the authors agree that these factors may have aggravated the
problem, they believe that the conflict’s real roots are in the very
different ways in which physicians and lawyers are trained and in the
different epistemologies that each profession has accepted, as a result of
which each reasons and solves problems in a manner that not only diverges
from but sometimes contradicts the other’s. The authors conclude that only
as the varying epistemologies begin to converge can physicians and lawyers
begin to approach problems in more similar ways, and to discover the
underlying compatibility of many of their interests and goals.
The Battle over Blood Collection
Authors: Stewart Douglas W. 
Published: April 2021

AbstractThe struggle for control of this nation's life-giving blood resources was, up until five years ago, largely a private affair between representative organizations of the blood collectors. The system that emerged from that struggle was declared unhealthy by several experts who complained that blood was too often unsafe or unavailable. Then in 1972 the government, predominantly the federal government, responded to public pressure and joined the fray. This Comment examines some legal, political, and policy aspects of the battle over blood collection—a battle from which no stable guiding force has yet evolved.