bluuebunny/crossref_metadata_2025_split huggingface dataset:
The influence in difference of compatibilizers on the mechanical and rheological properties of LDPE/PLST blends
Authors: Saki Tahseen A 
Published: November 2021

Abstract
In this present study, low density polyethylene/plasticizer starch (LDPE/PLST) blends were prepared as a product to be used in disposable packaging (film applications), reducing the negative polymeric environmental effect. Because of their different molecular structures, LDPE blends with starch are fully immiscible; therefore, a compatibility agent is required. Three different polymer and/or copolymer: poly (vinyl alcohol) hydrolyzed 75% (PVOH), styrene-allyl alcohol copolymer (SAA) and polyethylene glycol (PEG) were selected as compatibilizers containing –OH groups. The effects of compatibilizer on the mechanical and rheological properties of LDPE/PLST blends were investigated and compared to LDPE/PLST without compatibilzer. The blends are also characterized by FTIR, which strongly indicates the existence of compatibilizers that can enhance phase interaction and promote compatibility in the blends of LDPE/PLST. Comparing to the blend without a compatibilizer, the tensile strengths of the blends containing PVOH and SAA increased significantly. The elongation at break results shows similar observation. The rheological measurement results suggested that the addition of a compatibilizer exhibited an increase in the shear stress and apparent viscosity comparing to the uncompatibilized blend except the blend with PEG which exhibited phase separation.
Spectrophotometric assay of Nicotinamide in Pharmaceutical Dosages
Authors: Saleem Basima A A , Hamoo Raghad A M , Ismail Ghassan Q 
Published: November 2021

Abstract
The reaction of nicotinamide and alizarin reagent using charge transfer reaction at a pH of 5.54 lead to produce a red colored compound measured at 527 nm., while the blue colored complex was formed using the oxidation reduction reaction between nicotinamide and chromate at pH 3.49 in the presence of an indigo cochineal dye. Theses tow colored products were measured at 527 and 610 nm respectively using two simple, fast and an accurate spectrophotometric methods. The linearity of the charge transfer method was followed Beer’s law 0.4 - 32 μg while the oxidation reduction method was obeyed Beer’s law from 1.6 - 40 μg in depending on the concentration range. Molar absorptivity was 1.95×104 and 2.16×104 mol−1 cm−1 for the red and blue colored complex respectively. Finally, the values of Sandal’s sensitivity were 0.00626 and 0.00565 μg−2 cm−1 for the first and second methods respectively. These two methods have been applied to quantify the amount of nicotinamide in pharmaceuticals with good recovery.
Estimation and evaluation of medicinal efficacy of maximum inhibitory concentration of alkaloids extracted from Iraqi Cordia myxa leaves against some pathogenic bacteria
Authors: Al-Maliki Abbas D M , Aboud Maitham N , Hameed Mustafa F 
Published: November 2021

AbstractCordia myxais considered as one of traditional medicinal plants abundant in many countries including Iraq. Because of the healthy importance of this plant therefore the current research was established to extract the alkaloids from the its leaves with extraction percentage equal to 5.8% Preliminary qualitative detections were achieved for the alkaloids by using various chemical reagents. The medicinal efficacy of these alkaloids was determined depending on maximum inhibitory concentration (Max IC) which has value equal to 150 mg/ml and this concentration recorded inhibition zone diameters values equal to 30,22,26,25 and 30 mm againstStaphylococcus aureus, Escherichia coli, Pseudomonas aeroginosa, Proteus Sp.andklebsiella Sp.bacteria. SoCordia myxaleaves alkaloids can be used as natural chemical drug to treat the most infections and inflammatory caused by these pathogens.
Isolation and identification of some pathogenic species of Fungi from Shatt-al-Arab River
Authors: Al-Ibraheem Shrouk Abdulrazak Hassan , Al-Zeadei Angham O S 
Published: November 2021

Abstract
This study aimed to isolation and identification of pathogenic fungi from Shatt – al-Arab River in Basra city, Fourteen water samples were collected from different area from Shatt-al-Arab River (AL Ashar, AL Tnoma, AL Makal, AL Qurna, AL Karma, AL Jabiluh, AL-Hartha), from October to December in 2017, with 250 ml volume, this samples centrifuged at 5000 rpm for 10 min at room temperature, the floating was removed and then take the precipitate and pour directly into the center of the media of SDA and PDA and then incubation in a temperature range25-27c for 4 days after that the growth on the media made pure culture and each fungi species diagnosed based on the cultural and microbiological phenotypes, smear prepared with lacto phenol cotton blue stain and the results show 57.1% of growth was Aspergillus niger, 85.7% Aspergillus flavus and 42.8% was Aspergillus candidus and 14.2% was Rhizopus, while the results show 42.8% of growth was Penicillium..
Synthesis of some new Rhodium complexes containing diaryl chalcogenide ligands and their uses as catalysts in hydrosilylation of alkenes
Authors: Al-Rubaie Ali Z , Kadhim Zaki N , Al-Luaibi Majeed Y , Sabri Luma 
Published: November 2021

Abstract
Diaryl Chalcogenides (i.e. Ar2E where Ar = 4-CH3C6H4, 4-BrC6H4, E= S, Se and Te) were reacted with [RhCl(CO)2]2 and rhodium(III) chloride trihydrate to give compounds of type [RhCl(CO)2(Ar2E)] and [RhCl3(Ar2E)3], respectively. All compounds were characterized by IR, NMR, and mass spectroscopic data. Attempts to prepare hydroxyapatite (HAp) supported rhodium catalyst by using different methods were unsuccessful. Complexes [RhCl(CO)2((4-R-C6H4)2S)], [RhCl(CO)2((4-R-C6H4)2Se)] and [RhCl(CO)2((4-R-C6H4)2Te), where R= CH3 or Br], were evaluated as catalysts for hydrosilylation of allyl phenyl ether and 1-decene. They showed good catalytic activities for hydrosilylation of alkenes with triethoxysilane.
Preparation, Characterization and Analytical Studies of novel Azo dyes and Diazo dyes
Authors: Mutar Muthanna M , Ali Hanan M 
Published: November 2021

Abstract
The amino {4-hydroxy-3-[(E)-{4-[(5-methylisoxazol-3-yl) sulfamoyl] phenyl} diazenyl] phenyl} acetic acid (1) and the amino {4-hydroxy-3,5-bis[(E)-{4-[(5-methylisoxazol-3-yl) sulfamoyl] phenyl} diazenyl] phenyl} acetic acid (2) were Prepared. The resulting azo and diazo dyes were then characterized using m.p., IR, UV-visible, mass spectrum and 1H-NMR spectrum. Analytical studies were carried on the azo dye (1) and the diazo dye (2). The best solubility of (1) and (2) was in methanol and ethyl acetate respectively, with no deviation from the linear relationship in each dye, which is due to the fact that the effect of the dielectric constant is the main factor that can control the shift of the absorption beaks. Though, the pH effects of (1) and (2) in a range of buffer solution were showed one and two isopiestic points respectively. Calculation of the ionization (pKa) and the protonation (pKp) constants by using the half height method was associated to the nitrogen atom and the OH-groups respectively. The pKp1, pKa1 and pKa2 were also intended. But, the value of the pKp2 was absent in the azo dye (1) and seems to be equal to 2.5 in the diazo dye (2). These results were indicated the suggested ionization scheme in acidic and basic medium of each dye. Furthermore, the dyes with different concentrations have harmless, nontoxic and no haemolysis effects.
Preparation, analytical Studies and application of a New Azodye Derived from Pharmaceutical Materials (Procaine Hydrochloride & Salicylic acid)
Authors: Thuiny Huda T , Fahad Tarek A , Ali Asaad A 
Published: November 2021

Abstract
Procaine hydrochloride was used as an aromatic amine, and salicylic acid (5-[2-(diethylamino)-4-benzoateazo]-2-hydroxybenzoic acid) was used to make a new azodye derived from pharmaceutical materials ( PS ).C.H.N., H1-NMR, I.R., and visible spectroscopic techniques have also been used to characterize dye. At different pH values ( 2 - 12 ), the electronic spectra of this azo dye was investigated in terms of acid-base properties, which included defining isobestic points and determining protonation and ionization constants. The effect of different polarities of solvents on the electronic spectra was the subject of another study. The dye has been used in a variety of applications, including as an indicator for strong acid with strong base and for nitrite determination.
Study the fluorescent and conductivity properties of a 4-hydroxy-3-nitro-1,8-naphthalic anhydride
Authors: Al-Aqar Roza 
Published: November 2021

AbstractThe compound of (4-hydroxy-3-nitro-1,8-naphthalic anhydride) and the dopant material (4-hydroxy-m-benzene-disulfonic acid) were synthesized. The UV-Vis absorption and fluorescence spectra of the compound were recorded. The bathochromic shifts in absorption due to the changes in the solvent polarity was observed, in DMSO solvent, the compound shows different peaks, three bands in the UV region and one band in the visible region, one absorption peak at 402 nm, which might be attributed to the (ICT) band. The emission spectra of this compound were sensitive to the solvent polarity. They moved to lower energies with increasing the polarity of the solvent. The influence of the solvent polarity on the fluorescence maximum was more pronounced compared with the absorption maximum, showing ca. 3 nm red shift on moving from butanol to DMSO. The effect of the dopant material on the conductivities (ionic and specific) of the compound was studied, the ionic conductivity was increased as the weight of the dopant material increases, and the ionic conductivity (G) was measured in water as a solvent. the (G) of the compound was 2.4X10-6Siemens at 0.01 gm of the dopant material, and was 2.62X10-4Siemens after the dopant material was added (0.1 gm).
Combined CFA-AFM Analytical approach for precipitation reaction regarding crystal growth building single and multiple monolayers based on surface area calculation with image surface roughness analysis (unseen surface)
Authors: Shakir Ali Issam Mohammad , Shakir Nagham , Turkie  , Hussein Fares Abd Al-razackAbd 
Published: November 2021

Abstract
A reaction of Mebeverine hydrochloride (0.03mM) in pure form with sodium nitroprusside (0.07mM) to form OFF White precipitate. A constant feed was used to collect an enough amount in weight for AFM study. Continuous flow injection analysis was conducted as it is the aim of this study to combine FIA with AFM. To elucidate the study of surface morphology. Various parameters of AFM image surface roughness analysis were discussed in relation to the kind of precipitate formed. Skewness, kurtosis, peak-peak, ten peak height, fractal dimension, wavelength, core roughness depth, and reduced valley depth. All these with the four parameter mainly amplitude, hybrid, functional and spetial. Since no previous study of such was conducted; all usual mode of imaging was dealt with i.e., contact, non-contact and intermittent contact was defined. A non contact mode was used in this study. A detailed study of how the crystal growth buildup first mono layer (hypothetical based on the date obtained also how much each grain carry a concentration with the number that are on the first mono layer. Number of given samples of surface area calculation plus a demonstration of the hypothetically formed multi mono layers specially at high reactant concentration. The main aim of this project was the binding of AFM with FIA which is regarded as an new approach which might be a very useful knowledge for other researcher.
Xylanase Production via Aspergillus niger: Effect of Carbon Source and Composition
Authors: Tan C.Z. , Chang W. T. , Tarrsini M. , Teoh Y. P. , Lee K. C. , Kunasundari B. , Ng Q. H. , Ooi Z. X. , Low C. Y. 
Published: November 2021

Abstract
Xylanases are secondary metabolite product of variety organisms from various agriculture wastes. Xylanases’ demands in industrial level are increasing. Precisely, the necessity of enzyme such as xylanase to breaks down the xylan into reducing sugar for biofuel production is inevitable. However, the production of xylanases is insufficient to support the market demand. Hence, Aspergillus niger is used as the xylanase producer in this research. In this study, effect of carbon sources (corn cob-based xylan (CCX) and empty fruit bunches (EFB)) and concentrations of carbon source (2.5g/L to 4.0g/L) on xylanase production through One-factor-at-time (OFAT) experimental technique were investigated. The optimum fermentation period of 5 days determined by using mycelial dry cell mass and Bradford protein concentration growth profile is 5 days was set as the incubation period. Among these data, both carbon sources shown the maximum value at concentration of 3.5g/L. CCX showed a higher xylanase concentration (0.882±0.005μg/mL) compared to EFB (0.533 ± 0.006μg/mL). Hence, among these data analysis CCX has a better performance compared to EFB. Hence, among these data analysis CCX has a better performance compared to EFB.
The Influence of Compounding Parameters on the Electrical Conductivity of LDPE/Cu Conductive Polymer Composites (CPCs)
Authors: Badrul Farah , Halim Khairul Anwar Abdul , Salleh MohdArif Anuar Mohd , Osman Azlin Fazlina , Muhamad Nor Asiah , Zakaria Muhammad Salihin , Saad Nurul Afiqah , Noor Syatirah Mohd 
Published: November 2021

Abstract
Low-linear density (LDPE) and copper (Cu) were used as main polymer matrix and conductive filler in order to produce electrically conductive polymer composites (CPC). The selection of the matrix and conductive filler were based on their due to its excellence properties, resistance to corrosion, low cost and electrically conductive. This research works is aimed to establish the effect of compounding parameter on the electrical conductivity of LDPE/Cu composites utilising the design of experiments (DOE). The CPCs was compounded using an internal mixer where all formulations were designed by statistical software. The scanning electron micrograph (SEM) revealed that the Cu conductive filler had a flake-like shape, and the electrical conductivity was found to be increased with increasing filler loading as measured using the four-point probe technique. The conductivity data obtained were then analysed by using the statistical software to establish the relationship between the compounding parameters and electrical conductivity where it was found based that the compounding parameters have had an effect on the conductivity of the CPC.
Effect of Thermal Treatment on Natural Dolomite
Authors: Abdullah Siti Fatimah Azzahran , Saleh Siti Shuhadah Md , Mohammad Nur Farahiyah , Idris Mohd Sobri , Saliu H. R. 
Published: November 2021

Abstract
Dolomite is a mineral material that is formed from limestone which is mostly contains the calcite (CaCO3) and magnesite (MgCO3). This paper aimed to study on thermal decomposition of dolomite under air atmosphere. Calcination of dolomite was carried out by using furnace with heating rate of 10 °C/minute in an air atmosphere. The different temperature of calcination was varied at 400 °C, 600 °C, 800 °C, and 1000 °C within 6 hours. Phase analysis (XRD) and functional group analysis (FTIR) were carried out to analysis the dolomite after calcination. Microstructural (SEM) and Energy Dispersive X-ray (EDX) analysis showed that the main constituents of pure dolomite include CaCO3 (calcite), MgCO3 (magnesite), CaO, and MgO. From the results, XRD showed that the high intensity of CaO and MgO at 800 - 1000 °C was much stronger than that of dolomite at 400 - 600 °C. In addition, FTIR presents strong and intense bands are observed at 3632.23 and 3690.98 cm−1 (800 °C), and also 3694.03 and 3633.60 cm−1 (1000 °C) due to the calcium oxide.
Processing and Characterisation of Charcoal Briquettes Made from Waste Rice Straw as A Renewable Energy Alternative
Authors: Adam Syed Nuzul Fadzli Syed , Aiman Jamil Haer Muhammad , Zainuddin Firuz , Hamdan Yahya 
Published: November 2021

Abstract
In Malaysia, waste paddy plant after rice harvesting were abundant and have no commercial value and significant usage. This paddy waste is commonly burnt on the landfilled which cause open firing and leads to environmental problem. This study determines the potential of rice straw waste for charcoal briquette production and study the effect of using different binders (corn and tapioca starch) in making the briquettes. Raw rice straws were combusted at 260°C for 4 hours in oven to form char powder. Corn starch and tapioca starch used as binder and each of them was mixed with char powder before compacted into briquettes. Each briquette was characterized in terms of their bulk density, moisture content, ash content, compressive strength and flammable characteristics. It was found that corn starch-charcoal briquette showed higher ash content, higher bulk density and compressive strength up to 68 MPa. Increased of both binders has increased the bulk density and compressive strength of briquettes. Both type of charcoal briquettes showed similar ignition time and burning characteristic, approximately at 18 minutes and 0.08 gm/min respectively.
Effect of Nickel-Coated Precipitated Calcium Carbonate on Corrosion Properties of Sn-9Zn Solder
Authors: Leong Wai Keong , Mohamad Ahmad Azmin , Nazeri Muhammad Firdaus Mohd 
Published: November 2021

Abstract
The effect of 0.5 wt. % Nickel (Ni)-coated precipitated calcium carbonate (PCC) additions on the corrosion properties of Sn-9Zn solder was investigated in 3.5% sodium chloride (NaCl) solution employing potentiodynamic polarization. The morphological differences before and after corrosion analysis have been investigated to support the findings. The scan rate used was 1 mVs−1 after stable potential developed. Slight improvement of corrosion potential (Ecorr) with a significant reduction in corrosion current (icorr) was seen for the Sn-9Zn/Ni-coated PCC compared to Sn-9Zn, indicating the kinetics of corrosion reaction was reduced. The current consumed under the passivation stage for the Sn-9Zn/Ni-coated PCC was also smaller, highlighting that further corrosion protection was improved. Microstructural observation also verified that the number and size of blackish spot clusters were reduced for the Sn-9Zn/Ni-coated PCC, revealing that Ni-PCC additions improve the overall corrosion performance of Sn-9Zn solder.
Effects of different pH of 3.5% NaCl solution on steel under zero charge corrosion protection technique
Authors: Wardan Rajaselan , Shamsudin Shaiful Rizam , Sampasivam Thivyasai , Wahid Mohd Fitri Mohamad , Yati Mohd Subhi Din 
Published: November 2021

Abstract
The study is carried out to understand the new corrosion protection technique, non-polarization concept, using current/voltage pulses to achieve a potential of zero charges (Epzc) of the metal-solution interface. As a result, a cost-saving and ecological method has been proposed as a new anti-corrosion method. In the methodology, U-bend samples are immersed in a 3.5% NaCl solution with different pH values. The readings prove the occurrence of electrochemical reaction, absence of charges, and the effect of Epzc. An examination on the ZCCP on low-carbon steel in 3.5% NaCl solution was analyze for 120 hours days. This study is carried out to understand the concept of corrosion behaviour and a new corrosion protection technique which applies non-polarization concept. A U-bend mild steel is used to corrosion effect in various pH values under zero charge protection. Samples were then immersed in 3.5% NaCl solution with different pH values. Electrochemical behaviour of steel sample in 3.5% NaCl solution was analysed by means of Tafel extrapolation. It was found that Ecorr and icorr recorded dissimilar readings at different pH values. As Ecorr rises, icorr drops from pH 6 to pH 9, hence corrosion rate also decreases from pH 6 to pH 9. Zero charge corrosion protection (ZCCP) technique is used to study the efficiency of corrosion protection method in different pH values. Readings of alternating current (IAC) and direct voltage (VDC) are recorded throughout the ZCCP experiment. These readings prove the occurrence of electrochemical reaction, absence of charges and the effect of Epzc.
Different Setup of Capacitive Coupling Protection System on Mild Steel
Authors: Ahmad Wan Mohd Haqqi Wan , Salleh Siti Hawa Mohamed , Shamsudin Shaiful Rizam , wardan Rajaselan , Yati Mohd Subhi Din , Gunasilan Mahalaksmi 
Published: November 2021

Abstract
A Capacitive Coupling Corrosion Protection (CCCP) technology based on coupler pads was investigated. The layout of the coupler pads on the mild steel surface was studied to get the best outdoor corrosion protection. A square wave of current/voltage is supplied to the steel surface for 72 hours via a copper coupler pad in three arrangements, i.e., single, double-sided, and opposite configurations. The efficiency of the CCCP configuration was assessed by measuring electrical current consumption, weight loss, and post-experimental surface morphology observations. It is found that the current consumption of 600 μA/cm2 in the double-sided configuration is practically stable. The lowest weight loss and clean surface morphology also prove that the double-sided configuration can improve the corrosion protection of mild steel. It was discovered that by employing more coupling pads on both sides of the metal sheet, the excessive positive charge capable of producing oxidation of mild steel could be easily discharged.
Microstructure and Phase Investigation of Sn-58Bi-xCu Lead-Free Solder After Immersion in Sodium Chloride Solution
Authors: Samsudin Rabiatul Adawiyah , Wong Wei Yee , Nazeri Muhammad Firdaus Mohd , Singh Pramod K , Othman Rosli , Masri Mohamad Najmi 
Published: November 2021

Abstract
The changes in microstructure and phase of tin-bismuth-copper (Sn-58Bi-xCu) were investigated after immersion in 3.5 wt. % sodium chloride (NaCl) at variations of Cu micro-alloying at 0.25, 0.50, 0.75, 1.00 and 1.25 wt. %. The morphological observation revealed that the long crystal grains of the Cu-rich phase were produced as the amount of Cu increased. The phase analysis shows that at 0.5 wt. % Cu additions, the intermetallic compound od Cu6Sn5 began to form and dominate the microstructure. After immersion in NaCl, a porous structure was seen covering the surface of the ternary solder, indicating the formation of a defective corrosion protection layer. The predominance of Cu6Sn5 is believed to boost the galvanic corrosion coupling potential of the ternary solder. As a result, the more electrochemically reactive phase was pushed to be eliminated during immersion in 3.5 wt.% NaCl solution. Thus the black spots were formed. The presence of Cu6Sn5 was seen to be detrimental to the electrochemical performance of Sn-58Bi-xCu.