bluuebunny/crossref_metadata_2025_split huggingface dataset:
Bouncing back fromCOVID‐19: Individual and ecological factors influence national resilience in adults from Israel, the Philippines, and Brazil
Authors: Ballada Christine Joy A. , Aruta John Jamir Benzon R. , Callueng Carmelo M. , Antazo Benedict G. , Kimhi Shaul , Reinert Maurício , Eshel Yohanan , Marciano Hadas , Adini Bruria , da Silva Juliano Domingues , Verdu Fabiane Cortez 
Published: October 2021

AbstractOne way that countries may differ in responding to the COVID‐19 pandemic is how they withstand extreme adversity while maintaining their societal values and institutions. This study explored national resilience in Israel, the Philippines, and Brazil during the COVID‐19 pandemic. Using Crisis in Context Theory, cross‐national understanding of national resilience was examined by assessing measurement models, exploring country differences in perceptions, and determining its predictors. Data from an internationally diverse sample of 1,587 adults were collected using multiple measures and subsequently subjected to various analytical strategies. Results on the factor structure of NR‐13 demonstrated acceptable fit of both first‐order and higher‐order models for each country, with generally high factor loadings. However, measurement invariance was only supported at the configural level for the first‐order model. Among the three countries, national resilience was highest in Israel, followed by the Philippines, and lowest in Brazil. Taken collectively, both individual and ecological variables contributed a significant variance in national resilience in each country. Community resilience, quality of life, and perceived threats were consistently strong predictors of national resilience across countries. Results are discussed. TheCommunity and Social Impact Statementof the study can be found in the Supplementary Material section.
Follow‐up of two cases of suspected interstitial lung disease following severe COVID‐19 infection shows persistent changes in imaging and lung function
Authors: Cherrez‐Ojeda Ivan , Robles‐Velasco Karla , Osorio María F. , Cottin Vincent , Vergara Centeno José , Felix Miguel 
Published: October 2021

AbstractPhysicians are observing persisting symptoms and unexpected organ dysfunction after severe COVID‐19. In this report, we present the follow‐up of two cases of suspected interstitial lung disease following the viral infection. Up to the last month of follow‐up, both patients presented with persistent changes in imaging and pulmonary function tests.
The Electrochemical cis‐Chlorination of Alkenes
Authors: Strehl Julia , Fastie Cornelius , Hilt Gerhard 
Published: October 2021

AbstractThe first example for the electrochemical cis‐dichlorination of alkenes is presented. The reaction can be performed with little experimental effort by using phenylselenyl chloride as catalyst and tetrabutylammoniumchloride as supporting electrolyte, which also acts as nucleophilic reagent for the SN2‐type replacement of selenium versus chloride. Cyclic voltammetric measurements and control experiments revealed a dual role of phenylselenyl chloride in the reaction. Based on these results a reaction mechanism was postulated, where the key step of the process is the activation of a phenylselenyl chloride‐alkene adduct by electrochemically generated phenylselenyl trichloride. Like this, different aliphatic and aromatic cyclic and acyclic alkenes were converted to the dichlorinated products. Thereby, throughout high diastereoselectivities were achieved for the cis‐chlorinated compounds of >95 : 5 or higher.
Investigation of Bis(Perfluoro‐tert‐Butoxy) Halogenates(I/III)
Authors: Pröhm Patrick , Berg Willi R. , Rupf Susanne M. , Voßnacker Patrick , Riedel Sebastian 
Published: October 2021

AbstractA systematic study of halogenate(I/III) anions with polyatomic ligands is presented. The bis(perfluoro‐tert‐butoxy) halogenates(I) [X(OC4F9)2]−, X=Cl, Br, I, of chlorine, bromine, and iodine are prepared as their tetraethylammonium salts and characterized with IR, Raman, and NMR spectroscopic methods, as well as single‐crystal X‐ray diffraction analyses. Spectroscopical data are supported by quantum‐chemical calculations. Additionally, the bonding situation of the species in question are analyzed and discussed. Furthermore, the oxidation to the corresponding halogenate(III) derivatives was studied. For [Br(OC4F9)2]−, oxidation with elemental fluorine gave [BrF2(OC4F9)2]−. Iodide was directly oxidized by ClOC4F9 to the IIII species [I(OC4F9)4]−, which is a surprisingly inert anion that might be used as a weakly coordinating anion (WCA) in the future. For [Cl(OC4F9)2]−, the decomposition products of the synthetic approaches towards a chlorine(III) system were analyzed.
Difluorocarbene‐Induced Ring‐Opening Difluoromethylation‐Halogenation of Cyclic (Thio)Ethers with TMSCF2X (X=Br, Cl)**
Authors: Zhang Rongyi , Li Qigang , Xie Qiqiang , Ni Chuanfa , Hu Jinbo 
Published: October 2021

AbstractThe ring‐opening difluoromethylation‐halogenation of cyclic (thio)ethers is reported through a simple strategy relying on carbon‐chalcogen bond activation with difluorocarbene. The reaction proceeds through in situ protonation of the previously little‐known difluoromethylene oxonium or sulfonium ylide intermediate followed by ring‐opening with halide ion to afford halogenated acyclic difluoromethyl (thio)ethers that can then be employed for further elaboration. TMSCF2X (X=Br, Cl) are unique reagents to achieve this synthetic purpose, which serve as both the difluorocarbene source and the halide ion source.
Mitosis‐Karyorrhexis Index evaluation by digital image visual analysis for application of International Neuroblastoma Pathology Classification in FNA biopsy
Authors: Bhardwaj Neha , Rohilla Manish , Trehan Amita , Bansal Deepak , Kakkar Nandita , Srinivasan Radhika 
Published: October 2021

BackgroundThe Mitosis‐Karyorrhexis Index (MKI) score is important in neuroblastoma evaluation and in the application of the International Neuroblastoma Pathology Classification (INPC). Currently, it is not standardized for smears. Hence, the aim of this study was to devise and validate methods for MKI evaluation in fine‐needle aspiration biopsy (FNAB) of neuroblastoma.MethodsA total of 50 cases of neuroblastoma diagnosed by FNAB from January 2017 to December 2019 were retrieved, and detailed cytomorphological evaluations were performed. The MKI was evaluated, and the eyeball visual assessment score (EVAS) was compared with the digital image visual analysis score (DIVAS) on cytology smears and corresponding histology sections of cell blocks. The interobserver reproducibility and concordance were calculated. INPC subtyping into favorable and unfavorable groups was performed by the collation of age, MKI, and cytomorphology and was correlated to clinical outcomes.ResultsNeuroblastoma was categorized as undifferentiated (22 of 50) or poorly differentiated (28 of 50) on cytomorphology. The overall concordance for the MKI by 3 observers was 86% (κ = 0.85), and this increased to 98% in the high MKI category. MKI evaluations on smears showed 96% concordance with cell block histology, and the EVAS was concordant with the DIVAS in 86% of the cases. Overall, the MKI was high in 39 cases, intermediate in 4 cases, and low in 7 cases. The INPC category was unfavorable in 90% (n = 45) and favorable in 10% (n = 5) and had significant correlations with outcomes (P = .029).ConclusionsAn MKI assessment on smears by digital image visual analysis is accurate, reproducible, and objective and should be incorporated into the routine reporting of neuroblastoma FNAB for diagnostic schemas as per the INPC.
Effect of Spectator Ligands on Haptotropic Rearrangements of Metal‐Azulene Complexes
Authors: Guzmán‐Espinoza Carlos Víctor , Ledesma‐Olvera Lydia Gabriela , Barquera‐Lozada José Enrique 
Published: October 2021

AbstractAzulene is a very remarkable ligand because of its zwitterionic character and the large variety of ways that it can coordinate with a metal. However, there is little knowledge about the factors that control the diversity of coordination modes in metal‐Azulene complexes. We carry out an energy and electron density analysis in the framework of DFT and QTAIM to understand how the nature of the spectator ligands affects the azulene‘s coordination preference in these systems. The results show that the π back‐donation plays a fundamental role in the coordination preference of the metal and also show that the π‐acidity of spectator ligands can be used to control inter‐ring haptotropic preferences. If the spectator ligands are strong acceptors as CO, the metal centre prefers to coordinate at the five‐membered ring. Meanwhile, poor acidic ligands as amines, favour a coordination to the seven‐membered ring.
Syntheses of Optically Active V‐Shaped Molecules: Relationship Between their Chiroptical Properties and the Orientation of the Stacked π‐Electron System
Authors: Asakawa Ryo , Tabata Daiki , Miki Nanami , Tsuchiya Motoki , Inoue Ryo , Morisaki Yasuhiro 
Published: October 2021

AbstractTwo kinds of optically active V‐shaped molecules were synthesized from enantiopure disubstituted and tetrasubstituted [2.2]paracyclophane as chiral building blocks. The p‐arylene‐ethynylene‐type π‐electron systems in these species were stacked at an angle of 60°, and although the two molecules consisted of the same π‐electron system, the orientations of these systems were different. In addition, their optical properties were almost identical, while in contrast, significant differences were observed between their chiroptical properties. It was therefore suggested that circularly polarized luminescence behavior could be controlled by adjusting the orientation of the stacked π‐electron systems.
Usability evaluation of augmented reality‐based maintenance instruction system
Authors: Wang Chao‐Hung , Lo Wei‐Jen , Wang Mao‐Jiun J. 
Published: October 2021

AbstractThis article presents an augmented reality‐based instruction (ARBI) system for maintenance tasks. A traditional manual instruction method and a computer‐assisted instruction method were compared. Three maintenance instruction methods, three task difficulty levels (low, medium, and high), and the user's gender (male and female) were specified as the independent variables in the experimental design. The dependent variables included task completion time and error rate as objective measures, and system usability scale (SUS) and NASA‐task load index (NASA‐TLX) scores as subjective measures. There were 30 participants (15 males and 15 females) in the experiment. The results indicated that the instruction method and task difficulty significantly affected the task completion time, error rate, SUS, and NASA‐TLX. Among the instruction methods, the ARBI method exhibited the highest SUS score, lowest NASA‐TLX score, shortest task completion time, and minimum error rate. In conclusion, the proposed ARBI method was beneficial for assisting iPhone maintenance tasks.
Investigating the carbon emission aspects of agricultural land utilization in Turkey
Authors: Kara Funda , Bas Tugba , TIrmandioğlu Talu Nimet Hülya , Alola Andrew Adewale 
Published: October 2021

Abstract
As a pathway to environmental sustainability, several approaches to sustainable agriculture practices have consistently been echoed through international government agencies such as the Sustainable Development Goals of the United Nations Development Programme. Given this perspective, this study examines the carbon emission effects of the categories of agricultural land utilization (this includes arable land, permanent cropland, meadows land, and forest land) for Turkey over the period 1988–2019. The study further explores the dimension of carbon dioxide (CO2) emission from agricultural land use for sown crops, fruits and beverages, vineyards, and olives, in addition to the effect of economic expansion. By employing the autoregressive distributed lag empirical approach, the study finds that the use of agricultural land for arable farming and permanent plantation helps to reduce carbon emissions, especially in the long-run, while the impact of meadows is also desirable only in the short-run. Consequently, the study further shows that the use of farmland for fruits and beverages, and vineyard mitigates carbon emission, especially in the long-run. Whereas the use of farmland for olives plantation and fallow exhibits a significant contribution of carbon emission, especially in the short-run with elasticities of 0.91 and 1.48 respectively. Moreover, economic expansion in Turkey causes significant harm to environmental quality in the long-run thereby truncating its short-run desirable environmental effect. In order to sustain the largely efficient agricultural practice in Turkey, the study offers two policy dimensions to the government and the country's stakeholders in the agricultural sector. Integr Environ Assess Manag 2022;18:988–996. © 2021 SETAC
KEY POINTS
We examine categories of land utilization for agriculture in Turkey. Carbon emissions are mitigated through land use for arable and permanent plantation. There is environmental benefit from the use of land for meadows purpose. Using farmland for fruits and beverages, and vineyard mitigates carbon emission.
Intrapulmonary Pharmacokinetic Modeling and Simulation of Cefiderocol, a Parenteral Siderophore Cephalosporin, in Patients With Pneumonia and Healthy Subjects
Authors: Kawaguchi Nao , Katsube Takayuki , Echols Roger , Wajima Toshihiro , Nicolau David P. 
Published: October 2021

AbstractCefiderocol is a siderophore cephalosporin for the treatment of infections caused by gram‐negative bacteria including carbapenem‐resistant strains. The aim of this study was to develop an intrapulmonary pharmacokinetic (PK) model of cefiderocol and assess the PK profile in lungs. An intrapulmonary PK model of cefiderocol was developed using the concentration data in plasma and epithelial lining fluid (ELF) from 7 patients with pneumonia requiring mechanical ventilation and 20 healthy subjects. Subsequently, the model was applied to assess the ELF exposure of 125 patients with nosocomial pneumonia. Monte Carlo simulations were performed to calculate the probability of target attainment for the percentage of time for which free ELF concentrations exceed the minimum inhibitory concentration (MIC) over the dosing interval (%fT>MIC,ELF). The developed model adequately described ELF concentrations and suggested the delayed distribution in ELF for patients with pneumonia compared to healthy subjects. Lung penetration ratio of cefiderocol in patients with pneumonia was calculated to be 34%, which was 1.4‐fold that in healthy subjects. The estimated %fT>MIC,ELF was 100% in most of patients with nosocomial pneumonia, and no PK/pharmacodynamic relationship with %fT>MIC,ELF was found for microbiological or clinical outcome. The probability of target attainment for 100% fT>MIC,ELF was ≥ 99.5% against MICs ≤2 μg/mL and ≥87.0% against MICs ≤4 μg/mL regardless of renal function. The median of simulated ELF trough concentrations at steady state was >4 μg/mL regardless of renal function. These results reveal the adequacy of cefiderocol exposure in plasma and ELF at the recommended dosing regimens adjusted on the basis of renal function in critically ill patients with pneumonia.
Unaccounted for no more: Explicating managers' role in accountability enactment
Authors: Brees Jeremy , Ellen B. Parker 
Published: October 2021

SummaryAccountability research has focused primarily on how subordinates perceive or react to workplace accountabilities and largely ignored how managers choose to enact it. This omission has occurred despite repeated claims that managers hold subordinates accountable to different degrees and in different ways. We conducted a systematic review of accountability research for insights into managers' role in, and differential application of, workplace accountability. Through this review, we inductively developed a model of managerial accountability enactment, which highlights how managers choose to enact accountability in reaction to relevant subordinate events. Research suggests that variations in managers' enactment of accountability depend upon a myriad of individual, organizational, and situational characteristics. We discuss implications and suggest new directions for future accountability research that consider managers' role in the accountability process.
Characteristics and large‐scale drivers of atmospheric rivers associated with extreme floods in New Zealand
Authors: Kingston Daniel G. , Lavers David A. , Hannah David M. 
Published: October 2021

AbstractThe Southern Alps in the South Island of New Zealand are one of wettest places globally, making it critical to understand the mechanisms for delivery of extreme precipitation and river flooding. Atmospheric rivers (ARs) are recognized as key causes of extreme precipitation in New Zealand, but relatively little is known about their large‐scale meteorological drivers. Here, we aim to investigate these hydroclimatological connections for five major South Island catchments located from south–north along the axis of the Southern Alps: Te Anau, Matukituki, Pūkaki, Rakaia and Waiau Toa. For each catchment, the top eight flood events over a 38‐year period are characterized. Specifically, vertically integrated horizontal water vapour transport (IVT), 500 hPa geopotential and 300 hPa winds are examined to quantify the large‐scale atmospheric drivers of flood events. The Kidson synoptic weather classification is also employed to understand better the connection of IVT to New Zealand weather patterns. Intense IVT is associated with flood events for all five catchments and, in most instances, corresponds to AR‐type events. Spatial patterns of IVT display substantial variation between flood events and catchments; however, there are some generalizable patterns. First, clear AR‐type IVT patterns dominate for all catchments (except the Waiau Toa) with AR orientation ranging from westerly to northwesterly. For the most northerly catchment (Waiau Toa), cyclonic zones of high IVT occur instead for some events. Second, AR length varies from those restricted to the Tasman Sea (~2,000 km) to those extending to the west or north of Australia. Third, northwesterly ARs are associated with the passage of a depression in the general westerly circulation, characterized in particular by the Kidson “Trough” weather type. Finally, AR orientation is associated strongly with 300 hPa winds, and in many cases to the general wave characteristics of Southern Hemisphere circulation, particularly the Zonal Wave 3 pattern.
Glacial oscillations during the Bølling–Allerød Interstadial–Younger Dryas transition in the Ruda Valley, Central Pyrenees
Authors: Fernandes M. , Oliva M. , Vieira G. , Palacios D. , Fernández‐Fernández J. M. , Garcia‐oteyza J. , Schimmelpfennig I. , Team Aster , Antoniades D. 
Published: October 2021

ABSTRACTThe Upper Garonne Basin included the largest glacial system in the Pyrenees during the last glacial cycle. Within the long‐term glacial retreat during Termination‐1 (T‐1), glacier fluctuations left geomorphic evidence in the area. However, the chronology of T‐1 glacial oscillations on the northern slopes of the Central Pyrenees is still poorly constrained. Here, we introduce new geomorphological observations and a 12‐sample dataset of 10Be cosmic‐ray exposure ages from the Ruda Valley. This U‐shaped valley, surrounded by peaks exceeding 2800 m a.s.l., includes a sequence of moraines and polished surfaces that enabled a reconstruction of the chronology of the last deglaciation. Following the maximum ice extent, warmer conditions prevailing at ~15–14 ka, during the Bølling–Allerød (B–A) Interstadial, favoured glacial retreat in the Ruda Valley. Within the B–A, glaciers experienced two phases of advance/stillstand with moraine formation at 13.5 and 13.0 ka. During the early Younger Dryas (YD), glacial retreat exposed the highest surfaces of the Saboredo Cirque (~2300–2350 m) at 12.7 ka. Small glaciers persisted only inside the highest cirques (~2470 m), such as in Sendrosa Cirque, with moraines stabilising at 12.6 ka. The results of this work present the most complete chronology for Pyrenean glacial oscillations from the B–A to the YD.
The Safety and Efficacy of Mandibular Distraction Osteogenesis Among Infants Less Than 3 kg
Authors: Taufique Zahrah , Ebert Bridget , Smith Emily C. , Zavala Hanan , Scott Andrew R. , Roby Brianne B. 
Published: October 2021

Objectives/HypothesisMandibular distraction osteogenesis (MDO) is a safe and effective surgery to address respiratory and feeding issues due to micrognathia in patients with Robin Sequence (RS). Previous studies examining postoperative complications in neonates receiving MDO have considered 4 kg as the cut‐off for low weight; however, an increasing number of MDO interventions are performed in infants <4 kg. To determine if a weight <3 kg at time of MDO is a risk factor for postoperative complications or need for subsequent tracheostomy or gastrostomy tube (G‐tube).Study DesignRetrospective chart review.MethodsA retrospective review of all infants <6 months of age undergoing MDO at two tertiary pediatric hospitals from 2008 to 2018. Demographic data, syndromic status, weight, and age at time of surgery, length of postoperative hospital stay, and postoperative outcomes were recorded including tracheostomy placement, G‐tube placement, hardware infection, reintubation, facial/marginal mandibular nerve damage, and need for revision MDO.ResultsSixty‐nine patients with RS were included. The mean age at MDO was 25 ± 20 days and mean weight was 3.32 ± 0.44 kg. There was no statistically significant correlation between weight (P = .699) or age (P = .422) and unfavorable postoperative outcomes. No patients (0%) underwent tracheostomy pre‐MDO. Two patients (2.9%) required tracheostomy postsurgery; neither was <3 kg. Eight patients (11.6%) required a G‐tube postoperatively.ConclusionNewborns <3 kg who undergo MDO experience the same rates of success and complication as larger infants, suggesting that MDO is a safe and efficacious procedure in infants less than 3 kg. Laryngoscope, 132:1295–1299, 2022
“Right” on the day: How the timing of date‐specific promotions influences consumer responses
Authors: Deng Huixin , Jin Liyin , Xu Qian 
Published: October 2021

AbstractWhile it is common for companies to send greetings that include special promotions to their customers on special days (e.g., birthdays, holidays, etc.), consumers express mixed responses to such date‐specific promotions. Building upon the persuasion knowledge model, the present work examines the conditions under which sending date‐specific promotions lead to favorable consumer responses. In four studies, we demonstrate that consumers respond to date‐specific promotions more positively when they are sent in advance than when they are sent on specific days, especially for companies perceived as less warm (vs. warm). Sending promotions on the exact day elicits an ulterior motive inference from consumers regarding the company, which can be alleviated by sending promotions in advance. We further find that this effect is weakened when the message includes only greetings without highlighting specific promotional information. These findings have important implications for marketers regarding how firms should design date‐specific promotions and communicate with their customers.