bluuebunny/crossref_metadata_2025_split huggingface dataset:
Urbanismo participativo: una herramienta docente para tiempos de incertidumbre
Authors: Carrasco Bonet Marta , Fava Nadia 
Published: December 2021

Crises and uncertainties characterise the current life space of future professionals while there is a widening gap between academia and the territorial governance system and society. The teaching of urban planning is questioning itself how to prepare university students for these challenges, taking advantage of this situation to propose adaptive pedagogical methods that emphasise constructive nuances ina creative and participatory way. The experience of the Covadonga Urban Lab (2019-2020), Erasmus +, during the time of the Covid 19 pandemic, multiplied the difficulties and challenges of a process designed by specific objectives and teaching methodologies that included the participation of local actors and various universities. The results showed that open education processes, as well as participatory processes, make it possible to address the desirability of revising not only the academic system, but in parallel, the current model of governance of the territory.
Las crisis y las incertidumbres caracterizan el espacio actual de la vida de los futuros profesionales al tiempo que se produce una brecha cada vez mayor entre el mundo académico y el sistema de gobierno territorial y la sociedad. La enseñanza del urbanismo se cuestiona cómo preparar a los universitarios para estos retos, aprovechando esta coyuntura para plantear métodos pedagógicos adaptativos que destaquen los matices constructivos de forma creativa y participativa. La experiencia del Covadonga Urban Lab (2019-2020), durante la época de la pandemia del Covid 19, multiplicó las dificultades y retos de un proceso diseñado por objetivos concretos y metodologías docentes que incluían la participación de los actores locales y diversas universidades. Los resultados mostraron que los procesos de enseñanza abierta, así como los procesos participativos, permiten atender la conveniencia de revisar no sólo el sistema académico, sino el actual modelo de gobierno del territorio.
Conservation status of sea turtles in Spain (review of the period 2013-2018)
Authors: Camiñas Juan Antonio , Báez José Carlos , Ayllón Enrique , Marco Adolfo , Hernández-Sastre Luis , López María Isabel , Moreno Helena , Macías David , Cardona Luis , Belda Eduardo , Bellido Juan Jesus , Tomás Jesús , García de los Rios y de los Huertos Alvaro , Lopez Alfredo , Zaldua Nagore , Liria Ana , Varo Nuria , Gonzalez Carballo Marta , Carrillo Manuel , García Barcelona Salvador 
Published: December 2021

El presente documento revisa la situación y aporta nuevos datos para las tortugas marinas en España durante el periodo 2013-2018. Se revisa el estado de conservación para el periodo 2013-2018 en cada una de las demarcaciones marítimas españolas: Levante –Baleares y Estrecho-Alborán para el Mediterráneo, y Noratlántica, Sudatlántica y Macaronesia en aguas del océano Atlántico. Se incluyen análisis de tendencias, las presiones y amenazas que afectan a cada especie y bibliografía actualizada. Para Caretta caretta, se recopila la información de los nidos en las costas mediterráneas españolas desde 2013 hasta 2018 y los movimientos de juveniles nacidos en España, tras su liberación.
This document reviews the situation and provides new data for sea turtles in Spain during the period 2013-2018. The conservation status for such period is reviewed in each of the Spanish maritime demarcations: Levante -Baleares and Estrecho-Alborán for the Mediterranean, and Noratlántica, Sudatlántica and Macaronesia in waters of the Atlantic Ocean. Analysis of trends, pressures and threats that affect each species and updated bibliography are included. For Caretta caretta, information is collected on nests on the Spanish Mediterranean coasts from 2013 to 2018 and the movements of juveniles born in Spain, after their release.
Guest editorial - Networked collaboration, sharing and response
Authors: Skundberg Olav 
Published: December 2021

This issue of Seminar.net contains three articles that were written in connection with a Norwegian e-learning conference titled “Networked collaboration, sharing and response”. The conference was held in Mars 2008 in Trondheim, and the presentations from the conference is available (in norwegian language) at http://www.nvu.no. Networked collaboration was chosen as a theme because collaboration is important to achieve learning, according to the social-constructivistic pedagogy that has a strong standing in Norway, but how should this occur on the net? Sharing of content, as in digital learning resources, is a phenomenon with increasing popularity as described in the OECD-report “Giving Knowledge for Free”. But to achieve reuse of content, not only publishing it, it is important with a networked community where the plethora of information can be sorted with relevance to specific topics. Response is about guiding, coaching and tutoring. In what ways may resources and tools be used to move in the direction of solving Bloom’s two sigma problem/challenge? The first article, by Morten Flate Paulsen, shows how cooperative learning can be implemented successfully so that students have optimal individual freedom within online learning communities. The second article, by Carl F. Dons, shows how student teachers can be prepared to deal with pupils who have a wide range of experiences of the digital world. The third and last article, by Kristin Dale, is sharing experiences with multiple choice-tests to give midterm responses to students. In addition, this issue has a commentary article by Rune Krumsvik discussing the need to develop new practices for teachers and students on the background of the digital developments. The conference and articles covers three big themes. It may be difficult to find more important issues, apart from finding money and time to support its development. Olav Skundberg, guest editorAssociate professorSør-Trøndelag University CollegeEmail: olav.skundberg@hist.no
Long-term follow-up of mandibular dental arch changes in patients with complete non-syndromic unilateral cleft lip, alveolus, and palate
Authors: Sumardi Sariesendy , Latief Benny S. , Kuijpers-Jagtman Anne Marie , Ongkosuwito Edwin M. , Bronkhorst Ewald M. , Kuijpers Mette A.R. 
Published: December 2021

Background
Treatment of cleft lip and palate (CLP) requires a comprehensive interdisciplinary approach and long-term follow-up. Only a few studies are available that reported on changes after treatment, which showed that in particular the transverse dimension, in patients with CLP is prone to changes after treatment. However, those studies did not pay attention to concomitant changes in the mandibular arch that occur after treatment.

Objectives
To evaluate mandibular transverse dental arch dimensions and interarch transverse changes in patients with complete non-syndromic unilateral cleft lip, alveolus, and palate (CUCLAP) up to five years after treatment.

Material and Methods
Retrospective longitudinal study in 75 consecutive patients with CUCLAP directly after comprehensive treatment (T0), two (T2), and 5 years after treatment (T5). Great Ormond Street, London and Oslo (GOSLON) scores were available for all patients. Three-dimensional scans of all dental casts were made. Inter premolar and intermolar distances between the mandibular contralateral teeth were measured. The modified Huddart Bodenham (MHB index) was applied to assess the transverse interarch relationship. Paired t-tests and ANOVA were used to analyze transverse and interarch transverse changes. Linear regression analysis was done to define contributing factors.

Results
Paired t-tests showed a significant decrease of the mandibular inter first and second premolar distances (p < 0.05) and an increase of the inter second molar distance, whilst the MHB Index deteriorated at all time points for all segments and for the total arch score (p < 0.05). Linear regression showed no significant contributing factors on the decrease of the transverse distances. However, inter arch transverse relationship was significantly affected by age at the end of treatment, missing maxillary lateral incisor space closure, and the GOSLON Yardstick score at the end of treatment (p < 0.05), especially during the first two years after treatment.

Conclusions
Changes occurred in the mandibular arch expressed as changes in the transverse dimensions and interarch relationship measured by the MHB Index. A younger age at the end of treatment, space closure for a missing maxillary lateral incisor and a higher GOSLON score at the end of treatment negatively influence the interarch transverse deterioration especially in the first two years after treatment. For the transverse dimensional changes in the mandibular arch such influencing factors could not be determined.
The Environmental Implications of the Rohingya Refugee Crisis in Bangladesh
Authors: Halim Md. Abdul , Rinta Sumiya Majumder , Amin Md. Al , Khatun Azmira , Robin Adnan Habib 
Published: December 2021

Purpose: The main focus is to find out the environmental challenges that Bangladesh is dealing for the huge influx of Rohingya refugee people to Bangladesh. The research also aims to assess the dynamic situation of the crisis, identify the roles of Bangladesh government, NGOs as well as the International Organisations’ for Rohingya refugee crisis.
Methodology: This study is context-dependent on information and an inductive data analysis. The paper uses a descriptive qualitative approach case study design that focuses on primary and secondary data showing the real ground of crisis. Data has been collected from the interviewees and experts. This research sets multiple methods of data collection including documents, policy, and historical analysis.
Findings: Environmental imbalance occurred due to allocating 1,000 acres forest land for providing shelters to the refugees. Reserve forest has been destroyed endangering wild elephants. And it is causing landslides in the area, soil erosion, water scarcity, extreme heat wave, extreme rainfall, drought, deforestation, air pollution, and so on.
Conclusion: This research leads to identifying the areas which have already been affected. The plans that need to work on to overcome the problems and that could provide necessary and sustainable solutions for Rohingya refugee. This study also could let people know the catastrophe Bangladesh is dealing and the impacts which can cause the ecological imbalance and failure the biodiversity of the areas in a greater way. This paper could bring benefit to society and make people conscious about the environment and also make them raise voices for the conservation of environment.
Real-time Optimization and Implementation of Multi-rate Digital FIR Kernel Filter
Authors: U. Ufoaroh Stephen , Nnamani Kelvin N. , N. Aniedu Azubuike 
Published: December 2021

One ideal performance of this design is in the areas of decimation where a decimation factor of 10, 45-order and pass band ripple of 1dB and interpolation of sampled rates where a sinusoidal signal input produced a ripple free output with interpolation factor of 10, 52-order and stopband attenuation of 60dB. Owing to the multiple samples of filter length of 200, the filter performed down sampling preceded with filtering as well as up sampling preceded with filtering, hence multi-rate filter by allowing a low threshold of frequency of to be passed, blocking a high threshold of and vice versa. There was resampled output increased to 150% preceded by filtering. The filter coefficients for low pass and high pass Digital FIR filter, through the least square regression method, parks McClellan Algorithm and window methods were employed for easy optimization. More so, there was creation of 2-4-5 filter channel banks through the 2nd-level convolution of their down sampling and up sampling filtering techniques during the multi-irate filtering to ensure the design of error-free Digital FIR Filter using MATLAB File editor(M-File) and tool boxes for writing the C-programming of the design. In the analysis, the mean and standard deviation of the low pass Digital FIR Filter output during decimation and interpolation are (0.26, 6.13) and (0.004,1.22) respectively.
Metal–Organic Frameworks as Enzyme Mimics
Authors: Liebing Phil , Kulak Nora 
Published: December 2021

Abstract
In this article we are presenting the design of metal–organic frameworks (MOFs) for applications as enzyme mimics (artificial enzymes). MOFs have been the topic of current and intense research for various applications ranging from gas storage, catalysis, to sensing. Their biocatalytic activity, however, has been discovered and investigated only recently—literature exists only for the past decade. High stability also at harsh conditions, low cost, and activity that can be tailored are advantages that compete oftentimes lower activity in comparison to the natural enzymes. Among the nanomaterials with enzymatic activity (nanozymes), MOFs are of special potential, since it is possible to mimic not only the active site of an enzyme but also its microenvironment.
We firstly introduce MOFs along with synthetic strategies and secondly give an overview of their nanozymatic activity for oxidation and hydrolytic reactions. This activity has found many applications in biosensing and biomedicine, which are presented in the last chapter of this article. Medicinal applications cover cancer and antimicrobial therapy.
The relation between harsh parenting and bullying involvement and the moderating role of child inhibitory control: A population‐based study
Authors: Hogye Sara I. , Jansen Pauline W. , Lucassen Nicole , Keizer Renske 
Published: December 2021

AbstractHarsh parenting has been linked to children's bullying involvement in three distinct roles: perpetrators, targets (of bullying), and perpetrator‐targets. To understand how the same parenting behavior is associated with three different types of bulling involvement, we examined the moderating roles of children's inhibitory control and sex. In addition, we differentiated between mothers’ and fathers’ harsh parenting. We analyzed multi‐informant questionnaire data from 2131 families participating in the Dutch Generation R birth cohort study. When children were three years old, parents reported on their own harsh parenting practices. When children were four, mothers reported on their children's inhibitory control. At child age six, teachers reported on children's bullying involvement. Our results revealed that fathers’, and not mothers’, harsh parenting increased the odds of being a perpetrator. No moderation effects with children's inhibitory control and sex were found for the likelihood of being a perpetrator. Moderation effects were present for the likelihood of being a target and a perpetrator‐target, albeit only with mothers’ harsh parenting. Specifically, for boys with lower‐level inhibitory control problems, mothers’ harsh parenting increased the odds of being a target. In contrast, for boys with higher‐level inhibitory control problems, mothers’ harsh parenting decreased the odds of being a target. Furthermore, for girls with higher‐level inhibitory control problems, mothers’ harsh parenting increased the odds of being a perpetrator‐target. Overall, our results underscore the importance of differentiating by children's cognitive skills and by parent and child sex to fully understand how harsh parenting and bullying involvement are related.
An Intermediate Unit‐Mediated, Continuous Structural Inheritance Strategy for the Dilemma between Injectability and Robustness of Hydrogels
Authors: Li Sidi , Yu Jiaqi , Zhang Man , Ma Zhenyu , Chen Ning , Li Xueping , Ban Jiamin , Xie Jiunan , Chen Zhennan , Ma Jiasheng , Tian Chunxi , Qin Yashuai , Wang Jian , Gao Weicheng , Long Lixia , Zhao Jin , Hou Xin , Yuan Xubo 
Published: December 2021

AbstractHydrogels with injectability and robustness have great promise in clinical practice. However, current injectable hydrogels are usually mechanically weak. Here, an idea, “preformed hydrogel reversion”, is proposed to develop robust injectable hydrogels through an intermediate unit‐mediated, continuous structural inheritance strategy. In this strategy, robust preformed hydrogels are physically disassembled into intermediate injectable structure‐inherited microgels (SIMs), and upon encountering water in physiological environment, the SIMs can construct a macroscopical robust structure with the driving force of hydrogen bonds (H‐bonds). The physical disassembly and construction process enables the inheritance of robust structures through SIMs, thereby realizing both excellent injectability and robustness. Beyond that, the SIMs also exhibit long‐term storage stability and convenient usability. Using protein drug loading and hemostasis as examples, it is demonstrated that the SIM system shows superiorities in biomedical applications. The proposed idea of “preformed hydrogel reversion” can open new horizons for developing robust injectable hydrogels for diverse applications.
Millimeter‐Sized Clusters of Triple Cation Perovskite Enables Highly Efficient and Reproducible Roll‐to‐Roll Fabricated Inverted Perovskite Solar Cells
Authors: Othman Mostafa , Zheng Fei , Seeber Aaron , Chesman Anthony S. R. , Scully Andrew D. , Ghiggino Kenneth P. , Gao Mei , Etheridge Joanne , Angmo Dechan 
Published: December 2021

AbstractThe high‐power conversion efficiencies (PCEs) of perovskite solar cells (PSCs) on lab‐scale devices trigger the need to develop scalable manufacturing processes to accelerate their commercialization transition. A roll‐to‐roll (R2R) vacuum‐free printing on flexible substrates allows for high‐volume and low‐cost manufacturing which is especially well‐suited for PSCs due to its solution processibility and low‐temperature annealing requirements. Herein, a facile hot deposition technique is reported to fabricate triple‐cation (Cs0.07FA0.79MA0.14Pb(I0.83Br0.17)3) perovskite films in an ambient environment using a R2R slot‐die coating method. This perovskite composition, whilst being most studied in lab devices due to its high efficiency and stability, has not been applied in R2R fabrication thus far. The demonstrated R2R slot‐die coated flexible PSCs achieve stabilized PCE reaching 12% at maximum power point in inverted “p‐i‐n” architectures, the highest efficiency reported to date for R2R inverted PSCs. To achieve this, the underlying hole transport layer (poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate) is modified with guanidinium iodide additive which leads to the formation of large millimeter‐sized perovskite clusters, improved perovskite crystallinity, and enhanced charge‐transfer efficiency. This study highlights the potential of the facile hot‐deposition method while providing critical insights into the role of interfacial engineering in eliminating performance losses and fabricating efficient printed flexible PSCs.
Size‐Dependent Catalytic Behavior of Gold Nanoparticles
Authors: Liang Chen , Cheong Jun Young , Sitaru Gabriel , Rosenfeldt Sabine , Schenk Anna S. , Gekle Stephan , Kim II‐Doo , Greiner Andreas 
Published: December 2021

AbstractGold nanoparticles (AuNP) are widely used for reaction catalysis. The common understanding is that the smaller the particles, the more reactive they are. It is reported here that this is not always the case for citrate (Ct) or polyvinylpyrrolidone (PVP) stabilized AuNP in the catalytic reduction of 4‐nitrophenol with sodium borohydride (NaBH4), when the total surface area is kept constant. The results prove that for AuNP in the size range of 10–58 nm, the reactivity increases with increasing particle diameter for the investigated model reaction. The trend of catalytic activity is independent of the conjugated ligands for citrate and PVP ligands. Purely based on size and resulting surface area, the trend in catalytic activity is unexpected. Only a more detailed structural investigation revealed that internal structure parameters like defect tendency also play a strong role. Larger AuNP possess more defects between crystalline domains. Further, the influence of the ligand density on the surface of AuNP and the diffusion effect of reactants are excluded for the nitrophenol reduction.
Capacitive Ammonia Sensor Based on Graphene Oxide/Polyaniline Nanocomposites
Authors: Wu Chenggen , Han Lei , Zhang Jichao , Wang Yongqing , Wang Rui , Chen LiJun 
Published: December 2021

AbstractToxic and irritant gases such as ammonia in enclosure space could destroy the respiratory system with an unobtrusive way. Monitoring high‐risk gases are imperative when humans expose in a vulnerable environment with unpredictable gases. Capacitive sensors are supposed to be an ideal choice applying to contactless gas sensing in enclosed space. This research develops an innovative model based on barrier capacitance theory for capacitive ammonia sensor. A capacitive ammonia sensor based on graphene oxide/polyaniline (GO/PANI) nanocomposites, which can be attached to enclosure space (pipes, storage tanks, etc.), is manufactured and exhibits high sensitivity (49.3 × 10–5 ppm) and fast response (≈200 s) in the ammonia concentration range of 0–100 ppm. In particular, GO/PANI nanocomposites are modeled as barrier capacitance. The model of ammonia sensor is described as width variation of space charge region in GO/PANI barrier capacitance which is caused by electron injection from adsorbed ammonia molecule. Variation trend of the model is consistent with the experimental results. Maximum deviation is limited to 9.25% in ammonia concentration range of 0–100 ppm between theoretical and experimental results. The model is able to accomplish the accurate quantitative analysis for capacitive ammonia sensors and provides an exhilarating enlightenment for other capacitive gas sensors.
A Rational Molecular Design Strategy of TADF Emitter for Achieving Device Efficiency Exceeding 36%
Authors: Yi Chih‐Lun , Lin Chun‐Yen , Tang Yukun , Wang Chun‐Yu , Huang Chih‐Wei , Gong Xu , Gong Shaolong , Wu Chung‐Chih , Wong Ken‐Tsung 
Published: December 2021

AbstractAn excellent thermally activated delayed fluorescence (TADF) emitter requires a sophisticated molecular design strategy to incorporate structural features to simultaneously achieve high photoluminescence quantum yield (PLQY) and high horizontal emission dipole ratio (Θ//). This work reports the uses of heteroarenes and dicarbonitrile benzenes to design four new acceptors PymCN, PyoCN, PmmCN, and PmoCN, which are linked to a common donor dimethylacridine (DMAC) for making new TADF emitters. The emission wavelength, ΔEST, krisc, kr, and the resulting PLQY of the target TADF emitters are governed by the combined natures of the heteroaryl bridges (Py vs Pm) and the CN‐substituted patterns (o‐CN vs m‐CN). The photophysical and device characteristics reveal the best acceptor to be PyoCN, which is further coupled with spiroacridine to afford a new emitter SpiroAC‐PyoCN with an enhanced PLQY of 100% compared to that (91%) of the DMAC‐based counterpart DMAC‐PyoCN. Furthermore, linking PyoCN with spiro‐bisacridine (SBAC) gives an A–D–A‐configured TADF emitter SBAC‐PyoCN with both enhanced PLQY (100%) and Θ// (90%). The device employing SBAC‐PyoCN as emitter renders a maximum external quantum efficiency up to 36.1% owing to its unity PLQY and superior light out‐coupling efficiency. This rational molecular design strategy provides a feasible means to achieve an excellent TADF emitter design.