bluuebunny/crossref_metadata_2025_split huggingface dataset:
The government contract in the system of the contractual relations in activity of penal system
Authors: Новиков Роман Валерьевич 
Published: November 2021

В статье рассматриваются существующие на сегодняшний день в юридической науке точки зрения на правовую природу государственного контракта. На основе действующего гражданского законодательства и законодательства о контрактной системе, проводится анализ понятий «контракт» и «договор», рассматриваются вопросы правовой природы государственного контракта, особенности правового регулирования и определения условий государственного контракта. Автором выделяются признаки государственного контракта и высказывается авторская позиция относительно места государственного контракта в системе договорных отношений в деятельности УИС, рассматриваются отличия государственного контракта и предпринимательского договора.
The article discusses the points of view on the legal nature of a state contract existing in legal science on the basis of existing civil law and legislation on the contract system, analyzes the concept of a contract, considers the legal nature of a state contract, features of legal regulation and defines the conditions of state the contract. The author highlights the signs of the state contract and expresses the author’s position regarding the place of the state contract in the system of contractual relations, examines the differences between the state contract and the business contract.
Mechanism of interaction of criminal penalties at the stage of execution of the sentence of the court: theoretical and practical issues of punishment replacement
Authors: Звонов Андрей Викторович 
Published: November 2021

Статья посвящена вопросам функционирования системы уголовных наказаний в аспекте взаимодействия ее объектов на стадии исполнения вступившего в законную силу приговора суда. Среди множества форм такого взаимодействия внимание акцентируется на замене наказания как более мягким, так и более строгим наказанием. Индивидуализируя особенности замены отдельных наказаний и дифференцируя их по группам, выявляются проблемные вопросы реализации данного уголовно-правового института. Полученные результаты проведенного исследования позволяют говорить об отсутствии у законодателя системного подхода к формированию и развитию института замены наказаний: в отношении одних наказаний предусмотрены широкие возможности замены наказаний, что в большей степени свойственно наказаниям изоляционной группы, в части других такие возможности весьма ограничены, что в первую очередь свойственно наказаниям, альтернативным лишению свободы, относительно третьих - не предоставляет возможности замены в принципе. В заключение обращается внимание на негативное влияние созданного механизма замены наказаний на функционирование всей системы уголовных наказаний.
The article is devoted to the functioning of the system of criminal penalties in the aspect of interaction of its objects at the stage of execution of a court sentence that has entered into force. Among the many forms of such interaction, attention is focused on the replacement of punishment with both softer and more severe punishment. Individualizing features of replacement of separate punishments and differentiating them on groups, problem questions of realization of this criminal law Institute are revealed. The results of the study suggest that the legislator does not have a systematic approach to the formation and development of the institution of replacement of punishments: for some punishments there are ample opportunities to replace punishments, which is more typical of the punishment of the isolation group, for others such opportunities are very limited, which is primarily characteristic of punishments alternative to imprisonment, for the third-does not provide the possibility of replacement in principle. In conclusion, the study draws attention to the negative impact of the established mechanism of replacement of penalties on the functioning of the entire system of criminal penalties.
The twilight zone of the Earth’s carbon cycle
Authors: Gali Marti , Ruprich-Robert Yohan 
Published: November 2021

The twilight zone of the Earth’s carbon cycle
The oceans’ mesopelagic layer or ‘Twilight Zone’ (200–1,000 m) acts as the gateway for long-term storage of atmospheric carbon in the deep ocean, mitigating global warming due to human carbon emissions. In the OPERA project, we will perform comprehensive model simulations, constrained by observations, to better understand and quantify mesopelagic carbon budgets (and their uncertainty) in the North Atlantic Ocean.
Implikasi Teologis Makna Peristiwa Pentakosta Dalam Kisah Para Rasul 2: 1-13
Authors: Lumbanraja Daido Tri Sampurna 
Published: November 2021

Naturally the discussion about the Spirit leads to the book of Acts which is the basis of the Baptism of the Holy Spirit by the Pentecostal school. As Pentecostalism developed, advocates emerged as people who were trained theologically, so that the discussion became moreweighty with the consensus that the interpretation of Acts must be carried out responsibly by applying correct hermeneutic principles. The author is interested in delving deeper into the text about the Holy Spirit from the events of Pentecost, namely Acts 2: 1-13, by applying hermeneutic principles in an exegetical study. Therefore, this article uses a type of literature research to support exegetical studies of the text of Acts 2: 1-13. The results obtained were in the form of interpretations of the Pentecost event, namely: the moment of the outpouring of the Holy Spirit as the fulfillment of God's promise and the moment of the outpouring was the fulfillment of the promise regarding the Power of the Holy Spirit as empowerment to become a witness of Jesus Christ. This article also includes the theological implications of today's Pentecost events.
Secara natural diskusi mengenai Roh Kudus mengarah pada kitab Kisah Para Rasul yang menjadi landasan pengajaran tentang baptisan Roh Kudus oleh aliran Pentakosta. Seiring dengan berkembangnya aliran Pentakosta, bermunculan para advokat sebagai orang-orang yang terlatih secara teologis, sehingga diskusi menjadi lebih berbobot dengan adanya konsensus bahwa penafsiran Kisah Para Rasul, harus dilakukan secara bertanggung jawab dengan menerapkan prinsip-prinsip hermeneutik yang benar. Penulis tertarik untuk mengkaji lebih mendalam teks mengenai Roh Kudus dari peristiwa Pentakosta, yaitu Kisah Para Rasul 2: 1-13, dengan menerapkan prinsip-prinsip hermeneutik dalam suatu studi eksegesis. Dengan demikian artikel ini menggunakan jenis penelitian kepustakaan untuk mendukung studi eksegesis terhadap teks Kisah Para Rasul 2: 1-13. Hasil yang didapat berupa pemaknaan terhadap peristiwa Pentakosta, yaitu: momen pencurahan Roh Kudus sebagai penggenapan janji Allah dan momen pencurahan adalah penggenapan janji mengenai Kuasa Roh Kudus sebagai pemberdayaan untuk menjadi saksi Yesus Kristus. Artikel ini juga menyertakan implikasi teologis peristiwa Pentakosta pada masa sekarang.
INVESTIGAÇÃO DA PERCEPÇÃO DE NASALIDADE VOCÁLICA NO PORTUGUÊS DO BRASIL
Authors: Souza Maria das Graças Amaral de 
Published: November 2021

Objetivou-se, com o presente trabalho, investigar qual a porção da vogal nasal é responsável por desencadear o processo de percepção da nasalidade vocálica no Português Brasileiro, e avaliar se há interferência da consoante subsequente nesse processo. Para tanto, gravamos o sinal acústico com corpus composto de 58 palavras com estrutura silábica CVC.CV, nas quais as vogais /a/, /i/ e /u/ ocupam núcleo silábico da primeira sílaba, e a posição de onset da segunda sílaba foi ocupada por consoantes obstruintes. Posteriormente, manipulamos esse sinal, dividimos as vogais nasais /aN/, /iN/ e /uN/ em três porções: inicial, medial e final. Os resultados mostraram que a divisão da vogal em três partes altera a percepção da nasalidade dependendo da consoante que a segue, reforçando ainda mais a complexibilidade do fenômeno. Seguida tanto de oclusiva quanto de fricativa, a vogal /aN/ nas três porções não apresentou perda de nasalidade. Com a vogal /iN/ a perceptibilidade da nasal não foi recuperada em nenhuma das três porções quando seguida de oclusiva bilabial surda e da fricativa alvéolo palatal. A vogal /uN/ nas três porções em que foi dividida, quando seguida de oclusivas velar, alveolar e bilabial sonoras, foi percebida com recuperação da nasalidade.

Como citar
Souza, Maria das Graças Amaral de. Investigação da percepção de nasalidade vocálica no português no Brasil. Orientadora: Vera Pacheco. Coorientadora: Marian Oliveira. 2016. 63f. Dissertação (mestrado em Linguística) – Universidade Estadual do Sudoeste da Bahia, Programa de Pós-graduação em Linguística, Vitória da Conquista, 2016. DOI: DOI: https://doi.org/10.54221/rdtdppglinuesb.2016.v4i1.90 . Acesso em: xxxxxxxx
TRAJETÓRIA DO MAIS-QUE-PERFEITO: CONTRIBUIÇÕES PARA A HISTÓRIA DO PORTUGUÊS POPULAR DE VITÓRIA DA CONQUISTA – BA
Authors: Rocha Sivonei Ribeiro 
Published: November 2021

Esta pesquisa trata da função de anterioridade a um ponto de referência passado. A este respeito, acreditamos que tal função está codificada no português por meio de outras categorias verbais, além do mais-que-perfeito composto, tais como o pretérito perfeito, evidenciando que a forma simples do mais-que-perfeito parece estar em extinção. Para tanto, esta pesquisa se insere dentro do quadro teórico do Funcionalismo Linguístico. E para comprovar empiricamente isso, verificamos os dados do corpus do Grupo de Pesquisa em Linguística Histórica e em Sociofuncionalismo/CNPQ da região urbana de Vitória da Conquista, na Bahia. Ao discutirmos as noções de tempo, aspecto e ponto de referência, procuramos demonstrar que tal função, até certo ponto, não está vinculada apenas à forma verbal, mas perpassa por toda sentença, sendo inclusive reforçados por advérbios de tempo. Acreditamos que a função de anterioridade não é exercida apenas pelo mais-que-perfeito, outros verbos exercem tal função de igual modo, o que, todavia, não é citado pelas gramáticas de cunho normativo. Os resultados obtidos evidenciam também que a função de anterioridade a ponto de referencia passado é reforçada por outras categorias além da verbal, como os advérbios e até mesmo os contextos em que determinadas sentenças são ditas. Com isso, ficou claro ser necessária uma ampliação das noções comumente definidas nos manuais de gramática para a definição do mais- que-perfeito, o que ao fazermos, teremos que revisitar, junto aos contextos funcionais deste tempo verbal, as noções de tempo, aspecto e ponto de referência em literaturas especializadas. A selecionar falantes com baixa escolaridade, acreditamos que a função de anterioridade está relacionada à heterogeneidade dos utentes. Assim, ao afirmar que o contexto comunicativo é importante, para compreender a dinâmica da língua no que respeita ao fenômeno em estudo, trazemos ao interior de nossa análise o Funcionalismo, teoria linguística que inter-relaciona forma e função, vistas de maneira dinâmica e adaptável às situações de comunicação. Esta pesquisa faz-se necessária para que futuros estudiosos do fenômeno em discussão encontrem nela caminhos problematizarem suas reflexões. Assim, nosso objetivo é ampliar a discussão sobre tempo verbal que, haja vista, é um campo muito rico para que mais pesquisas tenham mais desdobramentos, e assim, possamos conhecer cada vez mais a nossa língua.

Como citar:
ROCHA, Sivonei Ribeiro Trajetória do mais-que-perfeito: contribuições para a história do português popular de Vitória da Conquista - BA. Orientador: Jorge Augusto Ales da Silva; coorientadora: Valéria Viana Sousa; 2016. 128f. Dissertação (mestrado em Linguística) – Universidade Estadual do Sudoeste da Bahia, Programa de Pós-graduação em Linguística, Vitória da Conquista, 2016. DOI: https://doi.org/10.54221/rdtdppglinuesb.2016.v4i1.96 . Acesso em: xxxxxxxx
High‐Throughput On‐Chip Human Mesenchymal Stromal Cell Potency Prediction
Authors: Schneider Rebecca S. , Vela Alexandra C. , Williams Evelyn Kendall , Martin Karen E. , Lam Wilbur A. , García Andrés J. 
Published: November 2021

AbstractHuman mesenchymal stromal cells (hMSCs) are a promising source for regenerative cell therapy. However, hMSC clinical use has been stymied by product variability across hMSC donors and manufacturing practices resulting in inconsistent clinical outcomes. The inability to predict hMSC clinical efficacy, or potency, is a major limitation for market penetration. Standard metrics of hMSC potency employ hMSCs and third‐party immune cell co‐cultures, however, these assays face translational challenges due to third‐party donor variability and lack of scalability. While surrogate markers of hMSC potency have been suggested, none have yet had translational success. To address this, a high‐throughput, scalable, low‐cost, on‐chip microfluidic potency assay is presented with improved functional predictive power and recapitulation of in vivo secretory responses compared to traditional approaches. Comparison of hMSC secretory responses to functional hMSC‐medicated immune cell suppression demonstrates shortcomings of current surrogate potency markers and identifies on‐chip microfluidic potency markers with improved functional predictive power compared to traditional planar methods. Furthermore, hMSC secretory performance achieved in the on‐chip microfluidic system has improved similarity compared to an in vivo model. The results underscore the shortcomings of current culture practices and present a novel system with improved functional predictive power and hMSC physiological responses.
Efficient Broadband Near‐Infrared Emission in the GaTaO4:Cr3+ Phosphor
Authors: Zhong Jiyou , Zhuo Ya , Du Fu , Zhang Hongshi , Zhao Weiren , You Shihai , Brgoch Jakoah 
Published: November 2021

AbstractEfficient broadband near‐infrared (NIR) emitting materials with an emission peak centered above 830 nm are crucial for smart NIR spectroscopy‐based technologies. However, the development of these materials remains a significant challenge. Herein, a series of design rules rooted in computational methods and empirical crystal‐chemical analysis is applied to identify a new Cr3+‐substituted phosphor. The compound GaTaO4:Cr3+ emerged from this study is based on the material's high structural rigidity, suitable electronic environment, and relatively weak electron–phonon coupling. Irradiating this new phosphor with 460 nm blue light generates a broadband NIR emission (λem,max = 840 nm) covering the 700–1100 nm region of the electromagnetic spectrum with a full width at half maximum of 140 nm. The phase has a high internal quantum yield of 91% and excellent thermal stability, maintaining 85% of the room temperature emission intensity at 100 °C. Fabricating a phosphor‐converted light‐emitting diode device shows that the new compound generates an intense NIR emission (178 mW at 500 mA) with photoelectric efficiency of 6%. This work not only provides a new material that has the potential for next‐generation high‐power NIR applications but also highlights a set of design rules capable of developing highly efficient long‐wavelength broadband NIR materials.
Synthesis, Aromaticity, and Application of peri‐Pentacenopentacene: Localized Representation of Benzenoid Aromatic Compounds
Authors: Jousselin‐Oba Tanguy , Mamada Masashi , Wright Karen , Marrot Jérome , Adachi Chihaya , Yassar Abderrahim , Frigoli Michel 
Published: November 2021

AbstractWe report the synthesis and optoelectronic properties of TIPS‐peri‐pentacenopentacene (TIPS‐PPP), a vertical extension of TIPS‐pentacene (TIPS‐PEN) and a low‐band‐gap material with remarkable stability. We found the synthetic conditions to avoid the competition between 1,2‐ and 1,4‐addition of lithium acetylide on the large aromatic dione. The high stability of TIPS‐PPP is due to the peri‐fusion which increases the aromaticity by generating two localized aromatic sextets that are flanked with 2 diene fragments, similar to two fused‐anthracenes. Like TIPS‐PEN, TIPS‐PPP shows the archetypal 2D brickwall motif in crystals with a larger transfer integral and smaller reorganization energy. The high mobility of up to 1 cm2 V−1 s−1 was obtained in an organic field‐effect transistor fabricated by a wet process. Also, TIPS‐PPP was used as a near‐infrared (NIR) emitter for NIR organic‐light‐emitting‐diode devices resulting in a high external quantum efficiency at 800 nm.
Room‐Temperature Spin‐Dependent Transport in Metalloporphyrin‐Based Supramolecular Wires
Authors: Aragonès Albert C. , Martín‐Rodríguez Alejandro , Aravena Daniel , di Palma Giuseppe , Qian Wenjie , Puigmartí‐Luis Josep , Aliaga‐Alcalde Núria , González‐Campo Arántzazu , Díez‐Pérez Ismael , Ruiz Eliseo 
Published: November 2021

AbstractHere we present room‐temperature spin‐dependent charge transport measurements in single‐molecule junctions made of metalloporphyrin‐based supramolecular assemblies. They display large conductance switching for magnetoresistance in a single‐molecule junction. The magnetoresistance depends acutely on the probed electron pathway through the supramolecular wire: those involving the metal center showed marked magnetoresistance effects as opposed to those exclusively involving the porphyrin ring which present nearly complete absence of spin‐dependent charge transport. The molecular junction magnetoresistance is highly anisotropic, being observable when the magnetization of the ferromagnetic junction electrode is oriented along the main molecular junction axis, and almost suppressed when it is perpendicular. The key ingredients for the above effect to manifest are the electronic structure of the paramagnetic metalloporphyrin, and the spinterface created at the molecule–electrode contact.
Synthesis and Processing of Nanomaterials Mediated by Living Organisms
Authors: Calvo Víctor , González‐Domínguez José M. , Benito Ana M. , Maser Wolfgang K. 
Published: November 2021

AbstractNanomaterials offer exciting properties and functionalities. However, their production and processing frequently involve complex methods, cumbersome equipment, harsh conditions, and hazardous media. The capability of organisms to accomplish this using mild conditions offers a sustainable, biocompatible, and environmentally friendly alternative. Different nanomaterials such as metal nanoparticles, quantum dots, silica nanostructures, and nanocellulose are being synthesized increasingly through living entities. In addition, the bionanofabrication potential enables also the in situ processing of nanomaterials inside biomatrices with unprecedented outcomes. In this Minireview we present a critical state‐of‐the‐art vision of current nanofabrication approaches mediated by living entities (ranging from unicellular to higher organisms), in order to expand this knowledge and scrutinize future prospects. An efficient interfacial interaction at the nanoscale by green means is within reach through this approach.
Design of a novel fractional‐order internal model controller‐based Smith predictor for integrating processes with large dead‐time
Authors: Kumar Deepak , Aryan Pulakraj , Raja G. Lloyds 
Published: November 2021

AbstractA novel multi‐loop control configuration with two controllers is suggested for integrating processes having large dead‐time. The inner‐loop consists of a Smith predictor having proportional (P)/proportional‐derivative (PD) controller for first/second‐order integrating processes, respectively. Once the dead‐time is compensated by the inner‐loop Smith predictor, a fractional‐order internal model controller (FOIMC) is designed in the outer‐loop. The P/PD controllers are tuned using direct synthesis methodology. The proposed control architecture has three adjustable parameters (inner and outer closed‐loop adjustment parameters, fractional‐order of the FOIMC low‐pass filter). Based on extensive simulations, the tuning ranges for the above‐mentioned adjustable parameters are specified. Suitable justification is also provided for the suggested range of tuning parameters. Several benchmark examples of plant models are used to study the set‐point following and disturbance elimination capabilities of the proposed control architecture. Quantitative performance measures are also computed for comparing the suggested and previously reported schemes. It is evident that the suggested FOIMC based Smith predictor yields enhanced control performance than some recently reported techniques.
Assessment of the adsorption capacity of phenol on magnetic activated carbon
Authors: Gonçalves Júnior Degival Rodrigues , de Araújo Paulo Cardozo Carvalho , Simões André Luis Gomes , Voll Fernando Augusto Pedersen , Parizi Marcela Prado Silva , de Oliveira Leonardo Hadlich , Ferreira‐Pinto Leandro , Cardozo‐Filho Lucio , de Jesus Santos Edilson 
Published: November 2021

AbstractIn this work, an alternative utilization of agro‐industrial waste coconut endocarp (Cocos nucifera L.) as raw material for the synthesis of magnetic adsorbent aiming the phenol removal is proposed. The synthetized adsorbent, denominated magnetic activated carbon (MAC), was prepared by coprecipitation of cobalt ferrite (CoFe2O4) onto activated carbon surface obtained by carbonization of coconut endocarp. Characterization of MAC was carried out by point of zero charge (PZC), Brunauer, Emmett, and Teller (BET) surface area, scanning electron microscopy (SEM), x‐ray fluorescence (XRF), Fourier transform infrared spectroscopy (FTIR), x‐ray diffractometry (XRD) analysis, and magnetization curves. Adsorption experiments were performed in batch system to evaluate kinetics and equilibrium of phenol adsorption. Adsorbent regeneration method was proposed to evaluate the reutilization of MAC in successive cycles of adsorption–desorption. Results showed that obtained magnetic compounds present cubic phase structure covered in activated carbon surface. MAC has microporous structure with functional groups like carbonyl and hydroxyl that can behave as adsorption sites. Kinetic studies indicate that adsorption rate increased rapidly around the initial 60 min, reaching equilibrium at 240 min; following pseudo‐first‐order and pseudo‐second‐order kinetic models in characterization concentrations of 50 and 100 mg L−1, only the second‐order model fit the kinetic data at 150 mg L−1, while both models were outside the chi‐square interval at 200 and 230 mg L−1. The adsorption equilibrium is represented by Langmuir isotherm with high adsorption capacity of 116.0 ± 3.61 mg g−1. The desorption experiments revealed that adsorption capacities of MAC still viable after three adsorption–desorption cycles. It was observed that chemical affinity of small concentrations of methanol with phenol allowed to exert greater desorption capacity to other solvents with permanence of adsorbed phenol of 17.5 mg g−1.
On the need of bias adjustment for more plausible climate change projections of extreme heat
Authors: Iturbide Maialen , Casanueva Ana , Bedia Joaquín , Herrera Sixto , Milovac Josipa , Gutiérrez José Manuel 
Published: November 2021

AbstractThe assessment of climate change impacts in regions with complex orography and land‐sea interfaces poses a challenge related to shortcomings of global climate models. Furthermore, climate indices based on absolute thresholds are especially sensitive to systematic model biases. Here we assess the effect of bias adjustment (BA) on the projected changes in temperature extremes focusing on the number of annual days with maximum temperature above 35°C. To this aim, we use three BA methods of increasing complexity (from simple scaling to empirical quantile mapping) and present a global analysis of raw and BA CMIP5 projections under different global warming levels. The main conclusions are (1) BA amplifies the magnitude of the climate change signal (in some regions by a factor 2 or more) achieving a more plausible representation of future heat threshold‐based indices; (2) simple BA methods provide similar results to more complex ones, thus supporting the use of simple and parsimonious BA methods in these studies.