bluuebunny/crossref_metadata_2025_split huggingface dataset:
Attaining Full Li‐Ion Storage Capacity in Nearly Defect‐free and Preferential Orientation Grown LiCoPO4 Via ab initio Solvothermal Crystallization Control
Authors: Woo Moohyun , Park Sang‐Wook , Lee Jinhyuk , Seo Dong‐Hwa , Demopoulos George P. 
Published: December 2024

AbstractBoosting energy density beyond the current status of Li‐ion batteries is actively sought after yet it remains very challenging. One promising pathway toward this goal is the development of defect‐free high‐voltage cathode materials via novel crystal engineered approaches. In response to this demand, the present study focuses on synthesizing LiCoPO4, which is a high‐voltage polyanionic compound, into nearly defect‐free structure and preferential orientation grown crystals via solvothermal method using ethylene glycol (EG) as surface energy control medium. Notably, ab initio molecular dynamics simulations and density functional theory calculations elucidate the role of interfacial energy variations induced by EG molecule interaction with particular crystal facets of LiCoPO4 giving rise to the desired growth direction in comparison with hydrothermal method. In addition to solvent regulated crystal growth, Argon‐annealing alleviates the undesired charge transfer resistance on the crystal surface by eliminating EG residue and further reduces the anti‐site defect concentration, thereby engineering essentially highly ordered crystal structure. The novel LiCoPO4 crystals are shown to possess nearly theoretical full discharge capacity (163.0 mAh g−1 and 774.7 Wh kg−1 at C/10) and superior rate capability (151.6 mAh g−1 and 716.9 Wh kg−1 at 1 C), a truly unmatched functionality offering new high‐voltage cathode design possibilities.
Denture use and a slower rate of cognitive decline among older adults with partial tooth loss in China: A 10‐year prospective cohort study
Authors: Qi Xiang , Zhu Zheng , Pei Yaolin , Wu Bei 
Published: December 2024

AbstractObjectiveDenture use has been shown to improve nutritional intake and diet quality in people with tooth loss. Despite evidence linking tooth loss and dementia, few studies have examined the association between denture use and cognitive decline. We investigated the relationship between denture use and cognitive decline among Chinese older adults with tooth loss.MethodsWe analyzed data from the Chinese Longitudinal Healthy Longevity Survey 2008–2018, including 27,708 community‐dwelling dentate and edentulous (i.e., who have lost all natural teeth) older adults aged 65 and older. Cognitive function was assessed using the Mini‐Mental State Examination from 2008 to 2018. Linear mixed‐effect models were employed to assess the association of denture use with baseline cognitive function and rate of cognitive decline, adjusting for sociodemographic characteristics, health‐related behavior, and health status. Subgroup analyses evaluated differences in associations among dentate participants with varying degrees of tooth loss (1–9, 10–19, 20–31).ResultsCompared to non‐denture users, dentate participants who used dentures had better baseline cognitive function (β, 1.032; 95% CI, 0.813–1.251; p < 0.001) and a slower annual decline in cognitive function (β, 0.127; 95% CI, 0.047–0.206; p < 0.01). For edentulous participants, denture use was associated with higher baseline cognitive function (β, 3.063; 95% CI, 2.703–3.423; p < 0.001) but not with the rate of cognitive decline (β, 0.011; 95% CI, –0.082 to 0.105; p = 0.818). Results remained consistent across subgroups of dentate participants with various degrees of missing teeth.ConclusionsDenture use may help protect against cognitive decline in older adults with partial tooth loss. This study highlights the potential importance of prosthodontic rehabilitation in preserving cognitive health. Further research is needed to establish a causal relationship between denture use and cognitive function.
Support‐Layer Integrated Zeolite Membranes through In Situ Interfacial Transformation of Clay‐Based Protomembranes
Authors: Zhang Jun‐Bin , Liu Qiang , Pan Wen‐Yan , Wu Jia‐Wen , Li Xingyang , Pan Meng , Shi Zhi‐Sheng , Du Chun‐Liang , Wei Xue‐Ling 
Published: December 2024

AbstractZeolite membranes are considered ideal inorganic membrane materials for separating mixtures with molecular‐level differences. However, their complex preparation process with excessive synthesis solutions for traditional hydrothermal heating methods leads to various drawbacks. Here, we describe a membrane preparation strategy involving an in situ interfacial transformation of the protomembrane without solvents. Inexpensive clay powder forms the protomembrane, and the active ingredients subsequently migrate from the interior of this protomembrane to its surface and transform into a zeolite layer. Ultimately, the protomembrane is calcined to obtain the support‐layer integrated zeolite membrane. Systematic research shows that clay not only serves as a raw material for the support but also provides active ingredients for the growth of zeolite crystals; thus, zeolite membranes with zeolite particles inserted into the support are formed. The zeolite membrane calcined at 800 °C possesses a p‐xylene/o‐xylene separation factor approaching 6263 with a permeation flux of 1.21×10−7 mol ⋅  m−2 ⋅  s−1 ⋅  Pa−1. This interfacial transformation method can be applied to other membranes and promote the development of membrane separation technology.
Spatially Preorganized Hybridization Chain Reaction for the Prompt Diagnosis of Inflammation
Authors: Jia Bin , Ge Jingru , Ma Yuxuan , Sun Xiaolei , Li Zhe , Jiang Shuoxing , Yu Hanyang 
Published: December 2024

AbstractBiological systems utilize precise spatial organization to facilitate and regulate information transmission within signaling networks. Inspired by this, artificial scaffolds that enable delicate spatial arrangements are desirable to increase the local concentration of reactants, expedite specific interactions, and minimize undesired interference. In this study, we presented an integrated biosensing nanodevice, termed TRI‐HCR, in which hybridization chain reaction (HCR) probes were precisely organized on a triangular DNA origami nanostructure (TRI) with finely‐tuned distance, quantity, and pattern. Compared to traditional HCR in the free form, this nanodevice demonstrated increased reaction rate and signal level. We further employed the optimized TRI‐HCR for in vivo imaging of a nucleic acid biomarker of inflammatory diseases. In both acute gouty arthritis (AGA) and sepsis‐associated acute kidney injury (SA‐AKI) model mice, TRI‐HCR was capable of diagnosing inflammation in the early stages, significantly earlier than histological examination. We anticipate that this precise spatial preorganization strategy for HCR holds promise for broader applications in early disease detection and monitoring.
Heterocoupling Two Similar Benzyl Radicals by Dual Photoredox/Cobalt Catalysis
Authors: Yang Wei , Zhao Zhenyan , Lan Yu , Dong Zhou , Chang Ruiying , Bai Yihang , Liu Shihan , Li Shi‐Jun , Niu Linbin 
Published: December 2024

AbstractTransition‐metal‐regulated radical cross coupling enables the selective bonding of two distinct transient radicals, whereas the catalytic method for sorting two almost identical transient radicals, especially similar benzyl radicals, is still rare. Herein, we show that leveraging dual photoredox/cobalt catalysis can selectively couple two similar benzyl radicals. Using easily accessible methylarenes and phenylacetates (benzyl N‐hydroxyphthalimide (NHPI) esters) as benzyl radical sources, a range of unsymmetrical 1,2‐diarylethane classes via the 1°–1°, 1°–2°, 1°–3°, 2°–2°, 2°–3° and 3°–3° couplings were obtained with broad functional group tolerance. Besides the photochemical continuous flow synthesis, the one‐pot procedure that directly uses phenylacetic acids and NHPI as the starting materials to avoid the pre‐preparation of benzyl NHPI esters for the gram‐scale synthesis is also feasible and affords good yields, showcasing the synthetic utility of our protocol.
Boosting Electrocatalytic Nitrate Reduction through Enhanced Mass Transfer in Cu‐Bipyridine 2D Covalent Organic Framework Films
Authors: Zhu Ying , Duan Haiyan , Gruber Christoph G. , Qu Wenqiang , Zhang Hui , Wang Zhenlin , Zhong Jian , Zhang Xinhe , Han Lupeng , Cheng Danhong , Medina Dana D. , Cortés Emiliano , Zhang Dengsong 
Published: December 2024

AbstractElectrocatalytic nitrate reduction (NO3RR) is a promising method for pollutant removal and ammonia synthesis and involves the transfer of eight electrons and nine protons. As such, the rational design of catalytic interfaces with enhanced mass transfer is crucial for achieving high ammonia yield rates and Faradaic efficiency (FE). In this work, we incorporated a Cu‐bipyridine catalytic interface and fabricated crystalline 2D covalent organic framework films with significantly exposed catalytic sites, leading to improved FE and ammonia yield (FE=92.7 %, NH3 yield rate=14.9 mg ⋅ h−1cm−2 in 0.5 M nitrate) compared to bulk catalysts and outperforming most reported NO3RR electrocatalysts. The film‐like morphology enhances mass transfer across the Cu‐bipyridine interface, resulting in superior catalytic performance. We confirmed the reaction pathway and mechanism through in situ characterizations and theoretical calculations. The Cu sites act as primary centers for adsorption and activation, while the bipyridine sites facilitate water adsorption and dissociation, supplying sufficient H* and accelerating proton‐coupled electron transfer kinetics. This study provides a viable strategy to enhance mass transfer at the catalytic interface through rational morphology control, boosting the intrinsic activity of catalysts in the NO3RR process.
Modular Access to Silicon‐Containing Amino Acids and Peptides by Cobalt Catalysis
Authors: Wang Jixin , Chen Zexu , Chen Kaixin , Cui Zhili , Li Jie 
Published: December 2024

AbstractA regioselective cobalt‐catalyzed three‐component silylamidation that rapidly and reliably incorporates dioxazolones and silylzinc pivalates into unconjugated alkenyl amides is disclosed. Notably, the unique power of this protocol is demonstrated by the possibility of achieving peptide ligation using peptide‐containing dioxazolones or alkenyl amides as the coupling partners. Moreover, this approach is distinguished by its mild condition, synthetic simplicity, and ample scope, thus providing a new platform for modular access to silicon‐containing amino acid derivatives and peptides.
Tunable Mechanically Interlocked Semi‐Crystalline Networks
Authors: Qin Wen‐Yu , Shi Chen‐Yu , Liu Guo‐Quan , Tian He , Qu Da‐Hui 
Published: December 2024

AbstractHigh‐performance polymers based on dynamic chemistry have been widely explored for multi‐field advanced applications. However, noncovalent sacrificial bond‐mediated energy dissipation mechanism causes a trade‐off between mechanical toughness and resilience. Herein, we achieved the synchronous boost of seemingly conflicting material properties including mechanical robustness, toughness and elasticity via the incorporation of mechanical chemistry into traditional semi‐crystalline networks. Detailed rheological tests and all‐atom molecular dynamics simulation reveal that the excellent mechanical robustness and toughness are attributed to the dissociation of crystalline domains threading through the sieve‐shape macrocycles. Reversible nano‐crystalline domains and ring‐sliding‐effect accelerated segment motion efficiently reduce energy dissipation to achieve instantaneous resilience. Moreover, the model polymers demonstrate that the multiple dynamic components endow the resulting polymer with excellent reprocessability under mild conditions. This mechanically interlocked semi‐crystalline polymer exhibits potential applications as a thermal/photo actuator. This work reveals the synergic effects of mechanically interlocked sites and tunable crystalline domains, thus providing a reliable guide for the comprehensive improvement of material performance.
Synergistic Effect of Glycerol and Calcium Chloride on the Properties of Cellulose Acetate Film
Authors: Barman Ananda R. , Dutta Polash P. , Kapila Karanjit , Bania Kusum K. , Haloi Dhruba J. 
Published: December 2024

ABSTRACTThe present work investigates the development and characterization of cellulose acetate (CA) films with varying concentrations of CA, incorporating glycerol as a plasticizer and calcium chloride (CaCl2) as a crosslinker. The films were fabricated using solution casting and phase inversion techniques. The inclusion of glycerol significantly enhanced the surface morphology, tensile strength (TS), and elongation at break (EAB) of the films. The optimal composition, containing 10% (w/v) CA and 1% (v/v) glycerol, achieved the highest TS (3.199 ± 0.077 MPa) and EAB (9.500% ± 0.401%). The addition of CaCl2 to CA resulted in improved thermal properties of the films, suggesting effective crosslinking between CA and glycerol, as demonstrated by the DSC and TGA analyses. FTIR analysis suggested that glycerol interacts with cellulose, through hydrogen bonding, modifying the intermolecular forces within the cellulose matrix. Glycerol also improved the films' hydrophilicity and reduced swelling, solubility, and water contact angle (WCA). The films also exhibited antimicrobial properties against
Staphylococcus aureus
(
S. aureus
), a gram‐positive bacterium, and achieved a soil biodegradation rate of 43.65% within 30 days. These results suggest that CA films with optimized glycerol and CaCl2 are promising for various industrial and medical applications where enhanced mechanical properties, permeability control, and biodegradability are essential.
Synthesis of Low‐Surface‐Energy Fluorinated Microemulsions by High‐Pressure Homogenization Processing Using Thermally Decomposable Amphoteric Surfactants
Authors: Zhang Bin , Zhang Hongen , Ren Qiang , He Bei , Xiao Li , Jiang Zhengwu 
Published: December 2024

ABSTRACTIn this paper, fluorinated microemulsions with small particle size, good stability, and low surface energy were successfully prepared by using high‐pressure homogenization processing for the dispersion of monomers and thermally decomposable N‐dodecyl‐N, N‐dimethylamine N‐oxide (LDAO) as surfactant. The synthesized products were determined to be fluorinated terpolymers using FTIR, 1H NMR, and GPC. The effect of homogenization processing and LDAO on the synthesis of the emulsions was investigated by determining the monomer conversion rate, emulsion particle size, mechanical stability, and surface energy. The results showed that when the homogeneous pressure was 45 kPa, the pH value was 2, and the LDAO concentration was 2%, the fluorine microemulsion with 98.9% monomer conversion, 61.7 nm particle size, good centrifugal stability, and 9.3 N m−1 surface energy could be produced. Common substrates became superhydrophobic (or strongly hydrophobic) and oil repellent after modification by prepared microemulsion. The modified substrates have excellent corrosion resistance and lower water absorption (water absorption value of only 1.3%). In addition, the coatings prepared in this paper are more difficult to be wetted by NaCl solution compared to coatings prepared with conventional fluorinated emulsions. It has great potential for application in the preparation of long‐life and corrosion‐resistant surfaces.
Efficiency, Safety, and Dissemination: Considerations for Research and Practice Related to the Practical Functional Assessment
Authors: Kranak Michael P. , Briggs Adam M. 
Published: December 2024

ABSTRACTResearchers have developed and evaluated procedural modifications to the functional analysis (FA) to improve its efficiency and safety while maintaining its precision. A contemporary FA modification is the interview‐informed synthesized contingency analysis (IISCA) or practical functional assessment (PFA). Nearly all of the extant dissemination efforts related to the IISCA/PFA support this approach, with little attention to its drawbacks and limitations. Further, the IISCA/PFA has been widely disseminated and seems to have been readily adopted by many clinicians as the nonpareil FA. However, researchers and clinicians should be aware of several lingering issues and considerations to have a more balanced understanding of the IISCA/PFA (e.g., the conditions under which this approach should be considered). Accordingly, we outline the strengths of the IISCA/PFA, considerations surrounding various factors (e.g., the dissemination tactics), ideas for future research, and how the discussion on this topic should move forward.
Mapping the Nexus: A Bibliometric Analysis and Social Network Analysis of Transformative Innovation Policies and Sustainable Development Goals
Authors: Falcone Pasquale Marcello , Tutore Ilaria 
Published: December 2024

ABSTRACTThe pursuit of sustainable development has become a critical global objective, especially in light of increasing global challenges. The United Nations Sustainable Development Goals (SDGs), established in 2015, aim to address poverty, protect the environment, and ensure prosperity for all. Transformative innovation policies (TIPs) are emerging as vital strategies in achieving these goals by fostering systemic change rather than incremental improvements. TIPs are distinct because they seek to instigate profound transformations in sectors, societies, and economies, focusing on collaboration among diverse stakeholders. This manuscript aims to provide a comprehensive literature review and social network analysis to understand and highlights the interplay between TIPs and SDGs and elucidate business and management roles in advancing this global agenda. By analyzing existing research and visualizing the relationships within the literature, this study highlights the significant role of TIPs in advancing SDGs. The findings emphasize the necessity of innovative, inclusive, and purpose‐driven approaches to reshape society toward sustainable and equitable development.
Bridging the Gap Between Legitimacy and Voluntary Disclosure Theory and Current Corporate Nonfinancial Reporting Practices: Insights From Japanese Companies
Authors: Nishitani Kimitaka , Park Jin Dong , Haider Mohammad Badrul 
Published: December 2024

ABSTRACTThe purpose of this study is to bridge the gap between conventional assumptions of legitimacy and voluntary disclosure theories and current practices of corporate nonfinancial reporting. The analysis conducts regressions using data on 244 Japanese companies in 2019 to clarify whether the triadic relationship between a company's nonfinancial reporting motivation and practices and user information satisfaction is consistent. It contributes to the literature by showing that conventional assumptions have limitations in explaining the triadic relationship and identifying the mechanism underpinning how corporate nonfinancial reporting functions. First, although companies are more motivated by financial accountability than legitimacy in nonfinancial reporting, these motivations are not directly opposing, but are instead relative. Second, even when the financial accountability and legitimacy motivations are clear, they do not consistently satisfy user information needs. Finally, companies fulfil the financial accountability role only after they fulfil the legitimacy role.
Exploring anxiety, uncertainty perception, treatment experiences and coping strategies: An interpretative phenomenological analysis
Authors: Parlar‐Yazıcı Aysun , Norman Alyson , Bacon Alison 
Published: December 2024

AbstractObjectiveStress and anxiety are considered a major causative factor of various behavioural outcomes, such as insomnia, debilitating psychological and psychosomatic symptoms, and certain physiological ill‐health. The individual's appraisal process heavily influences a stress response, with the interpretation of the stressful situation being more important than the situation itself. This study aimed to examine the experiences and perceptions of stress and anxiety among individuals with anxiety. This included their coping mechanisms and experiences of treatment for anxiety. The concept of intolerance of uncertainty, a cognitive mechanism influencing anxiety, was also investigated.MethodA qualitative interpretative phenomenological analysis (IPA) was applied as a suitable method to gain a deep understanding of individuals' lived experiences of anxiety. Ten participants were selected to participate in a semi‐structured interview.ResultThree main themes were identified from participants' testimonies: (1) anxious narratives, (2) navigating anxiety and (3) healing journeys. The study revealed that participants experienced significant levels of stress and anxiety in their lives, with these conditions being perceived as substantial burdens. The coping mechanisms employed by participants predominantly centred around interpersonal support, particularly through engaging in conversations with loved ones. Common treatments for anxiety included antidepressants, private cognitive behavioural therapy (CBT) sessions and counselling provided by general practitioners. However, accessibility issues and dissatisfaction with outcomes were reported concerning both CBT and antidepressant treatment.ConclusionThe findings underscore the need for further research on effective interventions for stress‐ and anxiety‐related disorders and emphasise the importance of personalised treatments based on intolerance of uncertainty and resilience factors.
Morphological Characteristics Following Self‐Expanding Transcatheter Heart Valve Implantation and Implications for Hypoattenuating Leaflet Thickening
Authors: Shi Wence , Niu Guannan , Feng Dejing , Hu Xiangming , Wang Can , Zhao Zhenyan , Zhang Hongliang , Wang Moyang , Wu Yongjian 
Published: December 2024

ABSTRACTBackgroundHypoattenuating leaflet thickening (HALT) following transcatheter aortic valve replacement (TAVR) may compromise valve durability, posing a significant barrier to the broader adoption of this technology among younger patients. Self‐expanding valves (SEVs) are the most commonly used transcatheter heart valves (THVs) among Chinese patients with aortic stenosis. Understanding the potential mechanisms underlying HALT is, therefore, critical to guide future THV design and development.AimsIdentify morphological factors associated with HALT Unidentified after SEVs implantation.MethodsThis study included 195 consecutive patients from Fuwai Hospital who underwent TAVR with SEVs. All participants underwent their first postoperative 4D‐CT scan within 6 months of the procedure. Key parameters following THV implantation were measured and recorded using 3mensio software. Univariate and multivariable logistic regression models were applied to identify associations between variables and HALT. Discriminatory ability was assessed using receiver operating characteristic (ROC) analysis, followed by bootstrap validation for model robustness.ResultsHALT was observed in 36.4% of patients (71 out of 195 patients). New sinus height (NSH) and leaflet outflow area were identified as independent risk factors for HALT. The areas under the curve (AUC) for NSH and leaflet outflow area were 0.689 (95% CI: 0.612–0.767) and 0.602 (95% CI: 0.521–0.683), respectively, with no significant difference between them (p = 0.082). Bootstrap validation confirmed the robustness of both NSH and leaflet outflow area, showing performance comparable to the initial stepwise model.ConclusionNSH and leaflet outflow area were identified as critical post‐THV implantation parameters associated with HALT in TAVR patients treated with SEVs. These findings provide valuable insights that could inform the future design and optimization of SEVs.