bluuebunny/crossref_metadata_2025_split huggingface dataset:
Gifted Identification Inventory for Teacher Awareness: Development, Validation, and Measurement Invariance
Authors: Özbaşi Durmuş , Yilmaz Defne 
Published: January 2025

ABSTRACTThe purpose of this study is to develop a self‐awareness tool for teachers to help them in identification, and support the gifted and talented students in educational settings via more accurate nominations by educators. The Gifted Identification Inventory for Teacher Awareness (GIIFTA) was developed via fourth stages of writing essay (n = 5), Delphi method (n = 10), the exploratory factor analysis (EFA) (n = 273), and the confirmatory factor analysis (CFA) (as a different group from EFA, n = 286). The construct of GIIFTA consists of 22 items in three dimensions with a 5‐point Likert scale. The three dimensions of the inventory are: Noticing the Gifted Students, Distinguishing Cognitive Traits, and Distinguishing Emotional Social Traits. The fit index values of the CFA analysis were calculated (χ2/SD = 2.65; GFI = 0.86; CFI = 0.92; IFI = 0.86; NFI = 0.88; NNFI = 0.91; SRMR = 0.05 and RMSEA = 0.07). In addition, convergent and divergent validity were also examined and found to be within acceptable limits. The measurement invariance of the emerging dimensions was also examined in terms of gender variable and it was found that the structure did not change. The item‐total correlation values of the items in the measurement tool ranged from 0.51 to 077. Its structure does not change by gender. The reliability coefficients for the entire scale were calculated to range from 0.88 to 0.95. These results indicate that GIIFTA has good psychometric properties to assess teachers' awareness of gifted students in their classrooms.
Factors Influencing Body Image Among Chinese Secondary School Students: A Mixed Methods Approach
Authors: Liu Fangfang , Chen Fu , Li Guang , Li Xiaofei 
Published: January 2025

ABSTRACTThis study aims to assess the current physical health status and levels of body image satisfaction among Chinese secondary school students and identify the influencing factors of student body image perception. Guided by a mixed‐methods research design, data was obtained through collecting 903 secondary student questionnaires and interviewing 15 students. The results identified various factors that influence the body image of Chinese secondary school students, including personal growth, academic stress, peers, families, and social media. However, there are no significant differences in the overall perception of body image between students of different grades or between males and females. The findings of this study can provide valuable insights for individuals, families, schools, and society, with the intention of assisting Chinese adolescents in cultivating positive body images, enhancing self‐satisfaction, and fostering a healthy state of mind and body. The findings hold significant implications for promoting overall well‐being and fostering a better future for secondary school students.
Mechanical properties of hemp fiber‐reinforced thermoset and thermoplastic polymer composites: A comprehensive review
Authors: Islam Shahidul , Hasan Md. Byzed , Kodrić Marija , Motaleb K. Z. M. Abdul , Karim Fahmida‐E‐ , Islam Md. Redwanul 
Published: January 2025

AbstractHemp fibers have mechanical characteristics similar to those of synthetic fibers, which makes them an attractive material for producing environmentally friendly composites. Hemp fibers have excellent mechanical properties and a unique hydrophilicity, requiring for extra attention in composite formulations. Hemp fibers are a very versatile vegetable fiber that is frequently utilized in structural composites. In addition, hemp has shown potential in a variety of other fields, including as sports goods, building, and lighter materials. The present article aims to give a comprehensive summary of the status of sophisticated studies in hemp fiber reinforced composites at present time. The most important research on thermoset and thermoplastic materials reinforced with hemp fiber is compiled and discussed in this publication. This document also provides an overview of the primary attributes of hemp fibers, talks about how to develop these attributes chemically, explains how to create and describe hemp fiber composites, and identifies areas that need more research. In summary, this study ends with several important recommendations and future approaches that draw attention to the issues that require further investigation and potential industrialization of composites.Highlights
Advances in hemp fiber extraction and chemical treatments.
Performance traits of hemp‐reinforced thermoset and thermoplastic composites.
Tribological, and moisture absorption properties of hemp fiber composites.
SEM analysis revealing composite structural characteristics.
Future applications and sustainability of hemp fiber in polymers.
Theoretical Study on ESIPT for NHBQ‐NO2 and NHBQ‐NH2: A DFT/TDDFT Study
Authors: Zeng Wen , Shao Wenlong , Zhao Jinfeng , Chen Jiahe 
Published: January 2025

ABSTRACTInspired by distinguished characteristics of novel optical materials, there has been significant research interest in organic molecules that present excited‐state intramolecular proton transfer (ESIPT) properties. Given the vital effects of substituent effect on molecular designs, in this study, we focus on probing into excited state behaviors of NHBQ‐NO2 (i.e., submitted by strong electron‐withdrawing group ‐NO2) and NHBQ‐NH2 (i.e., submitted by strong electron‐donating group ‐NH2). Exploring hydrogen bonding effects via photoexcitation, we verify the impact of substituent effect (‐NO2 and ‐NH2) on interactions involving photo‐induced hydrogen bonding effects, redistribution of charges, and associated phenomena related to ESIPT reaction. By comparing and quantifying the barriers for reactions in relative excited state, our results indicate electron‐donating substituent ‐NH2 enhances the ESIPT reaction for NHBQ fluorophore.
Systematic Review of Pain Assessment Measures Used in Pediatric Acute Lymphoblastic Leukemia
Authors: Klages Kimberly L. , Gibson Courtney A. , Barnett Kimberly A. , Schwartz Laura E. , Hicks Chloe A. , Norris Robin E. , Kashikar‐Zuck Susmita , Pai Ahna L. H. 
Published: January 2025

ABSTRACTBackgroundPain is a prevalent, frequent, and often persistent symptom among children with acute lymphoblastic leukemia (ALL). Despite its high prevalence, pain has remained understudied, and no evidence‐based recommendations exist for how best to assess and treat pain in this population. Without proper assessment, clinical efforts to improve pain management in pediatric ALL will be ineffective.AimsTherefore, the purpose of this systematic review is to describe and identify gaps in measurement approaches that have been used to assess pain in pediatric ALL, evaluate the psychometric properties of available pediatric pain measures, and provide recommendations for clinical research and practice.MethodsLiterature searches were performed following Cochrane and PRISMA guidelines for systematic reviews. Domains of pain assessed, measures used to assess pain, measure format, respondent, and timing of pain assessment were extracted from studies that met inclusion criteria. The psychometric properties of included measures were then evaluated. A total of 238 full‐text articles were screened and 123 met inclusion criteria.ResultsMost studies assessed pain using generic health‐related quality of life instruments rather than pain‐specific measures. A total of 39 measures were used across the 123 included studies, and the psychometric properties of the measures varied considerably.ConclusionsRecommendations include a selection of well‐validated pain assessment measures that are currently available and can be used to facilitate best practices in ALL pain assessment. Clinicians and investigators are encouraged to utilize a multidimensional pain assessment approach to inform and enhance pain care in pediatric ALL.
Plant phenotyping and root‐associated metabolomics reveal insights into pathogen protection by diverse arbuscular mycorrhizal fungi
Authors: Weinberger Natascha V. , Cibils‐Stewart Ximena , Brien Chris , Jewell Nathaniel , Berger Bettina , Cavagnaro Timothy R. , Salomon Matthias J. , Mikhael Meena , Plett Jonathan M. , Plett Krista L. , Powell Jeff R. 
Published: January 2025

Societal Impact StatementArbuscular mycorrhizal (AM) fungi support plant development by enhancing growth and resistance to pathogens through mycorrhiza‐induced resistance (MIR). However, the varying capacities of individual AM fungal species to induce MIR are not well‐understood, limiting their agricultural potential. This study reveals that specific AM fungal isolates differ in their ability to enhance tomato growth and reduce biomass losses due to Rhizoctonia solani infection, a major root pathogen. By identifying MIR‐effective fungal isolates and linking them to shifts in root‐associated chemical composition, we highlight potential to improve crop resilience and productivity, advancing agriculture by enabling more efficient use of AM fungi.Summary
Mycorrhiza‐induced resistance (MIR) can increase plant resistance to pathogens, reducing disease symptoms and biomass losses. However, the beneficial effects of different arbuscular mycorrhizal (AM) fungal species vary greatly, and the mechanisms behind these differences are not well‐understood. This study investigates varying levels of MIR among AM fungal isolates and their impact on the plant root‐associated metabolome, examining the influence of AM fungi's functional diversity on plant growth, defence, and molecular patterns.
Using phenotyping observations, we assessed temporal variation in growth responses of tomato plants inoculated with Rhizoctonia solani and four different AM fungal isolates from the Glomeraceae and Gigasporaceae families, comparing these responses to changes in the root‐associated metabolome.
Our results show that most AM fungal isolates enhanced plant growth, with two out of four demonstrating MIR‐effective potential during symbiosis with tomatoes without trade‐offs. The effectiveness of MIR was reflected in variations in metabolomic profiles, with an increase in downregulated metabolomic compounds in effective species.
This study enhances understanding of AM fungal species‐specific differences in growth‐related MIR responses in tomatoes and the roles of biochemistry, supporting findings that Glomeraceae species have better MIR abilities. Our results suggest greater MIR‐related biochemical capabilities within Glomeraceae compared to Gigasporaceae.
Research Paradigm of the International Classification of Functioning, Disability and Health (ICF) With Item Response Theory: Clarification, Classification, and Challenge
Authors: Feng Chun , Liu Shou‐Guo , Zhou Liang , Lin Feng 
Published: January 2025

ABSTRACTBackgroundThe International Classification of Functioning, Disability and Health (ICF) is the worldwide terminology system for measuring health and disability at both individual and population levels. However, the underlying challenges remain in achieving widespread adoption and implementation of ICF within healthcare contexts, including the unequal interval scale of the ICF Likert‐type qualifier system ranging from 0 to 4, a lack of consensus on conceptualization and grading criteria of ICF items, and an excessive number of ICF items associated with each disease. The utilization of item response theory (IRT) for ICF studies demonstrated potential benefits in addressing these issues. Here, a review attempted to provide clarification of two predominant needs (sufficiency and efficiency) and two dimensions of scoring principles (stratification and assignment principles) in the ICF.MethodsA literature search was conducted on the PubMed database, and 44 relative articles were selected. On this basis, this review was undertaken to track the research progress of the ICF based on the parameter IRT method, typically the Rasch model.ResultsThis review outlined the classification of Item response model (IRM) for ICF studies and summarized existing IRT‐based ICF research paradigms. Moreover, this review identified blind spots regarding assignment principles and the difficulty parameter in current ICF‐based IRT studies. The Mokken scale analysis (MSA), as a non‐parametric IRT method, was introduced as a data shaping tool for parametric IRM. The pipeline of the ICF‐based MSA‐Rasch modeling might advance the understanding of ICF clinical application and shed light on a new paradigm of questionnaire design.ConclusionThe advent of ICF‐oriented IRM algorithms may advance the comprehension of ICF clinical application and pave the way for a new paradigm for IRT‐derived ICF questionnaires, namely the parsimonious ICF core set. Additionally, the Wright map holds promise in facilitating insight into rehabilitation trajectories and personalizing rehabilitation goals.
Efficacy and safety of Brucea javanica oil soft capsules combined with oral chemotherapy for maintenance therapy in advanced gastric cancer
Authors: Kou Yingying , Sun Mengting , Ling Bingxun , Ma Xianglei , Zhu Wenbo , Zhao Min 
Published: January 2025

AbstractThe objective of this study is to compare the efficacy and safety of Brucea javanica (Yadanzi) oil soft capsules (YDZ capsules) with or without Capecitabine/S‐1 in maintenance therapy for advanced gastric cancer (GC). From January 2019 to December 2021, 105 patients treated at Jiangsu Cancer Hospital were enrolled and categorized into 3 treatment groups: Group A received YDZ capsules, Group B received Capecitabine or S‐1, and Group C received a combination of YDZ capsules with Capecitabine or S‐1. The study compared the efficacy across these groups using the Objective Response Rate (ORR) and Disease Control Rate (DCR) metrics, focusing on the differences between Group A and Group B, and between Group B and Group C. Additionally, safety profiles were assessed and compared between these groups to evaluate the tolerability of each regimen. YDZ capsules alone had lower efficacy than chemotherapy (DCR: 51.4% vs. 68.6%, p = .14). While combination showed significantly higher efficacy with improved ORR (65.7% vs. 37.2%, p < .05) and DCR (88.6% vs. 68.6%, p < .05). YDZ capsules showed a significantly lower overall incidence of adverse reactions (ADRs) compared to capecitabine/S‐1‐treated group (p < .05). Combination therapy had significantly reduced the incidence of ADRs such as anemia, thrombocytopenia, nausea, vomiting, and fatigue (p < .05). Combination of YDZ capsules and Capecitabine/S‐1 demonstrate an obvious synergism and attenuation in maintenance treatment for advanced GC, highlighting their therapeutic potential especially for patients treated with palliative chemotherapy.
Structure of the Complex of Lactoperoxidase With Nitric Oxide at 1.95 Å Resolution
Authors: Maurya Ankit , Ahmad Nabeel , Sharma Pradeep , Sharma Sujata , Singh T. P. 
Published: January 2025

ABSTRACTLactoperoxidase (LPO) is a heme‐containing mammalian enzyme that is found in the extracellular fluids of animals including plasma, saliva, airway epithelial and nasal lining fluids, milk, tears, and gastric juices. LPO uses hydrogen peroxide (H2O2) to convert substrates into oxidized products. Previous structural studies have shown that H2O2, CO, and CN are bound to LPO at the distal heme cavity by coordinating with heme iron. The structure of the complex of LPO with NO shows that NO also binds to LPO at the distal heme cavity and forms a coordinate linkage with heme iron. The structure shows that the nitrogen atom of NO is linked to heme iron at a distance of 1.97 while the oxygen atom is attached to the Nε2 atom of His109 at a distance of 2.23 Å. On the other hand, N atom of NO is located with an interatomic distance of 3.25 Å allowing a hydrogen‐bonding interaction with the Nε2 atom of Gln105. A comparison of the bindings of NO, CO, CN, and H2O2 in coordination with heme iron indicates stereochemical compatibility of the distal heme cavity for the binding of diatomic molecules. However, notable differences are observed in their orientations in the distal heme cavity indicating functional differences. The bindings of NO, CO, and CN by coordinating with heme iron result in the inhibition of LPO while the binding of H2O2 to heme iron produces an intermediate of LPO known as Compound I.
Acceptance—Rejection Criteria Based on Birnbaum–Saunders Lifetime Distribution Using Intervened Poisson Distribution
Authors: Kumarasamy Pradeepa Veerakumari , Ramesh Thulasilakshmi , Thottathil Asif T. 
Published: January 2025

ABSTRACTThe Birnbaum–Saunders (BS) distribution is used to represent the impact of fatigue on the products produced in a continuous cycle, which is the primary quality characteristic that determines the product's failure time. This article explains the acceptance sampling plan for the BS distribution, which uses percentiles when the life test ends at a certain time, along with the intervened Poisson distribution. More specifically, this article primarily aims to determine the minimum sample size required to confirm the specified life percentile under a specific customer's risk. The operating characteristic values and the producer's risk are established.
An Efficient Sol–Gel Strategy to Fabricate Superhydrophobic and Oleophobic Polyester Fabrics With Enhanced Mechanical Stability and Chemical Durability Using Perfluorodecyltrimethoxysilane (PFDMS)
Authors: Xu Tianlu , Tang Wei , Shao Mingjun , Jian Yulan , Yang Xionghang , Xie Linkun 
Published: January 2025

ABSTRACTThe development of functionalized amphiphobic coatings on polyester (PET) fabrics has always been a research hotspot. However, maintaining the physical and chemical stability of the coating poses challenges. A high‐efficiency, convenient, one‐step sol–gel approach to fabricate PET fabrics coated with perfluorodecyltrimethoxysilane (PFDMS) was introduced, imparting fabrics both superhydrophobic and oleophobic properties. The PFDMS coating significantly enhanced the fabric's resistance to wear, UV light, and chemical erosion. The wettability, morphology, and chemical composition of the PET fabric were characterized by contact angle measurement, scanning electron microscopy (SEM), energy dispersive X‐ray (EDX), and X‐ray photoelectron spectroscopy (XPS). The effects of PFDMS concentration and hydrolysis time on the fabric's wettability were investigated. When PFDMS:NH4OH:EtOH = 3:50:50, and the hydrolysis time was 10 min, the modified PET fabric exhibited a water contact angle (WCA) of 152.2° and an oil contact angle (OCA) of 130.5°. Further tests demonstrated that PFDMS‐modified PET fabrics possessed excellent mechanical stability, chemical durability, and environmental stability. Additionally, these fabrics showed remarkable antipollution and self‐cleaning properties. Thus, a new method for creating robust, long‐lasting, and stable amphiphobic coatings was proposed, aiming to streamline production, enhance scalability, and broaden product applications.
A Fluorometric Method for Diclofenac Determination in Liquid Formulations: Experimental and Computational Assessments
Authors: Şarkaya Koray , Fitoz Alper , Ergun Ece , Orhan Ersin , Ergun Ümit 
Published: January 2025

AbstractDiclofenac (DCF) is an important non‐steroidal anti‐inflammatory drug frequently used to relieve rheumatic pain and acute injuries. Therefore, determination of DCF in real‐life samples using an efficient and cost‐effective indirect method is vital in pharmaceutical science. The proposed novel method is based on the formation of a solid Zn‐BMHM complex (chemosensor BMHM; (E)‐1‐((((1H‐benzo[d]imidazol‐2‐yl)methyl)imino)methyl)‐5‐methylphenol) via the displacement of zinc ions from the Zn‐DCF complex in an ethanol medium. The method consists of rapid precipitation steps that prevent interference effects and a turn‐on fluorescence effect by using a chemosensor. The increase in fluorescence intensity was linearly correlated with the concentration of Zn‐DCF solution over the range of 5.0–50.0 µM (R2: 0.999) with a LOD value of 1.64 µM. The method was applied to liquid pharmaceutical formulations and obtained excellent recovery values (99.09%–103.9%). Geometry optimization, molecular orbitals, and NBO population analyses were performed using density functional theory to display the exchange reaction's characteristics between ligand DCF and chemosensor BMHM. Global reactivity parameters and local interaction sites on the DCF and BMHM were examined in detail in view of the analyzed reaction. Theoretical assessments supported the analysis of reaction selectivity towards the BMHM ligand.
Ultrafast Electrodeposition of Durable NiFe Catalysts for Efficient Hydrogen Evolution Reaction
Authors: Qin Caiwei , Bai Minghua , Cao Dianwei , Ma Yuanqi , Zhao Jia , Kang Yanhong , Zhao Zhen 
Published: January 2025

AbstractFinding noble‐metal‐free hydrogen evolution reaction (HER) catalysts with facile synthesis and efficient performance is essential to carry out electrochemical overall water splitting for hydrogen energy development. An ultrafast electrodeposition technique for the synthesis of NiFe catalysts is developed. The rapid synthesis of NiFe catalysts with nanoparticle film morphology was achieved by uniformly anchoring particles onto three‐dimensional nickel foam (NF) via one‐step constant‐current electrodeposition in 30 s. The catalyst exhibited excellent HER electrocatalytic activity and stability in 1.0 M KOH solution. To attain a current density of 10 mA·cm−2, the hydrogen evolution reaction displayed favorable kinetics with an overpotential of 168 mV and a Tafel slope of 168.5 mV·dec−1. Continuous stability tests of the NiFe/NF electrode were conducted for up to 23 h at a current density of 10·mA·cm−2. The overpotential exhibited a decrease of merely 2 mV, exhibiting outstanding durability.
Novel Aromatic Heterocycles for Dual MAO A and B Inhibitors: A Promising Strategy for Parkinson's Disease Treatment
Authors: Swati  , Raza Amir , Singh Bhupendra , Wadhwa Pankaj 
Published: January 2025

AbstractRecent advancements in the synthesis of aromatic heterocycles have shown promise in the inhibition of monoamine oxidase (MAO) A and B enzymes implicated in the pathophysiology of Parkinson's disease (PD). These heterocyclic compounds are of particular interest due to their structural diversity and significant pharmacological potential.This review discusses various strategies for enhancing MAO inhibitory activity, emphasizing positional modifications. Notable progress includes the development of thiazole‐based and imidazole‐based heterocycles with detailed exploration of their synthetic methodologies and structure–activity relationships. These compounds have demonstrated potential in targeting the metabolism of neurotransmitters, particularly dopamine, which is crucial for managing PD symptoms.The synthesis of aromatic heterocycles targeting MAO A and B inhibition offers a promising pathway for developing novel therapeutics for Parkinson's disease. The structural diversity and pharmacological potential of these compounds, combined with their ability to modulate neurotransmitter levels, present a hopeful avenue for more effective PD management. However, further research, including structure‐based design and in vivo validation, is essential to fully realize their therapeutic efficacy and improve treatment outcomes for Parkinson's disease.