bluuebunny/crossref_metadata_2025_split huggingface dataset:
Impact assessment of the three gorges reservoir on the contribution rate for diversion through the three outlets
Authors: Chen M F , Li Y T , Li A Q , Yao W 
Published: December 2021

Abstract
The Dongting Lake distributes water and sediment of the Yangtze River through the three outlets. Influencing factors of the diversion capacity are complicated. In order to evaluate the influences of the operation of the Three Gorges Reservoir (TGR) on the diversion of the three outlets, this paper investigates systematically the variation process of the runoff at the three outlets based on substantially raw data and principles of variable control. By using comparative analysis and the calculation method of runoff reduction, the change magnitude of the runoff at the three outlets in different periods were quantified and the contribution rates of different influencing factors were estimated. Results show that (1) Inflow difference from the Yangtze River is the primary factor causing the runoff reduction of the three outlets. After the operation of TGR, the Yangtze River was in dry years. Therefore, over 60% of runoff reduction can be attributed to the variation of natural inflow discharge. (2) As the flow is retained by TGR, the runoff of the three outlets further reduced. From 2003-2008, the contribution rates of natural flow, sediment trapping and reservoir regulation to the runoff reduction at the three outlets were 76.19%, 13.49%, 10.32%, while their counterparts after optimal operation of TGR became 66.05%, 14.20% and 19.75% respectively. (3) Reservoir operation after the flood season showed the most significant impact on runoff of the three outlets, resulting in an increase in the number of shut-off days of the three-distributary channels from September to October, especially at Shadaoguan and Kangjiagang.
Recovery of cobalt and molybdenum from spent catalyst using citric acid
Authors: Nugroho M E C , Sutijan  , Prasetya A , Astuti W 
Published: December 2021

Abstract
Valuable metals play essential roles in various industrial sectors, such as petroleum, petrochemical, and steel industries. Potential secondary resources of these metals can be obtained from spent catalysts, which are a solid waste of the chemical and oil industries. Spent catalysts contain valuable metal compounds such as nickel (Ni), vanadium (V), cobalt (Co), molybdenum (Mo), rhodium (Rh), platinum (Pt), alumina (Al), etc. In this research, the recovery of cobalt and molybdenum from the spent catalyst of Pertamina Refinery Unit IV, Cilacap, Indonesia, was leaching using citric acid. Samples of spent catalyst were analyzed using EDXRF prior to the leaching process. Citric acid at various concentrations of 1.0, 1.5 and 2 M was used as a leaching agent. The leaching experiment was carried out for 300 minutes and sampling was undertaken at 1, 3, 5, 15, 30, 90 and 300 minutes. Each sample was separated between solid and liquid phases using a centrifuge at 400 rpm for 10 minutes. For analysis, 2 ml of the liquid phase was taken and the cobalt and molybdenum concentrations were analyzed using ICP-OES. It was found that at higher the citric acid concentration and temperature, the recovery of cobalt and molybdenum was also higher. The best leaching condition is obtained at a citric acid concentration of 2 M and 60ºC, where recovery of cobalt and molybdenum were 17.35% and 2.27%, respectively.
Synthesis of Al(OH)3 nanoparticles from Indonesian bauxite and tomato waste extract as chelating agent for nanofluids applications
Authors: Hardian A , Nirmalasari C , Budiman S , Murniati A , Kusumaningtyas V A , Yuliana T , Syarif D G 
Published: December 2021

Abstract
This study aimed to determine the effect of calcination time on the properties of Al(OH)3 or gibbsite nanoparticles in the sol-gel process, which was then used as the basic material in the manufacturing of water-Al(OH)3 based nanofluids. Nanofluid is a mixture of basic fluids such as water with solid nanoparticles. Al(OH)3 nanoparticles have been successfully synthesized from Indonesia local mineral bauxite using the sol-gel method by utilizing tomato waste extract as a chelating agent at a calcination temperature of 700ºC for 1 hour, 3 hours, and 5 hours. The obtained calcined powders were characterized using X-ray diffractometer (XRD). The evaluation toward nanofluids application based on theirs stability based on visual observation and zeta potential. Based on XRD analysis, all calcined powders has single Al(OH)3 or gibbsite phase. Increasing the calcined temperature gave impact on crystallinity, crystallite size, and reorientation of crystal. The water-Al(OH)3 nanofluid was relatively less stable with a zeta potential value of -25.2 mV; -26.4 mV; and -17.4 mV for calcination time 1 h, 3 h, and 5 h, respectively.
Cu-Mn Co-doped NiFe2O4 based thick ceramic film as negative temperature coefficient thermistors
Authors: Hardian A , Greshela S , Yuliana T , Budiman S , Murniati A , Kusumaningtyas V A , Syarif D G 
Published: December 2021

Abstract
NTC (Negative Temperature Coefficient) thermistors are widely used as temperature sensors in industrial and medical applications due to their high-temperature sensitivity, durability, and low cost. Generally, NTC thermistors are made from spinel structured ceramics formed by transition metal oxides with the general formula AB2O4. One of the spinel structured ceramics that can be made for NTC thermistors is NiFe2O4 nanoparticles. This work aimed to prepare Cu-Mn co-doped NiFe2O4 based thick ceramic film using Jarosite mineral as a precursor. The synthesis method used was a simple coprecipitation method, while the technique used in making a thick ceramic film was a simple screen printing technique. The sintering temperatures used were 1000 °C, 1100 °C, and 1200 °C. Based on x-ray diffraction analysis, the thick films consist of spinel phase, hematite phase, and some unidentified phase. The constant thermistor values (B) for thick films obtained with 1000, 1100, and 1200 °C sintering temperatures were 4740 K, 5669 K, and 5731 K, respectively. These results showed that all obtained thick films had passed the minimum value in market needs (B ≥2000 K).
Synthesis of TiO2-NiFe2O4 nanocomposites using coprecipitation method as photocatalyst for methylene blue removal
Authors: Hardian A , Devikha  , Budiman S , Yuliana T , Sujono H , Murniati A , Kusumaningtyas V A , Syarif D G 
Published: December 2021

AbstractMethylene blue, a basic dye that is important in the coloring process in the textile industry. However, the use of the dye Methylene blue is hazardous for the skin, the eyes, and swallowed. Three composition types of TiO2-NiFe2O4nanocomposites (75:25, 50:50, and 25:75) had been synthesized using a simple coprecipitation method. The photodegradation and adsorption performance of the nanocomposites were also evaluated. Based on X-ray diffraction analysis, both the titania anatase and nickel ferrite spinel phases appeared in each nanocomposite’s diffraction pattern. The average crystallite size of the nanocomposites was 38 nm, 33 nm, and 41 nm for compositions 75:25, 50:50, and 25:75, respectively. The optimum photodegradation activity of TiO2-NiFe2O4nanocomposites was achieved at composition 75:25 %mol with >99% methylene blue degraded during 120 minutes of UV irradiation time. However, all nanocomposites also have adsorption capability toward methylene blue with an optimum percentage of 98%. Therefore, TiO2-NiFe2O4nanocomposites can be used either as photocatalysts or adsorbents for methylene blue removal in an aqueous solution.
Critical raw materials enrichment in bauxite laterite: a case study of diverse parent rock types
Authors: Nugraheni R D , Riyandhani C P , Apriniyadi M , Sunjaya D 
Published: December 2021

Abstract
High demand in utilizing the mineral and metal for industrial manufacture, which is unequal to the resources, has caused a vulnerable disruption. To compensate stocks in the global market, exploration of raw materials should be carried out for by-products. This study aims to elucidate the enrichment mechanism of Sc, Ga, and Nb elements from the bauxite weathering profile and sediment residue. An observation has been conducted using petrography, mineragraphy, x-ray fluorescence spectroscopy (XRF), x-Ray diffraction (XRD), inductively coupled plasma combined with mass spectrometry (ICP-MS), and scanning electron microscope - energy dispersive spectrometry (SEM-EDS). The results indicate that bauxite ores (gibbsite) hold the metal compounds of Ga, while some iron minerals of goethite and hematite are present as Sc-bearing minerals, and Nb is highly concentrated within saprolite of bauxite. The maximum enrichment of Ga and Sc is observed from the bauxite sample and sediment residue derived from microdiorite pyroxene, which makes up 24.2 - 42.1 ppm and 39.9 - 55.4 ppm, respectively. By contrast, Nb enriched about nine-fold higher in the saprolite zone relative to bauxite produced by weathering of granitic parent rocks. It suggests that metal concentration in the lateritic products depending immensely on the precursor rock types.
Impact of coal pile leachate on soil geochemistry: case study of PT Bukit Asam Tbk. Tarahan Port Unit and its surroundings
Authors: Farishi B A , Iqbal M , Candany M , Radityo D , Natalia H C , Erica T F , Hassan M A A 
Published: December 2021

AbstractSurface runoff that flows through the coal stockpile and penetrates the ground can be a source of trace elements that can damage the environment. The trace elements possessed by coal in significant amounts can affect the geochemistry of soil, groundwater and human health, and it has become the concern of PT Bukit Asam Tbk. Port Units. This research aims to identify the effect of coal stockpiles on trace elements in the soil. The method was to take the soil sample around the research area and then performed X-ray fluorescence (XRF) analysis. The data obtained was then displayed in a distribution map of elements which has an anomaly. Based on the XRF test results, six elements, including K, Mn, Cr, Zn, Pb, and Cu, were exceeded the threshold. Based on further analysis, it could be concluded that there were several sources of these elements, including plant fertilizers, ash, and stockpile. The presence of the elements was directly related to stockpiles are Mn, Cr, Zn, Pb, and Cu.
Performance and boiler efficiency using low-grade coal on 400 MWe coal-fired power plant: case study of Suralaya Power Plant Unit 2
Authors: Supriyanto Eko , Cahyo Nur , Sitanggang Ruly , Rasgianti  , Triani Meiri , Bakti Dheka 
Published: December 2021

Abstract
In a coal steam power plant, changes in coal quality significantly affect plant performance, especially in its boiler. A coal-fired power plant with a capacity of 400 MWe had been commissioned using coal with a calorific value of 5,242 kCal/kg. This study aims to determine the effect on unit performance and boiler efficiency due to changes in fuel use with the typical calorific value of 3,520 kCal/kg, 34,17% lower than the initial design. The performance tests were conducted using the heat loss method at loads: 50%, 65%, 75%, and 100%. The test result showed that using low-grade coal reduces boiler efficiency by 6.26%. There were four dominant boiler losses: heat loss due to moisture in dry flue gas, heat loss due to combustible in refuse, heat loss due to moisture in fuel, and heat loss due to hydrogen burning. Furthermore, the gross plant heat rate using low-grade coal was increased from 2,120 kCal/kWh to 2,718 kCal/kWh; however, the electric price becomes cheaper from 1.99 cent-USD/kWh becomes 1.31 cent-USD/kWh.
Preparation of carbon anode sheet precursor using raw Air Laya–Bukit Asam coal and its application for battery
Authors: Mursito A T , Listiyowati L N , Arifin D N , Santoso D B , Wicaksono M D S 
Published: December 2021

Abstract
Research has been carried out on manufacturing carbon electrode thin sheets used as anode for solid battery cells. The material used is raw coal carbonized at 800 and 1000oC, polyvinylidene fluoride (PVDF), and N-Dimethylacetamide (DMAC) as a solvent. Observation of crystal structure by X-rays diffraction method shows a diffraction pattern where crystallites in all product samples have an intermediate structure between graphite and amorphous known as a turbostratic structure or a random layer lattice structure. The distance between the crystallite structure’s aromatic layers (d002) is in the range 3.52-3.62 Å. Aromaticity (fa) is in the range 0.42 - 0.48 for all samples. The high value of d002 indicated that the crystallinity or level of graphitization obtained by all samples was still low. Manufacturing technique using a Doctor Blade-based tape casting method. The discharge capacities of the samples reach about 60 and 18 mAh.g-1, while their charge capacities at the first cycle are 50 and 16 mAh.g1, respectively. Cyclic voltammetry (CV) was performed using anodes resulted at 0.1 to 2.3 volt. During the forward scan, CV curves of the sample reveal a reduction current starting from around 1.2 V and exhibiting two-reduction waves, between 1.2 and 0.6 V.
Mitigation in erosion control and management of ex-mining water through revegetation and sustainable environmental management technologies
Authors: Istiqomah E , Aryanto R , Purwiyono T T 
Published: December 2021

Abstract
In the open-pit mining system that is being carried out by a company in the mining sector with gold and silver commodities, PT Citra Palu Minerals, land clearing can cause soil erosion which can lead to soil sedimentation, increased turbidity of water that will be released into the environment and potential entry soil eroded into the tailings pond at the Dry Tailing Management Facility (DTMF). Therefore, further action is needed to control erosion and sedimentation as well as water management so that the water to be released into the environment is following environmental quality standards that have been set by the government. Before determining and controlling erosion, it is necessary to know the rate of erosion that occurs at the research location, in this study the USLE (Universal Soil Loss Equation) method was used to predict the rate of erosion with the results obtained, namely 17.07 tonnes/ha on the North DTMF slopes and 21.04 tonnes/ha for DTMF South slopes. To reduce the rate of erosion, it is necessary to control erosion by revegetation of the land, create a water drainage system to the sedimentation pond and treat the collected water using biophytoremediation of land with the use of chemicals to accelerate the deposition process, constructed swamp forest to the latest sustainable technology recommended by the Indonesian Academy of Sciences (LIPI).
Quality of coal seam D of Muara Enim Formation, Central Palembang Subbasin
Authors: Purnama A B , Yudha S S , Surono W 
Published: December 2021

Abstract
Coal seam D belongs to Muara Enim Formation in Central Palembang Subbasin, South Sumatera Basin, which ages of Middle Miocene to Late Miocene. This study aims to determine the quality of the coal, especially sulphur content and form, ash content and composition, and trace elements of heavy metals. Those are important to know as a reference in suitability in the use of this coal. Methods of analysis is proximate, total of sulphur, form of sulphur, SEM-EDS, ash composition, and trace element. The coal is categorized as low rank coal or lignite with a very low total sulphur max 0.25%, dominated by the organic sulphur formed during the peatification and coalification process (syngenetic). The coal has a safe ash composition. It shows from a very low metal oxide content that causes slagging and fouling at low temperatures process. Likewise, the trace element content of the coal such as chromium (Cr), cadmium (Cd), manganese (Mn), lead (Pb), nickel (Ni) is still far below the threshold for trace element content in coal.
The application of “line drilling” and “buffer holes” methods to reduce blasting vibration
Authors: Pradatama Dhion , Pradasara Chani , Syafiq Isnaya M. 
Published: December 2021

Abstract
PT Multi Nitrotama Kimia is one of the largest mining service companies that provide blasting services and sales of explosives in Indonesia. PT Putra Perkasa Abadi Jobsite Borneo Indobara is one of PT Multi Nitrotama Kimia’s customers who is facing challenges in optimizing blasting activities. Currently, blasting activities at PT Putra Perkasa Abadi Jobsite Borneo Indobara are carried out within 500 m of the active slope, so that the blasting distance is optimized. In optimizing the blasting distance, it is necessary to maintain slope conditions (no underbreak / no overbreak) and to consider the vibration of blasting results on the slopes. The line drilling method was chosen for the blasting trial stage. In the observation activity, an analysis of the resulting blasting and fragmentation vibrations was carried out. Precise planning and good control in field operations play an important role in this experimental process. Based on the results of the blasting trial, no damage was found in the area 25 m – 100 m from the blasting location and a 10% - 20% reduction in blasting vibration results (Peak Vector Sum) was obtained when compared between normal blasting designs with controlled blasting designs.
Characterization of potential mercury contamination in the ASGM area of Mandailing Natal, North Sumatera
Authors: Astika H , Handayani S , Damayanti R , Surono W , Maryono  , Suciyanti M , Octaviano H A 
Published: December 2021

Abstract
A large amount of Hg is used for gold extraction through the amalgamation process in the Mandailing Natal derived from artisanal and small-scale gold mining (ASGM) area located in the North Sumatera Province, Indonesia. The objective of this work was to characterize the potential contamination of total Hg in water, sediments, and soil in this ASGM area. Sampling was done in two locations in West Panyabungan and Huta Bargot Districts using grab sampling method. Results showed that accumulation of Hg in the studied soils and sediments was the highest, but Hg in aquatic solution was below the detection limit of the analytical method of the studied community wells and rivers. The highest concentration of Hg was found in the river sediments of the Saba Padang irrigation (1,63 mg/kg), and in the soil of the plantation area of Huta Bargot (1,62 mg/kg) respectively. These concentrations may pose a serious problem for aquatic and land life, related ecosystems, and human health. For further study, there is a need to study Hg availability in riverine biota to better understand the cycling of Hg in this ASGM area. Understanding the ecological impacts can assist in the prioritizing of impact mitigation efforts.
Utilization of Tephrosia vogelii in post-mining land reclamation
Authors: Kusumaningtyas V A , Murniati A , Budiman S , Hardian A , Ruhaniyah H , Melina M , Juliawaty L D , Syah Y M 
Published: December 2021

AbstractReclamation is an effort to repair the damaged mining sector to provide optimal benefits. This review article aims to propose a natural product technology approach to the reclamation of post-coal mining land by increasing the content of soil organic matter so that the post-mining land becomes fertile and can be used for agricultural land. The method used is an observation and literature study. Literature searches were using them ScienceDirect, Scopus, PubMed, and Google Scholar databases. Land-use change of post-mining site to agricultural land provides prospective economic value to the community. However, the land quality of the post-mining area should be improved before food crop production.Tephrosia vogeliiis a member of the Papilionoideae subfamily is important for land revegetation. They can fertilize the soil because of mutualistic symbiosis with the bacteria Rhizobium sp. which is capable to fix nitrogen in the soil and hence provide available nitrogen. Thus, the use of post-mining land as agriculture can improve the economy and sustainability as well as protect life and the environment with natural product technology.
Legalization of illegal small-scale mining, as a policy of business guarantee and environmental management
Authors: Sugiarti S , Yunianto B , Damayanti R , Hadijah N R 
Published: December 2021

Abstract
Small-scale mining has a very long history, and the majority operated without permits: coal and almost all kinds of minerals they cultivate. The area of operation covers most of Indonesia. There are grab licensed mining areas. The number of illegal miners is estimated at more than 3.6 million people, about 1.4 million gold miners. This activity has been going on for years, never be solved. The Negative impacts of illegal mining, include the loss of potential state revenue, environmental damage and mercury pollution, mining accidents, social vulnerabilities, conflicts with licensed companies, and no resource conservation. It is time for this issue serious attention of the government to be resolved. Legalization by granting permits can be a business guarantee that will grow responsibility for regulations and become the basis for environmental management. This research is socio-legal research. The role of local governments, associations, and the state-owned company is required in technical guidance on mining and the environment, institutions, business management, and product markets. If the activities can be managed and developed, the negative impacts can be overcome. So, the benefits of their business can become a forum for people’s activities in the mining sector, and state revenues can be collected.
Utilization of Sodium Bicarbonate as Anesthetic During Routine Husbandry Activities in Ornamental Fish
Authors: Caipang C M A , Deocampo J E , Pakingking R V , Suharman I , Fenol J T , Onayan F B 
Published: December 2021

Abstract
The tropical ornamental fish industry requires the stock to be reared in captivity before being sold; thus, exposing them to various handling- and transport-related stressors. A number of commercially available anesthetics are used during fish husbandry procedures, but these products are expensive and not readily available to small-scale ornamental fish operators. The use of sodium bicarbonate as an inexpensive anesthetic during routine husbandry activities in molly, Poecilia sp., a freshwater ornamental fish was assessed in terms of its effect on sedation, recovery and survival post-exposure in three independent experimental runs. Juvenile molly were exposed to sodium bicarbonate at a concentration of 100 g L−1 and the time to sedation and recovery were monitored. It took longer for the fish to be fully sedated than their recovery. Survival of the fish a week post-exposure ranged 40-60%. Simulated transport of fish for 6 hrs in water containing 1 g L−1 of sodium bicarbonate showed survival ranging 70-100% a week after transport. These findings demonstrated that sodium bicarbonate could be potentially used as a low-cost anesthetic during handling and short-term transport of ornamental fish. Future studies shall focus on discovering the underlying physiological mechanisms in fish following sedation with this chemical.