bluuebunny/crossref_metadata_2025_split huggingface dataset:
Understanding the relationship between personality pathology and attachment style in the context of the DSM‐5 Alternative Model of Personality Disorders
Authors: Pad Rachel A. , Okut Hayrettin , Zackula Rosey , Macaluso Matthew , Huprich Steven K. 
Published: October 2021

AbstractThis study utilizes the two different criteria of the DSM‐5 Alternative Model of Personality Disorder Assessment to evaluate the relationship between attachment style and personality pathology. One‐hundred forty patients from a combined sample of psychiatric and internal medicine clinics were given a survey composed of the DSM‐5 Levels of Personality Functioning Questionnaire (DLOPFQ), the Personality Inventory for DSM‐5—Brief Form (PID‐5‐BF), and the Relationship Questionnaire (RQ). Analysis of variance indicated that attachment styles were differentiated across all four the DLOPFQ scales and the Detachment trait domain. Elastic net regression modeling with bootstrap was used to assess the strength of the level of personality functioning dimensions and trait domains in the prediction of attachment style, both independently and interactively while accounting for multicollinearity. This study offers readers insight to a novel statistical approach to model building that addresses two issues among psychiatric data: high correlation and small sample size.
Thiol‐yne photoclick polymerization as a method for preparing imidazolium‐containing ionene networks
Authors: Lindenmeyer Katelyn M. , Miller Kevin M. 
Published: October 2021

AbstractHerein, the thiol‐yne photoclick reaction was utilized as a method for synthesizing imidazolium‐containing ionene networks whereby a bisalkynyl‐functionalized imidazolium [NTf2] ionic liquid was polymerized with the tetrafunctional thiol PTMP (pentaerythritol tetrakis(3‐mercaptopropionate)). The thiol:yne functional group ratio was varied in order to examine the breadth of thermal, mechanical, and conductive properties available from the resulting networks. The stoichiometric 1:1 thiol:yne network exhibited very high thiol and alkyne conversions by FT‐IR spectroscopy and a gel fraction greater than 95%. The highest Tg value (3.5°C) and stress at break (1.13 MPa) were also observed for this network. As either thiol or alkyne functional group concentration was increased, the networks were noticeably lower in Tg and stress at break with a modest increase in % elongation. Ionic conductivities were found to be on the order of 10−9 to 10−7 S/cm at 30°C. Normalization of the ionic conductivity curves did not lead to a complete collapse meaning that the observed differences in conductivity are not solely dependent upon Tg. When compared to analogous imidazolium‐containing, thiol‐ene ionene networks, the thiol‐yne networks were found to be slightly more mechanically robust, but approximately one order of magnitude lower in terms of ionic conductivity.
Synthesis of Metal‐Free Nanoporous Carbon with Few‐Layer Graphene Electrocatalyst for Electrochemical NO2− Oxidation
Authors: Chavan Parag P. , Sapner Vijay S. , Munde Ajay V. , Mali Shivsharan M. , Sathe Bhaskar R. 
Published: October 2021

AbstractHerein, electrochemical oxidation of nitrite (NO2−) is demonstrated using metal‐free and electrochemically highly stable nanoporous carbon (NC) system. The surface features of nanoporous carbon were studied using both spectroscopic and microscopic techniques including scanning electron microscope (SEM), transmission electron microscope (TEM) and is having layered mesh‐like features with a particle size of ∼20 to ∼100 nm. The as‐synthesized electrocatalyst is found to be more active towards electrooxidation of nitrite (NO2−) at considerably low onset potential of 0.58 V vs SCE with a significantly high current density of 5.2 μA/cm2 determined from linear sweep voltammetry (LSV), and cyclic voltammetry (CV) studies. The concentration and scan rate dependent studies confirm the nitrite oxidation is diffusion‐controlled process. The interfacial electron transfer features and parameters involved are determined by electrochemical impedance spectroscopic (EIS) studies. Moreover, current stability at a nitrite oxidation (0.58 V vs SCE) potential is also tested by chronoamperometric (i‐t) measurements and it demonstrates nanoporous carbon is having long term electrochemical stability. These studies establish the metal‐free nanoporous carbon as an efficient electrocatalyst for nitrite oxidation and will be good futuristic electrode material for other energy and environmental based electrochemical monitoring studies.
A Highly Reversible Lithium Metal Anode by Constructing Lithiophilic Bi‐Nanosheets
Authors: Liu Xiaoyu , Xu Pan , Zhang Jieling , Hu Xinyu , Hou Qing , Lin Xiaodong , Zheng Mingsen , Dong Quanfeng 
Published: October 2021

AbstractAs a favorable candidate for the next‐generation anode materials, metallic lithium is faced with two crucial problems: uncontrollable lithium plating/stripping process and huge volume expansion during cycling. Herein, a 3D lithiophilic skeleton modified with nanoscale Bi sheets (Ni@Bi Foam, i.e., NBF) through one‐step facile substitution reaction is constructed. Benefiting from the nanoscale modification, smooth and dense lithiophilic Li3Bi layer is in situ formed, which improves the uniform deposition of Li subsequently. Meanwhile, the 3D structure inhibits the growth of Li dendrites effectively by reducing local areal current density. Consequently, the NBF exhibits outstanding cycling stability with a high average Coulombic efficiency of 98.46% at 1 mA cm−2 with 1 mAh cm−2 (>500 cycles). Symmetrical cell with NBF exhibits a high reversibility at 1 mA cm−2 with 1 mAh cm−2 (>2000 h). Moreover, superior long‐term cycling and rate performance of NBF@Li anode are also acquired when assembled with high areal loading of LiFePO4 (10.1 mg cm−2) cathode (Negative/Positive ratio: 2.91). Even in anode‐free metal lithium batteries, NBF has higher capacity during cycling compared with NF. To conclude, NBF shows excellent electrochemical performance and provides an idea of facile preparation method which can be extend to other metal batteries.
Transpositional Circularly Polarized Luminescence from Transient Charge‐Transfer Coassembly
Authors: Wang Zhuoer , Hao Aiyou , Xing Pengyao 
Published: October 2021

AbstractCharge‐transfer (CT) complexation between electron‐rich and deficient aromatics has been widely applied in functional optical and photovoltaic materials. The selective complexation and spontaneous disassociation behavior of a dynamic charge‐transfer coassembly possess potential in designing smart and dynamic luminescent materials, which however have not been addressed so far. In this work, the transient charge‐transfer driven coassembly between π‐conjugated amino acids and tetracyanobenzene, showing dynamic luminescent transition and circularly polarized luminescence (CPL) evolution property, is illustrated. Transient coassembly behaviors are independent to the diverse binding sites covering fluorene, naphthalene, and anthracene, attributed to the intramolecular CH…π interaction. Incorporation of fluorescent dyes enables a transient light harvesting process with hyperchromic CPL properties. Spontaneous green‐to‐red CPL transition hydrogels are also fabricated by embedding a competitive CT donor. Using a polymeric matrix treated by organic solvents, charge‐transfer coassembly is immobilized with diverse circularly polarized luminescence. Such sensitive complexation shows applications in moisture‐responsive luminescent materials and multiple luminescent color evolutions are realized.
Site and Enantioselective Aliphatic C−H Oxidation with Bioinspired Chiral Complexes
Authors: Costas Miquel 
Published: October 2021

AbstractSelective oxidation of aliphatic C−H bonds stands as an unsolved problem in organic synthesis, with the potential to offer novel paths for preparing molecules of biological interest. The quest for reagents that can perform this class of reactions finds oxygenases and their mechanisms of action as inspiration motifs. Among the numerous families of synthetic catalysts that have been explored, complexes with linear tetraazadentate ligands combining two aliphatic amines and two aromatic amine heterocycles display a structural versatility proven instrumental in the design of C−H oxidation reactions showing site and enantioselectivities, not accessible by conventional oxidants. This manuscript makes a review of recent advances in the field.
Determination of frequency, multiple antibiotic resistance index and resistotype of Salmonella spp. in chicken meat collected from southeast of Iran
Authors: Mir Reza , Salari Saeed , Najimi Mohsen , Rashki Ahmad 
Published: October 2021

AbstractBackgroundZoonotic food‐borne pathogens such as Salmonella spp., which can be hosted by some raw foods, play a crucial role in ranking the public health of a countryObjectivesThe present study was conducted to assess the frequency, antibiotic resistance pattern and index of multiple antibiotic resistance (MAR) of Salmonella spp. in chicken meatMethodsA cross‐sectional survey was conducted from October 2017 to March 2018. One‐hundred and fifty chicken meat samples were collected from meat stores in Zahedan, southeast of Iran and screened for contamination with Salmonella spp. using the polymerase chain reaction assay targeting the inv‐A gene. Antimicrobial susceptibility testing was performed against 11 commonly prescribed antimicrobial agents in the veterinary treatment to calculate the MAR indexResultsThe contamination rate was 2.7% (4/150). The antimicrobial resistance rate was 100% (n = 4) against penicillin, tylosin, tetracycline, erythromycin and tiamulin, 50% (n = 2) against trimethoprim/sulfamethoxazole, difloxacin and lincomycin/spectinomycin and 25% (n = 1) against flumequine and florfenicol. All isolates were sensitive to fosfomycin. Interestingly, all isolates (n = 4) exhibited different MAR patterns. Furthermore, the MAR index ranged from 0.45 to 0.81ConclusionsIn addition to the MAR index, which indicated that the isolate originated from a source where antibiotics were used to a great degree and/or in large amounts, the results showed that the chicken meat hosted resistant strains of Salmonella spp. in the study area. Overall, the findings indicated an important public health problem. To reduce this alarming signal, the poultry industry should implement control measures in the study area.
Effect of functionalized silicon carbide nano‐particles as additive in cross‐linkedPVAbased composites for vibration damping application
Authors: Bisht Nitesh , Verma Akarsh , Chauhan Sakshi , Singh Vinay Kumar 
Published: October 2021

AbstractIn this research study, a comprehensive effort has been made to functionalize silicon carbide particles using the acidic oxidation with nitric acid to obtain homogeneous stabilized distribution of activated SiC particles within a polymer matrix, and develop functionalized silicon carbide (f‐SiC) particle reinforced polyvinyl alcohol (PVA) based cross‐linked composite. After fabrication of functionalized silicon carbide (f‐SiC) particle reinforced polyvinyl alcohol based cross‐linked composite with varying f‐SiC weight percentages of PVA (0%, 1%, 2%, 3%, and 4%) were placed to various investigations. Processed samples are initially examined based by the physical tests (water absorption tests), followed by mechanical test (tensile test) and then micro‐structural tests (scanning electron microscopy). Lastly, thermal tests were also concluded which involved the dynamic mechanical, differential thermal and thermo gravimetric analysis. The cross‐linked polyvinyl alcohol‐based composite with 2 weight % of f‐SiC content is observed to be the superlative of all the compositions under this research study that was confirmed by the mechanical and micro‐structural tests. This composite material shows high storage modulus with visco‐elastic behavior, therefore, the material can be utilized to diminish the transmission of noise, as a shock absorber and vibration isolator.
Fishing Livelihoods and Fisheries Governance
Authors: Fabinyi Michael , Barclay Kate 
Published: October 2021

AbstractThis book centres on an understanding of fishing livelihoods within processes of historical change, and the social and political relationships within which they are embedded. Drawing on our research experience from the Asia-Pacific region, we examine where fishing livelihoods have come from, and where they are going. This introductory chapter introduces fishing livelihoods and the governance challenge that they face, before examining social science research in greater depth. We then develop the idea of a relational approach to fishing livelihoods, describing how they are shaped by wider political and economic trajectories, by local social relationships and by institutional structures.
Responding to Global Change
Authors: Fabinyi Michael , Barclay Kate 
Published: October 2021

AbstractThis chapter focuses on the wider processes of political-economic change that drive key characteristics of fishing livelihoods. Globalisation has dramatically expanded the scale and accelerated the pace of fisheries capture and trade, generating new opportunities and challenges for livelihoods and marine environments. Here we document some of the major characteristics of the history of fishing across the Asia-Pacific, before focusing on case studies of the Philippines and PNG. We highlight three related features of globalisation that have influenced fishing livelihoods and that continue to shape them today: migration, engagement with markets and new technologies, and interactions with other forms of economic activity, including those outside the fisheries sector.
Fishing Livelihoods and Wellbeing
Authors: Fabinyi Michael , Barclay Kate 
Published: October 2021

AbstractThe final chapter of this book discusses the implications of a relational approach to fishing livelihoods for governance for improved social and ecological outcomes. The chapter reviews some of the ways in which academics, activists and policymakers can use approaches that emphasise the relational context of fishing livelihoods, and specifies the concept of wellbeing as one that can usefully and practically build bridges between fisheries stakeholders with diverse interests. The chapter then examines two assessments of fisheries on community wellbeing: the social and economic impacts of fisheries in Australia, and the effects of governance on wellbeing of fishing communities in Indonesia and Solomon Islands.
Pharmacokinetics and pharmacodynamics of cyclopropylfentanyl in male rats
Authors: Bergh Marianne Skov-Skov , Bogen Inger Lise , Garibay Nancy , Baumann Michael H. 
Published: October 2021

Abstract
Background
Illicitly manufactured fentanyl and its analogs are a major driving force behind the ongoing opioid crisis. Cyclopropylfentanyl is a fentanyl analog associated with many overdose deaths, but limited knowledge is available about its pharmacology. In the present study, we developed a bioanalytical method for the determination of cyclopropylfentanyl and its main metabolite cyclopropylnorfentanyl and evaluated pharmacokinetic-pharmacodynamic relationships in rats.

Method
An ultra-high performance liquid chromatography tandem mass spectrometry (UHPLC-MS/MS) method was developed and validated for determination of cyclopropylfentanyl and cyclopropylnorfentanyl in rat plasma. Male Sprague–Dawley rats fitted with jugular catheters and temperature transponders received cyclopropylfentanyl (30, 100, and 300 μg/kg) or saline subcutaneously. Blood specimens were withdrawn over an 8-h time period, along with measurements of pharmacodynamic endpoints.

Results
The analytical method was validated, and both analytes exhibited a low limit of quantification (15 pg/mL). Cyclopropylfentanyl caused dose-related increases in hot plate latency (ED50 = 48 µg/kg) and catalepsy (ED50 = 87 µg/kg) and produced long-lasting hypothermia at the highest dose. Plasma cyclopropylfentanyl rose rapidly in a dose-related fashion, reaching maximal concentration (Cmax) after 15–28 min, whereas metabolite Cmax occurred later at 45–90 min. Cyclopropylfentanyl Cmax values were similar to concentrations measured in non-fatal intoxications in humans; however, differences in parent drug: metabolite ratio indicated possible interspecies variance in metabolism.

Conclusion
Our study shows that cyclopropylfentanyl produces typical opioid-like effects in male rats. Cyclopropylfentanyl displays much greater analgesic potency when compared to morphine, suggesting that cyclopropylfentanyl poses increased overdose risk for unsuspecting users.
Nuclear depletion of RNA-binding protein ELAVL3 (HuC) in sporadic and familial amyotrophic lateral sclerosis
Authors: Diaz-Garcia Sandra , Ko Vivian I. , Vazquez-Sanchez Sonia , Chia Ruth , Arogundade Olubankole Aladesuyi , Rodriguez Maria J. , Traynor Bryan J. , Cleveland Don , Ravits John 
Published: October 2021

AbstractAmyotrophic lateral sclerosis is a progressive fatal neurodegenerative disease caused by loss of motor neurons and characterized neuropathologically in almost all cases by nuclear depletion and cytoplasmic aggregation of TDP-43, a nuclear RNA-binding protein (RBP). We identified ELAVL3 as one of the most downregulated genes in our transcriptome profiles of laser captured microdissection of motor neurons from sporadic ALS nervous systems and the most dysregulated of all RBPs. Neuropathological characterizations showed ELAVL3 nuclear depletion in a great percentage of remnant motor neurons, sometimes accompanied by cytoplasmic accumulations. These abnormalities were common in sporadic cases with and without intermediate expansions in ATXN2 and familial cases carrying mutations in C9orf72 and SOD1. Depletion of ELAVL3 occurred at both the RNA and protein levels and a short protein isoform was identified, but it is not related to a TDP-43-dependent cryptic exon in intron 3. Strikingly, ELAVL3 abnormalities were more frequent than TDP-43 abnormalities and occurred in motor neurons still with normal nuclear TDP-43 present, but all neurons with abnormal TDP-43 also had abnormal ELAVL3. In a neuron-like cell culture model using SH-SY5Y cells, ELAVL3 mislocalization occurred weeks before TDP-43 abnormalities were seen. We interrogated genetic databases, but did not identify association of ELAVL3 genetic structure with ALS. Taken together, these findings suggest that ELAVL3 is an important RBP in ALS pathogenesis acquired early and the neuropathological data suggest that it is involved by loss of function rather than cytoplasmic toxicity.
Spinneret geometry modulates the mechanical properties of man-made cellulose fibers
Authors: Moriam Kaniz , Sawada Daisuke , Nieminen Kaarlo , Ma Yibo , Rissanen Marja , Nygren Nicole , Guizani Chamseddine , Hummel Michael , Sixta Herbert 
Published: October 2021

AbstractThe production of cellulose-based textile fibers with high toughness is vital for extending the longevity and thus developing a sustainable textile industry by reducing the global burden of microplastics. This study presented strategies to improve fiber toughness by tuning spinneret geometries. Experimental studies were conducted by spinning with different spinneret geometries and measuring the mechanical and structural properties of the spun fibers. In addition, numerical simulation tools were used to better understand the effects of spinneret geometry. The altering parameters of the spinneret geometries were the capillary diameters D, the angle of the entry cone into the spinning capillary, and the ratio of capillary length to diameter L/D. The highest fiber toughness could be achieved at a capillary aspect ratio of 1 to 2. The obtained maximum fiber toughness was 93 MPa with a tensile strength of 60 cN/tex and a concomitant elongation of 16.5%. For these fiber properties, a 13 wt% solution of a high-purity pulp with higher viscosity in [DBNH][OAc] was spun into a 1.3 dtex fiber using a D100 spinneret with a capillary of 1:1 length/diameter and an entrance angle of 8°. It was noticeable that the microvoid orientations decreased almost linearly with increasing toughness of the fibers. The morphologies of the fibers were similar regardless of the spinneret geometries and the raw materials used in the spinning process. In summary, by modulating the spinneret geometries, Ioncell fibers obtained high toughness that have the potential to replace synthetic fibers.
Should gains from criminal knowledge be forfeited?
Authors: Mamak Kamil , Barczak-Oplustil Agnieszka , Kwiatkowski Daniel , Małecki Mikołaj , Zając Dominik 
Published: October 2021

AbstractNobody should profit from crime; this fundamental moral principle is uncontroversial. At the level of public declaration, few people are likely to disagree with this statement; however, controversies arise when the implementation of this principle is under discussion. Numerous provisions exist that aim to strip criminals of the proceeds from their crimes, but not all aspects of this issue are immediately apparent. For example, a significant question is how to treat profits that a criminal makes from activities including recounting stories about their criminal activities, publishing books describing their actions, or creating YouTube videos presenting details about their crimes. Such profits are either treated as legitimate or are targeted by complicated legal methods of deprivation. The view presented in this paper could facilitate the ability to strip criminals from these forms of profit. This article argues that revenue accruing from knowledge gained from association with crime should be treated as indirect proceeds of crime and, as such, should be forfeited.
Flow cytometric approach to evaluate the impact of hydro-technical concrete compounds’ release to the freshwater microbiome
Authors: Wojtasik Barbara , Zbawicka Małgorzata , Grabarczyk Lucyna , Juzwa Wojciech 
Published: October 2021

AbstractThe aim of this research was to test the potential of applying a flow cytometric procedure to evaluate the impact of concrete compounds’ release to the freshwater microbiome. Cells from the collected samples were stained with a fluorogenic redox indicator dye that measures the redox potential of microbial cells. This novel approach was combined with the assessment of microorganisms’ penetration into the internal structures of concrete using the Rose Bengal sodium salt staining. Rose Bengal staining revealed an intense fouling of the upper and side walls of the concrete cubes and also indicated the penetration of microorganisms inside the concrete as observed for the cubes’ cross-sections. Flow cytometric cellular redox potential measurement revealed high percentages of active cells within the concrete’s porous structures and in non-exposed water (32.7% and 30.2% of active cells) versus samples from exposed water and concrete’s outer surfaces (6.8%, 6.1%, and 3.3% of active cells). The results demonstrated a detrimental impact of hydro-technical concrete on the vitality of microbial cells within the freshwater environment. Tested protocol by analyzing the physiology of microbial cells improved the functional description of complex communities to evaluate the fate of contaminants present in the concrete-based hydro-technical infrastructure.