bluuebunny/crossref_metadata_2025_split huggingface dataset:
Worlds Apart? – The Challenges of Aligning Brand Value for NGO’s
Authors: Hand Karen , Murphy Rebecca , MacLachlan Malcolm , Carr Stuart Colin 
Published: October 2021

AbstractBrands are increasingly part of how international aid and development Non-Government Organisations (NGOs) operate, but there are challenges in aligning NGO brand value across diverse stakeholders. This research explores how key decision makers within one major NGO – Oxfam—construct the challenges of brand value alignment, using an Interpretative Phenomenological Analysis methodology. Three master-themes emerge demonstrating key tensions around aligning NGOs brand value: the difficulty of balancing competing stakeholder needs, the internal cultural conflict around branding, and the existential dilemma underlying the societal effectiveness of NGOs. This paper proposes that NGOs can better navigate these intra—brand tensions using Brand-as-Purpose as an organizing principle; framing shared identity, creating a dynamic container for stakeholder interests and cultivating Moral Capital strongly anchored in increasing recipient wellbeing. This paper is one of the first pieces of research which explores how NGOs make sense of aligning brand value in the context of complex stakeholder cultures and recipient sovereignty. Brand-as Purpose is put forward as an organizing principle to help balance three key tensions around brand value alignment. This paper proposes that Moral Capital anchored in recipient wellbeing underpins NGO brand value and societal legitimacy and needs to be paramount in how NGO’s establish and legitimize their brands.
A Computational Framework for Pre-Interventional Planning of Peripheral Arteriovenous Malformations
Authors: Franzetti Gaia , Bonfanti Mirko , Tanade Cyrus , Lim Chung Sim , Tsui Janice , Hamilton George , Díaz-Zuccarini Vanessa , Balabani Stavroula 
Published: October 2021

Abstract
Purpose
Peripheral arteriovenous malformations (pAVMs) are congenital lesions characterised by abnormal high-flow, low-resistance vascular connections—the so-called nidus—between arteries and veins. The mainstay treatment typically involves the embolisation of the nidus, however the complexity of pAVMs often leads to uncertain outcomes. This study aims at developing a simple, yet effective computational framework to aid the clinical decision making around the treatment of pAVMs using routinely acquired clinical data.

Methods
A computational model was developed to simulate the pre-, intra-, and post-intervention haemodynamics of a patient-specific pAVM. A porous medium of varying permeability was employed to simulate the sclerosant effect on the nidus haemodynamics. Results were compared against clinical data (digital subtraction angiography, DSA, images) and experimental flow-visualization results in a 3D-printed phantom of the same pAVM.

Results
The computational model allowed the simulation of the pAVM haemodynamics and the sclerotherapy-induced changes at different interventional stages. The predicted inlet flow rates closely matched the DSA-derived data, although the post-intervention one was overestimated, probably due to vascular system adaptations not accounted for numerically. The nidus embolization was successfully captured by varying the nidus permeability and increasing its hydraulic resistance from 0.330 to 3970 mmHg s ml−1. The nidus flow rate decreased from 71% of the inlet flow rate pre-intervention to 1%: the flow completely bypassed the nidus post-intervention confirming the success of the procedure.

Conclusion
The study demonstrates that the haemodynamic effects of the embolisation procedure can be simulated from routinely acquired clinical data via a porous medium with varying permeability as evidenced by the good qualitative agreement between numerical predictions and both in vivo and in vitro data. It provides a fundamental building block towards a computational treatment-planning framework for AVM embolisation.
The Interplay between Individual and Collective Activity: an Analysis of Classroom Discussions about the Sierpinski Triangle
Authors: Saxe Geoffrey B. , Farid Amelia M. 
Published: October 2021

AbstractThis article uses a cultural-developmental framework to illuminate the interplay between collective and individual activity in the mathematical reasoning displayed in a university Masters level lesson on fractals. During whole class and small group discussions, eleven students, guided by an instructor, engage in inductive reasoning about the area and perimeter of the Sierpinski triangle, a unique mathematical object with zero area and infinite perimeter. As participants conceptualize and communicate about the Sierpinski problem, they unwittingly generate a linguistic register of action word forms (e.g., fencing, zooming) and object word forms (e.g., area, infinity) to serve Sierpinski-linked mathematical reasoning functions, a register that we document in the first analytic section of the article. In the second analytic section, we report a developmental analysis of microgenetic, ontogenetic, and sociogenetic shifts in the word forms constitutive of the register and their varied functions in participants’ activities. In the third analytic section, we provide a cultural analysis of the classroom’s collective practices, practices that enable and constrain participants’ constructions of form-function relations constituting the register. We examine the ways in which participants work to establish a common ground of talk in their communicative exchanges, exchanges supported by classroom norms for public displays of reasoning and active listening to one another’s ideas. We show that it is as participants work to establish a common ground that the register emerges and is reproduced and altered. We conclude by pointing to ways that the analytic framework can be extended to illuminate learning processes in other classroom settings.
Rational Design of MOF-Based Materials for Next-Generation Rechargeable Batteries
Authors: Ye Zhengqing , Jiang Ying , Li Li , Wu Feng , Chen Renjie 
Published: October 2021

AbstractMetal–organic framework (MOF)-based materials with high porosity, tunable compositions, diverse structures, and versatile functionalities provide great scope for next-generation rechargeable battery applications. Herein, this review summarizes recent advances in pristine MOFs, MOF composites, MOF derivatives, and MOF composite derivatives for high-performance sodium-ion batteries, potassium-ion batteries, Zn-ion batteries, lithium–sulfur batteries, lithium–oxygen batteries, and Zn–air batteries in which the unique roles of MOFs as electrodes, separators, and even electrolyte are highlighted. Furthermore, through the discussion of MOF-based materials in each battery system, the key principles for controllable synthesis of diverse MOF-based materials and electrochemical performance improvement mechanisms are discussed in detail. Finally, the major challenges and perspectives of MOFs are also proposed for next-generation battery applications.
Full Detector Simulation with Unprecedented Background Occupancy at a Muon Collider
Authors: Bartosik Nazar , Andreetto Paolo , Buonincontri Laura , Casarsa Massimo , Gianelle Alessio , Griso Simone Pagan , Jindariani Sergo , Lucchesi Donatella , Meloni Federico , Pastrone Nadia , Sestini Lorenzo 
Published: October 2021

AbstractIn recent years, a Muon collider has attracted a lot of interest in the high-energy physics community, thanks to its ability of achieving clean interaction signatures at multi-TeV collision energies in the most cost-effective way. Estimation of the physics potential of such an experiment must take into account the impact of beam-induced background on the detector performance, which has to be carefully evaluated using full detector simulation. Tracing of all the background particles entering the detector region in a single bunch crossing is out of reach for any realistic computing facility due to the unprecedented number of such particles. To make it feasible a number of optimisations have been applied to the detector simulation workflow. This contribution presents an overview of the main characteristics of the beam-induced background at a Muon collider, the detector technologies considered for the experiment and how they are taken into account to strongly reduce the number of irrelevant computations performed during the detector simulation. Special attention is dedicated to the optimisation of track reconstruction with the conformal tracking algorithm in this high-occupancy environment, which is the most computationally demanding part of event reconstruction.
Slug flow as tool for selectivity control in the homogeneously catalysed solvent-free epoxidation of methyl oleate
Authors: Gladius Anoj Winston , Vondran Johanna , Ramesh Yashwanth , Seidensticker Thomas , Agar David William 
Published: October 2021

AbstractCatalytic oxidation of sustainable raw materials like unsaturated fats and oils, or fatty acids and their esters, lead to biobased, high-value products. Starting from technical grade methyl oleate, hydrogen peroxide as a green oxidant produces only water as by-product. A commercially available, cheap water-soluble tungsten catalyst is combined with Aliquat® 336 as a phase-transfer agent in solvent-free reaction conditions. In this study, we first report the transfer of this well-known batch system into continuous mode. The space–time yield is improved from 0.08 kg/L.h in batch to 1.29 kg/L.h in flow mode. The improved mass transfer and reduced back mixing of the biphasic liquid–liquid slug flow allows for selectivity control depending on physical parameters of slug flow namely volumetric phase ratio, volumetric flow rate, and slug length. Even though the product, methyl 9,10-epoxystearate is obtained at a maximum selectivity of only 58% in flow mode, higher space time yield combined with possible reactant recycling in flow mode offers a promising avenue of research. This work analyses the use of slug flow parameters as tools for controlling selectivity towards oxidation products of methyl oleate.
Republican Theory and the EU: Emergency Laws and Constitutional Challenges
Authors: Herlin-Karnell E. 
Published: October 2021

AbstractThe COVID-19 pandemic has raised many intriguing questions both in the EU and globally, from the critical task of safeguarding lives to technical legal issues about competences to regulate health as well as the boundaries of emergency laws. This paper is interested in the connection between non-domination theory and the EU’s constitutional structure in the context of emergency laws. A key theme of the paper is that risk and emergencies are nothing new in an EU context, but concepts used by the legislator in a wide range of policy areas which give rise to a number of constitutional challenges. The paper sketches out the main characteristics of non-domination and republication theory and addresses the question of how and why the notion of non-domination may be useful for understanding the EU constitutionalism venture in the framework of risk and emergency laws.
Mycorrhiza Reduces Phosphorus Uptake from Struvite in Rye (Secale cereale L.) Plants
Authors: Schwalb Sanja Annabell , Hemkemeyer Michael , Watson Conor , Wichern Florian 
Published: October 2021

AbstractTo reduce dependency on inorganic phosphorus (P) fertiliser, secondary P fertilisers such as struvite are becoming more important. However, the P uptake of these new fertilisers by plants is often not known and may be enhanced by plant associated microorganisms. We therefore investigated the effect of arbuscular mycorrhizae (AM) on P uptake in rye (Secale cereale L.), grown in the middle compartment of a box with chambers separated by a 30 µm mesh allowing fungal hyphae but not roots to penetrate. Plants with (AM) or without (control) mycorrhizae (Rhizophagus irregularis) were grown in a P limited sand medium for 72 days. After harvest, plants were analysed for mycorrhizal colonization, shoot and root development and nutrient (P, Ca, Mg) uptake. Further, pH was measured in each compartment. Shoot biomass of both treatments was not different, but root biomass was significantly lower in AM plants. Despite plants of the AM treatment being colonised by mycorrhizae, their P uptake was substantially lower compared to the control treatment, but root nutrient concentration was higher. Even though the pH in the mycorrhizal compartment of the AM treatment was significantly lower compared to the control, water- and CAL-extractable P were similar, indicating little P uptake from this compartment. Extractable P was reduced only in the root compartment of the control, which was associated with a lower pH compared to the AM treatment. In conclusion, mycorrhizae did not increase P uptake from struvite in rye plants. Non-mycorrhizal plants which invested more biomass into roots took up more P.
Graphical abstract
Combined Mastectomy and Laparoscopic Hysterectomy with Salpingo-Oophorectomy in Transgender Men: a Cohort Study
Authors: Gold Daniela , Galvez Marie-Christine Bertholin y , Laback Christian , Hartleb Riccarda , Tomasch Gordana , Schöpfer Stephanie , Bjelic-Radisic Vesna , Hochstätter Rüdiger , Pristauz-Telsnigg Gunda , Laky Rene , Reif Philipp , Bader Arnim , Tamussino Karl 
Published: October 2021

Abstract
There are few data on complications with gender affirming surgery. The aim of this study was to assess peri- and postoperative complications of laparoscopic hysterectomy and mastectomy performed in a single sitting in transgender men. Assessment of intra- and postoperative complications in a series of 65 transgender men (mean age 27, range 18–47) undergoing concomitant mastectomy and laparoscopic hysterectomy with salpingo-oophorectomy. Mean operating time was 292 ± 47 min. Thirty-four (52%) patients experienced complications: 28 (41%) DINDO grade I, 0 DINDO grade 2, 6 (11%) DINDO grade III. The six grade 3 complications consisted of 5 hematomas requiring evacuation after mastectomy and 2 vaginal tears requiring transvaginal repair. Three patients were readmitted within 30 days, all for postoperative bleeding/hematoma. In transgender men, performing laparoscopic hysterectomy and mastectomy at a single sitting has a modest rate of perioperative complications, and may improve resource utilization.
Linking research, education and citizen codesign: compact cities as social intensification
Authors: Stenberg Jenny , Thuvander Liane , Kain Jaan-Henrik , Adelfio Marco 
Published: October 2021

AbstractBoth research and policy argue for more compact cities, but there is little clarity regarding which urban qualities must be made more compact to achieve the purported benefits. This paper discusses an example of how to conduct immersive and localised studies by connecting research and education to community outreach. Three potential positive outcomes of linking are examined: (a) linking may improve research activities, (b) linking may have a positive impact on student learning, and (c) better valorisation of research results may be achieved. Within a master’s course, architectural students used codesign methods to investigate how the compact city concept can be understood and applied at the neighbourhood level; this assignment was formulated within a research project. The researchers performed observations and feedback tutorials, and the students applied mixed methods, including a literature review, meetings with researchers and stakeholders, site analysis, interviews and a pop-up workshop with residents, strategy development, design proposals, and feedback meetings with critics and local stakeholders. The results show that this linking may contribute significantly to research activities, as the results of a collaborative process between students and local residents were noteworthy. Rather than focusing on the physical environment, the residents argued that the starting point for urban development should be the social aspects. The residents helped the students understand what social aspects to focus on and how to think about certain locations. In terms of education, the collaboration gave students access to the latest research. Better valorisation of research results was achieved with actors at the local level. However, higher up in the municipal hierarchy, valorisation remained a challenge. Linking research and education to community outreach is not particularly common, even if linking all three activities has the potential to lead to systemic change.
Effectiveness of ketofol versus propofol induction on hemodynamic profiles in adult elective surgical patients: A Randomized Controlled Trial
Authors: Hailu Seyoum , Getachew Hailemariam , Hailu Sileshi , Abebe Teshome , Seifu Ashenafi , Regassa Teshome , Girma Timsel , Dastew Belete , Zemedkun Abebayehu , Neme Derartu , Teshome Diriba , Tadesse Muhuddin 
Published: October 2021

ABSTRACT

Background:
Most of the time propofol and ketamine have been used as an induction agent in adult surgical patients but propofol may cause cardiorespiratory depression while ketamine increases heart rate and arterial blood pressure. On the other hand, the clinical effects of propofol and ketamine seem to be complementary. Ketofol is most commonly used for procedural sedation hence exploring its effectiveness for induction will be paramount for the clinical care of surgical patients.

Objective:
This study aims to compare the hemodynamic changes between ketofol and propofol within 30 min after induction of general anesthesia for elective surgical patients.

Methodology:
A Double-blind Randomized Controlled Trial was done on 62 patients aged between 18 and 65 years and the American Society of Anesthesiologist class I & II those have been allocated randomly into ketofol and propofol groups. A change in systolic blood pressure, mean arterial pressure, and heart rate within 30mins was followed for both groups. After the normal distribution of data was tested analytic statistics were calculated for variables in the study using Mixed ANOVA, Independent samples T-test, and Mann Whitney U test as appropriate, and for categorical data Chi-square test or fisher's exact test was used for analysis. P-value < 0.05 is considered statistically significant with a power of 90%.

Results:
Both the mean systolic blood pressure and mean arterial pressure were significantly decreased in the propofol group immediately after induction, at 5th minute, 10th minute, and 15th minute compared to the baseline value with a statistically significant value of (p < 0.05).
There was a significant increase in mean heart rate in the ketofol group immediately after induction and on the 5th minute after induction compared to the baseline value (p = 0.001 and p = 0.022 respectively).

Conclusion and recommendations:
We conclude the administration of ketofol (0.75 mg/kg of ketamine and 1.5 mg/kg of propofol) for induction of general anesthesia has better hemodynamic stability than propofol during the first 30 min after induction. We recommend to researchers to do further randomize controlled trials, with invasive blood pressure measurement and multicenter study.

Highlights
La Loi sur la laïcité de l’État et les conditions de la fondation juridique d’un modèle interculturel au Québec
Authors: Lampron Louis-Philippe 
Published: October 2021

RésuméL’interculturalisme québécois est un modèle de gestion de la diversité culturelle et religieuse qui, pour plusieurs, se distinguerait du multiculturalisme à la canadienne et ferait l’objet d’un large consensus au sein de la population québécoise. Résolument pluraliste, ce modèle distinct de gestion de la diversité aurait pu être opérationnalisé juridiquement dans le cadre constitutionnel canadien avant l’adoption de la Loi sur la laïcité de l’État. Or, le processus suivi par le gouvernement québécois pour faire adopter cette dernière, le 16 juin 2019, et tenter d’éviter que sa constitutionnalité puisse être contestée devant les tribunaux canadiens rend très difficile – voire impossible – la fondation juridique de l’interculturalisme québécois dans le contexte actuel.
Marge ou crève
Authors: Delgrange Xavier 
Published: October 2021

RésuméSous son aspect positif, la marge d’appréciation que la Cour européenne des droits de l’homme reconnaît aux États permet à ceux-ci d’enrichir le socle des droits fondamentaux établi par la Convention européenne des droits de l’homme. Elle met en avant la responsabilité de chaque État dans la concrétisation de la Convention. Elle contribue alors au développement de la démocratie qui croît avec le renforcement des droits de l’homme. Sous son aspect négatif, l’invocation de la marge d’appréciation permet à la Cour d’absoudre certains États alors que ceux-ci sapent le socle des droits fondamentaux. Elle s’y sent contrainte pour amadouer les États qui contestent son autorité au nom de leur autonomie. Question de survie donc ou à tout le moins de préservation de son rôle unificateur. Le réalisme politique l’emporte alors sur les exigences démocratiques.
Convergence culturelle et légistique: pour un modèle québécois d’intégration distinct consacré par une loi-cadre
Authors: Rousseau Guillaume 
Published: October 2021

RésuméSuite à la loi 101, la Politique québécoise du développement culturel a visé à faire en sorte que la culture québécoise soit commune à tous et puisse s’enrichir d’apports en provenance des minorités culturelles. Puis, divers écrits ont contribué à faire évoluer le concept de convergence culturelle, à le critiquer ou à répondre à ceux qui le critiquent. À la lumière de cette politique et de ces écrits, on peut associer ce concept à sept principes : lien consubstantiel entre la langue française et la culture québécoise, impératif de la préservation du statut majoritaire de la culture québécoise et de la langue française, refus de l’assimilation des minorités culturelles, intégration, appropriation identitaire, mixité, et rôle vital des œuvres et productions artistiques. Reprenant ces principes et respectant certains critères de la légistique (clarté, cohérence, concision, véracité), le présent article propose le texte d’une loi-cadre sur la convergence culturelle, et la situe théoriquement.
Autism spectrum disorder in older adults with intellectual disability: a scoping review
Authors: Maguire E. , Mulryan N. , Sheerin F. , McCallion P. , McCarron M. 
Published: October 2021

Introduction:Ireland has an ageing population of persons with intellectual disability (ID), autism spectrum disorder (ASD) and both (ID/ASD). Despite this, little is known about the prevalence of ASD and its effect on functional outcomes, psychiatric comorbidity or diagnostic issues in an older population with ID. This article reviews the literature on older adults with ID/ASD and identifies opportunities for future research in this population.Method:The authors searched the Medline, Pubmed, Embase, CINAHL and PsychInfo databases using the search terms using key words: (older adults) AND (ID OR mental retardation OR learning disability) AND (autism OR ASD). After excluding articles for relevance, a scoping review was carried out on the results retrieved.Results:Of the 1227 articles retrieved from the literature on ID and autism/ASD in older adults, 85 articles were relevant to an adult population with ID/ASD. The data were collated and are presented covering domains of diagnosis, prevalence, psychiatric comorbidities and functional outcomes.Conclusions:Despite increased prevalence in childhood ASD in the last 20 years, there is a lack of research regarding adults, especially older adults, with ASD, up to half of whom will have some level of ID. The existing literature suggests that older adults with ID/ASD may have reduced functional independence, increased psychiatric comorbidity and psychotropic prescribing and more behavioural presentations than the older population generally or those with ID only. There is a need for longitudinal data to be collected on this ageing population so that care and management needs can be met in the future.