bluuebunny/crossref_metadata_2025_split huggingface dataset:
Phase composition, morphology, properties and improved catalytic activity of hydrothermally-derived manganese-doped ceria nanoparticles
Authors: Kurajica S , Ivković I K , Dražić G , Shvalya V , Duplančić M , Matijašić G , Cvelbar U , Mužina K 
Published: December 2021

Abstract
Manganese-doped ceria nanoparticles were prepared by hydrothermal synthesis and the prepared samples were thermally treated at 500 °C for 2 h. The samples were investigated using x-ray diffraction (XRD), high-resolution transmission electron microscopy (HR-TEM), energy-dispersive x-ray spectroscopy (EDS), N2 adsorption and x-ray photoelectron spectroscopy (XPS). XRD revealed that nanocrystalline ceria is the main phase in all samples, while a romanechite-like phase (Na2Mn5O10) appears in the sample doped with 30% of Mn. TEM coupled with EDS exposed the presence of the same phase in the sample doped with 20% Mn. While ceria particles have spherical morphology and particle size ranging from 4.3 to 9.2 nm, the rare crystals of the romanechite-like phase adopt a tubular morphology with a length of at least 1 μm. However, the decrease in the ceria lattice constant and the EDS spectra of the ceria nanoparticles clearly indicate that a substantial amount of manganese entered the ceria crystal lattice. Manganese doping has a beneficial impact on the specific surface area of ceria. XPS measurements reveal a decrease in the Ce3+/Ce3+ + Ce4+ content in the doped samples which is replaced by Mn3+. Moreover, a drastic increase in adsorbed oxygen is observed in the doped samples which is the consequence of the increase in Mn3+ species that promotes oxygen migrations to the surface of the sample. Compared to the pure sample, the doped samples showed significantly higher catalytic activity for the process of toluene oxidation.
Network Analysis to Determine the Optimal Route for Firefighters in Makassar City
Authors: Widyantoro Bimo Aji , Santosa Purnama Budi 
Published: December 2021

Abstract
Makassar city experiences many residential fire disasters during the last years. One of the causes of fires is difficult to overcome due to the firefighters’ late response. The number of fires occurred due to the ineffectiveness of the fire fighting road, obstructed by traffic conditions, in its operation. Developing a geospatial route analysis can help firefighters quickly find the best route to a fire point to overcome this problem. Geospatial route analysis is currently a key role in emergency responses for urban fire disasters. A routing system can provide network analysis that allows users to navigate between source and destination points. In this case, the system can help firefighters to arrive as quickly as possible. On complicated road networks, some impedance factors would slow down drivers on a particular road. This study aims to provide firefighters from the base stations to residential fire disaster locations. The method used in the studies is Dijkstra’s algorithms to calculate weights of the impedance factors to optimal routing based on length of the road, speed drive, and traffic conditions. Implementation of routing analysis using open source geospatial software, PostgreSQL as database management system with PostGIS, and pgrouting as extensions. The modeling results show that the optimal route selection with speed parameters based on road classification has a low weight value. Therefore, it can be used as a reference for selecting a firefighter’s routing.
Analysis of accuracy comparison tidal global (FES2014, TPXO9) and regional (BIG Prediction) models to the existing tides in Surabaya and surrounding waters
Authors: Khomsin  , Pratomo D G , Rohmawati C N 
Published: December 2021

Abstract
Tidal data has a significant role in various fields in hydrographic surveys and navigation, port planning, and other coastal management. The number of fixed tide stations in Indonesia is minimal compared to the vast territorial waters in Indonesia. So that for areas that are not covered by tidal fixed stations, direct tidal observation with a certain length of observation is necessary, and of course, this requires quite expensive costs. Fortunately, there are regional and global tidal data predictions that can be used to determine tidal conditions in Indonesian waters. In this study, the regional (BIG) and the global (FES2014 and TPXO9) tidal data prediction models were validated with direct observation in the five locations such as Surabaya, Gresik1, Gresik2, Bangkalan, and Giligenting for 39 hours. The root means square error (rmse) calculation results show that in the five locations, the BIG tidal prediction has the smallest rmse value in three tidal stations at Gresik 1, Gresik 2, and Gili Genting with 0.303 m, 0.050 m, and 0.155 m respectively. At the same time, the TPXO9 tidal model shows the biggest rmse at Gresik 1, Gresik 2, and Bangkalan with 0.420 m, 0.195 m, and 0.630 m, respectively.
Approximate decoherence free subspaces for distributed sensing
Authors: Hamann Arne , Sekatski Pavel , Dür Wolfgang 
Published: December 2021

Abstract
We consider the sensing of scalar valued fields with specific spatial dependence using a network of sensors, e.g. multiple atoms located at different positions within a trap. We show how to harness the spatial correlations to sense only a specific signal, and be insensitive to others at different positions or with unequal spatial dependence by constructing a decoherence-free subspace for noise sources at fixed, known positions. This can be extended to noise sources lying on certain surfaces, where we encounter a connection to mirror charges and equipotential surfaces in classical electrostatics. For general situations, we introduce the notion of an approximate decoherence-free subspace, where noise for all sources within some volume is significantly suppressed, at the cost of reducing the signal strength in a controlled way. We show that one can use this approach to maintain Heisenberg-scaling over long times and for a large number of sensors, despite the presence of multiple noise sources in large volumes. We introduce an efficient formalism to construct internal states and sensor configurations, and apply it to several examples to demonstrate the usefulness and wide applicability of our approach.
Factors influencing household-level positive and negative solid waste management practices in rapidly urbanizing cities: insights from Santa Cruz de la Sierra, Bolivia
Authors: Lozano Lazo Denise P , Gasparatos Alexandros 
Published: December 2021

Abstract
Household solid waste management (HSWM) practices are a critical aspect of municipal solid waste management (MSWM) systems. Despite efforts to implement source separation and recycling at the household level in developing countries, negative practices such as illegal dumping and backyard burning remain ubiquitous, particularly in rapidly urbanizing cities. Source separation and recycling behaviors have been rarely studied in such cities. Moreover, studies on illegal dumping and backyard burning using robust tools and frameworks are practically non-existent. This study aims to (a) estimate the prevalence of ‘negative’ and ‘positive’ behaviors for different HSWM practices, and (b) identify their observable and non-observable influencing factors. The focus is Santa Cruz, a rapidly urbanizing city of Bolivia. Household surveys (n = 305) are used to establish the connections between latent constructs (e.g. awareness, satisfaction), and observable variables (e.g. location, socio-demographic characteristics) with each behavior. This is achieved through the combination of exploratory factor analysis to validate the constructs to be included in the analysis, and structural equation modeling to identify the most influential factors. Two causal models are developed, one for the positive behaviors (i.e. source separation, recyclables donation, recyclables selling, and use of drop-off facilities), and the other for the negative behaviors (i.e. illegal dumping and backyard burning). Results indicate that, satisfaction with the MSWM service has a negative and significant influence on the prevalence of illegal dumping and backyard burning behaviors, while the remoteness of the household (i.e. distance to the city center) has a positive significant effect on the prevalence of these behaviors. Source separation and recyclable donation are influenced positively by latent constructs such as attitudes, knowledge, and awareness. For recyclables selling and use of drop-off stations, income and location are the most relevant factors, although with smaller effects.
Chemometric and DoE-Based Analytical Quality Risk Management to HPTLC Method for Simultaneous Estimation of Metronidazole and Norfloxacin
Authors: Prajapati Pintu B , Patel Payal R , Shah Shailesh A 
Published: December 2021

Abstract
According to the upcoming ICH Q14 guideline, the development of an analytical method by the implementation of the AQbD approach based on analytical quality risk management and design of experiments will become a regulatory requirement for the registration of new drug substances and products. In literature, the HPTLC method has not been reported yet for simultaneous estimation of metronidazole and norfloxacin. Hence, the robust HPTLC method has been developed and validated for simultaneous estimation of metronidazole and norfloxacin using QRM and the DoE-based enhanced AQbD approach. The principal component analysis was applied for chemometric-based risk assessment of method risk parameters. The high-risk method parameters were optimized by a DoE-based full-factorial design. The MODR and control strategy was estimated for quality risk management throughout the lifecycle of the HPTLC method. The HPTLC method was developed using silica gel 60 F254 as stationary phase and acetonitrile-methanol-formic acid-ammonia (9.5 + 0.5 + 0.5 + 0.3, v/v) as mobile phase. The developed method was validated as per ICH Q2 (R1) guideline. The developed method was applied for the assay of combined pharmaceutical dosage forms of metronidazole and norfloxacin and results were found in compliance with their respective labeled claim.
Sex Difference and Interaction of SIRT1 and FOXO3 Candidate Longevity Genes on Life Expectancy: A 10-Year Prospective Longitudinal Cohort Study
Authors: Ji John S , Liu Linxin , Shu Chang , Yan Lijing L , Zeng Yi 
Published: December 2021

Abstract
SIRT1 and FOXO3 are both associated with longevity. Molecular biology research in many organisms (yeast, nematode worm Caenorhabditis elegans, and mice mammalian models) shows SIRT1 acts on the FOXO family of forkhead transcription factors to respond to oxidative stress better, shifting processes away from cell death toward stress resistance. Human population studies need epidemiologic evidence. We used an open cohort of 3 166 community-dwelling participants in China with follow-up from 2008 to 2018. The mean age at baseline was 84.6 years. In 16 375 person-years of follow-up, there were 1 968 mortality events. SIRT1 and FOXO3 exhibited Mendelian randomization as there was no correlation with each other and with baseline study population characteristics. Some SIRT1 and FOXO3 single-nucleotide polymorphisms showed protective effects for mortality risk. The FOXO3 protective effect was stronger in females, and the SIRT1 protective effect was stronger in male study participants. We did not see evidence of a synergistic effect of being carriers of both SIRT1 and FOXO3 advantageous alleles.
Trans-dimensional imaging of the random inhomogeneity structure in the southern Ryukyu arc, Japan
Authors: Takahashi Tsutomu , Kaiho Yuka , Ishihara Yasushi , Obana Koichiro , Miura Seiichi , Kodaira Shuichi , Kaneda Yoshiyuki 
Published: December 2021

SUMMARY
The seismic velocity structure of the lithosphere shows various inhomogeneities over a wide range of scales, and such inhomogeneity causes complex seismic waves above a few hertz due to multiple scattering. Medium around active volcanoes and large faults tends to show strong random inhomogeneity in relatively small areas. For a more precise understanding of such random velocity inhomogeneities, it is necessary to estimate their detailed spatial variation without smoothing constraints. This study introduces a trans-dimensional approach for the 3-D imaging of random inhomogeneity using the reversible jump Markov chain Monte Carlo (rjMCMC) method, and set the number of structural parameters and their spatial layout as unknown parameters. Since the scale dependence of the random inhomogeneity is related to the frequency dependence of seismic wave scattering, the covariance matrix of the likelihood function was defined to be non-diagonal so that residuals at different frequencies in each ray path are correlated. A synthetic test showed this covariance matrix worked adequately for estimating parameters of a power-law-type spectrum of random inhomogeneity. Analysis of seismic data at the southern Ryukyu arc in the southwest Japan found anomalies with strong and weak inhomogeneities. A strongly inhomogeneous band with a width of 20–30 km was distributed in the Okinawa Trough at depths of 0–20 km. In part of this area, magma intrusions and associated complex structures have been detected by a seismic reflection survey. The scale of the structures discussed in this study is almost the same with that discussed in the reflection survey. The rjMCMC-based analysis made it possible to compare random inhomogeneities with the structural variations estimated by the deterministic seismic reflection survey. Since analyses of scattered seismic waves can examine much greater depths than seismic reflection surveys, further comparisons between the two methods in the shallow crust could provide useful insights for detailed interpretation of complex structures at deeper depth.
Investigations into the relationship between domoic acid and copepods in Scottish waters
Authors: Cook Kathryn B , Lacaze Jean-Pierre , Machairopoulou Margarita , Bresnan Eileen 
Published: December 2021

Abstract
This study investigated impacts of the algal toxin domoic acid (DA) on copepods in Scottish waters. Inspection of seasonal patterns revealed that several common copepods (Acartia spp. Dana, 1846, Calanus spp. Leach, 1816, Centropages spp. Krøyer, 1849, Pseudocalanus spp. Boeck, 1872, and Temora longicornis (Müller O.F., 1785)) regularly coexist with potentially toxic species from the diatom genus Pseudo-nitzschia H. Peragallo in H. Peragallo and M Peragallo, 1900. A short field study investigating the DA content of Calanus spp. at the Scottish Coastal Observatory site at Stonehaven recorded DA during every sampling event. The highest DA levels were associated with a July bloom (∼135000 cells L−1) of Pseudo-nitzschia cf. plurisecta Orive & Pérez-Aicua 2013. Several studies have previously investigated effects of ingested DA on copepods but information on effects of dissolved DA is lacking, therefore, simple exposure experiments were carried out to measure mortality of copepod species at ecologically relevant concentrations of dissolved DA. The highest concentrations tested (≥ 50 ng DA mL−1) decreased survival in Temora longicornis only; survival of other copepod species was unaffected. However, T. longicornis feeding on non-toxic algae in the presence of dissolved DA did not accumulate DA in their tissue. This study provides evidence of the potential for Calanus spp. to act as vectors for DA to higher trophic levels in Scottish waters.
Shifts in neritic copepod communities off the Basque coast (southeastern Bay of Biscay) between 1998 and 2015
Authors: Iriarte Arantza , Villate Fernando , Uriarte Ibon , Bidegain Gorka , Barroeta Ziortza 
Published: December 2021

Abstract
The interannual variations in absolute and relative densities of copepods from the neritic waters of the southeastern Bay of Biscay and their relationship to climate teleconnections and local environmental factors were assessed using time series for the 1998–2015 period. Opposite patterns of variation of the absolute densities of spring Acartia clausi and Centropages typicusspecies vs. summer/autumn species, mainly Oncaea media, but also Ditrichocorycaeus anglicus, Oithona nana, Temora stylifera, and Oithona plumifera were detected. This type of opposite patterns were also observed between the relative densities of the spring A. clausi and summer Paracalanus parvus species. These opposite density patterns were positively correlated to all seasons North Atlantic Oscillation (NAO), spring East Atlantic pattern (EA), summer and autumn water temperature and summer chlorophyll a. They were negatively correlated to summer EA pattern, the winter and spring Atlantic Multidecadal Oscillation (AMO) and water temperature, and the upwelling index of all seasons. In these patterns of copepod variation two regime shifts were detected, one in 2008 towards an increase in the spring species and the other one in 2014–2015 towards an increase of summer species. This latter regime shift coincides in time with the abrupt community shifts predicted in the literature for 2014.
Pipecolic Acid, a Putative Mediator of the Encephalopathy of Cerebral Malaria and the Experimental Model of Cerebral Malaria
Authors: Keswani Tarun , Obeidallah Aisha , Nieves Edward , Sidoli Simone , Fazzari Melissa , Taylor Terrie , Seydel Karl , Daily Johanna P 
Published: December 2021

Abstract

Background
We explored a metabolic etiology of cerebral malaria (CM) coma.

Methods
Plasma metabolites were compared between Malawian children with CM and mild Plasmodium falciparum malaria. A candidate molecule was further studied in animal models of malaria.

Results
Clinically abnormal concentrations of pipecolic acid (PA) were present in CM plasma, and nearly normal in mild malaria samples. PA is renally cleared and the elevated PA blood levels were associated with renal insufficiency, which was present only in CM subjects. Prior studies demonstrate that PA has neuromodulatory effects and is generated by malaria parasites. PA brain levels in Plasmodium berghei ANKA–infected animals in the experimental cerebral malaria (ECM) model inversely correlated with normal behavior and correlated with blood-brain barrier (BBB) permeability. Mice infected with malaria species that do not induce neurological abnormalities or manifest BBB permeability had elevated plasma PA levels similar to ECM plasma at 7 days postinfection; however, they had low PA levels in the brain compared to ECM mice brains at 7 days postinfection.

Conclusions
Our model suggests that malaria-generated PA induces coma in CM and in ECM. The role of BBB permeability and the mechanisms of PA neuromodulation in CM will require additional investigation.
Unequal order T-spline meshes for fracture in poroelastic media
Authors: Hageman Tim , de Borst René 
Published: December 2021

Abstract
Spline-based meshes allow for a higher inter-element continuity. For coupled problems, e.g. poroelasticity, different meshes with different orders of interpolation are normally used for the various fields in order to avoid spurious oscillations. When including discontinuities in these meshes, there exist several options for the discretisation. Herein we will discuss two options which use T-splines, one aiming at a minimum number of degrees of freedom around the crack tip, the other trying to maximise this number. Both meshes retain a higher-order continuity along the fracture, but the mesh which maximises the number of degrees of freedom mesh introduces two additional degrees of freedom around the crack tip to allow for a sharper crack. The two discretisations are used to simulate a pressurised fracture inside a poroelastic material and the results are compared to results obtained using a Non-Uniform Rational B-Spline (NURBS) mesh. A comparison between the two discretisations shows the effect of including additional degrees of freedom close to the crack tip. However, both meshes yield similar results further away from the crack tip. It is shown that both T-spline meshes capture a fully closed discontinuity at the fracture tip, whereas the NURBS mesh retains a small opening due to the discontinuity which exists for the cracked as well as the intact elements. A fully closed fracture aperture results in T-splines with a lower discontinuity pressure compared to NURBS, making T-splines more suitable for simulations in which the fracture propagation is limited by the fluid transport within the fracture.
The weak dependence of velocity dispersion on disc fractions, mass-to-light ratio, and redshift: implications for galaxy and black hole evolution
Authors: Marsden Christopher , Shankar Francesco , Bernardi Mariangela , Sheth Ravi K , Fu Hao , Lapi Andrea 
Published: December 2021

ABSTRACT
Velocity dispersion (σ) is a key driver for galaxy structure and evolution. We here present a comprehensive semi-empirical approach to compute σ via detailed Jeans modelling assuming both a constant and scale-dependent mass-to-light ratio M*/L. We compare with a large sample of local galaxies from MaNGA and find that both models can reproduce the Faber–Jackson (FJ) relation and the weak dependence of σ on bulge-to-total (B/T) ratio (for B/T ≳ 0.25). The dynamical-to-stellar mass ratio within R ≲ Re can be fully accounted for by a gradient in M*/L. We then build velocity dispersion evolutionary tracks σap[M*, z] (within an aperture) along the main progenitor dark matter haloes assigning stellar masses, effective radii, and Sérsic  indices via a variety of abundance matching and empirically motivated relations. We find: (1) clear evidence for downsizing in σap[M*, z] along the progenitor tracks; (2) at fixed stellar mass σ ∝ (1 + z)0.2−0.3 depending on the presence or not of a gradient in M*/L. We extract σap[M*, z] from the TNG50 hydrodynamic simulation and find very similar results to our models with constant M*/L. The increasing dark matter fraction within Re tends to flatten the σap[M*, z] along the progenitors at z ≳ 1 in constant M*/L models, while σap[M*, z] have a steeper evolution in the presence of a stellar gradient. We then show that a combination of mergers and gas accretion is likely responsible for the constant or increasing σap[M*, z] with time. Finally, our σap[M*, z] are consistent with a nearly constant and steep Mbh − σ relation at z ≲ 2, with black hole masses derived from the LX − M* relation.
How D-type H ii region expansion depends on numerical resolution
Authors: Pittard J M , Kupilas M M , Wareing C J 
Published: December 2021

ABSTRACT
We investigate the resolution dependence of H ii regions expanding past their Strömgren spheres. We find that their structure and size, and the radial momentum that they attain at a given time, is in good agreement with analytical expectations if the Strömgren radius is resolved with $dr \le 0.3\, R_{\rm st}$. If this is not satisfied, the radial momentum may be over- or underestimated by factors up to 10 or more. Our work has significance for the amount of radial momentum that a H ii region can impart to the ambient medium in numerical simulations, and thus, on the relative importance of ionizing feedback from massive stars.