bluuebunny/crossref_metadata_2025_split huggingface dataset:
High‐Index Faceted PdPtCu Ultrathin Nanorings Enable Highly Active and Stable Oxygen Reduction Electrocatalysis
Authors: Li Menggang , Tian Fenyang , Lin Tianshu , Tao Lu , Guo Xin , Chao Yuguang , Guo Ziqi , Zhang Qinghua , Gu Lin , Yang Weiwei , Yu Yongsheng , Guo Shaojun 
Published: May 2021

AbstractUltrathin nanosheet catalysts deliver great potential in catalyzing the oxygen reduction reaction (ORR), but encounter the ceiling of the surface atomic utilizations, thus presenting a challenge associated with further boosting catalytic activity. Herein, a kind of PdPtCu ultrathin nanorings with increased numbers of electrocatalytically active sites is reported, with the purpose of breaking the activity ceiling of conventional catalysts. The as‐made PdPtCu nanorings possess abundant high‐index facets at the edge of both the exterior and interior surfaces. An ultrahigh electrochemical active surface area of 92.2 m2 g–1PGM is achieved on this novel catalyst, much higher than that of the commercial Pt/C catalyst. The optimized Pd39Pt33Cu28/C shows a great enhanced ORR activity with a specific activity of 2.39 mA cm–2 and a mass activity of 1.97 A mg–1PGM at 0.9 V (versus RHE), as well as superior durability within 30 000 cycles. Density function theory calculations reveal that the high‐index facets and alloying Cu atoms can optimize the oxygen adsorption energy, explaining the enhanced ORR activity. Overcoming a key technical barrier in sub‐nanometer electrocatalysts, this work successfully introduces the hollow structures into the ultrathin nanosheets, heralding the exciting prospects of high‐performance ORR catalysts in fuel cells.
Model‐based assisted migration of oracle forms applications: The overall process in an industrial setting
Authors: Rodríguez Cristo , Garcés Kelly , Cabot Jordi , Casallas Rubby , Melo Fabián , Escobar Daniel , Salamanca Alejandro 
Published: May 2021

AbstractThe migration of software is an economically important niche since the daily operations of many business still rely on systems based on legacy technologies. Migration to more recent technologies comes with major technical and management challenges mainly related to knowledge‐loss issues on the specific technology but also on the architecture and design of the legacy. This article presents a method that addresses the reverse/forward engineering tasks as well as some management challenges such as the planning of the migration based on a better understanding of the system. The process relies on the use of models and transformations to create high‐level abstraction views of the legacy. A big challenge with the migration of certain legacy applications is that much of the business logic is inside triggers which are written in the PL/SQL language and scattered across the application layers. Therefore, developers need to know what they need to migrate and where it is. The main contribution of our work is that the abstractions allow developers to understand and plan the migration without the need of having a vast knowledge on the initial technology. Furthermore, our views help developers to decide about the structure and business logic they want to have in the target system. In this article, we describe the application of the method to the Oracle Forms case study. Nevertheless, the approach can be generalized to other technologies through new bridges that transform from said technologies to the abstract views. The article ends by reporting lessons learned from our experience.
Big data analytics in single‐cell transcriptomics: Five grand opportunities
Authors: Bhattacharya Namrata , Nelson Colleen C. , Ahuja Gaurav , Sengupta Debarka 
Published: May 2021

AbstractSingle‐cell omics technologies provide biologists with a new dimension for systematically dissecting the underlying complexities within biological systems. These powerful technologies have triggered a wave of rapid development and deployment of new computational tools capable of teasing out critical insights by analysis of large volumes of omics data at single‐cell resolution. Some of the key advancements include identifying molecular signatures imparting cellular identities, their evolutionary relationships, identifying novel and rare cell‐types, and establishing a direct link between cellular genotypes and phenotypes. With the sharp increase in the throughput of single‐cell platforms, the demand for efficient computational algorithms has become prominent. As such, devising novel computational strategies is critical to ensure optimal use of this wealth of molecular data for gaining newer insights into cellular biology. Here we discuss some of the grand opportunities of computational breakthroughs which would accelerate single‐cell research. These are: predicting cellular identity, single‐cell guided in silico drug screening for precision medicine, transfer learning methods to handle sparsity and heterogeneity of expression data, establishing genotype–phenotype relationships at single‐cell resolution, and developing computational platforms for handling big data.This article is categorized under:
Algorithmic Development > Biological Data Mining
Fundamental Concepts of Data and Knowledge > Big Data Mining
Technologies > Machine Learning
Modeling of thermoelastic diffusion plate under two temperature, fractional‐order, and temperature‐dependent material properties
Authors: Bajpai Ankit , Sharma P. K. , Kumar Rajneesh 
Published: May 2021

AbstractA mathematical model is formulated to study the thermoelastic diffusion in the plate using two temperature fractional order theory in materials having temperature‐dependent elastic properties. Governing equations for the considered two‐dimensional problem are deduced. The plate is considered as unstrained and unstressed at uniform temperature initially. Governing equations are non‐dimensionalized and simplified by making use of potential functions. A combination of Laplace and Fourier transform is used to reduce the problem to ordinary differential equations. The arbitrary constants in solution are obtained by considering the loading environment on surfaces. The physical quantities like stresses, temperature field, mass concentration and chemical potential are determined analytically in the closed‐form. A numerical transform inversion technique is used to obtain the resulting quantities for the original region and displayed in the form of graphs to present the different physical effects.
CT-gesteuerte Schmerztherapie des spezifischen Rückenschmerzes
Authors: Stueckle Christoph. A. , Talarczyk Sarah , Stueckle Kerstin F. , Haage Patrick 
Published: May 2021

Zusammenfassung
Hintergrund
Rückenschmerz ist häufig und führt den Patienten sowohl zur Diagnostik als auch in bestimmten Fällen für eine Therapie zum Radiologen.

Fragestellung
Die vorliegende Untersuchung vergleicht die schmerzreduzierende Wirkung der mikroinvasiven Computertomographie(CT)-gesteuerten Schmerztherapie bei diskogenem und spondylarthrotisch bedingtem spezifischem Rückenschmerz.

Material und Methode
Über einen Zeitraum von 3,3 Jahren wurden 239 Patienten in die Untersuchung eingeschlossen, bei denen 686 CT-gesteuerte periradikuläre Therapien (PRT) und 264 CT-gesteuerte Facettengelenktherapien (FAC) durchgeführt und beurteilt wurden. Bei allen Patienten wurde vor der Intervention, im Verlauf und am Ende der Schmerzscore mittels visueller analoger Schmerzskala (VAS) bestimmt. Abschließend wurde der Behandlungserfolg in Abhängigkeit von der durchgeführten Behandlungsart und den morphologisch vorliegenden Veränderungen korreliert.

Ergebnisse
In beiden Gruppen zeigte sich unter der Behandlung eine gute Beschwerdebesserung (74 % bei PRT-Patienten und 60 % bei FAC-Patienten). Die Patienten, bei denen eine PRT durchgeführt wurde, zeigten durchschnittlich eine Verbesserung des Schmerzscores von 3,1, bei Patienten mit durchgeführter FAC von 2,1. Die Wirksamkeit der FAC zeigte eine Abhängigkeit der Wirksamkeit vom Grad der vorhandenen degenerativen Veränderungen. Je ausgeprägter die nachgewiesene Degeneration im behandelten Segment war, desto mehr Interventionen waren für ein gutes Therapieansprechen notwendig.

Schlussfolgerung
Die CT-gesteuerte PRT und FAC führen beide zu einer guten Reduktion der Beschwerdesymptomatik. Im Vergleich erzielte die PRT eine signifikant höhere Schmerzreduktion als die FAC.
The impact of epicardial adipose tissue in patients with acute myocardial infarction
Authors: Fisser Christoph , Colling Stefan , Debl Kurt , Hetzenecker Andrea , Sterz Ulrich , Hamer Okka W. , Fellner Claudia , Maier Lars S. , Buchner Stefan , Arzt Michael 
Published: May 2021

Abstract
Aims
Epicardial adipose tissue (EAT) has been linked to impaired reperfusion success after percutaneous coronary intervention (PCI). Whether EAT predicts myocardial damage in the early phase after acute myocardial infarction (MI) is unclear. Therefore, we investigated whether EAT in patients with acute MI is associated with more microvascular obstruction (MVO), greater ST-deviation, larger infarct size and reduced myocardial salvage index (MSI).

Methods and results
This retrospective analysis of a prospective observational study including patients with acute MI (n = 54) undergoing PCI and 12 healthy matched controls. EAT, infarct size and MSI were analyzed with cardiac magnetic resonance imaging, conducted 3–5 days and 12 weeks after MI. Patients with acute MI showed higher EAT volume than healthy controls (46 [25.;75. percentile: 37;59] vs. 24 [15;29] ml, p < 0.001). The high EAT group (above median) showed significantly more MVO (2.22 [0.00;5.38] vs. 0.0 [0.00;2.18] %, p = 0.004), greater ST-deviation (0.38 [0.22;0.55] vs. 0.15 [0.03;0.20] mV×10−1, p = 0.008), larger infarct size at 12 weeks (23 [17;29] vs. 10 [4;16] %, p < 0.001) and lower MSI (40 [37;54] vs. 66 [49;88] %, p < 0.001) after PCI than the low EAT group. After accounting for demographic characteristics, body-mass index, heart volume, infarct location, TIMI-flow grade as well as apnea–hypopnea index, EAT was associated with infarct size at 12 weeks (B = 0.38 [0.11;0.64], p = 0.006), but not with MSI.

Conclusions
Patients with acute MI showed higher volume of EAT than healthy individuals. High EAT was linked to more MVO and greater ST-deviation. EAT was associated with infarct size, but not with MSI.

Graphic abstract
Othello syndrome in Parkinson’s disease: a systematic review and report of a case series
Authors: De Michele Giovanna , Palmieri Gianluigi Rosario , Pane Chiara , Dello Iacovo Carmen Diletta Paola , Perillo Sandra , Saccà Francesco , De Michele Giuseppe , De Rosa Anna 
Published: May 2021

Abstract
Introduction
Psychosis in Parkinson’s disease (PD) is common and consists of hallucinations, illusions, and delusions. Among the latter, delusional jealousy, also named Othello syndrome (OS), might impair the quality of life of both patients and their partners. We aimed to perform a systematic review and report a series of PD patients presenting with OS.

Methods
A systematic review research was performed in PubMed database, excluding non-English articles, single case reports, reviews and neuropathology articles, comments, and articles concerning OS associated with deep brain stimulation (DBS) and levodopa-carbidopa intestinal gel infusion. We also described eleven PD patients (9 M and 2 F) with OS, identified in a cohort of consecutive 153 patients, comparing them with eleven matched no OS (nOS) PD subjects taken from the same cohort.

Results
We included eight articles (four case series and four cross-sectional studies). OS resulted more common among males than females. We did not find higher levodopa dose and levodopa equivalent dose for dopamine agonists and for all anti-parkinsonian drugs in our OS group. In our case series, OS patients showed visual hallucinations (p=0.001) and a trend to have depression (p=0.080) more frequently than nOS ones.

Conclusions
OS is not a rare disorder in PD, probably due not only to abnormal dopaminergic stimulation but also to serotonergic dysfunction in biologically predisposed subjects. Visual hallucinations and other concomitant psychiatric diseases, in particular depression, might represent a risk factor for the OS development.
Tuning magnetic and magnetocaloric properties of Pr0.6Sr0.4MnO3 through size modifications
Authors: Souza Anita D , Vagadia Megha , Daivajna Mamatha 
Published: May 2021

AbstractParticle size as an effective tool for controlling the magnetic and magnetocaloric properties of Pr0.6Sr0.4MnO3 samples has been studied. In the present work, a direct influence of particle size on the magnitude of magnetization and magnetic transition temperature, TC, can be seen. The TC drops from 309 to 242 K, while the saturation magnetization (MS) decreases from 3.6 to 0.5 μB/f.u. as the particle changes from 120 to 9 nm. Concurrently, coercivity (HC) exhibits a drastic rise emphasizing the enhanced surface disorder in the nanoparticles. Another interesting observation is in the magnetic entropy change, ΔS, which though decreases in magnitude from 5.51 to 3.90 J/Kg-K as particle size decreases from 120 to 30 nm, but the temperature range of ΔS (i.e., relative cooling power, RCP) increases from 184.33 to 228.85 J/Kg. Such interplay between magnitude and wider temperature range of ΔS, which can be fine-tuned by particle size, provides an interesting tool for using surface spin disorder, as a control mechanism in modifying physical properties.
Dynamic analysis of a belt transmission with the GMS friction model
Authors: Kubas Krzysztof , Harlecki Andrzej 
Published: May 2021

AbstractThe paper presents a certain method of analysing the dynamics of a belt transmission. A flat transmission model developed by us was presented. For the analysis, it assumed the transmission 5PK belt. A discrete belt model, being a system of rigid beams interconnected with flexible and shock-absorbing elements, was used. To account for the mutual influence between the belt and pulleys, the Kelvin–Voigt contact model was used. The GMS friction model was also implemented, which allows all basic known friction phenomena to be taken into account. For this purpose, the vector of generalized coordinates was expanded with additional sub-systems of coordinates modelling the flexible belt-pulley connection. Moreover, two additional cases of a sudden transmission start were presented: with values of driving and resistance torque not causing a significant slip in the transmission as well as values of torque that cause slip.
Interpretative expressivism: A theory of normative belief
Authors: Brown James L. D. 
Published: May 2021

AbstractMetaethical expressivism is typically characterised as the view that normative statements express desire-like attitudes instead of beliefs. However, in this paper I argue that expressivists should claim that normative statements express beliefs in normative propositions, and not merely in some deflationary sense but in a theoretically robust sense explicated by a theory of propositional attitudes. I first argue that this can be achieved by combining an interpretationist understanding of belief with a nonfactualist view of normative belief content. This results in a view I call ‘interpretative expressivism’. I then argue that traditional arguments employed by expressivists that normative statements express noncognitive attitudes can just as well support the claim that normative statements express nonfactual or nonrepresentational beliefs. Finally, I argue that this view has a number of advantages to versions of expressivism that deny that normative statements express non-deflationary normative beliefs.
A round of dancing and then one more: embedding intuition in the ballet of entrepreneurial decision making
Authors: Manesh Mohammad Fakhar , Flamini Giulia , Petrolo Damiano , Palumbo Rocco 
Published: May 2021

AbstractThe dance metaphor allows us to figuratively depict entrepreneurial decision making processes. Being conventionally conceived of as a sequence of purposeful behaviors rooted in a rational cognition process, entrepreneurial decision making can be featured as a ‘ballet’. This interpretation puts in the background the improvisational nature of decision making, which revokes ‘lindy hop’ as a dance style. The article intends to illuminate the role of intuition, highlighting its overlap with rationality in the entrepreneurial decision making dance. For this purpose, a bibliometric analysis followed by an interpretive literature review advances a comprehensive report of 66 peer-reviewed journal articles published from 1995 to 2019, constructing evidence on the nature of entrepreneurial decision making and on the interplay between intuition and rationality. Literature is categorized in five clusters, which are reciprocally intertwined. Firstly, intuition is unconsciously used as a strategy to deal with the uncertainty that inherently affects entrepreneurial ventures. Secondly, intuition is rooted in the entrepreneurs’ impulsivity, that echoes the role of emotions in decision making. Thirdly, the merge of rationality and intuition improves the entrepreneurs’ ability to keep up with the erratic rhythm of the decision making dance. Fourthly, the mix of intuition and rationality serves as a catalyst of entrepreneurs’ ability to thrive in complex and unpredictable environments. Fifthly, intuition generates drawbacks on entrepreneurs’ meta-cognitive knowledge, which should be carefully recognized. Embracing the dance metaphor, intuition turns out to be crucial to make entrepreneurs able to fill in the gap between rationality and uncertainty.
Beta Titanium Alloys Processed By Laser Powder Bed Fusion: A Review
Authors: Colombo-Pulgarín J. C. , Biffi C. A. , Vedani M. , Celentano D. , Sánchez-Egea A. , Boccardo A. D. , Ponthot J. -P. 
Published: May 2021

AbstractIn βTi-alloys, some advances and developments have been reached toward optimizing their mechanical performance and their processability. However, the applications of these alloys via laser powder bed fusion (LPBF) are still under investigation. In this work, the processing of βTi-alloys via LPBF and their properties is reviewed with a focus on six selected metallurgical systems which are expected to be top performance materials in applications in the aeronautical and biomedical contexts. These six systems promise a better mechanical and functional performance considering different in-service environments for medical implants and structural applications. After literature analysis, the applicability of βTi-alloys to be processed via LPBF is then discussed considering the relevant fields of applications.
On processes of coloniality and decoloniality of knowledge: notions for analysing the international history of mathematics teaching
Authors: Schubring Gert 
Published: May 2021

AbstractThe aspiration of this paper is to develop a novel approach towards investigating the socio-political history of mathematics teaching in educational systems. Traditionally, historical studies are confined to just one country, the author’s country. Broader approaches address international developments by confronting and comparing global and local aspects—revealing general patterns and more specific ‘local’ structures and characteristics. Yet, already in antiquity and medieval times, the specific characteristic of mathematics teaching, namely to operate at the crossroads of general education and vocational training, proved to be intimately tied to the functioning of the particular political system. In pre-modern times, however, a truly international pattern emerged for the first time: European powers conquered, occupied and colonised overseas regions. Given that educational systems were emerging at the same time within these states, they often transmitted elements of these structures to their colonies. This phenomenon included mathematics, and the history of its teaching is analysed here as a part of coloniality. It is shown that this was not a uniform process, and the differences between the various colonial powers are discussed. The involvement of mathematics in the process of decolonisation is addressed, as well as its role in the tension between continued coloniality and movements of decoloniality. Finally, the general framework provided for studying socio-political processes connected with establishing mathematics teaching within public educational systems is applied, in order to analyse recent coloniality practices effected by international achievement studies.
Manual on the proper use of sodium astatide ([211At]NaAt) injections in clinical trials for targeted alpha therapy (1st edition)
Authors: Watabe Tadashi , Hosono Makoto , Kinuya Seigo , Yamada Takahiro , Yanagida Sachiko , Namba Masao , Nakamura Yoshihide 
Published: May 2021

AbstractWe present the guideline for use of [211At] sodium astatide (NaAt) for targeted alpha therapy in clinical trials on the basis of radiation safety issues in Japan. This guideline was prepared by a study supported by the Ministry of Health, Labour, and Welfare, and approved by the Japanese Society of Nuclear Medicine on 8th Feb, 2021. The study showed that patients receiving [211At]NaAt do not need to be admitted to a radiotherapy room and outpatient treatment is possible. The radiation exposure from the patient is within the safety standards of the ICRP and IAEA recommendations for the general public and caregivers. Precautions for patients and their families, safety management associated with the use of [211At]NaAt, education and training, and disposal of medical radioactive contaminants are also included in this guideline. Treatment using [211At]NaAt in Japan should be carried out according to this guideline. Although this guideline is applied in Japan, the issues for radiation protection and evaluation methodology shown here are considered internationally useful as well.
Does Tenure Security Reduce Disaster Risk? A Comparative Study of the Nairobi Settlements of Kibera and Kawangware
Authors: McDermott Rónán , Gibbons Pat , Ochieng Dalmas , Olungah Charles Owuor , Mpanje Desire 
Published: May 2021

AbstractWhile scholarship suggests that improving tenure security and housing significantly reduces disaster risk at the household level within urban settings, this assertion has not been adequately tested. Tenure security can be conceived as being composed of three interrelated and overlapping forms: tenure security as determined by legal systems; de facto tenure security; and tenure security as perceived by residents. This article traces the relationship between tenure security, the quality of housing, and disaster risk on the basis of a mixed methods comparative case study of the settlements of Kawangware and Kibera in Nairobi. Although the findings suggest that owner-occupancy is associated with the structural integrity of dwellings to a greater extent than tenantship, no association was found between the length of occupancy by households and the structural integrity of the dwelling. Moreover, tenantship is not found to be closely associated with fires and flooding affecting the dwelling as extant scholarship would suggest. Formal ownership is linked with greater investment and upgrading of property with significant implications for disaster risk. Our findings highlight the complex relationship between tenure security and disaster risk in urban informal settlements and provide impetus for further investigation.