bluuebunny/crossref_metadata_2025_split huggingface dataset:
ЦЕРКВА В УМОВАХ ГОЛОДОМОРУ 1932–1933 РР.: ІСТОРІОГРАФІЧНИЙ ДИСКУРС
Authors: Ігнатуша О. М. , Грузова Т. С. 
Published: December 2021

У статті охарактеризовано здобутки сучасної української історичної науки у визначенні місця й ролі церкви в умовах Голодомору 1932–1933 рр., становища та діяльності церковних організацій, релігійних спільнот, духовенства, вірян. Показано коло авторів, тематику та географію досліджень. Розкрито основні напрями й динаміку вивчення теми. Простежено залежність її розробки від громадсько-політичних впливів. Визначено перспективи подальших досліджень.
Ключові слова: церква, радянська держава, Голодомор, геноцид, історіографія.
Новітнє державотворення Словацької Республіки: історичні уроки режиму В. Мечяра (1993–1998 рр.)
Authors: Гулай В. В. , Максимець В. Є. 
Published: December 2021

Аналізуються історичні передумови, інституційно-процедурні особливості та наслідки становлення політичної системи Словацької Республіки в 1993–1998 рр. Основну увагу зосереджено на причинах виникнення, характері та причинах поразки гібридного політичного режиму прем’єр-міністра Словаччини В. Мечяра. Окремо акцентується на історичних уроках реалізації політичного курсу В. Мечяра, де декларації просування європейського та євроатлатичного стратегічного вибору супроводжувалися формуванням режиму з обмеженням реальних демократичних прав і свобод громадян.
Ключові слова: Словацька Республіка, державотворення, політичний режим, режим В. Мечяра.
T Regulatory Cells in the Visceral Adipose Tissues
Authors: Fooks Allen N. , D'Cruz Louise M. 
Published: December 2021

Abstract
CD4+ Foxp3+ T regulatory cells (Tregs) residing in the visceral adipose tissues (VAT) have profound effects on local and systemic metabolism. Although many of the molecular characteristics of VAT resident Tregs have been identified, how these cells promote metabolic homeostasis is still unclear. Several new publications help to illuminate the molecular mechanisms that underpin VAT resident Treg function and will be discussed here.
ELECTROCATALYTIC COBALT-VANADIUM COATINGS FOR THE HYDROGEN EVOLUTION REACTION
Authors: Sakhnenko Mykola , Zhelavska Yulia , Zyubanova Svitlana , Proskurina Valeriia 
Published: December 2021

The study of existing energy-saving materials and obtaining the new ones for reducing the cost of the hydrogen production, is relevant for modern hydrogen energy industry. Such properties can be predicted for materials containing vanadium, molybdenum, tungsten and exhibiting catalytic activity for the hydrogen evolution reaction Aforementioned metals can be co-deposited from aqueous solutions with iron subgroup metal-catalysts through the formation of cluster intermetallic compounds with Me-V bond adsorbed on the cathode surface. The induced co-deposition of cobalt with vanadium from the complex citrate electrolyte was investigated in the current work. As a result of the research, it was found that the uniform microcrystalline light-gray high-quality cobalt-vanadium alloy coating is possible to precipitate from a citrate electrolyte with content of 20 g/dm3 vanadium (in terms of metal) as a citrate complex The process was carried out at a current density of 5–10 A/dm2, at a temperature of 30–40°С, pH = 2,8–3,2. The content of vanadium in the coating is 0,37–0,53 % by weight. The maximum vanadium content in the coating is observed at current densities 8–9 А/dm2. The catalytic activity study of the coating that was obtained using cobalt-vanadium alloy in the reaction of hydrogen reduction at the cathode was performed in solution of 2,5М NaOH + 0,02 M NaCl. By increasing the vanadium content in the coating from 0,37 to 0,53% the hydrogen evolution overvoltage is reduced by 0,5 V. It was found that the overvoltage of the hydrogen ion evolution reaction on cathodes from steel 20 with cobalt-vanadium coating is 0.08–0,1 V lower, and the exchange current is higher than on electrodes made of steel 20, which are used in industrial water-alkali electrolysis. This indicates the electrocatalytic activity of the investigated materials for the hydrogen evolution reaction. Electrodes with coating, obtained by cobalt-vanadium alloy can be recommended as a cathode material for the hydrogen electrochemical production. Hydrogen evolution overvoltage reduction also decrease the energy consumption for this process by 15–20 %.
MODERN TECHNOLOGIES FOR THE MANUFACTURE OF GLASS-CERAMIC DENTAL PROSTHESES
Authors: Savvova Oksana , Fesenko Oleksii , Voronov Hennadii , Bairamov Emin Salekh Ohly 
Published: December 2021

The relevance of the problem of improving the quality of life and protecting human health in the context of the successful development of the modern society was presented. A literary review of well-known modern technologies for the design and manufacture of dental prostheses was carried out, as well as the leading domestic and foreign companies that were engaged in this were given. The history of the development of materials for obtaining clinical restorations (crowns, inlays, onlays, etc.) was considered and the main directions of the development of innovative ceramic materials for dental prosthetics were outlined. Based on the analysis of the properties of various types of materials for dental prosthetics, the prospects of using glass-ceramic materials in the development of dental prostheses have been substantiated. The chemical compositions of lithium silicate glasses for the synthesis of the glass matrix have been developed and the technological parameters for the production of glass-ceramic dental prostheses have been selected (Тgl. melting = 1350–1400 °С, Тheat treatment = 600–650 °С). Preliminary heat treatment before the formation of products ensures the formation of the required number of the nucleus of crystalline phase and the prerequisites for creating a volume crystallized structure under conditions of short-term heat treatment. The glass-ceramic prosthesis with a formed interpenetrating sitallized structure was obtained by the method of hot pressing with a short exposure (18-20 min). It was found that the obtained glass-ceramic material containing lithium disilicate as a crystalline phase in an amount of 40-60 vol. %, had high values of bending strength (σ = 400 MPa) and fracture toughness. The indicated mechanical properties of the developed materials, along with the approximate values of their modulus of elasticity to natural teeth, will significantly extend the service life of products under conditions of significant alternating loads that arise during the chewing cycle. A comparative assessment of the competitiveness of the developed dental prostheses based on lithium disilicate with world analogues was carried out, in particular the products of Ivoclar Vivadent and Vita Zahnfabrik, in terms of the main operational parameters. The positive effect of the introduction of domestic developed glass-ceramic dental prostheses to reduce import dependence has been determined.
DEVELOPMENT OF LOW-MELTING GLASSCERAMIC BONDS FOR HIGH RESOURCE DIAMOND-ABRASIVE TOOLS
Authors: Fedorenko Olena , Yashchenko Larysa , Fedorenko Dmytro , Fedorovych Volodymyr , Koniev Oleksandr 
Published: December 2021

Research is aimed at creating high-resource diamond-abrasive tools with a large-pore structure of the working layer, the use of which reduces the occurrence of grinding defects when processing materials sensitive to overheating. The formation of an open structure of the working layer ensures effective chip removal, which excludes a decrease in the сutting ability of the tool due to contamination with grinding sludge and creates favorable conditions for intensifying the processing of materials when using high-speed cutting modes. As part of the research, low-melting glass-ceramic binders for diamond-abrasive tools have been developed, which make it possible to increase the tool service life due to the prevention of diamond grains premature destruction and the creation of a large-pore open structure of the working layer. Using a set of calculated data about the main characteristics of glass compositions by factor planning means, the dependences «composition - properties» were determined and the area of optimal compositions of glass-ceramic bonds was established, which ensure sintering of a diamond-containing composite at a temperature of 550–650 °C. The efficiency of the use of alumino-silicate microspheres of technogenic origin as a structure-forming filler providing the formation of a large-pore structure is shown. The features of the chemical and phase composition of the technogenic spheres recovered from the fly ash of the Krivoy Rog TPP have been determined. It has been established that when the diamond-bearing layer of the tool is sintered in the shell of the ash spheres, crystalline new formations with high hardness (hercynite, mullite, maghemite, spinel) are formed. Using ash spheres and developed low-melting binders, which include up to 30 mass. % of glass waste, the laboratory samples of diamond-containing composites with open porosity of 45-50% were made. Studies of their microstructure and morphological features made it possible to determine the pore size (130-200 μm) and establish that during grinding, partial destruction of ash spheres occurs with the formation of additional cutting elements, which increases the tool cutting ability. The research results indicate the advisability of using the proposed approach for selection of the diamond-ceramic composite components and the modes of heat treatment of the diamond-bearing layer when creating a tool. This approach will significantly expand the possibilities of manufacturing large-pore diamond-abrasive tools with a high service life at minimal material costs and will improve the processing of parts made of difficult-to-machine materials.
Neutralization of solvent vapors of brand 650 by the adsorption‑catalytic method
Authors: Panasyugin A. S. , Pavlovskiy N. D. , Masherova N. P. , Tsyganov A. R. , Kurilo I. I. 
Published: December 2021

The purpose of this work is to study the process of neutralization of vapors of a mixed solvent of the brand 650 by the adsorption‑catalytic method. The essence of the method consists in the concentration of solvent components on the sorbent, thermal desorption followed by periodic flameless catalytic oxidation of accumulated organic substances to carbon dioxide and water. Synthetic zeolite of the NaX brand was used as a sorbent, and a porous material based on foam ceramics of the Al2O3/SiO2 composition with a highly developed modified surface with an active catalytic phase was used as a catalyst. The mixed solvent contains, xylenes, ethylcellosol, n‑butanol. It is shown that the value of the sorption volume of zeolite for each class of the considered compounds is influenced by certain factors: the length and structure of the carbon skeleton, the position of the hydroxyl group (for alcohols and esters), the number of methyl groups in the composition of molecules (for the production of benzene). The conversion rate of the mixed solvent components was 65.4–90.1 %.
Влияние геометрии и граничных условий в области сцепления материалов на рассеяние ультразвуковых волн. Ч. 2. Особенности экспериментального моделирования
Authors: Baev A. R. , Levkovitch N. V. , Asadchaya M. V. , Mayorov A. L. , Razmyslovich G. I. , Burnos A. Y. 
Published: December 2021

Повышение эффективности акустической диагностики объектов со слоистой структурой применительно к выявлению слабо выявляемых дефектов сцепления материалов является важной производственной задачей. Цель работы состояла в экспериментальном моделировании рассеяния ультразвуковых волн на образцах предложенных конструкций имитаторов дефектов с дискретно и плавно изменяющимися граничными условиями, коррелирующими с фазовой характеристикой продольных волн в процессе их взаимодействия с дефектной границей контактирующих материалов.Проведён краткий анализ некоторых методов и средств экспериментального моделирования рассеяния объёмных и поверхностных волн на границах контактирующих материалов применительно к совершенствованию метода обнаружения слабо выявляемых дефектов сцепления (адгезии) материалов. Для этого разработана и изготовлена иммерсионная установка, работающая в теневом режиме и позволяющая моделировать пространственные поля рассеянных продольных волн на неоднородной или дефектной границе сцепления материалов. Как предполагается, взаимодействующие с такой границей волны приобретают дискретный или плавно изменяющийся фазовый сдвиг, существенно сказывающийся на формировании поля рассеяния в его периферийной зоне. Увеличение же этого сдвига позволяет значительно повысить чувствительность обнаружения слабо выявляемых дефектов.Проведено экспериментальное исследование рассеяния продольных волн на разработанной установке и имитаторах дефектов, моделирующих дискретно и плавно изменяющиеся граничные условия, которые согласуются с изменением фазового сдвига рассеиваемых волн. Получены амплитудные зависимости поля рассеяния в зависимости от угла их приема в диапазоне от 20º до + 20º и смещения центра моделируемого дефекта относительно оси зондирующего акустического луча. Как установлено, наблюдается качественное соответствие между расчётными и опытными данными.Настоящие исследования представляют интерес для решения ряда задач по повышению эффективности ультразвукового контроля современных объектов со слоистой структурой и будут способствовать расширению возможностей использования предложенного метода.
Application of Solutions of Uncorrected Tasksʼ Theory for Managing of Production Processesʼ Robustness
Authors: Serenkov P. S. , Romanchak V. M. , Pesliak I. E. 
Published: December 2021

The industrial revolution of “Industry 4.0” is currently underway at an active pace. Individualization of provided products and services, transition to single production, the issues of acceptability of production processes at the stage of development and design have became urgent. The aim of this work was to develop a strategy for a fundamental solution to the task of guaranteed acceptability of production processes as an integral quality characteristic.We have proposed a systematic approach to strategy development. The basis of the approach was the theory of incorrect tasks solving. We adapted signs of correctness of mathematical tasks by J. Adamar to the tasks of ensuring acceptability of production processes (technological and measurement). They were used in the part of identification of properties of display of incorrectness and ways of incorrectnessʼ management.We have proposed to consider the property of robustness as a generalized index of acceptability for production processes (technological and measurement). We substantiate the equivalence of the concepts of incorrectness of tasks according to J. Adamar and losses of robustness of production processes. We conclude that the developed approaches and techniques of the theory of incorrect tasks can be put in a basis of the system approach to an estimation and management of losses of robustness of production processes. We have proposed a classification of situations of robustness losses in production processes in accordance with the classification of the signs of incorrect tasks by J. Adamar.We have developed a two-step algorithm for ensuring the robustness of production processes at the stage of their development. It included identification of the sources of robustness losses and management of input factors that cause significant variation in process output. This has given a practical implementation of a strategy to guarantee the acceptability of production processes. We have systematized the sources of potential losses in the robustness of production processes and proposed a two-stage mechanism for managing them. We have justified rational methods of ensuring the robustness of production processes for each stage based on, the practice of uncorrected tasks solving. We have proposed a method for ensuring high efficiency of robustness loss management in certain situations. The principles of G. Taguchiʼs robust redesigning of production processes formed the basis of our method.
Increasing of the Accuracy of Signalsʼ Time Parameters Measuring Using Double Pulse Trains
Authors: Isaev A. V. , Suchodolov U. V. , Sushko A. S. , Sheinikau A. A. 
Published: December 2021

In modern diagnostics, much attention is paid to measuring of time parameters, as well as their change over time. The purpose of this work is to develop a method for measuring of time intervals which made it possible to increase the measurement accuracy by reducing errors associated with the instability of main parameters of the pulse signal.In the most of approaches used, the error associated with the instability of main parameters of signals under study is not enough taken into account. As an alternative, a spectral method is proposed in which the measurement of time intervals, as well as their changes, is performed based on the analysis of pulse sequences formed on the basis of characteristic points of the measured signal. For this a double pulse sequence was considered, an equation for the amplitudes of its spectral components was obtained, and in accordance with this it was determined that the delay time between double pulses is the most informative parameter.Using the Mathcad software, an analysis of the sensitivity regions was carried out for the change in the main parameters of the pulse sequence, namely the repetition rate, as the main destabilizing factor.As a result of the implementation of the developed technique, a structural diagram of the measuring system is proposed and an analysis of the measurement error associated with the instability of the main parameters of the pulse sequence is carried out. This error is estimated to be less than 0.01 %.The considered method makes it possible to increase the accuracy of measuring time intervals due to the almost complete elimination of the influence of the instability of the reference frequency and the amplitude of the generated pulses which is unattainable with modern hardware, including digital signal processing.
Automated Approaches Determine Solids Content in Drilling and Completions Fluids
Authors: Carpenter Chris 
Published: December 2021

This article, written by JPT Technology Editor Chris Carpenter, contains highlights of paper SPE 201368, “Automated Solids-Content Determination in Drilling and Completions Fluids,” by Sercan Gul, SPE, Ali Karimi Vajargah, and Eric van Oort, SPE, The University of Texas at Austin, et al., prepared for the 2020 SPE Annual Technical Conference and Exhibition, originally scheduled to be held in Denver, 5–7 October. The paper has not been peer reviewed.
Monitoring of low- and high-gravity-solids (LGS and HGS) content and maintaining these at ideal levels is essential for optimal drilling fluid performance, efficient hole cleaning and equivalent-circulating-density management, and prevention of failures of surface and downhole equipment during drilling. LGS and HGS monitoring in the field is currently accomplished using the API retort-kit measurement, which has certain drawbacks and is difficult to automate. In the complete paper, two new approaches are investigated to automate the LGS and HGS content measurements of drilling fluids, which potentially can replace the retort test.

Introduction
The conventional way to characterize LGS and HGS in the field is by using a retort-kit measurement specified in API Recommended Practices 13B-1 and 13B-2. The longevity of these tests is testament to the effectiveness of the API standards and the tests themselves in providing useful and practical field guidance.
Despite their evident success, however, various downsides exist in current solids-content-testing methods. Retort-kit measurements present the following issues:
- Difficulty in obtaining accurate and repeatable test results
- Safety issues associated with laboratory testing at elevated temperatures (over 930°F)
- Interpretive bias issues associated with test results, including the potential for deliberate manipulation of these results
- Difficulty in automating the retort test for improved efficiency and safety
The authors’ opinion is that automating antiquated API test protocols is not a useful practice. They write that a clean-slate approach would be better, in which a determination is made whether solids-content information can be provided in a novel and meaningful way using methods that deviate from standard API recommended practices. In the complete paper, the authors investigate a machine-learning (ML) and data-analytics method for this purpose in combination with a novel inline X-ray fluorescence (XRF) measurement method.
Technology Focus: EOR Operations (November 2021)
Authors: Fassihi Reza 
Published: December 2021

As the discovery rate of new hydrocarbon resources decreases, the need for more-efficient enhanced-oil-recovery (EOR) processes increases. Unlike in the past, however, when the efficiency was defined in terms of maximizing the recovery factor (RF), the new interpretation of efficiency is based on optimizing the balance between RF and the reduction of carbon footprint. This is done through an integrated approach in which both surface and subsurface elements of the oil-production systems are used to determine energy efficiency and carbon footprint of a unit volume of oil produced by EOR methods.
When choosing traditional EOR methods, new innovations may be needed to arrive at new injectant composition to reduce emissions or make the process more efficient. Adding chemicals to the injectant gas to improve the mobility ratio and increase the sweep efficiency is desirable. One example is the use of hydrogels. These are hydrophilic structures that swell when hydrated. Hydrogels are of interest in EOR because of their ability to respond to stimuli such as pH, temperature, light, and ionic strength.
EOR methods that involve use of fresh water are also switching to alternative methods that reduce or remove its usage as part of water sustainability. The produced water could be treated properly to make it suitable for injection. Alternatively, polymers that are effective under high salinity or temperature could be used to deal with injecting saline water. For unconventional reservoirs, waterless fracturing techniques are progressing.
Paper SPE 201609 discusses the application of a reversible hydrogel that can be added to the injected carbon dioxide (CO2) stream in order to make it a more-efficient injectant for EOR and,
hence, create more opportunity for CO2 storage. Paper SPE 202809 deals with utility of new polymers that are suitable for injection into carbonate reservoirs under high-temperature and ultrahigh-salinity conditions. Finally, paper OTC 30437 discusses ways of mitigating safety risks associated with CO2 waterless fracturing in unconventional reservoirs as part of water sustainability as well as prevention of environmental pollution.
Recommended additional reading at OnePetro: www.onepetro.org.
SPE 200357 - Fundamental Investigation of Auto-Emulsification of Water in Crude Oil: An Interfacial Phenomenon and Its Pertinence for Low-Salinity EOR by Duboué Jennifer, TotalEnergies, et al.
SPE 205118 - Experimental Design and Evaluation of Surfactant Polymer for a Heavy-Oil Field in South of Sultanate of Oman by Ali Reham Al-Jabri, Petroleum Development of Oman, et al.
SPE 200256 - Chemical Enhanced Oil Recovery and the Dilemma of More and Cleaner Energy by Rouhi Farajzadeh, Delft University of Technology, et al.