bluuebunny/crossref_metadata_2025_split huggingface dataset:
Single‐Atom Catalysts: A Sustainable Pathway for the Advanced Catalytic Applications
Authors: Singh Baljeet , Sharma Vikas , Gaikwad Rahul P. , Fornasiero Paolo , Zbořil Radek , Gawande Manoj B. 
Published: February 2021

AbstractA heterogeneous catalyst is a backbone of modern sustainable green industries; and understanding the relationship between its structure and properties is the key for its advancement. Recently, many upscaling synthesis strategies for the development of a variety of respectable control atomically precise heterogeneous catalysts are reported and explored for various important applications in catalysis for energy and environmental remediation. Precise atomic‐scale control of catalysts has allowed to significantly increase activity, selectivity, and in some cases stability. This approach has proved to be relevant in various energy and environmental related technologies such as fuel cell, chemical reactors for organic synthesis, and environmental remediation. Therefore, this review aims to critically analyze the recent progress on single‐atom catalysts (SACs) application in oxygen reduction reaction, oxygen evolution reaction, hydrogen evolution reaction, and chemical and/or electrochemical organic transformations. Finally, opportunities that may open up in the future are summarized, along with suggesting new applications for possible exploitation of SACs.
Externality and COVID‐19
Authors: Leeson Peter T. , Rouanet Louis 
Published: February 2021

AbstractNegative infectious disease externalities are less prevalent in the absence of government intervention and less costly to society than is often supposed. That is so for three reasons. (1) Unlike externality‐creating behaviors in many classical externality contexts, such behaviors are often self‐limiting in the context of infectious disease. (2) In market economies, behaviors that may create infectious disease externalities typically occur at sites that are owned privately and visited voluntarily. Owners have powerful incentives to regulate such behaviors at their sites, and visitors face residual infection risk contractually. (3) The social cost of infectious disease externalities is limited by the cheapest method of avoiding externalized infection risk. That cost is modest compared to the one usually imagined: the value of life (or health) lost to the disease if government does not intervene. We elaborate these arguments in the context of the COVID‐19 pandemic.
Accurate and rapid detection of Fasciola hepatica copro‐DNA in sheep using loop‐mediated isothermal amplification (LAMP) technique
Authors: Amiri Siamak , Shemshadi Bahar , Shirali Saloomeh , Kheirandish Farnaz , Fallahi Shirzad 
Published: February 2021

AbstractFascioliasis is a parasitic infection caused by Fasciola spp. in humans and animals. Despite significant advances in vaccination and new therapeutic agents, little attention has been paid to validate methods for the diagnosis of fascioliasis in animals. This study aimed to compare the loop‐mediated isothermal amplification (LAMP) technique with PCR assay for the diagnosis of F. hepatica in sheep. In this cross‐sectional study, 195 stool samples were collected from sheep for 3 months in Lorestan province, West of Iran. Specimens’ parasitological examination was performed by using the direct wet mount and formalin‐ether concentration method. After DNA extraction from the samples, molecular analysis was done using PCR and LAMP techniques based on the Fasciola ribosomal intergenic spacer (IGS) sequence. Of 195 specimens of sheep, 11 specimens were identified as F. hepatica‐positive infection by using microscopic, PCR and LAMP assays. Kappa agreement test results showed that there was a significant agreement between the results of microscopic examination diagnostic tests, PCR and LAMP (Kappa = 0.51–0.72 and p < .001). According to the results of chi‐square comparisons between parasite prevalence applying different techniques and variables of age, sex breed, and type of drinking water, there was no significant relationship (p ≥ .05). However, most of the infected sheep with Fasciola were 3‐ to 4‐year‐old females, of the Lori breed and consumed tap water. In many endemic areas, successful prevention and treatment of fascioliasis in animals depend on rapid and accurate diagnosis. Based on the results of the Kappa agreement, the significant agreement among the results of the microscopic examination, PCR and LAMP indicates the accuracy and reliability of these tests in the diagnosis of F. hepatica in sheep. However, molecular methods, especially the LAMP technique, are suggested because of their higher sensitivity and reliability for the diagnosis of F. hepatica even under field conditions.
Scalar leptoquarks in leptonic processes
Authors: Crivellin Andreas , Greub Christoph , Müller Dario , Saturnino Francesco 
Published: February 2021

Abstract
Leptoquarks are hypothetical new particles, which couple quarks directly to leptons. They experienced a renaissance in recent years as they are prime candidates to explain the so-called flavor anomalies, i.e. the deviations between the Standard Model predictions and measurements in b → sℓ+ℓ− and b → cτν processes and in the anomalous magnetic moment of the muon. At the one-loop level these particles unavoidably generate effects in the purely leptonic processes like Z → ℓ+ℓ−, Z →$$ v\overline{v} $$
v

v
¯

, W → ℓν and h → ℓ+ℓ− and can even generate non-zero rates for lepton flavor violating processes such as ℓ → ℓ′γ, Z → ℓ+ℓ′−, h → ℓ+ℓ′− and ℓ → 3ℓ′. In this article we calculate these processes for all five representations of scalar Leptoquarks. We include their most general interaction terms with the Standard Model Higgs boson, which leads to Leptoquark mixing after the former acquires a vacuum expectation value. In our phenomenological analysis we investigate the effects in modified lepton couplings to electroweak gauge bosons, we study the correlations of the anomalous magnetic moment of the muon with h → μ+μ− and Z → μ+μ− as well as the interplay between different lepton flavor violating decays.
De Sitter decay through goldstino evaporation
Authors: Farakos Fotis , Kehagias Alex , Liatsos Nikolaos 
Published: February 2021

Abstract
We study supergravity theories with supersymmetry intrinsically non-linearly realized supported only by four-form flux. We demonstrate that supersymmetry can be restored by the evaporation of the goldstino multiplet. Such procedure requires the existence of a super-extremal 2-brane, in accordance with the WGC, and suggests an imminent decay in de Sitter supergravity, leaving the system to relax in supersymmetric AdS after the transition. In particular, the same decay mechanism also implies that the KKLT de Sitter vacua are short-lived. Our findings thus provide an effective realization of KPV-type of decays within 4D supergravity and in this way may reconcile the nilpotent superfield constructions of de Sitter with some aspects of the swampland program.
Free fermions, vertex Hamiltonians, and lower-dimensional AdS/CFT
Authors: de Leeuw Marius , Paletta Chiara , Pribytok Anton , Retore Ana L. , Torrielli Alessandro 
Published: February 2021

Abstract
In this paper we first demonstrate explicitly that the new models of integrable nearest-neighbour Hamiltonians recently introduced in PRL 125 (2020) 031604 [36] satisfy the so-called free fermion condition. This both implies that all these models are amenable to reformulations as free fermion theories, and establishes the universality of this condition. We explicitly recast the transfer matrix in free fermion form for arbitrary number of sites in the 6-vertex sector, and on two sites in the 8-vertex sector, using a Bogoliubov transformation. We then put this observation to use in lower-dimensional instances of AdS/CFT integrable R-matrices, specifically pure Ramond-Ramond massless and massive AdS3, mixed-flux relativistic AdS3 and massless AdS2. We also attack the class of models akin to AdS5 with our free fermion machinery. In all cases we use the free fermion realisation to greatly simplify and reinterpret a wealth of known results, and to provide a very suggestive reformulation of the spectral problem in all these situations.
A gauge invariant order parameter for monopole condensation in QCD vacuum
Authors: Di Giacomo Adriano 
Published: February 2021

Abstract
In this paper we improve the existing order parameter for monopole condensation in gauge theory vacuum, making it gauge-invariant from scratch and free of the spurious infrared problems which plagued the old one. Computing the new parameter on the lattice will unambiguously detect weather dual superconductivity is the mechanism for color confinement.As a byproduct we relate confinement to the existence of a finite correlation length in the gauge-invariant correlator of chromo-electric field strengths.
Integrality of volumes of representations
Authors: Bucher Michelle , Burger Marc , Iozzi Alessandra 
Published: February 2021

AbstractLetMbe an oriented complete hyperbolicn-manifold of finite volume. Using the definition of volume of a representation previously given by the authors in [3] we show that the volume of a representation$$\rho :\pi _1(M)\rightarrow \mathrm {Isom}^+({{\mathbb {H}}}^n)$$ρ:π1(M)→Isom+(Hn), properly normalized, takes integer values ifnis even and$$\ge 4$$≥4. IfMis not compact and 3-dimensional, it is known that the volume is not locally constant. In this case we give explicit examples of representations with volume as arbitrary as the volume of hyperbolic manifolds obtained fromMvia Dehn fillings.
Increased Needle Visibility in Ultrasound-Guided Percutaneous Liver Biopsy by an Echogenic Sheath: A Proof of Concept Study in a Human Cadaver
Authors: Hopstaken Jana S. , de Jong Leon , Fütterer Jurgen J. 
Published: February 2021

Abstract
Purpose
For the safety and success of an ultrasound-guided percutaneous liver biopsy, needle visibility and needle tip identification are critical. The aim of this pilot study was to evaluate the influence of an innovative echogenic sheath placed over a standard biopsy needle on needle visibility in ultrasound imaging.

Materials and methods
Ultrasound videos of three sheaths with different coating characteristics (echogenicity) and one conventional liver biopsy needle were recorded at two angles (30° and 60°) and two depths (5 and 10 cm) in a human cadaver. The videos were blinded for needle type and presented to five independent radiologists who used Likert-scale scoring to rank each video for six characteristics on needle visibility. In addition, a phantom model was used to acquire standardized images for quantitative evaluation of the ultrasound visibility. Comparative statistical analysis consisted of a one-way ANOVA.

Results
The three prototype sheaths were ranked higher than the control needle at 60° with 5 cm depth, with an equal performance for the other conditions. The radiologists expressed more confidence in taking a biopsy with the echogenic sheaths than with the control needle, with 1 Likert score difference at 30°. Contrast analysis in the phantom model showed a statistically significant effect of a sheath (p = 0.004) on echogenic intensity.

Conclusion
This pilot study suggests that the use of an echogenic sheath may increase needle visibility, particularly for trajectories requiring steeper insertion angles. To investigate the superiority of the echogenic sheath over conventional needles, a clinical study is necessary.
XCOVNet: Chest X-ray Image Classification for COVID-19 Early Detection Using Convolutional Neural Networks
Authors: Madaan Vishu , Roy Aditya , Gupta Charu , Agrawal Prateek , Sharma Anand , Bologa Cristian , Prodan Radu 
Published: February 2021

AbstractCOVID-19 (also known as SARS-COV-2) pandemic has spread in the entire world. It is a contagious disease that easily spreads from one person in direct contact to another, classified by experts in five categories: asymptomatic, mild, moderate, severe, and critical. Already more than 66 million people got infected worldwide with more than 22 million active patients as of 5 December 2020 and the rate is accelerating. More than 1.5 million patients (approximately 2.5% of total reported cases) across the world lost their life. In many places, the COVID-19 detection takes place through reverse transcription polymerase chain reaction (RT-PCR) tests which may take longer than 48 h. This is one major reason of its severity and rapid spread. We propose in this paper a two-phase X-ray image classification called XCOVNet for early COVID-19 detection using convolutional neural Networks model. XCOVNet detects COVID-19 infections in chest X-ray patient images in two phases. The first phase pre-processes a dataset of 392 chest X-ray images of which half are COVID-19 positive and half are negative. The second phase trains and tunes the neural network model to achieve a 98.44% accuracy in patient classification.
Does remote ischaemic conditioning reduce inflammation? A focus on innate immunity and cytokine response
Authors: Pearce Lucie , Davidson Sean M. , Yellon Derek M. 
Published: February 2021

AbstractThe benefits of remote ischaemic conditioning (RIC) have been difficult to translate to humans, when considering traditional outcome measures, such as mortality and heart failure. This paper reviews the recent literature of the anti-inflammatory effects of RIC, with a particular focus on the innate immune response and cytokine inhibition. Given the current COVID-19 pandemic, the inflammatory hypothesis of cardiac protection is an attractive target on which to re-purpose such novel therapies. A PubMed/MEDLINE™ search was performed on July 13th 2020, for the key terms RIC, cytokines, the innate immune system and inflammation. Data suggest that RIC attenuates inflammation in animals by immune conditioning, cytokine inhibition, cell survival and the release of anti-inflammatory exosomes. It is proposed that RIC inhibits cytokine release via a reduction in nuclear factor kappa beta (NF-κB)-mediated NLRP3 inflammasome production. In vivo, RIC attenuates pro-inflammatory cytokine release in myocardial/cerebral infarction and LPS models of endotoxaemia. In the latter group, cytokine inhibition is associated with a profound survival benefit. Further clinical trials should establish whether the benefits of RIC in inflammation can be observed in humans. Moreover, we must consider whether uncomplicated MI and elective surgery are the most suitable clinical conditions in which to test this hypothesis.
Detection of hysteroscopic fluid in the pouch of Douglas: a prospective cohort study about the predictability of bilateral tubal occlusion
Authors: Hager Marlene , Ott Johannes , Göbl Christian , Holzer Iris , Seemann Rudolf , Kurz Christine , Parry John Preston 
Published: February 2021

Abstract
Purpose
To determine whether an increase in cul de sac (CDS) fluid after hysteroscopy is predictive of tubal patency.

Methods
In a prospective clinical cohort study, 115 subfertile women undergoing laparoscopic and hysteroscopic surgery at the Medical University of Vienna were invited to participate. The primary outcome was determining whether an increase in fluid in the pouch of Douglas was reflective of unilateral or bilateral tubal patency. Vaginal sonography before and after hysteroscopy was performed to detect fluid in the pouch of Douglas, directly followed by laparoscopy with chromopertubation.

Results
Laparoscopic chromopertubation revealed bilateral Fallopian tube occlusion in 28 women (24.3%). Twenty-seven/40 patients (67.5%) with no fluid shift had bilateral occlusion during the consecutive laparoscopy (p < 0.001). One/75 patients (1.3%) showing a fluid shift had bilateral occlusion (sensitivity of a present fluid shift for uni- or bilateral patency 85.1%, 95% CI: 81.7–99.9, specificity: 96.4%, 95% CI: 75.8–91.8). Intracavitary abnormalities (odds ratio, OR, 0.038; p = 0.030) and adhesions covering one or both tubes (OR 0.076; p = 0.041) increased the risk for a false abnormal result, i.e., uni- or bilateral tubal patency despite the lack of a fluid shift.

Conclusion
When CDS fluid does not change after hysteroscopy, this is a sensitive test for tubal occlusion and further testing may be warranted. However, if there is an increase in CDS fluid after hysteroscopy, particularly for a patient without fluid present prior, this is both sensitive and specific for unilateral or bilateral tubal patency.
Spin Dynamics in Quantum Sine-Gordon Spin Chains: High-Field ESR Studies
Authors: Zvyagin Sergei 
Published: February 2021

AbstractA spin-1/2 Heisenberg antiferromagnetic chain is one of the most important paradigmatic models in quantum magnetism. Its ground state is a spin singlet, while the excitation spectrum is formed by gapless fractional excitations, spinons. The presence of alternating g-tensors and/or the staggered Dzyaloshinskii-Moriya interaction results in opening the energy gap $$\varDelta \propto H^{2/3}$$

Δ
∝

H

2
/
3

, once the magnetic field H is applied. A fairly good understanding of this phenomenon was achieved in the framework of the sine-Gordon quantum-field theory, taking into account the effective transverse staggered field induced by the applied uniform field. The theory predicts solitons and antisolitons as elementary excitations, as well as their bound states, breathers. Here, I review recent high-field electron spin resonance spectroscopy studies of such systems, focusing on peculiarities of their spin dynamics in the sine-Gordon regime and beyond.
Diffusion-based degeneration of the collagen reinforcement in the pathologic human cornea
Authors: Gizzi Alessio , De Bellis Maria Laura , Vasta Marcello , Pandolfi Anna 
Published: February 2021

AbstractWe describe a multiphysics model of the collagen structure of the cornea undergoing a progressive localized reduction of the stiffness, preluding to the development of ectasia and keratoconus. The architecture of the stromal collagen is assumed to follow the simplified two-family model proposed in Pandolfi et al. (A microstructural model of cross-link interaction between collagen fibrils in the human cornea. Philos Trans R Soc A 377:20180079, 2019), where the mechanical stiffness of the structure is supplied by transversal bonds within the fibrils of the same family (inter-crosslink bonds) and across the fibrils of the two families (intra-crosslink bonds). In Pandolfi et al. (A microstructural model of cross-link interaction between collagen fibrils in the human cornea. Philos Trans R Soc A 377:20180079, 2019), it was shown that the loss of the spherical shape due to the protrusion of a cone can be ascribed to the mechanical weakening of the intra-crosslink bonds in the central region of the collagen structure. In the present study, the reduction of bond stiffness is coupled to an evolutive pathologic phenomenon, modeled as a reaction–diffusion process of a normalized scalar field. We assume that the scalar field is a concentration-like measure of the degeneration of the chemical bonds stabilizing the structural collagen. We follow the evolution of the mechanical response of the system in terms of shape change, according to the propagation of the degeneration field, and identify the critical loss of mechanical stability resulting in the typical bulging of keratoconus corneas.
Long wave generation and coastal amplification due to propagating atmospheric pressure disturbances
Authors: Dogan Gozde Guney , Pelinovsky Efim , Zaytsev Andrey , Metin Ayse Duha , Ozyurt Tarakcioglu Gulizar , Yalciner Ahmet Cevdet , Yalciner Bora , Didenkulova Ira 
Published: February 2021

AbstractMeteotsunamis are long waves generated by displacement of a water body due to atmospheric pressure disturbances that have similar spatial and temporal characteristics to landslide tsunamis. NAMI DANCE that solves the nonlinear shallow water equations is a widely used numerical model to simulate tsunami waves generated by seismic origin. Several validation studies showed that it is highly capable of representing the generation, propagation and nearshore amplification processes of tsunami waves, including inundation at complex topography and basin resonance. The new module of NAMI DANCE that uses the atmospheric pressure and wind forcing as the other inputs to simulate meteotsunami events is developed. In this paper, the analytical solution for the generation of ocean waves due to the propagating atmospheric pressure disturbance is obtained. The new version of the code called NAMI DANCE SUITE is validated by comparing its results with those from analytical solutions on the flat bathymetry. It is also shown that the governing equations for long wave generation by atmospheric pressure disturbances in narrow bays and channels can be written similar to the 1D case studied for tsunami generation and how it is integrated into the numerical model. The analytical solution of the linear shallow water model is defined, and results are compared with numerical solutions. A rectangular shaped flat bathymetry is used as the test domain to model the generation and propagation of ocean waves and the development of Proudman resonance due to moving atmospheric pressure disturbances. The simulation results with different ratios of pressure speed to ocean wave speed (Froude numbers) considering sub-critical, critical and super-critical conditions are presented. Fairly well agreements between analytical solutions and numerical solutions are obtained. Additionally, basins with triangular (lateral) and stepwise shelf (longitudinal) cross sections on different slopes are tested. The amplitudes of generated waves at different time steps in each simulation are presented with discussions considering the channel characteristics. These simulations present the capability of NAMI DANCE SUITE to model the effects of bathymetric conditions such as shelf slope and local bathymetry on wave amplification due to moving atmospheric pressure disturbances.
Examining secondary school students’ views of model evaluation through an integrated framework of personal epistemology
Authors: Lee Silvia Wen-Yu , Wu Hsin-Kai , Chang Hsin-Yi 
Published: February 2021

AbstractThe aim of the study was to investigate students’ views of model evaluation through the lens of personal epistemology. We developed an integrated analytical framework by combining a developmental framework, including absolutist, multiplist, and evaluatist, with a multi-dimensional framework, including limits of knowing, certainty of knowing, and criteria of knowing. Furthermore, we examined the potential influence of the question contexts and the students’ grade levels. A total of 188 secondary school students were surveyed. Students answered two sets of model evaluation questions based on two scientific contexts. After reading the information about the two models, the students had to choose from three epistemic assumptions and then provide written justifications explaining their choice of assumptions. Quantitative and qualitative analyses were conducted for the multiple-choice questions and the written responses. In both contexts there were higher percentages of 11th-grade students choosing the evaluatist assumptions than the eighth-grade students. For students choosing multiplist and evaluatist assumptions, the 11th-grade students were more likely than the eighth-grade students to think in terms of pragmatic and evidential criteria as the criteria of knowing. Different contexts of the questions evoked different views of model evaluation particularly regarding the limits of knowing. Four additional categories of epistemic levels also emerged from the data. This study provides a new framework for understanding students’ thinking about model evaluation. Implications and suggestions for future research are provided.