bluuebunny/crossref_metadata_2025_split huggingface dataset:
Spatial and Seasonal Variation of Polycyclic Aromatic Hydrocarbons (Pahs) Deposition Flux and Sources in Shanghai
Authors: Wu Jian , Sha Chenyan , Li Dayan , Shen Cheng , Tang Hao , Huang Shenfa 
Published: November 2021

Abstract
Spatial and temporal variations of PAHs deposition flux and sources may significantly facilitate risk evaluations of super magacity in China. A study on polycyclic aromatic hydrocarbons of wet deposition and dry deposition in Shanghai was conducted from January to December, 2019. 17 sites were investigated located in four representative functional areas, covering iron and steel industry (BS), petrochemical industry (JS), central city (CC) and agricultural area (CM). The results showed that atmospheric PAHs level in shanghai was the lowest in autumn and the highest in winter. As industrial area, BS and JS demonstrated higher PAHs deposition fluxes than those in CC and CM sites. Triangle map indicated that the PAHs distribution in winter and spring samples were more homogeneous, suggesting possible common origins, whereas that of summer and autumn seemed to be more dispersed. Isomar ratio and positive matrix factorization model were employed to identify the potential sources of PAHs in specific functional areas. BS was dominated by a high percentage (46%) of coal combustion. In JS site, the petroleum volatilization source percentage was 47.6%. The highest biomass burning (55.3%) contributions were in CM. Vehicle emission (49.3%) was identified as the predominant source of PAHs in CC. This study highlighted that local emission sources have a greater influence on PAHs deposition to specific functional regions in Shanghai.
Microplastic Pollution in The Topsoil of Hot And Dried Areas, Human Exposure and Source Assessment, Aghili Plain, Iran
Authors: ravanbakhsh Maryam , Fard Neamatollah Jaafarzadeh Haghighi , Abbasi Sajjad , ravanbakhsh Mina , Zahedi Amir , Sharifi Reza , Dehbandi Reza 
Published: November 2021

Abstract
Although the distribution of microplastic (MPs) has been studied in different environmental compartments during the last decade, there is still a knowledge gap in their distribution and abundances in soil. This study aimed to investigate the abundance, distribution, and type of MPs in the soil of Aghili plain as a hot and dry area in southwest of Iran. In this study, composite soil samples (n=102) were collected from the residential and agricultural areas in Aghili plain, Iran. A combination of visual observations, Scanning Electron Microscopy (SEM) – Energy-dispersive X-ray spectroscopy (EDS), and Raman micro -spectroscopy was conducted to quantify and characterize MPs in soil samples. The intakes of MPs in adults and children were estimated through two exposure EPA scenarios. The total MPs loading in the studies soil was 11.93 ± 0.9 items in Kg-1 of surface soil in Aghili plain. The MPs had various morphology (fiber, pellet, fragment, and spherule shapes), colors (white-transparent, yellow-orange, red-pink, blue-green and black-grey colors), and sizes (<100 µm up to 1000 ≤ µm). Black-grey fibers in size less than 100 μm were dominant MPs in soil samples using a binocular microscope. Trace amounts of C, N, O, Na, P, Si revealed by EDS suggested the organic and inorganic contaminations on the surface of identified MPs. Intake of MPs per day/year through ingestion of polluted soil was calculated. Mean normal and acute exposure was estimated at 0.435 and 0.871 MPs per year through ingestion by children and adults, respectively.
Biofuel production over Fischer-Tropsch synthesis: effect of Fe-Co/meso-HZSM-5 catalyst weight on product composition and process conversion
Authors: Jimmy Jimmy , Roesyadi Achmad , Suprapto Suprapto , Kurniawansyah Firman 
Published: November 2021

Fischer-Tropsch Synthesis (FTS) using Fe-Co/meso-HZSM-5 catalyst has been investigated. The impregnated iron and cobalt on HZSM-5 could be used as bifunction catalyst which combined polimerizing synthesis gas and long hydrocarbon cracking for making biofuel (saturated C5–C25 hydrocarbons as gasoline, kerosene and diesel oil). The study emphasized the effect of catalyst weight on product composition and process conversion. The HZSM-5, had been converted from ammonium ZSM-5 through calcination, and then desilicated with NaOH solution. The Co(NO3)2.6H2O and Fe(NO3)3.9H2O were used as precursor for incipient wetness impregnation (IWI) on amorphous meso-HZSM-5. The catalyst consisted of 10 % Fe and 90 % Co by weight, called 10Fe-90Co/meso-HZSM-5. All catalysts were reduced in situ in the continuous reactor with flowing hydrogen at 25 mL/min, 1 bar, 400 °C for 10 hours. The catalyst performance was observed in the same continuous fixed bed reactor at 25 mL/min synthesis gas (30 % CO, 60 % H2, 10 % N2), 250 °C, 20 bar for 96 hours. Various catalyst weight (1, 1.2, 1.4, 1.6 gram) were applied in FTS. The desilicated HZSM-5 properties (BET analysis) were 6.1–29.9 nm mesoporous diameter, 0.3496 cc/g average mesoporous volume, 526.035 cc/g pore surface area, and the EDX analysis gave 22.1059 Si/Al ratio and 16.11 % loading (by weight) on meso-HZSM-5. The reduced catalyst showed the XRD spectra of Fe (66°), Fe-Co alloy (44.50°) and Co3O4 (36.80°). The reaction using 1 gram of 10Fe-90Co/meso-HZSM-5 catalyst produced the largest composition and conversion. The 1 gram catalyst gave the largest normal selectivity of gasoline (19.15 %) and kerosene (55.18 %). While the largest normal diesel oil selectivity (24.17 %) was obtained from 1.4 gram of catalyst. The CO conversion per gram of catalyst showed similar value (CO conversion of 26–28 %) for all catalyst weight
Analysis of gas preparation processes for improvement of gas transportation technology
Authors: Gurbanov Abdulaga , Sardarova Ijabika , Damirova Javida 
Published: November 2021

At production, collection and transport of low – pressure gas to deep water offshore platforms in sea conditions because of thermodynamic indices change in the system, complications are generated in connection with liquid phases – separation. These complications disturb normal operational well behavior, gas preparation unit and trunk (main) pipeline conditions. As a result of these phenomena high – volume losses of gas, gas condensate and chemical reagent take place.
In the process of testing, the following process parameters were determined: pressure, gas temperature, facility performance, regeneration temperature, amount of absorbent injected into the gas flow, concentration of regenerated and saturated absorbent, dry gas dew point and so on. In the process of investigating the effect of the amount of inhibitor on the degree of corrosion prevention, hydrate formation and salt deposit at the facilities, regression equations. That is why, to guarantee uninterrupted transportation of low-pressure gas in field conditions, new methods are required for these phenomena prevention.
On the basis of field study results some variants of calculation were given to increase efficiency of low-pressure gas transportation system in offshore oil and gas field’s conditions.
Results of high-pressure gas optimal working pressure calculation for precipitated liquid phase displacement at low-pressure petroleum gas transportation to deepwater offshore platforms are shown in the article.
As well, method for precipitated liquid phase displacement from low-pressure gas pipeline with usage of high-viscosity elastic gelling compositions on the basis of domestic petrochemical products
The crystal structure of mineral magadiite, Na2Si14O28(OH)2∙8H2O
Authors: Marler Bernd , Krysiak Yaşar , Grosskreuz Isabel , Gies Hermann , Kolb Ute 
Published: November 2021

Abstract
Magadiite from Lake Magadi was structurally analyzed based on X-ray powder diffraction data. The idealized chemical composition of magadiite is Na16[Si112O224(OH)16]∙64H2O per unit cell. The XRD powder diffraction pattern was indexed in orthorhombic symmetry with lattice parameters a0 = 10.5035(9) Å, b0 = 10.0262(9) Å, and c0 = 61.9608(46) Å. The crystal structure was solved from a synthetic magadiite sample in a complex process using 3D electron diffraction combined with model building as presented in an additional paper. A Rietveld refinement of this structure model performed on a magadiite mineral sample in space group F2dd (No. 43) converged to residual values of RBragg = 0.031 and RF = 0.026 confirming the structure model. Physico-chemical characterization using solid-state NMR spectroscopy, SEM, TG-DTA, and DRIFT spectroscopy further confirmed the structure. The structure of magadiite contains two enantiomorphic silicate layers of, so far, unknown topology. The dense layers exhibit no porosity or micro-channels and have a thickness of 11.5 Å (disregarding the van der Waals radii of the terminal O atoms) and possess a silicon Q4 to Q3 ratio of 2.5. 16 out of 32 terminal silanol groups are protonated, and the remaining groups compensate for the charge of the hydrated sodium cations. Bands of edge-sharing [Na(H2O)6/1.5] octahedra are intercalated between the silicate layers extending along (110) and (110). The water molecules are hydrogen bonded to terminal silanol groups with O···O distances of 2.54–2.91 Å. The structure of magadiite is slightly disordered, typical for hydrous layer silicates (HLS), which possess only weak interactions between neighboring layers. In this respect, the result of the structure refinement represents a somewhat idealized structure. Nevertheless, the natural magadiite possesses a higher degree of structural order than any synthetic magadiite sample. The structure analysis also revealed the presence of strong intra-layer hydrogen bonds between the terminal O atoms (silanol/siloxy groups), confirmed by 1H MAS NMR and DRIFT spectroscopy. The surface zone of the silicate layers, as well as the interlayer region containing the [Na(H2O)6/1.5] octahedra, are closely related to the structure of Na-RUB-18.
Characterizing Patient-Clinician Communication in Secure Medical Messages: Retrospective Study
Authors: Huang Ming , Fan Jungwei , Prigge Julie , Shah Nilay D , Costello Brian A , Yao Lixia 
Published: November 2021

Background
Patient-clinician secure messaging is an important function in patient portals and enables patients and clinicians to communicate on a wide spectrum of issues in a timely manner. With its growing adoption and patient engagement, it is time to comprehensively study the secure messages and user behaviors in order to improve patient-centered care.

Objective
The aim of this paper was to analyze the secure messages sent by patients and clinicians in a large multispecialty health system at Mayo Clinic, Rochester.

Methods
We performed message-based, sender-based, and thread-based analyses of more than 5 million secure messages between 2010 and 2017. We summarized the message volumes, patient and clinician population sizes, message counts per patient or clinician, as well as the trends of message volumes and user counts over the years. In addition, we calculated the time distribution of clinician-sent messages to understand their workloads at different times of a day. We also analyzed the time delay in clinician responses to patient messages to assess their communication efficiency and the back-and-forth rounds to estimate the communication complexity.

Results
During 2010-2017, the patient portal at Mayo Clinic, Rochester experienced a significant growth in terms of the count of patient users and the total number of secure messages sent by patients and clinicians. Three clinician categories, namely “physician—primary care,” “registered nurse—specialty,” and “physician—specialty,” bore the majority of message volume increase. The patient portal also demonstrated growing trends in message counts per patient and clinician. The “nurse practitioner or physician assistant—primary care” and “physician—primary care” categories had the heaviest per-clinician workload each year. Most messages by the clinicians were sent from 7 AM to 5 PM during a day. Yet, between 5 PM and 7 PM, the physicians sent 7.0% (95,785/1,377,006) of their daily messages, and the nurse practitioner or physician assistant sent 5.4% (22,121/408,526) of their daily messages. The clinicians replied to 72.2% (1,272,069/1,761,739) patient messages within 1 day and 90.6% (1,595,702/1,761,739) within 3 days. In 95.1% (1,499,316/1,576,205) of the message threads, the patients communicated with their clinicians back and forth for no more than 4 rounds.

Conclusions
Our study found steady increases in patient adoption of the secure messaging system and the average workload per clinician over 8 years. However, most clinicians responded timely to meet the patients’ needs. Our study also revealed differential patient-clinician communication patterns across different practice roles and care settings. These findings suggest opportunities for care teams to optimize messaging tasks and to balance the workload for optimal efficiency.
Individuals With SARS-CoV-2 Infection During the First and Second Waves in Catalonia, Spain: Retrospective Observational Study Using Daily Updated Data
Authors: Alves-Cabratosa Lia , Comas-Cufí Marc , Blanch Jordi , Martí-Lluch Ruth , Ponjoan Anna , Castro-Guardiola Antoni , Hurtado-Ganoza Abelardo , Pérez-Jaén Ana , Rexach-Fumaña Maria , Faixedas-Brunsoms Delfi , Gispert-Ametller Maria Angels , Guell-Cargol Anna , Rodriguez-Batista Maria , Santaularia-Font Ferran , Orriols Ramon , Bonnin-Vilaplana Marc , Calderón López Juan Carlos , Sabater-Talaverano Gladis , Queralt Moles Francesc Xavier , Rodriguez-Requejo Sara , Avellana-Revuelta Esteve , Balló Elisabet , Fages-Masmiquel Ester , Sirvent Josep-Maria , Lorencio Carol , Morales-Pedrosa Josep Miquel , Ortiz-Ballujera Patricia , Ramos Rafel 
Published: November 2021

Background
A description of individuals with SARS-CoV-2 infection comparing the first and second waves could help adapt health services to manage this highly transmissible infection.

Objective
We aimed to describe the epidemiology of individuals with suspected SARS-CoV-2 infection, and the characteristics of patients with a positive test comparing the first and second waves in Catalonia, Spain.

Methods
This study had 2 stages. First, we analyzed daily updated data on SARS-CoV-2 infection in individuals from Girona (Catalonia). Second, we compared 2 retrospective cohorts of patients with a positive reverse-transcription polymerase chain reaction or rapid antigen test for SARS-CoV-2. The severity of patients with a positive test was defined by their admission to hospital, admission to intermediate respiratory care, admission to the intensive care unit, or death. The first wave was from March 1, 2020, to June 24, 2020, and the second wave was from June 25, 2020, to December 8, 2020.

Results
The numbers of tests and cases were lower in the first wave than in the second wave (26,096 tests and 3140 cases in the first wave versus 140,332 tests and 11,800 cases in the second wave), but the percentage of positive results was higher in the first wave than in the second wave (12.0% versus 8.4%). Among individuals with a positive diagnostic test, 818 needed hospitalization in the first wave and 680 in the second; however, the percentage of hospitalized individuals was higher in the first wave than in the second wave (26.1% versus 5.8%). The group that was not admitted to hospital included older people and those with a higher percentage of comorbidities in the first wave, whereas the characteristics of the groups admitted to hospital were more alike.

Conclusions
Screening systems for SARS-CoV-2 infection were scarce during the first wave, but were more adequate during the second wave, reflecting the usefulness of surveillance systems to detect a high number of asymptomatic infected individuals and their contacts, to help control this pandemic. The characteristics of individuals with SARS-CoV-2 infection in the first and second waves differed substantially; individuals in the first wave were older and had a worse health condition.
Health Education Through a Campaign and mHealth to Enhance Knowledge and Quality of Life Among Patients With Chronic Kidney Disease in Bangladesh: Protocol for a Randomized Controlled Trial
Authors: Sarker Mohammad Habibur Rahman , Moriyama Michiko , Rashid Harun Ur , Rahman Md Moshiur , Chisti Mohammod Jobayer , Das Sumon Kumar , Jahan Yasmin , Saha Samir Kumar , Arifeen Shams El , Ahmed Tahmeed , Faruque A S G 
Published: November 2021

BackgroundDespite the growing burden of chronic kidney disease (CKD), disease knowledge and understanding are still lacking, especially in Bangladesh.ObjectiveThe aim of this study was to evaluate the outcome of a health education intervention in order to enhance knowledge, health-related quality of life (QOL), and motivation regarding healthy lifestyles among rural and periurban adults suffering from CKD.MethodsA parallel-group (1:1) randomized controlled trial is ongoing in the Mirzapur subdistrict, Bangladesh, where two groups of patients with CKD are being compared. Patients aged 18 years and over with CKD (stages 1-3) were enrolled in November 2020. Patients were randomly allocated into either the intervention group (n=63) or the control group (n=63). The control group received usual treatment, while the intervention group received health education through a CKD campaign facilitated by a nephrologist and via mHealth (ie, periodic mobile phone calls) from community health workers. Both groups were followed up for a period of 6 months. The primary endpoint is patients’ increased knowledge measured using the Chronic Kidney Disease Knowledge Questionnaire. The secondary endpoints are improved QOL measured using the standardized EuroQol 5-Dimension 5-Level (EQ-5D-5L) questionnaire as well as improvements in the levels of blood pressure, BMI, serum creatinine, fasting blood sugar, hemoglobin, cholesterol, high-density lipoprotein cholesterol, triglyceride, serum uric acid, blood urea nitrogen, and albumin to creatinine ratio.ResultsEnrollment of participants began in November 2020; the intervention and follow-up were completed in May 2021. We enrolled 126 patients in the study. Patients’ mean ages were 57.97 (SD 15.03) years in the control group and 57.32 (SD 14.37) years in the intervention group. There were 45 out of 63 (71%) females in the control group and 38 out of 63 (60%) females in the intervention group. In addition, there were 38 out of 63 (60%) literate patients in the control group and 33 out of 63 (52%) literate patients in the intervention group.ConclusionsIt is expected that a combined approach, incorporating both a CKD campaign and mHealth, for health education may be an effective tool for increasing knowledge and improving QOL among patients with CKD.Trial RegistrationClinicalTrials.gov NCT04094831; https://clinicaltrials.gov/ct2/show/NCT04094831International Registered Report Identifier (IRRID)DERR1-10.2196/30191
Momentary Manifestations of Negative Symptoms as Predictors of Clinical Outcomes in People at High Risk for Psychosis: Experience Sampling Study
Authors: Paetzold Isabell , Hermans Karlijn S F M , Schick Anita , Nelson Barnaby , Velthorst Eva , Schirmbeck Frederike ,   EU-GEI High Risk Study, van Os Jim , Morgan Craig , van der Gaag Mark , de Haan Lieuwe , Valmaggia Lucia , McGuire Philip , Kempton Matthew , Myin-Germeys Inez , Reininghaus Ulrich 
Published: November 2021

Background
Negative symptoms occur in individuals at ultrahigh risk (UHR) for psychosis. Although there is evidence that observer ratings of negative symptoms are associated with level of functioning, the predictive value of subjective experience in daily life for individuals at UHR has not been studied yet.

Objective
This study therefore aims to investigate the predictive value of momentary manifestations of negative symptoms for clinical outcomes in individuals at UHR.

Methods
Experience sampling methodology was used to measure momentary manifestations of negative symptoms (blunted affective experience, lack of social drive, anhedonia, and social anhedonia) in the daily lives of 79 individuals at UHR. Clinical outcomes (level of functioning, illness severity, UHR status, and transition status) were assessed at baseline and at 1- and 2-year follow-ups.

Results
Lack of social drive, operationalized as greater experienced pleasantness of being alone, was associated with poorer functioning at the 2-year follow-up (b=−4.62, P=.01). Higher levels of anhedonia were associated with poorer functioning at the 1-year follow-up (b=5.61, P=.02). Higher levels of social anhedonia were associated with poorer functioning (eg, disability subscale: b=6.36, P=.006) and greater illness severity (b=−0.38, P=.045) at the 1-year follow-up. In exploratory analyses, there was evidence that individuals with greater variability of positive affect (used as a measure of blunted affective experience) experienced a shorter time to remission from UHR status at follow-up (hazard ratio=4.93, P=.005).

Conclusions
Targeting negative symptoms in individuals at UHR may help to predict clinical outcomes and may be a promising target for interventions in the early stages of psychosis.
Differences in Secure Messaging, Self-management, and Glycemic Control Between Rural and Urban Patients: Secondary Data Analysis
Authors: Robinson Stephanie A , Netherton Dane , Zocchi Mark , Purington Carolyn , Ash Arlene S , Shimada Stephanie L 
Published: November 2021

Background
Rural patients with diabetes have difficulty accessing care and are at higher risk for poor diabetes management. Sustained use of patient portal features such as secure messaging (SM) can provide accessible support for diabetes self-management.

Objective
This study explored whether rural patients’ self-management and glycemic control was associated with the use of SM.

Methods
This secondary, cross-sectional, mixed methods analysis of 448 veterans with diabetes used stratified random sampling to recruit a diverse sample from the United States (rural vs urban and good vs poor glycemic control). Administrative, clinical, survey, and interview data were used to determine patients’ rurality, use of SM, diabetes self-management behaviors, and glycemic control. Moderated mediation analyses assessed these relationships.

Results
The sample was 51% (n=229) rural and 49% (n=219) urban. Mean participant age was 66.4 years (SD 7.7 years). More frequent SM use was associated with better diabetes self-management (P=.007), which was associated with better glycemic control (P<.001). Among rural patients, SM use was indirectly associated with better glycemic control through improved diabetes self-management (95% CI 0.004-0.927). These effects were not observed among urban veterans with diabetes (95% CI –1.039 to 0.056). Rural patients were significantly more likely than urban patients to have diabetes-related content in their secure messages (P=.01).

Conclusions
More frequent SM use is associated with engaging in diabetes self-management, which, in turn, is associated with better diabetes control. Among rural patients with diabetes, SM use is indirectly associated with better diabetes control. Frequent patient-team communication through SM about diabetes-related content may help rural patients with diabetes self-management, resulting in better glycemic control.