Microscopy Supported Multi-Scale Modeling of PEM Fuel Cells
Authors: Putz Andreas Michael Vincent , Zhang Shawn , Jankovic Jasna , Susac Darija , Sabharwal Mayank , Secanell Marc 
Published: February 2020

Proton exchange membrane fuel cells (PEMFCs) are being developed as alternative energy sources for both residential and automotive applications. For this technology to reach its full commercial potential, however, a significant reduction in cost is still required while the performance and durability of PEMFCs being maintained or improved. The key in this process is continuous improvement of membrane electrode assembly (MEA) through both the development of new materials and the optimization of the 3D structural arrangement of individual MEA components [1,2] . Structural optimization of MEA remains to be challenging due to multiple materials interacting across 6 orders of magnitude in their characteristic length scales, from several nanometers for the catalyst particle size to hundreds of micrometers for carbon fibers in porous transport layer.
In recent years, several microscopy techniques have become widely available to characterize the three-dimensional (3D) structure of PEMFC catalyst layers. Due to the heterogeneous nature of the PEMFCs sample, a correlative, multi-scale imaging protocol is developed in this work. The following technology is used where their corresponding resolution limit is pushed.

Transmission Electron Microscope tomography, TEMt [3] (0.60nm X 0.60nm X 0.60nm Voxel Size)

Focussed Ion Beam - Scanning Electron Microscope tomography, FIB-SEM [4] (2.5nm X 2.5nm X20 nm Voxel Size)

Micro and Nano X-ray Computed Tomography, NanoCT [5] (367nm X 367nm X 367nm Voxel Size)

Each technique by itself supports valuable insight to be obtained on the investigated structure at the corresponding length scale. By combining 3D imaging data at multiple scales, an unified structural characterization workflow is developed. Furthermore, an up scaling approach is developed based on TEMt, SEM and NanoCT reconstruction of catalyst layer, micro-porous layer and porous gas transport layer of a PMEFC cathode. Structural properties and effective transport properties are computed at each scale via image-based numerical simulation. Effective transport properties are up-scaled. MEA performances are predicted based on the obtained effective quantities at micro-scale.

References

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[2] S.W. Peterson, The Effect of Microstructure On Transport Properties of Porous Electrodes, Brigham Young University, 2015.
[3] H. Jinnai, R.J. Spontak, Transmission electron microtomography in polymer research, Polymer (Guildf). 50 (2009) 1067–1087.
[4] C. Ziegler, S. Thiele, R. Zengerle, Direct three-dimensional reconstruction of a nanoporous catalyst layer for a polymer electrolyte fuel cell, J. Power Sources. 196 (2011) 2094–2097.
[5] W.K. Epting, J. Gelb, S. Litster, Resolving the Three-Dimensional Microstructure of Polymer Electrolyte Fuel Cell Electrodes using Nanometer-Scale X-ray Computed Tomography, Adv. Funct. Mater. 22 (2012) 555–560.

Figure 1