bluuebunny/crossref_metadata_2025_split huggingface dataset:
Calcium metaborate induced thin walled carbon nanotube syntheses from CO2 by molten carbonate electrolysis
Authors: Wang Xirui , Liu Xinye , Licht Gad , Licht Stuart 
Published: September 2020

AbstractAn electrosynthesis is presented to transform the greenhouse gas CO2 into an unusually thin walled, smaller diameter morphology of Carbon Nanotubes (CNTs). The transformation occurs at high yield and coulombic efficiency of the 4-electron CO2 reduction in a molten carbonate electrolyte. The electrosynthesis is driven by an unexpected synergy between calcium and metaborate. In a pure molten lithium carbonate electrolyte, thicker walled CNTs (100–160 nm diameter) are synthesized during a 4 h CO2 electrolysis at 0.1 A cm−2. At this low current density, CO2 without pre-concentration is directly absorbed by the air (direct air capture) to renew and sustain the carbonate electrolyte. The addition of 2 wt% Li2O to the electrolyte produces thinner, highly uniform (50–80 nm diameter) walled CNTs, consisting of ~ 75 concentric, cylindrical graphene walls. The product is produced at high yield (the cathode product consists of > 98% CNTs). It had previously been demonstrated that the addition of 5–10 wt% lithium metaborate to the lithium carbonate electrolyte boron dopes the CNTs increasing their electrical conductivity tenfold, and that the addition of calcium carbonate to a molten lithium carbonate supports the electrosynthesis of thinner walled CNTs, but at low yield (only ~ 15% of the product are CNTs). Here it is shown that the same electrolysis conditions, but with the addition of 7.7 wt% calcium metaborate to lithium carbonate, produces unusually thin walled CNTs uniform (22–42 nm diameter) CNTs consisting of ~ 25 concentric, cylindrical graphene walls at a high yield of > 90% CNTs.
Constraining the preservation of organic compounds in Mars analog nontronites after exposure to acid and alkaline fluids
Authors: Gil-Lozano Carolina , Fairén Alberto G. , Muñoz-Iglesias Victoria , Fernández-Sampedro Maite , Prieto-Ballesteros Olga , Gago-Duport Luis , Losa-Adams Elisabeth , Carrizo Daniel , Bishop Janice L. , Fornaro Teresa , Mateo-Martí Eva 
Published: September 2020

AbstractThe presence of organic matter in lacustrine mudstone sediments at Gale crater was revealed by the Mars Science Laboratory Curiosity rover, which also identified smectite clay minerals. Analogue experiments on phyllosilicates formed under low temperature aqueous conditons have illustrated that these are excellent reservoirs to host organic compounds against the harsh surface conditions of Mars. Here, we evaluate whether the capacity of smectites to preserve organic compounds can be influenced by a short exposure to different diagenetic fluids. We analyzed the stability of glycine embedded within nontronite samples previously exposed to either acidic or alkaline fluids (hereafter referred to as “treated nontronites”) under Mars-like surface conditions. Analyses performed using multiple techniques showed higher photodegradation of glycine in the acid-treated nontronite, triggered by decarboxylation and deamination processes. In constrast, our experiments showed that glycine molecules were preferably incorporated by ion exchange in the interlayer region of the alkali-treated nontronite, conferring them a better protection against the external conditions. Our results demonstrate that smectite previously exposed to fluids with different pH values influences how glycine is adsorbed into their interlayer regions, affecting their potential for preservation of organic compounds under contemporary Mars surface conditions.
Factors associated with psychological stress and distress among Korean adults: the results from Korea National Health and Nutrition Examination Survey
Authors: Cheon Yejin , Park Jinju , Jeong Bo Yoon , Park Eun Young , Oh Jin-Kyoung , Yun E Hwa , Lim Min Kyung 
Published: September 2020

AbstractThe prevalence of stress and distress has been increasing and being important public health issues; nevertheless, few studies have assessed the factors associated at the population level. This study identified factors associated and how they differentially influence stress and distress. A total of 35,105 individuals aged 19 years and older using nationally representative data from the Korea National Health and Nutrition Examination Survey (2007–2012) were included in the study. Subjects were differentiated by gender and psychological state (no symptoms, stress, distress). The associations of socio-demographics, psychosocial factors, health behaviours, and chronic illness with psychological states were analysed by gender. Socio-demographics and psychosocial factors such as lower household income, lower education level, living alone or negative outcome of marriage, and unemployment were associated with distress in both genders. Male and female educated higher and with short sleep duration, male living alone and with higher household income, and female married and with a lower household income was associated with stress. A perceived body image of slim or fat was associated with distress and stress in both genders. Behavioural factors, such as smoking, higher alcohol consumption, and abnormal calorie intake, were associated with stress and distress in both genders, with the exception of alcohol consumption in distress and abnormal calorie intake in stress of male. Socio-economic deprivation and negative psychosocial and behavioural factors were differently associated with psychological distress or stress by gender. Intervention strategies for distress and stress should be specifically tailored regarding these differences.
Using GRACE satellite observations for separating meteorological variability from anthropogenic impacts on water availability
Authors: Hosseini-Moghari Seyed-Mohammad , Araghinejad Shahab , Ebrahimi Kumars , Tang Qiuhong , AghaKouchak Amir 
Published: September 2020

AbstractGravity Recovery and Climate Experiment (GRACE) observations provide information on Total Water Storage Anomaly (TWSA) which is a key variable for drought monitoring and assessment. The so-called Total Water Storage Deficit Index (TWSDI) based on GRACE data has been widely used for characterizing drought events. Here we show that the commonly used TWSDI approach often exhibits significant inconsistencies with meteorological conditions, primarily upon presence of a trend in observations due to anthropogenic water use. In this study, we propose a modified version of TWSDI (termed, MTWSDI) that decomposes the anthropogenic and climatic-driven components of GRACE observations. We applied our approach for drought monitoring over the Ganges–Brahmaputra in India and Markazi basins in Iran. Results show that the newly developed MTWSDI exhibits consistency with meteorological drought indices in both basins. We also propose a deficit-based method for drought monitoring and recovery assessment using GRACE observations, providing useful information about volume of deficit, and minimum and average time for drought recovery. According to the deficit thresholds, water deficits caused by anthropogenic impacts every year in the Ganges–Brahmaputra basin and Markazi basins is almost equal to an abnormally dry condition and a moderate drought condition, receptively. It indicates that unsustainable human water use have led to a form of perpetual and accelerated anthropogenic drought in these basins. Continuation of this trend would deplete the basin and cause significant socio-economic challenges.
The SDGs and human well-being: a global analysis of synergies, trade-offs, and regional differences
Authors: De Neve Jan-Emmanuel , Sachs Jeffrey D. 
Published: September 2020

AbstractThis paper explores the empirical links between achieving the Sustainable Development Goals (SDGs) and subjective well-being. Globally, we find that in terms of well-being, there are increasing marginal returns to sustainable development. Unpacking the SDGs by looking at how each SDG relates to well-being shows, in most cases, a strong positive correlation. However, SDG12 (responsible production and consumption) and SDG13 (climate action) are negatively correlated with well-being. This suggests that in the short run there may be certain trade-offs to sustainable development, and further heterogeneity is revealed through an analysis of how these relationships play out by region. Variance decomposition methods also suggest large differences in how each SDG contributes to explaining the variance in well-being between countries. These and other empirical insights highlight that more complex and contextualized policy efforts are needed in order to achieve sustainable development while optimising for well-being.
Assessing the population-wide exposure to lead pollution in Kabwe, Zambia: an econometric estimation based on survey data
Authors: Yamada Daichi , Hiwatari Masato , Hangoma Peter , Narita Daiju , Mphuka Chrispin , Chitah Bona , Yabe John , Nakayama Shouta M. M. , Nakata Hokuto , Choongo Kennedy , Ishizuka Mayumi 
Published: September 2020

AbstractThis study quantitatively assessed the population-wide lead poisoning conditions in Kabwe, Zambia, a town with severe lead pollution. While existing data have reported concerning blood lead levels (BLLs) of residents in pollution hotspots, the data representing the entire population are lacking. Further, selection bias is a concern. Given the lack of compulsory testing schemes, BLLs have been observed from voluntary participants in blood sampling surveys, but such data can represent higher or lower BLLs than the population average because of factors simultaneously affecting participation and BLLs. To illustrate the lead poisoning conditions of the population, we expanded the focus of our surveys and then econometrically estimated the BLLs of individuals representing the population, including those not participating in blood sampling, using background geographic, demographic, and socioeconomic information. The estimated population mean BLL was 11.9 μg/dL (11.6–12.1, 95% CI), lower than existing data because of our wide focus and correction of selection bias. However, the scale of lead poisoning remained immense and 74.9% of residents had BLLs greater than 5 μg/dL, the standard reference level for lead poisoning. Our estimates provide a deeper understanding of the problem and a foundation for policy intervention designs.
Rate of torque development and striatal shape in individuals with prodromal Huntington's disease
Authors: Cruickshank Travis , Reyes Alvaro , Pulverenti Timothy S. , Rankin Tim , Bartlett Danielle M. , Blazevich Anthony J. , Poudel Govinda , Ziman Mel , Trajano Gabriel S. 
Published: September 2020

AbstractThe aim of the present study was to quantify explosive joint torque or the ability to develop joint torque rapidly, typically measured as the rate of torque development, in individuals with prodromal Huntington’s disease and healthy controls and its associations with measures of disease burden and striatal pathology. Twenty prodromal Huntington’s disease and 19 healthy control individuals volunteered for this study. Plantar flexor isometric rate of torque development values were evaluated using isokinetic dynamometry. Pathological changes in striatal shape were evaluated using magnetic resonance imaging. Disease burden was evaluated using the disease burden score and cytosine-adenine-guanine age product score. No statistical differences in the rate of torque development were observed between individuals with prodromal Huntington’s disease and healthy controls. However, significant associations were observed between the rate of torque development values and measures of disease burden (r = −0.42 to −0.69) and striatal pathology (r = 0.71–0.60) in individuals with prodromal Huntington’s disease. We found significant associations between lower rate of torque development values and greater striatal shape deflation and disease burden and striatal pathology in individuals with prodromal Huntington’s disease. While no significant differences in the rate of torque development were found between prodromal Huntington’s disease and healthy controls, the noted associations suggest that differences may emerge as the disease advances, which should be investigated longitudinally in future studies.
Concentration of fifteen elements in herbaceous stems of Ephedra intermedia and influence of its growing soil
Authors: Liu Anli , Li Siqi , Cen Nana , Mao Fuying , Yang Ruixia , Li Linfei , Sui Hong , Zhao Yunsheng 
Published: September 2020

AbstractMineral nutrients play important roles in the growth and metabolism of Ephedra intermedia, and are affected by soil factors. Fifteen elements were measured from wild E. intermedia as well as their growing soils using inductively coupled plasma mass spectroscopy to investigate the influences and characteristics of herb elements. The pH, cation exchange capacity, humus and soil mechanical composition were also determined in rhizosphere soils. Results showed that E. intermedia stems contained high N, low P concentrations in macronutrients and high Fe in micronutrients, and enriched N, S, Cl, P and Sr from soils. The 15 herb elements were affected by one or more soil factors, and K, P, Zn, Fe and Mn were important soil elements that influenced the mineral accumulation of E. intermedia. This study was useful for the artificial cultivation of wild E. intermedia.
Proximity-based vocal networks reveal social relationships in the Southern white rhinoceros
Authors: Jenikejew Julia , Chaignon Brenda , Linn Sabrina , Scheumann Marina 
Published: September 2020

AbstractVocal communication networks can be linked to social behaviour, allowing a deeper understanding of social relationships among individuals. For this purpose, the description of vocal dyads is fundamental. In group-living species, this identification is based on behavioural indicators which require a high level of reactivity during social interactions. In the present study, we alternatively established a proximity-based approach to investigate whether sex-specific differences in vocal communication reflect social behaviour in a species with rather loose social associations and low levels of reactivity: the Southern white rhinoceros (Ceratotherium simum simum). We performed audio- and video recordings of 30 captive animals from seven groups. Vocal networks for the four most common call types were constructed by considering conspecifics at close distance (≤ 1 body length) to the sender as potential receivers. The analysis of the resulting unidirectional structures showed that not only the sex of the sender but also the sex of the potential receiver, the quality of social interactions (affiliative or agonistic) as well as association strength predict the intensity of vocal interactions between group members. Thus, a proximity-based approach can be used to construct vocal networks providing information about the social relationships of conspecifics—even in species with loose social associations where behavioural indicators are limited.
Attosecond betatron radiation pulse train
Authors: Horný Vojtěch , Krůs Miroslav , Yan Wenchao , Fülöp Tünde 
Published: September 2020

AbstractHigh-intensity X-ray sources are essential diagnostic tools for science, technology and medicine. Such X-ray sources can be produced in laser-plasma accelerators, where electrons emit short-wavelength radiation due to their betatron oscillations in the plasma wake of a laser pulse. Contemporary available betatron radiation X-ray sources can deliver a collimated X-ray pulse of duration on the order of several femtoseconds from a source size of the order of several micrometres. In this paper we demonstrate, through particle-in-cell simulations, that the temporal resolution of such a source can be enhanced by an order of magnitude by a spatial modulation of the emitting relativistic electron bunch. The modulation is achieved by the interaction of the that electron bunch with a co-propagating laser beam which results in the generation of a train of equidistant sub-femtosecond X-ray pulses. The distance between the single pulses of a train is tuned by the wavelength of the modulation laser pulse. The modelled experimental setup is achievable with current technologies. Potential applications include stroboscopic sampling of ultrafast fundamental processes.
Statistical learning in domestic chicks is modulated by strain and sex
Authors: Santolin Chiara , Rosa-Salva Orsola , Lemaire Bastien S. , Regolin Lucia , Vallortigara Giorgio 
Published: September 2020

AbstractStatistical learning is a key mechanism for detecting regularities from a variety of sensory inputs. Precocial newborn domestic chicks provide an excellent model for (1) exploring unsupervised forms of statistical learning in a comparative perspective, and (2) elucidating the ecological function of statistical learning using imprinting procedures. Here we investigated the role of the sex of the chicks in modulating the direction of preference (for familiarity or novelty) in a visual statistical learning task already employed with chicks and human infants. Using both automated tracking and direct human coding, we confirmed chicks’ capacity to recognize the presence of a statistically defined structure underlying a continuous stream of shapes. Using a different chicken strain than previous studies, we were also able to highlight sex differences in chicks’ propensity to approach the familiar or novel sequence. This could also explain a previous failure to reveal statistical learning in chicks which sex was however not determined. Our study confirms chicks’ ability to track visual statistics. The pivotal role of sex in determining familiarity or novelty preferences in this species and the interaction with the animals’ strain highlight the importance to contextualize comparative research within the ecology of each species.
Experimental neoichnology of post-autotomy arm movements of sea lilies and possible evidence of thrashing behaviour in Triassic holocrinids
Authors: Gorzelak Przemysław , Salamon Mariusz A. , Brom Krzysztof , Oji Tatsuo , Oguri Kazumasa , Kołbuk Dorota , Dec Marek , Brachaniec Tomasz , Saucède Thomas 
Published: September 2020

AbstractEchinoderms exhibit remarkable powers of autotomy. For instance, crinoids can shed arm and stalk portions when attacked by predators. In some species, it has been reported that the autotomized arms display vigorous movements, which are thought to divert the attention of predators. This phenomenon, however, has not been well explored. Here we present results of experiments using the shallowest water species of living stalked crinoid (Metacrinus rotundus) collected at 140 m depth. A wide range of movements of detached arms, from sluggish writhing to violent flicks, was observed. Interestingly, autotomized arms produce distinct traces on the sediment surface. They are composed of straight or arched grooves usually arranged in radiating groups and shallow furrows. Similar traces were found associated with detached arms of the oldest (Early Triassic) stem-group isocrinid (Holocrinus). This finding may suggest that the origins of autotomy-related thrashing behaviour in crinoids could be traced back to at least the Early Triassic, underscoring the magnitude of anti-predatory traits that occurred during the Mesozoic Marine Revolution. A new ethological category, autotomichnia, is proposed for the traces produced by thrashing movements of shed appendages.
Predictors of normalized HbA1c after gastric bypass surgery in subjects with abnormal glucose levels, a 2-year follow-up study
Authors: Ekberg Neda Rajamand , Falhammar Henrik , Näslund Erik , Brismar Kerstin 
Published: September 2020

AbstractClinical biomarkers can predict normalization of HbA1c after Roux-en-Y gastric bypass (RYGB) surgery, but it is unclear which are the most predictive.The aim of this study was to compare biomarkers for insulin sensitivity and other clinical parameters in the prediction of normalization of HbA1c after RYGB surgery. This study included 99 (23 men) obese subjects (BMI > 35 kg/m2) undergoing a laparoscopic RYGB. Clinical and biochemical examinations were performed pre-operatively and up to 2 years after surgery. Pre-operatively, normal fasting glucose levels were found in 25 individuals (NG), prediabetes in 46 and type 2 diabetes (T2DM) in 28. At baseline IGF-I (SD), IGFBP-1 and adiponectin levels were low while leptin was high. Weight loss was observed in all three groups, most in the prediabetes group. After 2 years HbA1c was decreased in prediabetes and T2DM. In all three groups insulin, HOMA-IR, lipids and blood pressure improved, IGFBP-1 and adiponectin increased and leptin decreased. IGF-I (SD) increased only in T2DM. In those with prediabetes or T2DM (n = 74), HbA1c at 2 years correlated to baseline BMI (r = -0.27, p = 0.028), age (r = 0.43, p < 0.001), HbA1c (r = 0.37, p = 0.001) and IGFBP-1 (r = 0.25, p = 0.038), and was normalized in 45/74 (61%) at 1 year and in 36 subjects (49%) at 2 years. These responders were younger, had higher BMI, larger waist circumference, lower HbA1c and lower IGFBP-1 levels at baseline. In a multiple regression model age (negative, p = 0.021) and waist circumference (positive, p = 0.047) were the only predictors for normalized HbA1c. RYGB normalized HbA1c in 49% at two years follow-up, which was predicted by low baseline IGFBP-1 level, a marker of hepatic insulin sensitivty and insulin secretion. However,. younger age and larger waist circumference were the only predictors of normalized HbA1c in multivariate analysis.
Morphological composition and fiber partitioning along regrowth in elephant grass CT115 intended for ethanol production
Authors: Rueda José A. , Guerrero-Rodríguez Juan de Dios , Ramírez-Ordoñes Sergio , Aguilar-Martínez Cecilio U. , Hernández-Montiel Wilber , Ortega-Jiménez Eusebio 
Published: September 2020

AbstractLeaf share, plant age and growth season are often overlooked as modifiers of the biomass quality in energy crops. The current work studied the effect of the given factors on the biomass yield and the biomass quality in Elephant grass CT115, intended for bioethanol production, in Veracruz, Mexico. Two seasons per year, 5 months each, were tracked on a 2-weeks basis. The climate is warm wet with summer rains, 1,142 mm of annual rainfall, and 26 °C monthly temperature. From day 56 of the wet season or from day 84 of the dry season, stems accumulated 12 or 6 Mg ha−1, respectively, while green leaves increased only 1 Mg. Higher biomass quality was recorded for the leaf fraction, or for the wet season regrowth. For instance, lignin contained in stems meant twice that of leaves, whereas stems recorded 20% less lignin in the wet season as compared to the dry season. Despite holocellulose being similar between fractions or seasons, hemicellulose and cellulose showed inverse correlation, while lignin and cellulose contents were directly correlated in stems. Increasing the annual harvest of green leaves will improve biomass quality, which is known to increase biodegradability and might improve the annual ethanol yield.