bluuebunny/crossref_metadata_2025_split huggingface dataset:
Assessment of turbulence effects on effective solute diffusivity close to a sediment-free fluid interface
Authors: Baioni E. , Porta G. M. , Mousavi Nezhad M. , Guadagnini A. 
Published: September 2020

AbstractOur work is focused on the analysis of solute mixing under the influence of turbulent flow propagating in a porous system across the interface with a free fluid. Such a scenario is representative of solute transport and chemical mixing in the hyporheic zone. The study is motivated by recent experimental results (Chandler et al. Water Res Res 52(5):3493–3509, 2016) which suggested that the effective diffusion parameter is characterized by an exponentially decreasing trend with depth below the sediment-water interface. This result has been recently employed to model numerically downstream solute transport and mixing in streams. Our study provides a quantification of the uncertainty associated with the interpretation of the available experimental data. Our probabilistic analysis relies on a Bayesian inverse modeling approach implemented through an acceptance/rejection algorithm. The stochastic inversion workflow yields depth-resolved posterior (i.e., conditional on solute breakthrough data) probability distributions of the effective diffusion coefficient and enables one to assess the impact on these of (a) the characteristic grain size of the solid matrix associated with the porous medium and (b) the turbulence level at the water-sediment interface. Our results provide quantitative estimates of the uncertainty associated with spatially variable diffusion coefficients. Finally, we discuss possible limitations about the generality of the conclusions one can draw from the considered dataset.
Influence of NAO on forming the UTCI index in Kłodzko
Authors: Głogowski Arkadiusz , Bryś Krystyna , Bryś Tadeusz 
Published: September 2020

AbstractThe aim of this paper is to understand the role of the macrocirculation factor in shaping the dynamics of long-term bioclimatic conditions, with reference to Kłodzko in the Polish part of the Central Sudetes. The variability of bioclimatic conditions in Kłodzko for the period 1966–2017 was analysed, exposing its local specificity. The Universal Thermal Climate Index (UTCI) was taken as an indicator of the analysed bioclimatic features. The influence of the North Atlantic Oscillation (NAO) on the variability of this index and its constituent meteorological elements, e.g. air temperature, vapour pressure, wind speed, and solar conditions, was examined. On the basis of the winter NAO Hurrell coefficient, the analysed years were divided into two opposing groups representing either a negative or positive Hurrell index. A comparison between these two year-groups for the mean values of UTCI and the examined meteorological elements showed a clear intergroup difference in these values. Except for cloudiness, the importance of the macrocirculation genesis of NAO was verified by the statistically significant correlation between the Hurrell index on the one hand and the tested UTCI index and its constituent meteorological elements on the other.
New high-resolution gridded dataset of daily mean, minimum, and maximum temperature and relative humidity for Central Europe (HYRAS)
Authors: Razafimaharo Christène , Krähenmann Stefan , Höpp Simona , Rauthe Monika , Deutschländer Thomas 
Published: September 2020

AbstractThis study presents daily high-resolution (5 km × 5 km) grids of mean, minimum, and maximum temperature and relative humidity for Germany and its catchment areas, from 1951 to 2015. These observational datasets (HYRAS) are based upon measurements gathered for Germany and its neighbouring countries, in total more than 1300 stations, gridded in two steps: first, the generation of a background field, using non-linear vertical temperature profiles, and then an inverse distance weighting scheme to interpolate the residuals, subsequently added onto the background field. The modified Euclidian distances used integrate elevation, distance to the coast, and urban heat island (UHI) effect. A direct station-grid comparison and cross-validation yield low errors for the temperature grids over most of the domain and greater deviations in more complex terrain. The interpolation of relative humidity is more uncertain due to its inherent spatial inhomogeneity and indirect derivation using dew point temperature. Compared with other gridded observational datasets, HYRAS benefits from its high resolution and captures complex topographic effects. HYRAS improves upon its predecessor by providing datasets for additional variables (minimum and maximum temperature), integrating temperature inversions, maritime influence and UHI effect, and representing a larger area. With a long-term observational dataset of multiple meteorological variables also including precipitation, various climatological analyses are possible. We present long-term historical climate trends and relevant indices of climate extremes, pointing towards a significantly warming climate over Germany, with no significant change in total precipitation. We also evaluate extreme events, specifically the summer heat waves of 2003 and 2015.
Impact of single vs. blended functional electrolyte additives on interphase formation and overall lithium ion battery performance
Authors: von Aspern Natascha , Wölke Christian , Börner Markus , Winter Martin , Cekic-Laskovic Isidora 
Published: September 2020

AbstractTwo functional high-voltage additives, namely 2-(2,2,3,3,3-pentafluoropropoxy)-1,3,2-dioxaphospholane (PFPOEPi) and 1-methyl-3,5-bis(trifluoromethyl)-1H-pyrazole (MBTFMP) were combined as functional additive mixture in organic carbonate–based electrolyte formulation for high-voltage lithium battery application. Their impact on the overall performance in NMC111 cathode-based cells was compared with the single-additive–containing electrolyte counterpart. The obtained results point to similar cycling performance of the additive mixture containing electrolyte formulation compared with the MBTFMP-containing cells, whereas the single PFPOEPi-containing cells displayed the best cycling performance in NMC111||graphite cells. With regard to the cathode electrolyte interphase (CEI), characterized and analyzed by means of scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), both the MBTFMP and the PFPOEPi functional additives decompose on the NMC111 surface in single-additive–containing electrolyte formulations. However, the thickness of the CEI formed in the additive mixture–containing electrolyte formulation is determined by the MBTFMP additive, whereas the PFPOEPi additive impacts a change in the composition of the CEI. Furthermore, the MBTFMP additive decomposes prior to the PFPOEPi and, therefore, dominates the cycling performance of NMC111||graphite cells containing functional additive mixture–based electrolyte. This systematic approach allows us to understand the synergistic impact of each functional additive in an electrolyte formulation containing an additive mixture and helps to identify the right additive combination for advanced electrolyte formulation as well as to elucidate whether the single-additive or the additive mixture approach is more effective for the development of advanced functional electrolytes for lithium-based cell chemistries.Graphical abstract
Q-switched Nd-YAG laser alone and in combination with innovative hyaluronic acid gels improve keratinocytes wound healing in vitro
Authors: de Filippis Anna , D’Agostino Antonella , Pirozzi Anna Virginia Adriana , Tufano Maria Antonietta , Schiraldi Chiara , Baroni Adone 
Published: September 2020

AbstractDuring the last years, several attempts have been accomplished to improve the wound healing. Device application aimed at enhancing skin ability to reconstruct its damaged sites through a proper dermal regenerative process. In particular, Q-switched Nd-YAG laser (Medlite C6 laser, Conbio, USA) applied with a fluence of 8 J/cm2, a pulse width of 5 ns, and a spot size of 4 mm exerts a photo-mechanical action that improve skin repair. Besides, hyaluronan hybrid cooperative complexes (HCC) widely exploited in dermoesthetic applications proved specific actions on keratinocytes and fibroblasts monolayer repair. We evaluated this specific laser treatment in vitro on a wound healing model based on human keratinocytes (HaCaT) alone and in combination with HCC. In addition, we evaluated key biomarkers of dermal repair. Scratched HaCaT monolayers were treated with laser and successively with HA-based formulations (HHA and HCC). For each treatment and the control samples, at least 3 different wells were analyzed. Wound closure was quantified, measuring five view filed for each well at increasing incubation time, exploiting time lapse videomicroscopy and image analysis, permitting to compare the different healing rate of treatments respect to control. By real-time PCR and western blotting, we evaluated biomarkers of wound regeneration, such as integrins, aquaporin three (AQP3), and proinflammatory cytokines. The ANOVA test was used to assess statistical significance of the results obtained. Laser-treated cells achieved wound closure in about 37 h, faster than the control, while when coupled to HCC, the complete reparation was obtained in 24 h. Integrin αV was upregulated by treatments, with in particular about four-fold increase respect to the control when HCC + laser was used. In addition, integrin β3 was upregulated by all treatments especially with the combination of laser and HCC proved more efficient than others (~ 14-folds). A slighter but significant increase of AQP3 gene expression of 61% was found for laser treatment while the latter combined with HCC determined an upregulation of 72%. By coupling laser treatment and HCC, further healing improvement and consistent biomarker modulation was observed. Our results may support clinical implementation of new dermatology protocols conjugating laser treatments with topical or injective HA formulations as a valid tool in treatments to repair scars or other skin defects.
New Excavations at Umhlatuzana Rockshelter, KwaZulu-Natal, South Africa: a Stratigraphic and Taphonomic Evaluation
Authors: Sifogeorgaki Irini , Klinkenberg Victor , Esteban Irene , Murungi May , Carr Andrew S. , van den Brink Valentijn B. , Dusseldorp Gerrit L. 
Published: September 2020

AbstractUmhlatuzana rockshelter has an occupation sequence spanning the last 70,000 years. It is one of the few sites with deposits covering the Middle to Later Stone Age transition (~40,000–30,000 years BP) in southern Africa. Comprehending the site’s depositional history and occupation sequence is thus important for the broader understanding of the development of Homo sapiens’ behavior. The rockshelter was first excavated in the 1980s by Jonathan Kaplan. He suggested that the integrity of the late Middle Stone Age and Later Stone Age sediments was compromised by large-scale sediment movement. In 2018, we initiated a high-resolution geoarchaeological study of the site to clarify the site formation processes. Here, we present the results of the excavation and propose a revised stratigraphic division of the Pleistocene sequence based on field observations, sedimentological (particle size) analyses, and cluster analysis. The taphonomy of the site is assessed through phytolith and geochemical (pH, loss on ignition, stable carbon isotope) analyses. The results indicate a consistent sedimentological environment characterized by in situ weathering. The analysis of the piece-plotted finds demonstrates semihorizontal layering of archaeologically dense zones and more sterile ones. There was no indication of large-scale postdepositional sediment movement. We show that the low-density archaeological horizons in the upper part of the Pleistocene sequence are best explained by the changing patterns of sedimentation rate.
Melancholy of the Law
Authors: Tacik Przemyslaw 
Published: September 2020

AbstractThe paper attempts to construct a theoretical account of what melancholy—in a psychoanalytical and cultural sense—may mean for jurisprudence. It argues that the map of relations and displacements between the object and the subject that is associated with melancholy in different psychoanalytical approaches can be fruitfully adopted for understanding of normativity. Based on a thorough re-reading of Freud’s Trauer und Melancholie (Mourning and Melancholy), it suggests that there is an irremovable component of melancholy contained in the primordial act of separation of normativity from non-normative reality. This interpretation is confronted with Kelsen’s Theory of Pure Law in order to analyse in which respect the momentum of self-sufficiency within normativity entails structures of melancholy. Kelsen’s concept of ‘effectiveness’ is proposed as a key link which explains how melancholic withdrawal allows the law to interact with reality. Then the paper discusses Agamben’s theory of applicability and of the state of exception to demonstrate the law’s melancholic trap. Finally, the paper draws on Lacanian and post-Lacanian approaches to melancholy in order to investigate how melancholic momentum is inherent in the very structure of the law’s validity.
Land-use legacies of twentieth-century forestry in the UK: a perspective
Authors: Raum Susanne 
Published: September 2020

AbstractContextComplex interactions between societies and their environment have shaped landscapes across Europe over centuries. Therefore, taking a historical perspective can be important when designing new forestry policy and management activities.ObjectivesThis perspective aims to improve our appreciation of how a better historical understanding of landscapes can increase our understanding of current conditions and inform current and future policy and practice. I provide a perspective on land-use legacies and forest change, with a particular emphasis on landscapes, and using the example of forestry in the United Kingdom.MethodsFor this purpose, I undertook a comprehensive review of scholarly forestry literature and of relevant policy and legal documents in the UK, covering the last 100 years.ResultsThis brief review of the dynamics of forest landscapes in the UK over the last 100 years, shows that certain decisions, policies and management activities had major effects on the landscape, especially in terms of landscape patterns and species distribution, constraining it until today. Historic research investigated some of these legacies, leading to real change in policy and management, including a Broadleaved Policy, an Ancient Woodland Inventory, habitat restoration, habitat network and rewilding schemes. Research on past experiences of Dutch Elm disease in the UK and of similar outbreaks in other countries have guided responses to today’s tree pest/disease outbreaks and plant trade decisions.ConclusionA better appreciation of past decisions and activities, especially in forestry, helps to anticipate landscape legacy effects and potential cross-scale interactions of new policies and practices. It may also help to better justify and negotiate new decisions and long-term planning among multiple actors.
Host plant selection and virus transmission by Rhopalosiphum maidis are conditioned by potyvirus infection in Sorghum bicolor
Authors: Klein Peter , Smith C. Michael 
Published: September 2020

AbstractMany plant viruses are significant pathogens that are able to utilize arthropod vectors to infect a vast range of host plants, resulting in serious economic damage to world food crops. One such crop is Sorghum bicolor, grain sorghum, which is the fifth most important global cereal crop, it is grown for human consumption, animal feed, and biofuel. In this study, the Potyviruses Johnsongrass mosaic virus (JGMV), Maize dwarf mosaic virus (MDMV), Sugarcane mosaic virus (SCMV), and Sorghum mosaic virus (SRMV) were tested for their rates of transmission into tissues of S. bicolor by the corn leaf aphid, Rhopalosiphum maidis. In addition, virus infected and non-infected S. bicolor plants were assessed for their effects on R. maidis host plant selection behavior. Further, the propagation of each virus (viral ssRNA copy number) in infected plants was determined using qPCR amplification of viral coating protein gene fragments. The mean rate of JGMV transmission into S. bicolor plants by R. maidis was significantly lower than transmission of MDMV, SCMV, and/or SRMV. Sorghum bicolor plants infected with MDMV, SCMV or SRMV also attract significantly more R. maidis than non-infected plants. JGMV-infected plants do not effect a similar change in R. maidis plant choice preference. The preference of non-viruliferous R. maidis toward S. bicolor plants infected with MDMV, SCMV or SRMV, and lack of such attraction by JGMV-infected plants may play a role in virus transmission strategy and efficiency by the vector.
Anti-Exceptionalism About Requirements of Epistemic Rationality
Authors: Field Claire 
Published: September 2020

AbstractI argue for the unexceptionality of evidence about what rationality requires. Specifically, I argue that, as for other topics, one’s total evidence can sometimes support false beliefs about this. Despite being prima facie innocuous, a number of philosophers have recently denied this. Some have argued that the facts about what rationality requires are highly dependent on the agent’s situation and change depending on what that situation is like (Bradley,Philosophers’ Imprint,19(3). 2019). Others have argued that a particular subset of normative truths, those concerning what epistemic rationality requires, have the special property of being ‘fixed points’—it is impossible to have total evidence that supports false belief about them (Smithies,Philosophy and Phenomenological Research, 85(2). 2012; Titelbaum 2015). Each of these kinds of exceptionality permits a solution to downstream theoretical problems that arise from the possibility of evidence supporting false belief about requirements of rationality. However, as I argue here, they incur heavy explanatory burdens that we should avoid.
Geoheritage and Resilience of Dallol and the Northern Danakil Depression in Ethiopia
Authors: Vereb Viktor , van Wyk de Vries Benjamin , Hagos Miruts , Karátson Dávid 
Published: September 2020

AbstractThe Danakil Depression, located in the northern segment of the Afar rift, is a world-class example of active rifting and the birth of a new ocean. The unique, yet only partially interpreted geothermal system of Dallol in northern Danakil is currently receiving renewed attention by researchers and visitors despite its extreme climate since the recent improvements of infrastructure and the stabilisation of Ethio-Eritrean political relations. Previous studies focused on the general geological description, the economic exploitation of potash reserves and interpretation of the complex hydrothermal processes. Continuing monitoring of geothermal activity has not yet been carried out, and the valorisation of local geoheritage has not accompanied the increased interest of tourists. Here, we present a three-step study in order to demonstrate the unique geological environment and international geoheritage significance of Dallol and Danakil. A three-year-long remote sensing campaign has been done to provide information on improving the resilience of visitors through interpreted, monthly hazard maps, and on following up the changes of geothermal activity. Over the same time, the first geoheritage assessment of the region for 13 geosites was carried out along with a comparative analysis of three quantitative methods (to evaluate the scientific importance and the geotouristic development potential of the area). Finally, with the input of the assessment, a preliminary geoheritage management plan was created for practical consideration by stakeholders toward a geoconservation and geotourism development, as well as a resilience system of this peculiar area.
On metal and ‘spoiled’ wine: analysing psimythion (synthetic cerussite) pellets (5th–3rd centuries BCE) and hypothesising gas-metal reactions over a fermenting liquid within a Greek pot
Authors: Photos-Jones E. , Bots P. , Oikonomou E. , Hamilton A. , Knapp C. W. 
Published: September 2020

AbstractA Pb-based synthetic mineral referred to aspsimythion(pl.psimythia) was manufactured in the Greek world at least since the 6th c BCE and routinely by the 4th c BCE. Theophrastus (On Stones, 56) describes its preparation from metallic Pb suspended over a fermenting liquid. Psimythion is considered the precursor of one of western art’s most prominent white pigments, i.e. lead white (basic lead carbonate or synthetic hydrocerussite). However, so far, and for that early period, published analyses of psimythia suggest that they consisted primarily of synthetic cerussite. In this paper, we set out to investigate how it was possible to manufacture pure cerussite, to the near exclusion of other phases. We examined the chemical and mineralogical composition (pXRF/XRD) of a small number of psimythion pellets found within ceramic pots (pyxis) from Athens and Boeotia (5th–4th c BCE) in the collection of the National Archaeological Museum (NAM), Athens. Analyses showed that the NAM pellets consisted primarily of Pb/cerussite with small amounts of Ca (some samples) and a host of metallic trace elements. We highlight the reference in the Theophrastus text to ‘spoiled wine’ (oxos), rather than ‘vinegar’, as has been previously assumed, the former including a strong biotic component. We carried out DNA sequencing of the pellets in an attempt to establish presence of microorganisms (Acetic Acid Bacteria). None was found. Subsequently, and as a working hypothesis, we propose a series of (biotic/abiotic) reactions which were likely to have taken place in the liquid and vapour phases and on the metal surface. The hypothesis aims to demonstrate that CO2would be microbially induced and would increase, as a function of time, resulting in cerussite forming over and above hydrocerussite/other Pb-rich phases. Psimythion has for long been valued as a white pigment. What has perhaps been not adequately appreciated is the depth of empirical understanding from the part of psimythion manufacturers of the reactions between abiotic and biotic components within ‘oxos’/pot, as key drivers of minerals synthesis. Ultimately, psimythion manufacture may rest in understanding the nature of ‘oxos’, antiquity’s relatively little researched strongest acid.
Adsorption of lead ions on magnetically separable Fe3O4 watermelon composite
Authors: Adebowale Kayode , Egbedina Abisola , Shonde Blessed 
Published: September 2020

AbstractThe search for green methods for the synthesis of eco-friendly and sustainable materials is the focus of many studies. In this paper, magnetite nanoparticles (WM-Fe3O4) were synthesized using watermelon rind as a stabilizing agent and their adsorption capacity for the removal of lead ions was evaluated. The synthesized WM-Fe3O4 was characterized using Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy. Adsorption capacity and mechanism of WM-Fe3O4 for the removal of lead ions from water were evaluated. The adsorption isotherms data were well described by both Langmuir and Freundlich isotherms showing the heterogeneous nature of the adsorbent. Adsorption kinetics followed the pseudo-second-order model which confirmed the heterogeneity of the adsorbent and shows that adsorption followed chemisorption. Adsorption capacity was found to be 138 mg/g for lead. The initial solution pH had an influence on the adsorption. The removal efficiency decreased after pH 7. Effect of varying adsorbent mass indicates that a low dosage is required thereby favouring industrial scale up. The adsorption of lead ions was mainly controlled by electrostatic attraction and polar interactions. This adsorbent has potentials for the efficient capture of heavy metals with possibilities for the future replacement of expensive adsorbents.