bluuebunny/crossref_metadata_2025_split huggingface dataset:
INDEPENDÊNCIA, PODER JUDICIÁRIO E MINISTÉRIO PÚBLICO
Authors: Kerche Fábio 
Published: November 2019

<p><span>Os estudos acadêmicos sobre a questão da independência do Poder Judiciário e dos juízes, tanto do ponto de vista normativo quanto descritivo, são razoavelmente desenvolvidos. A produção é significativa e discute os dilemas e as dificuldades da existência de um Poder de Estado com altas doses de autonomia em regimes democráticos. Do ponto de vista da democracia, a questão é como atores pouco </span><em>accountable</em><span> convivem em um sistema baseado fundamentalmente no voto dos cidadãos. Em relação a esse debate, menor atenção é dada ao Ministério Público e aos promotores. Este ensaio bibliográfico analisa, sintetiza e reinterpreta parte da produção acadêmica sobre independência e suas tensões na democracia em relação ao Poder Judiciário e apresenta uma proposta de como estudar o mesmo tema em relação ao Ministério Público.</span></p><p>INDEPENDENCE, JUDICIARY AND PUBLIC PROSECUTOR’S OFFICE</p><p>Academic studies on the issue of the Judiciary and judges’ independence, both normatively and descriptively, are reasonably developed. The current academic production is significant and discusses both the dilemmas and difficulties of there being a branch of the government with high doses of autonomy in democratic regimes. From the democratic point of view, the issue is how barely-accountable actors coexist in a system based fundamentally on citizens’ vote. In relation to this debate, less attention is given to the Public Prosecutor’s Office and the prosecutors. This bibliographic essay analyzes, synthesizes and reinterprets part of the academic production on independence and its tensions in democracy in relation to the Judiciary and also presents a proposal of how to study the same subject in the Public Prosecutor’s Office.</p><p><strong>Key words: </strong>Judiciary; Public Prosecutor’s Office; Independency; Democracy</p><div><p class="trans-title">INDÉPENDANCE, POUVOIR JUDICIAIRE ET MINISTÈRE PUBLIC</p><p>Les études académiques sur la question de l’indépendance du Judiciaire et des juges, tant sur le plan normatif que sur le plan descriptif, sont raisonnablement développés. La production est significative et discute les dilemmes et les difficultés de l’existence d’un pouvoir d’Etat avec de fortes doses d’autonomie dans les régimes démocratiques. Du point de vue de la démocratie, la question est de savoir comment des acteurs si peu responsables coexistent dans un système basé fondamentalement sur le vote des citoyens. Moins d´attention est accordée au Ministère Public et aux procureurs en ce qui concerne ce débat. Cet essai bibliographique analyse, synthétise et réinterprète une partie de la production académique sur l’indépendance et ses tensions dans la démocratie par rapport à la magistrature et présente une proposition sur la façon d’étudier le même sujet par rapport au Ministère Public.</p><p><strong>Key words: </strong>Judiciaire; Ministère Public; Indépendance; Démocratie</p></div>
O RECONHECIMENTO JURÍDICO DAS VIOLÊNCIAS PSICOLÓGICAS NAS RELAÇÕES DE TRABALHO NO BRASIL
Authors: Magno e Silva Barbosa Attila , Bender Mateus 
Published: November 2019

<div><p class="trans-title">No Brasil, as violências psicológicas no trabalho são atualmente caracterizadas como afrontas aos direitos fundamentais do trabalho, ao princípio da dignidade da pessoa humana e ao valor social do trabalho. Embora não haja uma legislação específica sobre violências psicológicas no ambiente de trabalho, o judiciário tem apresentado um recente e crescente reconhecimento jurídico do tema, norteando-se, principalmente, por princípios constitucionais e de proteção à saúde do trabalhador. O objetivo deste artigo é demonstrar como tem ocorrido o reconhecimento jurídico da proteção à saúde psicológica no ambiente de trabalho. Para tal, utilizamos o procedimento monográfico e nos baseamos na realização de pesquisa bibliográfica e jurisprudencial.</p><p class="trans-title"> </p><p class="trans-title"><strong>THE LEGAL RECOGNITION OF PSYCHOLOGICAL VIOLENCES IN LABOR RELATIONS IN BRAZIL</strong></p><p>Psychologically violence at work, in Brazil, has only recently been recognized as a transgression to the fundamental rights of work, to the principle of the dignity of the human person and to the social value of work. Although there is no specific legislation on psychological violence at the workplace, the judiciary has presented a recent and growing juridical recognition to the subject, being guided mainly by constitutional principles as well as by principles related to the protection of the health of the worker. The aim of this article is to discuss how has been occurred the legal recognition of the protection of the psychological health at the work environment. In order to reach the aim of this article, we analyse a specific monographic procedure as well as bibliographical and jurisprudential research.</p><p><strong>Key words: </strong>Psychologically violence at work; Moral harassment; Legal recognition</p><p class="trans-title"> </p></div><div><p class="trans-title"><strong>LA RECONNAISSANCE JURIDIQUE DES VIOLEN-CES PSYCHOLOGIQUES DANS LES RAPPORTS DE TRAVAIL AU BRÉSIL</strong></p><p>Au Brésil, les violences psychologiques au travail sont actuellement caractérisés comme un affront aux droits fondamentaux du travail, au principe de la dignité humaine et à la valeur sociale du travail. Bien qu’il n’existe pas de législation spécifique sur les violences psychologiques dans l’environnement de travail, le pouvoir judiciaire a présenté une reconnaissance juridique récente et croissante du thème, principalement guidée par des principes constitutionnels et de protection de la santé des travailleurs. Le but de cet article est démontrer le processus de reconnaissance juridique de la protection de la santé psychologique dans l’environnement de travail. Pour cela, nous avons utilisé la procédure monographique et recherches bibliographiques et jurisprudentielles.</p><p><strong>Key words: </strong>Violence psychologique au travail; Harcèlement moral; Reconnaissance juridique</p><p class="trans-title"><strong><br /></strong></p></div>
Botanical‐Inspired 4D Printing of Hydrogel at the Microscale
Authors: Hu Yanlei , Wang Zhongyu , Jin Dongdong , Zhang Chenchu , Sun Rui , Li Ziqin , Hu Kai , Ni Jincheng , Cai Ze , Pan Deng , Wang Xuewen , Zhu Wulin , Li Jiawen , Wu Dong , Zhang Li , Chu Jiaru 
Published: November 2019

AbstractBotanical systems have evolved the intriguing ability to respond to diverse stimuli due to long‐term survival competition. Mimicking these dynamic behaviors has greatly advanced the developments in wide fields ranging from soft robotics, precision sensors to drug delivery and biomedical devices. However, realization of stimuli‐responsive components at the microscale with high response speed still remains a significant challenge. Herein, the miniature biomimetic 4D printing of pH‐responsive hydrogel is reported in spatiotemporal domain by femtosecond laser direct writing. The dimension of the printed architectures is at the microscale (<102 µm) and the response speed is reduced down to subsecond level (<500 ms). Shape transformation with multiple degrees of freedom is accomplished by taking advantage of pH‐triggered expansion, contraction, and torsion. Biomimetic complex shape‐morphing is enabled by adopting flexible scanning strategies. In addition, application of this 4D‐printed micro‐architecture in selective micro‐object trapping and releasing is demonstrated, showcasing its possibilities in micromanipulation, single‐cell analysis, and drug delivery.
Density Modulation of Embedded Nanoparticles via Spatial, Temporal, and Chemical Control Elements
Authors: Tan Edward K. W. , Shrestha Pawan K. , Pansare Amol V. , Chakrabarti Subhananda , Li Shunpu , Chu Daping , Lowe Christopher R. , Nagarkar Amit A. 
Published: November 2019

AbstractNanoparticle polymer composites have enabled material multifunctionalities that are difficult to obtain otherwise. A simple modification to a commercially available resin system enables a universal methodology to embed nanoparticles in resins via spatial, temporal, thermal, concentration, and chemical control parameters. Changes in nanoparticle density distribution are exploited to demonstrate dynamic optical and electronic properties that can be processed on‐demand, without the need for expensive equipment or cleanroom facilities. This strategy provides access to the control of optical (cooperative plasmonic effects), electronic (insulator to a conductor), and chemical parameters (multimetal patterning). Using the same composite resin system, the followings are fabricated: i) diffraction gratings with tuneable diffraction efficiencies (10–78% diffraction efficiencies), ii) organic electrochemical transistors with a low drive voltage, and iii) embedded electrodes in confined spaces for potential diagnostic applications.
Ligand‐Controlled C−O Bond Coupling of Carboxylic Acids and Aryl Iodides: Experimental and Computational Insights
Authors: Li Li , Song Feifei , Zhong Xiumei , Wu Yun‐Dong , Zhang Xinhao , Chen Jiean , Huang Yong 
Published: November 2019

AbstractPalladium‐catalyzed cross‐coupling reactions between carboxylic acids and aryl halides have several possible competitive pathways. Decarboxylative C−C bond coupling and C−H arylation are well established in the literature. However, direct C−O bond coupling between carboxylic acids and aryl halides has received little success. In this report, we describe a protocol for exclusive C−O bond formation, enabled by a bidentate N,N‐ligand such as 1,10‐phenanthroline. The reaction is general for a broad range of carboxylic acids and iodoarenes. Experimental evidence and computational results suggest a high energy barrier for the alternative pathway of decarboxylative carbon‐carbon bond coupling.magnified image
Advances in Chemocatalytic Asymmetric Baeyer–Villiger Oxidations
Authors: Liu Chao , Wen Kai‐Ge , Zeng Xing‐Ping , Peng Yi‐Yuan 
Published: November 2019

AbstractBaeyer–Villiger oxidations, first reported by Adolf von Baeyer and Victor Villiger 120 years ago, are highly efficient methodologies for the syntheses of esters or lactones from ketones. The asymmetric Baeyer–Villiger oxidations using racemic, prochiral and meso‐cyclic ketones allow a rapid access to chiral lactones, which are valuable intermediates for the subsequent synthesis of bioactive compounds and natural products. The current review provides a summary on the advances in chemocatalytic enantioselective B‐V oxidations. The latest achievements in this field and their applications are presented.magnified image
Halogen Engineering for Operationally Stable Perovskite Solar Cells via Sequential Deposition
Authors: Li Qi , Zhao Yao , Zhou Wenke , Han Zhengyuan , Fu Rui , Lin Fang , Yu Dapeng , Zhao Qing 
Published: November 2019

AbstractThe performance of perovskite solar cells (PSCs) relies on the synthesis method and chemical composition of the perovskite materials. So far, PSCs that have adopted two‐step sequential deposited perovskite with the state‐of‐art composition (FAPbI3)1−x(MAPbBr3)x (x < 0.05) have achieved record power conversion efficiency (PCE), while their one‐step antisolvent dripping counterparts with typical composition Cs0.05FA0.81MA0.14Pb(I0.85Br0.15)3 with more bromine have exhibited much better long‐term operational stability. Thus, halogen engineering that aims to elevate bromine content in sequential deposited perovskite film would push operational stability of PSCs toward that of antisolvent dripping deposited perovskite materials. Here, a Br‐rich seeding growth method is devised and perovskite seed solution with high bromine content is introduced into a PbI2 precursor, leading to bromine incorporation in the resulting perovskite film. Photovoltaic devices fabricated by Br‐rich seeding growth method exhibit a PCE of 21.5%, similar to 21.6% for PSCs having lower bromine content. Whereas, the operational stability of PSCs with higher bromine content is significantly enhanced, with over 80% of initial PCE retained after 500 h tracking at maximum power point under 1‐sun illumination. This work highlights the vital importance of halogen composition for the operational stability of PSCs, and introduces an effective way to incorporate bromine into mixed‐cation‐halide perovskite film via sequential deposition method.
Nonthermal plasma (NTP) activated metal–organic frameworks (MOFs) catalyst for catalytic CO2 hydrogenation
Authors: Chen Huanhao , Mu Yibing , Shao Yan , Chansai Sarayute , Xiang Huan , Jiao Yilai , Hardacre Christopher , Fan Xiaolei 
Published: November 2019

AbstractA systematic study of Ni supported on metal–organic frameworks (MOFs) catalyst (i.e., 15Ni/UiO‐66) for catalytic CO2 hydrogenation under nonthermal plasma (NTP) conditions was presented. The catalyst outperformed other catalysts based on conventional supports such as ZrO2, representing highest CO2 conversion and CH4 selectivity at about 85 and 99%, respectively. We found that the turnover frequency of the NTP catalysis system (1.8 ± 0.02 s−1) has a nearly two‐fold improvement compared with the thermal catalysis (1.0 ± 0.06 s−1). After 20 hr test, XPS and HRTEM characterizations confirmed the stability of the 15Ni/UiO‐66 catalyst in the NTP‐activated catalysis. The activation barrier for the NTP‐activated catalysis was calculated as ~32 kJ mol−1, being lower than the activation energy of the thermal catalysis (~70 kJ mol−1). In situ DRIFTS characterization confirmed the formation of multiple carbonates and formates on catalyst surface activated by NTP, surpassing the control catalysts (e.g., 15Ni/α‐Al2O3 and 15Ni/ZrO2).
An overview of the Department of Energy's CarbonSAFE Initiative: Moving CCUS toward commercialization
Authors: Sullivan Mary , Rodosta Traci , Mahajan Kanwal , Damiani Darin 
Published: November 2019

AbstractThe U.S. Department of Energy (DOE) Office of Fossil Energy (FE) National Energy Technology Laboratory (NETL) Carbon Storage Program helps develop technologies that safely and permanently store carbon dioxide (CO2) without adversely impacting natural resources or hindering economic growth. Since 1997, the program has significantly advanced carbon capture, utilization, and storage (CCUS) science and technology, with more than 10.5 million metric tons (MMT) of CO2 safely stored. However, key gaps in experience and knowledge remain (e.g., the technology, expertise, and processes needed to safely characterize and monitor 50+ MMT‐scale geologic CO2 storage sites). DOE's Carbon Storage Assurance Facility Enterprise (CarbonSAFE) Initiative (launched in FY16) is beginning to address this gap. The CarbonSAFE Initiative currently consists of 13 projects in Phase I: Integrated Carbon Capture and Storage (CCS) Pre‐Feasibility and six projects in Phase II: Storage Complex Feasibility. This article includes the latest updates from the CarbonSAFE Initiative.
Total disability days in interprovincial and home‐province workers injured in Alberta, Canada: A mixed‐methods study with matched‐pair analysis of compensation data and participant interviews
Authors: Cherry Nicola , Galarneau Jean‐Michel , Haynes Whitney 
Published: November 2019

AbstractIntroductionWorkers moving between states or provinces to find employment are reported to take longer to return to work after the injury.MethodsThe Alberta Workers Compensation Board (WCB) identified all workers from four Canadian Atlantic provinces who sustained a work injury in Alberta resulting in greater than 5 total temporary disability days (TTDDays) from January 2015 to June 2017. Each was matched on sex, age, and injury date with an Alberta claimant also with greater than 5 TTDDays. WCB information extracted included employment, injury, cost and place of treatment, and modified work. Cox regression identified factors associated with TTDDays. Semi‐structured interviews were also undertaken.ResultsTwo‐hundred forty pairs were identified and 60 interviews completed. Those from the Atlantic provinces had more TTDDays (median 63 days) than Alberta (median 22 days) with an unadjusted hazard ratio (HR) 0.50 (95% confidence interval [CI], 0.42‐0.61). When adjusted for all factors, the HR moved closer to unity (HR = 0.62; 95% CI, 0.50‐0.76). Total health care costs were the strongest predictor, with modified work, injury type, and claim status also explanatory factors. Among the Atlantic workers, leaving Alberta for treatment was strongly related to a lower likelihood of ending wage replacement (HR = 0.45; 95% CI, 0.32‐0.62). Participants in the interview study emphasized the importance of returning to the family after injury and the financial difficulties of maintaining a second home with reduced income after the injury.ConclusionThe higher costs of wage replacement associated with extended time off work may be inherent to the practice of employing out‐of‐province workers for jobs for which there is a shortage of local labor.
Interleukin 1α and 1β gene variations are associated with tuberculosis in silica exposed subjects
Authors: Salum Kaio Cezar Rodrigues , de Castro Marcos Cesar Santos , Moreira Valéria Barbosa , Nani Angela Santos Ferreira , Kohlrausch Fabiana Barzotto 
Published: November 2019

AbstractIntroductionSilicosis is a fibrotic lung disease resulting from the inhalation of crystalline silica and can be classified as simple or complicated according to the International Labour Organization criteria. Furthermore, individuals exposed to crystalline silica also have a higher risk for the development of tuberculosis (Tb). The contribution of inflammatory cytokines to the risk of silicosis and Tb in different populations has previously been reported. Since genetic background might be related to susceptibility to silicosis and Tb, the study of polymorphisms within IL‐1α, IL‐1β, and tumor necrosis factor protein‐coding genes may contribute to elucidating the genetic basis of these diseases.MethodsSingle nucleotide polymorphisms (SNPs) were genotyped by polymerase chain reaction using restriction fragment length polymorphism or by Taqman methodology, in a sample of 102 silica‐exposed patients from Brazil.ResultsNo significant associations were observed between the SNPs studied and the severity of silicosis. However, significant associations were found between Tb and the C allele (odds ratio [OR] = 1.93, 95% confidence interval [CI], 1.01‐3.73) and the CC genotype (OR = 2.34, 95% CI, 1.04‐5.31) of IL1A −899C>T. The IL1B +3954C>T polymorphism also showed an association with Tb (T allele dominant model OR = 2.38, 95% CI, 1.04‐5.41).ConclusionThese preliminary results demonstrate that the IL1A and IL1B gene variations may contribute to some extent to susceptibility to Tb, but not silicosis. However, additional studies are still needed to confirm these results.
A dyadic genotype–phenotype approach to diagnostic criteria for Proteus syndrome
Authors: Sapp Julie C. , Buser Anna , Burton‐Akright Jasmine , Keppler‐Noreuil Kim M. , Biesecker Leslie G. 
Published: November 2019

AbstractPhenotype‐based diagnostic criteria were developed for Proteus syndrome in 1999 and updated in 2006. Subsequently, the causative mosaic gene alteration was discovered, the c.49G>A p.E17K variant in AKT1. As well, a number of overlapping overgrowth disorders attributable to mosaic PIK3CA variants have now been characterized, leading to the designation of PIK3CA‐related overgrowth spectrum (PROS). Finally, ongoing work to better characterize Proteus syndrome has led to identification of additional features of that disorder that could be useful in diagnostic criteria. We have taken the opportunity of these discoveries to re‐evaluate the Proteus syndrome diagnostic criteria. Here we propose a new set of diagnostic criteria that establishes a weighted, point‐based system for the phenotypic attributes and then integrates that with the potential molecular test results to result in one of two designations: AKT1‐related Proteus syndrome or AKT1‐related overgrowth spectrum. A patient whose only manifestation is an AKT1 c.49G>A‐positive tumor would receive neither of these designations. Here we review the rational basis of diagnostic criteria and argue that a unitary diagnostic entity is a distinct gene‐phenotype dyad and that this should be the model for all mendelian disorders. The gene‐alone or phenotype‐alone approach is inadequate to rigorously delineate a unitary diagnostic entity.
Promoter Activation in Δhfq Mutants as an Efficient Tool for Specialized Metabolite Production Enabling Direct Bioactivity Testing
Authors: Bode Edna , Heinrich Antje K. , Hirschmann Merle , Abebew Desalegne , Shi Yan‐Ni , Vo Tien Duy , Wesche Frank , Shi Yi‐Ming , Grün Peter , Simonyi Svenja , Keller Nadine , Engel Yvonne , Wenski Sebastian , Bennet Reuel , Beyer Sophie , Bischoff Iris , Buaya Anthony , Brandt Sophie , Cakmak Ibrahim , Çimen Harun , Eckstein Simone , Frank Denia , Fürst Robert , Gand Martin , Geisslinger Gerd , Hazir Selcuk , Henke Marina , Heermann Ralf , Lecaudey Virginie , Schäfer Wilhelm , Schiffmann Susanne , Schüffler Anja , Schwenk Rebecca , Skaljac Marisa , Thines Eckhard , Thines Marco , Ulshöfer Thomas , Vilcinskas Andreas , Wichelhaus Thomas A. , Bode Helge B. 
Published: November 2019

AbstractNatural products (NPs) from microorganisms have been important sources for discovering new therapeutic and chemical entities. While their corresponding biosynthetic gene clusters (BGCs) can be easily identified by gene‐sequence‐similarity‐based bioinformatics strategies, the actual access to these NPs for structure elucidation and bioactivity testing remains difficult. Deletion of the gene encoding the RNA chaperone, Hfq, results in strains losing the production of most NPs. By exchanging the native promoter of a desired BGC against an inducible promoter in Δhfq mutants, almost exclusive production of the corresponding NP from the targeted BGC in Photorhabdus, Xenorhabdus and Pseudomonas was observed including the production of several new NPs derived from previously uncharacterized non‐ribosomal peptide synthetases (NRPS). This easyPACId approach (easy Promoter Activated Compound Identification) facilitates NP identification due to low interference from other NPs. Moreover, it allows direct bioactivity testing of supernatants containing secreted NPs, without laborious purification.
Intermolekulare stereospezifische Substitution von underivatisierten enantiomerenangereicherten sekundären Alkoholen durch Organokatalyse
Authors: Akkarasamiyo Sunisa , Samec Joseph S. M. 
Published: November 2019

AbstractDie stereospezifische Substitution von nicht‐derivatisierten und nicht‐allylischen enantiomerenangereicherten Alkoholen, bei der lediglich Wasser als Beiprodukt anfällt, würde die Verwendung von leicht verfügbaren Alkoholen als Substrat für nachhaltige Transformationen ermöglichen. Die schlechte Abgangsgruppenfähigkeit der OH‐Gruppe hat jedoch die Entwicklung eines solchen Prozesses bislang behindert. Denton und Mitarbeiter beschrieben nun kürzlich die Verwendung von (2‐Hydroxybenzyl)diphenylphosphinoxid als Katalysator einer redoxneutralen und abfallfreien Mitsunobu‐Reaktion. Dieser innovative Prozess stellt die erste intermolekulare stereospezifische Substitution von nicht‐allylischen Alkoholen dar und könnte industrielle Anwendung finden.
Asymmetric Wacker‐Type Oxyallenylation and Azaallenylation of Cyclic Alkenes
Authors: Teng Shenghan , Jiao Zhiwei , Chi Yonggui Robin , Zhou Jianrong Steve 
Published: November 2019

AbstractPalladium‐catalyzed three‐component carboetherification of cyclic alkenes proceeded to give trans adducts exclusively with excellent enantioselectivity through a Wacker‐type pathway. The reaction is also applicable to other oxygen nucleophiles, such as water, phenols, and carboxylic acids, as well as some electron‐poor aryl amines.