bluuebunny/crossref_metadata_2025_split huggingface dataset:
Exploring the role of grafting in abiotic stress management: Contemporary insights and automation trends
Authors: Razi Kaukab , Suresh Preethika , Mahapatra Pritam Paramguru , Al Murad Musa , Venkat Ajila , Notaguchi Michitaka , Bae Dong Won , Prakash Muthu Arjuna Samy , Muneer Sowbiya 
Published: December 2024

AbstractGrafting is a technique that involves attaching a rootstock to the aerial part of another genotype or species (scion), leading to improved crop performance and sustainable growth. The ability to tolerate abiotic stresses depends on cell membrane stability, a reduction in electrolyte leakage, and the species of scion and rootstock chosen. This external mechanism, grafting, serves as a beneficial tool in influencing crop performance by combining nutrient uptake and translocation to shoots, promoting sustainable plant growth, and enhancing the potential yield of both fruit and vegetable crops. Grafting helps to enhance crop production and improve the capacity of plants to utilize water when undergoing abiotic stress, particularly in genotypes that produce high yields upon rootstocks that are capable of decreasing the impact of drought stress on the shoot. The rootstock plays a pivotal role in establishing a grafted plant by forming a union between the graft and the rootstock. This process is characterized by its integrative, reciprocal nature, enabling plants to tolerate abiotic stress conditions. Grafting has been shown to alleviate the overproduction of lipid peroxidation and reactive oxygen species in the leaves and roots and enhance drought tolerance in plants by maintaining antioxidant enzyme activities and stress‐responsive gene expression. Phytohormones, such as cytokinin, auxin, and gibberellin, play a critical role in maintaining rootstock‐scion interactions. This review unveils the role of grafting in mitigating various environmental stressors, establishment of a robust graft junction, physiology of rootstock‐scion communication, the mechanism underlying rootstock influence, hormonal regulations and the utilization of agri‐bots in perfect healing and further cultivation of vegetable crops through grafting.
The impact of body mass index on rehabilitation outcomes after lower limb amputation
Authors: Dubin Andrew , Zarreii Parisa , Sharififar Sharareh , Nixon Ryan M. , Conic Rosalynn R. Z. , Pendem Kailash , Vincent Heather K. 
Published: December 2024

AbstractPurposeTo determine the effect of obesity on physical function and clinical outcome measures in patients who received inpatient rehabilitation services for lower extremity amputation.MethodsA retrospective review was performed on patients with lower extremity amputation (n = 951). Patients were stratified into five categories adjusted for limb loss mass across different levels of healthy body mass index (BMI), overweight, and obesity. Outcomes included the Inpatient Rehabilitation Facility Patient Assessment Instrument functional scores (GG section), discharge home, length of stay (LOS), therapy time, discharge location, medical complications and acute care readmissions. Deep learning neural networks (DLNNs) were developed to learn the relationships between adjusted BMI and discharge home.ResultsThe severely obese group (BMI > 40 kg/m2) demonstrated 7%–13% lower toileting hygiene functional scores at discharge compared to the remaining groups (p < .001). The severely obese group also demonstrated 8%–9% lower sit‐to‐lying and lying‐to‐sitting bed mobility scores than the other groups (both p < .001). Sit‐to‐stand scores were 16%–21% worse and toilet transfer scores were 12%–20% worse in the BMI > 40 kg/m2 group than the other groups (all p < .001). Walking 50 ft with two turns was most difficult for the BMI > 40 kg/m2 group, with mean scores 7%–27% lower than the other BMI groups (p = .011). Wheelchair mobility scores for propelling 150 ft were worst for the severely obese group (4.9 points vs. 5.1–5.5 points for all other groups; p = .021). The LOS was longest in the BMI > 40 group and shortest in the BMI < 25 group (15.0 days vs. 13.3 days; p = .032). Logistic regression analysis indicated that BMI > 40 kg/m2 was associated with lower odds risk (OR) of discharge‐to‐home (OR = 0.504 [0.281–0.904]; p < .022). DLNNs found that adjusted BMI and BMI category were ranked 11th and 12th out of 90 model variables in predicting discharge home.ConclusionPatients with severe obesity (>40 kg/m2) achieved lower functional independence for several tasks and are less likely to be discharged home despite higher therapy volume than other groups. If a patient is going home, obesity will pose unique demands on the caregivers and resources can be put in place to help reintegrate the patient into life.
The Effects of Weekly Levels of Supervisor Support and Workload on Next Week Levels of Well‐Being, Satisfaction, and Performance as Mediated by Weekend Work Recovery
Authors: Cheyroux Pierre , Morin Alexandre J. S. , Colombat Philippe , Blechman Yael , Gillet Nicolas 
Published: December 2024

ABSTRACTThis diary study sought to examine the direct and indirect effects of individuals' perceptions of supervisor support and workload during a work week (week 1) on their well‐being, satisfaction, and performance at work during the following work week (week 2) as mediated through the quality of their weekend work recovery experiences (psychological detachment, relaxation, mastery, and control) and sleep quantity. Moreover, we also investigated the possible interaction between supervisor support and workload in the prediction of weekend recovery experiences and sleep quantity. A sample of 90 second‐year nursing students taking part in a professional internship completed self‐report questionnaires after each of their five working days during week 1 (i.e., supervisor support and workload), then at the end of the day for 2 days during the weekend (i.e., recovery experiences and sleep quantity), and finally after each of their five working days during week 2 (i.e., workplace well‐being, performance, and satisfaction). Our results revealed indirect effects of supervisor support on workplace well‐being and job satisfaction, as mediated by weekend recovery experiences. Workload was also associated with higher levels of sleep quantity during the weekend and had a direct negative association with the levels of satisfaction and well‐being experienced during the following week. Furthermore, workload was associated with better weekend recovery experiences for participants exposed to low levels of supervisor support in week 1. Alternatively, the positive effects of supervisor support on weekend recovery experiences were attenuated as workload levels increased. Theoretical and practical implications of the present study are discussed.
Molecular Engineering of AIE‐Active Photosensitizers with High Biosafety for Effect Extracellular Antibacteria
Authors: Ma Ke , Dong Jianxia , Yan Dingyuan , Wang Deliang , Wang Yuanwei , Wang Jianxing , Wang Dong , Tan Hui , Tang Ben Zhong 
Published: December 2024

AbstractDeveloping versatile photosensitizers to actualize selective antibacteria over normal cells presents an appealing yet significantly challenging task. In this study, a novel photosensitizer named DMMA‐SCPI is rationally designed and facilely synthesized, which is demonstrated as a type‐I photosensitizer featured by aggregation‐induced emission tendency. DMMA‐SCPI is capable of effectively eliminating both Galanz positive bacteria and Galanz negative bacteria in vitro and in vivo, and showed insignificant injury to normal cells and tissues, probably resulting from its pyridinium halide that has stronger adsorption property on negatively charged bacteria compared to normal cells, as well as its suitable antimicrobial activity. The antimicrobial activity of pyridinium salt type photosensitizer depends on the adsorptive activities on the surface of bacterial cells as well as the antimicrobial activity of the reactive oxygen species (ROS). Among three photosensitizers, DMMA‐SCPI has better water solubility, which provides greater surface activity to adsorb bacteria. Moreover, DMMA‐SCPI produces more superoxide anion radicals as ROS, which has proper antimicrobial activity with high biosafety for effect extracellular antibacteria.
High‐Responsivity Self‐Powered Photoelectrochemical UV Photodetector Based on Integrated Self‐Supporting SiC/ZnS Heterojunction Nanowire Arrays
Authors: Zou Bocong , Yang Yang , Wang Hulin , Li Weijun , Wang Lin , Gao Fengmei , Zhang Dongdong , Gloginjić Marko , Erić Marko , Petrović Srdjan , Yang Weiyou , He Huan , Chen Shanliang 
Published: December 2024

AbstractIn the realm of photodetector (PD) technology, photoelectrochemical (PEC) PDs have garnered attention owing to their inherent advantages. Advances in this field depend on functional nanostructured materials, which are pivotal in improving the separation and transport of photogenerated electron–hole pairs to improve device efficiency. Herein, a highly photosensitive PEC UV PD is built using integrated self‐supporting SiC/ZnS heterojunction nanowire array photoelectrodes through anodization and chemical deposition. Compared with the original SiC nanoarrays, the optimized SiC/ZnS‐25 nanoarrays exhibit high photocurrent density (Dph, 809.2 µA cm−2), rapid rise/decay times (τr/τd, 4/21 ms), high responsivity (Rλ, 1.226 A W−1), remarkable detectivity (D*, 2.517 × 1011 Jones), and large external quantum efficiency (EQE, 40.57%) under 375 nm UV light with a bias voltage of 0.6 V. Furthermore, SiC/ZnS‐25 delivers excellent self‐powered performance, with Rλ, D*, and EQE reaching 0.91 A W−1, 1.69 × 1011 Jones, and 30.24%, respectively. In addition, the device exhibits excellent long‐term operation and aging stability under a bias voltage of 0.6 V and under self‐powered conditions. The excellent photodetection behaviors of the SiC/ZnS PEC PD are mainly ascribed to the synergistic effect of the novel well‐aligned nanowire geometry, heterojunction with ZnS nanofilms of optimal thickness, and integrated self‐supporting configuration of the photoelectrode.
An Electrochemical Oxidation and Intercalation Strategy for Iodide Removal Using LDHs
Authors: Guo Xiaomeng , Ren Tengxiao , Zhang Jian , Qiu Shixin , Zhang Wen 
Published: December 2024

AbstractRadioactive iodide harms the ecosystem and human health, necessitating its immobilization to mitigate aquatic iodine pollution. Layered double hydroxides (LDHs), a family of 2D clays with intercalated anions and controllable interlayer structures, are technologically and economically viable adsorbents to eliminate various anion pollutants. However, LDHs exhibit an extremely low affinity toward iodide species. Here, an electrochemical oxidation and intercalation strategy is developed to successfully remove and immobilize iodide using LDHs. The iodide can be transformed into I2/I3− and subsequent IO3− ions on NiFe‐LDH/CC electrode at 0.6 and 1.0 V (vs Ag/AgCl), with an iodine adsorption capacity of 962 and 355 mg g−1, respectively. I2/I3− are adsorbed on the surface of NiFe‐LDH with a weak interaction, while IO3− inserts into the interlayer of LDH with a high affinity due to the strong hydrogen bonding and coordination between IO3− and Ni atoms. This LDH‐based electrochemical removal strategy also has high adaptability to a low iodide concentration, wide pH range, and outstanding ion selectivity. This study can lay the foundation for efficient iodide elimination and immobilization from radioactive liquids.
Dry Bondable Porous Silk Fibroin Films for Embedding Micropatterned Electronics in Hierarchical Silk Nacre
Authors: Xue Jiajin , Cai Duote , Zhang Xiaojing , Qin Chunlian , Yu Xiu , Liu Haitao 
Published: December 2024

AbstractFuture structural materials is not only be lightweight, strong, and tough, but also capable of integrating functions like sensing, adaptation, self‐healing, deformation, and recovery as needed. Although bio‐inspired materials are well developed, directly integrating microelectronic patterns into nacre‐mimetic structures remains challenging, limiting the widespread application of electronic biomimetic materials. Here, an in situ freeze‐drying method is reported for the successful preparation of porous silk fibroin materials that can achieve dry bonding. The in situ freeze‐drying method preserves the structural integrity of the lyophilized membrane while reducing procedural steps, achieving control over pore gradient not feasible with traditional freeze‐drying techniques. By leveraging their smooth surfaces and capacity to support heat transfer patterns, layer‐by‐layer assembly at a macroscopic scale is achieved. The material's excellent mechanical properties, controllable graded structure, and adjustable degradation behavior enable the construction of electronically functionalized hierarchical structures. Additionally, the dry‐state, layer‐by‐layer bonding method for porous polymer films provides advantages in precision control, mechanical stability, functional versatility, hierarchical structuring, and scalability. It represents an innovative approach, offering multi‐functional and customizable bulk materials, especially suited for biomedical applications. This work offers an effective pathway for developing high‐performance and multifunctional biomimetic devices with controllable hierarchical structures.
Adhesion Strategy for Cross‐Linking AgNWs/MXene Janus Membrane: Stretchable and Self‐Healing Electromagnetic Shielding and Infrared Stealth Capabilities
Authors: Bai Yang , Zhang Boyuan , Ma Jiacheng , Cheng Yakun , Cui Peiyu , Kang Yifan , Wu Fan , Chen Chaochan , Huang Wenhuan 
Published: December 2024

AbstractDeveloping lightweight polymer shielding membranes with additional physicochemical properties is of great significance for addressing the complex contemporary security demands. However, precise structural design at the molecular level remains a challenge. Herein, a unique Janus composite membrane is assembled from conductive AgNWs/MXene 1D/2D network and polyurethane elastomer (MPHEA), displaying combined superior electromagnetic shielding effectiveness (EMSE) of up to 80 dB and remarkable infrared stealth capability at a wide temperature range of room temperature to 50 °C. Moreover, the endowed chemical crosslinking in the membrane resulted in the exceptional mechanical strength, self‐healing, and superior adhesion. The maintained electromagnetic shielding (over 20 dB) even under a strain of 40% and the recovered shielding efficiency of 90% after mechanical damage and self‐healing are observed, which is attributed to the synergistic 3D polymer elastic and 1D/2D conductive network in the multi‐dimensional crosslinked MPHEA@AgNWs/MXene composite membrane. This work has represented an excellent micro‐nano structure design strategy on multifunctional electromagnetic wave manager in complex application scenario.
25.91%‐Efficiency and Durable Inverted Perovskite Solar Cells Enabled by a Multifunctional Molecule Mediated Precursor Engineering
Authors: Yao Yuqi , Wang Qi , Chen Xin , Yang Jiewei , Tang Weijian , Xu Xiaopeng , Wu Yihui , Peng Qiang 
Published: December 2024

AbstractThe stability of the precursor is essential for producing high‐quality perovskite films with minimal non‐radiative recombination. In this study, methionine sulfoxide (MTSO), which features multiple electron‐donation sites, is strategically chosen as a precursor stabilizer and crystal growth mediator for inverted perovskite solar cells (PSCs). MTSO stabilizes the precursor by inhibiting the oxidation of iodide ions and passivates charged traps through coordination and hydrogen bonding interactions. This leads to enhanced crystallinity, reduced non‐radiative recombination, and decreased internal residual stress in perovskite film. As a result, remarkable power conversion efficiencies of 25.91% (certified 25.76%) with a minimal voltage deficit of 0.36 V for a 0.09‐cm2 inverted PSC, and 21.96% for a 12.96‐cm2 (active area) perovskite minimodule, have been achieved, respectively. Furthermore, the unencapsulated devices demonstrated excellent long‐term thermal aging and operational stability, retaining over 90% and 92% of their original efficiencies after 500 h of continuous thermal aging at 85 °C and 2500 h of continuous maximum power point tracking under 1 sun (white light LED array) illumination at 30 ± 5 °C. This study underscores the importance of the rational design of functional molecules for stabilizing the precursor and regulating the crystallization of perovskite films, advancing the practical development of PSCs.
Selective Photocatalytic C─H Oxidation Using All‐Inorganic Perovskite Quantum Dots Encapsulated in UiO‐Series MOFs
Authors: Liu Xiyu , Huang Sai , Khoo Rebecca Shu Hui , Huang Lu , Zhu Wenqing , Wang Linjun 
Published: December 2024

AbstractAll‐inorganic cesium lead halide (CsPbX3, X = Cl, Br, I) perovskite quantum dots (PeQDs) are successfully incorporated within the cages of zirconium‐based UiO‐series metal–organic frameworks (MOFs) using in situ ship‐in‐a‐bottle method at room temperature under ambient conditions. The resulting mBPP‐MOF, which includes the 4,4′‐(2,2′‐bipyridyl‐5,5′‐diyl)dibenzoic acid (H2BPP) linker, features a larger cavity size than UiO‐66 and UiO‐67‐bpy, allowing for uniform accommodation of PeQDs within its cages. This PeQDs@MOF hybrid heterostructure enhances the separation and transfer of photogenerated charges, enabling the synthesized CsPbBr3@mBPP‐MOF to demonstrate highly selective and stable performance in the photocatalytic oxidation of toluene under visible light irradiation at 395 nm. This advancement represents a potential breakthrough in organic photocatalysis due to the material's low cost, ease of processing, high efficiency, and tunable bandgap.
Optimierung von aufgeschweißten Lamellen unter Ermüdungsbeanspruchung
Authors: Dürr André , Mensinger Martin , Roth Jakob , Rausch Niclas 
Published: December 2024

AbstractAufgeschweißte Lamellen sind im Brücken‐ und Maschinenbau ein häufig vorkommendes Detail, das zur lokalen Querschnittsverstärkung verwendet wird und somit zur Ausführung wirtschaftlicher Konstruktionen beiträgt. Allerdings weist dieses Kerbdetail ein ungünstiges Ermüdungsverhalten auf und ist daher in vielen Fällen maßgebend beim Ermüdungsnachweis. Im Rahmen des Forschungsprojekts FOSTA P 1413 wurden numerische und experimentelle Untersuchungen an verschiedenen Lamellenformen und ‐ausführungen durchgeführt und auf Grundlage dieser Ergebnisse eine hinsichtlich Ermüdungsverhalten und Fertigungsaufwand optimierte Ausführung entwickelt. Im Rahmen des Beitrags werden die wesentlichen Ergebnisse dieser Untersuchungen und die sich daraus abgeleiteten Empfehlungen hinsichtlich Bemessung und Fertigung vorgestellt.
A general thermodynamical model for finitely-strained continuum with inelasticity and diffusion, its GENERIC derivation in Eulerian formulation, and some application
Authors: Mielke Alexander , Roubíček Tomáš 
Published: December 2024

Abstract
A thermodynamically consistent visco-elastodynamical model at finite strains is derived that also allows for inelasticity (like plasticity or creep), thermal coupling, and poroelasticity with diffusion. The theory is developed in the Eulerian framework and is shown to be consistent with the thermodynamic framework given by General Equation for Non-Equilibrium Reversible-Irreversible Coupling (GENERIC). For the latter we use that the transport terms are given in terms of Lie derivatives. Application is illustrated by two examples, namely volumetric phase transitions with dehydration in rocks and martensitic phase transitions in shape-memory alloys. A strategy toward a rigorous mathematical analysis is only very briefly outlined.
Preclinical comparison of (radio)lanthanides using mass spectrometry and nuclear imaging techniques: biodistribution of lanthanide-based tumor-targeting agents and lanthanides in ionic form
Authors: Wallimann Rahel H. , Mehta Avni , Mapanao Ana Katrina , Köster Ulli , Kneuer Rainer , Schindler Patrick , van der Meulen Nicholas P. , Schibli Roger , Müller Cristina 
Published: December 2024

Abstract

Purpose
With the growing interest in exploring radiolanthanides for nuclear medicine applications, the question arises as to whether they are generally interchangeable without affecting a biomolecule’s pharmacokinetic properties. The goal of this study was to investigate similarities and differences of four (radio)lanthanides simultaneously applied as complexes of biomolecules or in ionic form.

Methods
Inductively coupled plasma mass spectrometry (ICP-MS) was employed for the simultaneous detection of four lanthanides (Ln = lutetium, terbium, gadolinium and europium) in biological samples. In vitro tumor cell uptake and in vivo biodistribution studies were performed with Ln-DOTATATE, Ln-DOTA-LM3, Ln-PSMA-617 and Ln-OxFol-1. AR42J cells, PC-3 PIP cells and KB cells expressing the somatostatin receptor, the prostate-specific membrane antigen and the folate receptor, respectively, were used in vitro as well as to obtain the respective tumor mouse models for in vivo studies. The distribution of lanthanides in ionic form was investigated in immunocompetent mice. Dual-isotope SPECT/CT imaging studies were performed with mice administered with the radiolabeled biomolecules or chloride salts of lutetium-177 and terbium-161.

Results
Similar in vitro cell uptake was observed for all four lanthanide complexes of each biomolecule into the respective tumor cell lines. AR42J tumor uptake of Ln-DOTATATE and Ln-DOTA-LM3 in mice showed similar values for all lanthanide complexes (3.8‒5.1% ID/g and 4.5‒5.0% ID/g; 1 h p.i., respectively). Accumulation of Ln-PSMA-617 in PC-3 PIP tumors (24–25% ID/g; 1 h p.i.) and of Ln-OxFol-1 in KB tumors (28–31% ID/g; 24 h p.i.) were also equal for the four lanthanide complexes of each biomolecule. After injection of lanthanide chloride salts (LnCl3; Ln = natLu, natTb, natGd, natEu), the liver uptake was different for each metal (~ 12% ID/g, ~ 22% ID/g, ~ 31% ID/g and ~ 37% ID/g; 24 h p.i., respectively) which could be ascribed to the radii of the respective lanthanide ions. In the bones, accumulation was considerably higher for lutetium than for other lanthanides (25 ± 5% ID/g vs. 14‒15% ID/g; 24 h p.i.). These data were confirmed visually by 177Lu/161Tb-based dual-isotope SPECT/CT images.

Conclusions
The presented study confirmed similar properties of Ln-complexes, suggesting that lutetium-177 can be replaced by other radiolanthanides, most probably without affecting the tissue distribution profile of the resultant radiopharmaceuticals. On the other hand, the different radii of the lanthanide ions affected their uptake and resorption mechanisms in liver and bones when injected in uncomplexed form.
Acalculous cholecystitis– an imaging and therapeutic update
Authors: Morgan Matthew A , DePietro Daniel M , Whorms Debra S , Pantel Austin R , Ganeshan Dhakshinamoorthy , Goldman Inessa A , Yang Julie , Khot Rachita 
Published: December 2024

AbstractIn this review, we highlight current understanding of the pathogenesis of acalculous cholecystitis, as well as its key imaging and clinical features. We also review what happens after a diagnosis and outline current interventional methods.