bluuebunny/crossref_metadata_2025_split huggingface dataset:
A tool to minimize the need of Monte Carlo ray tracing code for 3D finite volume modelling of a standard parabolic trough collector receiver under a realistic solar flux profile
Authors: Islam Majedul , Saha Suvash C. , Yarlagadda Prasad K. D. V. , Karim Azharul 
Published: June 2020

AbstractThe energy collection element of a parabolic trough collector includes a selective coated metallic receiver tube inside an evacuated glass tube. Perpendicularly incident sun light on the parabolic trough mirror aperture is concentrated on the receiver tube highly nonuniformly along its circular direction. This solar energy is collected as thermal energy circulating a suitable heat transfer fluid (HTF) through the tube. This conjugate heat transfer phenomenon under nonuniform heat flux boundary condition is computationally studied applying 3D finite volume (FV) modelling technique of computational fluid dynamics coupled with Monte Carlo ray tracing (MCRT) optical data. The MCRT model simulates the actual flux profile around the receiver tube. Apart from a FV model, this coupled study requires expertise in, and access to, a suitable MCRT code. A combination of polynomial correlations and user‐defined function (UDF) is introduced in this article in order to minimize the need of MCRT codes from subsequent FV modelling of the receiver tube of the Luz Solar 2 (LS2) collector. The correlations are developed from a verified 3D MCRT model, which is equivalent to the local irradiation data as a function of receiver circular location. The UDF includes two algorithms: one to develop solar flux profile from the correlations around the receiver, and the other to calculate heat loss from the receiver. Interpreting the UDF into ANSYS Fluent, a 3D FV model of the LS2 receiver is developed and validated with experimental results. The effectiveness of the UDF as an alternative to MCRT code is verified. The FV model is capable to investigate the heat transfer characteristics of the LS2 collector receiver at different solar irradiation level, optical properties of the collector components, glass tube conditions, HTFs, inserts or swirl generators, collector length, and internal diameter of the tube.
Research on cross‐well pseudorandom electromagnetic detection method and extraction of response characteristics
Authors: Song Xijin , Momayez Moe , Wang Xuelong , Chen Tao , Dang Feng 
Published: June 2020

AbstractA method is proposed that uses the metal casing of an oil and gas production well to construct a long dipole emission line source and applies pseudorandom multifrequency excitation signals to it to identify reservoir characteristics of interwell reservoirs. This method can significantly improve the work efficiency and precision of electrical prospecting. The cross‐well pseudorandom response signal contains multiple main frequency components, as well as various measuring frequency points. Targeting the frequency components with different amplitudes and initial phases in the pseudorandom signal, the digital coherent detection method and its noise resistance are studied. Using this method can effectively extract the amplitude and phase information of each frequency component in different noise environments and has a strong ability to suppress signals of other frequencies. In the heterogeneous interwell reservoir detection model, the amplitude characteristics of each frequency component of the pseudorandom electromagnetic response at the measuring line with different well spacings are extracted. Numerical results show that the curve of equal‐frequency measurement appears downwardly "concave" at the interface of the low‐resistivity interlayer, and upwardly "convex" at the interface of the high‐resistivity interlayer. With the increase in the resistivity of the low‐resistivity interlayer, the dynamic range of the extraction component of the same frequency decreases gradually, and the family of equal‐frequency response curves overlap with each other. By contrast, for the high‐resistivity interlayer, as its resistivity gradually increases, the dynamic range of the extraction component of same frequency also increases gradually. Moreover, as well spacing varies, the response characteristics of the equal‐frequency curve family on different measuring lines are also obviously different. The digital coherent detection method significantly simplifies the receiving circuit system. In practical application, response information of different discrete frequency components can be extracted according to requirements. This thus provides a theoretical basis for the extraction of resistivity and characteristic identification of interwell heterogeneous oil and gas reservoirs.
Three‐dimensional antidunes coexisting with alternate bars
Authors: Inoue Takuya , Watanabe Yasunori , Iwasaki Toshiki , Otsuka Junichi 
Published: June 2020

AbstractAntidunes are fluvial bedforms that form in rivers with supercritical flows. The water surface over antidunes is strongly in phase with the bed surface, and the water surface is amplified to produce large surface waves. Many experimental studies have addressed antidunes; however, the shapes of three‐dimensional antidunes in a wide channel with alternate bars have not yet been appropriately understood. In this study, we experimentally investigated the streamwise and transverse length scales of antidunes under conditions with a large width–depth ratio. Our experimental results provide evidence for the coevolution of antidunes and free alternate bars, and show for the first time that the development of free bars greatly alters the three‐dimensional shape of water surface waves over antidunes. In the absence of free bars in a wide channel, multiple longitudinal wave trains form, and the number of wave trains counted in the transverse direction increases with increases in the width–depth ratio. However, the presence of free bars affects the local flow characteristics, resulting in a decrease of the number of wave trains in the transverse direction. Therefore, we propose a simple model for predicting the reduction in the number of wave trains by combining two previous theories for antidunes and free bars. Results obtained by the model were found to largely agree with experimental observations. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd
Grain‐energy release governs mobility of debris flow due to solid–liquid mass release
Authors: Cao Zhixian , Li Ji , Borthwick Alistair , Liu Qingquan , Pender Gareth 
Published: June 2020

AbstractDebris flows often exhibit high mobility, leading to extensive hazards far from their sources. Although it is known that debris flow mobility increases with initial volume, the underlying mechanism remains uncertain. Here, we reconstruct the mobility–volume relation for debris flows using a recent depth‐averaged two‐phase flow model without evoking a reduced friction coefficient, challenging currently prevailing friction‐reduction hypotheses. Physical experimental debris flows driven by solid–liquid mass release and extended numerical cases at both laboratory and field scales are resolved by the model. For the first time, we probe into the energetics of the debris flows and find that, whilst the energy balance holds and fine and coarse grains play distinct roles in debris flow energetics, the grains as a whole release energy to the liquid due to inter‐phase and inter‐grain size interactions, and this grain‐energy release correlates closely with mobility. Despite uncertainty arising from the model closures, our results provide insight into the fundamental mechanisms operating in debris flows. We propose that debris flow mobility is governed by grain‐energy release, thereby facilitating a bridge between mobility and internal energy transfer. The initial volume of debris flow is inadequate for characterizing debris flow mobility, and a friction‐reduction mechanism is not a prerequisite for the high mobility of debris flows. By contrast, inter‐phase and inter‐grain size interactions play primary roles and should be incorporated explicitly in debris flow models. Our findings are qualitatively encouraging and physically meaningful, providing implications not only for assessing future debris flow hazards and informing mitigation and adaptation strategies, but also for unravelling a spectrum of earth surface processes including heavily sediment‐laden floods, subaqueous debris flows and turbidity currents in rivers, reservoirs, estuaries, and ocean. © 2020 John Wiley & Sons, Ltd.
Beyond cell parameters: Exploiting cell operation towards optimizing the SEI and suppressing dendrite growth on lithium metal anodes
Authors: Patino Daisy , Dong Bo , Villalobos Fabian , Herrera Steven , Bell Jeffrey , Ozkan Mihrimah , Ozkan Cengiz S. 
Published: June 2020

AbstractLithium metal electrodes are regarded as the optimal anode for next generation lithium ion batteries especially in the lithium‐sulfur architecture. Unfortunately, the lithium metal anode falls subject to several challenges such as dendrite formation and low Coulombic efficiency, which inhibit its candidacy as a viable technology. As such, substantial research efforts alter cell parameters in effort to manipulate interfacial chemistries, mitigate dendrite growth, and improve cyclability. Unlike conventional efforts, we demonstrate a practical cell operation approach to reinforce the Solid Electrolyte Interphase in lithium anodes via a refined formation protocol governed by the redox reactions found in lithium‐sulfur systems. Galvanostatic and electrochemical impedance data on Li‐Li symmetrical cells reveal that cell operation during the formation phase plays a critical role on interface stability of lithium metal anodes. Li‐Li symmetrical cells subject to our refined protocol, P2, displayed advantages in steadily enduring high cycling currents of 6 mA with minimal polarization, and in lowering the charge transfer resistance at the cell interfaces by a fourfold when compared to cells subject to conventional formation protocols. Additionally, scanning electron microscopy images demonstrate that our formation protocol significantly minimizes the size and dispersion of lithium dendrites, as well as the degree of plated lithium. These effects are enabled by the reinforced SEI formed during P2 which offers a stable ratio between the rates of lithium intercalation to lithium deposition. Microcomputerized tomography characterization further supports these findings by revealing that P2 averts dendrite nucleation sites, and yields greater quantity of SEI species, encompassing 41.1% volume of the entire anode, compared to just 21.5% from the common formation protocol found in literature. Overall, this approach deviates from the convention of materials exploration yet highlights the importance of understanding the nature of interfacial chemistries in response to cell operation. We believe the transferability of this approach has the potential to expedite the commercialization of next‐generation lithium ion technologies.
Hydrogen Atom Transfer Reaction Free Energy as a Predictor of Abiotic Nitroaromatic Reduction Rate Constants: A Comprehensive Analysis
Authors: Di Toro Dominic M. , Hickey Kevin P. , Allen Herbert E. , Carbonaro Richard F. , Chiu Pei C. 
Published: June 2020

Abstract
A linear free energy model is presented that predicts the second-order rate constant for the abiotic reduction of nitroaromatic compounds (NACs). Previously presented models use the one-electron reduction potential EH1(ArNO2) of the NAC reaction ArNO2+e−→ArNO2•−. If EH1(ArNO2) is not available, it has been proposed that EH1(ArNO2) be computed directly or estimated from the gas-phase electron affinity (EA). The model proposed uses the Gibbs free energy of the hydrogen atom transfer (HAT) reaction ArNO2+H•→ArNOOH• as the parameter in the linear free energy model. Both models employ quantum chemical computations for the required thermodynamic energies. The available and proposed models are compared using experimentally determined second-order rate constants from 5 investigations from the literature in which a variety of NACs were exposed to a variety of reductants. A comprehensive analysis utilizing all the NACs and reductants demonstrate that the HAT energy model and the experimental one-electron reduction potential model have similar root mean square errors and residual error probability distributions. In contrast, the model using the computed EA has a more variable residual error distribution with a significant number of outliers. The results suggest that a linear free energy model utilizing computed HAT reaction free energy produces a more reliable prediction of the NAC abiotic reduction second-order rate constant than previously available methods. The advantages of the proposed HAT energy model and its mechanistic implications are discussed as well. Environ Toxicol Chem 2020;39:1678–1684. © 2020 SETAC
Histological and Behavioral Toxicity of Tributyltin in the Tropical Guppy Poecilia vivipara
Authors: de Paulo Driele Ventura , Mariz Célio Freire , de Melo Alves Maria Karolaine , Alves Romulo Nepomuceno , Batista Rodrigo Moço , Fillmann Gilberto , Carvalho Paulo S.M. 
Published: June 2020

Abstract
The tropical estuarine guppy Poecilia vivipara was used to address fish early life stage toxicity caused by the antifouling contaminant tributyltin. Six-day-old P. vivipara were exposed for 7 d to control water and waterborne tributyltin at 15.8, 83.8, 716, and 818 ng tin (Sn) L–1. After exposure, swimming, feeding, growth, and eye histological endpoints were evaluated. Histopathological analysis of the retinal pigment epithelium (RPE) indicated alterations in pigment positioning at all tributyltin concentrations. A dose-dependent increase in photoreceptor layer disorganization and iris melanin hyperpigmentation was verified, and high frequencies of RPE invaginations and iris epithelial cell atrophy were observed even at the lowest exposure concentration of 15.8 ng Sn L–1. At the highest exposure level (818 ng Sn L–1) fish also presented reductions in swimming speed, swimming resistance, daily capture of Artemia nauplii, and growth in weight of 85, 60, 33, and 56% relative to controls, respectively. This association between retinal histopathology and reduced swimming and foraging behavior can reduce recruitment to the adult population. Environ Toxicol Chem 2020;39:1953–1963. © 2020 SETAC
Use of Zinc Carbonate Spiking to Obtain Phytotoxicity Thresholds Comparable to Those in Field-Collected Soils
Authors: Grigorita Gabriela , Neaman Alexander , Brykova Ramilla , Brykov Vasyl A. , Morev Dmitry V. , Ginocchio Rosanna , Paltseva Anna A. , Vidal Kooichi , Navarro-Villarroel Claudia , Dovletyarova Elvira A. 
Published: June 2020

Abstract
Several studies have reported the presence of smithsonite (ZnCO3) in soils polluted by zinc mining. The present study aimed to determine upper critical threshold values of Zn phytotoxicity in a substrate spiked with ZnCO3 and to compare them with those obtained in field-collected soils. We studied Zn toxicity to perennial ryegrass (Lolium perenne L.) grown in pots with unpolluted peat treated with increasing concentrations of ZnCO3 that produced nominal total Zn concentrations of 0, 0.7, 1.3, 2.0, 2.6, and 3.3%. To keep constant near-neutral pH value in all the treatments, we used decreasing concentrations of dolomitic lime. In the treatment with total soil Zn of 3.3% (pH 6.8), the foliar Zn concentration of L. perenne was 1914 ± 211 mg kg–1, falling into the range of 2400 ± 300 mg kg–1 reported for Lolium species grown under similar laboratory conditions in a polluted soil (total soil Zn 5.4%, pH 7.3) collected near a Zn smelter. The value of 92 ± 98 mg kg–1 was obtained for the median effective concentration (EC50) values of 0.01 M KNO3-extractable Zn using the responses of shoot dry biomass, shoot length, and total pigments. This value falls within the range of 95 ± 46 mg kg–1 reported in other studies for the EC50 values of salt-extractable Zn using field-collected soils. The application of ZnCO3 for spiking was able to mimic foliar Zn concentrations of Lolium species observed in field-collected soils. The effective concentrations of soil Zn obtained in the present study are comparable to those obtained in field-collected soils. Future research should determine effective concentrations of metals using soils spiked with metal-containing compounds that mimic a real source of contamination. Environ Toxicol Chem 2020;39:1790–1796. © 2020 SETAC
Testing for knowledge: Application of machine learning techniques for prediction of flashover in a 1/5 scale ISO 13784‐1 enclosure
Authors: Dexters Arjan , Leisted Rolff Ripke , Van Coile Ruben , Welch Stephen , Jomaas Grunde 
Published: June 2020

AbstractA machine learning algorithm was applied to predict the onset of flashover in archival experiments in a 1/5 scale ISO 13784‐1 enclosure constructed with sandwich panels. The experiments were performed to assess whether a small‐scale model could provide a better full‐scale correlation than the single burning item test. To predict the binary output, a regularized logistic regression model was chosen as ML environment, for which lasso‐regression significantly reduced the amount of variance at a negligible increase in bias. With the regularized model, it was possible to discern the predictive variables and determine the decision boundary. In addition, a methodology was put forward on how to use the to update the learning algorithm iteratively. As a result, it was shown how a learning algorithm can be used to facilitate ongoing experimentation. At first as a crude guideline, and in later stages, as an accurate prediction algorithm. It is foreseen that, by iteratively updating the algorithm, by compiling existing and new experiments in databases, and by applying fire safety knowledge, the final learned algorithm will be able to make accurate predictions for unseen samples and test conditions.
Optimization of beef broth processing technology and isolation and identification of flavor peptides by consecutive chromatography and LC‐QTOF‐MS/MS
Authors: Wang Linhan , Qiao Kaina , Huang Yan , Zhang Yuyu , Xiao Junfei , Duan Wen 
Published: June 2020

AbstractTo investigate the flavor peptides of beef broth obtained under optimized stewing conditions, separation procedures such as ultrafiltration, Sephadex G‐15 column chromatography, and reversed‐phase high‐performance liquid chromatography were employed to isolate the umami taste peptides. Sensory evaluation was combined with liquid chromatography–mass spectrometry to detect the flavor peptides. The optimization of the stewing process conditions was studied using the orthogonal method, which indicated that time had the most significant effect on the taste efficiency of sensory evaluation, followed by the mixed spices, sucrose, and salt. The optimized cooking conditions included 3.5 hr of cooking time, 1.800 g of sucrose, 2.125 g of salt, and 1.500 g of mixed spices. The results showed that six peptides, including SDEEVEH, AEVPEVH, GVDNPGHP, GSDGSVGPVGP, SDGSVGPVGP, and DEAGPSIVH, were detected in sample X1M1; and seven peptides, including VAPEEHPT, VVSNPVDIL, VGGNVDYK, PFGNTHN, EAGPSIVHR, VDFDDIQK, and DEAGPSIVH, were detected in sample X2M2. This study compared the flavor peptides in stewed beef before and after the optimization, and thus provided a basis for the improvement of beef processing technology.
Frequency and prognostic impact of PAX5 p.P80R in pediatric acute lymphoblastic leukemia patients treated on an AIEOP‐BFM acute lymphoblastic leukemia protocol
Authors: Jung Mareike , Schieck Maximilian , Hofmann Winfried , Tauscher Marcel , Lentes Jana , Bergmann Anke , Stelter Marie , Möricke Anja , Alten Julia , Schlegelberger Brigitte , Schrappe Martin , Zimmermann Martin , Stanulla Martin , Cario Gunnar , Steinemann Doris 
Published: June 2020

AbstractPAX5 is a member of the paired box (PAX) family of transcription factors involved in B‐cell development. PAX5P80R has recently been described as a distinct genetic B‐cell precursor (BCP) acute lymphoblastic leukemia (ALL) subtype with a favorable prognosis in adults. In contrast, an unfavorable outcome has been observed in children. Our aim was to determine the frequency of PAX5P80R in childhood BCP‐ALL treated according to the Associazione Italiana Ematologia ed Oncologia Pediatrica‐Berlin‐Frankfurt‐Muenster (AIEOP‐BFM) ALL 2000 protocol and to evaluate its clinical significance within this study cohort. The analyses included 1237 patients with ALL treated in the AIEOP‐BFM ALL 2000 trial with complete information for copy number variations (CNVs) of IKZF1, PAX5, ETV6, RB1, BTG1, EBF1, CDKN2A, CDKN2B, and ERG. A customized TaqMan genotyping assay was used to screen for PAX5P80R. Sanger sequencing was used to confirm PAX5P80R‐positive results as well as to screen for second variants in PAX5. Agilent CGH + SNP arrays (e‐Array design 85 320; Agilent Technologies) were performed in PAX5P80R‐positive patients to verify additional CNVs. Almost 2% (20/1028) of our BCP‐ALL cohort were PAX5P80R‐positive. White blood cell counts higher than 50 000/μl as well as male sex were significantly (P < .05) associated with PAX5P80R. Most of the PAX5P80R‐positive cases were 10 years of age or older. PAX5P80R‐positive samples were enriched for deletions affecting PAX5, IKZF1, CDKN2A, and CDKN2B. Compared to PAX5P80R‐wildtype BCP‐ALL, PAX5P80R‐positive patients showed a significantly reduced 5‐year overall survival (P = .042). Further studies should evaluate the interaction of PAX5P80R with other genetic aberrations to further stratify intermediate risk pediatric BCP‐ALL.
Invasive versus non‐invasive mapping of the motor cortex
Authors: Weiss Lucas Carolin , Nettekoven Charlotte , Neuschmelting Volker , Oros‐Peusquens Ana‐Maria , Stoffels Gabriele , Viswanathan Shivakumar , Rehme Anne K. , Faymonville Andrea Maria , Shah N. Jon , Langen Karl Josef , Goldbrunner Roland , Grefkes Christian 
Published: June 2020

AbstractPrecise and comprehensive mapping of somatotopic representations in the motor cortex is clinically essential to achieve maximum resection of brain tumours whilst preserving motor function, especially since the current gold standard, that is, intraoperative direct cortical stimulation (DCS), holds limitations linked to the intraoperative setting such as time constraints or anatomical restrictions. Non‐invasive techniques are increasingly relevant with regard to pre‐operative risk‐assessment. Here, we assessed the congruency of neuronavigated transcranial magnetic stimulation (nTMS) and functional magnetic resonance imaging (fMRI) with DCS. The motor representations of the hand, the foot and the tongue regions of 36 patients with intracranial tumours were mapped pre‐operatively using nTMS and fMRI and by intraoperative DCS. Euclidean distances (ED) between hotspots/centres of gravity and (relative) overlaps of the maps were compared. We found significantly smaller EDs (11.4 ± 8.3 vs. 16.8 ± 7.0 mm) and better spatial overlaps (64 ± 38% vs. 37 ± 37%) between DCS and nTMS compared with DCS and fMRI. In contrast to DCS, fMRI and nTMS mappings were feasible for all regions and patients without complications. In summary, nTMS seems to be the more promising non‐invasive motor cortex mapping technique to approximate the gold standard DCS results.