bluuebunny/crossref_metadata_2025_split huggingface dataset:
ГОТОВНОСТЬ ГРАЖДАН К УЧАСТИЮ В КОРРУПЦИОННЫХ ДЕЙСТВИЯХ БЫТОВОЙ НАПРАВЛЕННОСТИ В СВЕТЕ ТЕОРИИ СТРУКТУРАЦИИ Э. ГИДДЕНСА
Authors: ВАТОРОПИН А.С. , ЧЕВТАЕВА Н.Г. , ВАТОРОПИН С.А. 
Published: December 2024

В статье исследуется одна из детерминант бытовой коррупции в современном российском обществе — осознанная готовность граждан к участию в коррупционных действиях. Проанализированы основные теоретические подходы, традиционно используемые при рассмотрении этой проблемы в отечественной и зарубежной научной литературе. С учетом неоднозначных результатов борьбы с бытовой коррупцией в современном обществе в статье поставлена цель применить для исследования указанной детерминанты данного негативного феномена еще один подход, в основе которого лежит теория структурации известного англий- ского социолога Э. Гидденса. Для анализа полученных авторами результатов эмпирического социологического исследования бытовой коррупции в Свердловской области апробирована стратификационная модель агента, разработанная Э. Гидденсом. Сделан вывод о возможно- сти изменения в положительную сторону одного из компонентов сознания рядовых граждан, потенциально готовых участвовать в коррупционных действиях, — теоретического сознания, что может помочь в формировании антикоррупционных установок у населения.
The article examines one of the determinants of everyday corruption in modern Russian society — the conscious readiness of citizens to participate in corrupt practices. The main theoretical approaches traditionally used in considering this problem in domestic and foreign scientific literature are analyzed. Taking into account the ambiguous results of the fight against everyday corruption in modern society, the article aims to apply another approach to the study of this determinant of this negative phenomenon, which is based on the theory of structuring by the famous English sociologist E. Giddens. To analyze the results of the empirical sociological study of everyday corruption in the Sverdlovsk region obtained by the authors, the stratification model of the agent developed by E. Giddens was tested. A conclusion is made about the possibility of changing for the positive one of the components of the consciousness of ordinary citizens potentially ready to participate in corrupt practices — theoretical consciousness, which can help in the formation of anti-corruption attitudes among the population.
ФАКТОРЫ БРАЧНОГО ВЫБОРА ЖИТЕЛЕЙ Г. ИВАНОВО: ПОКОЛЕНЧЕСКИЙ
Authors: ЗВОНАРЕВА А.Е. 
Published: December 2024

В данной статье подвергнуты сравнительному анализу факторы брачного выбора по- колений X и Z, выявлены особенности факторов брачного выбора поколений X и Z, предложен опросник для вступающих в брак. В введении обозначена актуальность выбранной темы. Исследование факторов брачного выбора было проведено в г. Иваново, в мае 2024 года при помощи метода формализованного и неформализованного интервью (неформализованное, глубинное интервью было использовано в качестве пилотажного метода исследования). Объем выборочной совокупности составил 204 человека. Объектом исследования выступили жители г. Иваново поколений X (1965–80 гг.) и Z (1997–2007 гг.). Предметом исследования стали факторы брачного выбора жителей г. Иваново: поколенче- ский аспект. Цель исследования: изучить факторы брачного выбора поколений X (1965–80 гг.) и Z (1997–2007 гг.) на примере жителей г. Иваново. Результаты проведенного исследования представлены в данной статье.
The article is dedicated to a comparative analysis of factors of marriage choice of generations X and Z, reveals the characteristics of the factors of marriage choice of generations X and Z. Article offers a questionnaire for those entering into marriage. The introduction indicates the relevance of the selected topic. The study of factors of marriage choice was conducted in Ivanovo in May 2024 using the method of formalized and informal interviews (an informal interview was used as a pilot research method). The sample size was 204 people. The object of the study were residents of the city of Ivanovo of generations X (1965–80) and Z (1997–2007). The subject of the study was the factors of marriage choice of residents of Ivanovo. The aim of the study: to study the factors of marriage choice of generations X (1965–80) and Z (1997–2007) using the example of residents of the city of Ivanovo. The results of the study are presented in this article.
Stakeholders’ Training Initiatives by Neo-Pentecostal Churches can Alleviate Domestic Water Scarcity in Tigania West Constituency
Authors: Atheru, PhD Kiambi James Thambura , Gichohi, PhD Paul 
Published: December 2024

Church teachings and doctrines are expected to be all-inclusive. Therefore, Neo-Pentecostal Churches (NPCs) in Tigania West should incorporate water stakeholder training into their spiritual and community responsibilities. By partnering with NGOs, Bible schools, and technical institutions, NPCs can equip leaders with skills in sustainable water management to address domestic water scarcity, improve access, reduce diseases, and enhance livelihoods. This study explored the training initiatives for water stakeholders by Neo-Pentecostal churches on alleviation of domestic water scarcity in Tigania West constituency, where 97% of the population faces severe water challenges. Despite biblical mandates in Matthew 28:20 and Ezekiel 34:17-19, which call for addressing both spiritual and practical needs, NPCs however perceive water stakeholder training as outside their biblical mandate. This narrow focus on spiritual matters highlights a gap in their involvement in addressing water scarcity menace. Using the Theological Reflection Theory, the study adopted a qualitative approach and phenomenological research design. It targeted 22 registered NPCs in Tigania West, with a sample of 59 participants who were sampled using cluster sampling technique. Respondents were pastors and church members. Data was collected through interviews, focus group discussions, and document analysis, with pre-testing ensuring validity and reliability. Thematic analysis technique was applied to analyze the collected data. Findings revealed that NPCs lacked formal water management training programs, although some churches expressed interest in vocational initiatives like rainwater harvesting and infrastructure development. The study concluded that NPCs’ limited engagement with water scarcity represents a missed opportunity to align spiritual teachings with community development. The study recommends collaboration of NPCs, Faith-Based Organizations (FBOs), NGOs, and Bible schools, with technical institutions in organizing workshops, seminars, and other capacity-building initiatives regarding water management and access. These initiatives would provide practical knowledge on water catchment protection, rainwater harvesting, and infrastructure development, thus enhancing NPCs' role in bridging faith and social responsibility.
On the role of the prosecutor in protecting the labor rights of minors
Authors: Usov Aleksei Yur'evich , Nesterova Natal'ya Aleksandrovna 
Published: December 2024

The subject of the research is the prosecutor's protection of the labor rights of minors. The authors of the article investigate not only the features of prosecutorial supervision over the observance of labor rights of citizens under the age of 18, but also analyze other types of prosecutorial activities in this area. The paper pays attention to the specifics and legal grounds for the participation of prosecutors in the consideration of labor disputes by the courts. Proposals have been formulated on the specifics of the implementation of legal education by prosecutors among employers, as well as underage workers. In order to distinguish between the subject of prosecutorial supervision and the competence of state control bodies in the studied area, the issues that are subject to verification by the prosecutor are reflected, and the limits of prosecutorial activity are outlined. In the course of the study, the authors applied the method of statistical analysis of data on the number of violations of the labor rights of minors identified by prosecutors. Comparing this information with data on the number of claims filed by prosecutors allowed us to establish that the number of cases of prosecutors send to courts is relatively small. The scientific novelty of the research lies in the systematization of knowledge about the role of the prosecutor in protecting the labor rights of minors. The paper also formulated separate proposals for improving this type of prosecutorial activity. In particular, a legal justification has been developed for the prosecutor's right to bring the cases to court in order to protect the labor rights of a minor employee, even in cases where the minor himself does not want to file a written application with the prosecutor's office, but the violation of his labor rights is significant. In addition, the research contains proposals to tighten administrative responsibility for violations of the labor rights of minors.
Prognostic value of inflammatory and nutritional indexes among patients with unresectable advanced gastric cancer receiving immune checkpoint inhibitors combined with chemotherapy—a retrospective study
Authors: Zhu Meiqin , Zhang Lin-Ting , Lai Wenjuan , Yang Fang , Zhou Danyang , Xu Ruilian , Tong Gangling 
Published: December 2024

Background
Recent studies have revealed that inflammatory factors and nutritional status of patients with advanced gastric cancer (AGC) are related to the efficacy of drug therapy and patient prognosis. This study seeks to evaluate the correlation between inflammatory markers, nutritional status, and clinical outcomes of immune checkpoint inhibitor (ICI)-based therapies among inoperable AGC patients.

Method
This retrospective study included 88 AGC patients who received ICIs combined with chemotherapy. Inflammatory and nutritional indicators from patients before and after two cycles of treatment were collected. Finally, the correlations between these indicators and the clinical response and survival of AGC patients with ICI treatment were examined.

Results
The results revealed that an Eastern Cooperative Oncology Group performance status (ECOG PS) score of 0, neutrophil count to lymphocyte count ratio (NLR) < 2.84, platelet count to lymphocyte count ratio (PLR) < 82.23, lymphocyte count to monocyte count ratio ≥ 2.35, the hemoglobin, albumin, lymphocyte and platelet score (HALP) ≥ 31.17, prognostic nutritional index (PNI) ≥ 46.53, albumin ≥ 41.65, the decreased HALP group and the decreased PNI group were significantly correlated with improved objective response rate. Additionally, an ECOG PS score of 0, NLR < 2.84 and the decreased HALP group was associated with a superior disease control rate. Meanwhile, an ECOG PS score of 0 (progression-free survival (PFS): P = 0.003; overall survival (OS): P = 0.001) and decreased PLR following treatment (PFS: P = 0.011; OS: P = 0.008) were significant independent predictors of PFS and OS. Lastly, a systemic immune inflammation index ≥ 814.8 was also a positive independent predictor of OS among AGC patients.

Conclusion
Our study supports the potential of inflammatory and nutritional factors to serve as predictors of the efficacy and prognosis in patients undergoing ICI-based therapies for AGC. However, further investigations are necessary to validate these findings.
Recent Advances in the Stereoselective Additions of Allylic Boronates to Carbonyl Compounds
Authors: Clement Helen A. , Hall Dennis G. 
Published: January 2020

Abstract
The addition of allylboronates to carbonyl compounds remains an invaluable transformation in synthetic organic chemistry for the stereoselective synthesis of a wide variety of substituted homoallylic alcohols. The use of allylboronates is an exceptionally attractive tool, in part due to the stability of organoboron nucleophiles and the inherently high and predictable stereoselectivity consistently observed. Herein, key advances regarding the thermal and catalyzed allylboration of aldehydes and ketones from the past decade are summarized, with a focus on aspects concerning the scope, mechanism, and stereoselectivity. Notably, novel modes of activation are described for both enantioenriched α‐substituted allylboronates and catalytic enantioselective additions of achiral boronates using chiral protic acids and organocatalysts. A number of innovative metal‐catalyzed enantioselective borylation approaches to allylboronates and their subsequent use as substrates, including bimetallic double allylation reagents, are also highlighted. The current innovative progress and limitations in the field of carbonyl allylboration are discussed.
Bioinspired Biomaterials with a Brick‐and‐Mortar Microstructure Combining Mechanical and Biological Performance
Authors: Li Tian , Ma Bing , Xue Jianmin , Zhai Dong , Zhao Pengyu , Chang Jiang , Wu Chengtie 
Published: January 2020

AbstractThe fabrication of bone regeneration biomaterials, which simultaneously possess superior mechanical performances and excellent bioactivity, remains challenging because these properties are usually mutually exclusive. Herein, inspired by the brick‐and‐mortar architecture of nacre, lamellar silicate‐based bioceramic composites are successfully prepared by constructing orderly layered bioceramics infiltrated with a biomedical resin interlayer via the bidirectional freezing technique. The lamellar composites possess high strength and proper Young's moduli, which match with human cortical bone. Furthermore, the lamellar composites can release bioactive ions with a controlled profile, which significantly enhance the cell proliferation of both rabbit bone mesenchymal stem cells and periodontal ligament cells in vitro. Moreover, with the degradation of silicate bioceramics in vivo, newly formed bone tissue can grow into the materials to present the bioceramic/new bone/resin sandwich‐like lamellar microstructure. The silicate‐based bioceramic composites with brick‐and‐mortar architecture represent an excellent biomaterial in combination of superior mechanical performances matching that of human cortical bone, and excellent bioactivity for potential load‐bearing bone regeneration.
Cyber–Physiochemical Interfaces
Authors: Wang Ting , Wang Ming , Yang Le , Li Zhuyun , Loh Xian Jun , Chen Xiaodong 
Published: January 2020

AbstractLiving things rely on various physical, chemical, and biological interfaces, e.g., somatosensation, olfactory/gustatory perception, and nervous system response. They help organisms to perceive the world, adapt to their surroundings, and maintain internal and external balance. Interfacial information exchanges are complicated but efficient, delicate but precise, and multimodal but unisonous, which has driven researchers to study the science of such interfaces and develop techniques with potential applications in health monitoring, smart robotics, future wearable devices, and cyber physical/human systems. To understand better the issues in these interfaces, a cyber–physiochemical interface (CPI) that is capable of extracting biophysical and biochemical signals, and closely relating them to electronic, communication, and computing technology, to provide the core for aforementioned applications, is proposed. The scientific and technical progress in CPI is summarized, and the challenges to and strategies for building stable interfaces, including materials, sensor development, system integration, and data processing techniques are discussed. It is hoped that this will result in an unprecedented multi‐disciplinary network of scientific collaboration in CPI to explore much uncharted territory for progress, providing technical inspiration—to the development of the next‐generation personal healthcare technology, smart sports‐technology, adaptive prosthetics and augmentation of human capability, etc.
A High‐Kinetics Sulfur Cathode with a Highly Efficient Mechanism for Superior Room‐Temperature Na–S Batteries
Authors: Yan Zichao , Liang Yaru , Xiao Jin , Lai Weihong , Wang Wanlin , Xia Qingbing , Wang Yunxiao , Gu Qinfen , Lu Huanming , Chou Shu‐Lei , Liu Yong , Liu Huakun , Dou Shi‐Xue 
Published: January 2020

AbstractApplications of room‐temperature–sodium sulfur (RT‐Na/S) batteries are currently impeded by the insulating nature of sulfur, the slow redox kinetics of sulfur with sodium, and the dissolution and migration of sodium polysulfides. Herein, a novel micrometer‐sized hierarchical S cathode supported by FeS2 electrocatalyst, which is grown in situ in well‐confined carbon nanocage assemblies, is presented. The hierarchical carbon matrix can provide multiple physical entrapment to polysulfides, and the FeS2 nanograins exhibit a low Na‐ion diffusion barrier, strong binding energy, and high affinity for sodium polysulfides. Their combination makes it an ideal sulfur host to immobilize the polysulfides and achieve reversible conversion of polysulfides toward Na2S. Importantly, the hierarchical S cathode is suitable for large‐scale production via the inexpensive and green spray‐drying method. The porous hierarchical S cathode offers a high sulfur content of 65.5 wt%, and can deliver high reversible capacity (524 mAh g−1 over 300 cycles at 0.1 A g−1) and outstanding rate capability (395 mAh g−1 at 1 A g−1 for 850 cycles), holding great promise for both scientific research and real application.
Atomic Layer Deposition of ZnO on InP Quantum Dot Films for Charge Separation, Stabilization, and Solar Cell Formation
Authors: Crisp Ryan W. , Hashemi Fatemeh S. M. , Alkemade Jordi , Kirkwood Nicholas , Grimaldi Gianluca , Kinge Sachin , Siebbeles Laurens D. A. , van Ommen J. Ruud , Houtepen Arjan J. 
Published: January 2020

AbstractTo improve the stability and carrier mobility of quantum dot (QD) optoelectronic devices, encapsulation or pore infilling processes are advantageous. Atomic layer deposition (ALD) is an ideal technique to infill and overcoat QD films, as it provides excellent control over film growth at the sub‐nanometer scale and results in conformal coatings with mild processing conditions. Different thicknesses of crystalline ZnO films deposited on InP QD films are studied with spectrophotometry and time‐resolved microwave conductivity measurements. High carrier mobilities of 4 cm2 (V s)−1 and charge separation between the QDs and ZnO are observed. Furthermore, the results confirm that the stability of QD thin films is strongly improved when the inorganic ALD coating is applied. Finally, proof‐of‐concept photovoltaic devices of InP QD films are demonstrated with an ALD‐grown ZnO electron extraction layer.
Direct‐Ink Written Shape‐Morphing Film with Rapid and Programmable Multimotion
Authors: Mao Zhengyi , Zhu Kunkun , Pan Lulu , Liu Guo , Tang Tao , He Yunhu , Huang Jianpan , Hu Jinlian , Chan Kannie W. Y. , Lu Jian 
Published: January 2020

AbstractShape‐morphing structures are appealing in the material community to inspire a myriad of applications across domains, including soft robots, tissue engineering, and consumer products. However, it is a challenge to create fast response/recovery actuators with complicated and robust deformation due to the slow diffusion speed of water in hydrogel and small modulus of hydrogel. Herein, a facile strategy is proposed to fabricate a versatile patterned film configuration using chitin and poly(dimethylsiloxane) (PDMS). The direct‐ink writing (DIW) technique is leveraged to build simple, flat, patterned films, which can be morphed into complicated multidimensional architectures. Additionally, computational simulations are conducted to predict the deformation behaviors of the actuator. The sequential response structure can be precisely manipulated by the actuation speed of different structures. Moreover, an assembling method is proposed to create multifunction actuators.
Organic Functional Molecule‐Based Single‐Crystalline Nanowires for Optical Waveguides and Their Patterned Crystals
Authors: Zhang Xiao , Wu Jun‐Jie , Gao Hanfei , Zhao Yuyan , Qi Weiheng , Feng Jiangang , Wang Xue‐Dong , Wu Yuchen , Jiang Lei 
Published: January 2020

AbstractThe deterministic manufacturing and patterning of high‐quality organic single crystal semiconductors are core opportunities and challenges for large‐scale integrated functional devices with high efficiency and high performance. As for the solution patterning for the fabrication of the organic semiconductors, various methods are reported to efficiently control the position, alignment, and size of organic structures. Nevertheless, the poor control of the dewetting dynamics of organic solution leads to the low crystallinity and disordered crystallographic orientation of as‐fabricated organic architectures, which can limit their device performance. Herein, by use of the micropillar‐structured template with asymmetric wettability, the patterned organic 1D single crystals with precise position and geometry, flat morphology, and high alignment can be constructed. Moreover, the nanowire arrays are demonstrated with active optical waveguiding. In addition, the other patterned architectures of circle, triangle, square, pentagon, and hexagon shapes can also be constituted by regulating the surface geometry of substrates. This work not only facilitates the fundamental understanding on the patterning and crystallization of organic architectures, but also contributes greatly to the development of large‐scale assembly technology for patterning micro/nanostructures.
Palladium‐Catalyzed Three‐Component Reactions for the Synthesis of Norbornane‐Fused Indanes
Authors: Ji Xiaoming , Gu Yichao , Cheng Cang , Wu Zhuo , Zhang Yanghui 
Published: January 2020

AbstractTwo methods for the synthesis of norbornane‐fused indanes via palladium‐catalyzed three‐component reactions of iodoarenes, norbornenes, and CH2Br2 or α‐diazoesters have been developed. In the reactions, three C−C bonds were constructed and a wide range of norbornane‐fused indanes could be synthesized. The reactions with α‐diazoesters proceeded with a high degree of diastereoselectivity and indanes bearing an all‐carbon quaternary center were formed. The products obtained in the reactions of 1,4‐dihydro‐1,4‐epoxynaphthalene can be converted to fluorenes, providing an alternative way to access fluorene derivatives.magnified image
Photoredox‐Catalyzed Redox‐Neutral Minisci C−H Formylation of N‐Heteroarenes
Authors: Dong Jianyang , Wang Xiaochen , Song Hongjian , Liu Yuxiu , Wang Qingmin 
Published: January 2020

AbstractWe report a protocol for redox‐neutral Minisci C−H formylation of N‐heteroarenes using 1,3‐dioxoisoindolin‐2‐yl 2,2‐diethoxyacetate as a formyl equivalent at room temperature. This scalable benchtop protocol offers a distinct advantage over traditional reductive carbonylation and Minisci C−H formylation methods in not requiring the use of carbon monoxide, pressurized gas, a stoichiometric reductant, or a stoichiometric oxidant.magnified image