bluuebunny/crossref_metadata_2025_split huggingface dataset:
Crystallinity reduction and enhancement in the chemical reactivity of cellulose by non-dissolving pre-treatment with tetrabutylphosphonium acetate
Authors: del Cerro Daniel Rico , Koso Tetyana V. , Kakko Tia , King Alistair W. T. , Kilpeläinen Ilkka 
Published: February 2020

AbstractHerein, we demonstrate the activation of commercial chemical cellulose pulps towards chemical modification by a pre-treatment step with tetrabutylphosphonium acetate ([P4444][OAc]). A heterogeneous (non-dissolving) pre-treatment was applied allowing for a significant reduction in crystallinity, without concomitant formation of the thermodynamically stable cellulose II. An increase in chemical reactivity was demonstrated using two model reactions; (1) acetylation (organic swelling conditions), where high degrees of substitution (DS) were obtained without the need for a catalyst, and (2) 4-acetamido-TEMPO oxidation (aqueous swelling conditions), where significant degrees of oxidation (DO) were obtained, beyond those for the untreated pulps. In both tests a notable improvement in cellulose reactivity was observed. Regioselectivity of acetylation was assessed using 2D NMR for one low and one high DS sample. The low DS showed a small degree of acetylation of the 6-OH, whereas, the high DS from the pre-treated sample showed mainly mixtures of triacetate and diacetates. Important mechanistic information is attained for future development of aqueous and organic-based reactions involving this ionic liquid pre-treatment.
Lost without you: the Value of Falling out of Love
Authors: Lopez-Cantero Pilar , Archer Alfred 
Published: February 2020

AbstractIn this paper we develop a view about the disorientation attached to the process of falling out of love and explain its prudential and moral value. We start with a brief background on theories of love and situate our argument within the views concerned with the lovers’ identities. Namely, love changes who we are. In the context of our paper, we explain this common tenet in the philosophy of love as a change in the lovers’ self-concepts through a process of mutual shaping. This, however, is potentially dangerous for people involved in what we call ‘subsuming relationships’, who give up too much autonomy in the process of mutual shaping. We then move on to show how, through the relation between love and the self-concept, we can explain why the process of falling out of love with someone is so disorientating: when one is falling out of love, one loses an important point of reference for self-understanding. While this disorientating process is typically taken to be harmful to the person experiencing it, we will explain how it can also have moral and prudential value. By re-evaluating who we were in the relationship and who we are now, we can escape from oppressive practices in subsuming relationships. We finish by arguing that this gives us reason to be wary of seeking to re-orient ourselves -or others- too quickly after falling out of love.
An economic valuation of access to cultural institutions: museums, theatres, and cinemas
Authors: Wiśniewska Aleksandra , Budziński Wiktor , Czajkowski Mikołaj 
Published: February 2020

AbstractCultural institutions are the main beneficiaries of public funds for culture. However, cultural policies suffer from ‘adhocism’ in the administration of institutions, which are often publicly owned and receive little recognition of the benefits that society gains from their use. The aim of this study is to provide the measurement of the use value of access to cultural institutions. Based on the observed individual attendances and their costs, a two-stage budgeting model is employed to estimate the change in consumer surplus related to the loss of access to cinemas, museums, and theatres in Warsaw, Poland. It is the first non-market valuation of cinemas in the existing literature. The inclusion of institutions’ entire markets helps to overcome the bias caused by the embedding effect and the availability of substitutes, which affects many single-site valuations. The estimated use values are compared with the subsidies received by the three groups of cultural institutions. Results reveal substantial benefits provided by cinemas, although cinemas are nearly excluded from the circulation of public support. The estimated use value is enough to justify subsidies for both highly subsidised sectors of museums and theatres. The estimation of use values serves as a starting point for the evaluation of the use of public resources.
Geodesic Analysis in Kendall’s Shape Space with Epidemiological Applications
Authors: Nava-Yazdani Esfandiar , Hege Hans-Christian , Sullivan T. J. , von Tycowicz Christoph 
Published: February 2020

AbstractWe analytically determine Jacobi fields and parallel transports and compute geodesic regression in Kendall’s shape space. Using the derived expressions, we can fully leverage the geometry via Riemannian optimization and thereby reduce the computational expense by several orders of magnitude over common, nonlinear constrained approaches. The methodology is demonstrated by performing a longitudinal statistical analysis of epidemiological shape data. As an example application, we have chosen 3D shapes of knee bones, reconstructed from image data of the Osteoarthritis Initiative. Comparing subject groups with incident and developing osteoarthritis versus normal controls, we find clear differences in the temporal development of femur shapes. This paves the way for early prediction of incident knee osteoarthritis, using geometry data alone.
An analysis of urban renewal decision-making in China from the perspective of transaction costs theory: the case of Chongqing
Authors: Zhuang Taozhi , Qian Queena K. , Visscher Henk J. , Elsinga Marja G. 
Published: February 2020

AbstractIn China, there is a growing number of urban renewal projects due to the rapid growth of the economy and urbanization. To meet the needs of urban development, urban renewal requires a sound decision-making approach involving various stakeholder groups. However, current urban renewal decision-making is criticized for poor efficiency, equity, and resulting in many unintended adverse outcomes. It is claimed that high-level transaction costs (e.g., a great deal of time spent on negotiation and coordination) are the factors hidden behind the problems. However, few studies have analyzed urban renewal decision-making in a transaction costs perspective. Using the case of Chongqing, this paper aims at adopting transaction costs theory to understand the administrative process of urban renewal decision-making in China. This research focuses on four key stakeholder groups: municipal government, district government, local administrative organizations, and the consulting parties. A transaction costs analytical framework is established. First, the decision-making stages of urban renewal and involved key stakeholder groups are clarified. Second, the transactions done by different stakeholder groups in each stage is identified, thus to analyze what types of transaction costs are generated. Third, the relative levels of transaction costs among different stakeholder groups were measured based on the interview. The empirical analysis reveals how transaction costs occur and affect urban renewal decision-making. Finally, policy implications were proposed to reduce transaction costs in order to enhance urban renewal.
Adipose derived stem cells and platelet rich plasma improve the tissue integration and angiogenesis of biodegradable scaffolds for soft tissue regeneration
Authors: Naderi N. , Griffin M. F. , Mosahebi A. , Butler P. E. , Seifalian A. M. 
Published: February 2020

AbstractCurrent surgical reconstruction for soft tissue replacement involves lipotransfer to restore soft tissue replacements but is limited by survival and longevity of the fat tissue. Alternative approaches to overcome these limitations include using biodegradable scaffolds with stem cells with growth factors to generate soft tissue. Adipose derived stem cells (ADSCs) offer great potential to differentiate into adipose, and can be delivered using biodegradable scaffolds. However, the optimal scaffold to maximise this approach is unknown. This study investigates the biocompatibility of nanocomposite scaffolds (POSS-PCL) to deliver ADSCs with and without the addition of growth factors using platelet rich plasma (PRP) in vivo. Rat ADSCs were isolated and then seeded on biodegradable scaffolds (POSS-PCL). In addition, donor rats were used to isolate PRP to modify the scaffolds. The implants were then subcutaneously implanted for 3-months to assess the effect of PRP and ADSC on POSS-PCL scaffolds biocompatibility. Histology after explanation was examined to assess tissue integration (H&E) and collagen production (Massons Trichome). Immunohistochemistry was used to assess angiogenesis (CD3, α-SMA), immune response (CD45, CD68) and adipose formation (PPAR-γ). At 3-months PRP-ADSC-POSS-PCL scaffolds demonstrated significantly increased tissue integration and angiogenesis compared to PRP, ADSC and unmodified scaffolds (p < 0.05). In addition, PRP-ADSC-POSS-PCL scaffolds showed similar levels of CD45 and CD68 staining compared to unmodified scaffolds. Furthermore, there was increased PPAR-γ staining demonstrated at 3-months with PRP-ADSC-POSS-PCL scaffolds (p < 0.05). POSS-PCL nanocomposite scaffolds provide an effective delivery system for ADSCs. PRP and ADSC work synergistically to enhance the biocompatibility of POSS-PCL scaffolds and provide a platform technology for soft tissue regeneration.
Delivering Opportunistic Behavior Change Interventions: a Systematic Review of Systematic Reviews
Authors: Keyworth Chris , Epton Tracy , Goldthorpe Joanna , Calam Rachel , Armitage Christopher J. 
Published: February 2020

AbstractOpportunities for healthcare professionals to deliver health behavior change interventions are often missed, but understanding the barriers and enablers to this activity is limited by a focus on defined specialisms/health conditions. This systematic review of systematic reviews collates all the evidence across professional groups to provide guidance to policy makers for implementing healthcare professional delivery of behavior change interventions. Eight electronic databases were searched for systematic reviews reporting patient-facing healthcare professionals’ (e.g., general practitioners, nurses) barriers and enablers to delivering behavior change interventions (diet, physical activity, alcohol reduction, smoking cessation, and weight management). A narrative synthesis was conducted. Thirty-six systematic reviews were included. Four themes emerged as both barriers and enablers: (1) perceptions of the knowledge or skills needed to support behavior change with patients, (2) perceptions of the healthcare professional role, (3) beliefs about resources and support needed, and (4) healthcare professionals’ own health behavior. There were four cross-disciplinary barriers: (1) perceived lack of time, (2) perceived lack of prioritization of health behavior change, (3) negative attitudes towards patients and perceptions of patient risk, and (4) perceptions of patient motivation. The three enablers were as follows: (1) training, (2) context, and (3) attitudes towards delivering interventions. To enhance healthcare professionals’ delivery of behavior change interventions, policy makers should (a) address perceptions about patient need for interventions, (b) support diverse professional groups to identify opportunities to deliver interventions, and (c) encourage professionals to focus on prevention and management of health conditions.
Opportunities and Challenges in HIV Treatment as Prevention Research: Results from the ANRS 12249 Cluster-Randomized Trial and Associated Population Cohort
Authors: Tanser Frank , Kim Hae-Young , Vandormael Alain , Iwuji Collins , Bärnighausen Till 
Published: February 2020

Abstract
Purpose of Review
The ANRS 12249 treatment as prevention (TasP) trial investigated the impact of a universal test and treat (UTT) approach on reducing HIV incidence in one of the regions of the world most severely affected by the HIV epidemic—KwaZulu-Natal, South Africa. We summarize key findings from this trial as well as recent findings from controlled studies conducted in the linked population cohort quantifying the long-term effects of expanding ART on directly measured HIV incidence (2004–2017).

Recent Findings
The ANRS TasP trial did not—and could not—demonstrate a reduction in HIV incidence, because the offer of UTT in the intervention communities did not increase ART coverage and population viral suppression compared to the standard of care in the control communities. Ten controlled studies from the linked population cohort—including several quasi-experimental study designs—exploit heterogeneity in ART exposure to show a consistent and substantial impact of expanding provision of ART and population viral suppression on reduction in HIV incidence at the couple, household, community, and population levels.

Summary
In this setting, all of the evidence from large, population-based studies (inclusive of the ANRS TasP trial) is remarkably coherent and consistent—i.e., higher ART coverage and population viral suppression were repeatedly associated with clear, measurable decreases in HIV incidence. Thus, the expanded provision of ART has plausibly contributed in a major way toward the dramatic 43% decline in population-level HIV incidence in this typical rural African population. The outcome of the ANRS TasP trial constitutes a powerful null finding with important insights for overcoming implementation challenges in the population delivery of ART. This finding does not imply lack of ART effectiveness in blocking onward transmission of HIV nor its inability to reduce HIV incidence. Rather, it demonstrates that large increases in ART coverage over current levels will require health systems innovations to attract people living with HIV in early stages of the disease to participate in HIV treatment. Such innovations and new approaches are required for the true potential of UTT to be realized.
Facile Synthesis of FePS3 Nanosheets@MXene Composite as a High-Performance Anode Material for Sodium Storage
Authors: Ding Yonghao , Chen Yu , Xu Na , Lian Xintong , Li Linlin , Hu Yuxiang , Peng Shengjie 
Published: February 2020

AbstractSearching for advanced anode materials with excellent electrochemical properties in sodium-ion battery is essential and imperative for next-generation energy storage system to solve the energy shortage problem. In this work, two-dimensional (2D) ultrathin FePS3 nanosheets, a typical ternary metal phosphosulfide, are first prepared by ultrasonic exfoliation. The novel 2D/2D heterojunction of FePS3 nanosheets@MXene composite is then successfully synthesized by in situ mixing ultrathin MXene nanosheets with FePS3 nanosheets. The resultant FePS3 nanosheets@MXene hybrids can increase the electronic conductivity and specific surface area, assuring excellent surface and interfacial charge transfer abilities. Furthermore, the unique heterojunction endows FePS3 nanosheets@MXene composite to promote the diffusion of Na+ and alleviate the drastic change in volume in the cyclic process, enhancing the sodium storage capability. Consequently, the few-layered FePS3 nanosheets uniformly coated by ultrathin MXene provide an exceptional reversible capacity of 676.1 mAh g−1 at the current of 100 mA g−1 after 90 cycles, which is equivalent to around 90.6% of the second-cycle capacity (746.4 mAh g−1). This work provides an original protocol for constructing 2D/2D material and demonstrates the FePS3@MXene composite as a potential anode material with excellent property for sodium-ion batteries.
Layered Birnessite Cathode with a Displacement/Intercalation Mechanism for High-Performance Aqueous Zinc-Ion Batteries
Authors: Zhai Xian-Zhi , Qu Jin , Hao Shu-Meng , Jing Ya-Qiong , Chang Wei , Wang Juan , Li Wei , Abdelkrim Yasmine , Yuan Hongfu , Yu Zhong-Zhen 
Published: February 2020

AbstractMn-based rechargeable aqueous zinc-ion batteries (ZIBs) are highly promising because of their high operating voltages, attractive energy densities, and eco-friendliness. However, the electrochemical performances of Mn-based cathodes usually suffer from their serious structure transformation upon charge/discharge cycling. Herein, we report a layered sodium-ion/crystal water co-intercalated Birnessite cathode with the formula of Na0.55Mn2O4·0.57H2O (NMOH) for high-performance aqueous ZIBs. A displacement/intercalation electrochemical mechanism was confirmed in the Mn-based cathode for the first time. Na+ and crystal water enlarge the interlayer distance to enhance the insertion of Zn2+, and some sodium ions are replaced with Zn2+ in the first cycle to further stabilize the layered structure for subsequent reversible Zn2+/H+ insertion/extraction, resulting in exceptional specific capacities and satisfactory structural stabilities. Additionally, a pseudo-capacitance derived from the surface-adsorbed Na+ also contributes to the electrochemical performances. The NMOH cathode not only delivers high reversible capacities of 389.8 and 87.1 mA h g−1 at current densities of 200 and 1500 mA g−1, respectively, but also maintains a good long-cycling performance of 201.6 mA h g−1 at a high current density of 500 mA g−1 after 400 cycles, which makes the NMOH cathode competitive for practical applications.
Sandwich-Like Fe&TiO2@C Nanocomposites Derived from MXene/Fe-MOFs Hybrids for Electromagnetic Absorption
Authors: Deng Baiwen , Xiang Zhen , Xiong Juan , Liu Zhicheng , Yu Lunzhou , Lu Wei 
Published: February 2020

AbstractElectromagnetic pollution has been causing a series of problems in people’s life, and electromagnetic absorbers with lightweight and broad absorbing bandwidth properties are widely desired. In this work, novel sandwich-like 2D laminated Fe&TiO2 nanoparticles@C nanocomposites were rationally designed and successfully developed from the MXene–MOFs hybrids. The formation of Fe and rutile-TiO2 nanoparticles sandwiched by the two-dimensional carbon nanosheets provided strong electromagnetic energy attenuation and good impedance matching for electromagnetic wave (EMW) absorption. As expected, the nanocomposites achieved a broad effective absorption bandwidth of 6.5 GHz at a thickness of only 1.6 mm and the minimum reflection loss (RL) value of − 51.8 dB at 6.6 GHz with a thickness of 3 mm. This work not only provides a good design and fabricating concept for the laminated metal and functional nanoparticles@C nanocomposites with good EMW absorption, but also offers an important guideline to fabricate various two-dimensional nanocomposites derived from the MXene precursors.
Extreme Wave Statistics in Combined and Partitioned Windsea and Swell
Authors: Støle-Hentschel Susanne , Trulsen Karsten , Nieto Borge José Carlos , Olluri Shkurte 
Published: February 2020

AbstractWe investigate how the extreme wave statistics of a combined windsea and swell appears to be different from the extreme wave statistics of the corresponding windsea and swell partitions. We consider the situation of following long-crested windsea and swell in laboratory experiments and in simulations using a high-order spectral method (HOSM). We also consider the situation of short-crested windsea and swell crossing at nearly right angle, corresponding to the sea state when the Prestige accident happened, in hindcast simulations combined with HOSM. For cases when the two wave systems do not interact much, the combined wave system appears to be more Gaussian than the corresponding partitioned wave systems, consistent with the central limit theorem. This result is found for kurtosis and exceedance probability of envelope and crest height.
Nutrient composition of the Indonesian sago grub (Rhynchophorus bilineatus)
Authors: Köhler Realm , Irias-Mata Andrea , Ramandey Euniche , Purwestri Ratna , Biesalski Hans Konrad 
Published: February 2020

AbstractThe sago grub (Rhynchophorus bilineatus) [Montrouzier, Coleoptera, Dryophthoridae] is a local delicacy in the Papua Province in Indonesia. In this study, the nutrient content of the edible insect was measured using chromatographic and spectrometric methods. The results showed that it contains 10.39 g protein and 17.17 g oil/ 100 g fresh weight. The sago grub meets the FAO/WHO requirements of 40% essential amino acids and a 0.60 ratio between essential to non-essential amino acids. Its limiting amino acid is methionine + cysteine. The major fatty acids found in the sago grub are palmitic (42%), oleic (45%), and linoleic (3%) acids. Although vitamin E is exclusively produced by photosynthetic organisms, a gram of sago grub oil contains 51 μg vitamin E, which is composed mainly of tocopherols (92%). In contrast with palm oil, the sago grub oil contains δ-tocopherol (0.12 μg/g oil), and a significantly high amount of β-tocopherol (3.85 μg/g oil). It is a source of zinc and magnesium and contains safe levels of heavy metals. Based on these nutritional properties, the Indonesian sago grub can be considered as a good source of nutrients, and its propagation and utilization should be encouraged especially in other areas of Indonesia and maybe in neighboring countries where they are also endemic, and where malnutrition is prevalent. The consumption of edible insects should be considered as a component of dietary diversification – a sustainable way of alleviating the nutritional status of the population.
A comprehensive study on the microstructure and mechanical properties of arc girth welded joints of spiral welded high strength API X70 steel pipe
Authors: Węglowski M. St. , Dymek S. , Kopyściański M. , Niagaj J. , Rykała J. , De Waele W. , Hertelé S. 
Published: February 2020

AbstractIn the paper, the effect of welding technology on the microstructure and mechanical properties of girth welded joints was presented. Metallographic examinations based on light microscopy and SEM were conducted on girth welded joints of API X70 steel pipe. Research has shown that microstructure of the heat-affected zone (HAZ) of MMA girth welded joints is not homogeneous and depends on the thermal history of each area during the welding process. Near the fusion line the zone is coarse, and further away there is a fine-grained zone. In the area of root passes the microstructure consists of recrystallized ferrite grains unlike to cap passes where the fine bainitic microstructure can be observed. In the case of MAG girth welded joints, the weld microstructure consists of primary austenite grains. The primary austenite boundaries serve as nucleation sites of ferrite. The microstructure of the HAZ varies continuously from a coarse—to fine-grained microstructure of the base material. The results of mechanical properties of girth welded joints are also presented. The hardness and strength of arc welded joints depend on welding filler materials as well as welding technology. The results of hardness distribution of MMA and MAG girth welded joints confirmed the results of microstructural evaluation.
FORECASTING MULTIPLE FUNCTIONAL TIME SERIES IN A GROUP STRUCTURE: AN APPLICATION TO MORTALITY
Authors: Shang Han Lin , Haberman Steven 
Published: February 2020

AbstractWhen modelling subnational mortality rates, we should consider three features: (1) how to incorporate any possible correlation among subpopulations to potentially improve forecast accuracy through multi-population joint modelling; (2) how to reconcile subnational mortality forecasts so that they aggregate adequately across various levels of a group structure; (3) among the forecast reconciliation methods, how to combine their forecasts to achieve improved forecast accuracy. To address these issues, we introduce an extension of grouped univariate functional time-series method. We first consider a multivariate functional time-series method to jointly forecast multiple related series. We then evaluate the impact and benefit of using forecast combinations among the forecast reconciliation methods. Using the Japanese regional age-specific mortality rates, we investigate 1–15-step-ahead point and interval forecast accuracies of our proposed extension and make recommendations.