bluuebunny/crossref_metadata_2025_split huggingface dataset:
Dissolution–Recrystallization Formation of Huge Thin 2D Silicalite Lamella for Promoted Sorption
Authors: Liu Jie , Yang Danni , Wang Zheng‐Ming , Hiyoshi Norihito 
Published: January 2020

AbstractAn all silica MEL‐type silicalite‐2 nanocrystal is hydrothermally treated in coexistence with cetyltrimethylammonium bromide (CTAB) and tetrapropylammonium hydroxide (TPAOH) at ordinary and elevated temperatures. From monitoring its structural transition process by various physico‐chemical methodologies, it is found that, instead of simple delamination, silicalite‐2 nanocrystal changes with a dissolution and recrystallization mechanism by treatment at an elevated temperature and for a long time, that is, it is first dissolved and then reorganized to huge 2D platelets via an intermediate step forming periodic mesoporous material. The newly formed nanoplatelets (h‐nanoplatelets) from in‐plane growth along a (or b)‐, c‐directions (normal to b (or a)‐axis) are of silicalite (either MEL or MEL/MFI intergrowth)‐type framework topology with a thickness of 3.3 nm (the equivalent of ≈1.6 unit cell) and interspersed with a minor part of small square‐like MFI‐type nanoplatelets (s‐nanoplatelets). The h‐nanoplatelets have expanded lattice parameters and a larger micropore size compared to the parent silicalite‐2 nanocrystal and s‐nanoplatelets, whose micropore structure are modified so as to benefit from both equilibrium adsorption and desorption‐recovering ability of organic contaminants particularly at a low vapor pressure range. This is the first report regarding the dissolution–recrystallization formation of 2D lamella‐type silicalites mediated by popular types of surfactant and base species.
Stretchable and Broadband Cavity‐Free Lasers Based on All 2D Metamaterials
Authors: Yang Yu‐Fan , Hu Han‐Wen , Wu Meng‐Jer , Lin Tai‐Yuan , Shen Ji‐Lin , Chen Yang‐Fang 
Published: January 2020

AbstractThe development of two‐dimensional (2D) materials has brought the breakthrough for scientific discoveries and widespread applications in many emerging devices. However, the related study on lasers is rather limited. In this study, a stretchable and broadband cavity‐free laser device based on all 2D metamaterials consisting of molybdenum disulfide (MoS2)/graphene nanocomposites is designed and demonstrated. When the pumping power density of the device is more than 200 W cm−2, multiple pronounced narrow peaks with linewidth <0.5 nm superimpose on the spectra, providing the signature for laser actions. The optical properties of MoS2/graphene meta‐nanocomposites for MoS2 quantum dots (QDs) with different concentration of l‐histidine doping are also examined. It is emphasized that under optimized doping concentration of MoS2 QDs, the laser action of the device can be effectively enhanced. Furthermore, it is shown that the laser action of the devices is controllable by applying an external strain. It is demonstrated that after stretching for more than 200 times, the performance still remains the same with negligible change, indicating the robustness of the device. The presented stretchable laser devices based on all 2D meta‐nanocomposites therefore can open new possibilities for future developments of not‐yet realized optoelectronic devices.
Ensembles of Photonic Beads: Optical Properties and Enhanced Light—Matter Interactions
Authors: Aravindakshan Nikhil , Eftekhari Ehsan , Tan Say Hwa , Li Xiaomin , St John James , Nguyen Nam Trung , Zhao Huijun , Zhao Dongyuan , Li Qin 
Published: January 2020

AbstractLight management is of paramount importance to improve the performance of optoelectronic devices including photodetectors, optical sensors, solar cells, and light‐emitting diodes. Photonic crystals are shown as an effective metamaterial for trapping light among their various photon management functions. Herewith, it is demonstrated that spherical photonic crystals, or in other words, photonic beads, possess a stronger light‐trapping effect compared to the planar counterpart. The photonic beads are fabricated by colloidal self‐assembly under microdroplet confinement employing microfluidic devices. The light–matter interactions are illustrated by the emission intensity and lifetime of the embedded emitters, namely carbon dots and upconversion nanoparticles (UCNPs). The bandgaps of the photonic beads are selected according to the emission and excitation peaks of the light emitters, whereby the emission or excitation peak overlaps the blue edge or red edge of the photonic bands, respectively. Significantly stronger emission and extended luminescence lifetime are observed in photonic beads ensemble in comparison to the planar photonic crystals, demonstrating enhanced light trapping owing to the spherical geometry, which introduces additional microcavity effect. Photonic beads represent a perfect hierarchical light manipulation system. Combining both photonic and microcavity resonator effects, photonic beads potentially find applications in light harvesting, sensing, lighting devices, and light‐triggered manipulations.
Optically Pumped Broadband Terahertz Modulator Based on Nanostructured PtSe2 Thin Films
Authors: Jakhar Alka , Kumar Prabhat , Moudgil Akshay , Dhyani Veerendra , Das Samaresh 
Published: January 2020

AbstractHere, an optically pumped terahertz (THz) modulator based on the novel transition metal dichalcogenide (TMD) material platinum diselenide (PtSe2) is demonstrated. The nanostructured PtSe2 thin films are formed by direct selenization of the sputtered platinum film on a high‐resistivity silicon substrate. Raman spectroscopy, scanning electron microscopy, and high‐resolution transmission electron microscopy confirm the formation of polycrystalline PtSe2 nanostructures. The transmission measurements reveal the modulation of the THz waves in the wide frequency range of 0.1–1 THz. The modulation depth of 32.7% is achieved under low pumping laser power of 1 W cm−2. The numerical analysis based on the finite difference time domain method is in good agreement with the experimentally obtained results. Further, the simulation results manifest that higher modulation depth can be achieved with the utilization of higher laser power. This work provides a path for the application of TMD materials like PtSe2 in the development of THz tunable devices such as modulators, polarizers, filters.
Machine‐Learning‐Based Image Similarity Analysis for Use in Materials Characterization
Authors: Wang Zhi‐Lei , Ogawa Toshio , Adachi Yoshitaka 
Published: January 2020

AbstractMaterials with similar microstructural features exhibit similar properties, a fact which often provides useful insights for a detailed understanding of the materials. An analysis of material similarity in terms of microstructural images is proposed for predicting some properties of interest. This similarity analysis is inspired by the application of medical image retrieval to guide diagnostic decisions. Some relevant analyzing techniques including machine‐learning algorithms of zero‐normalized cross‐correlation, mutual information, maximum likelihood estimation, principal component analysis, and self‐organizing map are applied in this work. These techniques are systematically employed to identify the variances of the query images based on the metrics of image natural properties (such as brightness which is measured in pixel) or metallurgical features contained in the microstructural images. It is shown that the employed methods exhibit consistent similarity evaluation results. The proposed similarity analysis of microstructural images is expected to provide a new avenue for understanding the materials paradigm.
Seeding rate and nitrogen fertilizer rate effect on dryland no‐till hard red spring wheat yield and quality
Authors: Walsh Olga S. , Walsh Willow L. 
Published: January 2020

AbstractIncreasing the efficiency of spring wheat (Triticum aestivum L.) production is vitally important to Montana growers’ bottom line. In semiarid regions of the Northern Great Plains, agronomic practices must aim at maximum capture and utilization efficiency of plant growth resources. Appropriate plant population and N management are important for optimizing wheat yield and quality by enhancing N uptake and improving nitrogen use efficiency (NUE). Field experiments were conducted in 2014 at two locations in northcentral Montana. The aim of this study was to assess the effect of four N levels (0, 28, 84, and 140 kg N ha−1) in dryland no‐till hard red spring wheat seeded at two seeding rate levels (67 and 135 kg ha−1 pure live seed [PLS]). Nitrogen rate significantly improved wheat grain yield, grain protein content, protein yield, and N uptake at both locations, and NUE at one of two locations. The 135 kg ha−1 did not have an advantage over the 67 kg ha−1 PLS seeding rate, resulting in comparable wheat grain parameters, N uptake, and NUE. Wheat yield and quality was highest at 140 kg N ha−1; higher N rate (especially split‐applied) may have improved wheat production (especially grain protein content) further.
Cardiomyopathy due to PRDM16 mutation: First description of a fetal presentation, with possible modifier genes
Authors: Delplancq Geoffroy , Tarris Georges , Vitobello Antonio , Nambot Sophie , Sorlin Arthur , Philippe Christophe , Carmignac Virginie , Duffourd Yannis , Denis Charlotte , Eicher Jean Christophe , Chevarin Martin , Millat Gilles , Khallouk Bouchra , Rousseau Thierry , Falcon‐Eicher Sylvie , Vasiljevic Alexandre , Harizay Fara T. , Thauvin‐Robinet Christel , Faivre Laurence , Kuentz Paul 
Published: January 2020

AbstractPRDM16 (positive regulatory domain 16) is localized in the critical region for cardiomyopathy in patients with deletions of chromosome 1p36, as defined by Gajecka et al., American Journal of Medical Genetics, 2010, 152A, 3074–3083, and encodes a zinc finger transcription factor. We present the first fetal case of left ventricular non‐compaction (LVNC) with a PRDM16 variant. The third‐trimester obstetric ultrasound revealed a hydropic fetus with hydramnios and expanded hypokinetic heart. After termination of pregnancy, foetopathology showed a eutrophic fetus with isolated cardiomegaly. Endocardial fibroelastosis was associated with non‐compaction of the myocardium of the left ventricle. Exome sequencing (ES) identified a de novo unreported p.(Gln353*) heterozygous nonsense variant in PRDM16. ES also identified two rare variants of unknown significance, according to the American College of Medical Genetics and Genomics guidelines, in the titin gene (TTN): a de novo missense p.(Lys14773Asn) variant and a c.33043+5A>G variant inherited from the mother. Along with the PRDM16 de novo probably pathogenic variant, TTN VOUS variants could possibly contribute to the severity and early onset of the cardiac phenotype. Because of the genetic heterogeneity of cardiomyopathies, large panels or even ES could be considered as the main approaches for the molecular diagnosis, particularly in fetal presentations, where multiple hits seem to be common.
Nickel‐Catalyzed Synthesis of Pyrimidines via Dehydrogenative Functionalization of Alcohols
Authors: Chakraborty Gargi , Sikari Rina , Mondal Rakesh , Mandal Sutanuva , Paul Nanda D. 
Published: January 2020

AbstractHerein we report a comparative study of nickel‐catalyzed syntheses of pyrimidines via dehydrogenative multi‐component coupling of alcohols and amidines using two different classes of nickel catalysts (1 a/1 b and 2 a/2 b) differing with respect to their mode of action during catalysis. The catalysts 1 a and 1 b are two tetracoordinate Ni(II)‐complexes containing two apparently redox‐inactive tetraaza macrocyclic ligands while the catalysts 2 a and 2 b are square planar Ni(II)‐complexes featuring redox‐active diiminosemiquinonato type scaffolds. Catalyst 1 a and 1 b dehydrogenate alcohols via a two‐electron hydride transfer pathway involving energetically demanding nickel‐centered redox events while in the presence of 2 a and 2 b dehydrogenation of alcohols proceeds via a one‐electron hydrogen atom transfer (HAT) pathway via synergistic participation of metal and ligand centered redox processes avoiding high energy nickel centered redox events. Detailed substrate screening and control experiments were performed to unveil the reaction sequence and understand the advantages/disadvantages of these two pathways.
Potentially lethal cystic fibrosis gene variant in the orangutan
Authors: Taylor‐Cousar Jennifer L. , Evans Taylor A. , Cutting Garry R. , Sharma Neeraj 
Published: January 2020

AbstractA syndrome of chronic upper and lower airway disease leading to increased morbidity and mortality occurs primarily in captive orangutans. Similarities in symptoms to the inherited human respiratory disease, cystic fibrosis, led us to hypothesize that orangutan respiratory disease is a result of variants in the Cystic Fibrosis Transmembrane Conductance Regulator (CFTR) gene. We identified the nonsense variant, c.484A>T (p.Lys162X), in heterozygosity in an unaffected orangutan. Analysis of the pedigree of this orangutan confirmed that both his sire and deceased fetus also harbored the c.484A>T allele. An expression minigene harboring c.484A>T produced no full‐length CFTR protein in HEK293 cells. Finally, the c.484A>T CFTR messenger RNA abundance was severely reduced in primary nasal epithelial cells of the orangutan indicating that c.484A>T (p.Lys162X) is potentially lethal. Genetic screening of the captive orangutan population could be used to prevent transmission of this potentially lethal variant, and thus aid in the conservation of this critically endangered species.
Biomedical Applications of Calixarenes: State of the Art and Perspectives
Authors: Pan Yu‐Chen , Hu Xin‐Yue , Guo Dong‐Sheng 
Published: January 2020

AbstractCalixarenes (CAs), representing the third generation of supramolecular hosts and one of the most widely studied macrocyclic scaffolds, offer (almost) unlimited structure and application possibilities due to their ease of modification, which allows one to establish a large molecular library as a material basis for diverse biomedical applications. Moreover, CAs and their derivatives engage in various noncovalent interactions for the facile recognition of guests including bioactive molecules and are also important building blocks for the fabrication of supramolecular architectures. In view of their molecular recognition and self‐assembly properties, CAs are extensively applied in biosensing, bioimaging, and drug/gene delivery. Additionally, some CA derivatives exhibit biological activities and can therefore be used as new therapeutic agents. Herein, we summarize the diverse biomedical applications of CAs including in vitro diagnosis (biosensing), in vivo diagnosis (bioimaging), and therapy.
Novel bioresource‐based poly(3‐Hydroxybutyrate‐co‐4‐Hydroxybutyrate)/poly(LacticAcid) blend fibers with high strength and toughness via melt‐spinning
Authors: Chen Ziyang , Zhao Zuoxian , Hong Jianhan , Pan Zhijuan 
Published: January 2020

ABSTRACTNovel biodegradable blend fibers based on the biomaterials poly(3‐hydroxybutyrate‐co‐4‐hydroxybutyrate) (P3HB4HB) and poly(lacticacid) (PLA) were successfully prepared by combining melt spinning and hot drawing. The results showed that the commixture could continuous and stable spin for a P3HB4HB ratio of 30–35 wt% and winding speed of 20–30 m/min. The thermal stability of the P3HB4HB/PLA blend fiber was increased, as determined by thermogravimetric analysis. The crystallinity degree of the P3HB4HB/PLA blend fibers increased with increasing the P3HB4HB content. The addition of PLA resulted in a low cold crystallization temperature and diminutive size of the lamellar stacks, which would be favorable for the enhancement of the mechanical properties of the blend fiber, when the P3HB4HB content was 30–35 wt%. The P3HB4HB/PLA composite fiber was one type of high‐strength and high‐toughness fiber, with 1 GPa breaking stress and over 80% strain at break. © 2020 Wiley Periodicals, Inc. J. Appl. Polym. Sci.2020,137, 48956.
Hydrated and anhydrous zinc borate fillers for tuning the flame retardancy of epoxy nanocomposites
Authors: Mahajan Dhiraj S. , Deshpande Tushar D. , Bari Mahendra L. , Patil Ujwal D. , Narkhede Jitendra S. 
Published: January 2020

AbstractIn this study, hydrous (Zn3B6O12·3.5H2O) and anhydrous (ZnB2O4) forms of zinc borates were synthesized at 150 and 175°C under moderate pressure conditions (85 and 150 psi, respectively). Synthesized zinc borates were controllably incorporated (1, 5, and 10 wt%) in epoxy resin to prepare their nanocomposites. The flame‐retardant and mechanical properties of these nanocomposites were determined and compared in terms of their flame spread testing, smoke density, limiting oxygen index, and flexural strength. Superior properties in terms of flame retardancy were observed for epoxy composites containing hydrous filler as compared to anhydrous zinc borates. Although flexural strength was observed to be decreased with increasing filler concentration, the marked drop is lower for composites with hydrous zinc borate as compared to the anhydrous one. The variations in flame‐retardant and mechanical properties of composites with both types of fillers are related to their morphological (field emission scanning electron microscopy), X‐ray diffraction (XRD) analysis, Fourier Transform Infrared (FTIR), differential scanning calorimetry, and thermogravimetry analysis and explained with condensed phase mechanism.
Ubiquitin Dynamics in Stem Cell Biology: Current Challenges and Perspectives
Authors: de Dieuleveult Maud , Miotto Benoit 
Published: January 2020

AbstractUbiquitination plays a central role in the regulation of stem cell self‐renewal, propagation, and differentiation. In this review, the functions of ubiquitin dynamics in a myriad of cellular processes, acting along side the pluripotency network, to regulate embryonic stem cell identity are highlighted. The implication of deubiquitinases (DUBs) and E3 Ubiquitin (Ub) ligases in cellular functions beyond protein degradation is reported, including key functions in the regulation of mRNA stability, protein translation, and intra‐cellular trafficking; and how it affects cell metabolism, the micro‐environment, and chromatin organization is discussed. Finally, unsolved issues in the field are emphasized and will need to be tackled in order to fully understand the contribution of ubiquitin dynamics to stem cell self‐renewal and differentiation.
Phlebotomy resulting in controlled hypovolaemia to prevent blood loss in major hepatic resections (PRICE-1): a pilot randomized clinical trial for feasibility
Authors: Martel G , Baker L , Wherrett C , Fergusson D A , Saidenberg E , Workneh A , Saeed S , Gadbois K , Jee R , McVicar J , Rao P , Thompson C , Wong P , Abou Khalil J , Bertens K A , Balaa F K 
Published: January 2020

Abstract

Background
Major liver resection is associated with blood loss and transfusion. Observational data suggest that hypovolaemic phlebotomy can reduce these risks. This feasibility RCT compared hypovolaemic phlebotomy with the standard of care, to inform a future multicentre trial.

Methods
Patients undergoing major liver resections were enrolled between June 2016 and January 2018. Randomization was done during surgery and the surgeons were blinded to the group allocation. For hypovolaemic phlebotomy, 7–10 ml per kg whole blood was removed, without intravenous fluid replacement. Co-primary outcomes were feasibility and estimated blood loss (EBL).

Results
A total of 62 patients were randomized to hypovolaemic phlebotomy (31) or standard care (31), at a rate of 3·1 patients per month, thus meeting the co-primary feasibility endpoint. The median EBL difference was −111 ml (P = 0·456). Among patients at high risk of transfusion, the median EBL difference was −448 ml (P = 0·069). Secondary feasibility endpoints were met: enrolment, blinding and target phlebotomy (mean(s.d.) 7·6(1·9) ml per kg). Blinded surgeons perceived that parenchymal resection was easier with hypovolaemic phlebotomy than standard care (16 of 31 versus 10 of 31 respectively), and guessed that hypovolaemic phlebotomy was being used with an accuracy of 65 per cent (20 of 31). There was no significant difference in overall complications (10 of 31 versus 15 of 31 patients), major complications or transfusion. Among those at high risk, transfusion was required in two of 15 versus three of nine patients (P = 0·326).

Conclusion
Endpoints were met successfully, but no difference in EBL was found in this feasibility study. A multicentre trial (PRICE-2) powered to identify a difference in perioperative blood transfusion is justified. Registration number: NCT02548910 ( http://www.clinicaltrials.gov).
Can environmental governance lower toxic emissions? A panel study of U.S. high‐polluting industries
Authors: Kanashiro Patricia 
Published: January 2020

AbstractFirms have increasingly adopted environmental governance mechanisms in the form of environmental compensation and environmental board committees. The current study examines the argument that such environmental governance mechanisms contribute to lower toxic emissions in high‐polluting industries. The sample comprises firms that were part of the S&P 500 from the years 2006 to 2011 and were mandated to report toxic emissions to the U.S. Environmental Protection Agency under the Toxic Release Inventory program. A panel regression model with propensity score matching was employed to minimize endogeneity bias. The results indicate that environmental compensation is a compelling incentive to motivate managers to invest in long‐term and highly uncertain environmental projects. Likewise, the presence of an environmental board committee appears to be significant, suggesting that directors contribute to a firm's strategy with their expertise and political influence. This research also found evidence supporting the cumulative adoption of both environmental governance mechanisms in enhancing environmental performance and the firm's legitimacy.
Environmental management and the “soft side” of organisations: Discovering the most relevant behavioural factors in green supply chains
Authors: Muduli Kamala kanta , Luthra Sunil , Kumar Mangla Sachin , Jabbour Charbel Jose Chiappetta , Aich Satyabrata , de Guimarães Julio Cesar Ferro 
Published: January 2020

AbstractAnchored in the resource‐based view theory, the objective of this research is to empirically analyse the behavioural factors affecting the green supply chain management (GCSM) performance in a fast‐growing emerging economy by taking an empirical data set of 101 responses from personnel in the mining sector. Behavioural factors in green supply chains are still a critical challenge—not yet a well‐explored academic subject—when the focus is on the mining industry of emerging economies like India; the lack of studies in this field could be a factor preventing the Indian mining industry becoming more green. In terms of methodology, original survey data were processed through AMOS 4.0, adopted for assessing the causal connection among the six constructs, that is, top management support, teamwork, workplace culture, resistance to change, green innovation, and green motivation. We further explore the input from the human side of GCSM by highlighting that top management support and green motivation are the most crucial behavioural factors that influence GCSM in the Indian mining sector. The study will be helpful for mining companies because it will enable them to identify the areas that require their attention for enhancing GCSM performance related to behavioural aspects.