bluuebunny/crossref_metadata_2025_split huggingface dataset:
PENGARUH PENAMBAHAN GLISEROLTERHADAP SIFAT KEKUATAN TARIK DAN PEMANJANGAN SAAT PUTUS BIOPLASTIK DARI PATI UMBI TALAS
Authors: Rinaldi Febrianto Sinaga  , Gita Minawarisa Ginting  , M. Hendra S Ginting  , Rosdanelli Hasibuan  
Published: October 2019

Bioplastics are a type of plastic made ​​from renewable biomass sources, such as vegetable oil, corn starch, pea starch, and microbiota. Starch from tubers of talas (Colocasia esculenta) as a potential raw material for bioplastics by using glycerol as plastizicer. The purposes of the research are to know effect of adding glycerol to the properties of tensile strength and elongation at break bioplastic from starch taro tubers. In this research, the manufacture of bioplastics using casting methode with variations of starch solution (0,2 w/v, 0,3 w/v, and 0,4 w/v). The next additions to vary the volume of glycerol (1 % v, 2 % v, and 3 % v) and heating temperature of gelatin formation (60oC, 70oC, and 80oC). The results showed that bioplastics made ​​from taro tuber starch has gelatinization temperature of 70oC. The addition of glycerol volume effect value of tensile strength and elongation at break of bioplastics. Increasing volume of glycerol will decrease tensile strength but increase elongation at break value. The best of bioplastics in this research is a variation of starch bioplastic 0,3 w/v, addition of 1 % v glycerol at a temperature of 70°C with a value of tensile strength is 18,4992 MPa and elongation at break value is 2,1290%.
PENGARUH UKURAN PARTIKEL DAN KOMPOSISI TERHADAP SIFAT KEKUATAN BENTUR KOMPOSIT EPOKSI BERPENGISI SERAT DAUN NANAS
Authors: Syahrinal Anggi Daulay  , Fachry Wirathama  , Halimatuddahliana  
Published: October 2019

This research was aimed to investigate the effect of pineapple leafs particle size and pineapple leaf fiber composition of the impact strength of epoxy composites filled with pineapple leaf fibers. The composites were made by hand lay up method by mixing epoxy and pineapple leaf fiber with particle size variation of 30 mesh, 40 mesh, 70 mesh, 100 mesh, and volume fraction ratio between filler and matrix 5/95, 10/90, 15/85 (v/v). Mechanical properties wich tested was impact strength and supported with SEM analysis. The results obtained show that the addition pineapple leaf fiber as filler in epoxy composites generally increase the impact strength of the composites, with best performance shown by 100 mesh particle size variation with ratio 90/10 (v/v) which from SEM analysis show that this variation having better filler distribution.
ANALISIS LAJU ALIR SAMPAH DAN EMISI CARBON YANG DIHASILKAN KOTA BANDA ACEH
Authors: M. Faisal  
Published: October 2019

This research aims to analyze the material flow of solid waste of Banda Aceh city by using Material Flow Analysis (MFA) method. The domestic wastes used in this research are limited to organic waste, plastic and paper. Results show that the solid wastes in Banda Aceh city do not treated well and thus required further treatment process. Wastes are separated at the kampong Jawa waste treatment process. Leaves waste are treated for compost, while no treatment process for plastic and paper wastes. The percentage of organic wastes, paper and plastic produced from Banda Aceh city were 89,1 %; 2,5 %; 0,74 %, respectively. Total amount of waste in the city of Banda Aceh is 86057,64 t/month producing carbon emission of 83726,6 t/month.
PENGARUH JUMLAH KATALIS ABU CANGKANG TELUR AYAM DAN WAKTU REAKSI GLISEROLISIS PADA PEMBUATAN MONO DAN DIASILGLISEROL (MDAG) DENGAN MENGGUNAKAN CO-SOLVENT TERT-BUTANOL
Authors: Margareth Nainggolan  , Retno Dian Purba  , Mhd. Yusuf Ritonga  
Published: October 2019

Mono and diacylglycerol is one of oil diversification products that its economics value is higher and its market prospect is brighter in this globalization era. The purpose of this research is to produce mono and diacylglycerol from Refined, Bleached, Deodorized Palm Oil by using waste egg shell as catalyst. Waste egg shell was calcined at temperatur 70oC and time 2 hours to forming active CaO as catalyst. Then the process continued with glycerolysis process. Glycerolysis process produced mono and diacylglyserol. Then mono and diacylglycerol was separated by using separator fannel. Then the upper layer was vaporated to separate mono and diacylglycerol from tert-butanol. Effect of various varible process such as amount of catalyst and glycerolysis time was observed in this research. The best result was at temperature 70oC, co-solvent and oil rasio 3:1 (v/b), reaction time 2 hours, and catalyst amount 4% from oil with maksimum purity 68,61%. Mono and diacylglycerol formed in this reasearh is w/o emulsifier with HLB 5,19. The result of this research showed that waste egg shell is suitable to be used as the source of cheap catalyst to produce mono and diacylglycerol.
PENGARUH KOMPOSISI DAN UKURAN SERBUK KULIT KERANG DARAH (ANADORA GRANOSA) TERHADAP KEKUATAN TARIK DAN KEKUATAN BENTUR DARI KOMPOSIT EPOKSI-PSSERBUK KULIT KERANG DARAH
Authors: Addriyanus  , Tommy  , Halimatuddahliana  
Published: October 2019

This study was aimed to investigate the effect of filler content and particle size of cockle-shell powder in tensile strength and impact strength of epoxy-PS composite. Epoxy resin was used as matrix, polyaminoamide as hardener, cockle-shell powder as reinforcement, polystyrene as toughening agent and chloroform as solvent. Filler content was varied from 10-50% and the macro particle was varied from 50-260 mesh. The composite was prepared by using compression moulding, then tensile test and flexural test were done. The results showed that addition of cockle-shell powder improved both tensile strength and impact strength of the composite. Addition of 30% (wt) reinforcement with 200 mesh particle size had given maximum tensile strength of 5,50 MPa and maximum impact strength of 30044,3 J/m2.
KRISTALISASI LIKOPEN DARI BUAH TOMAT (Lycopersicon esculentum) MENGGUNAKAN ANTISOLVENT
Authors: Deviana Christianty  , Sola Fide Gavra  , Zuhrina Masyithah  
Published: October 2019

Studies on the utilization of lycopene had been conducted to determine the effect of comparison feed and solvent (F/S) and the addition of methanol for extraction of lycopene from tomatoes using mixture solvent of hexane:ethyl acetate (1:1) followed by crystallization antisolvent. In this research, ripe tomatoes juice was used with volume 150 ml. Lycopene extract was obtained through extraction method at temperature of 70 °C and the stirring speed 7 rpm. The other method was by the addition of methanol as antisolvent for crystallization. As for changing variable in this study were a comparison of feed and solvent (F/S) 1:2; 1:2.5; 1:3; 1:3.5; 1:4 and 1:4,5, and the volume of methanol as antisolvent were 50 ml, 100 ml, 150 ml and 200 ml. The results of this research about influence of feed and solvent to lycopene yield extracted obtained at the optimum condition 1:4 with a volume of 200 ml antisolvent. Whereas the influence about addition of methanol as antisolvent as an agent of precipitation and maximum condition occurs on volume of 200 ml. Wavelength analysis of C=C linkage with Fourier Transform Infrared (FT-IR) detected at wavenumber 1519,91 cm-1, CH2 linkage detected at wavenumber 1446,61 cm-1, R-CH=CH-R linkage detected at wavenumber 979,84 cm-1. While, C-C and C-CH linkage detected at wavenumber 1138 and 1373,32 cm-1.
PEMANFAATAN FLAVONOID EKSTRAK DAUN KATUK (Sauropus androgynus (L) Merr) SEBAGAI ANTIOKSIDAN PADA MINYAK KELAPA
Authors: Indah Cikita  , Ika Herawati Hasibuan  , Rosdanelli Hasibuan  
Published: October 2019

In this research, the katuk leaves (Sauropus androgynus (L) Merr) extracted for get flavonoid which used as antioxidant for the coconut oil. This research aims to determine the effect of the extraction time, the volume of the solvent, and the type of solvent for the yield and total flavonoid concentration of the katuk leaves extract and then to determine the effect of total flavonoid concentration and contact time the flavonoid of katuk leaves extract as antioxidants in coconut oil. The process used is extraction of katuk leaves used the solvent such as ethanol, n-heksana and etil asetat then extract will be analysed the yield and total flavonoid concentration of the katuk leaves extract. Then extract with the total flavonoid concentration 6,668%, 7,748% and 27,909% was used as a sample and contacted in the coconut oil with the contact time of 2, 4 and 6 days. Then, analysis is done of the coconut oil is the acid number, the iodine number and the peroxide number. The result obtained in this research is the best extraction time of 6 hours with solvent volume of 1250 ml with the best type of solvent is ethanol, the yield of extract is 0,243% and total flavonoid concentration is 27,909%. The total flavonoid concentration increasing cause a decrease the acid number, the iodine number increase and decrease the peroxide number which proved that katuk leaves extract can be used as antioxidants in the coconut oil with the best result is the total flavonoid concentration in 27,909% where the acid number is 0,962 mg KOH/g, the iodine number is 38,705 g I2/100 g and the peroxide number is 13,333 Meq/kg. The contact time of flavonoid in the coconut oil which increasing cause oil properties is getting worse but the results are better than the oil without the addition of extract.
PEMBAKARAN PREMIKS UAP MINYAK KELAPA DALAM HELE-SHAW CELL
Authors: Hadi Saroso  
Published: October 2019

Coconut oil combustion characteristic is observed experimentally by evaporating oil in the boiler then mix it with air before being burned at various equivalence ratios in the Hele-shaw cell. The result shows that, coconut oil tends to break into glycerol and fatty acid due to hydrolysis reaction producing the flame propagation, where the fatty acid flame propagates first then glycerol flame. Micro-explosion occurs when moisture from fatty acid combustion is absorbed by glycerol, and higher heating due to higher flame speed produces more micro-explosion.
PENGARUH AGING PADA KEKUATAN TARIK (TENSILE STRENGTH) FILM LATEKS KARET ALAM BERPENGISI NANOKRISTALIN SELULOSA DAN PENYERASI ALKANOLAMIDA
Authors: Marfuah Lubis  , Nuim Hayat  , Hamidah Harahap  
Published: October 2019

Nanocrystalline cellulose is nano sized filler with high crystallinity and obtanained by hydrolysis of alpha cellulose from sugarcane bagasse. Tensile test of natural rubber latex film filled nanocrystalline cellulose and alkanolamide as compatibilizer after aging treatment have been done. Natural rubber latex films were prepared by coagulant dipping method and followed by vulcanization process at temperature 100 oC and 20 minutes. Aging treatment of natural rubber latex films have done at temperature 70 oC for 24 hours. Tensile test result of natural rubber latex filled nanocrystalline cellulose showed the tensile strength value of aged natural rubber latex film were lower than unaged one. However, tensile strength value of aged natural rubber latex film filled nanocrystalline cellulose modified alkanolamide were higher than unaged film.
PENGARUH BAHAN PENGISI SILIKA DAN SERBUK TANDAN KOSONG SAWIT (STKS) TERMODIFIKASI TERHADAP KEKUATAN BENTUR DAN DAYA SERAP AIR KOMPOSIT HIBRID POLIESTER TIDAK JENUH
Authors: Halimatuddahliana  , Johan Evander Sirait  , Fermadi Sirait  
Published: October 2019

This research aims to determine the effect of palm oil empty fruit bunches (POEFB) powder and silica into the matrix of unsaturated polyester resin (UPR) and the influence of chemical modification OPEFB with using acetic acid 50% (v / v). In this study, (UPR) was mixed with silica and OPEFB to weight ratio (UPR: Silica: OPEFB) 80: 20: 0, 80: 15: 5, 80: 10: 10, 80: 5: 15, 80: 0: 20 by hand lay-up method. Analysis was done by impact test, and analysis of scanning electron microscopy (SEM). Results showed that impact strength at a ratio of 80: 5: 15 was higher than those without modification viz. 3622.5 J / m2. In this case the chemical modification has lowered OPEFB polarity so that the interfacial tencion between the filler with a matrix became low resulting in good interfacial interaction and adhesion between matrix and fille. Impact strength values ​​were supported by the results of SEM. From water adsorption test, composite with chemical modification showed low values as compared without modification indicating that modification has lowered the polarity of OPEFB.
EKSTRAKSI ACETOGENIN DARI DAUN DAN BIJI SIRSAK (Annona muricata L) DENGAN PELARUT ASETON
Authors: Siswarni MZ  , Nurhayani  , Suci Damayanti Sinaga  
Published: October 2019

Annona muricata L contain bioactive compounds acetogenins. Acetogenins which was synthesized through reaction between polyketide derived-acetic acid with 35-39 carbon atom in fatty acid, is the secondary metabolite of Annonaceae plant. This research aims to determine the variable that influence in leaf and Annona muricata seed extraction so that high yield value can be obtained and to prove the presence of acetogenins compound qualitatively. The materials used are Annona muricata leaves, Annona muricata seeds and aceton. The changing variables in this research is the mass of the samples for Annona muricata leaves powder that are 15 g, 25 g, 35 g and Annona muricata seeds powder that are 10 g, 20 g, 30 g which the extraction time are 30 minutes, 40 minutes, 50 minutes and 60 minutes. This research divided into two steps. The first step is the extraction of Annona muricata leaves and Annona muricata seeds using soxhletation method with 250 mL acetone for Annona muricata leaves, 200 mL aceton for Annona muricata seeds and extraction temperature is ± 58 oC. The second step is purification of the extract using distillation process. In this research, the highest yield value extract of Annona muricata leaves obtained is 55,33% with 15g mass of sample and 60 minutes for the extraction time. The highest yield value extract of Annona muricata seeds obtained is 62 % with 10 g mass of sample and 40 minutes for the extraction time. FTIR analysis showed the presence of functional groups such as lactone, THF, hyrdroxyl and aliphatic chains which indicates acetogenins compound’s presence.
PENGARUH PERBANDINGAN TEMPURUNG KELAPA DAN ECENG GONDOK SERTA VARIASI UKURAN PARTIKEL TERHADAP KARAKTERISTIK BRIKET
Authors: Iriany  , Firman Abednego Sarwedi Sibarani  , Meliza  
Published: October 2019

This research used raw material water hyacinth and coconut shell. The purpose of this research is to get briquettes with high heating value and to obtain briquettes with good quality. Comparison of the base material mixed water hyacinth and coconut shell in this research is 1:1, 1:2, 1:3, 1:4 with variations in particle size of 10 mesh, 42 mesh and 60 mesh, and using an adhesive tapioca 10% from the weight of raw material. The results of measurement in this research was compared to the quality parameters such as SNI, Japan standard, British, and America. The survey results revealed that the ideal composition made from a mixture of water hyacinth and coconut shell is briquette in comparison 1:4 with particle size 60 mesh and have the highest of heating value is 6.851,3311 cal/g, the lowest ash content is 8,1918%, the lowest of moisture content is 1,0140%, levels of substance evaporates is 13,7890%, the value of density is 0.9836 g/cm3, the firing rate is 2,9x10 -3 g/sec and the compressive strength is 11,3234 kg/cm2. The results are in accordance to SNI, Japan standard, British, and America, while the compression pressure of briquette only accordance to British standard.
PENGARUH UKURAN PARTIKEL, WAKTU DAN SUHU PADA EKSTRAKSI FENOL DARI LENGKUAS MERAH
Authors: Rondang Tambun  , Harry P. Limbong  , Christika Pinem  , Ester Manurung  
Published: October 2019

Galangal is one of spices containing phenol. This study aims to product phenol in a liquid phase from galangal. The variations performed in this study involve the time of extraction (3 hours, 6 hours, 9 hours), temperature (30 oC, 45 oC, 60 oC) and particle size of raw material (70 mesh, 100 mesh, 140 mesh). One of the analysis in this study is the yield of phenol. The highest phenol in this study is about 4,5%. This result is obtained using 140 mesh of tray at 60°C of temperature and 9 hours of extraction time.
PEMBUATAN BIOSORBEN DARI BIJI PEPAYA (Carica papaya L) UNTUK PENYERAPAN ZAT WARNA
Authors: Siswarni MZ  , Lara Indra Ranita  , Dandri Safitri  
Published: October 2019

Biosorbent is a material that has a pore - pore lot, where the adsorption process can take place on the pore walls or occur in certain regions of the particles. Preparation from papaya seeds biosorbent using H2SO4 as an activator, and then used as a textile dye absorption, namely methyl orange, methyl violet and methyl red. This study aims to determine the optimum conditions in the manufacturing biosorbent from papaya seeds. Analysis is iodine number, surface area, and test the ability of sarap to dyes (methyl orange, methyl violet and methyl red). In the manufacture biosorbent of this papaya seeds, the method used is chemical activation process. This study uses papaya seeds as raw material and sulfuric acid as an activator. The concentration of sulfuric acid used 5%, 7%, 10% and the drying time of 30 minutes, 60 minutes, 90 minutes, and 120 minutes. Biosorbent mass of 0.5 g (2.5% of 20 ml), 1.0 g (5% of 20 ml) and 1.5 g (7.5% of 20 ml) with adsorption time of 20 minutes, 30 minutes, and 40 minutes for the absorption of the dye. The results showed the highest iodine gained 482.22 mg / g on the drying time of 120 minutes and a sulfuric acid concentration of 10% and the highest surface area was obtained 33.43556 m2 / g on the drying time of 120 minutes and a sulfuric acid concentration of 10%. The analysis results of the adsorption capacity for methyl violet dye that is 9.547 mg / g on biosorbent mass of 1.0 g and the adsorption time of 40 minutes..
PENGARUH SUHU, WAKTU, DAN KADAR AIR PADA PIROLISIS PELEPAH KELAPA SAWIT
Authors: Frist Silia  , Seri Maulina  
Published: October 2019

Palm plantations in Indonesia began to grow rapidly since the early 80s. The area of ​​Indonesia's oil palm in 2013 was 10.4 million ha and increased 4.69% annually. The production of palm midrib was about 22 midribs per tree per year with the weight of midrib meat ranging from 2.2 kg. The palm midrib is composed of cellulose, hemicellulose, and lignin, which can be used as liquid smoke. The purpose of this study was to analyze the effect of temperature and time of pyrolysis on the yield and quality of liquid smoke produced. The pyrolysis process of fractured palm was performed at 150 ºC, 200 ºC, and 250 ºC for 30 minutes, 60 minutes, 90 minutes. The results indicated that the yield of liquid smoke tends to decrease with increasing pyrolysis temperature, and tends to increase with increasing pyrolysis time in which the difficult condensed gas production increases with increasing temperature and time of pyrolysis. The highest yield of liquid smoke pyrolysis temperature of 150 OC with pyrolysis time 120 minutes that is equal to 43.47%. In this study, obtained the best results for a pH value of 3.1 is done at process temperatures of 250 ° C with processing time 60 minutes
OPTIMASI SINTESIS BIOSURFAKTAN LAURIL AMIDA DARI ASAM LAURAT DAN DIETANOLAMINA MENGGUNAKAN PELARUT HEXANE DAN ENZIM LIPASE TERIMOBILISASI
Authors: Denny Samuel Silaen  , Tjahjono Herawan  , Zuhrina Masyithah  , Hiskia Arapenta Ginting  
Published: October 2019

Lauril amide is one of nonionic surfactant and has potency to become an ecofriendly surfactant. The main problem on lauril amide synthesis is the low conversion of lauric acid. Optimation of lauril amide synthesis is done with three variabels which give influence of amidation reaction. One stage amidation was done by reacting lauric acid with diethanolamine using catalyst Novozyme 435® with substrate ratio lauric acid:diethanolamine 1:1; 2:1; 3:1; 4:1; 5:1, amount of catalyst 1,8; 4; 7; 10; 11,8% from lauric acid total amount, solvent ratio 0; 1:1; 2:1; 3:1; 4:1 from lauric acid total amount and reacted for 24 hours with temperature reaction 55oC and 500 rpm. Product is separated from catalyst using filtration method and then purified by washing with acetone and heated at temperature of 90 oC to remove solvent. Product has been analyzed with acid value to obtained percent conversion of lauril amide, determine of Hydrophilic Liphophilic Balance value, spectroscopy Fourier Transform Infrared and determine of critical micelle concentrasion. Percent conversion optimum has obtained 86,16% at condition substrate ratio 1:1, enzyme concentration Novozyme 435® 7% and solvent ratio 2:1. Analysis result of lauril amide surfactant gave the hidrophile liphophile balance value about 11,93, it means that lauril amide surfactant can be used as emultion oil in water.
PENGARUH MASSA KATALIS DAN WAKTU REAKSI PADA PEMBUATAN BIODIESEL DARI LIMBAH MINYAK JELANTAH DENGAN MENGGUNAKAN KATALIS HETEROGEN K2O DARI LIMBAH KULIT KAKAO
Authors: Jefry R Turnip  , Trio F. L. Tarigan  , Mersi Suriani Sinaga  
Published: October 2019

Waste cooking oil is a waste oil that comes from many types of cooking oils such as corn oil, vegetable oil, ect. The purpose of this research is to waste cooking oil as a raw material to form biodiesel with K2O as the solid catalyst from cocoa pod ash (CPA) which is calcined on temperature 650 oC within 4 hours. This oil contains a high level of Free Fatty Acid (FFA) that is 3.13%. Therefore, pretreatment should be done by using activated carbon (1% w/w) to reduce levels of FFA. The research will be observed the effect of reaction time and the mass of catalyst. The characteristics of biodiesel is analyzed according to the levels of methyl ester in biodiesel, density, and viscosity based on the Indonesian National Standard (SNI). The best conditions of biodiesel are obtained with the amount of catalyst is 6% (w/w) that is calcined at 650 °C, reaction time 180 minutes, ratio mol of alcohol : oil is 12: 1, and 65 oC reaction of temperature, resulting the purity and yield of biodiesel is 99,8% and 92,68%. The results of this research indicates that the use of waste cooking as a raw material is suitable in the manufacture of biodiesel.
The Correlation Between Listening Habit to English Song and Vocabulary Mastery
Authors: . Wardiansyah , S. Barnabas , . Elfrida 
Published: October 2019

ABSTRACTThe aims of this research were to find out the correlation between students’ listening habit to English song and their vocabulary mastery. This research applied correlational study which was used quantitative design. The subjects were 60 students of Third Grade Students of SMPN 06 Kota Bengkulu. The data were collected from two instruments: (1) questionnaire was used to get data about students’ listening habit to English song and (2) VLT test was used to get data about students’ vocabulary mastery. The result of calculation was using Pearson Product moment formula process by SPSS IBM Statistic Version 20 Program, which showed the score of rxy bigger than the score of r table (0,835 > 0,254). It means that Ha was accepted and H0 was rejected. In conclusions, there is a positive and significant correlation between listening habit to English song and vocabulary mastery of third grade students of SMPN 06 Kota Bengkulu.
Cultura científica para la educación del siglo XXI
Authors: Sanz Merino Noemí , López Cerezo José Antonio 
Published: October 2019

En este artículo abordamos la cuestión de cómo entender la cultura científica si queremos desarrollar un tipo de educación científica que sea socialmente provechosa en la presente sociedad del conocimiento. Para hacerlo, tomamos brevemente en consideración los contextos actuales de apropiación social de la ciencia y la tecnología desde el punto de vista de los estudios sobre ciencia, tecnología y sociedad (cts). Finalmente, ofrecemos nuestras propias consideraciones sobre cómo superar algunos retos que surgen a la hora de implementar la enseñanza de dicha cultura científica.