bluuebunny/crossref_metadata_2025_split huggingface dataset:
Physician Workforce Response to the COVID-19 Pandemic at an Academic Medical Center
Authors: Jacobs Laurie G. , Korcak Jason A. , Zetkulic Marygrace 
Published: October 2020

ABSTRACTObjectives:The aim of this study was to describe the planning, implementation, and outcome of an acute care physician supplemental workforce during the local coronavirus disease 2019 (COVID-19) surge at a 771-bed academic medical center, from March 25 to May 5, 2020, in New Jersey, United States.Methods:The Department of Medicine sought participation by “independent” and redeployed “employed” physicians to provide acute hospital care, as well as assistance with occupational health and family communication. Plans addressed training, compensation, clinical privileges, malpractice, and collaboration with the existing hospitalist service.Results:Redeployed employed physicians (81% internists) selected either acute care (n = 68; median age, 52 y [range, 32-72 y]; 28% female) or non-face-to-face supportive roles (n = 69; median age, 52 y [range, 32-84 y]; 28% female). The redeployed physician group totaled 474 twelve-h daytime shifts typically caring for 10 patients per day. Six employed physicians refused redeployment, and only 3 independent physicians participated (all acute care). Of note, COVID-19 infection occurred in 10 hospitalists and intensivists, and in several redeployed physicians.Conclusions:Successful physician workforce staffing for medical disasters, such as the COVID-19 pandemic, requires consideration of personal risk, as well as medicolegal, financial, and clinical competency issues.
Actualist versus Naturalist and Conceptual Realist Interpretations of Hegel's Metaphysics
Authors: Redding Paul 
Published: October 2020

AbstractThe understanding of Hegel's metaphysics that is here argued for—that it is a metaphysics of the actual world—may sound trivial or empty. To counter this, in part one the actualist reading of Hegel's idealism is opposed to two other currently popular interpretations, those of the naturalist and the conceptual realist respectively. While actualism shares motivations with each of these positions, it is argued that it is better equipped to capture what both aim to bring out in Hegel's metaphysics, but also better able to resist criticisms of each of these opposed positions made from the viewpoint of the other.Like the conceptual realist, the actualist wants to affirm the objectivity of concepts in the world—an idea that can seem antithetical to the naturalist. While the position of “liberal naturalism” makes concessions to such a position, this feature is more easily accommodated by the actualist. However, like the liberal naturalist, the actualist is also suspicious of an implicit “supernaturalist” dimension of conceptual realism and, by weakening the scope of realism to the actual world, is better able to avoid it.The second and third parts of the paper attempt to show how the actualist position is reflected in Hegel's account of judgments and syllogisms in The Science of Logic. His account of judgments provides an irreducible place for judgments that are object-presupposing on the one hand and subject-locating on the other. Because such judgments are the components of syllogisms, these syllogisms have objectivity, but this is a type of objectivity within which we, as subjects, are by necessity located. The actual world has a conceptual structure because we conceptualizing beings belong to it.
Vitamin D status in children and adults in Sweden: dietary intake and 25-hydroxyvitamin D concentrations in children aged 10–12 years and adults aged 18–80 years
Authors: Nälsén Cecilia , Becker Wulf , Pearson Monika , Ridefelt Peter , Lindroos Anna Karin , Kotova Natalia , Mattisson Irene 
Published: October 2020

Abstract
The study aimed to estimate vitamin D intake and plasma/serum 25-hydroxyvitamin D (25(OH)D) concentrations, investigate determinants of 25(OH)D concentrations and compare two 25(OH)D assays. We conducted two nationwide cross-sectional studies in Sweden with 206 school children aged 10–12 years and 1797 adults aged 18–80 years (n 268 provided blood samples). A web-based dietary record was used to assess dietary intake. Plasma/serum 25(OH)D was analysed by liquid chromatography-mass spectrometry (LC-MS) and immunoassay in adults and LC-MS/MS in children. Most participants reported a vitamin D intake below the average requirement (AR), 16 % of children and 33 % of adults met the AR (7⋅5 μg). In adults, plasma 25(OH)D below 30 and 50 nmol/l were found in 1 and 18 % of participants during the summer period and in 9 and 40 % of participants during the winter period, respectively. In children, serum 25(OH)D below 30 and 50 nmol/l were found in 5 and 42 % of participants (samples collected March–May), respectively. Higher 25(OH)D concentrations were associated with the summer season, vacations in sunny locations (adults), and dietary intake of vitamin D and use of vitamin D supplements, while lower concentrations were associated with a higher BMI and an origin outside of Europe. Concentrations of 25(OH)D were lower using the immunoassay than with the LC-MS assay, but associations with dietary factors and seasonal variability were similar. In conclusion, vitamin D intake was lower than the AR, especially in children. The 25(OH)D concentrations were low in many participants, but few participants had a concentration below 30 nmol/l.
Stochastic modeling of subglacial topography exposes uncertainty in water routing at Jakobshavn Glacier
Authors: MacKie Emma J. , Schroeder Dustin M. , Zuo Chen , Yin Zhen , Caers Jef 
Published: October 2020

AbstractSubglacial topography is an important feature in numerous ice-sheet analyses and can drive the routing of water at the bed. Bed topography is primarily measured with ice-penetrating radar. Significant gaps, however, remain in data coverage that require interpolation. Topographic interpolations are typically made with kriging, as well as with mass conservation, where ice flow dynamics are used to constrain bed geometry. However, these techniques generate bed topography that is unrealistically smooth at small scales, which biases subglacial water flowpath models and makes it difficult to rigorously quantify uncertainty in subglacial drainage patterns. To address this challenge, we adapt a geostatistical simulation method with probabilistic modeling to stochastically simulate bed topography such that the interpolated topography retains the spatial statistics of the ice-penetrating radar data. We use this method to simulate subglacial topography using mass conservation topography as a secondary constraint. We apply a water routing model to each of these realizations. Our results show that many of the flowpaths significantly change with each topographic realization, demonstrating that geostatistical simulation can be useful for assessing confidence in subglacial flowpaths.
To see or not to see: The roles of item properties and language knowledge in Chinese missing logographeme effect
Authors: Tong Xiuli , Deng Qinli , Deacon Hélène , Saint-Aubin Jean , Wang Suiping 
Published: October 2020

AbstractThis study examined how language knowledge and item properties (i.e., semantic relatedness and position) influenced Chinese missing logographeme effects. Eighty-four Chinese readers and 53 English readers were asked to search for the Chinese logographeme 口 while reading a Chinese prose passage. The target 口 appeared in five different positions (i.e., left, right, top, bottom, or inside), varying its degree of semantic relatedness to its embedded characters. The generalized linear mixed-effect model revealed a significant interaction between semantic relatedness and position in Chinese, but not in English, readers when visual complexity and frequency were controlled. For Chinese readers, a higher omission rate occurred when 口 appeared in the top and inside positions and exhibited low semantic relatedness with its embedded characters, whereas 口 was omitted more when it was positioned on the right and exhibited high semantic relatedness to its embedded characters. English readers exhibited a different omission pattern: 口 was omitted more when it appeared in the left or right position irrespective of semantic relatedness. In addition, 口 was omitted more in the inside, rather than the bottom, position. These findings suggest that the omission rate of the logographeme is determined by item properties at the sublexical level and the reader’s language knowledge.
Acute aortic dissection in a patient with Williams syndrome infected by COVID-19
Authors: Mamishi Setareh , Navaeian Ameneh , Shabanian Reza 
Published: October 2020

AbstractCardiovascular involvement in COVID-19 has different features. Here we report the ominous fate of a neglected adolescent with Williams syndrome that was infected by SARS-CoV-2 and ended by acute aortic dissection.
Validity and reliability of the Iranian version of the Yale Food Addiction Scale for obese women
Authors: Panahi Moghaddam Seyedeh Atefeh , Amiri Parisa , Eini Zinab Hassan , Saidpour Atoosa 
Published: October 2020

AbstractObjective:The face and construct validity of the Iranian version of the Yale Food Addiction Scale (YFAS) was evaluated, and the convergent validity and test–retest reliability of both Iranian and original versions of YFAS for obese women were assessed.Design:The internal consistency of the YFAS was analysed. Exploratory factor analysis for dichotomous data was performed by varimax rotation, polychoric correlation coefficients and confirmatory factor analysis (CFA). Convergent validity was established by evaluating the correlation between the original and the Iranian versions of YFAS and the Binge Eating Scale (BES). The intraclass correlation coefficient (ICC) was measured between test–retest results.Setting:A weight management clinic in Tehran.Participants:450 obese women.Results:The single-factor structure indicated that the factor loadings for all the items were > 0·5, except for three items (explained proportion variance = 51 %). Based on CFA, the single factor had a better fit to the data after excluding three items. The Kuder–Richardson-20 coefficient was 0·86 for the total twenty-two items. The symptom count and diagnostic version of both the Iranian (ICC = 0·92 and 0·87, respectively) and original YFAS (ICC = 0·92 and 0·86, respectively) were stable over 2 weeks. Both the symptom count and the diagnostic version of these two scales had significant correlations with the measures of BES (P < 0·001).Conclusions:The initial reliability and validity of the Iranian version of the YFAS among obese women are supported. Further studies should be conducted on men and normal/overweight samples.
Radiation chemistry in astrochemical models: From the laboratory to the ISM
Authors: Shingledecker Christopher N. , Ivlev Alexei , Kästner Johannes , Herbst Eric , Caselli Paola 
Published: October 2020

AbstractMost interstellar and planetary environments are suffused by a continuous flux of several types of ionizing radiation, including cosmic rays, stellar winds, x-rays, and gamma-rays from radionuclide decay. There is now a large body of experimental work showing that these kinds of radiation can trigger significant physicochemical changes in ices, including the dissociation of species (radiolysis), sputtering of surface species, and ice heating. Even so, modeling the chemical effects that result from interactions between ionizing radiation and interstellar dust grain ice mantles has proven challenging due to the complexity and variety of the underlying physical processes. To address this shortcoming, we have developed a method whereby such effects could easily be included in standard rate-equations-based astrochemical models. Here, we describe how such models, thus improved, can fruitfully be used to simulate experiments in order to better understand bulk chemistry at low temperatures.
Non-exploding and exploding core-collapse supernova models and the multimessenger predictions
Authors: Kotake Kei , Kuroda Takami , Takiwaki Tomoya 
Published: October 2020

AbstractWe present results of full general relativistic (GR), three-dimensional (3D) core-collapse simulation of a massive star with multi-energy neutrino transport. Using a 70Mȯ zero-metallicity star, we show that the black-hole (BH) formation occurs at ∼ 300 ms after bounce. At a few ∼ 10 ms before the BH formation, we find that the stalled bounce shock is revived by neutrino heating from the forming hot proto-neutron star (PNS), which is aided by vigorous convection behind the shock. Our numerical results present the first evidence to validate the BH formation by the so-called fallback scenario. Furthermore we present results from a rapidly rotating core-collapse model of a 27Mȯ star that is trending towards an explosion. We point out that the correlated neutrino and gravitational-wave signatures, if detected, could provide a smoking-gun evidence of rapid rotation of the newly-born PNS.
Infrared spectra of protonated and hydrogenated corannulene (C20H10) and sumanene (C21H12) using matrix isolation in solid para-hydrogen – implications for the UIR bands
Authors: Sundararajan Pavithraa , Tsuge Masashi , Baba Masaaki , Sakurai Hidehiro , Lee Yuan-Pern 
Published: October 2020

AbstractPolycyclic aromatic hydrocarbons (PAH) and their derivatives, including protonated and cationic species, are suspected to be carriers of the unidentified infrared (UIR) emission bands observed from the galactic and extragalactic sources. We investigated the infrared (IR) spectra of protonated nonplanar PAHs: corannulene (C20H10) and sumanene (C21H12), that are regarded as a fragments of a fullerene,C60. The protonated corannulene H+ C20H10 and sumanene H+ C21H12 were produced in seperate experiments by bombarding a mixture of corannulene/sumanene and para-hydrogen (p-H2) with electrons during deposition at 3.2 K. During maintenance of the electron-bombarded matrix in darkness the intensities of IR lines of protonated corannulene decreased because of neutralization by electrons that were slowly released from the trapped sites whereas the hydrogenated species were produced. The observed lines were classified into several groups according to their responses to darkness and secondary irradiation at 365 nm/385 nm LEDs. Spectral assignments were derived based on a comparison of the observed spectra with those predicted with the B3PW91/6-311+ +G(2d,2p) method. The observed IR spectrum of hub-H+ C20H10, the most stable protonated isomer, resembles several bands of the Class-A UIR bands.
Density diagnostics of photoionized outflows in active galactic nuclei
Authors: Mao Junjie 
Published: October 2020

AbstractPhotoionized outflows in active galactic nuclei (AGNs) are thought to influence their circumnuclear and host galactic environment. However, the distance of the outflow with respect to the black hole is poorly constrained, which limits our understanding of the kinetic power by the outflow. Therefore, the impact of AGN outflows on their host galaxies is uncertain. If the density of the outflow is known, its distance can be derived. Density measurement via variability studies and density sensitive lines have been used, albeit not very effective in the X-ray band. Good measurements are rather demanding or challenging for the current generation of (grating) spectrometers. The next generation of spectrometers will certainly provide data with better quality and large quantity, leading to tight constraints on the location and the kinetic power of AGN outflows. This contribution summarizes the state-of-the-art in this field.
Bridging the gap between laboratory astrophysics and quantum chemistry: The concept of potential energy surfaces
Authors: Rocha C. M. R. 
Published: October 2020

AbstractAn exotic molecular inventory exists in space. While some species have well-known terrestrial analogs, others are very reactive and can hardly survive in the laboratory timely to allow for their characterization. With an eye toward these latter, we highlight in this contribution the role of quantum chemistry in providing astrochemically relevant data where experiment struggles. Special attention is given to the concept of molecular potential energy surfaces (PESs), a key aspect in theoretical chemical physics, and the possible dynamical attributes taken therefrom. As case studies, we outline our current efforts in obtaining global PESs of carbon clusters. It is thus hoped that, with such an active synergy between theoretical chemistry and state-of-the-art experimental/observational techniques (the pillars to the modern laboratory astrophysics), scientists may gather the required knowledge to explain the origins, abundances and the driving force toward molecular complexity in the Universe.
Measured mass to stoichoimetric formula through exhaustive search
Authors: Orthous-Daunay François-Régis , Thissen Roland , Vuitton Véronique 
Published: October 2020

AbstractElectrospray ionisation has revolutionised mass spectrometry. Coupled to high mass resolution, it provides the stoichiometric formula of a lot of molecules in a mixture. The link between the mass spectrometry data and the chemical description relies on an interpretation of the measured masses. We present here the tools and tricks developed to exploit Orbitrap mass spectra. This piece of work focuses on the numerical method to assign a molecular formula to a measured mass. The problem is restrained to the solving of the Diophantine equation where the constant coefficients are stoichiometric groups. Peculiar case of a set of convenient groups is given with the chemical constraints it brings to the problem.
Effects of satellite lines in fittings of He-like triplets of X-ray Spectra
Authors: Zhang Lan , Xue Xiangxiang , Yuan Dawei , Wei Huigang , Wang Feilu , Zhao Gang 
Published: October 2020

AbstractWe estimate the wind speeds with a Bayesian inference and a Markov Chain Monte Carlo (MCMC) tool for the high resolution X-ray spectra of Vela X-1, to understand the effect of satellite lines on spectral analysis. After modelling continua and He-like triplets of the spectra with a parameterized two-component power-law model and a mullti-Gaussian model, respectively, we estimate the contamination from satellite lines, and improve the self-consistency of wind speeds derived from the He-like triplet lines of different elements. Moreover, our fitting shows that the column density of scatter component varies from phase to phase.
Questions about the evolution of ices, from diffuse molecular clouds to comets
Authors: Boogert A. C. A. 
Published: October 2020

AbstractThe surfaces of interstellar and circumstellar dust grains are the sites of molecule formation, most of which, except H2, stick and form ice mantles. The study of ice evolution thus seems directly relevant for understanding our own origins, although the relation between interstellar and solar system ices remains a key question. The comparison of interstellar and solar system ices relies evidently on an accurate understanding of the composition and processes in both environments. With the accurate in situ measurements available for the comet 67P/Churyumov-Gerasimenko with the Rosetta mission, improving our understanding of interstellar ices is the more important. Here, I will address three specific questions. First, while laboratory experiments have made much progress in understanding complex organic molecule (COM) formation in the ices, the question remains, how does COM formation depend on environment and time? Second, what is the carrier of sulfur in the ices? And third, can ice absorption bands trace the processing history of the ices? Laboratory experiments, ranging from infrared spectroscopy to identify interstellar ice species, to surface experiments to determine reaction parameters in ice formation scenarios, to heating and irradiation experiments to simulate space environments, are essential to address these questions and analyze the flood of new observational data that will become available with new facilities in the next 2-10 years.
Kuiper Belt object 2014MU69, Pluto and Phoebe as windows on the composition of the early solar nebula
Authors: Pendleton Y. J. , Cruikshank D. P. , Stern S. A. , Dalle Ore C. M. , Grundy W. , Materese C. , Protopapa S. , Schmitt B. , Lisse C. 
Published: October 2020

AbstractThe initial chemical composition of a proto-planetary nebula depends upon the degree to which 1) organic and ice components form on dust grains, 2) organic and molecular species form in the gas phase, 3) organics and ices are exchanged between the gas and solid state, and 4) the precursor and newly formed (more complex) materials survive and are modified in the developing planetary system. Infrared and radio observations of star-forming regions reveal that complex chemistry occurs on icy grains, often before stars even form. Additional processing, through the proto-planetary disk (PPD) further modifies most, but not all, of the initial materials. In fact, the modern Solar System still carries a fraction of its interstellar inheritance (Alexander et al.2017). Here we focus on three examples of small bodies in our Solar System, each containing chemical and dynamical clues to its origin and evolution: the small-cold classical Kuiper Belt object (KBO) 2014 MU69, Pluto, and Saturn’s moon, Phoebe. The New Horizons flyby of 2014 MU69 has given the first view of an unaltered body composed of material originally in the solar nebula at ~45 AU. The spectrum of MU69 reveals methanol ice (not commonly found), a possible detection of water ice, and the noteworthy absence of methane ice (Stern et al. 2019). Pluto’s internal and surface inventory of volatiles and complex organics, together with active geological processes including cryo-volcanism, indicate a surprising level of activity on a body in the outermost region of the Solar System, and the fluid that emerges from subsurface reservoirs may contain material inherited from the solar nebula (Cruikshank et al.2019a,b). Meanwhile, Saturn’s captured moon, Phoebe, carries high D/H in H2O (Clark et al. 2019) and complex organics (Cruikshank et al. 2008), both consistent with its formation in, and inheritance from, the outer region of the solar nebula. Together, these objects provide windows on the origin and evolution of our Solar System and constraints to be considered in future chemical and physical models of PPDs.
Asteroid collisions as origin of debris disks: Asteroid shape reconstruction from BNAO Rozhen photometry
Authors: Apostolovska G. , Vchkova Bebekovska E. , Kostov A. , Donchev Z. 
Published: October 2020

AbstractAs a result of collisions during their lifetimes, asteroids have a large variety of different shapes. It is believed that high velocity collisions or rotational spin-up of asteroids continuously replenish the Sun’s zodiacal cloud and debris disks around extrasolar planets (Jewitt (2010)). Knowledge of the spin and shape parameters of the asteroids is very important for understanding collision asteroid processes. Lately photometric observations of asteroids showed that variations in brightness are not accompanied by variations in colour index which indicate that the shape of the lightcurve is caused by varying illuminations of the asteroid surface rather than albedo variations over the surface. This conclusion became possible when photometric investigations were combined with laboratory experiments (Dunlap (1971)). In this article using the convex lightcurve inversion method we obtained the sense of rotation, pole solutions and preliminary shape of 901 Brunsia.
Natural transportation routes in the Solar System
Authors: Todorović Nataša 
Published: October 2020

AbstractThe aim of this work is to explain the possible mechanism in the early Solar System, by which water-rich asteroids may have been delivered to Earth. Carbonaceous (C-type) asteroids, with a large fraction of water molecules, dominate in the outer part of the asteroid belt and the possibility of their migration toward Earth is still not well explained. In this work, we observe very efficient dynamical routes along which C-type water-bearing asteroids are delivered to Earth.