bluuebunny/crossref_metadata_2025_split huggingface dataset:
Integrated geochemical study of Chichali Formation from Kohat sub-basin, Khyber Pakhtunkhwa, Pakistan
Authors: Zeb Shah Faisal , Zafar Muhammad , Jehandad Samina , Khan Tahseenullah , Siyar Syed Mamoon , Qadir Anwar 
Published: July 2020

AbstractAn integrated geochemical study was performed for the assessment of the hydrocarbon potential, environment of deposition, thermal maturity and the organic matter’s source of the Chichali Formation in the Kohat sub-basin of Pakistan. The analytical techniques used included the total organic carbon (TOC), Rock–Eval (RE), organic petrography, column chromatography (CC) and gas chromatography mass spectrometry (GC–MS). The quantity of the organic matter (i.e., TOC), Rock–Eval parameters (such as the original hydrogen index, oxygen index and Tmax) and maceral analyses revealed that the shales of the Chichali Formation have poor to good petroleum source potential with Kerogen type II presently shown as type III (hydrogen index, oxygen index and Tmax) due to thermal maturation and with higher marine organic matter. The extracts of the rock samples have high amount of short-chain n-alkanes with high ratios of tricyclic terpanes to hopanes (TCT/H), C27 to C29 stranes and low ratios of pristane to phytane (Pr/Ph), C19/C23 TCT and C20/C23 TCT. These ratios and lack of terrestrial biomarker (oleanane) are pointing toward algal/marine organic source deposited under anoxic environment. The dibenzothiophene-to-phenanthrene ratios (DBT/P) versus Pr/Ph cross-plot also confirms the anoxic environment with sulfate poor mixed shale/carbonate lithology. The drill cuttings show relatively high maturity compared to outcrop samples indicated by n-alkanes ratios, isoprenoids vs n-alkanes cross-plot, methyl-phenanthrene index (MPI-1), methyl-dibenzothiophene ratios and absence of saturate biomarkers. All the above findings reveal that the Chichali Formation had mature algal source with anoxic environment of deposition and may prove to be a poor to good hydrocarbon source rock.
Association of chronic kidney disease with outcomes in acute stroke
Authors: Tung Iong Man , Barlas Raphae S. , Vart Priya , Bettencourt-Silva Joao H. , Clark Allan B. , Sawanyawisuth Kittisak , Kongbunkiat Kannikar , Kasemsap Narongrit , Tiamkao Somsak , Myint Phyo K. 
Published: July 2020

AbstractPrevious studies have found an association between chronic kidney disease and poor outcomes in stroke patients. However, there is a paucity of literature evaluating this association by stroke type. We therefore aimed to explore the association between CKD and stroke outcomes according to type of stroke. The data consisting of 594,681 stroke patients were acquired from Universal Coverage Health Security Insurance Scheme Database in Thailand. Binary logistic regression was used to assess the relationship of CKD and outcomes, which were as follows; in-hospital mortality, long length of stay (>3 days), pneumonia, sepsis, respiratory failure and myocardial infarction. Results: after fully adjusting for covariates, CKD was associated with increased odds of in-hospital mortality in patients with ischemic (OR 1.32; 95% CI = 1.27–1.38), haemorrhagic (OR 1.31; 95% CI = 1.24–1.39), and other undetermined stroke type (OR 1.44; 95% CI = 1.21–1.73). CKD was found to be associated with increased odds of pneumonia, sepsis, respiratory failure and myocardial infarction in ischaemic stroke. While CKD was found to be associated with increase odds of sepsis, respiratory failure, and myocardial infarction, decrease odds of pneumonia was observed in patients with haemorrhagic stroke. In other undetermined stroke type, CKD was found to only be associated with increase odds of sepsis and respiratory failure, while there is no significant association of CKD and increase or decrease odds with pneumonia and myocardial infarction. CKD was associated with poor outcomes in all stroke types. CKD should be considered as part of stroke prognosis as well as identifying at risk patient population for in-hospital complications.
Molecular Design of Conjugated Small Molecule Nanoparticles for Synergistically Enhanced PTT/PDT
Authors: Shao Wei , Yang Chuang , Li Fangyuan , Wu Jiahe , Wang Nan , Ding Qiang , Gao Jianqing , Ling Daishun 
Published: July 2020

AbstractSimultaneous photothermal therapy (PTT) and photodynamic therapy (PDT) is beneficial for enhanced cancer therapy due to the synergistic effect. Conventional materials developed for synergistic PTT/PDT are generally multicomponent agents that need complicated preparation procedures and be activated by multiple laser sources. The emerging monocomponent diketopyrrolopyrrole (DPP)-based conjugated small molecular agents enable dual PTT/PDT under a single laser irradiation, but suffer from low singlet oxygen quantum yield, which severely restricts the therapeutic efficacy. Herein, we report acceptor-oriented molecular design of a donor–acceptor–donor (D–A–D) conjugated small molecule (IID-ThTPA)-based phototheranostic agent, with isoindigo (IID) as selective acceptor and triphenylamine (TPA) as donor. The strong D–A strength and narrow singlet–triplet energy gap endow IID-ThTPA nanoparticles (IID-ThTPA NPs) high mass extinction coefficient (18.2 L g−1 cm−1), competitive photothermal conversion efficiency (35.4%), and a dramatically enhanced singlet oxygen quantum yield (84.0%) comparing with previously reported monocomponent PTT/PDT agents. Such a high PTT/PDT performance of IID-ThTPA NPs achieved superior tumor cooperative eradicating capability in vitro and in vivo.
Feeding habits, movement, and reproduction of the predatory flat bark beetles Cathartus quadricollis (Coleoptera: Silvanidae) and Leptophloeus sp. (Coleoptera: Laemophloeidae) in Hawaii coffee and macadamia nut
Authors: Brill Eva , Follett Peter A. , Kawabata Andrea M. 
Published: July 2020

AbstractHawaii has a multitude of scolytine (Coleoptera: Curculionidae: Scolitinae) pests includingHypothenemus hampei, coffee berry borer, which is apest of coffee,Hypothenemus obscurus,tropical nut borer, a significant pest of macadamia nut, andXylosandrus compactus, black twig borer, a pest of many tropical and ornamental crops. The flat bark beetles,Carthartus quadricollis(Coleoptera: Silvanidae) andLeptophloeussp. (Coleoptera; Laemophloeidae), are known to predate on coffee berry borer and tropical nut borer but their natural history (feeding habits, reproduction and movement) are poorly understood. Studies were conducted using molecular, field, and laboratory assays to examine 1) flat bark beetle reproduction and movement in coffee and the broader agricultural landscape, 2) establishment of augmentative releases for biological control, and 3) predation rates onH. hampei,H. obscurusandX. compactus. Various life stages ofC. quadricollisandLeptophloeussp. were found in seven different plant species common to the agricultural landscape around coffee farms, suggesting these predators are feeding and reproducing on theses hosts. Molecular analysis indicated thatC. quadricollisandLeptophloeussp. predated onH. hampei, H. obscurusandX. compactusin coffee, macadamia nut, and mixed coffee-macadamia nut farms. Laboratory reared predators were recaptured near release sites on coffee farms at 1, 2, and 7 weeks after augmentative releases. Predation ofC. quadricollisonH. hampeieggs placed inside artificial coffee berries in coffee farms was about 40%. PredatorsC. quadricollisandLeptophloeussp. are natural enemies of some significant agricultural scolytine pests in Hawaii and have excellent potential for biological control with augmentative releases.
The influence of environmental microseismicity on detection and interpretation of small-magnitude events in a polar glacier setting
Authors: Carr Chris G. , Carmichael Joshua D. , Pettit Erin C. , Truffer Martin 
Published: July 2020

AbstractGlacial environments exhibit temporally variable microseismicity. To investigate how microseismicity influences event detection, we implement two noise-adaptive digital power detectors to process seismic data from Taylor Glacier, Antarctica. We add scaled icequake waveforms to the original data stream, run detectors on the hybrid data stream to estimate reliable detection magnitudes and compare analytical magnitudes predicted from an ice crack source model. We find that detection capability is influenced by environmental microseismicity for seismic events with source size comparable to thermal penetration depths. When event counts and minimum detectable event sizes change in the same direction (i.e. increase in event counts and minimum detectable event size), we interpret measured seismicity changes as ‘true’ seismicity changes rather than as changes in detection. Generally, one detector (two degree of freedom (2dof)) outperforms the other: it identifies more events, a more prominent summertime diurnal signal and maintains a higher detection capability. We conclude that real physical processes are responsible for the summertime diurnal inter-detector difference. One detector (3dof) identifies this process as environmental microseismicity; the other detector (2dof) identifies it as elevated waveform activity. Our analysis provides an example for minimizing detection biases and estimating source sizes when interpreting temporal seismicity patterns to better infer glacial seismogenic processes.
Reducing Risk as well as Inequality: Assessing the Welfare State's Insurance Effects
Authors: Hacker Jacob S. , Rehm Philipp 
Published: July 2020

AbstractLeading accounts of the politics of the welfare state focus on societal demands for risk-spreading policies. Yet current measures of the welfare state focus not on risk, but on inequality. To address this gap, this letter describes the development of two new measures,risk incidenceandrisk reduction, which correspond to the prevalence of large income losses and the degree to which welfare states reduce that prevalence, respectively. Unlike existing indicators, these measures require panel data, which the authors harmonize for twenty-one democracies. The study finds that large losses affect all income and education levels, making the welfare state valuable to a broad cross-section of citizens. It also finds that taxes and transfers greatly reduce the prevalence of such losses, though to varying degrees across countries and over time. Finally, it disaggregates the measures to identify specific ‘triggers’ of large losses, and finds that these triggers are associated with risks on which welfare states focus, such as unemployment and sickness.
How good are default investment policies in defined contribution pension plans?
Authors: Duque Daniel , Morton David P. , Pagnoncelli Bernardo K. 
Published: July 2020

AbstractDefined contribution (DC) pension plans have been gaining ground in the last 10–20 years as the preferred system for many countries and other agencies, both private and public. The central question for a DC plan is how to invest in order to reach the participant's retirement goals. Given the financial illiteracy of the general population, it is common to offer a default policy for members who do not actively make investment choices. Using data from the Chilean system, we discuss an investment model with fixed contribution rates and compare the results with the existing default policy under multiple objectives. Our results indicate that the Chilean default policy has good overall performance, but specific closed-loop policies have a higher probability of achieving desired retirement goals and can reduce the expected shortfall at retirement.
Does physical ill-health increase the risk of suicide? A census-based follow-up study of over 1 million people
Authors: Onyeka I. N. , Maguire A. , Ross E. , O'Reilly D. 
Published: July 2020

Abstract

Aims
Mental ill-health is a known risk factor for suicide mortality. However, the relationship between physical ill-health and suicide is less clear. This study examined the relationship between different aspects of physical ill-health and the risk of suicide death.

Methods
Data for 1 196 364 adults (aged 18 years and over) were identified from the 2011 Northern Ireland Census and linked to death registrations until the end of 2015. Multivariate logistic regression was used to construct models to test associations with likelihood ratio tests for interactions.

Results
Over one in eight individuals (13.7%) reported multimorbidity (⩾2 physical health conditions) and one in four (25.4%) identified having limitation of daily activities. During follow-up, 51 672 individuals died; 877 due to suicide. The gradient in suicide risk by number of physical conditions disappeared following adjustment for activity limitation. Individuals with a lot of activity limitation were over three times more likely to die by suicide (OR = 3.13, 95% CI 2.50–3.93) compared to those with no limitations though this was reduced to OR = 1.72 (95% CI 1.35–2.20) with adjustment for poor mental health. The relationship between activity limitation and suicide was most pronounced at younger ages (18–34 years).

Conclusions
This study suggests that it is the effect that physical illness has on a person's life, in terms of disruption to daily activity, rather than the number of conditions that predicts suicide risk, especially at younger ages. Improved awareness and better management of mental wellbeing of individuals with physical health conditions may help to reduce suicides, especially in younger people.
A Global Model for Iodine Speciation in the Upper Ocean
Authors: Wadley Martin R. , Stevens David P. , Jickells Tim D. , Hughes Claire , Chance Rosie , Hepach Helmke , Tinel Liselotte , Carpenter Lucy J. 
Published: July 2020

AbstractAn ocean iodine cycling model is presented, which predicts upper ocean iodine speciation. The model comprises a three‐layer advective and diffusive ocean circulation model of the upper ocean and an iodine cycling model embedded within this circulation. The two primary reservoirs of iodine are represented, iodide and iodate. Iodate is reduced to iodide in the mixed layer in association with primary production, linked by an iodine to carbon (I:C) ratio. A satisfactory model fit with observations cannot be obtained with a globally constant I:C ratio, and the best fit is obtained when the I:C ratio is dependent on sea surface temperature, increasing at low temperatures. Comparisons with observed iodide distributions show that the best model fit is obtained when oxidation of iodide back to iodate is associated with mixed layer nitrification. Sensitivity tests, where model parameters and processes are perturbed, reveal that primary productivity, mixed layer depth, oxidation, advection, surface freshwater flux, and the I:C ratio all have a role in determining surface iodide concentrations, and the timescale of iodide in the mixed layer is sufficiently long for nonlocal processes to be important. Comparisons of the modeled iodide surface field with parameterizations by other authors show good agreement in regions where observations exist but significant differences in regions without observations. This raises the question of whether the existing parameterizations are capturing the full range of processes involved in determining surface iodide and shows the urgent need for observations in regions where there are currently none.
Active Thrusting in an Intermontane Basin: The Kumysh Fault, Eastern Tian Shan
Authors: Wang Siyu , Jiao Ruohong , Ren Zhikun , Wu Chuanyong , Ren Guangxue , Zhang Huiping , Lei Qiyun 
Published: July 2020

AbstractFaulting and folding on the margins of intermontane basins play important roles in accommodating the Cenozoic deformation of the Tian Shan, an intracontinental orogen in central Asia. In the eastern Tian Shan, the southern margin of the elongated Kumysh Basin is bounded by a NE dipping thrust fault, the Kumysh Fault. We report the first investigation of the slip rate of this fault, which is constrained at two sites by profiling the faulted topography and dating the abandoned alluvial fan surfaces. We obtained the topographic data using the satellite stereo imagery and dated geomorphic units using cosmogenic nuclide (10Be) exposure ages and optically stimulated luminescence methods. The results from Monte Carlo simulations of the data suggest an average dip‐slip rate of ~0.35 mm/yr on the Kumysh Fault since 50–60 ka. The “best fit” models indicate an increase after ~5 ka, which may be apparent or caused by the most recent earthquakes. Structural analysis of the displaced strata on a trench wall suggest at least 2.8 m dip offset caused by the late Holocene earthquakes, which is similar to the heights of fault scarps (1.8–2.9 m) on the second youngest alluvial fans (5.6–5.2 ka). Using the dip angle of ~25–40°, we estimate ~0.31 mm/yr shortening rate across the Kumysh Fault during the late Quaternary. By comparing our results with other estimates published in the easternmost Tian Shan, we suggest that deformation within intermontane basins may accommodate up to 50% of the total late Quaternary shortening rate between the Junggar and Tarim blocks, with only the remaining half accommodated by the main, range‐bounding thrusts.
Comparison of Thermal and Microwave Paleointensity Estimates in Specimens Displaying Non‐Ideal Behavior in Thellier‐Style Paleointensity Experiments
Authors: Grappone J. Michael , Biggin Andrew J. , Barrett Thomas J. , Hill Mimi J. , Sprain Courtney J. 
Published: July 2020

AbstractDetermining the strength of the ancient geomagnetic field is vital to our understanding of the core and geodynamo, but obtaining reliable measurements of the paleointensity is fraught with difficulties. Over a quarter of magnetic field strength estimates within the global paleointensity database from 0 to 5 Ma come from Hawaii. Two previous studies on the SOH1 drill core gave inconsistent, apparently method‐dependent paleointensity estimates, with an average difference of 30%. The paleointensity methods employed in the two studies differed both in demagnetization mechanism (thermal or microwave radiation) and Thellier‐style protocol (perpendicular and original Thellier protocols)—both variables that could cause the strong differences in the estimates obtained. Paleointensity experiments have therefore been conducted on 79 specimens using the previously untested combinations of thermal‐perpendicular and microwave‐original Thellier methods to analyze the effects of demagnetization mechanism and protocol in isolation. We find that, individually, neither demagnetization mechanism nor protocol entirely explains the differences in paleointensity estimates. Specifically, we found that non‐ideal multidomain‐like effects are enhanced using the original Thellier protocol (independent of demagnetization mechanism), often resulting in paleointensity overestimation. However, we also find evidence, supporting recent findings from the 1960 Kilauea lava flow, that microwave‐perpendicular experiments performed without partial thermal remanent magnetization checks can produce underestimates of the paleointensity due to unaccounted‐for sample alteration at higher microwave powers. Together, these findings support that the true paleointensities fall between the estimates previously published and emphasize the need for future studies (thermal or microwave) to use protocols with both partial thermal remanent magnetization checks and a means of detecting non‐ideal grain effects.
Drought Onset and Termination in India
Authors: Shah Deep , Mishra Vimal 
Published: July 2020

AbstractDespite the implications of meteorological drought propagation to agricultural, hydrological, and groundwater droughts, the focus of previous studies has been primarily on meteorological droughts in India. We use the well‐calibrated and evaluated Variable Infiltration Capacity‐ Simple Groundwater Model (VIC‐SIMGM) to simulate soil moisture, runoff, and groundwater storage variability in India for the 1951–2016 period. The Integrated Drought Index (IDI) that combines meteorological, agricultural, hydrological, and groundwater droughts was developed for the 1951–2016 period for India. Using a spatial clustering algorithm based on the traditional interpoint distance metric, eight homogeneous clusters based on IDI were identified. The majority of clusters in India experience the onset and termination of droughts during the summer monsoon season (June–September). The analysis of moisture back trajectories using the Hybrid Single‐Particle Lagrangian Integrated Trajectory (HYSPLIT) model showed that the Arabian Sea and Bay of Bengal are the two major moisture sources for the identified clusters in India. We performed the Empirical Orthogonal Function (EOF) and Maximum Covariance Analysis (MCA) using monthly IDI and Sea Surface Temperature (SST) to evaluate the influence of long‐term climate variability on droughts in India. Droughts based on 1‐month IDI that affect a majority of drought clusters are associated with the positive phase of El Nino Southern Oscillations (ENSO) and Indian Ocean Dipole (IOD). On the other hand, drought clusters in the Gangetic Plain and peninsular India are affected by the SST warming over the Indian Ocean. Overall, drought clusters based on IDI, their moisture source, and large‐scale teleconnection can assist in drought management and assessment in India.
Efficient full-path optical calculation of scalar and vector diffraction using the Bluestein method
Authors: Hu Yanlei , Wang Zhongyu , Wang Xuewen , Ji Shengyun , Zhang Chenchu , Li Jiawen , Zhu Wulin , Wu Dong , Chu Jiaru 
Published: July 2020

AbstractEfficient calculation of the light diffraction in free space is of great significance for tracing electromagnetic field propagation and predicting the performance of optical systems such as microscopy, photolithography, and manipulation. However, existing calculation methods suffer from low computational efficiency and poor flexibility. Here, we present a fast and flexible calculation method for computing scalar and vector diffraction in the corresponding optical regimes using the Bluestein method. The computation time can be substantially reduced to the sub-second level, which is 105 faster than that achieved by the direct integration approach (~hours level) and 102 faster than that achieved by the fast Fourier transform method (~minutes level). The high efficiency facilitates the ultrafast evaluation of light propagation in diverse optical systems. Furthermore, the region of interest and the sampling numbers can be arbitrarily chosen, endowing the proposed method with superior flexibility. Based on these results, full-path calculation of a complex optical system is readily demonstrated and verified by experimental results, laying a foundation for real-time light field analysis for realistic optical implementation such as imaging, laser processing, and optical manipulation.