bluuebunny/crossref_metadata_2025_split huggingface dataset:
The Interplay of Open-Shell Spin-Coupling and Jahn-Teller Distortion in Benzene Radical Cation Probed by X-ray Spectroscopy
Authors: Vidal Marta L. , Epshtein Michael , Scutelnic Valeriu , Yang Zheyue , Xue Tian , Leone Stephen , Krylov Anna I. , Coriani Sonia 
Published: September 2020

We report a theoretical investigation and elucidation of the x-ray absorption spectra of neutral benzene and of the benzene cation. The generation of the cation by multiphoton ultraviolet (UV) ionization as well as the measurement ofthe carbon K-edge spectra of both species using a table-top high-harmonic generation (HHG) source are described in the companion experimental paper [M. Epshtein et al., J. Phys.Chem. A., submitted. Available on ChemRxiv]. We show that the 1sC -> pi transition serves as a sensitive signature of the transient cation formation, as it occurs outside of the spectral window of the parent neutral species. Moreover, the presenceof the unpaired (spectator) electron in the pi-subshell of the cation and the high symmetry of the system result in significant differences relative to neutral benzene in the spectral features associated with the 1sC ->pi* transitions. High-level calculations using equation-of-motion coupled-cluster theory provide the interpretation of the experimental spectra and insight into the electronic structure of benzene and its cation.The prominent split structure of the 1sC -> pi* band of the cation is attributed to the interplay between the coupling of the core -> pi* excitation with the unpaired electronin the pi-subshell and the Jahn-Teller distortion. The calculations attribute most ofthe splitting (~1-1.2 eV) to the spin coupling, which is visible already at the Franck-Condon structure, and estimate the additional splitting due to structural relaxation tobe around ~0.1-0.2 eV. These results suggest that x-ray absorption with increased resolution might be able to disentangle electronic and structural aspects of the Jahn-Tellereffect in benzene cation.
sujeito e a coragem da verdade
Authors: Nunes Michael Douglas de Almeida , Caminha Iraquitan de Oliveira 
Published: September 2020

Resumo: Neste artigo procuramos fazer uma análise daquilo que se acredita ser o cerne do pensamento filosófico de Michel Foucault: a relação existente entre o sujeito e a verdade que o constitui como sujeito moral. Perpassando a antiguidade grega junto com Foucault, encontramos as práticas e técnicas de cuidar de si que determinam a profunda relação entre a verdade e o sujeito que se busca elucidar. Ademais, na explicitação de uma historiografia do conceito do cuidado de si e da parresia, Foucault revela que uma verdade única e universal para o sujeito é impossível. O que é imprescindível para a constituição do sujeito moral e político são verdades que revelam uma subjetividade históricana filosofia foucaultiana.
ensino religioso no processo de formação do aluno
Authors: Pereira Rodrigo de Araújo , Kill Celso 
Published: September 2020

Esse artigo trata do Ensino religioso no processo de formação do aluno, procurando refletir sobre as contribuições e as lacunas surgidas nesse processo de ensino--aprendizagem. A religiosidade surgiu com os primeiros seres humanos que manifestavam suas crenças nos seres inanimados representados nos fenômenos naturais: o relâmpago, a lua, o sol, as estrelas. A polêmica sobre a obrigatoriedade do ensino religioso em escolas públicas e privadas traz elementos da liberdade de expressão e da desvinculação expressa da administração pública das entidades religiosas a não ser as expressamente permitidas na legislação vigente. O objetivo geral deste artigo é refletir sobre a importância do ensino religioso na formação do aluno. Metodologicamente, essa é uma pesquisa bibliográfica, que utiliza materiais bibliográficos referentes ao tema levantados junto a fontes fidedignas voltadas à pesquisa científica e acadêmica. Como resultados, é apresentada a proposta da formação de professores especialistas ao nível de Licenciatura em Ciências da Religião que promoverão o ensino baseado na filosofia e sociologia das religiões de modo que o aluno conheça o fenômeno religioso e não a catequização conforme uma determinada religião.
O papel de pirronismo em Pensées, de Pascal
Authors: Sousa Joelson Pereira de 
Published: September 2020

Este artigo discute a posição de Pascal quanto ao pirronismo nas filosofias de Descartes e Montaigne, ao mesmo tempo em que esboça uma compreensão pascaliana acerca do tema, especialmente tratando a questão da “razão cética”. Mostra que a discussão se encontra em articulação com duas problemáticas clássicas da filosofia moderna
Ethical Theories in Research Evaluation: An Exploratory Approach
Authors: Biagetti Maria Teresa , Gedutis Aldis , Ma Lai 
Published: September 2020

Research evaluation encompasses the practices of assessing research quality and impact at various stages of research. The processes and criteria of research evaluation vary depending on the nature and objectives of the assessment. Different research evaluation systems influence the research strategies of universities and institutes. There are, however, some known issues of research evaluation with regards to the peer review and, most prominently, the use of citation-based metrics, which lead to recent calls for responsible use of metrics. In this paper, we argue that there is a need for ethical theories for considering research evaluation and that research evaluation ethics, as an overlapping area between research ethics and evaluation ethics, deserve its own treatment. The core of the article consists of a discussion of the most influential ethical theories in the context of the research evaluation, including the deontological ethics, the consequentialist ethics and the virtue ethics. The aim is to highlight the need to assume an ethical view that combines the deontological and the consequentialist concepts, adopting ‘common good’ as the most likely pillar for the research evaluation procedures. We propose that the mixed approach would be useful for developing a framework for research evaluation ethics and for analysing ethical approaches and ethical dilemmas in research evaluation. Policy HighlightsThe misuses and abuse of evaluative metrics have been discussed and debated in many high-profile publications including the San Francisco Declaration on Research Assessment (DORA), The Metrics Tide, the Leiden Manifesto, and the Hong Kong Principles. There are also many studies stating the limitations of and bias in peer review.The debates and discussions, however, have not been explored in light of ethical theories. The article considers also good practices in evaluation, including the American Evaluation Association Guiding Principles for Evaluators (AEA 2018), the Australasian Evaluation Society Guidelines for the ethical conduct of evaluations (AES 2000, 2010, 2013) the UK Evaluation Society Guidelines for Good Practices in Evaluation (UK 2019) and the United Nations Ethical Guidelines for Evaluation (UNEG 2008).The paper argues that ethical theories are useful in understanding ethical assumptions and ethical dilemmas in research evaluation and are pertinent in future design and development of research evaluation processes and criteria.Ethical theories that can construct ethical principles for research evaluation, including deontological and consequentialist ethics, taking into account the Mertonian normative theory, have been examined.In order to address the issues of research evaluation, we propose a mixed approach that combines the deontological and the consequentialist concepts that is able to infringe the boundaries of the rivaling theories and provide basis needed for research evaluation ethics.
A Case Study Exploring Coaching Practice and Coaching Perspectives at One Soccer (Football) Club
Authors: Karagiannis Konstantinos , Pill Shane 
Published: September 2020

This study investigated the extent to which three local club football (Soccer) coaches were aligning their practice with the Football Federation Australia (FFA) curriculum and if they are aware of and incorporating the Game Sense coaching methods advocated by the Australian Sports Commission through the Playing for Life Philosophy. There is currently a lack of research in the sport of Soccer and how the Game Sense coaching approach has been received and understood in Australian Soccer coaching. Further, the degree of alignment club coaches have with the FFA curriculum has only been investigated once, and that was in Sydney. Therefore, little is known about the implementation of the FFA curriculum in community coaching settings. This study found the three coaches to have good understanding of the mechanics of the FFA curriculum, and support for the use of small-sided games as a preferred practice form. The coaches had no understanding of the process of shaping and focussing player game development using the player-centred inquiry focus of the Game Sense approach.
Aplikasi e-diary DM sebagai alat monitoring manajemen selfcare pengelolaan diet pasien DM
Authors: Luawo Herman Priyono , Sjattar Elly Lilianty , Bahar Burhanuddin , Yusuf Saldy , Irwan Andi Masyitha 
Published: September 2020

Pendahuluan : Penatalaksanaan DM sangat penting dilakukan, upaya tersebut dapat melalui keterlibatan langsung penderita melalui program manajemen perawatan atau self care management. Tujuan : Mengetahui hasil monitoring aplikasi e-diary tehadap pegelolaan diet pasien diabetes mellitus. Metode : Menggunakan metode quasi eksperimen dengan rancangan pre post test with control group design, analisa data dilakukan dengan uji Wilcoxon dan Mann Whitney. Hasil : penelitian menujukkan bahwa terdapat pengaruh 75,9 %, penerapan e-diary memberikan kontribusi signifikan terhadap manajemen selfcare (P value=0,000). Pada kelompok intervensi sebelum diterapkan e-diary adalah 7,13 (SD 0,756), sedangkan sesudah dilakukan intervensi diperoleh nilai rata-rata pengeloaan diet sebesar 7,80 (SD 0,561) disimpulkan bahwa. Hasil tersebut menunjukkan adanya peningkatan skor rata-rata pengelolaan diet pada pasien DM sebesar 0,80. Hasil analisis uji Wilcoxon Rank Test diperoleh nilai p value 0,006. Penerapkan e-diary pada pasien diabetes militus secara bermakna dan signifikan efektif dalam meningkatkan manajemen selfcare pengelolaan diet pada pasien diabetes militus.
Respon psikologis pada perempuan pasca keguguran
Authors: Rahayu Tutik , Wahyuni Sri 
Published: September 2020

Pendahuluan: Kehamilan merupakan sesuatu yang sangat didambakan pada perempuan setelah menikah namun sebagian dari mereka mengalami kehamilan yang berujung keguguran.Keguguran ini berdampak pada kondisi psikologis. Penelitian ini bertujuan mengggali respon psikologis perempuan pasca keguguran. Metode:Metodeyang digunakan, yaitu kualitatif dengan pendekatan fenomenologi. Partisipan berjumlah 10 perempuan melaluiwawancara mendalam dengan pertanyaan semi terstruktur.Hasil diolah menurut langkah-langkah dari Colaizzi.Hasil: Ditemukan respon psikologis perempuan pasca keguguran,yaitu kesedihan kehilangan janin,merasa gagal menjadi orang tua, menyesal, ketakutan tidak bisa hamil lagi. Sebagian kehamilan pada perempuan dapat mengalami keguguran spontan yang memiliki dampak pada kondisi psikologis. Simpulan:Perawat mempunyai peran yang penting dalam upaya membantu perempuan yang mengalami keguguran spontan agar respon psikologis yang muncul sebagai dampak dari kehilangan janin tidak berlanjut menjadi respon kesedihan yang memanjang,sehingga dapat mengakibatkan perempuan jatuh pada kondisi yang lebih terpuruk, seperti ibu terus menerus menyalahkan diri sendiri, merasa tidak bergairah menghadapi hidup, merasa tidak percaya diri dapat menjadi seorang ibu dimasa yang akan datang dan depresi.
PENGABDIAN KEPADA MASYARAKAT (PKM) PENGEMBANGAN MARKETING WEBSITE DAN DESAIN KEMASAN PADA UKM BUMI CIPTA SEJAHTERA SURABAYA
Authors: Prasetya Ardian Jaya , Laksono Yunanto Tri , Hidayat Wahyu 
Published: September 2020

Pengembangan desain kemasan sangat diperlukan guna menghasilkan hasil dan kualitas dari kemasan yang lebih variatif. Kaitannya dengan perkembangan era 4.0 adalah kualitas dari produk yang akan dipasarkan juga terpengaruh dari label pada kemasan. Guna mencitrakan sebuah produk yang lebih unggul selain dari hasil kualitas pada produksinya. Dengan adanya kualitas produk dan kemasan yang menarik menjadikan produk yang dipasarkan kepada masyarakat bisa bersaing dengan baik dengan kualifikasi produk unggulan. Munculnya produk-produk unggulan lain yang memiliki kualifikasi yang baik juga menjadikan daya saing pada produk semakin beragam, entitas pada nilai produk tidak hanya dinilai dari segi kualitas produksi, higienitas, kemasan yang dipakai, namun juga dari kualifikasi branding pada kemasan. Tujuan yang didapatkan pada penyelenggaraan program ini yaitu pengembangan desain kemasan melalui teknologi dalam bentuk analog, digital (software), dan juga website, guna menunjang dan mengankat potensi masyarakat dalam memperluas kemampuan dan keunggulan produknya, sehingga pada proses pemasaran produk yang dihasilkan dapat lebih disebarluaskan tidak hanya pada wilayah lokal saja namun juga dapat disebarluaskan pada cakupan yang lebih luas yaitu nasional dan juga internasional. Pada kegiatan program yang dilakukan ini metode yang digunakan adalah pendampingan tentang bagaimana pelaku UKM dan UMKM dapat mengembangkan dasar dan pola pada produknya melalui desain kemasan dengan bentuk penggambaran desain menggunakan sketsa dasar gambar desain kemasan (analog), dan juga menggunakan desain dengan bentuk digital software. Proses pendampingan dilakukan secara langsung dimana pelaku UKM dan UMKM diberikan pembelajaran secara dasar sehingga diharapkan mampu mengembangkan inovasi dalam bentuk desain kemasarn yang lebih kreatif dan inovatif. Hasil akhir yang diberikan adalah berupa X-banner, dan juga peralatan dasar dalam membuat desain kemasan dasar. Dari bentuk hasil pada penelitian ini adalah pemberian label pada kemasan produk dalam bentuk botol dengan label dan kemasan yang terbaru. Diharapkan dengan hasil ini dapat menunjang potensi dalam pengembangan pemasaran. Kata Kunci: Desain Kemasan, Website, UKM Bumi Cipta Sejahtera Guna Surabaya.
Technical and radiographic considerations for magnetic resonance imaging–guided focused ultrasound capsulotomy
Authors: Davidson Benjamin , Mithani Karim , Huang Yuexi , Jones Ryan M. , Goubran Maged , Meng Ying , Snell John , Hynynen Kullervo , Hamani Clement , Lipsman Nir 
Published: September 2020

OBJECTIVE
Magnetic resonance imaging–guided focused ultrasound (MRgFUS) is an emerging treatment modality that enables incisionless ablative neurosurgical procedures. Bilateral MRgFUS capsulotomy has recently been demonstrated to be safe and effective in treating obsessive-compulsive disorder (OCD) and major depressive disorder (MDD). Preliminary evidence has suggested that bilateral MRgFUS capsulotomy can present increased difficulties in reaching lesional temperatures as compared to unilateral thalamotomy. The authors of this article aimed to study the parameters associated with successful MRgFUS capsulotomy lesioning and to present longitudinal radiographic findings following MRgFUS capsulotomy.

METHODS
Using data from 22 attempted MRgFUS capsulotomy treatments, the authors investigated the relationship between various sonication parameters and the maximal temperature achieved at the intracranial target. Lesion volume and morphology were analyzed longitudinally using structural and diffusion tensor imaging. A retreatment procedure was attempted in one patient, and their postoperative imaging is presented.

RESULTS
Skull density ratio (SDR), skull thickness, and angle of incidence were significantly correlated with the maximal temperature achieved. MRgFUS capsulotomy lesions appeared similar to those following MRgFUS thalamotomy, with three concentric zones observed on MRI. Lesion volumes regressed substantially over time following MRgFUS. Fractional anisotropy analysis revealed a disruption in white matter integrity, followed by a gradual return to near-baseline levels concurrent with lesion regression. In the patient who underwent retreatment, successful bilateral lesioning was achieved, and there were no adverse clinical or radiographic events.

CONCLUSIONS
With the current iteration of MRgFUS technology, skull-related parameters such as SDR, skull thickness, and angle of incidence should be considered when selecting patients suitable for MRgFUS capsulotomy. Lesions appear to follow morphological patterns similar to what is seen following MRgFUS thalamotomy. Retreatment appears to be safe, although additional cases will be necessary to further evaluate the associated safety profile.
Long-term impact of obesity on patient-reported outcomes and patient satisfaction after lumbar spine surgery: an observational study
Authors: Park Christine , Garcia Alessandra N. , Cook Chad , Shaffrey Christopher I. , Gottfried Oren N. 
Published: September 2020

OBJECTIVEObese body habitus is a challenging issue to address in lumbar spine surgery. There is a lack of consensus on the long-term influence of BMI on patient-reported outcomes and satisfaction. This study aimed to examine the differences in patient-reported outcomes over the course of 12 and 24 months among BMI classifications of patients who underwent lumbar surgery.METHODSA search was performed using the Quality Outcomes Database (QOD) Spine Registry from 2012 to 2018 to identify patients who underwent lumbar surgery and had either a 12- or 24-month follow-up. Patients were categorized based on their BMI as normal weight (≤ 25 kg/m2), overweight (25–30 kg/m2), obese (30–40 kg/m2), and morbidly obese (> 40 kg/m2). Outcomes included the Oswestry Disability Index (ODI) and the visual analog scale (VAS) for back pain (BP) and leg pain (LP), and patient satisfaction was measured at 12 and 24 months postoperatively.RESULTSA total of 31,765 patients were included. At both the 12- and 24-month follow-ups, those who were obese and morbidly obese had worse ODI, VAS-BP, and VAS-LP scores (all p < 0.01) and more frequently rated their satisfaction as “I am the same or worse than before treatment” (all p < 0.01) compared with those who were normal weight. Receiver operating characteristic curve analysis revealed that the BMI cutoffs for predicting worsening disability and surgery dissatisfaction were 30.1 kg/m2 and 29.9 kg/m2 for the 12- and 24-month follow-ups, respectively.CONCLUSIONSHigher BMI was associated with poorer patient-reported outcomes and satisfaction at both the 12- and 24-month follow-ups. BMI of 30 kg/m2 is the cutoff for predicting worse patient outcomes after lumbar surgery.
PENGARUH PERSEPSI KEPEMIMPINAN TRANSFORMASIONAL TERHADAP KREATIVITAS DOSEN DENGAN EFIKASI DIRI KREATIF SEBAGAI PEMEDIASI
Authors: Azliyanti Elfitra , Jadmiko Purbo , Utami Wiry 
Published: September 2020

AbstractThis study aims to identify and analyze the role of perception of transformational leadership and creative self-efficacy of employee (lecturer) creativity. The research methodology used is explanatory research through hypothesis testing. The object and population of this study are Bung Hatta University Lecturers. The sampling technique used was purposive sampling with sample criteria was Bung Hatta University Lecturer who had working period more than 1 (one) year (n = 170). The data analysis technique in this study use SEM-PLS (Smart PLS). This study consists of three hypotheses and the research results obtained from the study of perceptions of transformational leadership has no effect on employee creativity, Creative self-efficacy has a positive effect on employee creativity and creative self-efficacy mediates the relationship of perception of transformational leadership on employee creativity.Keywords : perception of transformational leadership, employee creativity , Creative self-efficacy
THE EFFECT OF THE CHARACTER QUOTES STRATEGY ON THE STUDENTSâ€™ READING ABILITY
Authors: Rosmiyati Evi 
Published: September 2020

The problem in this study â€œIs there any significant effect of the application of Character Quotes Strategy on the students reading ability on narrative text to the eighth grade students of PGRI junior high school of Tebedakâ€. The objective of the study was to find out whether or not there were significant effect of the application of Character Quotes Strategy on the students reading ability on narrative text to the eighth grade students of PGRI junior high school of Tebedak. The population was the eighth grade students of PGRI junior high school of Tebedak. The sample was 30 students chosen by using purposive sampling. The method used in this study was the poor experimental method. In collecting the data, the writer used written test consisted of 40 items in the form of multiple choice tests. The written test was used to collect the data and analyzed through the matched t-test. Based on the studentsâ€™ scores, it is found that it is significant effect of the application of Character Quotes Strategy on the students reading ability on narrative text to the eighth grade students of PGRI Junior High School of Tebedak. The studentsâ€™ achievement can be seen from the average of their score in pre-test it was 56.33 and the average score of post-test was 74.58. The t-obtain 14.919 exceeding 1.699 as it is critical value. In indicated that the Ho was rejected and Ha was accepted. It means that it was significant effect of the application of Character Quotes Strategy on the students reading ability on narrative text to the eighth grade students of PGRI Junior High School of Tebedak.Â Keywords: teaching reading, narrative texts, Character Quotes Strategy
THE PERSPECTIVE OF THE TENTH GRADE STUDENTS OF MUHAMMADIYAH VOCATIONAL HIGH SCHOOL 2 OF PALEMBANG TOWARDS LEARNING WRITING DESCRIPTIVE TEXTS THROUGH CONTENT-BASED INSTRUCTION (CBI)
Authors: Muhammad Ammarullah , Mulyadi Mulyadi , Hermansyah Hermansyah 
Published: September 2020

The problem of this study was â€œHow are students perspective of writing descriptive text through content-based instruction (CBI)?â€. Therefore, the objective of this study was to know the perspective of the students learning writing descriptive texts through content-based instruction. This study applied qualitative method. The population of this study was the tenth grade students of accountant 1 class in the academic year of 2019/2020 with the total of 30 students taken by using purposive sampling. The data were collected by using questionnaire, and were analyzed into interpretation. Based on the interpretation of students perspective of content-based instruction, the students said that content-based instruction could Â help them to improve their ability to write descriptive text.Keywords: Perspective, Writing, Descriptive Texts, and Content-Based Instruction.